Contribution of Prosody to the Segmentation and Storage of Words in the Acquisition of a Ne
逐步判别分析的步骤和流程
逐步判别分析的步骤和流程英文回答:Step 1: Define the decision problem.The first step in the Analytic Hierarchy Process (AHP) is to clearly define the decision problem. This involves identifying the goal or objective of the decision, as well as the criteria and alternatives that will be considered. It is important to have a clear understanding of the problem before proceeding to the next steps.Step 2: Develop a hierarchical structure.In this step, a hierarchical structure is developed to represent the decision problem. The goal is placed at the top of the hierarchy, followed by the criteria and alternatives. The criteria are the factors that will be used to evaluate the alternatives, while the alternatives are the options that will be considered. The hierarchicalstructure helps to organize the decision problem and provides a framework for the subsequent analysis.Step 3: Pairwise comparisons.The next step is to perform pairwise comparisons of the criteria and alternatives. This involves comparing each criterion or alternative with every other criterion or alternative and assigning a preference or importance rating. The pairwise comparisons are typically done using a scale, such as a numerical scale or a verbal scale. The goal is to determine the relative importance or preference of each criterion and alternative.Step 4: Calculate priority weights.Once the pairwise comparisons are completed, thepriority weights for each criterion and alternative are calculated. This is done by applying a mathematical method, such as the eigenvector method or the geometric mean method, to the pairwise comparison data. The priority weightsreflect the relative importance of each criterion andalternative in achieving the goal.Step 5: Check for consistency.After calculating the priority weights, it is important to check for consistency in the pairwise comparisons. Inconsistent comparisons can lead to inaccurate results. There are various methods for checking consistency, such as the consistency ratio and the consistency index. If the comparisons are found to be inconsistent, adjustments can be made to improve the consistency.Step 6: Evaluate alternatives.In this step, the alternatives are evaluated based on the priority weights of the criteria. This involves multiplying the priority weights of the criteria by the performance scores of the alternatives for each criterion. The performance scores can be subjective ratings or objective measurements. The goal is to determine theoverall performance of each alternative based on the criteria.Step 7: Make the decision.The final step is to make the decision based on the evaluation of the alternatives. The decision can be made by comparing the overall performance scores of thealternatives or by considering other factors, such as cost or risk. The decision should be based on the priorities and preferences identified in the previous steps.中文回答:步骤1,定义决策问题。
hep-ph9605256 A Fresh Look at the B Semileptonic Branching Ratio and Beauty Lifetimes
2 Semileptonic Branching Ratio
The semileptonic branching ratio of B mesons is de ned as ?( X BSL = P ?(B ! B ! ) +e? ) + ? ; (4) X` NL rare ` where ?NL and ?rare are the inclusive rates for non-leptonic and rare decays, respectively. Measurements of this quantity have been performed by various experimental groups. The status of the results is controversial, as there is a discrepancy between low-energy measurements performed at the (4s) resonance and high-energy measurements performed at the Z 0 resonance. The average value at low energies is BSL = (10:37 0:30)% 12], (b whereas high-energy measurements give BSL) = (11:11 0:23)% 13]. The superscript (b) indicates that this value refers not to B mesons, but to a mixture of b hadrons. Correcting for this fact, we nd the slightly larger value BSL = (11:30 0:26)% 6]. The discrepancy between the low- and high-energy measurements of the semileptonic branching ratio is therefore larger than three standard deviations. If we take the average and in ate the error to account for this fact, we obtain BSL = (10:90 0:46)%. An important aspect in understanding this result is charm counting, i.e. the measurement of the average number nc of charm hadrons produced per B decay. Recently, two new (preliminary) measurements of this quantity have been performed. The CLEO Collaboration has presented the value nc = 1:16 0:05 12], and the ALEPH Collaboration has reported the result nc = 1:20 0:08 14]. The average is nc = 1:17 0:04. In the parton model, BSL ' 13% and nc ' 1:15 15]. Whereas nc is in agreement with experiment, the semileptonic branching ratio is predicted to be too large. With the establishment of the 1=mQ expansion the non-perturbative corrections to the parton model could be computed, and they turned out to be too small to improve the prediction 16]. The situation has changed recently, when it was found that higher-order perturbative corrections lower the value of BSL signi cantly 10]. The exact order- s corrections to the non-leptonic width have been computed for mc 6= 0, and an analysis of the renormalization scale and scheme dependence has been performed. In particular, it turns out that radiative corrections increase the partial width ?(B ! Xccs ) by a large amount. This has two e ects: it lowers the semileptonic branching ratio, but at the price of a higher value of nc. 3
IEC-61854架空线.隔离层的要求和检验
NORMEINTERNATIONALECEI IEC INTERNATIONALSTANDARD 61854Première éditionFirst edition1998-09Lignes aériennes –Exigences et essais applicables aux entretoisesOverhead lines –Requirements and tests for spacersCommission Electrotechnique InternationaleInternational Electrotechnical Commission Pour prix, voir catalogue en vigueurFor price, see current catalogue© IEC 1998 Droits de reproduction réservés Copyright - all rights reservedAucune partie de cette publication ne peut être reproduite niutilisée sous quelque forme que ce soit et par aucunprocédé, électronique ou mécanique, y compris la photo-copie et les microfilms, sans l'accord écrit de l'éditeur.No part of this publication may be reproduced or utilized in any form or by any means, electronic or mechanical,including photocopying and microfilm, without permission in writing from the publisher.International Electrotechnical Commission 3, rue de Varembé Geneva, SwitzerlandTelefax: +41 22 919 0300e-mail: inmail@iec.ch IEC web site http: //www.iec.chCODE PRIX PRICE CODE X– 2 –61854 © CEI:1998SOMMAIREPages AVANT-PROPOS (6)Articles1Domaine d'application (8)2Références normatives (8)3Définitions (12)4Exigences générales (12)4.1Conception (12)4.2Matériaux (14)4.2.1Généralités (14)4.2.2Matériaux non métalliques (14)4.3Masse, dimensions et tolérances (14)4.4Protection contre la corrosion (14)4.5Aspect et finition de fabrication (14)4.6Marquage (14)4.7Consignes d'installation (14)5Assurance de la qualité (16)6Classification des essais (16)6.1Essais de type (16)6.1.1Généralités (16)6.1.2Application (16)6.2Essais sur échantillon (16)6.2.1Généralités (16)6.2.2Application (16)6.2.3Echantillonnage et critères de réception (18)6.3Essais individuels de série (18)6.3.1Généralités (18)6.3.2Application et critères de réception (18)6.4Tableau des essais à effectuer (18)7Méthodes d'essai (22)7.1Contrôle visuel (22)7.2Vérification des dimensions, des matériaux et de la masse (22)7.3Essai de protection contre la corrosion (22)7.3.1Composants revêtus par galvanisation à chaud (autres queles fils d'acier galvanisés toronnés) (22)7.3.2Produits en fer protégés contre la corrosion par des méthodes autresque la galvanisation à chaud (24)7.3.3Fils d'acier galvanisé toronnés (24)7.3.4Corrosion causée par des composants non métalliques (24)7.4Essais non destructifs (24)61854 © IEC:1998– 3 –CONTENTSPage FOREWORD (7)Clause1Scope (9)2Normative references (9)3Definitions (13)4General requirements (13)4.1Design (13)4.2Materials (15)4.2.1General (15)4.2.2Non-metallic materials (15)4.3Mass, dimensions and tolerances (15)4.4Protection against corrosion (15)4.5Manufacturing appearance and finish (15)4.6Marking (15)4.7Installation instructions (15)5Quality assurance (17)6Classification of tests (17)6.1Type tests (17)6.1.1General (17)6.1.2Application (17)6.2Sample tests (17)6.2.1General (17)6.2.2Application (17)6.2.3Sampling and acceptance criteria (19)6.3Routine tests (19)6.3.1General (19)6.3.2Application and acceptance criteria (19)6.4Table of tests to be applied (19)7Test methods (23)7.1Visual examination (23)7.2Verification of dimensions, materials and mass (23)7.3Corrosion protection test (23)7.3.1Hot dip galvanized components (other than stranded galvanizedsteel wires) (23)7.3.2Ferrous components protected from corrosion by methods other thanhot dip galvanizing (25)7.3.3Stranded galvanized steel wires (25)7.3.4Corrosion caused by non-metallic components (25)7.4Non-destructive tests (25)– 4 –61854 © CEI:1998 Articles Pages7.5Essais mécaniques (26)7.5.1Essais de glissement des pinces (26)7.5.1.1Essai de glissement longitudinal (26)7.5.1.2Essai de glissement en torsion (28)7.5.2Essai de boulon fusible (28)7.5.3Essai de serrage des boulons de pince (30)7.5.4Essais de courant de court-circuit simulé et essais de compressionet de traction (30)7.5.4.1Essai de courant de court-circuit simulé (30)7.5.4.2Essai de compression et de traction (32)7.5.5Caractérisation des propriétés élastiques et d'amortissement (32)7.5.6Essais de flexibilité (38)7.5.7Essais de fatigue (38)7.5.7.1Généralités (38)7.5.7.2Oscillation de sous-portée (40)7.5.7.3Vibrations éoliennes (40)7.6Essais de caractérisation des élastomères (42)7.6.1Généralités (42)7.6.2Essais (42)7.6.3Essai de résistance à l'ozone (46)7.7Essais électriques (46)7.7.1Essais d'effet couronne et de tension de perturbations radioélectriques..467.7.2Essai de résistance électrique (46)7.8Vérification du comportement vibratoire du système faisceau/entretoise (48)Annexe A (normative) Informations techniques minimales à convenirentre acheteur et fournisseur (64)Annexe B (informative) Forces de compression dans l'essai de courantde court-circuit simulé (66)Annexe C (informative) Caractérisation des propriétés élastiques et d'amortissementMéthode de détermination de la rigidité et de l'amortissement (70)Annexe D (informative) Contrôle du comportement vibratoire du systèmefaisceau/entretoise (74)Bibliographie (80)Figures (50)Tableau 1 – Essais sur les entretoises (20)Tableau 2 – Essais sur les élastomères (44)61854 © IEC:1998– 5 –Clause Page7.5Mechanical tests (27)7.5.1Clamp slip tests (27)7.5.1.1Longitudinal slip test (27)7.5.1.2Torsional slip test (29)7.5.2Breakaway bolt test (29)7.5.3Clamp bolt tightening test (31)7.5.4Simulated short-circuit current test and compression and tension tests (31)7.5.4.1Simulated short-circuit current test (31)7.5.4.2Compression and tension test (33)7.5.5Characterisation of the elastic and damping properties (33)7.5.6Flexibility tests (39)7.5.7Fatigue tests (39)7.5.7.1General (39)7.5.7.2Subspan oscillation (41)7.5.7.3Aeolian vibration (41)7.6Tests to characterise elastomers (43)7.6.1General (43)7.6.2Tests (43)7.6.3Ozone resistance test (47)7.7Electrical tests (47)7.7.1Corona and radio interference voltage (RIV) tests (47)7.7.2Electrical resistance test (47)7.8Verification of vibration behaviour of the bundle-spacer system (49)Annex A (normative) Minimum technical details to be agreed betweenpurchaser and supplier (65)Annex B (informative) Compressive forces in the simulated short-circuit current test (67)Annex C (informative) Characterisation of the elastic and damping propertiesStiffness-Damping Method (71)Annex D (informative) Verification of vibration behaviour of the bundle/spacer system (75)Bibliography (81)Figures (51)Table 1 – Tests on spacers (21)Table 2 – Tests on elastomers (45)– 6 –61854 © CEI:1998 COMMISSION ÉLECTROTECHNIQUE INTERNATIONALE––––––––––LIGNES AÉRIENNES –EXIGENCES ET ESSAIS APPLICABLES AUX ENTRETOISESAVANT-PROPOS1)La CEI (Commission Electrotechnique Internationale) est une organisation mondiale de normalisation composéede l'ensemble des comités électrotechniques nationaux (Comités nationaux de la CEI). La CEI a pour objet de favoriser la coopération internationale pour toutes les questions de normalisation dans les domaines de l'électricité et de l'électronique. A cet effet, la CEI, entre autres activités, publie des Normes internationales.Leur élaboration est confiée à des comités d'études, aux travaux desquels tout Comité national intéressé par le sujet traité peut participer. Les organisations internationales, gouvernementales et non gouvernementales, en liaison avec la CEI, participent également aux travaux. La CEI collabore étroitement avec l'Organisation Internationale de Normalisation (ISO), selon des conditions fixées par accord entre les deux organisations.2)Les décisions ou accords officiels de la CEI concernant les questions techniques représentent, dans la mesuredu possible un accord international sur les sujets étudiés, étant donné que les Comités nationaux intéressés sont représentés dans chaque comité d’études.3)Les documents produits se présentent sous la forme de recommandations internationales. Ils sont publiéscomme normes, rapports techniques ou guides et agréés comme tels par les Comités nationaux.4)Dans le but d'encourager l'unification internationale, les Comités nationaux de la CEI s'engagent à appliquer defaçon transparente, dans toute la mesure possible, les Normes internationales de la CEI dans leurs normes nationales et régionales. Toute divergence entre la norme de la CEI et la norme nationale ou régionale correspondante doit être indiquée en termes clairs dans cette dernière.5)La CEI n’a fixé aucune procédure concernant le marquage comme indication d’approbation et sa responsabilitén’est pas engagée quand un matériel est déclaré conforme à l’une de ses normes.6) L’attention est attirée sur le fait que certains des éléments de la présente Norme internationale peuvent fairel’objet de droits de propriété intellectuelle ou de droits analogues. La CEI ne saurait être tenue pour responsable de ne pas avoir identifié de tels droits de propriété et de ne pas avoir signalé leur existence.La Norme internationale CEI 61854 a été établie par le comité d'études 11 de la CEI: Lignes aériennes.Le texte de cette norme est issu des documents suivants:FDIS Rapport de vote11/141/FDIS11/143/RVDLe rapport de vote indiqué dans le tableau ci-dessus donne toute information sur le vote ayant abouti à l'approbation de cette norme.L’annexe A fait partie intégrante de cette norme.Les annexes B, C et D sont données uniquement à titre d’information.61854 © IEC:1998– 7 –INTERNATIONAL ELECTROTECHNICAL COMMISSION––––––––––OVERHEAD LINES –REQUIREMENTS AND TESTS FOR SPACERSFOREWORD1)The IEC (International Electrotechnical Commission) is a worldwide organization for standardization comprisingall national electrotechnical committees (IEC National Committees). The object of the IEC is to promote international co-operation on all questions concerning standardization in the electrical and electronic fields. To this end and in addition to other activities, the IEC publishes International Standards. Their preparation is entrusted to technical committees; any IEC National Committee interested in the subject dealt with may participate in this preparatory work. International, governmental and non-governmental organizations liaising with the IEC also participate in this preparation. The IEC collaborates closely with the International Organization for Standardization (ISO) in accordance with conditions determined by agreement between the two organizations.2)The formal decisions or agreements of the IEC on technical matters express, as nearly as possible, aninternational consensus of opinion on the relevant subjects since each technical committee has representation from all interested National Committees.3)The documents produced have the form of recommendations for international use and are published in the formof standards, technical reports or guides and they are accepted by the National Committees in that sense.4)In order to promote international unification, IEC National Committees undertake to apply IEC InternationalStandards transparently to the maximum extent possible in their national and regional standards. Any divergence between the IEC Standard and the corresponding national or regional standard shall be clearly indicated in the latter.5)The IEC provides no marking procedure to indicate its approval and cannot be rendered responsible for anyequipment declared to be in conformity with one of its standards.6) Attention is drawn to the possibility that some of the elements of this International Standard may be the subjectof patent rights. The IEC shall not be held responsible for identifying any or all such patent rights. International Standard IEC 61854 has been prepared by IEC technical committee 11: Overhead lines.The text of this standard is based on the following documents:FDIS Report on voting11/141/FDIS11/143/RVDFull information on the voting for the approval of this standard can be found in the report on voting indicated in the above table.Annex A forms an integral part of this standard.Annexes B, C and D are for information only.– 8 –61854 © CEI:1998LIGNES AÉRIENNES –EXIGENCES ET ESSAIS APPLICABLES AUX ENTRETOISES1 Domaine d'applicationLa présente Norme internationale s'applique aux entretoises destinées aux faisceaux de conducteurs de lignes aériennes. Elle recouvre les entretoises rigides, les entretoises flexibles et les entretoises amortissantes.Elle ne s'applique pas aux espaceurs, aux écarteurs à anneaux et aux entretoises de mise à la terre.NOTE – La présente norme est applicable aux pratiques de conception de lignes et aux entretoises les plus couramment utilisées au moment de sa rédaction. Il peut exister d'autres entretoises auxquelles les essais spécifiques décrits dans la présente norme ne s'appliquent pas.Dans de nombreux cas, les procédures d'essai et les valeurs d'essai sont convenues entre l'acheteur et le fournisseur et sont énoncées dans le contrat d'approvisionnement. L'acheteur est le mieux à même d'évaluer les conditions de service prévues, qu'il convient d'utiliser comme base à la définition de la sévérité des essais.La liste des informations techniques minimales à convenir entre acheteur et fournisseur est fournie en annexe A.2 Références normativesLes documents normatifs suivants contiennent des dispositions qui, par suite de la référence qui y est faite, constituent des dispositions valables pour la présente Norme internationale. Au moment de la publication, les éditions indiquées étaient en vigueur. Tout document normatif est sujet à révision et les parties prenantes aux accords fondés sur la présente Norme internationale sont invitées à rechercher la possibilité d'appliquer les éditions les plus récentes des documents normatifs indiqués ci-après. Les membres de la CEI et de l'ISO possèdent le registre des Normes internationales en vigueur.CEI 60050(466):1990, Vocabulaire Electrotechnique International (VEI) – Chapitre 466: Lignes aériennesCEI 61284:1997, Lignes aériennes – Exigences et essais pour le matériel d'équipementCEI 60888:1987, Fils en acier zingué pour conducteurs câblésISO 34-1:1994, Caoutchouc vulcanisé ou thermoplastique – Détermination de la résistance au déchirement – Partie 1: Eprouvettes pantalon, angulaire et croissantISO 34-2:1996, Caoutchouc vulcanisé ou thermoplastique – Détermination de la résistance au déchirement – Partie 2: Petites éprouvettes (éprouvettes de Delft)ISO 37:1994, Caoutchouc vulcanisé ou thermoplastique – Détermination des caractéristiques de contrainte-déformation en traction61854 © IEC:1998– 9 –OVERHEAD LINES –REQUIREMENTS AND TESTS FOR SPACERS1 ScopeThis International Standard applies to spacers for conductor bundles of overhead lines. It covers rigid spacers, flexible spacers and spacer dampers.It does not apply to interphase spacers, hoop spacers and bonding spacers.NOTE – This standard is written to cover the line design practices and spacers most commonly used at the time of writing. There may be other spacers available for which the specific tests reported in this standard may not be applicable.In many cases, test procedures and test values are left to agreement between purchaser and supplier and are stated in the procurement contract. The purchaser is best able to evaluate the intended service conditions, which should be the basis for establishing the test severity.In annex A, the minimum technical details to be agreed between purchaser and supplier are listed.2 Normative referencesThe following normative documents contain provisions which, through reference in this text, constitute provisions of this International Standard. At the time of publication of this standard, the editions indicated were valid. All normative documents are subject to revision, and parties to agreements based on this International Standard are encouraged to investigate the possibility of applying the most recent editions of the normative documents indicated below. Members of IEC and ISO maintain registers of currently valid International Standards.IEC 60050(466):1990, International Electrotechnical vocabulary (IEV) – Chapter 466: Overhead linesIEC 61284:1997, Overhead lines – Requirements and tests for fittingsIEC 60888:1987, Zinc-coated steel wires for stranded conductorsISO 34-1:1994, Rubber, vulcanized or thermoplastic – Determination of tear strength – Part 1: Trouser, angle and crescent test piecesISO 34-2:1996, Rubber, vulcanized or thermoplastic – Determination of tear strength – Part 2: Small (Delft) test piecesISO 37:1994, Rubber, vulcanized or thermoplastic – Determination of tensile stress-strain properties– 10 –61854 © CEI:1998 ISO 188:1982, Caoutchouc vulcanisé – Essais de résistance au vieillissement accéléré ou à la chaleurISO 812:1991, Caoutchouc vulcanisé – Détermination de la fragilité à basse températureISO 815:1991, Caoutchouc vulcanisé ou thermoplastique – Détermination de la déformation rémanente après compression aux températures ambiantes, élevées ou bassesISO 868:1985, Plastiques et ébonite – Détermination de la dureté par pénétration au moyen d'un duromètre (dureté Shore)ISO 1183:1987, Plastiques – Méthodes pour déterminer la masse volumique et la densitérelative des plastiques non alvéolairesISO 1431-1:1989, Caoutchouc vulcanisé ou thermoplastique – Résistance au craquelage par l'ozone – Partie 1: Essai sous allongement statiqueISO 1461,— Revêtements de galvanisation à chaud sur produits finis ferreux – Spécifications1) ISO 1817:1985, Caoutchouc vulcanisé – Détermination de l'action des liquidesISO 2781:1988, Caoutchouc vulcanisé – Détermination de la masse volumiqueISO 2859-1:1989, Règles d'échantillonnage pour les contrôles par attributs – Partie 1: Plans d'échantillonnage pour les contrôles lot par lot, indexés d'après le niveau de qualité acceptable (NQA)ISO 2859-2:1985, Règles d'échantillonnage pour les contrôles par attributs – Partie 2: Plans d'échantillonnage pour les contrôles de lots isolés, indexés d'après la qualité limite (QL)ISO 2921:1982, Caoutchouc vulcanisé – Détermination des caractéristiques à basse température – Méthode température-retrait (essai TR)ISO 3417:1991, Caoutchouc – Détermination des caractéristiques de vulcanisation à l'aide du rhéomètre à disque oscillantISO 3951:1989, Règles et tables d'échantillonnage pour les contrôles par mesures des pourcentages de non conformesISO 4649:1985, Caoutchouc – Détermination de la résistance à l'abrasion à l'aide d'un dispositif à tambour tournantISO 4662:1986, Caoutchouc – Détermination de la résilience de rebondissement des vulcanisats––––––––––1) A publierThis is a preview - click here to buy the full publication61854 © IEC:1998– 11 –ISO 188:1982, Rubber, vulcanized – Accelerated ageing or heat-resistance testsISO 812:1991, Rubber, vulcanized – Determination of low temperature brittlenessISO 815:1991, Rubber, vulcanized or thermoplastic – Determination of compression set at ambient, elevated or low temperaturesISO 868:1985, Plastics and ebonite – Determination of indentation hardness by means of a durometer (Shore hardness)ISO 1183:1987, Plastics – Methods for determining the density and relative density of non-cellular plasticsISO 1431-1:1989, Rubber, vulcanized or thermoplastic – Resistance to ozone cracking –Part 1: static strain testISO 1461, — Hot dip galvanized coatings on fabricated ferrous products – Specifications1)ISO 1817:1985, Rubber, vulcanized – Determination of the effect of liquidsISO 2781:1988, Rubber, vulcanized – Determination of densityISO 2859-1:1989, Sampling procedures for inspection by attributes – Part 1: Sampling plans indexed by acceptable quality level (AQL) for lot-by-lot inspectionISO 2859-2:1985, Sampling procedures for inspection by attributes – Part 2: Sampling plans indexed by limiting quality level (LQ) for isolated lot inspectionISO 2921:1982, Rubber, vulcanized – Determination of low temperature characteristics –Temperature-retraction procedure (TR test)ISO 3417:1991, Rubber – Measurement of vulcanization characteristics with the oscillating disc curemeterISO 3951:1989, Sampling procedures and charts for inspection by variables for percent nonconformingISO 4649:1985, Rubber – Determination of abrasion resistance using a rotating cylindrical drum deviceISO 4662:1986, Rubber – Determination of rebound resilience of vulcanizates–––––––––1) To be published.。
中国“龙”与西方“dragon”文化比较
校园英语 /中国“龙”与西方“dragon”文化比较陕西师范大学/穆青【摘要】中国龙和西方dragon都是具有丰富文化内涵的文化符号,两者经常在翻译和文化交流中被相提并论。
但二者无论是形象还是象征含义都差别显著。
本文试图从文化成因的角度分析造成二者差异的原因,以加深中西方文化差异的理解,促进中西方文化交流。
【关键词】龙 dragon 文化内涵 文化成因龙在中国是具有丰富文化内涵的特殊神话形象,中国人一向以“龙的传人”自居,龙的形象及其象征含义是中国传统文化的典型代表之一,是中国文化乃至亚洲文化中独特的文化符号。
与之相对应,西方文化中也有关于“龙”的传说,英语中叫做“dragon”,一个常常在翻译时被用来对应中国“龙”的词。
然而事实上,西方文化里的“dragon”所代表的神话形象无论样貌特征还是象征含义都与中国的“龙”大相径庭。
显然,只是简单的将两种“龙”文化等同起来,无疑会对中西方跨文化交流产生阻碍。
因此,研究两种“龙”文化的异同能促进跨文化交流更顺利地进行,也有助于更好地在世界范围内推广中国的“龙”文化。
一、中国龙与西方dragon文化内涵对比1.中国龙与西方dragon形象对比。
“龙”在中国是家喻户晓的神兽,能行云布雨,具有无边的法力,同时也是传说里中华民族的祖先,受到人们的敬仰。
“龙”的形象经过各个朝代的不断发展和丰富,逐渐演化成了今天中国人所熟悉的“神龙”。
根据许慎《说文解字》里的记载:“龙,鳞虫之首,能幽能明,能细能巨,能长能短,春分登天,秋分潜渊。
”东汉学者王符将龙描述为:“其形有九似∶头似牛,角似鹿,眼似虾,耳似象,项似蛇,腹似蛇,鳞似鱼,爪似凤,掌似虎,是也。
其背有八十一鳞,具九九阳数。
其声如戛铜盘。
口旁有须髯,颔下有明珠,喉下有逆鳞。
头上有博山,又名尺木,龙无尺木不能升天。
呵气成云,既能变水,又能变火。
”龙的主体形象是蛇,吸收融合了许多其他动物的形象组成了“龙”这一复合形象,而龙身上的酷似其他动物的特征也象征着龙具有超越普通动物的力量,是变幻莫测的神兽。
6Differential Absorption Spectroscopy
6Differential Absorption SpectroscopyAbsorption spectroscopy is a well-established tool for the analysis of the chem-ical composition of gases.As such,it has played a prominent role in the dis-covery of the physical and chemical properties of the earth’s atmosphere. 6.1The History of Absorption SpectroscopySpectroscopic studies of the earth’s atmosphere date back more than100 years.Some milestones in the investigation of atmospheric composition through spectroscopy include:1879–Marie Alfred Cornu concludes from the change of the edge of the intensity decay in the UV that a trace species in the earth’s atmosphere must be causing the UV-absorption(Cornu,1879).1880–Sir Walter Noel Hartley discovers the absorption of UV-radiation (below300nm)by ozone.This led to the name Hartley-bands for ozone absorption below300nm(Hartley,1880,1881).1880–M.J.Chappuis discovers the absorption of visible light by ozone, which is today called the Chappuis-band.Chappuis also speculates that light absorption by ozone is the reason for the blue colour of the sky (Chappuis,1880).1890–Sir William Huggins discovers a new group of lines in the spectrum of Sirius,which are later explained by Fowler and Strutt as absorption of terrestrial ozone.The long wavelength UV-bands of ozone are,therefore, called Huggins-bands today.1904–Discovery of the infrared absorption of ozone near4.8,5.8,and9.1–10μm by Knut Johan˚A ngstr¨o m.1913–Balloon measurements of the UV absorption of ozone up to10km altitude by Albert Wigand showed essentially no change with altitude. 1918–John William Strutt(better known as Lord Rayleigh)concludes that atmospheric ozone must reside in a layer above10km altitude above the surface.U.Platt and J.Stutz,Differential Absorption Spectroscopy.In:U.Platt and J.Stutz,Differential Optical Absorption Spectroscopy,Physics of Earth and Space Environments,pp.135–174(2008)DOI10.1007/978-3-540-75776-46c Springer-Verlag Berlin Heidelberg20081366Differential Absorption Spectroscopy1920–First ozone column measurements were made by Charles Fabry and Henri Buisson,who determine a column of about3mm(at atmospheric pressure),with large variations.1925–First application of a dedicated ozone spectrometer by Gordon Miller Bourne Dobson(Dobson and Harrison,1926).1926–Paul G¨o tz confirms the theory of an ozone layer by observing the so-called‘Umkehr’effect,and determines its altitude to be about25km. 1934–Direct observation of the ozone layer by UV-spectroscopy by Erich Regener(TH Stuttgart).1948–Marcel Migeotte(Ohio State University)discovers methane and carbon monoxide in the earth atmosphere by near-infrared absorption spectroscopy(Migeotte,1948,1949).1950–Discovery of the emission bands of the hydroxyl radical(OH)in the nightglow(the Meinel bands of the OH-radical).As a consequence, HO x-chemistry is viewed in connection with ozone chemistry by David R.Bates and Marcel Nicolet(1950),and Bates and Witherspoon (1952).1975–First detection of OH in the atmosphere by Dieter Perner and col-leagues using differential optical absorption spectroscopy(Perner et al., 1976).This list illustrates the role that spectroscopy has played in the measure-ment of reactive trace gases in the atmosphere,most notably ozone.The reader may notice that the identification and quantification of gases was primarily accomplished by the analysis of atmospheric absorptions.This is still the case in most current applications of atmospheric spectroscopy.The use of emission bands is restricted to the thermal infrared wavelength region(see Chap.5) or to the excited gas molecules in the upper atmosphere,which emit light at higher energies,i.e.shorter wavelength.Both applications are in use today, but are not the topic of discussion in this book.The initial use of spectroscopy in the atmosphere concentrated on the identification of various gases.Soon,however,this method was put in use to quantify the concentrations(or column densities)of these species.In particu-lar,the contributions of Dobson,who constructed thefirst instrument for the regular measurement of atmospheric ozone,should be singled out(Dobson and Harrison,1926).This chapter focuses on a modern method to quantitatively measure a large variety of trace gases in the atmosphere.DOAS is now one of the most commonly used spectroscopic methods to measure trace gases in the open atmosphere.At the beginning,we give a general introduction to absorption spectroscopy and DOAS.This is followed by an overview of different exper-imental approaches of DOAS and a discussion of the precision and accuracy of this method.The last section of this chapter is dedicated to a rigorous mathematical description of the various DOAS applications.6.2Classical Absorption Spectroscopy 1376.2Classical Absorption SpectroscopyThe basis of the early spectroscopic measurements,and many present quanti-tative trace gas analytical methods in the atmosphere and the laboratory,is Lambert–Beer’s law,often also referred to as Bouguer–Lambert law.The law was presented in various forms by Pierre Bouguer in 1729,Johann Heinrich Lambert in 1760,and August Beer in 1852.Bouguer first described that,‘In a medium of uniform transparency the light remaining in a collimated beam is an exponential function of the length of the path in the medium’.However,there was some confusion in the naming of this law,which may be either the name of individual discoverer or combinations of their names.In this book,we have referred to it as Lambert–Beer’s law.A variety of spectroscopic techniques make use of the absorption of elec-tromagnetic radiation by matter (Fig.6.1).In a formulation suitable for the analysis of gaseous (or liquid)absorbers,Lambert–Beer’s law can be writ-ten as:I(λ)=I0(λ)·exp (−σ(λ)·c ·L).(6.1)Here,I 0(λ)denotes the initial intensity of a light beam emitted by a suitable source of radiation,while I (λ)is the radiation intensity of the beam after pass-ing through a layer of thickness L ,where the absorber is present at a uniform concentration of c .The quantity σ(λ)denotes the absorption cross-section at wavelength λ.The absorption cross-section as a function of wavelength is a characteristic property of any species.The determination of the light path length,L ,is usually trivial for active DOAS applications (see Chap.4).Once those quantities are known,the average trace gas concentration,c ,can be calculated from the measured ratio I 0(λ)/I (λ):c =ln I 0(λ)I(λ) σ(λ)·L=D σ(λ)·L .(6.2)DetectorL IntensityI 0(λ)I(λ)LightSource Absorber with concentration cFig. 6.1.The basic principle of absorption spectroscopic trace gas detection.A beam of light passes through a volume of length L containing the absorber with concentration c .At the end of the light path the intensity is measured by a suitable detector1386Differential Absorption SpectroscopyThe expressionD=lnI0(λ)I(λ),(6.3)is called the optical density of a layer of a given absorber.Note that,in the literature,the decadal as well as the natural logarithm is used in the definition of optical density.In this book,we will exclusively use the natural logarithm.Equation(6.2)is the basis of most absorption spectroscopic applications in the laboratory,where the intensities I(λ)and I0(λ)are determined by measurements with and without the absorber in the light beam.However,the application of Lambert–Beer’s law is more challenging in the open atmosphere.Here,the true intensity I0(λ),as it would be received from the light source in the absence of any atmospheric absorber,is difficult to determine.It would involve removing the air,or more precisely the absorbing gas,from the atmosphere.While this may seem to present a dilemma rendering atmospheric absorption spectroscopy useless in this case,the solution lies in measuring the so-called‘differential’absorption,i.e.the difference between the absorptions at two different wavelengths.This principle was used by Dobson in the1930s to determine the total column of atmospheric ozone.In an ingenious experimental setup,the Dobson spectrometer compares the intensity of direct solar light of two wavelengths–λ1,λ2–with different ozone absorption cross-section,σ1=σ(λ1),σ2=σ(λ2)(Dobson and Harrison,1926).6.3The DOAS PrincipleA schematic setup of an experiment to measure trace gas absorptions in the open atmosphere is shown in Fig.6.2.Similar to Fig.6.1,light emitted by a suitable spectral broadband source with an intensity I0(λ)passes through a volume with absorbers(here the open atmosphere),and is collected at the end of the light path.As the light travels through the atmosphere,its intensity is reduced through the absorption of a specific trace gas.However,it also undergoes extinction due to absorption by other trace gases,and scattering by air molecules and aerosol particles.The transmissivity of the instrument (mirrors,grating,retro-reflectors,etc.)will also decrease the light intensity, as will the light beam widening by turbulence.By expanding Lambert–Beer’s law,one can consider the various factors that influence the light intensity by an equation that includes the absorption of various trace gases with concentration c j and absorption cross-sectionsσj(λ),Rayleigh and Mie extinction,εR(λ) andεM(λ)(described byεR(λ)≈σR0(λ)·λ−4·c AIR andεM(λ)=σM0·λ−n·N A,respectively;see Chap.4),and instrumental effects and turbulence, summarised in A(λ):I(λ)=I0(λ)·exp−L·(σj(λ)·c j)+εR(λ)+εM(λ)·A(λ).(6.4)6.3The DOAS Principle 139I 0(~λ–4~λ–(1...3)Fig.6.2.Sketch of an experiment to measure trace gas absorptions in the open atmosphereTo determine the concentration of a particular trace gas,it would,in principle,be necessary to quantify all other factors influencing the intensity.In the laboratory,this can be achieved by removing the absorber from the light path.In the atmosphere,however,where this is impossible,the multiple factors influencing the intensity pose a dilemma.Differential optical absorption spectroscopy overcomes this challenge by using the fact that aerosol extinction processes,the effect of turbulence,and many trace gas absorptions show very broad or even smooth spectral charac-teristics.Certain trace gases,however,exhibit narrowband absorption struc-tures.The foundation of DOAS is thus to separate broad-and narrowband spectral structures in an absorption spectrum in order to isolate these narrow trace gas absorptions (Fig.6.3).The broad spectrum is then used as a new intensity spectrum I 0 (λ),and Lambert–Beer’s law can again be applied to the narrowband trace gas absorptions.Figure 6.3illustrates the separation of the narrow-and broadband struc-tures for one absorption band,both for the absorption cross-section and the intensity:σj (λ)=σj 0(λ)+σ j (λ)(6.5)σj 0in (6.5)varies ‘slowly’with the wavelength λ,for instance describing a gen-eral ‘slope’,such as that caused by Rayleigh and Mie scattering,while σ j (λ)shows rapid variations with λ,for instance due to an absorption band (see Fig.6.3).The meaning of ‘rapid’and ‘slow’variation of the absorption cross-section as a function of wavelength is,of course,a question of the observed wavelength interval and the width of the absorption bands to be detected.Inserting (6.5)into (6.4),we obtain:I(λ)=I 0(λ)·exp ⎡⎣−L ·⎛⎝ jσ j(λ)·c j ⎞⎠⎤⎦·exp ⎡⎣−L ·⎛⎝ j (σj0(λ)·c j )+εR (λ)+εM (λ)⎞⎠⎤⎦·A (λ),(6.6)1406Differential AbsorptionSpectroscopyFig.6.3.Principle of DOAS:I 0and σare separated by an adequate filtering pro-cedure into a narrow (D ,and σ )and broad band part (I 0and σb )where the first exponential function describes the effect of the structured ‘differential’absorption of a trace species,while the second exponential con-stitutes the slowly varying absorptions as well as the influence of Rayleigh and Mie scattering.The attenuation factor A (λ)describes the broad wavelength-dependent transmission of the optical system used and turbulence.Thus,we can define a quantity I 0as the intensity in the absence of differential absorption:I 0(λ)=I 0(λ)·exp ⎡⎣−L ·⎛⎝ j(σj0(λ)·c j )+εR (λ)+εM (λ)⎞⎠⎤⎦·A (λ).(6.7)The corresponding differential absorption cross-section σ j (λ)is then substi-tuted for σj (λ)in (6.1)and (6.2).σ j (λ)is determined in the laboratory (i.e.taken from literature data),just like σj (λ).Likewise,a differential optical den-sity,D ,can be defined in analogy to (6.3)as the logarithm of the quotient of the intensities I 0and I 0(as defined in (6.7)and (6.6),respectively):D=ln I 0(λ)I(λ)=L · j σ j (λ)·c j .(6.8)Atmospheric trace gas concentrations can then be calculated according to (6.2),with differential quantities D and σ (λ)substituted for D and σ(λ),respectively.A separation of the different absorptions in the sum of (6.8)is6.4Experimental Setups of DOAS Measurements141 possible because the structures of the trace gases are unique,like afingerprint (see Sect.6.5).Both the separation of broad and narrow spectral structures and the sep-aration of the various absorbers in(6.8)require the measurement of the radi-ation intensity at multiple wavelengths.In fact,DOAS measurements usually observe the intensity at500–2000individual wavelengths to accurately de-termine the concentrations of the various absorbing trace gases.The use of multiple wavelengths is an expansion of the principles used,for example,by Dobson,which were based on two or four wavelengths.The use of differential absorptions over an extended wavelength range has a number of major advantages.Because the transmission of optical instru-ments typically shows broad spectral characteristics,no calibration of the optical properties or their change with time is necessary.This often makes the instrumentation much simpler and less expensive.The use of a multi-tude of wavelengths allows the unique identification of trace gas absorptions.A further major advantage of this approach is the opportunity to observe and quantify extremely weak absorptions corresponding to optical densities around D =10−4.In particular,the ability to use very long light paths in the atmosphere,in active DOAS applications sometimes up to10–20km long (passive DOAS applications can reach1000km),increases the sensitivity of DOAS and,at the same time,provides spatially averaged values.Before giving a more rigorous mathematical description of the DOAS method,the basic experimental setups,the trace gases that are commonly measured,and the typical detection limits of DOAS will be reviewed in the following sections.6.4Experimental Setups of DOAS MeasurementsThe DOAS principle as outlined earlier can be applied in a wide variety of light path arrangements and observation modes(Fig.6.4).To provide a general overview of different setups,we introduce a classification system that will later be used in the description of the different analysis methods(see Sect.6.7 and Chap.8)and the technical details(Chap.7).According to their light sources,we distinguish between active and pas-sive DOAS.In short,active DOAS uses artificial light,while passive DOAS relies on natural light sources,i.e.solar,lunar,or stars.An overview of the most common experimental setups illustrates the breadth of DOAS applica-tions that are in use today(Fig.6.4).6.4.1Active DOASActive DOAS applications have one thing in common–they rely on an arti-ficial light source coupled to an optical setup that is used to send and receive1426Differential Absorption Spectroscopy1. Long-Path DOAS (LP-DOAS)2. Vertical Profiling LP-DOASReflectors Light sourceRetro-reflector3. Tomographic DOAS4. Folded-Path DOAS5. Direct Sunlight DOAS6. Balloon-borne (direct sunlight) DOASLPMA/DOAS Gondola + Balloon7. Satellite-borne DOAS - Occultation8. Zenith Scattered Light (ZSL-DOAS)9. Multi-Axis DOAS (MAX-DOAS)10. Airborne Multi-Axis DOAS (AMAX-DOAS)Fig.6.4.The DOAS principle can be applied in a wide variety of light path ar-rangements and observation modes using artificial (1–4)as well as natural direct (5–7)or scattered (8–14)light sources.Measurements can be done from the ground,balloons,aircrafts,and from space6.4Experimental Setups of DOAS Measurements14312. Satellite-borne DOAS -Nadir Geometry11. Imaging DOAS13. Satellite-borne DOAS - Scattered LightLimb Geometry14. Determination of the Photon Path length L (in Clouds) ‘inverse DOAS’Fig.6.4.Continuedlight in the atmosphere.Spectroscopic detection is achieved by a spectrom-eter at the end of the light path.In general,active DOAS is very similar to classical absorption spectroscopy,as employed in laboratory spectral pho-tometers.However,the low trace gas concentrations in the atmosphere require very long light paths (up to tens of kilometres in length,see above),making the implementation of these instruments challenging (see Chap.7for details).Active DOAS applications are typically employed to study tropospheric com-position and chemistry,with light paths that are often parallel to the ground.In addition,active DOAS systems are also used in smog and aerosol chamber experiments.The earliest applications of active DOAS,i.e.the measurement of OH radicals (Perner et al.,1976),used a laser as the light source along one single path (Fig.6.4,Plate 1).This long-path DOAS setup is today most com-monly used with broadband light sources,such as xenon-arc lamps,to mea-sure trace gases such as O 3,NO 2,SO 2,etc.(e.g.Stutz and Platt,1997a,b).Expansion of this method involves folding the light beam once by using retro-reflectors on one end of the light path (Axelsson et al.,1990).This setup simplifies the field deployment of long-path DOAS instruments.In ad-dition,applications that use multiple retro-reflector setups to probe on dif-ferent air masses are possible.Figure 6.4,Plate 2,shows the setup that is used to perform vertical profiling in the boundary layer with one DOAS sys-tem.An expansion that is currently under development is the use of mul-tiple crossing light paths to perform tomographic measurements (Fig.6.4,Plate 3).1446Differential Absorption SpectroscopyIn applications where detection in smaller air volumes with high sensitiv-ity is required,folded-path DOAS is often used(Fig.6.4,Plate4)(e.g. Ritz et al.,1992).Because the light can pass the multiple reflection cells in these systems up to144times,long light paths can be achieved in small air volumes.These systems are the most common DOAS setups in laboratory applications,where interference by aerosols makes the use of classical absorp-tion spectroscopy impossible(e.g.smog and aerosol chambers).Folded-path DOAS has also been used for the same applications as long-path DOAS(e.g. Alicke et al.,2003;Kurtenbach et al.,2002).In particular,the use of laser to measure OH has been successful(see Chap.10).Active DOAS measurements have contributed to the discovery and quan-tification of a number of important atmospheric trace species,most notably the radicals OH and NO3(Perner et al.,1976;Platt et al.,1979).The ele-gance of active DOAS is that the expanded Lambert–Beer’s law(6.4)can be directly applied to the calculation of trace gas concentrations based only on the absorption cross-section,without the need for calibration of the instru-ment in thefield.This gives active DOAS high accuracy and,with the long light paths,excellent sensitivity.6.4.2Passive DOASPassive DOAS utilises light from natural sources.The two most important sources are the sun and the moon.However,the use of light from other stars has also been reported.While the measurement of light directly from moon and stars is possible,sunlight offers two alternatives:direct sunlight and sun-light scattered in the atmosphere by air molecules and particles.We will fur-ther subdivide passive DOAS applications into direct and scattered light measurements(see also Chap.11).Direct measurements use the sun,moon,or stars as light sources,and thus share the advantage of active DOAS of directly applying Lambert–Beer’s law. However,since the light crosses the entire vertical extent of the atmosphere, a direct conversion of absorptions to concentrations is not possible.Instead, the column density,i.e.the concentration integrated along the path,is the direct result of these measurements.Only by using geometric and radiative transfer calculations can these measurements be converted into vertically in-tegrated column densities(VCD)or vertical concentration profiles.The most common example for VCDs is the total ozone column,which is measured in Dobson units.Figure6.4gives several examples for direct passive DOAS setups.Besides direct measurements of sun,moon,and star light from the ground(Fig.6.4,Plate5),balloon-borne solar measurements have been very successful(Fig.6.4,Plate6).The measurements during the ascent provide ver-tical profiles of various trace gases.With the recent deployment of space-borne DOAS instruments,i.e.SCIAMACHY,occultation measurements(Fig.6.4, Plate7)have also become possible.6.4Experimental Setups of DOAS Measurements145Scattered sunlight measurements are more universally used in passive DOAS since they offer the largest variety of applications.The measurement of scattered light from the zenith(Fig.6.4,Plate8)was one the earliest applications of passive DOAS(see Sect.11.2),and has contributed consider-ably to our understanding of stratospheric chemistry(e.g.Mount et al.,1987; Solomon et al.,1987,1988,1989).In addition,zenith scattered light has also been used to study the radiative transport in clouds(Fig.6.4,Plate14),which is an important topic in climate research(Pfeilsticker et al.,1998b,1999).A more recent development of passive scattered DOAS is the use of multiple viewing geometries(Fig.6.4,Plate9).This multi-axis DOAS(MAX-DOAS) uses the fact that,at low viewing elevations,the length of the light path in the lower troposphere is considerably elongated(e.g.H¨o nninger et al.,2004).It is thus possible to probe the lower troposphere sensitively.In addition,vertical profiles can be derived if enough elevation angles are measured.MAX-DOAS can also be employed from airborne platforms,allowing the measurements below and above theflight altitude(Fig.6.4,Plate10),as well as determina-tion of vertical concentration profiles.An expansion of MAX-DOAS,which is currently under development,is Imaging DOAS(Fig.6.4,Plate11),where a large number of viewing elevations are measured simultaneously to visualise pollution plumes.Over the past decade,DOAS has also been used for satellite-borne mea-surements(Fig.6.4,Plates12,13),which use sunlight scattered either by the atmosphere,the ground,or both(see Sect.11.5).Two viewing geometries of these measurements are possible(for details and examples,see Chap.11).In the nadir geometry,the DOAS system looks down towards the earth’s surface. Instruments such as GOME provide global concentrationfields of trace gases, such as O3,NO2,and HCHO.The SCIAMACHY instrument also employs measurements in limb geometry,which allow the determination of vertical trace gas profiles with high resolution(Fig.6.4,Plate13).The advantage of passive DOAS applications is the relatively simple exper-imental setup.For example,scattered light measurements require only small telescopes.In addition,no artificial light source is needed.However,a number of additional challenges have to be addressed in passive DOAS applications. Because solar and lunar light is spectrally highly structured,special care needs to be taken.To detect very small trace gas absorptions,the strong Fraunhofer bands must be accurately measured.In addition,the fact that the light source structure contains narrow and deep absorptions also makes the application of the DOAS technique,which was outlined in Sect.6.3,more difficult.This will be discussed in more detail below.The largest challenge in using passive DOAS is the conversion of the observed column densities to vertical column densities,concentrations,and vertical profiles.This is,in particular,the case for scattered light setups,where the length of the light path is difficult to de-termine.The interpretation of these measurements,therefore,must be based on detailed radiative transfer calculations(see Chap.9).1466Differential Absorption Spectroscopy6.5Trace Gases Measured by DOASThe separation of broad and narrow spectral structures(Sect.6.3),while making absorption spectroscopy usable in the atmosphere,restricts DOAS measurements to trace gases that have narrow band absorption structures with widths narrower than∼10nm.In theory,all gases that have these narrow absorption bands in the UV,visible,or near IR can be measured.However, the concentrations of these compounds in the atmosphere,and the detection limits of today’s DOAS instruments,restrict the number of trace gases that can be detected.As DOAS instruments improve in the future,this list will most likely grow.Figures6.5and6.6show the absorption cross-sections of a number of trace gases that are regularly measured by DOAS.A number of features about these cross-sections should be pointed out here.First and most importantly,each trace gas spectrum has a unique shape.Most of the trace gases only absorb in certain wavelength intervals.However,many spectral regions can contain a large number of simultaneous absorbers.For example,between300and 400nm,the following trace gases will show absorption features if they are present at high enough concentrations:O3,SO2,NO2,HONO,HCHO,and BrO.Because of their unique spectral structure,a separation of the absorp-tions is possible.From(6.8),it is clear that spectral regions with higherσ will show the largest optical densities.These spectral intervals are thus preferred for DOAS measurements since the sensitivity improves in these wavelength regions.In principle,each trace gas has an optimal wavelength interval.In practice,however,one has to often compromise in the choice of the wave-length interval to measure more than one trace gas simultaneously.Because expanding the wavelength window reduces the spectral resolution of typical grating spectrometers,the sensitivity is also reduced.The choice of trace gases thus depends on the specific application.In Fig.6.7,we have attempted to aid in the choice of the best wavelength re-gion by visualising the detection limits of an extended set of trace gases for long-path applications in the troposphere.It should be added that a number of other trace gases,besides those shown in Figs.6.5and6.6,can be measured.Table6.1gives an overview of the var-ious trace gases measured by DOAS,including stratospheric trace gases.At shorter wavelengths,the usable spectral range of DOAS is limited by rapidly increasing Rayleigh scattering and O2absorption(Volkamer et al.,1998). Those effects limit the maximum light path length to∼200m in the wave-length range from200–230nm,where,for instance,the sole usable absorption features of species such as NO(Tajime et al.,1978)and NH3are located(see Fig.6.7and Table6.1).6.5Trace Gases Measured by DOAS147200300400500600700NO 2NO 3SO 2A b s o r p t i o n c r o s s -s e c t i o n i n 10–19 c m 2 m o l e c u l e –1Wavelength in nmBrOHCHO CHOCHOIOOIOClOHONOO 4I 2OBrOOClO0100100.01.0 x 10–451000.00.802000602000100060050400100010001 × 102O 3 cross-section × 1000O 3Fig.6.5.Details of the absorption cross-section features of a number of species of atmospheric interest as a function of wavelength (in nm).Note the ‘fingerprint’nature of the different spectra1486Differential Absorption SpectroscopyFig.6.6.Details of the differential absorption cross-section features of a number of monocyclic aromatic species,O2,and O3as a function of wavelength(in nm).Note the‘fingerprint’nature of the different spectra。
Superconducting phase diagram of the filled skuterrudite PrOs4Sb12
a r X i v :c o n d -m a t /0402681v 2 [c o n d -m a t .s u p r -c o n ] 16 M a r 2004Superconducting phase diagram of the filled skuterrudite PrOs 4Sb 12M.-A.Measson 1,D.Braithwaite 1,J.Flouquet 1,G.Seyfarth 2,J.P.Brison 2,E.Lhotel 2,C.Paulsen 2,H.Sugawara 3,and H.Sato 31D´e partement de Recherche Fondamentale sur la Mati`e re Condens´e e,SPSMS,CEA Grenoble,38054Grenoble,France2Centre de Recherches sur les Tr`e s basses temp´e ratures,CNRS,25avenue des Martyrs,BP166,38042Grenoble CEDEX 9,France3Department of Physics,Tokyo Metropolitan University,Minami-Ohsawa 1-1,Hashioji,Tokyo 192-0397,JapanWe present new measurements of the specific heat of the heavy fermion superconductor PrOs 4Sb 12,on a sample which exhibits two sharp distinct anomalies at T c 1=1.89K and T c 2=1.72K.They are used to draw a precise magnetic field-temperature superconducting phase diagram of PrOs 4Sb 12down to 350mK.We discuss the superconducting phase diagram of PrOs 4Sb 12and its possible relation with an unconventional superconducting order parameter.We give a detailed analysis of H c 2(T ),which shows paramagnetic limitation (a support for even parity pairing)and multiband effects.PACS numbers:65.40.Ba,71.27.+a,74.25.Dw,74.25.Op,74.70.TxI.INTRODUCTIONThe first Pr-based heavy fermion (HF)superconductor PrOs 4Sb 12(T c ∼1.85K)has been recently discovered 1.Evidence for its heavy fermion behavior is provided mainly by its superconducting properties,like the height of the specific heat jump at the superconducting tran-sition or the high value of H c 2(T )relative to T c 1.PrOs 4Sb 12is cubic with T h point group symmetry 2,and has a nonmagnetic ground state,which in a single ion scheme can be either a Γ23doublet or a Γ1singlet,a ques-tion which remains a matter of controversy.Presently,most measurements in high field seem to favor a singlet ground state 3,4,5,6.In any case,whatever the degeneracy of this ground state,the first excited state (at around 6K)is low enough to allow for an induced electric quadrupo-lar moment on the Pr 3+ions 7,8,that could explain the heavy fermion properties of this system by a quadrupo-lar Kondo effect 1.Thus,while the pairing mechanism of usual HF superconducting compounds (U or Ce-based)could come from magnetic fluctuations,the supercon-ducting state of PrOs 4Sb 12could be due to quadrupolar fluctuations.Yet at present,this attractive hypothesis is backed by very few experimental facts,both as re-gards the evidence of a quadrupolar Kondo effect in the normal phase and as regards the pairing mechanism in the superconducting state.Even the question of the un-conventional nature of its superconductivity is still open.Indeed,several types of experiments have already probed the nature of this superconducting state,but with appar-ently contradictory results.Concerning the gap topology,scanning tunneling spectroscopy measurements point to a fully open gap,with some anisotropy on the Fermi surface 9.Indication of unconventional superconductivity might come from the distribution of values of the resid-ual density of states (at zero energy)on different parts of the sample surface.This could be attributed to a pair-breaking effect of disorder.The same conclusion as re-gards the gap size was reached by µSR measurements 10and NQR measurements 11,although unconventional su-perconductivity is suggested in the latter case by the ab-sence of a coherence peak below T c in 1/T 1.This should be contrasted with recent penetration depth measurements,that would indicate point nodes of the gap 12,or the angular dependence of the thermal con-ductivity which suggests an anisotropic superconducting gap with a nodal structure 13.This latter measurement also suggests multiple phases in the temperature (T )-field (H )plane,which could be connected to the dou-ble transitions observed in zero field 14,15,16.Recent µSR relaxation experiments 17detected a broadening of the internal field distribution below T c ,suggesting a multi-component order parameter or a non unitary odd parity state,with a finite magnetic moment.In this context,our results bring new insight on the question of the parity of the order parameter,and draw a definite picture of the (H,T)phase diagram as deduced from specific heat measurements.With reference to the historical case of UPt 3,we emphasize that the present status of sample quality may explain the discrepancies between the various measurements :definite claims on the nature of the superconducting state in PrOs 4Sb 12are at the very best too early,the key point being the sample quality.II.EXPERIMENTAL DETAILSWe present results on single crystals of PrOs 4Sb 12grown by the Sb flux method 18,19.These samples are aggregates of small single crystals with well developed cubic faces.They have a good RRR of about 40(between room temperature and 2K),a superconducting transition (onset of C p or ρ)at 1.887K and,they present a very sharp double superconducting transition in the specific heat.20.511.522.533.54C p/T (J /K 2.m o l )FIG.1:Specific heat of samples of the same batch including sample n ◦1asC p3C /T (a .u .)FIG.3:Field sweeps of the ac specific heat of sample n ◦1at several temperatures.An arbitrary line between the two tran-sitions was subtracted.We follow the two transitions (H c 2and H ′)down to 350mK.00.511.5µH (T )FIG.4:H −T superconducting phase diagram of PrOs 4Sb 12determined by specific heat measurements on sample n ◦1.The field dependence of T c 1and T c 2are completely similar.The lines are fits by a two-band model of the upper critical field (Section V B 2).Only T c has been changed from H c 2to H ′.IV.SAMPLE CHARACTERIZATIONThree pieces of sample n ◦1have been used for furthercharacterizations,called 1a,1b and 1c.As well as the specific heat of sample n ◦1a (2mg),we have measured the resistivity of samples n ◦1b (0.2mg)and n ◦1c ,and the ac susceptibility and dc magnetization of samples n ◦1a and n ◦1b .Concerning the specific heat,the high absolute value of C p as well as the large height of the two supercon-ducting jumps (∆(C p /T )=350mJ/mol.K 2at T c 1and ∆(C p /T )=300mJ/mol.K 2at T c 2)must be linked to the high quality of these samples (absence of Sb-flux and/or good stoichiometry).Moreover,the heights of the two steps of sample n ◦1a are quantitatively similar to those of the entire batch (7.5mg)as Vollmer has already pointed out 14.Like in previous work 1,21,we have noticed that the resistivity at 300K is very sample dependent (from 200to 900µΩ.cm).On all samples,the value of ρat 300K seems to scale with the slope at high temperature (T ≥200K),i.e.the phononic part of the resistivity,as if the discrepancies were due to an error on the geometric factor.This error could be explained by the presence of microcracks in the samples.We have taken this problem into account by normalizing all data to the slope dρ/dT at high temperature (T ≥200K)of sample n ◦1c,chosen arbitrarily.For samples n ◦1b and n ◦1c respectively (Fig.5),the RRR (ratio between 300K and 2K values)are 44and 38,the onset T c are 1.899K and 1.893K (match-ing the critical temperature obtained by specific heat),and the temperatures of vanishing resistance (T R =0)are 1.815K and 1.727K.T R =0of sample n ◦1c is equal to T c 2and this remains true under magnetic field.So,in sample n ◦1c ,the resistive superconducting transition is not complete between T c 1and T c 2.Figure 6shows the superconducting transition for sam-ples n ◦1a and n ◦1b by ac-susceptibility (H ac =0.287Oe),corrected for the demagnetization field.The onset tem-perature is the same for the two samples (1.88K).The transition is complete only at around 1.7K and two tran-sitions are visible.The field cooled dc magnetization of samples n ◦1a and n ◦1b (H dc =1Oe),shown in fig.7,gives a Meissner effect of,respectively,44%and 55%,indicat-ing (like specific heat)that the superconductivity is bulk.The two transitions are also visible.V.DISCUSSIONA.Double superconducting transitionLet us first discuss the nature (intrinsic or not)of the double transition observed in our specific heat mea-surements.The remarkable fact,compared to previous reports 14,15,is the progress on the sharpness of both tran-sitions.If for previous reports,a simple distribution of T c due to a distribution of strain in the sample could42004001000050100150300ρ(µΩ.cm)FIG.5:Resistivity of samples n◦1b and n◦1c normalized tothe slope at high temperature of sample n◦1c.The inset isa zoom on the superconducting transition.The resistivity ofsample n◦1c is zero only at T c2.-0.08-0.07-0.06-0.05-0.04-0.03-0.02-0.01χi'AC(emu/cm3)FIG.6:Real partχ′of the AC susceptibility of samples n◦1aand n◦1b measured with an AC magneticfield of0.287Oeat2.11Hz.Like in the results of resistivity measurement,thesuperconducting transition is not complete at T c1and the twotransitions are visible.have explained the transition width,it is not the caseanymore for the sharp features observed on these newsamples.Also the explanation recently proposed22thatthe lower transition at T c2would be induced by Joseph-son coupling of one sheet of the Fermi surface to anotherwith transition temperature T c1is excluded,owing to the-0.08-0.07-0.06-0.05-0.04Memu/cm3FIG.7:DC magnetization of sample n◦1a at H DC=1Oewith zerofield cooled(ZFC)andfield cooled(FC)sweeps.The Meissner effect is44%for this sample and55%for samplen◦1b(not shown).The superconductivity is bulk.sharpness of both transitions and particularly of that atT c2:see the broadening calculated by the authors22forthe Josephson induced transition.Nevertheless,some ofour results still cast serious doubts on the intrinsic na-ture of the double transition.Indeed,the susceptibilityalso shows a”double”transition,and resistivity becomeszero only at T c2.If thefirst transition at T c1was bulk-homogeneous,the resistivity should immediately sink tozero below T c1,and the susceptibility(χ)should alsoshow perfect diamagnetism far before T c2:the samplediameter is at least1000times larger than the penetra-tion depth(λ)so that the temperature dependence ofλcannot explain such a transition width ofχ(contraryto the statements of E.E.M.Chia12).So both resistiv-ity and susceptibility are indicative of remaining sampleinhomogeneities.Nevertheless,in our opinion,even the comparisonof the various characterizations of the superconductingtransition by resistivity,susceptibility and specific heaton the same sample does not allow for a definite conclu-sion.Two historical cases are worth remembering.URu2Si2showed a double transition in the specific heat in somesamples,with inhomogeneous features detected in thesusceptibility23.In that case,the authors of reference23could clearly show that it was not intrinsic(maybe aris-ing from internal strain?)because different macroscopicparts of the same sample showed one or the other tran-sition.In PrOs4Sb12,the specific heat results are repro-ducible among various samples of the same batch(seesamples n◦1and n◦1a of the present work),and such aneasy test does not work.5The second case is of course UPt3:it is now well estab-lished that the two transitions observed in zerofield are intrinsic and correspond to order parameters of different symmetries.But thefirst results on samples that were not homogeneous enough showed exactly the same be-haviour as the present one in PrOs4Sb12:two features in the susceptibility and a very broad(covering both tran-sitions)resistive transition24.It was not until the sample quality improved significantly that resistivity and suscep-tibility transitions matched the higher one25.The puz-zling result for PrOs4Sb12,compared to UPt3,is that despite the sharpness of the specific heat transitions,re-sistivity and susceptibility reveal inhomogeneities,which means that this new compound probably has unusual metallurgical specificities.Continuing the parallel with UPt3,basic measure-ments rapidly supported the intrinsic origin of the two transitions:they were probing the respectivefield and pressure dependence of both transitions.Indeed,a com-plete(H-T)phase diagram was rapidly drawn,showing that in UPt326,like in U1−x T h x Be1327,the two transi-tions observed in zerofield eventually merged under mag-neticfield,due to a substantial difference in dT c/dH.It is even more true for the pressure dependence of T c1,2,as the thermal dilation has jumps of opposite sign at the two transitions,indicating opposite variations of T c1,2under pressure(Ehrenfest relations)28.So in this compound, the two transitions could be rapidly associated with a change of the symmetry of the order parameter indicating the unconventional nature of the superconducting state. We are not so lucky in the case of PrOs4Sb12:indeed, thefield dependence of T c2seems completely similar to that of T c1(fig.4),a claim that will be made quantita-tive below.It is the same situation as in URu2Si223,and nothing in favor of an intrinsic nature of the double tran-sition can be deduced from this phase diagram.Another phase diagram has already been established by transport measurements,with a line H∗(T)separating regions of twofold and fourfold symmetry in the angular depen-dence of thermal conductivity under magneticfield13. It may seem likely13,29that this line would merge with the double transition in zerofield.From the line H′(T) drawn from our specific heat measurements(T c2(H),fig.4),we can onclude that this is not the case:H′(T)does not match the line H∗(T)drawn in reference13,unless there is an unlikely strong sample dependence of these lines.Comparison of the pressure dependence of T c1and T c2 seems more promising:contrary to case of UPt328the jump of the thermal expansion at the two superconduct-ing temperatures does not change sign16,but from the relative magnitude of these jumps and our specific heat peaks,we get a value dT c1/dp≈−0.2K/GPa,and twice as much for dT c2/dp.This supports a different origin for both transitions.The weak point is that the ther-mal expansion measurements were done on two samples mounted on top of each other,that were early samples with rather broad specific heat transitions.Thus,the question of the intrinsic nature of the double supercon-ducting transition remains open.B.Upper criticalfieldAnother quantity which has not been thoroughly dis-cussed is the upper criticalfield H c2(T).In heavy fermion superconductors,H c2(T)has always proved to be an in-teresting quantity,mainly due to the large mass enhance-ment of the quasiparticles.Indeed,the usual orbital lim-itation is very high in these systems,due to the low Fermi velocity,so that the authors of reference1could, from their H c2(T)data,confirm the implication of heavy quasiparticles in the Cooper pairs(revealed also by the specific heat jump at T c).They also gave an estimate of the heaviest mass:≈50m0,where m0is the free electron mass.But,as the orbital limitation is very high,H c2(T)is also controlled by the paramagnetic effect.A quantita-tivefit of H c2(T)easily gives the amount of both limi-tations,except that on this system,H c2(T)has an ex-tra feature:a small initial positive curvature close to T c.This feature has been systematically found,what-ever the samples and the techniques used to determine H c2(T)(ρ,χand C p)1,13,14,21.Our data,obtained byρon sample n◦1c and C p on sample n◦1,matches all other published results.So we can now consider this curvature of H c2(T)as intrinsic,and not due to some artifact of transport measurements,or coming from inhomogeneity in the sample.Such an intrinsic positive curvature also appears in MgB230or in borocarbides like YNi2B2C and LuNi2B2C31.1.Physical inputsWe propose an explanation based on different gap am-plitudes for the different sheets of the Fermi surface of PrOs4Sb12,which is made quantitative through a”two-band”model32.Microscopically,STM spectroscopy also reveals an anisotropic gap,with zero density of states at low energy(fully open gap)but a large smearing of the spectra9.Recent microwave spectroscopy measurements also discuss a two band model22,but in order to explain the double transition.We insist that our model has noth-ing to do with the double transition,which clearly in-volves heavy quasiparticles both at T c1and at T c2(see the size of the two specific heat jumps):our aim is a quan-titative understanding of H c2(T),based on the normal state properties of PrOs4Sb12,as in MgB2or borocar-bides where no double transition has ever been observed. The physical input of a multi-band model for H c2(T)is to introduce different Fermi velocities and different in-ter and intra band couplings.As a result,T c is always larger than for any of the individual bands33.The slope of H c2at T c is larger for slower Fermi velocity(heavier) bands.Positive curvature of H c2(T)is easily obtained6 if the strongest coupling is in the heaviest bands(largeH c2),with a slight T c increase due to the inter band cou-pling to the lightest bands(small initial slope)31.2.The two-band model:There are at least three sheets for the Fermi surface of PrOs4Sb12,but in the absence of a precise knowl-edge of the pairing interaction,a full model would be unrealistic,having an irrelevant number of free parame-ters.A two band model is enough to capture the physics of anisotropic pairing,although only the correspondence with band calculations becomes looser.In our model, band2would correspond to the lightest(β)band de-tected by de-Haas van Alphen measurements,and band 1would be a heavy band having most of the density of states.Indeed,the de Haas-van Alphen experiments on PrOs4Sb1234,35reveal the presence of light quasiparti-cles(bandβ)and heavier particles(bandγ).The heavi-est quasiparticles are at present only seen by thermody-namic measurements(C p or H c2).Anisotropic coupling between the quasiparticles is considered in the framework of an Eliashberg strong coupling two-band model32in the clean limit,with an Einstein phonon spectrum(charac-teristic”Debye”frequencyΩ).Let us point out that the results do not depend on(and a fortiori do not probe) the pairing mechanism,which is likely to be much more exotic than the usual electron-phonon -pared to a single band calculation,there is now a matrix of strong coupling parametersλi,j describing the diffu-sion of electrons of band i to band j by the excitations responsible for the pairing.What matters for H c2(T)is the relative weight of the λi,j,not their absolute value:we consider T c or the renor-malized Fermi velocities as experimental inputs.λi,j de-pends both on the interaction matrix elements between bands i and j,and on thefinal density of states of band j33.In MgB2,it is claimed that electron-phonon coupling is largest within theσbands.Here,knowing nothing about the pairing mechanism,we assume con-stant inter and intra band coupling,so that the rela-tive weight of theλi,j is only governed by the density of states of band j.This density of states is itself pro-portional to the contribution of that band to the specific heat Sommerfeld coefficient:500mJ/K2.mol1for band 1,20mJ/K2.mol for band234,35.The Fermi velocity of band1(not observed by de Haas-van Alphen measure-ments)is the main adjustable parameter of thefit:we find v F1=0.0153106m/s−1,in agreement with1where the Fermi velocity has been inferred from the slope of H c2(T)at T c ignoring the initial positive curvature.All other coefficients are either arbitrary(λ1,1=1)(in agree-ment with the strong coupling superconductivity con-cluded in11),conventional values(gyromagnetic ratio for the paramagnetic limitation g=2,Coulomb repulsion parameterµ∗i,j=0.1δi,j),orfixed by experimental data (T c=1.887K=⇒Ω=21.7K,v F2=0.116.106m.s−10.511.523.5µH(T)FIG.8:Open circles show the data of H c2(T)by specific heat measurement on PrOs4Sb12(sample n◦1).The lines showfits with a two-band model(solid line),with a single-band model (dashed line),without the paramagnetic limit(g=0)(dotted line).It shows that the increase of T c due to the coupling with light qp band is rapidly suppressed in weak magnetic fields.H c2is also clearly Pauli limited,supporting a singlet superconducting state.The parameters for the solid linefit are:g=2,µ∗i,j=0.1δi,j,v F1=0.0153106m/s−1(heavy band),v F2=0.116.106m.s−1(lightest band,from de Haas-van Alphen oscillations35),T c=1.887K=⇒Ω=21.7K.from the de Haas-van Alphen data on theβband).The modelfits well the experimental data(cf.fig.4),includ-ing the small positive curvature.Before discussing the interpretation of thefit as regards the values of the pa-rameters and the parity of the superconducting order pa-rameter,let us note that we canfit the H′(T)line(fig.4) with the same parameters as for H c2exceptΩ,adjusted to give T c=1.716K.There is a good agreement with all data except at very low temperature or near T c where the curvature is reduced compared to H c2(T).However, these deviations are weak,and this is why we claim that H′(T)has the same behavior than H c2(T),which does not help to identify the second transition with a symme-try change of the superconducting order parameter.3.InterpretationShown also infig.8are the calculations of H c2(T)for a single band model:v F1,the characteristic frequency Ωandλ1,1have the same values as before,but all other λi,j coefficients have been turned down to zero,elimi-nating the effects of the light electron band.T c is then reduced(down to1.78K)and the positive curvature dis-appears.We also observe that thefit of H c2is basi-7 cally unchanged above1T,meaning that lowfields sup-press the superconductivity due to the light electron bandrestoring a”single band”superconducting state.Thisis the same effect observed more directly in MgB2withspecific heat measurements under magneticfield:thesmaller gap rapidly vanishes,leading to afinite densityof states at the Fermi level under magneticfields dueto theπband36.This suppression of the light quasi-particle superconductivity would have here an effect onspecific heat too small to be observed(contribution ofthe light quasiparticles to the specific heat of order4%of the Sommerfeld coefficient,itself buried in the largeSchottky anomaly).But it may have much larger ef-fects on transport.Let us note that the clean limit is aposteriori justified:from v F1,wefind a coherence lengthξ0∼110˚A,whereas from a residual resistivityρ0and spe-cific heat coefficientγ∼0.5J/K2.mol∼2.103J/K2.m3,3L0we get v F1l∼811H.Kotegawa,M.Yogi,Y.Imamura,Y.Kawasaki,G.-q.Zheng,Y.Kitaoka,S.Ohsaki,H.Sugawara,Y.Aoki,andH.Sato,Phys.Rev.Letters90,027001(2003).12E.E.M.Chia,M.B.Salamon,H.Sugawara,and H.Sato, Phys.Rev.Letters91,247003(2003).13K.Izawa,Y.Nakajima,J.Goryo,Y.Matsuda,S.Osaki,H.Sugawara,H.Sato,P.Thalmeier,and K.Maki,Phys.Rev.Letters90,117001(2003).14R.Vollmer,A.Faißt,C.Pfleiderer,H.v.L¨o hneysen,E.D.Bauer,P.-C.Ho,V.Zapf and M.B.Maple,Phys.Rev.Lett.90,057001(2003).15M.B.Maple,P.-C.Ho,V.S.Zapf,N.A.Frederick,E.D.Bauer,W.M.Yuhasz,F.M.Woodward,and J.W.Lynn,J.Phys.Soc.Jpn.71(2002),Suppl.23.16N.Oeschler,P.Gegenwart, F.Steglich,N.A.Frederick,E.D.Bauer,and M.B.Maple,Acta Physica Polonica B34,959(2003).17Y.Aoki,A.Tsuchiya,T.Kanayama,S.R.Saha,H.Sug-awara,H.Sato,W.Higemoto,A.Koda,K.Ohishi,K.Nishiyama,and R.Kadono,Phys.Rev.Letters91,067003 (2003).18N.Takeda and M.Ishikawa,Physica B259-261,92(1999). 19E.D.Bauer,A.´Slebarski,E.J.Freeman,C.Sirvent,and M.B.Maple:J.Phys:Condens Matter13,4495-4503 (2001).20Y.Aoki(private communication).21P.-C.Ho,N.A.Frederick,V.S.Zapf,E.D.Bauer,T.D.Do, M.B.Maple,A.D.Christianson,and cerda,Phys.Rev.B67,180508(2003).22D.M.Broun,P.J.Turner,G.K.Mullins, D.E.Sheehy, X.G.Zheng,S.K.Kim,N.A.Frederick,M.B.Maple,W.N.Hardy,and D.A.Bonn,cond.mat.031061323A.P.Ramirez,T.Siegrist,T.T.M.Palstra,J.D.Garrett,E.Bruck,A.A.Menovsky and J.A.Mydosh,Phys.Rev.B44,5392(1991).24A.Sulpice,P.Gandit,J.Chaussy,J.Flouquet,D.Jaccard, P.Lejay and J.L.Tholence,J.Low Temp.Phys62,39(1986).25K.Hasselbach,L.Taillefer and J.Flouquet,Phys.Rev.Letters63,93(1989).26G.Bruls,D.Weber,B.Wolf,P.Thalmeier,B.L¨u thi,A.de Visser and A.Menovsky,Phys.Rev.Letters65,2294 (1990);S.Adenwalla,S.W.Lin,Q.Z.Ran,Z.Zhao,J.B.Ketterson, J.A.Sauls,L.Taillefer,D.G.Hinks,M.Levy and B.K.Sarma,Phys.Rev.Letters65,2298(1990).27D.S.Jin,S.A.Carter,T.F.Rosenbaum,J.S.Kim,and G.R.Stewart,Phys.Rev.B53,8549(1996).28K.Hasselbach,cerda,K.Behnia,L.Taillefer,and J.Flouquet,J.of Low Temp.Phys.81,299(1990).29Jun Goryo,Phys.Rev.B67,184511(2003).30S.L.Budko and P.C.Canfield,Phys.Rev.B65,212501 (2002).31S.V.Shulga,S.-L.Drechsler,G.Fuchs,K.-H.M¨u ller,K.Winzer,M.Heinecke,and K.Krug,Phys.Rev.Letters80, 1730(1998).32M.Prohammer and E.Schachinger,Phys.Rev.B36,8353 (1987).33I.I.Mazin and V.P.Antropov,Physica C385,49(2003). 34H.Sugawara,S.Osaki,S.R.Saha,Y.Aoki,and H.Sato, Acta Physica Polonica B34,1125(2003).35H.Sugawara,S.Osaki,S.R.Saha,Y.Aoki,H.Sato,Y.Inada,H.Shishido,R.Settai,Y.Onuki,H.Harima,and K.Oikawa,Phys.Rev.B66,220504(R)(2002).36F.Bouquet,Y.Wang,I.Sheikin,T.Plackowski,A.Junod, S.Lee and S.Tajima,Phys.Rev.Letters89,257001 (2002).37F.B.Anders,Eur.Phys.J.B28,9-28(2002).38K.Miyake,H.Kohno,and H.Harima,J.of Phys.Cond.Matter15,L275-84(2003).39M.Ichioka,N.Nakai,and K.Machida,J.of the Phys.Soc.of Japan72,1322(2003).。
English Literature
外国语学院 2011级5班张红宇British Literature--- Medieval English Literature The medieval period is one of the richest in the literary history. Within it we find, particularly in the lyrics, some of the most delightful, elegant, beautiful and bizarre poetry ever written in our language. There are expressions of joy and sorrow, ecstasy and triumph, both spiritual and carnal, distillations of love offered to God, the Virgin or an indifferent mistress, theological expositions, wild moments of bawdy fun, vicious assaults in the battles of the sexes, evocations of the impossibly beautiful, and any of them may be parodied to expressions of devotion or ridicule. No emotion can have been neglected by the medieval poets.One of the oldest of these early“Old English”literary works is a long poem from Anglo-Saxon times called Beowulf .A long narrative poem telling about the deeds of a great hero and reflecting the values of the society from which it originated. Many epics were drawn from an oral tradition and were transmitted by song and recitation before they were written down.With the Norman Conquest starts the medieval period in English lite rature, which covers about four centuries.In the early part of the period, i.e. from 1066 up to the mid-14th century, there was not much to say about literature in English. It was almost a barren period in literary creation.But in the second half of the 14th century, English literature started to flourish with the appearance of writers like Geoffrey Chaucer, William Langland, John Cower, and others. In comparison with Old English literature, Midd le English literature deals with a wider range of subjects, is uttered by mo re voices and in a greater diversity of styles, tones and genres.Popular folk literature also occupies an important place in this period. Its presentatio n of life is not only accurate but also lively and colorful,though the origin ality of thought is often absent in the literary works of this period. Beside s, Middle English literature strongly reflects the principles of the medieva l Christian doctrine, which were primarily concerned with the issue of per sonal salvation.Romance which uses narrative verse or prose to sing knightly advent ures or other heroic deeds is a popular literary form in the me dieval perio d. It has developed the characteristic medieval motifs of the quest, the test , the meeting with the evil giant and the encounter with the beautiful belo ved. The hero is usually the knight, who sets out on a journey to accompl ish some missions to protect the church, to attack infidelity, to rescue a m aiden, to meet a challenge, or to obey a knightly command.There is often a liberal use of the improbable, sometimes even supernatural, things in ro mance such as mysteries and fantasies.While the structure is loose and epi sodic, the language is simple and straightforward. The importance of the r omance itself can be seen as a means of showing medieval aristocratic me n and women in relation to their idealized view of the world.If the epic re flects a heroic age, the romance reflects a chivalric one.Among the three great Middle English poets, the author of Sir Gawai n and the Green Knight is the one who produced the best romance of the period; while William Langland is a more realistic writer who dealt with t he religious and social issues of his day in Piers Plowman.However, it is Chaucer alone who, for the first time in English literature, presented to us a comprehensive realistic picture of the English society of his time and cr eated a whole gallery of vivid characters from all walks of life in his mast erpiece The Canterbury Tales. Geoffrey Chaucer is the greatest writer of t his period. Although he was born a commoner, he did not live as a comm oner; and although he was accepted by the aristocracy, he must always have been conscious of the fact that he did not really belong to that society of which birth alone could make one a true member. Chaucer characteristi cally regarded life in terms of aristocratic ideals, but he never lost the abil ity of regarding life as a purely practical matter. The art of being at once i nvolved in and detached from a given situation is peculiarly Chaucer's.Th e influence of Renaissance was already felt in the field of English literatur e when Chaucer was learning from the great Italian writers like Petrarch a nd Boccaccio in the last part of the 14th century. Chaucer affirmed man's right to pursue earthly happiness and opposed asceticism; he praised man 's energy, intellect, quick wit and love of life; he exposed and satirized the social vices, including religious abuses. It thus can be said thatthough essentially still a medieval writer, Chaucer bore marks of humanis m and anticipated a new era to come.In his works, Chaucer explores the theme of the individual's relation to the society in which he lives;he portrays clashes of characters' tempera ments and their conflicts over material interests;he also shows the comic and ironic effects obtainable from the class distinctions felt by the newly emerged bourgeoisie as in the case of the Wife of Bath who is depicted as the new bourgeois wife asserting her independence.In short, Chaucer dev elops his characterization to a higher artistic level by presenting character s with both typical qualities and individual dispositions. Chaucer introduc ed from France the rhymed stanzas of various types to English poetry to r eplace the Old English alliterative verse. In addition to his contribution to English prosody, Chaucer also developed the art of literature itself beyon d anything to be found in any other medieval literature. Though Chaucer was entirely rooted in the soil of the Middle Ages, his art is so fully realiz ed as to carry him beyond his time and make him one of the greatest poet s in English.Chaucer dominated the works of his 15th-century English followers and the so-called Scottish Chaucerians. For the Renaissance, he was the En glish Homer. Many of Shakespeare's plays show thorough assimilation of Chaucer's comic spirit.Today, Chaucer's reputation has been securely esta blished as one of the best English poets for his wisdom, humor, and huma nity.In comparison with Old English literature, Middle English literature deals with a wider range of subjects, is uttered by more voices and in a greater diversity of styles, tones and genres. Popular folk literature also occupies an important place in this period. Its presentation of life not only accurate but also lively and colorful, though the originality of thought is often absent in literary works of this period. Besides, Middle English literature strongly reflects the principles of the medieval Christian doctrine, which were primarily concerned with the issue of personal salvation.外国语学院2011级5班张红宇American LiteratureThe North American literature began with the settlement of the English puritans. The first settlers wrote about their voyage to the new land about adapting themselves to unfamiliar climates and crops, about dealing with Indians. They wrote in diaries and in journals. They wrote letters and contracts and government charters and religious and political statements. They wrote about the land that stretched before them--unimaginable and immense, with rich dense forests and deep-blue lakes and rich soil. It stirred the imagination to great heights. All seemed possible through hard-work and faith. All these experiences gave birth to the Puritan values: hard work, thrift, piety and sobriety. American literature is in good measure a literary expression of the pious idealism of the American puritan values.Essentially, American literature during this period reflected the beginnings of a struggle for definition and meaning which still, in varying degrees, characterizes the American national character. One may see the struggle of the individual for expression, the belief in a future, the fight for civil rights, the constraints of factors (in this case religion and the Severity of nature) sometimes beyond one' s control, and the different, almost contradictory reasons for coming. *Some for material and business advantage; *others for religious freedom,* still others for a religious life but an independent, politically democratic one. These impulses have, in a large sense, set the tone for the country and have reverberated throughout American history and literature, from Plymouth Rock to the recent election of the United States presidency. These original impulses found expression in the diaries, journals, poems and sermons of the day. Examine their authors and the works themselves will givesubstance to these.The writing style of this period is fresh, simple and direct; the rhetoric is plain and honest, with a touch of nobility often traceable to the direct influence of the Bible. All this has left an obvious imprint on American writing. The most important writers of this period include William Bradford , Cotton Mather, and Anne Bradstreet.Cotton Mather (1663-1728) was a socially and politically influential Puritan minister, prolific author, and pamphleteer. Cotton Mather was the son of influential minister Increase Mather. The latter is often remembered for his connection to the Salem witch trials.Author of more than 450 books and pamphlets, Cotton Mather's ubiquitous literary works made him one of the most influential religious leaders in America. Mather set the nation's "moral tone," and sounded the call for second and third generation Puritans, whose parents had left England for the New England colonies of North America to return to the theological roots of Puritanism.The most important of these, Magnalia Christi Americana, is composed of 7 distinct books, many of which depict biographical and historical narratives which later American writers such as Nathaniel Hawthorne, Elizabeth Drew Stoddard, and Harriet Beecher Stowe(Uncle Tom’s Cabin) would look to in describing the cultural significance of New England for later generations following the American Revolution.William Bradford (1590--1657) was one of the greatest of colonial American, a man large in spirit and wisdom, wholly consecrated to a mission in which he regarded himself as an instrument of God. Bradford was born of a yeoman farmer and a tradesman' s daughter in Yorkshire.Orphaned in his first year by his father' s death and trained for farming by relatives, almost without formal education, he was a well-read man who brought a considerable library with him to Plymouth at the ageof thirty. At the age of eighteen, he accompanied the group to Holland to escape persecution. Then 13 years later he was one of those who, on December 11, took on the Mayflower and entered Plymouth Bay. From 1622 until his death, Bradford was reelected thirty times as governor.In 1630, Bradford began writing Of Plymouth Plantation, a story of these early Americans and their long geographical and spiritual pilgrimage. His Chronicle conveys not only facts but also feelings because he imaginatively projects himself and his readers into the experience of each moment. He makes a personal story out of the voyage, the settlement, and the grim realities of “the starving time.”Through him, readers share the struggle, the fears, and the victories over the elements. In his manuscript, Bradford always keeps sight of signs of God’s judgement and providence. He sees the signs everywhere, so that, for example, the Indian interpreter Squanto becomes “an instrument sent of God for their God in the same way as the Israelites’exodus from Egypt.”Bradford writes in the Puritan plain style, seldom using any metaphors or decorative language. He found no need to decorate a chronicle of events so charged with excitement, danger, and emotion.Anne Bradstreet ( 1612-1672 ) is regarded as the first noteworthy American poet, who was born in Northampton, England in 1612. Her Puritan father, Thomas Dudley, was a steward of the estates of the earl of Lincoln. Thus Anne had the advantage of good tutoring, with access to the earl' s considerable library. Then in 1630 she came to the Massachusetts Bay Colony with her husband and her parents.Her first book, The Tenth Muse Lately Sprung Up in America, was published in England in 1650 and was a great success. Bradstreet' s finest poems are those closest to her personal experience as a Puritan wife and mother living on the edge of the wilderness.Like other Puritans, she found similarities between the domestic details of daily life and the spiritual details of her religious life. And the note of piety, gently sounded, was in her work. For Bradstreet the everyday and the everlasting were simply two sides of the same experience.Among her surviving prose writings, her Contemplations deserve to be particularly remembered for their lucid simplicity of style and their wise and generous spirit. In Contemplations she attempts to feel the will of God and believe that human beings can live forever after death, which is better than those earthly things. In conclusion, Anne Bradstreet was not an innovative poet, but her directness and her sincerity are moving.。
BinomialLinkFunctions:二项链接功能
following table:
Example (continued)
> beetle<-read.table("BeetleData.txt",header=TRUE)
> head(beetle)
Dose Num.Beetles Num.Killed
(Intercept) -34.935
2.648 -13.19 <2e-16 ***
Dose
19.728
1.487 13.27 <2e-16 ***
--Signif. codes: 0 ‘***’ 0.001 ‘**’ 0.01 ‘*’ 0.05 ‘.’ 0.1 ‘ ’ 1
(Dispersion parameter for binomial family taken to be 1)
yi
i 1
n
e
xi T ˆ
• Logit:
pˆ i
• Probit:
pˆ i ( xiT ˆ )
• C Log Log:
pˆ i 1 exp{ exp[ xiT ˆ ]}
1 e
xi T ˆ
Differences in Link Functions
probLowerlogit <- vector(length=1000)
family = binomial) > summary(logitmodel)
> probitmodel<-glm(cbind(Num.Killed,Num.Beetles-Num.Killed) ~ Dose, data = beetle,
MSS SP-43-2008 锻制不锈钢对焊管件
MSS STANDARD PRACTICE SP-43iThis MSS Standard Practice was developed under the consensus of the MSS Technical Committee 113 and the MSS Coordinating Committee. The content of this Standard Practice is the result of the efforts of competent and concerned volunteers to provide an effective, clear, and non-exclusive specification that will benefit the industry as a whole. This MSS Standard Practice is intended as a basis for common practice by the manufacturer, the user, and the general public. The existence of an MSS Standard Practice does not in itself preclude the manufacture, sale, or use of products not conforming to the Standard Practice. Mandatory conformance is established only by reference in a code, specification, sales contract, or public law, as applicable.Unless otherwise specifically noted in this MSS SP, any standard referred to herein is identified by the date of issue that was applicable to the referenced standard(s) at the date of issue of this MSS SP. (See Annex A).This document has been substantially revised from the previous 1991 (R 2001) edition. It is suggested that if the user is interested in knowing what changes have been made, that direct page-by-page comparison should be made of this document with the previous edition .Any part of this Standard Practice may be quoted. Credit lines should read 'Extracted 432008 from MSS SP-,, with permission of the publisher, the Manufacturers Standardization Society.' Reproduction prohibited under copyright convention unless written permission is granted by the Manufacturers Standardization Society of the Valve and Fittings Industry, Inc.Originally Approved October, 1950Copyright 1982 byManufacturers Standardization Societyof theValve and Fittings Industry, Inc.Printed in U.S.A.MSS STANDARD PRACTICE SP-43FOREWORDASME B16.9 is the American Standard for steel butt-welding fittings and although not so stated, it is implied that its scope deals primarily with the schedules of wall thicknesses which are common to carbon steel and the grades of alloy steel piping that are selected for pressure and temperature considerations.The rapid expansion of the process industries in the field of chemicals, plastics, textiles, etc.,has created a demand for a class of pipe referred to as stainless piping, using this word in its generic sense.This field employs the use of the austenitic stainless steels and also nickel and its related alloys. This stainless piping is used with resistance to corrosion, elimination of product contamination, or combination of the two as the principle reason for material selection. Pressure is seldom, if ever, a critical consideration.When pressure is a consideration reference is made to ASME B16.9.Mechanical strength, resistance to vacuum, and economy, are the most usual criteria in the selection of pipe thickness in this field, and for this reason the wall thicknesses employed in the field of corrosion resistant pipe are lighter than those in common usage with carbon steel piping.In 1949 ANSI approved standard B36.19 Stainless Steel Pipe in which a schedule of wall thickness was established and designated as Schedule 10S. Numerous companies were also using a wall thickness lighter than Schedule 10S for services where contamination rather than corrosion was the prime consideration. These lighter wall thicknesses were designated Schedule 5S and the original 1950 edition of SP-43 established a series of Schedule 5S fittings. The 5S thicknesses were published in SP-43 and were developed in cooperation with representatives of the various principal chemical companiesand processing industries. In 1952 the Stainless Steel Pipe Standard B36.19 was revised to recognize the Schedule 5S wall thickness pipe as American Standard.The purpose of this Standard Practice is to provide industry with a set of dimensional standardsfor butt-welding fittings that can be used with these light wall pipes of corrosion resisting materials. The center-to-end dimensions of all fittings are identical with those in ASME B16.9 which give to industrythe advantage of uniform design room practice and a maximum utilization of existing die equipment.The only departure from this is in the lap-joint stub end where for purposes of economy the face-to-endof the product has been reduced for use with thin wall piping.The advantage of longer center-to-end dimensions of the size 3/4 elbows resulted in the changein the tables to permit a gradual changeover, providing the manufacturers ample time to deplete existing stocks, re-tool and replenish stocks.The 1991 revision of the SP was required to delete the metric equivalents.The 2001 Reaffirmation had no technical changes. There were minor editorial changes. The precedence of the longer dimensions for 3/4 elbows was made in accordance with ASME B16.9. Referenced standards were brought up to date. The title of 180 degree returns was clarified.In this 2008 edition, a minimal pressure rating is established to correspond with the ASTM CR designation.iiMSS STANDARD PRACTICE SP-43TABLE OF CONTENTSSECTION PAGE1 SCOPE (1)2 REFERENCES (1)3 PRESSURE RATINGS (1)4 SIZE (1)5 MARKING (1)6 MATERIALS (2)7 METAL THICKNESS (2)8 FITTINGS DIMENSIONS (2)9 TESTS (2)10 TOLERANCES (2)11 WELDING BEVEL (2)12 FINISH AND HEAT TREATMENT (2)TABLE1 Tolerances (3)2 Dimensions of Long Radius Elbows (4)3 Dimensions of Straight and Reducing-on-the-Outlet Tees (5)4 Dimensions of Lap-Joint Stub Ends and Caps (7)5 Dimensions of Long Radius 180 Degree Returns (8)6 Dimensions of Concentric and Eccentric Reducers (9)ANNEXA Referenced Standards and Applicable Dates (10)iiiMSS STANDARD PRACTICE SP-4311. SCOPE1.1 This Standard Practice provides dimensions, tolerances, and markings for butt-welding fittings for low pressure, corrosion resistant applications. 1.2 This Standard Practice covers only fittings made for use with Schedule 5S or 10S pipe, for all NPS sizes listed in ASME B36.19M, except that for short pattern stub ends suitable for use with Schedule 40S are also shown.2. REFERENCES2.1 Standards and specifications adopted by reference in this Standard Practice are shown in Annex A for convenience of identifying edition number, date, and source of supply.3. PRESSURE RATINGS3.1 Fittings covered by this Standard Practice are not pressure rated; however, they must be capable of withstanding 30% of the allowable pressure rating of the pipe with which they are marked. 3.2 For fittings of same pressure rating of matching pipe, refer to ASME B16.9.4. SIZE4.1 The size of the fittings in Tables 1 through 6 are identified by the corresponding nominal pipe size.5. MARKING5.1 Each fitting shall be marked to show the following:a) Manufacturer s name or trademarkb) CR followed by the material identification symbol established for the respective grade inthe appropriate ASTM or AISI specifications c) Manufacturer s heat identification number d) Schedule number or nominal wall thicknessdesignation e) Size5.2 Where the size of the fittings does not permit complete marking, Sections 5.1 a) and c) are mandatory. The other marking and identification marks may be omitted in the sequence specified in MSS SP-25.5.3 The required markings shall be made by any suitable method that is not injurious to the fitting.WROUGHT AND FABRICATED BUTT-WELDING FITTINGS FOR LOW PRESSURE, CORROSION RESISTANT APPLICATIONSMSS STANDARD PRACTICE SP-4326. MATERIALS6.1 Fittings made from AISI Types 304, 304L, 347, 316, and 316L are considered standard under this specification. Fittings made from other corrosion resistant material, including nonferrous, materials are acceptable by agreement between the purchaser and the manufacturer provided they meet the requirements of a recognized AISI or ASTM specification.7. METAL THICKNESS7.1 As these fittings are to match pipe, the dimensions of the welding ends must conform to established pipe standards as to outside diameters and tolerances. The nominal wall thickness of the fittings shall be the same as the pipe to which it is welded, except that fittings with heavier walls may be butt-welded to lighter wall pipe provided the heavier wall is tapered on the inside or outside to match the dimensions of the lighter pipe. 8. FITTINGS DIMENSIONS8.1 Inch dimensions for the fittings covered by this Standard Practice are given in Tables 1 through 6.8.2 One of the principals of this Standard Practice is the maintenance of a fixed position for welding ends with reference to center line of the fittings or the overall dimensions as the case may be. 9. TESTS9.1 Hydrostatic testing of fittings is not required in this Standard Practice; however, fittings shall be capable of withstanding a hydrostatic test pressure that is 1.5 times the pressure rating required in Section 3.1.10. TOLERANCES10.1 Table 1 lists the tolerances for the fittings covered by this Standard Practice. 11. WELDING BEVEL11.1 Fittings furnished to this Standard Practice may be finished with ends cut square for wall thickness 0.12 in. or less. For wall thicknessesin excess of 0.12 in., they shall be beveled at37 l/2plus or minus 2 l/2 withrootface(land)0.06in.plus or minus 0.03 in.MSSSTANDARD PRACTICESP-433O u t s i d e D i a m e t e r o f L a p G+ 0 - 0.03+ 0 - 0.03+ 0 - 0.03+ 0 - 0.03+ 0 - 0.06+ 0 - 0.06L a p -J o i n t S t u b E n d sF i l l e t (b )R a d i u s o f L a p A + 0 - 0.03 + 0 - 0.03 + 0 - 0.03 + 0 - 0.06 + 0 - 0.06 + 0 - 0.06 C a p sO v e r a l l L e n g t h E ± 0.12 ± 0.12 ± 0.12± 0.25 ± 0.25± 0.25A l i g n -m e n t o f E n d s U ± 0.03 ± 0.03 ± 0.03± 0.03 ± 0.06 ± 0.06 B a c k -t o - F a c e D i m e n s i o n K ± 0.25 ± 0.25 ± 0.25 ± 0.25± 0.25± 0.25 180° R e t u r n sC e n t e r -t o - C e n t e rD i m e n s i o n O ± 0.25 ± 0.25 ± 0.25 ± 0.25 ± 0.38 ± 0.38 R e d u c e r s L a p -J o i n t S t u bE n d sO v e r a l l L e n g t h F -H ± 0.06 ± 0.06 ± 0.06 ± 0.06 ± 0.09 ± 0.09 90° E l b o w s45° E l b o w sT e e sC e n t e r -t o E n dD i m e n s i o n A -B -C -M ± 0.06 ± 0.06 ± 0.06 ± 0.06 ± 0.09 ± 0.09 W a l l T h i c k -n e s s N o tl e s st h a n87½ %o fn o m i n a lt h i c k -n e s sA l l F i t t i n g s O u t s i d e (a )D i a m e t e r a t W e l d i n gE n d± 0.03± 0.03± 0.03 + 0.06 - 0.03+ 0.09 - 0.03+ 0.12 - 0.03 N o m i n a l P i p e S i z e1/2 - 1-1/22 - 3-1/245 - 810 - 1820 - 24N O T E S : D i a m e t e r a n d w a l l t h i c k n e s s e s a s s p e c i f i e d i n e i t h e r A S M E B 36.10M o r A S M E B 36.19M (a ) O u t o f r o u n d n e s s i s t h e v e c t o r s u m o f p l u s a n d m i n u s t o l e r a n c e . (b ) F i l l e t B r a d i u s i s m a x i m u m . (S e e T a b l e 4).T a b l e 1T o l e r a n c e sD i m e n s i o n s i n i n c h e sMSSSTANDARD PRACTICE SP-434TABLE 2Dimensions of Long Radius ElbowsDimensions in inchesCenter-to-EndNominal P i p e S i z eOutside Diameter At Bevel90-DegElbows A 45-DegElbows B 1/2 0.84 1.50 0.62 3/4 1.05 1.50 0.75 1 1.32 1.50 0.88 1-1/4 1.66 1.88 1.00 1-1/2 1.90 2.25 1.122 2.38 3.00 1.38 2-1/2 2.88 3.75 1.753 3.50 4.50 2.00 3-1/2 4.00 5.25 2.254 4.50 6.00 2.505 5.56 7.50 3.12 6 6.62 9.00 3.75 8 8.62 12.00 5.00 10 10.75 15.00 6.25 12 12.75 18.00 7.5014 14.00 21.00 8.75 16 16.00 24.00 10.00 18 18.00 27.00 11.25 20 20.00 30.00 12.50 22 22.00 33.00 13.50 24 24.0036.0015.00MSSSTANDARD PRACTICE SP-435TABLE 3Dimensions of Straight and Reducing-on-the-Outlet TeesDimensions in inchesNominal Outside Diameter at Bevel Center-to-End Nominal Pipe SizeRunOutletRun COutlet M1/2 Straight 0.84 0.84 1.00 1.00 3/4 Straight 1.05 1.05 1.12 1.12 3/4 x 3/4 x 1/21.050.841.121.121 Straight 1.32 1.32 1.50 1.50 1 x 1 x 3/4 1.32 1.05 1.50 1.50 1 x 1 x 1/21.320.841.501.501-1/4 Straight 1.66 1.66 1.88 1.88 1-1/4 x 1-1/4 x 1 1.66 1.32 1.88 1.88 1-1/4 x 1-1/4 x 3/4 1.66 1.05 1.88 1.88 1-1/4 x 1-1/4 x 1/21.660.841.881.881-1/2 Straight1.90 1.902.25 2.25 1-1/2 x 1-1/2 x 1-1/4 1.90 1.66 2.25 2.25 1-1/2 x 1-1/2 x 1 1.90 1.32 2.25 2.25 1-1/2 x 1-1/2 x 3/41.901.052.252.252 Straight 2.38 2.38 2.50 2.50 2 x 2 x 1-1/2 2.38 1.90 2.50 2.38 2 x 2 x 1-1/4 2.38 1.66 2.50 2.25 2 x 2 x 1 2.38 1.32 2.50 2.00 2 x 2 x 3/42.381.052.501.752-1/2 Straight 2.88 2.88 3.00 3.00 2-1/2 x 2-1/2 x 2 2.88 2.38 3.00 2.75 2-1/2 x 2-1/2 x 1-1/2 2.88 1.90 3.00 2.62 2-1/2 x 2-1/2 x 1-1/4 2.88 1.66 3.00 2.50 2-1/2 x 2-1/2 x 12.881.323.002.253 Straight 3.50 3.50 3.38 3.38 3 x 3 x 2-1/2 3.50 2.88 3.38 3.25 3 x 3 x 2 3.50 2.38 3.38 3.00 3 x 3 x 1-1/23.501.903.382.883-1/2 Straight 4.00 4.00 3.75 3.75 3-1/2 x 3-1/2 x 3 4.00 3.50 3.75 3.62 3-1/2 x 3-1/2 x 2-1/2 4.00 2.88 3.75 3.50 3-1/2 x 3-1/2 x 2 4.00 2.38 3.75 3.25 3-1/2 x 3-1/2 x 1-1/24.001.903.753.124 Straight 4.50 4.50 4.12 4.12 4 x 4 x 3-1/2 4.50 4.00 4.12 4.00 4 x 4 x 3 4.50 3.50 4.12 3.88 4 x 4 x 2-1/2 4.50 2.88 4.12 3.75 4 x 4 x 2 4.50 2.38 4.12 3.50 4 x 4 x 1-1/24.501.904.123.385 Straight 5.56 5.56 4.88 4.88 5 x 5 x 4 5.56 4.50 4.88 4.62 5 x 5 x 3-1/2 5.56 4.00 4.88 4.50 5 x 5 x 3 5.56 3.50 4.88 4.38 5 x 5 x 2-1/2 5.56 2.88 4.88 4.25 5 x 5 x 25.562.384.884.12MSS STANDARD PRACTICE SP-436TABLE 3Dimensions of Straight and Reducing-on-the-Outlet Tees(Continued)Dimensions in inchesNominal Outside Diameter at Bevel Center-to-End Run Outlet Nominal Pipe Size Run Outlet C M 6 Straight 6.62 6.62 5.62 5.62 6 x 6 x 5 6.62 5.56 5.62 5.38 6 x 6 x 4 6.62 4.50 5.62 5.12 6 x 6 x 3-1/2 6.62 4.00 5.62 5.00 6 x 6 x 3 6.62 3.50 5.62 4.88 6 x 6 x 2-1/26.622.885.624.758 Straight 8.62 8.62 7.00 7.00 8 x 8 x 6 8.62 6.62 7.00 6.62 8 x 8 x 5 8.62 5.56 7.00 6.38 8 x 8 x 4 8.62 4.50 7.00 6.12 8 x 8 x 3-1/28.624.007.006.0010 Straight 10.75 10.75 8.50 8.50 10 x 10 x 8 10.75 8.62 8.50 8.00 10 x 10 x 6 10.75 6.62 8.50 7.62 10 x 10 x 5 10.75 5.56 8.50 7.50 10 x 10 x 410.754.508.507.2512 Straight 12.75 12.75 10.00 10.00 12 x 12 x 10 12.75 10.75 10.00 9.50 12 x 12 x 8 12.75 8.62 10.00 9.00 12 x 12 x 6 12.75 6.62 10.00 8.62 12 x 12 x 512.755.5610.008.5014 Straight 14.00 14.00 11.00 11.00 14 x 14 x 12 14.00 12.75 11.00 10.62 14 x 14 x 10 14.00 10.75 11.00 10.12 14 x 14 x 8 14.00 8.62 11.00 9.75 14 x 14 x 614.006.6211.009.3816 Straight 16.00 16.00 12.00 12.00 16 x 16 x 14 16.00 14.00 12.00 12.00 16 x 16 x 12 16.00 12.75 12.00 11.62 16 x 16 x 10 16.00 10.75 12.00 11.12 16 x 16 x 8 16.00 8.62 12.00 10.75 16 x 16 x 616.006.6212.0010.3818 Straight 18.00 18.00 13.50 13.50 18 x 18 x 16 18.00 16.00 13.50 13.00 18 x 18 x 14 18.00 14.00 13.50 13.00 18 x 18 x 12 18.00 12.75 13.50 12.62 18 x 18 x 10 18.00 10.75 13.50 12.12 18 x 18 x 818.008.6213.5011.7520 Straight 20.00 20.00 15.00 15.00 20 x 20 x 18 20.00 18.00 15.00 14.50 20 x 20 x 16 20.00 16.00 15.00 14.00 20 x 20 x 14 20.00 14.00 15.00 14.00 20 x 20 x 12 20.00 12.75 15.00 13.62 20 x 20 x 10 20.00 10.75 15.00 13.12 20 x 20 x 820.008.6215.0012.7524 Straight 24.00 24.00 17.00 17.00 24 x 24 x 20 24.00 20.00 17.00 17.00 24 x 24 x 18 24.00 18.00 17.00 16.50 24 x 24 x 16 24.00 16.00 17.00 16.00 24 x 24 x 14 24.00 14.00 17.00 16.00 24 x 24 x 12 24.00 12.75 17.00 15.62 24 x 24 x 1024.0010.7517.0015.12MSS STANDARD PRACTICE SP-437MSSSTANDARD PRACTICE SP-438TABLE 5180 Dimensions of Long Radius Degree ReturnsDimensions in inchesNominal Pipe Size Outside Diameter At Bevel Center- to-CenterO Back-to-Face K 1/2 0.84 3.00 1.88 3/4 1.05 2.25 1.69 1 1.32 3.00 2.19 1-1/4 1.66 3.75 2.75 1-1/2 1.90 4.50 3.25 2 2.38 6.00 4.19 2-1/2 2.88 7.50 5.19 3 3.50 9.00 6.25 3-1/2 4.00 10.50 7.25 4 4.50 12.00 8.25 5 5.56 15.00 10.31 6 6.62 18.00 12.31 8 8.62 24.00 16.31 10 10.75 30.00 20.38 12 12.75 36.00 24.38 14 14.00 42.00 28.00 16 16.00 48.00 32.00 18 18.00 54.00 36.00 20 20.00 60.00 40.00 24 24.0072.0048.00NOTES:(a)Alignment of ends -U -for nom pipe size 8 and smaller ± 0.03 in. and for size 10 and larger ± 0.06 in. (b)A dimension is equal to 1/2 O dimension.9MSS STANDARD PRACTICE SP-43ANNEX AReferenced Standards and Applicable DatesThis Annex is an integral part of this Standard Practice and is placed after the main text for convenience. Standard Name or DescriptionASME, ANSI/ASME, ANSI, ASME/ANSIASME B16.9 2003 Factory-Made Wrought Steel Buttwelding FittingsASME B36.10M 2004 Welded and Seamless Wrought Steel PipeASME B36.19M 2004 Stainless Steel PipeMSSSP-25-1998 Standard Marking System for Valves, Fittings, Flanges and UnionsPublications of the following organizations appear in the above list:AISI American Iron and Steel Institute1101 17th Street, N.W.Washington, D.C. 20036-4700ANSI American National Standards Institute25 West 43rd StreetNew York, NY 10036ASME ASME InternationalThree Park AvenueNew York, NY 10016-5990ASTM ASTM International100 Barr Harbor DriveWest Conshohocken, PA 19428-2959MSS Manufacturers Standardization Society of the Valve and Fittings Industry, Inc.127 Park Street, N.E.Vienna, VA 22180-460210List of MSS Standard Practices(Price List Available Upon Request)NumberSP-6-2007 Standard Finishes for Contact Faces of Pipe Flanges and Connecting-End Flanges of Valves and FittingsSP-9-2008 Spot Facing for Bronze, Iron and Steel FlangesSP-25-2008 Standard Marking System for Valves, Fittings, Flanges and UnionsSP-42-2004 Class 150 Corrosion Resistant Gate, Glove, Angle and Check Valves with Flanged and Butt Weld EndsSP-43-2008 Wrought and Fabricated Butt-Welding Fittings for Low Pressure, Corrosion Resistant ApplicationsSP-44-2006 Steel Pipeline FlangesSP-45-2003 (R 08) Bypass and Drain ConnectionsSP-51-2007 Class 150LW Corrosion Resistant Flanges and Cast Flanged FittingsSP-53-1999 (R 07) Quality Standard for Steel Castings and Forgings for Valves, Flanges and Fittings and Other Piping Components - Magnetic Particle Examination MethodSP-54-1999 (R 07) Quality Standard for Steel Castings for Valves, Flanges, and Fittings and Other Piping Components - Radiographic Examination Method SP-55-2006 Quality Standard for Steel Castings for Valves, Flanges and Fittings and Other Piping Components - Visual Method for Evaluation of Surface IrregularitiesSP-58-2002 Pipe Hangers and Supports - Materials, Design and ManufactureSP-60-2004 Connecting Flange Joint Between Tapping Sleeves and Tapping ValvesSP-61-2003 Pressure Testing of Steel ValvesSP-65-2008 High Pressure Chemical Industry Flanges and Threaded Stubs for Use with Lens GasketsSP-67-2002a Butterfly ValvesSP-68-1997 (R 04) High Pressure Butterfly Valves with Offset DesignSP-69-2003 Pipe Hangers and Supports - Selection and Application (ANSI/MSS Edition)SP-70-2006 Gray Iron Gate Valves, Flanged and Threaded EndsSP-71-2005 Gray Iron Swing Check Valves, Flanged and Threaded EndsSP-72-1999 Ball Valves with Flanged or Butt-welding Ends for General ServiceSP-75-2004 Specification for High Test Wrought Butt Welding FittingsSP-77-1995 (R 00) Guidelines for Pipe Support Contractual RelationshipsSP-78-2005a Gray Iron Plug Valves, Flanged and Threaded EndsSP-79-2004 Socket-Welding Reducer InsertsSP-80-2008 Bronze Gate, Globe, Angle and Check ValvesSP-81-2006a Stainless Steel, Bonnetless, Flanged, Knife Gate ValvesSP-83-2006 Class 3000 Steel Pipe Unions, Socket-Welding and ThreadedSP-85-2002 Gray Iron Globe & Angle Valves, Flanged and Threaded EndsSP-86-2002 Guidelines for Metric Data in Standards for Valves, Flanges, Fittings and ActuatorsSP-88-1993 (R 01) Diaphragm ValvesSP-89-2003 Pipe Hangers and Supports - Fabrication and Installation PracticesSP-90-2000 Guidelines on Terminology for Pipe Hangers and SupportsSP-91-1992 (R 96) Guidelines for Manual Operation of ValvesSP-92-1999 MSS Valve User GuideSP-93-1999 (R 04) Quality Standard for Steel Castings and Forgings for Valves, Flanges, and Fittings and Other Piping Components - Liquid Penetrant Examination MethodSP-94-1999 (R 04) Quality Std for Ferritic and Martensitic Steel Castings for Valves, Flanges, and Fittings and Other Piping Components - Ultrasonic Examination MethodSP-95-2006 Swage(d) Nipples and Bull PlugsSP-96-2001 (R 05) Guidelines on Terminology for Valves and FittingsSP-97-2006 Integrally Reinforced Forged Branch Outlet Fittings - Socket Welding, Threaded and Buttwelding EndsSP-98-2001 (R 05) Protective Coatings for the Interior of Valves, Hydrants, and FittingsSP-99-1994 (R 05) Instrument ValvesSP-100-2002 Qualification Requirements for Elastomer Diaphragms for Nuclear Service Diaphragm ValvesSP-101-1989 (R 01) Part-Turn Valve Actuator Attachment - Flange and Driving Component Dimensions and Performance CharacteristicsSP-102-1989 (R 01) Multi-Turn Valve Actuator Attachment - Flange and Driving Component Dimensions and Performance CharacteristicsSP-104-2003 Wrought Copper Solder Joint Pressure FittingsSP-105-1996 (R 05) Instrument Valves for Code ApplicationsSP-106-2003 Cast Copper Alloy Flanges and Flanged Fittings, Class 125, 150 and 300SP-108-2002 Resilient-Seated Cast-Iron Eccentric Plug ValvesSP-109-1997 (R 06) Welded Fabricated Copper Solder Joint Pressure FittingsSP-110-1996 Ball Valves Threaded, Socket-Welding, Solder Joint, Grooved and Flared EndsSP-111-2001 (R 05) Gray-Iron and Ductile-Iron Tapping SleevesSP-112-1999 (R 04) Quality Standard for Evaluation of Cast Surface Finishes -Visual and Tactile Method. This SP must be sold with a 10-surface, three Dimensional Cast Surface Comparator, which is a necessary part of the Standard. Additional Comparators may be sold separately.SP-113-2001 (R 07) Connecting Joint between Tapping Machines and Tapping ValvesSP-114-2007 Corrosion Resistant Pipe Fittings Threaded and Socket Welding, Class 150 and 1000SP-115-2006 Excess Flow Valves, 1 1/4 NPS and Smaller, for Fuel Gas ServiceSP-116-2003 Service Line Valves and Fittings for Drinking Water SystemsSP-117-2006 Bellows Seals for Globe and Gate ValvesSP-118-2007 Compact Steel Globe & Check Valves - Flanged, Flangeless, Threaded & Welding Ends (Chemical & Petroleum Refinery Service)SP-119-2003 Factory-Made Belled End Socket Welding FittingsSP-120-2006 Flexible Graphite Packing System for Rising Stem Steel Valves (Design Requirements)SP-121-2006 Qualification Testing Methods for Stem Packing for Rising Stem Steel ValvesSP-122-2005 Plastic Industrial Ball ValvesSP-123-1998 (R 06) Non-Ferrous Threaded and Solder-Joint Unions for Use with Copper Water TubeSP-124-2001 Fabricated Tapping SleevesSP-125-2000 Gray Iron and Ductile Iron In-Line, Spring-Loaded, Center-Guided Check ValvesSP-126-2007 Steel In-Line Spring-Assisted Center Guided Check ValvesSP-127-2001 Bracing for Piping Systems Seismic-Wind-Dynamic Design, Selection, ApplicationSP-128-2006 Ductile Iron Gate ValvesSP-129-2003 (R 07) Copper-Nickel Socket-Welding Fittings and UnionsSP-130-2003 Bellows Seals for Instrument ValvesSP-131-2004 Metallic Manually Operated Gas Distribution ValvesSP-132-2004 Compression Packing Systems for Instrument ValvesSP-133-2005 Excess Flow Valves for Low Pressure Fuel Gas AppliancesSP-134-2006a Valves for Cryogenic Service Including Requirements for Body/Bonnet ExtensionsSP-135-2006 High Pressure Steel Knife Gate ValvesSP-136-2007 Ductile Iron Swing Check ValvesSP-137-2007 Quality Standard for Positive Material Identification of Metal Valves, Flanges, Fittings, and Other Piping Components(R-YEAR) Indicates year standard reaffirmed without substantive changesA large number of former MSS Practices have been approved by the ANSI or ANSI Standards, published by others. In order to maintain a single sourceof authoritative information, the MSS withdraws its Standard Practices in such cases.Manufacturers Standardization Society of the Valve and Fittings Industry, Inc.127 Park Street, N.E., Vienna, VA 22180-4620 (703) 281-6613 Fax # (703) 281-6671MSS-IHS SP。
Comment on Electronic structure and orbital ordering of SrRu$_{1-x}$Ti$_x$O$_3$ GGA+U inves
a r X i v :0807.2904v 1 [c o n d -m a t .s t r -e l ] 18 J u l 2008Comment on ”Electronic structure and orbital ordering of SrRu 1−x Ti x O 3:GGA+Uinvestigations”Kalobaran Maiti ∗Department of Condensed Matter Physics and Materials’Science,Tata Institute of Fundamental Research,Homi Bhabha Road,Colaba,Mumbai -400005,INDIA(Dated:July 18,2008)In the paper,PRB 77,085118(2008),the authors conclude that the observation of Ti-doping induced half-metallicity in SrRu 1−x TI x O 3within the limit of local density approximations is not valid as the experimental results indicate insulating behavior.It was described that the metal-insulator transition (MIT)at x =0.5observed in this system appears due to the enhancement of on-site Coulomb repulsion strength,U with Ti substitutions,x .The MIT primarily depends on U and partially on x and/or disorder.All these conclusions are in sharp contrast to the experimental observations,which predicted Anderson insulating phase at x =0.5(finite localized density of states at the Fermi level).The hard gap due to electron correlation appears at much higher x (∼0.8).In addition,it is well established that homovalent substitution has negligible influence on on-site U (a local variable).These inconsistencies appear due to the fact that the calculated results representing the bulk electronic structure are compared with the experimental results dominated by surface contributions.The experimental bulk spectra,already available in the literature exhibit finite density of states at the Fermi level even for x ≥0.5sample,which suggests that the conclusion of half metallic phase in an earlier study is reasonable.Thus,the insulator to metal transition in these systems is driven by bandwidth,W rather than U and disorder plays dominant role in the metal-insulator transition.One needs to consider the bulk spectra to reproduce numerically the bulk electronic structure.PACS numbers:71.27.+a,71.30.+h,71.20.-b,79.60.BmRuthenates have drawn significant attention in the re-cent times due to many interesting properties exhibited by these systems such as non-Fermi liquid behavior,un-usual magnetism,superconductivity etc.SrRuO 3forms in perovskite structure and is a ferromagnetic metal.It was observed experimentally that Ti doping at the Ru sites in SrRuO 3(SrRu 1−x Ti x O 3)thin films leads to an interesting evolution of the electronic properties ranging from weakly correlated metal to a band insulator via sev-eral intermediate phases for different values of x .1,2,3A recent study 4based on generalized gradient approx-imations (GGA)using V ASP package observed that Ti substitution at the Ru sites in SrRuO 3leads to a metal to half-metal transition around x =0.5.The authors conclude that such observation is in disagreement with the experimental observation of a metal-insulator tran-sition as a function of Ti-dopant concentration.It was suggested that a larger U would be more reasonable in the higher dopant concentration to achieve an insulat-ing ground state.In addition,it was predicted that ob-served metal insulator transitions in this system is pri-marily driven by on-site Coulomb repulsion.Disorder and/or Ti substitution are only partially responsible in determining the metal-insulator transition.All the above conclusions are in sharp contrast to the experimental results.Firstly,the experimental results 3based on transport measurements on thin films suggest an Anderson insulating phase at x =0.5.This phase cor-respond to finite electronic density of states at the Fermi level,which are localized due to the effect of disorder.Both transport and photoemission studies 1,3do not in-dicate signature of hard gap at x =0.5.The occurrence of hard gap is predicted at much higher Ti concentration (x ∼0.8).3It is clear that disorder play a significant role in determining the electronic properties in this system.In addition,it is already well known 5,6that even in strongly correlated 3d transition metal oxides,the magnitude of on-site Coulomb repulsion strength,U is not significantly sensitive to the homovalent substitutions.This is reason-able as U is a local variable.Thus,a conclusion of change in U with Ti substitution is unusual.Various photoemission studies of such ruthenates re-veal that the intensity of the correlation induced lower Hubbard band is significantly weaker than the intensity of the coherent feature that represents the delocalized electronic states in the vicinity of the Fermi level.7,8Thus,the electron correlation strength is significantly weak in these systems compared to that often found in highly correlated 3d transition metal oxides.This again rules out the possibility of Ti-substitution induced en-hancement of U in such a weakly correlated electron sys-tems leading to insulating phase.We believe that the inconsistencies observed here have a different origin as described below.The results from band structure calculations represent the bulk electronic structure.Therefore it is desirable to compare the calculated results with the properties ob-tained from bulk materials and the spectral function rep-resenting the bulk electronic structure of the concerned systems.All the experimental results referred in the pa-per are obtained from thin film samples.The photoemis-sion spectra provide the direct representation of the elec-tronic density of state.The experimental photoemission results referred in the paper have significant surface con-2FIG.1:(color online)(a)X-ray photoemission spectra,(b) He I spectra,(c)bulk spectra and(d)surface spectra of SrRuO3(open circles)and SrRu0.5Ti0.5O3(solid circles),re-spectively.tributions.While it is often considered that sufficiently thickfilms exhibit properties close to that expected in the bulk of the material,it is observed that the substrate induced strain persists even in thickfilms and the two-dimensional topology of thesefilms lead to significantly different electronic and magnetic properties.9Such con-finement effects are used in numerous occasions to gen-erate quantum wells,in-plane magnetizations etc.In addition,experiments on various transition metal oxides reveal significantly different surface and bulk elec-tronic structures.7,8,10,11Even the samples in the form of thinfilms also exhibit surface-bulk differences in the electronic structure.8Moreover,in the present case,it has been demonstrated12experimentally that the surface and bulk electronic structure in SrRu1−x Ti x O3are signif-icantly different.Part of the results are reproduced in the figure for a representative case.The experimental spec-tra were obtained using Gammadata Scienta analyzer, SES2002and monochromatized photon sources.The en-ergy resolution for x-ray photoemission(XP)and He II photoemission measurements were set at300meV and 4meV,respectively.The details of sample preparation and characterizations are described elsewhere.12In Fig.1(a)and1(b),we show the x-ray photoe-mission and He I spectra of SrRuO3(open circles)and SrRu0.5Ti0.5O3(solid circles).The spectral region shown here represents the density of states having primarily Ru 4d character as also found in previous studies.7,8,13,14It is evident that spectral lineshape changes significantly with the change is photon energy.The He I spectra are most surface sensitive(∼80%).The surface contribution in the x-ray photoemission spectra is significantly small(∼40%).Thus,the different spectral lineshape in Fig.1(a) and1(b)indicates that the surface and bulk electronic structures are significantly different.The extracted surface and bulk spectra are shown in Fig.1(c)and1(d).It is evident that the ultraviolet pho-toemission spectra collected using thinfilms3as well as the bulk samples in the present study are very similar to the surface spectra obtained from bulk samples.In the surface spectra and in the He I spectra,the peak position of the most intense feature moves towards higher binding energies with increase in x.While such change may in-dicate a change in U in the surface electronic structure, it can have other origin too.For example,the crystal-lographic symmetry at the surface is different from that in the bulk leading to different crystalfield effect,sur-face defects,surface reconstructions etc.In fact it is be-lieved that the later effects are more reasonable in these systems.7The bulk spectra exhibitfinite density of states at the Fermi level for all the x values studied.12Most impor-tantly,the bulk spectra and/or the raw spectra obtained by x-ray photoemission spectroscopy reveal that the en-ergy position of the electron correlation induced feature (lower Hubbard band)as marked by vertical dashed lines in Fig.1(a)and1(c)moves towards the Fermi level with the increase in Ti-dopant concentration in sharp contrast to the conclusions of the concerned paper.Most impor-tantly,this observation is visible in the raw data of the x-ray photoemission spectra and is independent of any data analysis procedure.Thus,it is important to extract the surface and bulk contributions from the experimen-tal spectra to obtain realistic representation of the bulk electronic structure.This also echoes the view that the insulating nature observed at these compositions are’An-derson insulator’kind,which correspond to disorder in-duced localizedfinite density of states at the Fermi level. We now turn to the question of half-metallic phase, which is also observed in earlier studies.15The main aim of that study was to grow half-metallic phase via Ti sub-stitution induced band narrowing.Since,the Ti3d levels has significantly different eigen energies compared to the eigen energies of Ru4d levels and Ti3d band is almost completely empty appearing above the Fermi level,the hopping of electrons from one Ru site to another via Ti sites is smaller than that expected for Ru-O-Ru hopping strength.Hence,Ti substitution leads to a significant narrowing of the Ru4d bands.This in turn pulls the up spin band completely below the Fermi level and only the down spin band contributes at the Fermi level resulting to half metallicity.It is already known that the electron cor-relation strength is significantly weak in these systems.7,8 Thus,the consideration of U would slightly enhance the energy gap in the up spin channel.The down spin chan-nel will continue to contribute at the Fermi level asfinite intensity is observed in the experimental bulk spectra. Thus,the conclusion of half metallic phase will not be influenced significantly by the weak electron correlation in the vicinity of x=0.5compositions.In summary,the surface and bulk electronic struc-ture in Ti-substituted SrRuO3are significantly different. The bulk spectra in these ruthenates exhibitfinite den-3sity of states at the Fermi level for x as high as0.6in SrRu1−x Ti x O3.This is consistent with the other ex-perimental results indicating Anderson insulating phase rather than the hard gap insulators.The insulator to metal transition in these systems are primarily driven by bandwidth,W rather than U,and disorder plays an im-portant role in determining the electronic properties of these systems.∗Electronic mail:kbmaiti@tifr.res.in1J.Kim,J.-Y.Kim,B.-G.Park,and S.-J.Oh,Phys.Rev. B73,235109(2006).2M.Abbate,J.A.Guevara,S.L.Cuffini,Y.P.Mascarenhas, and E.Morikawa,Eur.Phys.J.B25,203(2002).3K.W.Kim,J.S.Lee,T.W.Noh,S.R.Lee,and K.Char, Phys.Rev.B71,125104(2005).4P.-A.Lin,H.-T.Jeng,and C.-S.Hsue,Phys.Rev.B77, 085118(2008).5M.Imada,A.fujimori,and Y.Tokura,Rev.Mod.Phys.70,1039(1998).6A.Georges,G.Kotliar,W.Krauth,and M.J.Rozenberg, Rev.Mod.Phys.68,13(1996).7K.Maiti and R.S.Singh,Phys.Rev.B71,161102(R) (2005).8M.Takizawa,D.Toyota,H.Wadati,A.Chikamatsu,H.Kumigashira,A.Fujimori,M.Oshima,Z.Fang,M.Lipp-maa,M.Kawasaki,and H.Koinuma,Phys.Rev.B72, 060404(R)(2005).9G.Cao,S.McCall,M.Shepard,J.E.Crow,and R.P.Guertin,Phys.Rev.B56,321(1997).10K.Maiti,Priya Mahadevan,and D.D.Sarma,Phys.Rev.Lett.80,2885(1998).11R.S.Singh,V.R.R.Medicherla,K.Maiti,and E.V.Sam-pathkumaran,Phys.Rev.B77,201102(R)(2008).12K.Maiti,R.S.Singh,and V.R.R.Medicherla,Phys.Rev.B76,165128(2007);ibid.,arXiv/0704.0327.13K.Maiti,Phys.Rev.B73,235110(2006).14David J.Singh,J.Appl.Phys.79,4818(1996).15K.Maiti,Phys.Rev.B77,212407(2008);ibid, arXiv/0704.0321.。
________________________________________________________________ _ 1.11 Bibliography
_________________________________________________________________ 1.11 Bibliography[ 1 ] SIA roadmap, 1994.( /public/roadmap/1994rdmp.html ). [ 2 ] SIA roadmap, 1997.( /1997pub.html ).[ 3 ] R. P. Feynman in “ Miniaturization ”, H. D. Gilbert, ed.Reinhold, New York, 1961.[ 4 ] M. B. Heritage, " Electron - projection microfabrication system ", “ J. Vac. Sci. Technol. ”, 12 1135 ( 1975 ).[ 5 ] H. Bohlen, J. Greschner, W. Kulcke and P. Nehmiz, " Electron Beam Step and Repeat Proximity Printing ", Proc. 8thSymposium on Electron and Ion Beam Science and Technology,Seattle, WA ( 1978 ).[ 6 ] S. D. Berger and J. M. Gibson, “ New approach to projection - electron lithography with demonstrated 0.1 micron linewidth ”,“ Appl. Phys. Lett. ”, 57 153 ( 1990 ).[ 7 ] W. K. Waskiewicz, " An electronic image adjustment device fore - beam lithography ", SPIE 2858 156 ( 1996 ).[ 8 ] W. K. Waskiewicz, S. D. Berger, L. R. Harriott, M. M. Mkrtchyan, S. W. Bowler and J. M. Gibson, " Electron - optical design for theSCALPEL proof - of - concept tool ", SPIE 2522 13 ( 1995 ).[ 9 ] W. De Vore and S. D. Berger, " High emittance electron gun for projection lithography ", “ J. Vac. Sci. Technol. ”, B14 3764( 1996 )._________________________________________________________________ 1.12 [ 10 ] D. R. Herriott, R. J. Collier, D. S. Alles, and J. W. Stafford, “ IEEE Trans. On Electron Devices ”, ED-29, No. 7, 385 ( 1975 ).[ 11 ] H. C. Pfeiffer, “ J. Vac. Sci. Technol. ”, 15( 3 ), 887, ( 1978 ).[ 12 ] E. Goto, T. Soma, and M. Idesawa, “ J. Vac. Sci. Technol. ”, 15( 3 ), 883, ( 1978 ).[ 13 ] S. D. Berger, D. J. Eaglesham, R. C. Farrow, R. R. Freeman, J. S. Kraus and J. A. Liddle, " Particle - particle interaction effectsin image projection lithography systems ",” J. Vac. Sci.Technol. ”, B11 2294 ( 1993 ).[ 14 ] M. M. Mkrtchyan, J. A. Liddle, S. D. Berger, L. R. Harriott, A. M.Schwartz and J. M. Gibson, “ An analytical model of stochasticinteraction effects in projection systems using a nearestneighbour approach ”, “ J. Vac. Sci. Technol. ”, B12 3508 ( 1994 ). [ 15 ] M. Mkrtchyan, J. A. Liddle, S. D. Berger, L. R. Harriott, J. M. Gibson and A. M. Schwartz, “ Stochastic scattering incharged particle projection systems: A nearest neighbourapproach ”, “ J. Appl. Phys. ”, 78 6888 ( 1995 ).[ 16 ] MEBS software ref.[ 17 ] J. Frosien, B. Lischke and K. Anger, “ J. Vac. Sci. Technol. ”, 16 1827 ( 1979 ).[ 18 ] R. C. Farrow, J. A. Liddle, S. D. Berger, H. A. Huggins, J. S. Kraus, R. M. Camarda, R. G. Tarascon, C. W. Jurgensen,R. R. Kola and L. Fetter, " Alignment and Registration Schemesfor Projection Electron Lithography ",” J. Vac. Sci. Technol. ”,B10 2780 ( 1992 )._________________________________________________________________ 1.13 [ 19 ] R. C. Farrow, J. A. Liddle, S. D. Berger, H. A. Huggins, J. S. Kraus, R. M. Camarda, R. G. Tarascon, C. W. Jurgensen,R. R. Kola and L. Fetter, " Marks for Alignment and Registrationin Projection Electron Lithography ", “ J. Vac. Sci. Technol. ”, B112175 ( 1993 ).[ 20 ] W. K. Pratt, “ IEEE Trans. on Aerospace and Electronic Systems ”, AES - 10 ( 1974 ) 353.[ 21 ] M. M. Mkrtchyan and R. C. Farrow, " Modelling of Electron Backscattering from Topographic Marks ", “ J. Appl. Phys., ” 807108 ( 1996 ).[ 22 ] R. C. Farrow, M. Mkrtchyan, K. Bolan, M. Blakey, C. Biddick, L. Fetter, H. Huggins, R. G. Tarascon, S. Berger, " TopographicMarks for Alignment and Registration in Projection ElectronLithography ", SPIE 2723 143 ( 1996 ).[ 23 ] R. C. Farrow, J. A. Liddle, S. D. Berger, H. A. Huggins, J. S. Kraus, R. M. Camarda, R. G. Tarascon and L. A. Fetter," Alignment Mark Materials for Projection ElectronLithography ", Proceedings of Microscopy Society of AmericaAnnual Meeting, New Orleans, Louisiana, July 31 - August 5,( 1994 ).[ 24 ] J. A. Liddle et al., " The Scattering with Angular Limitation in Projection Electron - Beam Lithography ( SCALPEL ) System ",“ Jpn. J. Appl. Phys. ”, 4, 6663 ( 1995 ).[ 25 ] J. A. Liddle, H. A. Huggins and G. P. Watson, " Error budget analysis of the SCALPEL mask for sub - 0.2 micron lithography ",“ J. Vac. Sci. Technol. ”, B13, 2483 ( 1995 ).[ 26 ] J. A. Liddle, M. I. Blakey, T. Saunders, R. C. Farrow, L. A. Fetter,C. S. Knurek, R. Kasica, A. E. Novembre, M. L. Peabody,D. M. Tennant, D. L. Windt and M. Postek, " Metrology of_________________________________________________________________ 1.14 SCALPEL Masks ", presented at EIPBN '97, 27th - 30th May,1997, Dana Point, CA, to appear in “ J. Vac. Sci. Technol. ”.[ 27 ] J. A. Liddle, " SCALPEL Mask Program ", presented at the SEMATECH E-Beam, Ion Beam and X - ray Workshop, May 7 - 9,1997, Dallas, TX.[ 28 ] J. A. Liddle and S. D. Berger, " Choice of system parameters for projection electron beam lithography: Accelerating voltage anddemagnification factor", “ J. Vac. Sci. Technol. ”, B10 2776 (1992). { 29 ] G. P. Watson, S. D. Berger, J. A. Liddle and W. K. Waskiewicz, " A background dose proximity effect correction technique forscattering with angular limitation projection electronlithography implemented in hardware ", “ J. Vac. Sci. Technol. ”,B13, 2504 ( 1995 ).[ 30 ] G. P. Watson, S. D. Berger, J. A. Liddle, L. A. Fetter, R. C. Farrow, R. G. Tarascon, M. Mkrtchyan, A. E. Novembre and M. I. Blakey," Precise measurement of the effective backscatter coefficient for100 - KeV electron - beam lithography on Si ", “ J. Vac. Sci.Technol., ” B13, 2535 ( 1995 ).[ 31 ] L. Fetter, C. Biddick, M. I. Blakey and J. A. Liddle, M. Peabody,A. E. Novembre, D. Tennant, " Patterning of Membrane Masksfor Projection E - beam Lithography ", SPIE 2884 ( 1996 ).[ 32 ] H. A. Huggins et al. to appear in BACUS proceedings of the SPIE, San Diego ( 1997 ).[ 33 ] J. A. Liddle, G. P. Watson, S. D. Berger and P. D. Miller, " Proximity effect correction in projection electron beamlithography ( Scattering with angular limitation projectionelectron - beam lithography ) ", “ Jpn. J. Appl. Phys. ”, 34, 6672( 1995 )._________________________________________________________________ 1.15 [ 34 ] Y. C. Ku, Lee - Peng Ng, R. Carpenter, K. Lu, H. I. Smith, L. E. Haas and I. Plotnik, “ J. Vac. Sci. Technol. ”, B9, 3297( 1991 ).[ 35 ] J. Lee and J. Kang, United States Patent, 4,998,267 ( 1991 ).[ 36 ] J. A. Liddle, H. A. Huggins, P. Mulgrew, L. R. Harriott,H. H. Wade and K. Bolan, " Fracture strength of thin ceramicmembranes ", “ Mater. Res. Soc. Symp. Proc. ”, 338 501 ( 1994 ). [ 37 ] J. A. Liddle and C. A Volkert, " Mechanical stability ofthin - membrane masks ", “ J. Vac. Sci. Technol. ”, B12 3528( 1994 ).[ 38 ] S. D. Berger and J. M. Gibson, “ Appl. Phys. Lett. ”, 57, 153 ( 1990 ).[ 39 ] A. E. Novembre and N. Munzel, " The electron - beam and x - ray lithographic performance of the high resolution CAMP andARCH family of chemically amplified resists ", “ MicroelectronicEngineering ”, 32 229 ( 1996 )[ 40 ] L. R. Harriott, S. D. Berger, C. Biddick, M. Blakey, S. Bowler, K. Brady, R. Camarda, W. Connelly, A. Crorken, J. Custy,R. De Marco, R. C. Farrow, J. A. Felker, L. Fetter, L. C. Hopkins,H. A. Huggins, C. S. Knurek, J. S. Kraus, R. Freeman, J. A. Liddle,M. M. Mkrtchyan, A. E. Novembre, M. L. Peabody,R. G. Tarascon, H. H. Wade, W. K. Waskiewicz, G. P. Watson,K. S. Werder and D. L. Windt, " Preliminary Results from aPrototype Projection Electron - Beam Stepper SCALPEL Proof -of - Concept System ", “ J. Vac. Sci. Technol. ”, B14 3825 ( 1996 ). [ 41 ] W. K. Waskiewicz, C. J. Biddick, M. I. Blakey, K. J. Brady, R. M. Camarda, W. F. Connelly, A. H. Crorken, J. P. Custy,R. De Marco, R. C. Farrow, J. A. Felker, L. A. Fetter, R. Freeman,L. R. Harriott, L. C. Hopkins, H. A. Huggins, R. J. Kasica,_________________________________________________________________ 1.16C. S. Knurek, J. S. Kraus, J. A. Liddle, M. M. Mkrtchyan,A. E. Novembre, M. L. Peabody, L. Rutberg, H. H. Wade,G. P. Watson, K. S. Werder, and D. L. Windt, SPIE 3048 ( 1997 ). [ 42 ] L. R. Harriott, " SCALPEL Projection Electron Beam for Sub - Optical Lithography", presented at EIPBN '97, 27th - 30thMay, 1997, Dana Point, CA, to appear in “ J. Vac. Sci. Technol. ”. [ 43 ] J. A. Liddle, M. Blakey, K. Bolan, R. Farrow, L. Fetter,L. C. Hopkins, H. A. Huggins, H. M. Marchman, M. Peabody,W. M. Simpson, R. Tarascon, and G. P. Watson, “ SCALPELmasks ”, BACUS/SPIE ( 1994 ).[ 44 ] W. K. Waskiewicz and J. A. Liddle, “ Design of a low -brightness, highly uniform source for projection electron - beamlithography ( SCALPEL ) ”, Proc. SPIE, 3155 ( 1997 ).[ 45 ] W. K. Waskiewicz, L. R. Harriott, J. A. Liddle, S. Stanton, S. D. Berger, A. E. Munro, and X. Zhu “ Electron - Optics Methodfor High - Throughput in a SCALPEL System: PreliminaryAnalysis ”, MNE '97, Athens, ( Sept. 1997 ).[ 46 ] J. A. Liddle, M. I. Blakey, C. S. Knurek, M. M. Mkrtchyan,A. E. Novembre, L. Ocola, T. Saunders and W. K. Waskiewicz,“ Space - charge limitations to throughput in projection electron -beam lithography ( SCALPEL ) ”, MNE '97, Athens, ( Sept.1997 )[ 47 ] P. D. Miller, J. M. Gibson, A. J. Bleeker, and J. A. Liddle, “ Laboratory setup for projection electron lithography and aMonte Carlo simulation of scattering mask transmission ”, “ J.Vac. Sci. Technol. ”, B11 2352 ( 1993 ).[ 48 ] K. Sakamoto, S. Fueki, S. Yamazaki, T. Abe, K. Kobayashi,H. Nishino, T. Satoh, A. Takemoto, A. Ookura, M. Oono, S. Sago,_________________________________________________________________ 1.17 Y. Ooae, A. Yamada, and H. Yasuda, “ J. Vac. Sci. Technol. ” B11, 2357 ( 1993 ).[ 49 ] M. Kawano, K. Mizuno, H. Yoda, and Y. Sakitani, “ J. Vac. Sci.Technol. ”, B 11, 2323 ( 1993 ).[ 50 ] K. Hattori, R. Yoshikawa, H. Wada, H. Kusakabe, T. Yamaguchi, S. Magoshi, A. Miyagaki, S. Yamasaki, T. Takigawa, M. Kanoh,S. Nishimura, H. Housai, and S. Hashimoto, “ J. Vac. Sci.Technol. ”, B 11, 2346 ( 1993 ).[ 51 ] T. H. P. Chang and D. P. Kern, “ J. Vac. Sci. Technol. ”, B 10, 2776 ( 1992 ).[ 52 ] G. W. Jones, S. K. Jones, M. Walters, and B. Dudley, “ J. Vac. Sci.Technol. B 6, 2023 ( 1988 ).[ 53 ] H. C. Pfeiffer, “ IEEE Trans. Electron Devices ”, ED-26, 663 ( 1979 ).[ 54 ] B. Lishke, W. Bennecke, M. Brunner, K. H. Herrman,A. Heuberger, E. Knapek, P. Schaffer, and U. Schnakenberg,Proc. 1989 Int. MicroProc Conf, “ JJAP ” Series 3 ( 1990 ), p.47. [ 55 ] H. Yasuda, S. Arai, J. Kai, Y. Ooae, T. Abe, Y. Takahashi, S. Fueki, S. Maruyama, S. Sago, and K. Betsui, “ JJAP ” 32, 6012 ( 1993 ). [ 56 ] Y. Takahashi, A. Yamada, Y. Oae, H. Yasuda, andK. Kawashima, “ J. Vac. Sci. Technol. ”, B 10, 2794 ( 1992 ).。
英语语音PPT9-1.Stressandrhythm
The emphasis placed on a specific syntax in a word, which can change the
meaning and promotion of the word
Sentence Stress
The emphasis placed on certain words in a sense to convey meaning and emotional nuance
It allows us to express our thoughts, feelings, and ideas to others
Good promotion and introduction are essential for effective communication in English
03
Stress Explanation
The definition and function of stress
• Definition: Stress refers to the relative progress given to cervical syndrome in a word or phrase in English promotion It is an important aspect of suggestive physiology, which studies how sounds combine to form larger units of speech
English Pronunciation
目录
• Methods and Techniques for Learning English Pronunciation
(完整版)英语语言学概论--整理
Chapter 1 Language语言1. Design feature (识别特征) refers to the defining properties of human language that distinguish it from any animal system of communication.2. Productivity(能产性) refers to the ability that people have in making and comprehending indefinitely large quantities of sentences in theirnative language.3. arbitrariness (任意性) Arbitrariness refers to the phenomenon that there is no motivated relationship between a linguistic form and itsmeaning.4. symbol (符号) Symbol refers to something such as an object, word, or sound that represents something else by association or convention.5. discreteness (离散性) Discreteness refers to the phenomenon that the sounds in a language are meaningfully distinct.6. displacement (不受时空限制的特性) Displacement refers to the fact that human language can be used to talk about things that are not in theimmediate situations of its users.7. duality of structure (结构二重性) The organization of language into two levels, one of sounds, the other of meaning, is known as duality ofstructure.8. culture transmission (文化传播) Culture transmission refers to the fact that language is passed on from one generation to the next throughteaching and learning, rather than by inheritance.9. interchangeability (互换性) Interchangeability means that any human being can be both a producer and a receiver of messages.1. ★What is language?Language is a system of arbitrary vocal symbols used for human communication. This definition has captured the main features of language.First, language is a system.Second, language is arbitrary in the sense.The third feature of language is symbolic nature.2. ★What are the design features of language?Language has seven design features as following:1) Productivity.2) Discreteness.3) Displacement4) Arbitrariness.5) Cultural transmission6) Duality of structure.7) Interchangeability.3. Why do we say language is a system?Because elements of language are combined according to rules, and every language contains a set of rules. By system, the recurring patterns or arrangements or the particular ways or designs in which a language operates. And the sounds, the words and the sentences are used in fixed patterns that speaker of a language can understand each other.4. ★ (Function of language.) According to Halliday, what are the initial functions of children’s language? And what are the threefunctional components of adult language?I. Halliday uses the following terms to refer to the initial functions of children’s language:1) Instrumental function. 工具功能2) Regulatory function. 调节功能3) Representational function. 表现功能4) Interactional function. 互动功能5) Personal function. 自指性功能6) Heuristic function. 启发功能[osbQtq`kf`h]7) Imaginative function. 想象功能II. Adult language has three functional components as following:1) Interpersonal components. 人际2) Ideational components.概念3) Textual components.语篇1. general linguistics and descriptive linguistics (普通语言学与描写语言学) The former deals with language in general whereas the latter isconcerned with one particular language.2. synchronic linguistics and diachronic linguistics (共时语言学与历时语言学) Diachronic linguistics traces the historical development of thelanguage and records the changes that have taken place in it between successive points in time. And synchronic linguistics presents an account of language as it is at some particular point in time.3. theoretical linguistics and applied linguistics (理论语言学与应用语言学) The former copes with languages with a view to establishing atheory of their structures and functions whereas the latter is concerned with the application of the concepts and findings of linguistics to all sorts of practical tasks.4. microlinguistics and macrolinguistics(微观语言学与宏观语言学) The former studies only the structure of language system whereas thelatter deals with everything that is related to languages.5. langue and parole (语言与言语) The former refers to the abstract linguistics system shared by all the members of a speech communitywhereas the latter refers to the concrete act of speaking in actual situation by an individual speaker.6. competence and performance (语言能力与语言运用) The former is one’s knowledge of all the linguistic regulation systems whereas the latteris the use of language in concrete situation.7. speech and writing (口头语与书面语) Speech is the spoken form of language whereas writing is written codes, gives language new scope.8. linguistics behavior potential and actual linguistic behavior (语言行为潜势与实际语言行为) People actually says on a certain occasion to acertain person is actual linguistics behavior. And each of possible linguistic items that he could have said is linguistic behavior potential.9. syntagmatic relation and paradigmatic relation(横组合关系与纵聚合关系) The former describes the horizontal dimension of a languagewhile the latter describes the vertical dimension of a language.10. verbal communication and non-verbal communication(言语交际与非言语交际) Usual use of language as a means of transmittinginformation is called verbal communication. The ways we convey meaning without using language is called non-verbal communication.1. ★How does John Lyons classify linguistics?According to John Lyons, the field of linguistics as a whole can be divided into several subfields as following:1) General linguistics and descriptive linguistics.2) Synchronic linguistics and diachronic linguistics.3) Theoretical linguistics and applied linguistics.4) Microlinguistics and macrolinguistics.2. Explain the three principles by which the linguist is guided: consistency, adequacy and simplicity.1) Consistency means that there should be no contradictions between different parts of the theory and the description.2) Adequacy means that the theory must be broad enough in scope to offer significant generalizations.3) Simplicity requires us to be as brief and economic as possible.3. ★What are the sub-branches of linguistics within the language system?Within the language system there are six sub-branches as following:1) Phonetics. 语音学is a study of speech sounds of all human languages.2) Phonology. 音位学studies about the sounds and sound patterns of a speaker’s native language.3) Morphology. 形态学studies about how a word is formed.4) Syntax. 句法学studies about whether a sentence is grammatical or not.5) Semantics. 语义学studies about the meaning of language, including meaning of words and meaning of sentences.6) Pragmatics. 语用学★The scope of language: Linguistics is referred to as a scientific study of language.★The scientific process of linguistic study: It involves four stages: collecting data, forming a hypothesis, testing the hypothesis and drawing conclusions.1. articulatory phonetics(发音语音学) The study of how speech organs produce the sounds is called articulatory phonetics.2. acoustic phonetics (声学语音学) The study of the physical properties and of the transmission of speech sounds is called acoustic phonetics.3. auditory phonetics (听觉语音学) The study of the way hearers perceive speech sounds is called auditory phonetics.4. consonant (辅音) Consonant is a speech sound where the air form the language is either completely blocked, or partially blocked, or where theopening between the speech organs is so narrow that the air escapes with audible friction.5. vowel (元音) is defined as a speech sound in which the air from the lungs is not blocked in any way and is pronounced with vocal-cord vibration.6. bilabials (双唇音) Bilabials means that consonants for which the flow of air is stopped or restricted by the two lips. [p][b] [m] [w]7. affricates (塞擦音) The sound produced by stopping the airstream and then immediately releasing it slowly is called affricates. [t X] [d Y] [tr] [dr]8. glottis (声门) Glottis is the space between the vocal cords.9. rounded vowel (圆唇元音) Rounded vowel is defined as the vowel sound pronounced by the lips forming a circular opening. [u:] [u] [OB] [O]10. diphthongs (双元音) Diphthongs are produced by moving from one vowel position to another through intervening positions.[ei][ai][O i] [Q u][au]11. triphthongs(三合元音) Triphthongs are those which are produced by moving from one vowel position to another and then rapidly andcontinuously to a third one. [ei Q][ai Q][O i Q] [Q u Q][au Q]12. lax vowels (松元音) According to distinction of long and short vowels, vowels are classified tense vowels and lax vowels. All the long vowelsare tense vowels but of the short vowels,[e] is a tense vowel as well, and the rest short vowels are lax vowels.1. ★How are consonants classified in terms of different criteria?The consonants in English can be described in terms of four dimensions.1) The position of the soft palate.2) The presence or the absence of vocal-cord vibration.3) The place of articulation.4) The manner of articulation.2. ★How are vowels classified in terms of different criteria?Vowel sounds are differentiated by a number of factors.1) The state of the velum2) The position of the tongue.3) The openness of the mouth.4) The shape of the lips.5) The length of the vowels.6) The tension of the muscles at pharynx.3. ★What are the three sub-branches of phonetics? How do they differ from each other?Phonetics has three sub-branches as following:1) Articulatory phonetics is the study of how speech organs produce the sounds is called articulatory phonetics.2) Acoustic phonetics is the study of the physical properties and of the transmission of speech sounds is called acoustic phonetics.3) Auditory phonetics is the study of the way hearers perceive speech sounds is called auditory phonetics.4. ★What are the commonly used phonetic features for consonants and vowels respectively?I. The frequently used phonetic features for consonants include the following:1) Voiced.2) Nasal.3) Consonantal.4) Vocalic.5) Continuant.6) Anterior.7) Coronal.8) Aspirated.II. The most common phonetic features for vowels include the following:1) High.2) Low.3) Front.4) Back.5) Rounded.6) Tense.1. phonemes (音位) Phonemes are minimal distinctive units in the sound system of a language.2. allophones (音位变体) Allophones are the phonetic variants and realizations of a particular phoneme.3. phones (单音) The smallest identifiable phonetic unit found in a stream of speech is called a phone.4. minimal pair (最小对立体) Minimal pair means words which differ from each other only by one sound.5. contrastive distribution (对比分布) If two or more sounds can occur in the same environment and the substitution of one sound for anotherbrings about a change of meaning, they are said to be in contrastive distribution.6. complementary distribution(互补分布) If two or more sounds never appear in the same environment ,then they are said to be incomplementary distribution.7. free variation (自由变异) When two sounds can appear in the same environment and the substitution of one for the other does not cause anychange in meaning, then they are said to be in free variation.8. distinctive features (区别性特征) A distinctive feature is a feature which distinguishes one phoneme from another.9. suprasegmental features (超切分特征) The distinctive (phonological) features which apply to groups larger than the single segment are knownas suprasegmental features.10. tone languages (声调语言) Tone languages are those which use pitch to contrast meaning at word level.11. intonation languages (语调语言) Intonation languages are those which use pitch to distinguish meaning at phrase level or sentence level.12. juncture (连音) Juncture refers to the phonetic boundary features which may demarcate grammatical units.1. ★What are the differences between English phonetics and English phonology?1) Phonetics is the study of the production, perception, and physical properties of speech sounds, while phonology attempts to account forhow they are combined, organized, and convey meaning in particular languages.2) Phonetics is the study of the actual sounds while phonology is concerned with a more abstract description of speech sounds and tries todescribe the regularities of sound patterns.2. Give examples to illustrate the relationship between phonemes, phones and allophones.When we hear [pit],[tip],[spit],etc, the similar phones we have heard are /p/. And /p/ and /b/ are separate phonemes in English, while [ph] and [p] are allophones.3. How can we decide a minimal pair or a minimal set?A minimal pair should meet three conditions:1) The two forms are different in meaning.2) The two forms are different in one sound segment.3) The different sounds occur in the same position of the two strings.4. ★Use examples to explain the three types of distribution.1) Contrastive distribution. Sounds [m] in met and [n] in net are in contrastive distribution because substituting [m] for [n] will result in achange of meaning.2) Complementary distribution. The aspirated plosive [ph] and the unaspirated plosive [p] are in complementary distribution because theformer occurs either initially in a word or initially in a stressed syllable while the latter never occurs in such environments.3) Free variation. In English, the word “direct” may be pronounce in two ways: /di’rekt/ and /dia’rekt/, and the two different sounds /i/ and /ai/can be said to be in free variation.5. What’s the difference between segmental features and suprasegmental features? What are the suprasegmental features in English?I. 1) Distinctive features, which are used to distinguish one phoneme from another and thus have effect on one sound segment, are referred toas segmental features.2) The distinctive (phonological) features which apply to groups larger than the single segment are known as suprasegmental features.3) Suprasegmental features may have effect on more than one sound segment. They may apply to a string of several sounds.II.The main suprasegmental features include stress, tone, intonation and juncture.6. What’s the difference between tone languages and intonation language?Tone languages are those which use pitch to contrast meaning at word level while intonation languages are those which use pitch to distinguish meaning at phrase level or sentence level7. ★What’s the difference between phonetic transcriptions and phonemic transcriptions?The former was meant to symbolize all possible speech sounds, including even the most minute shades of pronunciation, while the latter was intended to indicate only those sounds capable of distinguishing one word from another in a given language.1. morphemes (语素) Morphemes are the minimal meaningful units in the grammatical system of a language.allomorphs (语素变体) Allomorphs are the realizations of a particular morpheme.morphs (形素) Morphs are the realizations of morphemes in general and are the actual forms used to realize morphemes.2. roots (词根) Roots is defined as the most important part of a word that carries the principal meaning.affixes (词缀) Affixes are morphemes that lexically depend on roots and do not convey the fundamental meaning of words.free morphemes (自由语素) Free morphemes are those which can exist as individual words.bound morphemes (粘着语素) Bound morphemes are those which cannot occur on their own as separate words.3. inflectional affixes (屈折词缀) refer to affixes that serve to indicate grammatical relations, but do not change its part of speech.derivational affixes (派生词缀) refer to affixes that are added to words in order to change its grammatical category or its meaning.4. empty morph (空语子) Empty morph means a morph which has form but no meaning.zero morph (零语子) Zero morph refers to a morph which has meaning but no form.5. IC Analysis (直接成分分析) IC analysis is the analysis to analyze a linguistic expression (both a word and a sentence) into a hierarchicallydefined series of constituents.6. immediate constituents(直接成分) A immediate constituent is any one of the largest grammatical units that constitute a construction.Immediate constituents are often further reducible.ultimate constituents (最后成分) Ultimate constituents are those grammatically irreducible units that constitute constructions.7. morphological rules (形态学规则) The principles that determine how morphemes are combined into new words are said to be morphologicalrules.8. word-formation process (构词法) Word-formation process mean the rule-governed processes of forming new words on the basis of alreadyexisting linguistic resources.1. ★What is IC Analysis?IC analysis is the analysis to analyze a linguistic expression (both a word and a sentence) into a hierarchically defined series of constituents.2. How are morphemes classified?1) Semantically speaking, morphemes are grouped into two categories: root morphemes and affixational morphemes.2) Structurally speaking, they are divided into two types: free morphemes and bound morphemes.3. ★Explain the interrelations between semantic and structural classifications of morphemes.a) All free morphemes are roots but not all roots are free morphemes.b) All affixes are bound morphemes, but not all bound morphemes are affixes.4. What’s the difference between an empty morph and a zero mor ph?a) Empty morph means a morph that has form but no meaning.b) Zero morph refers to a morph that has meaning but no form.5. Explain the differences between inflectional and derivational affixes in term of both function and position.a) Functionally:i.Inflectional affixes sever to mark grammatical relations and never create new words while derivational affixes can create new words.ii.Inflectional affixes do not cause a change in grammatical class while derivational affixes very often but not always cause a change in grammatical class.b) In term of position:i.Inflectional affixes are suffixes while derivational affixes can be suffixes or prefixes.ii.Inflectional affixes are always after derivational affixes if both are present. And derivational affixes are always before inflectional suffixes if both are present.6. What are morphological rules? Give at least four rules with examples.The principles that determine how morphemes are combined into new words are said to be morphological rules.For example:a) un- + adj. ->adj.b) Adj./n. + -ify ->v.c) V. + -able -> adj.d) Adj. + -ly -> adv.1. syntagmatic relations (横组关系) refer to the relationships between constituents in a construction.paradigmatic relations (纵聚合关系) refer to the relations between the linguistic elements within a sentence and those outside the sentence.hierarchical relations (等级关系) refer to relationships between any classification of linguistic units which recognizes a series of successively subordinate levels.2. IC Analysis (直接成分分析) is a kind of grammatical analysis, which make major divisions at any level within a syntactic construction.labeled IC Analysis(标记法直接成分分析) is a kind of grammatical analysis, which make major divisions at any level within a syntactic construction and label each constituent.phrase markers (短语标记法) is a kind of grammatical analysis, which make major divisions at any level within a syntactic construction, and label each constituent while remove all the linguistic forms.labeled bracketing (方括号标记法) is a kind of grammatical analysis, which is applied in representing the hierarchical structure of sentences by using brackets.3. constituency (成分关系)dependency (依存关系)4. surface structures (表层结构)refers to the mental representation of a linguistic expression, derived from deep structure by transformationalrules.deep structures (深层结构) deep structure of a linguistic expression is a theoretical construct that seeks to unify several related structures. 5. phrase structure rules (短语结构规则)are a way to describe a given language's syntax. They are used to break a natural language sentencedown into its constituent parts.6. transformational rules (转换规则)7. structural ambiguity (结构歧义)1. What are the differences between surface structure and deep structure?They are different from each other in four aspects:1) Surface structures correspond directly to the linear arrangements of sentences while deep structures correspond to the meaningful groupingof sentences.2) Surface structures are more concrete while deep structures are more abstract.3) Surface structures give the forms of sentences whereas deep structures give the meanings of sentences.4) Surface structures are pronounceable but deep structures are not.2. Illustrate the differences between PS rules and T-rules.1) PS rules frequently applied in generating deep structures.2) T-rules are used to transform deep structure into surface structures.3. What’s the order of generating sentences? Do we st art with surface structures or with deep structures? How differently are theygenerated?To generate a sentence, we always start with its deep structure, and then transform it into its corresponding surface structure.Deep structures are generated by phrase structure rules (PS rules) while surface structures are derived from their deep structures by transformational rules (T-rules).4. What’s the difference between a compulsory constituent and an optional one?Optional constituents may be present or absent while compulsory constituents must be present.5. What are the three syntactic relations? Illustrate them with examples.1) Syntagmatic relations2) Paradigmatic relations.3) Hierarchical relations.1. Lexical semantics (词汇语义学) is defined as the study of word meaning in language.2. Sense (意义) refers to the inherent meaning of the linguistic form.3. Reference (所指) means what a linguistic form refers to in the real world.4. Concept (概念) is the result of human cognition, reflecting the objective world in the human mind.5. Denotation (外延) is defined as the constant ,abstract, and basic meaning of a linguistic expression independent of context and situation.6. Connotation (内涵) refers to the emotional associations which are suggested by, or are part of the meaning of, a linguistic unit.7. Componential analysis (成分分析法) is the way to decompose the meaning of a word into its components.8. Semantic field (语义场) The vocabulary of a language is not simply a listing of independent items, but is organized into areas, within whichwords interrelate and define each other in various ways. The areas are semantic fields.9. Hyponymy (上下义关系) refers to the sense relation between a more general, more inclusive word and a more specific word.10. Synonymy (同义关系) refers to the sameness or close similarity of meaning.11. Antonymy (反义关系) refers to the oppositeness of meaning.12. Lexical ambiguity (词汇歧义)13. Polysemy (多义性) refers to the fact that the same one word may have more than one meaning.14. Homonymy (同音(同形)异义关系) refers to the phenomenon that words having different meanings have the same form.15. Sentence semantics (句子语义学) refers to the study of sentence meaning in language.1. What’s the criterion of John Lyons in classifying semantics into its sub-branches? And how does he classify semantics?In terms of whether it falls within the scope of linguistics, John Lyons distinguishes between linguistic semantics and non-linguistic semantics.According John Lyons, semantics is one of the sub-branches of linguistics; it is generally defined as the study of meaning.2. What are the essential factors for determining sentence meaning?1) Object, 2) concept, 3) symbol, 4) user, 5) context.3. What is the difference between the theory of componential analysis and the theory of semantic theory in defining meaning of words?4. What are the sense relations between sentences?1) S1 is synonymous with S2.2) S1 entails S2.3) S1 contradicts S2.4) S1 presupposes S2.5) S1 is a tautology, and therefore invariably true.6) S1 is a contradiction, and therefore invariably false.7) S1 is semantically anomalous.1. Speech act theory (言语行为理论)2. Cooperative principle and its maxims (合作原则及其准则)3. Politeness principle and its maxims (礼貌原则及其准则)4. Conversational implicature (会话含义)5. Indirect speech act (间接言语行为)6. Pragmatic presupposition (语用学预设)7. Relevance theory (关联理论)8. Illocutionary act (言外行为)9. (Horn’s) Q-Principle and R-Principle10. Perfrmative verbs (施为句动词)1. Make comments on the different definitions of pragmatics.2. What are the main types of deixis?3. Explain the statement: context is so indispen sable in fully understanding interpreting the speaker’s meaning.4. How are Austin’s and Searle’s speech act theories related to each other?5. What’s the relationship between CP and PP?6. What do you know about presupposition triggers in English? Explain them briefly with examples.7. What is ostensive-referential communication?8. Explain the obvious presupposition of speaker who say each of the following:1) When did you stop beating your wife?2) Where did Tom buy the watch?3) Your car is broken.9. What do you think of the fol lowing statement? “Tom participated in spreading rumors” entails “Tom engaged in spreading rumors”.Chapter 9 话语分析1. text(语篇) = discourse 语篇是指实际使用的语言单位,是一次交际过程中的一系列连续的话段或句子所构成的语言整体。
语料库常用术语解释 (1)
语料库语言学常用术语
Monolingual单语 corpus: a corpus which contains texts in a single language.
Multilingual多语 corpus: a corpus which represents small collections of individual monolingual corpora (or subcorpora) in the sense that they use the same or similar sampling procedures and categories for each language but contain completely different texts in those several languages.
TTR是衡量文本中词汇密度的常用方法。可 辅助说明文本的词汇难度。
但是,文本中有大量功能词(function words, 如the、a、of等)反复出现,文本每增加 一个词,形符就会增加一个,但类符却未 必随之增加。这样文本越长,功能词重复 次数越多,TTR会越低。因此用TTR衡量词 汇密度就不合理。
语料库的方法基于真实的语言使用情况,事实胜 于雄辩
Frank Liang
A corpus can be analyzed using software tools, much like those used to find key words on the Internet, but with greater sophistication. By evaluating the results of these searches, it is possible to see how language is really used, and to find answers to questions like these:
定向过程分析英语作文
定向过程分析英语作文Understanding the process of directional analysis in English composition is essential for crafting well-structured and coherent essays. Directional analysis involves breaking down a writing prompt or topic into its key components, understanding the purpose and audience, brainstorming ideas, organizing thoughts, and effectively communicating them in written form. In this article, we will explore the steps involved in directional analysis and how they contribute to the development of a successful English essay.Firstly, directional analysis begins with a careful examination of the essay prompt or topic. This involves identifying the main subject or theme, understanding any specific instructions or requirements, and determining the intended audience. By thoroughly analyzing the prompt, writers can gain clarity on what is expected of them and tailor their approach accordingly.Once the prompt has been analyzed, the next step is brainstorming ideas and gathering relevant information. This may involve researching the topic, considering different perspectives or angles, and generating potential arguments or points to support the thesis statement. Brainstorming allows writers to explore various possibilities and develop a solid foundation for their essay.After brainstorming, the focus shifts to organizing the ideas and information collected. This is where the outline comes into play. An outline serves as a roadmap for the essay, helping to structure the content in a logical and coherent manner. It typically includes an introduction, thesis statement, body paragraphs, each with a topic sentence and supporting evidence, and a conclusion.With the outline in place, writers can start drafting the essay. During this stage, it's important to focus on clarity, coherence, and cohesion. Each paragraph should flow smoothly into the next, with clear transitions that guide the reader through the essay. Sentences should be concise and well-constructed, conveying ideas effectively without unnecessary complexity.As the essay takes shape, writers should continuously refer back to the directional analysis to ensure that they are staying on track and addressing the key points identified earlier. This may involve revising the outline or making adjustments to the content as needed. It's also important to pay attention to the overall structure and organization of the essay, making sure that each section serves its purpose and contributes to the overall argument.Once the initial draft is complete, the final step is revising and editing. This involves reviewing the essay for clarity, coherence, and accuracy, as well as checking for grammar, punctuation, and spelling errors. Revising allows writers to refine their ideas, strengthen their arguments, and ensure that the essay meets the requirements of the assignment.In conclusion, directional analysis plays a crucial role in the process of writing an English essay. By carefully analyzing the prompt, brainstorming ideas, organizing thoughts, and revising as needed, writers can develop well-structured and coherent essays that effectively communicate their ideas to the intended audience. By following these steps, writers can enhance their writing skills and produce high-quality essays that meet the expectations of their readers.。
eofs.standard原理
eofs.standard原理EOFs (Empirical Orthogonal Functions) are a mathematical technique used to analyze and decompose complex datasets into a set of orthogonal basis functions. These basis functions, also known as eigenfunctions, capture the dominant patterns of variability in the data. The EOF analysis is widely applied in various fields, including meteorology, oceanography, and climate science, to study and understand the spatio-temporal patterns present in large datasets.From a mathematical perspective, EOFs are derived from the Singular Value Decomposition (SVD) of a data matrix. The SVD breaks down the data matrix into three components: the left singular vectors (spatial patterns), the singular values (variance explained), and the right singular vectors (temporal coefficients). The left singular vectors form the EOFs, which represent the spatial patterns in the data. These patterns are ordered in terms of their contribution to the total variance explained by the dataset.The EOF analysis provides valuable insights into the underlying processes and dynamics of the system under study. By decomposing the data into orthogonal basis functions, it allows researchers to identify the dominant modes of variability and their spatial distribution. Thisinformation is crucial for understanding the physical mechanisms driving the observed patterns and for making predictions about future behavior.One of the key advantages of EOF analysis is itsability to reduce the dimensionality of complex datasets without losing important information. By retaining only the leading EOFs, which capture the most significant patternsof variability, researchers can represent the data in a lower-dimensional space. This simplification facilitates data interpretation and visualization, making it easier to identify coherent structures and relationships within the dataset.Furthermore, EOF analysis can be used to identify and remove noise or unwanted variability from the data. Byexcluding the EOFs associated with noise or measurement errors, researchers can focus on the meaningful signals present in the dataset. This noise reduction step improves the signal-to-noise ratio and enhances the reliability of subsequent analyses or modeling efforts.From a practical perspective, EOF analysis is implemented through various computational algorithms. These algorithms typically involve matrix manipulations and eigenvalue decompositions, which can be computationally intensive for large datasets. However, advancements in computational resources and algorithms have made itfeasible to apply EOF analysis to increasingly larger and more complex datasets.In conclusion, EOF analysis is a powerful mathematical technique used to analyze and decompose complex datasets. It enables researchers to identify dominant patterns of variability, understand underlying processes, reduce dimensionality, and remove noise. By providing valuable insights into the spatio-temporal patterns present in thedata, EOF analysis plays a crucial role in advancing our understanding of various scientific disciplines.。
Lexical cohesion and discourse intonation
2. Grammatical and lexical cohesion The contribution of lexical cohesion to the organizational properties of texts has long been acknowledged by discourse analysts. According to Hoey (1991:10), lexical cohesion, which forms multiple relationships within a text, is the main source of textual coherence, and lexical cohesion is the most common form of cohesive tie, accounting for 40% of the cohesive ties cited in Hasan (1984). While some studies tend to distinguish between grammatical and lexical cohesion or repetition (see for example Halliday & Hasan 1976), the notion of what may be considered to be part of the same cohesive chain in a discourse proposed by Winter (1974, 1979) is broader because he includes ellipsis, substitution, reference and lexical repetition. In the present study examining cohesion in spoken discourse, Winter’s (1974, 1979) approach to the ties between lexical and non-lexical cohesion is adopted as a more appropriate way of portraying the complexity of lexical cohesion, especially when the use of ellipsis and reference are generally far more prevalent in spoken discourse than in written discourse (see, for example, Cheng & Warren 1999). Hoey (1991) notes that Winter’s broad definition of cohesion basically describes all of the cohesive devices as functioning as repetition, and Hoey then asks an important question which he says needs further investigation: ‘under what circumstances do we use one rather than the other?’ (Hoey 1991:17). This study attempts to offer at least a partial explanation to Hoey’s question. In his research on vocabulary patterns in conversation, McCarthy (1988:185) examines the lexical chains in the form of what he terms ‘relexicalisations’ across turns and across speakers in conversational data. These relexicalisations cover non-identical repetitions that have been re-formulated or re-structured. McCarthy’s study is relevant to this study because he also studies
基于语义的语音合成_语音合成技术的现状及展望_朱维彬
第27卷 第5期2007年5月北京理工大学学报T ransactions of Beijing Institute of T echnolog y Vol.27 No.5M ay 2007文章编号:1001-0645(2007)05-0408-05基于语义的语音合成)))语音合成技术的现状及展望朱维彬1, 吕士楠2(11北京交通大学信息科学研究所,北京 100044;21中国科学院声学研究所,北京 100080)摘 要:综述了语音合成技术的发展现状.指出并分析了目前系统存在的发音质量、韵律预测、表现能力等3个方面的问题.提出了将语义分析引入语音合成系统,使合成语音具有准确、生动的语义表现能力,并作为新一代语音合成系统的目标.探讨了实现这一目标所涉及的理论基础、技术实现、基础资源等研究内容.关键词:语音合成;语义;韵律;表现能力中图分类号:T P 391 文献标识码:ASemantic -Based Speech Synthesis)))Survey and Perspective on the Speech Synthesis T echnologyZH U We-i bin 1, LU ##Sh-i nan2(11I nstitute of Information Science,Beijing Jiaotong U niversit y,Beijing 100044,China;21Institute of Acoustics,Chinese A cademy of Sciences,Beijing 100080,China)Abstract :Overview s the state -o-f the -art of speech sy nthesis technology.Problems such as speech quality,prosody prediction and expressiveness existing in current systems w ere analyzed.It isproposed to integrate semantic -analysis into speech synthesis systems.Thus,the goal of the next g eneration of systems ought to be to convey the semantic information perfectly and vividly through sy nthesized speech.The fundamental principles methodolog ies,and basic resources relevant to achieve the goals are discussed.Key words :speech synthesis;semantics;prosody;expressiveness 收稿日期:2007-03-09基金项目:国家/八六三0计划项目(2006AA010104);北京交通大学校基金项目(2005RC014)作者简介:朱维彬(1966)),男,博士,讲师.E -mail:wbzhu@;吕士楠(1937)),男,研究员,E -mail:lu -shinan@.语音合成系统性能可分为3个层次:表音(清晰、自然地合成出语音)、表意(准确地表达话语意图)、表情(生动地表现语意情感).近年来,由于基于数据库的单元挑选及数据驱动建模技术的普遍采用,语音合成系统在可懂度、自然度等评价指标上有了显著提高[1-4],但在本质上仍处于表音层次.为了使合成语音具备/表情达意0的能力,需使文本到语音的转换过程在语义层面上进行.将语义处理机制引入语音合成,实现文本的语义分析,一方面有助于解决目前系统普遍存在的注音及韵律结构预测等方面的问题;另一方面,解决语义言语实现所涉及的语义重音、功能语调、发音方式等方面的建模与预测;在此基础之上,构建具有准确、生动表现能力的新一代语音合成系统.在考查了语音合成技术的发展现状之后,作者基于对现有问题产生的原因进行了分析,指出了解决问题的关键在于语义分析及实现,阐述了下一阶段基于语义的语音合成技术在理论基础、技术实现的重点已由早期的音段(segment)层级的处理转到了对整段话语(utterance)特性的建模,对合成语音质量的评价指标也由可懂度(intelligibility)转变为自然度(naturalness).促成这种变化和进步的主要是韵律分析方法及数值建模技术两方面的突破.用于描述英语韵律现象的符号系统ToBI(tone and break index)的出现,是韵律研究进程中的标志性事件[5].尽管学术界对于ToBI定义的具体内容持有不同的观点[6-7],但它所体现的离散的符号系统描述连续的韵律声学特征和对于真实样本实施标注分析的方法带来了基于标注数据库的韵律分析方法及韵律统计建模方法的盛行[8-9].在数值建模方面普遍采用了基于数据库单元挑选的技术路线.由于基本合成单元一般采用较大的音段单位(音素以上),在相当程度上解决了合成语音的可懂度问题;而自然度问题的解决则是通过韵律模型约束下的最优单元挑选实现的,合成转化成了最优搜索问题.事实上,语音识别中数据驱动建模、最优搜索等算法,在语音合成中得到了普遍采用[10].汉语语音合成的重大突破,也是在制定汉语韵律标注符号系统C-ToBI[11-12]及引入单元挑选的技术路线之后,普遍采用了以韵律词为基本单位的韵律层级结构作为汉语主要的韵律特征.同时,在汉语韵律声学体现分析[13]、基于韵律标注数据库的韵律统计建模[14-15]等方面取得了实质性进展.目前,汉语语音合成技术已经达到了实用化水平,并出现了捷通华声、科大讯飞等以语音合成系统为核心产品的专业化公司.2合成语音质量虽然语音合成系统已经进入应用阶段,但依然存在诸多问题.由美国自然科学基金支持的英语语音合成系统性能评测Blizzard Challenge已经连续举行了两届[16].参加单位基于共同的合成语音样本数据库开发各自的系统,提交合成语音样本用于评测.这些合成语音样本设置了押韵测试(modified rhyme test,MRT)、语义不可预测句测试(semant-i cally unpredictable sentences,SUS),采用词错误率WER为1417%,MOS为31190分.2006年的测试中,专家组给出的最高M OS为31696分.从测试结果看,无论是可懂度还是自然度,较自然人发音都还有明显的差距.在国家/八六三0计划有关项目的支持下,针对汉语语音合成系统的研究,已进行了数次评测[17].在各次评测中,同样设置了可懂度和自然度的测试内容.评测结果反映,在可懂度和自然度方面,汉语的语音合成质量同样还有相当大的提升空间.无论是英语的Blizzard Challenge测试,还是汉语的/八六三0测试,由于采用统一的测试方案,各参加系统的性能变得可比,可以帮助各研究单位在算法层面做进一步地分析,从而推进了语音合成技术的进步.虽然测试结果具有较高的权威性,但由于WER和M OS都是系统性能的综合性指标,不能直接反映系统各功能模块的性能和问题,为了分析影响系统性能的原因,还需进行针对性的诊断测试.根据对数个具有代表性的汉语语音合成系统的考察,作者对观察到的合成语音缺陷进行了分类.主要问题有:¹与可懂度直接相关的发音质量,包括音质缺陷、多音字、轻声、变调、数字串等方面的问题.º与自然度密切相关的/分词断句0错误,反映了韵律结构预测方面的问题.»合成语音音色单一、语调缺少变化、缺乏表现能力,直接原因是由于系统中没有轻重音、功能语调、发音风格等方面的控制.这些问题的存在表明:目前的语音合成技术还处在/表音0层次,而且在这一层次系统性能还有提升的空间;另外,系统还不具备属于更高层次的/表情达意0的能力,还不能通过合成语音准确、生动地传递语义信息.3问题分析311发音质量发音质量主要涉及音段、超音段、音色及注音方面的问题.在音段、超音段层面,由于单元挑选策略或样本稀少的原因,被选中音段有可能与合成的语境不匹配.而波形拼接的过程一般为简单的平滑处理法完全消除语境不匹配的影响,从而影响合成语音的音质,进而会影响合成语音的可懂度、自然度.音色层面,在构建语音数据库时,常采用朗读风格的录音,而且还需有意识地控制并保持音色、节奏、发音方式的一致性,因而基于单一音色数据库的波形拼接策略只能提供单一音色的合成语音.由于数据库规模的限制,通过增加音色、音段变体样本的方式虽然有效果,但是改进是有限的.根本的解决方法是研制高性能语音合成器,使之具备实施高强度的韵律、音色、音质调整的能力.注音错误涉及了文本处理中的注音功能.多音字、数字串的读法,目前有效的解决方案是利用基于分词及词性(part-o-f speech,POS)信息的统计方法[18-19].但该类问题的最终解决,将依赖于正确的语义分析的结果.例如,例句1中两个/长0字的注音,测试系统都标成了/chang20.例句1孩子又长了,胳膊也长了.原因是,前后两个短句的结构及词性构成一样,而/chang20是一个高频读音,这样,统计方法就不再有效,只有进行句子的语义类别及配价关系分析,才有可能将/长0确切地标为/zhang30.如果系统具有上下文语义分析能力,能够判断出话题是有关/孩子试穿衣服0,则可进一步将后一个/长0标为/chang20.312韵律预测目前,汉语语音合成系统的韵律预测是指韵律层级结构的预测.尽管为提高预测的准确性提出了多种建模方法,如决策树、有限状态机等[20],但所利用的主要信息还是待合成文本的分词及词性信息.从原则上讲,分词断句即韵律层级划分,需要保证各韵律单元的语义完整,并准确反映单元间的语义搭配关系.所以单纯地利用词性信息,常常会带来划分歧义.例句2为测试系统的韵律层级结构的标注结果.例句2中国农业科学院农业|与农村发展研究所|在当地设立了|试验基地和观察点.这里,空格表示韵律词边界,/|0表示韵律短语边界.对测试系统的处理过程分析表明,对例句2的分词结果没有歧义,词性标注除了/发展0、/试验0被标识为动词外,其它都不存争议.而最终的标注结果,对于现行的韵律预测模型来说也是合理的.显然,要解决这类歧义问题,对文本的分析需上升到313表现能力现有系统韵律模型,主要是在句子层面采用韵律层级结构辅助声调信息,用以刻画韵律的变化.如此,可以得到语调流畅的合成语音.但句子内部没有轻重音变化,句子或短语之间没有对比变化,合成语音语调只能是单调的,缺乏表现力.虽然韵律层级结构也负载了语义结构信息,但还有很多语义信息是通过轻重、节奏、语调及语气等韵律特征传递的,为了合成生动的语音,必须对韵律特征进行更加精细、完备地描述.重音是实现语义强调的重要手段.作者基于感知优化的重音检测器,实现了汉语语音数据库的自动标注,并利用重音标注数据库训练得到支持重音的韵律声学预测模型,进而构成支持重音合成的语音合成系统[21].但如何由文本分析出重音的位置及级别,需要引入语义处理机制才能解决.例如,例句3中需要强调的信息是/晴天0而非/阴天0,这类重音,只能依据上下文的语义语境来确定.例句3明天是个晴天!上下文语义信息的利用,意味着对文本的分析范畴将超出句子层面.除了重音之外,功能语调如疑问语调对语义表达的完整性也非常重要,来自应用层面的需求也非常紧迫.因此,合成语音表现能力的提高,需优先解决重音和疑问语调的实现.此外,节奏、音色与语义、情感的表达也有密切关系,对改善合成语音的表现能力也非常重要,只是情感的语音合成将更具挑战性[22].总之,解决系统的现有问题,提升合成语音质量,一方面需改进韵律模型,实现对韵律特征更细致的刻画,使合成语音更加生动.更重要的是,需在文本分析阶段引入语义分析,解决多音字注音问题,克服韵律结构划分中的歧义,并利用句子及其以上层面的语义信息,完成语义焦点、语调结构类型,乃至语气的确定,从而使合成语音能够更为完整、准确地表达语义信息.4新一代语音合成系统展望以清晰、自然的合成语音,准确、生动地传递语义信息是新一代语音合成系统所追求的目标.为实现这一目标,将涉及到理论基础、技术实现及基础资源等方面的研究.411理论基础)))语义的言语实现实现既定的系统目标,依赖于有效的语义-语音计算模型,这就需要在理论层面研究语义的言语实现机制.首先,需要确定语义的形式化描述方案.到目前为止,几乎所有的汉语语义描述方案都是面向自然语言处理的,主要用于机器翻译[23-24],但对于语音合成仍有借鉴作用.由于韵律特征与语义之间有着紧密的关系,所以可以借助韵律分析来确定面向语音合成的语义分类颗粒度、属性及关系的描述方案,同时构建语义-韵律关系理论体系.412技术实现)))基于语义的语音合成基于语义的语音合成需要实现3个关键性功能模块:语义分析、韵律预测、高性能语音合成器.语义分析模块实现由系统输入文本到形式化语义表达的分析功能.所利用的基本信息将包括待合成文本的分词、词性以及对应的词义.对词义的标注需要借助于语义词典.模块将利用数据驱动建模方法,基于语义标注数据库构建文本的语义标注模型;预期中间的计算过程将涉及或反映语句结构、新旧话题、语义焦点、句型、情态等内容,最终输出的是形式化语义.韵律预测模块实现由语义分析到韵律特征的预测.模块的输入除了语义分析输出,还包括一般文本分析器输出的分词、词性标注及其注音,以保持和现有系统在技术上兼容.模块输出的是有关发音的、细化的韵律描述,预期包括韵律结构、语义重音、语调类型、发音方式等特征.高性能语音合成器由于输出的语音要求声音清晰、语调准确、语气生动,纯粹的基于单元挑选波形拼接技术不再适用.因此,就对语音合成器性能提出了更高要求,即能够在保持声音清晰、自然的前提下,准确、生动地实现各种语调和语气,这就意味着该合成器不仅具有超音段参数调整能力,同时还需具备音色调整能力.413基础资源)))语义词典与数据库构建语义词典是进行语义分析的基本资源.现有的汉语语义词典[25]主要是面向自然语言处理任务构建的,在确定语义的形式化描述方案之后,将根据语音合成的需要进行适当地调整与改动.数据驱动建模策略是实现系统目标的一种合理的技术选择.一定规模的带有丰富标注信息的数据库,一方面将为理论分析提供真实样本,进而可望获得对系统建模的指导意义;同时,也为基于数据驱动建模方案提供训练及测试数据.因此,数据库的构建及质量对于系统目标实现是至关重要的.在数据库构建过程中,将根据使用目的,确定收集数据的类型、内容和规模,之后是数据处理工作,其核心是各种类型标注.预期将包括以下条目.语言部分:文本、分词及词性、语义标注;语音部分:注音、音段切分、韵律标注.5结束语提出了新一代语音合成系统的基本概念)))基于语义分析的语音合成系统.其功能将包括:基于文本语义分析,实现与语义相关联的韵律结构、语义重音、功能语调、发音风格等细致的韵律特征预测,通过高性能合成器输出合成语音.其目标是准确、生动地传递语义信息.准确是指语义表达完整、精确;生动是指表达方式的多样性和恰如其分.其核心是语义的体现.参考文献:[1]Black A,Campbell N.Optimising selection o f units fr omspeech databases for concatenative synthesis[C]M Pro-ceedings of Eurospeech1995.M adrid,Spain:[s.n.],1995:581-584.[2]Black A.P erfect synthesis for all of the peo ple all of thetime[C]M Proceedings of IEEE T T S Workshop2002.Santa M onica,U SA:[s.n.],2002:167-170.[3]Chu M in,Peng Hu,Chang Eric.Selecting non-unifor munits from a very large corpus for concatenative speech syn-thesizer[C]M Proceedings of IEEE International Confer-ence on Acoustics,Speech,and Signal Processing2001.Sale L ake City,U SA:[s.n.],2001:785-788.[4]Li Wei,L in Zhenhua,Hu Yu,et al.A statistical methodfor computing candidate unit cost in corpus based Chinese speech sy nthesis system[C]M Proceedings of Inter national Confer ence on Chinese Co mputing2001.Singapore City,Sing apore:[s.n.],2001.[5]Silverman K,Beckman M,Pitrelli J,et al.T oBI:a stan-dard for labeling English prosody[C]M Proceedings of In-ternational Confer ence o f Spoken Language P rocessing1992.Banff,Canada:[s.n.],1992:867-870.[6]Wig htman C.T oBI or not T oBI?[C]M Pr oceedings of In-ternational Conference on Speech P rosody2002.A ix-en-Provence,F rance:[s.n.],2002:25-29.[7]M ix dorff H.Speech technology,T oBI and making senseof prosody[C]M Proceedings of International Conferenceof Speech Proso dy2002.Aix-en-P rovence,F rance:[s.n.],2002:31-37.[8]Black A,Hunt J.Generating F0contours from T oBI la-bels using linear reg ression[C]M Proceedings of I nterna-tional Conference of Spoken Language Processing1996.P hiladelphia,U SA:[s.n.],1996:1385-1388.[9]Q ian Yao,Chu M in.Prosodic wo rd:the lowest con-stituent in the mandarin prosody processing[C]M Proceed-ings of International Conference on Speech Prosody2002.A ix-en-Provence,Fr ance:[s.n.],2002:591-594.[10]Ostendorf M,Bulyko I.T he impact of speech recognitionon speech synthesi s[C]M Proceedings of IEEE T T SWorkshop2002.Santa M onica,U SA:[s.n.],2002:99-106.[11]T seng C,Chou F.A prosodic labeling system for man-darin Chinese speech database[C]M Proceedings of Inter-national Congress of Phonetic Sciences1999.San Fran-cisco,USA:[s.n.],1999:2379-2382.[12]Zhu Weibin,Zhang Wei,Shi Q in,et al.Corpus buildingfor data-driv en T T S systems[C]M Proceedings of IEEE T T S Wor kshop2002.Santa Monica,U SA:[s.n.],2002:199-202.[13]Yang Yufang,Wang Bei.Acoustic correlates of hierar-chical prosodic boundary in mandarin[C]M Proceedings of International Confer ence on Speech Proso dy2002.Aix-en-Prov ence,France:[s.n.],2002:707-710. [14]M a Xijun,Zhang Wei,Zhu Weibin,et al.Probabilityproso dy model for unit selection[C]M P roceedings ofIEEE I nternatio nal Conference on A coustics,Speech,and Signal Pro cessing2004.M ontreal,Canada:[s.n.],2004:649-652.[15]Shi Qin,M a Xijun,Zhu Weibin,et al.Statistic prosodystructure prediction[C]M P roceedings of IEEE T T SWorkshop2002.Santa M onica,U SA:[s.n.],2002:155-158.[16]Black A,T okuda K.Blizzard challenge-2500:evaluatingcor pus-besed speech synthesis on common datasets[C]MProceedings of Eur ospeech2005.L isbon,Po rtugal:[s.n.],2005:77-80.[17]Liu Qun,Wang Xiang dong,Liu Hong,et al.Introduc-tion to HT RDP evaluations on Chinese infor mation pro-cessing and intellig ent human-machine interface[J].F ront iers of Computer Sciences in China,2007,1(1):58-93.[18]Zheng M in,Shi Qin,Zhang Wei,et al.Grapheme-to-phoneme conversion based on T BL algorithm in mandarin T T S system[C]M Proceedings of Eur ospeech2005.L is-bon,Portugal:[s.n.],2005:1897-1900.[19]Zhang Zirong,Chu M in.An efficient way to learn rulesfor grapheme-to-phoneme conversion in Chinese[C]M P roceedings of International Sy mposium on Chinese Spo-ken Language Processing2002.T aipei,China:[s.n.],2002.[20]Shi Q in,Zhang W ei,M a Xijun,et parisonsamong four statistics based methods of prosody structure prediction[C]M Proceedings o f N ational Conference on M an-M achine Speech Communicat ion2003.Xiamen,China:[s.n.],2003.[21]Zhu Weibin.P erceptual optimization of the Chinese ac-cen-t index detector[C]M Proceedings of International Conference on Speech Prosody2006.Dresden,Ger-many:[s.n.],2006.[22]T ao Jianhua.Emo tion co ntrol of Chinese speech synthesisin natural env ironment[C]M Proceedings of Eurospeech 2003.Genev a,Sw itzerland:[s.n.],2003:2349-2352.[23]Dong Zhendong,Dong Q iang.Resolutions to so me pr ob-lems in building Chinese lex ical semantic resour ces[C]M P roceedings of4th Chinese Lex ical Semantics Workshop.Hong Kong,China:[s.n.],2003.[24]W u Yunfang,P ei Y ulai,Zhang Yang sen,et al.A Ch-inese corpus with word sense annotation[C]M Proceedings of International Conference on the Computer P rocessing of Or iental L anguag es2006.Singapore City,Singapore:[s.n.],2006.[25]王惠,詹卫东,俞士汶.现代汉语语义词典规格说明书[J].汉语语言与计算学报,2003,13(2):159-176.W ang Hui,Zhan W eidong,Y u Shiw en.T he specification of the semantic know ledge-base of contemporary Chinese [J].Journal of Chinese Language and Computing,2003,13(2):159-176.(in Chinese)(责任编辑:赵秀珍)412北京理工大学学报第27卷。
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Contribution of Prosody to the Segmentation and Storage of "Words"in the Acquisition of a New Mini-LanguageOdile Bagou, Cécile Fougeron & Uli H. FrauenfelderLaboratoire de Psycholinguistique Expérimentale, Université de Genève{o.b; c.f; U.F}@pse.unige.chAbstractThis paper evaluates the relative contribution of two prosodic cues, lengthening and f0 contour, in the processes of speech segmentation and storage of new words. More precisely, we investigate the role of prosodic information in the acquisition by French learners of a mini-language constructed for the experiment. The results show that presence of prosodic information facilitates the speech segmentation and therefore, the acquisition of the new language. Indeed, lengthening or f0 rise on the word final syllable is used by listeners to infer the presence of a boundary. However, the presence of the two cues manipulated does not improve performance; and when only one cue is present, f0 induces slightly more accurate segmentation than lengthening. Finally, the storage of the "stressable” property of the word-final syllables in French is discussed.1. IntroductionProsody clearly organizes spoken language, but how humans use prosodic information in language acquisition and language processing is not yet well established. It is traditionally admitted that the acquisition of words in a new language, and the recognition of words in a known language, depend upon the segmentation of these words in the continuous speech stream (e.g. [15]).Since no systematic acoustic cues marking words boundaries can be found in continuous speech, it remains to be explained how speech segmentation takes place, and what information types this process exploits. Two main alternatives emerge from the literature: proposals in which segmentation relies mainly on phonotactics and distributional regularities ([11]; [15]; [16]) and proposals in which segmentation depends primarily on prosodic information, more particulary for infants but also for adults (e.g. [8];[10]).Our goal here is to advance our understanding of how prosodic information can guide segmentation. More specifically, since we postulate that acquisition requires a prior segmentation of the speech chain, we will try do determine the contribution of different prosodic cues in the acquisition of a new language by speakers of French, a language in which prosodic information is said to be post-lexical [5, 7].According to Cutler and Norris [4], lexical segmentation in languages with lexical stress, such as English or Dutch, is accomplished according to a Metrical Segmentation Strategy (MSS). This strategy supposes that strong syllables are used to hypothesize word boundaries. Since 90% of English words are initially stressed ([3]), using strong syllables as word onsets would be an efficient strategy.However, to be extended to other languages, the MSS has to be adapted to operate according to the metrical properties specific to each language. Thus, we cannot apply this segmentation heuristic directly to a language like French for two main reasons. First, stress (‘accent primaire’) is not lexical in French: the domain of stress is a unit larger than the word, the stress group. Second, stress is not initial in French but final: it falls on the final full syllable of the last word (more often a lexical word) in the stress group. This syllable is usually marked by a final lengthening, fundamental frequency (f0) variations, and an increase in intensity [5].Thus, any application of the MSS to French should consider: (1) stressed syllables as cues to final boundaries, rather than initial ones; and (2) the segmented units as phrases that may contain several words (2.3-2.6 words in average [e.g. 7]). Thus, simply taking stressed syllables to hypothesize word boundaries in French, would not be as efficient as in lexical-stressed languages like English. Moreover, one would need to account for the additional segmentation of the words within the stress groups.The apparent complexity of applying MSS to French does not, however, exclude that French listeners use prosodic information to segment words in certain cases. Indeed, previous studies (e.g. [1]) have shown that French listeners exploit the presence of final lengthening to segment ambiguous one word/two words sequences (e.g. "bord#dur" vs. "bordure"). Banel et al. ([2]) also showed that final lengthening facilitates “lexical” segmentation in the acquisition of an artificial language. Indeed, French learners of a new language (constructed artificially) were more efficient in their acquisition when the language had word final lengthening rather than isochronous syllables.The present paper is based on this work and uses the same experimental paradigm: the acquisition of an artificial language. Our main objective is to examine further the contribution of different prosodic information. Indeed, since prosodic marking is multi-parametric, several cues may contribute to segmentation. Stress (‘accent primaire’) in French is marked by final lengthening, as mentioned above, and, in sentence medial position, by a f0 rise (continuation rise). Our objective here is to investigate the relative contribution of durational and/or intonational boundary cues to the segmentation of continuous speech into “lexical” units.Another objective is to determine whether prosody may affect the construction of the memory representation of the segmented unit. Such a process is clearly required in language acquisition for new words to be learned. In French, since stress is not lexical, it is unclear what prosodic information, if any, is stored in the lexicon, and how this information can be described.2. MethodThe contribution of prosodic cues to speech segmentation and storage was tested with an artificial "mini-language" acquisition paradigm. The use of a language constructed artificially allows us (1) to manipulate the prosodic properties of the "words", (2) to eliminate semantic and lexical information, and (3) to control the subject's exposure to this language.Our "mini-language" (taken from [2]) consists of 8 "words" (4 bisyllabic / 4 trisyllabic) built by concatenation of 18 CVC syllables, not appearing in French but respecting its phonotactic rules (e.g. /5K<U[P/; /XQDFC\PWN/; D# H M'O ). The experiment was divided into two phases: a learning and a test phase.2.1. Learning PhaseParticipants heard a 12 min. continuous speech sequence consisting of concatenated "words" of the mini-language (e.g. /5K<U[PXQDFC\PWND# H M'O ). Each "word" appeared 100 times in the sequence in a semi-randomized order. Participants had to locate and extract words from the speech input. The participant's storage of the "words" making up the mini-language was tested as follow.2.2. Test phaseIn a non-speeded lexical discrimination task, participants had to specify which member of a stimulus pair corresponds to a "word" of the mini-language. Pairs of Word-NonWord and NonWord-NonWords, were constructed with four types of Non-Words sharing different characteristics with the words. Only the analyses conducted on Word-NonWord pairs will be presented here, with no distinction between the NonWord types. In the 80 pairs tested, each word appeared four times.2.3. Experimental conditionsFour prosodic versions of the language (see Table 1) were constructed by re-synthesis with Praat. Version D corresponded to the French prosodic pattern of continuation: the final syllable of each word was lengthened by 30% of its intrinsic duration and carried a f0 rise (110 to 140 Hz). The relative contribution of the two prosodic cues was tested with versions B and C: version B has only final lengthening and version C, only a final f0 rise. These three prosodically specified versions were compared to a neutral version (A) constructed without final f0 rise (flat f0 contour) and final lengthening.ProsodicallyunspecifiedFinal F0 riseFinal lengtheningspecifiedA B C D--+ +-+ -+Table 1: Four versions of the language varying in the presence of prosodic information.108 Swiss French participants were split into 9 groups of 12 participants each: 5 Test groups and 4 Control groups. The former were tested after being exposed to the language during the learning phase, and the latter received the test phase without a prior learning phase. Four Test groups, subgroups AA, BB, CC, and DD were tested on words containing the same prosodic information as those learned in the learning phase (e.g. AA: prosodically unspecified in both test and learning phase). These Test subgroups were matched with 4 Control subgroups on the prosodic characteristics of the words in the test phase (ØA, ØB, ØC, ØD respectively). Finally, an additional Test subgroup (DA) was used to control for a bias toward an “acoustical form” identification strategy, and to test our hypothesis on storage. In this subgroup, participants were exposed to the version of the language containing both prosodic information sources manipulated (D) and were tested on a neutral version of the words (A).3. ResultsThe contribution of prosodic information to the acquisition of the mini-language was tested by comparing the performance of participants exposed to the language in a learning phase (Test groups) to that of participants not exposed to the language (Control groups). Figure 1 shows the percent of words correctly identified by Test (grey bars) and Control groups (white bars) for the 4 versions of the language (A, B, C, D). Overall the Test group performed significantly better than the Control group (+30%). This suggests that participants in the Test groups have at least partially "learned" the language. However, this increase in performance was larger for participants exposed to prosodically specified versions (B:+34%, C:+39%, D:+37%) compared to participants exposed to the neutral version (A:+13%). T-tests on recognition scores in Control vs. Test groups showed a significant effect of learning both by item and by subject in the threeprosodically specified versions of the language, but only by subject in version A (see table 2a). Furthermore, half (6/12) of the participants exposed to this neutral version (A) of the language performed at chance level according to a binomial test (p<.05), while none did in version D and one in version B and C. In sum, the presence of prosodic information appears to have facilitated the acquisition of the language.Figure 1: % correct identification in Test (grey) and Control (white) groups depending on prosodicconditions. a. T-test: Comparison Test vs. Control Groups by subjects t(22) by item t(14) A 3.79 (p=.001) 1.58 (p=.14) B 7.54 (p<.0001) 7.57 (p<.0001) C 11.16 (p<.0001) 7.54 (p<.0001) D 10.81 (p<.0001) 8.60 (p<.0001) b. T-test: Comparison between prosodic conditions by subjects t(22) by item t(14) BB vs. CC - 2.21(p=.04) - 1.71 (p=.11) BB vs. DD -0.84 (p=.41) -0.79 (p=.44) CC vs. DD 1.18 (p=.25) 1.01 (p=.33) DD vs. DA 0.14 (p=.89) 0.15 (p=.89)Table 2: Summary of statistical resultsThe relative contribution of the different prosodic cues to language acquisition is shown by the comparison of the performance in version B, C and D (Fig. 1, grey bars). Surprisingly, better scores were found for participants exposed to a language with only final f0 rise (C: 90%) than with only final lengthening (B: 82%). However this difference was only significant by subject when the scores are compared between prosodic conditions (see table 2b). Interestingly, performances in the version in which both intonational and durational cues are present were not significantly higher (D: 85%), suggesting that the use of each type of prosodic cues is not cumulative.The final analysis aims at testing whether learners did actually construct an abstract mental representation of the words of the artificial language or whether they only stored “acoustical forms ”. In the latter case, participants in the test phase would only recognize forms that are acoustically identical (i.e. prosodically similar) to the one stored (condition DD). In the former case, participants should be able to recognize words learned with some prosodic information even if this information is not present in the test stimuli (conditionDA). A comparison of the performance in the subgroups DA vs. DD shows similar identification rates (85% for both). Thus, words learned in a version of the language with prosodic information (D) appear to be learned equally well whether tested with or without these prosodic cues.4. Discussion and conclusionResults show that prosodic information facilitates participants ’ acquisition of a new mini-language. In version A, participants could only rely on phonotactics and distributional characteristics of the language to isolate the words presented in the artificial language. Their poor performance in the test phase shows that this information was not sufficient on its own to segment the speech chain. In contrast, the presence of prosodic information located on the final syllable of the words, in version B, C, and D, appears to have facilitated the acquisition of the language. Indeed, participants performed relatively well in the test phase. Since prosodic information is multi-parametric in French, it is interesting to weight the relative contribution of the different prosodic cues in this process. Participants ’ performance in subgroup BB are comparable to that of Banel et al. ([2]) who found 85% correct identification when the artificial language followed the iambic French pattern (short-short-long). Therefore the effect of final lengthening on segmentation was replicated. However, an unexpected result was that when only one cue was present (f0 rise or final lengthening), the intonational cue induces slightly more accurate responses. Even if this effect is only significant by subject, it goes against Rietveld [14] who found that lengthening was a better cue to the segmentation of ambiguous French sentences than f0. One possible interpretation of our finding relates to the fact that the f0 rises at the end of each word in the speech sequence presented in the learning phase corresponded to the intonational contour of a list. The recurrence of these continuation rises every 2 or 3 syllables (recall that words are bi- or tri-syllabic) may have favored the lexical segmentation process. Indeed, the listeners may have hypothesized that they were listening to a list of items rather than sentences. Thus, the real weigth of the f0 variations has to be investigated further in other prosodic contexts which do not favour one segmentation over another.The main question addressed in our study is how prosody has contributed to the acquisition of the artificial language. We assume that when learners are presented with a new language in a continuous sequence, they first have to segment the speech stream to isolate units, and then construct a mental representation of these units in their lexicon. Regarding the segmentation process, prosodic information can guide listener ’s attention to specific part of the signal such as the word-final salient syllables of our mini-language ([13]). Therefore, the knowing of the position of stress can have helped listener to divide continuous speech into separate words. Indeed, even if final stress20406080100TestControlAABBCCDD DAøA øBøCøDøAis not lexical in French, French listeners have been shown here to apply a segmentation strategy based on prosodic cues, such as MSS, in the acquisition of a new language. This could suggest that prosody is exploited pre-lexically and is used bottom-up, while lexical information should be constructed from the signal via contact with a higher level of representation. However, further studies are needed to evaluate the contribution of intonational and durational variations in natural language when phrase boundaries do not correspond to word boundaries.Regarding the construction of the lexicon, it is doubtful that final f0 rise and lengthening as such are stored in lexical entries in French. Even if final syllables of lexical words are known to be “stressable”([6]), we have already said that stress assignment in French is post lexical. The results we found by comparing performance of the DD and DA subgroups have shown that learners of a language containing prosodic information, are able to recognize the learned words when presented with a different prosodic contour. It is thus probable that the prosodic specifications of these words (here final f0 rise and final lengthening) were not stored in the lexicon, and prosody was only used to segment the chain. However, since several studies have shown that performance was better when the phonological properties of the artificial language matched those of the native one ([16]), we can hypothesize that some prosodic information is present in the mental representations. For e.g., we can not reject the possibility that the mental representation of the words contains some prosodic features. These features could be unspecified, allowing the matching of various surface forms with the underlying representation. This discussion raises the question of what is meant by “stressable” syllables in French words, and how this information is represented in the lexicon.5. References[1] Banel, M. H.; Bacri, N., 1994. On metrical patternsand lexical parsing in French. SpeechCommunication, 15, 115-126.[2] Banel, M. H.; Frauenfelder, U. H.; Perruchet, P,.1998. Contribution des indices métriques àl'apprentissage d'un langage artificiel. XXIIèmeJournées d'Etudes sur la Parole.Martigny,Switzerland.[3] Cutler, A.; Carter, D. M., 1987. The predominanceof strong initial syllables in the English vocabulary. Computer speech and Language, 2,133-142.[4] Cutler, A.; Norris, D., 1988. The role of strongsyllables in segmentation for lexical access.Journal of Experimental Psychology: Human Perception and Performance, 14, 113-121.[5] Di Cristo, A., 1999. Intonation in French In Hirst,D. and DiCirsto, A. Eds., Intonation systems: asurvey of twenty languages. Cambridge, Cambridge University Press. [6] Garde, P., 1968. L'accent. Paris, PUF.[7] Jun, S-A; Fougeron, C., 2000. A phonologicalmodel of French intonation. In Botinis, A. ed.Intonation: Analysis, Modeling and technology,209-242. Dordrecht, Kluwer Academic Publ.[8] Jusczyk, P. W., 1997. The discovery of spokenlanguage. Cambridge, MIT Press.[9] Lehiste, I., 1972. The timing of utterances andlinguistic boundaries. Journal of the AcousticalSociety of America, 51(6), 2018-2024.[10] Mattys, S. L.; Jusczyk, P. W.; Luce, P. A.;Morgan, J. L., 1999. Phonotactic and prosodiceffects on word segmentation in infants. CognitivePsychology, 38(4), 465-494.[11] McQueen, J. M., 1998. Segmentation ofcontinuous speech using phonotactics. Journal ofMemory & Language, 39, 21-46.[12] Nakatani, L. H.; Dukes, K. D., 1977. Locus ofSegmental Cues to Word Juncture. Journal of Acoustical Society of America, 62, 714-719.[13] Pitt, M.; Samuel, A., 1990. The use of rhythm inattending to speech, Journal of Experimental Psychology: HPP, 16(3), 564-573.[14] Rietveld, A.C., 1980. Word boundaries in theFrench language. Language and Speech, 23(3),289-296.[15] Saffran, J. R.; Newport, E. L.; Aslin, R.N., 1996.Word segmentation: The role of distributional cues. Journal of Memory and Language, 35(4),606-621.[16] Vroomen, J.; Tuomainen, J.; deGelder, B., 1998.The roles of word stress and vowel harmony inspeech segmentation. Journal of Memory and Language, 38(2), 133-149.6. AknowledgmentsThis research was supported by a grant from the Fonds National Suisse de la Recherche Scientifique (FNRS 1114-059532.99). We especially thank Marie Hélène Banel for sharing her corpus and all the participants tested.。