On the Classification of Bulk and Boundary Conformal Field Theories

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化学专业英语词汇

化学专业英语词汇

前沿讲座Seminar专业英语Professional English现代分析化学Modern analytical chemistry生物分析技术Bioanalytical techniques高分子进展Advances in polymers功能高分子进展Advances in functional polymers有机硅高分子研究进展Progresses in organosilicon polymers高分子科学实验方法Scientific experimental methods of polymers高分子设计与合成The design and synthesis of polymers反应性高分子专论Instructions to reactive polymers网络化学与化工信息检索Internet Searching for Chemistry & Chemical Engineerin ginformation有序分子组合体概论Introduction to Organized Molecular Assembilies两亲分子聚集体化学Chemistry of amphiphilic aggregates表面活性剂体系研究新方法New Method for studying Surfactant System微纳米材料化学Chemistry of Micro-NanoMaterials分散体系研究新方法New Method for studying dispersion分散体系相行为The Phase Behavior of Aqueous Dispersions溶液-凝胶材料Sol-Gel Materials高等量子化学Advanced Quantum Chemistry分子反应动力学Molecular Reaction Dynamic计算量子化学Computational Quantum Chemistry群论Group Theory分子模拟理论及软件应用Theory and Software of Molecular Modelling & Applicati on价键理论方法Valence Bond Theory量子化学软件及其应用Software of Quantum Chemistry & its Application分子光谱学Molecular Spectrum算法语言Computational Languange高分子化学Polymer Chemistry高分子物理Polymer Physics药物化学Medicinal Chemistry统计热力学Statistic Thermodynamics液-液体系专论Discussion on Liquid-Liquid System配位化学进展Progress in Coordination Chemistry无机材料及物理性质Inorganic Materials and Their Physical Properties物理无机化学Physical Inorganic Chemistry相平衡Phase Equilibrium现代无机化学Today's Inorganic Chemistry无机化学前沿领域导论Introduction to Forward Field in Inorganic Chemistry量子化学Quantum Chemistry分子材料Molecular Material固体酸碱理论Solid Acid-Base Theory萃取过程物理化学Physical Chemistry in Extraction表面电化学Surface Electrochemistry电化学进展Advances on Electrochemistry现代电化学实验技术Modern Experimental Techniques of Electrochemistry金属-碳多重键化合物及其应用Compounds with Metal-Carbon multiple bonds and T heir Applications叶立德化学:理论和应用Ylides Chemistry: Theory and Application立体化学与手性合成Stereochemistry and Chiral Synthesis杂环化学Heterocyclic Chemistry有机硅化学Organosilicon Chemistry药物设计及合成Pharmaceutical Design and Synthesis超分子化学Supramolecular Chemistry分子设计与组合化学Molecular Design and Combinatorial Chemistry纳米材料化学前沿领域导论Introduction to Nano-materials Chemistry纳米材料控制合成与自组装Controlled-synthesis and Self-assembly of Nano-materials前沿讲座Leading Front Forum专业英语Professional English超分子化学基础Basics of Supramolecular Chemistry液晶材料基础Basics of Liquid Crystal Materials现代实验技术Modern analytical testing techniques色谱及联用技术Chromatography and Technology of tandem发光分析及其研究法Luminescence analysis and Research methods胶束酶学Micellar Enzymology分析化学中的配位化合物Complex in Analytical Chemistry电分析化学Electroanalytical chemistry生物分析化学Bioanalytical chemistry分析化学Analytical chemistry仪器分析Instrument analysis高分子合成化学Polymers synthetic chemistry高聚物结构与性能Structures and properties of polymers有机硅化学Organosilicon chemistry功能高分子Functional polymers有机硅高分子Organosilicon polymers高分子现代实验技术Advanced experimental technology of polymers高分子合成新方法New synthetic methods of polymers液晶与液晶高分子Liquid crystals and liquid crystal polymers大分子反应Macromolecules reaction水溶性高分子Water-soluble polymers聚合物加工基础The basic process of polymers聚合物复合材料Composite materials高等化工与热力学Advanced Chemical Engineering and Thermodynamics 高等反应工程学Advanced Reaction Engineering高等有机化学Advanced Organic Chemistry高等有机合成Advanced Organic synthesis有机化学中光谱分析Spectrum Analysis in Organic Chemistry催化作用原理Principle of Catalysis染料化学Dye Chemistry中间体化学与工艺学Intermediate Chemistry and Technology化学动力学Chemical Kinetics表面活性剂合成与工艺Synthesis and Technology of Surfactants环境化学Environmental Chemistry化工企业清洁生产Chemical Enterprise Clean Production化工污染及防治Chemical Pollution and Control动量热量质量传递Momentum, Heat and Mass Transmission化工分离工程专题Separation Engineering耐蚀材料Corrosion Resisting Material网络化学与化工信息检索Internet Searching for Chemistry & Chemical Engineerin g information新型功能材料的模板组装Templated Assembly of Novel Advanced Materials胶体与界面Colloid and Interface纳米材料的胶体化学制备方法Colloid Chemical Methods for Preparing Nano-materia ls脂质体化学Chemistry of liposome表面活性剂物理化学Physico-chemistry of surfactants高分子溶液与微乳液Polymer Solutions and Microemulsions两亲分子的溶液化学Chemistry of Amphiphilic Molecules in solution介孔材料化学Mesoporous Chemistry超细颗粒化学Chemistry of ultrafine powder分散体系流变学The Rheolgy of Aqueous Dispersions量子化学Quantum Chemistry统计热力学Statistic Thermodynamics群论Group Theory分子模拟Molecular Modelling高等量子化学Advanced Quantum Chemistry价键理论方法Valence Bond Theory量子化学软件及其应用Software of Quantum Chemistry & its Application计算量子化学Computational Quantum Chemistry分子模拟软件及其应用Software of Molecular Modelling & its Application分子反应动力学Molecular Reaction Dynamic分子光谱学Molecular Spectrum算法语言Computational Languange高分子化学Polymer Chemistry高分子物理Polymer Physics腐蚀电化学Corrosion Electrochemistry物理化学Physical Chemistry结构化学structural Chemistry现代分析与测试技术(试验为主)Modern Analysis and Testing Technology(experimetally)高等无机化学Advanced Inorganic Chemistry近代无机物研究方法Modern Research Methods for Inorganic Compounds萃取化学研究方法Research Methods for Extraction Chemistry单晶培养Crystal Culture固态化学Chemistry of Solid Substance液-液体系专论Discussion on Liquid-Liquid System配位化学进展Progress in Coordination Chemistry卟啉酞箐化学Chemistry of Porphyrine and Phthalocyanine无机材料及物理性质Inorganic Materials and Their Physical Properties物理无机化学Physical Inorganic Chemistry相平衡Phase Equilibrium生物化学的应用Application of Biologic Chemistry生物无机化学Bio-Inorganic Chemistry绿色化学Green Chemistry金属有机化合物在均相催化中的应用Applied Homogeneous Catalysis with Organometallic Compounds功能性食品化学Functionalized Food Chemistry无机药物化学Inorganic Pharmaceutical Chemistry电极过程动力学Kinetics on Electrode Process电化学研究方法Electrochemical Research Methods生物物理化学Biological Physical Chemistry波谱与现代检测技术Spectroscopy and Modern Testing Technology理论有机化学theoretical Organic Chemistry合成化学Synthesis Chemistry有机合成新方法New Methods for Organic Synthesis生物有机化学Bio-organic Chemistry药物化学Pharmaceutical Chemistry金属有机化学Organometallic Chemistry金属-碳多重键化合物及其应用Compounds with Metal-Carbon multiple bonds and T heir Applications分子构效与模拟Molecular Structure-Activity and Simulation过程装置数值计算Data Calculation of Process Devices石油化工典型设备Common Equipment of Petrochemical Industry化工流态化工程Fluidization in Chemical Industry化工装置模拟与优化Analogue and Optimization of Chemical Devices化工分离工程Separation Engineering化工系统与优化Chemical System and Optimization高等化工热力学Advanced Chemical Engineering and Thermodynamics超临界流体技术及应用Super Critical Liguid Technegues and Applications膜分离技术Membrane Separation Technegues溶剂萃取原理和应用Theory and Application of Solvent Extraction树脂吸附理论Theory of Resin Adsorption中药材化学Chemistry of Chinese Medicine生物资源有效成分分析与鉴定Analysis and Detection of Bio-materials相平衡理论与应用Theory and Application of Phase Equilibrium计算机在化学工程中的应用Application of Computer in Chemical Engineering微乳液和高分子溶液Micro-emulsion and High Molecular Solution传递过程Transmision Process反应工程分析Reaction Engineering Analysis腐蚀电化学原理与应用Principle and Application of Corrosion Electrochemistry腐蚀电化学测试方法与应用Measurement Method and Application of Corrosion Ele ctrochemistry耐蚀表面工程Surface Techniques of Anti-corrosion缓蚀剂技术Inhabitor Techniques腐蚀失效分析Analysis of Corrosion Destroy材料表面研究方法Method of Studying Material Surfacc分离与纯化技术Separation and Purification Technology现代精细有机合成Modern Fine Organic Synthesis化学工艺与设备Chemical Technology and Apparatuas功能材料概论Functional Materials Conspectus油田化学Oilfield Chemistry精细化学品研究Study of Fine Chemicals催化剂合成与应用Synthesis and Application of Catalyzer低维材料制备Preparation of Low-Dimension Materials手性药物化学Symmetrical Pharmaceutical Chemistry光敏高分子材料化学Photosensitive Polymer Materials Chemistry纳米材料制备与表征Preparation and Characterization of Nanostructured material s溶胶凝胶化学Sol-gel Chemistry纳米材料化学进展Proceeding of Nano-materials Chemistry●化学常用词汇汉英对照表1●氨ammonia氨基酸amino acid铵盐ammonium salt饱和链烃saturated aliphatic hydrocarbon苯benzene变性denaturation不饱和烃unsaturated hydrocarbon超导材料superconductive material臭氧ozone醇alcohol次氯酸钾potassium hypochlorite醋酸钠sodium acetate蛋白质protein氮族元素nitrogen group element碘化钾potassium iodide碘化钠sodium iodide电化学腐蚀electrochemical corrosion电解质electrolyte电离平衡ionization equilibrium电子云electron cloud淀粉starch淀粉碘化钾试纸starch potassium iodide paper 二氧化氮nitrogen dioxide二氧化硅silicon dioxide二氧化硫sulphur dioxide二氧化锰manganese dioxide芳香烃arene放热反应exothermic reaction非极性分子non-polar molecule非极性键non-polar bond肥皂soap分馏fractional distillation酚phenol复合材料composite干电池dry cell干馏dry distillation甘油glycerol高分子化合物polymer共价键covalent bond官能团functional group光化学烟雾photochemical fog过氧化氢hydrogen peroxide合成材料synthetic material合成纤维synthetic fiber合成橡胶synthetic rubber核电荷数nuclear charge number核素nuclide化学电源chemical power source化学反应速率chemical reaction rate 化学键chemical bond化学平衡chemical equilibrium还原剂reducing agent磺化反应sulfonation reaction霍尔槽Hull Cell极性分子polar molecule极性键polar bond加成反应addition reaction加聚反应addition polymerization甲烷methane碱金属alkali metal碱石灰soda lime结构式structural formula聚合反应po1ymerization可逆反应reversible reaction空气污染指数air pollution index勒夏特列原理Le Chatelier's principle 离子反应ionic reaction离子方程式ionic equation离子键ionic bond锂电池lithium cell两性氢氧化物amphoteric hydroxide 两性氧化物amphoteric oxide裂化cracking裂解pyrolysis硫氰化钾potassium thiocyanate硫酸钠sodium sulphide氯化铵ammonium chloride氯化钡barium chloride氯化钾potassium chloride氯化铝aluminium chloride氯化镁magnesium chloride氯化氢hydrogen chloride氯化铁iron (III) chloride氯水chlorine water麦芽糖maltose煤coal酶enzyme摩尔mole摩尔质量molar mass品红magenta或fuchsine葡萄糖glucose气体摩尔体积molar volume of gas铅蓄电池lead storage battery强电解质strong electrolyte氢氟酸hydrogen chloride氢氧化铝aluminium hydroxide取代反应substitution reaction醛aldehyde炔烃alkyne燃料电池fuel cell弱电解质weak electrolyte石油Petroleum水解反应hydrolysis reaction四氯化碳carbon tetrachloride塑料plastic塑料的降解plastic degradation塑料的老化plastic ageing酸碱中和滴定acid-base neutralization titration 酸雨acid rain羧酸carboxylic acid碳酸钠sodium carbonate碳酸氢铵ammonium bicarbonate碳酸氢钠sodium bicarbonate糖类carbohydrate烃hydrocarbon烃的衍生物derivative of hydrocarbon烃基hydrocarbonyl同分异构体isomer同素异形体allotrope同位素isotope同系物homo1og涂料coating烷烃alkane物质的量amount of substance物质的量浓度amount-of-substance concentration of B 烯烃alkene洗涤剂detergent纤维素cellulose相对分子质量relative molecular mass相对原子质量relative atomic mass消去反应elimination reaction硝化反应nitratlon reaction硝酸钡barium nitrate硝酸银silver nitrate溴的四氯化碳溶液solution of bromine in carbon tetrachloride 溴化钠sodium bromide溴水bromine water溴水bromine water盐类的水解hydrolysis of salts盐析salting-out焰色反应flame test氧化剂oxidizing agent氧化铝aluminium oxide氧化铁iron (III) oxide乙醇ethanol乙醛ethana1乙炔ethyne乙酸ethanoic acid乙酸乙酯ethyl acetate乙烯ethene银镜反应silver mirror reaction硬脂酸stearic acid油脂oils and fats有机化合物organic compound元素周期表periodic table of elements元素周期律periodic law of elements原电池primary battery原子序数atomic number皂化反应saponification粘合剂adhesive蔗糖sucrose指示剂Indicator酯ester酯化反应esterification周期period族group(主族:main group)Bunsen burner 本生灯product 化学反应产物flask 烧瓶apparatus 设备PH indicator PH值指示剂,氢离子(浓度的)负指数指示剂matrass 卵形瓶litmus 石蕊litmus paper 石蕊试纸graduate, graduated flask 量筒,量杯reagent 试剂test tube 试管burette 滴定管retort 曲颈甑still 蒸馏釜cupel 烤钵crucible pot, melting pot 坩埚pipette 吸液管filter 滤管stirring rod 搅拌棒element 元素body 物体compound 化合物atom 原子gram atom 克原子atomic weight 原子量atomic number 原子数atomic mass 原子质量molecule 分子electrolyte 电解质ion 离子anion 阴离子cation 阳离子electron 电子isotope 同位素isomer 同分异物现象polymer 聚合物symbol 复合radical 基structural formula 分子式valence, valency 价monovalent 单价bivalent 二价halogen 成盐元素bond 原子的聚合mixture 混合combination 合成作用compound 合成物alloy 合金organic chemistry 有机化学inorganic chemistry 无机化学derivative 衍生物series 系列acid 酸hydrochloric acid 盐酸sulphuric acid 硫酸nitric acid 硝酸aqua fortis 王水fatty acid 脂肪酸organic acid 有机酸hydrosulphuric acid 氢硫酸hydrogen sulfide 氢化硫alkali 碱,强碱ammonia 氨base 碱hydrate 水合物hydroxide 氢氧化物,羟化物hydracid 氢酸hydrocarbon 碳氢化合物,羟anhydride 酐alkaloid 生物碱aldehyde 醛oxide 氧化物phosphate 磷酸盐acetate 醋酸盐methane 甲烷,沼气butane 丁烷salt 盐potassium carbonate 碳酸钾soda 苏打sodium carbonate 碳酸钠caustic potash 苛性钾caustic soda 苛性钠ester 酯gel 凝胶体analysis 分解fractionation 分馏endothermic reaction 吸热反应exothermic reaction 放热反应precipitation 沉淀to precipitate 沉淀to distil, to distill 蒸馏distillation 蒸馏to calcine 煅烧to oxidize 氧化alkalinization 碱化to oxygenate, to oxidize 脱氧,氧化to neutralize 中和to hydrogenate 氢化to hydrate 水合,水化to dehydrate 脱水fermentation 发酵solution 溶解combustion 燃烧fusion, melting 熔解alkalinity 碱性isomerism, isomery 同分异物现象hydrolysis 水解electrolysis 电解electrode 电极anode 阳极,正极cathode 阴极,负极catalyst 催化剂catalysis 催化作用oxidization, oxidation 氧化reducer 还原剂dissolution 分解synthesis 合成reversible 可逆的1. The Ideal-Gas Equation 理想气体状态方程2. Partial Pressures 分压3. Real Gases: Deviation from Ideal Behavior 真实气体:对理想气体行为的偏离4. The van der Waals Equation 范德华方程5. System and Surroundings 系统与环境6. State and State Functions 状态与状态函数7. Process 过程8. Phase 相9. The First Law of Thermodynamics 热力学第一定律10. Heat and Work 热与功11. Endothermic and Exothermic Processes 吸热与发热过程12. Enthalpies of Reactions 反应热13. Hess’s Law 盖斯定律14. Enthalpies of Formation 生成焓15. Reaction Rates 反应速率16. Reaction Order 反应级数17. Rate Constants 速率常数18. Activation Energy 活化能19. The Arrhenius Equation 阿累尼乌斯方程20. Reaction Mechanisms 反应机理21. Homogeneous Catalysis 均相催化剂22. Heterogeneous Catalysis 非均相催化剂23. Enzymes 酶24. The Equilibrium Constant 平衡常数25. the Direction of Reaction 反应方向26. Le Chatelier’s Principle 列·沙特列原理27. Effects of Volume, Pressure, Temperature Changes and Catalystsi. 体积,压力,温度变化以及催化剂的影响28. Spontaneous Processes 自发过程29. Entropy (Standard Entropy) 熵(标准熵)30. The Second Law of Thermodynamics 热力学第二定律31. Entropy Changes 熵变32. Standard Free-Energy Changes 标准自由能变33. Acid-Bases 酸碱34. The Dissociation of Water 水离解35. The Proton in Water 水合质子36. The pH Scales pH值37. Bronsted-Lowry Acids and Bases Bronsted-Lowry 酸和碱38. Proton-Transfer Reactions 质子转移反应39. Conjugate Acid-Base Pairs 共轭酸碱对40. Relative Strength of Acids and Bases 酸碱的相对强度41. Lewis Acids and Bases 路易斯酸碱42. Hydrolysis of Metal Ions 金属离子的水解43. Buffer Solutions 缓冲溶液44. The Common-Ion Effects 同离子效应45. Buffer Capacity 缓冲容量46. Formation of Complex Ions 配离子的形成47. Solubility 溶解度48. The Solubility-Product Constant Ksp 溶度积常数49. Precipitation and separation of Ions 离子的沉淀与分离50. Selective Precipitation of Ions 离子的选择沉淀51. Oxidation-Reduction Reactions 氧化还原反应52. Oxidation Number 氧化数53. Balancing Oxidation-Reduction Equations 氧化还原反应方程的配平54. Half-Reaction 半反应55. Galvani Cell 原电池56. Voltaic Cell 伏特电池57. Cell EMF 电池电动势58. Standard Electrode Potentials 标准电极电势59. Oxidizing and Reducing Agents 氧化剂和还原剂60. The Nernst Equation 能斯特方程61. Electrolysis 电解62. The Wave Behavior of Electrons 电子的波动性63. Bohr’s Model of The Hydrogen Atom 氢原子的波尔模型64. Line Spectra 线光谱65. Quantum Numbers 量子数66. Electron Spin 电子自旋67. Atomic Orbital 原子轨道68. The s (p, d, f) Orbital s(p,d,f)轨道69. Many-Electron Atoms 多电子原子70. Energies of Orbital 轨道能量71. The Pauli Exclusion Principle 泡林不相容原理72. Electron Configurations 电子构型73. The Periodic Table 周期表74. Row 行75. Group 族76. Isotopes, Atomic Numbers, and Mass Numbers 同位素,原子数,质量数77. Periodic Properties of the Elements 元素的周期律78. Radius of Atoms 原子半径79. Ionization Energy 电离能80. Electronegativity 电负性81. Effective Nuclear Charge 有效核电荷82. Electron Affinities 亲电性83. Metals 金属84. Nonmetals 非金属85. Valence Bond Theory 价键理论86. Covalence Bond 共价键87. Orbital Overlap 轨道重叠88. Multiple Bonds 重键89. Hybrid Orbital 杂化轨道90. The VSEPR Model 价层电子对互斥理论91. Molecular Geometries 分子空间构型92. Molecular Orbital 分子轨道93. Diatomic Molecules 双原子分子94. Bond Length 键长95. Bond Order 键级96. Bond Angles 键角97. Bond Enthalpies 键能98. Bond Polarity 键矩99. Dipole Moments 偶极矩100. Polarity Molecules 极性分子101. Polyatomic Molecules 多原子分子102. Crystal Structure 晶体结构103. Non-Crystal 非晶体104. Close Packing of Spheres 球密堆积105. Metallic Solids 金属晶体106. Metallic Bond 金属键107. Alloys 合金108. Ionic Solids 离子晶体109. Ion-Dipole Forces 离子偶极力110. Molecular Forces 分子间力111. Intermolecular Forces 分子间作用力112. Hydrogen Bonding 氢键113. Covalent-Network Solids 原子晶体114. Compounds 化合物115. The Nomenclature, Composition and Structure of Complexes 配合物的命名,组成和结构116. Charges, Coordination Numbers, and Geometries 电荷数、配位数、及几何构型117. Chelates 螯合物118. Isomerism 异构现象119. Structural Isomerism 结构异构120. Stereoisomerism 立体异构121. Magnetism 磁性122. Electron Configurations in Octahedral Complexes 八面体构型配合物的电子分布123. Tetrahedral and Square-planar Complexes 四面体和平面四边形配合物124. General Characteristics 共性125. s-Block Elements s区元素126. Alkali Metals 碱金属127. Alkaline Earth Metals 碱土金属128. Hydrides 氢化物129. Oxides 氧化物130. Peroxides and Superoxides 过氧化物和超氧化物131. Hydroxides 氢氧化物132. Salts 盐133. p-Block Elements p区元素134. Boron Group (Boron, Aluminium, Gallium, Indium, Thallium) 硼族(硼,铝,镓,铟,铊)135. Borane 硼烷136. Carbon Group (Carbon, Silicon, Germanium, Tin, Lead) 碳族(碳,硅,锗,锡,铅)137. Graphite, Carbon Monoxide, Carbon Dioxide 石墨,一氧化碳,二氧化碳138. Carbonic Acid, Carbonates and Carbides 碳酸,碳酸盐,碳化物139. Occurrence and Preparation of Silicon 硅的存在和制备140. Silicic Acid,Silicates 硅酸,硅酸盐141. Nitrogen Group (Phosphorus, Arsenic, Antimony, and Bismuth) 氮族(磷,砷,锑,铋)142. Ammonia, Nitric Acid, Phosphoric Acid 氨,硝酸,磷酸143. Phosphorates, phosphorus Halides 磷酸盐,卤化磷144. Oxygen Group (Oxygen, Sulfur, Selenium, and Tellurium) 氧族元素(氧,硫,硒,碲)145. Ozone, Hydrogen Peroxide 臭氧,过氧化氢146. Sulfides 硫化物147. Halogens (Fluorine, Chlorine, Bromine, Iodine) 卤素(氟,氯,溴,碘)148. Halides, Chloride 卤化物,氯化物149. The Noble Gases 稀有气体150. Noble-Gas Compounds 稀有气体化合物151. d-Block elements d区元素152. Transition Metals 过渡金属153. Potassium Dichromate 重铬酸钾154. Potassium Permanganate 高锰酸钾155. Iron Copper Zinc Mercury 铁,铜,锌,汞156. f-Block Elements f区元素157. Lanthanides 镧系元素158. Radioactivity 放射性159. Nuclear Chemistry 核化学160. Nuclear Fission 核裂变161. Nuclear Fusion 核聚变162. analytical chemistry 分析化学163. qualitative analysis 定性分析164. quantitative analysis 定量分析165. chemical analysis 化学分析166. instrumental analysis 仪器分析167. titrimetry 滴定分析168. gravimetric analysis 重量分析法169. regent 试剂170. chromatographic analysis 色谱分析171. product 产物172. electrochemical analysis 电化学分析173. on-line analysis 在线分析174. macro analysis 常量分析175. characteristic 表征176. micro analysis 微量分析177. deformation analysis 形态分析178. semimicro analysis 半微量分析179. systematical error 系统误差180. routine analysis 常规分析181. random error 偶然误差182. arbitration analysis 仲裁分析183. gross error 过失误差184. normal distribution 正态分布185. accuracy 准确度186. deviation偏差187. precision 精密度188. relative standard deviation 相对标准偏差(RSD)189. coefficient variation 变异系数(CV)190. confidence level 置信水平191. confidence interval 置信区间192. significant test 显著性检验193. significant figure 有效数字194. standard solution 标准溶液195. titration 滴定196. stoichiometric point 化学计量点197. end point滴定终点198. titration error 滴定误差199. primary standard 基准物质200. amount of substance 物质的量201. standardization 标定202. chemical reaction 化学反应203. concentration浓度204. chemical equilibrium 化学平衡205. titer 滴定度206. general equation for a chemical reaction化学反应的通式207. proton theory of acid-base 酸碱质子理论208. acid-base titration 酸碱滴定法209. dissociation constant 解离常数210. conjugate acid-base pair 共轭酸碱对211. acetic acid 乙酸212. hydronium ion水合氢离子213. electrolyte 电解质214. ion-product constant of water 水的离子积215. ionization 电离216. proton condition 质子平衡217. zero level零水准218. buffer solution缓冲溶液219. methyl orange 甲基橙220. acid-base indicator 酸碱指示剂221. phenolphthalein 酚酞222. coordination compound 配位化合物223. center ion 中心离子224. cumulative stability constant 累积稳定常数225. alpha coefficient 酸效应系数226. overall stability constant 总稳定常数227. ligand 配位体228. ethylenediamine tetraacetic acid 乙二胺四乙酸229. side reaction coefficient 副反应系数230. coordination atom 配位原子231. coordination number 配位数232. lone pair electron 孤对电子233. chelate compound 螯合物234. metal indicator 金属指示剂235. chelating agent 螯合剂236. masking 掩蔽237. demasking 解蔽238. electron 电子239. catalysis 催化240. oxidation氧化241. catalyst 催化剂242. reduction 还原243. catalytic reaction 催化反应244. reaction rate 反应速率245. electrode potential 电极电势246. activation energy 反应的活化能247. redox couple 氧化还原电对248. potassium permanganate 高锰酸钾249. iodimetry碘量法250. potassium dichromate 重铬酸钾251. cerimetry 铈量法252. redox indicator 氧化还原指示253. oxygen consuming 耗氧量(OC)254. chemical oxygen demanded 化学需氧量(COD) 255. dissolved oxygen 溶解氧(DO) 256. precipitation 沉淀反应257. argentimetry 银量法258. heterogeneous equilibrium of ions 多相离子平衡259. aging 陈化260. postprecipitation 继沉淀261. coprecipitation 共沉淀262. ignition 灼烧263. fitration 过滤264. decantation 倾泻法265. chemical factor 化学因数266. spectrophotometry 分光光度法267. colorimetry 比色分析268. transmittance 透光率269. absorptivity 吸光率270. calibration curve 校正曲线271. standard curve 标准曲线272. monochromator 单色器273. source 光源274. wavelength dispersion 色散275. absorption cell吸收池276. detector 检测系统277. bathochromic shift 红移278. Molar absorptivity 摩尔吸光系数279. hypochromic shift 紫移280. acetylene 乙炔281. ethylene 乙烯282. acetylating agent 乙酰化剂283. acetic acid 乙酸284. adiethyl ether 乙醚285. ethyl alcohol 乙醇286. acetaldehtde 乙醛287. β-dicarbontl compound β–二羰基化合物288. bimolecular elimination 双分子消除反应289. bimolecular nucleophilic substitution 双分子亲核取代反应290. open chain compound 开链族化合物291. molecular orbital theory 分子轨道理论292. chiral molecule 手性分子293. tautomerism 互变异构现象294. reaction mechanism 反应历程295. chemical shift 化学位移296. Walden inversio 瓦尔登反转n297. Enantiomorph 对映体298. addition rea ction 加成反应299. dextro- 右旋300. levo- 左旋301. stereochemistry 立体化学302. stereo isomer 立体异构体303. Lucas reagent 卢卡斯试剂304. covalent bond 共价键305. conjugated diene 共轭二烯烃306. conjugated double bond 共轭双键307. conjugated system 共轭体系308. conjugated effect 共轭效应309. isomer 同分异构体310. isomerism 同分异构现象311. organic chemistry 有机化学312. hybridization 杂化313. hybrid orbital 杂化轨道314. heterocyclic compound 杂环化合物315. peroxide effect 过氧化物效应t316. valence bond theory 价键理论317. sequence rule 次序规则318. electron-attracting grou p 吸电子基319. Huckel rule 休克尔规则320. Hinsberg test 兴斯堡试验321. infrared spectrum 红外光谱322. Michael reacton 麦克尔反应323. halogenated hydrocarbon 卤代烃324. haloform reaction 卤仿反应325. systematic nomenclatur 系统命名法e326. Newman projection 纽曼投影式327. aromatic compound 芳香族化合物328. aromatic character 芳香性r329. Claisen condensation reaction克莱森酯缩合反应330. Claisen rearrangement 克莱森重排331. Diels-Alder reation 狄尔斯-阿尔得反应332. Clemmensen reduction 克莱门森还原333. Cannizzaro reaction 坎尼扎罗反应334. positional isomers 位置异构体335. unimolecular elimination reaction 单分子消除反应336. unimolecular nucleophilic substitution 单分子亲核取代反应337. benzene 苯338. functional grou 官能团p339. configuration 构型340. conformation 构象341. confomational isome 构象异构体342. electrophilic addition 亲电加成343. electrophilic reagent 亲电试剂344. nucleophilic addition 亲核加成345. nucleophilic reagent 亲核试剂346. nucleophilic substitution reaction亲核取代反应347. active intermediate 活性中间体348. Saytzeff rule 查依采夫规则349. cis-trans isomerism 顺反异构350. inductive effect 诱导效应t351. Fehling’s reagent 费林试剂352. phase transfer catalysis 相转移催化作用353. aliphatic compound 脂肪族化合物354. elimination reaction 消除反应355. Grignard reagent 格利雅试剂356. nuclear magnetic resonance 核磁共振357. alkene 烯烃358. allyl cation 烯丙基正离子359. leaving group 离去基团360. optical activity 旋光性361. boat confomation 船型构象362. silver mirror reaction 银镜反应363. Fischer projection 菲舍尔投影式364. Kekule structure 凯库勒结构式365. Friedel-Crafts reaction 傅列德尔-克拉夫茨反应366. Ketone 酮367. carboxylic acid 羧酸368. carboxylic acid derivative 羧酸衍生物369. hydroboration 硼氢化反应370. bond oength 键长371. bond energy 键能372. bond angle 键角373. carbohydrate 碳水化合物374. carbocation 碳正离子375. carbanion 碳负离子376. alcohol 醇377. Gofmann rule 霍夫曼规则378. Aldehyde 醛379. Ether 醚380. Polymer 聚合物。

应用地球化学元素丰度数据手册-原版

应用地球化学元素丰度数据手册-原版

应用地球化学元素丰度数据手册迟清华鄢明才编著地质出版社·北京·1内容提要本书汇编了国内外不同研究者提出的火成岩、沉积岩、变质岩、土壤、水系沉积物、泛滥平原沉积物、浅海沉积物和大陆地壳的化学组成与元素丰度,同时列出了勘查地球化学和环境地球化学研究中常用的中国主要地球化学标准物质的标准值,所提供内容均为地球化学工作者所必须了解的各种重要地质介质的地球化学基础数据。

本书供从事地球化学、岩石学、勘查地球化学、生态环境与农业地球化学、地质样品分析测试、矿产勘查、基础地质等领域的研究者阅读,也可供地球科学其它领域的研究者使用。

图书在版编目(CIP)数据应用地球化学元素丰度数据手册/迟清华,鄢明才编著. -北京:地质出版社,2007.12ISBN 978-7-116-05536-0Ⅰ. 应… Ⅱ. ①迟…②鄢…Ⅲ. 地球化学丰度-化学元素-数据-手册Ⅳ. P595-62中国版本图书馆CIP数据核字(2007)第185917号责任编辑:王永奉陈军中责任校对:李玫出版发行:地质出版社社址邮编:北京市海淀区学院路31号,100083电话:(010)82324508(邮购部)网址:电子邮箱:zbs@传真:(010)82310759印刷:北京地大彩印厂开本:889mm×1194mm 1/16印张:10.25字数:260千字印数:1-3000册版次:2007年12月北京第1版•第1次印刷定价:28.00元书号:ISBN 978-7-116-05536-0(如对本书有建议或意见,敬请致电本社;如本社有印装问题,本社负责调换)2关于应用地球化学元素丰度数据手册(代序)地球化学元素丰度数据,即地壳五个圈内多种元素在各种介质、各种尺度内含量的统计数据。

它是应用地球化学研究解决资源与环境问题上重要的资料。

将这些数据资料汇编在一起将使研究人员节省不少查找文献的劳动与时间。

这本小册子就是按照这样的想法编汇的。

胶体化学专业英语

胶体化学专业英语

C. Properties of the solutions like colloids.
such as optical(光学的), rheological(流变 的) properties.
(2) Lyophobic colloids: There is a interface between dispersed phase and continuous phase, the colloids are unstable thermodynamically.
From thermodynamics that spontaneous process occur in the direction of decreasing Gibbs free energy. Therefore, the separation of a two-phase dispersion system to form distinct(明显 不同的) layers(层) is a change in the direction of decreasing Gibbs free energy.
(2) Kinetic stability(动力稳定性)
Kinetic stability: The separation rate of two phases is slow enough that the thermodynamic instability is of very little. Two-phase dispersions will always spontaneously change into a smaller number of larger particles given sufficient time. (unstable)

Chapter3-01-Analytical Chemistry

Chapter3-01-Analytical Chemistry

2014-3-6
3
Quantitative analysis tells us the relative amounts of one or more of these analytes in numerical terms. 定量分析是确定一种或多种不同形式的被分析物的相 对含量。 Qualitative information is required before a quantitative analysis can be undertaken. 在进行定量分析之前需要先进行定性分析。 A separation step is usually a necessary part of both qualitative and qualitative analysis. 通常情况下,样品的预先分离是进行定性和定量分析 之前必不可少的步骤。
2014-3-6 14



In a volumetric method, the volume of a solution containing sufficient reagent to react completely with the analyzer is measured. 容量法是指用含有过量试剂的溶液与被分析物完全 反应,并测量反应的溶液的体积的方法。 Electro-analytical methods involve the measurement of such electrical properties as potential, current, resistance, and quantity of electricity. 电化学分析法是测量电化学性质的方法,如测量电 压、电流、电阻及电量等。

光谱分析法是基于测量被分析物原子或分子与电磁辐 射之间的相互作用,或测量被分析物产生的辐射的方 法。

材料科学与工程_专业英语_Unit_2_Classification_of_Materials译文

材料科学与工程_专业英语_Unit_2_Classification_of_Materials译文

Solid materials have been conveniently grouped into three basic classifications: metals, ceramics, and polymers. This scheme is based primarily on chemical makeup and atomic structure, and most materials fall into one distinct grouping or another, although there are some intermediates. In addition, there are three other groups of important engineering materials—composites, semiconductors, and biomaterials.译文:固体材料被便利的分为三个基本的类型:金属,陶瓷和聚合物。

这个分类是首先基于化学组成和原子结构来分的,大多数材料落在明显的一个类别里面,尽管有许多中间品。

除此之外,有三类其他重要的工程材料-复合材料,半导体材料和生物材料。

Composites consist of combinations of two or more different materials, whereas semiconductors are utilized because of their unusual electrical characteristics; biomaterials are implanted into the human body. A brief explanation of the material types and representative characteristics is offered next.译文:复合材料由两种或者两种以上不同的材料组成,然而半导体由于它们非同寻常的电学性质而得到使用;生物材料被移植进入人类的身体中。

大学有机化学双语教学辅助材料 —单词对照

大学有机化学双语教学辅助材料 —单词对照

Learning Supplementsin Organic Chemistry有机化学双语教学辅助材料(常见中英文专业单词对照)有机化学常见概念中英对照中文名称英文名β-酮酸酯β-ketone esterDL规则DL conventionD-异构体D-isomerE-异构体E isomerL-异构体L-isomern+1规则n+1 ruleπ键pi bondR/S构型命名法Cahn–Ingold–Prelog (CIP) R/S convention R基R groups-反式构象s-trans conformationα,β-不饱和酮α,β-unsaturated ketoneσ键sigma bond氨、氨水ammonia(NH3)氨基amino group氨基酸amino acid氨络物ammine铵根离子ammonium ion(NH4+) ammonium. 胺amine螯合物chelate八隅规则octet rule半缩醛半缩酮hemiketal饱和脂肪族烃saturated aliphatic hydrocarbon 苯benzene苯环phenyl ring苯基phenyl group苯炔; 脱氢苯benzyne苄基;苯甲基benzyl group变性denaturation变旋Mutarotation氢离子活度的pH值pH丙二烯丙烷propane薄层色谱thin layer chromatography(TLC) 不饱和烃unsaturated hydrocarbon不规则的Atactic不完全八隅体incomplete octet布朗斯特碱Br.sted base布朗斯特酸Br.sted acid部分消旋的Scalemic差向异构化作用Epimerization差向异构体Epimers拆分; 分辨率; 分离度Resolution超共轭; 超共轭效应Hyperconjugation稠环芳烃Condensed aromatics船式构象Conformation (boat)纯手性; 纯手性的Homochiral醇Alcohol(ROH)醇酸Alcoholic acid醇盐Alkoxide(RO- M+) alkoxide ion. 醋酸盐Acetate单分子亲核取代反应SN1 reaction单分子消除反应E1 elimination reaction单配位基Monodentate蛋白质Protein等时的;同步的Isochronous等位; 等位的; Homotopic狄尔斯-阿尔德反应Diels-Alder reaction电负性Electronegativity电环化反应、π-键环化反应Electrocyclic reactions电价键; 离子键Ionic bond电偶极矩Electric dipole moment(μ) 电偶极子Electric dipole淀粉Starch动理学; 动力学Kinetics动力学拆分Kinetic resolution动力学产物Kinetic product对Para对称面Plane of symmetry对甲基苯磺酸盐Ots,Tosylate (toluene-4-sulfonate, 4-mec6h4so3)对溴苯磺酸盐Obs,Brosylate (4-bromobenzenesulfonate, 4-brc6h4so3), 对旋Disrotatory对映体Enantiomers对映体过量百分数Enantiomeric excess; enantiomeric ratio对映体过量的Enantiomerically enriched 对映异位的Enantiotopic非质子溶剂Aprotic solvent多步合成Multistep synthesis多配位基的Polydentate多原子分子Polyatomic molecule多原子离子Polyatomic ion惰性电子对Inert pair二环的Bicyclic二硫化物Disulfide二氯甲烷Dichloromethane(CH2Cl2) 二元化合物Binary compound反错构象Anti clinal反芳香性的Anti-aromatic反键轨道Antibonding orbital反平面Anti periplanar反式Trans反式的Anti反式构象Anti conformation反式加成Anti addition范德华力Van der Waals’ radius芳环; 芳族环Aromatic ring(Ar)芳基Aryl group芳烃Aromatic hydrocarbon芳香烃Arene芳族化合物; 芳香族化合物Aromatic compound非苯芳烃Nonbenzenoid aromatic hydrocarbon 非等时同步Anisochronous非对映异构的Diastereotopic非对映异构体Diastereoisomers非手性、非手性的Achiral肥皂Soap费歇尔投影式Fischer projection分馏Fractional distillation分歧、不同Allo-分子单元Formula unit分子轨道理论Molecular orbital theory 分子几何; 分子几何结构Molecular geometry分子离子Molecular ion分子量Molecular weight分子模型Molecular model分子筛Molecular sieve分子式Molecular formula酚Phenol酚酸Phenolic acid酚酞Phenolphthalein风化的Efflorescent砜Sulfone干馏Dry distillation甘油Glycerol甘油, 丙三醇Glycerol(HOCH2CH(OH)CH2OH) 甘油三酸酯Triglyceride高分子化合物Polymer隔离双键Isolated double bonds共扼二烯烃Conjugated diene共轭碱Conjugate base共轭双键Conjugated double bonds 共轭酸Conjugate acid共价键Covalent bond共振结构Resonance structures共振结构式Canonical forms共振效应Resonance effect构象Conformation构象异构体Conformers构型Configuration构造异构体Constitutional isomers固体石蜡Paraffin wax官能团Functional group冠醚Crown ether光学纯Enantiomerically pure (optically pure) 光学纯的Optically pure轨道Orbital国际纯粹与应用化学联合会Iupac过渡态Transition state过氧化物离子Superoxide ion合成材料Synthetic material合成纤维Synthetic fiber合成橡胶Synthetic rubber核磁共振Nmr核间距离,键长Bond length核酸外切酶Exo红外光谱IR spectroscopy,infrared spectroscopy 胡萝卜素Carotene互变体; 互变异构体Tautomer互变异构现象Tautomerism化学计量学; 化学计量法Stoichiometry化学键Chemical bond化学式量; 分子量Formula weight化学位移Chemical shift环化加成反应Cycloaddition reaction环氧化合物Epoxide缓冲溶液Bufferph buffer; buffer solution. 磺化反应Sulfonation reaction磺基Sulpho group磺酸Sulfonic acid混酸甘油酯Mixed glyceride活性亚甲基Active methylene group 基(后缀)-Yl极性分子Polar molecule极性键Polar bond几何异构体Geometric isomer加成反应Addition reaction加成化合物Addition compound加聚反应Addition polymerization 甲基Methyl(-CH3)甲烷Methane价电子Valence electron价键Valence bond假旋转Pseudorotation间位定位Meta-directing碱; 基极Base碱的、碱性的Alkaline碱水解常数Base hydrolysis constant 碱土金属Alkaline earth键焓Bond enthalpy键级Bond order键能Bond energy交叉式构象Conformation (staggered) 交叉式构象Staggered conformation 结构式Structural formula腈Nitrile肼、联氨Hydrazine(NH2NH2)锯架投影式Sawhorse projection聚合反应Po1ymerization均裂Homolytic bond cleavage 卡宾、碳烯Carbene R2C:.醌Quinone蜡Wax离去基团Leaving group离子电离; 离子电离作用Ionic dissociationionize; ionization. 离子盐Ionic compound salt立体化学Stereochemistry立体特异性的,立体专一性的Stereospecific立体选择性的,立体有择性的Stereoselective立体异构体Stereoisomers两性的Amphoteric两性离子Zwitterion两性溶剂Amphiprotic solvent 裂化Cracking裂解Pyrolysis邻Orthogonal邻近的Vicinal硫醇Thiol硫酚Thiophenol硫化物Sulfide卤代烃Halohydrocarbon卤离子Halide ion路易斯碱Lewis base路易斯结构Lewis structure路易斯酸Lewis acid螺环化合物Spiro compound螺旋度; 螺旋性Helicity马尔科夫尼科夫规则Markovniknov’s rule 麦芽糖Maltose煤Coal酶Enzyme醚Ether命名法; 命名原则Nomenclature内Endo内酰胺Lactam内消旋化合物Meso compounds内酯Lactone扭曲式构象Conformation (skewed) 扭转位阻Torsion barrier纽曼投影式Newman projection偶氮Azo偶极矩Dipole moment配体; 配基Ligand配位数Coordination number平键; 平伏键Equatorial bond平均键焓Average bond enthalpy 平面偏振光Plane polarized light葡萄糖Glucose前手性Prochiral强酸Strong acid羟基Hydroxy group羟基酸Hydroxy acid桥环化合物Bridged ring compound 桥头碳原子Bridgehead carbon亲电体; 亲电子试剂Electrophile亲核试剂Nucleophile亲核性Nucleophilicity亲双烯体Dienophile氢键Hydrogen bond氢氧化物Hydroxide氢氧化物、水合物Hydrate氰基Cyano group巯基Mercapto巯基Sulfhydryl group区域选择性Regioselective取代反应Substitution reaction取代基Substituent取代酸Substituted acid全规的;全同立构的Isotactic醛Aldehyde(RCHO)醛的后缀-Al炔烃Alkyne热力学Thermodynamics热力学产物Thermodynamic product 弱酸Weak acid叁键Triple bond石蜡Paraffin石蕊试纸Litmus paper石油Petroleum实验式; 经验式;Empirical formula手性; 手性的Chiral手性分子Chiral molecule手性中心Chiral center手性中心、不对称中心Stereogenic centre (Chiral centre, Asymmetric centre) 双分子亲核取代反应SN2 reaction双分子消除反应E2 elimination reaction双峰; 双重谱线Doublet双键Double bond双烯; 二烯烃Diene双原子分子Diatomic molecule水合氢离子Hydronium ion(H3O+)水解反应Hydrolysis reaction水煤气,蓝煤气;合成气Water gas;blue gas; synthesis gas 顺错构象Syn clinal顺式Cis顺式;同;共;Syn顺式共平面Syn periplanar顺式加成Syn addition顺旋Conrotatory赤式Erythro塑料Plastic塑料的老化Plastic ageing酸、酸的Acid酸电离常数Acid dissociation constant. 酸酐Acid anhydride酸碱指示剂Acid-base indicator羧基Carboxyl group羧酸Carboxylic acid缩氨脲Semicarbazone缩酮Ketal碳水化合物、糖类Carbohydrate碳正离子Carbocation羰基Carbonyl group糖Sugar天然产物Natural product铁离子Ferric ion.烃、碳氢化合物Hydrocarbon烃的衍生物Derivative of hydrocarbon 烃基Hydrocarbonyl同侧的Suprafacial同分异构体Isomer同系物Homo1og同系物; 同系化合物Homolog铜离子Cupric. (cu2+) cupric ion 酮Ketone酮Ketone(R-CO-R')酮酸Keto acid脱氢酶Dehydrogenases歪扭构象; 偏转构象Gauche conformation外消旋化作用Racemization外消旋混合物Racemic mixture烷基Alkyl group烷基Alkyl(-cnh2n+1) alkyl group. 烷烃Alkane paraffin.烷氧基Alkoxyl group王水Aqua regia未共用电子对Lone pair位阻Steric hindrance位阻异构体Atropisomers肟Oxime无机化合物Inorganic compound 无机化学Inorganic chemistry 无水的Anhydrous西佛碱Shiff's base吸湿的Hygroscopic吸湿性; 吸水性Hygroscopicity烯丙基Allyl group烯丙基正离子Allylic carbon烯烃Alkene洗涤剂Detergent洗脱; 洗脱法;洗剂Elution纤维素Cellulose酰胺Amide酰基Acyl group酰卤Acid halide消去反应Elimination reaction消旋体Racemate硝化反应Nitratlon reaction硝基Nitro group硝酸,王水Nitric acid. (hno3) aqua fortis 协定的, 一致的;协同的Concerted偕的Geminal辛烷Octane休克尔规则Hückel's rule溴的四氯化碳溶液Solution of bromine in carbon tetrachloride 溴水Bromine water旋光计Polarimeter旋光性Optical activity亚氨基Imino group亚砜Sulfoxide亚磺酸Sulfinic acid亚铁离子Ferrous ion亚铜离子Cuprous. (cu+) cuprous ion亚硝基Nitroso group 盐析Salting-out阳离子Cation乙醇Ethanol乙二胺四乙酸Edta乙醛Ethana1乙炔Ethyne乙酸Acetic acid乙酸Ethanoic acid 乙酸乙酯Ethyl acetate乙缩醛二乙醇Acetal乙烯Ethene乙酰乙酸乙酯Ethyl acetoacetate椅式构象Conformation (chair) 椅型构象; 椅式构象Chair conformation 异头物Anomers异位的Syndiotactic阴离子Anion阴碳离子; 负碳离子Carbanion银镜反应Silver mirror reaction 硬脂酸、十八酸Stearic acid油脂Oils and fats有机化合物Organic compound有旋光活性的Optically active右旋的Dextrorotatory (d)诱导效应Inductive effect原子化热Enthalpy of atomization. ( hat) 杂化; 杂交Hybridization杂化轨道Hybrid orbitals杂环的, 不同环式的Heterocyclic皂化作用Saponification蔗糖Sucrose正交Ortho脂肪酸Fatty acid脂肪族的Aliphatic脂环烃Alicyclic hydrocarbon 直角的;正交的Ortho-para director直立键Axial bonds指纹区Fingerprint region酯Ester酯化反应Esterification质谱法Mass spectrometry质子Proton质子给体; 质子给予体Proton donor质子溶剂Protic solvent中和反应Neutralization reaction 中间体Intermediate中介效应Mesomeric effect中性的Neutral轴手性;轴不对称性Axial chirality自由基,根,原子团Radical自由基; 游离基Free radical腙Hydrozone左旋的Laevorotatory (l)重氮化; 重氮化作用Diazotization重氮盐Diazonium salt重叠式构象Conformation (eclipsed) 重叠式构象Eclipsed conformation 重键; 多重键Multiple bond周环反应Pericyclic reactions。

船长_大副英文面试问题及参考答案

船长_大副英文面试问题及参考答案

船长面试问题及参考答案船长是船上最重要的职位,也是各方面要求最高的职位。

船东在面试船员时对船长的考核最认真,最浪费时间,也是最复杂的。

作为一名合格的船长,不但要求有丰富的海上工作经历、娴熟的船舶驾驶经验技术,更要有很好的商务操作能力、领导管理能力、极佳的个人人品、强大的人格魅力和感召力。

还要勤于动脑、身体力行,在所有船员面前树立典范。

船东在进行面试时,往往提问船长的问题最多,也最复杂,考察的时间也最长。

提问船长的问题涉及到国际安全管理规则、安全管理体系、船长资历、船舶管理、各种具体商务和技术问题等等。

下面收集了一部分面试试题,供广大面试船长参考。

其中的部分问题,不但船长必备,其他干部船员,尤其是大副也必须看,轮机长也应该参考一下。

1. Can you tell me about your education background?Please refer to an Master’s self-introduction in Part One of this book.实事求是,最好告诉人家在某个学校学了多长时间,最好也要告诉人家你接受某些社会培训的情况,谦虚好学毕竟是一个美德嘛。

2. What is a classification society? What is the purpose of classification survey? Please list some famous classification societies in the world.A classification society is usually an independent organization that carries out classification surveys, statutory surveys([船舶]法定检验.[ˈstætjutəri]), surveys related to notaries matters for ships, offshore installations, marine freight containers, materials and marine equipment. It also provides safety management certification services to shipping companies and their ships. The purpose of classification survey is to evaluate the situation of a ship and the management of a company and its ship.Some of the famous classification societies are: NK(Japanese 日本海事协会), CCS(Chinese classification society), ABS(American), DNV(Norwegian),LR(British Lloyd 英国劳氏), GL(German Lloyd 德国劳氏), KR(Korean), RINA(意大利船级社)。

化学化工类双语教学系列课程建设的研究与实践

化学化工类双语教学系列课程建设的研究与实践

化学化工类双语教学系列课程建设的研究与实践*胡瑞珏,苏海全(内蒙古大学化学化工学院,内蒙古呼和浩特010021)以双语教育为经,以讲授化学化工专业科学知识为纬,配合当前人们的科技信息和先进的教学策略,以培养国际化的材料合成及设计方面的高水平人才为宗旨的课程定位指导下,内蒙古大学的化学化工类双语教学(英汉)系列课程在教学目标、课程体系、讲学内容、方法和手段改革进行了理论和实践探索。

更新教学理念,搭建“专业科学知识教学与英语应用互通平台”和“双语教学与科研互通平台”;建设和改革课程体系及内容,改革教学方法和手段,实现教学方法多样化,教学手段现代化;建立多元化双语教学新模式全方位培养学生综合素质;培养了丰富教学经验的年龄结构合理的高学历教学团队,以教学团队作用保证授课质量。

一、建立多元化分层次双语教学新模式实施分层次双语教学,针对不同专业层次学生的培养目标,制定具体的双语教学计划,为在确保化学化工理论体系完整性的前提下因材施教。

内蒙古大学化学化工学院相继开设了“工程材料科学与设计”“精细化学品化学”“社会有机化学”和“分析化学”双语系列课程。

构建了课堂双语讲授研讨、英语演讲(presentation)训练,课外国外专家学术交流、专题讲座、撰写英语课题综述等多元化双语教学新模式,借鉴国际上先进的教学理念,营造浸润式语境,倡导探究式及合作式的学习方式,培养大学生的自我学习、自我获取知识能力以及全方位的综合科学素养与国际交流能力。

摘要:文章阐述了本学院化学化工类双语教学(英汉)系列课程建设的研究与实践。

通过搭建“专业科学知识教学与英语应用互通平台”和“双语教学与科研互通平台”,我们进行了课程体系及内容建设,教学方法和手段的改革;建立多元化分层次双语教学新模式。

国家教育部于2001年9月教高4号文件提出:国家重点建设大学三年内“双语教学”的课程比例要达到10%。

国家教育部于2007年颁发的《关于进一步深化本科教学改革全面提高教学质量的若干意见》中要求:鼓励开展双语教学工作,鼓励和支持留学回国人员用英语讲授专业课程,坚持教授上讲台,保证为学生提供高质量教学。

Rock mass classification

Rock mass classification

Rock mass classification3.1 IntroductionDuring the feasibility and preliminary design stages of a project, when very little detailedinformation on the rock mass and its stress and hydrologic characteristics is available, theuse of a rock mass classification scheme can be of considerable benefit.At its simplest,this may involve using the classification scheme as a check-list to ensure that all relevantinformation has been considered. At the other end of the spectrum, one or more rockmass classification schemes can be used to build up a picture of the composition andcharacteristics of a rock mass to provide initial estimates of support requirements, and toprovide estimates of the strength and deformation properties of the rock mass.It is important to understand that the use of a rock mass classification scheme does not(and cannot) replace some of the more elaborate design procedures. However, the use ofthese design procedures requires access to relatively detailed information on in situstresses, rock mass properties and planned excavation sequence, none of which may beavailable at an early stage in the project. As this information becomes available, the useof the rock mass classification schemes should be updated and used in conjunction withsite specific analyses.3.2 Engineering rock mass classificationRock mass classification schemes have been developing for over 100 years since Ritter(1879) attempted to formalise an empirical approach to tunnel design, in particular fordetermining support requirements. While the classification schemes are appropriate fortheir original application, especially if used within the bounds of the case histories fromwhich they were developed, considerable caution must be exercised in applying rockmass classifications to other rock engineering problems.Summaries of some important classification systems are presented in this chapter, andalthough every attempt has been made to present all of the pertinent data from theoriginal texts, there are numerous notes and comments which cannot be included. Theinterested reader should make every effort to read the cited references for a fullappreciation of the use, applicability and limitations of each system.Most of the multi-parameter classification schemes (Wickham et al (1972) Bieniawski(1973, 1989) and Barton et al (1974)) were developed from civil engineering casehistories in which all of the components of the engineering geological character of therock mass were included. In underground hard rock mining, however, especially at deeplevels, rock mass weathering and the influence of water usually are not significant andmay be ignored. Different classification systems place different emphases on the variousparameters, and it is recommended that at least two methods be used at any site duringthe early stages of a project.3.2.1 Terzaghi's rock mass classificationThe earliest reference to the use of rock mass classification for the design of tunnelsupport is in a paper by Terzaghi (1946) in which the rock loads, carried by steel sets, areestimated on the basis of a descriptive classification. While no useful purpose would beserved by including details of Terzaghi's classification in this discussion on the design ofsupport, it is interesting to examine the rock mass descriptions included in his originalpaper, because he draws attention to those characteristics that dominate rock massbehaviour, particularly in situations where gravity constitutes the dominant driving force.The clear and concise definitions and the practical comments included in thesedescriptions aregood examples of the type of engineering geology information, which ismost useful for engineering design.Terzaghi's descriptions (quoted directly from his paper) are:•Intact rock contains neither joints nor hair cracks. Hence, if it breaks, it breaks acrosssound rock. On account of the injury to the rock due to blasting, spalls may drop offthe roof several hours or days after blasting. This is known as a spalling condition.Hard, intact rock may also be encountered in the popping condition involving thespontaneous and violent detachment of rock slabs from the sides or roof.•Stratified rock consists of individual strata with little or no resistance againstseparation along the boundaries between the strata. The strata may or may not beweakened by transverse joints. In such rock the spalling condition is quite common.•Moderately jointed rock contains joints and hair cracks, but the blocks between jointsare locally grown together or so intimately interlocked that vertical walls do notrequire lateral support. In rocks of this type, both spalling and popping conditionsmay be encountered.•Blocky and seamy rock consists of chemically intact or almost intact rock fragmentswhich are entirely separated from each other and imperfectly interlocked. In suchrock, vertical walls may require lateral support.•Crushed but chemically intact rock has the character of crusher run. If most or all ofthe fragments are as small as fine sand grains and no recementation has taken place,crushed rock below the water table exhibits the properties of a water-bearing sand.•Squeezing rock slowly advances into the tunnel without perceptible volume increase.A prerequisite for squeeze is a high percentage of microscopic and sub-microscopicparticles of micaceous minerals or clay minerals with a low swelling capacity.•Swelling rock advances into the tunnel chiefly on account of expansion. The capacityto swell seems to be limited to those rocks that contain clay minerals such asmontmorillonite, with a high swelling capacity.3.2.2 Classifications involving stand-up timeLauffer (1958) proposed that the stand-up time for an unsupported span is related to thequality of the rock mass in which the span is excavated. In a tunnel, the unsupported spanis defined as the span of the tunnel or the distance between the face and the nearestsupport, if this is greater than the tunnel span. Lauffer's original classification has sincebeen modified by a number of authors, notably Pacher et al (1974), and now forms part ofthe general tunnelling approach known as the New Austrian Tunnelling Method.The significance of the stand-up time concept is that an increase in the span of thetunnel leads to a significant reduction in the time available for the installation of support.For example, a small pilot tunnel may be successfully constructed with minimal support,while a larger span tunnel in the same rock mass may not be stable without the immediateinstallation of substantial support. The New Austrian Tunnelling Method includes a number of techniques for safetunnelling in rock conditions in which the stand-up time is limited before failure occurs.These techniques include the use of smaller headings and benching or the use of multipledrifts to form a reinforced ring inside which the bulk of the tunnel can be excavated.These techniques are applicable in soft rocks such as shales, phyllites and mudstones inwhich the squeezing and swelling problems, described by Terzaghi (see previoussection), are likely to occur. The techniques are also applicablewhen tunnelling inexcessively broken rock, but great care should be taken in attempting to apply thesetechniques to excavations in hard rocks in which different failure mechanisms occur.In designing support for hard rock excavations it is prudent to assume that the stabilityof the rock mass surrounding the excavation is not time-dependent. Hence, if astructurally defined wedge is exposed in the roof of an excavation, it will fall as soon asthe rock supporting it is removed. This can occur at the time of the blast or during thesubsequent scaling operation. If it is required to keep such a wedge in place, or toenhance the margin of safety, it is essential that the support be installed as early aspossible, preferably before the rock supporting the full wedge is removed. On the otherhand, in a highly stressed rock, failure will generally be induced by some change in thestress field surrounding the excavation. The failure may occur gradually and manifestitself as spalling or slabbing or it may occur suddenly in the form of a rock burst. Ineither case, the support design must take into account the change in the stress field ratherthan the ‘stand-up’ time of the excavation.3.2.3 Rock quality designation index (RQD)The Rock Quality Designation index (RQD) was developed by Deere (Deere et al 1967)to provide a quantitative estimate of rock mass quality from drill core logs. RQD isdefined as the percentage of intact core pieces longer than 100 mm (4 inches) in the totallength of core. The core should be at least NW size (54.7 mm or 2.15 inches in diameter)and should be drilled with a double-tube core barrel. The correct procedures formeasurement of the length of core pieces and the calculation of RQD are summarised inFigure 5.1.Figure 5.1: Procedure for measurement and calculation of RQD (After Deere, 1989).Palmström (1982) suggested that, when no core is available but discontinuity tracesare visible in surface exposures or exploration adits, the RQD may be estimated from thenumber of discontinuities per unit volume. The suggested relationship for clay-free rockmasses is:RQD = 115 - 3.3 Jv (5.1)Where Jvis the sum of the number of joints per unit length for all joint (discontinuity)sets known as the volumetric joint count.RQD is a directionally dependent parameter and its value may change significantly,depending upon the borehole orientation. The use of the volumetric joint count can bequite useful in reducing this directional dependence.RQD is intended to represent the rock mass quality in situ. When using diamond drillcore, care must be taken to ensure that fractures, which have been caused by handling orthe drilling process, are identified and ignored when determining the value of RQD.When using Palmström's relationship for exposure mapping, blast induced fracturesshould not be included when estimating Jv.Deere's RQD has been widely used, particularly in North America, for the past 25years. Cording and Deere (1972), Merritt (1972) and Deere and Deere (1988) haveattempted to relate RQD to Terzaghi's rock load factors and to rockbolt requirements inL = 38 cmL = 17 cmL = 0no pieces > 10 cmL = 20 cmL = 35 cmDrilling breakL = 0no recoveryTotal length of core run = 200 cmsΣ Length of core pieces > 10 cm lengthx 100 = 55 %RQD =Total length of core runX 10038 + 17 + 20 + 35200RQD =44 Chapter 3: Rock mass classificationtunnels. In the context of this discussion, the most important use of RQD is as acomponent of the RMR and Q rock mass classifications covered later in this chapter.3.2.4 Rock Structure Rating (RSR)Wickham et al (1972) described a quantitative method for describing the quality of a rockmass and for selecting appropriate support on the basis of their Rock Structure Rating(RSR) classification. Most of the case histories, used in the development of this system,were for relatively small tunnels supported by means of steel sets, although historicallythis system was the first to make reference to shotcrete support. In spite of this limitation,it is worth examining the RSR system in some detail since it demonstrates the logicinvolved in developing a quasi-quantitative rock mass classification system.The significance of the RSR system, in the context of this discussion, is that itintroduced the concept of rating each of the components listed below to arrive at anumerical value of RSR = A + B + C .1. Parameter A, Geology: General appraisal of geological structure on the basis of:a. Rock type origin (igneous, metamorphic, sedimentary).b. Rock hardness (hard, medium, soft, decomposed).c. Geologic structure (massive, slightly faulted/folded, moderately faulted/folded,intensely faulted/folded).2. Parameter B, Geometry : Effect of discontinuity pattern with respect to the directionof the tunnel drive on the basis of:a. Joint spacing.b. Joint orientation (strike and dip).c. Direction of tunnel drive.3. Parameter C: Effect of groundwater inflow and joint condition on the basis of:a. Overall rock mass quality on the basis of A and B combined.b. Joint condition (good, fair, poor).c. Amount of water inflow (in gallons per minute per 1000 feet of tunnel).Note that the RSR classification used Imperial units andthat these units have been retained in this discussion.Three tables from Wickham et al's 1972 paper arereproduced in Tables 4.1, 4.2 and 4.3. Thesetables can beused to evaluate the rating of each of these parameters toarrive at the RSR value (maximum RSR = 100).For example, a hard metamorphic rock which is slightlyfolded or faulted has a rating of A = 22 (from Table 4.1). Therock mass is moderately jointed, with joints strikingperpendicular to the tunnel axis which is being driven east-west, and dipping at between 20° and 50°. Table 4.2 gives the rating for B = 24 for driving with dip (defined in themargin sketch).Drive with dipDrive against dipThe value of A + B = 46 and this means that, for joints of fair condition (slightlyweathered and altered) and a moderate water inflow of between 200 and 1,000 gallonsper minute, Table 4.3 gives the rating for C = 16. Hence, the final value of the rockstructure rating RSR = A + B + C = 62.A typical set of prediction curves for a 24 foot diameter tunnel are given in Figure 4.2which shows that, for the RSR value of 62 derived above, the predicted support would be2 inches of shotcrete and 1 inch diameter rockbolts spaced at 5 foot centres. As indicatedin the figure, steel sets would be spaced at more than 7 feet apart and would not beconsidered a practical solution for the support of this tunnel.For the same size tunnel in a rock mass with RSR = 30, the support could be providedby 8 WF 31 steel sets (8 inch deep wide flange I section weighing 31 lb per foot) spaced3 feet apart, or by 5 inches of shotcrete and 1 inch diameter rockbolts spaced at 2.5 feetcentres. In this case it is probable that the steel set solution would be cheaper and moreeffective than the use of rockbolts and shotcrete.Although the RSR classification system is not widely used today, Wickham et al'swork played a significant role in the development of the classification schemes discussedin the remaining sections of this chapter.Figure 4.2: RSR support estimates for a 24 ft. (7.3 m) diameter circular tunnel. Note that rockboltsand shotcrete are generally used together. (After Wickham et al 1972).。

材料科学与工程-专业英语-Unit--Classification-of-Materials译文

材料科学与工程-专业英语-Unit--Classification-of-Materials译文

材料科学与工程-专业英语-Unit--Classification-of-Ma terials译文————————————————————————————————作者:————————————————————————————————日期:Classification of Materials(材料分类)Solid materials have been conveniently grouped into three basic classifications: metals, ceramics, and polymers. This scheme is based primarily on chemical makeup and atomic structure, and most materials fall into one distinct grouping or another, although there are some intermediates. In addition, there are three other groups of important engineering materials—composites, semiconductors, and biomaterials.译文:固体材料被便利的分为三个基本的类型:金属,陶瓷和聚合物。

这个分类是首先基于化学组成和原子结构来分的,大多数材料落在明显的一个类别里面,尽管有许多中间品。

除此之外,有三类其他重要的工程材料-复合材料,半导体材料和生物材料。

Composites consist of combinations of two or more different materials, whereas semiconductors are utilized because of their unusual electrical characteristics; biomaterials are implanted into the human body. A brief explanation of the material types and representative characteristics is offered next.译文:复合材料由两种或者两种以上不同的材料组成,然而半导体由于它们非同寻常的电学性质而得到使用;生物材料被移植进入人类的身体中。

Principles of Plasma Discharges and Materials Processing9

Principles of Plasma Discharges and Materials Processing9

CHAPTER8MOLECULAR COLLISIONS8.1INTRODUCTIONBasic concepts of gas-phase collisions were introduced in Chapter3,where we described only those processes needed to model the simplest noble gas discharges: electron–atom ionization,excitation,and elastic scattering;and ion–atom elastic scattering and resonant charge transfer.In this chapter we introduce other collisional processes that are central to the description of chemically reactive discharges.These include the dissociation of molecules,the generation and destruction of negative ions,and gas-phase chemical reactions.Whereas the cross sections have been measured reasonably well for the noble gases,with measurements in reasonable agreement with theory,this is not the case for collisions in molecular gases.Hundreds of potentially significant collisional reactions must be examined in simple diatomic gas discharges such as oxygen.For feedstocks such as CF4/O2,SiH4/O2,etc.,the complexity can be overwhelming.Furthermore,even when the significant processes have been identified,most of the cross sections have been neither measured nor calculated. Hence,one must often rely on estimates based on semiempirical or semiclassical methods,or on measurements made on molecules analogous to those of interest. As might be expected,data are most readily available for simple diatomic and polyatomic gases.Principles of Plasma Discharges and Materials Processing,by M.A.Lieberman and A.J.Lichtenberg. ISBN0-471-72001-1Copyright#2005John Wiley&Sons,Inc.235236MOLECULAR COLLISIONS8.2MOLECULAR STRUCTUREThe energy levels for the electronic states of a single atom were described in Chapter3.The energy levels of molecules are more complicated for two reasons. First,molecules have additional vibrational and rotational degrees of freedom due to the motions of their nuclei,with corresponding quantized energies E v and E J. Second,the energy E e of each electronic state depends on the instantaneous con-figuration of the nuclei.For a diatomic molecule,E e depends on a single coordinate R,the spacing between the two nuclei.Since the nuclear motions are slow compared to the electronic motions,the electronic state can be determined for anyfixed spacing.We can therefore represent each quantized electronic level for a frozen set of nuclear positions as a graph of E e versus R,as shown in Figure8.1.For a mole-cule to be stable,the ground(minimum energy)electronic state must have a minimum at some value R1corresponding to the mean intermolecular separation (curve1).In this case,energy must be supplied in order to separate the atoms (R!1).An excited electronic state can either have a minimum( R2for curve2) or not(curve3).Note that R2and R1do not generally coincide.As for atoms, excited states may be short lived(unstable to electric dipole radiation)or may be metastable.Various electronic levels may tend to the same energy in the unbound (R!1)limit. Array FIGURE8.1.Potential energy curves for the electronic states of a diatomic molecule.For diatomic molecules,the electronic states are specifiedfirst by the component (in units of hÀ)L of the total orbital angular momentum along the internuclear axis, with the symbols S,P,D,and F corresponding to L¼0,+1,+2,and+3,in analogy with atomic nomenclature.All but the S states are doubly degenerate in L.For S states,þandÀsuperscripts are often used to denote whether the wave function is symmetric or antisymmetric with respect to reflection at any plane through the internuclear axis.The total electron spin angular momentum S (in units of hÀ)is also specified,with the multiplicity2Sþ1written as a prefixed superscript,as for atomic states.Finally,for homonuclear molecules(H2,N2,O2, etc.)the subscripts g or u are written to denote whether the wave function is sym-metric or antisymmetric with respect to interchange of the nuclei.In this notation, the ground states of H2and N2are both singlets,1Sþg,and that of O2is a triplet,3SÀg .For polyatomic molecules,the electronic energy levels depend on more thanone nuclear coordinate,so Figure8.1must be generalized.Furthermore,since there is generally no axis of symmetry,the states cannot be characterized by the quantum number L,and other naming conventions are used.Such states are often specified empirically through characterization of measured optical emission spectra.Typical spacings of low-lying electronic energy levels range from a few to tens of volts,as for atoms.Vibrational and Rotational MotionsUnfreezing the nuclear vibrational and rotational motions leads to additional quan-tized structure on smaller energy scales,as illustrated in Figure8.2.The simplest (harmonic oscillator)model for the vibration of diatomic molecules leads to equally spaced quantized,nondegenerate energy levelse E v¼hÀv vib vþ1 2(8:2:1)where v¼0,1,2,...is the vibrational quantum number and v vib is the linearized vibration frequency.Fitting a quadratic functione E v¼12k vib(RÀ R)2(8:2:2)near the minimum of a stable energy level curve such as those shown in Figure8.1, we can estimatev vib%k vibm Rmol1=2(8:2:3)where k vib is the“spring constant”and m Rmol is the reduced mass of the AB molecule.The spacing hÀv vib between vibrational energy levels for a low-lying8.2MOLECULAR STRUCTURE237stable electronic state is typically a few tenths of a volt.Hence for molecules in equi-librium at room temperature (0.026V),only the v ¼0level is significantly popula-ted.However,collisional processes can excite strongly nonequilibrium vibrational energy levels.We indicate by the short horizontal line segments in Figure 8.1a few of the vibrational energy levels for the stable electronic states.The length of each segment gives the range of classically allowed vibrational motions.Note that even the ground state (v ¼0)has a finite width D R 1as shown,because from(8.2.1),the v ¼0state has a nonzero vibrational energy 1h Àv vib .The actual separ-ation D R about Rfor the ground state has a Gaussian distribution,and tends toward a distribution peaked at the classical turning points for the vibrational motion as v !1.The vibrational motion becomes anharmonic and the level spa-cings tend to zero as the unbound vibrational energy is approached (E v !D E 1).FIGURE 8.2.Vibrational and rotational levels of two electronic states A and B of a molecule;the three double arrows indicate examples of transitions in the pure rotation spectrum,the rotation–vibration spectrum,and the electronic spectrum (after Herzberg,1971).238MOLECULAR COLLISIONSFor E v.D E1,the vibrational states form a continuum,corresponding to unbound classical motion of the nuclei(breakup of the molecule).For a polyatomic molecule there are many degrees of freedom for vibrational motion,leading to a very compli-cated structure for the vibrational levels.The simplest(dumbbell)model for the rotation of diatomic molecules leads to the nonuniform quantized energy levelse E J¼hÀ22I molJ(Jþ1)(8:2:4)where I mol¼m Rmol R2is the moment of inertia and J¼0,1,2,...is the rotational quantum number.The levels are degenerate,with2Jþ1states for the J th level. The spacing between rotational levels increases with J(see Figure8.2).The spacing between the lowest(J¼0to J¼1)levels typically corresponds to an energy of0.001–0.01V;hence,many low-lying levels are populated in thermal equilibrium at room temperature.Optical EmissionAn excited molecular state can decay to a lower energy state by emission of a photon or by breakup of the molecule.As shown in Figure8.2,the radiation can be emitted by a transition between electronic levels,between vibrational levels of the same electronic state,or between rotational levels of the same electronic and vibrational state;the radiation typically lies within the optical,infrared,or microwave frequency range,respectively.Electric dipole radiation is the strongest mechanism for photon emission,having typical transition times of t rad 10À9s,as obtained in (3.4.13).The selection rules for electric dipole radiation areDL¼0,+1(8:2:5a)D S¼0(8:2:5b) In addition,for transitions between S states the only allowed transitions areSþÀ!Sþand SÀÀ!SÀ(8:2:6) and for homonuclear molecules,the only allowed transitions aregÀ!u and uÀ!g(8:2:7) Hence homonuclear diatomic molecules do not have a pure vibrational or rotational spectrum.Radiative transitions between electronic levels having many different vibrational and rotational initial andfinal states give rise to a structure of emission and absorption bands within which a set of closely spaced frequencies appear.These give rise to characteristic molecular emission and absorption bands when observed8.2MOLECULAR STRUCTURE239using low-resolution optical spectrometers.As for atoms,metastable molecular states having no electric dipole transitions to lower levels also exist.These have life-times much exceeding10À6s;they can give rise to weak optical band structures due to magnetic dipole or electric quadrupole radiation.Electric dipole radiation between vibrational levels of the same electronic state is permitted for molecules having permanent dipole moments.In the harmonic oscillator approximation,the selection rule is D v¼+1;weaker transitions D v¼+2,+3,...are permitted for anharmonic vibrational motion.The preceding description of molecular structure applies to molecules having arbi-trary electronic charge.This includes neutral molecules AB,positive molecular ions ABþ,AB2þ,etc.and negative molecular ions ABÀ.The potential energy curves for the various electronic states,regardless of molecular charge,are commonly plotted on the same diagram.Figures8.3and8.4give these for some important electronic statesof HÀ2,H2,and Hþ2,and of OÀ2,O2,and Oþ2,respectively.Examples of both attractive(having a potential energy minimum)and repulsive(having no minimum)states can be seen.The vibrational levels are labeled with the quantum number v for the attrac-tive levels.The ground states of both Hþ2and Oþ2are attractive;hence these molecular ions are stable against autodissociation(ABþ!AþBþor AþþB).Similarly,the ground states of H2and O2are attractive and lie below those of Hþ2and Oþ2;hence they are stable against autodissociation and autoionization(AB!ABþþe).For some molecules,for example,diatomic argon,the ABþion is stable but the AB neutral is not stable.For all molecules,the AB ground state lies below the ABþground state and is stable against autoionization.Excited states can be attractive or repulsive.A few of the attractive states may be metastable;some examples are the 3P u state of H2and the1D g,1Sþgand3D u states of O2.Negative IonsRecall from Section7.2that many neutral atoms have a positive electron affinity E aff;that is,the reactionAþeÀ!AÀis exothermic with energy E aff(in volts).If E aff is negative,then AÀis unstable to autodetachment,AÀ!Aþe.A similar phenomenon is found for negative molecular ions.A stable ABÀion exists if its ground(lowest energy)state has a potential minimum that lies below the ground state of AB.This is generally true only for strongly electronegative gases having large electron affinities,such as O2 (E aff%1:463V for O atoms)and the halogens(E aff.3V for the atoms).For example,Figure8.4shows that the2P g ground state of OÀ2is stable,with E aff% 0:43V for O2.For weakly electronegative or for electropositive gases,the minimum of the ground state of ABÀgenerally lies above the ground state of AB,and ABÀis unstable to autodetachment.An example is hydrogen,which is weakly electronegative(E aff%0:754V for H atoms).Figure8.3shows that the2Sþu ground state of HÀ2is unstable,although the HÀion itself is stable.In an elec-tropositive gas such as N2(E aff.0),both NÀ2and NÀare unstable. 240MOLECULAR COLLISIONS8.3ELECTRON COLLISIONS WITH MOLECULESThe interaction time for the collision of a typical (1–10V)electron with a molecule is short,t c 2a 0=v e 10À16–10À15s,compared to the typical time for a molecule to vibrate,t vib 10À14–10À13s.Hence for electron collisional excitation of a mole-cule to an excited electronic state,the new vibrational (and rotational)state canbeFIGURE 8.3.Potential energy curves for H À2,H 2,and H þ2.(From Jeffery I.Steinfeld,Molecules and Radiation:An Introduction to Modern Molecular Spectroscopy ,2d ed.#MIT Press,1985.)8.3ELECTRON COLLISIONS WITH MOLECULES 241FIGURE 8.4.Potential energy curves for O À2,O 2,and O þ2.(From Jeffery I.Steinfeld,Molecules and Radiation:An Introduction to Modern Molecular Spectroscopy ,2d ed.#MIT Press,1985.)242MOLECULAR COLLISIONS8.3ELECTRON COLLISIONS WITH MOLECULES243 determined by freezing the nuclear motions during the collision.This is known as the Franck–Condon principle and is illustrated in Figure8.1by the vertical line a,showing the collisional excitation atfixed R to a high quantum number bound vibrational state and by the vertical line b,showing excitation atfixed R to a vibra-tionally unbound state,in which breakup of the molecule is energetically permitted. Since the typical transition time for electric dipole radiation(t rad 10À9–10À8s)is long compared to the dissociation( vibrational)time t diss,excitation to an excited state will generally lead to dissociation when it is energetically permitted.Finally, we note that the time between collisions t c)t rad in typical low-pressure processing discharges.Summarizing the ordering of timescales for electron–molecule collisions,we havet at t c(t vib t diss(t rad(t cDissociationElectron impact dissociation,eþABÀ!AþBþeof feedstock gases plays a central role in the chemistry of low-pressure reactive discharges.The variety of possible dissociation processes is illustrated in Figure8.5.In collisions a or a0,the v¼0ground state of AB is excited to a repulsive state of AB.The required threshold energy E thr is E a for collision a and E a0for Array FIGURE8.5.Illustrating the variety of dissociation processes for electron collisions with molecules.collision a0,and it leads to an energy after dissociation lying between E aÀE diss and E a0ÀE diss that is shared among the dissociation products(here,A and B). Typically,E aÀE diss few volts;consequently,hot neutral fragments are typically generated by dissociation processes.If these hot fragments hit the substrate surface, they can profoundly affect the process chemistry.In collision b,the ground state AB is excited to an attractive state of AB at an energy E b that exceeds the binding energy E diss of the AB molecule,resulting in dissociation of AB with frag-ment energy E bÀE diss.In collision b0,the excitation energy E b0¼E diss,and the fragments have low energies;hence this process creates fragments having energies ranging from essentially thermal energies up to E bÀE diss few volts.In collision c,the AB atom is excited to the bound excited state ABÃ(labeled5),which sub-sequently radiates to the unbound AB state(labeled3),which then dissociates.The threshold energy required is large,and the fragments are hot.Collision c can also lead to dissociation of an excited state by a radiationless transfer from state5to state4near the point where the two states cross:ABÃðboundÞÀ!ABÃðunboundÞÀ!AþBÃThe fragments can be both hot and in excited states.We discuss such radiationless electronic transitions in the next section.This phenomenon is known as predisso-ciation.Finally,a collision(not labeled in thefigure)to state4can lead to dis-sociation of ABÃ,again resulting in hot excited fragments.The process of electron impact excitation of a molecule is similar to that of an atom,and,consequently,the cross sections have a similar form.A simple classical estimate of the dissociation cross section for a level having excitation energy U1can be found by requiring that an incident electron having energy W transfer an energy W L lying between U1and U2to a valence electron.Here,U2is the energy of the next higher level.Then integrating the differential cross section d s[given in(3.4.20)and repeated here],d s¼pe24021Wd W LW2L(3:4:20)over W L,we obtains diss¼0W,U1pe24pe021W1U1À1WU1,W,U2pe24021W1U1À1U2W.U28>>>>>><>>>>>>:(8:3:1)244MOLECULAR COLLISIONSLetting U2ÀU1(U1and introducing voltage units W¼e E,U1¼e E1and U2¼e E2,we haves diss¼0E,E1s0EÀE11E1,E,E2s0E2ÀE1EE.E28>>>><>>>>:(8:3:2)wheres0¼pe4pe0E12(8:3:3)We see that the dissociation cross section rises linearly from the threshold energy E thr%E1to a maximum value s0(E2ÀE1)=E thr at E2and then falls off as1=E. Actually,E1and E2can depend on the nuclear separation R.In this case,(8.3.2) should be averaged over the range of R s corresponding to the ground-state vibrational energy,leading to a broadened dependence of the average cross section on energy E.The maximum cross section is typically of order10À15cm2. Typical rate constants for a single dissociation process with E thr&T e have an Arrhenius formK diss/K diss0expÀE thr T e(8:3:4)where K diss0 10À7cm3=s.However,in some cases E thr.T e.For excitation to an attractive state,an appropriate average over the fraction of the ground-state vibration that leads to dissociation must be taken.Dissociative IonizationIn addition to normal ionization,eþABÀ!ABþþ2eelectron–molecule collisions can lead to dissociative ionizationeþABÀ!AþBþþ2eThese processes,common for polyatomic molecules,are illustrated in Figure8.6.In collision a having threshold energy E iz,the molecular ion ABþis formed.Collisionsb andc occur at higher threshold energies E diz and result in dissociative ionization,8.3ELECTRON COLLISIONS WITH MOLECULES245leading to the formation of fast,positively charged ions and neutrals.These cross sections have a similar form to the Thompson ionization cross section for atoms.Dissociative RecombinationThe electron collision,e þAB þÀ!A þB Ãillustrated as d and d 0in Figure 8.6,destroys an electron–ion pair and leads to the production of fast excited neutral fragments.Since the electron is captured,it is not available to carry away a part of the reaction energy.Consequently,the collision cross section has a resonant character,falling to very low values for E ,E d and E .E d 0.However,a large number of excited states A Ãand B Ãhaving increasing principal quantum numbers n and energies can be among the reaction products.Consequently,the rate constants can be large,of order 10À7–10À6cm 3=s.Dissocia-tive recombination to the ground states of A and B cannot occur because the potential energy curve for AB þis always greater than the potential energycurveFIGURE 8.6.Illustration of dissociative ionization and dissociative recombination for electron collisions with molecules.246MOLECULAR COLLISIONSfor the repulsive state of AB.Two-body recombination for atomic ions or for mol-ecular ions that do not subsequently dissociate can only occur with emission of a photon:eþAþÀ!Aþh n:As shown in Section9.2,the rate constants are typically three tofive orders of magnitude lower than for dissociative recombination.Example of HydrogenThe example of H2illustrates some of the inelastic electron collision phenomena we have discussed.In order of increasing electron impact energy,at a threshold energy of 8:8V,there is excitation to the repulsive3Sþu state followed by dissociation into two fast H fragments carrying 2:2V/atom.At11.5V,the1Sþu bound state is excited,with subsequent electric dipole radiation in the ultraviolet region to the1Sþg ground state.At11.8V,there is excitation to the3Sþg bound state,followedby electric dipole radiation to the3Sþu repulsive state,followed by dissociation with 2:2V/atom.At12.6V,the1P u bound state is excited,with UV emission tothe ground state.At15.4V,the2Sþg ground state of Hþ2is excited,leading to the pro-duction of Hþ2ions.At28V,excitation of the repulsive2Sþu state of Hþ2leads to thedissociative ionization of H2,with 5V each for the H and Hþfragments.Dissociative Electron AttachmentThe processes,eþABÀ!AþBÀproduce negative ion fragments as well as neutrals.They are important in discharges containing atoms having positive electron affinities,not only because of the pro-duction of negative ions,but because the threshold energy for production of negative ion fragments is usually lower than for pure dissociation processes.A variety of pro-cesses are possible,as shown in Figure8.7.Since the impacting electron is captured and is not available to carry excess collision energy away,dissociative attachment is a resonant process that is important only within a narrow energy range.The maximum cross sections are generally much smaller than the hard-sphere cross section of the molecule.Attachment generally proceeds by collisional excitation from the ground AB state to a repulsive ABÀstate,which subsequently either auto-detaches or dissociates.The attachment cross section is determined by the balance between these processes.For most molecules,the dissociation energy E diss of AB is greater than the electron affinity E affB of B,leading to the potential energy curves shown in Figure8.7a.In this case,the cross section is large only for impact energies lying between a minimum value E thr,for collision a,and a maximum value E0thr for8.3ELECTRON COLLISIONS WITH MOLECULES247FIGURE 8.7.Illustration of a variety of electron attachment processes for electron collisions with molecules:(a )capture into a repulsive state;(b )capture into an attractive state;(c )capture of slow electrons into a repulsive state;(d )polar dissociation.248MOLECULAR COLLISIONScollision a 0.The fragments are hot,having energies lying between minimum and maximum values E min ¼E thr þE affB ÀE diss and E max ¼E 0thr þE af fB ÀE diss .Since the AB Àstate lies above the AB state for R ,R x ,autodetachment can occur as the mol-ecules begin to separate:AB À!AB þe.Hence the cross section for production of negative ions can be much smaller than that for excitation of the AB Àrepulsive state.As a crude estimate,for the same energy,the autodetachment rate is ffiffiffiffiffiffiffiffiffiffiffiffiffiM R =m p 100times the dissociation rate of the repulsive AB Àmolecule,where M R is the reduced mass.Hence only one out of 100excitations lead to dissociative attachment.Excitation to the AB Àbound state can also lead to dissociative attachment,as shown in Figure 8.7b .Here the cross section is significant only for E thr ,E ,E 0thr ,but the fragments can have low energies,with a minimum energy of zero and a maximum energy of E 0thr þE affB ÀE diss .Collision b,e þAB À!AB ÀÃdoes not lead to production of AB Àions because energy and momentum are not gen-erally conserved when two bodies collide elastically to form one body (see Problem3.12).Hence the excited AB ÀÃion separates,AB ÀÃÀ!e þABunless vibrational radiation or collision with a third body carries off the excess energy.These processes are both slow in low-pressure discharges (see Section 9.2).At high pressures (say,atmospheric),three-body attachment to form AB Àcan be very important.For a few molecules,such as some halogens,the electron affinity of the atom exceeds the dissociation energy of the neutral molecule,leading to the potential energy curves shown in Figure 8.7c .In this case the range of electron impact ener-gies E for excitation of the AB Àrepulsive state includes E ¼0.Consequently,there is no threshold energy,and very slow electrons can produce dissociative attachment,resulting in hot neutral and negative ion fragments.The range of R s over which auto-detachment can occur is small;hence the maximum cross sections for dissociative attachment can be as high as 10À16cm 2.A simple classical estimate of electron capture can be made using the differential scattering cross section for energy loss (3.4.20),in a manner similar to that done for dissociation.For electron capture to an energy level E 1that is unstable to autode-tachment,and with the additional constraint for capture that the incident electron energy lie within E 1and E 2¼E 1þD E ,where D E is a small energy difference characteristic of the dissociative attachment timescale,we obtain,in place of (8.3.2),s att¼0E ,E 1s 0E ÀE 1E 1E 1,E ,E 20E .E 28>><>>:(8:3:5)8.3ELECTRON COLLISIONS WITH MOLECULES 249wheres 0%p m M R 1=2e 4pe 0E 1 2(8:3:6)The factor of (m =M R )1=2roughly gives the fraction of excited states that do not auto-detach.We see that the dissociative attachment cross section rises linearly at E 1to a maximum value s 0D E =E 1and then falls abruptly to zero.As for dissociation,E 1can depend strongly on the nuclear separation R ,and (8.3.5)must be averaged over the range of E 1s corresponding to the ground state vibrational motion;e.g.,from E thr to E 0thr in Figure 8.7a .Because generally D E (E 0thr ÀE thr ,we can write (8.3.5)in the forms att %p m M R 1=2e 4pe 0 2(D E )22E 1d (E ÀE 1)(8:3:7)where d is the Dirac delta ing (8.3.7),the average over the vibrational motion can be performed,leading to a cross section that is strongly peaked lying between E thr and E 0thr .We leave the details of the calculation to a problem.Polar DissociationThe process,e þAB À!A þþB Àþeproduces negative ions without electron capture.As shown in Figure 8.7d ,the process proceeds by excitation of a polar state A þand B Àof AB Ãthat has a separ-ated atom limit of A þand B À.Hence at large R ,this state lies above the A þB ground state by the difference between the ionization potential of A and the electron affinity of B.The polar state is weakly bound at large R by the Coulomb attraction force,but is repulsive at small R .The maximum cross section and the dependence of the cross section on electron impact energy are similar to that of pure dissociation.The threshold energy E thr for polar dissociation is generally large.The measured cross section for negative ion production by electron impact in O 2is shown in Figure 8.8.The sharp peak at 6.5V is due to dissociative attachment.The variation of the cross section with energy is typical of a resonant capture process.The maximum cross section of 10À18cm 2is quite low because autode-tachment from the repulsive O À2state is strong,inhibiting dissociative attachment.The second gradual maximum near 35V is due to polar dissociation;the variation of the cross section with energy is typical of a nonresonant process.250MOLECULAR COLLISIONS。

A Versatile Zero Background T-Vector System for Gene

A Versatile Zero Background T-Vector System for Gene

Breakthrough TechnologiesA Versatile Zero Background T-Vector System for Gene Cloning and Functional Genomics1[C][W][OA]Songbiao Chen,Pattavipha Songkumarn,Jianli Liu,and Guo-Liang Wang*Department of Plant Pathology,The Ohio State University,Columbus,Ohio43210(S.C.,P.S.,J.L.,G.-L.W.); and Hunan Provincial Key Laboratory of Crop Germplasm Innovation and Utilization,Hunan Agricultural University,Changsha410128,China(G.-L.W.)With the recent availability of complete genomic sequences of many organisms,high-throughput and cost-efficient systems for gene cloning and functional analysis are in great demand.Although site-specific recombination-based cloning systems,such as Gateway cloning technology,are extremely useful for efficient transfer of DNA fragments into multiple destination vectors,the two-step cloning process is time consuming and expensive.Here,we report a zero background TA cloning system that provides simple and high-efficiency direct cloning of PCR-amplified DNA fragments with almost no self-ligation.The improved T-vector system takes advantage of the restriction enzyme Xcm I to generate a T-overhang after digestion and the negative selection marker gene ccdB to eliminate the self-ligation background after transformation.We demonstrate the feasibility andflexibility of the technology by developing a set of transient and stable transformation vectors for constitutive gene expression,gene silencing,protein tagging,protein subcellular localization detection,and promoter fragment activity analysis in plants.Because the system can be easily adapted for developing specialized expression vectors for other organisms, zero background TA provides a general,cost-efficient,and high-throughput platform that complements the Gateway cloning system for gene cloning and functional genomics.Rapid advances in genome sequencing technologies in the last few years have led to the complete decoding of many complex eukaryotic genomes and have stim-ulated large-scale analysis of gene functions in se-quenced genomes.In general,gene function can be elucidated using a variety of approaches,such as ectopic expression,gene silencing,protein subcellular localization examination,gene expression pattern analysis by promoter activity assay,structure-function analysis,and in vitro or in vivo biochemical assays (Hartley et al.,2000;Curtis and Grossniklaus,2003; Earley et al.,2006).Typically,all these approaches require the cloning of target genes,mutated fragments, or their promoter fragments into various specialized vectors for subsequent characterization.However,the traditional approach for engineering expression con-structs based on the restriction enzyme/ligase cloning method is extremely laborious and time consuming and is often hampered by lack of appropriate restric-tion sites;thus,the production of constructs is a significant technical obstacle for large-scale functional gene analysis in plants.In recent years,the Gateway cloning system from Invitrogen and the Creator cloning system from CLONTECH have been developed to facilitate large-scale production of gene constructs.The recombina-tional cloning systems are based on a two-step process (Marsischky and LaBaer,2004).The DNA fragment of interest isfirst cloned into a general donor plasmid. Subsequently,the DNA fragmentflanked by two site-specific recombination sites in the donor vector can be transferred precisely into a variety of expression vec-tors by site-specific recombination reactions.A great advantage of the recombinational cloning technologies is that once the DNA fragment has been engineered into a donor vector,the transfer of the DNA fragment into an expression destination vector is a simple reac-tion that requires no traditional restriction enzyme/ ligase cloning.The recombinational cloning systems, particularly the Gateway technology,have been widely used in the research community,and many Gateway-compatible open reading frame entry(do-nor)clone collections and expression vectors have been created for functional genomics in many organ-isms(Yashiroda et al.,2008),including plants(Karimi et al.,2007b).On the other hand,although extremely useful for the simple and efficient transfer of DNA fragments into multiple expression destination vec-tors,the usefulness of the Gateway cloning system is rather limited for many projects where only a single expression vector is required for a DNA fragment.The two-step cloning process of the Gateway technology is laborious and time consuming for the production of a1This work was supported by the National Science Foundation-Plant Genome Research Program(grant no.0605017).*Corresponding author;e-mail wang.620@.The author responsible for distribution of materials integral to the findings presented in this article in accordance with the policy described in the Instructions for Authors()is: Guo-Liang Wang(wang.620@).[C]Somefigures in this article are displayed in color online but in black and white in the print edition.[W]The online version of this article contains Web-only data.[OA]Open access articles can be viewed online without a sub-scription./cgi/doi/10.1104/pp.109.137125single expression vector.This is particularly true when a large number of plasmids must be cloned.Although a one-step recombinational cloning method was de-scribed to eliminate the production of an entry clone (Fu et al.,2008),the approach is rather limited in scope because long primers containing the specific attach-ment site(att)and two-step PCR are required(Fu et al., 2008).TA cloning is routinely used for cloning of PCR-amplified fragments.This technique exploits the ter-minal transferase activity of some DNA polymerases that add a3#-A overhang to each end of the PCR product.PCR products can be easily cloned into a linearized vector with3#-T overhangs compatible with 3#-A overhangs.Because it is difficult to generate a high-quality TA cloning vector in individual laborato-ries,many TA cloning kits are available in the market. Many of them use blue/white screening for recombi-nants,and the DNA fragments can only be cloned into the TA vector provided in the kit.To meet the need for high-throughput cloning of DNA fragments into di-verse expression vectors,we have developed a signif-icantly improved TA cloning vector system by taking advantage of the negative selection gene marker ccdB to eliminate the self-ligation background after trans-formation.We refer to this new method as the zero background TA cloning system(ZeBaTA).Numerous cloning tests in our laboratory have shown that ZeBaTA provides very high cloning efficiency with almost no self-ligation.Moreover,the ZeBaTA technology can be flexibly adapted for developing specialized expression vectors allowing single-step assembly of PCR-ampli-fied genes or fragments.We demonstrate the feasibility andflexibility of the technology by developing a set of 12transient and12stable transformation vectors for constitutive gene expression,gene silencing,protein tagging,protein subcellular localization,and promoter fragment activity analysis for rice(Oryza sativa)and Arabidopsis(Arabidopsis thaliana).Our results suggest that ZeBaTA technology can also be easily used to develop expression vectors for other organisms(e.g. Escherichia coli,yeast[Saccharomyces cerevisiae],insect, and mammal),thereby providing a novel and general high-throughput platform for functional genomics of target genes.RESULTSConstruction of the ZeBaTA SystemTwo different strategies were used to produce T-vectors,i.e.adding a single thymidine at the3# blunt ends of a linearized vector(Holton and Graham, 1991;Marchuk et al.,1991)and generating single3#-T overhangs of a linearized vector by restriction endo-nuclease digestion(Kovalic et al.,1991;Mead et al., 1991;Ichihara and Kurosawa,1993;Chen et al.,2006a). Although the former has been used to produce com-mercial cloning kits like the pGEM-T system,we selected the restriction endonuclease digestion-mediated strategy to develop a TA cloning vector system because this approach is easy to use for indi-vidual laboratories.Previous publications have de-scribed the use of restriction enzyme Xcm I(Kovalic et al.,1991;Mead et al.,1991)or Ahd I/Eam1105I (Ichihara and Kurosawa,1993;Chen et al.,2006a)to produce intermediate T-vectors.We chose Xcm I as the digestion enzyme to develop the ZeBaTA cloning system because it had a better digestion efficiency than AhdI.Figure1.Construction of the ZeBaTA system.A,Schematic represen-tation of direct cloning of PCR product using the ZeBaTA vector system. The linker of the vector(in gray)is removed after Xcm I digestion yielding a linearized T-vector.B,TA cloning tests of the ZeBaTA system.(1)Self-ligation of Xcm I-digested pGXT using T4DNA ligase from Promega.(2)Ligation of Xcm I-digested pGXT with the PCR product of the rice blast fungus M.oryzae gene MGG_07986.5using T4DNA ligase from Promega.(3)Ligation of Xcm I-digested pGXT with the PCR product of MGG_07986.5using T4DNA ligase from USB Corporation. C,Samples of restriction digestion analysis of the randomly selected colonies derived from ligation of Xcm I-digested pGXT with the PCR product of MGG_07986.5using T4DNA ligase from Promega.pGXT contains two Bam HI recognition sites outside the two Xcm I recognition sites(Supplemental Fig.S1),and MGG_07986.5contains one internal Bam HI site.All samples(lanes1–20)digested by Bam HI released two bands as expected.M,1-kb DNA ladder.Chen et al.The schematic illustration of the improved T-vector system for PCR-amplified gene/fragment cloning is shown in Figure 1A.A pair of Xcm I recognition sites,CCAATACT/TGTATGG,was introduced in the vec-tors,which allowed the generation of a single thymi-dine residue at both 3#ends of the vector when digested with Xcm I.To eliminate the potential self-ligation due to incomplete Xcm I digestion of the vec-tor,the ccdB gene (Bernard and Couturier,1992;Miki et al.,1992),which inhibits growth of E .coli strains by expressing a protein to interfere with its DNA gyrase,was introduced between the two Xcm I sites.Hence,any self-ligation transformants containing the ccdB gene will be eliminated.To test the cloning efficiency of the T-vector system,an intermediate vector pGXT was generated based on the backbone of the pGEM-T easy vector.After Xcm I digestion,ligation reactions of the resulting T-vector alone and T-vector with the PCR-amplified product of the rice blast fungus Mag-naporthe oryzae gene MGG_07986.5were set up follow-ing the standard protocol of the Promega pGEM-T easy vector system.Transformation tests showed that ligation of the T-vector with the MGG_07986.5frag-ments yielded a large number of colonies,whereas ligation of the T-vector alone yielded only a few colonies (Fig.1B).Restriction digestion screening con-firmed that the plasmids yielded from ligation of theT-vector with the PCR product were true recombinants (Fig.1C).To establish a general guide for consistently successful cloning,several factors,such as Xcm I over-digestion for generating a T-vector,insert-to-vector molar ratios,and different T4DNA ligases,were tested to determine their effect on cloning efficiency.Surprisingly,we observed that T4DNA ligases could have a significant impact on cloning efficiency.Liga-tions using Promega T4DNA ligase,the same product used by the pGEM-T easy vector system,consistently gave very high cloning efficiency with almost no self-ligation background.However,regular T4DNA li-gases from USB Corporation usually gave very low ligation efficiency for this TA cloning system (Fig.1B).Although the ligation efficiencies were a little higher at insert-to-vector molar ratios of 4:1to 8:1with the T-vector generated by standard digestion,ligations from vectors with 10-or 20-fold overdigestion and ligations with insert-to-vector molar ratios of 1:1,4:1,8:1,and 12:1all yielded good cloning efficiency when Promega T4DNA ligase was used (data not shown).Set of Expression ZeBaTA Vectors for PlantsUsing ZeBaTA,we developed a set of transient and stable expression vectors for different applications in both dicot and monocot plants.The backbone ofallFigure 2.Site-specific mutagenesis of the maize ubiqutin-1promoter (A)and the backbone of the binary vector pCAMBIA1300(B)in which three Xcm I recognition sites were deleted.The nucleotides represented in lowercase italic letters are the positions where deletions or mutations were made.Kan,Kanamycin resistance gene;LB,T-DNA left border;RB,T-DNA right border.C,Comparison of the levels of GUS expression mediated by the original and modified maize ubiquitin-1promoter in transiently transfected rice protoplasts.GUS activities are represented as a ratio of relative GUS/LUC.The experiment was repeated three times with similar results.1,Protoplast sample transfected with pUbiGUS;2,protoplast sample transfected with pXUN-GUS.A Zero Background Vector Systemtransient expression vectors is derived from pBlue-script II KS (),a high-copy-number cloning vector that can facilitate the isolation of a large amount of plasmid DNA for transient ex-pression.The backbone of all stable expression vectors is derived from pCAMBIA1300(),an Agrobacterium tumefaciens binary vector widely used for transformation in both dicot and monocot plants.Two different promoters,a cauliflower mosaic virus 35S promoter (Odell et al.,1985)and a maize (Zea mays )ubiquitin-1promoter (Christensen et al.,1992)were used to drive expression of genes of interest in dicots and monocots,respectively.The 35S promoter is more efficient in dicots,whereas the maizeubiquitin-1Figure 3.ZeBaTA-based expression vectors for gene overexpression/silencing,protein tagging,protein subcellular localization,and promoter analysis in plants.A,Schematic structures of the transient expression vectors generated by Xcm I digestion.B,Schematic structures of the Agrobacterium -mediated stable transformation vectors generated by Xcm I digestion.LB,T-DNA left border;RB,T-DNA right border.Chen et al.promoter is more efficient in monocots(Christensen et al.,1992).The original maize ubiquitin-1promoter and pCAMBIA1300vector,however,contain one and three Xcm I recognition sites,respectively(Fig.2,A and B).To facilitate the construction of the ZeBaTA-based expression vectors,the Xcm I recognition sites of the maize ubiquitin-1promoter and pCAMBIA1300vec-tor were eliminated by site-specific deletion or site-specific mutation(Fig.2,A and C).The designed expression vectors were all engineered with the cas-sette of the Xcm I-ccdB-Xcm I fragment(Supplemental Fig.S1).Figure3,A and B,illustrates the structural maps of the12transient and12stable transformation T-vectors.All vectors have been tested for cloning at least one time,and the results showed that these ZeBaTA expression vectors,including those binary vectors that are relatively large in size(.10kb), consistently yielded high cloning efficiency(Supple-mental Fig.S2).Because the maize ubiquitin-1promoter used in this system was modified to block its original Xcm I recog-nition site by deleting a single base(Fig.2A)at the position of nucleotide2480,a gus gene(Jefferson et al., 1987)was amplified by PCR and then cloned into the Xcm I-digested pXUN vector to produce an expression construct to test the expression activity of the modified maize ubiquitin-1promoter.The derived constructpXUN-GUS and a control construct pUbi-GUS(Chen et al.,2006b),of which a gus gene is driven by the original maize ubiquitin-1promoter,were tested tran-siently in the transfected rice protoplasts.Transient expression assays showed that the levels of GUS activity in rice protoplasts transfected with these two constructs were similar(Fig.2C),indicating that the deletion of nucleotide2480does not affect the activity of the maize ubiquitin-1promoter.Testing of Tagged Protein ExpressionEpitope tagging is a widely used method for the rapid and effective characterization,purification,and in vivo localization of the protein products of cloned genes.To facilitate gene cloning for epitope tagging in plants,a total of12epitope-tagging vectors(Fig.3,A and B)were constructed using ZeBaTA.These vectors contain a35S promoter or a maize ubiquitin-1pro-moter,allowing direct cloning of genes of interest into expression vectors to express a translational fusion of target protein with three commonly used epitope tags in plants(i.e.FLAG,HA,or Myc;Earley et al.,2006). To determine the feasibility of this epitope-tagging system,a gfp gene was cloned into the pXUN-HA vector to fuse with the HA tag.The resulting expres-sion construct pXUN-HA-GFP was transiently ex-pressed in rice protoplasts.As shown in Figure4,A and B,protoplasts transfected with pXUN-HA-GFP showed strong GFPfluorescence,and HA-tagged GFP protein was detected in protein extracts of trans-fected protoplasts but not in the nontransfected con-trol,demonstrating the potential application of this system for functional study of target proteins in plants.Gene Silencing by Hairpin RNAi or Artificial MicroRNA In plants,a typical and efficient approach to induce gene silencing is to use an inverted-repeat construct to express hairpin RNA(hpRNA;Waterhouse et al.,1998; Smith et al.,2000).However,a major limitation of the hpRNA interference(hpRNAi)approach for high-throughput gene functional analysis is the cumber-some cloning procedure for generating hpRNAi constructs(Helliwell and Waterhouse,2003).The gen-eration of a hpRNAi construct using conventional restriction enzyme digestion and DNA ligation meth-ods usually requires several cloning steps.Although Gateway cloning technology has been adapted to gen-erate hpRNAi constructs(Helliwell and Waterhouse, 2003;Miki and Shimamoto,2004),it still requires two cloning steps.With the ZeBaTA system,hpRNAi con-structs can be made by a single-step cloning procedure (Fig.5A).Instead of making an inverted-repeat cas-sette by DNA recombination techniques,we designed a new approach to assemble the hpRNAi cassette by overlapping PCR.Briefly,a target fragment with an additional3#-terminal sequence complementary to both the5#-and3#-terminal ends of a designed spacer fragment is amplified as afirst step.The overlapping fragments are then fused together in a subsequent PCR reaction,and the resulting inverted-repeat is cloned directly into a ZeBaTA expression vector(Fig.5A).To test the feasibility of this approach,an RNAiconstruct Figure4.Transient expression and protein-tagging detection of the ZeBaTA vectors in rice protoplasts.A,Fluorescence microscopy of the expression of HA-tagged GFP in rice protoplasts.B,Detection of HA-tagged GFP by western ne1,Nontransfected control protoplast sample;lanes2to4,independent protoplast samples transfected with pXUN-HA-GFP.[See online article for color version of thisfigure.]A Zero Background Vector Systemwas generated by overlapping PCR in which the sense and antisense 217-bp fragments of the Arabidopsis phytoene desaturase gene (PDS )were separated by a 420-bp stuffer fragment derived from the gus gene.The resulting fragment was cloned into the pCXSN vector (Fig.3B)to generate the expression construct pCXSN-atPDS-RNAi.The RNAi construct was introduced into Arabidopsis by the floral-dip method.Over 80%of transgenic plants had a clear albino phenotype (Fig.6A),a typical visible phenotype caused by silencing of the PDS gene (Guo et al.,2003;Miki and Shimamoto,2004).Recently,the artificial microRNA (amiRNA)ap-proach has been introduced for highly specific gene silencing in both dicot and monocot plants (Niu et al.,2006;Schwab et al.,2006;Ossowski et al.,2008;Warthmann et al.,2008).Typically,the amiRNA is generated by site-directed mutagenesis on precursors of endogenous miRNAs to exchange the natural miRNA sequences with those of amiRNAs using overlapping PCR (Ossowski et al.,2008).The same ZeBaTA-based vector system developed for ectopic gene expression and hpRNAi can also be used for making amiRNA expression constructs by simpleTAFigure 5.Schematic illustration of the construction of hpRNAi or amiRNA constructs by single-step cloning.A,Generation of hpRNAi constructs by overlapping PCR approach.The target gene fragment and the stuffer sequence fragment are amplified in the first-round PCR.Primers P2,P3,and P4introduce complementary adapters (indicated by vertically lined boxes)to the amplified fragments.The two amplified fragments are fused together as an inverted-repeat cassette in the second-round PCR by using single P1primer.The resulting fragment is then directly cloned into the plant expression T-vector.B,Generation of amiRNA constructs by overlapping PCR approach.C,Generation of amiRNA constructs for rice genes by single-step PCR.The expression vectors pXUN-osaMIR528and pCXUN-osaMIR528were preassembled with 5#and 3#stemloop backbone sequences of a rice miRNA precursor Osa-MIR-528(Warthmann et al.,2008).Thus,making amiRNA constructs for rice target genes only requires an amiRNA-amiRNA*fragment generated from single-step PCR.The nucleotides represented in lowercase letters are the positions where mutations were made to introduce two Xcm I recognition sites.Chen et al.cloning (Fig.5B),thus bypassing the time-consuming two-step procedure for the regular restriction enzyme digestion-mediated cloning or the Gateway cloning (Ossowski et al.,2008).We further developed a ZeBaTA-amiRNA system to simplify the generation of rice amiRNA constructs because our lab is focusing on rice functional genomics.The new ZeBaTA-amiRNA vector was designed based on the stemloop backbone derived from Osa-MIR528,an endogenous rice miRNA precursor that has been used to efficiently express amiRNAs for highly specific silencing of targeted genes in rice (Warthmann et al.,2008).By site-directed muta-genesis of a single base on the 5#and 3#stemloop backbones of Osa-MIR528,respectively,a cassette of 5#Osa-MIR528stemloop backbone-Xcm I-ccdB -Xcm I-3#Osa-MIR528was assembled and cloned into the expres-sion vectors where the expression of amiRNA is under the control of the maize ubiquitin-1promoter.Figure 5C illustrates the structural maps of the Osa-MIR528-based vectors pXUN-osaMIR528and pCXUN-osaMIR528.The vectors allow for high-throughput generationof rice amiRNA constructs by cloning the amiRNA-amiRNA*fragment generated from a single-step PCR into the ZeBaTA vector with the preassembled Osa-MIR528stemloop backbone (Fig.5C;Supplemental Fig.S3),thus avoiding the time-consuming overlapping PCR.The modified vector was evaluated by expression of the amiRNA for silencing of the OsPDS gene.The two constructs pCXUN-amiPDS and pCXUN528-PDS,which contain original or modified Osa-MIR528stem-loop backbone with amiRNA sequence targeting OsPDS ,respectively ,were introduced into rice cv Nip-ponbare by Agrobacterium -mediated transformation.Consistent with a previous study (Warthmann et al.,2008),70.1%of the primary transgenic lines transformed with pCXUN-amiPDS had a bleaching PDS silencing phenotype (Fig.6B;Table I).Similarly,77.1%of the primary transgenic lines transformed with pCXUN528-PDS had the same albino phenotype,suggesting that the mutagenesis on the Osa-MIR528stemloop backbone does not affect the biogenesis of the amiRNA for silenc-ing of the PDS gene.Protein Subcellular Localization/Colocalization and Promoter Activity AssayTo investigate the subcellular localization or colo-calization of particular proteins,a set of ZeBaTA vectors (i.e.pXDG,pXDR,pCXDG,and pCXDR)was devised for transient or stable expression of protein fusions with GFP or red fluorescent protein.The vectors contain a 35S promoter-driven gfp or DsRed cassette that has been used to visualize protein local-ization in both dicot and monocot plants (Goodin et al.,2002;Chen et al.,2006b).As shown in Figure 3,A and B,PCR products of genes of interest can be simply engineered into the vectors to fuse with the gfp or DsRed gene.To confirm whether the vectors can be used for detecting protein localization in plant cells,the rice Spin1gene encoding a putative RNA-binding protein previously shown to be nuclear targeted(Vega-Sa´nchez et al.,2008)was cloned into vectors pXDG and pXDR to fuse in-frame with gfp and DsRed ,respectively.Transient expression of the constructs pXDG-Spin1and pXDR-Spin1in rice protoplasts dem-onstrated that the GFP-and DsRed-SPIN1fusion proteins were targeted to the nuclear region as pre-dicted (Fig.7A).For promoter activity assays,two reporters,gus and gfp ,were used for constructing pXGUS-P/pCXGUS-P and pXGFP-P/pCXGFP-P ,respectively.The linear T-vectors of pXGUS-P/pCXGUS-P orpXGFP-P/Figure 6.Silencing of the PDS gene in Arabidopsis and rice by the ZeBaTA-based hpRNAi or amiRNA approaches.A,Arabidopsis plants transformed with the hpRNAi construct pCXSN-atPDS-RNAi showing the PDS silencing albino phenotype.(1)Control plant;(2and 3)two examples of transgenic Arabidopsis plants.B,Rice plants transformed with the amiRNA vectors showing the albino phenotype.(1)Control plant;(2)example of pCXUN-amiPDS-transformed plants;and (3)example of pCXUN528-PDS-transformed plants.C,RT-PCR analysis of PDS suppression transgenic rice plants.Five independent primary plants (1,2,3,4,and 5)transformed with pCXUN-amiPDS and five independent primary plants (6,7,8,9,and 10)transformed with pCXUN528-PDS were selected for the analysis.CK,Wild-type Nip-ponbare plant used as the control.Table I.PDS silencing frequency of transgenic rice mediated by the ZeBaTA-amiRNA systemamiRNA VectorTotal Independent TransformantsAlbino PhenotypeEfficiency%pCXUN-amiPDS 553970.1pCXUN528-PDS 352777.1A Zero Background Vector SystempCXGFP-P (Fig.3,A and B)allow direct cloning of PCR-amplified promoter fragments located in front of the reporter genes.As proof of concept,the 35S pro-moter was cloned into pCXGUS-P to drive expression of the reporter gene gus .Arabidopsis plants stably transformed with the construct pCX-35S-GUS showed constitutive GUS expression in the whole plants (Fig.7B),confirming the feasibility of the system for assay-ing promoter activity.DISCUSSIONWith the rapid development of the next-generation sequencing technology,more plant genomes will be sequenced in the near future.How to rapidly deter-mine the function of the identified genes on a large scale is a daunting challenge.The ability to efficiently make constructs to transiently and stably express specific genes in cells,tissues,or whole plants is a fundamental aspect and bottle neck of plant functional genomics research.Traditionally,the cloning vectorsfor plant research carry a multicloning site (MCS)within their target gene expression cassettes.The restriction sites in the MCS are rather limited,making cloning of most target genes difficult.Although TA cloning vectors have been widely used for cloning of PCR-amplified fragments,the system has not yet been incorporated in the cloning vectors for transient and stable expression of target genes because of the tech-nical challenge of generating low-background TA cloning vectors.The Gateway system has been a popular choice for generating various constructs be-cause it allows the gene of interest to be easily cloned into specifically designed plasmids without DNA re-striction digestions.The two-step cloning and expen-sive reagents,however,make the Gateway system impractical for large-scale cloning in most individual laboratories when the entry clone collections are not available.The ZeBaTA system described here over-comes the limitations of both the TA and Gateway cloning systems.After two Xcm I recognition sites have been introduced into the MCS,any PCR fragments with a T-overhang can be easily cloned into a ZeBaTA vector.With the introduction of the negative selection marker gene ccdB between the two Xcm I sites,any self-ligation transformants are ing this tech-nology,we constructed a set of 12transient and 12stable transformation vectors for plant gene expres-sion studies and tested the vectors in rice or Arabi-dopsis in our laboratories.These vectors can be used in a wide range of functional genomics projects in plants and will be distributed to the research community upon request.Under certain conditions,cloning with T-vectors generated by digestion with Ahd I or Xcm I gave low efficiency and the T residue of the insert-vector junc-tion in the recombinant clones is often missing (Mead et al.,1991;Chen et al.,2006a).Chen et al.(2006a)speculated that this may be due to the presence of unknown factors that,during digestion and prepara-tion of the T-vectors,influence the stability of 3#-T overhangs.In this study,we found that the main factor affecting successful cloning is the use of an appropri-ate T4DNA ligase.We tested the Promega T4DNA ligase,which is included in the pGEM-T easy vector system,and the T4DNA ligase from USB Corporation.The ligations using Promega T4DNA ligase consis-tently gave a very high cloning efficiency;most of the ligations using USB Corporation T4DNA ligases yielded low efficiency.Many of the recombinant plas-mids from the latter ligations missed a T residue in the insert-vector junction,consistent with observations by Mead et al.(1991)and Chen et al.(2006a).The T residue is missing mainly because regular commercial T4DNA ligases contain exonuclease activities that can remove the 3#-T tails from the vector,as reported in the technical manual of the pGEM-T and pGEM-T easy vector systems (/tbs/tm042/tm042.pdf);removal of the 3#-T tails from the vector results in very low cloning efficiency.When the Promega T4DNA ligase was used for ligation,weFigure 7.Protein subcellular localization and promoter activity anal-ysis using the ZeBaTA vectors.A,Fluorescence microscopy of the coexpression of GFP and DsRed,or GFP-SPIN1and DsRed-SPIN1fusions in rice protoplasts.Scale bar =20m m.The RNA binding nuclearprotein SPIN1was used as a tester (Vega-Sa´nchez et al.,2008).B,GUS staining of Arabidopsis transformed with pCX-35S-GUS,where the 35S promoter was cloned into the vector pCXGUS-P to test the system.CK,Plant transformed with control vector pCAMBIA1300();pCX-35S-GUS-1and pCX-35S-GUS-2,two independent primary transgenic plants.Chen et al.。

四级补全句子经典短语例句

四级补全句子经典短语例句

四级补全句子经典短语例句Talked to a stranger you meet by chance in the wood.对一个你在树林中偶然遇到的陌生人说话。

So it will have a free space to further develop, and be for certain of great significance of reality and society in the intelligence decision-making of commerce.因而具有更大的发展空间,必将在商业智能决策中产生巨大的现实意义和社会意义。

I wanted to be certain of my own wisdom by copying Solomon, who had knowledge of hyssop and of tree.我希望仿效通晓牛膝草和树木知识的所罗门王,确信自己的智慧。

Now he could focus his attention on examining the strange ring.现在他可以集中注意研究这枚戒指了。

However, people should be cautious of the excessive reliance on cell phones.但是,人们也要警惕对于手机的过度依赖。

In no case can we cheapen the quality of products.在任何情况下我们都不能降低产品质量。

What would happen to her in case I was ill, in case I died, or if we simply grew cold to one another?万一我病了,万一我死了,或者如果我们只是对彼此变得冷漠了,她将会怎么样呢?It should notify an administrator in case of a system error.在系统出错的情况下,它应该能够通知管理员。

Bulk Loading

Bulk Loading

IACSI N T E R N A TIONAL ASSOCIATIONOF CLASSIFICATION SOCIETIESBULK CARRIERSGuidance and Information on Bulk Cargo Loading and Discharging to Reduce the Likelihood ofOver-stressing the Hull Structure© IACS - International Association of Classification Societies, 1997All rights reserved.Except as permitted under current legislation no part of this work may be photocopied, stored in a retrieval system, published, performed in public, adapted, broadcast, transmitted, recorded or reproduced in any form or by any means, without prior permission of the copyright owner.Where IACS has granted written permission for any part of this publication to be quoted such quotation must include acknowledgement to IACS.Enquiries should be addressed to;The Permanent Secretary,International Association of Classification Societies,5 Old Queen Street,London,SW1H 9JATelephone:+(44) 171-976-0660Telefax+(44) 171-976-0440Internet permsec@ACKNOWLEDGEMENTIACS acknowledges the contributions make by a variety of marine industry sources in the preparation of this text and specifically acknowledges the kind contribution of the International Bulk Journal for the provision of a photograph for the front cover of this edition.TERMS AND CONDITIONS"The International Association of Classification Societies (IACS), its Member Societies and their officers, members, employees, and agents (on behalf of whom this notice is issued) shall be under no liability or responsibility in negligence or otherwise howsoever to any person in respect of any information or advice expressly or impliedly given in this document, or in respect of any inaccuracy herein or omission herefrom or in respect of any act or omission which has caused or contributed to this document being issued with the information or advice it contains (if any).Without derogating from the generality of the foregoing, neither IACS nor its Member Societies and their officers, members, employees or agents shall be liable in negligence or otherwise howsoever for any indirect or consequential loss to any person caused by or rising from any information, advice, inaccuracy or omission being given or contained herein or any act or omission causing or contributing to any such information, advice, inaccuracy, or omission being given or contained herein."EXECUTIVE SUMMARYThis publication is intended to provide the shipping community with guidance and information on the loading and discharging of bulk carriers to remain within the limitations as specified by the classification society to reduce the likelihood of over-stressing the ship's structure.The loads that affect the ship's structure are generally discussed with special reference to the structural strength limitations imposed by the ship's classification society.The process of planning and controlling cargo operations is addressed with special reference to the derivation of the loading and unloading plans and the requirements for ship/shore communication.A review of the potential problems that could be encountered during cargo operations is presented. Guidance is given on the measures that should be taken to monitor and control cargo and ballasting operations in order to reduce the possibility of over-stressing the ship's structure.LIST OF CONTENTSEXECUTIVE SUMMARY (i)1.INTRODUCTION (1)1.1FACTORS CONTRIBUTING TO HULL STRUCTURAL FAILURE (1)1.2ACTIONS TAKEN BY IACS (1)1.3AIMS OF THIS PUBLICATION (2)2.LOADS AND HULL STRUCTURE (3)2.1TYPICAL BULK CARRIER STRUCTURAL CONFIGURATION (3)2.2DESIGN LIMITATIONS (6)2.2.1General (6)2.2.2Hull Girder Shear Forces and Bending Moments (6)2.2.3Local Strength of Transverse Bulkhead, Double Bottom andCross Deck Structure (9)2.3CARGO DISTRIBUTIONS ALONG SHIP'S LENGTH (13)2.3.1General (13)2.3.2Homogeneous Hold Loading Conditions (Fully loaded) (13)2.3.3Alternate Hold Loading Conditions (Fully loaded) (13)2.3.4Block Hold Loading and Part Loaded Conditions (14)3.ONBOARD LOADING GUIDANCE INFORMATION (16)3.1LOADING MANUAL (16)3.2LOADING INSTRUMENT (16)4.PLANNING AND CONTROL OF CARGO LOADING AND UNLOADINGOPERATIONS (18)4.1PREPARATION FOR CARGO OPERATIONS (18)4.1.1Cargo and Port Information (18)4.1.2Devising a Cargo Stowage Plan and Loading/Unloading Plan (18)4.1.3Ship/Shore Communication Prior to the Commencement of CargoOperations (20)4.1.4Before Commencing Cargo Operations (21)4.2MONITORING AND CONTROLLING CARGO OPERATIONS (21)4.2.1Monitoring of Stevedoring Operation (21)4.2.2Monitoring the Ship's Loaded Condition (22)4.2.3Hull Damage Caused by Cargo Operations (22)5.POTENTIAL PROBLEMS (23)5.1DEVIATION FROM THE LIMITATIONS GIVEN IN THE APPROVEDLOADING MANUAL (23)5.2LOADING CARGO IN A SHALLOW DRAUGHT CONDITION (23)5.3HIGH LOADING RATES (23)5.4ASYMMETRIC CARGO AND BALLAST DISTRIBUTION (24)5.5LACK OF EFFECTIVE SHIP/SHORE COMMUNICATION (28)5.6EXCEEDING THE ASSIGNED LOAD LINE MARKS (29)5.7PARTIALLY FILLED BALLAST HOLDS OR TANKS (29)5.8INADEQUATE CARGO WEIGHT MEASUREMENT DURING LOADING (29)5.9STRUCTURAL DAMAGE (30)6.BALLAST EXCHANGE AT SEA (32)1.INTRODUCTION1.1 FACTORS CONTRIBUTING TO HULL STRUCTURAL FAILUREAs a result of concern regarding the high casualty rate of single side skin dry bulk carriers and the associated loss of life and cargo in the early 90s, where structural failure may have been a contributory factor, the International Association of Classification Societies (IACS) carried out comprehensive investigations in order to identify the likely causes of these ship casualties and introduced measures to minimise their recurrence.The evidence available indicates that a majority of the ships lost were over 15 years of age and were predominantly carrying iron ore at the time of loss. The investigations identified that the principal factors contributing to the loss of these ships were corrosion and cracking of the structure within the cargo spaces. Other factors which could have contributed to the hull structural failure were over-stressing of the hull structure due to incorrect loading of the cargo holds and physical damage to the side structure during cargo discharging operations.1.2 ACTIONS TAKEN BY IACSTo minimise the possibility of further casualties occurring on dry bulk carriers, a number of actions have already been implemented by the IACS Member Societies and ongoing work is being carried out which will bring further enhancements to the safety of these ships. The following list of actions have been implemented by IACS Member Societies. The results of the ongoing work will be made available to all interested parties in due course.1991The introduction of corrosion protection coating requirements for all salt water ballast spaces for new ships.1992Publication of the IACS brochure, 'Bulk Carriers: Guidance and Information to Shipowners and Operators', with the intention of advising the shipping community with regard to the potential problems of this ship type.1993The introduction of minimum thickness requirements for the webs of side shell frames in cargo areas for new ships.The introduction of corrosion protection coating requirements for side shell structure and transverse bulkheads in all cargo hold spaces for new ships.The introduction of more rigorous survey requirements. The implementation of the Enhanced Survey Programme (ESP) for bulk carriers by all IACS Member Societies at the first annual, intermediate or special survey from July 1993.1994Publication of the IACS Manual, 'Bulk Carriers: Guidelines for Surveys, Assessment and Repair of Hull Structures', providing guidance to surveyors of IACS Member Societies and other interested parties involved in the survey, assessment and repair of hull structures for bulk carriers.1995An implementation date of not later than 1st July 1997 has been agreed upon for the requirement that all existing bulk carriers of 150 metres in length and greater are to be fitted with an approved loading instrument.1996The introduction, as of January 1997, of an accelerated Enhanced Survey Program of the cargo holds of existing single skin bulk carriers which are 10 years of age or older, of 150 metres length or greater, and which have not commenced an enhanced special survey.Improvements in the Enhanced Survey Program for all existing bulk carriers of 10 years of age or older which will further enhance close-up surveys and thickness measurements at annual, intermediate and special surveys.A review of the requirements for loading instruments.1.3 AIMS OF THIS PUBLICATIONIACS Member Societies and other parties involved in bulk cargo shipping are concerned with the possible damage and loss of bulk carriers carrying heavy cargoes. Of particular concern are the potential problems which may result during operations such as the introduction of very high capacity loading systems, lack of communication between ship and terminal and inadequate planning of cargo operations. It is also of concern to IACS Members that some seafarers, and ship and cargo operators do not have a clear understanding of the limitations imposed by the ship's classification society regarding the strength capability of the hull structure.IACS considers that a positive step must now be taken to provide adequate guidance and information to all parties involved in the loading and unloading of dry bulk carriers so that there is an awareness and better understanding of the possible problems that may be encountered. To serve this purpose, it is the intention of IACS to make this publication available to all shipowners, ship masters, ship and cargo terminal operators and other interested parties worldwide.2.LOADS AND HULL STRUCTURE 2.1 TYPICAL BULK CARRIER STRUCTURAL CONFIGURATIONThe most widely recognised structural arrangement identified with bulk carriers is a single deck ship with a double bottom, hopper tanks, single skin transverse framed side shell, topside tanks and deck hatchways. For guidance on the structural terminology adopted in this publication, a typical structural arrangement of a bulk carrier cargo hold space is illustrated in Figure 1. In addition, a typical transverse section in way of a cargo hold and a longitudinal section of a typical corrugated transverse watertight bulkhead are illustrated in Figures 2 and 3 respectively.Bulk carrier design does not alter significantly with size; fundamentally, a bulk carrier of 30 000 tonnes deadweight usually has the same structural configuration as that of a ship of 80 000 tonnes deadweight.Figure 1Typical Cargo Hold Structural Configuration for a Single Side Skin Bulk Carrier 4177/01HoppertankSide shellframesTopsidetanktransversebulkheadDouble bottom tankCross deck stripEnd bracketsCorrugatedIn general, the plating comprising structural items such as the side shell, bottom shell, strength deck,transverse bulkheads, inner bottom and topside and hopper tank sloping plating provides local boundaries of the structure and carries static and dynamic pressure loads exerted by, for example,the cargo, bunkers, ballast and the sea. This plating is supported by secondary stiffening members such as frames or longitudinals. These secondary members transfer the loads to primary structural members such as the double bottom floors and girders or the transverse web frames in topside and hopper tanks, etc. see figure 2.Strength Deck plating HatchcoamingTopside tanklongitudinal plating(vertical strake)Topside tankSide shelllongitudinalSide shellplating Side shelllongitudinalHopper transverse ring web Hoppertank Bilge platingBottom longitudinal Bottom shellplating Double bottomfloor Keel plate Double bottom tank Double bottomgirderInnerbottom plating Innerbottomlongitudinal Hopper tank sloping platingHopper tank sloping plating longitudinalCARGO HOLDSide shell frame Topside tank sloping plating Topside tank transverse ring web Topside tank slopingplating longitudinalStrength Deck longitudinal 4177/02Ductkeel C L Figure 2Nomenclature for Typical Transverse Section in way of a Cargo HoldThe transverse bulkhead structures, including its upper and lower stools, see figure 3, together with the cross deck and the double bottom structures are the main structural members which provide the transverse strength of the ship to prevent the hull section from distorting. In addition, if ingress of water into any one hold has occurred, the transverse watertight bulkheads prevent progressive flooding of other holds.4177/03Cross deck structureCross deck structuretransverse beam Cross deck structurecantilever supportbracket Upper stoolUpper shelf plateCorrugated transverse bulkheadLower shelfplateLower stoolInner bottom plateCargo hatchwayend coamingCargo hatchwayend transverse beamFigure 3Nomenclature for Typical Corrugated Transverse Watertight BulkheadShedder plate2.2DESIGN LIMITATIONS2.2.1GeneralAll ships are designed with limitations imposed upon their operability to ensure that the structural integrity is maintained. Therefore, exceeding these limitations may result in over-stressing of the ship's structure which may lead to catastrophic failure. The ship's approved loading manual provides a description of the operational loading conditions upon which the design of the hull structure has been based. The loading instrument provides a means to readily calculate the still water shear forces and bending moments, in any load or ballast condition, and assess these values against the design limits.A ship's structure is designed to withstand the static and dynamic loads likely to be experienced by the ship throughout its service life.The loads acting on the hull structure when a ship is floating in still (calm) water are static loads. These loads are imposed by the:• Actual weight of the ship's structure, outfitting, equipment and machinery.• Cargo load (weight).• Bunker and other consumable loads (weight).• Ballast load (weight).• Hydrostatic pressure (sea water pressure acting on the hull).Dynamic loads are those additional loads exerted on the ship's hull structure through the action of the waves and the effects of the resultant ship motions (i.e. acceleration forces, slamming and sloshing loads). Sloshing loads may be induced on the ship's internal structure through the movement of the fluids in tanks/holds whilst slamming of the bottom shell structure forward may occur due to emergence of the fore end of the ship from the sea in heavy weather.Cargo over-loading in individual hold spaces will increase the static stress levels in the ship's structure and reduce the strength capability of the structure to sustain the dynamic loads exerted in adverse sea conditions.2.2.2Hull Girder Shear Forces and Bending MomentsAll bulk carriers classed with IACS Member Societies are assigned permissible still water shear forces (SWSF) and still water bending moment (SWBM) limits. There are normally two sets of permissible SWSF and SWBM limits assigned to each ship, namely:• Seagoing (at sea) SWSF and SWBM limits.• Harbour (in port) SWSF and SWBM limits.The seagoing SWSF and SWBM limits are not to be exceeded when the ship puts to sea or during any part of a seagoing voyage. In harbour, where the ship is in sheltered water and is subjected to reduced dynamic loads, the hull girder is permitted to carry a higher level of stress imposed by the static loads. The harbour SWSF and SWBM limits are not to be exceeded during any stage of harbour cargo operations.When a ship is floating in still water, the ship's lightweight (the weight of the ship's structure and its machinery) and deadweight (all other weights, such as the weight of the bunkers, ballast, provisions and cargo) are supported by the global buoyancy upthrust acting on the exterior of the hull. Along the ship's length there will be local differences in the vertical forces of buoyancy and the ship's weight. These unbalanced net vertical forces acting along the length of the ship will cause the hull girder to shear and to bend, see figures 4, 5 and 6, inducing a vertical still water shear force (SWSF) and still water bending moment (SWBM) at each section of the hull.Figure 4Shearing Action of the Hull Girder in Still WaterFigure 5Bending Action of the Hull Girder "Sagging" in Still Water(Exaggerated Condition - Illustration Purposes Only)Figure 6Bending Action of the Hull Girder "Hogging" in Still Water(Exaggerated Condition - Illustration Purposes Only)At sea, the ship is subjected to cyclical shearing and bending actions induced by continuously changing wave pressures acting on the hull. These cyclical shearing and bending actions give rise to an additional component of dynamic, wave induced, shear force and bending moment in the hull girder. At any one time, the hull girder is subjected to a combination of still water and wave induced shear forces and bending moments.The stresses in the hull section caused by these shearing forces and bending moments are carried by continuous longitudinal structural members. These structural members are the strength deck, side shell and bottom shell plating and longitudinals, inner bottom plating and longitudinals, double bottom girders and topside and hopper tank sloping plating and longitudinals, which are generally defined as the hull girder.Examples of permissible and calculated SWSF and SWBM are shown in figures 7 and 8respectively.Figure 7Relationship of the Permissible SWSF and the Calculated SWSFPermissibleHarbour SWSF PermissibleSeagoing SWSF Calculated SWSF NearPermissible Seagoing SWSFCalculatedSWSFBaselineFigure 8Relationship of the Permissible SWBM and the Calculated SWBM Permissible HarbourSWBM (Hog)Permissible HarbourSWBM (Sag)Calculated SWBM BaselinePermissible Seagoing SWBM (Hog)Permissible Seagoing SWBM (Sag)Calculated SWBM NearPermissible Seagoing SWBM2.2.3Local Strength of Transverse Bulkhead, Double Bottom and Cross Deck Structure To enhance safety and flexibility, some bulk carriers are provided with local loading criteria which define the maximum allowable cargo weight in each cargo hold, and each pair of adjacent cargo holds (i.e. block hold loading condition), for various ship draught conditions. The local loading criteria is normally provided in tabular and diagrammatic form.Over-loading will induce greater stresses in the double bottom, transverse bulkheads,hatch coamings, hatch corners, main frames and associated brackets of individual cargo holds, see figure 9.The double bottom, cross deck and transverse bulkhead structures are designed for specific cargo loads and sailing draught conditions. These structural configurations are sensitive to the net vertical load acting on the ship's double bottom. The net vertical load is the difference between the vertical downward weight of the cargo and water ballast in the double bottom and the hopper ballast tanks in way of the cargo hold and the upward buoyancy force which is dependent on the ship's draught.Figure 9Exaggerated Deformation of the Localised Structure due to Overloading of the Cargo HoldLoad ConditionIncreased stress in cross deck stripGreater distortion of topside tank Increased stressat hatch cornersand coamings Increased stressin main framesand brackets Increased stress in double bottom structure Increased stress in transverse bulkheadOverloading of the cargo hold in association with insufficient draught will result in an excessive net vertical load on the double bottom which may distort the overall structural configuration in way of the hold, see figures 10 and 11.Figure 10Shearing of the Transverse Corrugated Bulkhead and Compression of the Cross DeckBuoyancy Force Cargo Weight Shear Stress in Transverse Corrugated BulkheadFigure 11Excessive Flexural Deformation of the Double Bottom StructureCargo WeightBuoyancy ForceA typical Local Loading Diagram for a cargo hold (strengthened hold) combined with the adjacent hold limits, of a bulk carrier, are shown in figure 12.Figure 12An Example of a Local Loading Diagram for a Bulk Carrier Not AllowableC ar g o i n 1 H o l d AllowableMean DraughtC a r g o L o a d Seagoing LimitHarbour LimitC a r g o i n 2 A d j a c e n t H o l d s C a rg o i n 1 H o l dC a rg o i n 2 A d j a c e n t H o l d sThe important trend to note from the local loading diagram is that there is a reduction in the cargo carrying capacity of a hold with a reduction in the mean draught. To exceed these limits will impose high stresses in the ship's structure in way of the over-loaded cargo hold. There are two sets of local loading criteria depending upon the cargo load distribution namely, individual hold loading or two adjacent hold loading.The allowable cargo loads for each hold or combined cargo loads in two adjacent holds are usually provided in association with empty double bottom and hopper wing ballast tanks directly in way of the cargo hold. When water ballast is carried in the double bottom and hopper wing tanks, the maximum allowable cargo weight should be obtained by deducting the weight of water ballast being carried in the tanks in way of the cargo hold.The maximum cargo loads given in the Local Loading Criteria should be considered in association with the mean draught in way of the cargo hold(s). In the case of a single cargo hold, the ship draught at the mid-length of the hold should be used. For two adjacent cargo holds, the average of the draught in the mid-length of each cargo hold should be used.2.3CARGO DISTRIBUTIONS ALONG SHIP'S LENGTH2.3.1GeneralBulk carriers are designed and approved to carry a variety of cargoes. The distribution of cargo along the ship's length has a direct influence on both the global bending and shearing of the hull girder and on the stress in the localised hull structure.The more commonly adopted cargo distributions are:• Homogeneous hold loading condition.• Alternate hold loading condition.• Block hold loading condition.• Part hold loading condition.2.3.2Homogeneous Hold Loading Conditions (Fully Loaded)A homogeneous hold loading condition refers to the carriage of cargo, evenly distributed in all cargo holds, see figure 13. This loaded distribution, in general, is permitted for all bulk carriers and is usually adopted for the carriage of light (low density) cargoes, such as coal and grain. However, heavy (high density) cargoes such as iron ore may be carried homogeneously.Figure 13Homogeneous Hold Loading Condition (Fully Loaded)2.3.3Alternate Hold Loading Conditions (Fully Loaded)Heavy cargo, such as iron ore, is often carried in alternate cargo holds on bulk carriers, see figure 14. It is common for large bulk carriers to stow high density cargo in odd numbered holds with the remaining holds empty. This type of cargo distribution will raise the ship's centre of gravity, which eases the ship's rolling motion. When high density cargo is stowed in alternate holds, the weight of cargo carried in each hold is approximately double that carried in a homogeneous load distribution. To support the loading of the heavy cargo in the holds, the local structure needs to be specially designed and reinforced. It is important to note that the holds which remain empty, with this typeof cargo distribution, have not been reinforced for the carriage of heavy cargoes with a non-homogeneous distribution.Ships not approved for the carriage of heavy cargoes in alternate holds by their classification society must not adopt this cargo load distribution.Figure 14Alternate Hold Loading Condition (Fully Loaded)2.3.4Block Hold Loading and Part Loaded ConditionsA block hold loading condition refers to the stowage of cargo in a block of two or more adjoining cargo holds with the cargo holds adjacent to the block of loaded cargo holds empty, see figure 15. In many cases, block hold loading is adopted when the ship is partly loaded. Part loaded and block hold loading conditions are not usually described in the ship's loading manual unless they are specially requested to be considered in the design of the ship. When adopting a part loaded condition, to avoid over-stressing of the hull structure, careful consideration needs to be given to the amount of cargo carried in each cargo hold and the anticipated sailing draught.Figure 15Block Hold Loading ConditionWhen a ship is partly loaded, the cargo transported is less than the full cargo carrying capacity of the ship. Hence, the sailing draught of the ship is likely to be less than its maximum design draught. The weight of cargo in each hold must be adequately supported by the buoyancy upthrust acting on the bottom shell. A reduction in the ship’s draught causes a reduction in the buoyancy upthrust on the bottom shell to counteract the downward force exerted by the cargo in the hold. Therefore, when a ship is partly loaded with a reduced draught, it may be necessary to reduce the amount of cargo carried in any hold.To enable cargoes to be carried in blocks, the cross deck and double bottom structure needs to be specially designed and reinforced. Block loading results in higher stresses in the localised structure in way of the cross deck and double bottom structures and higher shear stress in the transverse bulkheads between the block loaded holds. The weight of cargo that can be carried in the block of cargo holds needs to be specially considered against the ship's sailing draught and the capability of the structure. In general, the cargo load that can be carried in blocks is much less than the sum of the full cargo capacity of the individual holds at the maximum draught condition.Part loaded and block hold loading conditions should only be adopted in either of the following situations:• The loading distributions are described in the ship's loading manual. In this case, the ship's structure has been approved for the carriage of cargo in the specified loading condition and the loading conditions described in the ship's loading manual should be adhered to, or,• The ship is provided with a set of approved local loading criteria which define the maximum cargo weight limit as a function of ship's mean draught for each cargo hold and block of cargo hold(s). In this case, it is necessary to ensure that the amount of cargo carried in each hold satisfies the cargo weight and draught limits specified by the local loading criteria and the hull girder SWSF and SWBM values are within their permissible limits.3.ONBOARD LOADING GUIDANCE INFORMATION3.1LOADING MANUALIt is a statutory requirement of the International Load Line Convention that, noting exemptions, "the Master of every new vessel be supplied with sufficient information, in an approved form, to enable him to arrange for the loading and ballasting of his ship in such a way as to avoid the creation of any unacceptable stresses in the ship's structure."Where the Master feels that he has insufficient information regarding the structural limitations or requires advice on the interpretation of the classification society's structural limitations imposed on his ship, advice should be sought from the ship's classification society.The ship's approved loading manual is an essential onboard documentation for the planning of cargo stowage, loading and discharging operations. This manual describes:• The loading conditions on which the design of the ship has been based, including permissible limits of still water shear force and bending moments.• The results of calculations of SWSF and SWBM for each included loading condition.• The allowable local loading of the structure.• Operational limits.The ship's loading manual is a ship specific document, the data contained therein is only applicable to the ship for which it has been approved.3.2LOADING INSTRUMENTThe loading instrument is an invaluable shipboard calculation tool which assists the ship's cargo officer in:• Planning and controlling cargo and ballasting operations.• Rapidly calculating SWSF and SWBM for any load condition.• Identifying the imposed structural limits which are not to be exceeded.It is important to note that the loading instrument is not a substitute for the ship's loading manual. Therefore, the officer in charge should also refer to the loading manual when planning or controlling cargo operations.。

化学专业英语复习资料

化学专业英语复习资料

Naming Inorganic CompoundsIntroduction:1.10 million known chemical substances.Need to establish a set of rules leading to informative, systematic name for each substance.2.Nomenclature: basic rules for naming simple compounds (organic compounds,inorganic compounds)Contents of current section:1.Preparatory materials(names of common elements in the periodic table);2.Ionic compounds (cations, anions,compounds);3.Acids;4.Molecular compounds Common Elements:Ac-Actinium锕, Ag-Silver, Al-Aluminum, Ar-Argon, As-Arsenic, Au-Gold, B-Boron, Ba-Barium, Be-Beryllium, Bi-Bismuth, Br-Bromine, C-Carbon, Ca-Calcium, Cd-Cadmium, Ce-Cerium铈, Cl-Chlorine, Co-Cobalt, Cr-Chromium, Cs-Cesium铯, Cu-Copper, F-Fluorine, Fe-Iron,Ga-Gallium镓, Ge-Germanium锗, H-Hydrogen, He-Helium, Hg-Mercury, I-Iodine, In-Indium, Ir-Iridium铱, K-Potassium, Kr-Krypton, La-Lanthanum镧, Li-Lithium, Mg-Magnesium, Mn-Manganese, Mo-Molybdenum钼, N-Nitrogen, Na-Sodium, Nb-Niobium铌, Nd-Neodymium钕, Ne-Neon, Ni-Nickel, O-Oxygen, Os-Osmium锇, P-Phosphorus, Pb- Lead, Pd-Palladium钯, Po-Polonium钋,Pt-Platinum, Pu-Plutonium钚, Ra-Radium, Rb-Rubidium铷, Re-Rhenium铼, Rn-Radon氡, Ru-Ruthenium钌, S-Sulfur, Sb-Antimony锑, Sc-Scandium钪, Se-Selenium硒, Si-Silicon, Sm-Samarium钐, Sn-Tin,Sr-Strontium锶, Ta-Tantalum钽, Te-Tellurium, Ti-Titanium, Tl-Thallium, U-Uranium, V-Vanadium钒,W-Tungsten, Xe-Xenon, Y-Yttrium钇, Zn-Zinc, Zr-Zirconium锆Ionic compoundsGeneral rule :The names of ionic compounds are based on the names of the ions of which they are composed. The positive ion (cation) is always named first and listed first in writing the formula for the compound. The negative ion (anion) is named and written last.Eg.:NaCl (sodium chloride)Naming cationsMonatomic ions (take the name of the element itself)Zn2+ (zinc ion), Al3+ (aluminum ion)Note: for an element (especially transition metals) with more than 1 positive ion, the positive charge of the ion is indicated by a Roman numeral in parentheses following the name of the metal: Fe2+ --- iron (II) ion, Cu+ ---copper (I) ionIf unsure, use the Roman numeral designation of charges as part of the name.Naming cationsNote: A widely used older method to distinguish between two differently charged ions of a metal is to apply the ending –ous for the lower charged ions or -ic for the higher charged ions, respectively. They are added to the root of the Latin name of the element.Eg.:Fe2+ (ferrous ion), Cu+ (cuprous ion)Fe3+ (ferric ions), Cu2+ (cupric ion)Naming cationsPolyatomic cations: Groups of atoms with a positive charge.NH4+ --- ammonium ion Hg22+ ---mercury (I) ion or mercurous ionNote: Hg2+ ---mercury (II) ion, or mercuric ionCommon ions:Cations: ammonium, cesium, copper(I) or cuprous, hydrogen, lithium, potassium, silver,sodium.(+1 ions); barium, cadmium, calcium, cobalt(II) or cobaltous, copper(II) or cupric,iron(II) or ferrous, lead(II) or plumbous,magnesium, manganese(II) ormanganous,mercury(I) or mercurous, mercury(II) or mercuric, nickel, strontium, tin(II) or stannous, zinc.(2+ ions); aluminum, chromium(III) or chromic, iron(III) or ferric.(3+ ions) Naming anionsMonatomic anions (named by dropping the ending of the name of the element and adding the ending -ide ):Naming anionsPolyatomic anionsNote: only a few polyatomic anions end in -ide:OH- hydroxide ion, CN- cyanide ion O22- peroxide ion, N3- azide ionNaming anionsOxyanions (polyatomic and oxygen-containing):when an element forms two oxyanions, the name of the one containing more oxygen ends in-ate; the name of the one with less oxygen ends in -ite: Eg.:NO2- nitrite ion, SO32- sulfite ion ,NO3- nitrate ion, SO42- sulfate ionNaming anionsNote: when the series of anions of a given element extends to three or four members,prefixes are also employed. The prefix hypo-indicates less oxygen, and per- more oxygen:Eg: ClO- hypochlorite ion, ClO2- chlorite ion ClO3- chlorate ion, ClO4- perchlorate ion chlor---root of chlorineNaming anionsPractice: selenate ion (?); selenite ion (?) perbromate (?) , hypobromite (?)Note: exceptions to rules: permanganate ion is MnO4-, manganate ion is MnO42-. ferrate-(or perferrate) FeO4-,chromate CrO42-, dichromate Cr2O72-Naming anionsPolyatomic anions with hydrogen ionsThese ions are named by prefixing the word hydrogen or dihydrogen, as appropriate,to the name of the hydrogen-free anion.Alternative way is to use the prefix bi-:Eg.:HCO3- hydrogen carbonate (or bicarbonate ) ion; HSO4- hydrogen sulfate ( or bisulfate) ion; H2PO4- dihydrogen phosphate ionCommon ionsAnions: acetate, azide, bromide, chlorate,chloride, cyanide, dihydrogen phosphate,fluoride, hydride, hydrogen carbonate or bicarbonate, hydrogen sulfate or bisulfate, hydroxide, iodide, nitrate, nitrite, perchlorate, permanganate, thiocyanate, cyanate. (1- ions);carbonate, chromate, dichromate, ferrate,hydrogen phosphate, oxide, peroxide, sulfate,sulfide, sulfite, thiosulfate.(2- ions); nitride,phosphate, phosphide. (3- ions).Naming ionic compoundsWrite the formulas for ionic compounds by combining the names of cations and anions:barium bromide- BaBr2copper(II) nitrate or cupric nitrate- Cu(NO3)2aluminum oxide-Al2O3mercury(I) chloride or mercurous chlorideHg2Cl2ferric oxide, Fe2O3Practice : Name the following compounds:(a)K2SO4;(b) Ba(OH)2;(c) FeCl3 (d) NH4Cl;(e) Cr2O3;(f)Co(NO3)2Write the chemical formulas for the following compounds:(a)calcium carbonate; (b)sodium fluoride; (c) iron(II) perchlorate; (d)magnesium sulfate; (e) silver sulfide; (f) lead nitrate.Naming AcidsAn acid here is defined as a substance whose molecules yield hydrogen ions (H+) when dissolved in water.Rule : The name of an non-oxyacid is related to the name of the anion. Anions with the ending -ide associate with acids having hydro- prefix and an -ic ending:Eg:Chloride (Cl-) to hydrochloric acid (HCl) sulfide (S2- ) to hydrosulfuric acid (H2S)Note: only water solution of HCl is called hydrochloric acid, the pure compound is called hydrogen chloride.Naming the acidsFor acids derived from oxyanions (oxyacids)Rule: If the anion has an –ate (-ite) ending,the corresponding acid is given an –ic (-ous) ending. Prefixes are retained:Naming the acidsExercisesName the following acids:(a) HCN, HSCN; (b) HNO3, HNO2 (c) H2SO4 (d) H2SO3Give the chemical formulas for(a)hydrobromic acid; (b) phosphoric acid.Naming molecular compoundsRule:The procedures for naming binary (two-element) molecular compounds are similar to those for naming ionic compounds. The element with the positive nature is named first and also appears first in the chemical formula. The second element is named with an–ide ending.Eg.:HCl hydrogen chlorideNaming molecular compoundsPrefixes are used in differentiating several binary compounds formed between nonmetals.Eg:CO -carbon monoxide CO2-carbon dioxideMeaning of the Greek prefixes:mono- (1); di- (2); tri-(3); tetra-(4); penta-(5);hexa-(6); hepta-(7); octa-(8); nona-(9); deca-(10)Naming molecular compoundsNote: when the prefix ends in a or o and the name of the anion begins with a vowel (such as oxide), the a or o is often dropped. The prefix mono- is usually omitted for the first-named element.Eg.:Cl2O - dichlorine monoxide; NF3- nitrogen trifluoride; N2O4- dinitrogen tetroxide; P4S10- tetraphosphorus decasulfide;ExercisesName the following compounds:(a) SO2; (b)PCl5; (c)N2O3Give the chemical formula for(a) silicon tetrabromide (b) disulfur dichlorideExercises for ReviewSodium fluoride, magnesium bromide,hydrogen iodide, sodium azide , calcium phosphide,copper(I) chloride, potassium azide,manganese (IV) oxideK2SO3, Ca(MnO4)2 , Ba3(PO4)2, H3PO4 ,H2SO4 ,HNO3 , ZnO , BaO2 ,FeO ,CuSO4•5H2O , Mn3(PO4)2Metaphosphoric acid, phosphoric acid,hypophosphorous acid, phosphorous acid,(hypo)phosphite, (meta)phosphateammonium acetate, perbromic acid , potassium nitrite, sodium peroxide , ammonium dichromate ,sodium carbonate , silver nitrate , aluminum acetate, hydrosulfuric acid, sulfurous acid, perferric acid, perferrate ion, hypoiodite ion,iodic acid , chlorous acid, hydrochloric acidB2O3, SiO2, PCl3,SiCl4, BrF3, IBr,N2S5, PCl3, SiS, S4N2Exercise: learning for useWhen ammonium thiocyanate and barium hydroxide octahydrate are mixed at room temperature,an endothermic reaction occurs.(write the chemical equation). As a result of this reaction, the temperature of the system drops from about 20°C to -9 °C.The reaction of powdered aluminum with ferric oxide (known as the thermite reaction) is highly exothermic. Once started, the reaction proceeds vigorously to form aluminum oxide and molten iron. (write the chemical equation)Nomenclature for Organic Compounds and GroupsWhy Do We Need a Separate Set of Rules?Examine some typical organic compounds (Name these using typical covalent rules)CH4:Carbon tetrahydride C2H6:Dicarbon hexahydrideThat wasn’t so bad, right?How about these:C4H10:Tetracarbon decahydride C5H12:Pentacarbon hydrideSee my point?Memorizing too many prefixes for large numbersIsomers:If that’s not enough, how about this one:Rules•Identify the longest unbranched chain of carbons•Name it as normal•Identify the branch•Name it but give it a “–yl”suffix•Put the names of all branches first, then put name of longest chain•Put the number of the carbon the branch is on (start numbering from the closest single end) Nomenclature for saturated hydrocarbonsa.Alkanes(CnH2n+2烷烃)---+ anefor n<=4:methane (甲烷), ethane(乙烷),propane (丙烷), butane (丁烷).Alkanefor n>4 , for normal alkanesA Greek prefix + ane suffix (if “-aa-”, drop one “a”)5 pent(a)-,6 hex(a)-,7 hept(a)-,8 oct(a)-,9 non(a)-,10 dec(a)-, 11 undec(a)-, 12 dodec(a)-, 13 tridec(a)-,14 tetradec(a)-, 15 pentadec(a)- 16 hexadec(a)-,17 heptadec(a), 18 octadec(a)-, 19 nonadec(a)-,20 eicos(a)-, 22 docos(a)-, 24 tetracos(a)-, 30triacot(a)-, 36 hexatriacot(a)-Eg:nonadecane; C19H40 decanedithiol; HS-C10H22-SHAlkanesn >4 , alkanes’main chain with branchesThe position and name of branch groups are added as prefixes to the name of the longest hydrocarbon chain. Use Greek prefixes to indicate the number of repeated branch group.2-chloropentane, 2-methylbutane2,2,4-trimethylpentane (or isooctane)1-chloro-3,3-dimethylpentane2-methylpropane (or isobutane)Cyclo’alkanes, CnH2n (naming rule similar to the above-mentioned) + add cycloStart numbering from the most “important”branch in the ringSupplementsPrimary, secondary, tertiary, quaternary carbon atom.Normal hydrocarbon: n-hexane or s of some groups derived from alkanes by replacing “ane”with “yl”:Eg.:methyl, ethyl, n-propyl, isopropyl, n-butyl, n-pentyl, cyclopropyl, cyclobutyl, cyclohexylPracticeDraw the structural formula for each of the following compounds(1) 3-hexyne(2)1,3-pentadiene(3)cyclcobutene(4) 3, 4-diethylhexane(5) 1-butyneNomenclature of aromatic hydrocarbonsThe name of a single substituent is added to benzene as a prefix. Three structurally isomeric forms are designated ortho (o-), meta (m-), and para (p-).Eg:ethylbenzene, p-nitrobenzoic acid, hexachlorobenzene, toluene, m-xylene.group: phenyl-diphenylmethane.Nomenclature for polycyclic aromatic hydrocarbonsPolycyclic aromatic hydrocarbonsEg:Nomenclature for functional groupsHalo (-X), hydroxyl (-OH), amino (-NR3. primary: RNH2,secondary: R2NH, tertiary: R3N), formyl (-CHO),carbonyl (-CO-), carboxyl (-COOH), a’mido (-CONH2),carbonyl halide (-COX), an’hydride (-COOCOR),ester(-COOR), nitro(-NO2), nitroalkane (R-NO2),sulfonic acid (-SO3H), cyano (-CN)Functional groups with covalent single bondsAlkyl (烷基)and aryl (芳基)halides (RX)Eg:Methyl bromide (bromomethane),methyl iodide (iodomethane), ethyl bromide(bromoethane), propyl bromide (1-bromopropane),propylene dibromide (1,2-dibromopropane), vinyl chloride (chloroethene), chlorobenzene.Functional groups with covalent single bondscommercial name:methyl alcohol ( 甲醇) , ethyl alcohol (乙醇), propyl alcohol (1-propanol), ethylene glycol (乙二醇),glycerol (甘油), isopropyl alcohol (异丙醇)Functional groups with covalent single bondsNomenclature for functional group with double bondsEsters (RCOOR’)in the two-word name for an ester, the first word is the name of the R’group (methyl, ethyl, …), the second word is the name of the carboxylic acid with the final -c ic replaced by –ate (回忆无机盐命名)methyl formate (methanoate), methyl acetate (ethanoate), ethyl benzoateNomenclature for functional group with double bonds。

高分子材料与工程专业英语课文

高分子材料与工程专业英语课文

UNIT 12 Bulk PolymerizationBulk polymerization traditionally has been defined as the formation of polymer from pure, undiluted monomers. Incidental amounts of solvents and small amounts of catalysts, promoters, and chain-transfer agents may also be present according to the classical definition. This definition, however, serves little practical purpose. It includes a wide variety of polymers and polymerization schemes that have little in common, particularly from the viewpoint of reactor design. The modern gas-phase process for polyethylene satisfies the classical definition, yet is a far cry from the methyl methacrylate and styrene polymerization which remain single-phase throughout the polymerization and are more typically thought of as being bulk. ®A common feature of most bulk polymerization and other processes not traditionally classified as such is the need to process fluids of very high viscosity. The high viscosity results from the presence of, dissolved polymer in a continuous liquid phase. Signific ant concentrations of a high molecular-weight polymer typically increase fluid viscosities by 104 or more compared to the unreacted monomers. This suggests classifying a polymerization as bulk whenever a substantial concentration of polymer occurs in the continuous phase. Although this definition encompasses a wide variety of polymerization mechanisms, it leads to unifying concepts in reactor design. The design engineer must confront the polymer in its most intractable form, i. e. , as a high viscosity solution or polymer melt.The revised definition makes no sharp distinction between bulk and solution polymerizations and thus reflects industrial practice. Several so-called bulk processes for polystyrene and ABS® use 5%~15% solvent as a processing aid and chain-transfer agent. Few successful processes have used the very large amounts of solvent needed to avoid high viscosities in the continuous phase, although this approach is sometimes used for laboratory preparations.Bulk polymerizations often exhibit a second, discontinuous phase. They frequently exhibit high exothermicity, but this is more characteristic of the reaction mechanism than of bulk polymerization as such. Bulk polymerizations of the free-radical variety are most common, although several commercially important condensation processes satisfy the revised definition of a bulk polymerization.In all bulk polymerizations, highly viscous polymer solutions and melts are handled. This fact tends to govern the process design and to a lesser extent, the process economics. Suitably robust equipment has been developed for the various processing steps, including stirred-tank and tubular reactors, flash devolatilizers, extruder reactors, and extruder devolatilizers. Equipment costs are high based on working volume, but the volumetric efficiency of bulk polymerizations is also high. If a polymer can be made in bulk, manufacturing economics will most likely favor this approach. ®It is tempting to suggest that polymer processes will gradually evolve toward bulk.® Recently, the suspension process for impact polystyrene has been supplanted by the bulk process, and the emulsion process for ABS may similarly be replaced. However, the modern gas-phase process for polyethylene appears to represent an opposite trend. It seems that polymerization technology tends to eliminate solvents and suspending fluids other than the monomers themselves. When the monomer is a solvent for the polymer, bulk processes as described in this article are chosen. When the monomer is not a solvent, suspension and slurry processes like those for polyethylene and polypropylene are employed. Hence, it is worthwhile avoiding a highly viscouscontinuous phase, but not at the price of introducing extraneous material. ®Reading MaterialsPolymerization ViscostitiesViscosity in itself is a nebulous term when describing the polymer or polymer solution in most polymerizations. Some polymerizations are carried out in water with small beads being formed and suspended in the water. The "viscosity" of such a system could actually mean the viscos.ty of the water, the viscosity of the slurry present with the beads in the water, the impeller viscosity, the process viscosity, the bulk viscosity, or the viscosity at the heat transfer surface.In the bulk polymerization method, knowledge of viscosity is of vital importance. Bulk polymerizations typically operate between 100 000 and 500 000 cP (100 and 500Pa • s) bulk viscosity. An accurate determination of the bulk viscosity is extremely important in addition to the rheology associated with the particular polymer. Because bulk polymerizations are generally high viscosity in nature, the corresponding mixing Reynolds number® is very low, normally less than 100. This is in the laminar region. Power is proportional to N2D3u in the laminar range; so the actual horsepower which the mixer will draw is proportional to viscosity. Because of this, it is a requirement that viscosity vs. shear rate data be known. For example, assume two separate companies manufacturing bulk polystyrene have presented viscosity data to mixer vendors. Both companies have stated that the bulk viscosity of this material is 300 000 cP (300Pa • s). Company A furnished only this information to the mixer suppliers. Company B furnished the bulk viscosity information in addition to the viscosity vs. shear rate data. Because the mixer manufacturer could determine the proper viscosity to load the impeller from the information that customer B furnished, the mixer recommended was a 25-hp design (18. 5 kW). Company A received a quote for a 50-hp mixer (37kW). Both mixers were for tanks of the same size and shape and operating at the same speed. Naturally the quotation for customer A will be at a higher price and a higher operating cost than for customer B. However, both mixers will accomplish the required results.About 85% of all high-viscosity materials are pseudoplastic and viscoelastic in nature. Bulk polystyrene, polyesters, and polyelectrolytes are pseudoplastic in nature. Most materials have a slope of — 0. 2 to — 0. 6 when viscosity is plotted vs. shear rate. By reviewing these data and comparing the viscosity-vs. -shear rate information with the known shear rate constant of close-clearance impellers, the impeller viscosity can be determined. The shear rate constant for anchors and helical impellers is 30.As indicated earlier, helical impellers and anchors are typically used in bulk polymerizations. However, neither of these two devices can operate effectively without viscous drag at the wall of the vessel. Without some drag the material in the tank will turn as one entire mass, and almost no mixing will occur. Therefore, in bulk polymerizations it is important to be sure that inlet pipes of low-viscosity material and reflux lines are directed toward a point at the liquid level one-half of the distance from the mixer shaft to the tank wall. This will allow incorporation of the low-viscosity material and prevent its migration to the tank walls where it could act as a lubricating layer, thereby reducing the agitation. It is also important to optimize the temperature differential A T between the bulk fluid and the heat transfer surface. Normally bulk viscosity applications only require tank jackets to obtain temperature control. A very high jackettemperature could reduce the viscosity of the material at the tank wall to a point where it acts as a lubricating boundary layer. Too cold a temperature at the tank wall could increase the viscosity dramatically to a point where the mixer is not designed to handle it. In this case a totally stagnant boundary layer at the wall could occur and product quality could be affected. Further more, damage could result to the mixer, drive motor, and vessel.Viscosities for solution polymerizations are normally 25 000 and 500 000 cP (25 and 500 Pa • s) bulk viscosity. The same problems exist with the term viscosity in this type of polymerization as in bulk polymerizations. An exact knowledge of the bulk viscosity and viscosity at the impeller are important. In lower viscosity materials, where open impellers are used , the importance of the viscosity determination is slightly reduced because the mixing Reynolds numbers are normally in the transition region where horsepower is not proportional to viscosity. Therefore, a minor change in the viscosity will have little effect on the horsepower drawn by the mixer.Most solution polymerizations use tank jackets as heat transfer media; however, some solution polymerizations require additional surface area. Again, the A T optimization is important in solution polymerizations.UNIT 14 Styrene-Butadiene CopolymerThe synthetic rubber industry, based on the free-radical emulsion process, was created almost overnight during World War I . Styrene-butadiene (GR-S) rubber created at that time gives such good tire treads that natural rubber has never regained this market. ®The GR-S Standard recipe isThis mixture is heated with stirring and at 50°C gives conversions of 5% — 6% per hour. Polymerization is terminated at 70%~75% conversion by addition of a "short-stop", such as hydroquinone (approximately 0. 1 part), to quench radicals and prevent excessive branching and microgel formation. Unreacted butadiene is removed by flash distillation, and styrene by steam-stripping in a column. After addition of an antioxidant, such as iV-phenyl-β-naphthylamine (PBNA) (1.25 parts), the latex is coagulated by the addition of brine, followed by dilute sulfuric acid or aluminum sulfate. The coagulated crumb is washed, dried, and baled for shipment.This procedure is still the basis for emulsion polymerization today. An important improvement is continuous processing illustrated in Fig. 14.1; computer modeling has also been described.In the continuous process, styrene, butadiene, soap, initiator, and activator (an auxiliary initiating agent) are pumped continuously from storage tanks through a series of agitated reactors at such a rate that the desired degree of conversion is reached at the last reactor.® Shortstop is added, the latex warmed with steam, and the unreacted butadiene flashed off. Excess styrene is steam-stripped, and the latex finished as shown in Fig. 14.1.SBR prepared from the original GR-S recipe is often called hot rubber, cold rubber is made at 5'C by using a more active initiator system. Typical recipes are given in Table 14.1. At 5*C , 60% conversion to polymer occurs in 12~15h.Cold SBR tire treads are superior to those of hot SBR. Polymers with abnormally high molecular weight (and consequently too tough to process by ordinary factory equipment) can beprocessed after the addition of up to 50 parts of petroleum-base oils per hundred parts of rubber (phr) . These oil extenders make the rubbers more processible at lower cost and with little sacrifice in properties; they are usually emulsified and blended with the latex before coagulation.Recent trends have been toward products designed for specific uses. The color of SBR, which is important in many nontire uses, has been improved by the use of lighter-colored soaps, shortstops, antioxidants, and extending oils. For example, dithiocarbamates are substituted for hydroquinone as shortstop ; the latter is used on hot SBR where dark color is not objectionable. A shortstop such as sodium dimethyldithiocarbamate is more effective in terminating radicals and destroying peroxides at the lower temperatures employed for the cold rubbers.Free-radical dissociative initiators that function by dissociation of a molecule or ion into two radical species are normally limited to inorganic persulfates in the case of butadiene polymerization.The other important class of free-radical initiators, redox systems, contain two or more components that react to produce free radicals. Dodecyl mercaptan added to control molecular weight also appears to aid free-radical formation by reaction with persulfate. The commercial importance of such chain-transfer agents or modifiers cannot be overemphasized. ® Without molecular weight control the rubbers would be too tough to process.Reading MaterialsSteady-State Multilicity in Continuous Emulsion Polymerization The phenomenon of multiple steady states is seen in emulsion polymerization. Fig. 14. 2 is a plot of steady-state monomer conversion as a function of reactor residence time for methyl methacrylate emulsion polymerization in a CSTR. A region of multiplicity is indicated by the fact that the upper and lower branches of the curve overlap between residence times of 30 and 50 minutes. The dotted line is an estimate of the shape of the unstable middle branch which is experimentally unobservable. The dashed lines indicate experimental instances of ignition and extinction. At 50 minutes residence time the system has been observed to move from the lower steady state of 54% conversion to the upper steady state at approximately 80% with no discernible change in operating conditions (ignition). Extinction has been observed when the residence time is changed from 30 minutes to 20 minutes on the upper branch, resulting in a drop in conversion from the upper to the lower steady-state values. The phenomenon of multiple steady states arises in emulsion polymerization for much the same reason as it appears in solution polymerization: the autocatalytic nature of the polymerization (due to the gel effect), combined with the mass balance, results in the possibility of steady-state multiplicity.Steady-state multiplicity can be an operational problem for a number of reasons. If one wishes to operate at an intermediate level of monomer conversion (perhaps to minimize viscosity or prevent excessive chain branching), one may be forced to operate in the unstable region, relying on closed-loop control to stabilize the operating point. This is tricky at best. Additionally, the steady state (upper or lower) to which the system goes on start-up will depend on how the start-up is effected. A careful start-up policy may be needed to assure that the system arrives at the desired steady state. In general, a conservative start-up, with the temperature and initiator concentration brought to steady-state values slowly will result in operation on the lower branch, while aggressive start-up (high temperature and/or high initiator concentration during start-up) will result in steady-state operation on the upper branch. Finally, large upsets in the process may causeignition or extinction. This may lead to loss of temperature control in the case of ignition, or loss of reactor productivity in the case of extinction. A system designed to operate at the upper steady state will be operating way below design product yield at the lower steady state. Additionally, the product quality (MWD, CCD, etc. ) will be different for the two operating points. The polymerisation reactor designer should be aware of the potential for multiplicity, and, if possible, design the system to operate outside this region.CSTR polymerization reactors can also be subject to oscillatory behavior. A nonisothermal CSTR free radical solution polymerisation can exhibit damped oscillatory approach to a steady state, unstable (growing) oscillations upon disturbance, and stable (limit cycle) oscillations in which the system never reaches steady state,and never goes unstable, but continues to oscillate with a fixed period and amplitude. However, these Phenomena are more commonly observed in emulsion polymemation.High-volume products such as styrene-butadiene rubber (SBR) often are produced by continuous emulsion polymerization. This is most often done in a train of 5~15 CSTRs in series. Sustained oscillations (limit cycles) in conversion, particle number, and free emulsifier concentration gave been reported, under isothermal conditions in continuous emulsion polymerization systems. This limit cycle behavior leaves its mark on the product in the form of disturbances in the molecular weight distribution and particle size distribution which cannot be blended away. Fig. 14. 3 shows evidence of a sustained oscillation (limit cycle) during emulsion polymerization of methyl methacrylate in a single CSTR. Com parison of the monomer conversion and surface tension data graphically illustrates the mechanism of oscillation. It will be noted that the surface tension oscillates with the same period as the conversion (6—7 residence times). This can be explained with the classical micellar initiation mechanism (or with homogeneous nucleation) . Beginning at a time of about 300 minutes, the conversion rises rapidly as new particles form and old particles grow. As the particle surface area increases , additional surfactant is adsorbed on the particles. Meanwhile micelles dissociate to keep the aqueous phase saturated. Once all of the micelles have dissociated, it is no longer possible to maintain the aqueous phase at saturation, and the surface tension begins to rise. This is observed at about 320 minutes. At the point at which micelles are no longer present, micellar initiation stops and the rate of polymerization slows. Eventually, since particles are washing out while no new particles are being formed, the conversion begins to fall. Since the total particle surface area is decreasing at this point, and since surfactant is continually being introduced with the feed, the surface tension falls as the aqueous phase reapproaches saturation. As the aqueous phase becomes saturted initiation begins again. Saturation of aqueous phase may be observed by noting the point at which the surface tension reaches its CMC value. As new micelles are formed they adsorb free radicals, become polymer particles, and begin to grow and adsorb surfactant. The cycle then repeats.Modeling studies show that while the instability arises above the CMC (and is promoted by large values of initiator concentration and residence time, and low surfactant concentration), it is the on/off nature of the nucleation mechanism which governs the nature of oscillations in monomer conversion. The surface tension oscillation leads the conversion oscillation by approximately one residence time. This is consistent with the above explanation since changes in surfactant concentration are quite rapid while changes in the number of particles and rate of reaction require a finite growth time to appear as changes in the monomer conversion. Dampedoscillations at start-up have been noted for a large number of monomer systems.Damped oscillations will result in lost productivity since the product during these transients may be off quality. Unstable oscillations will, of course, preclude continued operation. Limit cycle oscillations, while not unstable, will result in a product having a quality (MWD, CCD, etc. ) which varies with time in a cyclic fashion. In most cases this is undesirable. As in the case of multiplicity, the polymerisation reactor designer must be aware of the potential for oscillatory phenomena, and should attempt to specify operating conditions at which these phenomena do not exist. In emulsion polymerizations • oscillations (both damped and sustained) are undesirable since the product is not of a consistent quality. and oscillations in free surfactant concentration may induce coagulation and reactor fouling. Several methods of eliminating oscillations in emulsion polymerization have been suggested. Poehlein has used a plug flow reactor upstream of a CSTR train. All polymer particles are nucleated in the PFR. Since PFR kinetics are essentially those of a batch reactor (and such oscillations do not occur in batch reactors), no oscillations occur. The CSTRs, then, are used to grow the existing particles. By segregating particle nucleation from particle growth, oscillations are eliminated. Another approach has been taken by Penlidis and others. This involves using a small CSTR as a seeder reactor. AH polymer particles are formed in the seeder. A portion of the monomer and water is bypassed around the seeder in such a way as to dilute out any remaining micelles in the reactor immediately following the seeder. Once again, nucleation and growth have been segregated, and oscillations are eliminated.UNIT 22 Mechanical Properties of PolymersThe mechanical properties of polymers are of interest in all applications where polymers are used as structural materials. Mechanical behavior involves the deformation of a material under the influence of applied forces.The most important and most characteristic mechanical properties are called moduli. A modulus is the ratio between the applied stress and the corresponding deformation. The re-ciprocals of the moduli are called compliances. The nature of the modulus depends on the na-ture of the deformation. The three most important elementary modes of deformation and the moduli (and compliances) derived from them are given in Table 22.1, where the definitions of the elastic parameters are also given. ® Other very important, but more complicated, de-formations are bending and torsion. From the bending or flexural deformation the tensile modulus can be derived. The torsion is determined by the rigidity.Cross-linked elastomers are a special case. Due to the cross-links this polymer class shows hardly any flow behavior. The kinetic theory of rubber elasticity was developed by Kuhn , Guth, James, Mark, Flory, Gee and Treloar. It leads, for Y oung's modulus at low strains, to the following equation sE=3RTp/Mcrl = 3zcrlRT/V=3C0The paragraphs above dealt with purely elastic deformations, i. e. deformations in which the strain was assumed to be a time-independent function of the stress. In reality, materials are never purely elastic: under certain circumstances they have nonelastic properties. This is especially true of polymers, which may show nonelastic deformation under circum-stances in which metals may be regarded as purely elastic. ® It is customary to use the ex-pression viscoelastic deformations that are not purely elastic. Literally the term viscoelastic means thecombinations of viscous and elastic properties. As the stress-strain relationship in viscous deformations is time-dependent, viscoelastic phenomena always involve the change of properties with time. Measurement of the response in deformation of a viscoelastic material to periodic forces, for instance during forced vjbration, shows that stress and strain are not in phase; the strain lags behind the stress by a phase angle 8, the loss angle. So the moduli of the materials, the complex moduli, include the storage moduli which determine the amount of recoverable energy stored as elastic energy, and the loss moduli which determine the dissipation of energy as heat when the material is deformed.UNIT 23 Thermal Properties of PolymerThe heat stability is closely related to the transition and decomposition temperature, i. e. to intrinsic properties. By heat stability is exclusively understood the stability (or re-tention) of properties (weight, strength, insulating capacity, etc. ) under the influence of heat. The melting point or the decomposition temperature invariably form the upper limit; the "use temperature" may be appreciably lower.The way in which a polymer degrades under the influence of thermal energy in an inert atmosphere is determined, on the one hand, by the chemical structure of the polymer itself, on the other hand, by the presence of traces of unstable structures.Thermal degradation does not occur until the temperature is so high that primary chemi-cal bonds are separated. For many polymers thermal degradation is characterized by the breaking of the weakest bond and is consequently determined by a bond dissociation energy. Since the change in entropy is of the same order of magnitude in almost all dissociation reac-tions, it may be assumed that also the activation entropy will be approximately the same. This means that, in principle, the bond dissociation energy determines the phenomenon. So it may be expected that the temperature at which the same degree of conversion is reached will be virtually proportional to this bond dissociation energy. ®The process of thermal decomposition or pyrolysis is characterized by a number of ex-perimental indices, such as the temperature of initial decomposition, the temperature of half decomposition, the temperature of the maximum rate of decomposition, and the average en-ergy of activation. The heat resistance of a polymer may be characterized by its "initial" and "half" decomposition.There are two types of thermal decomposition: chain depolymerization and random de-composition. The former is the successive release of monomer units from a chain end or at a weak link, which is essentially the reverse of chain polymerization; ® it is often called deprop-agation or unzippering. This depolymerization begins at the ceiling temperature. Random degradation occurs by chain rupture at random points along the chain, giving a disperse mix-ture of fragments which are usually large compared with the monomer unit. The two types of thermal degradation may occur separately or in combination; the latter case is rather nor-mal. Chain depolymerization is often the dominant degradation process in vinyl polymers, whereas the degradation of condensation polymers is mainly due to random chain rupture.The overall mechanism of thermal decomposition of polymers has been studied by Wolfs et al. The basic mechanism of pyrolysis is sketched in Fig. 23.1.In the first stage of pyrolysis (<550°C) a disproportionation takes place. Part of thede-composing materials is enriched in hydrogen and evaporated as tor and primary gas, the rest forming the primary char. In the second phase (>550°C) the primary char is further decom-posed, i.e. mainly dehydrogenated, forming the secondary gas and final char. During the disproportionation reaction, hydrogen atoms of the aliphatic parts of the structural units are "shifted" to saturate" part of the aromatic radicals. The hydrogen shift during dispropor-tionation is highly influenced by the nature of the structural groups.Reading MaterialsRequirements for Heat ResistanceHeat resistance is the capacity of a material to retain useful properties for a stated period of time at elevated temperatures (≥230°C) under defined conditions, such as pressure or vacuum, mechanical load, radiation, and chemical or electrical influences at temperatures ranging from cryogenic to above 500°C. Both reversible and irreversible changes can occur. In a reversible change, for example, as a polymer under load approaches the glass-transition temperature Tg, deformation occurs without change in chemical structure. Reversible changes occur primarily as & function of Tg, which for the purposes of this article, i. e. , for high temperature structural polymers, must be above 230°C. The maximum-use temperature for an amorphous or semicrystalline structural resin usually depends on Tg rather than the crystalline melt temperature Tm. A semicrystalline polymer can exhibit substantial loss of mechanical properties near the Tg, depending upon the degree of crystallinity. The Tm is usually so high that in its vicinity chemical degradation occurs. Irreversible changes alter the chemical structure. For example, exceeding the thermal stability results in bond breaking.The chemical factors which influence heat resistance include primary bond strength, secondary or van der Waals bonding forces, hydrogen bonding, resonance stabilization, mechanism of bond cleavage, molecular symmetry (structure regularity), rigid intrachain structure, and cross-Unking and branching. The physical factors include molecular weight and molecular weight distribution, close packing (crystallinity ), molecular (dipolar) interac-tions, and purity.The primary bond strength is the single most important influence contributing to heat resistance. The bond dissociation energy of a carbon-carbon single bond is ~ 350 kj/mol (83.6 kcal/mol), and that of a carbon-carbon double bond is ~610kJ/mol (145.8 kcal/ mol). In aromatic systems, the latter is even higher. Known as resonance stabilization, this phenomenon adds 164~287kJ/mol (39. 2—86. 6 kcal/mol). As a result, aromatic and hete-rocyclic rings are widely used in thermally stable polymers.Secondary or van der Waals bonding forces provide additional strength and thermal stability. Dipole-dipole interaction and H bonding contribute 25 ~ 41 kj/mol (6.0 ~ 9.8 kcal/mol)toward molecular stability and affect the cohesion energy density* which influences the stiffness , Tg, melting point , and solubility. Thus , beat-resistant polymers often contain polar groups, e.g. , —CO—, —S02—, that participate in strong intermolecular associa-tion. Polymers containing electron-withdrawing groups, e. g., —CO—, as connecting groups are generally more stable than those containing electron-donating groups, e. g. . —O—.The mechanism of bond cleavage also influences thermal stability. In polysiloxanes, for example, the energy of the silicon-oxygen single bond is ~445kJ/mol (106. 4kcal/mol), and that of the silicon-carbon single bond ~328kJ/mol (78. 4kcal/mol). Although the Si—C bond would be。

J-STD-020D(中英文对照版)

J-STD-020D(中英文对照版)

J-STD-020DMoisture/Reflow Sensitivity Classification for Nonhermetic Solid State Surface Mount Devices非密封固态表面贴装元件湿度/回流焊敏感度分级1 PURPOSE(目的)The purpose of this standard is to identify the classification level of nonhermetic solid state surface mount devices (SMDs) that are sensitive to moisture-induced stress so that they can be properly packaged, stored, and handled to avoid damage during assembly solder reflow attachment and/or repair operations.本标准旨在识别非密封固态表面贴装元件的湿度敏感等级以便其能合适的封装,储存,作业以避免在回流和维修作业中被损伤. This standard may be used to determine what classification/preconditioning level should be used for SMD package qualification. Passing the criteria in this test method is not sufficient by itself to provide assurance of long-term reliability本标准用于判定合格的SMT封装应使用何种等级/预处理水平.依据本测试方法且通过对应判定标准的元件并不能保证其长期可靠性1.1 Scope(范围)This classification procedure applies to all nonhermetic solid state Surface Mount Devices (SMDs) in packages, which, because of absorbed moisture, could be sensitive to damage during solder reflow. The term SMD as used in this document means plastic encapsulated surface mount packages and other packages made with moisture-permeable materials. The categories are intended to be used by SMD producers to inform users (board assembly operations) of the level of moisture sensitivity of their product devices, and by board assembly operations to ensure that proper handling precautions are applied to moisture/reflow sensitive devices. If no major changes have been made to a previously qualified SMD package, this method may be used for reclassification according to 4.2.此分类程序适用于所有非密封固体表面贴装元件,此部分元件由于吸收湿气而在回流焊接中容易损伤. 本文件所提及的术语“SMD”指的是塑封或本体为吸湿材料的元件.分类的目的是为了让元件制造商能告知元件使用者(PCBA组装)其产品的湿敏等级,确保元件使用者能恰当作业,如果对之前认证过的SMD封装没有重大更改,依据4.2此方法亦可用于元件的再次分类.This standard cannot address all of the possible component, board assembly and product design combinations. However, the standard does provide a test method and criteria for commonly used technologies. Where uncommon or specialized components or technologies are necessary, the development should include customer/manufacturer involvement and the criteria should include an agreed definition of product acceptance.此标准不能涵盖所有与设计,组装相关联的元件.但是,此标准为通用技术提供了一个测试方法和标准. 如果使用特殊技术或特殊元件,则需客户以及相关的制造方定义一个双方同意的产品接受标准.SMD packages classified to a given moisture sensitivity level by using Procedures or Criteria defined within any previous version ofJ-STD-020, JESD22-A112 (rescinded), or IPC-SM-786 (rescinded) do not need to be revision unless a change in classification level or a higher peak classification temperature is desired. Annex B provides an overview of major changes from Revision C to Revision D of this document.在使用之前版本J-STD-020,JESD22-A112(已作废),IPC-SM-786(已作废)标准中已分级的湿敏元件除非敏感等级变更或耐温峰值提高,否则无须重新分级.附件B提供了版本C升级到版本D的主要变更.Note: If the procedures in this document are used on packaged devices that are not included in this specification’s scope, the fail ure criteria for such packages must be agreed upon by the device supplier and their end user备注:当封装元件未在本标准规格范围内,如需使用此文件中的流程判定,则不良标准需元件供应商和其客户同意.1.2 Background(背景)The vapor pressure of moisture inside a nonhermetic package increases greatly when the package is exposed to the high temperature of solder reflow. Under certain conditions, this pressure can cause internal delamination of the packaging materials from the die and/or leadframe/substrate, internal cracks that do not extend to the outside of the package, bond damage, wire necking, bond lifting, die lifting, thin film cracking, or cratering beneath the bonds. In the most severe case, the stress can result in external package cracks. This iscommonly referred to as the ‘‘popcorn’’ phenomenon because the internal stress causes the package to bulge and then crack wit h an audible ‘‘pop.’’ SMDs are more susceptible to this problem than through-hole parts because they are exposed to higher temperatures during reflow soldering. The reason for this is that the soldering operation must occur on the same side of the board as the SMD device. For wave-soldered through-hole devices, the soldering operation occurs under the board that shields the devices from the hot solder through-hole devices, the soldering operation occurs under the board that shields the devices from the hot solder Throughhole devices that are soldered using intrusive soldering or ‘‘pin in paste’’ processes may experience the same type of moisture-induced failures as SMT devices.非密封元件封装在回流高温条件下,其内部水蒸气压力猛增.在某一件下,压力将导致封装从内部分层或者内裂,邦定受损。

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j ∈E
Si j ψA j ψB j S1 j

ቤተ መጻሕፍቲ ባይዱ
for all i ∈ I .
(2)
We have assumed that there is some quantity, for example a ZN charge, that discriminates representations with the same character, e.g. χi = χi∗ , and enables one to write equation (2) unambiguously. With the norm appropriate for boundary states [4, 7], orthonormality of |A and |B amounts to n1A B =
i∈I
niA B χi (q ),
q = e−πT /L . It also results from the “time” L evolution between states |A and |B : it is then a sesquilinear form in the components of these boundary states on Ishibashi states. If we write |A =
of the A chiral algebra acting on the left and right sectors. Then the A-invariant boundary states satisfy the conditions (Wn − (−1)sW W −n )|φ = 0. (Here we assume that the “gluing automorphism” [8, 2] is trivial.) Solutions to this system of equations are spanned by special states |j (called Ishibashi states [9]) labelled by the finite set E . Let ZAB be the partition function of the CFT on a cylinder of perimeter T and length L with boundary conditions A and B . Regarded as resulting from the periodic “time” T evolution of the system with prescribed boundary conditions, it is a linear form in the characters with integer coefficients: ZAB =

j ∈E
ψA j (ψB j )∗ =
δAB . Reality of ZAB implies that niA B = ni∗ B A . It is also natural to introduce conjugate states |A∗ such that ψA∗ j = ψA j = (ψA j )∗ . Suppose we have found a complete set of boundary states, i.e. such that the fact that the ratios
Paul A. Pearce
Department of Mathematics and Statistics University of Melbourne Parkville, Victoria 3052, Australia
Valentina B. Petkova
Institute for Nuclear Research and Nuclear Energy Tzarigradsko Chaussee 72 1784 Sofia, Bulgaria
On the Classification of Bulk and Boundary Conformal Field Theories
arXiv:hep-th/9809097v2 2 Nov 1998
Roger E. Behrend
Institute for Theoretical Physics State University of New York Stony Brook, NY 11794-3840, USA
j ∈E
ψA j ( S1 j ) 2
1
|j
,
(1)
then ZAB =
j ∈E
ψA j ψB j

χj (˜ q )/S1 j , q ˜ = e−4πL/T , and Cardy’s equation results
from the identification of χi in these two alternative expressions of ZAB : niA B =
The classification of conformal field theories (CFTs) remains an important issue, both in the study of bulk and boundary critical phenomena [1] and in string theory [2]. The guiding principle is that of consistency of the theory on an arbitrary 2D surface, with or without boundaries. To define a rational conformal field theory, one first specifies a chiral algebra A, e.g. the Virasoro algebra or one of its extensions, at a certain level. Rationality means that at this level, A has only a finite set I of admissible irreducible representations Vi , i ∈ I . We denote by Vi∗ the representation conjugate to Vi and i = 1 refers to the vacuum representation. We suppose that the characters χi (q ) of these representations, the symmetric matrix Si j of modular transformations of the χ’s and the fusion coefficients Nij k of the V ’s, assumed to be given in terms of S by the Verlinde formula [3], are all known. A physical theory is then fully defined by the collection of bulk and boundary fields and their 3-point couplings (“structure constants”). In particular, the spectrum of bulk fields is described by the finite set Spec of pairs (j, ) of representations (with possible multiplicities) of the left and right copies of A, such that the Hilbert space of the theory on an infinitely long cylinder reads H = ⊕Spec Vj ⊗V . We denote by E the finite set of labels of the left-right symmetric elements (up to conjugation) of the spectrum: E = {j |(j, = j ∗ ) ∈ Spec}, with these same multiplicities. In terms of all these data one is in principle able to compute exactly all correlation functions of the CFT on an arbitrary 2D surface with or without boundaries [4]. These data, however, are subject to consistency constraints. Much emphasis was originally put on bulk properties, namely on the consistency of the 4-point functions on the sphere [5] and the zero-point function (the modular invariant partition function) on a torus [6]. In this letter, we want to show that the consistency of the partition function on a finite cylinder is equivalent to a well-posed algebraic problem. Once solved, this not only determines the possible boundary conditions but also yields substantial information on the bulk properties, by determining the diagonal part E of the set Spec. The consistency condition on a cylinder is the well known equation of Cardy [7], but it seems that its consequences have never been fully exploited. We recall Cardy’s discussion. Let Wn and W n denote the spin sW generators 1
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