On Bayesian Estimation of Spectral Components for Broadband Noise Reduction in Audio Signal
基于稀疏贝叶斯学习的多频带雷达信号融合
基于稀疏贝叶斯学习的多频带雷达信号融合叶钒;何峰;梁甸农;朱炬波【摘要】针对多频带雷达信号融合,建立了多频带雷达信号表示模型,将多频带信号融合问题等价于一个信号表示问题。
研究了基追踪算法在多频带信号融合中的局限性,研究表明:由于多个频带的稀疏分布,破坏了字典的相干性,使得基追踪算法可能无法收敛到真实的稀疏解。
提出了基于稀疏贝叶斯学习的多频带信号融合方法,并证明了字典满足唯一表示性条件从而可以保证算法收敛到真实的稀疏解。
实验表明:基于稀疏贝叶斯学习的多频带信号融合方法能够更加真实地反映目标散射特性。
【期刊名称】《电波科学学报》【年(卷),期】2010(000)005【总页数】5页(P990-994)【关键词】多频带雷达信号融合;稀疏贝叶斯学习;基追踪【作者】叶钒;何峰;梁甸农;朱炬波【作者单位】国防科技大学电子科学与工程学院,湖南长沙410073【正文语种】中文【中图分类】TN9571.引言多频带雷达信号融合处理利用多部雷达在相同视角从不同频带获取目标的一维雷达观测信号,通过信号级的稀疏频带相干融合,提高雷达距离向分辨率[1-3]。
它打破了传统的单雷达成像距离分辨率受限于单部雷达带宽的约束,可明显改善一维距离像质量。
传统的雷达信号融合技术主要为基于谱估计类的融合方法,例如多重信号分类方法(MUSIC)[4]以及修正的求根多重信号分类(Root-MUSIC)方法[2]、矩阵增强矩阵束(MEMP)方法[5]、状态空间方法[6]等。
虽然这些方法的参数估计精度高,但是需要已知目标散射点个数,这在实际处理中往往是无法做到的。
虽然存在众多模型阶数的估计方法,例如最小描述长度(MDL)方法[7]和bootstrap[8]方法,但是估计精度受噪声的影响很大。
而基于自回归(AR)模型[3]、自回归积分滑动平均(ARIMA)模型[9]以及基于正则化[10]的外推内插方法,虽然对模型阶数相对不敏感、但是内插带宽的长度有限,不适合于稀疏子带信号融合[3]。
Estimation of evolutionary spectrum based on short time Fourier transform and modified grou
time-varying systems driven by stationary random noise [12,1]. The proposed estimator has been found to have good performance for both types of signals.
1. Introduction
In general, signals found in practice like speech, seismic, biomedical signals like EEG, communication signals like frequency shift keying, radar returns which involve Doppler shift, etc., display
AbstБайду номын сангаасact
This paper proposes a new estimator for evolutionary spectrum (ES) based on short time Fourier transform (STFT) and modified group delay function (GDFM). The STFT due to its built-in averaging suppresses the crossterms and the GDFM preserves the frequency resolution of the rectangular window as it reduces the Gibbs ripple without using any window function. The new estimator is applicable to random signals as the GDFM removes the effect of the zeros due to input noise driving the time-varying system and provides the system information effectively. The GDFM also provides signal-to-noise ratio enhancement as it removes the zeros due to the associated noise. The performance of the method is illustrated for linear chirp signals, frequency shift keying and for time-varying random process which indicate that its frequency resolution is better than evolutionary periodogram (EP) and STFT and nearer to that of Wigner Ville distribution. Further, its noise immunity is better than those of EP and STFT. r 2004 Elsevier B.V. All rights reserved.
新凯恩斯DSGE的推导模拟
[经济学模型] DSGE模型讨论之八——新凯恩斯DSGE的推导,模拟,频谱分析和参数估计(初级难度)这个帖子难度为初级。
此处下载note附件:BNK_corrected1.pdf (383.44 KB)这个新凯恩斯DSGE模型是根据Jordi Gali教材的第三章修改而来的。
包括了3个核心方程,如下图第一个是:Euler equation第二个是:New Keynesian Phillips Curve第三个是:Taylor Rule其中新凯恩斯菲利普斯曲线的推导最为复杂,最简化的版本都有至少40个步骤以上的推导。
Optimisation的方法我全部用的Lagrangian,没有用任何动态规划的内容。
推导模型和建立模型一样重要。
当你自己要做研究的时候,你往往要修改别人的模型,加入和减去一些成分,所以一般自己都要重新推导整个模型,如果你对benchmark(标尺)模型非常熟练,你才会知道什么地方可以添加新东西,什么地方添加新东西也没有意义(因为推导过程中那个部分会被消掉)。
在能够独立做研究之前,都是要熟悉推导很多个(如果你非要我给数字,我会说至少100个)标尺模型及变种版本,才会有能力建立和推导自己的模型.同时我做了最大似然估计和贝叶斯估计,用的数据是Euro area的GDP per capita, CPI 和 3 month interest rate。
这些数据都要经过处理才能喂给DSGE模型。
人均GDP要用先log difference,用AR(4)预测延长4期,回到未差分数据,然后HP滤波,剔掉trend。
然后三个时间序列都要demean,意思就是全部观测值减去均值。
这个根据是来自"Frisch-Waugh-Lovell theorm"。
然后做Spectral analysis(物理学上叫光谱分析)。
我是用IRIS工具箱做得,这个Matlab 工具箱是新西兰中央银行的一个项目,专门用来模拟和估计DSGE模型,学习门槛比Dynare 高很多,需要有一定的编程基础才能看懂代码。
地统计与遥感---专业英语词汇
地统计以及遥感英文词汇300个:gray level co-occurrence matrix algorithm灰度共生矩阵算法characteristic of atmospheric transmission 大气传输特性earth resources technology satellite,ERTS 地球资源卫星Land-use and land-over change 土地利用土地覆盖变化Multi-stage stratified random sample 多级分层随机采样Normalized Difference Vegetation Index归一化植被指数Soil-Adjusted Vegetation Index土壤调整植被指数Modified Soil-Adjusted Vegetation Index修正土壤调整植被指数image resolution ,ground resolution影象分辨力(又称“象元地面分辨力”。
指象元地面尺寸。
) remote sensing information transmission遥感信息传输remote sensing information acquisition遥感信息获取multi- spectral remote sensing technology多光谱遥感技术Availability and accessibility 可用性和可获取性Association of Geographic Information (AGI) 地理信息协会Difference Vegetation Index差值植被指数image quality 影象质量Enhanced Vegetation Index增强型植被指数Ratio Vegetation Index比值植被指数Spatial autocorrelation 空间自相关Lag Size 滞后尺寸Ordinary kriging 普通克里金Indicator kriging 指示克里金Disjunctive kriging 析取克里金Simple kriging 简单克里金Bivariate normal distributions 双变量正态分布Universal kriging 通用克里金conditional simulation 条件模拟image filtering 图像滤波optimal sampling strategy 最优采样策略temporal and spatial patterns 时空格局Instantaneous field-of-view瞬时视场角azimuth 方位角wavelet transform method 小波变换算法priori probability 先验概率geometric distortion 几何畸变active remote sensing主动式遥感passive remote sensing 被动式遥感multispectral remote sensing多谱段遥感multitemporal remote sensing 多时相遥感infrared remote sensing 红外遥感microwave remote sensing微波遥感quantizing,quantization量化sampling interval 采样间隔digital mapping数字测图digital elevation model,DEM 数字高程模型digital surface model,DSM 数字表面模型solar radiation spectrum太阳辐射波谱atmospheric window 大气窗atmospheric transmissivity大气透过率atmospheric noise 大气噪声atmospheric refraction 大气折射atmospheric attenuation 大气衰减back scattering 后向散射annotation 注解spectrum character curve 波谱特征曲线spectrum response curve 波谱响应曲线spectrum feature space波谱特征空间spectrum cluster 波谱集群infrared spectrum 红外波谱reflectance spectrum反射波谱electro-magnetic spectrum 电磁波谱object spectrum characteristic地物波谱特性thermal radiation 热辐射microwave radiation微波辐射data acquisition数据获取data transmission数据传输data processing 数据处理ground receiving station地面接收站environmental survey satellite环境探测卫星geo-synchronous satellite地球同步卫星sun-synchronous satellite太阳同步卫星satellite attitude卫星姿态remote sensing platform 遥感平台static sensor 静态传感器dynamic sensor动态传感器optical sensor光学传感器microwave remote sensor微波传感器photoelectric sensor光电传感器radiation sensor辐射传感器satellite-borne sensor星载传感器airborne sensor机载传感器attitude-measuring sensor 姿态测量传感器image mosai图象镶嵌c image digitisation图象数字化ratio transformation比值变换biomass index transformation生物量指标变换tesseled cap transformation 穗帽变换reference data 参照数据image enhancement 图象增强edge enhanceme边缘增强ntedge detection边缘检测contrast enhancement反差增强texture enhancement 纹理增强ratio enhancement 比例增强texture analysis 纹理分析color enhancement 彩色增强pattern recognition 模式识别classifier 分类器supervised classification监督分类unsupervised classification非监督分类box classifier method 盒式分类法fuzzy classifier method 模糊分类法maximum likelihood classification最大似然分类minimum distance classification最小距离分类Bayesian classification 贝叶斯分类Computer-assisted classification机助分类illumination 照度principal component analysis 主成分分析spectral mixture analysis 混合像元分解fuzzy sets 模糊数据集topographic correction 地形校正ground truth data 地面真实数据Tasselled cap 缨帽变换Artificial neural networks 人工神经网络Visual interpretation 目视解译accuracy assessment 精度评价Omission error漏分误差commission error 错分误差Multi-source data 多源数据heterogeneous 非均质的Training sample 训练样本ancillary data 辅助数据dark-object subtraction 暗目标相减法discriminant analysis 判别分析‘salt and pepper’ effects 椒盐效应spectral confusion光谱混淆Cluster sampling 聚簇采样systematic sampling 系统采样Error matrix误差矩阵hard classification 硬分类Soft classification 软分类decision tree classifier 决策树分类器Spectral angle classifier 光谱角分类器support vector machine支持向量机Fuzzy expert system 模糊专家系统endmember spectral端元光谱Future extraction 特征提取image mosaic图像镶嵌density slicing密度分割least squares correlation 最小二乘相关data fusion 数据融合Image segmentation图像分割urban remote sensing 城市遥感atmospheric remote sensing大气遥感geomorphological remote sensing地貌遥感ground resolution地面分辨率ground date processing system地面数据处理系统ground remote sensing地面遥感object spectrum characteristic地物波谱特性space characteristic of object地物空间特性geological remote sensing地质遥感multispectral remote sensing多光谱遥感optical remote sensing technology光学遥感技术ocean remote sensing海洋遥感marine resource remote sensing海洋资源遥感aerial remote sensing航空遥感space photography航天摄影space remote sensing航天遥感infrared remote sensing红外遥感infrared remote sensing technology红外遥感技术environmental remote sensing环境遥感laser remote sensing激光遥感polar region remote sensing极地遥感visible light remote sensing可见光遥感range resolution空间分辨率radar remote sensing雷达遥感forestry remote sensing林业遥感agricultural remote sensing农业遥感forest remote sensing森林遥感water resources remote sensing水资源遥感land resource remote sensing土地资源遥感microwave emission微波辐射microwave remote sensing微波遥感microwave remote sensing technology微波遥感技术remote sensing sounding system遥感测深系统remote sensing estimation遥感估产remote sensing platform遥感平台satellite of remote sensing遥感卫星remote sensing instrument遥感仪器remote sensing image遥感影像remote sensing cartography遥感制图remote sensing expert system遥感专家系统active remote sensing主动式遥感passive remote sensing被动式遥感resource remote sensing资源遥感ultraviolet remote sensing紫外遥感attributive geographic data 属性地理数据attributes, types 属性,类型Geographic database types 地理数据库类型attribute data 属性数据Geographic individual 地理个体Geographic information (GI) 地理信息Exponential transform指数变换false colour composite 假彩色合成Image recognition 图像识别image scale 图像比例尺Spatial frequency 空间频率spectral resolution 光谱分辨率Logarithmic transform对数变换mechanism of remote sensing 遥感机理adret 阳坡beam width波束宽度biosphere生物圈curve fitting 曲线拟合geostationary satellite对地静止卫星glacis缓坡Field check 野外检查grating 光栅gray scale 灰阶Interactive 交互式interference干涉inversion 反演Irradiance 辐照度landsatscape 景观isoline 等值线Lidar激光雷达landform analysis地形分析legend 图例Map projection地图投影map revision地图更新Middle infrared中红外Mie scattering 米氏散射opaco 阴坡orbital period 轨道周期Overlap重叠parallax 视差polarization 极化Phase 相位pattern 图案quadtree象限四分树Radar returns雷达回波rayleigh scattering 瑞利散射reflectance 反射率Ridge山脊saturation 饱和度solar elevation太阳高度角Subset 子集telemetry遥测surface roughness表面粗糙度Thematic map专题制图thermal infrared热红外uniformity均匀性Upland 高地vegetal cover 植被覆盖watershed流域White plate白板zenith angle天顶角radiant flux 辐射通量Aerosol 气溶胶all weather 全天候angle of field 视场角Aspect 坡向atmospheric widow大气窗口atmospheric 大气圈Path radiance 路径辐射binary code二进制码black body 黑体Cloud cover云覆盖confluence 汇流点diffuse reflection漫反射Distortion畸变divide分水岭entropy熵meteosat气象卫星bulk processing粗处理precision processing精处理Bad lines 坏带single-date image单时相影像Decompose 分解threshold 阈值relative calibration 相对校正post-classification 分类后处理Aerophotograph 航片Base map 底图muti-temporal datasets 多时相数据集detector 探测器spectrograph 摄谱仪spectrometer 波谱测定仪Geostatistics 地统计Semivariogram 半方差sill 基台Nugget 块金Range 变程Kriging 克里金CoKriging 共协克里金Anisotropic 各向异性Isotropic 各向同性scale 尺度regional variable 区域变量transect 横断面Interpolation 插值heterogeneity 异质性texture 纹理digital rectification数字纠正digital mosaic 数字镶嵌image matching影像匹配density 密度grey level灰度pixel,picture element 象元target area目标区searching area 搜索区Spacelab 空间实验室space shuttle航天飞机Landsat陆地卫星Seasat 海洋卫星Mapsat测图卫星Stereosat 立体卫星aspatial data 非空间数据。
XANES测定吸附态P在水铁矿和水铝石混合物之间的分布
XANES Determination of Adsorbed Phosphate Distribution between Ferrihydriteand Boehmite in MixturesNidhi Khare,Dean Hesterberg,*Suzanne Beauchemin,and Shan-Li WangABSTRACT centration in runoff water was positively correlated withsoil P concentration,and this relationship was soil spe-Iron-and Al-(hydr)oxide minerals are important sorbents for re-cific(Sharpley,1995;Pote et al.,1996).Being able to taining PO4in soils.Our objective was to determine the distributionof adsorbed PO4between ferrihydrite and boehmite in aqueous mix-predict PO4dissolution and mobility in different soils tures of these minerals.Phosphate was adsorbed in aqueous suspensions or under varying soil conditions would help in devel-up to maximum concentrations of1860,850,and1420mmol kgϪ1for oping soil management practices that decrease detri-ferrihydrite,boehmite,and1:1(by mass)mixtures of these minerals mental environmental impacts of P.Phosphate specia-at pH6.The solids were analyzed as moist pastes using P K-XANES tion,that is,the chemical forms of PO4in a soil,dictates(X-ray absorption near edge structure)spectroscopy.The adsorption the effects of soil PO4concentration,mineralogy,pH,isotherm for the mixed-mineral suspensions could essentially be de-and redox potential on PO4binding and dissolution. scribed as a linear combination of Freundlich isotherm models forPhosphate adsorption in soils has been correlated each single-mineral system,indicating negligible mineral interactivewith a number of indices derived from chemical extrac-effects on PO4adsorption in the mixtures.X-ray absorption near edgestructure spectra for PO4adsorbed on ferrihydrite or in ferrihydrite/tions(Beauchemin and Simard,1999).For example,the boehmite mixtures showed a pre-edge feature at approximately2146PO4sorption capacity of soils has been related to various eV that was absent in boehmite systems.Linear combination fitting indices based on acid-oxalate extractable Fe and Al, of the pre-edge region of XANES spectra for mixtures with average suggesting that poorly crystalline Fe-and Al-oxides arespectra for PO4adsorbed on boehmite or ferrihydrite alone,indicated largely responsible for PO4retention in acidic soilsthat59to97%of the PO4was adsorbed on ferrihydrite in the mixtures.(Beauchemin and Simard,1999).Similarly,chemical ex-With increasing concentration of adsorbed PO4in the mineral mix-traction analyses of Sallade and Sims(1997)suggested tures,the concentration adsorbed on the ferrihydrite component in-that PO4in sediments collected from drainage ditches creased linearly.Phosphate distribution trends in the mixtures sug-adjacent to agricultural fields was associated with Fe-gested an affinity preference for ferrihydrite at the lowest adsorbedPO4concentration(100mmol kgϪ1minerals),no affinity preference and Al-oxide minerals.Ferrihydrite,a poorly crystalline for either mineral at intermediate concentrations(200to600mmol Fe-oxide mineral is often found in sediments or hydro-PO4kgϪ1),and the possibility of a surface precipitate involving Al at morphic soils as a precursor of other Fe-oxide minerals the highest concentration(1300mmol PO4kgϪ1).(Schwertmann and Cornell,1991).Furthermore,trans-mission electron microscopy with energy dispersiveX-ray analysis(TEM/EDX)showed association of PO4 P hosphorus has been intensively studied due to its with Al and Fe in isolated particles from different soils importance as a plant macronutrient,and more re-(Pierzynski et al.,1990a,1990b)cently because of its negative role in the eutrophication Phosphate dissolution in soils may depend on theof surface waters.In deep sandy soils,soils rich in or-relative distribution of PO4between Fe-and Al-oxideganic matter,or soils with elevated P concentrations from minerals.For example,dissolution of PO4during soillong-term fertilization,P can also be leached through the reduction has been explained by release of PO4associ-soil profile and eventually be discharged with subsurface ated with Fe(III)-phosphate and Fe(III)-oxide minerals flow to surface waters(Sims et al.,1998).Soil P has(Patrick et al.,1973;Hongve,1997;Reddy et al.,1998). recently gained much attention due to the USDA-However,Al-oxide minerals are considered redox inac-USEPA policy to limit P input with animal waste and tive,so any associated PO4should be less susceptiblefertilizers(Sharpley et al.,2000).to release during soil reduction.Soil P concentration,soil matrix composition(e.g.,One barrier to evaluating such hypotheses is the lack mineralogy,and organic matter content),pH,and redoxof a direct method for quantifying PO4distribution be-potential are considered to be the main soil propertiestween Fe-and Al-oxide minerals when these minerals affecting PO4dissolution and mobility.Phosphate typi-occur as a mixture(as in soils).Past research characteriz-cally binds strongly with soils.However,dissolved P con-ing PO4adsorption in mineral mixtures specifically ka-olinite and goethite used equilibrium adsorption iso-N.Khare,D.Hesterberg,and S.L.Wang,Dep.of Soil Science,Box therms and kinetic measurements(Ioannou et al.,1998; 7619,North Carolina State University,Raleigh,NC27695-7619;S.Papadopoulos et al.,1998).However,definitive infor-Beauchemin,Natural Resources Canada,CANMET,555Booth St.,mation about the distribution of PO4between these two Office332A,Ottawa,ON,KIA0G1.S.L.Wang currently at Dep.ofSoil and Environ.Sci.,National Chung Hsing University,Taichung,minerals could not be obtained from empirical modeling 402,Taiwan.N.Khare currently at Dep.of Geology and Geophysics,(Langmuir and Freundlich fits)of the macroscopic ad-University of Wyoming,Laramie,WY82071.Received13Jan.2003.sorption data.In this research,we characterized the *Corresponding author(dean_hesterberg@).Published in Soil Sci.Soc.Am.J.68:460–469(2004).Soil Science Society of America Abbreviations:LCF,linear combination fitting;XANES,X-ray ab-sorption near-edge structure.677S.Segoe Rd.,Madison,WI53711USA460XANES测定吸附态P在水铁矿和水铝石混合物之间的分布KHARE ET AL.:ADSORBED PHOSPHATE DISTRIBUTION DETERMINED BY XANES4612.2,and10nm along the crystal a,b,and c axes respectively, distribution of PO4between ferrihydrite and boehmiteand the Brunauer–Emmett–Teller(BET)H2O surface area using P K-XANES analysis.reported for this mineral was514m2gϪ1(Wang et al.2003). Hesterberg et al.(1999)identified unique features inWater adsorption was previously used to avoid sample drying P K-XANES spectra of strengite(FePO4·2H2O)andand because this small polar molecule can access the internal variscite(AlPO4·2H2O)that indicated the possibility ofsurfaces present in a poorly crystalline material such as boehm-distinguishing adsorbed PO4in mixed Fe-and Al-oxideite(Wang et al.2003).Because a temperature-induced struc-systems.For example,due to electron orbital configura-tural change in poorly crystalline materials(such as boehmite tions and electronic transitions at the X-ray absorption and ferrihydrite)has been observed at100to110ЊC(Wangedge,PO4associated with Fe(III)and some other transi-et al.,2003),the N2BET surface areas of these minerals weretion metals in PO4minerals produces a distinct pre-edge not measured.feature on the low energy side of an intense white-line peak near2150eV in the P K-XANES spectrumAdsorption Isotherms(Behrens,1992;Hesterberg et al.,1999;Franke andHormes,1995;Okude et al.,1999).This feature is absent Adsorption isotherm experiments for ferrihydrite,boehm-in spectra of Al phosphates.Because of the ability of ite,and mixed ferrihydrite-boehmite(1:1mass ratio)suspen-sions were conducted at pH6.0in250-mL polycarbonate cen-XANES to distinguish PO4bound to Fe(III)versustrifuge bottles following the basic procedure described by Oh Al(III),this technique was considered suitable for char-et al.(1999).acterizing PO4on Fe-and Al-oxide minerals.All samples had a suspended solids concentration of1.50g The objective of this research was to utilize XANESkgϪ1,constant ionic strength of0.01mol LϪ1KCl,and total spectroscopy to quantify the distribution of PO4be-sample mass of133.34Ϯ0.01g.Aqueous solutions for adsorp-tween ferrihydrite and boehmite in mixtures of thesetion experiments(KCl,HCl,KOH,and KH2PO4,all at0.01 minerals,and thereby determine the relative affinity ofmol LϪ1concentrations)were prepared using analytical grade PO4for each mineral in the mixture.Two-line ferrihy-reagents and degassed(heated and N2purged)deionized wa-drite(Fe5HO8·4H20)and poorly crystalline boehmite ter.Stock mineral suspensions were shaken on a reciprocating(␥-AlOOH)were chosen because we expected that their shaker at a rate of1sϪ1for at least1h before use.Two to eight high(and comparable)PO4sorption capacities(relative grams of ferrihydrite,boehmite,or a1:1(by mass)mixture of to,e.g.,goethite and gibbsite)would allow better detec-ferrihydrite and boehmite prepared gravimetrically from stock tion of subtle changes in XANES spectra of the mix-suspensions were weighed while vigorously stirring a stock tures.Ferrihydrite is representative of poorly crystalline suspension on a magnetic stirrer,and brought to about70% Fe-(hydr)oxides in soils,and boehmite is a finely di-of the final sample mass with0.01mol LϪ1KCl.An appropriatealiquot of0.01mol LϪ1KH2PO4was slowly added to each vided,crystalline analog of noncrystalline Al hydroxidesvigorously stirred sample in random chronological order using in soils.a micropipetter.The pH was adjusted to pH6.0using0.01mol LϪ1HCl or0.01mol LϪ1KOH,and the sample headspaceMATERIALS AND METHODS was flushed with N2gas.Samples were shaken for42h on areciprocating water bath shaker at a rate of0.5sϪ1and22ЊC.Mineral Synthesis and CharacterizationKinetics of PO4sorption is complex,and this operationally Two-line ferrihydrite was synthesized by hydrolyzing Fe(III)chosen time of42h should be sufficiently long to complete with KOH according to the method of Schwertmann and Cor-fast sorption reactions(Li and Stanforth,2000).nell(1991)and aging for6mo before use.Poorly crystalline After about16h of shaking,the pH varied by an average boehmite was purchased from Reheis Co.(Berkeley Heights,of0.2units and was again adjusted to pH6.0and each sample NJ)in gel form under the trade name Rehydragel HPA.Both was brought to its final mass.The pH was again checked after ferrihydrite and boehmite were analyzed before experiments40h of equilibration and minor adjustments(usuallyϽ0.1 using X-ray powder diffraction to determine mineralogical units)were made if needed.After equilibration,samples were purity.The X-ray diffraction pattern for ferrihydrite showed centrifuged at approximately6000ϫg for15min,and the only two broad peaks at0.15and0.24nm,which is characteris-supernatant solutions were decanted.The pH was measured tic of two-line ferrihydrite.More crystalline Fe oxides,if pres-in a portion of the supernatant solution before filtering and ent,were not detected.The X-ray diffraction pattern for the was found to be6.0Ϯ0.1for all samples.The remaining boehmite sample showed all peaks reported for boehmite,solutions were filtered under vacuum using0.2-m Millipore and no peaks for gibbsite or any other crystalline Al-oxide Isopore polycarbonate filter membranes(Millipore Corp.,Bed-minerals.The maximum adsorption capacities of boehmiteford,MA).Dissolved PO4was measured in the supernatant and ferrihydrite remained constant within3%between Junesolutions using the molybdate colorimetric(Murphy-Riley)pro-2002and June2003,indicating that aging did not affect PO4cedure(Olsen and Sommers,1982).The concentration of PO4 adsorption on these minerals.adsorbed on samples was determined as the difference be-Ferrihydrite was washed thrice with1mol LϪ1KCl solutiontween total added PO4and PO4measured in supernatant solu-and further washed with0.01mol LϪ1KCl to obtain a0.01-tions.Samples were analyzed on a Shimadzu Model UV2101-mol LϪ1KCl background electrolyte.Boehmite gel in deion-PC spectrophotometer using a1-cm(for higher-P samples)or ized water was brought into a0.01-mol LϪ1KCl background5-cm path length cell.Additional isotherm data for the single by adding a1-mol LϪ1KCl solution.Both minerals were storedand mixed ferrihydrite/boehmite(mixed-mineral)systems were as stock aqueous suspensions of known(measured)solidsobtained on scaled down samples of30g total mass in50mL concentration in0.01mol LϪ1KCl(see Alcacio et al.,2001)polycarbonate centrifuge tubes prepared under identical con-containing40.2g ferrihydrite kgϪ1and14.1g boehmite kgϪ1.straints and following an analogous procedure as outlined The mean crystalline dimensions of poorly crystalline boehm-ite used in this study were previously determined to be4.5,above.Isotherm results from both procedures were integrated.462SOIL SCI.SOC.AM.J.,VOL.68,MARCH–APRIL2004et al.,1992).Hesterberg et al.(1999)calculated that self-XANES Data Collection and Analysisabsorption at the P K-edge wasϽ10%for PO4mineral samples Sample Preparation diluted to800mmol kgϪ1in boron nitride.If self-absorptionsignificantly affected our XANES spectra,we would expect to For XANES analysis,each sedimented mineral sample fromsee a decrease in the white-line peak intensity with increasing the250-mL centrifuge bottles used for concurrent isothermadsorbed P.However,the white-line peak intensities for PO4 experiments was rinsed into50-mL polycarbonate centrifugeadsorbed on ferrihydrite remained essentially constant be-tubes using a portion of its supernatant solution,and centri-tween100and1680mmol P kgϪ1(Fig.1,discussed below), fuged at approximately20000ϫg for15min.Because theindicating that self-absorption did not measurably impact supernatant solution in equilibrium with the solids from theour results.prior centrifugation was used,no adsorption or desorptionwas expected.Supernatant solutions were decanted and eachsedimented mineral sample was homogenized by mixing thor-Data Normalizationoughly with a clean teflon spatula in the50-mL tube.TheThe photon energy scale was normalized to a relative energy moist paste was dewatered to a clay/water ratio of about1:2scale by subtracting the calibration energy of2149eV from by placing it on a0.2-m Millipore filter,under vacuum,forall spectra(Hesterberg et al.,1999).The data were baseline Ͻ60s.Samples were loaded into labeled,acrylate samplecorrected using a linear regression betweenϪ40andϪ10eV holders and covered with5-m polypropylene X-ray filmrelative energy(Sayers and Bunker,1988).To quantitatively (Spex Industries,Metuchen,NJ)and secured with chemicallyanalyze the pre-edge region of the spectra,baselines were pure Kaptan tape(Budnick Converting,Inc.,Columbia,IL).further refined by adjusting all spectra in a set to a common Individually mounted samples were covered with a secondfluorescence yield value atϪ8eV.To remove P concentration piece of acrylate to protect the sample during transport,andeffects on the edge step,single-point background normaliza-sealed into a labeled low-density polyethylene plastic bag.Alltion(Sayers and Bunker,1988)was done in three ways,using samples were sealed into a second plastic bag with a moistthe fluorescence yield at each of three energies:(i)at the paper towel to prevent desiccation.Experiments were timedmaximum peak between10and18eV in the first derivative so that sample preparation was completed a maximum of3dXANES spectrum(edge normalized),(ii)at the maximum of in advance of XANES data collection.All XANES data fora post white-line resonance feature between14and18eV, single,and mixed-mineral systems were collected in June2002and(iii)at30eV relative energy in a flat portion of the (Jun02)during a single synchrotron beam time(a data collec-spectrum.In each case,the fluorescence yields over the entire tion period)except for five additional samples of mixed-min-spectrum were divided by the fluorescence yield at the given eral systems(100,570,760,920,and1190mmol PO4kgϪ1)normalization energy.collected in October2002(Oct02)to determine reproducibil-ity of results.Linear Combination FittingData Collection The proportions of total PO4adsorbed on each mineral inthe mixed-mineral suspensions were determined using least Phosphorus K-XANES data acquisition was done at Beam-squares linear combination fitting(Vairavamurthy et al.,1997; line X-19A at the National Synchrotron Light Source,Brook-Hutchison et al.,2001),with spectra for adsorbed PO4in the haven National Laboratory in Upton,NY.The electron beamsingle-mineral systems serving as standards.Fitting results energy was2.5GeV and the maximum beam current was300were judged according to their chi-square(goodness-of-fit) mA.The synchrotron radiation was monochromatized by avalues.Ge[Ge(111)]monochromator.The monochromator was cali-X-ray absorption near-edge structure spectra for PO4ad-brated to2149eV at the edge(maximum peak in the first-sorbed in single-and mixed-mineral systems at lower concen-derivative spectrum)of variscite.A variscite reference fortrations were noisier than spectra at higher adsorbed PO4 monochromator calibration could not be placed behind sam-concentrations.Therefore,standards for single-mineral sam-ples because of the low energy(low penetrating power)ofples of lower concentration(Յ100mmol PO4kgϪ1ferrihydrite the X-rays at the P K-edge.For example,we calculate basedorՅ200mmol kgϪ1boehmite)were used for mixed-mineral on absorption coefficients(McMaster et al.,1969)thatϾ99%samples of lower concentration(100mmol PO4kgϪ1).Simi-of the X-ray intensity at2150eV would be attenuated by alarly,standards for single-mineral samples of higher adsorbed 10-m thickness of Fe–oxide.Samples of thicknessϽϽ10mconcentration(Ͼ100mmol PO4kgϪ1ferrihydrite orϾ200 would be required for collecting data in transmission mode,mmol kgϪ1boehmite)were used for mixed-mineral samples which was not practical.Moreover thin samples can desiccateof higher concentration(Ͼ100mmol PO4kgϪ1).Further details quickly,thus defeating the purpose of using XANES analysisabout the rationale for choosing single-mineral standards for for moist samples to determine PO4distribution in situ.There-fitting analysis are included in the Results and Discussion fore,a0.1-mm thick moist paste was used for data collectionsection below.to maintain sample moisture.X-ray absorption near-edgestructure spectra were collected at photon energies between2079and2248eV,with a minimum step size of0.2eV between RESULTS AND DISCUSSION2099to2174eV.Two to four scans with consistent baselinesAdsorption Isothermswere ensemble averaged.Spectra were collected in fluorescence mode using a PIPS Adsorption isothermsfor PO4onferrihydrite,boehmite,(Passivated Implanted Planar Silicon)detector mounted into a and mixtures of ferrihydrite and boehmite(Fig.2)were He-filled sample chamber.X-ray absorption near-edge structureL-curves that could be fit with Freundlich models(Spos-data were also collected for variscite and strengite standardsito,1984).The adsorption isotherm for the mixed-min-diluted to400mmol P kgϪ1in boron nitride.Self-absorptioneral system was intermediate between those of the sin-effects can distort XANES spectra collected in fluorescencegle-mineral systems.The maximum levels of adsorption mode,particularly at low X-ray energies as used here,and athigh concentrations of the analyte(P in this case)(Troger observed were about1860,1420,and850mmol kgϪ1KHARE ET AL.:ADSORBED PHOSPHATE DISTRIBUTION DETERMINED BY XANES463Fig.1.Edge-normalized,stacked P K-XANES spectra for PO4adsorbed on boehmite,ferrihydrite(ferri.)or mixed-mineral systems(June2002 at pH6.0Ϯ0.1)at selected concentrations.Numbers in the legend denote adsorbed PO4in mmol kgϪ1.for ferrihydrite,mixed-mineral,and boehmite systems.a direct fit of the Freundlich model to the mixed mineralisotherm(solid lines in Fig.2).The isotherm fitting results Because of the shapes of the isotherms,these levelswere considered as maximum adsorption capacities for indicated that adsorption in the mixed-mineral system the purposes of this study.essentially behaved(within about10%variation)as a Freundlich isotherm models were used to determine linear combination of adsorption in the single-mineral whether PO4adsorption in the mixed-mineral systemsystems.That is,there was no interaction between the could be fit as a linear combination of adsorption in the minerals that notably affected PO4adsorption.In general,one cannot determine from the isotherm single-mineral systems.The predicted adsorption for the1:1mixture based on a linear combination of Freundlich data how PO4is distributed between ferrihydrite and models for the single-mineral systems(q mixed,predicted)wasboehmite at any given adsorbed PO4concentration in taken as the mixed-mineral systems.Therefore,XANES spec-troscopy was used to determine PO4distribution in the q mixed,predictedϭ0.5q fϩ0.5q bϭmixed-mineral systems.0.5[A f c f(f)ϩA b c b(b)],[1]where q f and q b denote the model-predicted adsorption Phosphorus K-XANESin single-mineral systems for a given aqueous concentra-Adsorbed Phosphate in Single-andtion(c f and c b)weighted by a factor of0.5for the1:1Mixed-Mineral Systems(mass basis)mixture,and A f,(f);A b,(b)are Freun-dlich model parameters for ferrihydrite and boehmite,Figure1shows examples of edge-normalized XANES respectively.For dissolved PO4concentrations betweenspectra for PO4adsorbed at different concentrations 100and1400mol LϪ1in the mixed system,q mixed,predicted on ferrihydrite,boehmite,or mixed-mineral systems. (dashed line,Fig.2)deviated byՅ10%on the lowAll spectra were characterized by an intense resonance side of q m,the predicted concentration determined by(white-line)near2150eV(1eV relative energy),and464SOIL SCI.SOC.AM.J.,VOL.68,MARCH–APRIL 2004Fig.2.Adsorption isotherms for PO 4on boehmite,ferrihydrite,and mixed boehmite/ferrihydrite (1:1mass basis)at pH 6.0Ϯ0.1,along with Freundlich isotherm models as solid lines for the June 2002data.Data for the mixed mineral isotherm for June 2002are fit using a mass weighted (1:1)linear combination of Freundlich models from the single-mineral systems (dashed line,see text).Some additional data collected in October 2002for PO 4adsorbed on ferrihydrite and mixed-mineral systems are shown.q f ,q m ,q b ,denote the Freundlich model predicted PO 4adsorption for ferrihydrite (f),mineral mixtures (m),and boehmite (b)as a function of dissolved PO 4concentration (c ).weaker oscillations between 5and 15eV (relative en-and is estimated in practice by the most intense peak ergy).The white-line peak intensity of XANES spectra in the first derivative XANES spectra (Stohr,1996;Say-for PO 4on boehmite or ferrihydrite did not change ers and Bunker,1988).However,in the P XANES,an systematically with adsorbed PO 4concentration (Fig.1).intense resonance (white-line)resulting from electronic However,a statistically significant difference (p Ͻ0.05)transitions of the core electron into unoccupied p like between the mean white-line peak intensity for PO 4on valence electronic states occurs at an energy less than boehmite (4.0Ϯ0.1)versus ferrihydrite (4.36Ϯ0.02)the absorption edge (Franke and Hormes,1995).There-was observed.The spectra for PO 4in mixed-mineral fore,we defined the edge as shown in Fig.1,at the systems showed some differences in the white-line peak energy yielding a relative maximum in the first deriva-intensity,but no trend with concentration (Fig.1).The tive XANES spectrum on the high-energy side of the spectra for PO 4on ferrihydrite showed a pre-edge fea-white-line peak.X-ray absorption near-edge structure ture near Ϫ4eV,which was not present in the spectra spectra for PO 4adsorbed on ferrihydrite and boehmite for PO 4on boehmite as discussed in more detail below.had edges at 12and 14eV,respectively (Fig.1).X-ray absorption near-edge structure spectra for PO 4Normalized XANES spectra for PO 4adsorbed on adsorbed in mixed-mineral systems (June 2002)also boehmite at concentrations Յ200mmol kg Ϫ1(data not showed a pre-edge feature (Fig.1),which tended to shown)and PO 4adsorbed on ferrihydrite at concentra-diminish in intensity with increasing adsorbed phos-tions Յ100mmol kg Ϫ1(data not shown)were noisier phate concentration (discussed below).than XANES spectra for these minerals at higher ad-X-ray absorption near-edge structure spectral fea-sorbed PO 4concentrations because of their lower con-tures arise from electronic transitions during X-ray ab-centration-dependent edge step.Data normalized to the sorption,as influenced by the atomic coordination envi-maximum fluorescence yield at the post edge feature ronment around the absorbing atom (P in this case).and at 30eV followed similar trends as edge normalized Features are due to electronic transitions into bound spectra,and are not shown.Hereafter,data for edge-states (pre-edge features)or to photoelectron backscat-normalized spectra will be shown and discussed,unless tering from surrounding atoms (post-edge features)otherwise noted.(Franke and Hormes,1995;Stohr,1996).For K-shell spectra,the observed resonances typically correspond Comparison with Iron(III)and to dipole-allowed transitions of a 1s electron to and Aluminum(III)-Phosphatesantibonding orbitals (Stohr,1996).The absorption For our research on adsorbed PO 4species,strengite edge is usually defined as the energy at which the 1s electron from the K shell escapes into the continuum,and variscite served as standards of known molecularKHARE ET AL.:ADSORBED PHOSPHATE DISTRIBUTION DETERMINED BY XANES465Fig.3.Edge-normalized P K-XANES spectra for strengite versus variscite and ensemble-averaged spectra for PO 4adsorbed on ferrihydrite (ferri.)versus boehmite at pH 6.0Ϯ0.1,showing a pre-edge feature for PO 4associated with Fe(III).structure of Fe(III)vs.Al(III)-bound PO 4.The XANES Phosphate Adsorbed in Mixed-Mineral spectrum for strengite showed a pronounced pre-edge Systems (Pre-edge)feature at 2146eV,whereas the variscite spectrum Because the pre-edge feature has been used to differ-showed no such pre-edge feature (Fig.3).The pre-edge entiate P associated with ferrihydrite versus boehmite,resonance observed for Fe(III)-coordinated PO 4as in we focused on the pre-edge region as a means for charac-strengite has been previously ascribed to hybridization terizing adsorbed PO 4in the mixed-mineral systems.of Fe-3d,O-2p,and P-3p valence orbitals giving some With increasing concentration of total adsorbed PO 4in p character to the d like unoccupied states from Fe(III)the mixed-system,the pre-edge feature intensity showed (Franke and Hormes,1995;Behrens,1992;Okude et a trend from being similar to PO 4on ferrihydrite,toward al.,1999).The lack of a pre-edge resonance in variscite having intensity intermediate between that of PO 4on is presumably due to the absence of d orbitals in Al.ferrihydrite and PO 4on boehmite (Fig.4).X-ray absorp-Thus,differences in electron orbital configuration re-sulted in differences in the pre-edge region of XANES tion near-edge structure spectra for mixed-mineral sys-spectra for strengite and variscite.Similarly,XANES tems from October 2002(data not shown)generally spectra for PO 4adsorbed on ferrihydrite (Fe-oxide)at followed the same trend.This trend indicated that with different adsorbed PO 4concentrations showed a pre-increasing adsorbed PO 4concentration in mixed-min-edge feature while XANES spectra for PO 4adsorbed eral systems,an increasingly greater proportion of PO 4on boehmite (Al-oxide)did not show such a pre-edge was adsorbed on boehmite.feature (average spectra from Fig.1shown in Fig.3).Because XANES analysis probes the weighted aver-Thus,the pre-edge feature could be used for distinguish-age of all P bonding environments in a sample (Beauche-ing PO 4associated with ferrihydrite versus boehmite.min et al.,2002),the XANES spectra for PO 4adsorbed Because the pre-edge feature for P K-XANES spectra in mixed-mineral systems were considered to be a linear of strengite has been attributed to P-O-Fe(III)coordina-combination of the spectra for PO 4adsorbed on boehm-tion (Franke and Hormes,1995;Behrens,1992;Okude ite and PO 4adsorbed on ferrihydrite.Furthermore,be-et al.,1999),a similar pre-edge feature observed in cause fitting of adsorption isotherms for the mixed-min-XANES spectra for PO 4adsorbed on ferrihydrite pro-eral system could be done within 10%as a combination vided direct evidence for inner sphere complexation of of isotherms for single-mineral systems,we assumed PO 4on the surface of ferrihydrite.Also,note that the that no species of PO 4unique to the mixed-mineral pre-edge feature for strengite was stronger (and the system were present in detectable quantities.Hence,white-line peak weaker)than that for PO 4on ferrihy-linear combination fitting (LCF)analysis was used to drite (Fig.3),likely because of more P-O-Fe bonds quantitatively assess the relative distribution of ad-in the bulk mineral.The weaker pre-edge for PO 4on sorbed PO 4between the two minerals in the mixed-ferrihydrite indicated that phosphate was dominantly adsorbed (not precipitated).mineral systems.。
BOLD效应fMRI图像的自适应阈值小波去噪方法
BOLD效应fMRI图像的自适应阈值小波去噪方法王泉德;肖继来;谢晟【摘要】OEF can be quantitatively calculated using fMRI images based on BOLD effect and a two-component model, and it may be helpful in clinical prognosing and diagnosing of cerebrovascular disease. However, the Signal-Noise-Ratio (SNR)of the image is so poor that it's urgent to research and design efficient denoising algorithm in order to improve accuracy of OEF computing. In this paper, a wavelet denoising algorithm based on Bayesian estimating the adaptive threshold is designed and applied to analyse and denoise fMRI images based on BOLD effect, and result images are pro-vided to the post processing and computing OEF. Experimental result shows that the algorithm in this paper can improve accuracy of OEF computing effectively.%利用基于BOLD(Blood Oxygenation Level Dependent)效应的fMRI图像和两室模型可以定量计算脑氧摄取分数(Oxygen Extraction Fraction,OEF),在脑血管病的预测和诊断上有较大的临床应用价值.但由于BOLD效应fMRI图像的信噪比较低,研究并设计有效的BOLD效应fMRI图像去噪算法,从而提高OEF计算结果的准确性是急需解决的问题.因此,设计了基于贝叶斯估计的自适应阈值小波去噪方法对BOLD效应fMRI图像进行分析和去噪,并将结果图像应用于OEF值的计算.实验结果表明该方法能有效提高OEF计算结果的准确性.【期刊名称】《计算机工程与应用》【年(卷),期】2017(053)008【总页数】5页(P170-173,239)【关键词】脑氧摄取分数;图像去噪;小波分析;贝叶斯估计【作者】王泉德;肖继来;谢晟【作者单位】武汉大学电子信息学院,武汉 430070;武汉大学电子信息学院,武汉430070;北京中日友好医院,北京 100029【正文语种】中文【中图分类】TP391WANG Quande,XIAO Jilai,XIE Sheng.Computer Engineering andApplications,2017,53(8):170-173.脑血管病目前排在人类致残性疾病的首位。
《IEEEsignalprocessingletters》期刊第19页50条数据
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/academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html9.《A Method For Fine Resolution Frequency Estimation From Three DFT Samples》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html10.《Position-Patch Based Face Hallucination Using Convex Optimization》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html11.《Signal Fitting With Uncertain Basis Functions》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html12.《Optimal Filtering Over Uncertain Wireless Communication Channels》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html13.《The Student's -Hidden Markov Model With Truncated Stick-Breaking Priors》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html14.《IEEE Signal Processing Society Information》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html15.《Acoustic Model Adaptation Based on Tensor Analysis of Training Models》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html16.《On Estimating the Number of Co-Channel Interferers in MIMO Cellular Systems》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html17.《Period Estimation in Astronomical Time Series Using Slotted Correntropy》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html18.《Multidimensional Shrinkage-Thresholding Operator and Group LASSO Penalties》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html19.《Enhanced Seam Carving via Integration of Energy Gradient Functionals》letters_thesis/020*********.html20.《Backtracking-Based Matching Pursuit Method for Sparse Signal Reconstruction》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html21.《Performance Bounds of Network Coding Aided Cooperative Multiuser Systems》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html22.《Table of Contents》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html23.《Bayesian Estimation With Imprecise Likelihoods: Random Set Approach》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html24.《Low-Complexity Channel-Estimate Based Adaptive Linear Equalizer》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html25.《Tensor Versus Matrix Completion: A Comparison With Application to Spectral Data》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html26.《Joint DOD and DOA Estimation for MIMO Array With Velocity Receive Sensors》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html27.《Regularized Subspace Gaussian Mixture Models for Speech Recognition》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html28.《Handoff Optimization Using Hidden Markov Model》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html29.《Standard Deviation for Obtaining the Optimal Direction in the Removal of Impulse Noise》letters_thesis/020*********.html30.《Energy Detection Limits Under Log-Normal Approximated Noise Uncertainty》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html31.《Joint Subspace Learning for View-Invariant Gait Recognition》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html32.《GMM-Based KLT-Domain Switched-Split Vector Quantization for LSF Coding》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html33.《Complexity Reduced Face Detection Using Probability-Based Face Mask Prefiltering and Pixel-Based Hierarchical-Feature Adaboosting》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html34.《RLS Algorithm With Convex Regularization》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html35.《Solvability of the Zero-Pinning Technique to Orthonormal Wavelet Design》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html36.《Power Spectrum Blind Sampling》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html37.《Noise Folding in Compressed Sensing》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html38.《Fast Maximum Likelihood Scale Parameter Estimation From Histogram Measurements》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html39.《Elastic-Transform Based Multiclass Gaussianization》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html40.《Improving Detection of Acoustic Signals by Means of a Time and Frequency Multiple Energy Detector》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html41.《Efficient Multiple Kernel Support Vector Machine Based Voice Activity Detection》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html42.《Performance Analysis of Dual-Hop AF Systems With Interference in Nakagami-$m$ Fading Channels》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html43.《Illumination Normalization Based on Weber's Law With Application to Face Recognition》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html44.《A Robust Replay Detection Algorithm for Soccer Video》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html45.《Regularized Adaptive Algorithms-Based CIR Predictors for Time-Varying Channels in OFDM Systems》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html46.《A Novel Semi-Blind Selected Mapping Technique for PAPR Reduction in OFDM》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html47.《Widely Linear Simulation of Continuous-Time Complex-Valued Random Signals》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html48.《A Generalized Poisson Summation Formula and its Application to Fast Linear Convolution》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html49.《Multiple-Symbol Differential Sphere Detection Aided Differential Space-Time Block Codes Using QAM Constellations》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html50.《Low Rank Language Models for Small Training Sets》原⽂链接:https:///doc/f83f6c1c4ad7c1c708a1284ac850ad02de800787.html /academic-journal-foreign_ieee-signal-processing-letters_thesis/020*********.html。
基于贝叶斯统计的汽车电子器件寿命分析
AUTO PARTS | 汽车零部件1 绪论随着汽车电气化乃至智能化的发展,汽车电子器件在车身各关键设备上的应用日渐广泛[1]。
汽车电子器件的工作状态、功能、寿命与汽车的正常行驶息息相关,若出现问题,轻则造成财产损失,重则造成人员伤亡。
因此,对汽车电子器件进行寿命分析,具有重大的实际意义。
1.1 加速寿命试验与加速模型为了快速地暴露产品的薄弱环节,在较高应力下以更短的试验时间推断正常应力下的寿命特征,常采取加速寿命试验(Life Accelerated Testing,ALT)。
即在失效机理不变的基础上,通过加速模型,利用加速应力水平下的寿命特征去外推评估正常应力水平下的寿命特征的试验技术。
加速寿命试验方法因其可缩短试验时间、提高试验效率、降低试验成本等优势已经被广泛应用于各类工程实际问题之中[2]。
为了能够利用ALT中搜集到的产品寿命信息外推产品在正常应力条件下的寿命特征,必须建立产品寿命特征与加速应力水平之间的关系,即加速模型。
常用的加速模型分为物理模型和统计模型,具体有阿伦尼斯模型、艾琳模型、广义艾琳模型、冲蚀磨损模型、逆幂律模型、Coffi n-Manson模型、Norris-Landzberg模型等[3]。
ALT的统计分析是通过估计寿命分布函数的参数和确定加速模型的参数,从而外推评估正常应力水平S0下的寿命特征。
1.2 贝叶斯理论在工程和实际试验中,对于待估计参数常常会有一定的现有经验和信息,为了利用好这一部分信息,同时通过新的数据对已有信息进行更新,则常用贝叶斯统计方法[4]进行统计推断。
()()()()f y pp ym yθθθ=()()()m y f y p dθθθ=∫p(θ|y)称为后验密度函数;p(θ)称为先验密度函数;m(y)是数据的边沿密度函数;f(y|θ)是数据的抽样密度函数。
由于汽车为批量生产的产品,因此其电子器件也具有相当多的历史信息,故采用基于贝叶斯统计ALT分析,能够更准确地评估汽车电子器件寿命,并对产品已有信息进行更新。
Matlab的第三方工具箱大全
Matlab的第三方工具箱大全(按住CTRL点击连接就可以到达每个工具箱的主页面来下载了)Matlab Toolboxes∙ADCPtools - acoustic doppler current profiler data processing∙AFDesign - designing analog and digital filters∙AIRES - automatic integration of reusable embedded software∙Air-Sea - air-sea flux estimates in oceanography∙Animation - developing scientific animations∙ARfit - estimation of parameters and eigenmodes of multivariate autoregressive methods∙ARMASA - power spectrum estimation∙AR-Toolkit - computer vision tracking∙Auditory - auditory models∙b4m - interval arithmetic∙Bayes Net - inference and learning for directed graphical models∙Binaural Modeling - calculating binaural cross-correlograms of sound∙Bode Step - design of control systems with maximized feedback∙Bootstrap - for resampling, hypothesis testing and confidence interval estimation ∙BrainStorm - MEG and EEG data visualization and processing∙BSTEX - equation viewer∙CALFEM - interactive program for teaching the finite element method∙Calibr - for calibrating CCD cameras∙Camera Calibration∙Captain - non-stationary time series analysis and forecasting∙CHMMBOX - for coupled hidden Markov modeling using max imum likelihood EM ∙Classification - supervised and unsupervised classification algorithms∙CLOSID∙Cluster - for analysis of Gaussian mixture models for data set clustering∙Clustering - cluster analysis∙ClusterPack - cluster analysis∙COLEA - speech analysis∙CompEcon - solving problems in economics and finance∙Complex - for estimating temporal and spatial signal complexities∙Computational Statistics∙Coral - seismic waveform analysis∙DACE - kriging approximations to computer models∙DAIHM - data assimilation in hydrological and hydrodynamic models∙Data Visualization∙DBT - radar array processing∙DDE-BIFTOOL - bifurcation analysis of delay differential equations∙Denoise - for removing noise from signals∙DiffMan - solv ing differential equations on manifolds∙Dimensional Analysis -∙DIPimage - scientific image processing∙Direct - Laplace transform inversion via the direct integration method∙DirectSD - analysis and design of computer controlled systems with process-oriented models∙DMsuite - differentiation matrix suite∙DMTTEQ - design and test time domain equalizer design methods∙DrawFilt - drawing digital and analog filters∙DSFWAV - spline interpolation with Dean wave solutions∙DWT - discrete wavelet transforms∙EasyKrig∙Econometrics∙EEGLAB∙EigTool - graphical tool for nonsymmetric eigenproblems∙EMSC - separating light scattering and absorbance by extended multiplicative signal correction∙Engineering Vibration∙FastICA - fixed-point algorithm for ICA and projection pursuit∙FDC - flight dynamics and control∙FDtools - fractional delay filter design∙FlexICA - for independent components analysis∙FMBPC - fuzzy model-based predictive control∙ForWaRD - Fourier-wavelet regularized deconvolution∙FracLab - fractal analysis for signal processing∙FSBOX - stepwise forward and backward selection of features using linear regression∙GABLE - geometric algebra tutorial∙GAOT - genetic algorithm optimization∙Garch - estimating and diagnosing heteroskedasticity in time series models∙GCE Data - managing, analyzing and displaying data and metadata stored using the GCE data structure specification∙GCSV - growing cell structure visualization∙GEMANOVA - fitting multilinear ANOVA models∙Genetic Algorithm∙Geodetic - geodetic calculations∙GHSOM - growing hierarchical self-organizing map∙glmlab - general linear models∙GPIB - wrapper for GPIB library from National Instrument∙GTM - generative topographic mapping, a model for density modeling and data visualization∙GVF - gradient vector flow for finding 3-D object boundaries∙HFRadarmap - converts HF radar data from radial current vectors to total vectors ∙HFRC - importing, processing and manipulating HF radar data∙Hilbert - Hilbert transform by the rational eigenfunction expansion method∙HMM - hidden Markov models∙HMMBOX - for hidden Markov modeling using maximum likelihood EM∙HUTear - auditory modeling∙ICALAB - signal and image processing using ICA and higher order statistics∙Imputation - analysis of incomplete datasets∙IPEM - perception based musical analysisJMatLink - Matlab Java classesKalman - Bayesian Kalman filterKalman Filter - filtering, smoothing and parameter estimation (using EM) for linear dynamical systemsKALMTOOL - state estimation of nonlinear systemsKautz - Kautz filter designKrigingLDestimate - estimation of scaling exponentsLDPC - low density parity check codesLISQ - wavelet lifting scheme on quincunx gridsLKER - Laguerre kernel estimation toolLMAM-OLMAM - Levenberg Marquardt with Adaptive Momentum algorithm for training feedforward neural networksLow-Field NMR - for exponential fitting, phase correction of quadrature data and slicing LPSVM - Newton method for LP support vector machine for machine learning problems LSDPTOOL - robust control system design using the loop shaping design procedure LS-SVMlabLSVM - Lagrangian support vector machine for machine learning problemsLyngby - functional neuroimagingMARBOX - for multivariate autogressive modeling and cross-spectral estimation MatArray - analysis of microarray dataMatrix Computation- constructing test matrices, computing matrix factorizations, visualizing matrices, and direct search optimizationMCAT - Monte Carlo analysisMDP - Markov decision processesMESHPART - graph and mesh partioning methodsMILES - maximum likelihood fitting using ordinary least squares algorithmsMIMO - multidimensional code synthesisMissing - functions for handling missing data valuesM_Map - geographic mapping toolsMODCONS - multi-objective control system designMOEA - multi-objective evolutionary algorithmsMS - estimation of multiscaling exponentsMultiblock - analysis and regression on several data blocks simultaneously Multiscale Shape AnalysisMusic Analysis - feature extraction from raw audio signals for content-based music retrievalMWM - multifractal wavelet modelNetCDFNetlab - neural network algorithmsNiDAQ - data acquisition using the NiDAQ libraryNEDM - nonlinear economic dynamic modelsNMM - numerical methods in Matlab textNNCTRL - design and simulation of control systems based on neural networks NNSYSID - neural net based identification of nonlinear dynamic systemsNSVM - newton support vector machine for solv ing machine learning problems NURBS - non-uniform rational B-splinesN-way - analysis of multiway data with multilinear modelsOpenFEM - finite element developmentPCNN - pulse coupled neural networksPeruna - signal processing and analysisPhiVis- probabilistic hierarchical interactive visualization, i.e. functions for visual analysis of multivariate continuous dataPlanar Manipulator - simulation of n-DOF planar manipulatorsPRT ools - pattern recognitionpsignifit - testing hyptheses about psychometric functionsPSVM - proximal support vector machine for solving machine learning problems Psychophysics - vision researchPyrTools - multi-scale image processingRBF - radial basis function neural networksRBN - simulation of synchronous and asynchronous random boolean networks ReBEL - sigma-point Kalman filtersRegression - basic multivariate data analysis and regressionRegularization ToolsRegularization Tools XPRestore ToolsRobot - robotics functions, e.g. kinematics, dynamics and trajectory generation Robust Calibration - robust calibration in statsRRMT - rainfall-runoff modellingSAM - structure and motionSchwarz-Christoffel - computation of conformal maps to polygonally bounded regions SDH - smoothed data histogramSeaGrid - orthogonal grid makerSEA-MAT - oceanographic analysisSLS - sparse least squaresSolvOpt - solver for local optimization problemsSOM - self-organizing mapSOSTOOLS - solving sums of squares (SOS) optimization problemsSpatial and Geometric AnalysisSpatial RegressionSpatial StatisticsSpectral MethodsSPM - statistical parametric mappingSSVM - smooth support vector machine for solving machine learning problems STATBAG - for linear regression, feature selection, generation of data, and significance testingStatBox - statistical routinesStatistical Pattern Recognition - pattern recognition methodsStixbox - statisticsSVM - implements support vector machinesSVM ClassifierSymbolic Robot DynamicsTEMPLAR - wavelet-based template learning and pattern classificationTextClust - model-based document clusteringTextureSynth - analyzing and synthesizing visual texturesTfMin - continous 3-D minimum time orbit transfer around EarthTime-Frequency - analyzing non-stationary signals using time-frequency distributions Tree-Ring - tasks in tree-ring analysisTSA - uni- and multivariate, stationary and non-stationary time series analysisTSTOOL - nonlinear time series analysisT_Tide - harmonic analysis of tidesUTVtools - computing and modifying rank-revealing URV and UTV decompositions Uvi_Wave - wavelet analysisvarimax - orthogonal rotation of EOFsVBHMM - variation Bayesian hidden Markov modelsVBMFA - variational Bayesian mixtures of factor analyzersVMT- VRML Molecule Toolbox, for animating results from molecular dynamics experimentsVOICEBOXVRMLplot - generates interactive VRML 2.0 graphs and animationsVSVtools - computing and modifying symmetric rank-revealing decompositions WAFO - wave analysis for fatique and oceanographyWarpTB - frequency-warped signal processingWAVEKIT - wavelet analysisWaveLab - wavelet analysisWeeks - Laplace transform inversion via the Weeks methodWetCDF - NetCDF interfaceWHMT - wavelet-domain hidden Markov tree modelsWInHD - Wavelet-based inverse halftoning via deconvolutionWSCT - weighted sequences clustering toolkitXMLTree - XML parserYAADA - analyze single particle mass spectrum dataZMAP - quantitative seismicity analysis。
ICAR模型的对贝斯前缀说明书
Package‘ref.ICAR’August22,2023Title Objective Bayes Intrinsic Conditional Autoregressive Model forAreal DataVersion2.0.1Author Erica M.Porter,Matthew J.Keefe,Christopher T.Franck,and Marco A.R.Ferreira Maintainer Erica M.Porter<*******************>Description Implements an objective Bayes intrinsic conditional autoregressiveprior.This model provides an objective Bayesian approach for modeling spatiallycorrelated areal data using an intrinsic conditional autoregressive prior on a vector ofspatial random effects.License MIT+file LICENSEEncoding UTF-8Imports sf,sp,spdep,mvtnorm,coda,MCMCglmm,Rdpack,graphics,pracma,stats,classInt,dplyr,ggplot2,gtoolsRdMacros RdpackSuggests maps,MASS,knitr,rmarkdown,RColorBrewer,rcrossrefVignetteBuilder knitrBuildManual yesRoxygenNote7.2.3NeedsCompilation noRepository CRANDate/Publication2023-08-2208:50:02UTCR topics documented:probs.icar (2)ref.analysis (3)ref.MCMC (5)ref.plot (7)ref.summary (8)reg.summary (10)shape.H (11)12probs.icar Index12 probs.icar OLM and ICAR model probabilities for areal dataDescriptionPerforms simultaneous selection of covariates and spatial model structure for areal data.Usageprobs.icar(Y,X,H,H.spectral=NULL,Sig_phi=NULL,b=0.05,verbose=FALSE)ArgumentsY A vector of responses.X A matrix of covariates,which should include a column of1’s for models with a non-zero interceptH Neighborhood matrix for spatial subregions.H.spectral Spectral decomposition of neighborhood matrix,if user wants to pre-compute itto save time.Sig_phi Pseudo inverse of the neighborhood matrix,if user wants to pre-compute it to save time.b Training fraction for the fractional Bayes factor(FBF)approach.verbose If FALSE,marginal likelihood progress is not printed.ValueA list containing a data frame with all posterior model probabilities and other selection information.probs.mat Data frame containing posterior model probabilities for all candidate OLMs and ICAR models from the data.mod.prior Vector of model priors used to obtain the posterior model probabilities.logmargin.all Vector of all(log)fractional integrated likelihoods.base.model Maximum(log)fractional integrated likelihood among all candidate models.All fractional Bayes factors are obtained with respect to this model.BF.vec Vector of fractional Bayes factors for all candidate models.Author(s)Erica M.Porter,Christopher T.Franck,and Marco A.R.FerreiraReferencesPorter EM,Franck CT,Ferreira MAR(2023).“Objective Bayesian model selection for spatial hierarchical models with intrinsic conditional autoregressive priors.”Bayesian Analysis,1(1),1–27.doi:10.1214/23BA1375.ref.analysis MCMC Analysis and Summaries for Reference Prior on an IntrinsicAutoregressive Model for Areal DataDescriptionPerforms analysis on a geographical areal data set using the objective prior for intrinsic conditional autoregressive(ICAR)random effects(Keefe et al.2019).It takes a shapefile,data,and region names to construct a neighborhood matrix and perform Markov chain Monte Carlo sampling on the unstructured and spatial random effects.Finally,the function obtains regional estimates and performs posterior inference on the model parameters.Usageref.analysis(shape.file,X,y,s,s,s=NULL,iters=10000,burnin=5000,verbose=TRUE,tauc.start=1,beta.start=1,sigma2.start=1,step.tauc=0.5,step.sigma2=0.5)Argumentsshape.file A shapefile corresponding to the regions for analysis.X A matrix of covariates,which should include a column of1’s for models with a non-zero intercepty A vector of responses.s A vector specifying the order of region names contained in X.s A vector specifying the order of region names contained in y.s A vector specifying the order of region names contained in the shapefile,if there is not a NAME column in thefile.iters Number of MCMC iterations to perform.Defaults to10,000.burnin Number of MCMC iterations to discard as burn-in.Defaults to5,000.verbose If FALSE,MCMC progress is not printed.tauc.start Starting MCMC value for the spatial dependence parameter.beta.start Starting MCMC value for thefixed effect regression coefficients.sigma2.start Starting MCMC value for the variance of the unstructured random effects.step.tauc Step size for the spatial dependence parameter.step.sigma2Step size for the variance of the unstructured random effects.ValueA list containing H,MCMC chains,parameter summaries,fitted regional values,and regional sum-maries.H The neighborhood matrix.MCMC Matrix of MCMC chains for all model parameters.beta.median Posterior medians of thefixed effect regression coefficients.beta.hpd Highest Posterior Density intervals for thefixed effect regression coefficients.tauc.median Posterior median of the spatial dependence parameter.tauc.hpd Highest Posterior Density interval for the spatial dependence parameter.sigma2.median Posterior median of the unstructured random effects variance.sigma2.hpd Highest Posterior Density interval for the unstructured random effects variance.tauc.accept Final acceptance rate for the spatial dependence parameter.sigma2.accept Final acceptance rate for the unstructured random effects variance.fit.dist Matrix offitted posterior values for each region in the data.reg.medians Vector of posterior medians forfitted response by region.reg.hpd Data frame of Highest Posterior Density intervals by region.Author(s)Erica M.Porter,Matthew J.Keefe,Christopher T.Franck,and Marco A.R.FerreiraExamples##Refer to the vignette attached to the package.ref.MCMC MCMC for Reference Prior on an Intrinsic Conditional AutoregressiveRandom Effects Model for Areal DataDescriptionImplements the Metropolis-within-Gibbs sampling algorithm proposed by Ferreira et al.(2021),to perform posterior inference for the intrinsic conditional autoregressive model with spatial random effects.This algorithm uses the spectral domain for the hierarchical model to create the Spectral Gibbs Sampler(SGS),which provides notable speedups to the MCMC algorithm proposed by Keefe et al(2019).Usageref.MCMC(y,X,H,iters=10000,burnin=5000,verbose=TRUE,tauc.start=1,beta.start=1,sigma2.start=1,step.tauc=0.5,step.sigma2=0.5)Argumentsy Vector of responses.X Matrix of covariates.This should include a column of1’s for models with a non-zero intercept.H The neighborhood matrix.iters Number of MCMC iterations to perform.Defaults to10,000.burnin Number of MCMC iterations to discard as burn-in.Defaults to5,000.verbose If FALSE,MCMC progress is not printed.tauc.start Starting value for the spatial dependence parameter.beta.start Starting value for the vector offixed effect regression coefficients.sigma2.start Starting value for the variance of the unstructured random effects.step.tauc Step size for the spatial dependence parameterstep.sigma2Step size for the variance of the unstructured random effects.ValueA list containing MCMC chains and parameter summaries.MCMCchain Matrix of MCMC chains.tauc.MCMC MCMC chains for the spatial dependence parameter.sigma2.MCMC MCMC chains for the variance of the unstructured random effects.phi.MCMC MCMC chains for the spatial random effects.beta.MCMC MCMC chains for thefixed effect regression coefficients.accept.sigma2Final acceptance number for variance of the unstructured random effects.accept.tauc Final acceptance number for spatial dependence parameter.accept.phi Final acceptance number for spatial random effects.Author(s)Erica M.Porter,Matthew J.Keefe,Christopher T.Franck,and Marco A.R.FerreiraReferencesKeefe MJ,Ferreira MAR,Franck CT(2019).“Objective Bayesian analysis for Gaussian hierarchi-cal models with intrinsic conditional autoregressive priors.”Bayesian Analysis,14(1),181–209.doi:10.1214/18BA1107.Keefe MJ,Ferreira MAR,Franck CT(2018).“On the formal specification of sum-zero con-strained intrinsic conditional autoregressive models.”Spatial Statistics,24,54–65.doi:10.1016/ j.spasta.2018.03.007.Ferreira MAR,Porter EM,Franck CT(2021).“Fast and scalable computations for Gaussian hier-archical models with intrinsic conditional autoregressive spatial random effects.”Computational Statistics and Data Analysis,162,107264.ISSN0167-9473,doi:10.1016/j.csda.2021.107264, https:///science/article/pii/S0167947321000980.Examples####Fit the model for simulated areal data on a grid#######Load extra librarieslibrary(sp)library(methods)library(spdep)library(mvtnorm)###Generate areal data on a gridrows=5;cols=5tauc=1sigma2=2;beta=c(1,5)###Create gridgrid<-GridTopology(c(1,1),c(1,1),c(cols,rows))polys<-as(grid,"SpatialPolygons")ref.plot7 spgrid<-SpatialPolygonsDataFrame(polys,data=data.frame(s=s(polys)))###Create neighborhood matrixgrid.nb<-poly2nb(spgrid,queen=FALSE)W<-nb2mat(grid.nb,style="B")###Put spatially correlated data in gridp<-length(beta)num.reg<-(rows*cols)if(p>1){x1<-rmvnorm(n=num.reg,mean=rep(0,p-1),sigma=diag(p-1))}else{x1<-NULL}X<-cbind(rep(1,num.reg),x1)Dmat<-diag(apply(W,1,sum))H<-Dmat-Ws(H)<-NULL###Obtain true response vectortheta_true<-rnorm(num.reg,mean=0,sd=sqrt(sigma2))Q<-eigen(H,symmetric=TRUE)$vectorseigH<-eigen(H,symmetric=TRUE)$valuesD<-diag(eigH)Qmat<-Q[,1:(num.reg-1)]phimat<-diag(1/sqrt(eigH[1:(num.reg-1)]))z<-t(rmvnorm(1,mean=rep(0,num.reg-1),sigma=diag(num.reg-1)))phi_true<-sqrt((1/tauc)*sigma2)*(Qmat%*%phimat%*%z)Y<-X%*%beta+theta_true+phi_true###Fit the modelset.seed(5432)model<-ref.MCMC(y=Y,X=X,H=H,iters=15000,burnin=5000,verbose=TRUE,tauc.start=.1,beta.start=-1, sigma2.start=.1,step.tauc=0.5,step.sigma2=0.5)####Small example for checkingmodel<-ref.MCMC(y=Y,X=X,H=H,iters=1000,burnin=50,verbose=TRUE,tauc.start=.1,beta.start=-1, sigma2.start=.1,step.tauc=0.5,step.sigma2=0.5)ref.plot Trace Plots for Parameters in ICAR ModelDescriptionThis function creates trace plots for the parameters in the ICAR reference prior model(Keefe et al.2019).Usageref.plot(MCMCchain,X,burnin,num.reg)ArgumentsMCMCchain Matrix of MCMC chains for the model parameters.X Matrix of covariates.burnin Number of MCMC iterations from MCMCchain discarded as burn-in.num.reg Number of regions in the areal data set.ValueTrace plots for thefixed effect regression coefficients,the precision parameter,and the unstructured random effects variance.Author(s)Erica M.Porter,Matthew J.Keefe,Christopher T.Franck,and Marco A.R.FerreiraExamples##Refer to the vignette attached to the package.ref.summary Parameter Summaries for MCMC AnalysisDescriptionTakes a matrix of MCMC chains,iterations,and acceptance values to return posterior summaries of the parameters,including posterior medians,intervals,and acceptance rates.Usageref.summary(MCMCchain,tauc.MCMC,sigma2.MCMC,beta.MCMC,phi.MCMC,accept.phi,accept.sigma2,accept.tauc,iters=10000,burnin=5000)ArgumentsMCMCchain Matrix of MCMC chains for the ICAR model parameters.tauc.MCMC MCMC chains for the spatial dependence parameter.sigma2.MCMC MCMC chains for the variance of the unstructured random effects.beta.MCMC MCMC chains for thefixed effect regression coefficients.phi.MCMC MCMC chains for the spatial random effects.accept.phi Final acceptance number for spatial random effects.accept.sigma2Final acceptance number for variance of the unstructured random effects.accept.tauc Final acceptance number for the spatial dependence parameter.iters Number of MCMC iterations in MCMCchain.burnin Number of MCMC iterations discarded as burn-in for MCMCchain.ValueParameter summariesbeta.median Posterior medians of thefixed effect regression coefficients.beta.hpd Highest Posterior Density intervals for thefixed effect regression coefficients.tauc.median Posterior median of the spatial dependence parameter.tauc.hpd Highest Posterior Density interval for the spatial dependence parameter.sigma2.median Posterior median of the unstructured random effects variance.sigma2.hpd Highest Posterior Density interval for the unstructured random effects variance.tauc.accept Final acceptance rate for the spatial dependence parameter.sigma2.accept Final acceptance rate for the unstructured random effects variance.Author(s)Erica M.Porter,Matthew J.Keefe,Christopher T.Franck,and Marco A.R.FerreiraExamples##Refer to the vignette attached to the package.reg.summary Regional Summaries for Areal Data Modeled by ICAR Reference PriorModelDescriptionThis function takes data and sampled MCMC chains for an areal data set and givesfitted posterior values and summaries by region using the model by(Keefe et al.2019).Usagereg.summary(MCMCchain,X,Y,burnin)ArgumentsMCMCchain Matrix of MCMC chains,using the sampling from(Keefe et al.2019).X Matrix of covariates.Y Vector of responses.burnin Number of MCMC iterations discarded as burn-in in MCMCchain.ValueA list of thefitted distributions by region,and medians and credible intervals by region.fit.dist Matrix offitted posterior values for each region in the data.reg.medians Vector of posterior medians forfitted response by region.reg.cred Data frame of credbile intervals by region.Author(s)Erica M.Porter,Matthew J.Keefe,Christopher T.Franck,and Marco A.R.FerreiraExamples##Refer to the vignette attached to the package.shape.H11 shape.H Creating a Neighborhood Matrix for Areal Data from a ShapefileDescriptionTakes a path to a shapefile and creates a neighborhood matrix.This neighborhood matrix can be used with the objective ICAR model(Keefe et al.2018).Usageshape.H(shape.file)Argumentsshape.file File path to a shapefile.ValueA list containing a neighborhood matrix and the SpatialPolygonsDataFrame object correspondingto the shapefile.H A neighborhood matrix.map SpatialPolygonsDataFrame object from the provided shapefile.Author(s)Erica M.Porter,Matthew J.Keefe,Christopher T.Franck,and Marco A.R.FerreiraExamples####Load extra librarieslibrary(sp)library(sf)###Read in a shapefile of the contiguous U.S.from package datasystem.path<-system.file("extdata","us.shape48.shp",package="ref.ICAR",mustWork=TRUE) yer<-gsub( .shp , ,basename(system.path))shp.path<-dirname(system.path)us.shape48<-st_read(dsn=path.expand(shp.path),layer=yer)shp.data<-shape.H(system.path)names(shp.data)Indexprobs.icar,2ref.analysis,3ref.MCMC,5ref.plot,7ref.summary,8reg.summary,10shape.H,1112。
Inference of Population Structure Using Multilocus Genotype Data
Copyright©2000by the Genetics Society of AmericaInference of Population Structure Using Multilocus Genotype DataJonathan K.Pritchard,Matthew Stephens and Peter DonnellyDepartment of Statistics,University of Oxford,Oxford OX13TG,United KingdomManuscript received September23,1999Accepted for publication February18,2000ABSTRACTWe describe a model-based clustering method for using multilocus genotype data to infer populationstructure and assign individuals to populations.We assume a model in which there are K populations(where K may be unknown),each of which is characterized by a set of allele frequencies at each locus.Individuals in the sample are assigned(probabilistically)to populations,or jointly to two or more popula-tions if their genotypes indicate that they are admixed.Our model does not assume a particular mutationprocess,and it can be applied to most of the commonly used genetic markers,provided that they are notclosely linked.Applications of our method include demonstrating the presence of population structure,assigning individuals to populations,studying hybrid zones,and identifying migrants and admixed individu-als.We show that the method can produce highly accurate assignments using modest numbers of loci—e.g.,seven microsatellite loci in an example using genotype data from an endangered bird species.The softwareused for this article is available from /فpritch/home.html.I N applications of population genetics,it is often use-populations based on these subjective criteria representsa natural assignment in genetic terms,and it would beful to classify individuals in a sample into popula-tions.In one scenario,the investigator begins with a useful to be able to confirm that subjective classifications sample of individuals and wants to say something aboutare consistent with genetic information and hence ap-the properties of populations.For example,in studies propriate for studying the questions of interest.Further, of human evolution,the population is often consideredthere are situations where one is interested in“cryptic”to be the unit of interest,and a great deal of work has population structure—i.e.,population structure that isdifficult to detect using visible characters,but may be focused on learning about the evolutionary relation-ships of modern populations(e.g.,Cavalli et al.1994).significant in genetic terms.For example,when associa-In a second scenario,the investigator begins with a settion mapping is used tofind disease genes,the presence of predefined populations and wishes to classify individ-of undetected population structure can lead to spurious uals of unknown origin.This type of problem arisesassociations and thus invalidate standard tests(Ewens in many contexts(reviewed by Davies et al.1999).A and Spielman1995).The problem of cryptic population standard approach involves sampling DNA from mem-structure also arises in the context of DNAfingerprint-bers of a number of potential source populations and ing for forensics,where it is important to assess thedegree of population structure to estimate the probabil-using these samples to estimate allele frequencies inity of false matches(Balding and Nichols1994,1995; each population at a series of unlinked ing theForeman et al.1997;Roeder et al.1998).estimated allele frequencies,it is then possible to com-Pritchard and Rosenberg(1999)considered how pute the likelihood that a given genotype originated ingenetic information might be used to detect the pres-each population.Individuals of unknown origin can beence of cryptic population structure in the association assigned to populations according to these likelihoodsmapping context.More generally,one would like to be Paetkau et al.1995;Rannala and Mountain1997).able to identify the actual subpopulations and assign In both situations described above,a crucialfirst stepindividuals(probabilistically)to these populations.In is to define a set of populations.The definition of popu-this article we use a Bayesian clustering approach to lations is typically subjective,based,for example,ontackle this problem.We assume a model in which there linguistic,cultural,or physical characters,as well as theare K populations(where K may be unknown),each of geographic location of sampled individuals.This subjec-which is characterized by a set of allele frequencies at tive approach is usually a sensible way of incorporatingeach locus.Our method attempts to assign individuals diverse types of information.However,it may be difficultto populations on the basis of their genotypes,while to know whether a given assignment of individuals tosimultaneously estimating population allele frequen-cies.The method can be applied to various types ofmarkers[e.g.,microsatellites,restriction fragment Corresponding author:Jonathan Pritchard,Department of Statistics,length polymorphisms(RFLPs),or single nucleotide University of Oxford,1S.Parks Rd.,Oxford OX13TG,United King-dom.E-mail:pritch@ polymorphisms(SNPs)],but it assumes that the marker Genetics155:945–959(June2000)946J.K.Pritchard,M.Stephens and P.Donnellyloci are unlinked and at linkage equilibrium with one observations from each cluster are random draws another within populations.It also assumes Hardy-Wein-from some parametric model.Inference for the pa-berg equilibrium within populations.(We discuss these rameters corresponding to each cluster is then done assumptions further in background on clusteringjointly with inference for the cluster membership of methods and the discussion.)each individual,using standard statistical methods Our approach is reminiscent of that taken by Smouse(for example,maximum-likelihood or Bayesian et al.(1990),who used the EM algorithm to learn about methods).the contribution of different breeding populations to aDistance-based methods are usually easy to apply and sample of salmon collected in the open ocean.It is alsoare often visually appealing.In the genetics literature,it closely related to the methods of Foreman et al.(1997)has been common to adapt distance-based phylogenetic and Roeder et al.(1998),who were concerned withalgorithms,such as neighbor-joining,to clustering estimating the degree of cryptic population structuremultilocus genotype data(e.g.,Bowcock et al.1994). to assess the probability of obtaining a false match atHowever,these methods suffer from many disadvan-DNAfingerprint loci.Consequently they focused ontages:the clusters identified may be heavily dependent estimating the amount of genetic differentiation amongon both the distance measure and graphical representa-the unobserved populations.In contrast,our primarytion chosen;it is difficult to assess how confident we interest lies in the assignment of individuals to popula-should be that the clusters obtained in this way are tions.Our approach also differs in that it allows for themeaningful;and it is difficult to incorporate additional presence of admixed individuals in the sample,whoseinformation such as the geographic sampling locations genetic makeup is drawn from more than one of the Kof individuals.Distance-based methods are thus more populations.suited to exploratory data analysis than tofine statistical In the next section we provide a brief descriptioninference,and we have chosen to take a model-based of clustering methods in general and describe someapproach here.advantages of the model-based approach we take.TheThefirst challenge when applying model-based meth-details of the models and algorithms used are given inods is to specify a suitable model for observations from models and methods.We illustrate our method witheach cluster.To make our discussion more concrete we several examples in applications to data:both onintroduce very briefly some of our model and notation simulated data and on sets of genotype data from anhere;a fuller treatment is given later.Assume that each endangered bird species and from humans.incorpo-cluster(population)is modeled by a characteristic set rating population information describes how ourof allele frequencies.Let X denote the genotypes of the method can be extended to incorporate geographicsampled individuals,Z denote the(unknown)popula-information into the inference process.This may betions of origin of the individuals,and P denote the useful for testing whether particular individuals are mi-(unknown)allele frequencies in all populations.(Note grants or to assist in classifying individuals of unknownthat X,Z,and P actually represent multidimensional origin(as in Rannala and Mountain1997,for exam-vectors.)Our main modeling assumptions are Hardy-ple).Background on the computational methods usedWeinberg equilibrium within populations and complete in this article is provided in the appendix.linkage equilibrium between loci within populations.Under these assumptions each allele at each locus ineach genotype is an independent draw from the appro-BACKGROUND ON CLUSTERING METHODSpriate frequency distribution,and this completely speci-Consider a situation where we have genetic data fromfies the probability distribution Pr(X|Z,P)(given later a sample of individuals,each of whom is assumed toin Equation2).Loosely speaking,the idea here is that have originated from a single unknown population(nothe model accounts for the presence of Hardy-Weinberg admixture).Suppose we wish to cluster together individ-or linkage disequilibrium by introducing population uals who are genetically similar,identify distinct clusters,structure and attempts tofind population groupings and perhaps see how these clusters relate to geographi-that(as far as possible)are not in disequilibrium.While cal or phenotypic data on the individuals.There areinference may depend heavily on these modeling as-broadly two types of clustering methods we might use:sumptions,we feel that it is easier to assess the validityof explicit modeling assumptions than to compare the 1.Distance-based methods.These proceed by calculatingrelative merits of more abstract quantities such as dis-a pairwise distance matrix,whose entries give thetance measures and graphical representations.In situa-distance(suitably defined)between every pair of in-tions where these assumptions are deemed unreason-dividuals.This matrix may then be represented usingable then alternative models should be built.some convenient graphical representation(such as aHaving specified our model,we must decide how to tree or a multidimensional scaling plot)and clustersperform inference for the quantities of interest(Z and may be identified by eye.2.Model-based methods.These proceed by assuming that P).Here,we have chosen to adopt a Bayesian approach,947Inferring Population Structureby specifying models(priors)Pr(Z)and Pr(P),for both Assume that before observing the genotypes we haveZ and P.The Bayesian approach provides a coherent no information about the population of origin of eachframework for incorporating the inherent uncertainty individual and that the probability that individual i origi-of parameter estimates into the inference procedure nated in population k is the same for all k,and for evaluating the strength of evidence for the in-Pr(z(i)ϭk)ϭ1/K,(3) ferred clustering.It also eases the incorporation of vari-ous sorts of prior information that may be available,independently for all individuals.(In cases where somesuch as information about the geographic sampling lo-populations may be more heavily represented in thecation of individuals.sample than others,this assumption is inappropriate;itHaving observed the genotypes,X,our knowledge would be straightforward to extend our model to dealabout Z and P is then given by the posterior distribution with such situations.)We follow the suggestion of Balding and Nichols Pr(Z,P|X)ϰPr(Z)Pr(P)Pr(X|Z,P).(1)(1995)(see also Foreman et al.1997and Rannala While it is not usually possible to compute this distribu-and Mountain1997)in using the Dirichlet distri-tion exactly,it is possible to obtain an approximate bution to model the allele frequencies at each locus sample(Z(1),P(1)),(Z(2),P(2)),...,(Z(M),P(M))from Pr(Z,within each population.The Dirichlet distributionP|X)using Markov chain Monte Carlo(MCMC)meth-D(1,2,...,J)is a distribution on allele frequenciesods described below(see Gilks et al.1996b,for more pϭ(p1,p2,...,p J)with the property that these frequen-general background).Inference for Z and P may then cies sum to1.We use this distribution to specify the be based on summary statistics obtained from this sam-probability of a particular set of allele frequencies pkl·ple(see Inference for Z,P,and Q below).A brief introduc-for population k at locus l,tion to MCMC methods and Gibbs sampling may befound in the appendix.pkl·فD(1,2,...,J l),(4)independently for each k,l.The expected frequency of MODELS AND METHODS allele j is proportional toj,and the variance of thisfrequency decreases as the sum of thej increases.We We now provide a more detailed description of ourtake1ϭ2ϭ···ϭJ lϭ1.0,which gives a uniform modeling assumptions and the algorithms used to per-distribution on the allele frequencies;alternatives are form inference,beginning with the simpler case wherediscussed in the discussion.each individual is assumed to have originated in a singleMCMC algorithm(without admixture):Equations2, population(no admixture).3,and4define the quantities Pr(X|Z,P),Pr(Z),and The model without admixture:Suppose we genotypePr(P),respectively.By settingϭ(1,2)ϭ(Z,P)and N diploid individuals at L loci.In the case without admix-letting(Z,P)ϭPr(Z,P|X)we can use the approach ture,each individual is assumed to originate in one ofoutlined in Algorithm A1to construct a Markov chain K populations,each with its own characteristic set ofwith stationary distribution Pr(Z,P|X)as follows: allele frequencies.Let the vector X denote the observedAlgorithm1:Starting with initial values Z(0)for Z(by genotypes,Z the(unknown)populations of origin ofdrawing Z(0)at random using(3)for example),iterate the the individuals,and P the(unknown)allele frequenciesfollowing steps for mϭ1,2,....in the populations.These vectors consist of the follow-ing elements,Step1.Sample P(m)from Pr(P|X,Z(mϪ1)).(x(i,1)l,x(i,2)l)ϭgenotype of the i th individual at the l th locus,Step2.Sample Z(m)from Pr(Z|X,P(m)).where iϭ1,2,...,N and lϭ1,2,...,L;z(i)ϭpopulation from which individual i originated;Informally,step1corresponds to estimating the allele p kljϭfrequency of allele j at locus l in population k,frequencies for each population assuming that the pop-where kϭ1,2,...,K and jϭ1,2,...,J l,ulation of origin of each individual is known;step2 where J l is the number of distinct alleles observed at corresponds to estimating the population of origin of locus l,and these alleles are labeled1,2,...,J l.each individual,assuming that the population allele fre-Given the population of origin of each individual,quencies are known.For sufficiently large m and c,(Z(m), the genotypes are assumed to be generated by drawing P(m)),(Z(mϩc),P(mϩc)),(Z(mϩ2c),P(mϩ2c)),...will be approxi-alleles independently from the appropriate population mately independent random samples from Pr(Z,P|X). frequency distributions,The distributions required to perform each step aregiven in the appendix.Pr(x(i,a)lϭj|Z,P)ϭp z(i)lj(2)The model with admixture:We now expand ourmodel to allow for admixed individuals by introducing independently for each x(i,a)l.(Note that p z(i)lj is the fre-a vector Q to denote the admixture proportions for each quency of allele j at locus l in the population of originof individual i.)individual.The elements of Q are948J.K.Pritchard,M.Stephens and P.Donnellyq (i )k ϭproportion of individual i ’s genome thattion of origin of each allele copy in each individual isknown;step 2corresponds to estimating the population originated from population k.of origin of each allele copy,assuming that the popula-It is also necessary to modify the vector Z to replace the tion allele frequencies and the admixture proportions assumption that each individual i originated in some are known.As before,for sufficiently large m and c ,unknown population z (i )with the assumption that each (Z (m ),P (m ),Q (m )),(Z (m ϩc ),P (m ϩc ),Q (m ϩc )),(Z (m ϩ2c ),P (m ϩ2c ),observed allele copy x (i ,a )l originated in some unknown Q (m ϩ2c )),...will be approximately independent random population z (i ,a )l :samples from Pr(Z ,P ,Q |X ).The distributions required to perform each step are given in the appendix.z (i ,a )l ϭpopulation of origin of allele copy x (i ,a )l .Inference:Inference for Z,P,and Q:We now discuss how We use the term “allele copy”to refer to an allele carried the MCMC output can be used to perform inference on at a particular locus by a particular individual.Z ,P ,and Q.For simplicity,we focus our attention on Q ;Our primary interest now lies in estimating Q.We inference for Z or P is similar.proceed in a manner similar to the case without admix-Having obtained a sample Q (1),...,Q (M )(using suitably ture,beginning by specifying a probability model for large burn-in m and thinning interval c )from the poste-(X ,Z ,P ,Q ).Analogues of (2)and (3)arerior distribution of Q ϭ(q 1,...,q N )given X using the MCMC method,it is desirable to summarize the Pr(x (i ,a )l ϭj |Z ,P ,Q )ϭp z (i ,a )l lj(5)information contained,perhaps by a point estimate of andQ.A seemingly obvious estimate is the posterior meanPr(z (i ,a )l ϭk |P ,Q )ϭq (i )k ,(6)E (q i |X )≈1M ͚M m ϭ1q (m )i .(8)with (4)being used to model P as before.To complete our model we need to specify a distribution for Q ,which However,the symmetry of our model implies that the in general will depend on the type and amount of admix-posterior mean of q i is (1/K ,1/K ,...,1/K )for all i ,ture we expect to see.Here we model the admixturewhatever the value of X.For example,suppose that there proportions q (i )ϭ(q (i )1,...,q (i )K )of individual i using are just two populations and 10individuals and that the the Dirichlet distributiongenotypes of these individuals contain strong informa-tion that the first 5are in one population and the second q (i )فD (␣,␣,...,␣)(7)5are in the other population.Then eitherindependently for each individual.For large values of ␣(ӷ1),this models each individual as having allele q 1...q 5≈(1,0)and q 6...q 10≈(0,1)(9)copies originating from all K populations in equal pro-orportions.For very small values of ␣(Ӷ1),it models each individual as originating mostly from a single popu-q 1...q 5≈(0,1)and q 6...q 10≈(1,0),(10)lation,with each population being equally likely.As with these two “symmetric modes”being equally likely,␣→0this model becomes the same as our model leading to the expectation of any given q i being (0.5,without admixture (although the implementation of the 0.5).This is essentially a problem of nonidentifiability MCMC algorithm is somewhat different).We allow ␣caused by the symmetry of the model [see Stephens to range from 0.0to 10.0and attempt to learn about ␣(2000b)for more discussion].from the data (specifically we put a uniform prior on In general,if there are K populations then there will ␣[0,10]and use a Metropolis-Hastings update step be K !sets of symmetric modes.Typically,MCMC to integrate out our uncertainty in ␣).This model may schemes find it rather difficult to move between such be considered suitable for situations where little is modes,and the algorithms we describe will usually ex-known about admixture;alternatives are discussed in plore only one of the symmetric modes,even when run the discussion.for a very large number of iterations.Fortunately this MCMC algorithm (with admixture):The following does not bother us greatly,since from the point of algorithm may be used to sample from Pr(Z ,P ,Q |X ).view of clustering all the symmetric modes are the same Algorithm 2:Starting with initial values Z (0)for Z (by drawing Z (0)at random using (3)for example),iterate the [compare the clusterings corresponding to (9)and following steps for m ϭ1,2,....(10)].If our sampler explores only one symmetric mode then the sample means (8)will be very poor estimates Step 1.Sample P (m ),Q (m )from Pr(P ,Q |X ,Z (m Ϫ1)).of the posterior means for the q i ,but will be much better Step 2.Sample Z (m )from Pr(Z |X ,P (m ),Q (m )).estimates of the modes of the q i ,which in this case turn Step 3.Update ␣using a Metropolis-Hastings step.out to be a much better summary of the information in the data.Ironically then,the poor mixing of the Informally,step 1corresponds to estimating the allele MCMC sampler between the symmetric modes gives frequencies for each population and the admixture pro-portions of each individual,assuming that the popula-the asymptotically useless estimator (8)some practical949Inferring Population Structure value.Where the MCMC sampler succeeds in moving Simulated data:To test the performance of the clus-tering method in cases where the “answers”are known,between symmetric modes,or where it is desired to combine results from samples obtained using different we simulated data from three population models,using standard coalescent techniques (Hudson 1990).We as-starting points (which may involve combining results corresponding to different modes),more sophisticated sumed that sampled individuals were genotyped at a series of unlinked microsatellite loci.Data were simu-methods [such as those described by Stephens (2000b)]may be required.lated under the following models.Inference for the number of populations:The problem of Model 1:A single random-mating population of con-inferring the number of clusters,K ,present in a data stant size.set is notoriously difficult.In the Bayesian paradigm the Model 2:Two random-mating populations of constant way to proceed is theoretically straightforward:place a effective population size 2N.These were assumed to prior distribution on K and base inference for K on the have split from a single ancestral population,also of posterior distributionsize 2N at a time N generations in the past,with no subsequent migration.Pr(K |X )ϰPr(X |K )Pr(K ).(11)Model 3:Admixture of populations.Two discrete popu-However,this posterior distribution can be peculiarly lations of equal size,related as in model 2,were fused dependent on the modeling assumptions made,even to produce a single random-mating population.Sam-where the posterior distributions of other quantities (Q ,ples were collected after two generations of random Z ,and P ,say)are relatively robust to these assumptions.mating in the merged population.Thus,individuals Moreover,there are typically severe computational chal-have i grandparents from population 1,and 4Ϫi lenges in estimating Pr(X |K ).We therefore describe an grandparents from population 2with probability alternative approach,which is motivated by approximat-(4i )/16,where i {0,4}.All loci were simulated inde-ing (11)in an ad hoc and computationally convenient pendently.way.We present results from analyzing data sets simulated Arguments given in the appendix (Inference on K,the under each model.Data set 1was simulated under number of populations )suggest estimating Pr(X |K )usingmodel 1,with 5microsatellite loci.Data sets 2A and 2B Pr(X |K )≈exp(Ϫˆ/2Ϫˆ2/8),(12)were simulated under model 2,with 5and 15microsatel-lite loci,respectively.Data set 3was simulated under wheremodel 3,with 60loci (preliminary analyses with fewer loci showed this to be a much harder problem than ˆϭ1M ͚M m ϭ1Ϫ2log Pr(X |Z (m ),P (m ),Q (m ))(13)models 1and 2).Microsatellite mutation was modeled by a simple stepwise mutation process,with the mutation andparameter 4N set at 16.0per locus (i.e.,the expected variance in repeat scores within populations was 8.0).ˆ2ϭ1M ͚Mm ϭ1(Ϫ2log Pr(X |Z (m ),P (m ),Q (m ))Ϫˆ)2.We did not make use of the assumed mutation model in analyzing the simulated data.(14)Our analysis consists of two phases.First,we consider We use (12)to estimate Pr(X |K )for each K and substi-the issue of model choice—i.e.,how many populations tute these estimates into (11)to approximate the poste-are most appropriate for interpreting the data.Then,rior distribution Pr(K |X ).we examine the clustering of individuals for the inferred In fact,the assumptions underlying (12)are dubious number of populations.at best,and we do not claim (or believe)that our proce-Choice of K for simulated data:For each model,we dure provides a quantitatively accurate estimate of the ran a series of independent runs of the Gibbs sampler posterior distribution of K.We see it merely as an ad for each value of K (the number of populations)be-hoc guide to which models are most consistent with the tween 1and 5.The results presented are based on runs data,with the main justification being that it seems of 106iterations or more,following a burn-in period of to give sensible answers in practice (see next section for at least 30,000iterations.To choose the length of the examples).Notwithstanding this,for convenience we burn-in period,we printed out log(Pr(X |P (m ),Q (m ))),and continue to refer to “estimating”Pr(K |X )and Pr(X |K ).several other summary statistics during the course of a series of trial runs,to estimate how long it took to reach (approximate)stationarity.To check for possible prob-APPLICATIONS TO DATAlems with mixing,we compared the estimates of P (X |K )and other summary statistics obtained over several inde-We now illustrate the performance of our method on both simulated data and real data (from an endangered pendent runs of the Gibbs sampler,starting from differ-ent initial points.In general,substantial differences be-bird species and from humans).The analyses make use of the methods described in The model with admixture.tween runs can indicate that either the runs should950J.K.Pritchard,M.Stephens and P.DonnellyTABLE 1Estimated posterior probabilities of K ,for simulated data sets 1,2A,2B,and 3(denoted X 1,X 2A ,X 2B ,and X 3,respectively)K log P (K |X 1)P (K |X 2A )P (K |X 2B )P (K |X 3)1ف1.0ف0.0ف0.0ف0.02ف0.00.210.999ف1.03ف0.00.580.0009ف0.04ف0.00.21ف0.0ف0.05ف0.0ف0.0ف0.0ف0.0The numbers should be regarded as a rough guide to which models are consistent with the data,rather than accurate esti-mates of posterior probabilities.Figure 1.—Summary of the clustering results for simulated data sets 2A and 2B,respectively.For each individual,webe longer to obtain more accurate estimates or that computed the mean value of q (i )1(the proportion of ancestry independent runs are getting stuck in different modes in population 1),over a single run of the Gibbs sampler.Thein the parameter space.(Here,we consider the K !dashed line is a histogram of mean values of q (i )1for individuals from population 0;the solid line is for individuals from popula-modes that arise from the nonidentifiability of the K tion 1.populations to be equivalent,since they arise from per-muting the K population labels.)We found that in most cases we obtained consistent and Q estimating the number of grandparents from estimates of P (X |K )across independent runs.However,each of the two original populations,for each individual.when analyzing data set 2A with K ϭ3,the Gibbs sampler Intuitively it seems that another plausible clustering found two different modes.This data set actually con-would be with K ϭ5,individuals being assigned to tains two populations,and when K is set to 3,one of clusters according to how many grandparents they have the populations expands to fill two of the three clusters.from each population.In biological terms,the solution It is somewhat arbitrary which of the two populations with K ϭ2is more natural and is indeed the inferred expands to fill the extra cluster:this leads to two modes value of K for this data set using our ad hoc guide [the of slightly different heights.The Gibbs sampler did not estimated value of Pr(X |K )was higher for K ϭ5than manage to move between the two modes in any of our for K ϭ3,4,or 6,but much lower than for K ϭ2].runs.However,this raises an important point:the inferred In Table 1we report estimates of the posterior proba-value of K may not always have a clear biological inter-bilities of values of K ,assuming a uniform prior on K pretation (an issue that we return to in the discussion ).between 1and 5,obtained as described in Inference for Clustering of simulated data:Having considered the the number of populations.We repeat the warning given problem of estimating the number of populations,we there that these numbers should be regarded as rough now examine the performance of the clustering algo-guides to which models are consistent with the data,rithm in assigning particular individuals to the appro-rather than accurate estimates of the posterior probabil-priate populations.In the case where the populations ities.In the case where we found two modes (data set are discrete,the clustering performs very well (Figure 2A,K ϭ3),we present results based on the mode that 1),even with just 5loci (data set 2A),and essentially gave the higher estimate of Pr(X |K ).perfectly with 15loci (data set 2B).With all four simulated data sets we were able to The case with admixture (Figure 2)appears to be correctly infer whether or not there was population more difficult,even using many more loci.However,structure (K ϭ1for data set 1and K Ͼ1otherwise).the clustering algorithm did manage to identify the In the case of data set 2A,which consisted of just 5population structure appropriately and estimated the loci,there is not a clear estimate of K ,as the posterior ancestry of individuals with reasonable accuracy.Part probability is consistent with both the correct value,K ϭof the reason that this problem is difficult is that it is 2,and also with K ϭ3or 4.However,when the number hard to estimate the original allele frequencies (before of loci was increased to 15(data set 2B),virtually all of admixture)when almost all the individuals (7/8)are the posterior probability was on the correct number of admixed.A more fundamental problem is that it is diffi-populations,K ϭ2.cult to get accurate estimates of q (i )for particular individ-Data set 3was simulated under a more complicated uals because (as can be seen from the y -axis of Figure model,where most individuals have mixed ancestry.In 2)for any given individual,the variance of how many this case,the population was formed by admixture of two populations,so the “true”clustering is with K ϭ2,of its alleles are actually derived from each population。
土壤有机质高光谱自反馈灰色模糊估测模型
山东农业大学学报(自然科学版),2023,54(4):495-499VOL.54NO.42023 Journal of Shandong Agricultural University(Natural Science Edition)doi:10.3969/j.issn.1000-2324.2023.04.003土壤有机质高光谱自反馈灰色模糊估测模型于锦涛1,李西灿1,曹双1,刘法军2*1.山东农业大学信息科学与工程学院,山东泰安2710182.山东省地质矿产勘查开发局第五地质大队,山东泰安271000摘要:为克服光谱估测中的不确定性和提高光谱估测精度,本文利用灰色系统理论和模糊理论建立土壤有机质高光谱估测模型。
基于山东省济南市章丘区和济阳区的121个土壤样本数据,首先对土壤光谱数据进行光谱变换,根据极大相关性原则选取光谱估测因子;然后,利用区间灰数的广义灰度对建模样本和检验样本的估测因子进行修正,以提高相关性。
最后,利用模糊识别理论建立土壤有机质高光谱自反馈模糊估测模型,并通过调整模糊分类数进行模型优化。
结果表明,利用区间灰数的广义灰度可有效提高土壤有机质含量与估测因子的相关性,所建估测模型精度和检验精度均显著提高,其中20个检验样本的决定系数为R2=0.9408,平均相对误差为6.9717%。
研究表明本文所建立的土壤有机质高光谱自反馈灰色模糊估测模型是可行有效的。
关键词:土壤有机质;高光谱遥感;估测模型中图法分类号:TP79;S151.9文献标识码:A文章编号:1000-2324(2023)04-0495-05Self-feedback Grey Fuzzy Estimation Model of Soil Organic Matter Using Hyper-spectral DataYU Jin-tao1,LI Xi-can1,CAO Shuang1,LIU Fa-jun2*1.School of Information Science and Engineering/Shandong Agricultural University,Tai’an271018,China2.The Fifth Geological Brigade of Shandong Geological and Mineral Resources Exploration and Development Bureau, Tai’an271000,ChinaAbstract:To overcome the uncertainty in spectral estimation and improve the accuracy of spectral estimation,a hyper-spectral estimation model of soil organic matter is established in this paper by using grey system theory and fuzzy theory.Based on121soil samples from Zhangqiu and Jiyang districts of Jinan City,Shandong Province,the spectral data are firstly transformed and the spectral estimation factors are selected according to the principle of great correlation;then,the estimation factors of the modeling samples and the test samples are corrected by using the generalized greyness of the interval grey number to improve the correlation.Finally,the fuzzy estimation model with self-feedback of soil organic matter based on hyper-spectral is established by using the fuzzy recognition theory,and the model is optimized by adjusting the fuzzy classification number.The results show that the correlation between soil organic matter content and estimation factors can be effectively improved by using the generalized greyness of interval grey number,and the accuracy of the built estimation model and the test accuracy are significantly improved,among which the determination coefficient of20test samples is R2=0.9408,and the average relative error is6.9717%.The study indicates that the grey fuzzy estimation model with self-feedback of soil organic matter using hyper-spectral data developed in this paper is feasible and effective. Keywords:Soil organic matter;Hyper-spectral remote sensing;stimation model土壤有机质是评定土壤肥力的一个重要指标,快速获取土壤有机质含量对发展精准农业具有现实意义[1]。
缺帧环境下弱纹理图像的三维重建方法
缺帧环境下弱纹理图像的三维重建方法王芳;汪伟【摘要】针对传统方法进行缺帧环境下弱纹理图像三维重建时容易受到边缘缺帧点干扰的影响,降低三维重建效果的问题,提出一种基于边缘轮廓角点分割和相邻帧补偿缺帧环境下弱纹理图像三维重建方法.构建缺帧环境下图像采集模型,采用阈值降噪算法对采集的缺帧环境下弱纹理图像进行降噪滤波预处理,对降噪输出图像进行边缘轮廓角点分割,采用相邻帧补偿方法进行弱纹理修复和稳像处理,提高了对图像弱纹理特征的重建能力,实现图像三维重建的改进.仿真结果表明,改进方法能提高图像纹理识别和修复重建能力,输出图像质量得到有效改善.【期刊名称】《西安工程大学学报》【年(卷),期】2016(030)004【总页数】6页(P477-482)【关键词】弱纹理图像;边缘轮廓;相邻帧补偿;图像识别【作者】王芳;汪伟【作者单位】郑州升达经贸管理学院信息工程系,河南郑州451191;河南工程学院计算机学院,河南郑州451191【正文语种】中文【中图分类】TP391随着图像处理技术的发展,对图像进行纹理分割和边缘轮廓特征提取,在图像识别和图像修复等领域具有较好的应用价值.在复杂环境下受采集设备和环境因素影响,导致图像采集的帧丢失,在缺帧环境下,会导致图像纹理细节丢失,对缺帧环境下弱纹理图像进行三维重建是实现图像识别的重要环节,相关算法研究受到人们的极大重视[1-5].传统方法对缺帧环境下弱纹理图像三维重建方法主要有基于CT/MRI/US的缺帧环境下弱纹理图像重构算法,或基于统计形状模型(Statistical Shape Model, SSM)的缺帧环境下弱纹理图像重构方法、基于模板形状匹配的缺帧环境下弱纹理图像重构方法等[6-7],但这些方法在信噪比较低时,降低图像三维重建抗干扰性能[8-14].为此,提出一种基于边缘轮廓角点分割和相邻帧补偿缺帧环境下弱纹理图像三维重建方法.1.1 图像采集模型及图像特征分析文中构建的缺帧环境下图像采集模型如图1所示.根据上述图像采集模型,采用正方形网格立体建模,将背景图像B和当前缺帧环境下弱纹理图像I划分为(W/2)×(H/2)个子块,划分后不规则三角网中的像素灰度值满足采用深度超像素图像融合方法得到图像的边缘纹理区域中的2×2个像素点,假设缺帧环境下弱纹理图像边缘分量,且满足C([a,b],R)的像素特征收敛判决条件,得到缺帧环境下弱纹理图像的边缘网格轮廓标记线集合为采用视点切换运动方程进行图像的稳像处理:其中:x,y,z为纹理规则化的特征分布位置;ψV为视点切换运动的轮廓标记线偏角.计算弱纹理图像轮廓波域的邻域在(x,y)(x∈[0,W-1],y∈[0,H-1])处的像素值,进行图像特征点采集,使用归一化分割模型进行缺帧环境下弱纹理图像特征分割,相邻帧像素点的近似解为通过小波尺度分解,得到缺帧环境下弱纹理图像纹理特征序列子样,利用图像采集的帧误差T,得到图像主分量边缘轮廓信息特征,获取缺帧环境下弱纹理图像信息的采集形式为采用二阶不变矩作为向量量化参数,得到三维成像数据的补偿量度,成像区域特征点的灰度像素为1.2 弱纹理图像降噪预处理文中采用阈值降噪法进行图像降噪滤波,首先利用Harris角点分割,把图像分割为M个子块[15],利用Hessian矩阵,判断成像区域的极值点是否为图像的噪点,Hessian矩阵为假设Ix表示主分量边缘轮廓中含有较大噪点的特征值;Iy表示较小的特征值,通过对图像特征值的匹配和融合,计算α与β的比值γ,即α/β=γ,得到缺帧环境下弱纹理图像的透射率为当时,则深度超像素特征分割点为图像的边缘点.统计各个子块的噪声点数,判断噪声点数是否大于阈值.如果是,则命令N=5;如果否,则N=3,实现阈值降噪滤波,输出的降噪图像为其中:Δx和Δy分别表示缺帧环境下弱纹理图像的梯度水平幅值和竖直幅值;k表示缩放因子;θ表示差异性旋转角度.2.1 问题描述及边缘轮廓角点分割首先对降噪输出的图像进行边缘轮廓角点分割,利用式(12)获取缺帧环境下弱纹理图像噪声强度:其中:J(x)为一个7×7像素滑动窗口内的干扰强度;A为帧丢失的幅值;t(x)为背景噪声干扰下缺帧环境下弱纹理图像的透射率;J(x)t(x)为图像噪点的衰减项;边缘轮廓子空间内图像的帧差损失为计算全部帧图像对应的粗尺度和细尺度,通过Harris角点检测,得到图像角点包络特征方程描述为其中:ρ(x)表示两帧之间的运动位移;exp(-βd(x))是高斯函数的尺度;d(x)是相邻帧的方差.假设Ii(x,y)是小波特征分解细节重构函数,P(x,y)iv和P(x,y)if分别为两帧之间运动的成像区域像素,则尺度不变性约束函数为通过Harris角点特征提取,实现对采集的缺帧环境下弱纹理图像特征分割.2.2 弱纹理图像三维重建实现过程在上述进行缺帧环境下弱纹理图像的边缘轮廓角点分割基础上,采用相邻帧补偿方法实现弱纹理图像三维重建,相邻帧补偿示意图描述如图2所示.实现步骤如下:(1)对缺帧环境下弱纹理图像特征点及参量进行初始化,假设弱纹理图像度量区域间的差异性级数N,在相邻两帧之间求解失真阀值ε;弱纹理图像像素值的训练序列{xj},j=0,1,…,m-1,初始化帧序列n=0,D-1=∞;(2)根据缺帧环境下弱纹理图像的角点特征幅值n={yi},i=1,2,…,N,得到缺帧环境下弱纹理图像角点周围的像素点子集序列{xj},j=0,1,…,m-1和关于n 的目标图像运动参数估计值,利用角点匹配值si={xj:d(xj,yi)≤d(xj,yl)}实现误差补偿,∀l=0,1,…,N,计算缺帧环境下弱纹理图像的融合邻域空间,得到(3)如果(Dn-1-Dn)/Dn≤ε,停止;求得相应时刻的最佳估算值s(k|k),否则继续;(4)在图像边缘点进行中心像素差异值补偿,得到图像三维重建的输出码书(sj)},j=1,2,…,N;在阈值降噪后输出图像中进行边缘轮廓分割与特征提取,使得图像的像素值输出失真最小;(sj),令n=m+1,采用第2帧补偿第1帧图像,以此类推,实现相邻帧补偿和图像的三维重建.为了测试本文算法在缺帧环境下弱纹理图像三维重建中的性能,进行仿真实验.硬件环境:Intel(R) 2.3 GHz CPU,2 GB内存,32位Windows 7系统的PC机.基于Matlab 2010编程平台,根据上述仿真环境和参数设定,得到原始采集的弱纹理图像如图3所示.从图3可见,原始图像采集受边缘缺帧点干扰的影响,导致图像纹理特征较弱,为实现图像三维重建,采用本文方法对缺帧环境下弱纹理图像进行降噪预处理,对降噪输出的图像进行边缘轮廓角点分割,实现角点提取,为了对比性能,采用本文方法和传统的小波检测方法和SUSAN角点方法进行对比,得到结果如图4所示.从图4可见,采用本文方法进行缺帧环境下弱纹理图像角点提取,能有效实现对弱纹理特征的重建和边缘轮廓分割,提高图像的修复和重建能力.最后得到不同算法下进行不同帧图像的三维重建修复处理结果如图5所示.从图5可见,采用本文方法进行缺帧环境下图像三维重建,具有较好的降噪和纹理修复性能,提高对图像成像和识别能力.本文提出一种基于边缘轮廓角点分割和相邻帧补偿缺帧环境下弱纹理图像三维重建方法.仿真结果表明,采用本文方法进行缺帧环境下弱纹理图像的三维重建,提高纹理的修复能力,三维重建后图像成像的质量提高,性能优越于传统方法,展示了较好的应用价值.[2] KARLSSON J,ROWE W,XU L,et al. Fast missing-data IAA with application to notched spectrum SAR[J]. IEEE Transactions on Aerospace Electronic Systems,2014,50(2):959-971.[3] PARK H R,LI Jie. Sparse covariance-based high resolution time delay estimation for spread spectrum signals[J].Electronics Letters,2015,51(2):155-157.[4] GLENTIS G O,JAKOBSSON A,ANGELOPOULOS K. Block-recursiveIAA-based spectral estimates with missing samples using data interpolation[C]//International Conference on Acoustics, Speech and Signal Processing (ICASSP), Florence,2014,12(10):350-354.[5] 王慧贤,靳惠佳,王娇龙,等. k均值聚类引导的遥感影像多尺度分割优化方法[J]. 测绘学报,2015,44(5):526-532.[6] 宋涛,李鸥,刘广怡. 基于空时多线索融合的超像素运动目标检测方法[J]. 电子与信息学报,2016,38(6):1503-1511.[7] BROX T,MALIK J. Large displacement optical flow:Descriptor matching in variational motion estimation[J]. IEEE Transactions on Pattern Analysis and Machine Intelligence,2010,33(3):500-513.[8] 李秦,夏选太. 基于Kinect传感器的三维重建算法研究[J]. 电子设计工程,2015,23(17):30-31.[9] 赫高进,熊伟,陈荦,等. 基于MPI的大规模遥感影像金字塔并行构建方法[J]. 地球信息科学学报,2015,17(5):515-522.[10] 李旭超,宋博,甘良志. 改进的迭代算法在图像恢复正则化模型中的应用[J]. 电子学报,2015,43(6):1152-1159.[11] 于海琦,刘真,田全慧. 一种基于RBF神经网络的打印机光谱预测模型[J]. 影像科学与光化学,2015,33(3):238-243.[12] 柏猛,李敏花,吕英俊. 基于对称性分析的棋盘图像角点检测方法[J]. 信息与控制,2015,44(3):276-283.[13] 张子龙,薛静,乔鸿海,等. 基于改进 SURF 算法的交通视频车辆检索方法研究[J]. 西北工业大学学报,2014,32(2):297-301.[14] EVANGELIO R H,PATZOLD M,KELLER I. Adaptively splitted GMM with feedback improvement for the task of background subtraction[J]. IEEE Transactions on Information Forensics and Security,2014,9(5):863-874.[15] MARTINS P,CASEIRO R,BATISTA J. Non-parametric bayesian constrained local models[C]//Proceedings of the IEEE Conference on Computer Vision and Pattern Recognition, Columbus,2014:1797-1804.WANG Fang,WANG Wei.Three dimensional reconstruction method ofweak texture image under the condition of lack of frame[J].Journal of Xi′an Polytechnic University,2016,30(4):477-482.【相关文献】[1] 周镭,单锋,刘鹏,等. 基于供应链的企业信息化评价模型的建立[J]. 西安工程大学学报,2015,29(6):772-779.。
高光谱遥感信息中的特征提取与应用研究(中英对照)
Spectral Features Extraction in Hyperspectral RS Data andIts Application to Information ProcessingOriented to the demands of hyperspectral RS information processing and applications, spectral features in hyperspectral RS image can be categorized into three scales: point scale, block scale and volume scale. Based on the properties and algorithms of different features, it is proposed that point scale features can be divided into three levels: spectral curve features, spectral transformation features and spectral similarity measure features. Spectral curve features include direct spectra encoding, reflection and absorption features. Spectral transformation features include Normalized Difference of Vegetation Index (NDV I) , derivate spectra and other spectral computation features. Spectral similarity measure features include spectral angle ( SA ) , Spectral Information Divergence ( SID ) , spectral distance, correlation coefficient and so on. Based on analysis to those algorithms, several problems about feature extraction, matching and application are discussed further, and it p roved that quaternary encoding, spectral angle and SID can be used to information processing effectively.1 IntroductionHyperspectral Remote Sensing was one of the most important breakthroughs of Earth Observation System ( EOS) in 1990 s. It overcomes the limitations of conventional aerial and multispectral RS such as less band amount, wide band scope and rough spectral information expression, and can provide RS information with narrow band width, more band amount and fine spectral information, also it can distinguish and identify ground objects from spectral space, so hyperspectral RS has got wide applications in resources, environment, city and ecological fields. Because hyperspectral RS is different from conventional RS information obviously in both information acquisition and information processing, there are many problems should be solved in practice. One of the most important problems isabout spectral features extraction and application in hyperspectral RS data including hyperspectral RS image and standard spectral database. Nowadays, studies on hyperspectral are mainly focused on band selection and dimensionality reduction, image classification, mixed pixel decomposition and others, and studies on spectral features are few. In this paper, spectral features extraction and application will be taken as our central topic in order to provide some useful advices to hyperspectral RS applications.2 Framework of spectral features in hyperspectral RS dataIn general, hyperspectral RS image can be expressed by a spatial-spectral data cube ( Fig. 1). In this data cube, every coverage expressed the image of one band, and each pixel forms a spectral vector composed of albedo of ground object on every band in spectral dimension, and that vector can be visualized by spectral curve ( Fig. 2 ). Many features can be extracted from spectral vector or curve, and spectral features are the key and basis of hyperspectral RS applications. Also each spectral curve in spectral database can be analyzed with same method. Although there are some algorithms to compute spectral features, the framework and system is still not obvious, so we would like to propose a framework for spectral features in hyperspectral RS data including hyperspectral RS image and standard spectral database.2. 1Three scales of spectral featuresAccording to the operational objects of extraction algorithms, spectral features can be categorized into three scales: point-scale,block-scale and volume-Scale.Point scale takes pixel and its spectral curve as operational object and some useful features can be extracted from this spectral vector (or spectral curve).In general, hyperspectral RS image takes spectral vector of each pixel as processing object.Block scale is oriented image block or region. Block is the set of some pixels, and it can be homogeneous or heterogeneous. Homogeneous regions are got by image segmentation and pixels in this region are similar in some given features; heterogeneous region are those image blocks with regular or irregular size, and they are cut from original image directly, for example, an image can be segmented according to quadtree method. In hyperspectral RS image, block scale features can be computed from two aspects. One is to compute texture feature of a block on some characterized bands, and the other is to compute spectral feature of a block. If the block is homogeneous its mean vector can be computed firstly and then spectral of this mean vector can be extracted to describe the block. If the block is heterogeneous, it can be segmented to some homogeneous blocks.Volume scale combines spatial and spectral features in a whole and extracts features in 3D ( row, column and spectra ) space. Here, some 3D operational algorithms are needed, for example, 3D wavelet transformation and high order Artificial Neural Network (ANN ). Because this type of features is difficult to compute and analyze, we don′t research it in current studies.In this paper, we would like to focus on point scale feature, or those features extracted from spectral vector that may be spectral vector of a pixel or mean vector of a block.2. 2Three levels of point scale featuresFrom operation object, algorithm principles, feature properties, application modes and other aspects, we think it is feasible to categorize spectral features into three levels: spectral curve features, spectral transformation features and spectral similarity measure features. They are corresponding to analysis on spectral curve with all bands, data transformation and combination with partof all bands and similarity measure of spectral vectors. In our study, data from OM IS and PHI hyperspectral image, USGS spectral database and typical spectra data in China is experimented and two examples are given in this paper. One is to select three regions from PH I image (Region I is vegetation, Region II is built-up land, and Region III is mixed region of some land covers) , and the other is spectral curve of three ground objects from USGS spectral database, among them S1 is Actinolite_HS22. 3B, S2 is Actinolite_HS116. 3B and S3 is Albite_HS66. 3B, so S1 and S2 are similar and they are different from S3.3 Spectra l curve featuresSpectral curve features are computed by some algorithms based on the spectral curve of certain pixel or ground object, and it can describe shape and properties of the curve. The main methods include direct encoding and feature band analysis.3. 1 Direct encodingThe important idea of spectral curve feature is to emphasize spectral curve shape, so direct encoding is a very convenient method, and binary encoding is used more widely. Its principle is to compare the attribute value at each band of a pixel with a threshold and assign the code of “0”or “1”according to its value. That can be expressed byHere, []s i is code of the ith band, i X is the original attribute valueof this band, and T is the threshold. Generally, threshold is the mean of spectral vector, and it can also be selected by manual method according to curve shape, sometimes median of spectral vector is probably used.Only one threshold is used in binary encoding, so the divided internal is large and precision is low. In order to improve the appoximaty and precision, the quaternary encoding strategy is proposed in this paper. Its primary idea is as follows: ( 1 ) the mean of the total pixel spectral vector is computed and denoted by T 0 , and the attribute is divided into two internal including [min X ,[]()1i if X T s i o else≥⎧=⎨⎩0T ] and [0T , min X ]; (2) the pixels located in the two internalsare determined and the mean of each internal is got and donated by T and TR , so four internals are formed including [min X , TL ], [0T , TR ] and [TR , min X ]; ( 3) each band is assigned one of the code sets{ 0, 1, 2, 3 } according to the internal it is located; (4) to compute the ratio of matched bands number to the total band number as final matching ratio. It p roved that quaternary encoding could describe the curve shape more precisely.If quarternary encoding is used, the ratio of the same region is smaller than binary encoding, but the ratio between different regions decreased dramatically. So quarternary encoding is more effective in measuring the similarity between different pixels.Because direct encoding will disperse the continuous albedo into discrete code, the encoding result is affected by threshold obviously and will lead to information loss. Although its operation is very simple, it is only used to some applications requiring low precision, and the threshold should be selected according to different conditions.3. 2 Spectral absorption or reflection featureDiffering from direct encoding in which all bands are used, spectral absorption or reflection feature only emphasizes those bands where valleys or apexes are located. That means those bands with local maximum or minimum in spectral curve should be determined at first and then further analysis can be done. In general, albedo is used to describe the attribute of a pixel, so those bands with local maximum are reflection apex and those with local minimum are absorption valley.After the location and related parameters are got, the detail analysis can be done. In general two methods are used, one is to give direct encoding and analysis to feature bands, and the other is to compute some quantitative index using feature bands and their parameters.3.3 Encoding of spectra l absorption or reflection features The locations of feature bands are directly used in spectral feature encoding. The following will take absorption feature as anexample. If one band is the location of absorption valley, its code will be “1 ”, otherwise its code is “0 ”. After the encoding is completed further matching and comparison can be done. Because of those uncertainties and errors in hyper spectral imaging process, the locations of feature bands perhaps move in near bands, and that will lead to low match ratio. In order to reduce the impact of band displacement, the extended encoding method is proposed and used in this paper. Its idea is that if the code of a certain band is“1”then the bands prior to and behind it will be assigned the same code “1”, and then matching and analysis will be done.The similarity measure to code vector is matching by bit. The matching ratio is got by the ratio of matched bands to total band count. In this study, two match schemes are used. One is matching the code of all bands and the other is only matching those feature bands.Based on above analysis, four schemes are used and compared. These are: ( 1) direct encoding to all bands and matching by all bands, and ( 2 ) direct encoding to all bands and matching only by feature bands, and ( 3) extended encoding and matching by all bands, and ( 4 ) extended encoding and matching only by feature bands.From above analysis and comparison to spectral absorption and reflection feature encoding and matching, it can be found that although absorption and reflection band can describe the spectral properties of ground object, effective matching operation should be used in order to overcome the impacts of noise, band displacement and other factors. In practical applications, absorption and reflection can be used to extract thematic information and retrieve a certain type of object effectively.Based on spectral absorption and reflection features, the spectral absorption index ( SA I) or spectral reflection index ( SR I) can be computed by wavelength, albedo of feature band and its left and right shoulders, and those indexes can describe spectral feature more precisely on some occasions.4 Spectra l computation and transformation featuresBoth correlativity and mutual compensation exist in differentbands of hyper spectral RS information, so many new features can be got by certain computation and combination to some bands and used to classification, information extraction and other tasks.4. 1 Normalized difference of vegetation index (NDVI)NDVI plays very important roles in hyper spectral application. It can describe some fine information about vegetation such as Leaf Area Index (LA I) , ratio of vegetation and soil, component of vegetation and so on. In some classifiers ( for example, ANN classifier) NDVI usually is used as an independent feature in classification.4. 2Derivative spectrumDerivative spectrum is also called as spectral derivative technique. One rank and two rank derivative spectrum can be computed by Equation.Each rank derivative spectrum can be computed using algorithms similar to above. After derivative computation is end, we can find that each type of ground object may have some features distinguished from other entities in a certain rank derivative spectrum and that can be used to identify information. Sometimes derivative spectrum image can be used as the input of classifier directly. Although spectral derivative can provide new features in addition to original information, some new images will be formed after derivative operation and that will increase data volume dramatically. Form rank derivative spectrum, N - 2M bands will be formed, so how to process relationship between data volume and efficiency becomes a new question.5Conclusions and discussionsIn this paper, oriented to the demands of hyper spectral RS information processing to spectral features, the framework of spectral features is proposed and some major feature extraction algorithms and their applications are discussed, and some improvement, experiments and analysis are finished. From the studies in this paper, the following conclusions can be drawn:1 ) Based on the extraction principle and algorithm, spectral features in hyper spectral RS information can be categorized intothree levels: spectral curve features, spectral transformation and computation features and spectral similarity measure features. This framework is useful for further analysis and applications.2) As the common style of pixel spectral vector, some features can be extracted and used. The algorithm and computation of binary encoding is simple and easy but it will lead to loss of some detail information. Quaternary encoding can describe curve features with high rescission and be used to matching, retrieval and other work. The reflection and absorption features based on spectral curve have wide applications in retrieval, thematic information extraction and other tasks, but effective matching strategy must be adopted in order to control errors. In this paper two new app roaches including extended encoding and matching and combined matching of reflectance and absorption features are proposed and it p roved that they can get better results than traditional methods in feature measure.3) As the main computation and transformation features, NDV I and derivative spectrum can provide new features participating in classification, extraction and other processing and extract those useful patterns and information hidden behind original data, so they are very useful in hyper spectral RS information processing.4) For those spectra similarity measure indexes, Spectral Angle and SID are more effective than traditional indexes because they can measure the similarity more precisely, so they are usually used to classification, clustering and retrieval.Some topics about the feature extraction and application of spectral feature are discussed in this paper. Our further studies will be focused on classification, object identification and thematic information extraction in hyper spectral RS information and the specific application modes of different spectral features in order to promote the development of hyper spectral RS application.高光谱遥感信息中的特征提取与应用研究面向高光谱遥感信息处理和应用的需求,在高光谱遥感图像的光谱特征可分为三个尺度:点规模,块规模和数量规模。
药物中钯的测定样品处理方案(欧洲标准)
2.2.23.Atomic absorption spectrometry EUROPEAN PHARMACOPOEIA8.0by diluting the sample solution,by matching the matrix or byusing the method of standard additions.Chemical interferenceis reduced by using chemical modifiers or ionisation buffers.MEMORY EFFECTThe memory effect caused by deposit of analyte in theapparatus may be limited by thoroughly rinsing between runs,diluting the solutions to be measured if possible and thusreducing their salt content,and by aspirating the solutionsthrough as swiftly as possible.METHODUse of plastic labware is recommended wherever possible.Operate an atomic emission spectrometer in accordance withthe manufacturer’s instructions at the prescribed wavelength.Optimise the experimental conditions(flame temperature,burner adjustment,use of an ionic buffer,concentration ofsolutions)for the specific element to be analysed and in respectof the sample matrix.Introduce a blank solution into theatomic generator and adjust the instrument reading to zero orto its blank value.Introduce the most concentrated referencesolution and adjust the sensitivity to obtain a suitable reading.It is preferable to use concentrations which fall within thelinear part of the calibration curve.If this is not possible,thecalibration plots may also be curved and are then to be appliedwith appropriate calibration software.Determinations are made by comparison with referencesolutions with known concentrations of the element tobe determined either by the method of direct calibration(Method I)or the method of standard additions(Method II).METHOD I-DIRECT CALIBRATIONFor routine measurements3reference solutions of the elementto be determined and a blank are prepared and examined.Prepare the solution of the substance to be examined(testsolution)as prescribed in the monograph.Prepare not fewerthan3reference solutions of the element to be determined,the concentrations of which span the expected value in thetest solution.For assay purposes,optimal calibration levelsare between0.7and1.3times the expected content of theelement to be determined or the limit prescribed in themonograph.For purity determination,calibration levels arebetween the limit of detection and1.2times the limit specifiedfor the element to be determined.Any reagents used in thepreparation of the test solution are added to the referencesolutions and to the blank solution at the same concentration.Introduce each of the solutions into the instrument using thesame number of replicates for each solution,to obtain a steadyreading.Calculation.Prepare a calibration curve from the mean ofthe readings obtained with the reference solutions by plottingthe means as a function of concentration.Determine theconcentration of the element in the test solution from thecurve obtained.METHOD II-STANDARD ADDITIONSAdd to at least3similar volumetricflasks equal volumes ofthe solution of the substance to be examined(test solution)prepared as prescribed.Add to all but1of theflasksprogressively larger volumes of a reference solution containinga known concentration of the element to be determined toproduce a series of solutions containing steadily increasingconcentrations of that element known to give responses in thelinear part of the curve,if at all possible.Dilute the contentsof eachflask to volume with solvent.Introduce each of the solutions into the instrument using thesame number of replicates for each solution,to obtain a steadyreading.Calculation.Calculate the linear equation of the graph usinga least-squaresfit,and derive from it the concentration of theelement to be determined in the test solution.VALIDATION OF THE METHODSatisfactory performance of methods prescribed inmonographs is verified at suitable time intervals.LINEARITYPrepare and analyse not fewer than4reference solutions overthe calibration range and a blank solution.Perform not fewerthan5replicates.The calibration curve is calculated by least-square regressionfrom all measured data.The regression curve,the means,themeasured data and the confidence interval of the calibrationcurve are plotted.The operating method is valid when:–the correlation coefficient is at least0.99,–the residuals of each calibration level are randomlydistributed around the calibration curve.Calculate the mean and relative standard deviation for thelowest and highest calibration level.When the ratio of the estimated standard deviation of thelowest and the highest calibration level is less than0.5orgreater than2.0,a more precise estimation of the calibrationcurve may be obtained using weighted linear regression.Bothlinear and quadratic weighting functions are applied to thedata tofind the most appropriate weighting function to beemployed.If the means compared to the calibration curveshow a deviation from linearity,two-dimensional linearregression is used.ACCURACYVerify the accuracy preferably by using a certified referencematerial(CRM).Where this is not possible,perform a testfor recovery.Recovery.For assay determinations a recovery of90per centto110per cent is to be obtained.For other determinations,for example for trace element determination,the test is notvalid if recovery is outside of the range80per cent to120percent at the theoretical value.Recovery may be determined ona suitable reference solution(matrix solution)which is spikedwith a known quantity of analyte(middle concentration ofthe calibration range).REPEATABILITYThe repeatability is not greater than3per cent for an assayand not greater than5per cent for an impurity test.LIMIT OF QUANTIFICATIONVerify that the limit of quantification(for example,determinedusing the10σapproach)is below the value to be measured.01/2008:202232.2.23.ATOMIC ABSORPTIONSPECTROMETRYGENERAL PRINCIPLEAtomic absorption is a process that occurs when a groundstate-atom absorbs electromagnetic radiation of a specificwavelength and is elevated to an excited state.The atoms inthe ground state absorb energy at their resonant frequencyand the electromagnetic radiation is attenuated due toresonance absorption.The energy absorption is virtually adirect function of the number of atoms present.This chapter provides general information and definesthe procedures used in element determinations by atomicabsorption spectrometry,either atomisation byflame,byelectrothermal vaporisation in a graphite furnace,by hydridegeneration or by cold vapour technique for mercury.Atomic absorption spectrometry is a technique fordetermining the concentration of an element in a sample bymeasuring the absorption of electromagnetic radiation bythe atomic vapour of the element generated from the sample.The determination is carried out at the wavelength of one of 36See the information section on general monographs(cover pages)EUROPEAN PHARMACOPOEIA 8.0 2.2.23.Atomic absorptionspectrometrythe absorption (resonance)lines of the element concerned.The amount of radiation absorbed is,according to theLambert-Beer law,proportional to the element concentration.APPARATUSThis consists essentially of:–a source of radiation;–a sample introduction device;–a sample atomiser;–a monochromator or polychromator;–a detector;–a data-acquisition unit.The apparatus is usually equipped with a backgroundcorrection system.Hollow-cathode lamps and electrodeless discharge lamps (EDL)are used as radiation source.The emission of such lamps consists of a spectrum showing very narrow lines with half-width of about 0.002nm of the element being determined.There are 3types of sample atomisers:–Flame techniqueA flame atomiser is composed of a nebulisation system with a pneumatic aerosol production accessory,a gas-flow regulation and a burner.Fuel-oxidant mixtures arecommonly used to produce a range of temperatures from about 2000K to 3000K.Fuel gases include propane,hydrogen and acetylene;air and nitrous oxide are used as oxidants.The configuration of the burner is adapted to the gases used and the gas flow is adjustable.Samples are nebulised,acidified water being the solvent of choice for preparing test and reference anic solvents may also be used if precautions are taken to ensure that the solvent does not interfere with the stability of the flame.–Electrothermal atomisation techniqueAn electrothermal atomiser is generally composed of a graphite tube furnace and an electric power source.Electrothermal atomisation in a graphite tube furnace atomises the entire sample and retains the atomic vapour in the light path for an extended period.This improves the detection limit.Samples,liquid as well as solid,are introduced directly into the graphite tube furnace,which is heated in a programmed series of steps to dry the sample and remove major matrix components by pyrolysis and to then atomise all of the analyte.Thefurnace is cleaned using a final temperature higher than the atomisation temperature.The flow of an inert gas during the pyrolysis step in the graphite tube furnace allows a better performance of the subsequent atomisation process.–Cold vapour and hydride techniqueThe atomic vapour may also be generated outside the spectrometer.This is notably the case for the cold-vapour method for mercury or for certain hydride-forming elements such as arsenic,antimony,bismuth,selenium and tin.For mercury,atoms are generated by chemical reduction with stannous chloride or sodium borohydride and the atomic vapour is swept by a stream of an inert gas into a cold quartz cell mounted in the optical path of the instrument.Hydrides thus generated are swept by an inert gas into a heated cell in which they are dissociated into atoms.INTERFERENCESChemical,physical,ionisation and spectral interferences are encountered in atomic absorption measurements.Chemical interference is compensated by addition of matrix modifiers,of releasing agents or by using high temperature produced by a nitrous oxide-acetylene flame;the use of specific ionisation buffers (for example,lanthanum and caesium)compensates for ionisation interference;by dilution of the sample,through the method of standard additions or by matrix matching,physical interference due to high salt content or viscosity is eliminated.Spectral interference results from the overlapping of resonance lines and can be avoided by using a different resonance line.The use of Zeeman background correction also compensates for spectral interference and interferences from molecular absorption,especially when using the electrothermal atomisation technique.The use of multi-element hollow-cathode lamps may also cause spectral interference.Specific or non-specific absorption is measured in a spectral range defined by the band-width selected by the monochromator (0.2-2nm).BACKGROUND CORRECTIONScatter and background in the flame or the electrothermal atomisation technique increase the measured absorbance values.Background absorption covers a large range ofwavelengths,whereas atomic absorption takes place in a very narrow wavelength range of about 0.005-0.02nm.Background absorption can in principle be corrected by using a blank solution of exactly the same composition as the sample,but without the specific element to be determined,although this method is frequently impracticable.With the electrothermal atomisation technique the pyrolysis temperature is to be optimised to eliminate the matrix decomposition products causing background absorption.Background correction can also be made by using 2different light sources,the hollow-cathode lamp that measures the total absorption (element +background)and a deuterium lamp with acontinuum emission from which the background absorption is measured.Background is corrected by subtracting the deuterium lamp signal from the hollow-cathode lamp signal.This method is limited in the spectral range on account of the spectra emitted by a deuterium lamp from 190-400nm.Background can also be measured by taking readings at a non-absorbing line near the resonance line and thensubtracting the results from the measurement at the resonance line.Another method for the correction of background absorption is the Zeeman effect (based on the Zeeman splitting of the absorption line in a magnetic field).This is particularly useful when the background absorption shows fine structure.It permits an efficient background correction in the range of 185-900nm.CHOICE OF THE OPERATING CONDITIONSAfter selecting the suitable wavelength and slit width for the specific element,the need for the following has to be ascertained:–correction for non-specific background absorption,–chemical modifiers or ionisation buffers to be added to the sample as well as to blank and reference solutions,–dilution of the sample to minimise,for example,physical interferences,–details of the temperature programme,preheating,drying,pyrolysis,atomisation,post-atomisation with ramp and hold times,–inert gas flow,–matrix modifiers for electrothermal atomisation (furnace),–chemical reducing reagents for measurements of mercury or other hydride-forming elements along with cold vapour cell or heating cell temperature,–specification of furnace design (tank,L’vov platform,etc).METHODUse of plastic labware is recommended wherever possible.The preparation of the sample may require a dissolution,a digestion (mostly microwave-assisted),an ignition step or a combination thereof in order to clear up the sample matrix and/or to remove carbon-containing material.If operating in an open system,the ignition temperature should not exceed 600°C,due to the volatility of some metals,unless otherwise stated in the monograph.General Notices (1)apply to all monographs and other texts372.2.24.Absorption spectrophotometry,infrared EUROPEAN PHARMACOPOEIA8.0Operate an atomic absorption spectrometer in accordance with the manufacturer’s instructions at the prescribed wavelength.Introduce a blank solution into the atomic generator and adjust the instrument reading so that it indicates maximum transmission.The blank value may be determined by using solvent to zero the apparatus.Introduce the most concentrated reference solution and adjust the sensitivity to obtain a maximum absorbance reading.Rinse in order to avoid contamination and memory effects.After completing the analysis,rinse with water R or acidified water.If a solid sampling technique is applied,full details of the procedure are provided in the monograph.Ensure that the concentrations to be determined fall preferably within the linear part of the calibration curve.If this is not possible,the calibration plots may also be curved and are then to be applied with appropriate calibration software. Determinations are made by comparison with reference solutions with known concentrations of the element tobe determined either by the method of direct calibration (Method I)or the method of standard additions(Method II). METHOD I-DIRECT CALIBRATIONFor routine measurements3reference solutions and a blank solution are prepared and examined.Prepare the solution of the substance to be examined(test solution)as prescribed in the monograph.Prepare not fewer than3reference solutions of the element to be determined, the concentrations of which span the expected value in the test solution.For assay purposes,optimal calibration levels are between0.7and1.3times the expected content of the element to be determined or the limit prescribed in the monograph. For purity determination,calibration levels are the limit of detection and1.2times the limit specified for the element to be determined.Any reagents used in the preparation of the test solution are added to the reference and blank solutions at the same concentration.Introduce each of the solutions into the instrument using the same number of replicates for each of the solutions to obtain a steady reading.Calculation.Prepare a calibration curve from the mean of the readings obtained with the reference solutions by plotting the means as a function of concentration.Determine the concentration of the element in the test solution from the curve obtained.METHOD II-STANDARD ADDITIONSAdd to at least3similar volumetricflasks equal volumes of the solution of the substance to be examined(test solution) prepared as prescribed.Add to all but1of theflasks progressively larger volumes of a reference solution containing a known concentration of the element to be determined to produce a series of solutions containing steadily increasing concentrations of that element known to give responses in the linear part of the curve,if possible.Dilute the contents of each flask to volume with solvent.Introduce each of the solutions into the instrument,using the same number of replicates for each of the solutions,to obtain a steady reading.Calculation.Calculate the linear equation of the graph using a least-squaresfit and derive from it the concentration of the element to be determined in the test solution.VALIDATION OF THE METHODSatisfactory performance of methods prescribed in monographs is verified at suitable time intervals. LINEARITYPrepare and analyse not fewer than4reference solutions over the calibration range and a blank solution.Perform not fewer than5replicates.The calibration curve is calculated by least-square regression from all measured data.The regression curve,the means,the measured data and the confidence interval of the calibration curve are plotted.The operating method is valid when:–the correlation coefficient is at least0.99,–the residuals of each calibration level are randomly distributed around the calibration curve.Calculate the mean and relative standard deviation for the lowest and highest calibration level.When the ratio of the estimated standard deviation of the lowest and the highest calibration level is less than0.5or greater than2.0,a more precise estimation of the calibration curve may be obtained using weighted linear regression.Both linear and quadratic weighting functions are applied to the data tofind the most appropriate weighting function to be employed.If the means compared to the calibration curve show a deviation from linearity,two-dimensional linear regression is used.ACCURACYVerify the accuracy preferably by using a certified reference material(CRM).Where this is not possible,perform a test for recovery.Recovery.For assay determinations a recovery of90per cent to110per cent is to be obtained.For other determinations, for example,for trace element determination the test is not valid if recovery is outside of the range80per cent to120per cent at the theoretical value.Recovery may be determined on a suitable reference solution(matrix solution)which is spiked with a known quantity of analyte(middle concentration of the calibration range).REPEATABILITYThe repeatability is not greater than3per cent for an assay and not greater than5per cent for an impurity test.LIMIT OF QUANTIFICATIONVerify that the limit of quantification(for example,determined using the10σapproach)is below the value to be measured.01/2008:20224 2.2.24.ABSORPTION SPECTROPHOTOMETRY,INFRARED Infrared spectrophotometers are used for recording spectra in the region of4000-650cm−1(2.5-15.4μm)or in some cases down to200cm−1(50μm).APPARATUSSpectrophotometers for recording spectra consist of a suitable light source,monochromator or interferometer and detector. Fourier transform spectrophotometers use polychromatic radiation and calculate the spectrum in the frequency domain from the original data by Fourier transformation. Spectrophotometersfitted with an optical system capable of producing monochromatic radiation in the measurement region may also be used.Normally the spectrum is given as a function of transmittance,the quotient of the intensity of the transmitted radiation and the incident radiation.It may also be given in absorbance.The absorbance(A)is defined as the logarithm to base10of the reciprocal of the transmittance(T):T=,I=intensity of incident radiation,I=intensity of transmitted radiation.38See the information section on general monographs(cover pages)。
On Sequential Monte Carlo Sampling Methods for Bayesian Filtering
methods, see (Akashi et al., 1975)(Handschin et. al, 1969)(Handschin 1970)(Zaritskii et al., 1975). Possibly owing to the severe computational limitations of the time these Monte Carlo algorithms have been largely neglected until recently. In the late 80’s, massive increases in computational power allowed the rebirth of numerical integration methods for Bayesian filtering (Kitagawa 1987). Current research has now focused on MC integration methods, which have the great advantage of not being subject to the assumption of linearity or Gaussianity in the model, and relevant work includes (M¨ uller 1992)(West, 1993)(Gordon et al., 1993)(Kong et al., 1994)(Liu et al., 1998). The main objective of this article is to include in a unified framework many old and more recent algorithms proposed independently in a number of applied science areas. Both (Liu et al., 1998) and (Doucet, 1997) (Doucet, 1998) underline the central rˆ ole of sequential importance sampling in Bayesian filtering. However, contrary to (Liu et al., 1998) which emphasizes the use of hybrid schemes combining elements of importance sampling with Markov Chain Monte Carlo (MCMC), we focus here on computationally cheaper alternatives. We describe also how it is possible to improve current existing methods via Rao-Blackwellisation for a useful class of dynamic models. Finally, we show how to extend these methods to compute the prediction and fixed-interval smoothing distributions as well as the likelihood. The paper is organised as follows. In section 2, we briefly review the Bayesian filtering problem and classical Bayesian importance sampling is proposed for its solution. We then present a sequential version of this method which allows us to obtain a general recursive MC filter: the sequential importance sampling (SIS) filter. Under a criterion of minimum conditional variance of the importance weights, we obtain the optimal importance function for this method. Unfortunately, for numerous models of applied interest the optimal importance function leads to non-analytic importance weights, and hence we propose several suboptimal distributions and show how to obtain as special cases many of the algorithms presented in the literature. Firstly we consider local linearisation methods of either the state space model 3
Abundances in plantetary nebulae Me 2-1
Received 9 January 2004 / Accepted 16 March 2004
Abstract. ISO and IUE spectra of the round planetary nebula Me 2−1 are combined with visual spectra taken from the literature
Astronomy & Astrophysics manuscript no. aa0041-04 (DOI: will be insertendances in planetary nebulae: Me 2−1
R. Surendiranath1 , S. R. Pottasch2 , and P. Garc´ ıa-Lario3
Send offprint requests to: R. Surendiranath, e-mail: nath@iiap.res.in Based on observations with ISO, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, The Netherlands and the UK) and with the participation of ISAS and NASA. This research has also used archival IUE and HST data. Tables 4 and 7 are only available in electronic form at
The purpose of this paper is to determine the chemical abundances for this nebula and to derive parameters like T eff , log g, etc., of its central star more accurately than before. This is achieved first by including the ISO (Infrared Space
Ch9 Bayesian Hypothesis Testingand Bayes Factors解读
Posterior Odds PriorOdds/Data * Bayes Factor
( M1 | x ) p( M1 ) / p( x ) 1 f1 ( x | 1) p1 (1)d1 ( M 2 | x ) p( M 2 ) / p( x ) f 2 ( x | 2 ) p2 (2 )d2
Bayes Factors
Notes taken from Gill (2002)
Bayes Factors are the dominant method of Bayesian model testing. They are the Bayesian analogues of likelihood ratio tests. The basic intuition is that prior and posterior information are combined in a ratio that provides evidence in favor of one model specification verses another. Bayes Factors are very flexible, allowing multiple hypotheses to be compared simultaneously and nested models are not required in order to make comparisons - it goes without saying that compared models should obviously have the same dependent variable.
计量经济学中英文词汇对照
Controlled experiments Conventional depth Convolution Corrected factor Corrected mean Correction coefficient Correctness Correlation coefficient Correlation index Correspondence Counting Counts Covaห้องสมุดไป่ตู้iance Covariant Cox Regression Criteria for fitting Criteria of least squares Critical ratio Critical region Critical value
Asymmetric distribution Asymptotic bias Asymptotic efficiency Asymptotic variance Attributable risk Attribute data Attribution Autocorrelation Autocorrelation of residuals Average Average confidence interval length Average growth rate BBB Bar chart Bar graph Base period Bayes' theorem Bell-shaped curve Bernoulli distribution Best-trim estimator Bias Binary logistic regression Binomial distribution Bisquare Bivariate Correlate Bivariate normal distribution Bivariate normal population Biweight interval Biweight M-estimator Block BMDP(Biomedical computer programs) Boxplots Breakdown bound CCC Canonical correlation Caption Case-control study Categorical variable Catenary Cauchy distribution Cause-and-effect relationship Cell Censoring
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On Bayesian Estimation of Spectral Components for Broadband Noise Reduction in Audio SignalsCUED/F-INFENG/TR.404Patrick J.Wolfe and Simon J.GodsillSignal Processing Group,University of CambridgeDepartment of Engineering,Trumpington StreetCB21PZ,Cambridge,UKAugust2001AbstractShort-time spectral attenuation is a common form of audio signal enhancement in which a time-varyingfilter,or suppression rule,is applied to the frequency-domaintransform of a corrupted signal.Here we review suppression rules derived under aGaussian statistical model and interpret them in a Bayesian framework.In particular,the Ephraim and Malah spectral amplitude estimator is both optimal in a minimummean-square error sense and well-known for its associated colourless residual noise.However,its implementation requires the evaluation of computationally expensive ex-ponential and Bessel functions.Here we show that under the same modelling assump-tions,alternative methods of Bayesian estimation lead to suppression rules exhibitingalmost identical behaviour.We derive three such rules and show that,in addition topermitting an efficient implementation,they also yield a more intuitive interpretation.1IntroductionHerein we address broadband noise reduction for audio signals via statistical modelling of their spectral components.We limit our investigation to short-time spectral attenuation,a popular method of broadband noise reduction in which a time-varyingfilter,or suppres-sion rule,is applied to the frequency-domain transform of a corrupted signal.Wefirst review existing suppression rules derived under a Gaussian statistical model and interpret them in a Bayesian framework.We then employ the same model and framework to derive three new suppression rules exhibiting near-optimal behaviour.This report is organised as follows:in the remainder of Section1we introduce the assumed statistical model and estimation framework,and then employ these in an al-ternate derivation of the minimum mean-square error(MMSE)suppression rules due to1y x expxexpxThe mean of the posterior density appearing in(4)follows directly from its Gaussian form:X Yexpif(8)otherwise(9)Y(10)where it is understood that(9)and(10)are defined over the range of in(7)andin(8);X and D denote the respective variances of the th short-time spectral component of the signal and noise.Additionally,definewhere and are interpreted after[7]as the a priori and a posteriori signal-to-noise ratios(SNR),respectively.Under the assumed model,the posterior density Y(following integration w.r.t. the phase term)is Rician[8]with parameters:Y(12)5(13) where is the gamma function[9,eq.8.310.1]and is the confluent hypergeometric function[9,eq.9.210.1].The MMSE solution of Ephraim and Malah is simply thefirst moment of(11);when combined with the optimal phase estimator(the observed phase[2]),it takes the form of a suppression rule:expYexpSince ln is a monotonically increasing function,one may equivalently maximise the natural logarithm of Y.DefineYln constant6cosFrom(15),we have cos;thereforeSolving the above quadratic equation,and substituting(17) Together(17)and(15)define the following suppression rule:ln constant(19) Substituting(12)and(16)into(19)and solving,we arrive at an estimator differing from that of the joint MAP solution only by a factor of two under the square root(owing to the factor(20) Combining(20)with the Ephraim and Malah phase estimator(i.e.,the observed phase )yields the following suppression rule:(22)3Comparison of ApproximationsFigure1shows the Ephraim and Malah suppression rule as a function of instantaneous SNR(defined in[2]as)and a priori SNR.Figures2,3,and4show the gain difference(in dB)between it and each of the three derived suppression rules(note the difference in scale).Table1shows a comparison of the magnitude of gain differences for the three approximations.The MMSE spectral power suppression rule provides the best and most consistent approximation to the Ephraim and Malah suppression rule,with only slightly less suppression in regions of low a priori SNR.The MAP spectral amplitude approximation,although still within5dB of the optimal value over a wide SNR range, is the poorest.While the sign of the deviation of each of these two approximations is constant,that of the joint MAP suppression rule depends on the instantaneous and a priori SNR.Ephraim and Malah[2]show that at high SNR,their derived suppression rule con-verges to the Wiener suppression rule detailed in Section1.3,formulated as a function of :3COMPARISON OF APPROXIMATIONS CUED/F-INFENG/TR.404dB dB Suppression Rule Mean Maximum Range Mean Maximum RangeTable1:Magnitude of deviation from Ephraim and Malah MMSE suppression rule gain This relationship is easily seen from the MMSE spectral power suppression rule given by(22),expanded slightly to the following:(24) As the instantaneous SNR becomes large,(24)may be seen to approach the Wiener sup-pression rule given by(23).As it becomes small,the term in(24)lessens the severity of the attenuation.Capp´e[10]makes the same observation concerning the behaviour of the Ephraim and Malah suppression rule,although the simpler form of the MMSE spectral power estimator shows the influence of the a priori and a posteriori SNR more explicitly.Lastly,we note that the success of the Ephraim and Malah suppression rule is largely due to the authors’decision-directed approach for estimating the a priori SNR[10]. For a given short-time block,the decision-directed a priori SNR estimate is given by a geometric weighting of the SNR in the previous and current blocks:Xarctancos sinsin cosandcos sinexpA solution to the inner integral of(26)is given by[9,p.357,eq.3.338.4]:A solution to(27)is given by[9,p.737,eq.6.631.1]:where is the confluent hypergeometric function[9,eq.9.210.1].Letting15Noting that[9,p.1086,eq.9.212.3]we obtainy which is zero whenx。