完整版化合物英文命名规则

Nomenclature of Inorganic Compounds 无机化合物的命名（Prefix 词头,前缀Suffix 词尾,后缀Stem 词根） 1.Trivial Names 俗名

H2O water 不说dihydrogen oxide

NH3 ammonia 不说nitrogen trihydride

CaO quicklime

CaCO3 limestone 2.Systematic Nomenclature 系统命名

1）Oxide 氧化物——先命名非氧元素

ZnOzinc oxide

CaO calcium oxide

CO carbon oxide

Na2O2 sodium peroxide

H2O2hydrogen peroxide 注：peroxide 过氧化物

2）Hydroxide 氢氧化物（base 碱）

Ba（OH）2 barium hydroxide

KOH potassium hydroxide

3）Acid 酸

Hydro acid 氢酸General formula 通式:HnX 命名：hydro- + stem of X + -ic acid H2S hydrosulfuric acid（英） hydrosulphuric（美）氢硫酸S:sulfur（英）、sulphur（美）HBr 氢溴酸hydrobromic acidBr: bromine HCl 氢氯酸（盐酸）hydrochloric acidCl: chlorine HF 氢氟酸hydrofluoric acidF: fluorine

Oxoacid or Oxyacid 含氧酸General formula 通式：HnXOm 命名：Stem of X + -ic acid 注：oxo- （oxy-）含氧, 氧代

H2SO4 sulfuric acid（英） sulphuric acid（美）

H2CO3 carbonic acid

H3PO4 phosphoric acid P： phosphorus H3BO3 boric acid B： boron HNO3 nitric acid N： nitrogen If X has two oxidation states ：

-ic：the higher oxidation state

-ous：the lower oxidation state

H2SO4 sulfuric acid

H2SO3 sulfurous acid 1/5

HNO3 nitric acid

HNO2 nitrous acid

If X （such as halogens） has more than two oxidation states ：halogen 卤素

per- （过，高） + -ic ：the still higher oxidation state hypo- （次,在,下） + -ous：the still lower oxidation state HClO3 chloric acid

HClO2 chlorous acid

HClO4 perchloric acid

HClO hypochlorous acid

HIO hypoiodous acid

4）Salt 盐

General formula 通式:MnXm 命名：Name of M stem of X + -ide （- ide, 化物）Oxide 、chloride 、nitride 、hydride

KI potassium iodide

Al2S3 aluminum sulfide

LiH lithium hydride

Oxysalt 含氧酸盐Name the metal ion first and then the anion Naming anions:

-ate anions derived from the -ic acid（the higher oxidation state of X） -ite anions derived from the -ous acid （the lower oxidation state of X） HNO3 nitric acid

NaNO3 sodium nitrate

HNO2 nitrous acid

NaNO2 sodium nitrite

SO42- sulfate

SO32- sulfite AgClO4 silver perchlorate

NaIO3 sodium iodate

KClO2 potassium chlorite KBrO potassium hypobromite MnO42- manganate MnO4- permanganate Acid salt 酸式盐Using “ hydrogen ” to specify NaHSO4 sodium hydrogen sulfate NaH2PO4 sodium dihydrogen phosphate Na2HPO4 disodium hydrogen phosphate P: phosphorus phosphate 磷酸盐（根）Using prefix bi- + name of anion if only one acid salt exists

NaHSO4 sodium bisulfate

H”

NaHSO3 sodium bisulfite

KHCO3 potassium bicarbonate

5）Metals （M ）with more than one oxidation state 2/5

Two methods: ①后缀法: 早期使用

stem of M + -ic the higher oxidation state of M stem of M + -ous the lower oxidation state of M HgI2 mercuric iodide

Hg2I2 mercurous iodide Hg:mercury Cr2+ chromous

Cr3+ chromic Cr: chromium

注：In most cases, Latin stem is used if the metal has symbol derived from its Latin name.（mercury is an exception）

Cu:cuprum （拉丁）,copper （英）

Cu+ cuprous

Cu2+ cupric

CuI cuprous iodide

CuS cupric sulfide Sn:stannum (拉丁), tin ( 英) SnCl2 stannous chloride

SnO2 stannic oxide

Fe:ferrum ( 拉丁), iron ( 英)

Fe(OH)2 ferrous hydroxide

FeBr3 ferric bromide

② IUPAC Rule 1957 年开始使用English name of metal(Roman numeral)

CuBr copper(I) bromide

CuF2 copper(II) fluoride