多升多降的化学方程式配平

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多升多降的化学方程式配平
英文回答:
Chemical equation balancing involving multiple oxidation states can be challenging, but with some practice and understanding of the concept, it can be done effectively. In this type of balancing, the goal is to ensure that the number of atoms of each element and the total charge are balanced on both sides of the equation.
To illustrate this, let's consider the reaction between potassium permanganate (KMnO4) and hydrogen peroxide (H2O2) in an acidic solution. The unbalanced equation is as follows:
KMnO4 + H2O2 -> K2MnO4 + O2 + H2O.
To begin the balancing process, we need to assign oxidation states to each element. In KMnO4, the oxidation state of potassium (K) is +1, the oxidation state of oxygen
(O) in the peroxide ion (O2-) is -1, and the oxidation state of manganese (Mn) is +7. In H2O2, the oxidation state of oxygen is -1, and the oxidation state of hydrogen (H) is +1.
Next, we need to balance the atoms and charges on both sides of the equation. Starting with the oxygen atoms, there are four oxygen atoms in KMnO4 and two in H2O2. To balance the oxygen atoms, we need to add two water molecules (H2O) to the product side of the equation:
KMnO4 + H2O2 -> K2MnO4 + O2 + 2H2O.
Now, let's balance the hydrogen atoms. There are four hydrogen atoms in H2O2, so we need to add four hydrogen ions (H+) to the reactant side of the equation:
KMnO4 + 4H+ + H2O2 -> K2MnO4 + O2 + 2H2O.
Finally, let's balance the charges. The total charge on the reactant side is +1 (from K) + 4(+1) (from H) = +5. On the product side, the total charge is +2 (from K) + 4(+1)
(from H) = +6. To balance the charges, we need to add one electron (e-) to the reactant side:
KMnO4 + 4H+ + H2O2 + e-> K2MnO4 + O2 + 2H2O.
Now, the equation is balanced both in terms of atoms and charges. The balanced equation is:
2KMnO4 + 3H2O2 + 2H+ -> 2K2MnO4 + 3O2 + 2H2O.
With practice, you will become more comfortable with balancing chemical equations involving multiple oxidation states. Remember to assign oxidation states, balance atoms, and charges, and make any necessary adjustments to achieve a balanced equation.
中文回答:
化学方程式配平涉及到多种氧化态时可能会有一定的挑战性,但通过一些实践和对概念的理解,可以有效地完成。

在这种类型的配平中,目标是确保每个元素的原子数和总电荷在方程式的两侧都是平衡的。

为了说明这一点,让我们考虑一下高锰酸钾(KMnO4)和过氧化氢(H2O2)在酸性溶液中的反应。

未配平的方程式如下:
KMnO4 + H2O2 -> K2MnO4 + O2 + H2O.
开始配平过程时,我们需要为每个元素分配氧化态。

在KMnO4中,钾(K)的氧化态为+1,过氧化物离子(O2-)中的氧(O)的氧化态为-1,锰(Mn)的氧化态为+7。

在H2O2中,氧的氧化态为-1,氢(H)的氧化态为+1。

接下来,我们需要平衡方程式两侧的原子和电荷。

从氧原子开始,KMnO4中有四个氧原子,而H2O2中有两个氧原子。

为了平衡氧原子,我们需要在产物一侧添加两个水分子(H2O):
KMnO4 + H2O2 -> K2MnO4 + O2 + 2H2O.
现在,让我们平衡氢原子。

H2O2中有四个氢原子,所以我们需要在反应物一侧添加四个氢离子(H+):
KMnO4 + 4H+ + H2O2 -> K2MnO4 + O2 + 2H2O.
最后,让我们平衡电荷。

反应物一侧的总电荷为+1(来自K)+ 4(+1)(来自H)= +5。

在产物一侧,总电荷为+2(来自K)+ 4(+1)(来自H)= +6。

为了平衡电荷,我们需要在反应物一侧添
加一个电子(e-):
KMnO4 + 4H+ + H2O2 + e-> K2MnO4 + O2 + 2H2O.
现在,方程式在原子和电荷方面都是平衡的。

平衡的方程式为: 2KMnO4 + 3H2O2 + 2H+ -> 2K2MnO4 + 3O2 + 2H2O.
通过实践,您将更加熟悉涉及多种氧化态的化学方程式配平。

记住要分配氧化态,平衡原子和电荷,并进行必要的调整以实现平
衡的方程式。

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