A Color-to-Speech Sensory Substitution Device for the Visually Impaired.
少儿英语之颜色课件
In man-made objects, colors are used to create visual effects and communicate information. For example, red often represents danger or stop, green represents go or proceed, and yellow represents caution or warning.
The Application of Color in Painting
要点一
Green
总结词
Green is a natural color that represents growth, harmony, and balance.
详细描述
Green is often associated with plants, nature, and health. It can be used to teach vocabulary words related to these items, as well as concepts like ecology and sustainability.
Color courseware for children's English
目录 CONTENTS
• Basic knowledge of color • Learning Color Words • The application of color in daily life • Color based games and activities • Extended knowledge of colors
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The application of color in daily life
微妙色调英语作文
微妙色调英语作文In the realm of English composition, the choice of words is akin to an artist's selection of hues on a canvas. The subtlety of tones can evoke a myriad of emotions and set the ambiance of a narrative or argument. This essay delves into the significance of employing nuanced language to craft an impactful piece of writing.The first brushstroke in painting with words is the selection of the lexicon. Words carry connotations that can subtlyalter the perception of a reader. For instance, the term'home' might invoke a sense of warmth and belonging, while'residence' could suggest a more formal or detached relationship to a place. As such, the choice between these synonyms can paint a different emotional landscape in the reader's mind.Moreover, the gradation of language is crucial. The use of adjectives and adverbs can add depth to a composition, much like the layers of color in a painting. However, an overabundance can lead to a cluttered and overwhelming piece, whereas a sparse application can leave the writing feeling flat and underdeveloped. Striking the right balance is an art in itself.The rhythm and flow of sentences are another aspect where subtlety plays a key role. Varying sentence lengths can create a dynamic pace, keeping the reader engaged. Short,crisp sentences can deliver a punch, while longer, more complex ones allow for a more detailed exploration of ideas. The interplay between these sentence structures is akin to the use of different brushstrokes in art.Furthermore, the tonal shifts within a composition can significantly affect its overall impact. A well-timed transition from a somber to a joyful tone can leave a lasting impression on the reader, much like a surprising turn in a painting that catches the viewer's eye.In conclusion, the subtle use of language is a powerful tool in English composition. It allows writers to weave anintricate tapestry of words that not only convey meaning but also engage the reader on an emotional level. Like an artist who understands the power of different hues, a writer who grasps the subtlety of language can create compositions that are as vibrant and compelling as a masterpiece.。
2023年-2024年教师资格之中学英语学科知识与教学能力精选试题及答案二
2023年-2024年教师资格之中学英语学科知识与教学能力精选试题及答案二单选题(共45题)1、What essentially distinguishes semantics and pragmatics is whether in the study of meaning _________ is considered.?A.referenceB.speech actC.practical usageD.context【答案】 D2、Tom said he would go to Hong Kong for winter vacation and he______ go.A.DidB.hadC.DoesD.will【答案】 A3、请阅读短文,完成此题。
A.SubjectiveB.ExaggeratedC.SarcasticD.Objective4、Liberia,the oldest independent Negro state in West Africa,has been struggling for survival ever since its foundation in 1822.Progress has been hampered by constant hostility between the AmericanA.1822B.1910C.1920D.1920s【答案】 B5、 Which teaching method combines form-focused teaching with communication-focused teaching?A.PPPB.TBLTC.CLTD.TPR【答案】 B6、Passage 1A.Bertha von SuttnerB.Ascanio SobreroC.Alfred NobelD.Immanuel Nobel7、Body language is a powerful communication system,__________it can signal very different things.A.butB.soC.forD.then【答案】 C8、Everyone knows that English departments are in trouble, but you can't appreciate just howmuch trouble until you read the new report from the Modern Language Association. The report is about Ph.D. programs, which have been in decline since 2008. These programs have gotten both more difficult and less rewarding: today, it can take almost a decade to get a doctorate, and, at the end of your program, you're unlikely to find a tenure-track job.A.The job openings for newly-graduated Ph.D.s are incredibly promisingB.It seems impossible for newly-graduated Ph.D.s to find a tenure-track joBC.The M.L.A. report has overestimated the number of tenure-track jobs on the job listD.s【答案】 C9、请阅读Passage 2,完成第小题。
心理学专业英语词汇
心理现象 mental phenomenon心理过程 mental process心理状态 mental state心理活动 mental activity意识 consciousness心理维度 psychological dimension心理运动 psychomotor内部活动 internal activity普通心理学 general psychology实验心理学 experimental psychology行为科学 behavioral science心身关系 mind-body relation心理机能定位 localization of mental function 心理能动性 mental activism外周论 peripheralism先天理论 nativistic theory强调遗传素质决定人心理的产生与发展。
遗传 heredity目的论 teleology认为生物和人类的活动受一定目的的引导。
活动 activity活动理论 activity theory认知心理学 cognitive psychology认知 cognition相对于情感、意志等心理过程的所有认识过程的总称。
包括知觉、注意、表象、学习记忆、问题解决、思维和言语等心理过程。
认知过程 cognitive process认知结构 cognitive structure元认知 metacognition认知失调 cognitive dissonance认知地图 cognitive map认知技能 cognitive skill认知方式 cognitive style信息 information信息论 information theory信息加工 information processing信息加工心理学 information processing psychology 信息加工理论 information processing theory信息加工模型 information processing model中央处理器模型 central processor model信息储存 information storage信息提取 information retrieval人工智能 artificial intelligence, AI计算机类比 computer analogy计算机模拟 computer simulation计算机模型 computer model唯心主义心理学 idealistic psychology意动心理学 act psychology唯意志论 voluntarism唯灵论 spiritualism强调超自然精神作用。
心理学名词翻译
[名词委审定]汉英心理学名词5-羟色胺5-hydroxytryptamine, 5-HT, s erotoninA 型行为类型type A behavior patternB 型行为类型type B behavior patternC 型行为类型type C behavior pattern F 分布F distributionF 检验F testP 物质substance P, SPP300 波P300 wavePM 理论PM theoryT型迷津T mazeX 理论theory XY 理论theory YY型迷津Y mazeZ 理论theory Z[对]人知觉person perception[视觉]变形小屋distorted room[心理]咨询counselingt 分布t distributiont 检验t testz 分数z scorez 检验z testⅠ型错误type ⅠerrorⅡ型错误type Ⅱerror[人格]表面特质surface trait[人类]工效学ergonomics[婴儿的]单词语holophraseα波α waveβ波β waveγ-氨基丁酸γ-aminobutyric acid, GABA δ波δ waveθ波θ waveφ系数φ coefficientχ2分布chi-square distributionχ2检验chi-square testχ2可加性additivity of chi-squareψ现象ψ-phenomenon阿德勒心理学Adlerian psychology阿德勒心理治疗Adlerian psychotherap y艾宾豪斯错觉Ebbinghaus illusion艾森克人格问卷Eysenck Personality Q uestionnaire, EPQ爱德华兹个人爱好量表Edwards Person al Preference Schedule, EPPS爱好preference安全标准safety criterion安全分析safety analysis安全工程safety engineering安全评价safety evaluation安全心理学safety psychology安全训练safety training安慰剂placebo安慰剂效应placebo effect暗示suggestion暗示性suggestibility暗示治疗suggestive therapy暗适应dark adaptation暗适应曲线dark adaptation curve暗视觉scotopic vision奥地利学派Austrian school巴宾斯基反射Babinski reflex巴黎学派Paris school靶细胞target cell白板说theory of tabula rasa白质white matter百分等级percentile rank伴随性负电位变化contingent negative variation, CNV半规管semicircular canal剥夺deprivation保持retention保持曲线retention curve保持性复述maintenance rehearsal保健health care保守性聚焦conservative focusing饱和度saturation抱负水平aspiration level暴露疗法exposure therapy背根dorsal root背景音乐background music贝利婴儿发展量表Bayley Scales of Inf ant Development贝叶斯定理Bayes' theorem倍音overtone备择假设alternative hypothesis被动-攻击性人格passive-aggressive pe rsonality被害妄想persecutory delusion被试变量subject variable本能instinct本能冲动instinctive impulse本能论instinct theory本能行为instinctive behavior本体感受proprioception本我id本族语native language比较认知comparative cognition比较水平comparison level比较心理学comparative psychology 比率量表ratio scale比率智商ratio intelligence quotient比内-西蒙智力量表Binet-Simon Scale of Intelligence比赛心理定向mental orientation in co mpetition比赛型运动员competition type athlete 比赛自我意象self-image in competitio n毕生发展观life-span perspective闭环控制closed-loop control; 具有反馈信息的控制[过程]。
color psychology
The color of the sky and the ocean, blue is one of the most popular colors. It causes the opposite reaction as red. Peaceful, tranquil(安静的) blue causes the body to produce calming chemicals, so it is often used in bedrooms. Fashion consultants recommend wearing blue to job interviews because it symbolizes loyalty. Blue is often used to decorate offices because research has shown that people are more productive in blue rooms. Blue can also be cold and depressing. It create feelings of sadness or aloofness (冷漠).
Made by
Jacy
It is the explanation of how colors affect our emotions, our moods, our health, our well being, our energy, our mind and our spiritual awareness at both a conscious and subconscious level. color is pervasive; it enriches our emotions, our relationships and our lives.
与颜色有关的英语演讲
目录
01
Introduction
Theme Introduction
The theme of this speech is color, which is an essential topic in our daily life Color not only affects our visual experience, but also has a profound impact on our emotions and mental state
Green is often associated with nature, health, and harmony In English, we use the color green to describe things that are fresh or new For example, "The leaves are green in spring" or "She has a green thumb."
03
In some cultures, blue is considered lucky and is used for special occasions or episodes In the United States, blue is a common color for baby boy diapers and clothing
Red is also used in marketing and advertising to attract attention and promote sales For example, "The company uses red in its logo to symbolize power and success."
自然语言处理及计算语言学相关术语中英对译表三_计算机英语词汇
multilingual processing system 多语讯息处理系统multilingual translation 多语翻译multimedia 多媒体multi-media communication 多媒体通讯multiple inheritance 多重继承multistate logic 多态逻辑mutation 语音转换mutual exclusion 互斥mutual information 相互讯息nativist position 语法天生假说natural language 自然语言natural language processing (nlp) 自然语言处理natural language understanding 自然语言理解negation 否定negative sentence 否定句neologism 新词语nested structure 崁套结构network 网络neural network 类神经网络neurolinguistics 神经语言学neutralization 中立化n-gram n-连词n-gram modeling n-连词模型nlp (natural language processing) 自然语言处理node 节点nominalization 名物化nonce 暂用的non-finite 非限定non-finite clause 非限定式子句non-monotonic reasoning 非单调推理normal distribution 常态分布noun 名词noun phrase 名词组np (noun phrase) completeness 名词组完全性object 宾语{语言学}/对象{信息科学}object oriented programming 对象导向程序设计[面向对向的程序设计]official language 官方语言one-place predicate 一元述语on-line dictionary 线上查询词典 [联机词点]onomatopoeia 拟声词onset 节首音ontogeny 个体发生ontology 本体论open set 开放集operand 操作数 [操作对象]optimization 最佳化 [最优化]overgeneralization 过度概化overgeneration 过度衍生paradigmatic relation 聚合关系paralanguage 附语言parallel construction 并列结构parallel corpus 平行语料库parallel distributed processing (pdp) 平行分布处理paraphrase 转述 [释意;意译;同意互训]parole 言语parser 剖析器 [句法剖析程序]parsing 剖析part of speech (pos) 词类particle 语助词part-of relation part-of 关系part-of-speech tagging 词类标注pattern recognition 型样识别p-c (predicate-complement) insertion 述补中插pdp (parallel distributed processing) 平行分布处理perception 知觉perceptron 感觉器 [感知器]perceptual strategy 感知策略performative 行为句periphrasis 用独立词表达perlocutionary 语效性的permutation 移位petri net grammar petri 网语法philology 语文学phone 语音phoneme 音素phonemic analysis 因素分析phonemic stratum 音素层phonetics 语音学phonogram 音标phonology 声韵学 [音位学;广义语音学] phonotactics 音位排列理论phrasal verb 词组动词 [短语动词]phrase 词组 [短语]phrase marker 词组标记 [短语标记]pitch 音调pitch contour 调形变化pivot grammar 枢轴语法pivotal construction 承轴结构plausibility function 可能性函数pm (phrase marker) 词组标记 [短语标记] polysemy 多义性pos-tagging 词类标记postposition 方位词pp (preposition phrase) attachment 介词依附pragmatics 语用学precedence grammar 优先级语法precision 精确度predicate 述词predicate calculus 述词计算predicate logic 述词逻辑 [谓词逻辑]predicate-argument structure 述词论元结构prefix 前缀premodification 前置修饰preposition 介词prescriptive linguistics 规定语言学 [规范语言学] presentative sentence 引介句presupposition 前提principle of compositionality 语意合成性原理privative 二元对立的probabilistic parser 概率句法剖析程序problem solving 解决问题program 程序programming language 程序设计语言 [程序设计语言] proofreading system 校对系统proper name 专有名词prosody 节律prototype 原型pseudo-cleft sentence 准分裂句psycholinguistics 心理语言学punctuation 标点符号pushdown automata 下推自动机pushdown transducer 下推转换器qualification 后置修饰quantification 量化quantifier 范域词quantitative linguistics 计量语言学question answering system 问答系统queue 队列radical 字根 [词干;词根;部首;偏旁]radix of tuple 元组数基random access 随机存取rationalism 理性论rationalist (position) 理性论立场 [唯理论观点]reading laboratory 阅读实验室real time 实时real time control 实时控制 [实时控制]recursive transition network 递归转移网络reduplication 重叠词 [重复]reference 指涉referent 指称对象referential indices 指针referring expression 指涉词 [指示短语]register 缓存器[寄存器]{信息科学}/调高{语音学}/语言的场合层级{社会语言学}regular language 正规语言 [正则语言]relational database 关系型数据库 [关系数据库]relative clause 关系子句relaxation method 松弛法relevance 相关性restricted logic grammar 受限逻辑语法resumptive pronouns 复指代词retroactive inhibition 逆抑制rewriting rule 重写规则rheme 述位rhetorical structure 修辞结构rhetorics 修辞学robust 强健性robust processing 强健性处理robustness 强健性schema 基朴school grammar 教学语法scope 范域 [作用域;范围]script 脚本search mechanism 检索机制search space 检索空间searching route 检索路径 [搜索路径]second order predicate 二阶述词segmentation 分词segmentation marker 分段标志selectional restriction 选择限制semantic field 语意场semantic frame 语意架构semantic network 语意网络semantic representation 语意表征 [语义表示] semantic representation language 语意表征语言semantic restriction 语意限制semantic structure 语意结构semantics 语意学sememe 意素semiotics 符号学sender 发送者sensorimotor stage 感觉运动期sensory information 感官讯息 [感觉信息]sentence 句子sentence generator 句子产生器 [句子生成程序]sentence pattern 句型separation of homonyms 同音词区分sequence 序列serial order learning 顺序学习serial verb construction 连动结构set oriented semantic network 集合导向型语意网络 [面向集合型语意网络]sgml (standard generalized markup language) 结构化通用标记语言shift-reduce parsing 替换简化式剖析short term memory 短程记忆sign 信号signal processing technology 信号处理技术simple word 单纯词situation 情境situation semantics 情境语意学situational type 情境类型social context 社会环境sociolinguistics 社会语言学software engineering 软件工程 [软件工程]sort 排序speaker-independent speech recognition 非特定语者语音识别spectrum 频谱speech 口语speech act assignment 言语行为指定speech continuum 言语连续体speech disorder 语言失序 [言语缺失]speech recognition 语音辨识speech retrieval 语音检索speech situation 言谈情境 [言语情境]speech synthesis 语音合成speech translation system 语音翻译系统speech understanding system 语音理解系统spreading activation model 扩散激发模型standard deviation 标准差standard generalized markup language 标准通用标示语言start-bound complement 接头词state of affairs algebra 事态代数state transition diagram 状态转移图statement kernel 句核static attribute list 静态属性表statistical analysis 统计分析statistical linguistics 统计语言学statistical significance 统计意义stem 词干stimulus-response theory 刺激反应理论stochastic approach to parsing 概率式句法剖析 [句法剖析的随机方法]stop 爆破音stratificational grammar 阶层语法 [层级语法]string 字符串[串;字符串]string manipulation language 字符串操作语言string matching 字符串匹配 [字符串]structural ambiguity 结构歧义structural linguistics 结构语言学structural relation 结构关系structural transfer 结构转换structuralism 结构主义structure 结构structure sharing representation 结构共享表征subcategorization 次类划分 [下位范畴化] subjunctive 假设的sublanguage 子语言subordinate 从属关系subordinate clause 从属子句 [从句;子句] subordination 从属substitution rule 代换规则 [置换规则] substrate 底层语言suffix 后缀superordinate 上位的superstratum 上层语言suppletion 异型[不规则词型变化] suprasegmental 超音段的syllabification 音节划分syllable 音节syllable structure constraint 音节结构限制symbolization and verbalization 符号化与字句化synchronic 同步的synonym 同义词syntactic category 句法类别syntactic constituent 句法成分syntactic rule 语法规律 [句法规则]syntactic semantics 句法语意学syntagm 句段syntagmatic 组合关系 [结构段的;组合的] syntax 句法systemic grammar 系统语法tag 标记target language 目标语言 [目标语言]task sharing 课题分享 [任务共享] tautology 套套逻辑 [恒真式;重言式;同义反复] taxonomical hierarchy 分类阶层 [分类层次] telescopic compound 套装合并template 模板temporal inference 循序推理 [时序推理] temporal logic 时间逻辑 [时序逻辑] temporal marker 时貌标记tense 时态terminology 术语text 文本text analyzing 文本分析text coherence 文本一致性text generation 文本生成 [篇章生成]text linguistics 文本语言学text planning 文本规划text proofreading 文本校对text retrieval 文本检索text structure 文本结构 [篇章结构]text summarization 文本自动摘要 [篇章摘要] text understanding 文本理解text-to-speech 文本转语音thematic role 题旨角色thematic structure 题旨结构theorem 定理thesaurus 同义词辞典theta role 题旨角色theta-grid 题旨网格token 实类 [标记项]tone 音调tone language 音调语言tone sandhi 连调变换top-down 由上而下 [自顶向下]topic 主题topicalization 主题化 [话题化]trace 痕迹trace theory 痕迹理论training 训练transaction 异动 [处理单位]transcription 转写 [抄写;速记翻译]transducer 转换器transfer 转移transfer approach 转换方法transfer framework 转换框架transformation 变形 [转换]transformational grammar 变形语法 [转换语法] transitional state term set 转移状态项集合transitivity 及物性translation 翻译translation equivalence 翻译等值性translation memory 翻译记忆transparency 透明性tree 树状结构 [树]tree adjoining grammar 树形加接语法 [树连接语法] treebank 树图数据库[语法关系树库]trigram 三连词t-score t-数turing machine 杜林机 [图灵机]turing test 杜林测试 [图灵试验]type 类型type/token node 标记类型/实类节点type-feature structure 类型特征结构typology 类型学ultimate constituent 终端成分unbounded dependency 无界限依存underlying form 基底型式underlying structure 基底结构unification 连并 [合一]unification-based grammar 连并为本的语法 [基于合一的语法] universal grammar 普遍性语法universal instantiation 普遍例式universal quantifier 全称范域词unknown word 未知词 [未定义词]unrestricted grammar 非限制型语法usage flag 使用旗标user interface 使用者界面 [用户界面]valence grammar 结合价语法valence theory 结合价理论valency 结合价variance 变异数 [方差]verb 动词verb phrase 动词组 [动词短语]verb resultative compound 动补复合词verbal association 词语联想verbal phrase 动词组verbal production 言语生成vernacular 本地话v-o construction (verb-object) 动宾结构vocabulary 字汇vocabulary entry 词条vocal track 声道vocative 呼格voice recognition 声音辨识 [语音识别]vowel 元音vowel harmony 元音和谐 [元音和谐]waveform 波形weak verb 弱化动词whorfian hypothesis whorfian 假说word 词word frequency 词频word frequency distribution 词频分布word order 词序word segmentation 分词word segmentation standard for chinese 中文分词规范word segmentation unit 分词单位 [切词单位]word set 词集working memory 工作记忆 [工作存储区]world knowledge 世界知识writing system 书写系统x-bar theory x标杠理论 ["x"阶理论]zipf's law 利夫规律 [齐普夫定律]。
光学传感器
Colorimetric chemosensors designed to provide high sensitivity for Hg 2þin aqueous solutionsQi Lin,Yong-Peng Fu,Pei Chen,Tai-Bao Wei,You-Ming Zhang *Key Laboratory of Eco-Environment-Related Polymer Materials,Ministry of Education of China,Key Laboratory of Polymer Materials of Gansu Province,College of Chemistry and Chemical Engineering,Northwest Normal University,Lanzhou,Gansu 730070,PR Chinaa r t i c l e i n f oArticle history:Received 25January 2012Received in revised form 28June 2012Accepted 29June 2012Available online 25July 2012Keywords:Mercury cationColorimetric sensor Speci fic selectivity High sensitivity Aqueous solutions Easy-to-makea b s t r a c tThe speci fic colorimetric detection of Hg 2þin the context of interference from coexisting metal ions in aqueous solutions is a challenge.Therefore,a series of easy-to-make Hg 2þcolorimetric chemosensors S1w S3,bearing thiourea moiety as binding site and nitrophenyl moiety as signal group,were designed and synthesized.Among these sensors,S3showed excellent colorimetric speci fic selectivity and high sensitivity for Hg 2þin DMSO and DMSO/H 2O binary solutions.When Hg 2þwas added to the solution of S3,a dramatic color change from brown to colorless was observed,while the cations Ca 2þ,Mg 2þ,Cd 2þ,Fe 3þ,Co 2þ,Ni 2þ,Cu 2þ,Zn 2þ,Pb 2þ,Ag þand Cr 3þdid not interfere with the recognition process for Hg 2þ.The detection limits were 5.0Â10À6and 1.0Â10À7M of Hg 2þusing the visual color changes and UV e vis changes respectively.Ó2012Elsevier Ltd.All rights reserved.1.IntroductionAs mercury has an extremely toxic impact on the environment and human health [1e 5],the development of chemosensors for the mercury cation (Hg 2þ)has received considerable attention [6e 10].As is well known,mercury can lead to dysfunctions of the brain,kidney,stomach,and central nervous systems [1e 5,11,12].There-fore,the rational design and synthesis of ef ficient sensors to selectively recognize mercury cations is an important topic in supramolecular chemistry [6e 10].Although previous work has involved the development of a wide variety of chemical [13e 43]and physical [44e 48]sensors for the detection of Hg 2þ,so far,improving the detection selectivity in the context of interference from coexisting metal ions has been challenging.Moreover,most of these methods require expensive equipment and involve time-consuming and laborious procedures that can be carried out only by trained professionals [44e 48],which signi ficantly restricting the practical application of these Hg 2þsensors.For simplicity,convenience and low cost,easily-prepared Hg 2þcolorimetric sensors [15e 23,30,38]are needed.On the other hand,in biological and environmental systems,mercury e sensor interactions commonly occur in aqueous solution [23e 26],therefore,muchattention has been paid to developing mercury sensors that work in the aqueous phase [17,23e 26,32,34,49e 52].In view of this requirement and as part of our research effort devoted to ion recognition [53e 60],an attempt was made to obtain ef ficient colorimetric sensors which could sense Hg 2þwith speci fic selectivity and high sensitivity in aqueous solutions.This paper details the design and synthesis of a series of Hg 2þcolorimetric sensors S1w S3bearing thiourea and nitrophenyl groups (Scheme 1).The strategies for the design of these sensors were as follows.Firstly,a thiourea group was introduced as the binding site.The C ¼S moiety on the thiourea group possesses a high af finity with Hg 2þ.Secondly,in order to achieve “naked-eye ”colorimetric recognition,we introduced nitrophenyl groups as the signal group.Finally,the sensor was designed to be easy to synthesize.In order to establish the signal group ’s contribution to the sensor ’s colorimetric sensing abilities for Hg 2þ,compound S1which without containing the nitro-group was also synthesized.2.Experimental section2.1.Materials and physical methods1H NMR spectra were recorded with a Mercury-400BB spec-trometer at 400MHz 1H chemical shifts are reported in ppm down field from tetramethylsilane (TMS,d scale with the solvent*Corresponding author.Tel.:þ869317970394.E-mail address:zhangnwnu@ (Y.-M.Zhang).Contents lists available at SciVerse ScienceDirectDyes and Pigmentsjournal homepage:w ww.else/locate/dyepig0143-7208/$e see front matter Ó2012Elsevier Ltd.All rights reserved./10.1016/j.dyepig.2012.06.023Dyes and Pigments 96(2013)1e 6resonances as internal standards).High-resolution mass spectra were recorded on a Bruker APEXII Fourier transform ion cyclotron resonance (FTICR)MS instrument.Ultraviolet e visible (UV e vis)spectra were recorded on a Shimadzu UV-2550spectrometer.Melting points were measured on an X-4digital melting-point apparatus (uncorrected).The infrared spectra were performed on a Digilab FTS-3000Fourier transform-infrared spectrophotometer.The inorganic salts Ca(ClO 4)2$6H 2O,Mg(ClO 4)2$6H 2O,Cd(ClO 4)2$6H 2O,Fe(ClO 4)3$6H 2O,Co(ClO 4)2$6H 2O,Ni(ClO 4)2$6H 2O,Cu(ClO 4)2$6H 2O,Zn(ClO 4)2$6H 2O,Pb(ClO 4)2$3H 2O,AgClO 4$H 2O and Cr(ClO 4)3$6H 2O were purchased from Alfa Aesar Chemical Reagent Co.(Tianjin,China).All solvents and other reagents were of analytical grade.2.2.General procedure for UV e vis spectroscopyAll the UV e vis experiments were carried out in DMSO solution on a Shimadzu UV-2550spectrometer.Any changes in the UV e vis spectra of the synthesized compound were recorded on the addi-tion of perchlorate metal salts while the ligand concentration was kept constant in all experiments.2.3.General procedure for 1H NMRFor 1H NMR titrations,two stock solutions were prepared in DMSO-d 6:one of them contained the host only and the second one contained an appropriate concentration of guest.Aliquots of the two solutions were mixed directly in NMR tubes.2.4.Synthesis and characterization of sensors S1w S3Benzoyl chloride (3mmol),dry and powdered KSCN (4mmol)and PEG-400(0.1mL,as phase transfer catalyst)were added to dry dichloromethane (15mL).Then the reaction mixture was stirred at room temperature for 2h,and the inorganic salts were filtered out.The filtrate was a solution of the corresponding benzoyl isothiocyanate,which did not need separating.Then 2.8mmol of phenylhydrazine was added to the filtrate solution and stirred at room temperature for 3h,yielding the precipitate of S1.After evaporating the solvent in a vacuum,the precipitate was filtered,washed with 75%ethanol three times,and recrystallized with ethanol to get white crystal of S1.The other compounds S2and S3were prepared by similar procedures.S1:yield:80.5%;m.p.138e 140 C;1H-NMR (DMSO-d 6,400MHz)d 12.61(s,2H,NH),11.59(s,1H,NH),7.99e 7.97(m,2H,ArH),7.71e 7.65(m,2H,ArH),7.57e 7.53(m,2H,ArH),7.45e 7.41(m,2H,ArH),7.30e 7.26(m,2H,ArH);13C NMR (DMSO-d 6,100MHz)d 179.18,168.37,138.02,133.20,132.18,128.75,128.69,128.53,126.42,124.37;IR (KBr,cm À1)v :3444(mb,N e H),3310(m,N e H),3235(m,N e H),1678(s,C ¼O),1601(s,C ¼C),1525(s,C ¼C),1474(s,C ¼C),1276(s,C ¼S);Anal.calcd.for C 14H 13N 3OS:C,61.97;H,4.83;N,15.49;Found:C,61.85;H,4.74;N,15.58.S2:yield:95.7%;m.p.199e 201 C;1H-NMR (DMSO-d 6,400MHz)d 12.02(s,2H,NH),9.77(s,1H,NH),8.15e 8.12(m,1H,ArH),7.95e 7.92(m,2H,ArH),7.72e 7.69(m,2H,ArH),8.15e 8.12(m,2H,ArH),6.98e 6.94(m,2H,ArH);13C NMR (DMSO-d 6,100MHz)d 182.07,167.02,159.06,138.56,133.11,132.07,128.94,126.42,125.86,111.14;IR (KBr,cm À1)v :3441(mb,N e H),3259(m,N e H),3065(m,N e H),1648(s,C ¼O),1609(s,C ¼C),1571(s,C ¼C),1470(s,C ¼C),1292(s,C ¼S);ESI-HRMS calcd.for [M þH]þ:m/z 316.0630,Found:317.0710;Anal.calcd.for C 14H 12N 4O 3S:C,53.16;H,3.82;N,17.71;Found:C,53.37;H,3.65;N,17.59.S3:yield:85.4%;m.p.216e 219 C;1H-NMR (DMSO-d 6,400MHz)d 11.77(s,2H,NH),10.65(s,1H,NH),8.90(s,1H,ArH),8.37(d,1H,J ¼7.2,ArH),8.00(d,2H,J ¼8.0,ArH),7.67(t,1H,J ¼7.2,ArH),7.55(t,Scheme 1.Synthetic procedures for sensors S1w S3.Fig.1.Color changes observed upon the addition of various cations (5equiv.)to the solutions of sensor S3(2Â10À5M)in DMSO solutions.A b s o r b a n c e /a .u .Wavelength/nmFig.2.UV e Vis absorption spectra of S3in the presence of 5equiv.of various cations in DMSO solution at room temperature.Q.Lin et al./Dyes and Pigments 96(2013)1e 622H,J ¼7.6,ArH),7.33(d,1H,J ¼9.6,ArH);13C NMR (DMSO-d 6,100MHz)d 181.35,167.07,162.32,147.00,137.25,133.18,132.01,129.99,128.78,128.50,123.07,116.17;IR (KBr,cm À1)v :3367(m,N e H),3265(m,N e H),3143(m,N e H),1682(s,C ¼O),1618(s,C ¼C),1596(s,C ¼C),1490(s,C ¼C),1275(s,C ¼S);ESI-HRMS calcd.for [M þH]þ:m/z 362.0481,Found:362.0554;Anal.calcd.for C 14H 11N 5O 5S:C,46.54;H,3.07;N,19.38;Found:C,46.83;H,3.28;N,19.27.3.Results and discussionThe colorimetric sensing abilities were primarily investigated by adding various cations (Ca 2þ,Mg 2þ,Cd 2þ,Fe 3þ,Co 2þ,Ni 2þ,Cu 2þ,Hg 2þ,Zn 2þ,Pb 2þ,Ag þand Cr 3þ)to the DMSO solutions of sensor S3.When 5equivalent (equiv.)of Hg 2þwas added to the solution of S3(2.0Â10À5M),the sensor responded with dramatic color changes from brown to colorless (Fig.1).In the corresponding UV e vis spectrum,the absorption at 470nm disappeared (Fig.2).When adding 5equiv.of Cu 2þ,the DMSO solution of S3showed color changes from brown to green.Meanwhile,the addition of Ag þand Fe 3þalso lead to slight color and UV e vis spectrum changes.Whereas when adding the cations Ca 2þ,Mg 2þ,Cd 2þ,Co 2þ,Ni 2þ,Zn 2þ,Pb 2þ,or Cr 3þinto the DMSO solutions of sensor S3,no signi ficant color or spectra changes were observed.Even though sensor S3showed colorimetric response toward Cu 2þ,Ag þand Fe 3þin DMSO solutions,owing to only Hg 2þcould bleaches the solution,therefore,in DMSO solution,S3showed speci fic colorimetric selectivity to Hg 2þ.The same tests were applied to S2and S1.In this case,when various cations were added to the DMSO solutions of S2respec-tively,it was not only Hg 2þthat induced a large blue shift from 495nm to 372nm (corresponding to a distinct color change from brown to colorless),but Fe 3þand Cr 3þcaused similar spectra and color changes also (Fig.3(a)).So sensor S2produced a colorimetric response to Hg 2þ,Fe 3þand Cr 3þin DMSO solutions,however,owing to the color and UV e vis spectra changes were very similar,sensor S2could not selectively recognize Hg 2þ,Fe 3þand Cr 3þ.In addition,when various cations were added to the DMSO solutions of S1respectively,no obvious color or spectra changes were observed (Fig.3(b)).Which indicated that S1couldn ’t colorimetric sense any cations under these conditions.In order to investigate the mercury recognition abilities of S3in aqueous solution,we carried out the similar experiments in DMSO/H 2O (9:1/v:v)HEPES buffered solution at pH 7.40.When adding 5equiv.of Hg 2þto the DMSO/H 2O HEPES buffered solution of S3(2.0Â10À5M),the sensor responded with dramatic color changes from brown to colorless,meanwhile,in the corresponding UV e visspectra,the absorption at 470nm disappeared (Fig.4).While other cations couldn ’t cause such distinct color and spectra changes,therefore,the sensor S3could colorimetric recognition Hg 2þin DMSO/H 2O binary solutions with speci fic selectivity.Simultaneously,the same tests were applied to S2and S1also.As shown in Fig.S-1in Supplementary data ,the compound S2could response a lot of cations such as Hg 2þ,Cu 2þ,Co 2þ,Cr 3þand Fe 3þin DMSO/H 2O (9:1/v:v)HEPES buffered solution,however,S2could not selectively recognize these cations.Similarly,S1couldn ’t colorimetric response any cations in DMSO/H 2O binary solutions as well (Fig.S-2in Supplementary data ).Therefore,according to these results we can find that,on the one hand,the nitrophenyl moiety acted as a signal group and played a crucial role in the process of colorimetric recognition.Because the S1doesn ’t employ nitrophenyl as signal group,it could not color-imetric sense any cations.On the other hand,S2and S3employ 4-nitrophenyl and 2,4-dinitrophenyl as signal groups respectively,they all possess colorimetric response abilities for above mentioned cations.However,due to the steric effects of ortho -nitro group on S3,other cations except Hg 2þcouldn ’t coordinate with S3,thus the sensor S3showed speci fic selectivity toward Hg 2þ.Owing to the compound S2does not contain ortho -nitro group,there are no steric effects,many cations could coordinate with S2,hence the S2could not show selectivity toward those cations.As S3showed speci fic selectivity for Hg 2þ,a series of experi-ments was carried out to investigate the Hg 2þrecognition capa-bility and mechanism of S3.To gain an insight into the stoichiometry of the S3-Hg 2þcomplex,the method of continuous2503003504004505005506006507007500.00.10.20.30.40.50.60.70.80.9A b s o r b a n c e /a .u .Wavelength/nm 3+Cu 2+Cr3+Hg 2+S2+other cationsOther cations are: Cd 2+, Ni 2+, Mg 2+2503003504004505005506000.00.20.40.60.81.01.21.4A o r b u .Wavelength/nmFe Ag Cu S1+Other cations are: Ca ,2+,Cd 2+,Co 2+,Ni 2+,Zn 2+,Pb 2+,an d Cr 3+aS2Ag +Fe ,Ni ,Mg ,Pb 2+,Co 2+,Zn 2+Ca 2+b s a nc e /a .3++2+Hg 2+S1,Other cations are: Ca 2+Mg Co and Cr bFig.3.UV e vis absorption of sensor (a)S2,(b)S1(2.0Â10À5M)in the presence of 5equiv.of various cations in DMSO solution at room temperature.3003504004505005506006507007500.00.20.40.60.81.0Host S3, other cations are Ca 2+, Mg 2+, Cd 2+,Fe 3+, Co 2+, Ni 2+, Cu 2+, Zn 2+, Pb 2+, and Cr 3+A b s o r b a n c e /a .u .Wavelength/nmHg2+Fig.4.UV e Vis absorption spectra of S3(2.0Â10À5M)in the presence of 5equiv.of various cations in (9:1/v:v)DMSO/H 2O HEPES buffered solution at pH 7.40,room temperature.Q.Lin et al./Dyes and Pigments 96(2013)1e 63variations (Job ’s method)was used (Fig.5a).As expected,when the molar fraction of sensor S3was 0.50,the absorbance value approached a maximum,which demonstrated the formation of a 1:1complex between the sensor S3and Hg 2þ.The binding properties of sensor S3with Hg 2þwere further studied by UV e vis titration experiments (Fig.5b).It turned out that in DMSO solution of S3,with an increasing amount of Hg 2þ,the absorbance at 470nm decreased while a new band appeared at 398nm.Such a blueshift led to the solution color changing from brown to colorless.Two clear isosbestic points were observed at 434and 337nm,which indi-cated the formation of an S3-Hg 2þcomplex.By nonlinear least-squares fitting [61]at l max ¼469nm,the association constant Ka of the sensor S3toward Hg 2þwas obtained as 6.04Â104M À1.To further elucidate the binding mode of the sensor S3with Hg 2þ,1H NMR-titration were carried out by gradually adding Hg 2þinto DMSO-d 6solution of S3.As shown in Fig.6,before the addition of Hg 2þ,there were two intramolecular hydrogen bonds in the molecular structure of S3:one was N e H b .O ¼C,and the other was N e H c .O ¼N.The formation of these hydrogen bonds led to the 1H NMR chemical shifts of N e H b and N e H c appearing at low-field.Owing to the fact that N e H b .O ¼C is a very strong intra-molecular hydrogen bond,as shown in Fig.7,the 1H NMR chemical shift of N e H b appeared at the lowest field of the molecular S3at d 11.77ppm,which overlapped the proton signal of N e H a .The 1H NMR chemical shift of N e H c appeared at d 10.65ppm.After the addition of 0.2equivalent of Hg 2þ,an intergradation was formed between S3and Hg 2þ(Fig.6),which caused the 1H NMR chemical shifts of the N e H a ,N e H b and N e H c to appear as two very broad peaks.For the same reason,the proton signals of N e H e and N e H f shifted down field and broadened (Fig.7).With the continuous addition of Hg 2þ,as shown in Fig.6the molecular structure underwent an intramolecular rotation,which induced the breaking of N e H b .O ¼C and N e H c .O ¼N;simultaneously,the interactions between the Hg 2þ.H e e C and Hg 2þ.H f e C were interruptedalso.Fig.5.(a)A Job plot of S3and Hg 2þ,which indicated that the stoichiometry of S3-Hg 2þcomplex was 1:1.(b)UV e vis spectral titration of sensor S3with Hg 2þin DMSO solution.The non-linear fitting curve of the change in absorbance of S3with respect to the amounts of Hg 2þis shown in theinset.Fig.6.The proposed reaction mechanism of the sensor S3with Hg 2þ.Fig.7.Partial 1H NMR of sensor S3(2.5mM)in DMSO-d 6upon the addition of Hg 2þ:(a)S3alone,then after adding (b)0.1,(c)0.2,(d)0.5,(e)0.7,(f)0.9and (g)1equiv.of Hg 2þ.Q.Lin et al./Dyes and Pigments 96(2013)1e 64As a result,the stable Hg 2þ-S31:1complex was formed via the coordination of Hg 2þwith S ¼C and O ¼C groups on S3.The breaking of the hydrogen bonds led to an obvious up field shift of N e H b and N e H c (Fig.7d e f).On the other hand,owing to the interactions between the Hg 2þ.H e e C and Hg 2þ.H f e C were broken,the signals of N e H e and N e H f returned to their original positions (Fig.7d e f).Namely,before all the 1equiv.of Hg 2þwas added,the intergradations and the stable Hg 2þ-S3complex coexisted in the solution.Therefore,every proton signal of N e H a ,N e H b ,N e H c ,C e H e and C e H f displayed two signals,for the intergradations state and the stable Hg 2þ-S3complex state respectively (Fig.7d e f).After 1equiv.of Hg 2þhad been added,the intergradations completely changed into stable Hg 2þ-S3complex.Accordingly,in the whole titration process,the signals of N e H c ,N e H b and N e H a shifted to d 11.22,10.49and 10.24ppm,respectively,and the proton signals of C e H e and C e H f were back to their original posi-tions (Fig.7g).In summary,according to the 1H NMR-titration experiments,the Hg 2þions and S3formed a stable 1:1complex by the coordination of Hg 2þwith S ¼C and O ¼C groups on S3.The recognition mechanism of the sensor S3with Hg 2þwere investigated by IR spectra (Fig.S-3in Supplementary data )also.In the IR spectra of S3,the stretching vibration absorption peaks of C ¼O and C ¼S appeared at 1682and 1275cm À1respectively.However,when S3coordinated with Hg 2þ(1:1,solid complex,KBr),an electron transfer effect occurred from C ¼S and C ¼O to Hg 2þ,which induced the stretching vibration absorption peaks of C ¼O and C ¼S shifted to 1643and 1262cm À1accordingly.At the same time,owing to the in fluence of above mentioned electron transfer effect and the rupture of intra-molecular hydrogen bonds N e H b .O ¼C and N e H c .O ¼N,stretching vibration absorption peaks of N e H b and N e H c shifted from 3265and 3143to 3225and 3100cm À1respectively.Which con firmed that S3coordinated with Hg 2þby C ¼O and C ¼S groups as shown in Fig.6.An important feature of the sensor is its high selectivity toward the analyte over other competitive species.The variations of UV e vis spectral and visual color changes of sensor S3in DMSO solutions caused by the metal ions Ca 2þ,Mg 2þ,Cd 2þ,Fe 3þ,Co 2þ,Ni 2þ,Cu 2þ,Zn 2þ,Pb 2þ,Ag þand Cr 3þwere recorded in Fig.8.It is noticeable that the miscellaneous competitive metal ions did not lead to any signi ficant interference.In the presence of these ions,the Hg 2þstill produced similar color (Fig.8(b))and absorption changes (Fig.8(a):the absorption at 470nm disappeared).These results shown that the selectivity of sensor S3toward Hg 2þwas not affected by the presence of other cations and suggested that it could be used as a colorimetric chemosensor for Hg 2þ.The colorimetric and UV e vis limits of sensor S3for Hg 2þcation were also tested and are presented in Fig.9.The detection limit using visual color changes was a concentration of 5.0Â10À6M of Hg 2þcation in 1.0Â10À6M solution of sensor S3,while the detection limit of the UV e vis changes calculated on the basis of 3s B /S [62]is 1.0Â10À7M for Hg 2þcation,which pointing to the high detection sensitivity.4.ConclusionAn easy-to-make Hg 2þcolorimetric sensor S3,bearing thiourea moiety as the binding site and nitrophenyl moiety as the signal group,was designed and synthesized.This sensor showed speci fic selectivity for Hg 2þin DMSO and DMSO/H 2O binary parison with sensor S1indicated that the nitrophenyl moiety acted as a signal group and played a crucial role in the process of colorimetric recognition.Investigation of the recognition mechanism indicated that the sensor S3recognized Hg 2þby forming a stable 1:1S3-Hg 2þcomplex.The coexistence of other cations did not interfere with the Hg 2þrecognition process.Moreover,the detection limit of the sensor S3toward Hg 2þwas 1.0Â10À7M,which indicated that the sensor S3may be useful as a colorimetric sensor for monitoring Hg 2þlevels in physiological and environmental systems.AcknowledgmentThis work was supported by the National Natural Science Foundation of China (NSFC)(Nos.21064006and 21161018),the Natural Science Foundation of Gansu Province (1010RJZA018)and the Program for Changjian Scholars and innovative Research Team in University of Ministry of Education of China (IRT1177).Appendix A.Supplementary dataSupplementary data related to this article can be found online at /10.1016/j.dyepig.2012.06.023.Fig.8.(a)UV e Vis absorption spectra,(b)photographs and UV e Vis absorption at 470nm of sensor S3(2.0Â10À5M)in DMSO solutions in the presence of Hg 2þ(5equiv.)and the miscellaneous cations Ca 2þ,Mg 2þ,Cd 2þ,Fe 3þ,Co 2þ,Ni 2þ,Cu 2þ,Zn 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[27]Cheng X,Li S,Zhong A,Qin J,Li Z.Newfluorescent probes for mercury(II)withsimple structure.Sensor Actuat B2011;157:57e63.[28]Zou Q,Tian H.Chemodosimeters for mercury(II)and methylmercury(I)basedon2,1,3-benzothiadiazole.Sensor Actuat B2010;149:20e7.[29]Santra M,Roy B,Ahn KH.A“reactive”ratiometricfluorescent probe formercury Lett2011;13:3422e5.[30]Cheng C-C,Chen Z-S,Wu C-Y,Lin CC,Yang CR,Yen Y-P.Azo dyes featuringa pyrene unit:new selective chromogenic andfluorogenic chemodosimetersfor Hg(II).Sensor Actuat B2009;142:280e7.[31]Yin BC,You M,Tan W,Ye BC.Mercury(II)ions detection via pyrene-mediatedphotolysis of disulfide bonds.Chem Eur J2012./10.1002/ chem.201103348.[32]Leng B,Jiang J,Tian H.A mesoporous silica supported Hg2þchemodosimeter.AIChE J2010;56:2957e64.[33]Liu B,Tian H.A selectivefluorescent ratiometric chemodosimeter for mercuryion.Chem Commun2005:3156e8.[34]Zou Q,Zou L,Tian H.Detection and adsorption of Hg2þby new mesoporoussilica and membrane material grafted with a chemodosimeter.J Mater Chem 2011;21:14441e7.[35]Aksuner N,Basaran B,Henden E,Yilmaz I,Cukurovali A.A sensitive andselectivefluorescent sensor for the determination of mercury(II)based ona novel triazine-thione derivative.Dyes Pigm2011;88:143e8.[36]Ramesh GV,Radhakrishnan TP.A universal sensor for mercury(Hg,Hg I,Hg II)based on silver nanoparticle-embedded polymer thinfilm.ACS Appl Mater Interfaces2011;3:988e94.[37]Liu Y,Lv X,Zhao Y,Chen M,Liu J,Wang P,et al.A naphthalimide e rhodamineratiometricfluorescent probe for Hg2þbased onfluorescence resonance energy transfer.Dyes Pigm2012;92:909e15.[38]Cheng X,Li S,Jia H,Zhong A,Zhong C,Feng J,et al.For mercury(II):tunablestructures of electron donor and p-conjugated bridge.Chem Eur J2012;18: 1691e9.[39]Wang C,Xu L,Wang Y,Zhang D,Shi X,Dong F,et al.Fluorescent silvernanoclusters as effective probes for highly selective detection of mercury(II)at parts-per-billion levels.Chem Asian J2012;7:1652e6.[40]Hu J,Wu T,Zhang G,Liu S.Highly selectivefluorescence sensing of mercuryions over a broad concentration range based on mixed polymeric micelles.Macromolecules2012;45:3939e47.[41]Huang R,Zheng X,Wang C,Wu R,Yan S,Yuan J,et al.Reaction-based two-photonfluorescent probe for turn-on mercury(II)sensing and imaging in live cells.Chem Asian J2012;7:915e8.[42]Wen S,Zeng T,Liu L,Zhao K,Zhao Y,Liu X,et al.Highly sensitive and selectiveDNA-based detection of mercury(II)with a-hemolysin nanopore.J Am Chem Soc2011;133:18312e7.[43]Khan TK,Ravikanth M.3-(Pyridine-4-thione)BODIPY as a chemodosimeter fordetection of Hg(II)ions.Dyes Pigm2012;95:89e95.[44]Tang X,Liu H,Zou B,Tian D,Huang H.Afishnet electrochemical Hg2þsensingstrategy based on gold nanoparticle-bioconjugate and thymine e Hg2þe thy-mine coordination chemistry.Analyst2012;137:309e11.[45]Lin L-Y,Chang L-F,Jiang S-J.Speciation analysis of mercury in cereals by liquidchromatography chemical vapor generation inductively coupled plasma-mass spectrometry.J Agric Food Chem2008;56:6868e72.[46]Dolan SP,Nortrup DA,Bolger PM,Capar SG.Analysis of dietary supplementsfor arsenic,cadmium,mercury,and lead using inductively coupled plasma mass spectrometry.J Agric Food Chem2003;51:1307e12.[47]Filippelli M.Determination of trace amounts of organic and inorganic mercuryin biological materials by graphite furnace atomic absorption spectrometry and organic mercury speciation by gas chromatography.Anal Chem1987;59: 116e8.[48]Erxleben H,Ruzicka J.Atomic absorption spectroscopy for mercury,auto-mated by sequential injection and miniaturized in lab-on-valve system.Anal Chem2005;77:5124e8.[49]Yang H,Zhou Z,Huang K,Yu M,Li F,Yi T,et al.Multisignaling optical-elec-trochemical sensor for Hg2þbased on a rhodamine derivative with a ferrocene Lett2007;9:4729e32.[50]Zhang M,Yu M,Li F,Zhu M,Li M,Gao Y,et al.A highly selectivefluorescenceturn-on sensor for cysteine/homocysteine and its application in bioimaging.J Am Chem Soc2007;129:10322e3.[51]Ros-Lis JV,Marcos MD,Mártinez-Máñez R,Rurack K,Soto J.A regenerativechemodosimeter based on metal-induced dye formation for the highly selective and sensitive optical determination of Hg2þions.Angew Chem Int Ed 2005;44:4405e7.[52]Cheng X,Li S,Jia H,Zhong A,Zhong C,Feng J,et al.Fluorescent and colori-metric probes for mercury(II):tunable structures of electron donor and p-conjugated bridge.Chem Eur J2012./10.1002/ chem.201102376.[53]Zhang Y-M,Lin Q,Wei T-B,Wang D-D,Yao H,Wang Y-L.Simple colorimetricsensors with high selectivity for acetate and chloride in aqueous solution.Sensor Actuat B2009;137:447e55.[54]Zhang Y-M,Lin Q,Wei T-B,Qin X-P,Li Y.A novel smart organogel which couldallow a two channel anion response by proton controlled reversible sol e gel transition and color changes.Chem Commun2009:6074e6.[55]Liu M-X,Wei T-B,Lin Q,Zhang Y-M.A novel5-mercapto triazole schiff base asa selective chromogenic chemosensor for Cu2þ.Spectrochim Acta A2011;79:1837e42.[56]Li J-Q,Wei T-B,Lin Q,Li P,Zhang Y-M.Mercapto thiadiazole-based sensorwith colorimetric specific selectivity for AcOÀin aqueous solution.Spec-trochim Acta A2011;83:187e93.[57]Zhang Y-M,Li P,Lin Q,Wei T-B,Li J-Q.A simple colorimetric sensor with highselectivity for mercury cation in aqueous solution.Phosphorus Sulfur2011;186:2286e94.[58]Zhang Y-M,Li Q,Zhang Q-S,Lin Q,Cao-C,Liu M-X,et al.Novel hydrazone-based tripodal sensors:single selective colorimetric chemosensor for acetate in aqueous solution.Chin J Chem2011;29:1529e34.[59]Zhang Y-M,Liu M-X,Lin Q,Li Q,Wei T-B.Mercapto thiadiazole-based sensorswith high selectivity and sensitivity for Hg2þin aqueous solution.J Chem Res 2010:619e21.[60]Zhang Y-M,Qin J-D,Lin Q,Li Q,Wei T-B.Convenient synthesis and anionrecognition properties of N-flurobenzoyl-N’-phenylthioureas in water-containing media.J Fluorine Chem2006;127:1222e7.[61]Valeur B,Pouget J,Bouson J,Kaschke M,Ernsting NP.Tuning of photoinducedenergy transfer in a bichromophoric coumarin supermolecule by cation binding.J Phys 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基于近红外光谱表征品质设计烟叶配方
湖南农业大学学报(自然科学版)2023,49(3):284–290.DOI:10.13331/ki.jhau.2023.03.005Journal of Hunan Agricultural University(Natural Sciences)引用格式:郝贤伟,彭钰涵,杨泽会,陈晓水,江智敏,李波,毕一鸣.基于近红外光谱表征品质设计烟叶配方[J].湖南农业大学学报(自然科学版),2023,49(3):284–290.HAO X W,PENG Y H,YANG Z H,CHEN X S,JIANG Z M,LI B,BI Y M.Design of tobacco formulationbased on the quality characterization by near infrared spectroscopy[J].Journal of Hunan AgriculturalUniversity(Natural Sciences),2023,49(3):284–290.投稿网址:基于近红外光谱表征品质设计烟叶配方郝贤伟1,彭钰涵1,杨泽会2,陈晓水1,江智敏1,李波1,毕一鸣1*(1.浙江中烟工业有限责任公司,浙江杭州310024;2.云南烟叶复烤有限责任公司宣威复烤厂,云南曲靖655400)摘要:针对传统烟叶配方设计客观性不强、设计效率低的问题,提出了一种基于近红外光谱表征品质的烟叶配方设计方法:利用偏最小二乘法建立烟叶化学成分、部位、香型的近红外光谱模型,并预测烟叶品质指标;以品质指标为多维向量构建综合质量表征指数,依据“相似相替”规则,参照目标配方中的原烟等级,筛选相似的替代烟叶并组成候选烟叶集合,采用线性规划求解方法计算替代配方的构成比例。
利用指标评价与感官验证相结合的方式,验证2020年度四川烟叶配方设计效果。
结果表明:替代配方的烟叶部位、烟叶总糖、还原糖、总植物碱、总氮含量等与目标配方的相对误差小于6%;除刺激性指标外,替代配方烟叶香气量、清晰度、透发性、成团性、杂气、余味及劲头等感官质量指标与目标配方的差异不显著。
现象解释型英语作文概念
现象解释型英语作文概念英文回答:Phenomenon Explanation.As human beings, we are constantly observing and trying to make sense of the world around us. There are many phenomena that occur in our daily lives that may seem mysterious or unexplainable at first. In this essay, I will discuss and provide explanations for some common phenomena.One phenomenon that many people have experienced is the "phantom vibration" sensation. This is when you feel your phone vibrating in your pocket or purse, but when you check, there is no incoming call or message. This phenomenon canbe explained by a psychological concept called "sensory substitution." Our brain is constantly processinginformation from our senses, and sometimes it can misinterpret signals. In the case of phantom vibrations,our brain may mistake the sensation of movement from ourclothing or muscles for a phone vibration.Another phenomenon that often puzzles people is the "Mandela Effect." This refers to the collective misremembering of a fact or event. For example, many people remember Nelson Mandela dying in prison in the 1980s, when in reality, he was released and went on to become the President of South Africa. The Mandela Effect can be attributed to the fallibility of human memory. Our memories are not perfect and can be influenced by external factors, such as social reinforcement or misinformation. Therefore, when a large group of people misremember the same thing, it creates the illusion of a shared false memory.One more phenomenon that I would like to discuss is the "placebo effect." This is when a person experiences a perceived improvement in their symptoms or condition after receiving a treatment that has no therapeutic value. The placebo effect is a result of the mind-body connection. Our beliefs and expectations can have a powerful influence on our physical well-being. For example, if a person believes that a sugar pill is a powerful painkiller, their brain mayrelease endorphins, natural pain-relieving chemicals, which can lead to a reduction in pain.In conclusion, there are many phenomena that occur in our daily lives that may seem unexplainable at first. However, upon closer examination, these phenomena can be explained by psychological and physiological processes. The "phantom vibration" sensation can be attributed to sensory substitution, the "Mandela Effect" can be explained by the fallibility of human memory, and the "placebo effect" is a result of the mind-body connection. By understanding these explanations, we can gain a deeper insight into the workings of the human mind and body.中文回答:现象解释。
信管专业英语课件上标的红色的词汇
collar(项圈)Startled(大吃一惊)leash(皮带,束缚)object-oriented(面向对象的)stuff(材料,原料,东西)gasped (气呼呼) project management(项目管理). Initiation(引发,启动,开始)elicitation(获取) collation(校对) Parallel programming(并行程序设计)Complexity(复杂性)Cabling & Wiring(布电缆和电线)inclusions(加入部分) time delays (时间延误)compatibility(兼容性)interference(干扰) side-effects(副作用) Pilot(试点) Piecewise(分段) Parallel running(并行处理)rolling plan(后续计划) upgrades(升级,增加,加强)outstanding accounts(未付清的帐) Adaptive (适应,适配)Corrective(改正的,改善法)Enhancement (增加,放大,加强)enthusiastic (充满热情的)vital(至关重要的)Stakeholders (利益相关者)endorsement (Approval/ Support) grease(油脂,贿赂)bureaucratic (官僚的,官僚主义的)smoothest (平稳的,最顺畅)temptation(诱惑) leap(跳跃)contingency(不测事件) receptive(接受的)anticipated(期望) swallow (忍受,吞下)lump(块,成块的)decomposition( break up/separate)(分解,腐烂,变质)deviate(偏离轨道) come up( consider) permanence( state of being permanent)(永久性)snowflake (雪花)quicksand(流沙). Scope creep (范围蔓延)imply( to express/suggest indirectly)(意味,暗示,意指)immutable (不变的)stifled( to prevent from happening or developing)(堵,窒息,被抑制的)meander ( wander in a slow easy aimless way)(漫步)rigid (not easy to bend)(严格的,坚硬的)shatter (to break suddenly into very small pieces)(破坏,粉碎)tosses (throw)(投,仍)introduced (to bring into practice or use) (出台,介绍,引进)eliminate (to remove or get rid of completely)(消除,排除)right (most suitable)(合适的,权利)ideology( a set of ideas)(意识形态,思想意识)dictate(要求) trade-offs(权衡) inherent(不可分割) proportion (比例,比,部分)phenomenon(现象) inevitable (can not avoid to be happen)(不可避免的)disastrous( being or causing a disaster)(灾难性的,破坏性的)tackle (to take action to deal with)(处理)strait-jacket (狂人约束衣)irrevocably (can not be changed)(不能撤回的,不能撤销的)axes(中心juggle(杂耍) commencement (beginning)(开始)feasibility study (可行性研究)revolve around(旋转)present (现在,出席的)‘assertion’(statement (模糊的)regrettable(遗憾的,可悲的)clutter up (to make untidy or confused)(使杂乱)handicapped(弱智) availability (可用性)confidential (机密的,秘密的,表示信任的)taken into account(考虑在内)levels(水平,标准,层面)access(访问,接近,进入)Waterfall(瀑布)Spiral (螺旋形的)Reverse(反向,相反的)methodologies(方法论,方法)segments (分块)fixed(固定)complexity (复杂程度)Fact-finding (事实发现)cross-life-cycle(横跨生命周期) Presentation (交流讲座)Approximate(大约的,近似的)effort(努力,成就)productivity(工作效率) quality(素质).. ongoing(持续不断的) establishes( set up)(建立,设立)under the control.(处于控制之下)Participants(参与人员) mentioned(提到) research fellow(研究员) inadequate(不足的,不充分的)Management(管理人员) analysts(分析员) supervisor(主管) leader(领导者)alternative(可选的)Submit(提交) corporate(公司的) charters(章程)executives(执行官,高管)paperwork(文书工作) nonessential (非本质的,不必要的)pervasive(蔓延) sense(认识) paper-based(纸基的)justify(证明。
03_Consumer_Perception_S1
19
Stimulus Organization
• Stimulus interpretation is associated with other related events, sensations, or images • Gestalt: “the whole is greater than the sum of its parts”
– Marketers contribute to the commotion – Advertisements, product packages, radio & TV commercials, billboards
3
Sensation & Perception
• Sensation
– Immediate response of our sensory receptors…
– Company’s own strengths and weaknesses in comparison with competitors
21
Interpretational Biases
• We often interpret ambiguous stimuli based on our experiences, expectations, and needs
22
Semiotics
• Correspondence between signs and symbols and their role in the assignment of meaning • Consumer products = social identities
15
Subliminal Perception
吸色程度不同英语表达
吸色程度不同英语表达Title: The Variability of Color Absorption: A Technical Exploration.In the realm of color science and technology, the concept of color absorption plays a pivotal role. This process, which involves the interaction of light with matter, determines how we perceive the hues and shades of the visible spectrum. However, a fascinating aspect of color absorption is its variability—the degree to which different materials, surfaces, and environments absorb and reflect light. This article delves into the factors that influence the degree of color absorption and its significance across various applications.### Factors Influencing Color Absorption.1. Material Properties: The physical and chemical properties of a material significantly impact its ability to absorb light. Certain materials, such as dark-coloredfabrics or pigmented plastics, are highly absorbent, while others, like mirrors or certain types of glass, reflect most of the incident light.2. Surface Texture: The roughness or smoothness of a surface also affects color absorption. Rough surfaces scatter light more, reducing the intensity of absorbed colors, while smooth surfaces allow for more uniform absorption.3. Environmental Conditions: External factors like lighting conditions, temperature, and humidity can alter the absorption properties of materials. For instance, changes in lighting intensity or color temperature can shift the perceived hue of a surface.4. Spectral Composition of Light: The specific wavelengths of light incident on a surface determine the colors absorbed. Natural light, for instance, contains a broad spectrum of wavelengths, while artificial light sources may emit a narrower range.### Applications of Color Absorption.1. Printing and Dyeing: In the printing and dyeing industries, understanding color absorption is crucial for achieving consistent color reproduction. Different fabrics absorb dyes differently, necessitating precise adjustmentsin dye concentration and application techniques.2. Photography and Filmmaking: Photographers and filmmakers rely on color absorption principles to capture and manipulate images. The choice of film or digital sensor, as well as post-processing techniques, can significantly affect the final color rendition.3. Paint and Coatings: The paint and coatings industry benefits from a detailed understanding of color absorption. This knowledge helps in developing paints that adhere well, dry uniformly, and maintain color consistency over time.4. Display Technology: In displays such as LCDs and OLEDs, color absorption plays a key role in defining the color gamut and accuracy. The materials used in thesedisplays must have precise absorption characteristics to reproduce a wide range of colors accurately.### Conclusion.The degree of color absorption is a complex phenomenon influenced by various factors, including material properties, surface texture, environmental conditions, and the spectral composition of light. Understanding and controlling these factors is essential for achieving consistent and accurate color reproduction across various applications. As technology continues to evolve, so does our understanding of color absorption, opening up new possibilities for manipulating and experiencing color in unique and captivating ways.。
2023年-2024年教师资格之中学英语学科知识与教学能力通关考试题库带答案解析
2023年-2024年教师资格之中学英语学科知识与教学能力通关考试题库带答案解析单选题(共45题)1、Passage 1A.SkippyB.Robin OldsC.Sante FeD.Forrest Fenn【答案】 D2、Again as __________ in this experiment, he didn′ t lose heart.A.he failedB.did he failC.he did failD.had he failed【答案】 A3、Which of the following terms best describes the pair of words"kill"and"drill"?A.Minimal pairB.A phonemic contrastC.Closed class wordsD.Bound morphemes【答案】 A4、Passage 1A.revealed a cunning personalityB.centered on trivial issuesC.was hardly convincingD.was part of a conspiracy【答案】 C5、While teaching, we should keep our clas running smoothly andA.thoroughlyB.efficientlyC.speedilyD.directly【答案】 B6、Which of the following words has a different stress pattern?A.FacilityB.CaterpillarmunityD.Accompany【答案】 B7、Which of the following do not belong to the same type according to the manner or place ofarticulationA./p//b//m/B./θ/ // /h/C./g/ /h/ /k/D./g/ // /w/【答案】 C8、In the college-admissions wars, we parents are the true fighters. We're pushing our kids to get good grades, take SAT preparatory courses and build resumes so they can get into the college of our first choice. I've twice been to the wars, and as I survey the battlefield, something different is happening. We see our kids' college background as a prize demonstrating how well we've raised them. But we can't acknowledge that our obsession is more about us than them. So we've contrivedvarious justifications that turn out to be half-truths, prejudices or myths. It actually doesn't matter much whether Aaron and Nicole go to Stanford.A.Continuing education is more important to a person's successB.A person's happiness should be valued more than their educationC.Kids' actual abilities are more important than their college backgroundD.What kids learn at college cannot keep up with job market requirements【答案】 C9、Which of the following is NOT a suitable pre-reading activity?A.Demonstrating "skimming" and "scanning" techniquesB.Writing a similar textC.Introducing the elements of the reading textD.Writing questions about the topic【答案】 B10、Which of the following pairs of words are synonyms?A.Red-colorB.Tall-shortC.Petrol-gasolineD.Father-father【答案】 C11、Which of the following instructions is helpful in developing students′ ability to makeinferencesA.Listen to a story and write a summaryB.Listen to a story and work out the writer' s intentionC.Listen to the story of a boy and then draw a picture of himD.Listen to a story and note down the specific date of an event【答案】 B12、Until then, his family __________ from him for six months.A.didn't hearB.hasn't been hearingC.hasn't heardD.hadn't heard【答案】 D13、I don't mind picking up your things from the store. __________, the walk will do me good.A.EntirelyB.StillC.OtherwiseD.Besides【答案】 D14、A teacher handed out a list of twenty "if" sentences and asked students to discuss and find out the gram-matical rules. What is the teacher′s grammar teaching method?A.DeductionB.PresentationC.ConsolidationD.Induction【答案】 D15、--What you said is not__________with what you do, which has a bad effect on our kids.A.consistentB.controversialC.confidentD.considerate【答案】 A16、Passage 1A.employers could specify the ages of people they want to hire in the pastB.all employers recruited workers through advertisement in the pastC.legislation prohibiting discrimination can't free old workers from age discriminationD.the recent proposed congressional legislation is ineffective【答案】 A17、When the Viaduct de Millau opened in the south of France in 2004, this tallest bridge in the world won worldwide accolades. German newspapers described how it “floated above the clouds” with “elegance and lightness” and “breathtaking” beauty. In France, papers praised the “immense” “concrete giant.” Was it mere coincidence that the Germans saw beauty where the French saw heft and power? Lera Borodisky thinks not. In a series of clever experiments guided by pointed questions, Boroditsky is amassing evidence that, yes, language shapes thought. The effect is powerful enough, she says, that “the private mental lives of speakers of different languages may differ dramatically,” not only when they are thinking in order to speak, “but in all manner of cognitive tasks,”including basic sensory perception. “Even a small fluke of grammar”—the gender of nouns—“can have an effect on how people think about things in the world,” she says.A.Reflecting on topics that appeal to the author and readersB.Introducing new evidence to what has been confirmed beforeC.Identifying the kinds of questions supported by the experimentsD.Claiming that speakers of different languages differ dramatically【答案】 B18、Passage 2A.BirdsB.FlowersC.Food scrapesD.Scavengers【答案】 A19、请阅读Passage 2,完成第小题。
玫瑰花粉添加量对面条品质、色泽和生物活性物质的影响
分析检测玫瑰花粉添加量对面条品质、色泽和生物活性物质的影响韦芙蓉(上海海洋大学,上海 201306)摘 要:将0%~4%的玫瑰花粉与小麦粉混合制作成干制玫瑰面条,研究了玫瑰花粉添加量对面条品质、色泽以及多酚含量的影响。
结果表明,烹煮后玫瑰面条的硬度和咀嚼性均低于对照组,黏性显著增大;感官评定结果显示玫瑰花粉添加量为3%时面条的感官效果最佳。
玫瑰花粉添加量越高,面条的亮度值(L*)和黄蓝值(b*)越低,红绿值(a*)越高,且玫瑰面条中的游离酚和花色苷含量显著高于未添加玫瑰花粉的对照组。
关键词:玫瑰花粉;面条;品质特性;色泽Effect of Rose Powder Addition on Quality, Color andPolyphenol Content of NoodlesWEI Furong(Shanghai Ocean University, Shanghai 201306, China)Abstract: In order to clarify the effect of rose powder addition on the quality characteristics, color and bioactive substance content of noodles, 0% to 4% rose powder was mixed with wheat flour to make dried rose noodles. It was found that the hardness and chewiness of dried rose noodles after cooking were lower than those of the control group, but the viscosity was significantly increased; the best sensory effect was obtained when the rose powder addition was 3%. The higher the rose powder addition, the lower the brightness value (L*) and yellow-blue value (b*), as well as the higher the red-green value (a*) of dried rose noodles. The free polyphenol and anthocyanin contents of dried rose noodles were significantly higher than control group without added rose powder.Keywords: rose powder; noodles; quality characteristics; color面条是中国传统谷物食品之一,而干制挂面是市场上比较常见的面条销售品种。
小学下册G卷英语第3单元暑期作业(含答案)
小学下册英语第3单元暑期作业(含答案)考试时间:90分钟(总分:120)A卷一、综合题(共计100题共100分)1. 选择题:Which bird is known for its colorful feathers?A. PigeonB. SparrowC. PeacockD. Crow答案:C2. 填空题:My pet ______ (狗) loves to go for walks with me.3. 听力题:A _______ is a reaction that produces a pungent aroma.4. 填空题:The ocean is ________ (深蓝色).5. 填空题:A coyote is a wild ________________ (动物).6. 填空题:I will visit my ________ (祖父母) this weekend.7. 听力题:The ancient Greeks held the first Olympic Games in ________.8. 听力题:The puppy is very ________.9. 选择题:What is the main ingredient in a Caesar salad?A. LettuceB. TomatoC. CucumberD. Spinach10. 填空题:The garden has colorful _______ that bloom all year.11. 填空题:The turtle can live for over a ______ (十年).12. 选择题:What do we call the time of day when we wake up?A. MorningB. AfternoonC. EveningD. Night13. 听力题:The chemical formula for potassium nitrate is ______.14. 填空题:A chameleon can change its _______ (外表) to hide.15. 选择题:What do we call a person who creates maps?A. CartographerB. GeographerC. SurveyorD. Explorer答案: A16. 听力题:The flowers are ________ and colorful.17. 填空题:The iguana basks in the _______ (阳光).18. 听力题:An element's properties can be predicted based on its ______.19. 听力题:We have a ______ in the garden. (pool)20. 填空题:The lobster has pincers to catch its _________ (食物).21. 选择题:What is 6 x 2?A. 12B. 10C. 8D. 1422. 选择题:What is the chemical symbol for silver?A. AuB. AgC. PbD. Fe答案: B23. 听力题:My brother loves to build with ____ (Legos).24. 选择题:How many sides does a square have?A. 3B. 4C. 5D. 6答案:B25. 听力题:The chemical formula for iron oxide is _______.26. 听力题:A ______ is a type of animal that lives in groups.27. 填空题:My sister enjoys __________ (参与社团).28. n the summer are very ______ (美丽). 填空题:Taking c29. 听力题:My sister is very _____ (聪明).30. 选择题:How many legs does a spider have?A. SixB. EightD. Ten31. 选择题:What is the capital of Japan?A. BeijingB. TokyoC. SeoulD. Bangkok32. 填空题:The __________ (历史的深刻) inspires thought.33. 听力题:A reaction that occurs in the absence of oxygen is called an ______ reaction.34. 填空题:I have a collection of ______ (邮票) from different countries. Each stamp tells a ______ (故事).35. 选择题:What is the capital of France?A. RomeB. LondonC. ParisD. Berlin答案: C36. 听力题:A solution is a type of ______.37. 听力题:The cake is ________ and sweet.38. 选择题:What do you call a place where you can see wild animals?A. ZooB. AquariumC. MuseumD. Farm答案:A39. 选择题:What do you call a vehicle with two wheels?A. CarB. TruckD. Bus40. 选择题:What is the capital of Portugal?A. LisbonB. PortoC. FaroD. Braga答案: A41. 填空题:The __________ (种子的发芽) is an exciting process.42. 选择题:What do we call a young hedgehog?A. HogletB. PupC. KitD. Calf答案:A. Hoglet43. 听力题:The Boston Tea Party was a protest against British _______.44. 听力题:The atomic number of an element represents the number of _______ in its nucleus.45. 选择题:What do we call the time of year when leaves fall from trees?A. SpringB. SummerC. FallD. Winter答案: C. Fall46. 听力题:Electric charges can be positive or ______.47. 填空题:The sky is _______ (蓝色的).48. 填空题:The __________ (历史的回声) resonates deeply.49. (52) contains many islands. 填空题:The ____50. 听力题:The teacher is ______ (friendly) to everyone.51. 听力题:The chemical formula for sulfur trioxide is _____.52. 听力题:I like to ride my ______. (scooter)53. 填空题:My favorite animal is a _______ because it’s cute.54. 选择题:What is the name of the famous American national park known for its geysers?A. YellowstoneB. YosemiteC. Grand CanyonD. Zion答案:A55. 填空题:A butterfly lands on a ______.56. 填空题:My friend is __________ (非常有帮助).57. 选择题:Which season comes after winter?A. FallB. SpringC. SummerD. Autumn答案: B58. 选择题:How many players are on a volleyball team?A. 5B. 6C. 7D. 859. 填空题:A ________ (植物文化传统) enriches history.Which instrument has keys and is played by pressing them?A. GuitarB. DrumsC. PianoD. Flute答案: C61. 填空题:The abolition of slavery was achieved in the ________ (19世纪).62. 听力题:Light from the sun takes about eight ______ to reach us.63. 听力题:The boy likes to play ________.64. 选择题:What is the capital city of Saudi Arabia?A. RiyadhB. JeddahC. MeccaD. Medina65. 选择题:What do you call the process of a plant producing seeds?A. GerminationB. PollinationC. FertilizationD. Seed Dispersal答案: B66. 选择题:What is the main color of grass?A. BlueB. GreenC. BrownD. Yellow答案:B67. 填空题:A flamingo stands on one leg to ______ (平衡).68. 填空题:The teacher, ______ (老师), prepares us for tests and exams.What do we use to keep our food cold?A. OvenB. MicrowaveC. RefrigeratorD. Toaster70. 填空题:The _______ (兔子) has big ears.71. 听力题:The cat chases _______ around the house.72. 选择题:What is the capital city of Brunei?A. Bandar Seri BegawanB. Kuala BelaitC. SeriaD. Tutong73. 选择题:What is the capital of Kyrgyzstan?A. BishkekB. OshC. Jalal-AbadD. Batken答案: A74. 填空题:A kangaroo's pouch protects its ________________ (幼崽).75. 听力题:My favorite subject is ________ (science).76. 听力题:Light can bend when it passes through different ______.77. 听力题:My grandma enjoys watching ____ (shows) on TV.78. global warming) affects climates worldwide. 填空题:The ____79. 选择题:What is 100 25?a. 65c. 75d. 80答案:C80. 选择题:What is the main ingredient in cheese?A. MilkB. EggsC. FlourD. Sugar81. 填空题:When I go to the movies, I like to bring my favorite ________ (玩偶) along.82. 听力题:A saturated solution contains the maximum amount of ________ that can dissolve.83. 听力题:A black hole forms from a collapsing ______.84. 选择题:What is 6 + 7?A. 12B. 13C. 14D. 1585. 听力题:An indicator is a substance that changes color in response to _____.86. 选择题:What do you call a person who studies rocks?A. BiologistB. GeologistC. AstronomerD. Chemist87. 听力题:His favorite color is ________.88. 选择题:Which animal is known as the king of the jungle?A. ElephantB. TigerC. Lion答案: C89. 选择题:What do we call a plant that grows in water?A. Aquatic PlantB. Terrestrial PlantC. XerophyteD. Halophyte答案:A90. 选择题:How many legs does an insect have?A. FourB. SixC. EightD. Ten91. 填空题:_____ (温室) help plants grow in any season.92. 填空题:A ________ (温室) helps plants grow all year round.93. 填空题:The __________ is a large desert located in northern Africa. (撒哈拉沙漠)94. 听力题:The children are ___ in the playground. (playing)95. 选择题:What is the name of the river that runs through Egypt?A. NileB. AmazonC. YangtzeD. Mississippi答案: A96. 听力题:The process of making sugar from sugar cane is called _______.97. 填空题:The _______ (猴子) can climb very well.98. 选择题:What is the name of the famous music festival held in California?A. CoachellaB. LollapaloozaC. BonnarooD. Glastonbury答案: A. Coachella99. 填空题:I find ________ (宇宙) fascinating and mysterious.100. 选择题:Which planet is known as the "Giant Planet"?A. EarthB. SaturnC. JupiterD. Neptune。
小学下册第四次英语第5单元期中试卷
小学下册英语第5单元期中试卷考试时间:80分钟(总分:120)A卷一、综合题(共计100题共100分)1. 选择题:What is the name of the famous bear who loves adventures in the Hundred Acre Wood?A. Paddington BearB. Winnie the PoohC. Yogi BearD. Baloo答案: B2. 选择题:What do you call a young meerkat?A. KitB. PupC. CalfD. Cub3. 填空题:The __________ (纪念碑) honors a historic event.4. 填空题:The nurse provides _____ (护理) for patients.5. 填空题:My sister is a great __________ (编程员).6. 选择题:What is the color of a healthy leaf?A. BrownB. YellowC. GreenD. Red答案:C7. 选择题:What is 24 - 12?A. 10B. 11C. 12D. 138. 选择题:What is the largest mammal in the ocean?A. DolphinB. SharkC. WhaleD. Octopus答案:C9. 选择题:Which holiday is celebrated on December 25th?A. ThanksgivingB. New YearC. ChristmasD. Halloween答案:C10. 填空题:The _____ (兔子) hops quickly across the grass. It is very cute! 兔子在草地上快速跳跃。
它非常可爱!11. 选择题:What do we call a machine used to take pictures?A. CameraB. ProjectorC. ScannerD. Television12. 听力题:Sublimation is when a solid changes directly into a ______.13. 听力题:A ____ is a small creature that spins webs in corners.14. 选择题:What color is the center of a target?A. RedB. BlueC. YellowD. Black答案:A15. 填空题:My dad drives us to ____.16. 选择题:What is the main language spoken in Brazil?A. SpanishB. PortugueseC. FrenchD. Italian17. 选择题:What do you wear on your feet?A. HatB. ShirtC. ShoesD. Belt18. 填空题:The jellyfish floats in the ________________ (海水).19. 填空题:The scientist, ______ (科学家), researches animals in the wild.20. 填空题:My ___ (小猫) catches bugs in the summer.21. 填空题:The _____ (zucchini) is a popular vegetable.22. 填空题:We are learning about _______ (动物) in school.23. 填空题:The ________ was a crucial treaty that ended a territorial dispute.24. 填空题:The country famous for its glaciers is ________ (冰岛).25. 选择题:What do you call a large animal that lives in the sea and has fins?A. SharkB. WhaleC. DolphinD. All of the above答案:D26. 选择题:What is the capital of the UK?A. ParisB. LondonC. BerlinD. Madrid27. 填空题:The __________ is a major river in Nigeria. (尼日尔河)28. 填空题:The ________ is a famous painting by Leonardo da Vinci.29. 听力题:The dog is ________ the ball.30. 听力题:She has a nice ___. (smile)31. 听力题:The _____ (沙滩) is sandy.32. 选择题:What is the capital of Sweden?A. OsloB. CopenhagenC. StockholmD. Helsinki33. 选择题:What do you call a type of dance?A. BalletB. Hip-hopC. SalsaD. All of the above34. 听力题:The chemical formula for acetone is __________.35. 选择题:What do we call a young goose?A. GoslingB. ChickC. DucklingD. Nestling答案:A. Gosling36. 填空题:I enjoy visiting historical ______ (遗址) to learn about the past. It’s fascinating to see how people lived long ago.37. 填空题:We need to protect ______ (植物) from pollution.38. 选择题:What is the name of the famous scientist known for his work on genetics?A. Gregor MendelB. Charles DarwinC. Louis PasteurD. Albert Einstein答案: A39. 听力题:A chemical bond can form between ______.40. 听力题:A suspension is a mixture where particles are _____ in a liquid.41. 选择题:What is the name of the famous art museum in New York City?A. The LouvreB. The MetC. The GuggenheimD. The Tate Modern42. 听力题:My dad is a ________.43. 填空题:I take my ________ (玩具名称) on vacation with me.44. 填空题:A ____(youth engagement) inspires the next generation.45. 听力题:I have a _____ for my birthday. (celebration)46. 选择题:What is 6 x 7?A. 42B. 36C. 48D. 5447. 选择题:What do you call a vehicle designed to travel on water?A. PlaneB. CarC. BoatD. Train答案:C48. 填空题:We should _______ (help/ignore) each other.49. 听力题:I love to _____ in the garden. (play)50. 填空题:The emu is a large, flightless ______ (鸟).51. 听力题:I need to _______ (get) a haircut.52. 听力题:She has a ________ (background) in education.53. 选择题:Which instrument has keys and is played by pressing them?A. GuitarB. PianoC. ViolinD. Drum答案:B54. 听力题:A ____ is often kept as a pet and enjoys being around people.55. 听力题:We strive for ________ (excellence) in our work.56. 选择题:Which fruit is known for its high vitamin C content?A. BananaB. OrangeD. Grape57. 选择题:What is the name of the famous mountain in Japan?A. FujiB. EverestC. KilimanjaroD. Denali58. 选择题:What is the capital of Eswatini?a. Mbabaneb. Manzinic. Sitekid. Piggs Peak答案:a59. 听力题:The Great Wall of China can be seen from ______.60. 选择题:What do we call a series of mountains?A. RangeB. HillC. ValleyD. Plateau答案: A61. 听力题:She is reading a ___. (novel)62. 填空题:The __________ (古代波斯) was known for its great emperors.63. 选择题:What do we call the sweet substance made by bees?A. SyrupB. SugarC. HoneyD. Jam答案:C64. 选择题:What is the name of the famous river in Egypt?A. AmazonC. MississippiD. Yangtze答案: B65. 填空题:A _____ (自然探索) can reveal unique plants in the wild.66. 填空题:Bees make _________. (蜂蜜)67. 填空题:__________ (科学社会) promotes collaboration and advancements in research.68. 选择题:Which day comes after Friday?A. SaturdayB. SundayC. MondayD. Tuesday69. 填空题:I often research online to find out more about my ________ (玩具名).70. 听力题:I can ___ (draw) a cat.71. 听力题:A telescope helps astronomers study distant ______.72. 听力题:A __________ is a measurement of the angle of a slope.73. 听力题:The lunch is ___. (ready)74. 填空题:The _______ (The Great Migration) reshaped urban landscapes in America.75. 填空题:I have a special ________ that makes me feel happy.76. 填空题:My ________ (玩具名称) is a great conversation starter.Which animal barks?A. CatB. DogC. CowD. Sheep78. 听力题:She likes to play with her ___. (friends)79. 听力题:The apples are ________ in the basket.80. 选择题:What is the main ingredient in tofu?A. SoybeansB. WheatC. CornD. Rice81. 填空题:Grandma always tells me I am her little _______.82. 听力题:The chemical formula for potassium iodide is ______.83. 听力题:I enjoy ______ (watching) sports on TV.84. 选择题:What is the capital of the Netherlands?A. AmsterdamB. RotterdamC. UtrechtD. The Hague85. 选择题:What do we call the line that divides the Earth into two halves?A. EquatorB. Prime MeridianC. Tropic of CancerD. Arctic Circle答案:A86. 填空题:I like to draw ______ in my spare time.What is the name of the famous tower in Paris?A. Leaning TowerB. Big BenC. Eiffel TowerD. Colosseum答案: C88. 听力题:A _______ is used to measure the amount of heat produced in a reaction.89. 听力题:The capital of Singapore is __________.90. 选择题:What do we call a place where we can see historical artifacts?A. MuseumB. GalleryC. LibraryD. Archive91. 填空题:I like to make ______ for my classmates.92. 听力题:I see a _______ (fox) in the distance.93. 听力题:The sun is shining ________ today.94. 听力题:The __________ is the temperature at which a substance changes from solid to liquid.95. 选择题:What do we call a story with talking animals?A. FableB. NovelC. BiographyD. Poetry答案:A96. 听力题:My dad works in an ________.97. 填空题:The __________ (历史的思维模式) inspires innovation.98. 填空题:The __________ (二战后的重建) focused on rebuilding Europe.99. 填空题:A frog has long _______ for jumping.100. 听力题:Chemical reactions can be sped up by increasing the __________.。
(2021年整理)心理学专业英语词汇汇总
心理学专业英语词汇汇总编辑整理:尊敬的读者朋友们:这里是精品文档编辑中心,本文档内容是由我和我的同事精心编辑整理后发布的,发布之前我们对文中内容进行仔细校对,但是难免会有疏漏的地方,但是任然希望(心理学专业英语词汇汇总)的内容能够给您的工作和学习带来便利。
同时也真诚的希望收到您的建议和反馈,这将是我们进步的源泉,前进的动力。
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心理现象 mental phenomenon心理过程 mental process心理状态 mental state心理活动 mental activity意识 consciousness心理维度 psychological dimension心理运动 psychomotor内部活动 internal activity普通心理学 general psychology实验心理学 experimental psychology行为科学 behavioral science心身关系 mind—body relation心理机能定位 localization of mental function 心理能动性 mental activism外周论 peripheralism先天理论 nativistic theory强调遗传素质决定人心理的产生与发展。
遗传 heredity目的论 teleology认为生物和人类的活动受一定目的的引导。
活动 activity活动理论 activity theory认知心理学 cognitive psychology认知 cognition相对于情感、意志等心理过程的所有认识过程的总称。
包括知觉、注意、表象、学习记忆、问题解决、思维和言语等心理过程。
认知过程 cognitive process认知结构 cognitive structure元认知 metacognition认知失调 cognitive dissonance认知地图 cognitive map认知技能 cognitive skill认知方式 cognitive style信息 information信息论 information theory信息加工 information processing信息加工心理学 information processing psychology信息加工理论 information processing theory信息加工模型 information processing model中央处理器模型 central processor model信息储存 information storage信息提取 information retrieval人工智能 artificial intelligence, AI计算机类比 computer analogy计算机模拟 computer simulation计算机模型 computer model唯心主义心理学 idealistic psychology意动心理学 act psychology唯意志论 voluntarism唯灵论 spiritualism强调超自然精神作用。
朋友关系的存续是以相互尊重为前提的
朋友关系的存续是以相互尊重为前提的, 容不得半点强求、干涉和控制。
朋友之间, 情趣相投、脾气对味则合、则交; 反之, 则离、则绝。
朋友之间再熟悉, 再亲密, 也不能随便过头,不恭不敬。
不然,默契和平衡将被打破, 友好关系将不复存在。
每个人都希望拥有自己的私密空间,朋友之间过于随便,就容易侵入这片禁区,从而引起冲突,造成隔阂。
待友不敬,或许只是一件小事,却可能已埋下了破坏性的种子。
维持朋友亲密关系的最好办法是往来有节,互不干涉。
I thought that it was a Sunday morning in May; that it was Easter Sunday, and as yet very early in the morning. I was standing at the door of my own cottage. Right before me lay the very scene which could really be commanded from that situation, but exalted, as was usual, and solemnized by the power of dreams. There were the same mountains, and the same lovely valley at their feet; but the mountains were raised to more than Alpine height, and there was interspace far larger between them of meadows and forest lawns; the hedges were rich with white roses; and no living creature was to be seen except that in the green churchyard there were cattle tranquilly reposing upon the graves, and particularly round about the grave of a child whom I had once tenderly loved, just as I had really seen them, a little before sunrise in the same summer, when that child died.So far as we can tell, all human languages are equally complete and perfect asinstruments of communication: that is, every language appears to be well equipped as any other to say the things their speakers want to say.There may or may not be appropriate to talk about primitive peoples or cultures, but that is another matter. Certainly, not all groups of people are equally competent in nuclear physics or psychology or the cultivation of rice or the engraving of Benares brass. Whereas this is not the fault of their language. The Eskimos can speak about snow with a great deal more precision and subtlety than we can in English, but this is not because the Eskimo language (one of those sometimes miscalled 'primitive') is inherently more precise and subtle than English. This example does not come to light a defect in English, a show of unexpected 'primitiveness'. The position is simply and obviously that the Eskimos and the English live in similar environments. The English language will be just as rich in terms for 1 2 345 6 7similar kinds of snow, presumably, if the environments in which English was habitually used made such distinction as important.Similarly, we have no reason to doubt that the Eskimo language could be as precise and subtle on the subject of motor manufacture or cricket if these topics formed the part of the Eskimos' life. For obvious historical reasons, Englishmen in the nineteenth century could not talk about motorcars with the minute discrimination which is possible today: cars were not a part of their culture. But they had a host of terms for horse-drawn vehicles which send us, puzzled, to a historical dictionary when we are reading Scott or Dickens. How many of us could distinguish between a chaise, a landau, a victoria, a brougham, a coupe, a gig, a diligence, a whisky, a calash, a tilbury, a carriole, a phaeton, and a clarence ?8 91031. Which of the following statements in INCORRECT?A. The British constitution includes the Magna Carta of 1215.B. The British constitution includes Parliamentary acts.C. The British constitution includes decisions made by courts of law.D. The British constitution includes one single written constitution.32. The first city ever founded in Canada is A. Quebec.B. V ancouver.C. Toronto.D. Montreal.33. When did the Australian Federation officially come into being?A. 1770.B. 1788.C. 1900.D. 1901.34. The Emancipation Proclamation to end the slavery plantation system in the South of the U.S. was issued by A. Abraham Lincoln.B. Thomas Paine.C. George Washington.D. Thomas Jefferson.35. ________ is best known for the technique of dramatic monologue in his poems..A. Will Blake B. W.B. Yeats C. Robert Browning D. William Wordsworth36. The Financier is written by A. Mark Twain.B. Henry James.C. William Faulkner.D. Theodore Dreiser.37. In literature a story in verse or prose with a double meaning is defined as A. allegory.B. sonnet.C. blank verse.D. Rhyme.38. ________ refers to the learning and development of a language.A. Language acquisition B. Language comprehension C. Language production D. Language instruction39. The word “ Motel” comes from “motor + hotel”. This is an example of ________ in morphology.A. BackformationB. ConversionC. BlendingD. Acronym40. Language is t tool of communication. The symbol “ Highway Closed” on a highwa y serves A. an expressive function.B. an informative function.C. a performative function.D. a persuasive function.现代社会无论价值观的持有还是生活方式的选择都充满了矛盾。
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G. McMorrow, X. Wang and P.F. Whelan (1997), "A colour-to-speech sensory substitution device forthe visually impaired", Proceedings of the SPIE - The International Society for Optical Engineering, Vol. 3205 - Machine Vision Applications, Architectures, and Systems Integration VI,Pittsburgh (USA), pp 272-281.A Color-to-Speech Sensory Substitution Device for theVisually Impaired.Gabriel McMorrow a, Xiaojun Wang b, Paul F. Whelan aa Vision Systems Laboratory, Dublin City University, Irelandb Microelectronics and Materials Group, Dublin City University, IrelandAbstractA hardware device is presented that converts color to speech for use by the blind and visually impaired. The use of audio tones for transferring knowledge of colors identified to individuals was investigated but was discarded in favor of the use of direct speech. A unique color-clustering algorithm was implemented using a hardware description language (VHDL), which in-turn was used to program an Altera Corporation’s programmable logic device (PLD). The PLD maps all possible incoming colors into one of 24 color names, and outputs an address to a speech device, which in-turn plays back one of 24 voice recorded color names.To the author’s knowledge, there are only two such color to speech systems available on the market. However, both are designed to operate at a distance of less than an inch from the surface whose color is to be checked. The device presented here uses original front-end optics to increase the range of operation from less than an inch to sixteen feet and greater. Because of the increased range of operation, the device can not only be used for color identification, but also as a navigation aid. Keywords: color, sensory substitution, clustering, VHDL, speech1. Using Audio Tones for Color Recognition.This project originally intended to use audio tones as the method to convey color to a blind or visually impaired person. This original choice was partly due to the fact that the device was intended to be a small hand-held piece of hardware, and speech synthesis might complicate the design drastically. The first method attempted was the writing of VHDL code to recognize one of 16 colors, by outputting a square wave whose frequency identified each color, i.e. a color-controlled oscillator. These square wave outputs then need to be converted to sine waves with enough current to drive a small speaker. To make these audio tones more recognizable to the user, one might map these 16 tones to two octaves of the diatonic music scale. This could mean that a blind person could be trained to associate musical notes with colors by learning the musical scale. However, the use of two octaves restricts us to the use of only 16 colors. One possible method of increasing this range is to use the intensity of each tone. The intensity could be broken out into four different levels, i.e. dark red, red, bright red, pale red.But how can we transfer this knowledge of intensity to the user without using more than 16 tones? One method would be to play these 16 tones, or notes, using four different musical instruments, i.e. middle ‘C’ on the cello might indicate “dark red”, whilst middle ‘C’ on the “harmonica” might indicate “bright red”, etc. However, we now need to electronically synthesize four waveforms whichwould approximate four musical instruments, (note: they would only need to be discernable from each other as a ‘cello’ is from a ‘harmonica’). What makes middle ‘C’ on the ‘cello’ sound different from middle ‘C’ on the harmonica?The answer is the number of harmonics of the fundamental frequency of middle ‘C’ generated by each instrument, coupled with the relative amplitudes of these harmonics. 11Rather than electronically synthesize the sound of each instrument, the speech chip used in this project, see Section 5, could be used to record different instruments. We accept that there may be applications where the use of audio tones may be preferable to the spoken color name, but we contend that in this particular application, the use of direct speech is by far the better choice.2. Color ClusteringWhat is color clustering and is it necessary? The answer to these questions will become intuitively clear to the reader, by examining the results of trying to identify colors without using a clustering technique. Before proceeding, however, let us examine some fundamental properties of color. Every color we see, is in fact a combination of the three primary colors, red, green and blue. The “color cube” illustrated in Figure 1, is a graphical representation of this fact.As a first attempt at identifying colors, the following technique was examined. The first step in color identification had to be splitting the incoming light into it’s red, green, and blue primary component intensities. In order to use digital circuitry to decide what the incoming color is, these primary intensities need to be converted to analog voltages and then digitized.This naturally leads to the following question: What should the resolution of the digitization process be?, i.e. how many bits should the analog RGB components be digitized into. Suppose that 2-bit digitization were used. This would provide the ability to discern 4 different shades of red, green, and blue. This in-turn implies we have the ability to identify 64 colors. If such a scheme were used, it would be necessary to give names to these colors. To aid in naming these colors, they first needed to be displayed.Once displayed, it became obvious that it was futile to try to give names to these colors without using some kind of quantitative method. For this purpose an RGB Color Table3was used. The disadvantage of using this method would be the use of color names not used in daily conversation, names such as “Cinnabar Green”, or “Medium Aqua Marine”. These are names that most sited people might have difficulty visualizing in their minds, and are not suitable for describing colors to people blind since birth. To a certain extent this is a debatable point, however the next disadvantage is particularly critical.RedFigure 1. Color cube.The diagonal of the color-cube shown in Figure 1, is a line in color-space where the red, green, and blue components are equal to each other. This in fact is the grayscale, which extends from black, through dark gray, and finally to white. This diagonal line of grayscale is extremely sensitive, such that points slightly off the diagonal contain color, not grayscale. When other colors other than grayscale are explored the error does not appear as serious, as it is difficult to tell, for example, close shades of green apart, however, for grayscale, small tints of color are noticeable. The only way to reduce this quantization error is by increasing the color resolution, i.e. increasing the number of shades of the primary colors, red, green, and blue. It was found that 4-bit digitization gave a visually acceptable color quantization error for grayscale color bins.However, using 4-bit digitization provides the ability to discern 24 x 24 x 24 = 4096 color bins. Does this imply we need to derive 4096 different color names? The answer is no, because there are large regions or clusters of the same colors. For example, there are large regions of yellow, orange, green etc. This was observed when using MATLAB’s Image Processing Toolbox to display colors found at the centroid of 4096 color bins. Having the colors displayed enables the viewer to visually segregate or cluster regions of red, orange, yellow, etc. Figure 2 illustrates 3 of 16 layers of the color cube digitized to 4-bit Red, Green, and Blue.3. Design of Cluster Logic Using VHDLAs logic designs get larger, gate-level descriptions become unmanageable, making it necessary to describe designs in more abstract ways, and mandatory to adopt a higher-level, top-down design approach.1. Logic diagrams and Boolean equations have been used as methods for hardware description, but the complexity of these methods increases rapidly as the system complexity increases. Hardware Description Languages (HDLs) evolved as a solution. An HDL is similar to a high-level software programming language and provides a means of:1). Precise yet concise description of a design at desired level of detail;2). Convenient documentation to generate users manuals, service manuals, etc.;3). Design capture for automatic design systems, e.g. high-level synthesis tools, and siliconcompilers;4). Incorporation of design changes and corresponding changes in documentationefficiently;5). Design/user communication interface at the desired level of abstraction.In 1987 the IEEE Std-1076 VHDL (Very High Speed Integrated Circuit Hardware Description Language), compiler became an industry standard with full support of the United States Department of Defense (US DOD). As of 30 September 1988, VHDL is mandated by the US DOD for documentation for all application specific integrated circuit (ASIC) designs developed in military contracts.In VHDL, a hardware component is represented by the design entity, which in turn is a composite of an entity declaration and an architecture body. The entity declaration provides the “external” view of the component’s ports, which are the points through which data flows into the device from the outside world. This includes the component’s ports, which are the points through which data flows into and out of the component. 2 . The entity declaration for the clustering device is as follows:This VHDL code defines three input ports to the device, four bits red, green, and blue, and defines the output to be a 10-bit address to be sent to the speech chip, see Section 5.Figure 2.3 of 16 layers of the color cube digitized to 4-bit Red, Green, and Blue.The architecture body provides the “internal view”; it describes the behavior or the structure of the component. The following VHDL is a shortened version of the architecture body used to define the behavior of the cluster device, and is almost a direct transcription of the visual clustering shown in Figure 2.The architecture body has a process sensitivity list. This means the device is inactive, and only becomes active when it senses a change of the input signals red, green, and blue. The entire architecture essentially makes decisions of the form: if there is this amount of blue, then if there is this amount of green, and finally, if there is this amount of red, then the color is pink, say. Therefore, output the appropriate 10-bit address to enable the speech chip to play back the voice recorded color name, “pink”.The VHDL code was compiled and exhaustively simulated by stimulating with all 4096 possible combinations of red, green, and blue.8 The code was debugged until all simulation outputs were as expected.4. Front End Optics and SensorsOf the two color-to-speech conversion systems available on the market at the time of writing, both need to be operated within an inch of the surface whose color is to be checked. A main goal of this research was to design a device, which would operate over much larger ranges. The use of a color camera to convert the incoming light to current was discarded in favor of a trio of photodiodes. This was done since another goal of this research was to keep the cost of the device to a possible end-user as low as possible to enable it to be purchased by Health Authorities.In order for the device to operate at greater distance ranges, it is necessary to use a lens to gather the incoming light, and project it onto the light sensitive surface of the photodiodes. In addition, the lens is required to have a narrow field of view (FOV). The narrow field of view is important so that the color of an object’s surface is tested at a minimal surface area. This is to avoid the identified color being an averaged color, i.e. the result of checking a large FOV encompassing multiple surfaces of different colors.It would be preferable to have the minimal surface area being checked to remain constant over a large range of operating distances. This would be possible only through the use of an auto-zoom lens. Consideration of the increase in overall cost of the device with an auto-zoom lens resulted in the use of a fixed single lens. The disadvantage of using a fixed single lens is that the minimal area being checked grows in proportion to the distance the surface being checked is from the lens. Therefore, using a single fixed lens implies that the continuity of color of the surface in question determines the range the device must be operated at to get a correct color reading. For example, pointing the device at a cloudless sky should return blue because although the minimal surface area being checked is large, the sky should be a constant blue over all the area being checked. Similarly, the green grass in a field should return green when the device operates at large ranges. However, for surfaces whose color changes over areas of, say, an inch diameter, the device should be within 8 feet of the surface, to get correct color readings, etc.As already indicated, it is necessary that the light gathering lens of the device have a narrow FOV. Figure 3 illustrates how a plano-convex lens can be used to limit a detector’s FOV.5 The angle β subtends half the field of view of the lens, and is given by:where D2 is the diameter of the photodiode used to convert the light to current, and f is the focal length of the lens. Placing the detector one focal length behind the lens ensures focus of objects one focal length in front of the lens. However, a focussed image is not important in this application. It was found that by placing his eye one focal length behind the lens of choice, using plastic tubing between eye and lens to exclude all light but that which comes through the lens, that objects one focal length in front of the lens were sharply focussed. Surfaces at distances greater than one focal length in front of the lens become increasingly blurred. However, this did not appear to affect the color of the surface. It was also seen that the reduction in FOV resulted in a single incoming color at a time, scanning over an average sized room.Figure 3. Using a plano-convex lens to limit a detector’s FOV.Obviously it is important to center the photosensor on the axial line of the lens. Knowing where the light will go is, however, only the first step in the design of a light projection system; it is just as important to know how much light is transmitted. The light gathering power of a lens is given by:Figure 3 shows how the numerical aperture controls the angle of light accepted by the lens. As the F_number decreases, θ (the acceptance angle) increases and the lens becomes capable of gathering more light. In the design of any lens system it is important to consider the term throughput (TP), a quantitative measure of transmitted light energy. Because the photodiode is an area and not a point, lens diameter affects throughput even when the F_number remains constant. The following equations were used to calculate the throughput of the lens.number F aperture numerical NA lens of diameter D lens of length focal f number F _5.0)()()(_==2222222)21(**)()4(*5.0*)1(1;12;22D G TP Throughput Y X Z Z G Y X Z D f Y f D X π=−−=++===radians f D *22=βBecause the device is to be physically small, a small lens diameter is required whilst at the same time maintaining a large throughput. For example for a particular lens system the TP’s for each of three lens choices are: TP (6mm lens) = 16.77, TP(12mm lens) = 19.04, and TP(25mm lens) = 19.69. In this example the 12mm diameter lens is the best compromise between diameter and throughput. The following table is a subset of calculations that resulted in a final choice of the plano-convex lens used in this application:Using the table as a guideline, and given a restricted choice of C-Mount lens holders led to the choice of the 100mm focal length lens with diameter 19.8 mm. The relatively small value of TP = 0.175 imply that the photodiodes will output smaller currents, but this may be compensated for by electrically amplifying the photodiode currents.At this stage in the design, it becomes necessary to choose a particular photodiode from a vast array commercially available devices. All photodiode specification sheets contain a graph showing the relative spectral response characteristics of the sensor. This plots the relative sensitivity of the sensor versus the wavelength of incoming light in nanometers (nm). The visible spectrum of light ranges from 400nm to about 700nm. The color bands of the visible spectrum span the following wavelengths: 11From 400-450nm VioletFrom 450-500nm BlueFrom 500-550nm GreenFrom 550-600nm YellowFrom 600-650nm OrangeFrom 650-700nm RedIt is known that the human eye’s response to light is most sensitive or peaks in the Green, or 550-600nm wavelengths. Searching through the Toshiba Photo Sensor Catalog, in particular, it appeared that most devices peak in the near if not infrared. However, a photo-diode whose response matches closely the human eye was found. The device is the BPW 21 photodiode, whose main application is exposure and color measurement. It comes in a hermetically sealed case, has a radiant sensitive area of 7.5 mm2, and it’s typical sensitivity is 7 nA/lux. Typical room light is about 700 lux.Before considering the amplification used with these photodiodes, the important topic of color filtering needs to be addressed. The incoming light needs to be split up into it’s primary color components, (red, green, and blue), prior to being converted to electrical signals. Various color filter options are available. Acrylic filter material is cheap but the filter responses were found to be substandard for this application. Glass color separation filters have excellent filter responses and are used in machine vision applications. Two choices of design for color separation was examined, see Figure 4.Choice B requires three lenses. These would have to be small in diameter and arranged in a mosaic structure similar to a fly’s eyes. Choice A is by far the better choice as only a single lens is used whose diameter may be large. Choice A is made possible by the availability of Color Separating Dichroic Filters. A light filtering system using a 45 degree blue reflector/corrector, 45 degree red reflector/corrector, and green corrector set allow a single source of light to be split into it’scomponent parts. An aluminum structure was designed and manufactured to hold the glass filters at their appropriate angles, and support the three photodiodes.Figure 4. Color separation design choices.5. Hardware DesignAnalog to Digital ConversionAssuming that the incoming primary component intensities have already been converted to analog voltages, it is then necessary to convert the RGB analog signals to 4-bit binary logic levels. This will form the appropriate input into the cluster device described previously. The A/D device chosen was Analog Devices’ AD7575, which uses the successive approximation conversion technique. This provides a necessary high conversion speed of 5 microseconds. A standard 555 timer was used to control the start of conversion and the reading of data from the AD7575.Light Sensor AmplificationNext in consideration is the amplification of the individual red, green, and blue signals coming from the photodiodes. It is desired that the A/D converters output 4-bit binary patterns spanning the range of 0 to 15. To accomplish this it is necessary for the output signals of the photodiodes to span the analog voltage range 0 to 2Vref, i.e. 0 to 2.4V. Single supply TLC271 operational amplifiers were chosen for amplification using the following configuration: 6Figure 5. Light sensor amplification.Through examination it was found that to increase the ambient light rejection, i.e. current flows through the photodiode when all light is absent, that R2 should be small. This implies that the gain is BLUE RED GREEN BLUE RED GREEN Choice Bessentially R4 / R3. The following values were used: R2 = 1 kΩ, R4 = 2 MΩ potentiometer, R3 = 1 kΩ. R4 was set with the sensor receiving pure daylight, i.e. light reflected from bright cloud cover to yield 2.4V, the maximum voltage range of the A/D converter. This resulted in all LED’s on the outputs of the A/D converter to be lit. By increasing covering the face of the photodiode, the LED’s were seen to go through the 4-bit binary pattern from 15 to 0.The ISD2590 Single-Chip Voice Record/Playback DeviceThe ISD25904, manufactured by Information Storage Devices provides an excellent method for verbal description of identified colors required in this project. It allows cueing of recorded color names, which can then be directly addressed. Therefore, once the incoming red, green, and blue intensities have been digitized, and clustering performed by the Altera Programmable Logic Device, one of 24 colors (addresses) can be input to the speech chip to cause it to “speak” out the name of the color. This EEPROM device allows analog data to be written directly into a single cell without A/D or D/A conversion. This results in increase in density over equivalent digital methods, and non-volatile storage. The ISD2590 allows a total of 90 seconds recording time. It provides excellent voice quality, and the two output pins provide direct speaker drive capability of about 12.5 mW RMS (25 mW peak) into a 16 Ω speaker. This is enough to be clearly heard from the other side of an average room. The external components; a microphone, loudspeaker, switches, a few resistors and capacitors, and a power source, are all that is required to build a complete voice record/playback system. All other functions; preamplifier, filters, AGC, power amplifier, control logic and analog storage, are performed on-chip, see Figure 6.The ISD2590 provides a total of 90 seconds of recording time, and a total of 600 individual messages. This gives rise to the term message resolution, which is 90/600 = 150 milliseconds. The address bits control the message start pointer (MSP). The value of an address to access a particular message x seconds into the recording is given as follows:Address (in decimal) = (x seconds) / (message resolution)i.e. to access a message 1.5 seconds into the recording use address = 1.5 / .15 = 10. To access a message 3.0 seconds into the recording use address = 3.0/.15 = 20, etc. These addresses, 10, 20,30 etc. require that each message be exactly 1.5 seconds long. However, it is impossible to record each different color name with a microphone, and have each recording exactly 1.5 seconds long. It was for this reason that it was decided to use the Windows Digital Speech Record/Processing package COOL. COOL provides a variety of editing features such as amplification and message length adjustment of the digitally sampled and stored recording. This allowed the calculation of the addresses needed to be presented to the speech chip to access each of 24 different color names, for example:COLOR NAMES Address (binary)into chipAddress(Decimal)into chipTime in secondsinto the totalrecordingDARK RED “0000000000” 0 0RED “0000001110” 14 2.1 VIOLET RED “0000011100” 28 4.2PINK “0000100111” 39 5.85Etc. Etc. Etc. Etc.6. ConclusionsAt the time of concluding this report we were still awaiting delivery of the red 45-degree reflector color filter. This restricted the full testing of the device. However, by manipulating light falling on the unfiltered red sensor, various intensities of RED could be achieved. When the device was presented with full blue, full red, and no green, pressing a button on the speech chip resulted in it “playing back” the word MAGENTA. Full red only generated the word RED, etc. This demonstrated correct operation of the A/D converters, the cluster logic and the speech chip. By tying the inputs of the A/D converters together, the grayscale was tested using a variable DC level in lieu of the sensors. For 0VDC the device said BLACK. When the DC level was increased it said DARK GRAY, GRAY, and finally WHITE at DC level 2.4V.This pseudo testing of the overall device brought to light many areas of improvement. The gain of the sensors is definitely a calibration issue. Lens choice provides a tradeoff between shorter focal length (larger FOV) versus lens diameter to provide larger throughput (TP). These tradeoff and calibration issues require further field testing of the device.Figure 6. Block diagram of complete system, and photograph of prototype.7. References1. X. Wang, “VHDL and High-Level Logic Synthesis”, Course Notes, School of ElectronicEngineering, Dublin City University, 1994.2. R. Lipsett, VHDL : Hardware Description and Design, Kluwer Academic Publishers, 1989.3. C. A. Lindley, Practical Ray Tracing in C, Wiley 1992.4. Information Storage Devices’, “Application Notes and Design Manual for ISD’s Single-ChipVoice Record/Playback Devices”, July 1994.5. Edmund Scientific, Annual Reference Catalog for Optics, Science, and Education, 19946. Horowitz and Hill, The Art of Electronics, 19927. E. Parr, “IC 555 Projects”, Bernard Babani 19948. Mentor Graphics Corp., “QuickVHDL User and Reference Manual”, April 1994.9. Altera Corp., “MAX+PLUS II Getting Started”, 199410. Altera Corp., “Altera Data Book”, 1993.11. Sears, Zemansky, and Young, University Physics, Addison Wesley, 1976。