Formal Synthesis and Code Generation of Real-Time Embedded Software using Time-Extended Qua
CCF推荐的国际学术会议和期刊目录修订版发布
CCF推荐的国际学术会议和期刊目录修订版发布CCF(China Computer Federation中国计算机学会)于2010年8月发布了第一版推荐的国际学术会议和期刊目录,一年来,经过业内专家的反馈和修订,于日前推出了修订版,现将修订版予以发布。
本次修订对上一版内容进行了充实,一些会议和期刊的分类排行进行了调整,目录包括:计算机科学理论、计算机体系结构与高性能计算、计算机图形学与多媒体、计算机网络、交叉学科、人工智能与模式识别、软件工程/系统软件/程序设计语言、数据库/数据挖掘/内容检索、网络与信息安全、综合刊物等方向的国际学术会议及期刊目录,供国内高校和科研单位作为学术评价的参考依据。
目录中,刊物和会议分为A、B、C三档。
A类表示国际上极少数的顶级刊物和会议,鼓励我国学者去突破;B类是指国际上著名和非常重要的会议、刊物,代表该领域的较高水平,鼓励国内同行投稿;C类指国际上重要、为国际学术界所认可的会议和刊物。
这些分类目录每年将学术界的反馈和意见,进行修订,并逐步增加研究方向。
中国计算机学会推荐国际学术刊物(网络/信息安全)一、 A类序号刊物简称刊物全称出版社网址1. TIFS IEEE Transactions on Information Forensics andSecurity IEEE /organizations/society/sp/tifs.html2. TDSC IEEE Transactions on Dependable and Secure ComputingIEEE /tdsc/3. TISSEC ACM Transactions on Information and SystemSecurity ACM /二、 B类序号刊物简称刊物全称出版社网址1. Journal of Cryptology Springer /jofc/jofc.html2. Journal of Computer SecurityIOS Press /jcs/3. IEEE Security & Privacy IEEE/security/4. Computers &Security Elsevier http://www.elsevier.nl/inca/publications/store/4/0/5/8/7/7/5. JISecJournal of Internet Security NahumGoldmann. /JiSec/index.asp6. Designs, Codes andCryptography Springer /east/home/math/numbers?SGWID=5 -10048-70-35730330-07. IET Information Security IET /IET-IFS8. EURASIP Journal on InformationSecurity Hindawi /journals/is三、C类序号刊物简称刊物全称出版社网址1. CISDA Computational Intelligence for Security and DefenseApplications IEEE /2. CLSR Computer Law and SecurityReports Elsevier /science/journal/026736493. Information Management & Computer Security MCB UniversityPress /info/journals/imcs/imcs.jsp4. Information Security TechnicalReport Elsevier /locate/istr中国计算机学会推荐国际学术会议(网络/信息安全方向)一、A类序号会议简称会议全称出版社网址1. S&PIEEE Symposium on Security and Privacy IEEE /TC/SP-Index.html2. CCSACM Conference on Computer and Communications Security ACM /sigs/sigsac/ccs/3. CRYPTO International Cryptology Conference Springer-Verlag /conferences/二、B类序号会议简称会议全称出版社网址1. SecurityUSENIX Security Symposium USENIX /events/2. NDSSISOC Network and Distributed System Security Symposium Internet Society /isoc/conferences/ndss/3. EurocryptAnnual International Conference on the Theory and Applications of Cryptographic Techniques Springer /conferences/eurocrypt2009/4. IH Workshop on Information Hiding Springer-Verlag /~rja14/ihws.html5. ESORICSEuropean Symposium on Research in Computer Security Springer-Verlag as.fr/%7Eesorics/6. RAIDInternational Symposium on Recent Advances in Intrusion Detection Springer-Verlag /7. ACSACAnnual Computer Security Applications ConferenceIEEE /8. DSNThe International Conference on Dependable Systems and Networks IEEE/IFIP /9. CSFWIEEE Computer Security Foundations Workshop /CSFWweb/10. TCC Theory of Cryptography Conference Springer-Verlag /~tcc08/11. ASIACRYPT Annual International Conference on the Theory and Application of Cryptology and Information Security Springer-Verlag /conferences/ 12. PKC International Workshop on Practice and Theory in Public Key Cryptography Springer-Verlag /workshops/pkc2008/三、 C类序号会议简称会议全称出版社网址1. SecureCommInternational Conference on Security and Privacy in Communication Networks ACM /2. ASIACCSACM Symposium on Information, Computer and Communications Security ACM .tw/asiaccs/3. ACNSApplied Cryptography and Network Security Springer-Verlag /acns_home/4. NSPWNew Security Paradigms Workshop ACM /current/5. FC Financial Cryptography Springer-Verlag http://fc08.ifca.ai/6. SACACM Symposium on Applied Computing ACM /conferences/sac/ 7. ICICS International Conference on Information and Communications Security Springer /ICICS06/8. ISC Information Security Conference Springer /9. ICISCInternational Conference on Information Security and Cryptology Springer /10. FSE Fast Software Encryption Springer http://fse2008.epfl.ch/11. WiSe ACM Workshop on Wireless Security ACM /~adrian/wise2004/12. SASN ACM Workshop on Security of Ad-Hoc and Sensor Networks ACM /~szhu/SASN2006/13. WORM ACM Workshop on Rapid Malcode ACM /~farnam/worm2006.html14. DRM ACM Workshop on Digital Rights Management ACM /~drm2007/15. SEC IFIP International Information Security Conference Springer http://sec2008.dti.unimi.it/16. IWIAIEEE International Information Assurance Workshop IEEE /17. IAWIEEE SMC Information Assurance Workshop IEEE /workshop18. SACMATACM Symposium on Access Control Models and Technologies ACM /19. CHESWorkshop on Cryptographic Hardware and Embedded Systems Springer /20. CT-RSA RSA Conference, Cryptographers' Track Springer /21. DIMVA SIG SIDAR Conference on Detection of Intrusions and Malware and Vulnerability Assessment IEEE /dimva200622. SRUTI Steps to Reducing Unwanted Traffic on the Internet USENIX /events/23. HotSecUSENIX Workshop on Hot Topics in Security USENIX /events/ 24. HotBots USENIX Workshop on Hot Topics in Understanding Botnets USENIX /event/hotbots07/tech/25. ACM MM&SEC ACM Multimedia and Security Workshop ACM。
FPGA开发专业词汇对照表
Electrical Idle 电路空闲 Error Correction Coding (ECC) 纠错代码 Error Message 错误信息
专业词汇对照表
Ethernet 以太网 External Memory Interfaces 外部存储器接 口 (IP)
F
Fast Passive Parallel (FPP) 快速被动并行配 置(FPP) Fitter 布局布线器 Filtered Luma Adaptive Algorithm 亮度滤波 自适应算法 Functional Blocks 功能模块
N
Nios II IDE Nios II 集成开发环境
O
offset 偏置/偏移量 On-Chip Debug On-Chip 调试 on-chip memory 片内存储器
P
Pad Placement 垫布局 Parallel Flash Loader 并行 Flash 加载 Parallel Synthesis 并行综合 part per million (ppm) 百万分率 Passive Serial (PS) 被动串行配置(PS) patch 补丁 PCI Express-to-DDR2 reference design PCI
B
Base Address Register 基址寄存器 (BAR) Biasing Circuitry 偏置电路 block diagram 结构框图 Board Design and Layout 板级设计及布板 Board Test, Design and Layout 板级测试,设 计及布板 Boot Copier 引导复制程序 boundary-scan description language (BSDL) 边界扫描描述语言 burst length 突发长度 burst transfers 突发传输
计算机国际顶级会议列表及其影响因子
服务计算技术与系统教育部重点实验室整理推荐的会议列表(软件工程、系统软件、程序设计会议缩写会议全称CCF推荐等级影响因子FSEACM Conference on the Foundations of SoftwareEngineeringAPOPLACM SIGPLAN - SIGACT Symposium on Principlesof Programming LanguagesA 54.44 PLDIACM SIGPLAN Symposium on ProgrammingLanguage Design & ImplementationA 36.15 SOSP ACM Symposium on Operating Systems Principles A 51.54 ICSE International Conference on Software Engineering A 16.06 OOPSLAOO Programming Systems, Languages andApplicationsA 9.55 OSDIUSENIX Symposium on Operating Systems Designand ImplementationsA 66.23 PEPMACM SIGPLAN Symposium on Partial Evaluation andSemantics Based Programming ManipulationB 11.1 ECOOP European Conference on Object-Oriented B 33.39ProgrammingESEC European Software Engineering Conference B 14.64 FM Formal Methods, World Congress B 10.56 IEEE International Requirement EngineeringREB 13.4ConferenceLICS IEEE Symposium on Logic in Computer Science B 27.42International Computer Software and ApplicationsB 3.41 COMPSACConferenceInternational Conference on Automated SoftwareASEB 9.65EngineeringCC International Conference on Compiler Construction B 13.4 International Conference on ComputationalCOLINGB 9.36LinguisticsCONCUR International Conference on Concurrency Theory B 19.97 International Conference on Model DrivenB 4.29 MoDELSEngineering Languages and SystemsICSM International. Conference on Software Maintenance B 11.98 ICSR International Conference on Software Reuse B 10.2 ICFP International Conf on Function Programming B 15 SAS International Static Analysis Symposium B 15.28 International Symposium on Software Testing andISSTAB 13.34AnalysisACM SIGPLAN-SIGSOFT Workshop on ProgramPASTEC 14.78Analysis for Software Tools and EngineeringAPSEC Asia-Pacific Software Engineering Conference C 3.48 CAV Computer Aided Verification C 30.57 ESOP European Symposium on Programming C 18.34 IEEE International Conference on Engineering ofICECCSC 4.07Complex Computer SystemsIEEE International Working Conference on SourceSCAMC 6.24Code Analysis and ManipulationInternational Conference on Advanced InformationCAiSEC 7.07Systems EngineeringEMSOFT International Conference on Embedded Software C 7.06 International Conference on Formal EngineeringICFEMC 5.88MethodsInternational Conference on Foundations of FoSSaCSC 11.31Software Science and Computation StructuresInternational Conference on Objects, Models,C 4.41 TOOLSComponents, PatternsInternational Conference on Principles and PracticeCPC 12.25of Constraint ProgrammingInternational Conference on Rewriting TechniquesC 9.55 RTAand ApplicationsInternational Conference on Tools and AlgorithmsC 21.97 TACASfor the Construction and Analysis of SystemsInternational Workshop on Model Checking ofC 22.87 SPINSoftwareLOPSTRInternational Symposium on Logic-based ProgramSynthesis and TransformationC 6.61 FATESInternational Workshop on Formal Approaches toTesting of SoftwareC 11.31 IWSSDInternational Workshop on Software Specifications& DesignC 13.57 服务计算技术与系统教育部重点实验室整理推荐的会议列表(网络与信息安全)会议缩写会议全称CCF推荐等级影响因子CCSACM Conference on Computer andCommunications SecurityA 33.99 S&P IEEE Symposium on Security and Privacy A 47.92 CRYPTO International Cryptology Conference A 51.61 ACSACAnnual Computer Security ApplicationsConferenceB 12.01ASIACRYPT Annual International Conference on the Theoryand Application of Cryptology and InformationSecurityB 20.53Annual International Conference on the TheoryEurocryptB 36.32and Applications of Cryptographic TechniquesEuropean Symposium on Research in ComputerESORICSB 13.18SecurityCSFW IEEE Computer Security Foundations Workshop B 23.59 International Symposium on Recent Advances inRAIDB 19.59Intrusion DetectionISOC Network and Distributed System SecurityNDSSB 39.56SymposiumThe International Conference on DependableDSNB 13.13Systems and NetworksTCC Theory of Cryptography Conference B 14.66 Security USENIX Security Symposium B 42.57 IH Workshop on Information Hiding B 26.15 WiSec ACM Conference on Wireless Network Security C 7.52 ACM MM&SEC ACM Multimedia and Security Workshop C 8.24 ACM Symposium on Access Control Models andSACMATC 22.32TechnologiesSAC ACM Symposium on Applied Computing C 4.33 DRM ACM Workshop on Digital Rights Management C 7.96 WORM ACM Workshop on Rapid Malcode C 30.14 ACNS Applied Cryptography and Network Security C 7.59Australasia Conference on Information SecurityACISPC 7.34and PrivacyDFRWS Digital Forensic Research Workshop C 16.13FSE Fast Software Encryption C 19.61 FC Financial Cryptography C 13.79 Conference on Detection of Intrusions andDIMVAC 8.04Malware and Vulnerability AssessmentIEEE International Information AssuranceIWIAC 7.88WorkshopIAW IEEE SMC Information Assurance Workshop C 5.05IFIP International Information SecuritySECC 3.95ConferenceISC Information Security Conference C 8.15 International Conference on Information andC 6.4 ICICSCommunications SecurityInternational Conference on Security and Privacy SecureCommC 3.84in Communication NetworksInternational Workshop on Practice and Theory inC 16.34 PKCPublic Key CryptographyNSPW New Security Paradigms Workshop C 18.7 CT-RSA RSA Conference, Cryptographers' Track C 16.5 SOUPS Symposium On Usable Privacy and Security C 6.79 Workshop on Cryptographic Hardware andC 26.19 CHESEmbedded Systems。
Combustion_synthesis
and mixtures
oxides.
has been used
Addresses Department of Inorganic and Physical Science, Bangalore012, India *e-mail: kcpatil@postoffice.iisc.ernet.in Current 2:156-l Electronic 0 Current Opinion 65 in Solid State Chemistry, Indian institute of
synthesis
Introduction
The synthesis of solids possessing desired structures, composition and properties continues to be a challenge to chemists, material scientists and engineers. Formation of solids by the ceramic method is controlled by the diffusion of atoms and ionic species through reactants and products and thus requires repeated grinding, pelletizing and calcination of reactants (oxides or carbonates) for longer durations (than soft chemical routes) at high-temperatures. Attempts have recently been made to eliminate the diffusion control problems of solid synthesis by using various innovative synthetic strategies [l]. One such approach is ‘combustion synthesis’ also known as ‘self-propagating high-temperature synthesis’ (SHS) and fire or furnaceless synthesis. The process makes use of highly exothermic redox chemical reactions between metals and nonmetals, the metathetical (exchange) reaction between reactive compounds or reactions involves redox compounds/mixtures. The term ‘combustion’ covers flaming (gas-phase), smouldering (heterogeneous) as well as explosive reactions. The combustion method has been successfully used in the preparation of a large
计算机b类刊物与会议分类信息
Neural Networks
NN
9/12
2
109.
International Journal of Knowledge-Based and Intelligent Engineering Systems
KES
月刊
110.
AIE
月刊
111.
Computational Intelligence: An International Journal
JPDC
月
0.43
33.
ACMTransactions onEmbedded Computing Systems
TECS
月
34.
IEEETransactions onSystems, Man and Cybernetics
SMC
月
A:0.98
B:1.538
C:0.885
35.
ACMTransactions onAutonomous and Adaptive Systems
月刊
0.185
4.
IEEETransactions onReliability
季
0.8
5.
ACM Transactions on information and system security
季
6.
Journal ofInformation Technology
月
1.239
7.
IEEE Transaction on Information Theory
TVLSI
月
0.771
30.
IEEETransactions onComputer-Aided Design of Integrated Circuits and Systems
Universities in Evolutionary Systems(系统变革中的大学)
Universities in Evolutionary Systems of InnovationMarianne van der Steen and Jurgen EndersThis paper criticizes the current narrow view on the role of universities in knowledge-based economies.We propose to extend the current policy framework of universities in national innovation systems(NIS)to a more dynamic one,based on evolutionary economic principles. The main reason is that this dynamic viewfits better with the practice of innovation processes. We contribute on ontological and methodological levels to the literature and policy discussions on the effectiveness of university-industry knowledge transfer and the third mission of uni-versities.We conclude with a discussion of the policy implications for the main stakeholders.1.IntroductionU niversities have always played a major role in the economic and cultural devel-opment of countries.However,their role and expected contribution has changed sub-stantially over the years.Whereas,since1945, universities in Europe were expected to con-tribute to‘basic’research,which could be freely used by society,in recent decades they are expected to contribute more substantially and directly to the competitiveness offirms and societies(Jaffe,2008).Examples are the Bayh–Dole Act(1982)in the United States and in Europe the Lisbon Agenda(2000–2010) which marked an era of a changing and more substantial role for universities.However,it seems that this‘new’role of universities is a sort of universal given one(ex post),instead of an ex ante changing one in a dynamic institutional environment.Many uni-versities are expected nowadays to stimulate a limited number of knowledge transfer activi-ties such as university spin-offs and university patenting and licensing to demonstrate that they are actively engaged in knowledge trans-fer.It is questioned in the literature if this one-size-fits-all approach improves the usefulness and the applicability of university knowledge in industry and society as a whole(e.g.,Litan et al.,2007).Moreover,the various national or regional economic systems have idiosyncratic charac-teristics that in principle pose different(chang-ing)demands towards universities.Instead of assuming that there is only one‘optimal’gov-ernance mode for universities,there may bemultiple ways of organizing the role of univer-sities in innovation processes.In addition,we assume that this can change over time.Recently,more attention in the literature hasfocused on diversity across technologies(e.g.,King,2004;Malerba,2005;Dosi et al.,2006;V an der Steen et al.,2008)and diversity offormal and informal knowledge interactionsbetween universities and industry(e.g.,Cohenet al.,1998).So far,there has been less atten-tion paid to the dynamics of the changing roleof universities in economic systems:how dothe roles of universities vary over time andwhy?Therefore,this article focuses on the onto-logical premises of the functioning of univer-sities in innovation systems from a dynamic,evolutionary perspective.In order to do so,we analyse the role of universities from theperspective of an evolutionary system ofinnovation to understand the embeddednessof universities in a dynamic(national)systemof science and innovation.The article is structured as follows.InSection2we describe the changing role ofuniversities from the static perspective of anational innovation system(NIS),whereasSection3analyses the dynamic perspective ofuniversities based on evolutionary principles.Based on this evolutionary perspective,Section4introduces the characteristics of a LearningUniversity in a dynamic innovation system,summarizing an alternative perception to thestatic view of universities in dynamic economicsystems in Section5.Finally,the concludingVolume17Number42008doi:10.1111/j.1467-8691.2008.00496.x©2008The AuthorsJournal compilation©2008Blackwell Publishingsection discusses policy recommendations for more effective policy instruments from our dynamic perspective.2.Static View of Universities in NIS 2.1The Emergence of the Role of Universities in NISFirst we start with a discussion of the literature and policy reports on national innovation system(NIS).The literature on national inno-vation systems(NIS)is a relatively new and rapidly growingfield of research and widely used by policy-makers worldwide(Fagerberg, 2003;Balzat&Hanusch,2004;Sharif,2006). The NIS approach was initiated in the late 1980s by Freeman(1987),Dosi et al.(1988)and Lundvall(1992)and followed by Nelson (1993),Edquist(1997),and many others.Balzat and Hanusch(2004,p.196)describe a NIS as‘a historically grown subsystem of the national economy in which various organizations and institutions interact with and influence one another in the carrying out of innovative activity’.It is about a systemic approach to innovation,in which the interaction between technology,institutions and organizations is central.With the introduction of the notion of a national innovation system,universities were formally on the agenda of many innovation policymakers worldwide.Clearly,the NIS demonstrated that universities and their interactions with industry matter for innova-tion processes in economic systems.Indeed, since a decade most governments acknowl-edge that interactions between university and industry add to better utilization of scienti-fic knowledge and herewith increase the innovation performance of nations.One of the central notions of the innovation system approach is that universities play an impor-tant role in the development of commercial useful knowledge(Edquist,1997;Sharif, 2006).This contrasts with the linear model innovation that dominated the thinking of science and industry policy makers during the last century.The linear innovation model perceives innovation as an industry activity that‘only’utilizes fundamental scientific knowledge of universities as an input factor for their innovative activities.The emergence of the non-linear approach led to a renewed vision on the role–and expectations–of universities in society. Some authors have referred to a new social contract between science and society(e.g., Neave,2000).The Triple Helix(e.g.,Etzkowitz &Leydesdorff,1997)and the innovation system approach(e.g.,Lundvall,1988)and more recently,the model of Open Innovation (Chesbrough,2003)demonstrated that innova-tion in a knowledge-based economy is an inter-active process involving many different innovation actors that interact in a system of overlapping organizationalfields(science, technology,government)with many interfaces.2.2Static Policy View of Universities in NIS Since the late1990s,the new role of universi-ties in NIS thinking emerged in a growing number of policy studies(e.g.,OECD,1999, 2002;European Commission,2000).The con-tributions of the NIS literature had a large impact on policy makers’perception of the role of universities in the national innovation performance(e.g.,European Commission, 2006).The NIS approach gradually replaced linear thinking about innovation by a more holistic system perspective on innovations, focusing on the interdependencies among the various agents,organizations and institutions. NIS thinking led to a structurally different view of how governments can stimulate the innovation performance of a country.The OECD report of the national innovation system (OECD,1999)clearly incorporated these new economic principles of innovation system theory.This report emphasized this new role and interfaces of universities in knowledge-based economies.This created a new policy rationale and new awareness for technology transfer policy in many countries.The NIS report(1999)was followed by more attention for the diversity of technology transfer mecha-nisms employed in university-industry rela-tions(OECD,2002)and the(need for new) emerging governance structures for the‘third mission’of universities in society,i.e.,patent-ing,licensing and spin-offs,of public research organizations(OECD,2003).The various policy studies have in common that they try to describe and compare the most important institutions,organizations, activities and interactions of public and private actors that take part in or influence the innovation performance of a country.Figure1 provides an illustration.Thefigure demon-strates the major building blocks of a NIS in a practical policy setting.It includesfirms,uni-versities and other public research organiza-tions(PROs)involved in(higher)education and training,science and technology.These organizations embody the science and tech-nology capabilities and knowledge fund of a country.The interaction is represented by the arrows which refer to interactive learn-ing and diffusion of knowledge(Lundvall,Volume17Number42008©2008The AuthorsJournal compilation©2008Blackwell Publishing1992).1The building block ‘Demand’refers to the level and quality of demand that can be a pull factor for firms to innovate.Finally,insti-tutions are represented in the building blocks ‘Framework conditions’and ‘Infrastructure’,including various laws,policies and regula-tions related to science,technology and entre-preneurship.It includes a very broad array of policy issues from intellectual property rights laws to fiscal instruments that stimulate labour mobility between universities and firms.The figure demonstrates that,in order to improve the innovation performance of a country,the NIS as a whole should be conducive for innovative activities in acountry.Since the late 1990s,the conceptual framework as represented in Figure 1serves as a dominant design for many comparative studies of national innovation systems (Polt et al.,2001;OECD,2002).The typical policy benchmark exercise is to compare a number of innovation indicators related to the role of university-industry interactions.Effective performance of universities in the NIS is judged on a number of standardized indica-tors such as the number of spin-offs,patents and licensing.Policy has especially focused on ‘getting the incentives right’to create a generic,good innovative enhancing context for firms.Moreover,policy has also influ-enced the use of specific ‘formal’transfer mechanisms,such as university patents and university spin-offs,to facilitate this collabo-ration.In this way best practice policies are identified and policy recommendations are derived:the so-called one-size-fits-all-approach.The focus is on determining the ingredients of an efficient benchmark NIS,downplaying institutional diversity and1These organizations that interact with each other sometimes co-operate and sometimes compete with each other.For instance,firms sometimes co-operate in certain pre-competitive research projects but can be competitors as well.This is often the case as well withuniversities.Figure 1.The Benchmark NIS Model Source :Bemer et al.(2001).Volume 17Number 42008©2008The AuthorsJournal compilation ©2008Blackwell Publishingvariety in the roles of universities in enhanc-ing innovation performance.The theoretical contributions to the NIS lit-erature have outlined the importance of insti-tutions and institutional change.However,a further theoretical development of the ele-ments of NIS is necessary in order to be useful for policy makers;they need better systemic NIS benchmarks,taking systematically into account the variety of‘national idiosyncrasies’. Edquist(1997)argues that most NIS contribu-tions are more focused onfirms and technol-ogy,sometimes reducing the analysis of the (national)institutions to a left-over category (Geels,2005).Following Hodgson(2000), Nelson(2002),Malerba(2005)and Groenewe-gen and V an der Steen(2006),more attention should be paid to the institutional idiosyncra-sies of the various systems and their evolution over time.This creates variety and evolving demands towards universities over time where the functioning of universities and their interactions with the other part of the NIS do evolve as well.We suggest to conceptualize the dynamics of innovation systems from an evolutionary perspective in order to develop a more subtle and dynamic vision on the role of universities in innovation systems.We emphasize our focus on‘evolutionary systems’instead of national innovation systems because for many universities,in particular some science-based disciplinaryfields such as biotechnology and nanotechnology,the national institutional environment is less relevant than the institu-tional and technical characteristics of the technological regimes,which is in fact a‘sub-system’of the national innovation system.3.Evolutionary Systems of Innovation as an Alternative Concept3.1Evolutionary Theory on Economic Change and InnovationCharles Darwin’s The Origin of Species(1859)is the foundation of modern thinking about change and evolution(Luria et al.,1981,pp. 584–7;Gould,1987).Darwin’s theory of natural selection has had the most important consequences for our perception of change. His view of evolution refers to a continuous and gradual adaptation of species to changes in the environment.The idea of‘survival of thefittest’means that the most adaptive organisms in a population will survive.This occurs through a process of‘natural selection’in which the most adaptive‘species’(organ-isms)will survive.This is a gradual process taking place in a relatively stable environment, working slowly over long periods of time necessary for the distinctive characteristics of species to show their superiority in the‘sur-vival contest’.Based on Darwin,evolutionary biology identifies three levels of aggregation.These three levels are the unit of variation,unit of selection and unit of evolution.The unit of varia-tion concerns the entity which contains the genetic information and which mutates fol-lowing specific rules,namely the genes.Genes contain the hereditary information which is preserved in the DNA.This does not alter sig-nificantly throughout the reproductive life-time of an organism.Genes are passed on from an organism to its successors.The gene pool,i.e.,the total stock of genetic structures of a species,only changes in the reproduction process as individuals die and are born.Par-ticular genes contribute to distinctive charac-teristics and behaviour of species which are more or less conducive to survival.The gene pool constitutes the mechanism to transmit the characteristics of surviving organisms from one generation to the next.The unit of selection is the expression of those genes in the entities which live and die as individual specimens,namely(individual) organisms.These organisms,in their turn,are subjected to a process of natural selection in the environment.‘Fit’organisms endowed with a relatively‘successful’gene pool,are more likely to pass them on to their progeny.As genes contain information to form and program the organisms,it can be expected that in a stable environment genes aiding survival will tend to become more prominent in succeeding genera-tions.‘Natural selection’,thus,is a gradual process selecting the‘fittest’organisms. Finally,there is the unit of evolution,or that which changes over time as the gene pool changes,namely populations.Natural selec-tion produces changes at the level of the population by‘trimming’the set of genetic structures in a population.We would like to point out two central principles of Darwinian evolution.First,its profound indeterminacy since the process of development,for instance the development of DNA,is dominated by time at which highly improbable events happen (Boulding,1991,p.12).Secondly,the process of natural selection eliminates poorly adapted variants in a compulsory manner,since indi-viduals who are‘unfit’are supposed to have no way of escaping the consequences of selection.22We acknowledge that within evolutionary think-ing,the theory of Jean Baptiste Lamarck,which acknowledges in essence that acquired characteris-tics can be transmitted(instead of hereditaryVolume17Number42008©2008The AuthorsJournal compilation©2008Blackwell PublishingThese three levels of aggregation express the differences between ‘what is changing’(genes),‘what is being selected’(organisms),and ‘what changes over time’(populations)in an evolutionary process (Luria et al.,1981,p.625).According to Nelson (see for instance Nelson,1995):‘Technical change is clearly an evolutionary process;the innovation generator keeps on producing entities superior to those earlier in existence,and adjustment forces work slowly’.Technological change and innovation processes are thus ‘evolutionary’because of its characteristics of non-optimality and of an open-ended and path-dependent process.Nelson and Winter (1982)introduced the idea of technical change as an evolutionary process in capitalist economies.Routines in firms function as the relatively durable ‘genes’.Economic competition leads to the selection of certain ‘successful’routines and these can be transferred to other firms by imitation,through buy-outs,training,labour mobility,and so on.Innovation processes involving interactions between universities and industry are central in the NIS approach.Therefore,it seems logical that evolutionary theory would be useful to grasp the role of universities in innovation pro-cesses within the NIS framework.3.2Evolutionary Underpinnings of Innovation SystemsBased on the central evolutionary notions as discussed above,we discuss in this section how the existing NIS approaches have already incor-porated notions in their NIS frameworks.Moreover,we investigate to what extent these notions can be better incorporated in an evolu-tionary innovation system to improve our understanding of universities in dynamic inno-vation processes.We focus on non-optimality,novelty,the anti-reductionist methodology,gradualism and the evolutionary metaphor.Non-optimality (and Bounded Rationality)Based on institutional diversity,the notion of optimality is absent in most NIS approaches.We cannot define an optimal system of innovation because evolutionary learning pro-cesses are important in such systems and thus are subject to continuous change.The system never achieves an equilibrium since the evolu-tionary processes are open-ended and path dependent.In Nelson’s work (e.g.,1993,1995)he has emphasized the presence of contingent out-comes of innovation processes and thus of NIS:‘At any time,there are feasible entities not present in the prevailing system that have a chance of being introduced’.This continuing existence of feasible alternative developments means that the system never reaches a state of equilibrium or finality.The process always remains dynamic and never reaches an optimum.Nelson argues further that diversity exists because technical change is an open-ended multi-path process where no best solu-tion to a technical problem can be identified ex post .As a consequence technical change can be seen as a very wasteful process in capitalist economies with many duplications and dead-ends.Institutional variety is closely linked to non-optimality.In other words,we cannot define the optimal innovation system because the evolutionary learning processes that take place in a particular system make it subject to continuous change.Therefore,comparisons between an existing system and an ideal system are not possible.Hence,in the absence of any notion of optimality,a method of comparing existing systems is necessary.According to Edquist (1997),comparisons between systems were more explicit and systematic than they had been using the NIS approaches.Novelty:Innovations CentralNovelty is already a central notion in the current NIS approaches.Learning is inter-preted in a broad way.Technological innova-tions are defined as combining existing knowledge in new ways or producing new knowledge (generation),and transforming this into economically significant products and processes (absorption).Learning is the most important process behind technological inno-vations.Learning can be formal in the form of education and searching through research and development.However,in many cases,innovations are the consequence of several kinds of learning processes involving many different kinds of economic agents.According to Lundvall (1992,p.9):‘those activities involve learning-by-doing,increasing the efficiency of production operations,learning-characteristics as in the theory of Darwin),is acknowledged to fit better with socio-economic processes of technical change and innovation (e.g.,Nelson &Winter,1982;Hodgson,2000).Therefore,our theory is based on Lamarckian evolutionary theory.However,for the purpose of this article,we will not discuss the differences between these theo-ries at greater length and limit our analysis to the fundamental evolutionary building blocks that are present in both theories.Volume 17Number 42008©2008The AuthorsJournal compilation ©2008Blackwell Publishingby-using,increasing the efficiency of the use of complex systems,and learning-by-interacting, involving users and producers in an interac-tion resulting in product innovations’.In this sense,learning is part of daily routines and activities in an economy.In his Learning Economy concept,Lundvall makes learning more explicit,emphasizing further that ‘knowledge is assumed as the most funda-mental resource and learning the most impor-tant process’(1992,p.10).Anti-reductionist Approach:Systems and Subsystems of InnovationSo far,NIS approaches are not yet clear and systematic in their analysis of the dynamics and change in innovation systems.Lundvall’s (1992)distinction between subsystem and system level based on the work of Boulding implicitly incorporates both the actor(who can undertake innovative activities)as well as the structure(institutional selection environment) in innovation processes of a nation.Moreover, most NIS approaches acknowledge that within the national system,there are different institu-tional subsystems(e.g.,sectors,regions)that all influence each other again in processes of change.However,an explicit analysis of the structured environment is still missing (Edquist,1997).In accordance with the basic principles of evolutionary theory as discussed in Section 3.1,institutional evolutionary theory has developed a very explicit systemic methodol-ogy to investigate the continuous interaction of actors and institutional structures in the evolution of economic systems.The so-called ‘methodological interactionism’can be per-ceived as a methodology that combines a structural perspective and an actor approach to understand processes of economic evolu-tion.Whereas the structural perspective emphasizes the existence of independent institutional layers and processes which deter-mine individual actions,the actor approach emphasizes the free will of individuals.The latter has been referred to as methodological individualism,as we have seen in neo-classical approaches.Methodological indi-vidualism will explain phenomena in terms of the rational individual(showingfixed prefer-ences and having one rational response to any fully specified decision problem(Hodgson, 2000)).The interactionist approach recognizes a level of analysis above the individual orfirm level.NIS approaches recognize that national differences exist in terms of national institu-tions,socio-economic factors,industries and networks,and so on.So,an explicit methodological interactionist approach,explicitly recognizing various insti-tutional layers in the system and subsystem in interaction with the learning agents,can improve our understanding of the evolution of innovation.Gradualism:Learning Processes andPath-DependencyPath-dependency in biology can be translated in an economic context in the form of(some-times very large)time lags between a technical invention,its transformation into an economic innovation,and the widespread diffusion. Clearly,in many of the empirical case studies of NIS,the historical dimension has been stressed.For instance,in the study of Denmark and Sweden,it has been shown that the natural resource base(for Denmark fertile land,and for Sweden minerals)and economic history,from the period of the Industrial Revolution onwards,has strongly influenced present specialization patterns(Edquist& Lundvall,1993,pp.269–82).Hence,history matters in processes of inno-vation as the innovation processes are influ-enced by many institutions and economic agents.In addition,they are often path-dependent as small events are reinforced and become crucially important through processes of positive feedback,in line with evolutionary processes as discussed in Section3.1.Evolutionary MetaphorFinally,most NIS approaches do not explicitly use the biological metaphor.Nevertheless, many of the approaches are based on innova-tion theories in which they do use an explicit evolutionary metaphor(e.g.,the work of Nelson).To summarize,the current(policy)NIS approaches have already implicitly incorpo-rated some evolutionary notions such as non-optimality,novelty and gradualism.However, what is missing is a more explicit analysis of the different institutional levels of the economic system and innovation subsystems (their inertia and evolution)and how they change over time in interaction with the various learning activities of economic agents. These economic agents reside at established firms,start-upfirms,universities,govern-ments,undertaking learning and innovation activities or strategic actions.The explicit use of the biological metaphor and an explicit use of the methodological interactionst approach may increase our understanding of the evolu-tion of innovation systems.Volume17Number42008©2008The AuthorsJournal compilation©2008Blackwell Publishing4.Towards a Dynamic View of Universities4.1The Logic of an Endogenous‘Learning’UniversityIf we translate the methodological interaction-ist approach to the changing role of universities in an evolutionary innovation system,it follows that universities not only respond to changes of the institutional environment(government policies,business demands or changes in scientific paradigms)but universities also influence the institutions of the selection envi-ronment by their strategic,scientific and entre-preneurial actions.Moreover,these actions influence–and are influenced by–the actions of other economic agents as well.So,instead of a one-way rational response by universities to changes(as in reductionist approach),they are intertwined in those processes of change.So, universities actually function as an endogenous source of change in the evolution of the inno-vation system.This is(on an ontological level) a fundamental different view on the role of universities in innovation systems from the existing policy NIS frameworks.In earlier empirical research,we observed that universities already effectively function endogenously in evolutionary innovation system frameworks;universities as actors (already)develop new knowledge,innovate and have their own internal capacity to change,adapt and influence the institutional development of the economic system(e.g., V an der Steen et al.,2009).Moreover,univer-sities consist of a network of various actors, i.e.,the scientists,administrators at technology transfer offices(TTO)as well as the university boards,interacting in various ways with indus-try and governments and embedded in various ways in the regional,national or inter-national environment.So,universities behave in an at least partly endogenous manner because they depend in complex and often unpredictable ways on the decision making of a substantial number of non-collusive agents.Agents at universities react in continuous interaction with the learn-ing activities offirms and governments and other universities.Furthermore,the endogenous processes of technical and institutional learning of univer-sities are entangled in the co-evolution of institutional and technical change of the evo-lutionary innovation system at large.We propose to treat the learning of universities as an inseparable endogenous variable in the inno-vation processes of the economic system.In order to structure the endogenization in the system of innovation analysis,the concept of the Learning University is introduced.In thenext subsection we discuss the main character-istics of the Learning University and Section5discusses the learning university in a dynamic,evolutionary innovation system.An evolution-ary metaphor may be helpful to make theuniversity factor more transparent in theco-evolution of technical and institutionalchange,as we try to understand how variouseconomic agents interact in learning processes.4.2Characteristics of the LearningUniversityThe evolution of the involvement of universi-ties in innovation processes is a learningprocess,because(we assume that)universitypublic agents have their‘own agenda’.V ariousincentives in the environment of universitiessuch as government regulations and technol-ogy transfer policies as well as the innovativebehaviour of economic agents,compel policymakers at universities to constantly respondby adapting and improving their strategiesand policies,whereas the university scientistsare partly steered by these strategies and partlyinfluenced by their own scientific peers andpartly by their historically grown interactionswith industry.During this process,universityboards try to be forward-looking and tobehave strategically in the knowledge thattheir actions‘influence the world’(alsoreferred to earlier as‘intentional variety’;see,for instance,Dosi et al.,1988).‘Intentional variety’presupposes that tech-nical and institutional development of univer-sities is a learning process.University agentsundertake purposeful action for change,theylearn from experience and anticipate futurestates of the selective environment.Further-more,university agents take initiatives to im-prove and develop learning paths.An exampleof these learning agents is provided in Box1.We consider technological and institutionaldevelopment of universities as a process thatinvolves many knowledge-seeking activitieswhere public and private agents’perceptionsand actions are translated into practice.3Theinstitutional changes are the result of inter-actions among economic agents defined byLundvall(1992)as interactive learning.Theseinteractions result in an evolutionary pattern3Using a theory developed in one scientific disci-pline as a metaphor in a different discipline mayresult,in a worst-case scenario,in misleading analo-gies.In the best case,however,it can be a source ofcreativity.As Hodgson(2000)pointed out,the evo-lutionary metaphor is useful for understandingprocesses of technical and institutional change,thatcan help to identify new events,characteristics andphenomena.Volume17Number42008©2008The AuthorsJournal compilation©2008Blackwell Publishing。
金属有机化学11 卡宾及烯烃复分解聚合反应
Triplet carbenes can be considered to be diradicals, and participate in stepwise radical additions
Addition of singlet carbenes to olefie than that of triplet carbenes. Addition reactions with alkenes can be used to determine whether the singlet or triplet carbene is involved.
Period Table
Organometallic compounds are normally named as substituted metals, e.g. alkyl metal or alkyl metal halide.
Group IX-VIII metal complexes are used in metathesis polymerization
Nucleophilic carbenes The metal-carbon bonds are more covalent in nature and highly polarized towards C resulting in a partial negative charge on the carbene C
Schrock Carbenes
Reactions
Lewis acid addition
Addition to carbonyls
Schrock Carbenes
Tebbe’s reagent
Tebbe’s Reagent
中国的打招呼方式英语作文
中国的打招呼方式英语作文Greetings are an integral part of every culture and society around the world. They serve as a way to initiate social interaction, establish rapport, and convey respect or familiarity. In China, the art of greeting others has evolved over thousands of years, shaped by the country's rich history, language, and social customs. Exploring the unique ways in which the Chinese people greet one another provides valuable insights into the country's cultural nuances and dynamics.One of the most prominent features of Chinese greetings is the emphasis on formality and hierarchy. In traditional Chinese culture, social status and age play a significant role in determining the appropriate greeting. Younger individuals are expected to greet their elders with more deference and respect, often using honorific titles or formal language. For instance, when greeting an older person, a common phrase would be "Ni hao, Lao shi" (Hello, Teacher), rather than simply "Ni hao" (Hello).This hierarchical approach to greetings is deeply rooted in Confucian principles, which emphasize the importance of maintaining socialorder and respecting one's superiors. In a society that values harmony and social cohesion, the way one greets others can be seen as a reflection of their character and upbringing. Failure to adhere to these social norms can be perceived as disrespectful or even rude.However, in recent years, as China has become increasingly urbanized and globalized, the traditional formality of greetings has begun to evolve. Younger generations, particularly those living in large cities, have adopted a more casual and egalitarian approach to greetings. The use of informal language, such as "Zai jian" (Goodbye) instead of the more formal "Bie zai" (Please leave), has become more widespread. This shift reflects the growing influence of Western culture and the desire of the younger Chinese population to assert their individuality and personal preferences.Despite these changes, certain traditional greeting customs remain deeply ingrained in Chinese culture. One such example is the importance of physical proximity and touch in greetings. In many Western cultures, a handshake or a hug is a common way to greet someone. In contrast, the Chinese typically avoid direct physical contact, especially between members of the opposite sex or those with significant age or status differences. Instead, a simple nod, a slight bow, or a gentle handshake is considered more appropriate.Another unique aspect of Chinese greetings is the use of auspiciousphrases and well-wishes. When greeting someone, it is common to ask about their health, their family, or their work, often using phrases that convey positive sentiments and hopes for good fortune. For instance, a common greeting is "Ni hao ma?" (How are you?), which can be followed by "Ni hao ma? Ni jiankang ma?" (How are you? Are you well?). These expressions reflect the Chinese cultural emphasis on harmony, interdependence, and the collective well-being of the community.Furthermore, the language used in Chinese greetings can be highly contextual and nuanced. The choice of words, the tone, and the body language all play a crucial role in conveying the appropriate level of respect, familiarity, and intent. For example, the phrase "Ni hao" can be used in a variety of contexts, from formal business meetings to casual encounters with friends. The subtle variations in inflection, facial expressions, and body language can significantly alter the meaning and the implied level of closeness or deference.In recent years, the globalization of Chinese culture has also led to the adoption of new greeting customs, particularly among the younger generation and in international business settings. The use of English greetings, such as "Hello," "Good morning," or "Nice to meet you," has become more prevalent, especially in interactions with foreigners or in professional contexts. This integration of global and local greeting practices reflects the dynamic and evolving nature ofChinese culture, as it adapts to the demands of a rapidly changing world.In conclusion, the unique greeting customs in China offer a fascinating glimpse into the country's rich cultural heritage and social dynamics. From the emphasis on formality and hierarchy to the use of auspicious phrases and the importance of physical proximity, the art of greeting in China is a complex and nuanced aspect of the country's social fabric. As China continues to evolve and interact with the global community, the ways in which its people greet one another will undoubtedly continue to adapt and change, reflecting the ongoing synthesis of tradition and modernity.。
天然产物(-)-石杉碱甲(Huperzine A)的人工全合成
天然产物(-)-石杉碱甲(Huperzine A)的人工全合成郭栋才;张超;雷小强;于芳【摘要】天然药物(-)-石杉碱甲被证明可以有效地抑制胆碱酯酶,可以用于治疗阿尔茨海默病(老年痴呆症)。
由于天然的(-)-石杉碱甲含量较少,所以(-)-石杉碱甲的人工全合成研究成为了近二十几年来有机合成研究的热点。
综述了关于天然产物分子(-)-石杉碱甲核心骨架近二十几年来的研究进展,介绍了各类反应的特点,为这一领域做了较为详细的归纳总结。
%Natural (-)-huperzine A has been found to be an effective inhibitor of acetylcholinesterase (AChE)and can be applied in the treatment of Alzheimer`s disease (AD).The pharmaceutical prospects and lack in natural resource have made the total synthesis of huperzine A an extremely attractive topic in the past decades.In this paper,the progress in the synthesis of the core carbonlectone of huperzine A is reviewed and various types of reactions are summarized in this area.【期刊名称】《辽宁石油化工大学学报》【年(卷),期】2015(000)002【总页数】6页(P6-11)【关键词】天然产物;(-)-石杉碱甲;全合成;小分子催化;生物活性分子【作者】郭栋才;张超;雷小强;于芳【作者单位】辽宁石油化工大学化学与材料科学学院,辽宁抚顺 113001;辽宁石油化工大学化学与材料科学学院,辽宁抚顺 113001;辽宁石油化工大学化学与材料科学学院,辽宁抚顺 113001;辽宁石油化工大学化学与材料科学学院,辽宁抚顺 113001【正文语种】中文【中图分类】TQ317天然产物[1](-)-石杉碱甲(简称石杉碱甲)是刘嘉森等于1986年从民间草药石杉科石杉属植物千层塔(蛇足石杉,Huperzia serrata)中提取分离的一种新型石松类生物碱有效单体[2]。
计算机国际会议
International Conference on Hybrid Systems: ACM, Springer / Computation and Control International Conference on Implementation and Springer Application of Automata International SPIN Workshop on Model Checking Springer Software International Conference on Verification, Model Springer Checking, and Abstract Interpretation International Symposium on Formal Methods for Springer Components and Objects International Conference on Formal Methods for Springer Open Object-based Distributed Systems ACM/IEEE International Conference on Formal IEEE Methods and Models for Co-Design / /spin08/ /vmcai08/ http://www-sop.inria.fr/oasis/FMCO/ fmco08.html http://discotec08.ifi.uio.no/FMOODS08/ /memocontest08/
69
动态
第 6 卷 第 10 期 2010 年 10 月
计算机体系结构
一、A类
序号 会议简称 1. 2. 3. ISCA MICRO HPCA 会议全称 主办 网址 International Symposium on Computer ACM SIGARCH, IEEE h t t p://w w w.a c m.o r g/p u b s/c o n t e n t s/ Architecture TCCA proceedings/series/isca/ MICRO High-Performance Computer Architecture IEEE, ACM SIGMICRO / IEEE /~hpca/
生物专业英语教学案 生物技术与生物制药
生物专业英语教学案生物技术与生物制药Title: Teaching Plan for Biotechnology and Biopharmaceuticals in Biological ScienceI. IntroductionBiotechnology and biopharmaceuticals are rapidly evolving fields within the realm of biological science. With the advancements in these fields, it is imperative to develop a comprehensive teaching plan that encompasses both theoretical knowledge and practical applications. This teaching plan aims to provide students with a solid foundation in the principles, techniques, and applications of biotechnology and biopharmaceuticals.II. ObjectivesThe objectives of this teaching plan are as follows:1. To familiarize students with the fundamentals of biotechnology and biopharmaceuticals.2. To introduce students to the various techniques and tools utilized in these fields.3. To cultivate critical thinking and problem-solving skills relevant to biotechnology and biopharmaceuticals.4. To expose students to real-world applications and industry practices.5. To enhance students' communication and collaborative skills through group projects and presentations.III. Curriculum Design1. Basic Conceptsa. Definition and scope of biotechnology and biopharmaceuticals.b. Historical development of the fields.c. Ethical considerations in biotechnology and biopharmaceutical industries.2. Principles of Biotechnologya. DNA structure and replication.b. Gene expression and regulation.c. Protein synthesis and modification.3. Techniques in Biotechnologya. DNA manipulation techniques (PCR, cloning, sequencing).b. Recombinant DNA technology.c. Immunological techniques (ELISA, Western blotting).d. Cell culture and transformation techniques.4. Biopharmaceuticalsa. Introduction to biopharmaceuticals.b. Production and purification of biopharmaceuticals.c. Types of biopharmaceuticals (recombinant proteins, monoclonal antibodies).d. Regulation and quality control in biopharmaceutical industries.5. Applications of Biotechnology and Biopharmaceuticalsa. Agricultural biotechnology (genetically modified crops, biopesticides).b. Medical biotechnology (gene therapy, personalized medicine).c. Industrial applications (biofuels, bioremediation).d. Current trends and future prospects in the field.IV. Teaching Strategies1. Lecture Sessionsa. Presenting key concepts and theories.b. Providing case studies and examples to illustrate practical applications.c. Encouraging student participation and discussion.2. Laboratory Exercisesa. Hands-on experience in DNA manipulation techniques.b. Culturing and transformation of cells.c. Protein expression and analysis techniques.d. Data analysis and interpretation.3. Group Projects and Presentationsa. Assigning group projects on selected topics.b. Encouraging independent research and critical analysis.c. Presenting findings and conclusions in a formal setting.4. Guest Lectures and Industry Visitsa. Inviting experts from biotechnology and biopharmaceutical industries.b. Organizing visits to research institutes and pharmaceutical companies.c. Providing students with exposure to real-world applications and opportunities.V. Assessment Methods1. Written Examinationsa. Assessing theoretical knowledge and understanding.b. Testing problem-solving abilities and critical thinking skills.2. Laboratory Reportsa. Evaluating practical skills and techniques.b. Analyzing experimental data and results.3. Group Project Evaluationa. Assessing research skills and teamwork abilities.b. Evaluating the quality of presentations and research findings.VI. ConclusionBy implementing this teaching plan for biotechnology and biopharmaceuticals, students will gain a well-rounded understanding of the subject matter. This comprehensive approach will equip them with the necessary knowledge and skills to succeed in the dynamic fields of biotechnology and biopharmaceuticals. Additionally, the incorporation of practical exercises, group projects, and industry exposure will further enhance their learning experience and prepare them for future career opportunities in these industries.。
数字后端版图设计
数字后端设计流程-9 布线
第二步 布线通道分配
在global route 时已经将信号线分配到每个GRC,而track assignment旳 功能就是将这些信号线在分配到每个track上,决定每条线要走旳途径。 Track assignment是以整个芯片为处理单位来作规划,尽量绕出又长又 直且via数目至少旳绕线。
Formal Verification (ECO Netlist vs
CT Inserted Netlist)
Post-layout STA
Power check
Timing OK? Yes
Tape Out
DC MODELSIM MBISTARCHITECT FORMALITY
PT
Astro AstroRail FORMALITY
数字后端设计流程-5 布局
一般来说cell面积旳拥有率控制在70%左右, 布线旳时候不会引起拥塞。
数字后端设计流程-5 时钟树和复位树综合
时钟树综合旳目旳: 低skew 低clock latency
数字后端设计流程-5 时钟树和复位树综合
芯片中旳时钟网络要驱动电路中全部旳时序单元,所以 时钟源端门单元带载诸多,其负载延时很大而且不平衡, 需要插入缓冲器减小负载和平衡延时。时钟网络及其上 旳缓冲器构成了时钟树。一般要反复几次才能够做出一 种比较理想旳时钟树。
布线工具会自动进行布线拥塞消除、优化时序、减 小耦合效应、消除串扰、降低功耗、确保信号完整性等 问题。
CCF推荐国际学术会议
CCF推荐国际学术会议类别如下计算机系统与⾼性能计算,计算机⽹络,⽹络与信息安全,软件⼯程,系统软件与程序设计语⾔,数据库、数据挖掘与内容检索,计算机科学理论,计算机图形学与多媒体,⼈⼯智能与模式识别,⼈机交互与普适计算,前沿、交叉与综合中国计算机学会推荐国际学术会议 (计算机系统与⾼性能计算)⼀、A类序号会议简称会议全称出版社⽹址1ASPLOS Architectural Support for Programming Languages andOperating SystemsACM2FAST Conference on File and Storage Technologies USENIX3HPCA High-Performance Computer Architecture IEEE4ISCA International Symposium on Computer Architecture ACM/IEEE5MICRO MICRO IEEE/ACM⼆、B类序号会议简称会议全称出版社⽹址1HOT CHIPS A Symposium on High Performance Chips IEEE2SPAA ACM Symposium on Parallelism in Algorithms andArchitecturesACM3PODC ACM Symposium on Principles of Distributed Computing ACM4CGO Code Generation and Optimization IEEE/ACM 5DAC Design Automation Conference ACM6DATE Design, Automation & Test in Europe Conference IEEE/ACM 7EuroSys EuroSys ACM8HPDC High-Performance Distributed Computing IEEE9SC International Conference for High PerformanceComputing, Networking, Storage, and AnalysisIEEE10ICCD International Conference on Computer Design IEEE 11ICCAD International Conference on Computer-Aided Design IEEE/ACM12ICDCS International Conference on Distributed ComputingSystemsIEEE13HiPEAC International Conference on High Performance andEmbedded Architectures and CompilersACM14SIGMETRICS International Conference on Measurement and Modelingof Computer SystemsACM15ICPP International Conference on Parallel Processing IEEE 16ICS International Conference on Supercomputing ACM17IPDPS International Parallel & Distributed ProcessingSymposiumIEEE18FPGA ACM/SIGDA International Symposium on Field-Programmable Gate ArraysACM19Performance International Symposium on Computer Performance,Modeling, Measurements and EvaluationACM20LISA Large Installation system Administration Conference USENIX 21MSST Mass Storage Systems and Technologies IEEE 22PACT Parallel Architectures and Compilation Techniques IEEE/ACM 23PPoPP Principles and Practice of Parallel Programming ACM24RTAS Real-Time and Embedded Technology and Applications SymposiumIEEE25USENIX ATC USENIX Annul Technical Conference USENIX26VEE Virtual Execution Environments ACM三、C类序号会议简称会议全称出版社⽹址1CF ACM International Conference on Computing Frontiers ACM2NOCS ACM/IEEE International Symposium on Networks-on-Chip ACM/IEEE3ASP-DAC Asia and South Pacific Design Automation Conference ACM/IEEE4ASAP Application-Specific Systems, Architectures, and Processors IEEE5CLUSTER Cluster Computing IEEE6CCGRID Cluster Computing and the Grid IEEE7Euro-Par European Conference on Parallel and Distributed Computing Springer 8ETS European Test Symposium IEEE9FPL Field Programmable Logic and Applications IEEE 10FCCM Field-Programmable Custom Computing Machines IEEE 11GLSVLSI Great Lakes Symposium on VLSI Systems ACM/IEEE12HPCC IEEE International Conference on High Performance Computing and CommunicationsIEEE13MASCOTS IEEE International Symposium on Modeling, Analysis, andSimulation of Computer and Telecommunication SystemsIEEE14NPC IFIP International Conference on Network and Parallel Computing Springer15ICA3PP International Conference on Algorithms and Architectures for Parallel ProcessingIEEE16CASES International Conference on Compilers, Architectures, and Synthesisfor Embedded SystemsACM17FPT International Conference on Field-Programmable Technology IEEE18CODES+ISSSInternational Conference on Hardware/Software Codesign & SystemSynthesisACM/ IEEE19HiPC International Conference on High Performance Computing IEEE/ ACM 20ICPADS International Conference on Parallel and Distributed Systems IEEE 21ISCAS International Symposium on Circuits and Systems IEEE 22ISLPED International Symposium on Low Power Electronics and Design ACM/IEEE 23ISPD International Symposium on Physical Design ACM 24ITC International Test Conference IEEE25HotInterconnectsIEEE26VTS IEEE中国计算机学会推荐国际学术会议 (计算机⽹络)⼀、A类序号会议简称会议全称出版社⽹址1MOBICOM ACM International Conference on Mobile Computing and NetworkingACM2SIGCOMM ACM International Conference on the applications,technologies, architectures, and 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成考英语作文万能开头结尾模板
成考英语作文万能开头结尾模板英文回答:Opening Paragraph:In the realm of academia, the pursuit of higher education often necessitates engagement in formal examination processes. Among these avenues, the National Adult Higher Education Entrance Examination, commonly abbreviated as the "chengkao," stands as a significant milestone for individuals seeking to further their academic endeavors. This comprehensive assessment evaluates candidates' proficiency in various disciplines, including English.In this context, it is imperative to craft a compelling essay that meets the stringent requirements of the chengkao English examination. While the essay's body paragraphs should meticulously address the specific prompt, it is equally essential to devise an effective opening paragraphthat sets the stage for the subsequent exposition.Closing Paragraph:In conclusion, the crafting of a well-structured essay for the chengkao English examination demands a nuanced synthesis of critical thinking and effective writing skills. By employing the aforementioned strategies, candidates can effectively convey their ideas, substantiate their arguments, and ultimately produce an essay that reflects their academic prowess.中文回答:开头段落:在学术领域,追求高等教育通常需要参加正式的考试程序。
不同物质的量之比乙二醛
林业工程学报,2021,6(1):86-91JournalofForestryEngineeringDOI:10.13360/j.issn.2096-1359.202004017收稿日期:2020-04-22㊀㊀㊀㊀修回日期:2020-09-28基金项目:云南省科技厅项目(2018FA014,2017HB030,2018FG001-063);国家自然科学基金(31860188)㊂作者简介:范恩庆,男,研究方向为木材胶黏剂㊂通信作者:邓书端,女,教授㊂E⁃mail:dengshuduan@163.com不同物质的量之比乙二醛⁃尿素⁃甲醛共缩聚树脂的合成与性能范恩庆,邓书端∗,曹龙,杜官本,康昆勇(西南林业大学,云南省木材胶粘剂及胶合制品重点实验室,昆明650224)摘㊀要:为了降低木材胶黏剂中的甲醛含量,减小胶合板甲醛释放对人体健康和环境造成的危害,采用乙二醛与单羟甲基脲(MMU)反应,合成了MMU与乙二醛物质的量之比分别为0.7ʒ1.0,0.9ʒ1.0,1.1ʒ1.0和1.3ʒ1.0的乙二醛⁃尿素⁃甲醛(GUF)共缩聚树脂;采用傅里叶变换红外光谱(FT⁃IR)和X射线衍射(XRD)对树脂的结构进行了表征,对树脂的基本性能㊁固化性能㊁润湿性能及胶合性能进行测定,并进行对比分析㊂结果表明,合成制备的GUF树脂稳定性较好,均超过了10d;外观均为酒红色均一液体㊂MMU与乙二醛的物质的量之比对树脂固体含量和黏度有较大影响,固体含量随着物质的量之比增大而增大,当MMU与乙二醛物质的量之比为1.3ʒ1.0时,树脂的固体含量为63.12%;当MMU与乙二醛物质的量之比为0.9ʒ1.0时,树脂黏度的最小值为23.91mPa㊃s㊂树脂的主要官能团(N H㊁O H㊁C O㊁C O C和C N)的红外吸收峰基本不受物质的量之比的影响㊂树脂对杨木单板的润湿性能良好,接触角为50.8ʎ 57.3ʎ;MMU与乙二醛的物质的量之比为1.3ʒ1.0时合成的GUF树脂性能较优,胶合板干状胶合强度和湿强度分别为1.81和1.47MPa;低物质的量之比的GUF树脂固化后会出现晶体结构㊂关键词:乙二醛;乙二醛⁃尿素⁃甲醛共缩聚树脂;原料物质的量之比;单羟甲基脲中图分类号:TQ041㊀㊀㊀㊀㊀文献标志码:A㊀㊀㊀㊀㊀开放科学(资源服务)标识码(OSID):文章编号:2096-1359(2021)01-0086-06SynthesisandperformanceofGUFresinswithdifferentmolarratiosFANEnqing,DENGShuduan∗,CAOLong,DUGuanben,KANGKunyong(YunnanKeyLaboratoryofWoodAdhesivesandGlueProducts,SouthwestForestryUniversity,Kunming650224,China)Abstract:Asthemostimportanttypeoftheso⁃calledaminoplasticresins,urea⁃formaldehyde(UF)resinsarewidelyusedaswood⁃adhesivebindersinmanufacturinginterior⁃usewood⁃basedcompositeslikeparticleboards,medium⁃den⁃sityfiberboardsandplywoodbecauseoftheirlowcost,fastcuringandgoodperformance.However,themajordraw⁃backoftoxicformaldehydeemissionfrombondedproductshashinderedtheirwidelyapplications.Withtheincreasesofpeople slivingrequirementsandtheenvironmentalawareness,themoreandmorestrictstandardregulationsofformaldehydeemissionhaveinducedconsiderableresearchfocusingnotonlyondecreasingformaldehydeemissionofUFresinsbutalsoonthedevelopmentofallkindsofalternativeresinstoUFresin.Herein,inordertoreducetheformaldehydecontentinwoodadhesivesandreducetheharmtohumanhealthandenvironmentscausedbyformalde⁃hydeemissionfromplywood,glyoxal(G)wasselectedtosubstituteformaldehydetoreactwithmonomethylol(MMU)tosynthesizeglyoxal⁃urea⁃formaldehyde(GUF)co⁃condensedresinwithdifferentMMU/Gmolarratios.TheFouriertransforminfraredspectroscopy(FT⁃IR)andX⁃raydiffraction(XRD)analysiswereusedtoexaminethestructureoftheresins.Thebasicproperties,curingproperties,wettabilityandbondingperformanceoftheresinsweremeasuredandcompared.TheresultsshowedthatthesynthesizedGUFco⁃condensedresinswithredwinecolorwereofgoodstabilitywithin10d,andthecolorbecamedarkerwiththeincreaseofMMU/Gmolarratio.TheMMU/Gmolarratiohadagreatinfluenceonthesolidcontentandviscosityoftheresins,andthesolidcontentoftheresinsincreasedwiththemolarratio.WhenMMU/Gmolarratiowas1.3ʒ1.0,thesolidcontentofGUFresinwas63.12%.Themini⁃mumviscositywas23.91mPa㊃s.Theinitialcuringtemperaturewasabout96ħwhenMMU/Gmolarratiowas0.7ʒ1.0,while104ħforotherthreemolarrations.FT⁃IRabsorptionpeaksofthemainfunctionalgroups(N H,O H,C O,C O CandC N)remainedunchangedwithdifferentMMU/Gmolarratios.Furthermore,theGUFresinhadgoodwettabilitytopoplarveneers,andthecontactanglevalueswerewithin50.8ʎ-57.3ʎwithMMU/㊀第1期范恩庆,等:不同物质的量之比乙二醛⁃尿素⁃甲醛共缩聚树脂的合成与性能Gmolarratiosof0.7ʒ1.0,0.9ʒ1.0and1.1ʒ1.0;butitwasincreasedto58.4ʎ-61.2ʎwithMMU/Gof1.3ʒ1.0,whichwasprobablyattributedtohighviscosity.TheGUFresinwiththemolarratioof1.3ʒ1.0ofMMU/Ghadbetterper⁃formanceandtheplywoodbondedwiththeresinhadbetterdrybondingstrengthandwetstrengthof1.81and1.47MPa,respectively,andthecrystalstructureappearedinthecuredGUFresinwithlowmolarratios.Keywords:glyoxal;glyoxal⁃urea⁃formaldehyde⁃co⁃condensedresin;rawmaterialmoleratio;monomethylolurea㊀㊀人造板用合成胶黏剂主要为传统醛类胶黏剂,其具有性能卓越㊁工艺流程简单以及成本低廉等优势㊂但生产和使用过程中大量的甲醛释放是传统醛类胶黏剂的致命弊端,既污染环境又危害公众健康㊂因此,寻求无毒无害㊁环境友好型木材胶黏剂已被全世界所关注,研发高性能㊁功能化和特种化的环保型胶黏剂已经成为国内人造板胶黏剂行业的一个紧迫的任务,人造板胶黏剂也将朝着无毒无害与胶接性能更优良的方向发展[1-3]㊂与甲醛相比,乙二醛具有低挥发性㊁无毒等优点㊂同时,乙二醛生产工艺成熟㊁价格低廉㊁易降解且绿色环保[4-5]㊂如果用乙二醛替代甲醛合成一种新型木材胶黏剂,可以从根源上降低胶黏剂的甲醛释放㊂国内已有部分将乙二醛应用于木材胶黏剂的研究[6-8],但大多是将乙二醛部分或全部替代甲醛合成乙二醛⁃尿素(GU)树脂或乙二醛⁃尿素⁃甲醛(GUF)共缩聚树脂,但由于乙二醛的反应活性比甲醛低,致使乙二醛系树脂的性能比甲醛系树脂稍差,且由于甲醛的存在,在所制备的树脂中仍然存在一定量的游离甲醛㊂而选用乙二醛直接与单羟甲基脲(MMU)反应制备GUF树脂:一方面可以从源头上消除树脂中的游离甲醛;另一方面,MMU是GU树脂[9-10]合成中的中间产物,其结构中含有活性基团羟甲基,既可进行加成反应又可进行缩聚反应,在一定程度上降低乙二醛的低反应活性对树脂性能的负面影响㊂鉴于此,笔者选用乙二醛与MMU反应,合成了不同物质的量之比的GUF共缩聚树脂;采用傅里叶变换红外光谱(FT⁃IR)和X射线衍射(XRD)对树脂的结构进行了表征;对树脂的基本性能㊁固化性能㊁润湿性能及胶合性能进行测定,并进行对比分析㊂旨在揭示原料物质的量之比对GUF树脂性能的影响规律,为以MMU起始制备GUF树脂的应用提供实验依据㊂1㊀材料与方法1.1㊀试验材料乙二醛(质量分数40%),分析纯,成都市科龙化工试剂厂;MMU(纯度98.0%),湖北恒景瑞化工有限公司;氯化铵(纯度99.5%),天津市致远化学试剂有限公司;木薯淀粉,工业级,广西木薯淀粉厂;杨木单板,厚度为1.5mm,含水率为8% 10%,河北文安单板厂㊂1.2㊀试验方法1.2.1㊀GUF树脂的合成将一定质量的乙二醛加入带有冷凝装置㊁搅拌器㊁温度计的三口烧瓶,并放于水浴锅中反应:常温下用质量分数30%的氢氧化钠溶液㊁质量分数30%的甲酸溶液将质量分数40%的乙二醛pH调为3.0 4.0;加入一定质量的MMU于反应装置;升温至70 80ħ,保温反应3h;冷却至40ħ以下,将pH调为7.0 8.0后出料,放置24h后检测其基本性能㊂1.2.2㊀胶合板的制备在制备好的GUF树脂中加入质量分数3%的氯化铵和质量分数10%的木薯淀粉,搅拌均匀后对准备好的杨木单板进行施胶,单面施胶量为200g/m2,制备3层杨木胶合板,注意保证单板的纹理互相垂直㊂热压压力为1.5MPa,热压时间为300s,热压温度为140ħ㊂制备的胶合板于室温下静置24h后进行性能测试㊂1.3㊀测试与表征1.3.1㊀树脂的基本性能测试树脂的状态㊁稳定性㊁黏度及固体含量均按照GB/T14074 2017‘木材工业用胶粘剂及其树脂检验方法“要求进行测定㊂1.3.2㊀差示扫描量热(DSC)分析采用DSC204F1型差示扫描量热仪(德国Netzsch)进行树脂的DSC分析:取一定质量GUF树脂于烧杯中,加入质量分数3%的氯化铵和质量分数10%的木薯淀粉,混合均匀后放置一段时间;称量铝质坩埚质量并记录;取5 10mg的树脂样品于坩埚中,记录树脂质量,将坩埚盖与坩埚压紧;将作为参比的空坩埚和样品一同放入仪器中,将称得的质量与设定参数输入程序进行扫描,扫描温度范围为20 180ħ,升温速率15K/min,N2流量为20mL/min[11]㊂1.3.3㊀FT⁃IR分析采用KBr压片法,将GUF树脂均匀涂在压好的KBr晶片上,置于NicoletiS50型红外光谱仪(美78林业工程学报第6卷国Thermo)中进行测试㊂扫描范围500 4000cm-1,分辨率4cm-1,扫描32次,室内温度22 25ħ,相对湿度ɤ60%㊂1.3.4㊀XRD分析将固化后的GUF树脂制备成粉末,置于D/max⁃TTRIVRigaku型X射线衍射仪(日本Rigaku)中进行连续扫描,扫描范围为5.0ʎ 60.0ʎ,步宽为0.02ʎ,扫描速度为2.0(ʎ)/min㊂1.3.5㊀润湿性能测定采用VCAOptimaXE型接触角测量仪(美国AST),测试不同物质的量之比GUF树脂在杨木单板上的接触角,每次滴出液体体积为2μL,滴出速度为1μL/s㊂拍摄并测定液滴接触角,结果取平均值[12]㊂1.3.6㊀胶合性能测试参照GB/T17657 2013‘人造板及饰面人造板理化性能试验方法“制备试件,使用高精度推台锯(上海费斯托设备有限公司)将样品裁制为长度为(100ʃ1)mm㊁宽度为(25ʃ1)mm的试件,选用A型试件开槽测试㊂对试件进行干状胶合强度和耐水性测试,耐水性测试将试件在(20ʃ3)ħ的冷水中浸泡24h后测量,胶合性能参照GB/T176572013进行测试㊂1.3.7㊀胶合板甲醛释放量测定胶合板的甲醛释放量严格按照国家标准GB/T17657 2013规定的干燥器法进行测定㊂2㊀结果与分析2.1㊀GUF树脂的基本性能为探究MMU与乙二醛的物质的量之比对GUF树脂性能的影响,合成了4组不同物质的量之比的GUF树脂㊂并对树脂的黏度㊁固体含量㊁树脂状态和树脂稳定性进行测定,结果见表1㊂以MMU为起始原料,与乙二醛反应制备GUF树脂,反应原料物质的量之比对树脂稳定性影响较小,各组树脂稳定性较好,均超过了10d;树脂外观均为表1㊀不同MMU/乙二醛物质的量之比的GUF树脂的基本性能Table1㊀BasicpropertiesofGUFresinwithdifferentMMU/glyoxalmolarratios序号MMU/乙二醛物质的量之比固体含量/%黏度/(mPa㊃s)GUF⁃10.7ʒ1.057.1035.01GUF⁃20.9ʒ1.060.3423.91GUF⁃31.1ʒ1.060.3434.58GUF⁃41.3ʒ1.063.1246.96酒红色均一液体,物质的量之比越高的树脂,颜色相对越深㊂物质的量之比对树脂固体含量和黏度均有明显影响,固体含量随着物质的量之比增大而逐渐增大,MMU与乙二醛物质的量之比为0.9ʒ1.0时,树脂黏度最小,为23.91mPa㊃s(表1)㊂2.2㊀GUF树脂的固化性能分析为了研究MMU起始制备GUF树脂的固化性能,对GUF树脂进行了DSC分析,不同MMU/乙二醛物质的量之比的GUF树脂的DSC曲线见图1㊂由图1可以看出,图中的吸收峰应该是GUF树脂在升温过程中,树脂中水分子及一些小分子物质蒸发㊁以及GUF树脂在发生交联固化等因素决定的㊂MMU/乙二醛物质的量之比为0.7ʒ1.0时树脂的固化起始温度在96ħ左右,峰值温度在108ħ左右,其他3组树脂的固化起始温度均在104ħ左右,峰值温度在115ħ左右,4组树脂的固化终止温度均在168ħ左右㊂物质的量之比在0.9ʒ1.0 1.3ʒ1.0范围内时,树脂的固化温度基本一致;MMU/乙二醛物质的量之比为0.7ʒ1.0时树脂的固化起始温度相比其他3组树脂低约8ħ左右,峰值温度比其他3组低约7ħ左右,说明该物质的量之比的GUF树脂发生固化反应所需的温度相对较低㊂图1㊀不同MMU/乙二醛物质的量之比GUF树脂的DSC曲线图Fig.1㊀TheDSCcurvesofGUFresinwithdifferentMMU/glyoxalmolarratios2.3㊀GUF树脂的结构分析2.3.1㊀GUF树脂的FT⁃IR分析为了研究MMU与乙二醛之间的反应和GUF树脂的主要官能团,测定了不同MMU/乙二醛物质的量之比条件下GUF树脂的FT⁃IR,并与乙二醛和MMU的FT⁃IR进行对比分析㊂乙二醛及MMU的FT⁃IR如图2所示,GUF树脂的FT⁃IR如图3所示㊂由图2a可知,谱图上3228 3563cm-1范围的宽强吸收峰为羟基中O H伸缩振动,表明乙二醛在水溶液中主要以水合物的形式存在[11];且在88㊀第1期范恩庆,等:不同物质的量之比乙二醛⁃尿素⁃甲醛共缩聚树脂的合成与性能图2㊀乙二醛及单羟甲基脲的FT⁃IR图Fig.2㊀Infraredabsorptionspectraofglyoxalandmonomethylolureaa为0.7ʒ1.0;b为0.9ʒ1.0;c为1.1ʒ1.0;d为1.3ʒ1.0㊂图3㊀不同MMU/G物质的量之比GUF树脂的FT⁃IR图Fig.3㊀FT⁃IRspectraofGUFresinswithdifferentMMU/glyoxalmolarratios2850及2720cm-1处无醛基特征峰存在,表明水图4㊀GUF树脂的XRD谱图Fig.4㊀XRDofGUFresin溶液中不存在或仅存在很少量的游离乙二醛[13];1633cm-1处为C O伸缩振动吸收峰,出现在低波数可能是因为氢键的效应使其移动;1419cm-1处出现饱和C H变形振动吸收峰,再次表明乙二醛可能与水发生了加成反应致使其结构中有饱和C H结构存在;1076cm-1处出现C O伸缩振动吸收峰㊂由图2b可知,MMU中所含有的主要基团种类较多,3428cm-1处的较弱的吸收峰为O H的伸缩振动;3338cm-1处出现的相对较强的吸收峰为N H的伸缩振动,N H的吸收峰强度比O H的吸收峰高说明MMU中氨基含量多于羟基,这也可以从MMU的分子结构中得到验证;2957及2841cm-1处分别为 NHCH2OH中C H不对称和对称伸缩振动吸收峰;C O伸缩振动出现在1651cm-1处的低波数,可能是因为羰基和氨基之间的共轭效应使其吸收移向低波数;1576cm-1处为N H变形振动;1456cm-1处为C H变形振动;1301cm-1处为C O C变形振动;1054cm-1处为C N伸缩振动的吸收峰;998cm-1处为C O伸缩振动的吸收峰㊂由图3可知,不同MMU/乙二醛物质的量之比的GUF树脂的特征基本一致,吸收峰位置和谱图形状高度相似,说明结构中所包含的主要官能团相同,即树脂的主要官能团基本不会受MMU/乙二醛物质的量之比的影响㊂与乙二醛㊁MMU的FT⁃IR进行对比分析,3414cm-1处出现一个宽而强的吸收峰,应为GUF树脂结构中N H伸缩振动和O H伸缩振动吸收峰的重合㊂因GUF树脂与MMU及乙二醛结构上的差异,GUF树脂的一些吸收峰发生了移动,如C O伸缩振动移动到1701cm-1处㊁C O C伸缩振动出现在1243cm-1处㊁C N伸缩振动出现在1055cm-1处等,表明乙二醛与MMU反应生成了GUF共缩聚树脂㊂2.3.2㊀GUF树脂的XRD分析为了解GUF树脂固化后的结晶情况,选定MMU/乙二醛物质的量之比为0.9ʒ1.0和1.3ʒ1.0的GUF树脂进行XRD分析,结果如图4所示㊂由图4可知,MMU/乙二醛物质的量之比为0.9ʒ1.098林业工程学报第6卷时,树脂出现结晶峰,而MMU/乙二醛物质的量之比为1.3ʒ1.0时树脂固化后没有发生结晶,可能是低物质的量之比导致树脂固化后出现结晶,这与传统GU树脂相似[14]㊂2.4㊀GUF树脂的润湿性能分析胶黏剂的润湿性能关系到树脂在木材表面的附着和渗透,一定程度上影响了胶黏剂的胶接机理及胶合质量[15]㊂为比较不同GUF树脂的润湿性能,对不同MMU/乙二醛物质的量之比的GUF树脂进行接触角测试,测试结果如图5所示㊂由图5可知,不同物质的量之比GUF树脂的接触角均远远小于90ʎ,表明树脂对杨木单板均具有良好的润湿性能;当MMU/乙二醛物质的量之比分别为0.7ʒ1.0,0.9ʒ1.0和1.1ʒ1.0时GUF树脂的接触角差别不大,均在50.8ʎ 57.3ʎ范围内,但当MMU/乙二醛物质的量之比为1.3ʒ1.0时GUF树脂的接触角在58.4ʎ 61.2ʎ范围,明显比其他物质的量之比GUF树脂稍大,表明MMU/乙二醛物质的量之比为1.3ʒ1.0的GUF树脂的润湿性能相对稍差,原因可能是因为此树脂的黏度与其他3组树脂相比有较大幅度提升(见表1),黏度的增加影响了树脂在杨木单板表面的扩散从而影响其润湿性能㊂树脂良好的润湿性能可保证胶合板制备过程中获得较好的施胶效果,从而使树脂的胶接性能提高[16]㊂但树脂的润湿性能需保持在一定的范围内,树脂的胶合性能不仅与树脂的润湿性有关,还与树脂在单板表面的渗透性有关,树脂的润湿性过大有可能造成透胶从而导致胶合性能下降,关于树脂润湿性能对胶合性能的影响仍需进一步深入研究㊂a)0.7ʒ1.0;b)0.9ʒ1.0;c)1.1ʒ1.0;d)1.3ʒ1.0㊂图5㊀不同物质的量之比GUF树脂的接触角Fig.5㊀ContactanglesofGUFresinwithdifferentmolarratios2.5㊀GUF树脂的胶合性能为研究原料物质的量之比对树脂胶合性能的影响,以不同原料物质的量之比的GUF树脂制备胶合板并对其物理力学性能进行测定,结果见表2㊂由表2可知,不同MMU/乙二醛物质的量之比的树脂,其干状胶合强度相差不大,均能达到国家标准GB/T9846 2015‘普通胶合板“对普通胶合板干状胶合强度的要求;MMU/乙二醛物质的量之比为1.3ʒ1.0的树脂在冷水中浸泡24h的湿强度最好,达到1.87MPa㊂表明以MMU起始制备的GUF树脂具有一定的耐冷水性能,且MMU/乙二醛物质的量之比为1.3ʒ1.0时树脂的性能较佳㊂根据前面树脂的基本性能及润湿性能分析结果,MMU/乙二醛物质的量之比为1.3ʒ1.0的树脂黏度相对较大,接触角也较大;但其胶合强度较好,原因可能是此树脂对单板既有一定的润湿性能又有合适的渗透性,从而使其胶合性能增加;而其他物质的量之比GUF树脂的黏度较低㊁润湿性较好,有可能会造成透胶而导致胶合强度下降㊂根据树脂的XRD分析结果,低物质的量之比GUF树脂固化后会出现结晶情况,结晶情况的出现也可能是低物质的量之比GUF树脂胶合性能下降的原因之一㊂表2㊀不同MMU/乙二醛物质的量之比GUF树脂胶合板的性能Table2㊀PerformanceoftheplywoodbondedusingGUFresinswithdifferentMMU/glyoxalmolarratios树脂编号MMU/乙二醛物质的量之比干状胶合强度/MPa冷水24h湿强度/MPa甲醛释放量/(mg㊃L-1)GUF⁃10.7ʒ1.01.291.050.48GUF⁃20.9ʒ1.01.480.780.87GUF⁃31.1ʒ1.01.430.971.48GUF⁃41.3ʒ1.01.811.871.89㊀㊀此外,不同物质的量之比GUF树脂胶合板均会释放一定量的甲醛,且胶合板的甲醛释放量随着MMU/乙二醛物质的量之比的增加而增加;当MMU/乙二醛物质的量之比为0.7ʒ1.0时,胶合板的甲醛释放量为0.48mg/L,小于0.5mg/L,能满足GB/T9846.3 2015‘普通胶合板通用技术条件“对E0级胶合板甲醛释放限量的要求,可直接用于室内;当MMU/乙二醛物质的量之比为0.9ʒ1.0和1.1ʒ1.0时,胶合板的甲醛释放量分别为0.87和1.48mg/L,均小于1.5mg/L,能满足GB/T9846.3 2015对E1级胶合板甲醛释放限量的要求,也可直接用于室内;当MMU/乙二醛物质的量之比为1.3ʒ1.0时,胶合板的甲醛释放量为1.89mg/L,小于5.0mg/L,能满足GB/T9846.3 2015对E2级胶合板甲醛释放限量的要求,经饰面处理后可用于室内㊂综合考虑树脂的胶合强度和甲醛09㊀第1期范恩庆,等:不同物质的量之比乙二醛⁃尿素⁃甲醛共缩聚树脂的合成与性能释放,以MMU起始制备GUF树脂,MMU/乙二醛的物质的量之比在0.7ʒ1.0 1.1ʒ1.0范围比较合适㊂3㊀结㊀论1)MMU起始制备GUF树脂,MMU/乙二醛物质的量之比对树脂固体含量和黏度均有较大影响,固体含量随着物质的量之比增大而增大㊂2)MMU起始制备GUF树脂,其固化峰值温度通常在115ħ左右;GUF树脂的润湿性良好;不同MMU/乙二醛物质的量之比的GUF树脂胶合板的干状胶合强度均能达到国家标准GB/T9846 2015对普通胶合板干状胶合强度的要求,并具有一定的耐水性㊂3)FT⁃IR分析表明GUF树脂主要含有O H㊁N H㊁C H㊁C O㊁C O C㊁C N等基团,树脂中的主要基团基本不会受到MMU/乙二醛物质的量之比的影响;XRD分析结果表明MMU起始制备GUF树脂在低物质的量之比条件下固化后会出现晶体结构,较高物质的量之比树脂固化后则不发生结晶㊂参考文献(References):[1]顾继友.我国木材胶黏剂的开发与研究进展[J].林产工业,2017,44(1):6-9,19.DOI:10.19531/j.issn1001-529901701002.GUJY.Thedevelopmentandresearchprogressofwoodadhesives[J].ChinaForestProductsIndustry,2017,44(1):6-9,19.[2]王文丽,彭晋达,赵子元,等.饰面板用三聚氰胺甲醛树脂的改性[J].林业工程学报,2020,5(2):42-47.DOI:10.13360/j.issn.2096-1359.201908018.WANGWL,PENGJD,ZHAOZY,etal.Modificationofmel⁃amineformaldehyderesinfordecorationboard[J].JournalofFor⁃estryEngineering,2020,5(2):42-47.[3]高强,刘峥,李建章.人造板用大豆蛋白胶黏剂研究进展[J].林业工程学报,2020,5(2):1-11.DOI:10.13360/j.issn.2096-1359.201906030.GAOQ,LIUZ,LIJZ.Researchprogressofsoyproteinadhesiveforwoodbasedcomposites[J].JournalofForestryEngineering,2020,5(2):1-11.[4]宋成剑,苏文强.乙二醛/尿素树脂的合成及改善瓦楞原纸抗水性能[J].纸和造纸,2010,29(3):51-55.DOI:10.13472/j.ppm.2010.03.010.SONGCJ,SUWQ.SynthesisofGUresinandimprovementofwaterresistancepropertyofcorrugatedpaper[J].PaperandPaperMaking,2010,29(3):51-55.[5]邓书端,曹龙,张俊,等.乙二醛⁃尿素⁃甲醛共缩聚树脂的结构与性能研究[J].中国胶粘剂,2018,27(1):1-6.DOI:10.13416/j.ca.2018.01.001.DENGSD,CAOL,ZHANGJ,etal.Studyonstructureandpropertiesofglyoxal⁃urea⁃formaldehydecopolycondensationresin[J].ChinaAdhesives,2018,27(1):1-6.[6]DENGSD,DUGB,LIXH,etal.Performanceandreactionmechanismofzeroformaldehyde⁃emissionurea⁃glyoxal(UG)resin[J].JournaloftheTaiwanInstituteofChemicalEngineers,2014,45(4):2029-2038.DOI:10.1016/j.jtice.2014.02.007.[7]DENGSD,PIZZIA,DUGB,etal.Synthesis,structureandcharacterizationofglyoxal⁃urea⁃formaldehydecocondensedresins[J].JournalofAppliedPolymerScience,2014,131(21):41009-41018.DOI:10.1002/app.41009.[8]邓书端,夏炎,张俊,等.反应条件对GUF树脂合成及动态热机械性能的影响研究[J].西南林业大学学报,2018,38(1):189-195.DOI:10.11929/j.issn.2095-1914.2018.01.030.DENGSD,XIAY,ZHANGJ,etal.Effectsofreactioncondi⁃tionsonsynthesisanddynamicthermo⁃mechanicalpropertiesofGUFresin[J].JournalofSouthwestForestryUniversity,2018,38(1):189-195.[9]席雪冬,吴志刚,王辉,等.高浓度甲醛制备脲醛树脂及其性能分析[J].森林与环境学报,2015,35(3):210-213.DOI:10.13324/j.cnki.jfcf.2015.03.004.XIXD,WUZG,WANGH,etal.Synthesisofurea⁃formalde⁃hyderesinbasedonhighconcentrationformaldehydeanditsprop⁃erties[J].JournalofForestandEnvironment,2015,35(3):210-213.[10]沈介发,陈代祥,马晓明,等.固化体系对脲醛树脂粘结强度的影响[J].中国胶粘剂,2018,38(1):189-195.DOI:10.13416/j.ca.2018.02.002.SHENJF,CHENDX,MAXM,etal.Influencesoncuringsystemonbondingstrengthofurea⁃formaldehyderesin[J].ChinaAdhesives,2018,38(1):189-195.[11]DAZMIRIMK,KIAMAHALLEHMV,DORIEHA,etal.EffectoftheinitialF/Umolarratioinurea⁃formaldehyderesinssynthesisanditsinfluenceontheperformanceofmediumdensityfiberboardbondedwiththem[J].InternationalJournalofAdhesionandAdhesives,2019,95:102440.DOI:10.1016/j.ijadhadh.2019.102440.[12]秦志永.酚醛树脂㊁脲醛树脂对杨木单板的润湿性研究[C]//北京粘接学会.第二十一届学术年会暨粘接技术创新与发展论坛论文集.2012:213-223.QINZY.Studyonthewettabilityofphenolicresinandureaform⁃aldehyderesintopoplarveneer[C]//Beijingadhesivesociety.Proceedingsofthe21stAnnualConferenceandForumofAdhesiveTechnologyInnovationandDevelopmentofBeijingAd⁃hesiveSociety.2012:213-223.[13]DENGSD,DUGB,LIXH,etal.Performance,reactionmechanismandcharacterizationofglyoxal⁃monomethylolurea(G⁃MMU)resin[J].Industrial&EngineeringChemistryResearch,2014,53(13):5421-5431.DOI:10.1021/ie404278d.[14]丁中建,田建国.固化时pH环境对脲醛树脂水解稳定性及结晶度的影响[J].林业科学,2017,53(12):120-125.DOI:10.11707/j.1001-7488.20171213.DINGZJ,TIANJG.InfluenceofpHconditiononthehydrolysisstabilityandcrystallinityofcuredurea⁃formaldehyderesinduringcuringprocess[J].ScientiaSilvaeSinicae,2017,53(12):120-125.[15]李坤泉.超疏水表面的构造和有机/无机杂化超疏水涂层的制备与性能研究[D].广州:华南理工大学,2015.LIKQ.Structureofsuperhydrophobicsurfaceandpreparationandpropertiesoforganic/inorganichybridsuperhydrophobiccoating[D].Guangzhou:SouthChinaUniversityofTechnology,2015.[16]王戈,揭二龙,郭起荣,等.不同胶粘剂在毛竹和杉木表面的润湿性[J].中南林学院学报,2006,26(6):155-159.DOI:10.3969/j.issn.1673-923X.2006.06.028.WANGG,JIEEL,GUOQR,etal.WetnessofvariousadhesivesonthesurfacesofmosobambooandChinesefir[J].JournalofCentralSouthForestryUniversity,2006,26(6):155-159.(责任编辑㊀李琦)19。
有机化学英文词汇
有机化学英文词汇有机化学英文词汇常见有机化学词汇Angular methyl group 角甲基Alkylidene group 亚烷基Allyl group 烯丙基Allylic 烯丙型[的]Aryl group 芳基Activating group 活化基团Auxochrome 助色团Acyl cation 酰[基]正离子Arenirm ion 芳[基]正离子Aci form 酸式Asymmetric atom 不对称原子Asymmetric carbon 不对称碳Absolute configuration 绝对构型Achiral 非手性[的]Anomer 端基[差向]异构体Anti conformation 反式构象Anti periplanar conformation 反叠构象Atropismer 阻转异构体Axial bond 直[立]键Aromaticity 芳香性Aromatic sexter 芳香六隅Antiaromaticity 反芳香性Alternant hydrocarbon 交替烃Antarafacial reaction 异面反应Ambident 两可[的]Acid-base catalyxed reaction 酸性溶剂Acid-base catalyzed reaction 酸碱催化反应Anomeric effect 端基异构效应Aromatic nucleophilic substitu-tion 芳香亲核取代Anti-Markovnikov addition 反马氏加成Addition-elimination mechanism 加成消除机理Apofacial reaction 反面反应Aryl action 芳正离子Anti-Zaitsev orientation 反札依采夫定向Anionic cleavage 负离子裂解Alkylation 烷基化Arylation 芳基化Acylation 酰化Amination 氨基化acyloxyation 酰氧基化Allylic halogenation 烯丙型卤化Additive dimerization 加成二聚Alkylolysis,alkyl cleavage 烷基裂解Acylolysis,acyl cleavage 酰基裂解Alcoholysis 醇解Aminomethylation 氨甲基化Aldol condensation 羟醛缩合Acyloin condensation 偶姻缩合Annulation,annelation 增环反应Autoxidation 自氧化Allylic hydroperoxylation 烯丙型氢过氧化Aromatization 芳构化Abstraction 夺取[反应]Aminomercuration 氨汞化Allylic migration 烯丙型重排Allylic migration 烯丙型迁移Acyl rearrangement 酰基重排Anionotropy 负离子转移Anionotropic rearrangement 负离子转移重排Aliphatic compound 脂肪族化合物Alkane 烷Alkene 烯Alkyen 炔Acetylide 炔化物Active hydrogen compounds 活泼氢化合物Allene 丙二烯Alkyl halide 卤代烷Alcohol 醇Amine 胺Amine oxide 氧化胺Aldehyde 醛Aldehyde hydrate 醛水合物Acetal 缩醛Aminal 缩醛胺Aldimine 醛亚胺Aldimine 醛肟Azine 嗪Acyl halide 酰卤Acyl fluoride 酰氟Acyl chloride 酰氯Acyl rtomide 酰溴Acyl iodide 酰碘Acyl tosylate 酰基对甲苯磺酸酐Acyl peroxide 酰基过氧化物Amide 酰胺Acyl azide 酰叠氮Amidine 脒Acyl cyanide 酰腈Allophanate 脲基甲酸酯Amino acid 氨基酸Aldol 羟醛Acyloin 偶姻Aldose 醛糖Aglycon 苷元Alditol 糖醇Alicyclic compound 脂环化合物Aromatic compound 稠环化合物Arene 芳香化合物Alkylbenzene 芳烃Aiaryl 联苄Acene 并苯Aryne 芳炔Annulene 烨烯Azulene ?Alkaloid 生物碱Azoxy compound 氧化偶氮化合物Azlactone 二氢?唑酮Azepine 氮杂?Arsine 胂Arsenic ylide 砷叶立德Azo cimpound 偶氮化物Benzyl group 苄基Benzylic 苄型[的]Bridged-ring system 桥环体系Benzylic cation 苄[基]正离子Bisecting conformation 等分构象Boat conformation 船型构象Banana bond 香蕉键Basic solvent 碱性溶剂B strain 后张力Bimolecular nucleophilic sub-stitution 双分Bimolecular nucleophilic substi-tution(withallylic rearrange-ment) 双分子亲核取代(含烯丙型重排)Bimolecular electrophilic substi-tution 双分子亲电取代Bimolecular elimination through theconjugate base 双分子共轭碱消除Bimolecular elimination 双分子消除Bimolecular elimination with for-mation of a carbonyl group 双分子羰基形成消除Bimolecular base-catalyzed acyl-oxygen cleavage双分子碱催化酰氧断裂Bimllecular base-catalyzed al-kyl-oxygen cleavage双分子碱催化烷氧断裂Borderline mechanism 边理机理Backside attack 背面进攻Briddgehead displacement 桥头取代Benzyne 苯炔Bredt rule 布雷特规则Bisamination 双氨基化Bimolecular reduction 双分子还原Benzilic rearrangement 二苯乙醇酸重排Betaine 甜菜碱Bibenzyl 烷基苯Biphenyl 联芳Biphenyl 联苯Benzvalene 盆苯Barrelene 桶烯Benzoin 苯偶姻Benzil 偶苯酰Chromophore 生色团Common ring 普通环Conjugation 共轭Conjugated-system 共轭体系Configuration 构型Chirality 手性Chiral 手性[的]Chiral center 手性中心Chiral molecule 手性分子Cahn-Ingold-Prelon sequence 顺序规则Cis-trans isomerism 顺反异构Conformation 构象Conformational 构象分析Conformational inversion 构象反转Chair conformation 椅型构象Cisoid conformation 顺向构象Conformer 构象异构体Conformational effect 构象效应Cram’srube 克拉姆规则Conformational transmission 构象传递Cross conjugation 交叉共轭Conrotatory 顺旋Cycloaddition 环加成Coordinate-covalent bond 配位共价键Conjugate base 共轭酸Conjugate base 共轭碱Counrer[gegen]ion反荷离子Carbocation 碳正离子Carbanion 碳负离子Carbenoid 卡宾体Carbene 卡宾Carbine 碳炔C-alkylation C-烷基化Carbalkoxylation 烷氧羰基化Carboamidation 氨羰基化Carboxylation 羧基化Cine substitution 移位取代Chlorosulfonation 氯磺酰化Chlorosulfenation 氯亚磺酰化Coupling reaction 偶联反应Cross-coupling reaction 交叉偶联反应Conjugate addition 共轭加成carbonylation 羧基化Cyanoethylation 氰乙基化Chiletropic reaction 螯键反应Chelation 螯环化Cyanomethylation 氰甲基化Cholromethylation 氯甲基化Condensation 缩合Cross aldol condensation 交叉羟醛缩合Cyclization 环化Catalytic hydrogenation 催化氢化Catalytic dehydrogenation 催化脱氢Cationotropic rearrangement 正离子转移重排Carbon acid 碳氢酸Ccumulene 累积多烯Cellosolve 溶纤剂Crown ether 冠醚Cyanohydrin 羟腈Carboxylic acid 羧酸Carbobenzoxy chloride 苄氧甲酰氯Carbon suboxide 二氧化三碳Carbammic acid 氨基甲酸Carbamate 氨基甲酸酯Cyanamide 氨腈Carbodiimide 碳二亚胺Carbohydrate 碳水化合物Cycloalkene 环烷Cage compound 螺烷Catenane 轮烷cyclophane 环芳Chalcone 查耳酮Chloroborane 氯硼烷carotene 胡萝卜素Charge-transfer spectrum 电荷转移光谱Chemical shift reagent 化学位移试剂Circularly polarized light 圆偏振光Cotton effect 卡滕效应Chiron,chiral building block 手性子Chiral induction 手性诱导Chiral reagent 手性试剂Chiral catalyst 手性催化剂Chiral solvent 手性溶剂Chiral auxiliary [reagent]手性助剂Convergent synthesis 汇集合成Diastereotopic 非对映异位[的]D-L system of nomenclatureD-L 命名体系Diastereomer 非对映[异构]体Delocalezed bond 离域键Diamagnetic ring cruuent 抗磁环电流Disroatatory 对旋Dielectric constant 介电常数Diaxial addition 双直键加成Deactivating group 钝化基团Demethylation 脱甲基化Decarboxylative nitration 脱羧卤化Dehalogenation 脱卤Decarboxylative nitration 脱羧硝化Nitrosation 亚硝化Desulfonation 脱磺酸基Diazotization 重氮化Diazo transfer 重氮基转移Diazonium coupling 重氮偶联Dimerization 二聚Decarbonylation 脱羰Decyanoethylation 脱氰乙基Diene synthesis 双烯合成Dienophile 亲双烯体Diels-Alder reaction 第尔斯-尔德反应Dipolar addition 偶极加成Dehydrohalogenation 脱卤化氢Deamination 脱氨基Decarboxylation 脱羧Decarboxamidation 脱酰胺Decyanation 脱氰基Dissolving metal reduction 溶解金属还原Deoxygenation 脱氧Desulfurization 脱硫Deselenization 脱硒Double bond migration 双键移位Diene 双烯Diyne 二炔Diazoalkane 重氮烷Detone 酮Dithiane 二噻烷Dewar benzene 杜瓦苯Diazo compound 重氮化合物Diazohydroxide 重氮氢氧化物Diketopiperazine 哌嗪二酮Diazine 二嗪Diterpene 二萜Diasteromeric excess,de 非对映体过量Enantiotopic 对映异位[的]Enantiomer 对映[异构]体Epimer 差向异构体Erythro configuration 赤型构型Erythro isomer 赤型异构体E isomerE 异构体Endo isomer 内型异构体Exo isomer 外型异构体Eclipsed conformation 重叠构象Envelope conformation 信封[型]构象Equatorial bond 平[伏]键Electrocyclic rearrangement 电环[化]重排Electrical effect 电场效应Electron donof-acceptor complex,EDAcomplex 电子给[体]受体络合物Eclipsing effect 重叠效应Eclipsing strain 重叠张力Electrophilic addition 亲电加成Electrophile 亲电体Electrophilic aromatic substitu-tion 亲电芳香取代Electron transfer 电子转移Electron-donating group 给电子基团Electron-Withdrawing group 吸电子基团Electrofuge 离电体Exhaustive methylation 彻底甲基化Ethylation 乙基化Endo addition 内型加成Exo addition 外型加成Ene synthesis 单烯合成elimination 消除Elimination-addition 消除-加成Esterification 酯化Ethanolysis 乙醇解Enolization 烯醇化Epoxidation 环氧化Electrochemical oxidation 电化学氧化Electrochemical reduction 电化学还原Electrophilic rearrangement 亲电重排Enyne 烯炔Ether 醚Epoxide 环氧化物Enol 烯醇Enol ether 烯醇醚Enol ester 烯醇酯Ester 酯Enantiomeric excess,ee 对映体过量Fluxional structure 循变结构Fischer projection 费歇尔投影式Field effect 场效应F strain 前张力Flash pyrolysis 闪热裂Fragmentation 碎裂Forbidden transition 禁阻跃迁Fluorene 芴fulvene 富烯Furan 呋喃Flavone 黄酮Ferocene 二铁Formal synthesis 中继合成Gauche conformation, skew con-formation 邻位交叉构象Guest 客体Glycidic acid 环氧丙酸Glycol 二醇Glycoside 糖苷Glucoside 葡[萄]糖苷Grignard reagent 格氏试剂Helical molecule 螺旋型分子Homotopic 等位[的]Heterotopic 异位[的]Half-chair conformation 半椅型构象Homolog 同系物Hyperconjugation 超共轭Huckel’rule休克尔规则Homoaromaticity 同芳香性Host 主体Hammond postulate 哈蒙德假说Homochiral 纯手性[的]Homolysis 均裂Heterolysis 异裂Heterolytic michanism 异裂机理Hofmann’srule 霍夫曼规则Hydroxylation 羟基化Hydroboration 硼氢化Hydroformylation 加氢甲酰基化Hydroacylation 加氢酰化Hydrocarboxylation 氢羧基化Homologization 同系化Hydroxymethylation 羟甲基化Hydroxyalkylation 羟烷基化Haloalkylation 卤烷基化Haloform reaction 卤仿反应Heterogeneous hydrogenation 多相氢化Homogeneous hydrogenation 均相氢化Hydrogenolysis 氢解Hydrometallation 氢金属化Homosigmatropic rearrangement 同迁移重排Hpdrocarbon 碳氢化合物Homoallylic alcohol 高烯丙醇Hydrazone 腙Hydrazide 酰肼Hydantion 乙内酰脲Helicene 螺旋烃Hydrazo compound 氢化偶氮化物Hydroquinone 氢醌Heterocyclic compound 杂环化合物Isomerism 异构[现象]Ipso position 本位Isovalent hyperconjugation 等价超共轭Inductive effect 诱导效应Imine-enamine atutomerism 亚胺-烯胺互变异构Inverse isotope effect 逆同位素效应Intermediate 中间体I strain 内张力Isoinversion 等反转Isoracemization 等消旋Internal nucleophilic substiru-tion 分子内亲核取代Ion pair 离子对Internal return 内返Inversion 反转Insertion 插入imine 亚胺Isonitrile 异腈Imide 二酰亚胺Indene 茚Imidazole 咪唑Isoquinoline 异喹啉Isoflavone 异黄酮Large ring 大环Laevo isomer 左旋异构体Leois structure 路易斯结构Linear free energy 线性自由能Large angle strain 大角张力Leaving group 离去基团Lithiation 锂化Lactone 内酯Lactol 内半缩醛Lactam 内酰胺Lipid 类脂Linear synthesis 线性合成Magnetically anisotropic group 磁各向异性基团Medium rimg 中环Mirror symmetry 镜面对称Meso compound 内消旋化合物Meta position 间位Para position 对位Molecular orbiral method 分子轨道法Mesomeric effect 中介效应Mobius system 默比乌斯体系Mechanism 机理Masked carbanion 掩蔽碳负离子Markovnikov’srube 马尔科夫尼科规则Michael addition 迈克尔加成Meta directing group 间位定位基Mitallation 金属化Mercuration 汞化Migratory aptitude 迁移倾向Migration 迁移Mercaptan 硫醇Macrolide 大环内酯Monoterpene 单萜Neoman projection 纽曼投影式No-bond resonance 无键共振Non-alternant hydrocarbon 非交替烷Non-bonded interaction 非键相互作用Nonclassical carbocation 非经典碳正离子Nitrene 氮宾Nucleophilic reaction 亲核反应Nucleophilicity 亲核体Nucleofuge 离核体Neighboring group participation 邻基基参与Neighboring proup assistance,anchimeric assistance 邻助作用Neighboring group effect 邻基效应N-alkylationN-烷基化Nitration 硝化Netro compound 硝基化合物Nitrile 腈Nitrile oxide 氧化腈N-bromo compound N-溴化物Nitrogen ylide 氮叶立德Octahedral compound 八面体化合物Optical activity 光学活性Quasi recemate 准外消旋体Ortho position 邻位Orinentation 取向Ortho-para directing group 邻对位定位基Ortho effect 邻位效应O-alkylation O-烷基化Oxyamination 羟氨基化Oxo process 羰基合成Oxonolysis 臭氧解Oxidative decarboxylation 氧化脱羧Oxymercuration 羟汞化Oxime 肟Oxime 亚硝基化合物orthoester 原酸酯Oligosaccharide 寡糖Osazone 脎Oxazine 嗪Organometallic 有机金属化合物Optical purity 光学纯度Optical induction 光学诱导Spiroannulation 螺增环Prototropic rearrangement 质了转移重排Pinacol rearrangement 频哪醇重排Prototropy 质子转移Photosensitization 光敏化photooxidation 光氧化Photoisomerization 光异构化Photochemical rearrangement 光化学重排Paraffin wax 石蜡Peracid 过酸Perester 过酸酯Peptide 肽Pyranose 吡喃糖Polysaccharide 多糖Propellane 笼型化合物Pyrrole 吡咯Pyrazole 吡唑Porphyrin 卟啉Pyridene 吡啶Piperidine 哌啶Phosphine 膦Phosphonium salt 膦盐Phosphorus ylide 磷叶立德Phospholipid 磷脂Pheromone 信息素Phytohormone 植物激素Polarized light 偏振光Partial synthesis 部分合成Protecting group 保护基Phenyl group 苯基Quinhydrone 醌Quinhydrone 醌氢醌Quinoline 喹啉Radical ion 自由基离子Radical cation 自由基正离子Radical anion 自由基负离子R-S syytem of nomenclatureR-S 命名体系Racemic mixture 外消旋混合物Racemic compound 外消旋化合物Racemic solid solution 外消旋固体溶液Rotamer 旋转异构体Retention of configuration 构型保持Regioselectivity 区域选择性Regiospecificity 区域专一性Resonance 共振Resonance effect 共振效应Reactive intermediate 活泼中间体Restricted rotation 阻碍旋转Racemization 外消旋化Ring clsure 环合Retro Diels-Alder reaction 逆第尔斯-阿尔德反应Retrograde aldol condensation 逆羟醛缩合Reductive alkylation 还原烷基化Reductive acylation 还原酰化Reductive dimerization 还原二聚Rearrangement 重排Ring contraction 环缩小[反应]Ring expansion,ring enlargement 扩环[反应]Rotazane 螺桨烷Rused ring 索烃Retrosynthesis 逆合成Relay synthesis 接替合成Spiro compound 螺环化合物Stereochemistry 立体化学Stereoisomerism 立体异构[现象]Symmetry factor 对称因素Si faceSi 面Synperiplanar conformation 顺叠构象Synclinal conformation 反错构象Synclinal conformation 顺错构象Staggered conformation 对位交叉构象Steric effect 空间效应Steric hindrance 位阻Skew boat conformation 扭船型构象Stereocelectivity 立体选择性Stereospecificty 立体专一性Stereochemical orientation 立体[化学]取向Symmetry forbidden-reaction 对称禁阻反应Synfacial reaction 同面反应Solvent effect 溶剂效应Solvated electron 溶剂化电子Secondary isotope effect 二级同位数效应Substrate 底物Small-angle strain 小角张力Substitution 取代Silylation 硅烷[基]化Seco alkylation 断裂烷基化Sulfonation 磺化Sulfenylation 亚磺酰化Sulfonylation 磺酰化sulfurization 硫化Selenylation 硒化Saponification 皂化Single electron transfer 单电子转移Semipinacol rearrangement 半频哪醇重排Sigmatropic rearrangement-迁移重排Super acid 超酸Sulfonic acid 磺酸Sulfoxide 亚砜Sulfone 砜Semicarbazone 缩氯基脲Saccharide 糖类Spirane 环烯Sydnone 悉尼酮Sulfur ylide 硫叶立德Sesquiterpene 倍半萜Steroid 甾族化合物Sex hormone 性激素Specific rotation 比旋光Synthesis 合成Synthon 合成子Tetrahedral configuration 四面体构型Threo configuration 苏型构型Threo isomer 苏型异构体Trigonal carbon 三角型碳Torsion angle 扭转角Twist conformation 扭型构象Transoid conformation 反向构象Trigonal hybridization 三角杂化Tautomerization 互变异构化tautomerism 互变异构Thermodynamic control 热力学控制Therm odynamic acidity 热力学酸度Torsional effect 扭转效应Transannular interaction 跨环相互作用Transannular strain 跨环张力Transamination 氨基交换Trimefization 三聚Transesterification 酯交换Transacetalation 缩醛交换Transfer hydrogenation 转移氢化Transannular insertion 跨环插入Transannular rearrangement 跨环重排Triene 三烯Thioester 硫代酸酯Thiol acid 硫羰酸Triazole 三唑Triazine 三嗪Thiazole 噻唑Terpene 萜Triterpene 三萜Tandem reaction sequence 连续反应过程Topochemistry 拓扑化学Unimolecular nucleophilic 单分子亲核取代Unimolecular electrophilic sub-stitution 单分子亲电取代Unimolecular elimination 单分子消除Unimolecular elimination through the conjugate base 单分子共轭碱消除Unimolecular acid-catalyzed acyl-oxygen cleavage 单分子酸催化酰氧断裂Unimolecular acid-catalyzed alkyl-oxygen cleavage 单分子酸催化烷氧断裂Umbrella effect 伞效应Umpolung 极反转Valence bond method 价键法Vinylog 插烯物Valence tautomerism 价互变异构Walden inversion 瓦尔登反转Wax 蜡Ylide 叶立德Ynamin 炔胺Z isomer Z 异构体Zaitsev rule 札依采夫规则Zwitterions 两性离子。
数字版图流程与工具1
ASIC design flow
SDF generation,pre_layout的SDF文件,用于pre_layout timing仿真,同时还需提供时序约
束文件(SDF格式)给layout tool做布局布线。script文件如下:
active_design=tap_controller
NETLIST
verilog
Standcell
library
布局布线工具根据基本单元库的时序-几何模型,
将电路单元布局布线成为实际电路版图
LAYOUT
gds2
对功能,时序,制造参数进行检查
TAPE-OUT
Contents
1
基于标准单元的ASIC设计流程
2
数字前端设计(front-end)
3
数字后端设计(back-end)
technology =“0.6 micro csmc”;
search_path =search_path+{“.” ~/csmc06/lib” };
target_library ={csmc06core.db};
link_library ={*, csmc06core.db, csmc06pad.db};
可以布局布线的网表为
终点。
数字后端设计。以生成
可以可以送交foundry
进行流片的GDS2文件
为终点。
术语:
tape-out—提交最终
GDS2文件做加工;
Foundry—芯片代工厂,
如中芯国际。。。
RTL simulation
Logic
Synthesis,Optimization
& Scan Insertion
计算机b类刊物与会议分类信息
15.
Journal of Chinese Information Processing
16.
Computer Speech and Language
季
0.689
17.
Machine Translation
季
18.
Language Resources and Evaluation
季
0.25
CJE
月刊
0.185
4.
IEEETransactions onReliability
季
0.8
5.
ACM Transactions on information and system security
季
6.
Journal ofInformation Technology
月
1.239
7.
IEEE Transaction on Information Theory
96.
International Journal of Corpus Linguistics
97.
IEEETransactions on Biomedical Engineering
月刊
2.302
98.
Speech Communication
月刊
0.678
99.
International Journal of Computer Processing of Oriental Languages
1.119
85.
Journal of Complexity
1.422
86.
Journal of Combinatorial Optimization
东南研究生学术英语写作教程
学术英语复习question Academic feature 学术写作的特征1. Complexity 复杂性1.1. grammatical complexityacademic English will use more clauses, participle structures, and the continuous use of prepositions. 更多从句,分词结构,连续使⽤介词 clauses ,participlesFormal written English uses verbs less than spoken English. -ed and -ing participles allow verbs to be used nominally or adjectively. 正式书⾯英语使⽤动词少于⼝语, ed ing 分词允许动词在名义或形容词上使⽤1.2. nominalization 名词化 norminalization名词化现象也学术英语写作的另⼀重要特⾊。
名词化现象指的是:简单的句⼦通过名词化的过程使其成为⼀个名词短语,这样写出的句⼦具有信息量⼤,结构更加严谨、逻辑性强和句式复杂。
1.3. Lexical complexity 词汇复杂性 Lexical complexity2. Objectivity(客观性)2.1. Avoid "I" and "you"避免使⽤你我 using third person pronouns 2.2. Using passive voice 使⽤被动2.3. avoid colloquial expression 避免⼝语表达2.4. Don't use informal abbreviations 不要使⽤⾮正式简称3. explicitness 清晰性3.1. coherence 衔接性natural or reasonable connection ⾃然合理的连接connectives appropriately 合理使⽤连词 connectives appropriately3.2. acknowledgement of sources 承认来源3.3. Hedging 严谨性tentative words 犹豫不决的词 seem4. Sequential markers 顺序标记putting the more important unit of information in the main clause, while placing the less important one in the subordinate clause. Thus, the reader can focus on the more important information and understand the writer's message more easily. 将最终的单元信息放到主句中,⽽把不重要的信息放在从句中,集中于重要信息,更容易理解作者的信息学术写作就像-旧瓶⼦⾥⾯装新酒,其中瓶⼦-酒-含义解释学术写作就像-旧瓶⼦⾥⾯装新酒。
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Formal Synthesis and Code Generation of Real-Time Embedded Software usingTime-Extended Quasi-Static Scheduling 1Pao-Ann Hsiung †§,Trong-Yen Lee ‡,and Feng-Shi Su ††Department of Computer Science and Information EngineeringNationalChung Cheng University,Chiayi,Taiwan‡Department of Electronic EngineeringNationalTaipei University of Technol ogy,Taipei,Taiwan§E-mail:hpa@ AbstractThe rapid escalation in complexity of real-time embed-ded systems design has made embedded software an inte-gral system part such that formalsoftware synthesis has become an indispensable design automation technique.The current work takes one more step forward in this research direction by proposing a formal synthesis method for com-plex real-time embedded pared to previous work,our method not only synthesizes embedded software with complex interrelated branching choices for execution within a user-given memory bound,but also tries to guar-antee the satisfaction of all user-given local and global time constraints.Our proposed method called Time-Extended Quasi-Static Scheduling (TEQSS)synthesizes real-time em-bedded software code from a set of Time Complex-Choice Petri Nets .The two most important issues in real-time em-bedded software,namely memory and time constraints are both elegantly and efficiently handled by TEQSS.We show the feasibility of our method through a master-slave role switch application which is a part of the Bluetooth wireless communication protocol.Keywords :real-time embedded software,Time Complex-Choice Petri Nets,time-extended quasi-static scheduling,code generation1Introduct i onEmbedded systems must interact with humans and with other embedded systems installed in a larger system.In general,these interactions are temporally constrained,or in other words,embedded systems are also intrinsically real-1Thiswork was supported in part by a project grant NSC91-2213-E-194-008from the NationalScience Council ,Taiwan.time systems.For example,an embedded system must often react to a button-push within 0.1second,otherwise a user will push the button a second time,thinking that it is mal-functioning.On the contrary,most current methods for the automatic synthesis of embedded software do not consider temporalconstraints [15,16,20,21],which resul ts in tem-porally infeasible schedules and thus incorrect systems.To solve this problem,we are proposing a time-extension of extended quasi-static scheduling [21],by generalizing the system modeland the synthesis and code-generation meth-ods.Software now accounts for more than 70%of embed-ded system functions.Software has enhanced the acces-sibility,testability,and flexibility of embedded systems,but along with these advantages the inherent complexity of software often introduces design errors that increase maintenance costs.To ensure the correctness of software designs in an embedded system,formalmethods are be-ing adopted successfully for embedded software design [5,9,10,12,15,16,20].Temporalcorrectness of a system is often formul ated in terms of deadlines for certain jobs,that are either spo-radic or periodic.Basically,we classify time constraints into two categories:local deadlines and global deadlines.A local deadline is imposed on the execution of a partial task,whereas a global deadline is imposed on the execution of all tasks in a system model [6,14].Correspondingly,two issues arise here:(1)How can the satisfaction of a local deadline be guaranteed?(2)How can a real-time embed-ded software be synthesized to satisfy all global deadlines?Before discussing how these problems are to be solved,we will give a motivating example along with a system model.The functions that an embedded software is required to perform are generally specified as a set of communicat-ing concurrent tasks,where each task is a sequentialpro-cess.Since Petri nets(introduced later in Section3.1)are a semantically precise model for several desirable common system properties such as concurrency,branching,synchro-nization,and mutualexcl usion,previous works on software synthesis were mainly based on a subclass of the Petri net model.We also adopt the Petri net model for software re-quirements specification,but we remove restrictions from previously used models.As a motivating example,con-sider the Petri net modelfor part of an Autonomous Cruise Controller(ACC)[7]depicted in Figure1.There are two sensors in ACC,one of which periodically senses the dis-tance between a preceding vehicle and the vehicle in which ACC is installed,and another periodically senses the speed limit of the road on which the vehicle is currently moving. Based on these sense data,there is a choice of decision on whether to decelarate or accelerate the vehicle with ACC. This choice is not a free one(as in Free-Choice Petri Nets [20]),thus the software for such a system cannot be mod-eled and synthesized by previous works[12,20]which have the Free-Choice restriction imposed on the system model. Further,as can be observed from thefigure,there are also time constraints on the execution of each action such as ac-celerate or decelarate,which cannot be synthesized by pre-vious methods[12,20,21].Thus,the example shows that we need new system models and new methods for synthe-sizing embedded software with time constraints.The above-described non-free choices with time con-straints appear often in many embedded systems,thus re-moving the restriction significantly expands the domain of applications that can be modeled and synthesized.How-ever,with the enhancements in modelexpressiveness,syn-thesis becomes more complicated.We propose an Time-Extended Quasi-Static Scheduling(TEQSS)method for the synthesis of real-time embedded software that are modeled using Time Complex-Choice Petri Nets(TCCPN).Details on the TCCPN system model,our target problem,and the proposed TEQSS method will be described in Sections3.1, 3.2,and3.3,respectively.TEQSS extends previously proposed quasi-static scheduling(QSS)[20]by handling non-free choices(or complex choices)that appear in TCCPN models.Further, TEQSS also ensures that limited embedded memory con-straints and time constraints are also satisfied.For feasible schedules,real-time embedded software code is generated as a set of communicating POSIX threads,which may then be deployed for execution by a real-time operating system.An application example on a master/slave switch software driver for Bluetooth wireless communication devices will illustrate the feasibility and benefits of our proposed method.The article is organized as follows.Section2gives some previous work related to embedded software synthesis.Sec-tion3formulates,models,and solves the embedded soft-ware synthesis problem.Section4illustrates the proposed problem solution through an application example.Section5 concludes the article giving some future work.2Previous WorkDue to the importance of ensuring the correctness of em-bedded software,formal synthesis has emerged as a pre-cise and efficient method for designing software in control-dominated and real-time embedded systems[6,12,20,21]. In the past,a large number of efforts was directed towards hardware synthesis and comparatively little attention paid to software synthesis.Partialsoftware synthesis was mainl y carried out for communication protocols[19],plant con-trollers[18],and real-time schedulers[1]because they gen-erally exhibited regular behaviors.Only recently has there been some work on automatically generating software code for embedded systems[2,16,20],including commercial tools such as MetaH from Honeywell.In the following,we will briefly survey the existing works on the synthesis of real-time embedded software,on which our work is based.Lin[16]proposed an algorithm that generates a software program from a concurrent process specification through in-termediate Petri-Net representation.This approach is based on the assumption that the Petri-Nets are safe,i.e.,buffers can store at most one data unit,which implies that it is always schedulable.The proposed method applies quasi-static scheduling to a set of safe Petri-Nets to produce a set of corresponding state machines,which are then mapped syntactically to thefinal software code.A software synthesis method was proposed for a more generalPetri-Net framework by Sgroi et al.[20].A quasi-static scheduling algorithm was proposed for Free-Choice Petri Nets(FCPN)[20].A necessary and sufficient condi-tion was given for a FCPN to be schedulable.Schedulability wasfirst tested for a FCPN and then a valid schedule gen-erated by decomposing a FCPN into a set of Conflict-Free (CF)components which were then individually and stati-cally scheduled.Code wasfinally generated from the valid schedule.Later,Hsiung integrated quasi-static scheduling with real-time scheduling to synthesize real-time embedded soft-ware[12].A synthesis method for soft real-time systems was also proposed by Hsiung[13].The free-choice restric-tion wasfirst removed by Su and Hsiung in their work[21] on extended quasi-static scheduling.Recently,Gau and Hsiung proposed a more integrated approach called time-memory scheduling[6]based on reachability trees.Balarin et al.[2]proposed a software synthesis proce-dure for reactive embedded systems in the Codesign Fi-nite State Machine(CFSM)[3]framework with the POLIS hardware-software codesign tool[3].This work cannot be easily extended to other more general frameworks.Figure1.Time Complex-Choice Petri Net Model for an Automatic Cruise ControllerBesides synthesis of software,there are also some recent work on the verification of software in an embedded system such as the Schedule-Verify-Map method[9],the linear hy-brid automata techniques[8,10],and the mapping strategy [5].Recently,system parameters have also been taken into consideration for real-time software synthesis[11].The work presented here extends two research results: (1)Sgroi et al’s work[20]:by removing the free-choice restriction on the Petri net model,and(2)Su and Hsi-ung’s work[21]:by adding time constraints in the Petri net model.Correspondingly,the work proposes a time-extended scheduling method for the unrestricted model,and implements a code generator that produces multithreaded embedded software code in the C programming language.3Embedded Software SynthesisMotivated by the Autonomous Cruise Controller exam-ple(Fig.1),the previous work described in Section2in-cluding QSS[20],QSS with real-time scheduling[12],and extended QSS[21]are all not adequate for synthesizing real-world,time-constrained,complex embedded software, because they either simply cannot be modeled or require a great dealof work-around efforts.QSS synthesizes free-choice Petri nets,which have free-choice restriction and no time constraints.QSS with real-time scheduling synthe-sizes free-choice Petri nets with time constraints,but the free-choice restriction is still imposed.EQSS synthesizes complex-choice Petri nets,which do not have free-choice restriction,but also do not have time constraints.However, our work in this article removes the free-choice restriction as well as adds time constraints in the Petri net model.In this work,we remove the free-choice restriction and add time constraints in the system modelby proposing Time Complex-Choice Petri Nets(TCCPN)as our system ing TCCPN,software designers can model a larger domain of real-time embedded applications by allow-ing choice(branching)and concurrency to synchronize at the same transition and each transition can be associated with an execution time and a local deadline.For example, in Fig.1when the preceding vehicle’s distance is greater than a given threshold(the“yes”arc)and the current speed of the vehicle with ACC is less than a detected speed limit (the“yes”arc),then the vehicle should accelerate(choice and concurrency synchronized at the accelerate transition), between2to4time units.An embedded software is specified as a set of TCCPNs, which wil lbe defined in Section3.1.We wil lformul ate our target problem in Section3.2and describe our time-extended QSS algorithm along with code generation in Sec-tion3.3.3.1System ModelWe define TCCPN as follows,where N is the set of pos-itive integers.Definition1Time Complex-Choice Petri Nets(TCCPN)A Time Complex-Choice Petri Net is a4-tuple(P,T,F,M0,τ),where:•P is afinite set of places,•T is afinite set of transitions,P∪T=∅,and P∩T=∅,•F:(P×T)∪(T×P)→N is a weightedflow relation between places and transitions,represented by arcs, where N is a set of nonnegative integers.Theflow relation has the following characteristics:–Synchronization at a transition is allowed be-tween a branch arc of a choice place and anotherindependent concurrent arc.–Synchronization at a transition is not allowedbetween two or more branch arcs of the samechoice place.–A self-loop from a place back to itself is allowedonly if there is an initial token in one of the placesin the loop.•M0:P→N is the initial marking(assignment of tokens to places),and•τ:T→N×(N∪∞),i.e.,τ(t)=(α,β),where t∈T,αis the earliestfiring time(EFT),andβis latestfiring time(LFT).We will use the abbreviations τα(t)andτβ(t)to denote EFT and LFT,respectively.Graphically,a TCCPN can be depicted as shown in Fig.1,where circles represent places,vertical bars repre-sent transitions,arrows represent arcs,black dots represent tokens,and integers labeled over arcs represent the weights as defined by F.Here,F(x,y)>0implies there is an arc from x to y with a weight of F(x,y),where x and y can be a place or a transition.Conflicts are allowed in a TCCPN, where a conflict occurs when there is a token in a place with more than one outgoing arc such that only one enabled tran-sition canfire,thus consuming the token and disabling all other transitions.The transitions are called conflicting and the place with the token is also called a choice place.For ex-ample,decelerate and accelerate are conflicting transitions in Fig.1.Intuitions for the characteristics of theflow relation in a TCCPN,as given in Definition1,are as follows.First,un-like FCPN,confusions are also allowed in TCCPN,where a confusion is a result of synchronization between an arc of a choice place and another independently concurrent arc.For example,the accelerate transition in Fig.1is such a syn-chronization.Second,synchronization is not allowed be-tween two or more arcs of the same choice place because arcs from a choice place represent(un)conditional branch-ing,thus synchronizing them would amount to executing both branches,which conflicts with the originaldefinition of a choice place(only one succeeding enabled transition is executed).Third,at least one place occurring in a loop of a TCCPN should have an initial token because our TEQSS scheduling method requires a TCCPN to return to its ini-tial marking after afinite complete cycle of markings.This is basically not a restriction as can be seen from most real-world system models because a loop without an initial token would result in two unrealistic situations:(1)loop triggered externally resulting in accumulation of infinite number of tokens in the loop,and(2)loop is never triggered.Semantically,the behavior of a TCCPN is given by a sequence of markings,where a marking is an assignment of tokens to places.Formally,a marking is a vector M= m1,m2,...,m|P| ,where m i is the non-negative number of tokens in place p i∈P.Starting from an initialmarkingM0,a TCCPN may transit to another marking through the firing of an enabled transition and re-assignment of tokens.A transition is said to be enabled when all its input places have the required number of colored tokens for the required amount of time,where the required number of colored to-kens is the weight as defined by theflow relation F and the required amount of time is the earliestfiring timeαas de-fined byτ.An enabled transition need not necessarilyfire. But uponfiring,the required number of tokens are removed from all the input places and the specified number of tokens are placed in the output places,where the specified number of tokens is that specified by theflow relation F on the out-going arcs from the transition.An enabled transition may notfire later than its latestfiring timeβ.3.2Problem FormulationA user specifies the requirements for an embedded soft-ware by a set of TCCPNs.The problem we are trying to solve here is tofind a construction method by which a set of TCCPNs can be made feasible to execute as a software code,running under given limited memory space and time constraints.The following is a formal definition of the real-time embedded software synthesis problem.Definition2Real-Time Embedded Software Synthesis Given a set of TCCPNs,an upper-bound on available mem-ory space,and a set of real-time constraints such as periods and deadlines,a piece of real-time embedded software code is to be generated such that(1)it can be executed on a sin-gle processor,(2)it satisfies all the TCCPN requirements, including local time constraints,(3)it uses memory no more than the user-specified upper-bound,and(4)it satisfies all the real-time constraints,including periods and deadlines.There are mainly two issues in solving the above de-fined real-time embedded software synthesis problem as de-scribed in the following.•TCCPN Scheduling :The first issue is how to sched-ule all the TCCPN requirements onto a single pro-cessor,while obeying the local time constraints and the global real-time constraints.Due to the complex-choice and time characteristics of TCCPN,generation of conflict-free components and scheduling are more intricate than that in QSS and extended QSS.•Code Generation :The second issue is how to gener-ate uni-processor code so that the multi-tasking behav-ior of a real-time embedded software is still visible ,thus increasing the ease of future maintenance.Fur-ther,how can interrupt handling code be generated?3.3Synthesis AlgorithmAs formulated in Definition 2and described in Sec-tion 3.2,there are two objectives for solving the embed-ded software synthesis problem,namely scheduling of TC-CPN requirements on a single processor and real-time em-bedded software code generation.For TCCPN scheduling,we propose a Time-Extended Quasi-Static Scheduling algo-rithm,which can handle complex-choices and can satisfy time constraints specified in a set of TCCPNs.For code generation,we propose a Code Generation with Multiple Threads method,which can generate code such that the multi-tasking behavior of an embedded software is still vis-ible,thus increasing the ease of future maintenance.3.3.1T i me-Extended Quas i -Stat ic Schedul ing To handle complex choices and to satisfy time constraints specified in a TCCPN,we propose the Time-Extended Quasi-Static Scheduling (TEQSS)method.TEQSS is based on the previously proposed QSS and extended QSS meth-ods,which make most scheduling decisions statically,leav-ing only the data-dependent decisions to run-time.Basi-cally,QSS work as follows [21,20].Whenever a choice place is encountered,a T-allocation selects one of the en-abled conflicting transition for execution,thus disabling all other conflicting transitions.The T-allocation is performed for each conflicting transition.Then,a T-reduction actu-ally eliminates all the disabled conflicting transition from a T-allocation,including all successor places and transitions that are no longer triggerable.Intuitively,each T-reduction is a possible computation behavior of the net,which is then scheduled independently from the other T-reductions.If all T-reductions can be scheduled,then the system is declared schedulable and valid schedules generated,which is used for code generation.The generated code ensures that the number of tasks is minimal,that is,it is the same as the number of source transitions with independent firing rates,where a source transition is one without any incoming place thus represents a system input event.Two source transitionsare said to have independent firing rates if the rates at whichthey fire are not related in any way.Table 1.Time-Extended Quasi Static AlgorithmTEQSS Schedule (S,µ,ψ)S ={A i |A i =(P i ,T i ,F i ,M i 0,τi ),i =1,2,...,n };µ:integer;//maximum memoryψ:real-time constraints;//periods,deadlines,etc.{while (C =Get CCS (S )=NULL ){(1)ExT able =Create Table (C );(2)for each transition t ∈C (3)for each transition t ∈C (4)if (M Exclusive(t,t ))ExT able [t,t ]=True;(5)//Decompose CCS C into conflict-free subsets D ={C };//D is a power-set of C (6)for each subset H ∈D (7)for each transition t ∈H (8)for each transition t ∈H(9)if (ExT able [t,t ]=True){(10)H =Copy Set (H );(11)Delete Trans(H,t );(12)Delete Trans(H ,t );(13)D =D ∪H ;}(14)//Decompose TCCPN according to D for each subset H ∈D(15)Decompose TCCPN(S,H );(16)}//Schedule all CF components for each TCCPN A i ∈S(17)for each conflict-free subnet X of A i {(18)X s =Schedule (X,µ);(19)if (X s =NULL )return ERROR;(20)else T EQSS i =T EQSS i ∪X s ;}(21)if (Check Sched (S,µ,ψ,T EQSS 1,...)==Fal se)return ERROR;(22)Gen Code (S,µ,T EQSS 1,...);(23)}As QSS cannot handle non-free choices,which we call complex choices ,thus extended QSS was proposed [21],which can handle complex choices,but extended QSS still could not synthesize software satisfying time constraints,thus TEQSS is proposed here.The details of our proposed TEQSS algorithm are as shown in Table 1.Given a set of TCCPNs S ={A i |A i =(P i ,T i ,F i ,M i 0,τi ),i =1,2,...,n },a maximum bound on memory µ,and a set of real-time constraints psi such as periods and deadlines,the algorithm finds and processes each set of complex choice transitions (Step (1)),which is simply called Com-plex Choice Set (CCS)and defined as follows.Definition 3Complex Choice Set (CCS)Given a TCCPN A i =(P i ,T i ,F i ,M i 0,τi ),a subset oftransitions C⊆T i is called a complex choice set if there exists a sequence of the transitions such that each adjacent pair of transitions has a common input place.From Definition3,we can see that a free-choice is a spe-cialcase of CCS.Thus,QSS and extended are specialcases of TEQSS.For each CCS,TEQSS analyzes the mutual ex-clusiveness of the transitions in that CCS and then records their relations into an Exclusion Table(Steps(2)–(5)).Two complex-choice transitions are said to be mutually exclu-sive if thefiring of any one of the two transitions disables the other transition.The(i,j)element of an exclusion table can take values True or False,where True means the i th and the j th transitions are mutually exclusive,and False means not mutually exclusive.Based on the exclusion table,a CCS is decomposed into two or more conflict-free(CF)subsets,which are sets of transitions that do not have any conflicts,neither free-choice nor complex-choice.The decomposition is done as follows (Steps(6)–(14)).•For each pair of mutually exclusive transitions t,t ,do the following.•Make a copy H of the CCS H(Step(11)),•Delete t from H(Step(12)),and•Delete t from H (Step(13)).Based on the CF subsets,a TCCPN is decomposed into conflict-free components(subnets)(Steps(15)–(16)).The CF components are not distinct decompositions as a tran-sition may occur in more than one component.Starting from an initialmarking for each component,afinite com-plete cycle is constructed,where afinite complete cycle is a sequence of transitionfirings that returns the net to its ini-tial marking.A CF component is said to be schedulable (Step(19))if afinite complete cycle can be found for it and it is deadlock-free.Once all CF components of a TCCPN are scheduled,a valid schedule for the TCCPN can be gen-erated as a set of thefinite complete cycles.The reason why this set is a valid schedule is that since each compo-nent always returns to its initial marking,no tokens can get collected at any place.Satisfaction of memory bound is checked by observing if the memory space represented by the maximum number of tokens in any marking does not ex-ceed the bound.Here,each token represents some amount of buffer space(i.e.,memory)required after a computation (transitionfiring).Hence,the totalamount of actualmem-ory required is the memory space represented by the max-imum total number of tokens that can get collected at all the places in a marking during its transition from the initial marking back to its initialmarking.After checking tempo-ral schedulability of all the schedules(Step(22)),real-time embedded software code is generated(Step(23)),which will be discussed in the following and in Section3.3.2,re-spectively.The procedure Check Sched()(Step(22)),which is de-tailed in Table2,ensures that the following conditions are satisfied by the generated set of schedules{T EQSS1,...}.•Transition Deadline:Each transition t in each of theschedules can befired within itsfiring time interval [τα(t),τβ(t)],•TCCPN Deadline:Each schedule of a TCCPN A i can be completed within the deadline d i of that TCCPN, and•Memory Usage:The maximum amount of totalmem-ory used by each set of concurrent schedules of all the TCCPNs is within the upper bound ofµ.From the above three conditions we can observe that due to the complexity of local and global time constraints,mere application of real-time scheduling does not suffice to solve this problem.For instance,suppose a task is executing in one of its schedules,and another task wants to preempt the first task,but thefirst task cannot be preempted at any ran-dom point in time.This restriction comes from the basic assumption that a subtask(as represented by thefiring of a transition)cannot be preempted.To solve this issue,we pro-pose a schedulability check algorithm as given in Table2, which in turn redefines schedulability in terms of real-time scheduling.In Steps(1)and(2)of Table2,from all the generated schedules{T EQSS1,...},system schedules are generated from the composition of net schedules as follows:1.One schedule is selected from each T EQSS i,i≥1.Each one of the schedule is called a net schedule.2.The selected set of net schedules is checked for feasi-bility,where a set of schedules is feasible if the sched-ules can be executed concurrently.If feasible,the set of net schedules is called a system schedule.3.Repeat the above two steps as long as a distinct set ofschedules can be selected and tested for feasibility.For each transition in a net schedule(Step(3)),wefirst find its concurrent set of transitions and then test that set for schedulability.The procedure Find Conc Trans(t i)in Step(4)of Table2constructs a set Conc(t i)of transitions which can be concurrently executed with a given transition t i,after all preceding transitions have been scheduled and executed.This set Conc(t i)of transitions is then tested for schedulability as follows(Schedulable()procedure in Step (5)).Table2.Schedulability Check Algorithm Check Sched(S,µ,ψ,T EQSS1,...)S={A i|A i=(P i,T i,F i,M i0,τi),i=1,2,...,n};µ:integer;//maximum memoryψ:real-time constraints;//periods,deadlines,etc.T EQSS1,...:TEQSS schedules{for each system schedule Y{(1)for each net schedule X s∈Y{(2)for each transition t i∈X s{(3) Conc(t i)=Find Conc Trans(t i);(4)if(Schedulable(Conc(t i))==False)return Trans Deadline Violated(t i);(5) }if(WCET(X s)>Deadline(ψ,A s))return TCCPN Deadline Violated(X s);(6) }if(Max Mem(Y)>µ)return Memory Bound Violated(Y);(7) }return True;(8) }1.A scheduling policy such as rate-monotonic schedul-ing or earliest deadlinefirst[17]is selected,2.A totalsystem time is maintained,which starts from0and gradually increments upon time elapse,3.It is assumed that the totalsystem time has reacheda stage where all predecessor transitions of the tran-sitions in Conc(t i)have been scheduled and executed using the selected policy from thefirst step.4.Now,Conc(t i)is said to be schedulable if all the transi-tions can be scheduled by whatever scheduling policy was chosen in thefirst step.5.Time is allowed to elapse and transitions from Conc(t i)are scheduled as long as no new transitions are en-abled.6.If a new transition is enabled,goto to Step(3).In Step(6)of Table2,the procedure WCET()checks if the worst case execution time of a net schedule exceeds the deadline of a TCCPN with which the schedule is associated. In Step(7),the procedure Max Mem()checks if the max-imum memory utilized by a system schedule exceeds the maximum memory boundµgiven by a user.Due to page-limit,details of these two procedures are omitted here.3.3.2Code Generation with Multiple ThreadsIn contrast to the conventionalsingl e-threaded embedded software,we propose to generate embedded software with multiple threads,which can be processed for dispatch by a real-time operating system.Our rationalizations are as follows:•With advances in technology,the computing power of microprocessors in an embedded system has increased to a stage where fairly complex software can be exe-cuted.•Due to the great variety of user needs such as inter-active interfacing,networking,and others,embedded software needs some level of concurrency and low context-switching overhead.•A multi-threaded software architecture preserves the user-perceivable concurrencies among tasks,such that future maintenance becomes easier.The procedure for code generation with multiple threads is given in Table3.Each source transition in a TCCPN represents an input event.Corresponding to each source transition,a P-thread is generated(Steps(1),(2)).Thus, the thread is activated whenever there is an incoming event represented by that source transition.There are two sub-procedures in the code generator,namely Visit Trans()and Visit Place(),which call each other in a recursive manner, thus visiting all transitions and places and generating the corresponding code segments.A TCCPN transition repre-sents a piece of user-given code,and is simply generated as call t k;as in Step(3).Code generation begins by visiting the source transition,once for each of its successor places(Steps(4),(5)).In both the sub-procedures Visit Trans()(Steps(1)–(3)) and Visit Place()(Steps(6)–(8)),a semaphore mutex is used for exclusive access to the token num variable as-sociated with a place.This semaphore is required because two or more concurrent threads may try to update the vari-able at the same time by producing or consuming tokens, which might result in inconsistencies.Based on thefiring semantics of a TCCPN,tokens are either consumed from an input place or produced into an output place,upon thefiring of a transition.When visiting a choice place,a switch() construct is generated as in Step(3).After all the codes in threads are generated,a main pro-cedure is generated,which creates all the threads and passes controlto the executing threads.4Application ExampleWe give an example to illustrate our proposed TEQSS algorithm and code generation procedures.It is an exam-ple on a real-time embedded software for the master-slave role switch between two wireless Bluetooth devices.In the Bluetooth wireless communication protocol[4],a piconet is。