A Carbon Nanotube Based Nanorelay

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Carbon Nanotubes as Molecular Biosensors

Carbon Nanotubes as Molecular Biosensors

Carbon Nanotubes as MolecularBiosensorsCarbon nanotubes (CNTs) are cylindrical structures made up of carbon atoms that are one-atom thick and can have a diameter of just a few nanometers. The unique physical and chemical properties of CNTs make them a promising candidate for a wide range of applications, including molecular biosensing.Molecular biosensors are devices that can detect and quantify the presence of specific biomolecules such as proteins, DNA, and RNA. These biomolecules are often indicative of disease states or environmental pollutants, and their detection can provide valuable insight into the underlying biological and chemical processes involved.To function as biosensors, CNTs are often modified with specific biomolecules, such as antibodies or aptamers, which bind to the target molecule of interest. The binding of the target molecule induces a change in the electrical or optical properties of the CNTs, which can be measured and used to detect the presence and concentration of the target molecule.One of the key advantages of CNT-based biosensors is their high sensitivity and selectivity. Due to their small size and high surface area, CNTs can detect biomolecules at very low concentrations, even down to the single-molecule level. Additionally, the surface chemistry of CNTs can be tailored to enhance their binding affinity for specific biomolecules, further improving their selectivity.Another advantage of CNT-based biosensors is their compatibility with various detection platforms. CNTs can be integrated with a range of transducers, such as field-effect transistors, optical sensors, or electrochemical sensors, to amplify and detect the binding-induced changes in electrical or optical signals.CNT-based biosensors have already shown promise in a range of applications, including early detection of cancer biomarkers, monitoring of bacterial infections, and detection of environmental pollutants such as heavy metals and pesticides.However, there are also some challenges and limitations to the use of CNTs as biosensors. One important consideration is their potential toxicity and biocompatibility. While CNTs are generally considered safe, there have been concerns about their potential accumulation and effects on living organisms. Therefore, extensive studies and regulations are necessary to ensure the safe use of CNTs in molecular biosensing applications.In conclusion, CNTs are emerging as a promising platform for molecular biosensing, with their high sensitivity, selectivity, and compatibility with various detection platforms. Further research and development in this field could lead to the development of CNT-based biosensors with improved performance and specificity, enabling their broader applications in disease diagnosis, environmental monitoring, and other areas.。

Properties and Uses of Carbon Nanotubes

Properties and Uses of Carbon Nanotubes

Properties and Uses of CarbonNanotubesCarbon nanotubes (CNTs) are one of the most promising materials in nanotechnology due to their extraordinary properties. They are cylindrical structures that consist of one or multiple graphene sheets rolled up into tubes. CNTs can be either single-walled (SWCNTs) or multi-walled (MWCNTs), and their properties are determined by the number of walls, diameter, and length. In this article, we will discuss the properties and uses of carbon nanotubes.Properties of Carbon NanotubesCNTs possess unique mechanical, electrical, and thermal properties that make them ideal for various applications:Mechanical Properties: CNTs have unparalleled mechanical strength and stiffness, with Young's modulus up to 1 TPa and tensile strength up to 100 GPa. They can withstand high loads without breaking, making them ideal reinforcement materials in composites.Electrical Properties: CNTs are excellent conductors of electricity and heat due to their sp2 hybridization. They can carry current densities up to 109 A/cm2, and their electrical conductivity is comparable to copper. Furthermore, CNTs have high thermal conductivity that exceeds that of diamond.Optical Properties: CNTs exhibit interesting optical properties, with their optical absorbance and reflectance varying with their diameter and chirality. CNTs can also emit light when excited, and they have potential applications in light-emitting devices.Uses of Carbon NanotubesCNTs have found numerous applications in various fields, including electronics, mechanics, energy, and medicine:Electronics: CNTs have been hailed as a replacement for silicon in the electronics industry due to their high charge-carrier mobility, low power consumption, and size compatibility. They can be used as field-effect transistors, sensors, memory devices, and interconnects.Mechanics: CNTs have been used as reinforcements in composites to improve their strength, stiffness, and toughness. They can also be used to develop lightweight materials, such as bicycle frames, tennis rackets, and airplanes.Energy: CNTs have been used as efficient catalysts, electrodes, and energy storage materials in energy applications. They can be used to produce hydrogen through the water-splitting reaction, to produce efficient and durable lithium-ion batteries, and to store hydrogen in fuel cells.Medicine: CNTs have been investigated for their biocompatibility and potential biomedical applications. They can be used as drug delivery vehicles, imaging agents, and tissue engineering scaffolds. However, their toxicity and environmental impact must be thoroughly investigated before their widespread use in medicine.ConclusionCarbon nanotubes possess unique properties that make them ideal for various applications in electronics, mechanics, energy, and medicine. Their mechanical strength, electrical and thermal conductivity, and optical properties have important implications for the development of new materials, devices, and systems. However, their commercialization and practical applications have been hindered by their high cost, scalability issues, and safety concerns. Further research and development are needed to overcome these challenges and fully exploit the potential of carbon nanotubes.。

Chemical modification of carbon nanotubes

Chemical modification of carbon nanotubes

Chemical modification of carbonnanotubesCarbon nanotubes (CNTs) are a unique form of carbon allotrope, consisting of cylindrical tubes composed of graphite sheets rolled into a seamless tube. They possess excellent electronic and mechanical properties, and their small size and high surface area make them promising candidates for a wide range of applications including drug delivery, electronics, and energy storage. However, their hydrophobic nature and tendency to aggregate pose significant challenges in their use.One approach to addressing these issues is through chemical modification, which involves covalently attaching functional groups to the surface of the CNTs. This modification can alter their physical and chemical properties, such as solubility, reactivity, and biocompatibility. Chemical modification enables the tailoring of CNTs to specific applications, enhancing their functionality and improving their performance.Oxidation is the most commonly employed method of chemical modification of CNTs. This involves the introduction of oxygen functionalities, such as carboxyl groups (-COOH) and hydroxyl groups (-OH), onto the CNT surface. This creates a more polar surface, rendering the CNTs more hydrophilic and amenable to dispersion in aqueous or polar solvents. In addition, the increased reactivity of the oxidized CNTs enables further functionalization using a variety of organic molecules or polymers.In addition to oxidation, other methods of chemical modification have been developed. One such method is non-covalent functionalization, which involves the non-covalent attachment of molecules onto the CNT surface. This can be achieved through π-π bonding, van der Waals interactions, or electrostatic interactions. Non-covalent functionalization offers advantages such as preserving the structural integrity of the CNTs and providing a reversible modification that can be easily removed.Another method of chemical modification is the direct functionalization of CNTs with organic or inorganic molecules. This involves the covalent attachment of a specificmolecule or chemical group onto the CNT surface, resulting in a modified CNT with unique physical and chemical properties. Direct functionalization has been employed in a range of applications, such as drug delivery and biosensors.Chemical modification of CNTs has significant implications for their use in drug delivery. The introduction of functional groups can enhance their biocompatibility, enabling their use as drug carriers and targeted drug delivery vehicles. Additionally, incorporation of targeting ligands onto the surface of modified CNTs can improve their specificity and selectivity towards specific cell types or tissues.Overall, chemical modification offers a powerful strategy to tailor the properties of CNTs to specific applications. The versatility and functionality of modified CNTs make them promising candidates for a vast array of applications. While challenges remain, continued research and development in this field will undoubtedly contribute to unlocking the full potential of CNTs in a range of fields.。

Properties of Carbon Nanotubes

Properties of Carbon Nanotubes

Properties of Carbon NanotubesCarbon nanotubes (CNTs) are cylindrical materials made from pure carbon, composed of graphene sheets rolled into tubes. They are one of the most extensively studied nanostructures with unique mechanical, electrical, and thermal properties. These characteristics make them ideal candidates for a wide range of applications such as drug delivery systems, electronics, energy storage, and nanocomposites. In this article, we will explore some of the properties that make carbon nanotubes so unique.1. Mechanical propertiesOne of the most significant properties of CNTs is their remarkable mechanical strength. CNTs are strong and stiff, and a single-walled carbon nanotube (SWCNT) can withstand strains of up to 10% without breaking. This remarkable strength is due to the strong covalent bonds between carbon atoms and the sp2 hybridization of carbon atoms within the graphene sheets. These features result in the tubes' exceptional stiffness, with an elastic modulus of up to 1 TPa, making them the stiffest known materials.2. Electrical propertiesCNTs possess unique electrical properties due to their one-dimensional structure, which behaves like a one-dimensional quantum wire. SWCNTs are either metallic or semiconducting, depending on their diameter and chirality. This feature makes them ideal for building electronic circuits with high performance and miniaturization attributes. Additionally, CNTs have outstanding electrical conductivity, outperforming copper by a factor of 100-1000 times. The unique combination of semiconducting and metallic properties of SWCNTs has made them an ideal material for building high-performance transistors.3. Thermal propertiesCNTs exhibit excellent thermal conductivity that can surpass copper's conductivity, making them an ideal candidate for high-temperature applications such as heat exchangers, electronics, and aerospace. The thermal conductivity of CNTs is dependenton their length, diameter, and chirality. The unique thermal properties of CNTs can be attributed to their one-dimensional structure.4. Optical propertiesThe unique one-dimensional structure of CNTs results in unusual optical properties such as strong light absorption in the visible and near-infrared regions of the electromagnetic spectrum. Additionally, CNTs have a high surface area that can be used to improve the efficiency of dye-sensitized solar cells.ConclusionCarbon nanotubes exhibit exceptional properties that make them ideal for a wide range of applications. Their remarkable mechanical strength, electrical conductivity, thermal properties, and optical properties make them ideal for use in a wide range of applications such as electronics, aerospace, nanocomposites, and energy storage. The future of carbon nanotubes looks very promising with exciting advances in their synthesis, characterization, and practical applications. As we continue to unravel the secrets of the carbon nanotube, we can only expect their wide-ranging applications to grow even further in the future.。

The Physical Properties of Carbon Nanotubes

The Physical Properties of Carbon Nanotubes

The Physical Properties of CarbonNanotubesCarbon nanotubes (CNTs) are one of the most fascinating materials developed in the past few decades. They are cylindrical nanostructures composed of carbon atoms arranged in a hexagonal pattern. CNTs have unique properties, including high strength and stiffness, small size, exceptional electrical conductivity, and thermal conductivity. These properties make them preferable for numerous applications in several fields, including electronics, materials science, aerospace, and biotechnology.Structure of carbon nanotubesCarbon nanotubes have two primary structural types: single-walled nanotubes (SWNTs) and multi-walled nanotubes (MWNTs). SWNTs consist of a single rolled sheet, while MWNTs contain multiple rolled sheets. The diameter of SWNTs ranges from 0.4to 2 nm, while MWNTs have diameters ranging from 2 to 100 nm. The length of CNTs is usually several micrometers, but they can be longer.Thanks to their small dimensions and tubular structure, CNTs have a high aspect ratio, which means that their length is much greater than their diameter. This aspect ratio gives CNTs their unique mechanical properties. They are exceptionally strong and stiff, with a Young's modulus three to four times higher than that of steel. Moreover, CNTs are quite resilient, and their deformation before failure is much more elevated than conventional materials, making them perfect for use in new structural materials.Electrical properties of carbon nanotubesOne of the most remarkable properties of CNTs is their electrical conductivity. They have excellent electrical properties, which means they can conduct electricity even better than copper. SWNTs are metallic or semiconducting depending on their chiral angle, while MWNTs are usually metallic.SWNTs have particular band structures, and their electrical properties depend heavily on their atomic structure. The electronic properties of CNTs make them ideal for use in electronic applications, such as field-effect transistors, diodes, and sensors. CNTs have the potential to improve the performance of transistors and other electronic devices significantly.Thermal properties of carbon nanotubesCNTs also have exceptional thermal conductivity, making them useful in thermal management materials. The thermal conductivity of CNTs is approximately seven times higher than that of copper. Moreover, CNTs are excellent heat conductors at the nanoscale, which gives them the potential to improve the efficiency of thermal management materials in electronic devices.Other physical properties of carbon nanotubesIn addition to their excellent mechanical, electrical, and thermal properties, CNTs also exhibit some other unique physical properties that make them advantageous for several applications. They are lightweight and can be dispersed in solvents, allowing them to be used in coatings, composites, and other materials.Furthermore, because of their nanoscale dimensions, CNTs have a high surface area-to-volume ratio, which makes them an effective adsorbent for gas and liquid molecules. This property makes CNTs promising candidates for gas storage and separation, as well as water purification.ConclusionCNTs are exceptional materials that have unique physical properties that lend themselves to several applications. They are lightweight, strong, stiff, and excellent electrical and thermal conductors, making them preferable for use in several fields, including electronics, materials science, and aerospace. Their physical properties make CNTs promising candidates for improving the performance of electronic devices, structural materials, and energy storage systems.。

Characterizing the properties of carbon nanotubes

Characterizing the properties of carbon nanotubes

Characterizing the properties ofcarbon nanotubesCarbon nanotubes (CNTs) have been the subject of extensive research due to their unique structural, electronic, mechanical, and thermal properties. CNTs are cylindrical tubes of carbon atoms, having a diameter of a few nanometers and a length of several micrometers. The walls of CNTs are made of graphene sheets that are rolled up into cylinders, resulting in a seamless tube with a hollow core. The properties of CNTs depend on their diameter, length, chirality, and defects, which can be controlled during the synthesis process.One of the most important properties of CNTs is their high aspect ratio, which is the ratio of their length to diameter. CNTs can have aspect ratios of up to 100,000, which makes them the strongest known materials, with tensile strengths up to 63 GPa. The strength of CNTs comes from their sp2 hybridized carbon bonds, which make the tubes extremely stiff and resilient. CNTs are also highly flexible, and can bend and twist without breaking, enabling them to be used in a wide range of applications.Another important property of CNTs is their electrical conductivity. CNTs are excellent conductors of electricity, with an electrical conductivity of up to 1x107 S/m, which is higher than that of copper. The conductivity of CNTs is dependent on their diameter and chirality, with smaller diameter tubes being more conductive than larger diameter tubes. The high conductivity of CNTs makes them a promising material for electronic and optoelectronic applications, such as transistors, sensors, and solar cells.CNTs also possess exceptional thermal conductivity, which is the ability to conduct heat. CNTs have an extremely high thermal conductivity of up to 3500 W/mK, which is higher than that of any other known material. The high thermal conductivity of CNTs makes them ideal for use in thermal management applications, such as heat sinks and nanocomposites.Furthermore, CNTs are highly hydrophobic, meaning that they repel water. This property makes them useful in applications where water resistance is required, such as in coatings and membranes. CNTs are also resistant to chemical corrosion and oxidation, which makes them highly durable and long-lasting.However, CNTs also have some limitations that need to be addressed. One of the major challenges is their toxicity. While CNTs have shown great promise in medical applications, such as drug delivery and cancer therapy, their potential toxicity to cells and tissues is a cause of concern. Studies have shown that CNTs can cause lung damage and inflammation in rodents, raising questions about their safety for human use. Therefore, it is important to thoroughly evaluate the toxicity of CNTs before using them in biomedical applications.In conclusion, CNTs are a remarkable material with unique and exceptional properties that make them suitable for a wide range of applications. Their high strength, electrical and thermal conductivity, hydrophobicity, and chemical stability make them a promising material in the fields of electronics, energy, and healthcare. However, their potential toxicity needs to be addressed before they can be widely used in biomedical applications. Understanding the properties of CNTs is essential for developing new applications that can exploit their exceptional properties while minimizing their drawbacks.。

Chemical Properties of Carbon Nanotube Transistors

Chemical Properties of Carbon Nanotube Transistors

Chemical Properties of Carbon NanotubeTransistorsCarbon nanotubes are one of the most promising materials in electronics due to their excellent electronic and mechanical properties. Carbon nanotube transistors have shown a great deal of promise due to their high performance, low power consumption, and small size. Understanding the chemical properties of carbon nanotube transistors is crucial for their successful integration into new technology.One of the most important chemical properties of carbon nanotube transistors is their electrical conductivity. Carbon nanotubes are excellent conductors of electricity due to their unique structure, which consists of a cylindrical tube made up of rolled-up graphene sheets. This structure allows electrons to move freely throughout the tube, creating a highly conductive material. The electrical conductivity of carbon nanotube transistors can be further enhanced through chemical doping, which involves adding impurities to the material to increase its conductivity.Another important chemical property of carbon nanotube transistors is their surface chemistry. The surface of a carbon nanotube is highly reactive due to the presence of functional groups, such as carboxyl and hydroxyl groups. These groups can be used to modify the surface chemistry of the carbon nanotubes, making them more suitable for specific applications. For example, the surface chemistry of carbon nanotubes can be modified to make them more biocompatible, allowing them to be used in biomedical applications.In addition to their electrical conductivity and surface chemistry, the chemical stability of carbon nanotube transistors is also an important consideration. Carbon nanotubes are susceptible to oxidation, which can degrade their electronic properties over time. To improve the stability of carbon nanotube transistors, researchers are investigating different surface treatments and coatings that can protect the material from oxidation.The chemical properties of carbon nanotube transistors are closely related to their mechanical properties. Carbon nanotubes are incredibly strong and can withstand significant amounts of stress without breaking. This mechanical strength is due to the strong covalent bonds between carbon atoms in the graphene structure. However, carbon nanotubes are also quite brittle, and can be easily damaged by mechanical stress. To ensure the longevity of carbon nanotube transistors, researchers are investigating ways to increase their mechanical strength while maintaining their electronic properties.In conclusion, the chemical properties of carbon nanotube transistors are crucial for their successful integration into new technology. Understanding the electrical conductivity, surface chemistry, chemical stability, and mechanical properties of carbon nanotube transistors is essential for developing new applications and improving their performance. As research in this field continues, it is likely that carbon nanotube transistors will become an increasingly important material in electronics and other fields.。

The properties of carbon nanotubes

The properties of carbon nanotubes

The properties of carbon nanotubesCarbon nanotubes (CNTs) have emerged as one of the most promising materials in the world of nanotechnology. Since their discovery in the early 1990s, they have been the subject of intense research due to their extraordinary physical and mechanical properties. CNTs are cylindrical structures made of carbon atoms, which are arranged in a honeycomb lattice. They can be single-walled or multi-walled, depending on the number of layers of carbon atoms.CNTs have many unique properties, including high tensile strength, thermal conductivity, and electrical conductivity. These properties make them suitable for a wide range of applications, from electronics to energy storage. In this article, we will explore the properties of CNTs in more detail.Tensile StrengthOne of the most remarkable properties of CNTs is their incredible tensile strength. In fact, CNTs are the strongest materials known to man. They are up to 100 times stronger than steel, yet only a fraction of the weight. This makes them ideal for use in materials that require high strength and low weight. For example, CNTs could be used to make stronger and lighter aircraft engines and components.Thermal ConductivityCNTs also have a high thermal conductivity, which makes them excellent heat conductors. This means that CNTs can quickly transfer heat from one point to another. This makes them ideal for use in heat sinks, which are used to dissipate heat from electronic devices. Additionally, CNTs can be used to improve the efficiency of energy storage devices, such as batteries and supercapacitors.Electrical ConductivityCNTs are also excellent electrical conductors, which makes them ideal for use in electronics. They have a very high current carrying capacity, which means they can carrya large amount of electricity without overheating. Additionally, they have a low resistance, which means that electrical signals can travel through them quickly and efficiently. CNTs could be used to make faster and more efficient computer chips, as well as more durable electronic components.Chemical StabilityCNTs are also very chemically stable, meaning they are resistant to chemical reactions. This is due to the strong covalent bonds between the carbon atoms in the honeycomb lattice. This property makes CNTs ideal for use in environments with harsh chemicals, such as in the oil and gas industry. They could be used to make stronger and more durable pipes and other components that are needed in these environments.ConclusionIn conclusion, CNTs have many unique and fascinating properties that make them ideal for a wide range of applications. From their incredible tensile strength to their high thermal and electrical conductivity, CNTs are proving to be one of the most promising materials in the world of nanotechnology. As research continues, it is likely that we will discover even more amazing properties of CNTs that could revolutionize the way we live and work.。

一维纳米材料

一维纳米材料

具有极好的可弯折性
具有极好的可扭曲性
碳纳米管可以制作成两维数据存储系统 (1015 bytes/cm2 compared to the current state of the 108 bytes/cm2) ...
• 。
碳纳米管的强度比钢高100多倍,杨氏模量估计 可高达5 TPa, 这是目前可制备出的具有最高比强度 的材料,而比重却只有钢的1/6;同时碳纳米管还具 有极高的韧性,十分柔软。它被认为是未来的 “超 级纤维”,是复合材料中极好的加强材料。
纳米棒、纳米丝和纳米线
准一维实心的纳米材料是指在两维方 向上为纳米尺度,长度比上述两维方向上的 尺度大得多,甚至为宏观量的新型纳米材 料. 纵横比(长度与直径的比率)小的称为 纳米棒,纵横比大的称作纳米丝.至今,关 于纳米棒与纳米丝之间并没有一个统一的标 准,通常把长度小于 1mm的纳米丝称为纳 米棒,长度大于 1mm的称为纳米丝线.半 导体和金属纳米线通常称为量子线.
纳米多层管
C纳米索线
C脚手架
C60晶体管
纳米变阻箱
The pictures show two different examples of final configurations just before rupture of the contact.
人工组装合成的纳米结构的体系 纳米齿轮
T形和Y形结
C纳米管 和C60球
H2原子和C纳米管
多层C纳米管
纳米棒
单晶纳米SiC丝 的透射电镜形貌
氮化硅纳米丝
SANDWICH
Microscopy methods reveal abrupt interfaces in an InAs/InP (green and orange, respectively) nanowire

Structure and Properties of Carbon Nanotubes

Structure and Properties of Carbon Nanotubes

Structure and Properties of CarbonNanotubesCarbon nanotubes (CNTs) are one of the most promising materials of the 21st century, with a broad range of applications from electronics to energy to biomedical engineering. These tiny, cylindrical structures are made entirely of carbon atoms, arranged in a unique pattern that gives them remarkable properties.Structure of Carbon NanotubesThe structure of CNTs is both simple and complex at the same time. The basic building block of a CNT is a single layer of graphene, a two-dimensional sheet of carbon atoms arranged in a hexagonal pattern. Graphene is essentially a flat version of a CNT, without the cylindrical shape. To form a CNT, the graphene is rolled up into a tube, with the carbon atoms forming strong covalent bonds that hold the structure together.There are two major types of CNTs: single-walled carbon nanotubes (SWCNTs) and multi-walled carbon nanotubes (MWCNTs). As the name suggests, SWCNTs are composed of a single layer of graphene rolled into a cylindrical shape, while MWCNTs consist of multiple layers of graphene tubes nested inside each other, like a set of Russian dolls.Properties of Carbon NanotubesOne of the most exciting things about CNTs is their unique combination of physical, chemical, and electrical properties. Here are a few of the most notable:1. Strength: CNTs are incredibly strong, with a tensile strength that is 100 times higher than steel. This makes them ideal for use in structural materials, such as lightweight composites.2. Conductivity: CNTs are excellent conductors of both heat and electricity, making them attractive for use in electronics and energy applications.3. Surface area: Because of their small size and high surface area, CNTs have enormous potential as catalysts for chemical reactions and as electrodes in batteries and supercapacitors.4. Flexibility: Despite their strength, CNTs are also flexible, making them useful as components in flexible electronics and wearable devices.Applications of Carbon NanotubesWith such a wide range of properties, it's no surprise that CNTs have a broad rangeof potential applications. Here are just a few examples:1. Electronics: CNTs are already being used in a variety of electronic components, including transistors, sensors, and displays. Because of their high conductivity and small size, they can be used to create faster, smaller, and more powerful devices.2. Energy storage: CNTs show promise as electrodes in batteries and supercapacitors, offering higher energy density and faster charging times than traditional materials.3. Biomedical engineering: CNTs have been explored as drug delivery vehicles and as scaffolds for tissue engineering, thanks to their biocompatibility and small size.4. Structural materials: CNTs can be used in composites to create strong, lightweight materials for aerospace, automotive, and other applications.ConclusionCarbon nanotubes are truly remarkable materials, with a unique combination of properties that make them useful in a wide range of applications. While there is still much research to be done to fully understand their properties and potential, the future looks bright for this tiny but mighty material.。

聚氨酯复合材料的研究进展

聚氨酯复合材料的研究进展

聚氨酯复合材料的研究进展周丰;武春雨【摘要】采用纳米填料制备聚合物基复合材料是改善聚氨酯耐老化性能及耐沾污性,拓展其应用领域的一种重要手段。

综述了聚氨酯与蒙脱土、石墨烯、碳纳米管、纳米TiO2、高岭土等无机材料制备的复合材料的研究进展。

目前,这些复合材料大多停留在实验室研究阶段,应不断改进复合材料生产工艺,降低成本,尽快实现产业化;应解决和控制复合材料制备过程中有关粒子的分散与团聚问题;采用个性定制等方法实现聚氨酯复合材料性能的多功能化等是今后的主要研究方向。

%Nano filler is used to prepare polymer based composites,which can improve the aging and stain resistance of polyurethane and extend its application. This paper reviews the research progress of the composites prepared by polyurethane with inorganic materials such as carbon nanotube,graphene,kaolinite, nano titanic oxide,and montmorillonite. It needs to improve the manufacturing process,reduce the costs to realizethe industrialization of the materials which are still in laboratory research.In addition,the dispersion and agglomeration of the particles need to be controlled during preparation of the composites. Customization is used to achieve the multifunction of the polyurethane composites,which will bethe future research direction.【期刊名称】《合成树脂及塑料》【年(卷),期】2016(033)003【总页数】6页(P97-102)【关键词】聚氨酯;复合材料;石墨烯;碳纳米管;蒙脱土;保温材料;硬质聚氨酯【作者】周丰;武春雨【作者单位】中国人民大学,北京市 100872;大连万达商业地产股份有限公司,北京市 100022【正文语种】中文【中图分类】TQ323聚氨酯是由多异氰酸酯在催化剂及助剂存在下与多元醇聚合而成的以氨基甲酸酯基团为重复基团的一种高分子材料,主要包括聚氨酯泡沫(分为硬质、半硬质、软质)、聚氨酯弹性体、聚氨酯涂料、防水聚氨酯、聚氨酯胶载剂等。

Carbon Nanotubes碳纳米管精彩介绍

Carbon Nanotubes碳纳米管精彩介绍

Connect two graphite rods to a power supply, place them millimeters apart, and throw switch. At 100 amps, carbon vaporizes in a hot plasma.
Can produce SWNT and MWNTs with few structural defects
Carbon Nanotubes
By Bryan Sequeira Bertug Kaleli Murshed Alam Farooq Akbar Zac Lochner
What are Carbon Nanotubes ?
Carbon nanotubes are fullerene-related structures which consist of graphene cylinders closed at either end with caps containing pentagonal rings
Arc discharge method
Chemical vapor deposition
Place substrate in oven, heat to 600 C, and slowly add a carbon-bearing gas such as methane. As gas decomposes it frees up carbon atoms, which recombine in the form of NTs
Tubes tend to be short with random sizes and directions
NTs are usually MWNTs and often riddled with defects

Research on the properties of carbon nanotubes

Research on the properties of carbon nanotubes

Research on the properties of carbonnanotubesCarbon nanotubes (CNTs) are unique materials with extraordinary mechanical, electrical and thermal properties. At the nanoscale, they exhibit a combination of properties that make them ideal for use in a wide range of applications.Properties of Carbon NanotubesOne of the most remarkable properties of CNTs is their strength. CNTs are 100 times stronger than steel, five times lighter than aluminum, and 10 times stronger than Kevlar. This strength is due to the strong covalent bonds between the carbon atoms in the nanotube structure. These bonds allow the nanotubes to resist deformation and fracture under high stresses.Another important property of CNTs is their electrical conductivity. CNTs are excellent conductors of electricity and can carry large amounts of current without overheating. This property makes them ideal for use in electronics, such as transistors, sensors, and interconnects.CNTs are also excellent thermal conductors. They can transport heat at rates that exceed those of any other known material. This thermal conductivity makes them ideal for use in heat sinks, which are used to cool electronic devices.Types of Carbon NanotubesThere are two main types of CNTs: single-walled nanotubes (SWNTs) and multi-walled nanotubes (MWNTs). SWNTs are thin tubes made up of a single layer of carbon atoms. They are extremely strong and have high electrical conductivity. MWNTs, on the other hand, are made up of several layers of carbon atoms and are not as strong or conductive as SWNTs.Applications of Carbon NanotubesThe unique properties of CNTs have led to their use in a variety of applications. One of the most promising applications for CNTs is in the field of electronics. The high electrical conductivity and small size of CNTs make them ideal for use in transistors and other electronic components.CNTs are also being used in the field of medicine. Researchers are exploring the use of CNTs in drug delivery systems, as well as in the development of new imaging techniques.In addition, CNTs have potential applications in the field of energy. They may be used in the development of new, lightweight batteries and in the production of more efficient solar cells.ConclusionThe unique properties of CNTs make them one of the most promising materials for a wide range of applications. The strength, electrical conductivity, and thermal conductivity of these materials are unparalleled at the nanoscale. As researchers continue to explore the properties of CNTs, it is likely that new applications and uses for these materials will be discovered.。

nature和science近年关于碳纳米管的文章

nature和science近年关于碳纳米管的文章

nature和science近年关于碳纳米管的文章碳纳米管是一种由碳原子构成的纳米结构,其直径约为纳米级别,长度可达微米级别。

由于其独特的结构和优异的物理化学性质,碳纳米管在材料科学、纳米技术、能源存储等领域具有广阔的应用前景。

近年来,顶级期刊Nature和Science相继发表了多篇关于碳纳米管的研究文章,本文将逐步介绍这些文章并总结其主要发现。

一、Nature上的关于碳纳米管的文章:1. “Enhanced Electrochemical Performance of Carbon Nanotube-Based Micro-Supercap acitors” (2017年)这篇文章报道了一种基于碳纳米管的微型超级电容器,通过控制碳纳米管的结构和形貌,实现了超高的电容性能。

研究者在文中详细描述了制备方法、电化学性能,以及与传统超级电容器的比较结果。

2. “Bioinspired Carbon Nanotube Transistors with Cytoskeleton-like Scaffolds”(2018年)本研究根据生物启发,通过制备具有细胞骨架类似结构的碳纳米管晶体,并将其应用于场效应晶体管中。

实验结果表明,这种生物仿生晶体管具有优异的电学性能和稳定性。

文中详细描述了合成方法、材料特性以及晶体管性能测试结果。

3. “Carbon Nanotubes as High-Performance Anode Materials for Sodium-Ion Batteries”(2019年)这篇文章探讨了碳纳米管作为钠离子电池高性能负极材料的潜力。

研究人员通过一系列实验和材料表征手段,证明了碳纳米管在钠离子电池中具有高容量、长循环寿命等优异特性。

文章中提供了详细的实验方法、电池测试结果以及相应机制的解释。

Nature上的这些文章详细描述了碳纳米管在微型超级电容器、场效应晶体管和钠离子电池等领域的应用前景和性能优势。

The properties and uses of carbon nanotubes

The properties and uses of carbon nanotubes

The properties and uses of carbonnanotubesCarbon nanotubes (CNTs) are one of the most impressive materials discovered in recent memory. A single-walled carbon nanotube (SWCNT) is just one atom thick, but their potential as a building block for a variety of innovative technologies is almost limitless. In this article, we will take a look at some of the properties and uses of this remarkable material.The Properties of Carbon NanotubesCarbon nanotubes are composed of a single layer of carbon atoms arranged in a long, thin, cylinder. Their small size and unique molecular structure give them some remarkable properties that set them apart from other materials.One of the most incredible properties of carbon nanotubes is their strength. They are 100 times stronger than steel but much lighter in weight. This strength comes from their unique molecular structure and the fact that the carbon atoms are arranged in a rigid, hexagonal pattern.Another interesting property of carbon nanotubes is their electrical conductivity. They conduct electricity better than copper, making them an attractive material for many electronic applications. Additionally, they are also excellent conductors of heat, making them useful in thermal management applications.Carbon nanotubes also have a very high surface area relative to their size. This property makes them useful as a catalyst in chemical reactions or as a material for energy storage. They are also very durable, meaning they can withstand extreme conditions without breaking down.Uses of Carbon NanotubesGiven the impressive properties of carbon nanotubes, it's no surprise that they have a variety of potential uses across a wide range of industries.Some of the most promising applications for carbon nanotubes include electronic and computer components. For example, carbon nanotubes can form the basis of high-performance transistors or light-emitting diodes. They could also be used in electronic displays, solar cells, and batteries.In addition to electronics, carbon nanotubes also hold promise for the development of stronger and lighter materials. For example, they could be used to make stronger composites for aircraft or cars.Another area where carbon nanotubes could prove useful is in medicine. Researchers have shown that carbon nanotubes can be used as drug delivery vehicles, enabling targeted treatment of cancer and other diseases.Finally, carbon nanotubes have been studied for use in water purification and desalination. Because of their high surface area, they can be used to adsorb contaminants from water, making it cleaner and safer to drink.ConclusionThere is no doubt that carbon nanotubes are one of the most exciting materials of our time. With their impressive strength, conductivity, and surface area, they hold promise for a wide range of applications in electronics, materials science, medicine, and beyond. The potential of this remarkable material is limitless, and we can only imagine what advances in technology and science we will see in the future thanks to the development of carbon nanotubes.。

Carbonnanotubeba...

Carbonnanotubeba...

Carbon nanotube based pressure sensor forflexible electronicsHye-Mi So a,Jin Woo Sim b,Jinhyeong Kwon c,Jongju Yun d,Seunghyun Baik d,Won Seok Chang a,*a Department of Nano Mechanics,Nanomechanical Systems Research Division,Korea Institute of Machinery and Materials,Daejeon305-343,Republic ofKoreab Advanced Nano Technology Ltd.,Seoul132-710,Republic of Koreac Department of Mechanical Engineering,Korea Advanced Institute of Science and Technology,Daejeon305-701,Republic of Koread SKKU Advanced Institute of Nanotechnology(SAINT),Department of Energy Science and School of Mechanical Engineering,Sungkyunkwan University,Suwon,Gyeonggi-do440-746,Republic of Korea1.IntroductionNovel biocompatible pressure sensors have been activelypursued toward the development of artificial electronic skinapplications[1–3].These also have been widely recognized asessential elements for the realization of artificial intelligencedevices that facilitate human interaction such as interactiveelectronics or robot systems with human-like epidermal sensors.Artificial electronic skins generally involve large arrays of pixelpressure sensors on aflexible and stretchable substrate with thegoal of achieving a high sensitivity to small pressure differentialsduring gentle contact.Lipomi et al.described a skin-likeflexiblestretchable pressure sensor formed by spraying single-walledcarbon nanotubes(SWNTs)onto a thin layer of silicone[4].In theirreport,the SWNTs sprayed onto the silicon substrate naturallyformed nanoscale bundles and aligned along the direction of thestretching motion during substrate stretching.Although this skinwas less sensitive than other skin-like devices[5],Lipomi et al.demonstrated the detection of both pressure and strain whilemaintaining the skin transparency and stretchability.Suh et al.developed a prototype‘flexible electronic sensor’that relied oninterlocking hairs to sense objects through static attraction[6].Despite many recent advances,most sensing elements are basedon passive matrix circuitry.Carbon nanotubes exhibit exceptional mechanical properties,including a high elastic modulus and a high strength that is100times the strength of steel[7,8].Several extensive reports havecharacterized the mechanical and electrical properties of CNT-reinforced polymers and pristine CNTs[9–13].Freestandingfilmscontaining vertically aligned CNTs exhibit super-compressiblefoam-like behavior[12],whereas ultra-long CNT blocks can act aspressure or strain sensors,exhibiting reversible electrical conduc-tivities and a compressive strain response[13].Here,we describe aflexible pressure sensor prepared using VACNTs embedded in aPDMS support matrix.The VACNTs in the PDMS matrix weredeformable and maintained their structuralflexibility uponrepeated compression due to the high elasticity of the PDMSand VACNTs.A single-walled carbon nanotubefield-effecttransistor(SWNT-FET)with an ion gel gate dielectric layer wasfabricated and combined with the pressure sensor in a proof-of-concept device.2.Experimental2.1.Preparation of VACNT blockVertically aligned multi-walled CNTs were grown on rigidsubstrates via chemical vapor deposition methods[14].An Fe/AlMaterials Research Bulletin48(2013)5036–5039A R T I C L E I N F OArticle history:Received25January2013Received in revised form24April2013Accepted9July2013Available online18July2013Keywords:A.NanostructuresB.Vapor depositionC.Electrical propertiesD.MicrostructureA B S T R A C TA pressure sensor was developed based on an arrangement of vertically aligned carbon nanotubes(VACNTs)supported by a polydimethylsiloxane(PDMS)matrix.The VACNTs embedded in the PDMSmatrix were structurallyflexible and provided repeated sensing operation due to the high elasticities ofboth the polymer and the carbon nanotubes(CNTs).The conductance increased in the presence of aloading pressure,which compressed the material and induced contact between neighboring CNTs,thereby producing a dense current path and better CNT/metal contacts.To achieveflexible functionalelectronics,VACNTs based pressure sensor was integrated withfield-effect transistor,which isfabricated using sprayed semiconducting carbon nanotubes on plastic substrate.ß2013Elsevier Ltd.All rights reserved.*Corresponding author.Tel.:+82428687134;fax:+82428687884.E-mail addresses:************.kr,******************(W.S.Chang).Contents lists available at ScienceDirectMaterials Research Bulletinj o u rn a l h om e p a g e:w w w.e l s e v i e r.c o m/l o c a t e/m a t r e s b u0025-5408/$–see front matterß2013Elsevier Ltd.All rights reserved./10.1016/j.materresbull.2013.07.022catalyst layer was deposited by e-beam evaporation.VACNTs were grown on the catalyst-deposited substrate at7508C in a furnace under a mixedflow of C2H4,Ar,and H2.The reactor was then slowly cooled to room temperature under an Ar atmosphere.The VACNTs were embedded in the PDMS matrix prepared by mixing PDMS(Sylgard184from Dow Corning)with the crosslinker in a10:1base to crosslinker mass ratio.The mixture was degassed under vacuum,diluted with hexane,and poured onto the VACNT substrate.After curing in an oven at908C for2h,the PDMS-VACNT block was peel away from the Si substrate.The bottom and top surfaces of the VACNTs were treated with O2plasma before metallization to provide good contacts between the CNTs and the metal.A5/50nm Cr/Au layer was then deposited to form the electrical contact.2.2.Fabrication of SWNT-FETChannel materials composed of semiconductive SWNTs(S-SWNTs)with a99%purity(NanoIntegris Inc.)were prepared on a polyethylene-naphthalate(PEN)substrate using the spray method to prepare aflexible SWNT-FET.The S-SWNT suspension was directly sprayed onto the substrate with the781S spray valve systems(Nordson,USA),which have a spray gun moving in the x-axis.During the process,the substrate was kept at808C to accelerate the drying of the mist on the surface.Finally,the sample was rinsed with DI water to remove the surfactant and dried in N2gas.By controlling the spraying conditions such as air pressure, nozzle diameter,and moving speed of nozzle,as well as the number of coated layers and the concentration of the suspension, the density of the S-SWNTfilms could be optimized.Onto the sprayed SWNTs were deposited the source and drain electrodes by conventional photolithography and thermal evaporation of Cr and Au.All SWNTs were removed,except within the channel region,by applying O2plasma treatment.The oxygen plasma process with a power of100W was carried out at300mTorr for10s under the flow of O260sccm.The channel length and width were5m m and 10m m,respectively.An ion gel dielectric layer was prepared using a mixture comprising PS-PMMA-PS triblock copolymer,the1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM][TFSI])ionic liquid,and dichloromethane,prepared in a ratio of3:7:90(wt%/wt%/wt%).The mixed solution was then dropped onto the channel region.Finally,a Ag paste gate electrode was applied to the ion gel dielectric layer.The electrical properties of the FETs were measured using an Agilent E5262A source measurement unit at room temperature.3.Results and discussionFig.1shows photographic and SEM images of the vertically aligned multi-walled CNTs.The dense arrays of VACNTs formed over the entire substrate and often assumed twisted or tangled configurations involving neighboring nanotubes.The synthesized CNTs reached uniform lengths of over5mm,with diameters ranging between30and50nm.The pressure response of the VACNTs was examined using piezoelectric actuators and a strain gauge-type load cell(Kyowa Electric Instruments,LTS-50GA).The pressure response was measured based on changes in the resistance between the top and bottom electrodes of the CNTs in a VACNT block as a function of the mechanical pressure.The area of the pressure-sensitive region was1mm2.The pressure response of the VACNT block is shown in Fig.2.As shown therein,the resistance decreased as the loading pressure was applied.As the pressure approached zero,the resistance nearly retraced itself.The hysteresis behavior of sensor structure in Fig.2is thought that it comes from residual strain of CNT and PDMS after the compression,which has been usually reported in the previous results about compression test of porous structures like PDMS[15,16].Similar characteristic curve were also observed in repeated compression tests.The conductance of the VACNT block could be reproducibly modulated within23%of the resting resistance.The induced pressure built wide contact area among neighboring CNTs and between CNTs and metal electrodes.It produced denser current paths than those observed among the free-standing CNTs at the same density without pressure.This effect increased the conduc-tance of the VACNT block.However PDMS around VACNT block showed highly resistant characteristic to the pressure more than 200kPa,which gave the saturated conductance of sensor partas Fig.1.(a)Photograph of VACNTs on a Si substrate;(b)SEM images of VACNTs.The inset shows a high-magnification image highlighting the CNT alignment.612182430Weight(g)Displacement (µm)Pressure (kPa)Resistance(Ω)Fig.2.Electrical resistance versus pressure for a VACNT block.H.-M.So et al./Materials Research Bulletin48(2013)5036–50395037shown in Fig.2.From these results,it is expected that the pressure sensitivity could be adjusted by controlling the length of the VACNTs and the hardness of the PDMS.We fabricated a SWNT-FET using an ion gel as a gate dielectric layer,and we measured the electrical properties using a semiconductor analyzer at room temperature.As a SWNT field-effect transistor,we prepared a S-SWNT film on a flexible substrate using the spray method.The spray method used in this study facilitated the formation of a uniform deposition layer on the polymer substrate,and the application method could be readily scaled to large area at low temperatures.The high degree of uniformity in the sprayed SWNT networks was critical to achieving high-performance large-scale electronics.The average diameter,length,and density of the sprayed SWNTs on the PEN substrate were 1.8nm,1m m,and 1.7SWNTs/m m 2,respectively.The ion gel gate dielectrics,first introduced by the Frisbie group [17],consisted of a polymer matrix swollen with an ionic liquid.Unlike conventional dielectrics,such as SiO 2,ion gels have a large capacitance that enables transistors to operate at low voltages.The specific capacitance of an ion gel usually ranges from 1to 40m F/cm 2[18,19].The output and transfer characteristics of ion gel-gated SWNT-FETs are shown in Fig.3.The ion gel gated SWNT-FETs exhibited p-type behavior,under a gate voltage below 2V,and on/off current ratios of 103.The field-effect mobility,m FE ,could be estimated using Eq.(1)[20].m FE ¼L 2CV ds dI ds dV g ¼L ln ½2ðh þr Þ=r 2p ee 0V ds dI dsdV g;(1)where L is the channel length,h is the thickness of the ion gel,r isthe SWNT radius,e 0is the permittivity of a vacuum,and e is theI d (µA )Vds (V)I d (µA )Vg (V)(a)(b)Fig.3.Electrical properties of the SWNT-FETs on a PEN substrate.(a)Output characteristics of the device.A top gate voltage between 0V and À1V was applied in À0.25Vsteps.(b)Transfer characteristics of the device.Fig.4.(a)Photograph and (b)schematic diagram of a CNT-based pressure sensor and an SWNT-FET integrated element.(c)Output and (d)transfer characteristics of SWNT-FETs at zero pressure or at a pressure of 170kPa.H.-M.So et al./Materials Research Bulletin 48(2013)5036–50395038dielectric constant of the embedding ion gel(e=12)[21].The estimatedfield effect mobility was98cm2/V s at a bias voltage of V ds=0.5V.We fabricated aflexible pressure-sensor device by connecting a VACNT block device to a SWNT-FET,as shown in Fig.4.The VACNT block was connected to the drain electrode of the SWNT-FET. Under an external pressure,the conductance of the VACNT block changed,which modulated the SWNT-FET characteristics.The gate and drain bias of a FET could potentially be used for the addressing of word and bit lines in the context of a sensor array matrix.The integrated sensor and transistor could potentially employ active-matrix circuitry,which is advantageous over passive-matrix circuitry in that it maintains its state unless an active switching device induces a change.Typical changes in the drain current in response to changes in the voltage induced by an applied pressure are shown in Fig.4(c,d).A maximum pressure of170kPa,applied to the CNT block,increased the source-drain current I ds of the SWNT-FETs.This increased conductance arose from the conduc-tance change exhibited by the VACNT block under the applied pressure.Despite the small change in resistance of CNT block under pressure,the source-drain current of the SWNT-FET increased greatly.The increase is caused by the conductance change of the CNT block as well as by the resistance change at the interface between metal and CNTs during locally applied pressure.In our device,the VACNT block effectively served as a variable resistor in series with the SWNT-FET.The performance of a SWNT-FET used in this work showed the possibility of the low-power,active-matrix backplane of theflexible pressure-sensor application.4.ConclusionsIn conclusion,we fabricated a pressure sensor based onflexible VACNTs embedded in a support matrix and connected to a SWNT-FET.The pressure on the VACNT block produced an increase in the conductance of the CNTs because the VACNTs formed better contacts among the neighboring CNTs,which formed denser current paths and better CNT/metal contacts under pressure.In an integrated device,the VACNT pressure sensor and SWNT-FET yielded an increase in the source-drain current I ds of the SWNT-FET under pressure.The CNT block used for pressure sensing may be reduced in size and fabricated in an array in order to prepare an active matrix system that can mimic the tactile sensing functions of a human epidermal system.The active channel materials described in here,which display a high on/off ratio and a low operation voltage,may improve the performance of an integrated sensor system.AcknowledgementsThis work was partially supported by a grant(Code No.2011-0032064)from the Center for Advanced Soft Electronics under the Global Frontier Program,and a grant-in-aid for Nano Material Technology Development Program(Green Nano Technology Development Program)through the National Research Foundation of Korea(NRF)funded by the Ministry of Education,Science and Technology.References[1]J.A.Rogers,T.Someya,Y.Huang,Science327(2010)1603–1607.[2]J.J.Boland,Nat.Mater.9(2010)790–792.[3]M.Ramuz,B.C.-K.Tee,J.B.-H.Tok,Z.Bao,Adv.Mater.24(2012)3223–3227.[4]D.J.Lipomi,M.Vosqueritchian,B.C.-K.Tee,S.L.Hellstrom,J.A.Lee,C.H.Fox,Z.Bao,Nat.Nanotechnol.6(2011)788–792.[5]S.C.B.Mannsfeld,B.C.-K.Tee,R.M.Stoltenberg,C.V.H.-H.Chen,S.Barman,B.V.O.Muir,A.N.Sokolov,C.Reese,Z.Bao,Nat.Mater.9(2010)859–864.[6]C.Pang,G.-Y.Lee,T.-i.Kim,S.M.Kim,H.N.Kim,S.-H.Ahn,K.-Y.Suh,Nat.Mater.11(2012)795–801.[7]E.T.Thostensona,Z.Renb,T.-W.Chou,Compos.Sci.Technol.61(2001)1899–1912.[8]M.R.Falvo,G.J.Clary,R.M.Taylor II,V.Chi,F.P.Brooks Jr.,S.Washburn,R.Superfine,Nature389(1997)582–584.[9]J.F.Despres,E.Deguerre,fdi,Carbon33(1995)87–89.[10]M.M.J.Treacy,T.W.Ebbesen,J.M.Gibson,Nature381(1996)678–680.[11]N.G.Chopra,L.X.Benedic,V.H.Crespi,M.L.Cohen,S.G.Louie,A.Zettle,Nature377(1995)135–138.[12]A.Cao,P.L.Dickrell,W.G.Sawyer,M.N.Ghasemi-Nejhad,P.M.Ajayan,Science310(2005)1307–1310.[13]V.L.Pushparaj,L.Ci,S.Sreekala,A.Kumar,S.Kesapragada,D.Gall,O.Nalamasu,P.M.Ajayan,J.Suhr,Appl.Phys.Lett.91(2007)153116.[14]H.Kim,C.Lee,J.Choi,K.Y.Chun,Y.Kim,S.Baik,J.Kor.Phys.Soc.54(2009)1006–1010.[15]P.Slobodian,P.Riha,A.Lengalova,P.Saha,J.Mater.Sci.46(2011)3186–3190.[16]R.L.D.Whitby,S.V.Mikhalovsky,V.M.Gun’ko,Carbon48(2010)145–152.[17]J.Lee,M.J.Panzer,Y.He,T.P.Lodge,C.D.Frisbie,J.Am.Chem.Soc.129(2007)4532–4533.[18]J.Lee,L.G.Kaake,J.H.Cho,X.Y.Zhu,T.P.Lodge,C.D.Frisbie,J.Phys.Chem.C113(2009)8972–8981.[19]J.H.Cho,J.Lee,Y.Xia,B.S.Kim,T.P.Lodge,C.D.Frisbie,Nat.Mater.7(2008)900–906.[20]R.Martel,T.Schmidt,H.R.Shea,T.Hertel,Ph.Avouris,Appl.Phys.Lett.73(1998)2447–2449.[21]I.Krossing,J.M.Slattery,C.Daguenet,P.J.Dyson,A.Oleinikova,H.Weinga¨rtner,J.Am.Chem.Soc.128(2006)13427–13434.H.-M.So et al./Materials Research Bulletin48(2013)5036–50395039。

A Tunable Carbon NanotubeOscillator

A Tunable Carbon NanotubeOscillator

• Good sensitivity requires
– Small m, High ω, High Q, Tunable
2005/05/31
一維奈米材料之成長及分析
Introduction
• Carbon nanotube
High Young’s modulus →high frequency No surface states → possibly high Q Low active mass → good mass sensitivity Active electronic material → detects its own motion – Defect-free – Ultrasmall cross-sections – – – –
2005/05/31
一維奈米材料之成長及分析
Possible Sources of Low Quality Factor
1 • Air drag Q ∝ pressure • Ohmic losses
Estimated to be negligible:
Qohmic
kδ z = 2 τ oscil I induced R
• AC gate voltage
– sets NT into motion when ω = ω0
一維奈米材料之成長及分析
2005/05/31
– induce the charge on the NT q = CgVg – controls tension
Measurements
VgDC = 2.2V, δVg = 7mV, δVsd = 7mV
2005/05/31 一維奈米材料之成長及分析
Nonlinear Regime

Materials Science of Carbon Nanotubes

Materials Science of Carbon Nanotubes

Materials Science of Carbon NanotubesCarbon nanotubes (CNTs) are cylindrical structures made of carbon atoms that are around a nanometer in diameter and several micrometers in length. With their unique properties, CNTs have emerged as an exciting material in the field of materials science. They possess excellent mechanical, electrical, and thermal properties, which make them an ideal candidate for various applications.Mechanical PropertiesCNTs are extremely strong and stiff, much stronger than most materials known today. This is attributed to the high tensile strength of carbon-carbon bonds in the tube structure. The Young's modulus of single-walled carbon nanotubes (SWCNTs) is estimated to be around 1 TPa, which is more than 100 times higher than that of steel.Moreover, CNTs have high flexibility due to their tube structure, giving them the ability to withstand bending without breaking. This property makes CNTs an ideal candidate for making nanocomposites, which can enhance the mechanical properties of other materials.Electrical PropertiesDue to their unique atomic structure, CNTs possess excellent electrical conductivity. The conductivity of a metallic SWCNT is comparable to that of copper, while that of a semiconductor SWCNT is similar to that of silicon.Furthermore, the electrical properties of CNTs can be precisely controlled by modifying their diameter, chirality, and doping. The small size of CNTs also makes them a promising material for the development of nanoelectronics, where miniaturization is crucial for device performance.Thermal PropertiesCNTs also exhibit excellent thermal conductivity, which is attributed to their one-dimensional structure, low defects, and high aspect ratio. The thermal conductivity ofCNTs can be as high as 6000 W/mK, which is higher than that of any other material known today.Moreover, the thermal conductivity of CNTs is direction-dependent, with the highest thermal conductivity observed along the tube axis. This property makes CNTs an ideal candidate for applications in thermal management, such as heat spreaders, sensors, and energy conversion devices.ApplicationsCNTs have potential applications in many fields, including nanoelectronics, energy storage, aerospace, and biomedicine. In nanoelectronics, CNTs can be integrated into transistors, interconnects, and sensors to develop high-performance devices with low power consumption. In energy storage, CNTs can be used as electrodes in supercapacitors and batteries to enhance their energy density and power density.In the aerospace industry, CNTs can be incorporated into composites to enhance the mechanical and thermal properties of materials, making them suitable for high-performance applications. In biomedicine, CNTs can be used for drug delivery, imaging, and tissue engineering, thanks to their biocompatibility and small size.ConclusionIn conclusion, carbon nanotubes are a unique material with excellent properties that make them ideal for numerous applications in various fields. The versatility of CNTs can be attributed to their mechanical, electrical, and thermal properties, which can be precisely controlled by modifying their atomic structure. With ongoing research and development, CNTs are expected to continue to drive innovation in materials science and various other fields.。

碳纳米管@碳化硅同轴异质结纳米管非金属光催化剂产氢性能

碳纳米管@碳化硅同轴异质结纳米管非金属光催化剂产氢性能

Chinese Journal of Catalysis 41 (2020) 62–71催化学报 2020年 第41卷 第1期 | available at journal homepage: /locate/chnjcArticle (Special Issue on Photocatalytic H2 Production and CO2 Reduction)Carbon nanotube@silicon carbide coaxial heterojunction nanotubes as metal-free photocatalysts for enhanced hydrogen evolutionXunfu Zhou, Qiongzhi Gao, Siyuan Yang *, Yueping Fang #College of Materials and Energy, South China Agricultural University, Guangzhou 510642, Guangdong, ChinaARTICLE INFOArticle history: Received 29 April 2019 Accepted 3 June 2019 Published 5 January 2020Keywords: Silicon carbide Coaxial core-shell nanotubes Nanoheterostructures Charge separation Hydrogen evolutionABSTRACTConsiderable research efforts have been devoted to developing novel photocatalysts with increased performances by hybridizing inorganic nanomaterials with carbon nanotubes. In this work, one-dimensional coaxial core-shell carbon nanotubes@SiC nanotubes were successfully synthesized via in situ growth of SiC coatings on carbon nanotubes by a vapor-solid reaction between silicon vapor and carbon nanotubes. High-resolution transmission electron microscope images show that SiC and carbon nanotubes link to form a robust heterojunction with intrinsic atomic contact, which results in efficient separation of the photogenerated electron-hole pairs on SiC and electron transfer from SiC to carbon nanotubes. Compared with those of similar materials such as pure SiC nanocrystals and SiC nanotubes, the metal-free carbon nanotubes@SiC exhibits an enhanced photocatalytic activity for hydrogen evolution, which is attributed to the enhanced light absorption and the efficient interfacial charge transfer/separation brought about by their one-dimensional coaxial nanoheterostructures. Moreover, the photocatalytic stability of the metal-free carbon nanotubes@SiC was tested for over 20 h without any obvious decay.© 2020, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.1. IntroductionThere is a growing need to develop sustainable “green” energy sources for replacing the classical fossil fuels for protecting our natural environment and alleviating the problem of global energy crisis [1]. Hydrogen (H2), with its high energy capacity and environmental friendliness, is a source of clean energy that is generated from renewable sources such as solar [2,3]. Notably, photocatalytic (PC) H2 generation through water splitting has received tremendous attention in recent decades [4]. However, many conventional PC materials (namely, metal sulphides and (oxy) nitrides such as TiO2, Zn0.8Cd0.2S, Cu2O, WO3, Ga2O3, g-C3N4, ZnIn2S4, CdS, and ZnS) cannot satisfy the requirements of low toxicity, low cost, high stability, and re-markable PC activity for practical applications [5–13]. In this context, the development of new photocatalysts, micro/nano structure engineering, and surface/interface engineering of heterogeneous semiconductors by optimizing suitable material combinations has been identified as a viable approach to improving the H2 production rates of functional compounds [14–21]. Hybridization of semiconductor photocatalysts with carbon nanotubes (CNTs) affords a powerful strategy of designing advanced PC materials [22,23]. Particularly, incorporation of CNTs into heterogeneous photocatalysts can offer potential advantages in terms of improved PC performances. On one hand, the one-dimensional (1-D) conductive channels of CNTs provide pathways for rapid electron transfer, which decrease the recombination of the photoinduced electron-hole* Corresponding author. E-mail: siyuan_yang@ # Corresponding author. E-mail: ypfang@ This research was supported by the National Natural Science Foundation of China (21673083, 21802046). The authors thank the Guangdong Provincial Science and Technology Project (2017A030313090, 2014A030310427). DOI: S1872-2067(19)63421-2 | /science/journal/18722067 | Chin. J. Catal., Vol. 41, No. 1, January 2020Xunfu Zhou et al. / Chinese Journal of Catalysis 41 (2020) 62–7163pairs [24]. On the other hand, CNTs with an elaborated 1-D morphology could serve as good templates to induce the growth of semiconductors with 1-D nanostructures [25,26] and core-shell architectures [27,28] that display enhanced charge transport and improved PC efficiency. Indeed, previous studies focusing on the coupling of CNTs and TiO2 have documented prominent improvements in the PC performance of the hybrid over those of the individual constituents [29–31]. For example, the activity of core-shell CNTs/TiO2 nanocomposites for the PC degradation of methylene blue increased 2-3 times upon hybridization with ~16 wt% of CNTs [32]. This considerable enhancement is attributed to the uniform coating of nanocrystal TiO2 onto CNTs to form a core-shell structure with high-quality interfacial contacts between CNTs and TiO2, which largely facilitate the separation of the electron-hole pairs and lead to a better PC performance. Furthermore, micro/nanocomposites that combine CNTs with other commonly used PC materials such as ZnO [33], ZnS [34], CdS [35], WO3 [36], and C3N4 [37], have also been demonstrated as hybrids that reveal enhanced PC performances through similar mechanisms.It is well known that β-SiC (cubic phase silicon carbide) is a potential photocatalyst that exhibits an appropriate band gap (Eg = 2.4 eV, ECB = −0.9 V vs. NHE at room temperature) for PC H2 generation [38]. Until now, there has been limited research on SiC photocatalysts. The main reason for this is the rapid recombination of the photoinduced electron-hole pairs in SiC photocatalysts [39,40]. Therefore, various engineering strategies, including the formation of unique SiC nanostructures (e.g., quantum dots [41], nanoparticles [42], nanowires [43], and hollow spheres[44]), construction of heterostructures (e.g., SiC-TiO2 [45], SiC-ZnS [46], SiC-MoS2 [47], SnO2-SiC [48,49], and SiC-CdS [50]), hybridization of SiC with metal co-catalysts (e.g., SiC-Pt [43], SiC-IrO2 [51]), and nanocarbon materials (e.g., SiC-graphene [52,53]), have been employed to promote the performance and durability of SiC photocatalysts since the initial research on water splitting in 1990 [54]. Further investigations show that the SiC-graphene nanoheterojunction with intimate interfacial contacts between SiC and graphene exhibits enhanced photoactivities for water splitting owing to the improved charge separation resulting from the formation of Schottky-junction interfaces [55]. In our previous studies, we have demonstrated that the well-designed CNTs/SiC nanowire nanoheterostructures exhibit enhanced PC activity, compared with that of individual SiC nanowires [56]. Owing to vapor-liquid-solid catalytic growth, the CNTs/SiC nanoheterostructures are composed of straight SiC nanowires and crooked CNTs. In the present work, we demonstrate that CNTs can be uniformly covered with SiC nanoshells to form coaxial CNT@SiC core-shell nanotubes (C@SiCNTs) via an in situ vapor-solid reaction between silicon vapor and CNTs. Owing to the rational coaxial core-shell structure with tight Schottky junctions between CNTs and SiC, both the interfacial coupling and charge separation of C@SiCNT nanoheterostructures can be greatly improved. As a result, the metal-free C@SiCNTs exhibits significantly improved performance in PC generation of H2 from pure water. The enhanced mechanisms of PC H2 generation over C@SiCNTs are discussed in detail.2. Experimental2.1. Material synthesisSodium sulphide, hydrofluoric acid, sulfuric acid, and nitric acid were supplied by Sinopharm Chemical Reagent Co., Ltd. Micro-grade silicon powder (40–200 mesh) was provided by Aladdin. Multi-walled carbon nanotubes (CNTs; length, 5–15 µm; specific surface area, 40–70 m2 g–1; diameter, 60–100 nm; purity, >97%) were purchased from Shenzhen Nanotech Port Co., Ltd.In a typical process, the CNTs were first purified with a mixed concentrated H2SO4/HNO3 solution (volume ratio, 3:1) at room temperature. Then, 0.6 g of the acid-purified CNTs and excess silicon powder were mixed and placed inside a horizontal furnace. Subsequently, the furnace was heated to 1320 °C. Simultaneously, argon gas was made to flow at 250 mL/min at one end of the tubular furnace. The temperature was kept at 1320 °C for 2 h. Subsequently, the sample was cooled and washed with a mixed HF/HNO3 diluted (aqueous) solution. Finally, the obtained C@SiCNT nanoheterostructures sample was filtered and dried for further use.The SiCNTs were obtained by increasing the reaction time to 4 h and keeping the other parameters unchanged, so that the carbon nanotubes were almost completely consumed.Reference SiC nanocrystals were synthesized by annealing the C@SiCNTs at 750 °C in air for 2 h, which consumed the CNTs by oxidation.2.2. CharacterizationThe crystalline structures of the specimens were characterized by X-ray diffraction (XRD) (Rigaku, Cu Kα radiation, λ = 0.15418 nm) in the scanning range 10°–80°. The N2 adsorption-desorption isotherm was determined at 77 K by using a surface area analyzer (Micromeritics Co., Gemini-2360). Then, Brunauer-Emmett-Teller (BET) method was used to determine the specific surface areas. X-ray photoelectron spectroscopy (XPS) was carried out with a VGESCALAB250 surface analysis system. The morphologies, structures, and elemental distributions of the products were examined by a scanning electron microscopy (SEM) (FEI Quanta 200 FEG) and a high-resolution transmission electron microscopy (TEM) (FEI Glacios Cryo-TEM, acceleration voltage: 200 kV). The carbon content was analyzed by a thermogravimetric analyzer under air flow. The UV-vis diffuse reflectance spectra were recorded by using a spectrophotometer (Shimadzu, model 2501 PC). The photoluminescence (PL) spectra were obtained with the help of a PerkinElmer fluorescence spectrophotometer at the excitation wavelength of 290 nm. The transient PL spectra were recorded by a fluorescence lifetime spectrophotometer (Edinburgh Instruments, UK FLS920) at the excitation wavelength of 290 nm.2.3. Photoelectrochemical measurements80 µL of 0.5 wt% Nafion solution and 10 mg of the photocatalyst powders were added to 2.0 ml ethanol, and then, ul-64Xunfu Zhou et al. / Chinese Journal of Catalysis 41 (2020) 62–71trasonic treatment was performed for 30 min to obtain a sus-pension. Then, 400 µL of the suspension was dropped onto a 3× 2 cm2 FTO glass substrate. Subsequently, the FTO glass sub-strate was dried and annealed at 150 °C for 1 h in argon flow.The transient photocurrent properties of the sample at 0.2 Vbias were measured by an electrochemical analyzer by using athree-electrode system. A platinum electrode and the Ag/AgClelectrode (with saturated KCl) were used as the counter elec-trode and reference electrode, respectively. The light sourcewas a 300 W Xe lamp (with AM 1.5 simulated sunlight cut-offfilter). The electrolyte was 0.5 mol/L Na2SO4 solution. TheMott-Schottky plots were recorded at an ac amplitude of 5 mVwith a frequency of 1000 Hz under dark condition. The elec-trochemical impedance spectra of the samples were obtainedunder the condition that the ac amplitude was 5 mV and thefrequency range 0.01–105 Hz.Electrocatalytic H2 evolution was also carried out by usingthe three-electrode cell. The polarization curves were recordedat 5 mV s–1 scan rate. To convert the measured potentials (ver-sus Ag/AgCl) to the RHE scale, Eq. (1) was employed.ERHE = EAgCl + 0.059pH+EA0 gCl(EA0 gCl = 0.197V)(1)2.4. PC water splittingA 300 W Xe lamp equipped with a simulated sunlight cut-offfilter (AM 1.5) was used as the light source. The PC H2 evolutionwas observed in a 200 mL Pyrex flask (three-necked,flat-bottom) at room temperature and pressure. The flask wassealed with a silicon rubber ring. The distance from the reactorto the light source was 20 cm. In a typical PC H2 evolution ex-periment, 15 mg of the photocatalyst was added to 100 mL ofaqueous Na2S (0.1 mol/L) solution, then ultrasonic treatmentwas carried out for 30 min to form a suspension in the flaskreactor. Nitrogen was bubbled into the suspension for 30 minto remove oxygen. 400 µL of the gas was extracted and ana-lyzed by using a gas chromatograph (GC-7900, TCD, argon at-mosphere) after 1 h of irradiation.A cyclic experiment was carried out to determine the PCstability of C@SiCNTs. After 5 h of irradiation, the H2 producedwas substituted by N2, which was followed by another 5 h ofirradiation. According to the practical H2 generation under 420nm illumination, the apparent quantum efficiencies (AQEs)were calculated to determine the solar energy conversion abili-ties of C@SiCNTs, SiCNTs, and the reference SiC by using thefollowing equation [57].AQE =2 × NH2(S-1· cm-2) Pλ(mW· cm-2) ÷ Eλ (mW·s-1)×100%(2)where NH2 is the number of molecules of H2 produced, λ isthe wavelength of the irradiated monochromatic light, Eλ and Pλare the average photon energy and the light intensity per unitarea corresponding to λ, respectively.3. Results and discussion3.1. Structure and composition of the photocatalystsThe fabrication of C@SiCNTs is illustrated in Scheme 1. Sili-Scheme 1. Fabrication of C@SiCNT hybrids and SiCNTs.con powder and CNTs were grinded together and placed insidea horizontal furnace. Then, the furnace was heated to 1320 °Cin argon atmosphere because the sublimation temperature andmelting point of the silicon powder are 1127 and 1420 °C, re-spectively. The formation of SiC shells on the CNTs involved avapor-solid reaction between the solid CNTs and the siliconvapor (Eq. (3)) [55]:Si(g) + C(s) = SiC(s)(3)After the in situ vapor-solid reaction between CNTs and sil-icon vapor for 2 h, C@SiCNTs were obtained. When the va-por-solid reaction time increased to 4 h, almost all the CNTswere consumed completely by the silicon vapor and convertedto SiC, then, SiCNTs were obtained. If the furnace was heated to1500 °C, micron SiC crystal of large particles was obtained.Because the synthesis temperature is higher than the meltingpoint of silicon, the reaction between silicon and carbonchanges from a vapor-solid reaction to a liquid-solid reaction.This phenomenon was observed and discussed in detail in ourprevious report [48]. Therefore, C@SiCNTs can only be formedwith the right combination of reaction conditions. The refer-ence SiC was obtained by annealing the C@SiCNTs at 750 °C for4 h in air. The obtained specimens were characterized by XRD,and the patterns are presented in Fig. 1(a). It is observed thatthe original CNTs exhibit hexagonal structure, and the spacegroup is P63/mmc (JCPDS PDF no. 41-1487). The diffractionpeak angles of 26.2°, 42.8°, and 44.6° correspond to the (002),(100), and (101) lattice planes of CNTs, respectively. After thereaction with silicon vapor for 2 h, the diffraction peaks at 42.8°and 44.6° disappeared, due to the formation of the SiC coatingon the CNTs. On the other hand, diffraction peaks at 35.4°,41.2°, 59.8°, 71.6°, and 75.4°, corresponding to the (111), (200),(220), (311), and (222) lattice planes of β-SiC (JCPDS PDF no.29-1129), respectively, can be found in the C@SiCNTs. Further,a diffraction peak at 26.2°, indexed to the (002) reflections ofCNTs, can also be observed in the XRD pattern of C@SiCNTs.The low intensity diffraction peak at 33.6° corresponds to thestacking faults of SiC. It is confirmed that the as-preparedC@SiCNTs are composed of CNTs and β-SiC [58]. Upon in-creasing the reaction time to 4 h, CNTs were almost completelytransformed to β-SiC in situ, so that only the diffraction peaksof β-SiC are observed in the XRD pattern of SiCNTs. Similarly,the reference SiC nanocrystals are composed of pure β-SiC.The SiC contents of the as-prepared samples were deter-mined by thermogravimetric analysis (Fig. 1(b)). The massfraction of SiC in C@SiCNTs is about 70.5 wt%. It is found thatSiCNTs and SiC are stable (up to 900 °C in air), since no re-markable weight losses (2.0% for SiCNTs and 1.5% for the ref-Xunfu Zhou et al. / Chinese Journal of Catalysis 41 (2020) 62–7165Fig. 1. Powder XRD patterns (a), TGA profiles (b), N2 adsorption and desorption isotherms (c) and the corresponding pore size distribution curves (d) of as prepared samples.erence SiC) are observed in this temperature range. The textural properties of the C@SiCNTs, SiCNTs, and ref-erence SiC samples are revealed in Fig. 1(c); obviously, all the specimens exhibit type III adsorption-desorption isotherms with type H3 hysteretic loops, which indicate the presence of mesopores connected by macropores in the samples [59]. Moreover, the isotherms reveal mass absorption in the high relative pressure zone (inset in Fig. 1(c)), which indicates the presence of large mesopores, which are observed in Fig. 1(d). As presented in Table 1, the BET surface areas of C@SiCNTs (62.57 m2 g–1) and SiCNTs (55.66 m2 g–1) are about 3.4 and 3.0 times that of the reference SiC (18.56 m2 g–1), respectively, which further suggest that C@SiCNTs and SiCNTs are topologically transformed from acid-purified CNTs (specific surface area, 40–70 m2 g–1; diameter, 60–100 nm). More interestingly, the mean pore diameters of C@SiCNTs (39.52 nm) and SiCNTs (32.94 nm) are smaller than that of CNTs (60–100 nm), which maybe correspond to the inner diameter of the CNTs. On the contrary, the mean pore diameter of the reference SiC (60.61 nm) is greater than that of the CNTs, which is because of the presence of slit-like pores that originated from the aggregation of particles. Such a nanostructure can significantly enhance the PC activity, because it provides open pores for guest molecules and also improves the light absorption through multiple scattering effects [60].To gain further insight into the surface compositions of the catalysts, XPS was employed. The high-resolution Si 2p spectrum (Fig. 2(a)) of C@SiCNTs can be deconvoluted into two peaks corresponding to the Si-C bonds (101.18 eV) of CNTs and Si–O bonds (102.03 eV) of SiOx. The deconvoluted C 1s spectrum (Fig. 2(b)) of the C@SiCNTs shows two peaks at the bind-Table 1 Textural properties of C@SiCNTs, SiCNTs, and the reference SiC.PhotocatalystC@SiCNTs SiCNTs Reference SiCBET surface area (m2 g–1)62.57 55.66 18.56Mean pore diameter (nm)39.52 32.94 60.61Pore volume (cm3 g–1)0.37 0.34 0.16Fig. 2. Si 2p and C 1s XPS spectra of C@SiCNTs (a, b) and SiCNTs (c, d).ing energies of 284.72 eV and 283.31 eV, which are indexed to the C–C bonds of CNTs and the C–Si bonds of SiC, respectively [61]. In addition, the deconvoluted Si 2p spectrum (Fig. 2(c)) of the SiCNTs reveals two peaks at 101.34 and 102.22 eV, which correspond to the Si–C bonds of SiC and the Si–O bonds of SiOx, respectively. The deconvoluted C 1s spectrum (Fig. 2(d)) of the SiCNTs displays two peaks at the binding energies of 284.70 and 283.44 eV, which are indexed to the C–C bonds of CNTs and the C–Si bonds of SiC, respectively. Notably, the peak intensity of the C–C bonds of SiCNTs is much lower than that of the C–C bonds of C@SiCNTs, which indicates a low content of carbon in the SiCNTs. The atomic fractions of silicon, carbon, and oxygen in the C@SiCNTs are 29.35%, 65.62%, and 5.03%, respectively. Similarly, the atomic fractions of silicon, carbon, and oxygen in the SiCNTs are 45.54%, 49.01%, and 5.45%, respectively. Calculated from the atomic fractions, the mass fraction of SiC in the C@SiCNTs is about 72.5 wt%, which is close to the results of thermogravimetric analysis (Fig. 1(b)). In addition, the mass fraction of SiC in the SiCNTs is about 96.2 wt%, which suggests that 3.8 wt% of the CNTs in the SiCNTs that are coated by SiC cannot be consumed by the silicon vapor.As presented in Fig. 3(a), the acid-purified CNTs display diameters of 60–100 nm, a smooth surface, and a crooked morphology. Comparing the morphologies of the acid-purified CNTs and the C@SiCNTs (Fig. 3(b)), it is interesting to note that the 1-D nanotube structures are still maintained. It indicates that CNTs with suitable acid-purification maintain their nanotube structures during ultrahigh-temperature sintering. In addition, the surfaces of C@SiCNTs are rougher than those of CNTs, because of the coating of SiC on the surfaces of CNTs. Furthermore, the lengths of the C@SiCNTs and SiCNTs nanotubes decrease slightly, compared with that of the CNTs. No SiC nanowires are observed in the C@SiCNTs and SiCNTs. On the other hand, the reference SiC sample consists of nanorods and nanoparticles (Fig. 3(d)).A perfect heterojunction interface with robust intrinsic contact in the C@SiCNTs was examined by using TEM and HRTEM. As presented in Fig. 4(a), the C@SiCNTs show a nanotube constructure with a rough surface, which is consistent66Xunfu Zhou et al. / Chinese Journal of Catalysis 41 (2020) 62–71Fig. 3. SEM images of acid-purified CNTs (a), C@SiCNTs (b), SiCNTs (c) and referenced SiC (d), respectively.with the SEM image (Fig. 3(b)), as discussed previously. For further investigation, the distributions of carbon and silicon elements are uniform, and the shapes are the same as the morphology of the C@SiCNTs. Compared to that of elemental carbon, the distribution shape of Si element is shrinked, which indicates that the SiC coating on the CNTs have formed a coaxial core-shell nanotube structure. This is further confirmed from the HRTEM image (Fig. 4(b)), in which the C@SiCNTs show two crystal lattice spacings of ca. 0.25 and 0.34 nm, which are indexed to the (111) planes of β-SiC and the (002) planes of CNTs, respectively. Obviously, the SiC (111) planes and the CNT (002) planes connect together to form an excellent heterojunction with intrinsic atomic contact (inset in Fig. 4(b)). In addition, the HRTEM image shows that the (002) planes of CNTs are covered by the (111) planes of SiC, which suggests the formation of a coaxial core-shell nanotube structure. As a result, rapid electron transfer from SiC to CNTs and electron-hole separation on the SiC shell will be realized, which is significant for improving the PC H2 evolution.3.2. Optical properties and photoelectricities of the photocatalystsThe UV-vis diffuse reflectance spectra of the samples wererecorded by using a spectrophotometer. As shown in Fig. 5(a), it is clear that the three specimens exhibit an absorption band in the range 200–800 nm. Furthermore, it is also seen that the absorption band of the C@SiCNTs nanocomposites is stronger than those of the SiCNTs and the reference SiC, which indicates better light response in the case of the C@SiCNTs, which is beneficial for the improvement of the PC activity. In addition, the band gap energies (Eg) of the SiC hybrids were calculated by the Kubelka-Munk method based on the tangent lines of (αhν)1/2 versus hν plots, where hν is the photon energy and α is the absorption coefficient [62]. As shown in Fig. 5(b), the Eg values of the C@SiCNTs, SiCNTs, and reference SiC are estimated to be 2.42, 2.64, and 2.72 eV, respectively. Obviously, the CNTs are incorporated into the SiC nanotubes, thus playing a powerful role in reducing the Eg of bulk SiC through a chemical interaction between SiC and CNTs. This phenomenon is similar to the result obtained in the case of ZnO-CNT composite materials [63]. In conclusion, narrowing the Eg is beneficial for improving the PC activity.The photogenerated carrier transition behaviors of the samples were further investigated based on the PL spectra. In general, a lower PL signal strength indicates better charge capture and more efficient transport [64,65]. As shown in Fig. 5(c), the reference SiC reveals a strong emission peak at 468 nm. Simultaneously, a clear fluorescence decay is seen for the C@SiCNTs sample, which indicates efficient charge separation between SiC and CNTs in the C@SiCNTs. Particularly, the emission peak intensity of the SiCNTs is lower than that of the reference SiC, because the 1-D nanotube structures permit efficient electron transfer [66]. These results suggest that coating SiC onto the surfaces of CNTs and 1-D nanotubes can distinctly promote the separation and transfer of the photogenerated charge carriers.The transient photocurrent responses of the three samples were measured for several simulated sunlight (AM 1.5) on-off cycles to demonstrate the enhanced separation of the photogenerated charge carriers. The C@SiCNTs exhibit a higher photocurrent density than the reference SiC (Fig. 5(d)), whichFig. 4. TEM (a) and HRTEM (b) images of C@SiCNTs and the corresponding elemental Si and C mapping.Fig. 5. UV-visible absorption spectra (a), Tauc plots (b), photoluminescence spectra (c) and transient photocurrent responses curves (d) of C@SiCNTs, SiCNTs and referenced SiC.Xunfu Zhou et al. / Chinese Journal of Catalysis 41 (2020) 62–7167indicates efficient charge separation after the hybridization of SiC with CNTs. Therefore, more electrons can be photoexcited and used to yield H2. In detail, the photocurrent density of the C@SiCNTs (about 1.3 µA cm–2) is 8.7 and 3.7 times higher than those of the reference SiC (about 0.15 µA cm–2) and the SiCNTs (about 0.35 µA cm–2), respectively. Understandably, the higher the photocurrent, the greater is the number of photogenerated electrons that can be transferred from the collected product to the counter electrode when a bias is applied [67]. Fluorescence lifetime measurements were carried out to reveal the separation of the photogenerated charge carriers, As seen in the transient PL spectrum (Fig. 6), the C@SiCNTs exhibit a slower exponential decay, with an average lifetime of 6.66 ns, which is 2.46 and 1.42 times longer than those of the reference SiC (2.70 ns) and the SiCNTs (4.69 ns), respectively. The increased exciton lifetime of the C@SiCNTs suggests that the photocarrier is more likely to be involved in surface redox reactions, which is conducive to improving the PC performance.3.3. PC activities of the photocatalystsThe PC H2 evolutions of the C@SiCNTs, SiCNTs, and reference SiC were measured under simulated sunlight irradiation (AM 1.5) in an aqueous Na2S solution (0.10 mol L–1). The total amount of H2 evolved increases linearly with the irradiation time during the PC reactions over all the samples (Fig. 7(a)), which suggests that all the samples display good photostability under simulated sunlight irradiation. The total H2 productions after 5 h of irradiation for the C@SiCNTs, SiCNTs, and reference SiC are 592.6, 302.8, and 105.3 µmol g–1, respectively.The average H2 evolution rates over the three samples after 5 h of irradiation were estimated, and the values are displayed in Fig. 7(b). The H2 production rate of the C@SiCNTs (118.5 µmol g–1 h–1) is about 5.62 and 1.95 times those of the reference SiC (21.1 µmol g–1 h–1) and the SiCNTs (60.6 µmol g–1 h–1) under simulated sunlight irradiation, respectively. A summary of the previously reported SiC/carbon-based photocatalysts is presented in Table 2. Even though the activity obtained here (118.5 µmol g–1 h–1) is lower than those of graphene-covered SiC/Pt [68], SiC-covered graphene [55], and SiC/carbon nanofibers[61], it is better than those of other SiC/carbon-based photocatalysts such as GO/SiC [53], SiC-graphene [52], and MWCNTs/SiC nanowires, which suggests an excellent synergetic effect between the CNT cores and the SiC shells.Fig. 7. The total amount of H2 produced by the C@SiCNTs, SiCNTs and referenced SiC photocatalysis under AM 1.5 simulated sunlight irradiation (a) and their corresponding average hydrogen production rates (b) the repeated runs of PC H2 evolution using the C@SiCNT heterostructures(c), the total amount of H2 produced for the C@SiCNTs in pure water without any sacrificial reagent under AM 1.5 simulated sunlight irradiation (d), the XRD patterns (e) and SEM image (f) of the C@SiCNTs after cyclic experiments.In addition, the stability of the C@SiCNTs in PC H2 evolution was investigated by cyclic experiments. As displayed in Fig. 7(c), after four repeated runs, no remarkable decay in the H2 evolution is observed after the PC reaction for 20 h under simulated sunlight irradiation. It is further demonstrated that the C@SiCNTs photocatalyst also exhibits excellent stability during PC H2 production. To further confirm the good stability of the C@SiCNTs photocatalyst, the structural morphology of the C@SiCNTs was characterized after the cyclic experiments. The XRD pattern and SEM image of the C@SiCNTs obtained after the cyclic experiments are shown in Fig. 7(e) and Fig. 7(f), respectively. As can be seen, there is no obvious change in the structure and morphology of the C@SiCNTs after the cyclic experiments.In order to clarify that the photogenerated holes were consumed by Na2S, the PC H2 evolution over the C@SiCNTs was investigated in pure under simulated sunlight irradiation. The total amount (Fig. 7(d)) of H2 produced increases linearly. The average H2 evolution rate over the C@SiCNTs after 5 h irradiation is 5.3 µmol g–1 h–1. The results confirmed that the H2 production rate of C@SiCNTs in a Na2S solution is higher than that in pure water under simulated sunlight irradiation, since the recombination of the photogenerated charge carriers is remarkably suppressed.Fig. 6. Transient PL spectra of C@SiCNTs, SiCNTs and referenced SiC.3.4. Discussion of the mechanism。

锂离子电池碳纳米管复合负极材料的进展_符冬菊

锂离子电池碳纳米管复合负极材料的进展_符冬菊

第43卷第4期2013年8月电池BATTERY BIMONTHLY Vol.43,No.4Aug.,2013作者简介:符冬菊(1977-),女,山西人,深圳清华大学研究院助理研究员,博士,研究方向:新能源材料,本文联系人;陈建军(1965-),男,湖南人,深圳清华大学研究院教授,研究方向:能源化学;檀满林(1980-),男,安徽人,深圳清华大学研究院副研究员,研究方向:新能源材料;马清(1980-),男,湖北人,深圳清华大学研究院博士后,博士,研究方向:能源化学。

基金项目:深圳市基础研究资助项目(JCYJ20120619140233056,JCYJ20120619140209259),深圳市能源存储与转化平台(CXC201104220014A )锂离子电池碳纳米管复合负极材料的进展符冬菊,陈建军,檀满林,马清(深圳清华大学研究院,深圳市锂电池活性电极材料工程实验室,广东深圳518057)摘要:综述了碳纳米管(CNT )及复合材料在锂离子电池负极中的研究进展,重点论述了合金/CNT 复合负极材料结构设计与制备方法的进展。

CNT 不仅缓冲该复合材料在嵌脱锂时的体积变化,形成的三维导电网络还可提高材料的倍率性能和循环寿命。

展望了CNT 复合负极材料的研究前景。

关键词:锂离子电池;碳纳米管(CNT );负极材料中图分类号:TM912.9文献标识码:A文章编号:1001-1579(2013)04-0242-03Progress in carbon nanotube based compositeanode materials for Li-ion batteryFU Dong-ju ,CHEN Jian-jun ,TAN Man-lin ,MA Qing(Research Institute of Tsinghua University in Shenzhen ,Shenzhen Engineering Laboratory of Active Electrode Material in Lithium Batteries ,Shenzhen ,Guangdong 518057,China )Abstract :Research progress in carbon nanotube (CNT )based composite anode materials for Li-ion battery was reviewed.The pro-gress in structure design and preparation method of alloy /CNT composite anode materials was T was acted as a me-chanically stable buffer to accommodate the volume effect during cycling ,the rate performances and cycle life of the material could be improved by 3-dimensional conductive network formed by CNT.A prospect for research developments in CNT based composite anode materials was proposed.Key words :Li-ion battery ;carbon nanotube (CNT );anode material负极材料作为关键材料之一,对锂离子电池性能的提高起着重要的作用。

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a r X i v :c o n d -m a t /0208427v 1 [c o n d -m a t .m e s -h a l l ] 22 A u g 2002A Carbon Nanotube Based NanorelayJ.M.Kinaret,T.Nord and S.ViefersDepartment of Applied Physics,Chalmers University of Technologyand G¨o teborg University,SE-41296G¨o teborg,Sweden(February 1,2008)We investigate the operational characteristics of a nanorelay based on a conducting carbon nan-otube placed on a terrace in a silicon substrate.The nanorelay is a three terminal device that acts as a switch in the GHz regime.Potential applications include logic devices,memory elements,pulse generators,and current or voltage amplifiers.Nanoelectromechanical systems (NEMS)are a rapidly growing research field with substantial potential for fu-ture applications.The basic operating principle under-lying NEMS is the strong electromechanical coupling in nanometer-size electronic devices in which the Coulomb forces associated with device operation are comparable with the chemical forces that hold the devices together.Carbon nanotubes (CNT)1are ideal candidates for nano-electromechanical devices due to their well-characterized chemical and physical structures,low masses,exceptional directional stiffness,and good reproducibility.Nanotube-based NEMS have internal operating frequencies in the gigahertz range,which makes them attractive for a num-ber of applications.Recent progress in this direction in-cludes fabrication of CNT nanotweezers,2,3CNT based random access memory,4and super-sensitive sensors.5,6In this paper we consider another example of CNT based NEMS,a so-called nanorelay.This three-terminal device consists of a conducting CNT placed on a terraced Si substrate and connected to a fixed source electrode.A gate electrode is positioned underneath the CNT so that charge can be induced in the CNT by applying a gate voltage.The resulting capacitive force between the CNT and the gate bends the tube and brings the tube end into contact with a drain electrode on the lower terrace,thereby closing an electric circuit.We describe the sys-tem with a model based on classical elasticity theory 7and the orthodox theory of Coulomb blockade,8,9and study its IV-characteristics and switching dynamics.Theoret-ical studies of a related two-terminal structure have re-cently been reported.10,11Model system.The geometry of the nanorelay is de-picted in Fig.1.We model the CNT as an elastic cantilever using continuum elasticity theory:7Assuming that only the lowest vibrational eigenmode is excited,and that the bending profile upon applying an external force is the same as that of free oscillations,one canexpress the potential energy of the bent tube in termsof the deflection x of its tip as V =kx 2/2.The ef-fective spring constant k depends on the geometry ofthe tube and is approximately given by k ≈3EI/L 3.Here E is Young’s modulus,experimentally determinedto be approximately 1.2TPa,12,13L is the tube length and I =π(D 4o −D 4i )/64its moment of inertia,D o and D i being the outer and inner diameters of the (multi-walled)CNT.The effective mass of the tube is m eff =k/Ω2≈3M/(1.875)2,where M is the total tube mass and Ωits lowest eigenfrequency.7It is known experimen-tally that Q-factors of CNT cantilevers are of the order of 170-500.14We model this by a phenomenological damp-ing force −γd ˙x in the equations of motion.FIG.1.Schematic picture of the model system consist-ing of a conducting carbon nanotube placed on a terraced Si substrate.The terrace height is labeled h ,and q denotes the excess charge on the tube.The CNT is connected to a source electrode (S),and the gate (G)and drain (D)elec-trodes are placed on the substrate beneath the CNT at lengths L and L G away from the terrace.The displacement x of the nanotube tip is measured towards the substrate.Typically,L ≈50−100nm,h ≈5nm.For a metallic nanotube,the effective impedance Z is dominated by the contact resistance at the source con-tact and is mostly ohmic.If a gate voltage is applied,the resulting capacitive force bends the tube so that a tunneling current can flow to drain,whereas due to the long tube-gate distance no electrons tunnel between the tube and the gate electrode.Finite element calculations show that the drain-and gate capacitances are well ap-proximated by those of parallel plate capacitors.15We thus model them as C d (x )=C 0h (1−C 0/C h ),C g (x )=2C 0h(1−C 0/C h ).(1)Here C 0≡C d (x =0)is the drain capacitance for a1horizontal tube and C h≡C d(x=h)is that for the tube in contact with the drain electrode.The latter can be estimated from experiments.16The constantκ(0<κ<1)accounts for the fact that the deflection at the position of the gate is smaller than that of the tip.The corresponding capacitive forces take the form F c=−(Q2/2)∇(1/C(x)).The tunneling resistance is modeled as R T= R0exp[(h−x)/λ],where the tunneling lengthλdepends on the contact material and is typically of the order of 0.5˚A,and R0is estimated from experimental results.16 Following Ingold and Nazarov9for the case of zero tem-perature and an ohmic environmental impedance Z,we determine the tunneling rate at a given deflection x and source-drain voltage V sd asΓ(x)=1g E0dE′ 1+πE c(x) 2 −1P(E′).(3)Here,E c(x)=e2/(2C(x))and g=R K/Z where R K= h/e2≈25.8kΩis the von Klitzing constant.The above model results in a set of coupled non-linear differential equations describing both the mechanical mo-tion and the currentflow in the system,m eff¨x(t)=−kx(t)−γd˙x(t)+F c,gate+F c,drain+F contact(4) Z˙q(t)=−q(t)+V g C g(x)15T.Johansson,M.Sc.Thesis,Chalmers University of Tech-nology(2001).16R.Tarkiainen,M.Ahlskog,J.Penttil¨a,L.Roschier,P. Hakonen,M.Paalanen and E.Sonin,Phys.Rev.B64, 195412(2001).17A.Isacsson,Ph.D.thesis,Chalmers University of Technol-ogy(2002).18J.N.Israelachvili,Intermolecular and Surface Forces(Aca-demic Press,London,1985).19C.J.Chen,J.Phys.:Condens.Matter3,1227(1991).20J.-M.Bonard,H.Kind,T.St¨o ckli and L.-O.Nilsson,Solid State Electronics45,893(2001).4。

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