A Hybrid ACDC Microgrid and
考虑车网互动的风-光-车-储微网容量配置方法
考虑车网互动的风-光-车-储微网容量配置方法*刘舒真1,崔昊杨1*,刘昊1,张明达2,孙益辉2,史晨豪3(1.上海电力大学电子与信息工程学院,上海200090;2.国网浙江宁波市奉化区供电有限公司,浙江宁波315500;3.上海电力大学电气工程学院,上海200090)随着化石能源的日益匮乏和环境的不断恶化,以风能和太阳能为代表的新能源具有绿色、清洁、可再生等优点而受到关注。
然而,高渗透率下的新能源出力的不确定性,也给电网运行带来新的挑战。
另一方面,“新基建”的建设给电动汽车(electric vehicle,EV)带来新的热潮,电动汽车规模化入网成为必然趋势。
特别地,以车网互动(vehicle to grid,V2G)模式接入电网后,电动汽车作为一种能量密集型移动储能单元,在平滑区域能量波动的同时提高可再生能源的接纳能力和利用效率。
因此,以风-光-车-储为能量单元的微电网系统的优化配置与管理,逐渐成为研究热点。
在风-光-车-储微电网的优化配置领域,文献[8]结合电动汽车与分布式电源的时空、时序特性,协同规划分布式电源与电动汽车充电站;文献[9-10]建立路径选择模型、耦合交通网与电力网,优化微电网容量配置方案。
以上文献均考虑分布式电源与电动汽车的协同规划,但忽略了对电动汽车充放电引导,所形成的规划方案存在容量浪费,投资额度大,回报周期长等问题。
另外一方面,已有研究或集中于对给定的微电网,研究电动汽车的充电引导策略。
文献[11-12]基于价格激励政策探究电动汽车摘要:以车网互动模式接入微电网后,电动汽车可与分布式电源在微电网内有机集成,促进二者的应用,有助于提高整体的运行能效。
因此,针对风-光-车-储微电网系统的电动汽车充电引导及微源容量优化问题,文章提出了一种考虑车网互动的风-光-车-储微电网容量配置方法。
首先建立了基于电价激励的电动汽车有序排队充放电模型,引导电动汽车充放电行为有序化;接着兼顾经济效益和联络线功率波动值,建立风-光-车-储微电网系统容量多目标优化模型;然后利用NSGA-II算法优化微源容量配置;最后通过不同场景下规划结果的对比,分析不同电动汽车调度策略对规划方案效益和联络线功率波动的影响。
rf and microwave circuit design pdf
rf and microwave circuit design pdfRF (Radio Frequency) and Microwave Circuit Design is a crucial area in the realm of electronics engineering. This technology enables the development of wireless communication systems, such as radio broadcasting, satellite communication, mobile networks, and radar systems. An RF and MicrowaveCircuit Design PDF provides a comprehensive guide to the theory, design, and implementation of RF and microwave circuits. In this article, we will discuss the various steps involved in RF and Microwave Circuit Design.Step 1: Understanding the Basics of RF and Microwave Circuit DesignBefore starting the design process, it is essential to have a solid grasp of the theory and concepts behind RF and Microwave circuitry. This includes understanding electromagnetic waves, transmission lines, impedance matching, and various other aspects of the RF and microwave spectrum.Step 2: Selecting the Desired Frequency BandThe selection of a frequency band is a critical step in the design process. The band of frequencies that you choose will depend on the particular application of the circuit. For example, a circuit designed for wireless communication will typically operate in the GHz (Gigahertz) range, while acircuit for a radar system might operate in the low MHz (Megahertz) range.Step 3: Designing the Circuit SchematicThe circuit schematic is the blueprint for the actualhardware implementation of the RF or microwave circuit. It isessential to design a schematic that accurately represents the desired functionality of the circuit. This includes selecting appropriate active and passive components, such as transistors, diodes, capacitors, and resistors.Step 4: Simulating and Testing the Circuit Design Simulating and testing the circuit design is a crucial stepin the design process. Computer-aided design (CAD) software can be used to simulate the circuit, enabling the designer to identify potential problems and modify the design as needed. Once the simulation is complete, the circuit should be tested in a real-world environment to ensure that it meets the desired specifications and performance requirements.Step 5: Fabricating the PCB BoardOnce the circuit design has been simulated and tested successfully, it is time to fabricate the printed circuit board (PCB). The PCB is the physical implementation of the circuit schematic and is the backbone of the overall circuit design.Step 6: Final Assembly and TestingThe final step in the design process is to assemble and test the completed circuit. This includes soldering components to the PCB, connecting any external components or peripherals, and conducting comprehensive testing to ensure that thecircuit meets the desired specifications and performance requirements.In conclusion, RF and microwave circuit design is a complex and critical area in electronics engineering. The design process involves understanding the theory and concepts of RF and Microwave circuitry, selecting the desired frequency band, designing the circuit schematic, simulating and testing the circuit design, fabricating the PCB board,and final assembly and testing. By following these steps, electronics engineers can design and implement high-performance RF and Microwave circuits that are optimized for their specific applications.。
best practices for radiative cooling
best practices for radiative cooling1. Choose the right materials: Opt for materials with high emissivity and low reflectivity to enhance radiative cooling. Materials such as ceramics, polymers, and certain metals can be effective in radiating heat away.2. Ensure proper insulation: Proper insulation is essential to prevent the interference of external heat sources. Insulating the radiative cooling surface can prevent heat from being conducted or convected into the system, allowing for more efficient cooling.3. Optimize surface geometry: The surface geometry plays a crucial role in radiative cooling. Designing the surface with features like nanoscale structures, microgrooves, or pyramid-like patterns can enhance radiative heat transfer by increasing the surface area and promoting better light absorption.4. Enhance thermal emissivity: Applying special coatings or pigments with high thermal emissivity on the cooling surface can boost its cooling performance. These coatings enhance the material's ability to emit thermal radiation, increasing the cooling efficiency.5. Maximize heat exchange: Design the cooling device to maximize heat exchange with the surroundings. This can be achieved by using finned heat sinks or incorporating heat pipes to enhance heat transfer from the cooling surface.6. Utilize selective radiative cooling: Selective radiative cooling involves selectively emitting thermal radiation in the atmospherictransparency window (around 8-13 μm). Incorporating selective radiators and filters can enhance the radiative cooling efficiency by allowing the surface to radiate heat effectively while minimizing absorption of solar radiation.7. Implement active cooling methods: Combining radiative cooling with active cooling methods, such as using fans or liquid cooling, can further enhance cooling efficiency. Active cooling can remove any excess heat absorbed by the cooling surface and maintain lower temperatures.8. Consider environmental factors: Factors like ambient conditions, humidity, and air quality can impact radiative cooling efficiency. Shielding the cooling surface from direct sunlight, ensuring proper ventilation, and keeping the surface clean from dust or contaminants are important considerations.9. Optimize system design: Consider the specific application and optimize the overall system design accordingly. Factors such as the size, shape, and positioning of the radiative cooling surface, as well as any additional components like heat sinks or thermal insulation, should be carefully considered to maximize cooling performance.10. Conduct regular maintenance and monitoring: Regular inspection and maintenance of the radiative cooling system can help identify any issues or performance degradation. Monitoring the system's cooling performance and making adjustments as needed will ensure its continued effectiveness.。
CoilDesigner
CoilDesignerA Refrigerant-to-Air Heat Exchanger Simulation and Design Tool withIntegrated Multi-Objective Optimization RoutinesCoilDesigner is a flexible, user-friendly software tool that was developed to assist in the design, simulation, and optimization of air-to-refrigerant heat exchangers used in heat pumping, air conditioning, and refrigeration systems, as well as applications like automotive radiators, and water coils for fuel cells. CoilDesigner was developed by students and faculty from the Center for Environmental Energy Engineering at the University of Maryland under the Integrated Systems and Optimization Consortium (ISOC). The development has taken place through numerous research projects supported by a diverse group of multinational stakeholders.CoilDesigner is a highly customizable tool with extensive capabilities for simulating tube-fin, micro-channel, and wire-fin heat exchangers of different geometries. One of the greatest benefits of CoilDesigner is its flexibility to model virtually any tube circuitry, including both merges and splits. The user friendly interface allows a user to connect tubes on-screen via consecutive mouse clicks. The software also supports multiple fin types and fins with holes. The number of tube rows and columns that the software can model is limited only by available computer memory. CoilDesigner’s solver analyzes a heat exchanger in a tube-by-tube fashion, where each tube is subdivided into as many segments as the user desires. Furthermore, in any segment where a flow regime change takes place, additional refinement of that particular segment is automatically performed by the software to identify the transition point. CoilDesigner provides built-in options for a user to automatically generate common coil circuitry, or to save any particular geometry in a template file for later use.When simulating the performance of a coil the user has the option to impose either a mass flow rate boundary condition, which tends to solve very quickly, or a pressure boundary condition, which requires more solution time but accounts for unequal refrigerant distribution in the various circuits. Additionally, the user has the option to account for 2-dimensional air side inlet flow distribution in three variables (velocity, temperature, and humidity) to simulate uneven loading that may be caused by a fan or other flow conditions.The ISOC software team provides ongoing development, support, and technical assistance for CoilDesigner. The software is updated continually with the latest heat transfer, pressure drop, fin efficiency, and void fraction correlations available from the literature. Over 30 such correlations areCEEE is a community of innovative and forward thinking students, faculty, staff, and visiting engineers at the University of Maryland who are dedicated to:• Researching energy conversion systems ofminimum impact to the environment and greatest benefit to society.• Educating the next generation ofengineering professionals• Developing innovative solutions to currentand emerging energy conversion challenges • Developing knowledge in support ofstrategic technology decisionsThe Integrated Systems OptimizationConsortium (ISOC) at CEEE specializes in the research and development of software for modeling and optimization of energy conversion systems.CoilDesigner Screen Shotpresently implemented, and CoilDesigner supports the ability for a user to define and employ custom in-house or proprietary correlations. The interface also incorporates an option to apply appropriate correction factors to the built-in correlations to provide a closer match between predicted results and experimental data. Within the CoilDesigner platform the user has the ability to perform parametric analyses on coil geometries and operating conditions by varying coil dimensions such as tube diameter and length, fin spacing, and by varying refrigerant or air inlet parameters. This feature gives the designer an ability to investigate coil performance and sensitivity to different environmental conditions and to different manufacturing options. CoilDesigner also incorporates built-in and user defined cost functions, which help to capture the economic impact of engineering decisions when designing a coil. Detailed results of parametric studies can be viewed and plotted within the program, and can be exported to a spreadsheet or optionally in formatted text.One of the premier features of CoilDesigner is the integrated multi-objective optimization routines that have been built-in to the software. CoilDesigner has the ability to perform optimization on continuous variables such as tube length or fin spacing, or on discrete variables such as tube diameters, which are typically available in a limited number of sizes. Discrete optimization is implemented in CoilDesigner through the use of genetic algorithms. Figure 1 shows the results of an optimization study that was completed on a condenser. The objective of the study was to maximize heat load and minimize coil cost relative to a baseline coil. The results of a multi-objective genetic algorithm optimization lead to a set of optimum values known as Pareto Solutions, shown as red dots in Figure 1. The pink dot represents the baseline coil. Throughout the development of CoilDesigner, extensive efforts have been taken to validate its prediction capabilities against experimental data. Figure 2 shows the results of a validation study for an indoor heat pump coil used in both heating and cooling modes in two different systems. All of the predicted data, with exception of only two points lies within ±5% of the experimental results. Similar studies have been completed, and continue to be performed, for different coils and operating conditions, all with comparable results.CoilDesigner provides a well integrated, experimentally validated toolbox with a user-friendly interface for designing, simulating, and optimizing the performance of air-to-refrigerant heat exchangers for use in heat pump, air conditioning, and refrigeration systems, as well as applications like automotive radiators, and water coils for fuel cells.Figure 1. Results of a Condenser Optimization Study.0.750.80.850.90.9511.051.10.650.750.850.95 1.05 1.15 1.25 1.35Cost (Normalized with respect to baseline coil)H e a t L o a d (N o r m a l i z e d )。
微电网英语
Operation and Control of Microgrid System Integration and Hierarchical Power Management Strategy for a Solid-State TransformerInterfaced Microgrid SystemSchool of Electrical EngineeringElectrical EngineeringContents1 Detail Abstract (1)2 Core techniques of the paper (1)2.1 Hardware integration of SST and dc microgrid (1)2.2 Hierarchical power management strategy (3)3 Potential problems and my opinion on future work (5)1 Detail AbstractThe existing dc microgrid can only interface with the distribution system by using a heavy and bulky line frequency transformer plus rectifier, and the passive transformer cannot provide functions such as Var compensation or harmonic filtering. Therefore, developing a more compact and active grid interface to enable a more intelligent dc microgrid system is a research focus.Under the situation, this paper investigates, and for the first time presents, the system integration of a novel solid-state transformer (SST) interfaced microgrid system. Accordingly, a hierarchical power management strategy is proposed for this system to enable islanding mode operation, SST enabled operation, and the seamless transfer between two modes.To begin with, the paper review the past achievements in the microgrid field and introduce the different types of microgrid from the architecture and the power management point of view. Then the author presents the detailed structure of the proposed system, as is shown in Fig. 1.Fig 1. SST-enabled dc microgrid diagram.Furthermore, the researcher depicts the hierarchical control frame and analyzes the hierarchical control for dc microgrid in islanding mode and SST-enabled mode. The hierarchical power management strategy includes three control levels: primary control for the local controller; secondary control for the dc microgrid bus voltage recovery; and tertiary control to manage the battery state of charge.Finally, a lab test bed is constructed to verify the system performance, and several typical case studies are carried out. The experimental results verify the proposed system and distributed power management strategy.Keywords: DC microgrid, hierarchical power management, islanding mode, solid-state transformer (SST)-enabled mode.2 Core techniques of the paper2.1 Hardware integration of SST and dc microgridAs previously mentioned, the conventional transformer interfaced with the dc microgrid is heavy and bulky, which takes too much space. The core technique of thispaper is, for the first time, presenting the hardware integration of SST and dc microgrid to demonstrate the feasibility of this novel concept. Compared to the conventional microgrid architecture, the presented microgrid system interfaces with the distribution system by an active grid interface with smaller size and less weight. The SST interfaced microgrid is, therefore, a more compact system.The SST is a power electronic device that replaces the traditional 50/60 Hz power transformer by means of high-frequency transformer isolated ac–ac conversion technique, and its topology is represented in Fig. 2, where a cascaded seven level rectifier is adopted as the font-end. Three dual active bridge (DAB) converters are connected to the floating dc links of the rectifier with the secondary side connected in parallelFig. 2. Topology of presented SST.The basic operation of the SST is first to change the 50/60 Hz ac voltage to a high-frequency voltage, then this high-frequency voltage is stepped up or down by a high frequency transformer, and finally shaped back into the desired 50/60 Hz voltage to feed the load. For a high-frequency transformer has significantly decreased volume and weight, the first advantage that the SST may offer is reduced volume and weight compared with traditional transformers. A laboratory prototype of a single-phase, three-stage SST was built, as shown in Fig. 3.Fig.3. Cascaded type three-stage SST prototype.It is further seen from the topology and the configuration of the SST that some other potential functionalities that are not available to traditional transformer may be obtained. A functional diagram of SST is illustrated in Fig. 4. The SST acts as a smart plug-and play interface for transforming and distributing electric energy from these various different subsystems, some via the ac port and others via the dc port. The use of SST separates the grid side parameters (voltage, frequency) from the DRER (Distributed renewable electric resource) and DESD (Distributed energy storage device) side. This is a very important capability of the proposed system that strengthens the system stability because the low-voltage side is strongly decoupled from the grid side by the SST.Fig. 4. Solid state transformer functional configuration.2.2 Hierarchical power management strategyFrom the power management point of view, the presented microgrid system need to ensure proper and optimal operation under different conditions. Some major challenges for SST-enabled dc microgrid include:1) how to make the dc microgrid more reliable in islanding mode;2) how to achieve seamless transfer between islanding mode andSST-enabled mode for the dc microgrid;3) how to manage individual modules in the dc microgrid considering thecharacter differences when system is in SST-enabled mode.To address these challenges, another core technique of this paper is a corresponding hierarchical power management strategy, which combines the advantages of centralized control and distributed control.Its basic structure is shown in Fig. 5.Fig 5. Hierarchical control frame.The primary control is the distributed control which ensures that the microgrid system can operate without communication. Therefore, the primary control usually takes effect at the microsecond level, which is basically the same level as the converter control. All the local information, including the voltage, current, SOC (State of charge), etc., are sent to the upper controller, which implements the tertiary control and secondary control through a bidirectional communication link. Here, the dc microgrid is enabled by the SST, and therefore the SST controller is used as the upper controller. The objective of secondary control is to recovery the microgrid bus voltage to achieve seamless transfer as the system switches from islanding mode to SST-enabled mode. The time scale for the secondary control is on the order of milliseconds to seconds. The objective of tertiary control is to ensure that battery operates in a reliable SOC range. Thus, the tertiary control is used to charge and discharge the battery in the dc microgrid based on battery’s SOC instead of controlling the point of common coupling power flow. Detailed structure of the hierarchical control strategy is depicted in Fig. 6.Fig. 6. DC microgrid operation diagram.In summary, the proposed SST-enabled dc microgrid can:1)interface with distribution system via SST;2)operate in islanding mode with distributed control;3)seamlessly transfer between islanding mode and SST enabled mode;4)enable battery management in SST-enabled mode.3 Potential problems and my opinion on future workAs is shown in Fig. 6, the SOC monitoring is implemented in the tertiary control, in which battery management is achieved by suitable charging and discharging, but the monitoring method and its hardware design are not mentioned in this paper.In my opinion, accurate monitoring of the energy storage system performance is the fundamental basis to achieve the hierarchical control. However, the current monitoring technology is still not mature enough, of which SOC cannot be directly measured. A pressing matter of the moment, therefore, is to establish an accurate estimation model of the SOC monitoring.In addition, the experimental results in this paper only demonstrate the feasibility of the SST interfaced microgrid system in island operation. But when it is parallel with Power Grid, the power electronic devices of SST may be so sensitive (usually take effects at the microsecond level) that the traditional grid devices as circuit breaker and isolating switch can’t respond synchronously. This may impact the stability of Power System.My opinion is to solve the problem from the following aspects:1) Taking the interaction between the SST and the distributed system intoconsideration to guide the design of the proposed microgrid system;2) Constructing the architecture of multi-layer-cross distributed renewable energymanagement based on the advantages of agent technology;3) Using artificial intelligence technology to control several nodes in themicrogrid and cooperatively;4) Connecting more PV and battery modules to the dc bus to verify the robustoperation of the system.[文档可能无法思考全面,请浏览后下载,另外祝您生活愉快,工作顺利,万事如意!]。
Smart Grid and Energy Storage
Smart Grid and Energy Storage The smart grid and energy storage are crucial components of the modern energy infrastructure, playing a pivotal role in ensuring a reliable, efficient, and sustainable supply of electricity. The smart grid encompasses a range of technologies and strategies aimed at optimizing the generation, transmission, and distribution of electricity, while energy storage systems enable the capture and utilization of surplus energy, providing a valuable resource for balancing supply and demand. However, despite their numerous benefits, the integration of smartgrid and energy storage technologies poses various challenges and considerations that must be carefully addressed to realize their full potential. One of the primary benefits of the smart grid is its ability to enhance the overallefficiency and reliability of the electricity system. By leveraging advanced communication and control capabilities, the smart grid enables real-time monitoring and management of electricity flows, facilitating the integration of renewable energy sources, demand response programs, and other distributed energy resources. This enhanced visibility and control empower utilities to optimizetheir operations, reduce system losses, and improve the overall resilience of the grid. Additionally, the smart grid enables more precise billing and consumption data, empowering consumers to make informed decisions about their energy usage and potentially reduce their electricity costs. Energy storage technologies play a complementary role in the smart grid ecosystem, offering a means to capture and store excess energy for later use. This capability is particularly valuable in the context of intermittent renewable energy sources, such as solar and wind, which may produce surplus energy during periods of low demand or low generation. By deploying energy storage systems, utilities can capture this surplus energy and deploy it during peak demand periods, thereby reducing the need for conventional peaking power plants and enhancing the overall flexibility and reliability of the grid. Furthermore, energy storage systems can provide backup power during outages, support critical infrastructure, and enable off-grid electrification in remote or underserved areas. Despite these benefits, the integration of smart grid and energy storage technologies presents various technical, regulatory, and economic challenges. From a technical perspective, the deployment of advanced communicationand control systems, as well as the integration of diverse energy storage technologies, requires careful planning and coordination to ensure compatibility and interoperability. Moreover, the intermittent and variable nature of renewable energy sources introduces additional complexity, requiring sophisticated forecasting and optimization algorithms to maximize the value of energy storage assets. On the regulatory front, the deployment of smart grid and energy storage technologies may raise concerns related to data privacy, cybersecurity, and grid reliability. As the smart grid enables the collection of granular consumption data and the remote control of grid assets, it is essential to establish robust regulations and standards to protect consumer privacy and ensure the secure operation of the grid. Additionally, the integration of energy storage systemsinto the grid may require updates to existing regulations and market structures to accurately value the services provided by these assets and incentivize their deployment. From an economic standpoint, the upfront costs of deploying smartgrid and energy storage technologies can be significant, requiring utilities and policymakers to carefully assess the potential benefits and trade-offs. While energy storage technologies are becoming increasingly cost-competitive, especially for applications such as peak shaving and grid support, the business case fortheir deployment may vary depending on local market conditions, regulatory frameworks, and the specific needs of the grid. Furthermore, the long-term operation and maintenance of these technologies must be carefully considered to ensure their continued performance and value over time. In conclusion, the integration of smart grid and energy storage technologies holds great promise for enhancing the efficiency, reliability, and sustainability of the electricity system. By leveraging advanced communication and control capabilities, the smart grid enables the seamless integration of renewable energy sources and demand-side resources, while energy storage systems provide a valuable means to capture and deploy surplus energy. However, realizing the full potential of these technologies requires careful consideration of technical, regulatory, and economic challenges, as well as ongoing innovation and collaboration among stakeholders. Ultimately, the smart grid and energy storage represent essential building blocks for thefuture of energy, offering a pathway to a more resilient, flexible, and sustainable electricity system.。
fundamentals of thermoelectricity oxford 2015
fundamentals of thermoelectricityoxford 2015The fundamentals of thermoelectricity, as discussed in the Oxford 2015 book, are crucial for understanding the conversion of heat into electrical energy. This field combines principles from thermodynamics, solid-state physics, and materials science to explore the behavior and performance of thermoelectric devices. Thermoelectricity has gained significance in recent years due to its potential application in waste heat recovery, portable power generation, and energy-efficient cooling systems. Let's dive into some key concepts covered in this book.Thermoelectric phenomena arise from a temperature gradient across a material or device. The underlying principle is the Seebeck effect, which describes the generation of an electric voltage when there is a temperature difference between two points in a conductor or semiconductor. This voltage is proportional to the gradient in temperature and depends on the material properties.热电现象是在材料或器件中存在温度梯度时产生的。
山东省费县第二中学2021届高三2月模拟考试英语试卷 Word版含答案
高三英语模拟考试题【满分:120分】本试卷满分120分,考试时间100分钟。
第一部分阅读理解(共两节,满分50分)第一节(共15小题;每小题2.5分,满分37.5分)阅读下列短文,从每题所给的四个选项(A、B、C和D)中,选出最佳选项。
ABusiness is all about making connections, but some connections are easier to make than others. Next time you travel the world, make sure the world travels with you. By staying at a CNN Partner Hotel, the world is always at your fingertips. Check-in, log on, and get connected with all of the latest developments.Anantara Siam Bangkok HotelFeel the heartbeat of this city in a very elegant and quiet place. Appreciate traditional Thai architecture, hand-painted silk ceilings, a magnificent hall and gardens. Fulfill your appetite for the sensational with plates in award-winning restaurants. Explore heritage sites, contemporary experiences and the hidden treasures of Bangkok from the most impressive of addresses.Radisson Blu HotelThe Radisson Blu Hotel in Nydalen, Oslo, Norway stands on the shores of the Aker River in the city's business district. Each of our contemporary rooms features thoughtful facilities and services including a minibar, a work desk and free high-speed Wi-Fi. To maintain your fitness routine on your trip to Oslo, walk across the street to Evo Fitness, where our hotel guests enjoy free service. Planning an event in Oslo? Choose from our 11 fully equipped meeting rooms, covering a total of 900 square meters.The Merrion HotelThe Merrion, located in the heart of Dublin city center, is the capital's most luxurious five-star hotel, and a proud member of The Leading Hotels of the World. The 142-bedroom and suite hotel is as welcoming as it is stylish. The Merrion is a marriage of extreme comfort, relaxed elegance and advanced guest facilities, including free Wi-Fi, an 18m pool, spa and gym. This five-star luxury hotel is to be found in the heart of Georgian Dublin, opposite Government Buildings and a few minutes' walk from galleries, museums, restaurants and the shops of Grafton Street.1.What is special about Anantara Siam Bangkok Hotel?A. It requires reservation ahead of time.B. It provides a combined experience ofpast and present.C. It allows visitors to explore everywhere.D. It offers traditional food for free.2.Which hotel can offer you the chance to arrange a conference?A. CNN Partner Hotel.B. The Merrion Hotel.C. Anantara Siam Bangkok Hotel.D. Radisson Blu Hotel.3.What kind of impression will The Merrion Hotel leave on you?A. Romantic.B. Plain.C. Adventurous.D.Fashionable.BAt the end of August this year I moved from London, UK, to a small town in Quebec, Canada, called Matane to work as an English language assistant. Patience is a word that has appeared in many forms over the past two months.I don't see myself as being the most patient person in the world but there was something that struck me on my first week of work. I had just finished a session with two students and just as they were leaving the classroom, one of the students turned back and said, "Thank you for your patience." That was an early reminder of the importance of being patient as a teacher. It also made me reflect on the language teachers that I have had over the years, ones that demonstrated a high level of patience and understanding that has shaped my language learning path. Moreover, it helped me to realize the importance of demonstrating patience in the classroom as it can be the difference between building someone's confidence in a language or breaking down their confidence entirely.Living my life constantly in French is not easy but the people of Quebec are very patient. They repeat things several times and they are more than happy to wait while I find the correct words to express myself and find the correct word order. It's a learning process but with the patience of others, the process is slightly less nervous. At the end of the day, making mistakes shows you are trying and I think that is greatly appreciated by Quebecers.When I first arrived in Matane I kept getting headaches from having to concentrate all the time due to the language and even overhearing other people's conversations was hard work! I had to keep reminding myself that it would take time, and two months later the headaches are a distant memory and my ears have become more tuned to their accent. The key is to be patient with yourself.4.What is important as a teacher according to Paragraph 2?A.Understanding.B.Patience.C.Confidence.D.Help.5.In a small town called Matane, which language do the local people speak?A.English.B.Spanish.C.French.D.Italian.6.What about the author when hearing the student's words?A.She felt kind of surprised.B.She thought he was wrong.C.She realized she needed more patience.D.She was at a loss what to do.7.What can we infer according to the last paragraph?A.The key to success is patient with yourself.B.Don't be always talking with others ina new place.C.It takes two months to master a new language.D.The headache left the author a poormemory.CGenerating electricity from thin air may sound like science fiction, but a new technology basedon nanowire(纳米线) bacteria does just that —as long as there's moisture(水分) in the air. A new study shows that when fashioned into a film, these wires —protein lines that send electrons(电子) away from the bacteria —can produce enough power to light a light-emitting diode(二极管). The film works by simply absorbing humidity from the surrounding air. Though researchers aren't sure exactly how these wires work, the tiny power plants make a great difference: Seventeen devices linked together can generate 10 volts, which is enough electricity to power a cellphone.The new method should be considered a "milestone advance" says Guo Wanlin, a materials scientist at Nanjing University who wasn't involved with the work. Guo studies hydrovoltaics, a molecular approach to harvesting electricity from water.The way hydrovoltaic devices work is still a bit of a mystery. When water droplets interact with certain kinds of graphene (石墨烯) or other materials, an electric charge is generated, and electrons move through the materials. Many questions remain about exactly how these devices generate electricity, however. "I think a deeper understanding… is needed," says Dirk de Beer, a microbiologist developing microsensors at the Max Planck Institute for Marine Microbiology.Researchers are also just starting to learn how electron-conducting bacteria function. More than 15 years ago, co-author Derek Lovley, a microbiologist at the University of Massachusetts(UMASS), Amherst, and his colleagues discovered that a bacterium called Geobacter shuttles electrons from organic material to metal-based mixtures, such as iron oxides. Since then, he and others have learned that many other bacteria make protein nanowires to transfer electrons to other bacteria or deposits in their environments. This transfer creates a small electrical current, which researchers have tried with varying degrees of success as clean energy. Using water vapor is "a revolutionary technology to get renewable, green, and cheap energy directly from atmospheric wetness," says Qu Liangti, a materials scientist at Tsinghua University.8.What do "the tiny power plants" in Paragraph 1 refer to?A. Electrons.B. Protein nanowires.C. Seventeen devices.D. Light-emitting diodes.9.What is the purpose of the second and third paragraphs?A. To explain what hydrovoltaics is.B.To introduce Dirk de Beer’sdoubts.C. To stress the new method's advance.D. To tell how electron-conductingbacteria function.10.W hat can we learn from the text?A. Guo Wanlin is a co-author of Derek Lovley.B. Researchers are sure how protein nanowires work.C. Graphene mixed with iron oxides can make electricity.D. Researchers sometimes fail to get electricity from bacteria.11.W hich of the following is the best title for the text?A. Water Vapor is a Green and Cheap Energy.B.Molecular Harve Electricity fromWater.C. Electric Bacteria Create Currents out of Air.D. Hydrovoltaic and Nanowire DevicesRequire Power.DA completely new type of cooling panel has been created by researchers at Stanford University. The new structure works to reflect significant amounts of sunlight back into space even in full sunlight.To explain the breakthrough in specific terms: "a typical one-story, single-family house with just 10 percent of its roof covered by radioactive cooling panels could make up for 35 percent its entire air conditioning needs during the hottest hours of the summer."As the press release from Stanford University's Engineering site states it, "Tapping the cold sky of outer space to cool the planet. Science fiction, you say? Well, maybe not any more.""People usually see space as a source of heat from the sun, but away from the sun outer space is really a cold, cold place," says Shanhui Fan, professor of electrical engineering and the paper's senior author. "We've developed a new type of structure that reflects the vast majority of sunlight, while at the same time it sends heat into that coldness, which cools human-made structures even in the day time."The engineering "trick" that makes this possible is the crossing of an important thresh-hold. The reflector needs to be effective enough that it absorbs only a very low minimum of sunlight, and avoids heating up at all as a result. The other important factor is that the structure needs to be very efficient at reflecting heat back into outer space. "Thus, the structure must send out heat radiation very efficiently within a specific wavelength range in which the atmosphere is nearly transparent (透明的). Outside this range, Earth's atmosphere simply reflects the light back down." You're probably already familiar with this effect, it's commonly known as the greenhouse effect.The new cooling panel, made from nano-structured quartz and silicon carbide (碳化硅), fulfills both of these requirements. It's very effective at reflecting most sunlight, while also very effectively sending heat radiation in the wavelength range necessary to escape the Earth's atmosphere.12.W hat can the new solar structure be used to do?A.To turn light energy into electric energyB.To reflect amounts of sunlightbackC.To provide information for researchersD.To extend the hours of sunlightin winter13.A ccording to Shanhui Fan we can know that ____________.A.the earth will be cooled by outer spaceB.human beings are fightingagainst natureC.no one is capable of living in outer spaceD.such structures will be sent tospace14.W hat is the function of the reflector?A.To support and fix a thresh-hold.B.To take in sunlight effectively.C.To play a trick in the process.D.To keep the wavelength in order.15.W hat can we conclude from the passage?A.The solar structure can lower our bills.B.A majority of sunlight can berefused.C.The Earth's atmosphere will disappear.D.Humans can rule out greenhouseeffect.第二节(共5小题;每小题2.5分,满分12.5分)根据短文内容,从短文后的选项中选出能填入空白处的最佳选项。
双向CLLLC型DC-DC变换器变频控制方法的研究
双向CLLLC型DC-DC变换器变频控制方法的研究王悦妹;郑丽君;宋建成;田慕琴;许春雨【摘要】CLLLC型BDC能够实现功率双向传输、电压等级转换效率高、正反向都具备软开关等优点,但在传统移相控制时,不能工作在调压模式.文章分析了CLLLC 型BDC的运行特性,优化谐振网络的参数,建立了小信号模型,设计了变频闭环的控制算法.实验结果表明,文章所提出控制方法具有很好的调节性能,可以实现软开关,减小了系统的功率损耗.%CLLLC BDC has the advantages of power bidirectional transmission, high voltage conversion efficiency, soft switch and so on. Under of traditional phase shift (PS) control method, CLLLC BDC can not work in the voltage regulator mode. In this paper, the operational characteristics of CLLLC BDC and the design of the resonant network are analyzed,the resonant paramenters are designed and the small signal model is established. Based on the above analysis the control algorithm of the variable frequency (VF) closed loop is proposed. Finally, experimental results show that the proposed method has good regulation performance, and can achieve soft switching,further reducing the loss of power system.【期刊名称】《可再生能源》【年(卷),期】2017(035)012【总页数】7页(P1798-1804)【关键词】双向传输;变频控制;软开关【作者】王悦妹;郑丽君;宋建成;田慕琴;许春雨【作者单位】太原理工大学电气与动力工程学院,山西太原 030024;矿用智能电器技术国家地方联合工程实验室,山西太原 030024;煤矿电气设备与智能控制山西省重点实验室,山西太原 030024;太原理工大学电气与动力工程学院,山西太原030024;矿用智能电器技术国家地方联合工程实验室,山西太原 030024;煤矿电气设备与智能控制山西省重点实验室,山西太原 030024;太原理工大学电气与动力工程学院,山西太原 030024;矿用智能电器技术国家地方联合工程实验室,山西太原030024;煤矿电气设备与智能控制山西省重点实验室,山西太原 030024;太原理工大学电气与动力工程学院,山西太原 030024;矿用智能电器技术国家地方联合工程实验室,山西太原 030024;煤矿电气设备与智能控制山西省重点实验室,山西太原030024;太原理工大学电气与动力工程学院,山西太原 030024;矿用智能电器技术国家地方联合工程实验室,山西太原 030024;煤矿电气设备与智能控制山西省重点实验室,山西太原 030024【正文语种】中文【中图分类】TK81近年来,世界各国将利用可再生能源做为发展战略。
Ad-hoc on-demand distance vector routing
TheScienceandEngineeringofMicroelectronicFabricati
The Science and Engineering of MicroelectronicFabrication 课后练习题含答案本文为 The Science and Engineering of Microelectronic Fabrication 的课后练习题,含有答案。
该课程旨在介绍微电子制造的基础知识及其相关工艺。
下面是该课程的练习题及解答。
Chapter 11. What is the general definition of microelectronic fabrication?Microelectronic fabrication is the process of manufacturing integrated circuits or microelectromechanical systems (MEMS) on a small scale using various techniques including photolithography, etching, and deposition.2. What is a typical size of an integrated circuit?A typical size of an integrated circuit is in the range of a few millimeters to a few centimeters.3. What is the importance of clean room environment in microelectronic fabrication?Clean room environment is important in microelectronic fabrication because the presence of contaminants can negatively affect the functionality and reliability of the fabricated devices. Contaminants can cause defects, short circuits, and other problems.4. Name three mn types of microelectronic fabrication processes.The three mn types of microelectronic fabrication processes are deposition, lithography, and etching.5. What is the function of a photomask in lithography?A photomask is a template used in lithography to transfer a pattern onto a substrate. The photomask contns the pattern, which is projected onto the substrate using a light source. The photomask determines the size and shape of the pattern that is transferred onto the substrate.Chapter 21. What is the difference between dry and wet etching?Dry etching is a process in which the material is removed from the substrate using a plasma etch. Wet etching is a process in which the material is removed from the substrate using a liquid etchant. Dry etching is more precise and less damaging to the substrate than wet etching, but it is also more expensive.2. What is the function of a mask in etching?A mask is used in etching to protect certn areas of the substrate from being etched. The mask is made from a material that is resistant to the etchant, and it is placed on the substrate before the etching process begins.3. What is the difference between isotropic and anisotropic etching?Isotropic etching removes material in all directions, whereas anisotropic etching removes material in a specific direction. Anisotropic etching is more precise than isotropic etching, but it is also more difficult to control.4. What are the advantages of plasma etching over wet etching?Plasma etching is more precise than wet etching and can be used to etch a wider range of materials. It is also less damaging to the substrate.5. Name two types of dry etching.The two mn types of dry etching are reactive ion etching (RIE) and deep reactive ion etching (DRIE).Chapter 31. What is the purpose of a chemical vapor deposition (CVD) process?The purpose of a chemical vapor deposition process is to deposit a thin film of material onto a substrate. The process involves introducing a gas or vapor mixture into a reaction chamber and allowing it to react on the surface of the substrate.2. What is the difference between physical vapor deposition (PVD) and chemical vapor deposition (CVD)?Physical vapor deposition is a process in which the material is evaporated in a vacuum and deposited onto the substrate. Chemical vapor deposition involves a chemical reaction between a gas or vapor mixture and the substrate.3. What is the function of a sputtering target in physical vapor deposition?A sputtering target is used in physical vapor deposition to generate a plasma of ions which are directed towards the substrate. The ions deposit the material onto the substrate to form a thin film.4. What is the purpose of ion implantation?Ion implantation is used to introduce dopants into a material in order to change its electrical properties. The process involves accelerating ions towards the substrate, where they penetrate the surface and become embedded in the material.5. What is the difference between epitaxy and doping?Epitaxy is the process of growing a thin film of material on a substrate. Doping involves introducing dopants into a material to change its electrical properties.。
Integrated Microgrid Laboratory System
Integrated Microgrid Laboratory SystemBo Zhao,Xuesong Zhang,and Jian ChenAbstract—The paper presents an integrated microgrid labora-tory system with aflexible and reliable multimicrogrid structure; it contains multiple distributed generation systems and energy storage systems and integrates with a diesel generator that serves as a back-up power source andflywheel energy storage for fast balancing to provide uninterruptible power-supply services in cooperation with the diesel generator.The microgrid system, by adopting the master–slave control strategy,can be transited flexibly between grid-connected and islanded modes and can be disconnected from the utility when a fault occurs or the power quality falls below specified standards.The developed bi-direc-tional inverter which is applied in the system plays an important role.The small microgrids of this system are intended to operate separately or in the form of one large microgrid with a certain switch status.Furthermore,experiments on control,protection, and other technologies have been carried out.The results show that the operation conditions meet the related IEEE Standard 1547and power quality requirements.The integrated microgrid laboratory system is able to operate stably and reliably under different conditions,including mode transition and fault events. Index Terms—Bi-directional inverter,diesel generator,flywheel energy storage,master–slave control,microgrid.I.I NTRODUCTIONT HE increase in the penetration depth of distributed gen-erations(DGs)and the presence of multiple DGs in the electrical proximity to one another have brought about the con-cept of the microgrid,which can provide more technical bene-fits and controlflexibilities to the utility gird[1]–[5].Research on microgrid technologies has received increasingly widespread attention recently.Many microgrid technologies such as en-ergy management,control strategies,protection methods,power quality,laboratory systems,andfield tests have been studied in particular[6]–[12].As the carrier of microgrid technologies, the microgrid laboratory system is designed to provide a verifi-cation platform for the researches.The development of labora-tory-scale microgrid systems with the DGs and energy storage systems has become one of the key technology problems that need to be solved in microgrid research.Many microgrid systems have been built in recent years internationally.In North America,the CERTS Microgrid Lab-oratory Test Bed[13]is one of the most authoritative microgridManuscript received October06,2011;revised February01,2012;accepted March13,2012.Date of publication May01,2012;date of current version October17,2012.This work was supported by the Hi-Tech Research and De-velopment Program of China(863)under Contract2011AA05A107.Paper no. TPWRS-00940-2011.B.Zhao and X.S.Zhang are with the Zhejiang Electric Power Test and Re-search Institute,Hangzhou,Zhejiang,310014,China(e-mail:zhaobozju@163. com;ee_zxs@).J.Chen is with the School of Electrical Engineering and Automation,Tianjin University,Tianjin,300072,China(e-mail:chenjiantju@).Color versions of one or more of thefigures in this paper are available online at .Digital Object Identifier10.1109/TPWRS.2012.2192140systems and plays an important role in microgrid research. FortZED(Zero Energy District)[14]is a community-driven initiative to create one of the world’s largest net zero energy districts in the downtown area and the main campus of Col-orado State University.The1-MW FREEDM System[15] demonstration laboratory of North Carolina State University not only demonstrates the Center-developed technologies,but it is also used to showcase the third-party renewable energy technologies,such as solar,wind,fuel cell,battery storage,flywheel storage,and plug-in vehicles.Perfect Power at the Illinois Institute of Technology(IIT)is setting an example for smart grid projects throughout the unched in 2006,the smart microgrid-based system is a ground-breaking approach to electricity distribution and management,creating a reliable power system[16],[17].Many works have been done in Europe as well.The Association of European Distributed Energy Resources Laboratories(DERlab)[18]aims to cluster the best European DER laboratories from each EU member state,including IWES,KEMA,AIT,NTUA,CRES,and so on.Each member laboratory of DERlab is strong in specific DER-related areas,and together they cover the wholefield of distributed generation and smart grids.The DERlab association offers an access point to the testing capabilities.Testing of the qualifications of system components and products can be per-formed according to standards or customer specifications.The Microgrids Consortium[19]comprises major European man-ufacturers,power utilities,and potential microgrid operators and research teams with complementary high-quality expertise. The microgrid systems include the Kythnos microgrid,the Manheim microgrid,CESI,the Bornholm microgrid,the Kozuf microgrid,and so on.European institutes play an important role in promoting microgrid systems.In Asia,a small-scale microgrid pilot plant has been designed at the Korea Elec-trotechnology Research Institute(KERI)[20].However,parts of the distributed power sources in this system are emulators, including the wind turbine(WT)simulator and photovoltaic (PV)simulator.Many microgrid projects have been constructed in Japan,including the Aichi microgrid project[21],Kyotango project,Hachinohe project,CRIEPI[22],and so on.The mi-crogrid testbed constructed at Hefei University of Technology (HFUT)[23]is a small laboratory-scale microgrid including different distributed power sources in China.At present,mi-crogrid laboratory and project systems are increasingly under construction.Microgrid systems which integrate more advan-tages are the development trend of the future.Recently,the Chinese government has paid more and more attention to microgrids that can help fulfill the targets of energy conservation and emission reduction.In this paper,we present the integrated microgrid laboratory system that was formulated at Zhejiang Electric Power Test and Research Institute in2010 as a cluster of multiple DGs and energy storage systems with the ability to operate stably and reliably under different conditions.0885-8950/$31.00©2012IEEEFig.1.Configuration of the integrated microgrid laboratory system.The DGs in the system are of multiple types,including a wind turbine(WT)system,photovoltaic(PV)system and Double-fed Induction Generator(DFIG)system.A battery energy storage system is used in the system and a diesel generator serves as a back-up power source.Moreover,flywheel energy storage has been used in this microgrid system,which is applicable for fast balancing and can provide uninterruptible power-supply ser-vices in cooperation with the diesel generator.The system struc-ture is soflexible that several different topological structures are available in accordance with different research requirements. The objective of the integrated microgrid laboratory system is to carry out experimental and theoretical studies on DGs and microgrids,including:1)studies on the operation control strategy and development of microgrid related equipment;2)studies on the impacts of microgrid on power systems;3)analyses of the economic efficiency and social benefits of microgrids;and4)formulation of guidelines regarding microgrids and implementation of microgrid security access to the utility grid.The project accomplishes this objective by developing and demonstrating advanced technologies in the first stage,including:1)control methods including islanded op-eration control and automatic and seamless transitions between grid-connected and islanded modes;2)dynamic simulation of the distribution network with DGs and microgrids;and3)an approach to microgrid protection considering the features and impacts of DGs.Section II introduces the physical configuration and control structure of the integrated microgrid laboratory system,and Section III describes the proposed control strategy in detail. The results of experiments and discussions are reported in Section IV.The conclusion is given in Section V.II.M ICROGRID L ABORATORY S YSTEMA.Physical System ConfigurationFig.1presents the configuration of the integrated microgrid laboratory system.The microgrid system,which is connected to the external grid through an isolation transformer,is composed of two small microgrids:microgrid A and microgrid B.The rules for naming switches are as follows:The switches in microgrid A are denoted by names beginning with the letter “A,”and the switches in microgrid B by names beginning with “B.”Meanwhile,switches which are connected to equipments have names beginning with“F.”The two switches that can be automatically controlled by the mode controller have names be-ginning with“M,”and the two interconnection switches have names beginning with“L.”Microgrid A includes three busbars:LM3,LM4,and LM5. It is composed of the PV system,WT system,DFIG simulation system,the Battery Energy Storage System(BESS),and two load banks.The30-kW DFIG simulation system is a simulator with an ABB frequency converter and a real generator to emu-late the real system.However,the33-kW PV system and10-kW WT system are real systems.The three-phase output power of the33-kW PV system passes through a three-phase PV inverter, and the BESS near to the point of common coupling(PCC) will be utilized while microgrid A is being transferred.The load banks are composed of RLC(resistance,inductance,capacity) branches that can be changed by remote control device.When microgrid A operates in islanded mode,the battery units provide the reference voltage and frequency.Microgrid A is connected to the external grid through M1.Microgrid B includes three busbars:LM7,LM8,and LM9. There are a PV system,flywheel energy storage,diesel gen-erator,and two load banks.However,differently from micro-grid A,in microgrid B,the three-phase output power of the 30-kW PV system passes through three single-phase inverters. Therefore,the PV system can be tested with different connec-tion forms,and theflywheel energy storage is utilized for fast balancing to supply uninterruptible power to important loads in the short-term during mode transition and other fault events. Then,the diesel generator starts to provide the long-term refer-ence voltage and frequency to microgrid B.The interconnection switch L2between LM8and LM9allows microgrid B to haveZHAO et al.:INTEGRATED MICROGRID LABORATORY SYSTEM2177Fig.2.Hierarchical control structure.different topological structures with certain switch statuses.Mi-crogrid B is connected to the external grid through M2.Details of the components of the system are as follows:1)System configuration:a)renewable sources:PV ,WT,and DFIG;b)energy storage system:BESS and flywheel energystorage;c)controllable source:diesel generator;2)Capacity of microsources:a)PV:63kW;b)WT:10kW;c)DFIG:30kW;d)diesel generator:250kW;3)Capacity of energy storage systems:a)BESS:168kWh;b)Bi-directional inverter of BESS:100kW;c)Flywheel energy storage:250kV A;4)Loads:a)Load 1:30kW 24kVar 24kVar;b)Load 2:60kW 45kVar 45kVar;c)Loads 3and 4:10kW 8kVar 8kVar.Interconnection switch L1is designed between LM5and LM8.When L1is opened,microgrids A and B operate sepa-rately.When L1is closed,microgrids A and B are combined into one large microgrid.In addition,the diesel generator or battery units provide the reference voltage and frequency when the large microgrid operates in islanded mode.Otherwise,each DG can be directly connected to the external grid when there are no tests.For example,when F22is opened with F72closed,the output power of the 33-kW PV system flows into LM1directly.Furthermore,in order to simulate real transmission lines,there are simulated lines with a certain resistance between different busbars.There are also five simulated fault points in the system,which are connected to ground only through a small resistance,to simulate different fault events.Faults 1and 4are designed to simulate the faults outside the microgrid.On the other hand,faults 3and 5are designed to simulate thefaults inside the microgrid,while fault 2is designed to simulate faults in PCC.Through the above five simulated fault points,different fault events can be simulated easily,allowing methods of protection of the microgrid to be studied further in this system.B.Control System StructureThe microgrid system has a hierarchical control structure,as shown in Fig.2.There are four control layers:the main sta-tion,coordinated control,the Feeder Terminal Unit (FTU)and protection device,and microgrid control.The main station layer implements the functions such as graphical display,monitoring,operation,management and application of historical data,re-mote and other communications (embedded),configuration,and modification of control logic.In the coordinated control layer,the controls of the bi-directional inverter and microsources in both grid-connected and islanded modes are managed by the mode controller.Without the mode controller,the microgrid system cannot be transited between grid-connected and islanded modes flexibly and automatically.The FTU and protection de-vice layer is composed of the devices which are responsible for protection and distribution terminal control.The microgrid con-trol layer,as the local controller,receives commands from the control logic and implements different functions.The designed hierarchical control structure contributes to DG control,coordi-nated control,and the whole control process.III.C ONTROL S TRATEGYA.OverviewThe microgrid control system is responsible for the overall control and coordination of operation,including mode transi-tion,frequency control,voltage control,stability control,black start,and so on.In general,microgrid control includes two main parts:a local distributed power control strategy and a system-level control mode.The major power sources of most microgrids are the inverter-type DGs that are based on power electronic inverters which2178IEEE TRANSACTIONS ON POWER SYSTEMS,VOL.27,NO.4,NOVEMBER2012decide the stability of the microgrid.At present,there are three inverter-based DG control strategies:1)constant power control, that is,PQ control;2)constant voltage and frequency control, that is,V/F control;and3)droop control[24]–[26].•PQ control:The purpose of PQ control is to enable the output power of the DGs to equal the reference value.PQ control generally adjusts the decoupled active power and reactive power,respectively.•V/F control:Regardless of the power changes of dis-tributed generation,the purpose of V/F control is to keep the voltage and frequency of the inverter connected bus system unchanged.•Droop control:Droop control simulates the power-fre-quency static characteristics of the generator,which can provide voltage and frequency support.The units adopting droop control can provide voltage and frequency support separately or combined with other support units.Also,there are three main system-level control modes.•Master–slave control:master–slave control refers to the operation mode in which only one DG adopts V/F con-trol to provide the reference voltage and frequency,while the other DGs adopt PQ control.The master control unit is usually stable output energy power.•Peer-to-peer control:peer-to-peer control refers to the op-eration mode in which the controls of all the DGs have the same status.The master–slave relationship does not exist.Each DG system is controlled based on the local voltage and frequency.The strategy of the DG controller is critical for this control mode,while a method that is currently of interest is the droop control mentioned previously.•Hierarchical control:the hierarchical control generally has a central controller to dispatch control information.The central controller is responsible for work including forecasting power generation and load demand,devel-oping appropriate operation plans,collecting voltage, current,power,and other status information,adjusting the real-time operation plan,and controlling the start-stop of DGs,load,and energy storage devices to ensure that the voltage and frequency are stable and also provide related protection.B.Master–Slave ControlMaster–slave control is adopted in the integrated microgrid laboratory system where a master control unit is needed for op-eration.A DG or energy storage system which adopts constant V/F control can serve as the master control unit,providing the reference voltage and frequency to other DGs.Obviously,there is no need to adjust the frequency when the microgrid operates in grid-connected mode as the external grid can stabilize the frequency.Thus,all of the DGs in the micro-grid,adopting PQ control,only output a certain active power and reactive power.Conversely,the master control unit,adopting V/F control,has to stabilize the voltage and frequency when the microgrid operates in islanded mode.The control strategy method is shown in Fig.3.In this system,the bi-directional inverter is the key part in microgrid operation,especially when battery units serve as the master control unit.Fig.4shows the portion of the structure in microgrid A.The microgrid control system is responsiblefor Fig.3.Control method of master controlunit.Fig.4.Part structure of microgrid A.managing the components’control units.As shown in Fig.4,the bi-directional inverter is composed of dc–dc and dc–ac circuits. The bi-directional inverter can operate in either grid-connected mode or islanded mode.When the bi-directional inverter oper-ates in grid-connected mode,the external grid provides the refer-ence voltage and frequency to it,and the bi-directional inverter, adopting PQ control,controls the powerflow in the dc–dc and dc–ac circuits by adjusting the dc bus voltage.When the bi-di-rectional inverter operates in islanded mode,battery units pro-vide the reference voltage and frequency to the system,and the bi-directional inverter,adopting V/F control,controls the output voltage and frequency by adjusting the dc bus voltage. Therefore,two kinds of control strategies are used to operate the bi-directional inverter.The inverter model differs according to the following control strategies.1)PQ Inverter Control:The PQ controlled inverter operates by injecting into the grid the power available at its input.The reactive power injected corresponds to a prespecified value,de-fined locally(using a local control loop)or centrally from the microgrid control center.As shown in Fig.5,when operating in grid-connected mode,the dc–dc module adopts constant cur-rent control and the dc–ac module adopts the control structure in which the dc bus voltage is the outer loop and the ac side cur-rent is the inner loop.The control’s target is to keep the dc bus voltage steady.2)V/F Inverter Control:The V/F controlled inverter emu-lates the behavior of a synchronous machine,thus controlling the voltage and frequency on the ac system.The inverter acts as a voltage source,with the magnitude and frequency of the output voltage being controlled.As shown in Fig.6,when operating inZHAO et al.:INTEGRATED MICROGRID LABORATORY SYSTEM2179Fig.5.Power control structure of grid-connectedmode.Fig.6.V oltage and frequency control structure of islanded mode.islanded mode,the dc–dc module adopts the double loop con-trol to keep the dc bus voltage steady,while the role of the dc–ac module is to control the voltage and frequency,keeping them steady.When the microgrid operates in islanded mode,if the output power of the DGs is smaller than the load,the bi-direc-tional inverter operates in islanded discharge mode at this time.Load that cannot be satisfied by the DGs is supplied by battery units.If the output power of the DGs is bigger than the load,the bi-directional inverter operates in islanded charge mode.Part of the output power of the DGs flows into the battery units.C.Mode Transition Control1)Microgrid A:The mode controller implements mode tran-sition of microgrid A by detecting voltage changes in LM2when microgrid A and microgrid B operate separately.Case 1:External fault occurs—fault 1:Fig.7shows the con-trol flow chart of microgrid A when fault 1occurs.In this case,PV and WT will disconnect from the grid when the voltage in microgrid A droops because of islanding protection,which al-lows harm due to non-synchronization closing to be avoided.The mode controller will open M1when the voltage of LM2falls below the set value and remains so for a certain duration (such as 3s,to avoid the transient effect).Then the bi-direc-tional inverter shifts to islanded discharge mode and serves as the master control unit of microgrid A.The PV and WT will re-connect to the grid when the bi-directional inverter providesaFig.7.Control flow chart of microgrid A.steady voltage and frequency to microgrid A.Finally,microgrid A operates in islanded mode.In islanded mode,the bi-directional inverter first shifts to standby mode when the voltage of LM2(external grid voltage)is normal and remains so for a certain duration (such as 3s).PV and WT disconnect from the grid because of voltage droops.The mode controller will close M1when LM3has no voltage.After M1has closed,the external grid supplies microgrid A again.Then the bi-directional inverter changes to grid-con-nected mode,and PV and WT reconnect to the grid.Microgrid A operates in grid-connected mode again.Case 2:Internal fault occurs—fault 2and fault 3:When fault 2occurs in LM3,the busbar differential protection will open A2,A3,and F12.In this case,electricity failure inevitably oc-curs in microgrid A.The mode controller does not issue a mode transition instruction.In another case,when fault 3occurs in the feeder,the voltage of LM2droops for a moment and the voltages in microgrid A soon droop.PV and WT disconnect from the grid because of islanding protection,and the bi-directional inverter changes to standby mode.The voltage of LM2will be established again after the pilot protection clears the fault.In this case,the mode controller does not issue a mode transition instruction because the voltage of LM2returns to normal 3s after the fault is cleared.Then DGs reconnect to the grid and the bi-directional inverter reverts to grid-connected mode.2)Microgrid B:The mode controller implements mode tran-sition of microgrid B by detecting voltage changes in LM6when microgrid A and microgrid B operate separately.As microgrid B has different topological structures,the situation where mi-crogrid B is operating under the condition where L2is closed and B3is open will be discussed.Case 1:External fault occurs—fault 4:Fig.8shows the con-trol flow chart of microgrid B when fault 4occurs.In this case,the flywheel is applicable as an energy storage device only for2180IEEE TRANSACTIONS ON POWER SYSTEMS,VOL.27,NO.4,NOVEMBER2012Fig.8.Controlflow chart of microgrid B.fast balancing during fault events.The mode controller will open M2when the voltage of LM6falls below the set value and re-mains so for a certain duration(such as3s).At the same time, the diesel generator starts instantly to provide voltage and fre-quency to microgrid B.After the diesel generator starts,the flywheel goes to charge mode again when the voltage of LM7 is normal.The diesel generator supplies microgrid B indepen-dently at this time.Finally,microgrid B operates in islanded mode.In islanded mode,the diesel generatorfirst stops when the voltage of LM6(external grid voltage)is normal and remains so for a certain duration(such as3s).Then the mode controller closes M2.Microgrid B reconnects to the grid and operates in grid-connected mode at this time.Case2:Internal fault occurs—fault5:When fault5occurs in microgrid B,directional pilot relaying will start to clear the fault,which leads to the exit of theflywheel.In this case,it does not make sense to start the diesel generator because there are no loads connected to it.Thus,microgrid B will not operate in islanded mode when fault5occurs.3)One Large Microgrid:In one-large microgrid mode,L1 is closed,and only one switch between M1and M2can be closed at the same time.The mode controller implements mode transition by detecting voltage changes of LM2or LM6.The diesel generator serves as the master control unit and the energy storage system serves as the regulating unit when the microgrid operates in islanded mode as one large microgrid.In this case, regardless of the microgrid operation mode,the bi-directional inverter operates in grid-connected mode all the time.The con-trol strategy is similar to that of microgrids A and B.4)Black Start:In microgrid A,the battery bi-directional in-verter is the startup power source in the black start process.After the battery bi-directional inverter begins operating,other DGs connect to microgrid A and begin to work normally.In micro-grid B,the diesel generator is the startup power source in the black start process.After the diesel generator begins operating, other DGs connect to microgrid B and begin to work normally. For one large microgrid,the battery bi-directional inverter or diesel generator can serve as the startup power source in the black start process.IV.E XPERIMENTAL S TUDYFig.9shows the major components of the integrated mi-crogrid laboratory system which is composed of the PV system,WT system,DFIG simulation system,BESS,flywheel, diesel generator,isolation transformer,bi-directional inverter, electricity meters,loads,primary equipments,and secondary equipment.These components communicate with the manage-ment software,which is installed on a remote PC,by network communication.Fig.10shows the supervisory software devel-oped for management of the microgrid system.It monitors and displays the system’s current states including power output, voltage,current,state of charge of battery storage,state of flywheel and diesel generator,and so on.Relying on this microgrid system,different classes of tests were performed. As is well known,a microgrid is a small autonomous power system that can operate in grid-connected mode or islanded mode,and the transition between the two modes is an impor-tant issue of microgrid control.Since the microgrid laboratory is composed of different DGs and energy storage systems,it is significant to study and implement the transition process in this system.Thus,experiments carried out with regard to this topic are mainly discussed next.A.Microgrid A1)Mode Transition of Microgrid A:In this experimental case,the control performance of mode transition of microgrid A is evaluated.Fig.11shows the dynamics of transition of mi-crogrid A from grid-connected to islanded mode.When the grid side switch opens at T1because of protection or maintenance, the voltage of LM2droops immediately.When this situation lasts for3s,the mode controller opens M1at T2and orders the bi-directional inverter to shift from grid-connected charge to islanded discharge mode.The voltage is established within 2.5s and microgrid A operates in islanded mode at this time. Fig.12shows the dynamics of transition of microgrid A from islanded to grid-connected mode.The voltage of LM2returns to normal at T1.The mode controller orders the bi-directional inverter to switch from islanded discharge to standby mode after ensuring the normal state,and then closes M1at T2when LM3 has no voltage.Microgrid A is supplied by the external grid and the bi-directional inverter shifts to grid-connected charge mode. Microgrid A operates in grid-connected mode again.PV and WT reconnect to the grid later as it takes several seconds for the PV and WT inverters to connect to the grid and work again.At this stage,the battery bi-directional inverter does not have the ability to achieve seamless transition.Thus,the voltage of the battery bi-directional inverter becomes zero during mode transition.After the voltage becomes zero,the DGs disconnect from the microgrid because of islanding protection,which al-lows harm due to non-synchronization closing to be avoided.。
Emulsions乳剂
Section 10EmulsionsBy Drs. Pardeep K. Gupta, Clyde M. Ofner and Roger L. SchnaareTable of Contents Emulsions (1)Table of Contents (1)Introduction and Background (3)Definitions (3)Types of Emulsions (3)Formation of an Emulsion (4)Determination of Emulsion Type (4)Miscibility or Dilution Test (4)Staining or Dye Test (4)Electrical Conductivity Test (4)Physical State of Emulsions (5)Pharmaceutical Application of Emulsions (5)Formulations (6)Typical Ingredients (6)Drug (6)Oil Phase (6)Aqueous Phase (6)Thickening Agents (6)Sweeteners (6)Preservative (6)Buffer (7)Flavor (7)Color (7)Sequestering Agents (7)Humectants (7)Antioxidants (7)Emulsifiers (7)Guidelines (7)Type of Emulsion Desired (7)Toxicity (8)Method of Preparation (8)Typical Formulas (8)Cod Liver Oil Emulsion (polysaccharide emulsifier) (8)Protective Lotion (divalent soap emulsifier) (8)Benzoyl Benzoate Emulsion (emulsifying wax emulsifier) (8)Barrier Cream (soap emulsifier) (9)Cold Cream (soap emulsifier) (9)All Purpose Cream (synthetic surfactant emulsifier) (9)Emulsifiers (10)Natural Products (10)Polysaccharides (10)Sterols (10)Phospholipids (10)Surfactants (10)Anionic Surfactants (11)Soaps (11)Detergents (11)Cationic Surfactants (11)Nonionic Surfactants (11)Finely Divided Solids (12)Methods to Prepare Emulsions (13)Classical Gum Methods (13)Dry Gum Method (13)Wet Gum Method (13)“In Situ” Soap Method (13)Lime Water/Vegetable Oil Emulsions (13)Other Soaps (13)With Synthetic Surfactants (13)Required HLB of the Oil Phase (14)HLB of Surfactant Mixtures (14)Emulsion Stability (15)Sedimentation or Creaming (15)Factors - Stoke’s Law (15)Droplet Size (15)Density Difference (15)The Gravitational Constant, g (15)Viscosity (15)Breaking or Cracking (16)Thermodynamics of Emulsions (17)Microemulsions (18)References (19)Selected Readings (19)Introduction and BackgroundDefinitionsEmulsions are pharmaceutical preparations consisting of at least two immiscible liquids.Due to the lack of mutual solubility, one liquid is dispersed as tiny droplets in the other liquid to form an emulsion. Therefore,emulsions belong to the group of prepara-tions known as disperse systems.The USP also defines several dosage forms that are essentially emulsions but historically are referred to by other names. For example;Lotions are fluid emulsions orsuspensions intended for external application.Creams are viscous liquid or semi-solid emulsions of either an oil-in-water (O/W) or the water-in-oil (W/O) type. They are ordinarily used topically. The term cream is applied most frequently to soft, cosmetically acceptable types of preparations.Microemulsions are emulsions withextremely small droplet sizes and usually require a high concentration of surfactant for stability. They can also be regarded as isotropic, swollen micellar systems.Multiple emulsions are emulsions that have been emulsified a second time,consequently containing three phases. They may be water-in-oil-in-water (W/O/W) or oil-in-water-in-oil (O/W/O).Fluid emulsions are generally composed of discrete, observable liquid droplets in a fluid media, while semi-solid emulsions generally have a complex, more disorganized structure.The liquid which is dispersed as droplets iscalled as the dispersed , discontinuous or internal phase, and the liquid in which thedispersion is suspended is the dispersion medium or the continuous or external phase.For example, if olive oil is shaken with water,it breaks up into small globules andbecomes dispersed in water. In this case the oil is the internal phase, and water is the external phase.The dispersed particles or globules can range in size from less than 1 µm up to 100 µm. An emulsion is rarely a monodis-perse system, e.g., all the particles are rarely of the same size. A typical emulsion contains a distribution of many sizes, making it a polydisperse system.Types of EmulsionsBased on the nature of the internal (or exter-nal) phase, emulsions are of two types; oil-in-water (O/W) and water-in-oil (W/O). In an O/W type the oil phase is dispersed in the aqueous phase, while the opposite is true in W/O emulsions. Figure 1 depicts these two types of emulsions.Figure 1: Representation of Two Types of EmulsionsO/W Emulsion W/O Emulsion (water black)(oil white)When two immiscible phases are shaken together, either type of emulsion can result.However, this result is not random, but is dependent primarily on two factors; most importantly the type of emulsifier used and secondly the relative ratio of the aqueous and oil phases (phase volume ratio). The emulsifiers and their role in the type of emulsion are discussed in detail later in this chapter.In terms of the phase volume ratio, the percent of the internal phase is generally less than 50%, although emulsions can have internal phase volume percent as high as 75%. Uniform spheres, when packed in a rhombohedral geometry occupy approxi-mately 75% of the total volume. Phase volumes higher than 75% require that the droplets of dispersed phase be distorted into geometric shapes other than perfect spheres. Although it is rare to find emulsions with higher than 75% internal volume, phase volumes of over 90% have been reportedin literature.Formation of an EmulsionWhen two immiscible liquids are placedin contact with each other, they form two separate layers. The liquid with higher density forms the lower layer and the one with lower density forms the upper layer. When this two-layer system is shaken vigorously, one of the layers disperses in the other liquid forming an unstable emul-sion. If left unstirred, the dispersed phase comes together and coalesces into larger drops until the layers become separate again. If no other ingredient is added, this process of separation is usually completein a matter of a few minutes to a few hours. Therefore, a liquid dispersion is inherently an unstable system.However, when an emulsifier is present in the system, it reduces the interfacial tension between the two liquids and forms a physical barrier between droplets, hence lowers the total energy of the system(see discussion on Thermodynamics of Emulsions), thereby reducing the tendency of the droplets to come together and coalesce. Consequently, the globules ofthe internal phase may remain intact for long periods of time, forming a “stable”emulsion. It should be noted, however,that even with an emulsifier, an emulsionis a thermodynamically unstable system and will eventually revert to bulk phases. The time required for this process is determined by kinetics.Determination of Emulsion TypeSeveral tests can be used to determine whether a given emulsion is an O/W or W/O type. These are as follows:Miscibility or Dilution TestThis method is based on the fact that an emulsion can be diluted freely with a liquid of the same kind as its external phase. Typically, a small amount of the emulsion is added to a relatively large volume of water and the mixture is stirred. If the emulsion disperses in water, it is considered to bean O/W type emulsion. If, however, the emulsion remains undispersed, it is a W/O type emulsion.Staining or Dye TestThis test is based on the fact that if a dye is added to an emulsion and the dye is soluble only in the internal phase, the emulsion contains colored droplets dispersed inthe colorless external phase. This can be confirmed by observing a drop of emulsion under a low power microscope. An example of such a dye is scarlet red, which is an oil soluble dye. When added to an O/W type emulsion, followed by observation under the microscope, bright red colored oil drops in an aqueous phase can be seen clearly. Electrical Conductivity TestThis test is based on the fact that onlythe aqueous phase can conduct electrical current. Thus, when a voltage is applied across a liquid, a significant amount of electrical current will flow only when the path of the current is through a continuous aqueous phase. Since oil is a non-conductor of electricity, when tested for conductivity, a W/O type emulsion will show insignificant current flow.Often times a single test may not be conclu-sive. In such circumstances, more than one test may need to be carried out to confirm the emulsion type.Physical State of EmulsionsMost emulsions are either liquid or semi-solid at room temperature. In general, due to their high viscosity, the semi-solid emulsions are relatively more physically stable. Liquid emulsions are more commonly compounded for internal use, while semisolids are usually for external use or for use in body cavities (rectal or vaginal).Other terms commonly used to describe emulsions are lotion and cream . The term lotion refers to a disperse system that flows freely under the force of gravity. A cream is a product that does not flow freely under the force of gravity. It should be noted, however,that these terms are meaningful only when the product is at room temperature. A cream product may behave like a lotion with a temperature increase of a few degrees. The physical state of the final product is also influenced by its intended use. For example suntan lotions are dispensed as lotions instead of creams because they need to be applied on large body surface. Lotion form makes it easy to pour and spread the product. For application over a small portion of skin, a cream is the preferred form of an emulsion.Pharmaceutical Applications of Emulsions There are several reasons for formulation of a product as an emulsion. These include the following:•To disguise the taste or smell of oils or oil soluble drugs. These emulsions are normally O/W types with the aqueous phase containing sweeteners and flavoring agents to mask the poor taste of oils. An O/W type of emulsionalso makes it easy to rinse off the residual dose from the mouth and does not leave an oily taste. Mineral oil and cod liver oil are emulsified for this reason.•To improve the absorption of poorly soluble drugs. Oil soluble drugs may not be soluble enough to be absorbed efficiently. An example of such a drug is cyclosporin, which is dispensed as a microemulsion. •To deliver nutrients and vitamins by intravenous injection. Intralipid is an emulsion product for administering an oil by the IV route.•To serve as a vehicle for the topical administration of a variety of drugs.Kb is the binding constant of the preservative with the surfactantSweeteners are added to emulsions to produce a more palatable preparation, toand sorbitol.AntioxidantsAntioxidants are often added to prevent oxidation of vegetable oils and/or the active drug.Table 1. Typical AntioxidantsEmulsifiersEmulsifiers are substances that have the ability to concentrate at the surface of a liquid or interface of two liquids, many of them reducing the surface or interfacial tension. Those emulsifiers that reduce surface tension are also called surfactants .Emulsifiers in general are discussed inmore detail in a later section of this chapter.GuidelinesBefore selecting a formula for an emulsion,one needs to consider several factors.These are listed below.Type of Emulsion DesiredSince O/W emulsions are more pleasant to touch and swallow, they are generally preferred. Preparations for internal use are almost always O/W type products.Externally used emulsions may be of either type. Creams and lotions that are used primarily to provide oil to the skin need to be W/O due to high concentration of oils in these preparations.The equation shows that the effective concentration in the aqueous phase will always be a fraction of the total concentration.Solvents such as alcohol, glycerin and propylene glycol are often used as apreservative at concentrations approaching 10%. See Table 5, Typical Preservatives in Section 9 of this manual.BufferMany chemical buffer systems have been used in emulsions to control the pH. The optimal pH is chosen to ensure activity of the emulsifier, control stability of the drug and to ensure compatibility and stability of other ingredients.FlavorFlavoring agents enhance patient accept-ance of the product, which is particularly important for pediatric patients.ColorColorants are intended to provide a more aesthetic appearance to the final product.Emulsions are generally not colored with the exception of some topical products. Sequestering AgentsSequestering agents may be necessary to bind metal ions in order to control oxidative degradation of either the drug or other ingredients. HumectantsHumectants are water soluble polyols that prevent or hinder the loss of water from semi-solid emulsions, i.e., topical creams.They also contribute to the solvent proper-ties of the aqueous phase and contribute to the sweetness of oral preparations. The most common are glycerin, propylene glycolToxicityMost emulsifiers are not suitable for internal use. For orally given emulsions, acacia is commonly used as an emulsifying agent.Taste is another factor in selection ofingredients. In this regard, most polysaccha-rides are tasteless and, hence, suitable from a taste standpoint.Method of PreparationSoaps and acacia are excellent forextemporaneous preparations. While soaps allow the preparation to be made by simply mixing the ingredients and shaking, acacia can be used in a pestle and mortar to prepare emulsions.Typical FormulasCod Liver Oil Emulsion (polysaccharide emulsifier)Preparationing a ratio of 4:2:1 for oil, water and gums(both combined), prepare a primary emulsion by dry gum method. (See Methods to Prepare Emulsions on page 13.)2.Dilute with water to a flowable consistency andpour in a measuring device.3.Add alcohol diluted with equal volume of water,followed by the benzaldehyde and saccharin sodium.4.Dilute to volume (200 mL) with waterPreparation1.Add benzyl benzoate to the wax in a beakerand heat in a water bath until the wax melts and the temperature reaches 60°C.2.In a separate beaker, add an appropriate volumeof water and heat to the same temperature.3.Add the water to the oil phase with continuousstirring.4.Continue to stir until the mixture begins tothicken and cools to room temperature.Preparation1.Mix the two powders in a mortar and trituratewell, taking care that all the lumps and large particles have been reduced.2.Then add oil slowly with constant trituration untilall the oil has been added. Triturate to form a smooth paste.3.Then add the limewater and triturate briskly toform the emulsion.Note: The emulsifier, calcium oleate (from limewater and olive oil), preferentially forms O/W emulsions.Protective Lotion (divalent soap emulsifier)Benzyl Benzoate Emulsion (emulsifying wax emulsifier)Preparation1.Mix the paraffins, cetostearyl alcohol andstearic acid in a beaker and heat in a water bath to about 60°C.2.Heat water and chlorocresol together to thesame temperature.3.Add the aqueous phase to the oil phase andstir until congealed and cooled to room temperature.Note:The emulsifier is triethanolamine stearate formed in situ.Preparation1.Melt the sorbitan monostearate and stearicacid in the liquid paraffin and cool to 60°C. 2.Mix the sorbitol solution, preservatives,polysorbate 60 and water and heat to the temperature of the oil mixture.3.Add the aqueous solution to the oil phase andstir until it has congealed and cooled to room temperature.Note:Propylene glycol serves as a solvent for the preservatives.Preparation1.Mix and melt the wax and paraffin together.2.Dissolve borax in water and heat both containerson a water bath to 70°C.3.Add the aqueous phase to the oil phase andstir until it has congealed and cooled to room temperature.Note:The fatty acid in white beeswax reacts with borax (sodium borate) to make a sodium soap which acts as an W/O type emulsifier.Barrier Cream (soap emulsifier)All Purpose Cream (synthetic surfactant emulsifier)Cold Cream (soap emulsifier)Surfactants or surface active agents are molecules that consist of two distinct parts,a hydrophobic tail and a hydrophilic head group. They are generally classified based on the hydrophilic properties of the head group (ionic charge, polarity, etc.). Since the hydrophobic chains do not vary much in their properties, the nature of surfactants is dependent mainly on the head group structure.A common problem with sterol-containing emulsifiers is that being complex mixtures of natural substances, they are prone to variability in their quality and, hence, performance. Also, these agents usually contain some degree of an odor, which varies with the purity and source. Some semi-synthetic substitutes are available that seek to overcome some of the problems associated with these agents.There are of basically three types of emulsifiers: natural products, surface active agents (surfactants), and finely divided solids. Based on whether a stable emulsion can be produced, emulsifiers are also classified either as primary emulsifying agents which produce stable emulsions by themselves, or secondary emulsifying agents (stabilizers) which help primary emulsifiers to form a more stable emulsion.of cholesterol. Cholesterol itself is a very efficient emulsifier and produces W/O type emulsions. Consequently, its use is limited to topical preparations such as Hydrophilic Petrolatum USP which readily absorbs water forming a W/O cream. Woolfat or lanolin contains a considerable amount of choles-terol esters and can absorb up to 50% of its own weight of water.This group of emulsifiers, which numbers in the hundreds, contain a polyoxyethylene chain as the polar head group. They arenonionic and, thus, are compatible with ionic compounds and are less susceptible to pH changes. There are several such surfactants official in the USP/NF , typified by sorbitan monooleate (a partial ester of lauric acid with sorbitol), polysorbate 80(polyoxyethyl-ene 20 sorbitan monooleate) which contains 20 oxyethylene units copolymerized sorbitanAmine soaps consist of an amine, such as triethanolamine, in the presence of a fatty acid. These surfactants are viscous solutions and produce O/W type emulsions. They offer the advantage that the final pH of the preparations is generally close to neutral,and, therefore, allows their use on skin for extended periods of time.monooleate) and polyoxyl 40 stearate(a mixture of stearic acid esters with mixed poloxyethylene diols equivalent to about40 oxyethylene units).The large number of nonionic emulsifiers results from the large number of possible combinations of various alkyl groups with polyoxyethylene chains of varying lengths. Compounds with saturated and/or large alkyl groups, such as stearyl, tend to be solids or semisolids while oleyl (also large, but unsaturated) compounds tend to be liquids. Also, the longer the polyoxyethylene chain, the higher the melting point.To characterize such a large number of compounds, they are each assigned an HLB number. The HLB number or hydrophile-lipophile balance, is a measure of the relative hydrophilic vs lipophilic character of the molecule as determined by the relative size of the polyoxyethylene chain vs the alkyl group. HLB numbers range from 0 for a pure hydrocarbon to 20 for a pure poly-oxyethylene chain. Some typical valuesare listed in Table 3.Ionic surfactants, such as sodium lauryl sulfate, were not included in the original definition of the HLB system but have been included as the HLB system was developed. The HLB number of 40 for sodium lauryl sulfate is outside of the range of 0 to 20 and simply means that sodium lauryl sulfate is much more soluble or hydrophilic thana pure polyoxyethylene chain.Table 3. Typical HLB Numbersof EmulsifiersFinely Divided SolidsFinely divided solids function as emulsifiers because of their small particle size. Fine particles tend to concentrate at a liquid-liquid interface, depending on their wetability, and form a particulate film around the dispersed droplets. They are seldom used as the primary emulsifier.phase. The emulsion type will depend on the type of soap formed.Basically the formula is divided into anoil phase and an aqueous phase with the ingredients dissolved in their proper phases (oil or water). The surfactant(s) is added to the phase in which it is most soluble. The oil phase is then added to the aqueous phase with mixing, and the coarse mixture passed through an homogenizer.When waxes or waxy solids are included in the formulation, the use of heat is necessary,as described above.Required HLB of the Oil Phase.It has been found that various oils and lipid materials form stable emulsions withsurfactants that have a certain HLB value.This HLB value is called the required HLB of the oil or lipid. Theoretically, any surfac-tant with the required HLB would produce a stable emulsion with the indicated oil or lipid. Some examples are given in Table 4.Table 4. Required HLB Values for Typical Oils and LipidsHLB of Surfactant MixturesIt may be difficult to find a surfactant with the exact HLB number required for a given oil phase in an emulsion. Fortunately, the HLB numbers have been shown to be additive for a mixture of surfactants. Thus, if one required a surfactant with a HLB of 10, one could use a mixture of sorbitan monooleate (HLB = 4.7) and polysorbate 80 (HLB = 15.6). Such a mixture can be calculated on the basis of a simple weighted average as follows.Suppose 5 g of surfactant mixture is required. Let = the g of sorbitanmonooleate, then 5 = the g of polysorbate 80 required.(4.7)+(5- )(15.6) = 10(5)4.7 + 78.0- 15.6= 10(5)10.9= 28= 2.57 and 5- = 2.43Thus a mixture of 2.57 g of sorbitanmonooleate and 2.43 g of polysorbate 80would have a HLB of 10.Griffin 2described an experimental approach for the formulation of emulsions using synthetic emulsifiers.1.Group the ingredients on the basis of theirsolubilities in the aqueous and oil phases.2.Determine the type of emulsion required andcalculate an approximate required HLB value.3.Blend a low HLB emulsifier and a high HLBemulsifier to the required HLB.4.Dissolve the oil soluble ingredients and the lowHLB emulsifier in the oil phase. Heat, if necessary,to approximately 5 to 10°over the melting point of the highest melting ingredient or to a maximum temperature of 70 to 80°C.5.Dissolve the water soluble ingredients (exceptacids and salts) in a sufficient quantity of water.6.Heat the aqueous phase to a temperature whichis 3 to 5°higher than that of the oil phase.7.Add the aqueous phase to the oil phase withsuitable agitation.8.If acids or salts are employed, dissolve them inwater and add the solution to the cold emulsion.9.Examine the emulsion and make adjustments inthe formulation if the product is unstable. It may be necessary to add more emulsifier, change to an emulsifier with a slightly higher or lower HLB value or to use an emulsifier with different chemical characteristics.In addition to chemical degradation of various components of an emulsion, which can happen in any liquid preparation, emulsions are subject to a variety of physical instabilities. Sedimentation or Creaming Factors - Stoke’s LawCreaming usually occurs in a liquid emulsion since the particle size is generally greater than that of a colloidal dispersion. The rate is described by Stoke’s Law for a single particle settling in an infinite container under the force of gravity as follows:d =d 2(2- 1)gdt 18where:d /d t= the sedimentation rate in distance/time d = droplet diameter 2= droplet density1= emulsion medium density g = acceleration due to gravity = viscosity of the emulsion mediumSince for most oil phases, 2< 1, then sedimentation will be negative, i.e., the oil droplets will rise forming a creamy whitelayer. While Stoke’s Law does not describe creaming quantitatively in an emulsion, it does provide a clear collection of factors and their qualitative influence on creaming.Droplet SizeReducing droplet size can have a significant effect on creaming rate. Since the diameter is squared in Stoke’s Law, a reduction in size by ¹⁄₂will reduce the creaming rate by (¹⁄₂)2or a factor of 4.Emulsion StabilityDensity DifferenceIf the difference in density between the emulsion droplet and the external phase can be matched, the creaming rate could be reduced to zero. This is almost impossi-ble with most oils and waxy solids used in emulsions.The Gravitational Constant, gThis parameter is not of much interest since it can not be controlled or changed unless in space flight.ViscosityViscosity turns out to be the most readily controllable parameter in affecting the creaming rate. While the viscosity in Stoke’s Law refers to the viscosity of the fluid through which a droplet rises, in reality the viscosity that controls creaming is the viscosity of the entire emulsion. Thus, doubling the viscosity of an emulsion will decrease the creaming rate by a factor of 2.There are three major ways to increase the viscosity of an emulsion:•Increase the concentration of the internal phase•Increase the viscosity of the internal phase by adding waxes and waxy solids to the oil phase.•Increase the viscosity of the external phase by adding a viscosity building agent. Most of the suspending agents described in the Suspensions Section in this manual have been used for this purpose.Creaming does not usually occur in a semi-solid emulsion.Breaking or CrackingThis problem arises when the dispersed globules come together and coalesce to form larger globules. As this process continues, the size of the globules increases, making it easier for them to coalesce. This eventually leads to separation of the oil and water phases. For cracking to occur, the barrier that normally holds globules apart has to break down. Some of the factorsthat contribute to cracking are as follows:•Insufficient or wrong kind of emulsifier in the system.•Addition of ingredients that inactivate the emulsifier. Incompatible ingredients may show their effect over a period of time.An example of such an incompatibilitywill be to use large anions in thepresence of cationic emulsifier.•Presence of hardness in water. The calcium and magnesium present in hard water can replace a part of the alkalisoap with divalent soap. Since thesesoaps form different kinds of emulsions, phase inversion usually takes place.•Low viscosity of the emulsion •Exposure to high temperatures can also accelerate the process of coalescence.This is due to the fact that at an elevated temperature, the collisions between theglobules can overcome the barrier tocoalescence, thereby increasing thechance that a contact between twoparticles will lead to their fusion.Temperature may have an adverse effect on the activity of emulsifiers, particularly if these are proteinaceous in nature.However, this usually happens at temper-atures higher than 50°C. Conversely, areduction in temperature to the point that the aqueous phase freezes also will break the emulsion.•An excessive amount of the internal phase makes an emulsion inherently less stable because there is a greater chance of globules coming together.Cracking is the most serious kind of physical instability of an emulsion. Cracking of an emulsion usually renders it useless. In creams, the problem of cracking may show up as tearing. This is a process where one phase separates and appears like drops on top of the cream.The basic difference between creamingand cracking is that the globules in creaming do not coalesce to form larger particles. Therefore, creaming is a less serious problem and most preparations that show creaming can be shaken to redisperse the internal phase to its original state. A com-mon example of creaming is the formation of cream on top of whole milk due to collection of emulsified fat of the milk. This problem is solved by homogenizing the milk to reduce the particle size of dispersed fat, thereby reducing the rate at which they travel tothe surface.。
Design and Development of Hybrid Supercapacitors
Design and Development of HybridSupercapacitorsIn recent years, there has been a growing interest in the development of hybrid supercapacitors, which combine the high energy density of batteries and the high power density of capacitors. These devices have the potential to revolutionize energy storage and power delivery systems, with applications ranging from consumer electronics to electric vehicles and grid-scale storage systems.Design Considerations:The design of a hybrid supercapacitor involves several key considerations, including the choice of electrode materials, the construction of the device, and the optimization of its performance. The materials used for the electrodes can significantly impact the performance of the device, with a focus on maximizing both energy density and power density.Graphene, carbon nanotubes, and metal oxides are among the most promising materials for use in hybrid supercapacitors. These materials have high surface areas, allowing for increased charge storage capacity, and can also exhibit excellent electrochemical stability and cycling efficiency.In addition to electrode materials, the configuration of the device is also critical. The most commonly used configurations include asymmetric and symmetric designs. Asymmetric designs, which consist of two electrodes with different charge storage mechanisms, can offer higher energy density. Symmetric designs, where both electrodes have similar charge storage mechanisms, offer higher power density.Performance Optimization:Once the materials and configuration are selected, the performance of the device can be optimized through various techniques. For example, the use of electrode coatings andadditives can improve the electrochemical stability and charge storage capacity of the device.In addition, the electrolyte used in the device can also affect performance. Traditional electrolytes, such as aqueous and organic solvents, suffer from various limitations such as low voltage windows, limited operating temperatures, and poor stability. However, the development of ionic liquids and solid-state electrolytes has opened up new possibilities for high-performance hybrid supercapacitors.Application:Hybrid supercapacitors have enormous potential for a wide range of applications, from portable electronics to electric vehicles and renewable energy systems. These devices can provide high power density for quick charging and discharging, and also offer high energy density for extended use.For example, in portable electronics, hybrid supercapacitors could replace conventional batteries, providing longer operating times in smaller devices. In electric vehicles, hybrid supercapacitors could provide instant, high power delivery for acceleration and braking, while also extending the range of the vehicle.Conclusion:Hybrid supercapacitors are a promising technology that could transform energy storage and power delivery systems. Their unique combination of high energy density and high power density offers many opportunities for advances in portable electronics, electric vehicles, and renewable energy systems. While there are still many challenges to overcome in their development and commercialization, the potential benefits make them a technology worth pursuing.。
化学专业英语-马永祥-兰州大学
ContentsTHE ELEMENTS AND THE PERIODIC TABLE01. ......................................................- 3 -THE NONMETAL ELEMENTS02. ..................................................................................- 5 -GROUPS IB AND IIB ELEMENTS03. ............................................................................- 7 -GROUPS IIIB—VIIIB ELEMENTS04. ............................................................................- 9 -INTERHALOGEN AND NOBLE GAS COMPOUNDS05. ...........................................- 11 -06. ....................................- 13 -THE CLASSIFICATION OF INORGANIC COMPOUNDSTHE NOMENCLATURE OF INORGANIC COMPOUNDS07. ....................................- 15 -BRONSTED'S AND LEWIS' ACID-BASE CONCEPTS08. ..........................................- 19 -09. ..........................................................................- 22 -THE COORDINATION COMPLEXALKANES10. ..................................................................................................................- 25 -11. .............................................................................- 28 -UNSATURATED COMPOUNDSTHE NOMENCLATURE OF CYCLIC HYDROCARBONS12. ...................................- 30 -SUBSTITUTIVE NOMENCLATURE13. .......................................................................- 33 -14. .......................................................- 37 -THE COMPOUNDS CONTAINING OXYGENPREPARATION OF A CARBOXYLiC ACID BY THE GRIGNARD METHOD15. ..- 39 -THE STRUCTURES OF COVALENT COMPOUNDS16. ............................................- 41 -OXIDATION AND REDUCTION IN ORGANIC CHEMISTRY17. ............................- 44 -SYNTHESIS OF ALCOHOLS AND DESIGN OF ORGANIC SYNTHESIS18. ..........- 47 -ORGANOMETALLICS—METAL π COMPLEXES19. ................................................- 49 -THE ROLE OF PROTECTIVE GROUPS IN ORGANIC SYNTHESIS20. ...................- 52 -ELECTROPHILIC REACTIONS OF AROMATIC COMPOUNDS21. ........................- 54 -POLYMERS22. ................................................................................................................- 57 -ANALYTICAL CHEMISTRY AND PROBLEMS IN SOCIETY23. ............................- 61 -VOLUMETRIC ANALYSIS24. ......................................................................................- 63 -QUALITATIVE ORGANIC ANALYSIS25. ..................................................................- 65 -VAPOR-PHASE CHROMATOGRAPHY26. .................................................................- 67 -INFRARED SPECTROSCOPY27. ..................................................................................- 70 -NUCLEAR MAGNETIC RESONANCE (I)28. ..............................................................- 72 -NUCLEAR MAGNETIC RESONANCE(II)29. ..............................................................- 75 -A MAP OF PHYSICAL CHEMISTRY30. ......................................................................- 77 -THE CHEMICAL THERMODYNAMICS31. ................................................................- 79 -CHEMICAL EQUILIBRIUM AND KINETICS32. ........................................................- 82 -THE RATES OF CHEMICAL REACTIONS33. ............................................................- 85 -NATURE OF THE COLLOIDAL STATE34. .................................................................- 88 -ELECTROCHEMICAL CELLS35. .................................................................................- 90 -BOILING POINTS AND DISTILLATION36. ...............................................................- 93 -EXTRACTIVE AND AZEOTROPIC DISTILLATION37. ............................................- 96 -CRYSTALLIZATION38. ................................................................................................- 98 -39. ...................................................................................- 100 -MATERIAL ACCOUNTINGTHE LITERATURE MATRIX OF CHEMISTRY40. ...................................................- 102 -01. THE ELEMENTS AND THE PERIODIC TABLEThe number of protons in the nucleus of an atom is referred to as the atomic number, or proton number, Z. The number of electrons in an electrically neutral atom is also equal to the atomic number, Z. The total mass of an atom is determined very nearly by the total number of protons and neutrons in its nucleus. This total is called the mass number, A. The number of neutrons in an atom, the neutron number, is given by the quantity A-Z.The term element refers to, a pure substance with atoms all of a single kind. To the chemist the "kind" of atom is specified by its atomic number, since this is the property that determines its chemical behavior. At present all the atoms from Z = 1 to Z = 107 are known; there are 107 chemical elements. Each chemical element has been given a name and a distinctive symbol. For most elements the symbol is simply the abbreviated form of the English name consisting of one or two letters, for example:oxygen==O nitrogen ==N neon==Ne magnesium ==MgSome elements,which have been known for a long time,have symbols based on their Latin names, for example: iron==Fe(ferrum) copper==Cu(cuprum) lead==Pb(plumbum)A complete listing of the elements may be found in Table 1.Beginning in the late seventeenth century with the work of Robert Boyle, who proposed the presently accepted concept of an element, numerous investigations produced a considerable knowledge of the properties of elements and their compounds1. In 1869, D.Mendeleev and L. Meyer, working independently, proposed the periodic law. In modern form, the law states that the properties of the elements are periodic functions of their atomic numbers. In other words, when the elements are listed in order of increasing atomic number, elements having closely similar properties will fall at definite intervals along the list. Thus it is possible to arrange the list of elements in tabular form with elements having similar properties placed in vertical columns2. Such an arrangement is called a periodic Each horizontal row of elements constitutes a period. It should be noted that the lengths of the periods vary. There is a very short period containing only 2 elements, followed by two short periods of 8 elements each, and then two long periods of 18 elements each. The next period includes 32 elements, and the last period is apparently incomplete. With this arrangement, elements in the same vertical column have similar characteristics. These columns constitute the chemical families or groups. The groups headed by the members of the two 8-element periods are designated as main group elements, and the members of the other groups are called transition or inner transition elements.In the periodic table, a heavy stepped line divides the elements into metals and nonmetals. Elements to the left of this line (with the exception of hydrogen) are metals, while those to the right are nonmetals. This division is for convenience only; elements bordering the line—the metalloids-have properties characteristic of - both metals and nonmetals. It may be seen that most of the elements, including all the transition and inner transition elements, are metals.Except for hydrogen, a gas, the elements of group IA make up the alkali metal family. They are very reactive metals, and they are never found in the elemental state in nature. However, their compounds are widespread. All the members of the alkali metal family, form ions having a charge of 1+ only. In contrast, the elements of group IB —copper, silver, and gold—are comparatively inert. They are similar to the alkali metals in that they exist as 1+ ions in many of their compounds. However, as is characteristic of most transition elements, they form ions having other charges as well.The elements of group IIA are known as the alkaline earth metals. Their characteristic ionic charge is 2+. These metals, particularly the last two members of the group, are almost as reactive as the alkali metals. The group IIB elements—zinc, cadmium, and mercury are less reactive than are those of group II A5, but are more reactive than the neighboring elements of group IB. The characteristic charge on their ions is also 2+.With the exception of boron, group IIIA elements are also fairly reactive metals. Aluminum appears to be inert toward reaction with air, but this behavior stems from the fact that the metal forms a thin, invisible film of aluminum oxide on the surface, which protects the bulk of the metal from further oxidation. The metals of group IIIA form ions of 3+ charge. Group IIIB consists of the metals scandium, yttrium, lanthanum, and actinium.Group IVA consists of a nonmetal, carbon, two metalloids, silicon and germanium, and two metals, tin and lead. Each of these elements forms some compounds with formulas which indicate that four other atoms are present per group IVA atom, as, for example, carbon tetrachloride, GCl4. The group IVB metals —titanium, zirconium, and hafnium —also forms compounds in which each group IVB atom is combined with four other atoms; these compounds are nonelectrolytes when pure.The elements of group V A include three nonmetals — nitrogen, phosphorus, and arsenic—and two metals — antimony and bismuth. Although compounds with the formulas N2O5, PCl5, and AsCl5 exist, none of them is ionic. These elements do form compounds-nitrides, phosphides, and arsenides — in which ions having charges of minus three occur. The elements of group VB are all metals. These elements form such a variety of different compounds that their characteristics are not easily generalized.With the exception of polonium, the elements of group VIA are typical nonmetals. They are sometimes known, as the, chalcogens, from the Greek word meaning "ash formers". In their binary compounds with metals they exist as ions having a charge of 2-. The elements of group ⅦA are all nonmetals and are known as the halogens. from the Greek term meaning "salt formers.” They are the most reactive nonmetals and are capable of reacting with practically all the metals and with most nonmetals, including each other.The elements of groups ⅥB, ⅦB, and VIIIB are all metals. They form such a wide Variety of compounds that it is not practical at this point to present any examples as being typical of the behavior of the respective groups.The periodicity of chemical behavior is illustrated by the fact that. excluding the first period, each period begins with a very reactive metal. Successive element along the period show decreasing metallic character, eventually becoming nonmetals, and finally, in group ⅦA, a very reactive nonmetal is found. Each period ends with a member of the noble gas family.02. THE NONMETAL ELEMENTSWe noted earlier. that -nonmetals exhibit properties that are greatly different from those of the metals. As a rule, the nonmetals are poor conductors of electricity (graphitic carbon is an exception) and heat; they are brittle, are often intensely colored, and show an unusually wide range of melting and boiling points. Their molecular structures, usually involving ordinary covalent bonds, vary from the simple diatomic molecules of H2, Cl2, I2, and N2 to the giant molecules of diamond, silicon and boron.The nonmetals that are gases at room temperature are the low-molecular weight diatomic molecules and the noble gases that exert very small intermolecular forces. As the molecular weight increases, we encounter a liquid (Br2) and a solid (I2) whose vapor pressures also indicate small intermolecular forces. Certain properties of a few nonmetals are listed in Table 2.Table 2- Molecular Weights and Melting Points of Certain NonmetalsDiatomic Molecules MolecularWeightMelting Point°CColorH22-239.1'NoneN228-210NoneF238-223Pale yellowO232-218Pale blueCl271-102Yellow — greenBr2160-7.3Red — brownI2254113Gray—blackSimple diatomic molecules are not formed by the heavier members of Groups V and VI at ordinary conditions. This is in direct contrast to the first members of these groups, N2 and O2. The difference arises because of the lower stability of πbonds formed from p orbitals of the third and higher main energy levels as opposed to the second main energy level2. The larger atomic radii and more dense electron clouds of elements of the third period and higher do not allow good parallel overlap of p orbitals necessary for a strong πbond. This is a general phenomenon — strong π bonds are formed only between elements of the second period. Thus, elemental nitrogen and oxygen form stable molecules with both σand π bonds, but other members of their groups form more stable structures based on σbonds only at ordinary conditions. Note3 that Group VII elements form diatomic molecules, but πbonds are not required for saturation of valence.Sulfur exhibits allotropic forms. Solid sulfur exists in two crystalline forms and in an amorphous form. Rhombic sulfur is obtained by crystallization from a suitable solution, such as CS2, and it melts at 112°C. Monoclinic sulfur is formed by cooling melted sulfur and it melts at 119°C. Both forms of crystalline sulfur melt into S-gamma, which is composed of S8 molecules. The S8 molecules are puckered rings and survive heating to about 160°C. Above 160°C, the S8 rings break open, and some of these fragments combine with each other to form a highly viscous mixture of irregularly shaped coils. At a range of higher temperatures the liquid sulfur becomes so viscous that it will not pourfrom its container. The color also changes from straw yellow at sulfur's melting point to a deep reddish-brown as it becomes more viscous.As4 the boiling point of 444 °C is approached, the large-coiled molecules of sulfur are partially degraded and the liquid sulfur decreases in viscosity. If the hot liquid sulfur is quenched by pouring it into cold water, the amorphous form of sulfur is produced. The structure of amorphous sulfur consists of large-coiled helices with eight sulfur atoms to each turn of the helix; the overall nature of amorphous sulfur is described as3 rubbery because it stretches much like ordinary rubber. In a few hours the amorphous sulfur reverts to small rhombic crystals and its rubbery property disappears.Sulfur, an important raw material in industrial chemistry, occurs as the free element, as SO2 in volcanic regions, asH2S in mineral waters, and in a variety of sulfide ores such as iron pyrite FeS2, zinc blende ZnS, galena PbS and such, and in common formations of gypsum CaSO4 • 2H2O, anhydrite CaSO4, and barytes BaSO4 • 2H2O. Sulfur, in one form or another, is used in large quantities for making sulfuric acid, fertilizers, insecticides, and paper.Sulfur in the form of SO2 obtained in the roasting of sulfide ores is recovered and converted to sulfuric acid, although in previous years much of this SO2 was discarded through exceptionally tall smokestacks. Fortunately, it is now economically favorable to recover these gases, thus greatly reducing this type of atmospheric pollution. A typical roasting reaction involves the change:2 ZnS +3 O2—2 ZnO + 2 SO2Phosphorus, below 800℃ consists of tetratomic molecules, P4. Its molecular structure provides for a covalence of three, as may be expected from the three unpaired p electrons in its atomic structure, and each atom is attached to three others6. Instead of a strictly orthogonal orientation, with the three bonds 90° to each other, the bond angles are only 60°. This supposedly strained structure is stabilized by the mutual interaction of the four atoms (each atom is bonded to the other three), but it is chemically the most active form of phosphorus. This form of phosphorus, the white modification, is spontaneously combustible in air. When heated to 260°C it changes to red phosphorus, whose structure is obscure. Red phosphorus is stable in air but, like all forms of phosphorus, it should be handled carefully because of its tendency to migrate to the bones when ingested, resulting in serious physiological damage.Elemental carbon exists in one of two crystalline structures — diamond and graphite. The diamond structure, based on tetrahedral bonding of hybridized sp3orbitals, is encountered among Group IV elements. We may expect that as the bond length increases, the hardness of the diamond-type crystal decreases. Although the tetrahedral structure persists among the elements in this group — carbon, silicon, germanium, and gray tin — the interatomic distances increase from 1.54 A for carbon to 2.80 A for gray tin. Consequently .the bond strengths among the four elements range from very strong to quite weak. In fact, gray tin is so soft that it exists in the form of microcrystals or merely as a powder. Typical of the Group IV diamond-type crystalline elements, it is a nonconductor and shows other nonmetallic properties7.03. GROUPS IB AND IIB ELEMENTSPhysical properties of Group IB and IIBThese elements have a greater bulk use as metals than in compounds, and their physical properties vary widely.Gold is the most malleable and ductile of the metals. It can be hammered into sheets of 0.00001 inch in thickness; one gram of the metal can be drawn into a wire 1.8 mi in length1. Copper and silver are also metals that are mechanically easy to work. Zinc is a little brittle at ordinary temperatures, but may be rolled into sheets at between 120° to 150℃; it becomes brittle again about 200℃-The low-melting temperatures of zinc contribute to the preparation of zinc-coated iron .galvanized iron; clean iron sheet may be dipped into vats of liquid zinc in its preparation. A different procedure is to sprinkle or air blast zinc dust onto hot iron sheeting for a zinc melt and then coating.Cadmium has specific uses because of its low-melting temperature in a number of alloys. Cadmium rods are used in nuclear reactors because the metal is a good neutron absorber.Mercury vapor and its salts are poisonous, though the free metal may be taken internally under certain conditions. Because of its relatively low boiling point and hence volatile nature, free mercury should never be allowed to stand in an open container in the laboratory. Evidence shows that inhalation of its vapors is injurious.The metal alloys readily with most of the metals (except iron and platinum) to form amalgams, the name given to any alloy of mercury.Copper sulfate, or blue vitriol (CuSO4 • 5H2O) is the most important and widely used salt of copper. On heating, the salt slowly loses water to form first the trihydrate (CuSO4 • 3H z O), then the monohydrate (CuSO4 • H2O), and finally the white anhydrous salt. The anhydrous salt is often used to test for the presence of water in organic liquids. For example, some of the anhydrous copper salt added to alcohol (which contains water) will turn blue because of the hydration of the salt.Copper sulfate is used in electroplating. Fishermen dip their nets in copper sulfate solution to inhibit the growth of organisms that would rot the fabric. Paints specifically formulated for use on the bottoms of marine craft contain copper compounds to inhibit the growth of barnacles and other organisms.When dilute ammonium hydroxide is added" to a solution of copper (I) ions, a greenish precipitate of Cu(OH)2 or a basic copper(I) salt is formed. This dissolves as more ammonium hydroxide is added. The excess ammonia forms an ammoniated complex with the copper (I) ion of the composition, Cu(NH3)42+. This ion is only slightly dissociated; hence in an ammoniacal solution very few copper (I) ions are present. Insoluble copper compounds, execpt copper sulfide, are dissolved by ammonium hydroxids. The formation of the copper (I) ammonia ion is often used as a test for Cu2+ because of its deep, intense blue color.Copper (I) ferrocyanide [Cu2Fe(CN)6] is obtained as a reddish-brown precipitate on the addition of a soluble ferrocyanide to a solution of copper ( I )ions. The formation of this salt is also used as a test for the presence of copper (I) ions.Compounds of Silver and GoldSilver nitrate, sometimes called lunar caustic, is the most important salt of silver. It melts readily and may be cast into sticks for use in cauterizing wounds. The salt is prepared by dissolving silver in nitric acid and evaporating the solution.3Ag + 4HNO3—3AgNO3 + NO + 2H2OThe salt is the starting material for most of the compounds of silver, including the halides used in photography. It is readily reduced by organic reducing agents, with the formation of a black deposit of finely divided silver; this action is responsible for black spots left on the fingers from the handling of the salt. Indelible marking inks and pencils take advantage of this property of silver nitrate.The halides of silver, except the fluoride, are very insoluble compounds and may be precipitated by the addition of a solution of silver salt to a solution containing chloride, bromide, or iodide ions.The addition of a strong base to a solution of a silver salt precipitates brown silver oxide (Ag2G). One might expect the hydroxide of silver to precipitate, but it seems likely that silver hydroxide is very unstable and breaks down into the oxide and water — if, indeed, it is ever formed at all3. However, since a solution of silver oxide js definitely basic, there must be hydroxide ions present in solution.Ag2O + H2O = 2Ag+ + 2OH-Because of its inactivity, gold forms relatively few compounds. Two series of compounds are known — monovalent and trivalent. Monovalent (aurous) compounds resemble silver compounds (aurous chloride is water insoluble and light sensitive), while the higher valence (auric) compounds tend to form complexes. Gold is resistant to the action of most chemicals —air, oxygen, and water have no effect. The common acids do not attack the metal, but a mixture of hydrochloric and nitric acids (aqua regia) dissolves it to form gold( I ) chloride or chloroauric acid. The action is probably due to free chlorine present in the aqua regia.3HCl + HNO3----→ NOCl+Cl2 + 2H2O2Au + 3Cl2 ----→ 2AuCl3AuCl3+HCl----→ HAuCl4chloroauric acid (HAuCl4-H2O crystallizes from solution).Compounds of ZincZinc is fairly high in the activity series. It reacts readily with acids to produce hydrogen and displaces less active metals from their salts. 1 he action of acids on impure zinc is much more rapid than on pure zinc, since bubbles of hydrogen gas collect on the surface of pure zinc and slow down the action. If another metal is present as an impurity, the hydrogen is liberated from the surface of the contaminating metal rather than from the zinc. An electric couple to facilitate the action is probably Set up between the two metals.Zn + 2H+----→ Zn2+ + H2Zinc oxide (ZnO), the most widely used zinc compound, is a white powder at ordinary temperatures, but changes to yellow on heating. When cooled, it again becomes white. Zinc oxide is obtained by burning zinc in air, by heating the basic carbonate, or by roasting the sulfide. The principal use of ZnO is as a filler in rubber manufacture, particularly in automobile tires. As a body for paints it has the advantage over white lead of not darkening on exposure to an atmosphere containing hydrogen sulfide. Its covering power, however, is inferior to that of white lead.04. GROUPS IIIB—VIIIB ELEMENTSGroup I-B includes the elements scandium, yttrium, lanthanum, and actinium1, and the two rare-earth series of fourteen elements each2 —the lanthanide and actinide series. The principal source of these elements is the high gravity river and beach sands built up by a water-sorting process during long periods of geologic time. Monazite sand, which contains a mixture of rare earth phosphates, and an yttrium silicate in a heavy sand are now commercial sources of a number of these scarce elements.Separation of the elements is a difficult chemical operation. The solubilities of their compounds are so nearly alike that a separation by fractional crystallization is laborious and time-consuming. In recent years, ion exchange resins in high columns have proved effective. When certain acids are allowed to flow down slowly through a column containing a resin to which ions of Group III B metals are adsorbed, ions are successively released from the resin3. The resulting solution is removed from the bottom of the column or tower in bands or sections. Successive sections will contain specific ions in the order of release by the resin. For example .lanthanum ion (La3+) is most tightly held to the resin and is the last to be extracted, lutetium ion (Lu3+) is less tightly held and appears in one of the first sections removed. If the solutions are recycled and the acid concentrations carefully controlled, very effective separations can be accomplished. Quantities of all the lanthanide series (except promethium, Pm, which does not exist in nature as a stable isotope) are produced for the chemical market.The predominant group oxidation number of the lanthanide series is +3, but some of the elements exhibit variable oxidation states. Cerium forms cerium( III )and cerium ( IV ) sulfates, Ce2 (SO4 )3 and Ce(SO4 )2, which are employed in certain oxidation-reduction titrations. Many rare earth compounds are colored and are paramagnetic, presumably as a result of unpaired electrons in the 4f orbitals.All actinide elements have unstable nuclei and exhibit radioactivity. Those with higher atomic numbers have been obtained only in trace amounts. Actinium (89 Ac), like lanthanum, is a regular Group IIIB element.Group IVB ElementsIn chemical properties these elements resemble silicon, but they become increasingly more metallic from titanium to hafnium. The predominant oxidation state is +4 and, as with silica (SiO2), the oxides of these elements occur naturally in small amounts. The formulas and mineral names of the oxides are TiO2, rutile; ZrO2, zirconia; HfO2, hafnia. Titanium is more abundant than is usually realized. It comprises about 0.44%of the earth's crust. It is over 5.0%in average composition of first analyzed moon rock. Zirconium and titanium oxides occur in small percentages in beach sands.Titanium and zirconium metals are prepared by heating their chlorides with magnesium metal. Both are particularly resistant to corrosion and have high melting points.Pure TiO2 is a very white substance which is taking the place of white lead in many paints. Three-fourths of the TiO2 is used in white paints, varnishes, and lacquers. It has the highest index of refraction (2.76) and the greatest hiding power of all the common white paint materials. TiO2 also is used in the paper, rubber, linoleum, leather, and textile industries.Group VB Elements: Vanadium, Niobium, and TantalumThese are transition elements of Group VB, with a predominant oxidation number of + 5. Their occurrence iscomparatively rare.These metals combine directly with oxygen, chlorine, and nitrogen to form oxides, chlorides, and nitrides, respectively. A small percentage of vanadium alloyed with steel gives a high tensile strength product which is very tough and resistant to shock and vibration. For this reason vanadium alloy steels are used in the manufacture ofhigh-speed tools and heavy machinery. Vanadium oxide is employed as a catalyst in the contact process of manufacturing sulfuric acid. Niobium is a very rare element, with limited use as an alloying element in stainless steel. Tantalum has a very high melting point (2850 C) and is resistant to corrosion by most acids and alkalies.Groups VIB and VIIB ElementsChromium, molybdenum, and tungsten are Group VIB elements. Manganese is the only chemically important element of Group VIIB. All these elements exhibit several oxidation states, acting as metallic elements in lower oxidation states and as nonmetallic elements in higher oxidation states. Both chromium and manganese are widely used in alloys, particularly in alloy steels.Group VIIIB MetalsGroup VIIIB contains the three triads of elements. These triads appear at the middle of long periods of elements in the periodic table, and are members of the transition series. The elements of any given horizontal triad have many similar properties, but there are marked differences between the properties of the triads, particularly between the first triad and the other two. Iron, cobalt, and nickel are much more active than members of the other two triads, and are also much more abundant in the earth's crust. Metals of the second and third triads, with many common properties, are usually grouped together and called the platinum metals.These elements all exhibit variable oxidation states and form numerous coordination compounds.CorrosionIron exposed to the action of moist air rusts rapidly, with the formation of a loose, crumbly deposit of the oxide. The oxide does not adhere to the surface of the metal, as does aluminum oxide and certain other metal oxides, but peelsoff .exposing a fresh surface of iron to the action of the air. As a result, a piece of iron will rust away completely in a relatively short time unless steps are taken to prevent the corrosion. The chemical steps in rusting are rather obscure, but it has been established that the rust is a hydrated oxide of iron, formed by the action of both oxygen and moisture, and is markedly speeded up by the presence of minute amounts of carbon dioxide5.Corrosion of iron is inhibited by coating it with numerous substances, such as paint, an aluminum powder gilt, tin, or organic tarry substances or by galvanizing iron with zinc. Alloying iron with metals such as nickel or chromium yields a less corrosive steel. "Cathodic protection" of iron for lessened corrosion is also practiced. For some pipelines and standpipes zinc or magnesium rods in the ground with a wire connecting them to an iron object have the following effect: with soil moisture acting as an electrolyte for a Fe — Zn couple the Fe is lessened in its tendency to become Fe2+. It acts as a cathode rather than an anode.。
基于混合储能的光伏微网孤网运行的综合控制策略分析
电力系统2020.20 电力系统装备丨7Electric System2020年第20期2020 No.20电力系统装备Electric Power System Equipment基于孤岛模式下,光伏微网系统运作的过程当中,电能显现出诸多方面的特性,如波动性与间歇性等,对于系统而言,其中装设了很多不同类型的储能设施。
一般来说,以超级电容器装置、蓄电池装置为主。
通常情况之下,超级电容装置具有很高的密度特征,能够达到瞬时功率吸纳,或放出的效果。
不过不可以长久为负荷供应电能,但是蓄电池则可以达到,同时存在着使用寿命较短、相应功率密度很低等不同方面的劣势。
因而,加大对混合储能系统的研究可谓十分关键。
鉴于此,系统思考和分析基于混合储能的光伏微网孤网运行的综合控制策略显得尤为必要,拥有一定的研究意义与实践价值。
1 系统组成相关概述通常情况下,借助铅酸电池较大的能量密度优势,使其能够当作相应的储能设备。
对于超级电容功率装置而言,在密度方面表现出很高的水平,属于短期阶段主要的储能设备之一,能够发挥出科学管控系统运行变动功率的作用。
关于超级电容与铅酸蓄电池的具体特征对比情况见表1。
表1 超级电容与铅酸蓄电池的特征对比情况超级电容器蓄电池放电的时间1~25 s 0.5~4 h 充电的时间1~25 s 1~4 h 能量密度/(Wh/kg )1~1525~150功率密度/(W/kg )1200~250055~250循环效率/%0.8~0.860.6~0.75循环寿命/次>100000600~2500在本次研究的系统当中,以主电路、管控电路为主。
在此过程当中,前者则拥有众多不同类型的构成部分,如常见的光伏组件、蓄电池组以及超级电容器设备等,详情见图1。
在这当中,无论光伏组件、蓄电池组装置,还是超级电容器装置,均能够依靠相关DC /DC 变换器设备,达到与500V 直流母线相接的效果,由此,使得交流电网得到稳定地运行,减小电能供应的压力。
Microgrid Test-Beds and Its Control Strategies
Microgrid Test-Beds and Its Control StrategiesManika Nakaththalage Suranjith Ariyasinghe;Kullappu Thantrige Manjula Udayanga Hemapala【期刊名称】《智能电网与可再生能源(英文)》【年(卷),期】2013(4)1【摘要】The scares of conventional energy resources and negative environmental impact of non renewable energy recourses are accelerating the technologies for new non conventional environment friendly energy options. Most of utility the grids are saturated with bulk energy resources but there are plenty of available small scale energy resources distributed around regions. Most of them are identified as wind, photo voltaic (PV), solar thermal and waste heat from industries and cooling tower of combined cycle power plants. It is difficult to gain full potential from these renewable energy resources as when they are connected to the power system individually, it leads to hindering the system stability. Microgrid is an attractive option to harness the benefits offered by distributed generation, eliminating constraints on high penetration of Distributed Energy Resources (DER). The microgrid provides an interface between central grid and micro devices to overcome these individual integration issues. So microgrid should capable to address those issues to optimize grid stability and power quality. Control system of the microgrid can be discriminated as voltage and frequency control, power flow balancing, loadsharing, and protection as well as islanding and resynchronization. This research is focused on design and development of a microgrid test-bed for experimenting several kinds of microgrid topologies and coordination of individual components with a well defined energy management scheme.【总页数】7页(P11-17)【关键词】Microgrid;Distributed;Generation;Renewable;Energy【作者】Manika Nakaththalage Suranjith Ariyasinghe;Kullappu Thantrige Manjula Udayanga Hemapala【作者单位】Department of Electrical Engineering, University of Moratuwa, Katubedda, Sri Lanka.【正文语种】中文【中图分类】R73【相关文献】1.An Overview of Bidirectional DC-DC Converter Topologies and Control Strategies for Interfacing Energy Storage Systems in Microgrids [J], Nisha Kondrath;2.A seamless operation mode transition control strategy for a microgrid based on master-slave control [J], WANG ChengShan;LI XiaLin;GUO Li;LI YunWei3.Decentralized Power Control Strategy in Microgrid for Smart Homes [J], Manzar Ahmed;Asif Nawaz;Mishaal Ahmed;Muhammad Shoaib Farooq4.An Integrated Control Strategy Adopting Droop Control with Virtual Inductance in Microgrid [J], Jianjun Su;Jieyun Zheng;Demin Cui;XiaoboLi;Zhijian Hu;Chengxue Zhang5.A Grid Interface Current Control Strategy for DC Microgrids [J], Muhannad Alshareef;Zhengyu Lin;Fulong Li;Fei Wang因版权原因,仅展示原文概要,查看原文内容请购买。
- 1、下载文档前请自行甄别文档内容的完整性,平台不提供额外的编辑、内容补充、找答案等附加服务。
- 2、"仅部分预览"的文档,不可在线预览部分如存在完整性等问题,可反馈申请退款(可完整预览的文档不适用该条件!)。
- 3、如文档侵犯您的权益,请联系客服反馈,我们会尽快为您处理(人工客服工作时间:9:00-18:30)。
278IEEE TRANSACTIONS ON SMART GRID, VOL. 2, NO. 2, JUNE 2011A Hybrid AC/DC Microgrid and Its Coordination ControlXiong Liu, Student Member, IEEE, Peng Wang, Member, IEEE, and Poh Chiang Loh, Member, IEEEAbstract—This paper proposes a hybrid ac/dc micro grid to reduce the processes of multiple dc–ac–dc or ac–dc–ac conversions in an individual ac or dc grid. The hybrid grid consists of both ac and dc networks connected together by multi-bidirectional converters. AC sources and loads are connected to the ac network whereas dc sources and loads are tied to the dc network. Energy storage systems can be connected to dc or ac links. The proposed hybrid grid can operate in a grid-tied or autonomous mode. The coordination control algorithms are proposed for smooth power transfer between ac and dc links and for stable system operation under various generation and load conditions. Uncertainty and intermittent characteristics of wind speed, solar irradiation level, ambient temperature, and load are also considered in system control and operation. A small hybrid grid has been modeled and simulated using the Simulink in the MATLAB. The simulation results show that the system can maintain stable operation under the proposed coordination control schemes when the grid is switched from one operating condition to another. Index Terms—Energy management, grid control, grid operation, hybrid microgrid, PV system, wind power generation.I. INTRODUCTION HREE PHASE ac power systems have existed for over 100 years due to their efficient transformation of ac power at different voltage levels and over long distance as well as the inherent characteristic from fossil energy driven rotating machines. Recently more renewable power conversion systems are connected in low voltage ac distribution systems as distributed generators or ac micro grids due to environmental issues caused by conventional fossil fueled power plants. On other hand, more and more dc loads such as light-emitting diode (LED) lights and electric vehicles (EVs) are connected to ac power systems to save energy and reduce CO emission. When power can be fully supplied by local renewable power sources, long distance high voltage transmission is no longer necessary [1]. AC micro grids [2]–[5] have been proposed to facilitate the connection of renewable power sources to conventional ac systems. However, dc power from photovoltaic (PV) panels or fuel cells has to be converted into ac using dc/dc boosters and dc/ac inverters in order to connect to an ac grid. In an ac grid, embedded ac/dc and dc/dc converters are required for various home and office facilities to supply different dc voltages. AC/DC/AC converters are commonly used as drives in order to control the speed of ac motors in industrial plants.Manuscript received June 28, 2010; revised November 07, 2010; accepted February 12, 2011. Date of publication March 17, 2011; date of current version May 25, 2011. Paper no. TSG-00085-2010. The authors are with the School of EEE, Nanyang Technological University, Singapore 639798, (e-mail: liux0039@.sg; epwang@.sg; epcloh@.sg). Digital Object Identifier 10.1109/TSG.2011.2116162TRecently, dc grids are resurging due to the development and deployment of renewable dc power sources and their inherent advantage for dc loads in commercial, industrial and residential applications. The dc microgrid has been proposed [6]–[10] to integrate various distributed generators. However, ac sources have to be converted into dc before connected to a dc grid and dc/ac inverters are required for conventional ac loads. Multiple reverse conversions required in individual ac or dc grids may add additional loss to the system operation and will make the current home and office appliances more complicated. The smart grid concept is currently prevailing in the electric power industry. The objective of constructing a smart grid is to provide reliable, high quality electric power to digital societies in an environmentally friendly and sustainable way. One of most important futures of a smart grid is the advanced structure which can facilitate the connections of various ac and dc generation systems, energy storage options, and various ac and dc loads with the optimal asset utilization and operation efficiency. To achieve those goals, power electronics technology plays a most important role to interface different sources and loads to a smart grid. A hybrid ac/dc microgrid is proposed in this paper to reduce processes of multiple reverse conversions in an individual ac or dc grid and to facilitate the connection of various renewable ac and dc sources and loads to power system. Since energy management, control, and operation of a hybrid grid are more complicated than those of an individual ac or dc grid, different operating modes of a hybrid ac/dc grid have been investigated. The coordination control schemes among various converters have been proposed to harness maximum power from renewable power sources, to minimize power transfer between ac and dc networks, and to maintain the stable operation of both ac and dc grids under variable supply and demand conditions when the hybrid grid operates in both grid-tied and islanding modes. The advanced power electronics and control technologies used in this paper will make a future power grid much smarter. II. SYSTEM CONFIGURATION AND MODELING A. Grid Configuration Fig. 1 shows a conceptual hybrid system configuration where various ac and dc sources and loads are connected to the corresponding dc and ac networks. The ac and dc links are connected together through two transformers and two four-quadrant operating three phase converters. The ac bus of the hybrid grid is tied to the utility grid. A compact hybrid grid as shown in Fig. 2 is modeled using the Simulink in the MATLAB to simulate system operations and controls. Forty kW PV arrays are connected to dc bus through1949-3053/$26.00 © 2011 IEEELIU et al.: A HYBRID AC/DC MICROGRID AND ITS COORDINATION CONTROL279Fig. 3. Equivalent circuit of a solar cell. TABLE I PARAMETERS FOR PHOTOVOLTAIC PANELFig. 1. A hybrid ac/dc microgrid system.Fig. 2. A compact representation of the proposed hybrid grid.a dc/dc boost converter to simulate dc sources. A capacitor is to suppress high frequency ripples of the PV output voltage. A 50 kW wind turbine generator (WTG) with doubly fed induction generator (DFIG) is connected to an ac bus to simulate ac sources. A 65 Ah battery as energy storage is connected to dc bus through a bidirectional dc/dc converter. Variable dc load (20 kW–40 kW) and ac load (20 kW–40 kW) are connected to dc and ac buses respectively. The rated voltages for dc and ac buses are 400 V and 400 V rms respectively. A three phase bidirectional dc/ac main converter with R-L-C filter connects the dc bus to the ac bus through an isolation transformer. B. Grid Operation The hybrid grid can operate in two modes. In grid-tied mode, the main converter is to provide stable dc bus voltage and required reactive power and to exchange power between the ac and dc buses. The boost converter and WTG are controlled to provide the maximum power. When the output power of the dc sources is greater than the dc loads, the converter acts as an inverter and injects power from dc to ac side. When the total power generation is less than the total load at the dc side, the converter injects power from the ac to dc side. When the total power generation is greater than the total load in the hybrid grid, it will inject power to the utility grid. Otherwise, the hybrid grid will receive power from the utility grid. In the grid tied mode, the battery converter is not very important in system operation because power is balanced by the utility grid. In autonomousmode, the battery plays a very important role for both power balance and voltage stability. Control objectives for various converters are dispatched by energy management system. DC bus voltage is maintained stable by a battery converter or boost converter according to different operating conditions. The main converter is controlled to provide a stable and high quality ac bus voltage. Both PV and WTG can operate on maximum power point tracking (MPPT) or off-MPPT mode based on system operating requirements. Variable wind speed and solar irradiation are applied to the WTG and PV arrays respectively to simulate variation of power of ac and dc sources and test the MPPT control algorithm. C. Modeling of PV Panel Fig. 3 shows the equivalent circuit of a PV panel with a load. The current output of the PV panel is modeled by the following three equations [11], [12]. All the parameters are shown in Table I:(1) (2) (3)D. Modeling of Battery Two important parameters to represent state of a battery are terminal voltage and state of charge (SOC) as follows [13]:280IEEE TRANSACTIONS ON SMART GRID, VOL. 2, NO. 2, JUNE 2011TABLE II PARAMETERS OF DFIGwhere the subscripts , , , and denote -axis, -axis, stator, and rotor respectively, represents the inductance, is the flux linkage, and represent voltage and current respectively, and are the angular synchronous speed and slip speed respec, is the mechanical torque, is the tively, electromagnetic torque and other parameters of DIFG are listed in Table II. If the synchronous rotating - reference is oriented by the stator voltage vector, the -axis is aligned with the stator voltage vector while the -axis is aligned with the stator flux reference and . The following equaframe. Therefore, tions can be obtained in the stator voltage oriented reference frame as [14]:(11) (4) SOC (5) III. COORDINATION CONTROL OF THE CONVERTERS There are five types of converters in the hybrid grid. Those converters have to be coordinately controlled with the utility grid to supply an uninterrupted, high efficiency, and high quality power to variable dc and ac loads under variable solar irradiation and wind speed when the hybrid grid operates in both isolated and grid tied modes. The control algorithms for those converters are presented in this section. A. Grid-Connected Mode where is air density, is rotor swept area, is wind speed, and is the power coefficient, which is the function of tip speed ratio and pitch angle . The mathematical models of a DFIG are essential requirements for its control system. The voltage equations of an induction motor in a rotating - coordinate are as follows: When the hybrid grid operates in this mode, the control objective of the boost converter is to track the MPPT of the PV array by regulating its terminal voltage. The back-to-back ac/dc/ac converter of the DFIG is controlled to regulate rotor side current to achieve MPPT and to synchronize with ac grid. The energy surplus of the hybrid grid can be sent to the utility system. The role of the battery as the energy storage becomes less important because the power is balanced by the utility grid. In this case, the only function of the battery is to eliminate frequent power transfer between the dc and ac link. The dc/dc converter of the battery can be controlled as the energy buffer using the technique [15]. The main converter is designed to operate bidirectionally to incorporate complementary characteristic of wind and solar sources [16], [17]. The control objectives of the main converter are to maintain a stable dc-link voltage for variable dc load and to synchronize with the ac link and utility system. The combined time average equivalent circuit model of the booster and main converter is shown in Fig. 4 based on the basic principles and descriptions in [18] and [19] for booster and inverter respectively. Power flow equations at the dc and ac links are as follows: (14) (15) (12) (13)where is internal resistance of the battery, is the open circuit voltage of the battery, is battery charging current, is polarization voltage, is battery capacity, is exponential voltage, and is exponential capacity. E. Modeling of Wind Turbine Generator Power output from a WTG is determined by (6) (6)(7)(8)The dynamic equation of the DFIG (9) (10)LIU et al.: A HYBRID AC/DC MICROGRID AND ITS COORDINATION CONTROL281Fig. 4. Time average model for the booster and main converter.where real power and are produced by PV and WTG respectively, and are real power loads connected to is the power exchange between ac and dc buses respectively, ac and dc links, is power injection to battery, and is power injection from the hybrid grid to the utility. The current and voltage equations at dc bus are as follows:Fig. 5. The control block diagram for boost converter and main converter.(16) (17) (18) (19) where is the duty ratio of switch ST. Equations (20) and (21) show the ac side voltage equations of the main converter in ABC and - coordinates respectively [20](20)(21) where verter, are ac side voltages of the main conare voltages across in Fig. 2, and and are the corresponding - co-, ordinate variables. In order to maintain stable operation of the hybrid grid under various supply and demand conditions, a coordination control algorithm for booster and main converter is proposed based on basic control algorithms of the grid interactive inverter in [19]. The control block diagram is shown in Fig. 5. The reference value of the solar panel terminal voltage is determined by the basic perturbation and observation (P&O) algorithm based on solar irradiation and temperature to harness the maximum power [21], [22]. Dual-loop control for the dc/dc boost converter is described in [23], where the control objective is to provide a high quality dc voltage with good dynamic response. This control scheme is applied for the PV system to track optimal solar panel terminal voltage using the MPPT algorithm with minor modifications. The outer voltage loop can guarantee voltage reference tracking with zero steady-state error and the inner current loop can improve dynamic response.The one-cycle delay and saturation limiter in Fig. 5 can asfaster. In steady state, resist controller to track sides in the linear region of the saturation limiter and is equal makes to . It can be seen that a step increase of becomes negative, which in turn makes to be zero during the first switching period of the transient process. This leads to a and uplower for driving the average voltage command. ward to follow the To smoothly exchange power between dc and ac grids and supply a given reactive power to the ac link, PQ control is implemented using a current controlled voltage source for the main converter. Two PI controllers are used for real and reactive power control respectively. When resource conditions or load capacities change, the dc bus voltage is adjusted to constant through PI regulation. The PI controller is set as instantaneous reference whereas the instantaneous reactive active current current reference is determined by reactive power compensation command. When a sudden dc load drop causes power surplus at dc side, the main converter is controlled to transfer power from the dc to leads to the ac side. The active power absorbed by capacitor the rising of dc-link voltage . The negative error caused by the increase of produces a higher active current reference through the PI control. The active current and its reference are both positive. A higher positive reference will force active current to increase through the inner current control loop. Therefore, the power surplus of the dc grid can be transferred to the ac side. Similarly, a sudden increase of dc load causes the power drop at the dc grid. The main converter is shortage and controlled to supply power from the ac to the dc side. The caused by drop makes the positive voltage error magnitude of increase through the PI control. Because and are both negative, the magnitude of is increased through the inner current control loop. Therefore, power is transferred from the ac grid to the dc side. The DFIG is controlled to maintain a stable dc-link voltage of the back-to-back ac/dc/ac converter. The objectives of the rotorside converter are to track MPPT of the WTG and to manage the stator side reactive power. Different control schemes such as282IEEE TRANSACTIONS ON SMART GRID, VOL. 2, NO. 2, JUNE 2011Fig. 6. The DTC control scheme for the rotor side converter.the direct torque control (DTC) and direct power control (DPC) have been proposed for a DFIG in literature [24] and [14], [25]. The DTC scheme as shown in Fig. 6 is selected as the control method for the rotor side converter in this paper. The rotor rotational speed is obtained through the MPPT algorithm, which is based on the power and speed characteristic of the wind turand mechanical power bine [26]. The rotational speed are used to calculate the electromagnetic torque . The -axis through rotor side current reference is determined based on stator flux estimation. The rotor side - voltages are maintained through controlling the corresponding current with appropriate feed forward voltage compensation. B. Isolated Mode When the hybrid grid operates in the islanding mode, the boost converter and the back-to-back ac/dc/ac converter of the DFIG may operate in the on-MPPT or off-MPPT based on system power balance and energy constraints. The main converter acts as a voltage source to provide a stable voltage and frequency for the ac grid and operates either in inverter or converter mode for the smooth power exchange between ac and dc links. The battery converter operates either in charging or discharging mode based on power balance in the system. The dc-link voltage is maintained by either the battery or the boost converter based on system operating condition. Powers under various load and supply conditions should be balanced as follows: (22) where is the total grid loss. Two level coordination controls are used to maintain system stable operation. At the system level, operation modes of the individual converters are determined by the energy manageand ment system (EMS) based on the system net power the energy constraints and the charging/discharging rate of battery. The system control logic diagram is shown in Fig. 7. is defined as the total maximum power generation minus the total load and minus . The energy constraints of the battery are determined based on the state of charge (SOC) limits SOC SOC . It should be noted that SOC using SOC cannot be measured directly, but can be attained through some estimation methods as described in [27], [28]. The constraint of . At local level, the charging and discharging rate is individual converters operate based on mode commends from the EMS. Either the PV system or WTG or both have to operate in the off-MPPT mode for Case 1 and Case 2 and in theFig. 7. Control mode diagram for the isolated hybrid grid.Fig. 8. Time average equivalent circuit model for the three converters.on-MPPT mode for other cases. The battery converter may operate in the idle, charging, or discharging mode for different cases. The main converter will operate in the inverter mode if is negative or in the converter mode with positive . Load shedding is required to maintain power balance if power supply is less than demand and the battery is at the minimum SOC. The time average equivalent circuit model of the booster, main converter, and battery converter for the isolated operation is shown in Fig. 8. The inverter part of the circuit model in Fig. 8 is based on the basic principles and descriptions in [29]. The current and voltage equations for the battery converter and dc link are as follows: (23) (24) (25) where and are the duty ratio of the switches and respectively. The ac side current equations of the main converter in coordinate are as follows: (26) and are - currents at the converter side of the where transformer respectively. Multi-loop voltage control for a dc/ac inverter is described in [30], where the control objective is to provide a high quality ac voltage with good dynamic response at different load conditions. This control scheme can also be applied for main converter control to provide high quality ac voltage inLIU et al.: A HYBRID AC/DC MICROGRID AND ITS COORDINATION CONTROL283TABLE III COMPONENT PARAMETERS FOR THE HYBRID GRID.Fig. 9. Block diagram of the battery and main converters for the normal case.been developed for conventional and power-converter-based distributed generators and various microgrids. Those techniques can be modified and implemented in the proposed hybrid grid to make the system transfer smoothly from the grid tied to isolated mode. IV. SIMULATION RESULTS The operations of the hybrid grid under various source and load conditions are simulated to verify the proposed control algorithms. The parameters of components for the hybrid grid are listed in Table III. A. Grid-Connected Mode In this mode, the main converter operates in the PQ mode. Power is balanced by the utility grid. The battery is fully charged and operates in the rest mode in the simulation. AC bus voltage is maintained by the utility grid and dc bus voltage is maintained by the main converter. The optimal terminal voltage is determined using the basic P&O algorithm based on the corresponding solar irradiation. The voltages for different solar irradiations are shown in Fig. 11. W/m from 0.0 s to 0.1 s, The solar irradiation level is set as increases linearly to W/m from 0.1 s to 0.2 s, keeps conW/m from 0.3 s to 0.4 s and stant until 0.3 s, decreases to keeps that value until the final time 0.5 s. The initial voltage for the P&O is set at 250 V. It can be seen that the P&O is continuously tracing the optimal voltage from 0 to 0.2 s. The algorithm only finds the optimal voltage at 0.2 s due to the slow tracing speed. The algorithm is searching the new optimal voltage from 0.3 s and finds the optimal voltage at 0.48 s. It can be seen that the basic algorithm can correctly follow the change of solar irradiation but needs some time to search the optimal voltage. The improved P&O methods with fast tracing speed should be used in the PV sites with fast variation of solar irradiation. Fig. 12 shows the curves of the solar radiation (radiation level times 30 for comparison) and the output power of the PV panel. The output power varies from 13.5 kW to 37.5 kW, which closely follows the solar irradiation when the ambient temperature is fixed. Fig. 13 shows the voltage (voltage times 0.2 for comparison) and current responses at the ac side of the main converter when W/m at 0.3 s to the solar irradiation level decreases from W/m at 0.4 s with a fixed dc load 20 kW. It can be seenFig. 10. Block diagram of the booster and battery converter for Case 1.stand-alone mode with minor modifications. The coordinated control block diagram for the normal case is shown in Fig. 9. To provide a stable dc-link voltage, the dual loop control scheme is applied for the battery converter. The injection current . It should be noted that the output before it is set as of the outer voltage loop is multiplied by the inner loop current reference. Current is defined positive when flowing into the battery, where the preset dc-link voltage is set to constant 400 V. Considering a decrease of caused by sudden load increase or decrease of solar irradiation, multiplied by through the positive voltage error the PI produces a negative for the inner current loop, which makes the battery to transfer from charging into discharging back to its preset value . The battery mode and to rise converter is transferred from discharging into charging mode in the similar control method. The main converter provides a stable ac bus voltage for the DFIG converter as shown in the bottom of Fig. 9. The control objectives for the converters change when the system transfers from one operating scenario to another. For example, the role of the boost converter is changed to provide a stable dc-link voltage rather than the MPPT for cases 1 and 2, while the battery converter is controlled to absorb the maximum power in case 1 and is switched off in case 2. The coordinated control block diagram for these two converters in Case 1 is described in Fig. 10. The boost converter provides a stable dc-link voltage. The main converter is controlled to provide a stable ac bus voltage. The current in Fig. 10 is equal to and is equal to . The anti-islanding technique is one of the essential functions for reliable operation of distributed generation systems. Many anti-islanding detection and control schemes [31], [32] have284IEEE TRANSACTIONS ON SMART GRID, VOL. 2, NO. 2, JUNE 2011Fig. 11. The terminal voltage of the solar panel.Fig. 15. DC bus voltage transient response.Fig. 12. PV output power versus solar irradiation.Fig. 16. Upper: output power of the DFIG; Lower: AC side voltage versus current (Voltage times 1/3 for comparison).B. Isolated Mode The control strategies for the normal case and Case 1 are verified. In the normal case, dc bus voltage is maintained stable by the battery converter and ac bus voltage is provided by the main converter. The reference of dc-link voltage is set as 400 V. Fig. 16 shows the dynamic responses at the ac side of the main converter when the ac load increases from 20 kW to 40 kW at 0.3 s with a fixed wind speed 12 m/s. It is shown clearly that the ac grid injects power to the dc grid before 0.3 s and receives power from the dc grid after 0.3 s. The voltage at the ac bus is kept 326.5 V constant regardless of load conditions. The nominal voltage and rated capacity of the battery are selected as 200 V and 65 Ah respectively. Fig. 16 also shows the transient process of the DFIG power output, which becomes stable after 0.45 s due to the mechanical inertia. Fig. 17 shows the current and SOC of the battery. Fig. 18 shows the voltage of the battery. The total power generated is greater than the total load before 0.3 s and less than the total load after 0.3 s. It can be seen from Fig. 17 that the battery operates in charging mode before 0.3 s because of the positive current and discharging mode after 0.3 s due to the negative current. The SOC increases and decreases before and after 0.3 s respectively. Fig. 18 shows that the voltage drops at 0.3 s and recovers to 400 V quickly. When the system is at off-MPPT mode in Case 1, the dc bus voltage is maintained stable by the boost converter and ac bus voltage is provided by the main converter. Fig. 19 shows the dc bus voltage, PV output power, and battery charging current respectively when the dc load decreases from 20 kW to 10 kW W/m . The at 0.2 s with a constant solar irradiation levelFig. 13. AC side voltage and current of the main converter with variable solar irradiation level and constant dc load.Fig. 14. AC side voltage and current of the main converter with constant solar irradiation level and variable dc load.from the current directions that the power is injected from the dc to the ac grid before 0.3 s and reversed after 0.4 s. Fig. 14 shows the voltage (voltage times 0.2 for comparison) and current responses at the ac side of the main converter when the dc load increases from 20 kW to 40 kW at 0.25 s with a W/m . It can be seen from the current fixed irradiation level direction that power is injected from dc to ac grid before 0.25 s and reversed after 0.25 s. Fig. 15 shows the voltage response at dc side of the main converter under the same conditions. The figure shows that the voltage drops at 0.25 s and recovers quickly by the controller.LIU et al.: A HYBRID AC/DC MICROGRID AND ITS COORDINATION CONTROL285Fig. 17. Battery charging current (upper) and SOC (lower) for the normal case.Matlab/Simulink. Various control methods have been incorporated to harness the maximum power from dc and ac sources and to coordinate the power exchange between dc and ac grid. Different resource conditions and load capacities are tested to validate the control methods. The simulation results show that the hybrid grid can operate stably in the grid-tied or isolated mode. Stable ac and dc bus voltage can be guaranteed when the operating conditions or load capacities change in the two modes. The power is smoothly transferred when load condition changes. Although the hybrid grid can reduce the processes of dc/ac and ac/dc conversions in an individual ac or dc grid, there are many practical problems for implementing the hybrid grid based on the current ac dominated infrastructure. The total system efficiency depends on the reduction of conversion losses and the increase for an extra dc link. It is also difficult for companies to redesign their home and office products without the embedded ac/dc rectifiers although it is theoretically possible. Therefore, the hybrid grids may be implemented when some small customers want to install their own PV systems on the roofs and are willing to use LED lighting systems and EV charging systems. The hybrid grid may also be feasible for some small isolated industrial plants with both PV system and wind turbine generator as the major power supply.REFERENCESFig. 18. DC bus voltage transient response in isolated mode. [1] R. H. Lasseter, “MicroGrids,” in Proc. IEEE Power Eng. Soc. Winter Meet., Jan. 2002, vol. 1, pp. 305–308. [2] Y. Zoka, H. Sasaki, N. Yorino, K. Kawahara, and C. C. Liu, “An interaction problem of distributed generators installed in a MicroGrid,” in Proc. IEEE Elect. Utility Deregulation, Restructuring. Power Technol., Apr. 2004, vol. 2, pp. 795–799. [3] R. H. Lasseter and P. Paigi, “Microgrid: A conceptual solution,” in Proc. IEEE 35th PESC, Jun. 2004, vol. 6, pp. 4285–4290. [4] C. K. Sao and P. W. Lehn, “Control and power management of converter fed MicroGrids,” IEEE Trans. Power Syst., vol. 23, no. 3, pp. 1088–1098, Aug. 2008. [5] T. Logenthiran, D. Srinivasan, and D. Wong, “Multi-agent coordination for DER in MicroGrid,” in Proc. IEEE Int. Conf. Sustainable Energy Technol., Nov. 2008, pp. 77–82. [6] M. E. Baran and N. R. Mahajan, “DC distribution for industrial systems: Opportunities and challenges,” IEEE Trans. Ind. Appl., vol. 39, no. 6, pp. 1596–1601, Nov. 2003. [7] Y. Ito, Z. Yang, and H. Akagi, “DC micro-grid based distribution power generation system,” in Proc. IEEE Int. Power Electron. Motion Control Conf., Aug. 2004, vol. 3, pp. 1740–1745. [8] A. Sannino, G. Postiglione, and M. H. J. Bollen, “Feasibility of a DC network for commercial facilities,” IEEE Trans. Ind. Appl., vol. 39, no. 5, pp. 1409–1507, Sep. 2003. [9] D. J. Hammerstrom, “AC versus DC distribution systems-did we get it right?,” in Proc. IEEE Power Eng. Soc. Gen. Meet., Jun. 2007, pp. 1–5. [10] D. Salomonsson and A. Sannino, “Low-voltage DC distribution system for commercial power systems with sensitive electronic loads,” IEEE Trans. Power Del., vol. 22, no. 3, pp. 1620–1627, Jul. 2007. [11] M. E. Ropp and S. Gonzalez, “Development of a MATLAB/simulink model of a single-phase grid-connected photovoltaic system,” IEEE Trans. Energy Conv., vol. 24, no. 1, pp. 195–202, Mar. 2009. [12] K. H. Chao, C. J. Li, and S. H. Ho, “Modeling and fault simulation of photovoltaic generation systems using circuit-based model,” in Proc. IEEE Int. Conf. Sustainable Energy Technol., Nov. 2008, pp. 290–294. [13] O. Tremblay, L. A. Dessaint, and A. I. Dekkiche, “A generic battery model for the dynamic simulation of hybrid electric vehicles,” in Proc. IEEE Veh. Power Propulsion Conf. (VPPC 2007), pp. 284–289. [14] D. W. Zhi and L. Xu, “Direct power control of DFIG with constant switching frequency and improved transient performance,” IEEE Trans. Energy Conv., vol. 22, no. 1, pp. 110–118, Mar. 2007.Fig. 19. DC bus voltage, PV output power, and battery current for Case 1.battery discharging current is kept constant at 65 A. The dc bus voltage is stabilized to 400 V after 0.05 s from the load change. The PV power output drops from the maximum value after 0.2 s, which means that the operating modes are changed from MPPT to off-MPPT mode. The PV output power changes from 35 kW to 25 kW after 0.2 s. V. CONCLUSION A hybrid ac/dc microgrid is proposed and comprehensively studied in this paper. The models and coordination control schemes are proposed for the all the converters to maintain stable system operation under various load and resource conditions. The coordinated control strategies are verified by。