乙醇与氯化氢的反应方程式
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乙醇与氯化氢的反应方程式
英文回答:
Reaction between Ethanol and Hydrogen Chloride.
Ethanol (C2H5OH) is a primary alcohol that can undergo a reaction with hydrogen chloride (HCl) to form ethyl chloride (C2H5Cl) and water (H2O). This reaction is known as an electrophilic addition reaction, where the electrophile is the hydrogen ion (H+) from the HCl molecule and the nucleophile is the alcohol molecule.
The mechanism of the reaction involves the following steps:
1. Protonation of the alcohol: The hydrogen ion from HCl adds to the oxygen atom of the alcohol molecule, forming a positively charged intermediate known as an oxonium ion (C2H5OH2+).
2. Nucleophilic attack: The chloride ion (Cl-) from the HCl molecule acts as a nucleophile and attacks the oxonium ion, forming a new bond between the carbon atom and the chlorine atom.
3. Deprotonation: The protonated oxygen atom of the oxonium ion undergoes deprotonation by losing a proton to form water.
The overall reaction can be represented by the
following equation:
C2H5OH + HCl → C2H5Cl + H2O.
中文回答:
乙醇与氯化氢的反应。
乙醇(C2H5OH)是一种伯醇,它可以与氯化氢(HCl)反应生成氯乙烷(C2H5Cl)和水(H2O)。
该反应被称为亲电加成反应,其中亲电试剂是 HCl 分子中的氢离子 (H+),而亲核试剂是醇分子。
该反应的机理涉及以下步骤:
1. 醇的质子化,HCl 中的氢离子加到醇分子的氧原子上,形成一种带正电的中间体,称为鎓离子(C2H5OH2+)。
2. 亲核攻击,HCl 分子中的氯离子 (Cl-) 充当亲核试剂并攻击鎓离子,在碳原子和氯原子之间形成一个新的键。
3. 去质子化,鎓离子中质子化的氧原子通过失去一个质子而被去质子化,生成水。
总的反应可以用以下方程式表示:
C2H5OH + HCl → C2H5Cl + H2O.。