无卤素板料的data-sheet S1155 MSDS
危险化学品特性表
危险化学品特性表（自制）危险化学品特性表（自制） (1)（1）丙烯酸 (3)（2）甲酸 (4)（3）氢氟酸 (6)（1）N,N-二甲基甲酰胺 (7)（2）丙烯酸丁酯 (8)（1）萘 (10)（2）乌洛托品 (11)（1）氯酸钠 (13)（1）四氯乙烯 (15)（2）二氯甲烷 (17)3.1.1.1丙酮 (18)3.1.1.2-丁酮 (20)3.1.1.3甲醇 (21)3.1.1.4乙醇 (23)3.1.1.5 环己酮 (24)3.1.1.6异丙醇 (25)3.1.1.7 甲苯 (27)3.1.1.8 1，2-二甲苯 (29)3.1.1.9 乙醚 (30)3.1.1.10 乙酸乙酯 (32)3.1.1.11过氧化氢 (33)3.1.1.12高锰酸钾 (35)3.1.1.13重铬酸钾 (36)3.1.1.14硝酸银 (38)3.1.1.15苯酚 (39)3.1.1.16三氯甲烷 (41)3.1.1.17四氯化碳 (42)3.1.1.18氢氧化铵水溶液 (44)3.1.1.19氢氧化钠 (45)3.1.1.20氢氧化钾 (46)3.1.1.21甲醛 (47)3.1.1.22盐酸 (49)3.1.1.23硝酸 (51)3.1.1.24硫酸 (52)3.1.1.25 乙酸 (54)3.1.1.26三氯乙酸 (56)3.1.1.27氢氟酸 (57)3.1.1.28次氯酸钠 (59)3.1.1.29亚硫酸氢钠 (60)（4）纯苯 (62)（5）1,1-二氯乙烷 (63)（7）正丁醇 (65)（10）二（正）丁醚 (66)（11）丙烯酸正丁酯 (68)（4）冰醋酸 (69)三氯乙醛 (70)硝酸钠 (72)连二亚硫酸钠 (73)石油醚 (74)对二甲苯 (76)氧 (77)⑺乙酸酐 (80)⑻2-丁酮 (81)（1）丙烯酸表3.1-1 丙烯酸简介（2）甲酸表3.1-2甲酸简介（3）氢氟酸表3.1-3氢氟酸简介（1）N,N-二甲基甲酰胺表3.1-4 N,N-二甲基甲酰胺简介（2）丙烯酸丁酯表3.1-5丙烯酸丁酯简介（1）萘表3.1-6萘简介（2）乌洛托品表3.1-7乌洛托品简介（1）氯酸钠表3.1-8氯酸钠简介（2）亚硝酸钠表3.1-9亚硝酸钠简介（1）四氯乙烯表3.1-10四氯乙烯简介（2）二氯甲烷表3.1-11二氯甲烷简介3.1.1.1丙酮3.1.1.2-丁酮3.1.1.3甲醇3.1.1.4乙醇3.1.1.5 环己酮3.1.1.6异丙醇3.1.1.7 甲苯3.1.1.8 1，2-二甲苯3.1.1.9 乙醚3.1.1.10 乙酸乙酯3.1.1.11过氧化氢3.1.1.12高锰酸钾3.1.1.13重铬酸钾3.1.1.14硝酸银3.1.1.15苯酚3.1.1.16三氯甲烷3.1.1.17四氯化碳3.1.1.18氢氧化铵水溶液3.1.1.19氢氧化钠3.1.1.20氢氧化钾3.1.1.21甲醛3.1.1.22盐酸。
铝箔英文版的MSDS
Material Safety Data SheetMaterial Name: WROUGHT ALUMINUM PRODUCTS, 1xxx SERIES ALLOYS ID: 663* * * Section 1 - Chemical Product and Company Identification * * *Chemical Formula: MixtureProduct Use: Various fabricated aluminum parts and products.Other Designations: 1xxx Series Alloys, 1xxx Cladding, 1350BS, 1435, 990LR, 995LR, C01A, C49A, C65A, C99A,C01B, C18B, C19B, C27B, C178, C479, C481, C531, C794, C798, CZ60, Clad 1100, KB10, MD56, MD115, MD119, MD230, MD251, MD335, RA91, RA179, W006.Alcoa Inc.Phone: Health and Safety: 1-412-553-4649201 Isabella StreetPittsburgh, PA 15212-5858Emergency Information:USA: Chemtrec: 1-800-424-9300 or 1-703-527-3887 Alcoa: 1-412-553-4001* * * Section 2 - Composition / Information on Ingredients * * *CAS #Component Percent7429-90-5Aluminum>997440-47-3Chromium<0.05 Component InformationAdditional compounds which may be formed during processing are listed in Section 8.* * * Section 3 - Hazards Identification * * *Emergency OverviewSolid. Silvery. Odorless. Non-flammable as supplied. Small chips, fine turnings and dust from processing may be readily ignitable.Explosion/fire hazards may be present when (See Sections 5, 7 and 10 for additional information):= Dust or fines are dispersed in the air.= Chips, dust or fines are in contact with water.= Dust or fines are in contact with certain metal oxides (e.g. rust).= Molten metal is in contact with water/moisture or certain metal oxides.Dust and fume from processing can cause irritation of eyes, skin and upper respiratory tract.Potential Health Effects(If dusts or fumes are generated by processing)EyesCan cause irritation.SkinCan cause irritation.InhalationCan cause irritation of upper respiratory tract and other health effects listed below. Cancer hazard.Health Effects of IngredientsChromium dust Can cause irritation of eyes, skin and respiratory tract. Chromium and trivalent chromiumIARC/NTP: Not classified by IARC.Aluminum dust, fines and fumes Low health risk by inhalation. ACGIH: Listed as nuisance dust (milling,cutting, grinding).Some products are supplied with a lubricant/oil coating or have residual oil from the manufacturing process. OilCan cause irritation of skin. Skin contact (prolonged or repeated): Can cause dermatitis. Mineral oils, untreated or mildly refined Studies with experimental animals by skin contact have found skin tumors. IARC/NTP: Listed as "known to be a human carcinogen" by the NTP. Listed as carcinogenic to humans by IARC (Group 1)*.Health Effects Of Additional Compounds Which May Be Formed During ProcessingHexavalent chromium (Chrome VI) Can cause irritation of eyes, skin and respiratory tract. Skin contact: Can cause irritant dermatitis, allergic reactions and skin ulcers. Chronic overexposures: Can cause perforation of the nasal septum, respiratory sensitization, asthma, fluid in the lungs (pulmonary edema), lung damage, kidneydamage, lung cancer, nasal cancer and cancer of the gastrointestinal tract. IARC/NTP: Listed as "known to be a human carcinogen" by the NTP. Listed as carcinogenic to humans by IARC (Group 1)*.Alumina Low health risk by inhalation. ACGIH: Listed as nuisance dust.If the product is heated well above ambient temperatures or machined, oil vapor or mist may be generated. Oilvapor and mist Can cause irritation of respiratory tract. Acute overexposures: Can cause bronchitis, asthma,headache, central nervous system effects (nausea, dizziness and loss of coordination) and drowsiness (narcosis).Welding, plasma arc cutting, and arc spray metalizing can generate ozone. Ozone Can cause irritation of eyes, nose and upper respiratory tract. Acute overexposures: Can cause shortness of breath, tightness of chest,headache, cough, nausea and narrowing of airways. Effects are reversible on cessation of exposure. Acuteoverexposures (high concentrations): Can cause respiratory distress, respiratory tract damage, bleeding and fluid in the lungs (pulmonary edema). Effects can be delayed up to 1-2 hours. Additional information: Studies withexperimental animals by inhalation have found genetic damage, reproductive harm, blood cell damage, lung damage and death.Welding fumes IARC/NTP: Listed as possibly carcinogenic to humans by IARC (Group 2B)*. AdditionalInformation: In one study, occupational asthma was associated with exposures to fumes from aluminum welding.Plasma arc cutting can generate oxides of nitrogen. Oxides of nitrogen (NO and NO2) Can cause irritation ofeyes, skin and respiratory tract. Acute overexposures: Can cause reduced ability of the blood to carry oxygen(methemaglobin). Can cause cough, shortness of breath, fluid in the lungs (pulmonary edema) and death. Effects may be delayed up to 2-3 weeks. Nitrogen dioxide (NO2) Chronic overexposures: Can cause scarring of the lungs (pulmonary fibrosis).*IARC ClassificationsGroup 1: The agent is carcinogenic to humans. There is sufficient evidence that a causal relationship existedbetween exposure to the agent and human cancer.Group 2B: The agent is possibly carcinogenic to humans. Generally includes agents for which there is limitedevidence in the absence of sufficient evidence in experimental animals.Medical Conditions Aggravated By Exposure to the ProductAsthma, chronic lung disease, and skin rashes.* * * Section 4 - First Aid Measures * * *First Aid: EyesFlush eyes with plenty of water or saline for at least 15 minutes. Consult a physician.First Aid: SkinWash skin with soap and water for at least 15 minutes. Consult a physician if irritation persists.First Aid: InhalationRemove to fresh air. If unconscious or severely injured, check for clear airway, breathing and presence of pulse.Perform CPR if there is no pulse or respiration. Consult a physician.* * * Section 5 - Fire Fighting Measures * * *Flammable PropertiesThis product does not present fire or explosion hazards as shipped. Small chips, turnings, dust and fines fromprocessing may be readily ignitable.Fire/ExplosionMay be a potential hazard under the following conditions:= Dust or fines dispersed in the air can be explosive. Even a minor dust cloud can explode violently.= Chips, dust or fines in contact with water can generate flammable/explosive hydrogen gas. Hydrogen gas could present an explosion hazard in confined or poorly ventilated spaces.= Fines and dust in contact with certain metal oxides (e.g., rust). A thermite reaction, with considerable heatgeneration, can be initiated by a weak ignition source.= Molten metal in contact with water/moisture or other metal oxides (e.g., rust). Moisture entrapped by moltenmetal can be explosive. Contact of molten aluminum with other metal oxides can initiate a thermite reaction. Extinguishing MediaUse Class D extinguishing agents on dusts, fines or molten metal. Use coarse water spray on chips and turnings.DO NOT USE: Halogenated agents on small chips, dusts or fines. Water around molten metal.Fire Fighting Equipment/InstructionsFire fighters should wear NIOSH approved, positive pressure, self-contained breathing apparatus and full protective clothing when appropriate.* * * Section 6 - Accidental Release Measures * * *Small/Large SpillIf molten: Contain the flow using dry sand or salt flux as a dam. Do not use shovels or hand tools to halt the flow of molten aluminum. Allow the spill to cool before remelting as scrap.* * * Section 7 - Handling and Storage * * *Handling/StorageProduct should be kept dry. Avoid generating dust. Avoid contact with sharp edges or heated metal. Hot and cold aluminum are not visually different.Requirements for Processes Which Generate Dusts or FumesIf processing of these products includes operations where dust or extremely fine particulate is generated, obtain and follow the safety procedures and equipment guides contained in Aluminum Association Bulletin F-1 and National Fire Protection Association (NFPA) brochures listed in Section 16. Cover and reseal partially empty containers. Use non-sparking handling equipment. Provide grounding and bonding where necessary to prevent accumulation of staticcharges during dust handling and transfer operations. (See Section 15).Local ventilation and vacuum systems must be designed to handle explosive dusts. Dry vacuums and electrostatic precipitators must not be used. Dust collection systems must be dedicated to aluminum dust only and should be clearly labeled as such. Do not co-mingle fines of aluminum with fines of iron, iron oxide (rust) or other metal oxides.Do not allow chips, fines or dust to contact water, particularly in enclosed areas.Avoid all ignition sources. Good housekeeping practices must be maintained.Requirements for Remelting of Scrap Material and/or IngotMolten metal and water can be an explosive combination. The risk is greatest when there is sufficient molten metal to entrap or seal off the water. Water and other forms of contamination on or contained in scrap or remelt ingot are known to have caused explosions in melting operations. While the products may have minimal surface roughness and internal voids, there remains the possibility of moisture contamination or entrapment. If confined, even a fewdrops of water can lead to violent explosions.All tooling and containers which come in contact with molten metal must be preheated or specially coated and rust free. Molds and ladles must be preheated or oiled prior to casting. Any surfaces that may contact molten metal(e.g., concrete) should be specially coated.Drops of molten metal in water (e.g. from plasma arc cutting), while not normally an explosion hazard, can generate enough flammable hydrogen gas to present an explosion hazard. Vigorous circulation of the water and removal of the particles minimize the hazards.During melting operations, the following minimum guidelines should be observed:= Inspect all materials prior to furnace charging and completely remove surface contamination such as water, ice, snow, deposits of grease and oil or other surface contamination resulting from weather exposure, shipment, orstorage.= Store materials in dry, heated areas with any cracks or cavities pointed downwards.= Preheat and dry large or heavy items such as ingot adequately before charging into a furnace containing molten metal. This is typically done by use of a drying oven or homogenizing furnace. The drying cycle should bring theinternal metal temperature of the coldest item of the batch to 400°F and then hold at that temperature for 6 hours.* * * Section 8 - Exposure Controls / Personal Protection * * *Engineering ControlsUse with adequate explosion-proof ventilation to meet the limits listed in Section 8.Personal Protective EquipmentRespiratory ProtectionUse NIOSH-approved respiratory protection as specified by an Industrial Hygienist or other qualified professional if concentrations exceed the limits listed in Section 8. Suggested respiratory protection: P95Eye ProtectionWear safety glasses/goggles to avoid eye contact.Skin ProtectionWear impervious gloves to avoid repeated or prolonged skin contact with residual oils and to avoid any skin injury. GeneralPersonnel who handle and work with molten metal should utilize primary protective clothing like face shields, fire resistant tapper's jackets, leggings, spats and similar equipment to prevent burn injuries. In addition to primaryprotection, secondary or day-to-day work clothing that is fire resistant and sheds metal splash is recommended for use with molten metal.Minimize breathing oil vapors and mist. Remove oil contaminated clothing; launder or dry-clean before reuse.Remove oil contaminated shoes and thoroughly clean and dry before reuse. Cleanse skin thoroughly after contact, before breaks and meals, and at the end of the work period. Oil coating is readily removed from skin with waterless hand cleaners followed by a thorough washing with soap and water.Exposure GuidelinesA: General Product InformationAlcoa recommends an Occupational Exposure Limit for Oil Mist of 0.5 mg/m3 TWA.B: Component Exposure LimitsAluminum (7429-90-5)ACGIH10 mg/m3 TWA (metal dust)OSHA15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)Chromium (7440-47-3)ACGIH0.5 mg/m3 TWAOSHA 1 mg/m3 TWAC: Additional Compounds Which May be Formed During ProcessingAlumina (non-fibrous) (1344-28-1)ACGIH as Al: 10 mg/m3 TWA (The value is for total dust containing no asbestos and < 1%crystalline silica)OSHA15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction)Chromium (II) compounds (Not Available)OSHA0.5 mg/m3 TWA (as Cr)Chromium (III) compounds (as Cr) (Not Available)ACGIH as Cr: 0.5 mg/m3 TWAChromium (VI) compounds- water soluble (Not Available)ACGIH0.05 mg/m3 TWAChromium (VI) compounds (certain water insoluble forms) (Not Available)ACGIH0.01 mg/m3 TWAChromic acid and chromates (7738-94-5)OSHA and chromates: C 1 mg/10m3Welding fumes (NOC) (Not Available)ACGIH 5 mg/m3 TWAOzone (10028-15-6)ACGIH Heavy work: 0.05 ppm TWA; Moderate work: 0.08 ppm TWA; Light work: 0.1 ppm TWA;heavy, moderate or light work, <= 2Hrs: 0.20 ppmOSHA0.1 ppm TWA; 0.2 mg/m3 TWANitrogen dioxide (10102-44-0)ACGIH 3 ppm TWAACGIH 5 ppm STELOSHA C 5 ppm; C 9 mg/m3Nitric oxide (10102-43-9)ACGIH25 ppm TWAOSHA25 ppm TWA; 30 mg/m3 TWA* * * Section 9 - Physical & Chemical Properties * * *Appearance:SilveryPhysical State:Solid: sheet, plate, wire, rod,bar, extrusion, forgings, etc.Boiling Point:Not applicable Melting Point:Range: generally 1190-1215 ºF(643-657 ºC)Vapor Pressure:Not applicable Vapor Density:Not applicableSolubility Water:None Specific Gravity:See DensitypH Level:Not applicableDensity:Range: generally 2.70-2.71g/cm³ (0.097-0.098 lb/in³)Odor:None Odor Threshold:Not applicableOctanol-Water Coefficient:Not applicable* * * Section 10 - Chemical Stability & Reactivity Information * * *StabilityStable under normal conditions of use, storage, and transportation as shipped.Conditions to AvoidChips, fines, dust and molten metal are considerably more reactive with the following:= Water: Slowly generates flammable/explosive hydrogen gas and heat. Generation rate is greatly increased with smaller particles (e.g., fines and dusts). Molten metal can react violently/explosively with water or moisture,particularly when the water is entrapped.= Heat: Oxidizes at a rate dependent upon temperature and particle size.= Strong oxidizers: Violent reaction with considerable heat generation. Can react explosively with nitrates (e.g., ammonium nitrate and fertilizers containing nitrate) particularly when heated or molten.= Acids and alkalis: Reacts to generate flammable/explosive hydrogen gas. Generation rate is greatly increased with smaller particles (e.g., fines and dusts).= Halogenated compounds: Many halogenated hydrocarbons, including halogenated fire extinguishing agents, can react violently with finely divided aluminum.= Iron oxide (rust) and other metal oxides (e.g., copper and lead oxides): A violent thermite reactiongenerating considerable heat can occur. Reaction with aluminum fines and dusts requires only very weak ignition sources for initiation. Molten aluminum can react violently with iron oxide without external ignition source.= Iron powder and water: An explosive reaction forming hydrogen gas occurs when heated above 1470°F(800°C).* * * Section 11 - Toxicological Information * * *Health Effects of IngredientsA: General Product InformationNo information available for product.B: Component Analysis - LD50/LC50No LD50/LC50's are available for this product's components.CarcinogenicityA: General Product InformationNo information available for product.B: Component CarcinogenicityChromium (7440-47-3)ACGIH A4 - not classifiable as a human carcinogenIARC Monograph 49; 1990* * * Section 12 - Ecological Information * * *EcotoxicityA: General Product InformationNo information available for product.B: Component Analysis - Ecotoxicity - Aquatic ToxicityNo ecotoxicity data was found for this product's components.Environmental FateNo information available for product.* * * Section 13 - Disposal Considerations * * *Disposal InstructionsReuse or recycle material whenever possible. Material may be disposed of at an industrial landfill.US EPA Waste Number & DescriptionsA: General Product InformationRCRA Status: Must be determined at time material is disposed. If material is disposed as waste, it must becharacterized under RCRA according to 40 CFR, Part 261, or state equivalent in the U.S.B: Component Waste NumbersRCRA waste codes other than described under Section A may apply depending on use of product. Refer to 40 CFR 261 or state equivalent in the U.S.* * * Section 14 - Transportation Information * * *Special TransportationPSN #1PSN #2PSN #3PSN #4Notes:(1)Proper Shipping Name:Not RegulatedHazard Class:-UN NA Number:-Packing Group:-RQ:-Other - Tech Name:-Other - Marine Pollutant:-Notes:(1)When "Not regulated," enter the proper freight classification, "MSDS Number," and "Product Name" on theshipping paperwork.Canadian TDG Hazard Class & PIN:Not regulated* * * Section 15 - Regulatory Information * * *US Federal RegulationsA: General Product InformationAll electrical equipment must be suitable for use in hazardous atmospheres involving aluminum powder inaccordance with 29 CFR 1910.307. The National Electrical Code, NFPA 70, contains guidelines for determining the type and design of equipment and installation which will meet this requirement.B: Component AnalysisThis material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).Aluminum (7429-90-5)SARA 313:form R reporting required for 1.0% de minimis concentration (fume or dust only) Chromium (7440-47-3)SARA 313:form R reporting required for 1.0% de minimis concentrationCERCLA:final RQ = 5000 pounds (2270 kg) (no reporting of releases of this hazardous material isrequired if the diameter of the pieces of the solid metal released is equal to or exceeds0.004 inches)SARA 311/312 Physical and Health Hazard Categories:Immediate (acute) Health Hazard:Yes, if particulates/fumes generated during processing.Delayed (chronic) Health Hazard:Yes, if particulates/fumes generated during processing.Fire Hazard:NoSudden Release of Pressure:NoReactive:Yes, if moltenState RegulationsA: General Product InformationPENNSYLVANIA "Special Hazardous Substance": Chromium compounds, hexavalentChemical(s) known to the State of California to cause cancer: Hexavalent chromiumB: Component Analysis - StateThe following components appear on one or more of the following state hazardous substances lists: Component CAS #CA FL MA MN NJ PAAluminum7429-90-5Yes Yes Yes Yes Yes Yes Chromium7440-47-3Yes Yes Yes Yes Yes Yes Other RegulationsA: General Product InformationIn reference to Title VI of the Clean Air Act of 1990, this material does not contain nor was it manufactured using ozone-depleting chemicals.B: Component Analysis - WHMIS IDLThe following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:Component CAS #Minimum ConcentrationAluminum7429-90-51% item 47 (197)C: Component Analysis - InventoryComponent CAS #TSCA DSL EINECS AUST.MITIAluminum7429-90-5Yes Yes Yes Yes NoChromium7440-47-3Yes Yes Yes Yes NoNote: Pure metals are not specifically listed by CAS or MITI number. The class of compounds for each of these metals is listed on the MITI inventory.* * * Section 16 - Other Information * * *MSDS HistoryOriginal: March 16, 1990Supersedes: March 4, 1999Revised: August 14, 2000MSDS StatusChanges in Sections 1 and 2.Prepared ByHazardous Materials Control Committee.MSDS System Number115949Other Information= Aluminum Association’s Bulletin F-1, "Guidelines for Handling Aluminum Fines Generated During VariousAluminum Fabricating Operations." The Aluminum Association, 900 19th Street, N.W., Washington, DC 20006.= Aluminum Association, "Guidelines for Handling Molten Aluminum, The Aluminum Association, 900 19th Street, N.W., Washington, DC 20006.= NFPA 65, Standard for Processing and Finishing of Aluminum (NFPA phone: 800-344-3555)= NFPA 651, Standard for Manufacture of Aluminum and Magnesium Powder= NFPA 70, Standard for National Electrical Code (Electrical Equipment, Grounding and Bonding)= NFPA 77, Standard for Static Electricity= Guide to Occupational Exposure Values-1999, Compiled by the American Conference of Governmental Industrial Hygienists (ACGIH).= Documentation of the Threshold Limit Values and Biological Exposure Indices, Sixth Edition, 1991, Compiled by the American Conference of Governmental Industrial Hygienists, Inc. (ACGIH).= NIOSH Pocket Guide to Chemical Hazards, U.S. Department of Health and Human Services, June 1994.= Dangerous Properties of Industrial Materials, Sax, N. Irving, Van Nostrand Reinhold Co., Inc., 1984.= Patty’s Industrial Hygiene and Toxicology: Volume II: Toxicology, 4th ed., 1994, Patty, F. A.; edited by Clayton,G. D. and Clayton, F. E.: New York: John Wiley & Sons, Inc.= TOMES CPS(TM), MICROMEDEX, Inc., 1999Key-Legend:ACGIH American Conference of Governmental Industrial HygienistsAICS Australian Inventory of Chemical SubstancesCAS Chemical Abstract ServiceCERCLA Comprehensive Environmental Response, Compensation, and Liability ActCFR Code of Federal RegulationsCPR Cardio-pulmonary ResuscitationDOT Department of TransportationDSL Domestic Substances List (Canada)ECOIN European Core InventoryE P A Environmental Protection ActIARC International Agency for Research on CancerLC50Lethal concentration (50 percent kill)LC Lo Lowest published lethal concentrationLD50Lethal dose (50 percent kill)LD Lo Lowest published lethal doseNFPA National Fire Protection AssociationNIOSH National Institute for Occupational Safety and HealthNTP National Toxicology ProgramOEL Occupational Exposure LimitOSHA Occupational Safety and Health AdministrationPEL Permissible Exposure LimitPIN Product Identification NumberRCRA Resource Conservation and Recovery ActSARA Superfund Amendments and Reauthorization ActSTEL Short Term Exposure LimitTCLP Toxic Chemicals Leachate ProgramTDG Transportation of Dangerous GoodsTLV Threshold Limit ValueTSCA Toxic Substance Control ActTWA Time Weighted Averageatm atmospherecm centimeterg, gm gramin inchkg kilogramlb poundm metermg milligramml, ML millilitermm millimetern.o.s.not otherwise specifiedppb parts per billionppm parts per millionpsia pounds per square inch absoluteu micronug microgramINFORMATION HEREIN IS GIVEN IN GOOD FAITH AS AUTHORITATIVE AND VALID; HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, CAN BE MADE.This is the end of MSDS # 663。
环氧树脂黑胶及固化剂物质安全资料表 低卤无红磷 MSDS
prepared the
MSDS
製表人 Prepared the 職稱 Professional Title：
MSDS
製表日期
Date the
MSDS
姓名(簽章) Name ：
容器保持密闭
儲存 Storage： 1． 储存于阴凉处，远离热源、火源 2． 储存及使用生产区应为禁烟区
八、暴露預防措施 Exposure controls measures: 工程控制 Engineering control： 用塑料桶或铁桶密封包装
控制參數 Control parameters： ˙八小時日時量平均容許濃度/短時間時量平均容許濃度/最高容許濃度 8 hours time weighted average
若患者自然呕吐，应让患者身体向前以避免吸入呕吐物，勿经口喂食其他东西，并立即就医。
最重要症狀及危害效應 The most important symptoms and hazardous effects： 无 對急救人員之防護 The protection of first-aiders： 无 對醫師之提示 Notes to physicians： 环氧树脂过敏
二、成分辨識資料 Ingredients identification information
純物質 Pure material:：
中/英文名稱
同義中/英文名稱
(Chemical Name)
(Synonym)
化學文摘社登記號碼 (CAS #)
A：环氧树脂 色粉
稀释剂
助剂
填充料 添加剂
B： 固化剂 助剂
製造商和供應商名稱、地址及電話 (Names, addresses, and phone numbers of the manufacturer or supplier)：
一氯化硒安全技术说明书(3篇)
第1篇一、概述一氯化硒（SeCl4），分子式为SeCl4，是一种无色或浅黄色液体，具有强烈的刺激性气味。
一氯化硒是一种重要的无机化工原料，广泛应用于医药、农药、电子、催化剂等领域。
由于一氯化硒具有腐蚀性、毒性和刺激性，因此在生产、使用和储存过程中必须严格遵守安全技术说明书的要求。
二、危险性概述1. 危险性分类根据GB 13690-2009《化学品分类和标签规范》，一氯化硒属于第8类腐蚀品。
2. 危害性（1）健康危害：一氯化硒具有刺激性、腐蚀性和毒性。
吸入或接触后可引起呼吸道、皮肤和眼睛刺激症状，严重时可导致肺水肿、皮肤腐蚀和中毒。
（2）环境危害：一氯化硒可污染环境，对水体、土壤和大气造成危害。
（3）火灾危害：一氯化硒与水反应剧烈，可产生有毒气体和热量，遇火源可能引起火灾。
三、理化性质1. 外观与性状：无色或浅黄色液体，具有强烈的刺激性气味。
2. 相对密度（水=1）：1.95（20℃）3. 沸点（℃）：1364. 闪点（℃）：385. 溶解性：不溶于水，溶于有机溶剂。
6. 稳定性：在空气中稳定，遇水反应剧烈。
7. 危险分解产物：氯化氢、硒化氢、氧化硒。
四、接触控制/个体防护1. 接触控制（1）作业场所应保持良好通风。
（2）操作人员应穿戴适当的防护用品，如防毒面具、防护服、防护手套和防护眼镜。
2. 个体防护（1）呼吸系统防护：空气中浓度超标时，佩戴自吸过滤式防毒面具（半面罩）。
（2）眼睛防护：戴化学安全防护眼镜。
（3）身体防护：穿防化学品渗透工作服。
（4）手防护：戴耐化学品手套。
五、紧急处理1. 吸入迅速脱离现场至空气新鲜处。
保持呼吸道通畅。
如呼吸困难，给输氧。
如呼吸停止，立即进行人工呼吸。
就医。
2. 皮肤接触立即脱去污染的衣着，用大量流动清水冲洗至少15分钟。
如有不适感，就医。
3. 眼睛接触立即提起眼睑，用大量流动清水或生理盐水冲洗至少15分钟。
如有不适感，就医。
4. 食入饮足量温水，催吐，就医。
材料安全数据表(MSDS)
材料安全数据表(MSDS)产品名称：硅烷Silane化学名称：氢化物分子式：SiH4代名称：四氢化硅，单硅烷，硅烷SiH4纯度> 99%CAS 号码: 7803-62-5暴露极限:OSHA : 未建立ACGIH: TLV＝5ppm NIOSH： REL＝5ppm紧急情况综述可自燃气体! 硅烷是一种无色、与空气反应并会引起窒息的气体。
该气体通常与空气接触会引起燃烧并放出很浓的白色的无定型二氧化硅烟雾。
它对健康的首要危害是它自燃的火焰会引起严重的热灼伤，如果严重甚至会致命。
如果火焰或高温作用在硅烷钢瓶的某一部分会使钢瓶在安全阀启动之前爆炸。
如果泄放硅烷时压力过高或速度过快会引起滞后性的爆炸。
泄漏的硅烷如没有自燃会非常危险，不要靠近。
处理紧急情况的人员必须要有个人防护设备和适应当时情况的防火保护。
不要试图在切断气源之前灭火。
急性潜在健康影响暴露途径：眼接触：硅烷会刺激眼睛。
硅烷分解产生无定型二氧化硅。
眼睛接触无定型二氧化硅颗粒会引起刺激。
摄入：摄入不可能成为接触硅烷的途径。
吸入：吸入高浓度的硅烷会引起头痛、恶心、头晕并刺激上呼吸道。
硅烷会刺激呼吸系统及粘膜。
过度吸入硅烷会引起肺炎和肾病，这是由于存在结晶二氧化硅的原因。
暴露于高浓度气体中还会由于自燃而造成热灼伤。
皮肤接触：硅烷会刺激皮肤。
硅烷分解产生无定型二氧化硅。
皮肤接触无定型二氧化硅颗粒会引起刺激。
重复暴露的潜在健康影响：进入路径：无损害器官：未建立症状：目前不清楚长期暴露于硅烷中对健康的进一步影响。
过份暴露造成的病状恶化：有皮肤和呼吸道疾病的人暴露在硅烷及其分解物中会加重病情。
致癌性：未被 NTP 、OSHA 及 IARC 列为致癌物热灼伤：由于硅烷泄漏引起人员灼伤时应由受过培训的人员进行急救，并立即寻求医疗处理。
眼接触：立即用水冲洗最少15分钟，水流不要太快，同时翻开眼睑。
使受难者为“O ”形眼，立即寻求眼科处理。
摄入：摄入不可能成为接触硅烷 的途径。
RoHS简介及无卤素教材
有害物质对人体危害
12. 多溴联苯(PBB)﹕计算机处理器和监视器上 的“毒尘”﹐含有可能使人畜生殖系统和 神经系统病变的化学物质﹐多溴联苯的毒 性相当于多氯联苯的5倍。
13. 多溴二苯醚(PBDE)﹕可以破坏甲状腺和伤 及儿童的脑部组织。
14. 有机锡化合物﹕破坏中枢神经系统。引起 神经元坏死。
环境违约的案例
SONY 2001年末推出针对圣诞节销往荷兰的140万台 Play-station出现问题,镉含量超过100PPM,损 失约2000亿
COMPAQ 1999年计算器违背瑞典制止使用难燃卤素材料 规定,损失约5000万美元
RoHS起源背景
1994年,奥斯陆部长论坛对于產品的延續化生產及消費作 出了明確的定義︰產品的生產、使用及服務應該滿足人類 的基本需求，提升人類的生活品性。然而在產品的整個生 命週期，應該減少對自然資源的使用，減少毒性物質和廢 棄物的排放和污染物的產生，以免危害到未來子孫的需要。 1996年至1998年的兩年時間裡，歐洲電氣設備循環工業 委員會（ICER-The Industry Council for Electronic Equipment Recycling）調查显示:電子電氣廢棄物的容量 正以每年3%-5%的速度增長. 在電子電氣設備中使用的一系列的材料和物質，構成了對 環境破壞的潛在危險.
要求 SJ/T11363-2006电子信息产品中有毒有害物质的限量要求 SJ/T11364-2006电子信息产品污染控制标识要求 SJ/T11365-2006电子信息产品中有毒有害物质的检测方法
中国《管理办法》与欧盟RoHS指令的异同
不同之处 法律效力不同 调整对象不同 推进方式不同 颁布和实施时间不同 贯彻、实施的条件不同 限制与禁止方式不同
RoHS_无卤
六价铬的危害
铬是广泛存在于环境中的一种元素，是人体的一种必需微 量元素。铬的化合物有二价、三价和六价三种。六价铬 及其化合物都溶于水，毒性也最强，三价铬和二价铬毒 性都很小。 铬对人的毒性主要是六价铬的毒性，主要影响物质的 氧化还原和水解过程，与核酸、核蛋白结合影响组织的 磷含量。六价铬为吞入性毒物/吸入性极毒物，皮肤接触 可能导致敏感和粘膜的损害；出现接触性皮炎、湿疹和 溃疡；更可能造成遗传性基因缺陷。六价铬对呼吸道有 刺激作用，可引起鼻炎、咽炎及支气管炎等，严重者可 致鼻中隔穿孔。吸入可能致癌。此外还可出现多发性黏 膜溃疡、咽部糜烂、齿龈炎、中毒性肝病、肾炎、贫血 和眼结膜炎等。对环境有持久危险性。 铬化合物污染是环境中最常见的有害物质之一，对 人体健康的危害也很大，因此必须认真对待，采取综合 22 10/21/11 治理措施
10/21/11
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为何要推行ROHS?
各国陆续推出针对环境有害物质之立法。 客户绿色采购准则对供应商之要求。 保护生态环境，维持资源循环，减轻 环境负荷,捍卫人类生活的健康和福祉。 提高产品在市场中之生命值,提升公司 的生产竞争力。
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ROHS有害物质简介
有毒物质 消 化 系 统 呼 吸 管 道 危害 心 中 枢 脏 神 系 经 统 生 殖 系 统 肝 脏 皮 肤 血 液 肾 脏 骨 胳 铅 Pb 镉 Cd 六价铬 Cr6+ 汞 Hg PBBs/PBDEs
ROHS指令的实施日期: 2006年7月1日 提醒RoHS正確寫法為中間O為小寫
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什么是重金屬?
重金屬的定义:
重金属原义是指比重大于5的金属，包括金、银、铜、铁、 铅等，重金属在人体中累积达到一定程度，会造成慢性中毒。 对什么是重金属目前尚无严格的定义，化学上跟据金属的 密度把金属分成重金属和轻金属，常把密度大于4.5g/cm3的 金属称为重金属。 如：金、银、铜、铅、锌、镍、钴、铬、 汞、镉等大约45种。 从环境污染方面所说的重金属是指： 汞、镉、铅、铬以及类金属砷等生物毒性显著的重金属。 对人体毒害最大的有5种：铅、汞、铬、 砷、镉。这些重金 属在水中不能被分解，人饮用后毒性放大，与水中的其他毒 素结合生成毒性更大的有机物或无机物。 重金属有毒非金属物质：砷、氟、氰等。
PVCMSDS全英文版,新版2021(5)
公司名英文MATERIAL SAFETY DATA SHEET (MSDS) 一、Product and Company IdentificationProduct Name : PVC Plastic pelletsProduct Code :塑胶料号英文填写Address & Tel. of Manufacturer or Agent ∙ 公司名英文+地址英文填写处！Emergency Phone Number/Fax :卷L：电话填写处FAX：传真填写处五、Fire Fighting MeasuresSuitable Extinguishing Media： Carbon Dioxide Gas, Dry Chemical, and Regular Foam Water Special Hazards in Fire : -------Special Fire-Fighting Procedures : N/ARequired Special Protective Equipment for Fire-Fighters : When outside temperature is higher than the fire point, it will have odor and smoke, then should wear face guard.六、Accidental Release MeasuresPersonal Precautions： Wear a simple dust mask to avoid inhalation from the respiratory tract Environmental Precautions : The reject can be sold, and should callback.Methods for Cleaning： PVC Plastic pellets can be clear generally, the remnant adhesive should to be clean use the alcohol and cotton.七、Handling and StorageHandling :1.Avoid to storage with the corrosive and volatility solvent, and regard to water and flame2.PoUr into a SUitabIe COntainen fb】reuse Or disposal.Storage :1.Ventilation, dryness and moistureproof, feasible temperature is 15~35°C, relative humidity is30% ~70%; the holder and support's surface is plane, not to stack on the ground.2.PVC resin contains trace amounts of residual VCM, which will volatilize into a suspectedcarcinogen when heated in a closed container, locomotive or storage cabinet.3.Keep away from heat, sparks and flames.4.The storage area should be properly ventilated.八、Exposure Controls, Personal Protection九、Physical and Chemical Properties十、Stability and ReactivityStability : Steady in generalPossible Hazard Reaction Under Special Conditions： High temperature incineration may ProdUCe HCL gasConditions to Avoid： Avoid open flame, heat speak and any other sources of ignition. Materials to Avoid： Avoid acid, alkali, oil and volatility solvent.Hazardous Decomposition Products： Non decompounded-∣—、Toxicological Information十二、Ecological informationPossible Environmental Impact： None decompounded, the reject can be sold, and callback. 十三、Disposal considerationsDisposal Methods： Pour into a suitable container for reuse or disposal. 十四、Transport informationInternational Transportation Regulations : -------UN Reference NO.： -----DomeStiC TranSPOrtation RegUIatiOnS : --------Special Transportation Methods and Precautions： Avoid leakage of PVC pellets during transportation十五、Regulatory informationApplicable Regulation : ------十六、Other information。
MSDS物质危险有害特性识别表184种
184种物质危险有害特性识别表MSDS大全目录表1－001 乙炔气 (1)表1－002 氧气 (2)表1－003 二氧化碳 (3)表1－004 氢气 (4)表1－005 氩气 (5)表1－006 甲烷 (6)表1－007 四氢噻吩 (7)表1－008 活性炭 (8)表1－009 三乙胺 (9)表1－010 硫代磷酰氯 (10)表1－011 硫黄 (11)表1－012 甲胺磷 (12)表1－013 多聚甲醛 (13)表1－014（附表1－3）甲缩醛 (14)表1－015 黄磷 (15)表1－016 氯 (16)表1－017 三氯化磷 (17)表1－018 甲醇 (19)表1－019 液碱 (20)表1－020 氨水 (21)表1－021 硫酸二甲酯 (22)表1－022 甲胺磷 (23)表1－023 液氨 (24)表1－024 氯仿 (25)表1－025 二氯乙烷 (26)表1－026 二硫化碳 (27)表1－027 甲苯 (28)表1－028 盐酸 (29)表1－029 氯甲烷 (30)表1－030 硫酸 (31)表1－031 二甲苯 (33)表1－032 醋酸酐 (34)表1－033 多聚甲醛 (35)表1－034 草甘膦 (36)表1－035 稻瘟灵 (37)表1－036 异丙胺 (38)表1－037 漂白粉 (39)表1－038 氯化氢 (40)表1－039 氰化氢 (41)表1－040 氰化钠 (42)表1－041 氯乙酸 (43)表1－043 丙烯腈 (45)表1－044 氧化亚铜 (46)表1－045 四氯化锡 (47)表1－046 四氧化三铅 (48)表1－047 三氯化铝（无水） (49)表1－048 松香水 (50)表1－049红丹油性防锈漆 (51)表1－050 酚醛树脂 (52)表1－051 硫磺粉(补充) (53)表1－052 一乙胺 (54)表1－053三聚氯氰 (55)表1－054 三氯乙烯 (57)表1－055 磷酸 (58)表1－056 四丁基锡 (59)表1－057 柴油 (60)表1－058 对氨基苯酚 (61)表1－059 醋酸乙酯 (62)表1－060 对氯硝基苯 (63)表1－061 氮气 (64)表1－062莠去津 (65)表1－063 扑草净 (66)表1－064 八氯二丙醚 (67)表1－065 硫化钠 (68)表１－066 异丙醇 (69)表１－067 丙酮 (70)表１－068 二氯丙烷 (71)表１－069 环己酮 (72)表１－070 乙酸异戊酯 (73)表1－071 锌粉 (74)表1－072 乙醇 (75)表1－073 次氯酸钠溶液 (76)表1－074 石脑油 (77)表1－075 双环戊二烯 (78)表1－076 乙酸丁酯 (79)表1－077 双氧水 (80)表1－078 丙烯酸丁酯 (81)表1－079 丙烯酸 (82)表1－080 苯乙烯 (83)表1－081 过硫酸铵 (84)表1－082 过硫酸钾 (85)表1－083 丙烯酰胺 (86)表1－084 甲醛 (87)表1－085 甲基丙烯酸甲酯 (88)表1－087 汽油 (90)表1－088 乙酸 (91)表1－089 丙烯酸树脂 (92)表1－090 丙烯酸清漆 (93)表1－091 丙烯酸漆稀释剂 (94)表1－092 丙烯酸磁漆 (95)表1－093 二乙醇胺 (97)表1－094 煤油 (98)表1－095 漂白粉 (99)表1－096 漂粉精 (100)表1－097 三氯异氰尿酸 (101)表1－098 松香 (102)表1－099 松节油 (103)表1－100 硫化钠 (104)表1－101 保险粉 (105)表1－102 7385聚氨酯清漆（分装） (106)表1－103 甲酸 (107)表1－104 乙酸乙二醇乙醚 (108)表1－105 H－3聚氨酯漆固化剂 (109)表1－106 聚氨酯漆稀释剂 (110)表1－107 263醇酸树脂 (111)表1－108 异噻唑啉酮 (112)表1－109 N-乙基苯胺 (113)表1－110苯胺 (114)表1－111 乙酰甲胺磷 (115)表1－112 亚磷酸 (117)表1－113 亚磷酸二甲酯 (118)表1－114 氯甲烷 (119)表1－115 乙醚 (120)表1－116 丙烯酸甲酯 (121)表1－117 一甲胺 (122)表1－118 硝酸镁 (123)表1－119 硫化氢 (124)表1－120 硫化铵 (125)表1－121 一甲胺水溶液 (126)表1－122 兔宝宝面漆 (127)表1－123 兔宝宝稀释剂 (128)表1－124 硫氢化钠 (129)表1－125丙酸 (130)表1－126乙酰氯 (131)表1－127丙酰氯 (132)表1－128 丁醇 (133)表1－129 醇酸调合漆（未列名） (134)表1－130 硝酸钠 (136)表1－131 溴甲烷 (137)表1－132 磷化铝 (138)表１－133 正丁醇 (139)表１－134 硝基木器漆 (140)表１－135 硝化棉（含氮≤12.6％） (141)表１－136 单丁醚 (142)表1－137 砷 (143)表1－138 碘化汞 (144)表1－139 氯化汞 (145)表1－140 叠氮化钠 (146)表1－141 重铬酸钠 (147)表1－142 高锰酸钾 (148)表1－143 氰化金钾 (149)表1－144丙烯酸 (150)表1－145甲基丙烯酸甲酯 (151)表1－146苯乙烯 (152)表1－147丙烯酸丁酯 (153)表1－148丁醇 (154)表1－149偶氮二异丁腈 (155)表1－150甲基丙烯酸异丁酯 (156)表1－151 甲基丙烯酸（正）丁酯 (157)表1－152 乙酰丙酮 (158)表1－153 2－丁酮 (160)表1－154 生松香 (161)表1－155 硫酸铜 (162)表1－155 硝酸 (163)表1－155 氰化钾 (164)表1－156硝基苯 (165)表1－157 氟化钠 (166)表1－158 氢氟酸 (167)表1－159蓄电池（注有酸液） (168)表1－160 环氧树脂 (169)表1－161 氯苯 (170)表1－162 乙苯 (171)表1－163 樟脑 (172)表1－164 赛璐珞 (173)表1-165 氢氧化钾 (174)表1-166 乙酸丁酯 (175)表1－001 乙炔气表1－002 氧气表1－003 二氧化碳表1－004 氢气表1－005 氩气表1－006 甲烷表1－007 四氢噻吩表1－008 活性炭活性炭 C 12.0Active carbon别名：Activated chlarcoal危规分类及编号：自燃物品。
FR2-55 MATT 4-8GU BASE GREY AFNOR 3605 化学品安全技术说明书
安全技术说明书根据 GB/ T 16483-2008 和 GB/ T 17519-2013化学品安全技术说明书FR2-55 MATT 4-8GU BASE GREY AFNOR 3605化学品的推荐用途和限制用途邮箱:SDS code:55763605B+33 (0)5 34 01 34 01+33 (0)5 61 60 23 30应急咨询电话（带值班时间）:产品用途:Waterborne coating for interior use.企业标识MAPAERO SAS10, Avenue de la Rijole CS3009809103 PAMIERS CedexFrance无法分类。
危险性类别:信号词:无信号词。
危险性说明:没有明显的已知作用或严重危险。
防范说明预防措施:P262 - 严防进入眼中、接触皮肤或衣服。
事故响应:不适用。
GHS标签要素物理和化学危险没有明显的已知作用或严重危险。
健康危害没有明显的已知作用或严重危险。
::废弃处置:P501 - 处置内装物/容器按照地方/区域/国家/国际规章。
环境危害:其他危害:没有已知信息。
没有出现就供应商当前所知可应用的浓度，被分类为对健康或环境有害及因此需要在本节报告的添加剂。
物质／混合物:职业暴露限制, 如果有的话, 列在第 8 节中。
混合物用水冲洗口腔。
将患者转移到空气新鲜处，休息，保持利于呼吸的体位。
如物质已被吞下且患者保持清醒，可饮少量水。
禁止催吐，除非有专业医疗人士指导。
如果出现症状，寻求医疗救护。
立即用大量水冲洗眼睛，并不时提起上下眼睑。
检查和取出任何隐形眼镜。
如果感到疼痛，请就医治疗。
用大量水冲洗受污染的皮肤。
脱去受污染的衣服和鞋子。
如果出现症状，寻求医疗救护。
将患者转移到空气新鲜处，休息，保持利于呼吸的体位。
如果出现症状，寻求医疗救护。
眼睛接触皮肤接触吸入食入::::急救措施的描述最重要的症状和健康影响吸入:没有明显的已知作用或严重危险。
MSDS-Pattex transparent-C__ (2008-01-01) version 2
汉高粘合剂化学品安全数据表（根据91/155/EEC - ISO 11014-1）第 1 页共 4 页安全数据表编号：FP0003百得透明万能胶版本： 2生效日期：2008-01-01 1. 产品及企业标识产品中文名称：百得透明万能胶产品俗名或商品名：万能胶产品英文名称：Pattex Transparent Contact Adhesive企业中文名称：汉高粘合剂有限公司企业英文名称：Henkel Adhesives Company Limited地址：中国广东省汕头市东厦北路下蓬工业区邮编：515065传真号码：（86）754-8347511应急电话：（86）532-83889090技术说明书编码：FP0003生效日期：2008年1月1日2. 成份/组成信息主要成分：聚氨酯和混合有机溶剂(丙酮和乙酸乙酯)的混合溶液。
有害成分浓度范围 CAS No.乙酸乙酯 40 ~ 60% 141-78-6丙酮 20 ~ 30% 67-64-13.危险性概述危险性类别：第3.2 类中闪点易燃液体侵入途径：吸入食入皮肤接触健康危害：持续吸入本产品的蒸汽可引起头晕、倦睡和其他一些麻醉症状。
怀孕妇女应该避免皮肤接触和吸入其蒸汽。
环境危害：本产品对环境有危害，应特别注意对水体的污染。
燃爆危险：易燃，产品蒸汽与空气可形成爆炸性混合物，遇明火、高热有燃烧爆炸危险。
4. 急救措施皮肤接触：脱去污染的衣服，先用沾湿汽油的棉花仔细小心清洗沾到胶的皮肤，再用肥皂和水洗净。
眼睛接触：立即翻开上下眼睑，马上用大量的水冲洗眼睛大约10分钟，用无菌纱布包扎，尽快就诊。
吸入：迅速脱离现场至空气新鲜处。
保持呼吸道通畅。
呼吸困难时给输氧。
如呼吸及心跳停止，立即进行人工呼吸和心脏按摩术。
就医。
安全数据表编号：FP0003 百得透明万能胶第 2 页 共 4 页食入：用水冲洗其口腔，饮用大量的水并立即就医诊治。
5. 消防措施危险特性：产品蒸汽与空气可形成爆炸性混合物，遇明火、高热能引起燃烧爆炸。
METALSTAR UV 21 6003 PALE GOLD 化学品安全技术说明书
版本7.4修订日期:2021/12/15SDS编号:102000023619打印日期: 2022/03/04最初编制日期: 2015/10/051. 化学品及企业标识产品名称: METALSTAR UV 21 6003 PALE GOLD产品代码: 072847N20化学性质: 印刷油墨制造商或供应商信息制造商或供应商名称: 爱卡特殊效果颜料（珠海）有限公司地址: 珠海市金湾区南水镇浪屿路3号电话号码: +8607567228600应急咨询电话: National Emergency Response Hotline for Chemical Incident(China)**************国家化学事故应急咨询电话（中国）**************电子邮件地址: ***************************传真: +86075672286012. 危险性概述紧急情况概述外观与性状: 液体颜色: 金色气味: 特征的吞咽有害。
造成皮肤刺激。
可能造成皮肤过敏反应。
造成严重眼刺激。
对水生生物毒性极大并具有长期持续影响。
GHS危险性类别急性毒性 (经口) : 类别 4皮肤腐蚀/刺激: 类别 2严重眼睛损伤/眼睛刺激性: 类别 2A皮肤过敏: 类别 1急性（短期）水生危害: 类别 1长期水生危害: 类别 1版本7.4修订日期:2021/12/15SDS 编号:102000023619打印日期: 2022/03/04最初编制日期: 2015/10/05GHS标签要素象形图:信号词: 警告危险性说明: H302吞咽有害。
H315造成皮肤刺激。
H317可能造成皮肤过敏反应。
H319造成严重眼刺激。
H410对水生生物毒性极大并具有长期持续影响。
防范说明:预防措施:P261避免吸入烟雾或蒸气。
P264作业后彻底清洗皮肤。
P270使用本产品时不要进食、饮水或吸烟。
P272受沾染的工作服不得带出工作场地。
柯莱托XP1A5产品安全数据表说明书
Version 6.0 Revision Date:11/08/2022SDS Number:1764064-00013Date of last issue: 04/01/2022Date of first issue: 06/21/2017SECTION 1. IDENTIFICATIONProduct name : Krytox™ XP 1A5Product code : D1*******SDS-Identcode : 130000024311Manufacturer or supplier's detailsCompany name of supplier : The Chemours Company FC, LLCAddress : 1007 Market StreetWilmington, DE 19801 United States of America (USA) Telephone : 1-844-773-CHEM (outside the U.S. 1-302-773-1000)Emergency telephone : Medical emergency: 1-866-595-1473 (outside the U.S. 1-302-773-2000) ; Transport emergency: +1-800-424-9300 (outsidethe U.S. +1-703-527-3887)Recommended use of the chemical and restrictions on useRecommended use : LubricantRestrictions on use : For industrial use only.Do not use or resell Chemours™ materials in medical applica-tions involving implantation in the human body or contact withinternal body fluids or tissues unless agreed to by Seller in awritten agreement covering such use. For further information,please contact your Chemours representative.SECTION 2. HAZARDS IDENTIFICATIONGHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR 1910.1200)Not a hazardous substance or mixture.GHS label elementsNot a hazardous substance or mixture.Other hazardsThe thermal decomposition vapors of fluorinated plastics may cause polymer fume fever with flu-like symptoms in humans, especially when smoking contaminated tobacco.SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTSSubstance / Mixture : MixtureComponentsChemical name CAS-No. Concentration (% w/w)Version 6.0 Revision Date:11/08/2022SDS Number:1764064-00013Date of last issue: 04/01/2022Date of first issue: 06/21/2017Poly(oxy<trifluoro(trifluoromethyl)ethylene>), omega-fluoro-alpha-<tetrafluoro-1 <<(hydroxyphenoxy-phosphinyl)oxy>methyl>ethyl>-Not Assigned >= 1 - < 5SECTION 4. FIRST AID MEASURESIf inhaled : If inhaled, remove to fresh air.Get medical attention if symptoms occur.In case of skin contact : Wash with water and soap as a precaution.Get medical attention if symptoms occur.In case of eye contact : Flush eyes with water as a precaution.Get medical attention if irritation develops and persists.If swallowed : If swallowed, DO NOT induce vomiting.Get medical attention if symptoms occur.Rinse mouth thoroughly with water.Most important symptoms and effects, both acute and delayed : Inhalation may provoke the following symptoms: IrritationPolymer fume feverSkin contact may provoke the following symptoms: IrritationDiscomfortItchingRednessEye contact may provoke the following symptoms IrritationLachrymationRednessDiscomfortProtection of first-aiders : No special precautions are necessary for first aid responders.Notes to physician : Treat symptomatically and supportively.SECTION 5. FIRE-FIGHTING MEASURESSuitable extinguishing media : Not applicableWill not burnUnsuitable extinguishing media : Not applicable Will not burnSpecific hazards during firefighting: Exposure to combustion products may be a hazard to health.Hazardous combustion prod-ucts : Hydrogen fluoride carbonyl fluorideVersion 6.0 Revision Date:11/08/2022SDS Number:1764064-00013Date of last issue: 04/01/2022Date of first issue: 06/21/2017potentially toxic fluorinated compoundsaerosolized particulatesCarbon oxidesSpecific extinguishing meth-ods : Use extinguishing measures that are appropriate to local cir-cumstances and the surrounding environment.Use water spray to cool unopened containers.Remove undamaged containers from fire area if it is safe to do so.Evacuate area.Special protective equipment for fire-fighters : Wear self-contained breathing apparatus for firefighting if necessary.Use personal protective equipment.SECTION 6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protec-tive equipment and emer-gency procedures : Follow safe handling advice (see section 7) and personal pro-tective equipment recommendations (see section 8).Environmental precautions : Avoid release to the environment.Prevent further leakage or spillage if safe to do so.Prevent spreading over a wide area (e.g., by containment oroil barriers).Retain and dispose of contaminated wash water.Local authorities should be advised if significant spillagescannot be contained.Methods and materials for containment and cleaning up : Soak up with inert absorbent material.For large spills, provide diking or other appropriate contain-ment to keep material from spreading. If diked material can be pumped, store recovered material in appropriate container.Clean up remaining materials from spill with suitable absor-bent.Local or national regulations may apply to releases and dispo-sal of this material, as well as those materials and items em-ployed in the cleanup of releases. You will need to determine which regulations are applicable.Sections 13 and 15 of this SDS provide information regarding certain local or national requirements.SECTION 7. HANDLING AND STORAGETechnical measures : See Engineering measures under EXPOSURECONTROLS/PERSONAL PROTECTION section.Local/Total ventilation : Use only with adequate ventilation.Advice on safe handling : Do not breathe decomposition products.Handle in accordance with good industrial hygiene and safetypractice, based on the results of the workplace exposure as-Version 6.0 Revision Date:11/08/2022SDS Number:1764064-00013Date of last issue: 04/01/2022Date of first issue: 06/21/2017sessmentTake care to prevent spills, waste and minimize release to theenvironment.Conditions for safe storage : Keep in properly labeled containers.Store in accordance with the particular national regulations.Materials to avoid : No special restrictions on storage with other products.Further information on stor-age stability: No decomposition if stored and applied as directed. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTIONIngredients with workplace control parametersContains no substances with occupational exposure limit values.Occupational exposure limits of decomposition productsComponents CAS-No. Value type(Form ofexposure) Control parame-ters / Permissible concentrationBasisHydrogen fluoride 7664-39-3 TWA 0.5 ppm(Fluorine)ACGIHC 2 ppm(Fluorine)ACGIHC 6 ppm5 mg/m³NIOSH RELTWA 3 ppm2.5 mg/m³NIOSH RELTWA 3 ppm OSHA Z-2 Carbonyl difluoride 353-50-4 TWA 2 ppm ACGIHSTEL 5 ppm ACGIHTWA 2 ppm5 mg/m³NIOSH RELST 5 ppm15 mg/m³NIOSH REL Carbon dioxide 124-38-9 TWA 5,000 ppm ACGIHSTEL 30,000 ppm ACGIHTWA 5,000 ppm9,000 mg/m³NIOSH RELST 30,000 ppm54,000 mg/m³NIOSH RELTWA 5,000 ppm9,000 mg/m³OSHA Z-1 Carbon monoxide 630-08-0 TWA 25 ppm ACGIHTWA 35 ppm40 mg/m³NIOSH RELC 200 ppm229 mg/m³NIOSH RELVersion 6.0 Revision Date:11/08/2022SDS Number:1764064-00013Date of last issue: 04/01/2022Date of first issue: 06/21/2017TWA 50 ppm55 mg/m³OSHA Z-1Engineering measures : Processing may form hazardous compounds (see section10).Ensure adequate ventilation, especially in confined areas.Minimize workplace exposure concentrations.Personal protective equipmentRespiratory protection : General and local exhaust ventilation is recommended tomaintain vapor exposures below recommended limits. Whereconcentrations are above recommended limits or areunknown, appropriate respiratory protection should be worn.Follow OSHA respirator regulations (29 CFR 1910.134) anduse NIOSH/MSHA approved respirators. Protection providedby air purifying respirators against exposure to any hazar-dous chemical is limited. Use a positive pressure air suppliedrespirator if there is any potential for uncontrolled release,exposure levels are unknown, or any other circumstancewhere air purifying respirators may not provide adequateprotection.Hand protectionRemarks : Wash hands before breaks and at the end of workday.Eye protection : Wear the following personal protective equipment:Safety glassesSkin and body protection : Skin should be washed after contact.Hygiene measures : If exposure to chemical is likely during typical use, provideeye flushing systems and safety showers close to the wor-king place.When using do not eat, drink or smoke.Wash contaminated clothing before re-use.SECTION 9. PHYSICAL AND CHEMICAL PROPERTIESAppearance : viscous liquidColor : colorlessOdor : odorlessOdor Threshold : No data availablepH : 7Melting point/freezing point : No data availableVersion 6.0 Revision Date:11/08/2022SDS Number:1764064-00013Date of last issue: 04/01/2022Date of first issue: 06/21/2017Initial boiling point and boilingrange: No data availableFlash point : Method: Pensky-Martens closed cupdoes not flashEvaporation rate : No data availableFlammability (solid, gas) : Not applicableFlammability (liquids) : Will not burnUpper explosion limit / Upperflammability limit: No data availableLower explosion limit / Lowerflammability limit: No data availableVapor pressure : No data availableRelative vapor density : No data availableRelative density : 1.89 - 1.93Solubility(ies)Water solubility : insolublePartition coefficient: n-octanol/water: Not applicableAutoignition temperature : No data availableDecomposition temperature : 662 °F / 350 °CViscosityViscosity, kinematic : No data availableExplosive properties : Not explosiveOxidizing properties : The substance or mixture is not classified as oxidizing.Particle size : Not applicableSECTION 10. STABILITY AND REACTIVITYReactivity : Not classified as a reactivity hazard.Chemical stability : Stable under normal conditions.Possibility of hazardous reac-tions : Hazardous decomposition products will be formed at elevated temperatures.Version 6.0 Revision Date:11/08/2022SDS Number:1764064-00013Date of last issue: 04/01/2022Date of first issue: 06/21/2017Conditions to avoid : None known.Incompatible materials : None.Hazardous decomposition productsThermal decomposition : Hydrogen fluorideCarbonyl difluorideCarbon dioxideCarbon monoxideSECTION 11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposureInhalationSkin contactIngestionEye contactAcute toxicityNot classified based on available information.Components:Poly(oxy<trifluoro(trifluoromethyl)ethylene>), omega-fluoro-alpha-<tetrafluoro-1 <<(hydroxyphe-noxyphosphinyl)oxy>methyl>ethyl>-:Acute oral toxicity : LD50 (Rat): > 5,000 mg/kgSkin corrosion/irritationNot classified based on available information.Components:Poly(oxy<trifluoro(trifluoromethyl)ethylene>), omega-fluoro-alpha-<tetrafluoro-1 <<(hydroxyphe-noxyphosphinyl)oxy>methyl>ethyl>-:Species : RabbitResult : No skin irritationSerious eye damage/eye irritationNot classified based on available information.Components:Poly(oxy<trifluoro(trifluoromethyl)ethylene>), omega-fluoro-alpha-<tetrafluoro-1 <<(hydroxyphe-noxyphosphinyl)oxy>methyl>ethyl>-:Species : RabbitResult : Irritation to eyes, reversing within 21 daysVersion 6.0 Revision Date:11/08/2022SDS Number:1764064-00013Date of last issue: 04/01/2022Date of first issue: 06/21/2017Respiratory or skin sensitizationSkin sensitizationNot classified based on available information.Respiratory sensitizationNot classified based on available information.Components:Poly(oxy<trifluoro(trifluoromethyl)ethylene>), omega-fluoro-alpha-<tetrafluoro-1 <<(hydroxyphe-noxyphosphinyl)oxy>methyl>ethyl>-:Routes of exposure : Skin contactSpecies : Guinea pigResult : negativeGerm cell mutagenicityNot classified based on available information.CarcinogenicityNot classified based on available information.IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens.NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.Reproductive toxicityNot classified based on available information.STOT-single exposureNot classified based on available information.STOT-repeated exposureNot classified based on available information.Aspiration toxicityNot classified based on available information.Version 6.0 Revision Date:11/08/2022SDS Number:1764064-00013Date of last issue: 04/01/2022Date of first issue: 06/21/2017SECTION 12. ECOLOGICAL INFORMATIONEcotoxicityComponents:Poly(oxy<trifluoro(trifluoromethyl)ethylene>), omega-fluoro-alpha-<tetrafluoro-1 <<(hydroxyphe-noxyphosphinyl)oxy>methyl>ethyl>-:Ecotoxicology AssessmentAcute aquatic toxicity : Toxic effects cannot be excludedChronic aquatic toxicity : Toxic effects cannot be excludedPersistence and degradabilityNo data availableBioaccumulative potentialNo data availableMobility in soilNo data availableOther adverse effectsNo data availableSECTION 13. DISPOSAL CONSIDERATIONSDisposal methodsWaste from residues : Dispose of in accordance with local regulations.Contaminated packaging : Empty containers should be taken to an approved wastehandling site for recycling or disposal.If not otherwise specified: Dispose of as unused product. SECTION 14. TRANSPORT INFORMATIONInternational RegulationsUNRTDGNot regulated as a dangerous goodIATA-DGRNot regulated as a dangerous goodIMDG-CodeNot regulated as a dangerous goodTransport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNot applicable for product as supplied.Domestic regulationVersion 6.0 Revision Date:11/08/2022SDS Number:1764064-00013Date of last issue: 04/01/2022Date of first issue: 06/21/201749 CFRNot regulated as a dangerous goodSpecial precautions for userNot applicableSECTION 15. REGULATORY INFORMATIONCERCLA Reportable QuantityThis material does not contain any components with a CERCLA RQ.SARA 304 Extremely Hazardous Substances Reportable QuantityThis material does not contain any components with a section 304 EHS RQ.SARA 302 Extremely Hazardous Substances Threshold Planning QuantityThis material does not contain any components with a section 302 EHS TPQ.SARA 311/312 Hazards : No SARA HazardsSARA 313 : This material does not contain any chemical components withknown CAS numbers that exceed the threshold (De Minimis)reporting levels established by SARA Title III, Section 313.US State RegulationsPennsylvania Right To KnowPFPE fluid Trade secretPoly(oxy<trifluoro(trifluoromethyl)ethylene>), omega-fluoro-alpha-<tetrafluoro-1 <<(hydroxyphenoxyphos-phinyl)oxy>methyl>ethyl>-Not AssignedCalifornia Prop. 65WARNING: This product can expose you to chemicals including Pentadecafluorooctanoic acid, which is/are known to the State of California to cause cancer, and Pentadecafluorooctanoic acid, which is/are known to the State of California to cause birth defects or other reproductive harm.For more information go to . Note to User: This product is not made with PFOA nor is PFOA intentionally present in the product; however, it is possible that PFOA may be present as an impurity at background (environmental) levels.SECTION 16. OTHER INFORMATIONFurther informationVersion 6.0 Revision Date: 11/08/2022 SDS Number: 1764064-00013 Date of last issue: 04/01/2022 Date of first issue: 06/21/2017NFPA 704:HMIS® IV:HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal haz-ards or risks, and 4 representing signifi-cant hazards or risks. The "*" represents a chronic hazard, while the "/" represents the absence of a chronic hazard.Krytox™ and any associated logos are trademarks or copyrights of The Chemours Company FC, LLC. Chemours™ and the Chemours Logo are trademarks of The Chemours Company.Before use read Chemours safety information.For further information contact the local Chemours office or nominated distributors.Full text of other abbreviationsACGIH : USA. ACGIH Threshold Limit Values (TLV)NIOSH REL : USA. NIOSH Recommended Exposure LimitsOSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim-its for Air ContaminantsOSHA Z-2 : USA. Occupational Exposure Limits (OSHA) - Table Z-2 ACGIH / TWA : 8-hour, time-weighted averageACGIH / STEL : Short-term exposure limitACGIH / C : Ceiling limitNIOSH REL / TWA : Time-weighted average concentration for up to a 10-hourworkday during a 40-hour workweekNIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceededat any time during a workdayNIOSH REL / C : Ceiling value not be exceeded at any time.OSHA Z-1 / TWA : 8-hour time weighted averageOSHA Z-2 / TWA : 8-hour time weighted averageAIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the Testing of Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub-stances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Haz-ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-tem; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous ChemicalsFlammability Instability Special hazard / 0 0 0 HealthVersion 6.0 Revision Date:11/08/2022SDS Number:1764064-00013Date of last issue: 04/01/2022Date of first issue: 06/21/2017in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation Organiza-tion; IECSC - Inventory of Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Korea Existing Chemi-cals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Convention for the Pre-vention of Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Oth-erwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic sub-stance; PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quanti-tative) Structure Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council concern-ing the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund Amend-ments and Reauthorization Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TECI - Thailand Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very BioaccumulativeSources of key data used to compile the Material Safety Data Sheet : Internal technical data, data from raw material SDSs, OECD eChem Portal search results and European Chemicals Agen-cy, http://echa.europa.eu/Revision Date : 11/08/2022Items where changes have been made to the previous version are highlighted in the body of this document by two vertical lines.The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-mation and belief at the date of its publication. The information is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and shall not be considered a warranty or quality specification of any type. The information provided relates only to the specific material identified at the top of this SDS and may not be valid when the SDS mate-rial is used in combination with any other materials or in any process, unless specified in the text. Material users should review the information and recommendations in the specific context of their intended manner of handling, use, processing and storage, including an assessment of the app-ropriateness of the SDS material in the user’s end product, if applicable.US / Z8。
南方测试股份有限公司化学品安全技术说明书
Page: 1 of 8
中检集团南方测试股份有限公司
化学品安全技术说明书
Material Safety Data Sheet （MSDS)
Report
委托单位： Client unit 深圳微点生物技术股份有限公司 Micropoint Biotechnologies Co., Ltd
样品名称： Name of sample 聚合物锂离子电池 Polymer lithium ion battery
委托单位地址： Address
中国广东省深圳市新安街道留仙二路润恒 电子厂 1 号厂房第三、四、五层，518101 3-5F, Building 1, Runheng Electronics
Factory, Liuxian 2 Road, Xinan Street, Baoan District, 518101 Shenzhen, China
Tested by ：
Checked By ：
Approved By ：
Date ：
May 17.2021 Date ：
May 17.2021
Date ：
May 17.2021
中检集团南方测试股份有限公司
中检集团南方测试股份有限公司
中检集团南方测试股份有限公司
中检集团南方测试股份有限公司
中检集团南方测试股份有限公司
中检集团南方测试股份有限公司
中检集团南方测试股份有限公司。
无铅锡丝MSDS
Safety Data Sheet according to (EC) No 1907/2006Page 1 of 7sds no. : 210766V002.1Revision: 04.08.2011printing date: 13.12.201197SC C811 5C 0.56MM 0.5KGSECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier:97SC C811 5C 0.56MM 0.5KGRelevant identified uses of the substance or mixture and uses advised against:Intended use:Solder WireDetails of the supplier of the safety data sheet:Henkel Limited2 Bishop Square Business ParkAL109EY Herfordshire HatfieldGreat BritainPhone: +44 1606 593933Fax-no.: +44 1606 863762@uk.henkelEmergency Telephone Number:24 Hours Emergency Tel: +44 (0)1442 278497SECTION 2: Hazards identificationClassification of the substance or mixture:Classification (DPD): Substances and preparations marketed in a specific form or within specific containers need not to be classified in accordancewith 67/548/EEC and 1999/45/EC for chemical substances and preparations.Label elements (DPD): Avoid breathing fumes given out during soldering.Flux fumes may irritate the nose, throat and lungs and may after prolonged/repeated exposure give an allergic reaction (asthma).After handling solder wash hands with soap and water before eating, drinking or smoking.Substances and preparations marketed in a specific form or within specific containers need not to be classified in accordancewith 67/548/EEC and 1999/45/EC for chemical substances and preparations.Keep out of reach of children.Other hazards:Flux fumes emitted during reflow will irritate the nose and throat and may cause an asthmatic type reaction.This product contains modified rosin.SECTION 3: Composition/information on ingredientsDeclaration of the ingredients according to CLP (EC) No 1272/2008:No data available.MSDS-No.: 210766V002.197SC C811 5C 0.56MM 0.5KGPage 2 of 7Declaration of ingredients according to DPD (EC) No 1999/45:Hazardous componentsCAS-No.EC NumberREACH-Reg No.content ClassificationTin7440-31-5231-141-880 - 100 %Silver7440-22-4231-131-31 - 5 %Copper Metal7440-50-8231-159-60,1 - 1 %For full text of the R-Phrases indicated by codes see section 16 'Other Information'.Substances without classification may have community workplace exposure limits available. SECTION 4: First aid measuresDescription of first aid measures:Inhalation:Move to fresh air. If symptoms persist, seek medical advice.Skin contact:Rinse with running water and soap.Obtain medical attention if irritation persists.Eye contact:Flush eyes with plenty of water for at least 5 minutes. If irritation persists seek medical attention. Ingestion:Do not induce vomiting.Seek medical advice.Most important symptoms and effects, both acute and delayed:No particular measures required.Indication of any immediate medical attention and special treatment needed:See section: Description of first aid measuresSECTION 5: Firefighting measuresCombustion behaviour:The product itself does not burn. Any fire extinguishing action should be appropriate to the surroundings. Extinguishing media:Extinguishing media which must not be used for safety reasons:Do not use water on fires where molten metal is present.Special hazards arising from the substance or mixture:High temperatures may produce heavy metal dust, fumes or vapours.The flux medium will give rise to irritating fumes.Advice for firefighters:Wear self-contained breathing apparatus.SECTION 6: Accidental release measuresPersonal precautions, protective equipment and emergency procedures: Wear protective equipment.MSDS-No.: 210766V002.197SC C811 5C 0.56MM 0.5KGPage 3 of 7Environmental precautions:Do not empty into drains / surface water / ground water.Methods and material for containment and cleaning up:Scrape up spilled material and place in a closed container for disposal. Reference to other sections:See advice in chapter 8SECTION 7: Handling and storagePrecautions for safe handling:Extraction is necessary to remove fumes evolved during reflow.When using do not eat, drink or smoke.Wash hands before breaks and immediately after handling the product.See advice in chapter 8Hygiene measures:Good industrial hygiene practices should be observed.Wash hands before work breaks and after finishing work.Do not eat, drink or smoke while working.Conditions for safe storage, including any incompatibilities:Ensure good ventilation/extraction.Store in a cool, dry place.Specific end use(s):Solder WireSECTION 8: Exposure controls/personal protection Control parameters:Valid forGreat BritainIngredient ppm mg/m3 Type Category RemarksTIN (INORGANIC COMPOUNDS AS SN)7440-31-52 Time Weighted Average(TWA):Indicative ECTLVSILVER (METALLIC)7440-22-40,1 Time Weighted Average(TWA):EH40 WELSILVER, METALLIC7440-22-40,1 Time Weighted Average(TWA):Indicative ECTLVColophony (Rosin) and derivatives: Rosin-based flux fume as total resin acids.Exposure controls:Engineering controls:Extraction is necessary to remove fumes evolved during reflow.Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Ensure good ventilation/extraction.Respiratory protection:Ensure adequate ventilation.An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated areaFilter type: AHand protection:Please note that in practice the working life of chemical resistant gloves may be considerably reduced as a result of many influencing factors (e.g. temperature). Suitable risk assessment should be carried out by the end user. If signs of wear and tear are noticed then the gloves should be replaced.The use of chemical resistant gloves such as Nitrile are recommended.MSDS-No.: 210766V002.197SC C811 5C 0.56MM 0.5KGPage 4 of 7Eye protection:Safety glasses with sideshields or chemical safety goggles should be worn if there is a risk of splashing.Skin protection:Wear suitable protective clothing.SECTION 9: Physical and chemical propertiesInformation on basic physical and chemical properties:Appearance solidgreyOdor NonepH not applicableInitial boiling point Not determinedFlash point NoneDecomposition temperature No data available / Not applicableVapour pressure not applicableDensity(25 °C (77 °F))7,5 g/cm3Bulk density No data available / Not applicableViscosity No data available / Not applicableViscosity (kinematic) No data available / Not applicableExplosive properties No data available / Not applicableSolubility (qualitative)(Solvent: Water)InsolubleSolidification temperature No data available / Not applicableMelting point 217 °C (422.6 °F)Flammability No data available / Not applicableAuto-ignition temperature No data available / Not applicableExplosive limits No data available / Not applicablePartition coefficient: n-octanol/water Not applicableEvaporation rate No data available / Not applicableVapor density No data available / Not applicableOxidising properties No data available / Not applicableOther information:No data available / Not applicableSECTION 10: Stability and reactivityReactivity:Solder alloy will react with concentrated nitric acid to produce toxic fumes of nitrogen oxides.Chemical stability:Stable under recommended storage conditions.Possibility of hazardous reactions:See section reactivityConditions to avoid:No decomposition if stored and applied as directed.Incompatible materials:None if used properly.Hazardous decomposition products:Thermal decomposition can lead to release of irritating gases and vapors.MSDS-No.: 210766V002.197SC C811 5C 0.56MM 0.5KGPage 5 of 7SECTION 11: Toxicological informationGeneral toxicological information:The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevantavailable health/ecological information for the substances listed under Section 3 is provided in the following.Oral toxicity:This material is considered to have low toxicity if swallowed.Inhalative toxicity:Fumes evolved at soldering temperatures will irritate the nose, throat and lungs. Prolonged or repeated exposure to flux fumes may result in sensitisation in sensitive workers.Dermal toxicity:This product is considered to have low dermal toxicity.Skin irritation:Fumes emitted during soldering may irritate the skin.Eye irritation:Fumes emitted during soldering may irritate the eyes.Acute toxicity:Hazardous componentsCAS-No.ValuetypeValueRoute ofapplicationExposuretimeSpecies MethodSilver7440-22-4LD50 > 2.000 mg/kg oral rat OECD Guideline 401 (AcuteOral Toxicity)Skin corrosion/irritation:Hazardous componentsCAS-No.Result ExposuretimeSpecies MethodSilver7440-22-4slightly irritating rabbit OECD Guideline 404 (AcuteDermal Irritation / Corrosion)Copper Metal7440-50-8irritatingSerious eye damage/irritation:Hazardous componentsCAS-No.Result ExposuretimeSpecies MethodSilver7440-22-4not irritating rabbit OECD Guideline 405 (AcuteEye Irritation / Corrosion)Copper Metal7440-50-8not irritatingSECTION 12: Ecological informationGeneral ecological information:The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevantavailable health/ecological information for the substances listed under Section 3 is provided in the following. Ecotoxicity:May cause long-term adverse effects in the aquatic environment.Mobility:The product is insoluble and sinks in water.Persistence and Biodegradability:The product is not biodegradable.Bioaccumulative potential:Octanol/Water distribution coefficient: Not applicableMSDS-No.: 210766V002.197SC C811 5C 0.56MM 0.5KGPage 6 of 7Toxicity:Hazardous componentsCAS-No.ValuetypeValue AcuteToxicityStudyExposuretimeSpecies MethodCopper Metal7440-50-8LC50 > 10 mg/l Fish 96 h Lepomis macrochirus OECD Guideline203 (Fish, AcuteToxicity Test)SECTION 13: Disposal considerationsWaste treatment methods:Product disposal:Wherever possible unwanted solder alloy should be recycled for recovery of metal.Otherwise dispose of in accordance with local and national regulations.Disposal of uncleaned packages:Dispose of in authorised landfill site or incinerate.Waste code06 04 05 - wastes containing other heavy metalsSECTION 14: Transport informationGeneral information:Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR.SECTION 15: Regulatory informationSafety, health and environmental regulations/legislation specific for the substance or mixture:VOC content < 5,0 %National regulations/information (Great Britain):Remarks The Health & Safety at Work Act 1974.The Control of Substances Hazardous to Health Regulations. L5:GeneralApproved Code of Practice to the COSHH Regulations. HS(G)97:A Step by StepGuide to the COSHH Regulations. HS(G)193:COSHH essentials: Easy steps tocontrol chemicals.IND (G)248L:Solder fume and you. IND(G)249L:Controlling health risks fromrosin (colophony) based solder fluxes.MSDS-No.: 210766V002.197SC C811 5C 0.56MM 0.5KGPage 7 of 7SECTION 16: Other informationFurther information:This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It isintended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.This safety data sheet was prepared in accordance with Council Directive 67/548/EEC and it's subsequent amendments, andCommission Directive 1999/45/EC.Substances and preparations marketed in a specific form or within specific containers need not to be classified in accordancewith 67/548/EEC and 1999/45/EC for chemical substances and preparations.。
5510-S21(鸥美MSDS)
頁次2/3
常盛科技股份有限公司
物 質 安 全 資 料 表
編 號
5 5 1 0 / S 2 1
六、洩漏處理方法 個人應注意事項：1.限制人員進入，直至外溢區完全清乾淨為止。2.進行清理前，穿戴適當的個人 防護裝備。3.收集在有蓋容器中等待處置。 環境注意事項：1.對該區域進行通風換氣。2.撲滅或除去所有發火源。 清理方法：1.依現行法規處理。2.用掃把清掃並放入垃圾桶裡，視狀況可回收使用或廢棄。 七、安全處置與儲存方法 處置：用掃把清掃並放入垃圾桶裡，視狀況可回收使用或廢棄。 儲存：1.保持容器乾燥及密封儲存與陰涼乾燥的地方並避免熱及陽光直接照射(產品可能結塊)。 2 避免容器受損及產品接觸到火源。 八、暴露預防措施 工程控制：良好的排氣通風，足以使人員暴露低於暴露界限值；密閉室應有局部排氣裝置。 控制參數： 八小時日時量平均容許濃度/短時間時量平均容許濃度/最高容許濃度：無資料。 生物指標：無資料。 個人防護設備：穿戴合適的防護衣及護目鏡，必要時於工作中戴防塵口罩。 呼吸防護：須佩戴防塵口罩。 手部防護：防護手套。材質：橡膠、塑膠。工作後洗手。 眼睛防護：護目鏡、安全眼鏡。 皮膚及身體防護：暴露於強烈噪音時，應配戴耳塞、耳罩。 衛生措施：1.工作後儘速脫掉污染之衣物，洗淨後才可再穿戴。2.工作場所嚴禁抽煙或飲食。 3.處理此物後，須徹底洗手。4.維持作業場所清潔。 九、物理及化學性質 物質狀態：固體 形狀：粉狀 顏色：紅 氣味：無味 pH 值：無資料。 沸點/沸點範圍：無資料。 閃火點： — ℉ — ℃ 分解溫度：無資料。 測試方法： 開杯 閉杯 自燃溫度：無法測試 爆炸界限：無法測試 蒸氣壓：不適用 蒸氣密度：無資料。 比重（水＝1） ：1.15-1.8g/cm3。 溶解度：不溶於水。。 十、安定性及反應性 安定性：在建議的儲存下穩定。 特殊狀況下可能之危害反應：不會自動發生。 應避免之狀況：產生粉塵、熱、火花。 應避免之物質：已知無危險的反應。 危害分解物：適當使用不會分解。 十一、毒性資料 暴露途徑：吸入、皮膚接觸、眼睛接觸、食入。 症狀：刺激感、過敏。 急毒性：吸入：刺激呼吸道。皮膚：無刺激性。眼睛：有刺激性。食入：可能有反胃現象。 慢毒性技股份有限公司
ROHS及无卤含义
R O H S及无卤含义-CAL-FENGHAI-(2020YEAR-YICAI)_JINGBIANROHS DirectiveROHS指令RoHS是由欧盟立法制定的一项强制性标准（2002/95/EC Directive），它的全称是《关于限制在电子电器设备中使用某些有害成分的指令》(the Restriction of the use of certain Hazardous Substances in electrical and electronic equipment)。
该标准已于2006年7月1日开始正式实施，主要用于规范电子电气产品的材料及工艺标准，使之更加有利于人体健康及环境保护。
RoHS指令限制使用以下六类有害物质1. 铅（Pb）使用该物质的例子：焊料、玻璃、PVC稳定剂2. 汞（Hg）（水银）使用该物质的例子：温控器、传感器、开关和继电器、灯泡3. 镉（Cd）使用该物质的例子：开关、弹簧、连接器、外壳和PCB、触头、电池4. 六价铬（Cr 6+ ）使用该物质的例子：金属附腐蚀涂层5. 多溴联苯（PBB）使用该物质的例子：阻燃剂，PCB、连接器、塑料外壳6. 多溴二苯醚（PBDE）使用该物质的例子：阻燃剂，PCB、连接器、塑料外壳其中，铅、汞、镉和六价铬是属于重金属，多溴联苯及多修联苯醚属于溴化阻燃剂·金属材质需测试四种有害金属元素如（Cd镉/Pb铅/Hg汞/Cr6+六价铬）·塑胶材质除了检查这四种有害重金属元素外还需检测溴化阻燃剂（多溴联苯PBB/多溴联笨醚PBDE）以下是RoHS中对六种有害物规定的上限浓度：镉：小于100ppm铅：小于1000ppm钢合金中铅小于3500ppm铝合金中铅小于4000ppm铜合金中铅小于40000ppm汞：小于1000ppm六价铬：小于1000ppm多溴联苯：小于1000ppm多溴二苯醚：小于1000ppm欧盟在2006年7月1日实施RoHS，届时使用或含有重金属以及多溴二苯醚PBDE，多溴联苯PBB等阻燃剂的电气电子产品限值超标将不允许进入欧盟市场欧盟27个成员国：法国、德国、意大利、荷兰、比利时、卢森堡、英国、丹麦、爱尔兰、希腊、西班牙、葡萄牙、奥地利、瑞典、芬兰、塞浦路斯、匈牙利、捷克、爱沙尼亚、拉脱维亚、立陶宛、马耳他、波兰、斯洛伐克、斯洛文尼亚、保加利亚、罗马尼亚。
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MATERIAL SAFETY DATA SHEET物质安全资料表1.CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 产品和公司资料PRODUCT NAME: The Halogen Free Copper Clad Laminate(S1155)产品名称：无卤型覆铜箔层压板（S1155）PRODUCT USE: P rinted circuit board ;Multilayer Boards.用途：用于制作印制电路板；制作多层板NAME of COMPANY and ADDRESS: .Shengyi SCI.TECH CO.,LTD.No.5 Western Industry Road North Industry District,Dongguan SSLSci.&Tech.Industry Park,Dongguan City,Guangdong ,P.R.China公司名称及地址：广东生益科技股份有限公司;中国广东省东莞市松山湖科技产业园区北部工业园工业西路5号FOR MORE INFORMATION CALL: IN CASE OF EMERGENCY CALL:紧急联络电话：(Monday-Friday, 8:00am-5:00pm) (24 Hours/Day, 7 Days/Week)(0769)22271828(万江)\ 22899388(松山湖) (0769)22271828(万江)\ 22899388(松山湖)2. COMPOSITION/INFORMATION ON INGREDIENTS 组成成份资料INGREDIENT NAME CAS # WEIGHT %成分名称化学文摘号重量比Continuous Filament Fiber Glass (65997-17-3) 10-60玻纤布Copper (7440-50-8) 5-80铜箔Inorganic fillers Trade secret5-30无机填料商业秘密Halogen free Epoxy Resin Trade secret15-60无卤环氧树脂商业秘密3.HAZARDS IDENTIFICATION 危害性资料EMERGENCY OVERVIEW:紧急情况概述：A nonflammable, sheet material. Dust, when machined or punched may cause skin or eye irritation. Fumes, if decomposed may irritate eyes, nose, and throat.是一种难燃的层压板。
当使用或打孔时可能产生粉末，可能使皮肤或眼睛感到刺激。
当分解时产生的气体会刺激眼睛、鼻和咽喉。
POTENTIAL HEALTH HAZARDS:潜在的危害健康的危险品：SKIN: Dust may cause moderate skin irritation.皮肤：粉末将导致中等程度皮肤过敏。
EYES: Dust may cause moderate eye irritation. Fumes may irritate eyes.眼睛：粉末将导致中等程度眼睛过敏。
INHALATION: Fibrous glass dust may be released from the fiber-glass cloth substrate when machined.吸入物：当使用玻璃布时玻璃纤维粉末可能会飞散出。
INGESTION: Not determined.摄食：没有参考值。
DELAYED EFFECTS: Our product is reinforced with continuous filament fiber glass. Dust generated from the cutting, grinding, machining, etc., would not be expected to produce respirable particles.IARCconsiders continuous filaments as unclassifiable or probably non-carcinogenic.慢性影响：我们的产品用的是加强型连续的玻璃纤维丝。
当切割、打孔加工时不会产生可吸入的颗粒。
IARC组织没有将连续型玻璃纤维丝列入致癌目录。
4. FIRST AID MEASURES 首要援助措施SKIN: Wash in flowing water or shower. Remove contaminated clothing.皮肤：脱下已污染衣服，用流动水冲洗。
EYE: Irrigate with flowing water for 15 minutes. If irritation persists, consult a physician.眼睛：用流动水冲洗15分钟，如过敏现象持续发生，请求助于医生。
NHALATION: If overcome by dust or smoke, move to fresh air. If not breathing, give mouth-to-mouth resuscitation.Call physician.吸入：如粉末烟尘太多请转移到有新鲜空气的地方，如没有呼吸，请进行人工呼吸。
并致电医生。
INGESTION: If large amounts are ingested, consult physician.摄食：如吸入大量，请致电医生。
ADVICE TO PHYSICIAN: Treat symptomatically建议医生：处理出现的症状。
5. FIRE FIGHTING MEASURES 火灾测试FLAMMABLE PROPERTIES: N/A易燃烧性：不适用FLASH POINT: N/A闪点：不适用FLASH POINT METHOD: N/A闪点方式：不适用AUTOIGNITION TEMPERATURE: Not determined自燃点温度：无规定UPPER FLAME LIMIT (Volume % in air): N/A燃烧上限：不适用LOWER FLAME LIMIT (Volume % in air): N/A燃烧下限：不适用FLAME PROPAGATION RATE (Solids): UL V-O燃烧等级：UL V-OOSHA FLAMMABILITY CLASS: N/AOSHA 燃烧级别：不适用EXTINGUISHING MEDIA: Water, CO2 and dry chemical灭火介质：水、CO2及干化学品SPECIAL FIREFIGHTING PRECAUTIONS/INSTRUCTIONS:特别火灾指导：Firemen should wear proper protective equipment and positive pressure self-contained breathing apparatus.消防员须身穿保护装置及正压呼吸设施。
6. ACCIDENTAL RELEASE MEASURES 意外事故的应变措施IN CASE OF SPILL OR OTHER RELEASE: (Always wear recommended personal protection equipment)如有泄漏或其他释放：（通常身穿所推荐的保护设施）Not applicable, material is an article.不适用于固体材料。
Spills and releases may have to be reported to local authorities.有关泄漏应报告当地政府。
7.HANDLING AND STORAGE 仓贮指南NORMAL HANDLING: (Always wear recommended personal protective equipment.)规范指南：（建议穿戴个人防护设施）The primary exposure route is inhalation of dust when machine/punchedor from fumes or vapors when heated.主要是预防暴露部位吸入当机器打孔时或冒烟、气化液体受热时所产生的粉尘。
STORAGE RECOMMENDATIONS: N/A贮存建议：不适用。
8.EXPOSURE CONTROLS/PERSONAL PROTECTION 泄漏控制/个人保护ENGINEERING CONTROLS: Use local exhaust ventilation to control dust.工程控制：使用当地除尘通风设施。
PERSONAL PROTECTIVE EQUIPMENT:个人保护措施：SKIN PROTECTION: For brief contact to dust, no precautions other than clean body-covering clothing should needed. Use gloves and aprons when prolonged or frequently repeated contact occurs.皮肤保护：对于短暂性的接触粉尘，需要时清洗身体或衣服，无预防措施。
对于长期性的接触，要配带手套和围裙EYE PROTECTION: Use appropriate eye protection when machining material.眼睛保护：当加工材料时使用眼睛保护装置。
RESPIRATORY PROTECTION: When respiratory protection is required for certain operations, use aNIOSH-approved dust respirator.呼吸保护：当进行产生大量粉尘的操作时使用规范的粉尘防毒面罩。
ADDITIONAL RECOMMENDATIONS: N/A其它建议：不适用9. PHYSICAL AND CHEMICAL PROPERTIES 物理化学性能APPEARANCE: Yellow to amber sheets外观：黄色PHYSICAL STATE: Solid物理形态：固体ODOR: None, unless heated气味：无味，除非加热SPECIFIC GRA VITY: (Water = 1.0) 1.5 +/- 0.25比重：（水=1.0）1.5+/-0.25SOLUBILITY IN WATER: (Weight %) Negligible in water水溶性：（重量%）在水中可忽略10.STABILITY AND REACTIVITY 稳定性及反应性NORMALLY STABLE? (conditions to avoid) Stable通常稳定？稳定INCOMPATIBILITIES: Not determined不兼容性：不确定HAZARDOUS DECOMPOSITION PRODUCTS: CO, CO2, Oxides of nitrogen if heated in excess of 300 deg. C.Laser drilling or cutting may result in copper metal fume.危险的腐化产品：CO, CO2, NO X（当加热超过300℃），激光打孔或切割时会产生铜金属烟尘。