炭黑MSDS of carbon black
炭黑MSDS
blacks. The foregoing are registered trade names of Cabot Corporation, and denote
physical differences in carbon black grades.
Manufacturer抯 Product Code: Not applicable.
MSDS
Page 2 of 6
MATERIAL SAFETY DATA SHEET
Swallowed: None expected.
Eye: Mechanical irritant with no adverse effects.
Skin: None expected but may dry skin with prolonged exposures. Use of quality barrier cream can prevent skin dryness.
Inhaled: None expected. Temporary discomfort to the upper respiratory tract may occur due to inhalation of dust concentrations above the OEL.
Human Studies: Epidemiological studies of workers in the carbon black producing industries of North America and Western Europe show no evidence of clinically significant, adverse health effects due to occupational exposure to carbon black.
炭黑msds.doc
材料安全数据表1.化学品及企业信息化学品中文名称炭黑编码 111俗名/商品名炭黑生效日期化学品英文名称 calcium hypochlorite企业名称上海卡博特化工有限公司企业应急电话地址邮编国家应急电话传真电子邮件地址2.成分 / 组成信息□混合物主要成分■纯品危害成分浓度CAS No. 1333-86-43.危险性概述危险性类别不是危险品侵入途径呼吸，眼睛接触，皮肤接触。
吸入刺激鼻腔、嘴、喉；接触刺激皮肤和眼睛；长期暴露，会损伤皮肤和指甲，造成暂时或永健康危害久性损伤，伤害肺和呼吸道，并对心脏产生不良影响。
慢性接触引起咳嗽、咳痰、烦燥、胸痛、头痛、肺损害、气管炎、皮疹。
健康危害 ( 蓝色 ) ：1环境危害燃烧危险4.急救措施皮肤接触用肥皂和水清洗，如果皮肤发红，水肿，发痒或灼伤。
就医。
眼睛接触用大量的水立即冲洗眼睛15 分钟。
如果发红，水肿，发痒，灼伤或视觉模糊就医。
吸入不必催吐。
如果清醒的，饮几杯水。
不要通过嘴给不清醒的人任何东西。
食入5.消防措施燃烧会产生刺激烟雾。
本品不溶于水并浮于水。
如可能，除去漂浮物，原因是漂浮物构成流动危险特性火灾的危险。
有害燃烧物一氧化碳，二氧化碳硫的氧化物灭火方法使用与所在地环境情况相适合的灭火方法。
如果用水，建议用喷雾水。
不能用强力的直流水，及灭火剂直流水会分散火源。
注意事项粉尘爆炸的粉尘与空气混合可能形成爆炸混合物，禁止使用掸，拂或者高压空气吹扫粉尘，避免形成粉尘风险团。
6.泄露应急处理应急处理须穿戴防护用具进入现场；排除一切火情隐患；用简便、安全的方法收集粉尘于密闭的容器内，待处理。
环境信息：应急计划和社区知情权法：款313 表 R，最低应报告浓度0 ． 1％。
消除方法7.操作处置与储存操作注意事项储存避免接触禁忌物，严禁烟火。
须贴“自燃”标签，严禁航空、铁路运输。
ERG 指南： 133 ERG 注意事项指南分类：易燃固体8.接触控制 / 个体防护最高容许浓度3 3监测方法4mg/mTWA 8mg/mSTEL工程控制保证正确的通风，控制暴露在职业卫生允许值以下。
活性炭 MSDS
活性炭安全说明书 MSDS
物质的理化常数:
国标编号 42521
中文名称 活性碳
英文名称 Carbon activated；Activated charcoal；Activated char；Carbon active；
Carbon Amorphous；Carbon black；Carbon decolorizing；Charcoal active
别 名 活性炭黑
分子式 C 外观与性状 黑色细微粉末。
无臭，无味，无砂性
分子量 12.011
沸 点 4200℃ 溶解性 不溶于水和有机溶剂
密 度 相对密度 1.8～2.1
主要用途 具有高容量吸附有机色素及含氮碱的能力
外观与性状: 黑色细微粉末。
无臭，无味，无砂性
2.对环境的影响:
一、健康危害
侵入途径：吸入
健康危害：症状有结膜炎，角膜再生不良、湿疹和支气管炎等。
二、毒理学资料及环境行为
危险特性：吸入粉尘有中等程度危险。
易燃。
5.环境标准:
美国(1976)公共给水标准 0.3mg/L
6.应急处理处置方法:
防护措施：操作时应戴防目镜，以避免眼反复接触。
工作者应每天淋浴。
急救措施：如进入眼中，迅速用水冲洗。
导电炭黑msds化学品安全说明书
文件编号
标准文件
版本
A/0
文件名称: MSDS（导电炭黑－SP）
页码
1of2
第一部分：化学品名称
化学品中文名称：导电炭黑
化学品英文名称：ElectricBlack Carbon
英文名称2：
技术说明书编码：无相关资料
分子式.：C
分子量：12.01
第二部分：成分/组成信息源自成分:碳第三部分：危险性概述
操作注意事项：密闭操作。密闭操作，提供良好的自然通风条件。操作人员必须经过专门培训，严格遵守操作规程。建议操作人员佩戴自吸过滤式防尘口罩。避免产生粉尘。储存于阴凉、干燥、通风的库房内，远离火种、热源，保持容器密封，应与氧化剂，食用化学品开存放。
第八部分：接触控制/个体防护
前苏联MAC(mg/m3)：10
急性毒性：无
第十二部分：生态学资料
无
第十三部分：废弃处置
废弃处置方法：处置前应参阅国家和地方有关法规。建议用焚烧法处置.
第十四部分：运输信息
包装类别：Z01
运输注意事项：起运时包装要完整，装载应稳妥。运输过程中要确保容器不泄漏、不倒塌、不坠落、不损坏。严禁与氧化剂等混装混运。运输途中应防曝晒、雨淋，防高温。
第十五部分：法规信息
法规信息：化学危险物品安全管理条例(1987年2月17日国务院发布)，化学危险物品安全管理条例实施细则(化劳发[1992] 677号)，工作场所安全使用化学品规定([1996]劳部发423号)等法规，针对化学危险品的安全使用、生产、储存、运输、装卸等方面均作了相应规定。
TLVTN：无
工程控制：密闭操作。提供良好的自然通风条件。
呼吸系统防护：必要时，戴化学安全防护眼镜。身体防护：穿一般作业防护服。
炭黑msds
如果工作地通风不良，需配备合适的呼吸保护设备。
眼睛防护
使用眼部和面部防护：有两侧防护的安全眼镜。
身体防护
穿着合适的防护服，每天清洗服装。污染的工作服不允许带出厂。
手防护
戴手套防止手弄脏，反复接触可能造成皮肤干燥或开裂。在处理本产品前可用油膏护手。
其他防护
用良好工业卫生及安全实践相一致的处理/操作方法进行日常的操作。附近可设置京戏急洗眼和冲洗设备。
强氧化剂
分解产物
聚合危害
避免接触的条件
11.毒理学资料
急性毒性
LD50：致癌。 IARC评价：3组，未分类物质；人类资料不足；动物证据不充分 IDLH：1750mg／m3 OSHA表Z—1空气污染物：以炭黑提取物计 NIOSH标准文件：NIOSH 78—204LC50：
其他
12.生态学资料
其他有害作用
燃烧危险
4.急救措施
皮肤接触
用肥皂和水清洗，如果皮肤发红，水肿，发痒或灼伤。就医。
眼睛接触
用大量的水立即冲洗眼睛15分钟。如果发红，水肿，发痒，灼伤或视觉模糊就医。
吸入
不必催吐。如果清醒的，饮几杯水。不要通过嘴给不清醒的人任何东西。
食入
5.消防措施
危险特性
燃烧会产生刺激烟雾。本品不溶于水并浮于水。如可能，除去漂浮物，原因是漂浮物构成流动火灾的危险。
消除方法
7.操作处置与储存
操作
注意事项
储存
注意事项
避免接触禁忌物，严禁烟火。须贴“自燃”标签，严禁航空、铁路运输。 ERG指南：133 ERG指南分类：易燃固体
8.接触控制/个体防护
最高容许浓度
4mg/m3TWA 8mg/m3STEL
炭黑 MSDS
1.化学品及企业信息
化学品中文名称
炭黑
编 码
111
俗名/商品名
炭黑
生效日期
化学品英文名称
calcium hypochlorite
企 业 名 称
上海卡博特化工有限公司
企业应急电话
地 址
邮 编
国家应急电话
传真
电子邮件地址
2.成分/组成信息
主要成分
■纯品 □混合物
危害成分
浓 度
CASNo.
1333-86-4
填表时间
2010-07-27
修改说明
重新编码
有害燃烧物
一氧化碳，二氧化碳硫的氧化物
灭火方法
及灭火剂
注意事项
使用与所在地环境情况相适合的灭火方法。如果用水，建议用喷雾水。不能用强力的直流水，直流水会分散火源。
粉尘爆炸的风险
粉尘与空气混合可能形成爆炸混合物，禁止使用掸，拂或者高压空气吹扫粉尘，避免形成粉尘团。
6.泄露应急处理
应急处理
须穿戴防护用具进入现场；排除一切火情隐患；用简便、安全的方法收集粉尘于密闭的容器内，待处理。 环境信息： 应急计划和社区知情权法：款313表R，最低应报告浓度 0．1％。
呼吸系统防护
如果工作地通风不良，需配备合适的呼吸保护设备。
眼睛防护
使用眼部和面部防护：有两侧防护的安全眼镜。
身体防护
穿着合适的防护服，每天清洗服装。污染的工作服不允许带出厂。
手防护
戴手套防止手弄脏，反复接触可能造成皮肤干燥或开裂。在处理本产品前可用油膏护手。
其他防护
用良好工业卫生及安全实践相一致的处理/操作方法进行日常的操作。附近可设置京戏急洗眼和冲洗设备。
关于炭黑方面的一些常识
关于炭黑方面的一些常识00炭黑中文名称:炭黑英文名称:blackcarbon定义:煤、石油、生物质燃料等不完全燃烧后所形成的细小颗粒。
炭黑进入大气后，能吸收太阳光，减少到达地面的太阳辐射。
烃类在严格控制的工艺条件下经气相不完全燃烧或热解而成的黑色粉末状物质。
其成分主要是元素碳，并含有少量氧、氢和硫等。
炭黑粒子近似球形，粒径介于10~500μm间。
许多粒子常熔结或聚结成三维键枝状或纤维状聚集体。
在橡胶加工中，通过混炼加入橡胶中作补强剂(见增强材料)和填料。
炭黑是最古老的工业产品之一。
编辑本段简介炭黑烃类在严格控制的工艺条件下经气相不完全燃烧或热解而成的黑色粉末状物质。
其成分主要是元素碳，并含有少量氧、氢和硫等。
炭黑粒子近似球形，粒径介于10~500μm间。
许多粒子常熔结或聚结成三维键枝状或纤维状聚集体。
在橡胶加工中，通过混炼加入橡胶中作补强剂(见增强材料)和填料。
炭黑是最古老的工业产品之一。
早在公元前，中国就用植物油不完全燃烧制取颜料炭黑。
1872年，美国首先以天然气为原料用槽法生产炭黑。
当时，炭黑也仍主要用作着色剂。
1912年S.C.莫特发现炭黑对橡胶的补强作用之后，炭黑工业才迅速发展起来。
20世纪20年代，又出现了以天然气为原料的气炉黑和热裂黑，R.D.斯诺于1937年开始研究高效的炭黑生产方法。
后来，J.C.克雷奇致力于从液态烃生产炭黑，开发了油炉法工艺。
1941年，试产出第一批油炉黑。
1943年，世界上第一座工业化规模的油炉黑工厂在美国投产。
当今，油炉法是效率最高、经济效益最好的炭黑生产方法。
油炉黑的产量已占炭黑总量的70%~90%。
编辑本段生产方法主要有炉法、槽法、热裂法三种。
炉法炭黑由天然气或高芳烃油料在反应炉中经不完全燃烧或热解生成炭黑，此种炭黑称为炉黑，是炭黑品种中产量最大、品种最多的一类。
炉黑与槽黑及热裂黑的显著区别是，其粒子的熔结或聚结程度可根据不同用途来调节。
所以,同一粒径范围的炉黑,又分为若干不同结构的衍生品种。
炭黑化学成分
炭黑化学成分
炭黑是一种黑色粉末，广泛用于橡胶、塑料、油墨、涂料等行业。
其主要成分是碳和少量杂质，包括氧、氢、氮、硫等元素。
炭黑的化学成分对其性质和应用具有重要影响。
1. 碳含量
炭黑的主要成分是碳，其碳含量通常在90%以上。
碳的含量越高，炭黑的表面积和吸附能力越大，对橡胶和塑料的增强作用也越强。
因此，高碳炭黑被广泛应用于高性能橡胶和塑料制品的生产中。
2. 表面化学性质
炭黑的表面化学性质主要与其表面官能团有关。
炭黑表面存在大量的羟基、羰基、羧基等官能团，因此具有良好的亲水性和亲油性。
这种表面官能团对炭黑的分散性、增强作用和润滑作用等性质产生重要影响。
3. 杂质含量
炭黑中的杂质主要包括氧、氢、氮、硫等元素。
这些杂质的含量对炭黑的性质和应用也有一定影响。
例如，氧的含量越高，炭黑的表面亲水性越强，但对橡胶的增强作用有一定负面影响。
因此，在炭黑的生产过程中需要控制杂质含量，以满足不同领域的需求。
4. 结晶度
炭黑的结晶度是指其碳原子排列的程度。
高结晶度的炭黑表面平整、粒径均匀，对橡胶的增强作用更加显著；而低结晶度的炭黑则具有更好的分散性和润滑作用。
因此，在生产中需要根据不同的应用需求来选择结晶度适宜的炭黑。
炭黑的化学成分对其性质和应用有重要影响。
在不同领域的应用中，需要根据其化学成分的特点来选择适宜的炭黑，以达到最佳的增强、填充、润滑等效果。
炭黑
炭黑：ca rbo n bla ck一种无定形碳。
轻、松而极细的黑色粉末，比表面积非常大，范围从10-3000m2/g（F-S orb2400比表面积仪BET方法测试），是有机物（天然气、重油、燃料油等）在空气不足的条件下经不完全燃烧或受热分解而得的产物。
比重 1.8-2.1 由天然气制成的称“气黑”，由油类制成的称“灯黑”，由乙炔制成的称“乙炔黑”。
此外还有“槽黑”“炉黑”。
按炭黑性能区分有“补强炭黑”、“导电炭黑”、“耐磨炭黑”等。
可作黑色染料，用于制造中国墨、油墨、油漆等，也用于做橡胶的补强剂。
炭黑比表面积研究是非常重要的，炭黑的比表面积检测数据只有采用BET方法检测出来的结果才是真实可靠的，国内目前有很多仪器只能做直接对比法的检测，现在国内也被淘汰了。
目前国内外比表面积测试统一采用多点BET法，国内外制定出来的比表面积测定标准都是以BET测试方法为基础的，请参看我国国家标准（GB/T19587-2004）-气体吸附B ET原理测定固态物质比表面积的方法。
比表面积检测其实是比较耗费时间的工作，由于样品吸附能力的不同，有些样品的测试可能需要耗费一整天的时间，如果测试过程没有实现完全自动化，那测试人员就时刻都不能离开，并且要高度集中，观察仪表盘，操控旋钮，稍不留神就会导致测试过程的失败，这会浪费测试人员很多的宝贵时间。
真正完全自动化智能化比表面积测试仪产品，才符合测试仪器行业的国际标准，同类国际产品全部是完全自动化的，人工操作的仪器国外早已经淘汰。
真正完全自动化智能化比表面积分析仪产品，将测试人员从重复的机械式操作中解放出来，大大降低了他们的工作强度，培训简单，提高了工作效率。
真正完全自动化智能化比表面积测定仪产品，大大降低了人为操作导致的误差，提高测试精度。
F-So rb2400比表面积测试仪是真正能够实现B ET法检测功能的仪器（兼备直接对比法），更重要的F-Sor b 2400比表面积测试仪是迄今为止国内唯一完全自动化智能化的比表面积检测设备，其测试结果与国际一致性很高，稳定性也很好，同时减少人为误差，提高测试结果精确性。
碳黑
商业化的碳黑应有一定的规格。
碳黑是仅次于钛白粉的重要颜料，全世界年消耗橡胶碳黑约六百万吨，着色和其他用途等特殊碳黑约为二十五万吨。所谓特殊碳黑即指其用途在“着色”或“导电”，而非橡胶碳黑之补强。碳黑是经过精密控制的生产方法制造，可形成约50种不同品种，用于橡胶工业的即达成30种。用于着色和其他用途的碳黑品种更多，包括碳黑的分散体、母料、导电复合料、浆料和漆片等。
1912 年人们发现炭黑对橡胶具有补强作用,从此炭黑逐渐成为橡胶工业不可缺少的原材料。目前世界橡胶工业原材料耗用量排在第一位的是生胶,第二位的是炭黑;换言之,炭黑已成为消费量最大的橡胶配合剂。炭黑的耗用量一般占橡胶耗用量的40%～50% ,也就是说,在橡胶配方中,通常每使用2 份橡胶就会搭配使用1 份炭黑。
大部分都是探讨导电粒子接触的几何学研究。该理论认为，炭黑填充量越大，处于分散状态的炭黑粒子或炭黑粒子集合体的密度也越大，粒子间的平均距离越小，相互接触的几率越高，炭黑粒子或炭黑粒子集合体形成的导电通路也越多。不同极性的高聚物与炭黑组成共混体系的极性越大，炭黑临界体积分数就越大，意味着体系的导电性下降，因为炭黑表面含有很强的极性基团，基体极性大，作用增强，这时强度增加，却妨碍导电粒子自身的凝集，以致导电性差。 但是在多组分基体树脂与炭黑组成的共混体系粒子在偏析相中的浓度和分布状态，还取决于偏析相高聚物所占比例。
炭黑的结构性是以炭黑粒子间聚成链状或葡萄状的程度来表示的。由凝聚体的尺寸、形态和每一凝聚体中的粒子数量构成的凝聚体组成的炭黑称为高结构炭黑。目前常用吸油值表示结构性，吸油值越大，炭黑结构性越高，容易形成空间网络通道，而且不易破坏。高结构炭黑颗粒细，网状链堆积紧密，比表面积大，单位质量颗粒多，有利于在聚合物中形成链式导电结构，其中在众多炭黑品种中以乙炔炭黑为最佳。粒径分布宽的炭黑粒子比分布窄的炭黑粒子更能赋予聚合物导电性，并用统计方法解释这个现象。粒径分布宽的炭黑，少数大直径粒子需要数目巨大，直径更小的粒子给予补偿，相同平均粒径分布宽的炭黑比分布窄的炭黑有更多的粒子总数。
炭黑英文msds
﹡﹡﹡MATERIAL SAFETY DATA SHEET﹡﹡﹡1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THECOMPANY/UNDERTAKINGProduct Name: CARBON BLACK N330Synonyms: Carbon Black, Furnace BlackUse of the Substance/Preparation: Various, Industrial ProductsSupplier:Carbon Black Co. ,Ltd.City, ChinaTEL: FAX:02. HAZARDS IDENTIFICATIONIndication of danger: Hazardous according to the Worksafe Australia designated list of hazardous substances.Xn - Harmful.C3 - Carcinogen Category 3.Principle Routes of Exposure: Inhalation, Eye contact, Skin contactPOTENTIAL HEALTH EFFECTSEye Contact:May cause mechanical irritation. Irritating, but will not permanently injure eye tissue.Low hazard for usual industrial or commercial handling.Skin Contact:No adverse effects expected.Inhalation:Dust may be irritating to respiratory tract. Provide appropriate exhaust ventilation at machinery and at places where dust can be generated. See also Section 8.Ingestion:Health injuries are not known or expected under normal use. Low hazard for usual industrial or commercial handling.Carcinogenic Effects:Substance listed by IARC (International Agency for Research on Cancer). See also Section 9.Target Organ Effects:LungsMedical Conditions Aggravated by Exposure:Asthma, Respiratory disorder1Potential Environmental Effects:No special environmental precautions required. Not soluble in water. See also Section 12.4. FIRST AID MEASURESSkin Contact:Wash thoroughly with soap and water. Seek medical attention if symptoms develop.Eye Contact:Flush eyes immediately with large amounts of water for 15 minutes. Seek medical attention if symptoms develop.Inhalation:If cough, shortness of breath or other breathing problems occur, move to fresh air.Seek medical attention if symptoms persist. If necessary, restore normal breathing through standard first aid measures.Notes to Physician:Treat symptomatically.5. FIRE-FIGHTING MEASURESExtinguishing Media:Use foam, carbon dioxide (CO2), dry chemical or water spray. A fog is recommended if water is used. DO NOT USE a solid water stream as it may scatter and spread fire.Special Protective Equipment for Firefighters:Wear suitable protective equipment. In the event of fire, wear self-contained breathing apparatus.Specific Hazards:It may not be obvious that carbon black is burning unless the material is stirred and sparks are apparent. Carbon black that has been on fire should be observed closely for at least 48 hours to ensure no smoldering material is present. Burning produces irritant fumes. The product is insoluble and floats on water. If possible, try to contain floating material. This material creates a fire hazard because it floats on water.Hazardous Decomposition and/or Combustion Products:Carbon monoxide, Carbon dioxide, Oxides of sulphur, Organic products of decomposition.Risk of Dust Explosion:Do not create a dust cloud by using a brush or compressed air.26. HANDLING AND STORAGEHandling:Avoid contact with skin and eyes. Do not breathe dust. Provide appropriate exhaust ventilation at machinery and at places where dust can be generated. Do not create adust cloud by using a brush or compressed air. Fine dust is capable of penetratingelectrical equipment and may cause electrical shorts. Take precautionary measuresagainst static discharge.Storage:Keep in a dry, cool and well-ventilated place. Keep away from heat and sources of ignition. Do not store together with strong oxidizing agents. Do not store together with volatile chemicals as they may be adsorbed onto product. Keep in properly labeled containers.7. PHYSICAL AND CHEMICAL PROPERTIESAppearance: Black PelletsOdor: NonepH: 7-10（non-oxidized carbon black）Density: 1.7 - 1.9 g/cm³ @ 20°CBulk Density: 20 - 550 kg/m3Specific Gravity: Not determinedBoiling Point/Range: Not applicableMelting Point/Range: Not applicableVapor Pressure: Not determinedWater Solubility: Soluble% Volatile (by Weight): < 2.5% @ 950°C (non-oxidized carbon black)Evaporation Rate: Not applicableViscosity: Not determinedPartition Coefficient (n-octanol/water): Not determinedFlash Point: Not applicableMethod: Not applicableExplosion Limits in Air - Upper (%): Not determinedExplosion Limits in Air - Lower (%): 50 g/m3 (dust)Autoignition Temperature: > 140°C (transport)3Method: IMDG-CodeMinimum Ignition Temperature: > 350°C (BAM Furnace)Burn Velocity: > 45 seconds(Not cl assifiable as "Highly Flammable” or "Easily Ignitable") Flammability Classification: Not applicable8. STABILITY AND REACTIVITYStability: Stable.Reactivity: May react exothermically upon contact with strong oxidizersIncompatible Materials: Strong oxidizers such as chlorates, bromates, and nitrates.Hazardous Polymerization: Hazardous polymerization does not occur.Mechanical Sensitivity (shock): Not sensitive to mechanical impact.Conditions to Avoid: Do not expose to temperatures above 300°C. Keep away from oxidizing agents in order to avoid exothermic reactions.Hazardous Decomposition and/or Combustion Products:Carbon monoxide, Carbon dioxide, Oxides of sulphur, Organic products ofdecomposition.Static Discharge Effects: Take precautionary measures against static discharges. Avoid dust formation. All metal parts of the mixing and processing equipment must be earthed/grounded. Ensure all equipment is electrically earthed/grounded before beginning transfer operations.9. TOXICOLOGICAL INFORMATIONACUTE TOXICITYOral LD50: LD50/oral/rat = > 8000 mg/kg.Eye Irritation: Rabbit. Draize score 10-17/110 @ 24 hr. Non-irritating.Skin Irritation: Rabbit. 0.6/8. Slight irritation.SUBCHRONIC TOXICITYRat, inhalation, duration 90 daysNOAEL = 1.0 mg/m3Target organ: lungsEffect: inflammation, hyperplasia, fibrosis.CHRONIC TOXICITYRat, oral, duration: 2 yearsEffect: no tumorsMouse, oral, duration: 2 years4Effect: no tumorsMouse, dermal, duration: 18 monthsEffect: no skin tumorsRat, inhalation, duration: 2 yearsTarget organ: lungsEffect: inflammation, fibrosis, tumorsNote: Tumors in the rat lung are related to the fine particle overload phenomenon rather than to a specific chemical effect of the dust particles in the lung. These effects in rats have been reported in studies on other inorganic insoluble particles and appear to be species specific. Tumors have not been observed in other species (i.e., mouse and hamster) for other insoluble particles under similar circumstances and study conditions.Carcinogenic Effects: Substance listed by IARC (International Agency for Research on Cancer). Does not contain any substances listed by NTP (National Toxicology Program), OSHA (Occupational Safety and Health Administration), ACGIH (American Conference for Governmental Industrial Hygienists) or EU (European Union).Carbon Black IARC Statement: In 1995 International Agency for Research on Cancer (IARC) concluded, "There is inadequate evidence in humans for the carcinogenicity of carbon black." Based on rat inhalation studies, IARC concluded that there is "sufficient evidence in experimental animals for the carcinogenicity of carbon black", resulting in their classifying carbon black as "possibly carcinogenic to humans (Group 2B)".Carbon black is not designated a carcinogen by the U.S. National Toxicology Program (NTP), the U.S. Occupational Safety and Health Administration (OSHA), the American Conference of Governmental Industrial Hygienists (ACGIH) or the European Union (EU).The U.S. National Institute of Occupational Safety and Health (NIOSH) 1978 criteria document on carbon black recommends that only carbon blacks with polycyclic aromatic hydrocarbon (PAH) levels greater than 0.1% require the measurement of PAHs in air. As some PAHs are possible human carcinogens, NIOSH recommends an exposure limit of 0.1 mg/m3 for PAHs in air, measured as the cyclohexane-extractable fraction.Epidemiology: Results of epidemiological studies of carbon black production workers suggest that cumulative exposure to carbon black may result in small decrements in lung function, as measured by FEV1. In addition to normal age related decline in the FEV1 of approximately 1200 ml over 40 years, according to a European investigation, exposure to 1 mg/m3 (inhalable fraction) of carbon black over a 40-year lifetime will result in an additional 48 milliliter (ml) decline in FEV1. Asimilar morbidity study in the United States suggested a 27 ml decline in FEV1 from a 1mg/m3 exposure over a 40-year period. The relationship between symptoms and exposure to carbon black is less clear. In the U.S. study, 9% of the highest exposure group (in contrast to 5% of the unexposed group) reported symptoms consistent with chronic bronchitis. In the European study, methodological limitations in the administration of the questionnaire limit the drawing of definitive conclusions about symptoms. This study, however, indicated a link between carbon black and small opacities on the chest films, with negligible effects on lung function. A study of carbon black workers in the UK showed an elevated incidence of lung cancer but it was not considered to be related to carbon black exposure. A study of workers at a large German carbon black manufacturing facility found increased lung cancer mortality among German carbon black workers, but found no apparent dose-response relationship between lung cancer mortality and several indicators of occupational exposure, including years of employment and carbon black exposure. The study concluded that the high lung cancer mortality could not be fully explained by selection, smoking, or other occupational risk factors, but the results also provided little evidence for an effect from carbon black exposure. A recent mortality study of US carbon black workers found no association between employment in carbon black production and lung cancer or any other type of cancer.Mutagenic Effects: A dimethylsulfoxide (DMSO) suspension of carbon black produced negative results in an Ames test. Organic solvent extracts of carbon black, however, can contain traces of5polycylic aromatic hydrocarbons (PAH), which may affect the results in different in-vitro test systems. In an experimental investigation, mutational changes in the hprtgene were reported in alveolar epithelial cells in the rat following inhalation exposure to carbon black. This observation is believed to be rat specific and a consequence of "lung overload" (see Chronic Toxicity above).Reproductive Toxicity: Did not show effects in animal experiments.Sensitizing Effects: Contains no known sensitizers.Synergistic Materials: None reasonably foreseeable.10. ECOLOGICAL INFORMATIONAquatic Toxicity:Fish (Brachydanio rerio): LC50 (96hr) > 1,000 mg/L. (Method: OECD 203).Daphnia magna: EC50 (24hr) > 5,600 mg/L. (Method: OECD 202).Algae (Scenedesmus subspicatus): EC50 (72hr) > 10,000 mg/L.Algae (Scenedesmus subspicatus): NOEC >= 10,000 mg/L.Activated sludge: EC0 (3hr) >= 800 mg/L. (Method: DEV L3 TTC test).ENVIRONMENTAL FATEMobility: Not expected to migrate. Insoluble.Bioaccumulation: Not expected due to physicochemical properties of the substance.Persistence / Degradability: Not expected to degrade.Distribution to Environmental Compartments: Insoluble. Expected to remain on soil surface.11. DISPOSAL CONSIDERATIONSProduct, as supplied, should be disposed of in accordance with the regulations issued by the appropriate federal, state and local authorities. Same consideration should be given to containers and packaging.12. TRANSPORT INFORMATIONThe following organizations do not classify carbon black as a "hazardous cargo" if it is "carbon,non-activated, mineralorigin". Cabot carbon blacks meets this definition.- Canadian Transport of Dangerous Goods Regulation- European Transport of Dangerous Goods Regulation- GGVS, GGVE, RID, ADR, IMDG Code, ICAO-TI- United Nations (no UN number)- US Department of TransportationCAS NO 1333-86-4UN Number: 1361UN Proper Shipping Name: Not classifiedUN Shipping Class: Not classified6UN Packing Group: Not classifiedInternational TransportationIdentification:"Carbon black, non-activated, mineral origin".Not dangerous according to IMDG-Code.Not dangerous according to ICAO-TI.US Rail Regulations: Not classified13. ACCIDENTAL RELEASE MEASURESPersonal Precautions: CAUTION: Wet carbon black produces slippery walking surfaces. Avoid dust formation. Ensure adequate ventilation. Use personal protective equipment. See alsoSection 8.Methods for Cleaning Up: Clean up promptly by vacuum. Use of a vacuum with high efficiency particulate air(HEPA) filtration is recommended. Do not create a dust cloud by using a brush orcompressed air. Pick up and transfer to properly labelled containers. See Section 13.Environmental Precautions: Do not allow material to contaminate ground water system. The product is insolubleand floats on water. If possible, try to contain floating material. Local authoritiesshould be advised if significant spillages cannot be contained.14. EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE LIMITSThe table below is a summary. Please see the specific legislation for complete information.Carbon Black, CAS RN 1333-86-4: Australia: 3.0 mg/m3, TWABelgium - OEL: 3.6 mg/m3, TWACanada: 3.5 mg/m3, TWAChina: 4.0 mg/m3, TWA8.0 mg/m3, STELFinland: 3.5 mg/m3, TWA7.0 mg/m3, STELFrance - INRS: 3.5 mg/m3, TWA/VMEGermany - TRGS 900: 3.0 mg/m3, respirable TWA10.0 mg/m3, inhalable TWAGermany - MAKs: 1.5 mg/m3, respirable TWA4.0 mg/m3, inhalable TWAIreland: 3.5 mg/m3, TWA7.0 mg/m3, STELItaly - OEL: 3.5 mg/m3, TWAKorea: 3.5 mg/m3, TWANetherlands - MAC: 3.5 mg/m3, TWA7Norway: 3.5 mg/m3, TWASpain: 3.5 mg/m3, TWASweden - TLV: 3.0 mg/m3, TWAUnited Kingdom - WEL: 3.5 mg/m3, inhalable TWA (a)7.0 mg/m3, inhalable STELUS ACGIH - TLV: 3.5 mg/m3, TWAUS OSHA - PEL: 3.5 mg/m3, TWANote: Unless otherwise indicated as "respirable" or "inhalable", the exposure limitrepresents a "total" value. The inhalable exposure limit has been demonstrated to bemore restrictive than the total exposure limit, by a factor of approximately 3.15. STABILITY AND REACTIVITYStability: Stable.Reactivity: May react exothermically upon contact with strong oxidizers.Cabot Corporation___________________________________________________________________ ______Product Name: REGAL 250R Product Code: R250R Revision Date: 18/June/2007 Page 6 of 10 Incompatible Materials: Strong oxidizers such as chlorates, bromates, and nitrates.Hazardous Polymerization: Hazardous polymerization does not occur.Mechanical Sensitivity (shock): Not sensitive to mechanical impact.Conditions to Avoid: Do not expose to temperatures above 300°C. Keep away from oxidizing agents inorder to avoid exothermic reactions.Hazardous Decomposition and/orCombustion Products:Carbon monoxide, Carbon dioxide, Oxides of sulphur, Organic products ofdecomposition.Static Discharge Effects: Take precautionary measures against static discharges. Avoid dust formation. Allmetal parts of the mixing and processing equipment must be earthed/grounded.Ensure all equipment is electrically earthed/grounded before beginning transferoperations.16. OTHER INFORMATIONCarbon Black Extracts:Manufactured carbon blacks generally contain less than 0.1% of solvent extractable polycyclic aromatic hydrocarbons(PAH). Solvent extractable PAH content depends on numerous factors including, but not limited to, the manufacturingprocess, desired product specifications, and the analytical procedure used to measure and identify solvent extractable8materials. Questions concerning PAH content of carbon black and analytical procedures should be addressed to yourcarbon black supplier.General Information:The carbon black industry continues to sponsor research designed to identify adverse health effects from long termexposure to carbon black. This MSDS will be updated as new safety and health information may become available.9。
炭黑MSDS通用安全技术说明书
化学品安全技术说明书1、企业资质认证产品名称：N炭黑别名：炭黑，炉法炭黑材料应用：各种工业产品供应商：炭黑有限公司地址：中国68号联系电话： 666 传真： 8882、炭黑的组成成分3、危险性概述危害显示：本品为非危险物品主要接触途径：吸入，眼睛接触，皮肤接触。
潜在的健康影响：眼睛接触：可能引起机械刺激。
但是不会永久的伤害眼膜。
对于平常的工业或商业接触有较低的危害。
皮肤接触：无已知的不良反应。
吸入：粉尘可能刺激呼吸道。
应对机器设备和能够产生灰尘的地方提供适当的排气通风。
另请参阅第8部分。
食入：正常使用下不会出现已知的健康损伤。
对于平常的工业或商业接触只有较低的危害。
致癌影响：国际癌症研究机构列出的物品。
另请参阅第9部分。
主要影响器官：肺。
暴露恶化的疾病：哮喘，呼吸障碍潜在的环境影响：不需要特别的环境预防措施。
不溶解于水。
另请参阅第12部分。
4、急救措施皮肤接触：应用肥皂和水彻底清洗。
若症状加重，请就医。
眼睛接触：应立即用大量的水冲洗眼睛15分钟。
若症状加重，请就医。
吸入：如果咳嗽，呼吸急促或者发生其他呼吸问题，请移到其他地方呼吸新鲜空气。
若症状无好转，请就医。
如果有必要的话，请通过标准的急救措施来恢复正常呼吸。
食入：不要催吐，如清醒，给予几杯水，千万不要给休克的人通过口腔喂任何东西。
医生提示：请根据症状处理。
5、消防措施灭火器：应使用泡沫，二氧化碳，干粉或者水喷雾。
如果已经使用过水，推荐使用水雾。
不要使用强直流水，因为它可能溅射扩散火苗。
消防员的特殊防护装备：要穿戴合适的防护装备。
发生火灾时，应佩带独立的呼吸设备。
具体危害：炭黑燃烧时可能不明显，除非搅拌时出现火花。
对已经着火的炭黑，我们应该严密地观察至少48小时以确保无隐燃存在。
燃烧会产生刺激性的烟气。
该产品不能溶解的，并且漂浮在水上。
如果可能，设法控制悬浮物质。
该物质会产生火灾隐患，因为它漂浮在水上。
分解或燃烧产生的危害物：一氧化碳，二氧化碳，硫的氧化物，分解的有机产物。
carbonblack-MSDS
Revision date: September 5, 2013Safety Data Sheet(Carbon Black)According to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)1.1Product name Carbon Black (all grades)1.2Manufacturer/supplier Sid Richardson Carbon & Energy Co.3560 W. Market Street, Suite 420Akron, OH 443331.3Emergency numbers for spills, leak, fire, exposure, or accidentCHEMTREC: 1-800-424-9300 (US)CANUTEC: 613-996-6666 (Canada)For all other inquiries about this product(330) 666-2777 – Day(800) 767-2227 – Night/Weekend1.4 Regulation (EC) No. 1907/2006 REACH Registration Number 01-2119384822-32-XXXX1.5 Use of substance/preparation Additive and filler for plastics, rubber, pigments, and other specialtyproducts2.1Globally Harmonized System of Classification and Labeling of Chemicals hazard identificationNot a hazardous substance or preparation under GHS. Not a hazardous substance or preparation under EC-directives 67/548/EEC or 1999/45/EC and their various amendments and adaptations. Not hazardoussubstance or preparation under CLP-Regulation (EC) No 1272/2008. Does not contain any of the“Candidate List of Substances of Very High Concern” (SVHC) at levels >0.1 % as defined in the REACH legislation.In 1995 IARC concluded, “There is inadequate evidence in humans for the carcinogenicity of carbonblack.” Based on rat inhalation studies IARC concluded that there is “sufficient evidence in exp erimental animals for the carcinogenicity of carbon black,” IARC’s overall evaluation was that “Carbon black ispossibly carcinogenic to humans (Group 2B).” This conclusion was based on IARC’s guidelines, whichrequire such a classification if one animal species exhibits carcinogenicity in two or more studies. Lungtumors in rats are the result of exposure under “lung overload” conditions. The development of lung tumors in rats is specific to this species. Mouse and hamster showed no carcinogenicity in similar studies.In 2006 IARC re-affirmed its 1995 classification of carbon black as, Group 2B (possibly carcinogenic tohumans).Overall, as a result of the detailed epidemiological investigations, no causative link between carbon black exposure and cancer risk in humans has been demonstrated. This view is consistent with the IARCevaluation in 2006. Furthermore, several epidemiological and clinical studies of workers in the carbonblack production industries show no evidence of clinically significant adverse health effects due tooccupational exposure to carbon black. No dose response relationship was observed in workers exposed to carbon black.Applying the rules of the Globally Harmonized System of Classification and Labeling (GHS, e.g. UN`Purple Book´ , EU CLP Regulation) the results of repeated dose toxicity and carcinogenicity studies inanimals do not lead to classification of Carbon Black for Specific target organ toxicity (Repeated exposure) and carcinogenicity. UN GHS says that even if adverse effects are seen in animal studies or in-vitro tests, no classification is needed if the mechanism or mode of action is not relevant to humans. The EuropeanCLP Regulation also mentions, that no classification is indicated if the mechanism is not relevant tohumans. Furthermore, the CLP guidance on classification and labeling states, that “lung overload” inanimals is listed under mechanism not relevant to humans.2.2 Emergency OverviewA black, odorless powder, which can burn or smolder at temperatures greater than 572ºF (>300ºC).Hazardous products of decomposition can include carbon monoxide, carbon dioxide, and oxides of sulfur.May cause mechanical irritation to the eyes and the respiratory tract especially at concentrations above the occupational exposure limit. Some grades of carbon black are sufficiently electrically non-conductive to allow a buildup of static charge during handling. Take measures to prevent the build up of electrostaticcharge.2.3 Routes of Exposure: Inhalation, eye and skin2.4 Potential Health EffectsInhalation: Temporary discomfort to upper respiratory tract may occur due to mechanical irritation when exposures are well above the occupational exposure limit. Long-term exposure may result in a small non-clinically significant increase in normal loss in one aspect of lung function (FEV1).(See Section 11)Ingestion: No evidence of adverse effects from available data.Eye: High dust concentrations may cause mechanical irritation to eye.Skin: May cause mechanical irritation, soiling and drying of skin.Sensitization: No cases of sensitization in humans have been reportedChronic: IARC listed; Group 2B (possibly carcinogenic to humans). Not listed as a carcinogen by NTP,ACGIH, OSHA or the European Union. (See Section 11)There are no known human carcinogenic effects related to the PAH content of carbon blacks. Recentresearch has shown that the PAH content of carbon blacks is not released from carbon black in biological fluids and thus not available for biological activity.2.5 Potential Environmental EffectsNo significant environmental hazards are associated with carbon black release to the environment. Carbon black is not soluble in water. (See Section 12)3.1 Component(s)Carbon Black, amorphous (100%)Chemical formula: CCAS number: 1333-86-4EINECS number: 215-609-94.1 First aid proceduresInhalation: Take affected persons out in fresh air, if necessary.Skin: Wash skin with mild soap and water. If symptoms develop, seek medical attention.Eye: Rinse eyes thoroughly with plenty of water keeping eyelid open. If symptoms develop, seek medicalattention.Ingestion: Do not induce vomiting. If conscious, rinse mouth with water.4.2Note to physicians: Treat symptomatically5.1 Extinguishing MediaUse foam, carbon dioxide (CO2), dry chemical, or water spray. Avoid high-pressure water stream as this may spread burning powder (burning powder will float). A fog spray is recommended if water is used.NOTE: It may not be obvious that carbon black is burning unless the material is stirred and sparks are apparent. Carbon black that has been on fire should be observed closely for at least 48 hours to ensure no smoldering material is present.5.2 Protection of FirefightersProducts of combustion include carbon monoxide (CO), carbon dioxide (CO2), and oxides of sulfur. Wear full protective fire fighting gear including self-contained breathing apparatus (SCBA).NOTE: Wet carbon black produces dangerously slippery walking surfaces. Small spills should be vacuumed when possible. Dry sweeping is not recommended. A vacuum equipped with HEPA (high efficiency particulate air) filtration is recommended. If necessary, light water spray will reduce dust for dry sweeping. Large spills may be shoveled into containers. (See Section 13) Wear appropriate personal protective equipment and respiratory protection. (See Section 8)Carbon black poses no significant environmental hazards. As a matter of good practice, minimize contamination of sewage water, soil, groundwater, drainage systems, or bodies of water.7.1 HandlingAvoid dust exposures above the occupational exposure limit. Wash exposed skin daily. Use local exhaust ventilation to control exposures to below occupational exposure limit. Fine dust may cause electrical shorts and is capable of penetrating electrical equipment unless tightly sealed. If hot work (welding, torch cutting, etc.) is required the immediate work area must be cleared of carbon black product and dust.7.2 StorageStore in dry place away from ignition sources and strong oxidizers. Before entering closed vessels andconfined spaces containing carbon black test for adequate oxygen, flammable gases and potential toxic air contaminants (e.g., CO). Follow safe practices when entering confined spaces.8.1 Exposure guidelinesOES = occupational exposure standardPEL = permissible exposure limitREL = recommended exposure limitSTEL = short-term exposure limitTWA = 8-hour time weighted average8.2 Engineering controlsUse process enclosures and/or exhaust ventilation to keep airborne dust concentrations below theoccupational exposure limit.8.3 Personal Protective Equipment (PPE)No special PPE required. Gloves may be used to protect hands from carbon black soiling. Work clothesshould not be taken home and should be washed daily. Eye protection recommended as a matter of goodindustrial safety practice.Skin Protection: Wash hands and other exposed skin with mild soap and use skin cream to prevent skin drying.Respiratory Protection: An approved air-purifying respirator (APR) may be used where airborneconcentrations are expected to exceed occupational exposure limits. Protection provided by APRs islimited. Use a positive-pressure, air supplied respirator if there is any potential for uncontrolled release,exposure levels are not known, or any circumstances where air-purifying respirators may not provideadequate protection. A complete respiratory protection program in accordance with national standards and current best practices must accompany use of any respirator.8.4General Hygiene ConsiderationsWash hands and face thoroughly with mild soap before eating and drinking. Frequent skin washing maydry skin. Application of a skin lotion is recommended.Appearance: powder or pelletColor: blackOdor: odorlessMolecular formula: CMolecular weight (as carbon): 12Melting point/range: not applicableBoiling point/range: not applicableVapor pressure : not applicableDensity: (20ºC) 1.7 – 1.9 g/cm3Bulk density: 20 – 550 kg/m3Solubility: insoluble in waterpH value: >7 [50 g/l water, 68ºF (20ºC)]Partition coefficient: not applicableViscosity: not applicableFlammable and Explosive PropertiesFlashpoint not applicableSpontaneous Ignition (transport): >284ºF (>140ºC)Explosive Limits (dust):Furnace black1Lower 50 g/m3Upper not determinedMaximum Absolute Explosion Pressure110 barMaximum Rate of Pressure Rise130-100 bar/sec.Dust Explosion Class2ST 1Ignition Energy1Furnace black >1 kJMinimum Ignition Temperature1Method: VDI 2263 (BAM Furnace) >932ºF (>500ºC)Goldberg-Greenwald Furnace >600ºF (>315ºC)Minimum Ignition Energy1>10 JBurn Velocity2(not clas sifiable as “Highly Flammable”, or “Easily Ignitable”)>45 secondsFlammability Classification (as defined by OSHA 1910.1200): not applicable1German VDI Guideline 2263, Test Methods for the Determination of the Safety Characteristics of Dusts.2German VDI Guideline 2263 and EC Directive 84/449Stability: stable under normal ambient conditionsDecomposition: >572ºF (>300ºC)Conditions to avoid: exposure to high temp. >572ºF (>300ºC) and open flamesMaterials to avoid: strong oxidizers such as chlorates, bromates, and nitratesHazardous decomposition products: carbon monoxide, carbon dioxide, organic products of decomposition, oxides or sulfur (sulfoxides) form if heated above decomposition temperatureHazardous polymerization: will not occur11.1 Acute ToxicityAcute oral toxicity: LD50 (rat), > 8000 mg/kgPrimary skin irritation:rabbit: non-irritative, index score 0.6/8 (4.0 = severe edema)Primary eye irritation:rabbit: non-irritative, Draize score 10-17/110(100 = maximally irritating)11.2 Subchronic toxicityRat, inhalation, duration 90 days, NOAEL – 1.0 mg/m3 (respirable)Target organ: lungs;Effect: inflammation, hyperplasia, fibrosis11.3 Chronic toxicityRat, oral, duration 2 yearsEffect: no tumorsMouse, oral, duration 2 yearsEffect: no tumorsMouse, derma, duration 18 monthsEffect: no skin tumorsRat, inhalation, duration 2 yearsTarget organ: lungsEffect: inflammation, fibrosis, tumorsNote: Tumors in the rat lung are considered to be related to the “particle overload phenomenon” ratherthan to a specific chemical effect of carbon black itself in the lung. These effects in rats have been reported in many studies on other poorly soluble inorganic particles and appear to be rat specific. Tumors have not been observed in other species (i.e., mouse and hamster) for carbon black or other poorly soluble particles under similar circumstances and study conditions.11.4 SensitizationNo evidence of sensitization was found in animals.No cases of sensitization in humans have been reported.11.5 CarcinogenicityTumor development in Rats caused by lung overload, no epidemiological evidence for lung tumors inHumans.Lung tumors in rats are the result of exp osure under “lung overload” conditions. The development of lung tumors in rats is specific to this species. Mouse and hamster do not develop lung tumors under similar test conditions. The CLP guidance on classification and labeling states, that “lung overl oad“ in animals is listed under mechanism not relevant to humans.IARC listed: Group 2B (possibly carcinogenic to humans). Not listed as a human carcinogen by NTP,ACGIH, OSHA, or the European Union. ACGIH listed as A3 Confirmed animal carcinogen with unknown relevance to humans: The agent is carcinogenic in experimental animals at a relatively high dose, byroute(s) of administration, at site(s), of histological type(s), or by mechanism(s) that may not be relevant to worker exposure. Available epidemiologic studies do not confirm an increased risk of cancer in exposedhumans. Available evidence does not suggest that the agent is likely to cause cancer in humans exceptunder uncommon or unlikely routes or levels of exposure.11.6 Mutagenic effectsIn VitroCarbon black is not suitable to be tested in bacterial (Ames test) and other in vitro systems because of itsinsolubility. When tested, however, results for carbon black showed no mutagenic effects. Organic solvent extracts of carbon black can, however, contain traces of polycyclic aromatic hydrocarbons (PAHs). Astudy to examine the bioavailability of these PAHs showed that PAHs are very tightly bound to carbonblack and not bioavailable.In VivoIn an experimental investigation, mutational changes in the hprt gene were reported in alveolar epithelialcells in the rat following inhalation exposure to carbon black. This observation is believed to be rat specific and a consequence of “lung overload” which led to chronic inflammation and release of oxy gen species.(see Chronic toxicity above). This is considered to be a secondary genotoxic effect and, thus, carbon black itself would not be considered to be mutagenic.11.7 Reproductive effectsNo effects have been reported in long-term animal studies.11.8 EpidemiologyResults of epidemiological studies of carbon black production workers suggest that cumulative exposure to carbon black may result in small decrements in lung function. A recent U.S. respiratory morbidity studysuggested a 27 ml decline in FEV1 from a 1 mg/m3 (inhalable fraction) exposure over a 40-year period. An older European investigation suggested that exposure to 1 mg/m3 (inhalable fraction) of carbon black over a 40-year working lifetime would result in a 48 ml decline in FEV1. However, the estimates from bothstudies were only of borderline statistical significance. Normal age-related decline over a similar period of time would be approximately 1200 ml.The relationship between other respiratory symptoms and exposure to carbon black is even less clear. Inthe U.S. study, 9% of the highest exposure group (in contrast to 5% of the unexposed group) reportedsymptoms consistent with chronic bronchitis. In the European study, methodological limitations in theadministration of the questionnaire limit the conclusions that can be drawn about reported symptoms. This study, however, indicated a link between carbon black and small opacities on chest films, with negligibleeffects on lung function.A study on carbon black production workers in the UK (Sorahan et al 2001) found an increased risk of lungcancer in two of the five plants studied; however, the increase was not related to the dose of carbon black.Thus, the authors did not consider the increased risk in lung cancer to be due to carbon black exposure. A German study of carbon black workers at one plant (Wellmann et al. 2006, Morfeld et al. 2006(a), Buechte et al. 2006, Morfeld et al. 2006(b)) found a similar increase in lung cancer risk but, like the 2001 UK study, found no association with carbon black exposure. In contrast, a large US study (Dell et al. 2006) of 18plants showed a reduction in lung cancer risk in carbon black production workers. Based upon thesestudies, the February 2006 Working Group at IARC concluded that the human evidence for carcinogenicity was inadequate (Baan et al. 2006).Since this IARC evaluation of carbon black, Sorahan and Harrington (2007) re-analyzed the UK study data using an alternative exposure hypothesis and found a positive association with carbon black exposure intwo of the five plants. The same exposure hypothesis was applied by Morfeld and McCunney (2007) to the German cohort; in contrast, they found no association between carbon black exposure and lung cancer risk and, thus, no support for the alternative exposure hypothesis used by Sorahan and Harrington. Overall, as a result of these detailed investigations, no causative link between carbon black exposure and cancer risk in humans has been demonstrated. This view is consistent with the IARC evaluation in 2006.EcotoxicityAquatic toxicity: Acute fish toxicity: LC50 (96 h) > 1000mg/l, Brachydanio rerio (zebrafish), (OECD Guideline 203).Acute water flea toxicity: EC50 (24 h) > 5600 mg/l. Daphnia magna (waterflea), (OECD Guideline 202).Acute algae toxicity: EC 50 (72 h) >10,000 mg/l NOEC 50 >10,000 mg/l (Scenedesmus subspicatus), (OECD Guideline 201)Behavior in water treatment plants: Activated sludge, EC0 (3 h) >= 800 mg/l. DEV L3 (TTC test)Mobility: Not soluble in water.Bioaccumulation: Potential bioaccumulation is not expected because of physio-chemical properties of thesubstance.Product can be burned in suitable incineration plants or disposed of in a suitable landfill in accordance with the regulations of the appropriate federal, provincial, state and local authorities.EU - See European Waste Catalogue (Council Directive 75/422/EEC).U.S. - Not a hazardous waste under U.S. RCRA, 40 CFR 261.Canada - Not a hazardous waste under provincial regulations.Container/Packaging - Return reusable containers to manufacturer. Paper bags may be incinerated, recycled, ordisposed of in an appropriate landfill in accordance with national and local laws.Carbon black is not classified as a hazardous material by the following country regulations/agencies:Canadian Transport of Dangerous Goods RegulationEuropean Transport of Dangerous Goods RegulationsGGVS, GGVE, RID, ADR, IMDG Code, ICAO-TIUnited Nations ( no UN number)U.S. Department of TransportationInternational transportation identification:“Carbon black, non-activated, mineral origin”Not dangerous according to IMDG-CodeNot dangerous according to ICAO-TIUN Shipping Class: Not classified.UN Packing Group: Not classified.U.S. Rail Regulations: Not classified.15.1 European Union (EU)Classification: Not defined as a dangerous substance or preparation according to Council Directive67/548/EEC and its various amendments and adaptations.Symbol: None required15.2Germany: water classification.WGK Number (Kenn-Nr): 1742. WGK Class (Wassergefährdungsklasse):nwg (non-hazardous to waters). Not a hazardous substance as defined by the Chemicals Act or HazardousSubstance Ordinance.15.3Canada: WHMIS Classification: D2AStatement of Equivalence: "This product has been classified in accordance with the hazard criteria of theControlled Products Regulations and the MSDS contains all the information required by the ControlledProducts Regulations." Ingredient Disclosure List: Contains carbon black. See Section 2.15.4United StatesFederal RegulationsSuperfund Amendments and Reauthorization Act (SARA) Title IIISection 313 Toxic Substances: Does not contain any components subject to this section.Toxic Release Inventory (TRI): Under EPA’s Toxics Release Inventory (TRI) program the reporting threshold for21 Polycyclic Aromatic Compounds (PACs) has been lowered to 100 pounds per year manufactured, processed, orotherwise used. (64 CFR 58666, Oct. 29, 1999) The 100 pounds/yr applies to the cumulative total of 21 specific PACs. Carbon black may contain certain of these PACs and the user is advised to evaluate their own TRI reporting responsibilities.State RegulationsCalifornia Safe Drinking Water and Toxics Enforcement Act of 1986(Proposition 65): "Carbon black (airborne, unbound particles of respirable size)" is a CaliforniaProposition 65 listed substance. All three listing qualifiers (airborne, unbound (not bound within a matrix),and respirable size (10 micrometers or less in diameter)) must be met for this substance to be considered aProposition 65 listed substance.15.5 Inventory StatusAll components either are listed on or exempt from the following inventories:Australia: Australian Inventory of Chemical Substances (AICS)Canada: Domestic Substances List (DSL)China: Inventory of Existing Chemical SubstancesEuropean Union: European Inventory of Existing Commercial Chemical Substances (EINECS) No. 215-609-9.Japan: Existing and New Chemical Substances (ENCS) No. 5-3328.Korea: Existing Chemical Substances List (ECL) No. KE-04882New Zealand: Hazardous Substances and New Organisms Act, approval code HSR002801 (New ZealandInventory of ChemicalsPhilippines: Philippine Inventory of Chemicals and Chemical Substances (PICCS)United States: Toxic Substances Control Act (TSCA)16.1Polycyclic Aromatic Hydrocarbon (PAH) Content. Manufactured carbon blacks generally contain less than0.1% of solvent extractable polycyclic aromatic hydrocarbons (PAH). Solvent extractable PAH contentdepends on numerous factors including, but not limited to, the manufacturing process, desired productspecifications, and the analytical procedure used to measure and identify solvent extractable materials.Questions concerning PAH content of carbon black and analytical procedures should be addressed to yourcarbon black supplier.16.2National Fire Protection Association (NFPA) Rating:Health: 0Flammability: 1Reactivity: 00 = minimal, 1 = slight, 2 = moderate, 3 = serious, 4 = severe[Note: Chronic effects are not taken into consideration in the NFPA rating ]16.3 Hazardous Materials Identification System® (HMIS®) Rating:Health: 1*Flammability: 1Physical Hazard: 00 = minimal, 1 = slight, 2 = moderate, 3 = serious, 4 = severeHMIS® is a registered trademark of the National Paint and Coatings Association[Note: the Health rating is a "1*". The asterisk must be added to represent the chronic hazard (carbonblack listed on IARC)]DisclaimerThe data and information presented herein corresponds to the present state of our knowledge and experience andis intended to describe our product with respect to possible occupational safety and health concerns. The user ofthis product has sole responsibility to determine the suitability of the product for any use and manner of use intended, and for determining the regulations applicable to such use in the relevant jurisdiction. This MSDS is updated on a periodic basis in accordance with applicable health and safety standards.。
安全周知卡(炭黑)
安全周知卡
危险性提示词品名危险性标志
可燃有毒炭黑用焦化原料油
危险性理化数据：中闪点；密度：1.21 ；
颜色：棕黑色气味：味中
燃烧爆炸危险特性：蒸汽可引起眼及上呼吸道刺激；吸入液态可引起吸入性肺炎；摄入可引起口腔、咽喉和胃肠道刺激慢性影响：神经衰弱、眼及呼吸道刺激症状，接触性皮炎，干燥等皮肤损害。
接触后表现：损害一般无特异性，症状取决于接触物物理化学性质、浓度，接触方式，接触时间长短。
轻者仅局部出现水肿性红斑和豆疹，重者发展到形成水疱，大疮，糜烂、溃疡、坏死。
自觉瘙痒、灼热、肿痛，严重者头痛、恶心、发热、畏寒。
现场急救措施：
皮肤接触：脱去污染衣着，用肥皂水或清水彻底冲洗。
眼睛接触：立即提起眼睑，用流动清水冲洗10分钟或2%碳酸氢钠溶液冲洗。
吸入：迅速脱离现场到空气新鲜处。
呼吸困难时输氧。
呼吸停止时进行人工呼吸。
就医。
食入：患者清醒时立即漱口，如发生呕吐，使其取侧卧位，防止呕吐物进入气管。
就医。
身体防护措施：
泄漏处置：
消防措施：
容许浓度mg/m3当地应急救援单位名称当地营救救援电话。
炭黑安全技术说明书
炭黑安全技术说明书1. 引言1.1 背景炭黑（Carbon Black）是一种广泛应用于信息安全领域的终端安全解决方案，通过收集、分析和处理终端设备上的安全事件数据，提供全面的威胁情报和应对措施。
本文档旨在介绍炭黑的使用方法、安全优势以及常见问题的解决方案，帮助用户更好地理解和应用炭黑安全技术。
1.2 目的本文档的目的是提供炭黑技术的详细说明和使用指南，帮助用户更好地理解和应用炭黑安全技术，提升终端设备的安全性和保护能力。
2. 炭黑的安全优势炭黑作为一种终端安全解决方案，具有如下安全优势：2.1 实时监测和防御炭黑能够实时监测终端设备上的安全事件和威胁，及时采取相应的防御措施，确保终端设备的安全。
2.2 精准的威胁检测和分析炭黑利用先进的威胁情报和机器学习算法，可以精准地检测和分析各种恶意软件、网络攻击和数据泄露等威胁行为，帮助用户提前预警和应对。
2.3 主动防御和自动化响应炭黑具备主动防御和自动化响应能力，可以根据安全策略自动阻止恶意活动，减轻人工干预的压力，并及时采取相应的响应措施。
2.4 综合的安全分析和报告炭黑提供综合的安全分析和报告功能，帮助用户全面了解终端设备的安全状况和事件情况，有针对性地制定安全策略和风险防范措施。
3. 炭黑的使用方法3.1 安装和部署用户可以按照炭黑的安装手册进行安装和部署，确保终端设备上的炭黑客户端能够正常工作和接收安全事件数据。
3.2 配置和管理用户可以使用炭黑的管理控制台进行配置和管理，设置安全策略、监测规则和响应动作，以适应不同的安全需求。
3.3 监测和响应炭黑能够实时监测终端设备上的安全事件和威胁行为，当发现异常或恶意行为时，可以及时采取响应措施，如阻止访问或隔离设备。
3.4 分析和报告炭黑提供丰富的安全分析和报告功能，用户可以通过控制台查看设备的安全状况、事件的详细信息以及威胁的趋势分析，为后续的安全决策提供依据。
4. 常见问题解决方案4.1 炭黑客户端无法正常启动如果炭黑客户端无法正常启动，请检查以下几个方面：•确保终端设备的操作系统符合最低系统要求。
CABOT CSX938F Carbon Black-安全技术说明书
化学品安全技术说明书根据中国国务院591号令：危险化学品安全管理条例，应为危险物质或混合物编制安全技术说明书(S D S )。
本产品不符合危险化学品国标的分类标准。
因此，此产品不在危险化学品安全管理条例的管辖范围内，国标对安全技术说明书各部分的规定均不适用该产品.1. 化学品及企业标识产品名称产品名称：：CSX Ô 938F Carbon Black 产品代码产品代码：：CSX938F 同义词同义词：：炭黑, 炉黑该S D S 对下列品种是有效的:炭黑品种系列 : B L A C K P E A R L S ®, E L F T E X ®, M O G U L ®, M O N A R C H ®, R E G A L ®,S P H E R O N ®, S T E R L I N G ®, V U L C A N ®, C S X ™, C R X ™, I R X ™, F C X Ô, SHOBLACK Ô,DL Ô, PROPEL Ò, LITX Ò, and PBX Ò carbon black. Oxidized grades include:BLACK PEARLS® / MOGUL® L, BLACK PEARLS® / MOGUL® E, MOGUL® H, and REGAL® 400/400R carbon black. *不包括 : B L A C K P E A R L S ® / M O N A R C H ®1000, 1300, 1400, 1500; BLACK PEARLS® 1300B1; Monarch® 4750; and Black P e a r l s ® 4350/4750 c a r b o n b l a c k ; 以及所有油性颗粒品种。
炭黑MSDS通用安全技术说明书
化学品安全技术说明书1、企业资质认证产品名称：N炭黑别名：炭黑，炉法炭黑材料应用：各种工业产品供应商：炭黑有限公司地址：中国68号联系电话： 666 传真： 8882、炭黑的组成成分3、危险性概述危害显示：本品为非危险物品主要接触途径：吸入，眼睛接触，皮肤接触。
潜在的健康影响：眼睛接触：可能引起机械刺激。
但是不会永久的伤害眼膜。
对于平常的工业或商业接触有较低的危害。
皮肤接触：无已知的不良反应。
吸入：粉尘可能刺激呼吸道。
应对机器设备和能够产生灰尘的地方提供适当的排气通风。
另请参阅第8部分。
食入：正常使用下不会出现已知的健康损伤。
对于平常的工业或商业接触只有较低的危害。
致癌影响：国际癌症研究机构列出的物品。
另请参阅第9部分。
主要影响器官：肺。
暴露恶化的疾病：哮喘，呼吸障碍潜在的环境影响：不需要特别的环境预防措施。
不溶解于水。
另请参阅第12部分。
4、急救措施皮肤接触：应用肥皂和水彻底清洗。
若症状加重，请就医。
眼睛接触：应立即用大量的水冲洗眼睛15分钟。
若症状加重，请就医。
吸入：如果咳嗽，呼吸急促或者发生其他呼吸问题，请移到其他地方呼吸新鲜空气。
若症状无好转，请就医。
如果有必要的话，请通过标准的急救措施来恢复正常呼吸。
食入：不要催吐，如清醒，给予几杯水，千万不要给休克的人通过口腔喂任何东西。
医生提示：请根据症状处理。
5、消防措施灭火器：应使用泡沫，二氧化碳，干粉或者水喷雾。
如果已经使用过水，推荐使用水雾。
不要使用强直流水，因为它可能溅射扩散火苗。
消防员的特殊防护装备：要穿戴合适的防护装备。
发生火灾时，应佩带独立的呼吸设备。
具体危害：炭黑燃烧时可能不明显，除非搅拌时出现火花。
对已经着火的炭黑，我们应该严密地观察至少48小时以确保无隐燃存在。
燃烧会产生刺激性的烟气。
该产品不能溶解的，并且漂浮在水上。
如果可能，设法控制悬浮物质。
该物质会产生火灾隐患，因为它漂浮在水上。
分解或燃烧产生的危害物：一氧化碳，二氧化碳，硫的氧化物，分解的有机产物。
炭黑说明
001.炭黑的定义炭黑（CARBON BLACK）分子量：12.01 是以含碳原料（主要为石油）经不完全燃烧而产生的微细粉末。
外观为纯黑色的细粒或粉状物。
颜色的深浅，粒子的细度，比重的大小，均随所用原料和制造方法的不同而有差异。
碳黑不溶于水、酸、碱；能在空气中燃烧变成二氧化碳。
碳黑的主要组成物是碳元素，还含有少量的氢、氧、硫、灰分、焦油和水分。
商业化的碳黑应有一定的规格。
1. 最好的黑色颜料。
2. 几乎是最廉价的颜料。
3. 着色力及遮盖力最强的颜料。
4. 视觉感官上呈中性。
5. 最稳定的颜料、耐热、耐化学品、耐光。
炭黑是仅次于钛白粉的重要颜料，全世界年消耗橡胶碳黑约六百万吨，着色和其他用途等特殊碳黑约为二十五万吨。
所谓特殊碳黑即指其用途在“着色”或“导电”，而非橡胶碳黑之补强。
碳黑是经过精密控制的生产方法制造，可形成约50种不同品种，用于橡胶工业的即达成30种。
用于着色和其他用途的碳黑品种更多，包括碳黑的分散体、母料、导电复合料、浆料和漆片等。
据记载,中国是世界上最早生产炭黑的国家之一。
在古时候,人们焚烧动植物油、松树枝,收集火烟凝成的黑灰,用来调制墨和黑色颜料。
这种被称之为“炱”的黑灰就是最早的炭黑。
1821 年人们在北美地区首次用天然气为原料生产炭黑,从此炭黑不再是“炱”那么简单,它是“气态或液态的碳氢化合物在空气不足的条件下进行不完全燃烧或热裂分解所生成的无定形碳,为疏松、质轻而极细的黑色粉末”。
大片油气田相继开采,源源不断的原料供应推动炭黑生产由手工操作迈入了大规模工业化时代。
1912 年人们发现炭黑对橡胶具有补强作用,从此炭黑逐渐成为橡胶工业不可缺少的原材料。
目前世界橡胶工业原材料耗用量排在第一位的是生胶,第二位的是炭黑;换言之,炭黑已成为消费量最大的橡胶配合剂。
炭黑的耗用量一般占橡胶耗用量的40%～50% ,也就是说,在橡胶配方中,通常每使用2 份橡胶就会搭配使用1 份炭黑。
002.炭黑的简单分类描述一种无定形碳。
炭黑各型号英文描述及简写--(1)
1. N110OTHER NAME Super Abrasion Furnace Black; SAFPHYSICAL AND CHEMICAL PROPERTIES The particle size of carbon black N110 is the smallest among those of the rubber carbon blacks. Carbon black N110 has standard structure. Its iodine adsorption value is 145g/kg, and DBP adsorption is 113cm3/100g.APPLICATION Carbon black N110 is used in the treadcompound of truck tire and passenger tire. It isalso used in rubber articles with high strength andhigh abrasion resistance such as high strengthconveyor belt and industrial rubber articles etc.USAGE AND FUNCTION Carbon black N110 is has the smallest particlediameter, highest reinforcement and abrasionresistance. When mixing, it shall be welldispersed to avoid coking due to over-hightemperature. It can be used with anti-cokingagent or other carbon black if necessary.2. N115OTHER NAME Super Abrasion Furnace Black; SAFPHYSICAL AND CHEMICAL PROPERTIES Carbon black N115 has similar physical and chemical properties as carbon black N110. Its iodine adsorption value is 160g/kg, and DBP adsorption is 113cm3/100g.APPLICATION Carbon black N110 is used in the treadcompound of truck tire and passenger tire. It isalso used in rubber articles with high strength andhigh abrasion resistance such as high strengthconveyor belt and industrial rubber articles etc. USAGE AND FUNCTION Same as carbon black N110.3. N121OTHER NAME Super Abrasion Furnace Black-high Structure(New Technology); SAF-HS(New Technology)PHYSICAL AND CHEMICAL PROPERTIES Carbon black N121 is super abrasion furnace black-high structure, made in new technology. It has small particle size and high structure. Itsiodine adsorption value is 121g/kg, and DBPadsorption is cm3/100g.APPLICATION Carbon black N121 is used in the tire treadcompound, especially high-speed car tire tread. USAGE AND FUNCTION Carbon black N121 has moderate reinforcementand similar dispersion as carbon black N220while its abrasion resistance is better than N220filled compound. In the carbon black N110 series,carbon black N121 has the best processingperformance.4. N220OTHER NAME Intermediate Super Abrasion Furnace Black;ISAFPHYSICAL AND CHEMICAL PROPERTIES Carbon black N220 with high re-enforcement property is a widely used furnace black. It has high structure, and its abrasion is between those of super abrasion furnace black and high abrasion furnace black. Its iodine adsorption value is 121g/kg, and DBP adsorption is 114cm3/100g.APPLICATION Carbon black N220 is used in tread compoundsof truck tire, passenger tire and high strength highabrasion rubber products, such as high strengthconveyor belt and industrial rubber articles etc. USAGE AND FUNCTION Carbon black N220 can be used in various rubbercompounds. Compared to the compounds filledwith carbon black N330, those with N220 hashigher abrasion of 10%~20%, higher tensilestrength and higher crack resistance, higher heat-up and hardness. The compound filled with N220is conductive.5. N234OTHER NAME Intermediate Super Abrasion Furnace Black-highstructure（New technology）；ISAF-HS（Newtechnology）PHYSICAL AND CHEMICAL PROPERTIES Carbon black N234, compared to other grades of N220 series, has higher structure, higher abrasion. Its iodine adsorption value is 120g/kg,and DBP adsorption is 125cm3/100g. APPLICATION Carbon black N234 is used in the treadcompounds of high speed tire and highperformance rubber products.USAGE AND FUNCTION The compound filled with N234 has betterabrasion than those with N220, N242 and N339.Its abrasion is about 10% higher than those ofcompounds with N220. Especially in the rigorousconditions, it shows very good abrasionperformance. The process performance of theN234 compounds is good too. The surface issmooth, suitable for various compounds. Thedeficiency of the N234 compounds is its highheat-up and high hysteresis loss.6. N326OTHER NAME High Abrasion Furnace Black-low Structure; HAF-LSPHYSICAL AND CHEMICAL PROPERTIES Carbon black N326 has iodine adsorption value 82g/kg, and DBP adsorption 72cm3/100g. TheN326 compound has high re-inforcement and low heat-up.APPLICATION Carbon black N326 is used in the treadcompounds with high strength and low heat-up. Itis also used in the conveyor belt, seals and otherhigh performance compounds.USAGE AND FUNCTION Carbon black N326 in the natural rubbercompounds has similar physical-mechanicalperformance as channel black while thevulcanization rate is kept same. The compoundfilled with N326 has high tensile strength, crackresistance and abrasion. Compared to thecompounds with other high abrasion furnaceblacks, the N326 compound has lower tensilestress, lower elongation and similar tensilestrength at break. The deficiency of the N326compounds is lower tensile strength, abrasionand fatigue resistance.7. N330OTHER NAME High Abrasion Furnace Black；HAFPHYSICAL AND CHEMICAL PROPERTIES Carbon black N330 is the most widely used high abrasion furnace black. Its iodine adsorption value is 82 g/kg, and DBP adsorption is102cm3/100g. The abrasion of the N330 compounds is lower than ISAF compounds but better than those of channel black-compounds.APPLICATION Carbon black N330 is used in the treadcompound, cord fabric compound, inner tire andindustrial compounds.USAGE AND FUNCTION Carbon black N330 has good re-inforcement,resulting in good tensile properties, crackresistance, abrasion and elasticity. Thehysteresis loss of the passenger tire filled withN330 is lower than the compounds with otherN300 series except N351. The N330 has gooddispersion and extrusion properties too, suitablefor various synthetic rubbers and natural rubbers.8. N339OTHER NAME High Abrasion Furnace Black-high Structure（New technology）；HAF-HS（Newtechnology）PHYSICAL AND CHEMICAL PROPERTIES Its iodine adsorption value is 90 g/kg, and DBP adsorption is 120cm3/100g. Compared to N330, N339 has higher structure, smaller particles. The N339 compound has better abrasion and crack resistance than those of high abrasion furnace black –high structure (old technology) such asN347.APPLICATION N339 is used in the tread compounds ofpassenger tire and truck tire, coating compoundsof conveyor belt, hose and industrial compoundswith high abrasion properties.USAGE AND FUNCTION The tread compound filled with N339 has similarre-inforcement, abrasion and crack resistanceproperties as those of N220 compounds, and hasgood extrusion property, very suitable for butylbenzene rubber/ butyl rubber compound. TheN339 compound has the highest rollingresistance among all the compounds with N330series.9. N375OTHER NAME High abrasion furnace black-high structure（New technology）；HAF-HS（Newtechnology）PHYSICAL AND CHEMICAL PROPERTIES Carbon black N375 is another grade of high abrasion furnace black with high structure (new technology). Its structure is a little lower than N339, and its properties are similar as N339. Its iodine adsorption value is 90 g/kg, and DBP adsorption is 114cm3/100g.APPLICATION The application of carbon black N375 is similar asN339, mainly used in the tread compounds ofpassenger tire, truck tire and cross-country tire. Itis also used in coating compounds of conveyorbelt.USAGE AND FUNCTION The usage and function of carbon black N375 issimilar as carbon black N339 although thestructure and heat-up is a little lower than N339.10. N539OTHER NAME Fast Extrusion Furnace Black –low Structure ;FEF-LSPHYSICAL AND CHEMICAL PROPERTIES Its iodine adsorption value is 43 g/kg, and DBP adsorption is 111cm3/100g.Carbon blackN539 is derived from carbon black N550. Its structure is lower than N550. Carbon black N539 with intermediate re-inforcement property is a general-purpose furnace black.APPLICATION Carbon black N539 is used in carcass compound,especially suitable for buffering layer compoundwith natural rubber base. It is also used in thematrix compound of tire, coating compound ofbelt and other rubber products as well as wireand cable compounds.USAGE AND FUNCTION The compound filled with N539 has smoothextrusion surface, small swelling rate, hightensile strength and high elongation. TheN539 compound has lower tensile stress thanN550 compound. The N539 compound has goodelasticity and fatigue resistanceproperties.11. N550OTHER NAME Fast Extrusion Furnace Black; FEFPHYSICAL AND CHEMICAL PROPERTIES Its iodine adsorption value is 43 g/kg, and DBP adsorption is 121cm3/100g. Carbon black N550 has smooth particle surface and high structure, resulting in best reinforcement properties among soft carbon blacks.APPLICATION Carbon black N550 is used in fabric cord,tire side compound, extrusion and rollingcompounds.USAGE AND FUNCTION Carbon black N550 is suitable for natural rubberand synthetic rubbers. N550 is easy to disperse,resulting in high enduring property, high extrusionrate, smooth surface, small expansion, hightemperature resistance and high heat-conductive,high re-inforcement, high elasticity andrebounding properties. Carbon black N550 ismainly used in fabric cord of tire, tire side,extrusion and rolling compounds. Carbon blackN550 is preferred to use with N660 when used inbutyl rubber compounds.12. N660OTHER NAME General Purpose Furnace Black ; GPFPHYSICAL AND CHEMICAL PROPERTIES Its iodine adsorption value is 36 g/kg, and DBP adsorption is 90cm3/100g.Carbon black N660 has high tensile stress, good processing performance, high rebounding performance and high flexibility. It is widely used in various fields.APPLICATION Carbon black N660 is used in fabric cord of tire,inner tire, bicycle tire, hose, belt, cable, shoes,extrusion compounds and rolling compounds. USAGE AND FUNCTION Carbon black N660 is suitable for variousvulcanizates. Compared to semi-reinforcementblacks, carbon black N660 has higher structure,smaller particle size, easy to disperse, highertensile stress and strain at break, lower heat-up,good elasticity and fatigue properties. Thedeficiency carbon black N660 is the lowelongation.13. NATURAL GAS SEMI-REINFORCING FURNACE CARBON BLACk OTHER NAME Semi-reinforcing Furnace; SRFPHYSICAL AND CHEMICAL PROPERTIES Natural gas semi-reinforcing furnace carbon black has the largest particle size and lowest structure among rubber carbon black. Its iodine adsorption value is 14 g/kg, and DBP adsorption is 47cm3/100g.APPLICATION Natural gas semi-reinforcing furnace carbonblack is suitable for natural rubber and syntheticrubbers, mainly used in compounds of bufferinglayer and tire cord, hose, belt, extrusion products,industrial rubber products, wire and cable etc.USAGE AND FUNCTION Natural gas semi-reinforcing furnace carbonblack can be used as filler with high load. Itscompound has high elongation, low heat-up, highelasticity and good aging-resistance.[文档可能无法思考全面，请浏览后下载，另外祝您生活愉快，工作顺利，万事如意!]。
- 1、下载文档前请自行甄别文档内容的完整性，平台不提供额外的编辑、内容补充、找答案等附加服务。
- 2、"仅部分预览"的文档,不可在线预览部分如存在完整性等问题,可反馈申请退款(可完整预览的文档不适用该条件!)。
- 3、如文档侵犯您的权益，请联系客服反馈,我们会尽快为您处理(人工客服工作时间：9:00-18:30)。
SECTION 2 COMPOSITION/ INFORMATION ON INGREDIENTS COMPONENT CAS NUMBER AMOUNT CARBON BLACK 1333-86-4 100.00 % weight Occupational Exposure Limits: Component Limit TWA STEL Ceiling Notation CARBON BLACK ACGIH_TLV 3.5 mg/m3 NA NA NA CARBON BLACK OSHA_PEL 3.5 mg/m3 NA NA NA
SECTION 3 HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Odorless black powder. - MAY CAUSE RESPIRATORY TRACT IRRITATION IF INHALED IMMEDIATE HEALTH EFFECTS: Eye: Not expected to cause prolonged or significant eye irritation. Skin: Not expected to be harmful to internal organs if absorbed through the skin. Contact with the skin is not expected to cause prolonged or significant irritation. Ingestion: Not expected to be harmful if swallowed. Inhalation: The dust from this material may cause respiratory irritation. Symptoms of respiratory irritation may include coughing and difficulty breathing. DELAYED OR OTHER HEALTH EFFECTS: Cancer: May cause cancer in laboratory animals, but the available information is inadequate to determine if this material can cause cancer in humans. See Section 11 for additional information. Risk depends on duration and level of exposure
HEBEI NEIL CHEMICAL CO.,LTD
NO.60 SHILUITY,CHINA TEL NO.：86-311-89803787 FAX NO.：86-311-85250322
CARBON BLACK
MATERIAL SAFETY DATA SHEET
SECTION 7 HANDLING AND STORAGE
READ AND OBSERVE ALL PRECAUTIONS ON PRODUCT LABEL. REFER TO PRODUCT LABEL OR MANUFACTURERS TECHNICAL BULLETINS FOR THE PROPER USE AND HANDLING OF THIS MATERIAL.
Precautionary Measures: Do not get in eyes, on skin, or on clothing. Wash thoroughly after handling. Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding may be necessary but may not, by themselves, be sufficient. Review all operations, which have the potential of generating an accumulation of electrostatic charge and/or a flammable atmosphere (including tank and container filling, splash filling, tank cleaning, sampling, gauging, switch loading, filtering, mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures. For more information, refer to OSHA Standard 29 CFR 1910.106, 'Flammable and Combustible Liquids', National Fire Protection Association (NFPA 77), 'Recommended Practice on Static Electricity', and/or the American Petroleum Institute (API) Recommended Practice 2003, 'Protection Against Ignitions Arising Out of Static, Lightning, and Stray Currents'.
and shoes or thoroughly clean before reuse. Ingestion: If swallowed, do not induce vomiting. Give the person a glass of water or milk to drink and get medical attention. Never give anything by mouth to an unconscious person. Inhalation: Move the exposed person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention if breathing difficulties continue.
SECTION 4 FIRST AID MEASURES Eye: No specific first aid measures are required because this material is not expected to cause eye irritation. As a precaution, remove contact lenses, if worn, and flush eyes with water. Skin: To remove the material from skin, use soap and water. Discard contaminated clothing
SECTION 5 FIRE FIGHTING MEASURES The ignition temperature of this material in air is approximately 900C. If ignited, flames may not be visible in the burning powder. Some heat and smoke may be noticeable. Soaking with water may spread the fire due to the burning powder floating on the water. High pressure fire extinguishing equipment may blow the burning powder into other areas resulting in more fires. RECOMMENDED ACTION: If possible, isolate the burning powder into an open area (preferably outside), monitor, and allow the fire to burn it out. Gently applying a fine water mist to the area of the fire may be helpful. Stop spraying if water starts to puddle. Eliminating the source of oxygen may also be helpful. DO NOT spray with high pressure fire extinguishers. NFPA RATINGS: Health: 1 Flammability: 1 Reactivity: 0 FLAMMABLE PROPERTIES: Flashpoint: NDA Autoignition: 900 °C (1652°F) Flammability (Explosive) Limits (% by volume in air): Lower: NA Upper: NA PROTECTION OF FIRE FIGHTERS: Fire Fighting Instructions: For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment, including self-contained breathing apparatus. This material will burn although it is not easily ignited. Combustion Products: Normal combustion forms carbon dioxide and water vapor; incomplete combustion can produce carbon monoxide.