年产20万吨硫酸生产车间工艺设计

年产20万吨硫酸生产车间工艺设计

摘要

硫酸是最重要的基础化工原料之一，主要用于制造磷肥及无机化工原料，其次作为化工原料广泛应用于有色金属的冶炼、石油炼制和石油化工、橡胶工业以及农药、医药、印染、皮革、钢铁工业的酸洗等。本设计以硫磺为原料生产硫酸，因为以硫磺为原料生产硫酸不需净化，大大简化了工艺过程，节省投资费用，且产品质量高。

本设计完成了年产20万吨硫酸生产车间工艺设计，介绍了硫酸生产的主要方法和成熟的工艺流程。主要内容包括原料熔硫工段、焚硫转化工段、干吸工段及主要设备的选择、环保措施等。完成了化工设计的各个设计环节，达到了设计目标。经分析，设计技术可靠，经济合理。在设计过程中，还重点对废水处理进行了分析。

关键词：硫酸；硫磺制酸；焚烧炉；转化塔

The Production Process Design of the Workshop for Sulfuric acid with an Annual Output of 200,000 Tons

Abstract

Sulfuric acid is one of the most important basic chemical raw materials, mainly used in the manufacture of phosphate fertilizer and inorganic chemical raw materials, as a chemical raw material, it is widely used in non-ferrous metal smelting, petroleum refining and petroleum chemical industry, rubber industry, as well as pesticides, pharmaceuticals, printing and dyeing, leather pickling of iron and steel industry. This design is used sulfuric acid as raw material to product sulfur, thus it products sulfur without purification, the process is greatly simplified to save investment costs and gain high product quality.

It is an annual output of 200,000 tons of sulfuric acid production plant process design, introduces the main methods of sulfuric acid production and mature process. The main contents include the raw material sulfur melting section, and burning sulfur conversion section, drying and absorption section and the major equipments selection, environmental protection measures. It completes various links of the chemical engineering design, and achieves the design objectives. Through the analysis of the design, design technology is reliable, and the design is economical and reasonable. In the design process, it is also focusing on wastewater treatment.

Keywords: Sulfuric acid; Producing Sulfuric Acid by Sulfur; The stove of sulfur; Conversion tower

目录

1 引言 (1)

1.1概述 (1)

1.2全球硫酸工业概况 (1)

1.3我国工业概况 (2)

1.4硫酸的性质 (3)

1.4.1物理性质 (3)

1.4.2浓硫酸的化学性质 (4)

1.4.3稀硫酸的化学性质 (7)

1.4.4相对密度 (7)

1.4.5硫酸的结晶温度 (8)

1.4.6硫酸的热容、热焓 (8)

1.4.7硫酸的沸点蒸气压和蒸气组成 (9)

1.5硫酸几种不同的生产工艺 (10)

1.5.1以硫磺为原料 (10)

1.5.2以硫铁矿含伴生硫铁矿为原料 (11)

1.5.3冶炼烟气和其它原料 (11)

1.6低浓度二氧化硫气体的处理 (12)

1.7硫酸污水处理 (13)

1.8二氧化硫尾气 (13)

2 工艺流程 (13)

2.1快速熔硫与液硫过滤工段 (14)

2.2转化工段 (15)

2.2.1二氧化硫转化反应的基本原理 (15)

2.2.2二氧化硫转化三氧化硫工艺操作条件选择和选定理由 (17)

2.3吸收工段 (27)

2.3.1吸收流程配置的方式 (28)

2.3.2吸收工段的流程 (29)

2.3.3吸收工段主要工艺指标分析 (29)

2.4废热回收工艺 (30)

2.5关于低温位热能回收工艺 (31)

3 物料衡算 (32)

3.1 设计要求： (32)

3.2物料衡算 (32)

3.2.1硫磺焚烧的物料衡算 (32)

3.2.2转化器物料衡算 (33)

3.3热量衡算 (36)

3.3.1热量衡算的目的 (36)

3.3.2热量衡算依据 (36)

3.3.3各物质热力学参数[23]（标况下） (36)

3.3.4各工段的热量衡算 (37)

4 主要设备的设计与选型 (46)

4.1焚硫炉 (46)

4.2转化塔 (47)