NSS Chem Part 3 Metals MC
各种耐蚀镍合金的化学成分,物理特性介绍
m3 ℃
℃)
133
8.6
5 10.1(100 138 ℃)
0
比热 容 J/kg• ℃
408
弹性 模量 GPa
211
剪切模 量 GPa
电阻 率 μΩ•m
1.24
泊松 比
线膨胀系数 a/10-6℃-1
10.9(20~100℃ )
NS335力学性能:(在20℃检测机械性能的最小值)
热处理方式
抗拉强度 σb/MPa
1、该合金具有良好的冷、热成形性能,钢锭锻造加热温度 1120℃。
2、该合金的晶粒度平均尺寸与锻件的变形程度、终锻温度密切相关。
3、合金的焊接性能良好,可在保护气氛下用钨极或本合金作添料进行氩弧焊接,也可用钎焊连接及
电阻缝焊。
4、表面处理工艺:除去合金表面氧化皮时先碱洗,再在销酸、氢氟酸 -水溶液中酸洗。
NS336
NS336特性及应用领域概述:
该合金是以钼铌为主要强化元素的固溶强化型镍基变形高温合金 ,具有优良的耐腐蚀和搞氧化性
能,从低温到980℃均具有良好的拉伸性能和疲劳性能,并且耐盐雾气氛下的应力腐蚀。因此,可广
泛用于制造航空发动机零部件、宇航结构部件和化工设备。
NS336相近牌号:
Inconel625 NO6625(美国)、 NC22DNb(法国)、W.Nr.2.4856(德国)
NS336 化学成份:(GB/T14992-2005)资料参考:
镍铬铁
钴
合金 牌号
%
钼 N C F Mo
铌 Nb
碳锰硅 硫 铜 铝 C C Mn Si S Cu Al
钛 Ti
ire
o
2
最小
0 .
8. 3.15 0
NIPAM-四氧化三铁
PAPER
Published on 23 October 2013. Downloaded by Southeast University - Jiulonghu Campus on 28/0nline
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Received 26th July 2013 Accepted 22nd October 2013 DOI: 10.1039/c3ra43919d /advances
1
Introduction
The combination of magnetic nanoparticles (MNs, e.g. Fe3O4) and polymers promotes the mechanical and chemical stabilities of MNs in acidic or ionic conditions.1 In ferrouid, MNs coated with polymer layers possess stabilization against gravitational force, avoiding strong interaction and agglomeration of MNs. The resulting magnetic polymer nanoparticles (MPNs) not only have particular properties of polymers that respond to volume or shape changes to external temperature, pH, ionic strength and so forth, but also exhibit magnetism speciality. In a magnetic eld, the MPNs can directionally move to a specic site or be quickly separated from the surrounding medium. So, the MPNs display potential applications in many elds, such as protein absorption, cellular separation, detection and diagnosis of immunity, smart carriers of drug and gene.2–6 Poly(N-isopropylacrylamide) (PNIPAM, a classical stimulusresponsive polymer) has being generating increasing interest for applications because it has a lower critical solution temperature (LCST) and undergoes a volume phase transition
助焊剂介绍
焊接曲线
7
助焊剂的涂布方式
▪ 助焊剂对被焊表面的涂布方法有传统波焊中的泡沫式,喷 头喷雾式,滚筒喷雾式及表面沾浸式的涂布方法。
8
助焊剂的成份组成
▪ 1成膜剂 ▪ 保护剂覆盖在焊接部位,在焊接过程中起防止氧化作用的物质,焊接完成后,
能形成一层保护膜。常用松香用保护剂,也可以添加少量的高分子成膜物质。 ▪ 2.活化剂 ▪ 焊剂去除氧化物的能力主要依靠有机酸对氧化物的溶解作用,这种作用由
▪ 有一些材料可以去除氧化物且盖住金属表面使氧化物不 再形成,这就是助焊剂,它是焊接工程必要的材料。它 们尚需具备其他的特性,如耐焊接温度、自由流动和不 阻碍焊锡的流动。理想上,它们也不攻击焊点上的金属 或四周的材料,而且也必须易于被去除。助焊剂(FLUX) 这个字是来自拉丁文,是“流动”的意思,但在此处它 的作用不只是帮助流动,还具有其它的作用。
M
份铜镜被除去
蚀时尚可允许, 但是FLUX须通
过卤化物
H
铜镜全部被去除 卤化物可高于2% 可允许有严重的 腐蚀出现
19
J-STD-004
▪ 对于J-STD-004而言,没有不合格的 助焊剂产品,仅仅类别不同而已。JSTD-004 将所有的焊剂分成24个类别, 涵盖 了目前所有的焊剂类型,该标准 根据助焊剂的主要组成材料将其四大 类:松香型(Rosin,RO);树脂型 (Resin,RE)有机酸型(organic,OR),无 机酸型(Inorganic,IN),括号中的缩写 字母代号。其次,根据铜镜试验的结 果将焊剂的活性成分水平划分为三级:
图A:液体焊料在基底金属上的扩散,接触角(由界面张力的 平衡来决定小润湿角形成良好的焊接获得小润湿角的原则(1) 低表面张力的助焊剂(2)高的表面张力,即高表面能的基板 (3)低有面张力的焊料)。图B 基底金属溶解入液体焊料。图 C基底金属与液体焊料起反应形成金属间化合物层(IMC)
金属有机(第三讲)
金属有机化学Email: iamjsong@
影响反应的选择性
甲基戊烯
21.6
9.9
0.1
金属增加两个配位数,氧化态增加2。
2. 双核还原消除,涉及两个过渡金属有机化合物,生成金属-金属
相对速率
16 电子18 电子
, dsp22sp3正八面体
卤代烯烃
C−Η
1983年Bergman:
H
歧化
6. C-N,C-P,O-H,N-H键的氧化加成反应
氧化加成的逆反应是还原消除,反应过程中金属的配位数和氧化
烷基或芳基以顺式消除,还原消除立体保持
烷基或芳基是以顺式消除的,因而当两个基团处于反位时,反应不能进行。
CR2(卡宾)
插入反应是指有机分子的多重键插入到M-R键中,开成新的金属有机中间体的过程。
这一过程是金属有机中间体M-R键转换的重要途径,尤其是过渡金属参与的分子内环化反应中插入反应是非常重要的步骤。
插入反应的逆过程即为反插入反应,其中最重要的是β-消除反应。
必须强调的是发生β-消除的必要条件是中心金属必须有空的配位点,同时被消除的原子或基团
充满电子的金属d轨道与CO重叠生成键,发生电子反馈
叔膦
Et
从反应结果看也证明是R迁移。
如果是CO插入机理,则结果相反。
这种CO插入反应从机理上看是通过烷基迁移进行的,应称作烷基向CO的迁移反应,但从原料和生成物来看,如果称为CO插入反应,则不须考虑机理而比较方便,所以继续沿用。
新型三维网状纳米金复合物的制备及表征
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o A C4 i a H e rsneo eit eeao o a iomn G A M)a i esn aet fH u Iwt N B 4nt eec fh r nri pl mda ie( 1P MA h i hp t fsg tn y s s r tegn. dp a r
21 00年 9月
湖南师范大学 自然科学学报
Ju a fNaua ce c fHu a r l iest o r l trlS in eo n nNoma Unvri n o y
V0. 3 No 3 13 . S p ,0 0 e .2 1
第3ቤተ መጻሕፍቲ ባይዱ第3 3 期
新 型 三维 网状 纳米 金复合 物 的 制备及 表 征
的影响. 采用紫外分光光度计 、 傅里叶红外光谱仪 以及透射 电子 显微镜对其进行 了表 征. 实验 结果表 明 : 室温 搅拌 下 , 金酸根离子可与聚酰胺. 氯 胺形成稳定络合物 , 再加 入还原剂 原位合成 了纳米金复合物 , 复合物呈三维有 序网 状结构. 合成方法简便 , 有望用于生化分子及生物传感等领域.
三甲基铝气相沉积
三甲基铝气相沉积三甲基铝气相沉积(TMAl CVD)是一种常用的化学气相沉积技术,用于制备薄膜材料。
在TMAl CVD过程中,三甲基铝(TMAl)被用作前体物质,通过热解分解产生金属铝,并在基底表面形成薄膜。
TMAl CVD具有很高的化学反应活性和沉积速率,因此被广泛应用于半导体、光电子、纳米技术等领域。
下面将详细介绍TMAl CVD的原理、工艺参数及应用。
1. 原理TMAl CVD的原理是在高温下,将TMAl气体输送到反应室中,通过热解分解反应产生金属铝,并在基底表面形成薄膜。
整个反应过程可以分为三个主要步骤:TMAl的输送、热解分解和膜的形成。
TMAl气体通过气体输送系统被引入到反应室中。
在反应室中,TMAl 气体被加热至高温,从而使其发生热解分解反应。
热解分解反应将TMAl分解为金属铝和甲烷等副产物。
金属铝以原子形式沉积在基底表面,形成薄膜。
2. 工艺参数TMAl CVD的工艺参数包括反应温度、反应压力、载气流量和沉积时间等。
这些参数对薄膜的性质和沉积速率有着重要影响。
反应温度是TMAl CVD的关键参数之一。
适宜的反应温度可以提高反应速率和薄膜质量。
通常,反应温度在300-600摄氏度之间。
反应压力是控制反应过程中气体浓度和输送速率的重要参数。
适宜的反应压力可以提高反应速率和薄膜均匀性。
通常,反应压力在0.1-10 torr之间。
载气流量是将TMAl气体输送到反应室中的关键参数。
适宜的载气流量可以改善TMAl气体的输送和分解效果。
通常,载气流量在100-1000 sccm之间。
沉积时间是决定薄膜厚度的重要参数。
适宜的沉积时间可以控制薄膜的厚度和成分。
通常,沉积时间在几分钟到几小时之间。
3. 应用TMAl CVD广泛应用于半导体和光电子领域。
在半导体领域,TMAl CVD可用于制备金属铝薄膜,用作电极、导线和衬底等。
在光电子领域,TMAl CVD可用于制备金属铝薄膜,用作反射镜、导电层和光学薄膜等。
拉曼光谱法研究连接体氧化层应力变化及其进展
拉曼光谱法研究连接体氧化层应力变化及其进展虞自由;陈志远;周国治【摘要】合金连接体是固体氧化物燃料电池重要组件,它的服役状况很大程度上决定着电池的工作寿命.高温氧化过程或者热循环过程中金属氧化层应力的变化是造成氧化层破坏的重要原因,这也是导致合金连接体失效的主要因素.利用拉曼光谱对氧化层应力的在线监测和实验研究可以为改善合金连接体服役年限提供重要依据.本文首先总结了近年来的连接体氧化层应力实验研究工作,分析了氧化层应力产生的原因.并且本文在比较了氧化层应力的测试方法的基础上讨论拉曼光谱法在测试氧化层应力方面的研究方法进展.【期刊名称】《光散射学报》【年(卷),期】2015(027)004【总页数】8页(P342-349)【关键词】连接体;氧化层;应力;拉曼光谱【作者】虞自由;陈志远;周国治【作者单位】北京科技大学钢铁冶金新技术国家重点实验室,北京100083;北京科技大学材料与科学工程学院,北京100083;北京科技大学钢铁冶金新技术国家重点实验室,北京100083【正文语种】中文【中图分类】TG172.82固体氧化物燃料电池(SOFCs)具有能量转换率高、稳定性能好、绿色环保等优点,被称为21世纪的无污染、无噪音的绿色能源[1-2]。
连接体是SOFC的一个重要组成部分,它的功能是实现SOFC电池堆的气体流场布局、电极集电功能及单电池之间的连接[3-4]。
由于连接体在电池组件中的关键作用,它的性能衰减就成了SOFC寿命的决定性因素之一。
连接体的材料可以分为两大类,一类是陶瓷连接体,具有较强电子导电性能,但是高温下的热冲击韧性不够,复杂工艺使得加工成本高[5];另一类是合金连接体,随着技术的不断发展,SOFC的工作温度降至中低温区,这使得金属可以作为连接体材料使用[6]。
一般常用的合金连接体有三类[7]:Ni基合金,Cr基合金与Fe基合金。
这些合金高温抗氧化性主要由合金中的铬成份氧化后形成的致密氧化铬保护膜提供。
甘肃某高砷金矿伴生金属综合回收试验研究
2021年第2期!色金属(%矿'今)・77・doi:10・3969/j.issn.1671-9492.2021.02.012某咼碑金矿伴生金属综合回收试验研究杨俊龙,郭艳华(西北矿冶研究院,甘肃白银730900)摘要:甘肃某金矿属于含碑较高的铅、锌、金、银多金属矿,有用矿物种类较多。
在原矿性质研究的基础上,进行了不同工艺方案的试验研究。
在综合分析了各种方案的技术指标及优缺点的情况下,确定采用优先选铅一锌硫混浮一锌硫分离工艺试验方案。
在最佳条件试验基础上,最终闭路试验可以获得铅品位为47.71%,铅回收率为71.45%,伴生金品位为16.50g/t,金回收率为8.82%,伴生银品位3561g/t,银回收率为72.62%的铅精矿,锌品位为40.42%,锌回收率为48.07%的锌精矿和金品位为30.86g/t,金回收率为84.01%的金精矿。
该方案产品结构合理,铅、锌、金、银等有价金属均能得到较好的回收。
关键词:高F;硫化铅;金;浮选中图分类号:TD953文献标志码:A文章编号:1671-9492(2021)02-0077-06Experimental Study on Comprehensive Recovery of AssociatedMetals from a High Arsenic Gold Ore in GansuYANG Julong,GUO YanhuaQNorthxvest Research Institute o f Mining and Metallurgy,Baiyin730900,Gansu,China#Abstract:A gold mine in Gansu province belongs to lead,zinc,gold and silver polymetallic ore with high arsenic content,and there are many kinds of useful minerals.On the basis of the study on the properties of raw ore,the experimental study on different process schemes has been carried out.Based on the comprehensive analysis of the technical indicators and advantages and disadvantages of various schemes, the test scheme of preferential separation of lead-zinc-sulfur bulk flotation-zinc-sulfur separation process was determined.On the basis of the optimum conditions,the final closed-circuit test can obtain lead concentrate with Pb grade of47.71%,Pb recovery of71.45%,associated Au grade of16.50g/t,Au recovery of 8.82%,associated Ag grade of3561g/1,Ag recovery of72.62%and zinc concentrate with Zn grade of 40.42%Zn:ecove:y of48.07%and gold concent:ate with Au g:ade of30.86g/t Au:ecove:y of 84.01%.The product structure of this scheme is reasonable,and valuable metals such as lead,zinc,gold andsilverwerewe l recovered.Keywords:high-arsenic;lead sulfide;gold;flotation据统计,中国脉金矿中低品位和含复杂硫化物的金矿资源,金高神硫化矿,不仅资源,而且金品位较高,在黄金资源中占有很大的比例。
通过盐酸刻蚀和生长作用来选择性合成不同尺寸大小的金纳米团簇(英文)
通过盐酸刻蚀和生长作用来选择性合成不同尺寸大小的金纳米
团簇(英文)
黄婷;孙治湖;潘国强
【期刊名称】《化学物理学报》
【年(卷),期】2018(31)2
【摘要】本文在两个Auss的合成反应过程中,在不同的反应时间加入盐酸调控反应路径,分别能合成Au7和Au13团簇.用原位质谱和原位紫外可见光吸收谱监测这两个盐酸加入后的反应过程,发现盐酸在Au7和Au13团簇的合成反应中分别起着刻蚀剂和生长剂的作用.分别用H^+和Cl^-代替盐酸来重复上述的反应,发现盐酸中的H^+和Cl^-分别起着刻蚀和生长作用.构建了盐酸对团簇的刻蚀和生长作用机理即盐酸中的H^+可以使团簇表面的Au(I)-PPha键断裂,从而实现团簇的刻蚀;盐酸中的Cl^-能促使溶液中产生含Au-Cl键的前驱物,这些前驱物通过化学吸附作用吸附在团簇表面,从而使团簇长大.
【总页数】7页(P223-228)
【关键词】选择性合成;路径调控;盐酸;刻蚀和生长作用
【作者】黄婷;孙治湖;潘国强
【作者单位】中国科学技术大学国家同步辐射实验室
【正文语种】中文
【中图分类】O644.12
【相关文献】
1.金纳米团簇荧光探针的合成与生物检测应用 [J], 陈萌;谈立伟;许娜;冯大千;刘国良;王伟
2.液相合成金纳米团簇 [J], 刘钊;金申申;朱满洲
3.精确尺寸巯基保护贵金属纳米团簇的合成进展 [J], 汪恕欣;李杨枫;朱满洲
4.金纳米团簇在盐酸和十二硫醇刻蚀作用下的原位生长动力学研究 [J], 杨丽娜;黄莉;宋雪洋;贺文雪;姜泳;孙治湖;韦世强
5.己硫醇单层保护金纳米团簇的合成及其性质 [J], 徐琴;夏纲;胡效亚;郭荣
因版权原因,仅展示原文概要,查看原文内容请购买。
天然物质表面的电化学金属化方法
天然物质表面的电化学金属化方法
覃奇贤
【期刊名称】《电镀与精饰》
【年(卷),期】2005(27)1
【摘要】首先将欲金属化的天然物质表面浸入40~80℃的碱金属碘酸盐水溶液中进行改性处理(该碱金属碘酸盐的质量分数为3%~15%),当表面上形成导电的硫化物膜,并在空气中老化之后,即可电镀金属镀层。
用上述方法在天然物质表面获得的金属镀层与表面结合牢固,镀层连续性好,没有针孔,
【总页数】1页(P37)
【作者】覃奇贤
【作者单位】无
【正文语种】中文
【中图分类】TG174
【相关文献】
1.Ru-Fe异金属化合物及其在Au表面上SAM的电化学研究 [J], 李朝晖;Fehlner T. P.;付贤智
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世界粉末冶金高速钢的研究和生产现状
[ 8]
。
( 5) 抗疲劳性能好。细小均匀的内部组织大大 改善了粉末冶金高速钢的延展性 , 因而, 在与其他钢 种的耐磨性能一样的情况下, 粉末冶金高速钢的抗 疲劳性能更为优越。 Meurling
[ 9]
等人详细比较了粉
末冶金高速钢 ASP2023 、 ASP2014 和传统高速钢 M2 以及冷作工具钢 VANADIS10 的疲劳性能, 发现粉末 冶金高速钢 ASP2014 和 ASP2023 的抗疲 劳性能最 好 , 明显优于传统高速钢 M2 的抗疲劳性能。
新型三维电催化工艺处理NS废水研究
新型三维电催化工艺处理NS废水研究盛晨军;崔国旗;杨茜;于婷;刘金锁【摘要】采用酸析曝气预处理结合三维电催化技术以及絮凝沉淀工艺对NS废水进行处理,结果显示:原水COD由6471mg/L降至800mg/L,去除率达88%,并且颜色为无色透明.综合工艺的运行成本估算展现出良好的应用前景.【期刊名称】《天津化工》【年(卷),期】2016(030)005【总页数】4页(P49-52)【关键词】橡胶硫化促进剂NS废水;三维电解;催化剂;预处理【作者】盛晨军;崔国旗;杨茜;于婷;刘金锁【作者单位】天津一化化工有限公司,天津300280;天津一化化工有限公司,天津300280;天津一化化工有限公司,天津300280;天津一化化工有限公司,天津300280;天津一化化工有限公司,天津300280【正文语种】中文【中图分类】X783N-叔丁基-2-苯并噻唑次磺酰胺(促进剂NS)是次磺酰胺类硫化促进剂的重要品种之一,具有抗焦烧性和硫化速度快,并且在操作温度下非常安全,不产生致癌的亚硝胺,是有致癌性可能的N-氧二亚乙基苯并噻唑-2-亚磺酰胺(NOBS)的替代品,广泛的应用于多种橡胶剂的生产。
然而在NS生产过程中产生大量高盐高COD废水,废水中存在含大量多种杂环有机物,并且较高的含盐量,限制了生化处理的应用,处理难度非常大。
三维电极电解技术是在反应器内添加催化剂,构成了一个三维粒子电极催化装置,具有较高的电流效率和单位时空处理率,并且具有较少使用化学药品,占地面积小,处理能力大,操作管理方便,反应条件温和,无二次污染等优点[1],受到污水处理工作者日益广泛的关注。
本文利用独创设计的实验装置采用预处理结合三维电催化技术对NS废水进行降解实验,考察催化剂种类对NS废水处理效果的影响,得出NS废水水处理的最佳工艺。
1.1 仪器和材料仪器:电磁式空气压缩机,直流稳压电源。
试剂:硝酸铜,硝酸铁,椰壳活性炭,聚合氯化铝,阴离子聚丙烯酰胺,氢氧化钠,浓硫酸。
第36届中国化学奥林匹克初赛试题及答案
注:本答案及评分仅供参考,一切以中国化学会公布版本为准(2022年9月4日 9:00~12:00第36届中国化学奥林匹克(初赛)试题参考答案)第1题(10分)根据要求和所给条件,书写反应方程式。
1-1 为获得性能良好的纳米材料,利用团簇化合物K 12Si 17和NH 4Br 反应制备纳米硅。
1-2 硒代硫酸根在酸性条件下被一定浓度的H 2O 2氧化,主产物与硫代硫酸根被I 2氧化的产物相似。
1-3 单质碲(Te)和AsF 5在溶剂SO 2中按计量比6:3反应,主产物为灰色抗磁性固体,其阴离子为八面体结构。
1-4 利用XeF 2和溴酸根溶液反应制备高溴酸根。
1-5 钼酸钠(Na 2MoO 4)和硫代乙酰胺(CH 3CSNH 2)混合溶液在水热条件下强酸性介质中发生反应,制备二维材第2题(7分)高压碳酸盐化学 常温常压下,碳酸根通常以分离的CO 32-基团形式存在,但在高压下可发生聚合,甚至改变配位方式形成类似于硅酸根及其多聚阴离子的结构。
2-1 在20 GPa 的高压下,用激光加热SrCO 3和SrO 的混合物,得到组成为Sr 3CO 5的物质,其结构类似于钙钛矿ABX 3,其中BX 6八面体共顶点连接,写出Sr 3CO 5中分别对应于A 、B 、X 的离子(须注明电荷)。
2-2 在82~138 GPa 的高压下,MgCO 3中的碳酸根形成环状三聚体(C ),画出C 的结构示意图。
在30~40 GPa 的高压下,用激光加热MCO 3(M=Ca 或Sr)和干冰的混合物,得到组成为MC 2O 5的物质。
第3题(7分)锗的团簇化合物 含锗化合物A 的分子式可以表示为Ge 5(NR 2)4,R 为三异丙基硅基。
该化合物中存在两种锗锗键,键长分别为250 pm 和234 pm 。
A 的合成方法如下:控制GeCl 2与KNR 2按1:1计量反应生成B ,B 被金属钾还原得到A 。
在B 转化为A 的过程中,可能经过中间产物C ,C 中含有两个锗原子;C 与B 按1:1计量反应得到环状化合物D ,D 与C 在金属钾还原下反应得到A 。
培训教材(镀金工艺)
最佳值 250m/l
45℃ 5min 70g/l 3% (V/V) 30℃ 50μin 50m/l 100m/l
溶液更换基准
5m2/L
Cu 含量大于 20g/l 3m2/L 3m2/L
18
工艺控制参数及溶液更换基准
序号 工序名称
5 催化
6
后浸
7 化学镍
控制项目 Pd HCL 温度 时间 搅拌 HCL Ni
可能导致降低附着力和槽 液老化时出现镍腐蚀
更高的金带出速度
在很低 PH 时能够导致氰化 物沉淀
可能导致降低附着力和镍腐蚀。
23
化学镀镍缸参数变化对镀层磷含量 及沉积速度的影响
镍缸参数 镍浓度↑ 次磷酸钠浓度↑
PH↑ 温度↑ 槽液负载↓ (<0.25dm2/l) 槽液负载↑ (>2.5dm2/l) 空气搅拌↑ MTO ↑
31
流程控制要点
5. 化学镍 - 不锈钢槽体须用硝酸钝化,防析出整流器控制电压0.9V。 - 防止催化液带入。 - 防析出棒不可与槽体接触 - 防止局部过热,加药区须有充分的搅拌 - 使用10µm聚丙烯滤芯连续过滤,循环量5-10cycle/hr。 - 使用自动加药器控制药液添加 - 须有抽气系统,以除去水点及蒸气。 - 停产时镀槽要有遮盖物,防止外来物污染镀液及镀液蒸发。
Ni2+ +2e Ni0 H2PO2- + H P + H2O +OH-
16
化学镍金各流程概述
8. 浸镀金:
浸金层作用: 保护底层镍不被氧化及维持可焊性 (Solderability)和铝线Bondability。
原理:
在刚沉积上的镍层表面,以置换方式在镍面上沉积一层 很薄而均匀之金层。当镍表面上完全地覆盖了一层金沉 积层后,金之沉积反应便停止,故金属的厚度有极限。
维萨拉化学机械研磨 抛光悬浮液监测手册说明书
www.vaisala.cn客户案例化学机械研磨/抛光 (CMP) 是一项至关重要但成本高昂且难度高的纳米抛光工艺过程,它结合运用了化学反应和机械磨损。
这是集成电路制造中关键的基础构建步骤,既影响产量又影响生产率。
CMP 概述使用含有氧化剂的悬浮液来完成抛光,该氧化剂通常为过氧化氢 (H2O2)。
在制造过程中,将晶圆压向抛光垫,同时以略微不同的速度逆时针旋转晶圆和抛光垫。
将悬浮液施加到抛光垫的中心,然后通过结合采用机械操作和化学操作来逐步将材料从晶圆表面去除,形成局部和整体均平坦的表面。
使用 CMP 悬浮液前,工厂会将其进行混合或稀释。
购买时,氧化物抛光悬浮液通常是浓缩液的,需要在工作现场用水进行稀释,以减少运输和人工成本。
一些多组分的抛光悬浮液只能在即将使用时混合,因为混合后它们将很快失效。
正确的混合操作是至关重要的,因为它直接影响化学反应速率和晶圆抛光速率;混合液的任何缺陷都会对可制造性和可靠性产生负面影响。
尽管生产点 (POM) 对悬浮液的控制很严格,但运输、搬运和过滤等后续过程都会对其化学性能有所影响,因此需要对悬浮液进行持续监控,直到其抵达使用点(POU),这样才能确保高产量。
为此,制造工厂需要用到有效、快速、可靠、精确和具有成本效益的计量工具和方法,许多工厂都选择使用折光仪。
为什么当需要在钨 CMP 工艺过程中使过氧化氢(H2O2)浓度保持在合格水平时,维萨拉成为了半导体制造工厂的供应商折射率如何辅助提高生产质量?折射率 (RI) 是一种可连续在线测量的参数,且测量过程不消耗悬浮液,它能够反映工艺过程的实时信息,帮助制造厂快速发现悬浮液的成分缺陷,从而降低面临风险的晶圆的数量。
CMP 悬浮液所含有的纳米颗粒的固体含量为 1-30%(取决于悬浮液类型),因此分析时颇有难度。
但是,当按照特定悬浮液的温度/ RI 特性进行了校准后,即使在这些困难的条件下,RI 测量结果也可以成功反映钨悬浮液中的过氧化氢浓度,误差在重量的 ±0.03% 以内。
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NSS Chemistry Part 3 MetalsHKCEE Past Paper Questions – Multiple Choice Questions1. 1995 Q5Which of the following methods can be used to extract lead from lead(II) oxide?A.heating lead(II) oxide in the absence of airB.heating lead(II) oxide in the presence of airC.heating lead(II) oxide with copper at high temperatureD.heating lead(II) oxide with carbon at high temperatureAns: D 2. 1995 Q6Which of the following fertilizers contains the largest percentage by mass of nitrogen?(Relative atomic mass : H = 1.0, N = 14.0, O = 16.0, Na = 23.0, S = 32.0, Cl = 35.5, K = 39.0)A.ammonium chlorideB.ammonium sulphateC.potassium nitrateD. sodium nitrateAns: A3. 1995 Q18Metal X reacts with dilute hydrochloric acid to liberate hydrogen, but metal Y and metal Z have no reaction with the dilute acid. The oxide of metal Y decomposes on heating but the oxide of metal Z does not. Which of the following arrangement represents the order of increasing reactivity of the three metals?A.X < Y < ZB.Y < Z < XC.X < Z < YD.Z < Y < XAns: BA certain amount of silver oxide is he plot of the mass of the contents of theA.C.5. 1996 Q8Zinc blocks are often attached to the s A. zinc can protect steel from corrosi B. zinc is more resistant to corrosion C. zinc is harder than steel. D. zinc does not react with crude oil.6. 1996 Q12Consider the following experiment :After the experiment, the residue in obtained. X may be A. carbon. B. magnesium. C. silver. D. sulphur.e is heated in a test tube. Which of the following grap of the test tube against time?B.D.o the steel legs of off-share oil platforms because orrosion. osion than steel. de oil.ent :ue in the combustion tube is dissolved in water and g graphs represents the correct Ans: CAns: Aer and an alkaline solution is Ans: BWhich of the following statements concerning one mole of nitrogen gas is/are correct?(1)It has a mass of 14.0 g.(2)It occupies the same volume as 4.0 g of helium gas at room temperature and pressure.(3)It contains 6.02×1023 atoms of nitrogen.(Relative atomic masses : He = 4.0, N = 14.0; Avogadro constant = 6.02×1023 mol–1)A.(1) onlyB.(2) onlyC.(1) and (3) onlyD.(2) and (3) onlyAns: B 8. 1997 Q10Which of the following combinations in INCORRECT?Chemical Method of storageA. calcium under waterB. potassium under paraffin oilC. ethanol in a cool placeD. potassium permanganate in a brown bottlesolutionAns: A 9. 1997 Q28What mass of copper is obtained when 0.40 mol of copper(II) oxide are completely reduced by carbon?(Relative atomic masses : O = 16.0, Cu = 63.5)A.12.7 gB.15.9 gC.25.4 gD.31.8 gAns: C10. 1997 Q32Which of the following metal oxides can be reduced to the metal when heated with carbon?(1)aluminium oxide(2)lead(II) oxide(3)iron(III) oxideA.(1) onlyB.(2) onlyC.(1) and (3) onlyD. (2) and (3) onlyAns: DOne mole of sulphur atoms has a mass twice that of one mole of oxygen atoms. Which of the following statement is/are correct?(1)2 g of sulphur and 1 g of oxygen each occupy the same volume at room temperature and pressure.(2)2 g of sulphur and 1 g of oxygen each contain the same number of atoms.(3)The number of atoms contained in one mole of sulphur is twice that contained in one mole of oxygen.A.(1) onlyB.(2) onlyC.(1) and (3) onlyD.(2) and (3) onlyAns: B 12. 1997 Q41Aluminium is used to make window frames because(1)it is strong.(2)it can resist corrosion.(3)it is the most abundant metallic element in the earth crust.Which of the above statements are correct?A.(1) and (2) onlyB.(1) and (3) onlyC.(2) and (3) onlyD.(1), (2) and (3)Ans: A13. 1998 Q10The formula for hydrated iron(II) sulphate is FeSO4⋅xH2O. On strong heating, 20.1 g of the sulphate produces9.1 g of water. What is the value of x?(Relative atomic masses : H = 1.0, O = 16.0, S = 32.1, Fe = 56.0)A. 5B. 6C.7D.8Ans: CConsider the following experiment.During the experiment, a gas is liberat A.copper. B.lead. C. silver. D. zinc.15. 1998 Q19In each of the four solutions shown be Which of the following combinationsTubeObservation A. Ino change B. II brown coating on zinc C. IIIno changeD. IVgrey coating on zinc 16. 1998 Q20 The following equation represents thePb 3O 4(s) + 4H 2(g) 3Pb (s) + 4H What mass of lead would be obtained(Relative atomic mass : O = 16.0, Pb =A. 20.7 g B. 41.4 g C. 62.1 g D. 82.8 gent.iberated. The gas can burn at the end of the delivery tu wn below, a strip of zinc is added.tions is correct? n zinc zincts the reaction of an oxide of lead with hydrogen: + 4H 2O (l)ained if 68.5 g of the oxide was consumed in the reacti 0, Pb = 207.0) ery tube. X is probably Ans: DAns: Creaction? Ans: CIron can be produced from iron(III) oxide by the following reaction:Fe2O3(s) + 3CO(g) 2Fe(s) + 3CO2(g)What mass of iron(III) oxide is required to produce 2.1 g of iron?(Relative atomic masses: O = 16.0, Fe = 56.0)A. 3.0 gB. 4.5 gC. 6.0 gD.9.0 gAns: A18. 1999 Q17The compound X2S contains 58.9% of X by mass. What is the relative atomic mass of X?(Relative atomic mass : S = 32.1)A.11.5B.23.0C.39.0D.46.0Ans: B19. 1999 Q18Which of the following processes would NOT produce hydrogen gas?A.adding calcium to waterB.adding magnesium to dilute hydrochloric acidC.adding copper to dilute nitric acidD.passing steam over red hot ironAns: C20. 1999 Q22In which of the following situations is iron prevented from rusting by sacrificial protection?A.Iron plates are joined together with copper rivets.B.Iron pipes are connected to lead blocks.C.Iron sheets are plated with zinc.D.Iron cans are coated with tin.Ans: CWhich of the following reactions will occur when aluminium powder is added to silver nitrate solution?(1)displacement(2)anodization(3)redoxA.(1) onlyB.(2) onlyC.(1) and (3) onlyD.(2) and (3) onlyAns: C22. 2000 Q3Iron cans used for canning food are usually coated with tin instead of zinc. This is becauseA.tin is more reactive than zinc.B.tin ions are non-toxic but zinc ions are toxic.C.tin forms an alloy with iron and this alloy is corrosion resistant.D.tin prevents iron cans from rusting by sacrificial protection.Ans: B 23. 2000 Q4Metal X forms an oxide. 27.53 g of this oxide contains 24.96 g of X. What is the mole ratio of X to oxygen in the oxide?(Relative atomic masses: O = 16.0, X = 207.0)A. 1 : 1B. 1 : 2C. 2 : 3D. 3 : 4Ans: D24. 2000 Q33In an experiment, a piece of calcium metal was added to a beaker of water. Which of the following statements concerning the experiment is/are correct?(1)The calcium metal sank to the bottom of the beaker.(2)The calcium metal burnt with a brick red flame.(3)At the end of the experiment, an alkaline solution was formed in the beaker.A.(1) onlyB.(2) onlyC.(1) and (3) onlyD.(2) and (3) onlyAns: CConsider the reaction;4H 2(g) + Fe 3O 4(s) 3Fe (s) + 4H What mass of iron would be obtained consumed in the reaction?(Relative atomic mass : Fe = 56.0; mo A. 0.056 g B. 0.084 g C. 0.168 g D. 0.224 g26. 2001 Q26What is the percentage by mass of chr (Relative atomic mass : O = 16.0, K =A. 17.7 B. 25.1 C. 35.4 D. 40.827. 2001 Q30 Which iron nail in the test tubes showA.B.C.D.2O(l)tained if 96.0 cm 3 of hydrogen, measured at room tem 0; molar volume of gas at room temperature and press of chromium in potassium dichromate? 0, K = 39.1, Cr = 52.0) shown below would rust most slowly? B.D.m temperature and pressure, is pressure = 24 dm 3) Ans: CAns: CAns: CWhich of the following statement correctly describe(s) the advantages(s) of using aluminium over iron to make soft drink cans?(1)Aluminium is stronger than iron.(2)Aluminium is less dense than iron.(3)Aluminium is more corrosion-resistant than iron.A.(1) onlyB.(2) onlyC.(1) and (3) onlyD.(2) and (3) onlyAns: D29. 2001 Q38In which of the following experiments would a metal be produced?(1)heating silver oxide(2)heating iron pyrite(3)heating a mixture of lead(II) oxide and carbon powderA.(1) and (2) onlyB.(1) and (3) onlyC.(2) and (3) onlyD.(1), (2) and (3)Ans: B 30. 2002 Q3An oxide of element X has the formula X2O3. 10.2 g of this oxide contains 5.4 g of X. What is the relative atomic mass of X?(Relative atomic mass : O = 16.0)A.12.0B.18.0C.27.0D.36.0Ans: C31. 2002 Q8Which of the following statements concerning aluminium is correct?A.Aluminium is used to make stainless steel.B.The strength of aluminium can be enhanced by anodization.C.Aluminium is the most abundant element in the earth’s crust.D.When aluminium is exposed to air, a layer of aluminium oxide is formed on its surface.Ans: DAmmonium dichromate, (NH4)2Cr2O7, decomposes on heating to give chromium(III) oxide, water and nitrogen.What mass of water is obtained when 126 g of ammonium dichromate undergoes complete decomposition?(Relative atomic masses : H = 1.0, N = 14.0, O = 16.0, Cr = 52.0)A.9 gB.18 gC.36 gD.72 gAns: C33. 2002 Q26When a piece of copper is dropped into an aqueous solution of compound X, the copper gradually dissolves. X is probablyA.magnesium chloride.B.lead(II) nitrate.C.silver nitrate.D.ammonium chloride.Ans: C34. 2002 Q27Which of the following objects is least likely to contain titanium?A.missileB.water tapC.bicycle frameD.artificial hip jointAns: B 35. 2003 Q3When a small piece of calcium metal is put into a trough of water, a reaction occurs. Which of the following statements concerning this reaction is correct?A. It is an endothermic reactionB. It is a redox reactionC. A slight explosion occurs.D. The calcium metal burns spontaneously in water.Ans: B36. 2003 Q5Which of the following methods can be used to obtain aluminium from aluminium oxide?A. reducing the oxide with carbonB. heating the oxide strongly.C. electrolysis of the molten oxideD. heating the oxide with iron powder.Ans: CWhich iron nail in the beakers shownA.C.38. 2003 Q11A sample of MgSO 4⋅xH 2O (s) of mass 1(Relative atomic masses: H = 1.0,A.4 B.5 C.6 D. 739. 2003 Q42Iron pyrite (FeS 2) looks like gold and be used to distinguish iron pyrite from (1) comparing their densities(2) comparing their electrical conduct (3) comparing the effect of heat on thA. (1) and (2) onlyB. (1) and (3) onlyC. (2) and (3) onlyD. (1), (2) and (3)hown below would undergo corrosion most readily?B.D.mass 123.2 g contains 63.0 g of water of crystallization = 1.0, O = 16.0, Mg = 24.3, S = 32.1) d and its common name is “fool’s gold”. Which of th e from gold? onductivity on themAns: Bzation. What is the value of x? Ans: Dof the following methods can Ans: DThe relative atomic masses of hydrogen and oxygen are 1.0 and 16.0 respectively. Which of the following statements concerning 36.0 g of water is correct?(Molar volume of gas at room temperature and pressure = 24 dm3; Avogadro constant = 6.02×1023 mol-1)A. It contains 4 mol of hydrogen atoms.B. It contains 3×6.02×1023atomsC. It contains 6×6.02×1023 molecules.D. It has a volume of 48 dm3 at room temperature and pressure.Ans: A41. 2004 Q12The relative atomic mass of element X is 7439. It forms an oxide containing 24.3 % of oxygen by mass. What is the mole ratio of X to oxygen in the oxide?(Relative atomic mass: O = 16.0)A. 1:2B. 1:3C. 2:3D. 2:5Ans: C 42. 2004 Q16Magnesium can be obtained from magnesium oxide byA. electrolysis of the molten oxide.B. heating the oxide strongly.C. heating the oxide with carbon.D. heating the oxide with zinc powder.Ans: A43. 2004 Q26What is the percentage by mass of nitrogen in the fertilizer (NH4)2HPO4?(Relative atomic masses: H = 1.0, N = 14.0, O = 16.0, P = 31.0)A. 10.6 %B. 12.3 %C. 21.2 %D. 24.6 %Ans: CDirections : Questions 44 and 45 refer to the following experiment.Rust indicator solution was poured into the following glass dishes to cover the iron nails, which were wrapped with different metal strips. The dishes were allowed to stand in air for some time.silver strip dish 1zinc strip dish 2copper strip dish 3magnesium stripdish 444. If the iron nail rusts, what would the colour of the rust indicator be around the nail ?A. yellowB. brownC. redD. blueAns: D45. In which of the dishes would the iron nail rust?A. dish 1 onlyB. dish 2 onlyC. dish 1 and dish 3 onlyD. dish 2 and dish 4 onlyAns: C46. 2005 Q36Which of the following properties of Group I elements decreases down the group?A. melting pointB. reducing powerC. reactivityD. tendency to form cationsAns: AMethane burns completely in oxygen according to the following equation:CH 4 + 2O 2 → CO 2 + 2H 2OWhat is the mass of oxygen required for the complete combustion of 48 g of methane? (Relative atomic mass: H = 1.0, C = 12.0, O = 16.0) A. 48 g B. 96 g C. 192 g D. 384 gAns: C48. 2006 Q9Which of the following properties is considered the most important one when choosing an alloy for making fuse in electric plugs?A. low melting pointB. high electricity conductivityC. good ductilityD. high mechanical strengthAns: A49. 2006 Q13X and Y are two different metals. Which of the following shows that Y is more reactive than X ?A. X forms an ion with a charge of +2 while Y forms an ion with a charge of +1.B. X reacts with dilute hydrochloric acid but Y does not.C. X can displace Y from an aqueous solution of a salt of Y .D.The oxide of X undergoes decomposition upon strong heating but the oxide of Y does not.Ans: D50. 2006 Q18Element X forms two oxides XO and XO 2. If 1 mole of XO contains n atoms, 2 moles of XO 2 would contain A.23n atoms. B. 2n atoms. C. 3n atoms. D. 6n atoms.Ans: CThe relative atomic mass of metal X is 55.8. 23.90 g of X is allowed to react with excess oxygen until X is completely oxidised. The mass of the metal oxide obtained is 34.18 g. What is the empirical formula of the oxide?(Relative atomic mass: O = 16.0)A. XOB. X2O3C. X3O2D. X3O4Ans: B 52. 2006 Q41Metal X forms an oxide with the formula X2O. Upon strong heating, the oxide undergoes decomposition according to the following equation:2X2O(s) → 4X(s) + O2(g)Complete decomposition of 2.90 g of the oxide gives 150 cm3 of oxygen, measured at room temperature and pressure. What is the relative atomic mass of X?(Relative atomic mass: O = 16.0;molar volume of gas at room temperature and pressure = 24 dm3)A. 54.0B. 108.0C. 216.0D. 232.0Ans: B 53. 2007 Q7X, Y and Z are metals. The table below shows the observations when each of them is put into copper(II) sulphate solution:Metal ObservationX no observable changeY brown solid formed and colourless gas evolvedZ brown solid formedWhich of the following arrangements correctly represents the ascending order of reactivity of the metals?A.X < Z < YB.Y < Z < XC.Z < X < YD.X < Y < ZAns: AHow many moles of ethane contain y hydrogen atoms?(L represents the Avogardo’s constant.)A.y / LB.L / yC.y / 6LD.6y / LAns: C55. 2007 Q34What mass of iron can be obtained by complete reduction of 7.18 g of iron(III) oxide?(Relative atomic masses: Fe = 55.87, O = 16.0)A. 2.51 gB. 3.86 gC. 5.02 gD. 5.58 gAns: C 56. 2007 Q35Different metals are dropped into water or dilute hydrochloric acid. Assuming that the experimentalconditions are the same, which of the following comparisons concerning the initial rates of hydrogenformation is correct?Initial rate of hydrogenformation Initial rate of hydrogenformationA. Ca and H2O > Ba and HClB. Fe and HCl > K and H2OC. K and H2O > Cs and H2OD. Cs and H2O > Ca and H2OAns: D57. 2008 Q12Green patches appear on the surface of a metallic statue in a museum. It can be deduced that the statue may containA. tin.B. iron.C. silver.D. copper.Ans: DThe oxidation number of metal M in its oxide is +2. Complete reduction of 11.9 g of this oxide by hydrogen gas produces metal M and 2.7 g of water. What is the relative atomic mass of M ? (Relative atomic masses : H = 1.0, O = 16.0) A. 9.3 B. 24.3 C. 63.3 D. 137.3Ans: C59. 2008 Q20 A small piece of potassium is dropped into a trough of water containing methyl orange. Which of the following observations is / are correct?(1) The potassium moves about on the water surface with a hissing sound. (2) The potassium dissolves in water and the solution turns red. (3) The potassium burns with a golden yellow flame. A. (1) only B. (2) only C. (1) and (3) onlyD. (2) and (3) onlyAns: A60. 2008 Q31 Organic compound Q has the following composition by mass : C : 37.5%H : 12.5%O : 50.0%What is the possible chemical formula of Q ? (Relative atomic masses : H = 1.0, C = 12.0, O = 16.0) A. OH CH 3 B. OH H C 52 C. HCOOH D.COOH CH 3Ans: A61. 2008 Q34 From which of the following processes can lead be obtained in a school laboratory? A. Lead(II) oxide is heated strongly. B. Lead(II) oxide is mixed with carbon. C. Dilute lead(II) nitrate solution is electroylsed. D. Zinc is added to dilute lead(II) nitrate solution.Ans: DWhat is the percentage by mass of oxygen in Na2CO3‧10H2O?(Relative atomic masses: H = 1.0, C = 12.0, O = 16.0, Na = 23.0)A. 72.7B. 55.9C. 22.4D. 16.8Ans: A 63. 2009 Q6Which of the following rust prevention methods does NOT match with the iron-made object?Rust prevention method Iron-made objectA. painting gateB. greasing machinery partsC. zinc plating food canD. chromium plating car bumperAns: C 64. 2009 Q20Which of the following half equations are involved when iron rusts?(1) Fe → Fe3++3e-(2) Fe → Fe2++2e-(3) Fe2+ → Fe3++e-A. (1) and (2) onlyB. (1) and (3) onlyC. (2) and (3) onlyD. (1), (2) and (3)Ans: C 65. 2009 Q33An oxide of metal M reacts completely with carbon to give 12.6 g of metal M and 2.38 dm3 of carbon dioxide measured at room temperature and pressure. What is the chemical formula of the oxide?(Relative atomic masses: M=63.5, O= 16.0;Molar volume of gas at room temperature and pressure = 24 dm3)A. M OB. M O2C. M2OD. M2O3Ans: AAnodised aluminium is more commonly used than iron for making window frames. This is because(1) the cost for extracting aluminium is lower than the cost for extracting iron.(2) anodised aluminium is more corrosion resistant than iron.(3) anodised aluminium is harder than iron.A. (1) onlyB. (2) onlyC. (1) and (3) onlyD. (2) and (3) onlyAns: B67. 2009 Q46Which of the following information is needed in order to deduce the molecular formula of a compound from its empirical formula?(l) relative molecular mass of the compound(2) percentage by mass of each constituent element(3) relative atomic mass of each constituent elementA. (1) and (2) onlyB. (1) and (3) onlyC. (2) and (3) onlyD. (1), (2) and (3)Ans: B68. 2009 Q47Which of the following statements concerning the anodisation of an aluminium object are correct?(1) The electrolyte used can be dilute sulphuric acid.(2) A layer of aluminium oxide is formed on the surface of the object.(3) The aluminium object should be connected to the negative terminal of the power supply.A. (1) and (2) onlyB. (1) and (3) onlyC. (2) and (3) onlyD. (1), (2) and (3)Ans: A69. 2010 Q14What mass of methane upon complete combustion gives 0.90 g of water ?(Relative atomic masses: H= 1.0, C= 12.0, O = 16.0)A. 0.40 gB. 0.45 gC. 0.75 gD. 0.80 gAns: AThe oxide of metal Z reacts with dilute hydrochloric acid to form a colourless solution. Which of the following metals may Z be?(1) zinc(2) copper(3) silverA. (1) onlyB. (2) onlyC. (1) and (3) onlyD. (2) and (3) onlyAns: A71. 2010 Q26Which of the following safety measures should be taken when investigating the reaction between sodium and water ?(1) Use forceps to pick sodium.(2) Use a small piece of sodium.(3) Use a small amount of water.A. (1) and (2) onlyB. (1) and (3) onlyC. (2) and (3) onlyD. (1), (2) and (3)Ans: A72. 2010 Q33A certain oxide of manganese contains 49.5% of manganese by mass. What is the empirical formula of thisoxide ?(Relative atomic masses : O = 16.0, Mn = 54.9)A. MnOB. MnO2C. Mn2O3D. Mn2O7Ans: D。