Very rapid optical variability of PKS 2155-304

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The BeppoSAX spectrum of the composite galaxy Mrk609

The BeppoSAX spectrum of the composite galaxy Mrk609

a r X i v :a s t r o -p h /0204514v 1 30 A p r 2002Mon.Not.R.Astron.Soc.000,000–000(0000)Printed 1February 2008(MN L A T E X style file v1.4)The BeppoSAX spectrum of the composite galaxy Mrk609A.Pappa 1,2,I.Georgantopoulos 3,M.Ward 1,A.L.Zezas 41Departmentof Physics and Astronomy,University of Leicester,Leicester,LE17RH,UK1Institute for Astronomy,University of Edinburgh,Royal Observatory,Blackford Hill,Edinburgh EH93HJ,UK3Institute of Astronomy &Astrophysics,National Observatory of Athens,Lofos Koufou,Palaia Penteli,15236,Athens,Greece 4Harvard-Smithsonian Center for Astrophysics,60Gardes St.,Cambridge,MA 02138,USA1February 2008ABSTRACTWe present BeppoSAX observations of the starburst/Seyfert composite galaxy Mrk609.This enigmatic object has an optical spectrum dominated by the features of starburst galaxies,yet its X-ray luminosity (6.3×1042erg s −1)is typical of an AGN.The X-ray spectrum of Mrk609can be parameterised by a single power-law model with a photon index Γ∼1.6±0.1and no evidence for significant absorption above the Galactic value.Long term variability in both the 0.1-2keV and 2-10keV energy bands is detected,again suggesting that the X-ray emission is dominated by an AGN.The observed broad Ha component is a factor of 40below that predicted by the X-ray flux implying a deficit of ionizing UV photons.Key words:galaxies:AGN –galaxies:starburst -X-rays:galaxies1INTRODUCTIONMoran,Halpern &Helfand (1996),after careful spectroscopy of a sample based on the cross-correlation of the IRAS PSC and ROSAT All Sky Survey,reported the discovery of an “anomalous”class of objects.The optical spectra of these sources are dominated by the features of starburst galaxies,based on the emission line diagnostic diagrams (Veilleux &Osterbrock 1987),yet their X-ray luminosities are typical of Seyfert 2galaxies.Close examination of their optical spectra reveals some weak Seyfert-like features:[OIII]significantly broader than all other narrow lines in the spectrum and in some cases a weak broad H αcomponent.The authors desig-nated these objects “starburst/Seyfert composite”galaxies and presented them as a new class of X-ray luminous source.Similar ”composite”objects have also been noticed by Veron et al.(1997).Indeed,they presented observations of 15ob-jects with transition spectra ie showing the simultaneous presence of a strong star-forming component and an active nucleus and they showed that fall either on the starburst region or on the borderlines between the different classes.Hereafter,we will refer to these objects as composite galax-ies and we will distinguish them from the Sy2/Starburst galaxies that show emission from both components at all wavelengths.The composite galaxies bear close resemblance to the narrow-line X-ray galaxies (NLXGs)detected in large num-bers in deep ROSAT surveys (eg Boyle et al.1995,Griffiths et al.1996).These NLXGs again have spectra composite of Seyfert and starburst galaxies (Boyle et al.1995)with lumi-nosities L 2−10keV ∼1042−43erg s −1.Unfortunately the faintfluxes of these NLXGs do not allow their detailed study in either optical or X-ray wavelengths.Although it is unclear whether these nearby “composites”are the same class of ob-jects as those found in ROSAT deep field NLXGs,their high luminosities need to be explained.It is unclear how their in-tense X-ray emission can be reconciled with weak or absent Seyfert characteristics.1.1Composite galaxies in X-raysOnly a few composite galaxies have been studied so far in X-rays.Specifically,IRAS00317-2142(Georgantopoulos 2000)has been observed with ASCA and is the most luminous object (L x =∼1043erg s −1in the 0.1-2keV band)in the Moran et al.(1996)sample.The spectrum is represented by a power-law with Γ∼1.76and there is no evidence for absorption above the Galactic value.Strong variability in the 1-2keV band (by a factor of three)is detected between the ROSAT and ASCA observations.These characteristics indicate an AGN origin for the X-ray emission.However no iron line is detected and the 90per cent upper limit on the equivalent width is 0.9keV.The ratio f HX /f [OIII ]∼2.5rule out the Compton thick interpretation for IRAS00317-2142.However,the precise nature of this object and the relative contribution of the starburst and AGN components could not be determined.A further composite object studied in X-rays with ROSAT and ASCA is AXJ1749+684(Iwasawa et al.1997).AXJ1749+684was serendipitously detected with the ASCAc0000RAS2 A.Pappa,I.Georgantopoulos,M.Ward and A.L.ZezasGIS.Its X-ray spectrum isflat(Γ=1.23+0.21−0.27).Theflat-ness is attributed by the authors to absorption mainly be-cause of the:(a)large Balmer decrement in the narrow line region,Hα/Hβ=7.32and(b)lack of significant X-ray de-tection at<0.4keV.On the other hand,the optical coun-terpart of AXJ1749+684is detected in the Kiso Schmidt Survey of UV-excess galaxies.Iwasawa et al.(1997)claimed that the UV emission is due to large-scale starburst activ-ity,however in this case strong far infrared emission should be expected,which is inconsistent with the non-detection of this source by IRAS.They concluded that the X-ray spectrum of AXJ1749+684is wellfitted by an obscured(N H=2.1+6.2−2.1×1021cm−2)Seyfert nucleus embeddedwithin a star-forming galaxy.Recently Levenson et al.2001,examined NGC6221as a further example of a composite galaxy.They proposed that the X-ray spectrum of this object is characterised by a Seyfert1like spectrum.They detect an iron line and con-tinuum variability on short-and long-term timescales.The source has a column density of N H=1022cm−2.They pro-posed that the central region is obscured by a surrounding starburst.Thus the optical spectrum has the characteristics of the starburst component alone.1.2Mrk609Mrk609is at a redshift of0.034.The optical position of the object is032525.3,-060839(J2000)and the Galactic absorption is N H=4.41×1020cm−2.The Hβprofile is∼110 km sec−1wide,while the[OIII]lines are∼4times wider.In addition,the broad blueshifted wings seen on the[OIII]lines are completely missing in Hβ(Heckman et al.1981).The UV spectrum show strong contribution from hot stars(Rudy et al.1988)indicating the presence of an intense starburst component in Mrk609.The broad Hα/Hβvalue is7.8(Osterbrock1981).In a later observation,Rudy et al.(1988)obtained a value for the broad Hα/Hβ=5.The discrepancy was attributed to continuum variability.The high broad Hα/Hβvalue was attributed by Osterbrock1981to reddening of the broad line region.However the broad Lyα/Hβvalue is16,which is large for Seyfert1galaxies,ruling out obscuration(see Rudy et al.1988for a detailed discussion).2OBSER V ATIONS AND DATA REDUCTION Mrk609was observed by BeppoSAX three times.Thefirst observation was carried out on20/01/2000for∼18ksec (LECS exposure7.13ksec),the second one on14/02/2000 for∼2.5ksec(LECS exposure1.4ksec)and the third one on4/03/2000for∼28ksec(LECS exposure6668ksec).It should be reminded here,that the exposure time for the LECS is lower than the MECS because it is limited by stronger operational constraints to avoid UV light contam-ination,thus it is operated during Earth dark time only. Spectra and light curves of Mrk609have been extracted from circular regions centered on the source.We used a circular extraction cell of4and6arcminutes in radius for MECS and LECS data respectively.The background spectra were extracted from blank deepfield exposures,using the same region of the detector in each case.Table1.χ2for the long-term light curves.0.1-2keV8.16(2) 1.7×10−22-5keV30.08(2) 2.9×10−75-10keV 2.76(2)0.432-10keV45(2) 1.4×10−10BeppoSAX spectrum of Mrk6093(a)(b)(c)(d)Figure 1.The long term light curves for Mrk609;(a)the 0.1-2keV,(b)2-5keV,(c)5-10keV,(d)2-10keV curves.spectral fitting results is given in Table 2.In the following analysis all three BeppoSAX observations are fitted together.Throughout this paper values of H o =75km s −1Mpc −1and q o =0.5are assumed.4.1The AGN modelsWe first fit the data with a single power-law model (PL).We obtain an acceptable fit (χ2=98.89for 82dof)with Γ=1.57+0.10−0.10,and N H ≤1.32×1021cm−2.This model together with the data points and the data to model ratio are plotted in Figure 2.The observed flux in the 2-10keV band for this model is 2.86×10−12erg s −1cm −2,which corresponds to aluminosity of 6.3×1042erg s −1in the same band.If the slope of the power-law model is fixed at the 1.9value,the nominal value for the Seyfert 1galaxies (Nandra &Pounds 1994),the model yields an unacceptable fit (χ2=119.26for 83dof)with N H =2.03+1.5−1.8×1021cm −2.Although Seyfert galaxies show strong narrow iron K αemission lines,no such line is detected in Mrk609.However an upper limit of ∼283eV is obtained,consistent with values seen in Seyfert galaxies.In the context of the unified models we expect to see some faction of the primary emission through the torus,with a component superimposed upon this that represents a fraction of emission scattered back into our line of sight byc0000RAS,MNRAS 000,000–0004 A.Pappa,I.Georgantopoulos,M.Ward and A.L.ZezasFigure2.The BeppoSAX time averaged spectrum,when the single power-law model is applied to the data.Thefilled squares represent the LECS data points and the stars the MECS data points.The top panel shows the data with the model and the bottom panel shows the data/model ratiomaterial lying above the torus.This model is representingby two power-laws with the same photon index but differ-ent normalisations and absorptions-the scattering model.When this model is applied to the data,the normalisationsof the two power-laws are comparable,whereas no excess ab-sorption above the Galactic is required and thus this modeleffectively is the same as the single power-law model.There-fore it is evident that the scattering model does not providea good representation of the data.Finally,an ionised warm absorber model in additionto the Galactic column density wasfitted to the data(PL+warm).The temperature of the absorber isfixed atT=105K(Brandt et al.1999).The model provides an ac-ceptablefit(χ2=98.84for81dof)but does not represent astatistically significant improvement to the single power-lawmodel.The bestfit parameters areΓ=1.60+0.16−0.12and warmcolumn density N H w=6.73+25.47−6.73×1021cm−2,while theionisation parameter is practically unconstrained,possiblybecause of the poor statistics of the data.4.2The composite modelGiven the composite classification of this object,it is nat-ural to investigate a model in which X-ray emission origi-nates from both a starburst and an AGN.A power-law plusa Raymond-Smith model(PL+RS)with the temperaturefixed at0.8keV is adopted.The power-law component isallowed to have additional absorption over and above thatof the thermal component.This model yields an acceptablefit(χ2=99.81for81dof)withΓ=1.57+0.09−0.11,whereas noexcess absorption above the Galactic is required.When thetemperature of the thermal component is a free parameter,wefind kT>18keV andΓ=2.81+2.59−0.96(χ2=95.00for80dof).However,the temperature of the thermal componentis far too high for a starburst and thus this model cannotprovide a physical description of the data.4.3The pure starburst modelFor completeness we have also investigated pure starburstmodels.Firstly a single Raymond-Smith model(RS)wasfit-ted to the data.An acceptablefit was obtained(χ2=108.94for83dof)with kT1=18.92+10.15−6.02keV.No starbursts withsuch a high temperature have been found as yet.Then a two Raymond-Smith model representing ther-mal emission from a pure starburst galaxy following Zezaset al.(1998)was utilised.The soft emission is parameterisedby a thermal component with kT1≤1keV and the emissionin the hard band by kT2=21.8+14.33−7.69keV,again too high fora starburst.Therefore it is obvious that this model cannotprovide a physical description of the data.From the above it is evident that the pure starburstmodel is ruled out,whereas the composite model does notprovide a physically accepted model.5SPECTRAL V ARIABILITYMrk609was observed three times with BeppoSAX,allow-ing us to examine whether there is spectral variability.Inparticular it is interesting to see whether the drop in theflux during the second observation is related to a change inthe spectrum of Mrk609and examine whether the X-ray be-haviour is similar to that of black hole candidates(BHC)inour galaxy during their high and low states.For this analysisonly the single power-law is applied to the MECS data.In addition any spectral variability at soft energies willbe examined by comparing the ROSAT PSPC and LECSc 0000RAS,MNRAS000,000–000BeppoSAX spectrum of Mrk6095 Table2.The spectralfits results on the BeppoSAX data.single PL1.57+0.10−0.10≤1.32---98.89(82)1.9f2.03+1.53−0.98119.26(83)PL+warm1.60+0.16−0.12g≤369.11≥0-97.90(81)PL+RS1.57+0.09−0.11g--0.8f99.00(81)RS-g--18.92+10.05−6.02108.94(83)2RS-g--≤1105.57(80)21.81+14.33−7.696 A.Pappa,I.Georgantopoulos,M.Ward and A.L.Zezasmodel NGC6221is a Seyfert1galaxy which is surrounded by a starburst component.The starburst accounts for the X-ray obscuration(N H∼1022)cm−2and its characteristics dominate the optical spectrum.Although in principal this model can explain qualitatively the optical appearance of the composite galaxies it doesn’t seem tofit the X-ray ob-servations of Mrk609.Our object does not show concrete ev-idence for significant X-ray absorption.In addition the soft X-ray variability and the high luminosity at low energies (L0.5−2keV∼2×1042erg s−1)probably rule out a dusty ob-scuring circumnuclear starburst.We note here that the spec-tral X-ray properties of Mrk609are similar to the composite IRAS00317-2142(Georgantopoulos et al.2000).Again this galaxy has a low column density,consistent with the Galac-tic,and thus the obscuring starburst model cannot explain the properties of IRAS00317-2142.Although the single power-law model yields a good rep-resentation of the Mrk609spectrum the X-ray long term variability indicates that the spectrum of Mrk609consists of more than one components.An AGN covered by a warm ab-sorbing screen could provide an explanation for the observed long term variability.In this case changes in the X-ray con-tinuumflux,will be followed by changes in the ionisation state of the warm absorber resulting in changes in the emis-sion in the soft band.However,the quality of the data does not allow to examine the viability of the model to Mrk609.Given the composite nature of Mrk609it is natural to investigate whether emission from starburst regions con-tribute to the X-ray wavelengths.In principle,in a compos-ite starburst-AGN model,the power-law component is heav-ily absorbed,and thus the star-forming component,which is located outside the obscuring screen,dominates the soft emission.However,when this model is applied to Mrk609 data,no excess absorption above the Galactic is required by the data for the power-law component.In addition the poor quality of the data at energies below∼2keV do not allow us to constrain the temperature of the thermal emission and make an unambiguous estimate of the starburst contribu-tion to the X-ray emission.The strength of the star-forming component can be indirectly estimated from the observed IRflux.The expected X-ray contribution from stars was calculated using the empirical relationship between infrared and X-ray luminosity(equation[2]David,Jones&Forman 1992)found in a sample of IRAS galaxies.However,note that some of the infrared(IR)flux could arise from nuclear reprocessed emission from the obscuring medium.Thus any starburst contribution to the X-rayflux derived using the above relation may be overestimated and the derivedflux should only be treated as an upper limit.First we calcu-lated the IR luminosities using thefluxes IRASfluxes at 60µm and100µm and equation[1]from David,Jones et al. 1992.Wefind that the upper limit of the expected contribu-tion of a starburst in the0.5-4keV band is2.75×1042erg s−1. The luminosity in the same band derived by the spectral fitting is∼4.7×1042erg s−1,indicating that about half of the soft emission may be due to an intense starburst com-ponent.However,the variable soft X-ray emission clearly argues that any starburst contribution in soft energy band should be low.To further test the AGN interpretation of Mrk609 the broad Hαline and the2-10keVflux were compared. Ward et al.(1988)found a strong correlation between the two quantities in a sample of IRAS selected Seyfert 1galaxies.The observed luminosity of the broad Hαis L(Hα)=8.4×1039erg s−1,whereas the2-10keV luminosity is ∼7.5×1042erg s−1.According to the above relation the pre-dicted broad Hαluminosity should be∼40times higher.The above discrepancy between the optical and X-ray spectrum could be explained by variability.Possibly the AGN was weaker during the optical observation(1984),but bright-ened over the∼15years timescale between the optical and X-ray observations.Alternatively the source may have un-usually low UV emission.Then the photoionised emission lines would have lowerfluxes than those typical for AGNs. To examine this possibility the Mrk609spectral energy dis-tribution(SED)was computed.This is shown in Figure3. It is indeed clear that Mrk609lacks a big blue bump(BBB). This feature is characteristic of high luminosity unobscured AGNs and is thought to be a signature of the presence of a cold accretion disk around the black hole(see Koratkar &Blaes1999).We note here that lack of ultraviolet ex-cess has also been observed in a sample of low-luminosity AGN(Ho1999).Low accretion rate models have been em-ployed to account for the absence of the BBB feature.Note that Mrk609has a very strong Lyαline(Rudy et al.1988). The abnormally strong Lyαline and anomalous emission line strengths in Mrk609could be explained if the optical depth and ionisation parameter in the region where the lines form is significantly less than believed typical for Seyfert-1 galaxies.In this scenario the discrepancy between the op-tical and X-ray spectrum could be ing Paβspectroscopy Goodrich(1990)and Rix et al.(1990)showed that Mrk609line properties are indeed well explained by the optical depth/ionisation parameter theory.As mentioned in the introduction the optical spectrum of the composite objects like Mrk609bear close resemblance to the narrow line X-ray galaxies detected in ROSAT sur-veys.The X-ray spectrum of these sources isflat(Almaini et al.1996)but it is unclear whether theflatness of the spectrum is intrinsic or due to obscuration.On the other hand,our observations show that Mrk609has a relatively steep X-ray spectrum and no significant X-ray absorption. If the narrow line X-ray galaxies detected in ROSAT surveys have X-ray spectra similar to Mrk609then they should not contribute significantly to the XRB.7SUMMARYWe have analysed BeppoSAX data of the composite galaxy Mrk609.The spectrum is described by a power-lawΓ=1.6 with negligible absorption.The absence of absorption is con-sistent with the small Balmer decrement and the large Ly a flux observed(Rudy et al.1988).The absence of an ob-scuring column clearly does notfit the absorbed starburst model proposed by Levenson et al.2001to explain the mul-tiwavelength properties of the composite galaxy NGC6221. The detection of significant soft and hard X-ray variability, clearly suggests that the AGN emission dominates the X-ray spectrum.Any starburst contribution to the X-ray emission should be small.In addition Mrk609does not follow the L Hα−L x correlation of bright AGN(Ward et al.1988), showing a weak broad Hαcomponent(∼40times less than predicted by the X-rayflux).The discrepancy between thec 0000RAS,MNRAS000,000–000BeppoSAX spectrum of Mrk6097Figure3.The spectral energy distribution of Mrk609,from far infrared to hard X-rays.optical and X-ray spectrum can be explained as a deficit ofUV ionising photons.This is supported by the SED,whichshows no upturn of the spectrum below3000A,implying theabsence of a UV bump.Alternatively,as the optical and theX-ray observations were taken15years apart,dramatic vari-ability in the X-rayflux could result in a low L Hα−L x ratio.Finally the above discrepancy and anomalous line proper-ties could be explained by small optical depth and ionisationparameter in the line emitting regions.8ACKNOWLEDGMENTSWe would like to thank the referee Dr.J.Halpern for usefulcomments and suggestions and A.Burston for producing theSED of Mrk609.REFERENCESAlmaini O.,Shanks T.,Boyle B.J.,Griffiths R.E.,Roche N.,Stewart G.C.,Georgantopoulos I.,1996,MNRAS,282,295Boyle B.J.,McMahon R.G.,Wilkes B.J.,Elvis,M.,1995,MN-RAS,276,315Brandt W.N.,Fabian A.C.,Takahashi K.,Fujimoto R.,Ya-mashita A.,Inoue H.,Ogasaka Y.,1997,MNRAS,290,617David L.P.,Jones C.,Forman W.,1992,APJ,181,1513Georgantopoulos,I.2000,MNRAS,315,77Goodrich R.W.,1990,ApJ,355,88Griffiths R.E.,Georgantopoulos I.,Boyle B.J.,Stewart G.C.,Shanks T.,della Ceca R.,1996,MNRAS,275,77Heckman T.M.,Miley G.K.,van Breugel W.J.M,.Butcher H.R,1981,ApJ,247,403Iwasawa K.,Fabian A.C.,Brandt W.N.,Crawford C.S.,AlmainiO.,1997,MNRAS,291,L17Koratkar A.&Blaes O.,1999,PASP,111,1Levenson N.A.,Cid Fernandes R.Jr.,Weaver K.A.,HeckmanT.M.,Storchi-Bergmann T.,2001,astro-ph/0104316Moran E.,Halpern J.P,Helfand D.J.,1996,ApJS,106,341Nandra K.&Pounds K.,1994,MNRAS,268,405Osterbrock D.E.,1981,ApJ,249,462Rix H-W.,Carleton N.P.,Rieke G.,Rieke M.,1990,ApJ,363,480Rudy,R.J.,Cohen R.D.,Ake T.B.,1988,ApJ,332,172Veilleux S.,Osterbrock D.E.,1987,ApJS,63,295Veron P.,Goncalves A.C.,Veron-Cetty M.-P.,1997,A&A,319,52Ward M.J.,Done C.,Fabian A.C.,Tennant A.F.,Shafer R.A.,1988,Apj,324,767c 0000RAS,MNRAS000,000–000。

Performing Fluorescence Polarization Assays on the

Performing Fluorescence Polarization Assays on the

Multimode Detection Performing FluorescencePolarization Assays on theVICTOR NivoIntroductionFluorescence Polarization (FP) is a homogeneous assay formatthat is highly suitable for many applications from occasionalusage to high throughput screening, due to rather inexpensive reagents and its signal stability1. In FP assays, polarized light isused to determine the rotation capabilities of smallfluorescently labelled molecules. With this assay principle, onecan indirectly detect whether tracer molecules are bound to amuch larger molecule or are freely rotating in solution. Theseare rather complex interrelationships on the assay as well as on the device side compared to other homogeneous, plate reader compatible assays. Hence, for users, it is often difficult to set up an FP assay correctly.For this reason, we describe in this T echnical Note how to set up a Fluorescence Polarization assay on the VICTOR® Nivo™multimode plate reader and provide guidance for protocoloptimization. The VICTOR Nivo is a compact multimode plate reader that provides all detection modes which are routinelyused in drug discovery: Absorbance, Luminescence,Fluorescence Intensity, as well as options for Alpha, Time-Resolved Fluorescence and Fluorescence Polarization. Due toits intuitive control software and small footprint, the platereader fits easily in any lab.For research use only. Not for use in diagnostic procedures.As an example assay, the Predictor™ hERG Fluorescence Polarization Assay2 was used and its principle is shown in Figure 1, where the fluorescently labelled small moleculesof the Predictor™ hERG Tracer Red can either bind to the hERG channel protein in Predictor™ membrane fraction or can rotate freely.Blocking of the hERG potassium channel is known to be a potential off-target activity of drug candidates2,3, that can lead to life-threatening arrhythmias. For this reason, effects on the hERG channel are investigated early in the drug discovery process using various methodologies, one of them being the Fluorescence Polarization assay.VICTOR Nivo Multimode Plate Reader2Figure 2. Plate layout for the instrument setup run on the VICTOR Nivo.Instrument Setup Run for Predictor ™ hERG FP Assay The instrument setup run is a step used to optimize the FP measurement protocol specifically for the Predictor ™ hERGFluorescence Polarization Assay (Invitrogen, # PV5365) with regard to Z-height and G factor . For this experiment, a set of assay controls is needed: Buffer Blank, Assay Blank, Free tracer control, Negative control and Positive control. The controls were prepared according to the assay manual 5 and were transferred in triplicates to a black 384-well assay plate (PerkinElmer , ProxiPlate # 6008260 or OptiPlate # 6007270) at a volume of 20 ul/well (Figure 2).1. Selection of FiltersIn order to set up a FP measurement protocol on the VICTOR Nivo, three filters and a dichroic mirror are needed: a 530/30 nm excitation filter, two 580/20 nm emission filters and a 565 nm dichroic mirror. Alternatively, a 50/50 beam splitter can be used, but assay performance may be impaired. Dedicated polarization filters are not needed as the necessary polarizing components are already located inside the plate reader, if the instrument is equipped with FP technology.2. Z-focus Height OptimizationUsing a free tracer control well (reference polarization control), the Z-focus height optimization was demonstrated for a 384-well ProxiPlate and 384-well OptiPlate. A FP Z-focus scan protocol was set up (excitation at 530 nm, emission at 580 nm) with 20 scan points between 0 and 20 mm (Figure 3). The emission values (either S or P) were plotted in the VICTOR Nivo control software (Figure 4). The plate specific optimal Z-focus height was determined at the emissionintensity maximum. For future FP measurements, this Z-focus height was transferred to the FP endpoint protocol ofthe control software.Figure 1. Assay Principle. If polarized light excites Tracer Red bound to the hERG channel protein, the emission light remains polarized, because the tracer-channel-complex rotates slowly during fluorescent lifetime. In contrast, inhibiting compounds in the ion channel block Tracer Red from binding. In case Tracer Red is replaced in the ion channel by a compound, it rotates quickly during fluorescent lifetime due to its small size. This is leading to highly depolarized emission light, which is detected by the instrument not only in S, but also in P orientation.3Figure 3. Z-focus scan protocol for the plate specific optimization of the Z-focus height.3. G Factor CalculationThe G factor is a correction factor used to compensate for differences in parallel and perpendicular optical components of the measurement device. Calculating the G factor isrecommended, if the true polarization should be determined. Here, it was calculated using the free tracer control wells. In the Predictor ™ hERG FP Assay, this reference control has a known value of 50 mP 5. As a first step, the assay plate was measured once with the FP endpoint protocol including a G factor of 1. The S and P channel results were then used to calculate the G factor using Microsoft Excel according to the following formula:G =S*(1 – )mP (T racer )1000P*(1 + )mP (T racer )1000If the literature polarization value is not known for the used fluorophore, the relative change of polarization values (ΔmP) upon treatment can be plotted to create dose-responsecurves. For this, the G factor does not need to be adjusted and can be kept at 1. T o calculate ΔmP , all resulting mP values of the curve are normalized to an assay relevant sample showing low polarization values such as the free tracer control, positive control or even the lowest compound concentration in this example.As a rule of thumb, G is usually 0.8 < G < 1.2. The assayspecific calculated G factor was inserted in the FP endpoint protocol of the control software and the measurement of the assay plate repeated. The G factor was determined correctly, if the known mP value of the reference control (here 50 mP , see above) is obtained as a result.4Figure 5. Final VICTOR Nivo measurement protocol for the Predictor™ hERG FP assay shown here for 384-well ProxiPlates.Compound Testing in the Predictor ™ hERG FP AssayThe known hERG channel inhibitors Astemizole (Cayman chemical, #16967) and T erfenadine (Cayman chemical, #20305) were tested in 16-point dose response curves in a concentration range of 3.3 µM - 0.2 pM in the FP assay. T o allow data correction in case of unspecific compound effects, both compounds were also tested in the presence of a saturating concentration of the inhibitor E-4031 (30 µM). The plate layout is shown in Figure 6.First, the test compounds were dissolved in DMSO and a 3-fold dilution series was prepared. Afterwards, all samples were diluted 1:25 in assay buffer. Compounds were transferred to the assay plate at a volume of 5 µl/well. The tracer was diluted to 4 nM and 5 µl/well were transferred into the assay. Finally, 10 µl/well of the Predictor™ hERG Membrane were dispensed into a ProxiPlate (PerkinElmer, # 6008260). After 2 hours ofincubation at room temperature, the assay plate was placed in the VICTOR Nivo to run the FP protocol with the measurementsettings shown in Figure 5.Figure 4. Z-focus height optimization was demonstrated in PerkinElmer OptiPlate and ProxiPlate using a FP Z-focus scan protocol (excitation at 530 nm, emission at 580 nm) with 20 scan points between 0 and 20 mm. The emission intensity maximum (red intersecting lines) was determined directly in the VICTOR Nivo software.5Figure 6. Plate layout for Compound Profiling in the Predictor ™ hERG assay. The compounds Astemizole and T erfenadine were tested in 16-point dose response (3.3 µM - 0.2 pM, triplicates per concentration) in the presence and absence of the inhibitor E-4031.ResultsAfter optimizing the FP protocol on the VICTOR Nivo, it was used to measure the assay plate containing controls. As shown in Figure 7, the free tracer control results in 50 mP on average, showing that the G factor has been optimized correctly using the literature value 5. Nevertheless, the actual assay window is the span between the negative (tracer and membrane) and positive control (tracer, membrane and 30 µM E-4031) in these experiments ~100 mP . Comparable results were obtained in the OptiPlate and ProxiPlate at a volume of 20 µl (data not shown). In addition, it can be helpful to look not only at the mP results but also to calculate the total intensity with the formula 2*P+S. For example, background signal (assay blank and buffer blank) is often highly polarized, but the intensities are actually very low. T aking the total intensity into account during data analysis can therefore helpavoid misinterpretation of results.Figure 7. Resulting mP values (left) and total intensity (right) of assay controls in ProxiPlate after protocol optimization on the VICTOR Nivo. For each sample, the mean and standard deviation of three wells are shown.In a subsequent experiment, the known inhibitors T erfenadine and Astemizole were tested in dose response in the FP assay, results are shown in Figure 8. The FP signal was detected 2 hours after incubation. Assay statistics for the two independent experiments are summarized in T able 1. For the calculations,16 positive control wells and 16 negative control wells were used. The Z prime values of 0.73 and 0.87 indicate a robust assayperformance for both experiments.Figure 8. The compounds Astemizole and Terfenadine were tested in dose response experiments. The following IC 50 values were determined: IC 50 (Astemizole)= 0.97 nM and IC 50 (Terfenadine)= 2.8 nM. For comparison, the assay manual 5 reports an IC 50 value of 1.9 nM for Astemizole. For each data point, the mean and standard deviation of three wells are shown.For a complete listing of our global offices, visit /ContactUsCopyright ©2021, PerkinElmer, Inc. All rights reserved. PerkinElmer ® is a registered trademark of PerkinElmer, Inc. All other trademarks are the property of their respective owners.211120 (145315) PKIPerkinElmer, Inc. 940 Winter StreetWaltham, MA 02451 USA P: (800) 762-4000 or (+1) 203-925-4602ConclusionWe demonstrated the steps for FP protocol setup and optimization on the VICTOR Nivo and used the established measurement protocol for testing hERG inhibitors in dose response in two independent experiments. Using the protocol optimization steps described in this technical note, VICTOR Nivo’s simple and flexible software enables users to quickly optimize FP assays. Software features such as the graph view for Z-focus scans and the applied G factor make it easy for users to determine the correctmeasurement height and to directly export the polarization values. Also, the innovative filter wheel with its built-in polarizingcomponents makes it possible to use any Fluorescence Intensity filter combination for FP assays. No dedicated polarization filters are needed, only a second identical emission filter is required. In summary, this demonstrates that its ease of use of FP assays is a valuable addition to the VICTOR Nivo, along with its standard detection technologies.References1. Lea WA, Simeonov A. Fluorescence Polarization assays in small molecule screening. Expert Opin Drug Discov. 2011;6(1):17-32. doi:10.1517/17460441.2011.5373222. Piper DR, Duff SR, Eliason HC, et al. Development of the predictor hERG Fluorescence Polarization assay using a membrane protein enrichment approach. Assay Drug Dev T echnol. 2008;6(2):213-223. doi:10.1089/adt.2008.1373. Birgit Priest, Ian M. Bell & Maria Garcia (2008) Role of hERG potassium channel assays in drug development, Channels, 2:2, 87-93, DOI: 10.4161/chan.2.2.60044. Dierk Thomas, Christoph Karle & Johann Kiehn (2004) Modulation of hERG potassium channel function by drug action, Annals of Medicine, 36:sup1, 41-46, DOI: 10.1080/174313804100325805. Predictor hERG Assay Manual (Rev. date: 28 October 2009, https:///order/catalog/product/PV5365#/PV5365)。

光纤布拉格光栅

光纤布拉格光栅
21
7.3.1 Quasi-Static Strain Monitoring



A lot of schemes used for recovery the wavelength- shift information is required for smart structure application. The most fundamental means for interrogating a FBG relies on broad band illumination of the device. The grating used in sensor applications have bandwidth of 0.05 to 0.3nm.
17
7.3 Wavelength Demodulation of Bragg Grating Point Sensors

For FBG point sensors 1 pm resolution is required to resolve ~ 0.1o C or 1 By OSA+ Tunable laser.
VH n n 2
(7.5)
16
7.3 Wavelength Demodulation of Bragg Grating Point Sensors
7.3.1 Quasi-Static Strain Monitoring 7.3.2 Dynamic Strain Sensing 7.3.3 Simultaneous Interrogation of Bragg Gratings and Interferometric Sensors
2
7.Fiber Bragg Grating Sensors

(完整版)超快光学第02章概述

(完整版)超快光学第02章概述

Inversion
B N2 I > B N1 I
Canceling the BI factors, N2 > N1, or:
DN N1 N2 < 0
This condition is called inversion. It does not occur naturally (it’s forbidden by the Boltzmann distribution). It’s inherently a non-equilibrium state.
Usually, additional losses in intensity occur, such as absorption, scattering, and reflections. In general, the laser will lase if, in a round trip:
Total Gain > Total Loss
Laser medium
Output mirror
Will this intensity be sufficient to achieve inversion, N2 > N1? It’ll depend on the laser medium’s energy level system.
Rate Equations for a Two-Level System
Proportionality constant is the absorption/gain cross-section,
I(z) I(0)exp N2 N1 z
There can be exponential gain or loss in irradiance. Normally, N2 < N1, and there is loss (absorption). But if N2 > N1, there’s gain, and we define the gain, G:

HOTECH高级Cassegrain望远镜激光对齐仪用户操作手册(v5)说明书

HOTECH高级Cassegrain望远镜激光对齐仪用户操作手册(v5)说明书

Instruction SheetADVANCED CT LASER COLLIMATOR for CASSEGRAIN TELESCOPESThank you for purchasing the state-of-the-art HOTECHAdvanced CT Laser Collimator instrument. This instrumentuses the most advanced laser optical technologies achievingexcellent collimation in a very short distance. Collimation is amethod to align your telescope’s optics. The laser collimatormakes the collimation process more efficient and it canincrease collimation accuracy with the guide of theinstrument. Your telescope is aligned at the factory, butharsh handling during shipping can sometimes misaligncollimation. Some telescopes are not well collimated whenshipped. Misaligned collimation can mean decrease ofoptical efficiency thus introduces poor image contrast,astigmatism, and blurry images. The following describeshow to collimate your Cassegrain style telescope with theaid of the Advanced CT Laser Collimator to optimize theoptical efficiency of your telescope.Please read the entire instruction sheet before using your Advanced CT Laser CollimatorBe aware of the following as you use your Laser Collimator:Only turn ON your laser(s) when you are going to use it. Turn ON your laser(s) with adult supervision for collimating the telescope purpose use only. Do not point the laser(s) directly or indirectly via reflected glass or mirror other than your telescope to anyone’s eye. We will demonstrate the laser collimation on a Schmidt Cassegrain Telescope which applies to collimating all Cassegrain style telescopes in the similar way. All lasers on the collimator are class II (<1mW). For additional information, please visit our website, , or write us at .Collimation Basics You Must Know Before You StartWhat to Adjust:The only user accessible alignment component on a Cassegrain Telescope (includes CT, SCT, RC, Maksutov.) is the secondary mirror alignment screws. Therefore, you only need to adjust the three alignment screws located at the front of the telescope behind the secondary mirror (see illustration below). The limited adjustment makes the collimation simple to adjust but difficult to achieve. For ease of manual adjustment, we recommend replacing the stock alignment screws to a larger thumb screws for easier access and finer feel adjustment.How the Collimator Works:The Advanced CT Laser Collimator samples your entire optical system (primary, secondary mirror, and the eyepiece axial position) with a simulated large aperture flat-wavefront light source generated by three parallel lasers positioned behind the target plate. The target plate provides a clear view of the optics’ alignment condition when the three lasers are reflected back on the target (FIG. 1). It is extremely critical that the lasers must point square (co-aligned) with your primary mirror for an accurate reading. It is just like looking at a distant star and centering the star in the eyepiece FOV during a star test, except the star is about 3 feet in front of your telescope.To ensure accurate aiming, you must use the crosshair laser emitting from the center of the collimator as a guide to the center point on your primary mirror (FIG. 2A), and the reflected crosshair from the telescopes primary mirror to the center point of the target (FIG. 2C). Please expect to spend most of the time on iterating the aiming adjustment. Be patient and consistent, the reward is beyond your imagination.How to Adjust Collimation on Your Scope:You can collimate your telescope at almost any position (e.g. telescope 20 deg. up) as long asboth the collimator and the telescope point square at each other. Once the lasers and yourtelescope are co-aligned, adjust the necessary secondary alignment screws gently to move thethree projecting laser dots to line up on the same track on the target plate.Process Flow Chart:1. Setup collimator distance2. Install reflector in eyepiece3. Aim collimator at telescope (FIG. 2A)4. Aim telescope at collimator (FIG. 2C)5. Adjust secondary to bring the three laser dots on the same trackPackage Content:1 x Premium Soft Carrying Case1 x Advanced CT Laser Collimator1 x SCA Reflector Mirror (1.25” or 2”)1 x 3V, CR123 Lithium Battery1 x Paper Ruler1 x External alignment Tab Strap(in bottom layer)3 x Alignment Tabs (in bottom layer)1 x Users Manual (in cover pocket)1.0. Setting Up the Laser Collimator on the Tripod1.1. Where to setup the telescope and the collimatorStation both the collimator and the telescope on a solid ground (no carpeted, wooden floor, or any other surface that will flex or vibrate). It is required to have both stationed on the same ground floor.1.2. Setup the collimator on the tripoda). Fasten the laser collimator on the recommended fine adjustment stage with the threadknob on the mount to the ¼-20 screw hole at bottom of the rail base.b). Further lock the thread knob with the fly wheel lock.c). Use the standard ¼-20 screw on your tripod to fasten the fine adjustment stage.2.0. Getting Familiar with Your Instrument2.1. Installing the batteryUnthread the battery compartment cap then insert the CR123 lithium battery with the positive side up(tip side up) then close the battery cap.2.2. Switching the laser to the proper modePosition the collimator on a tripod about 4 feet distance from a white wall with the target side facingthe wall. Rotate the rotary knob on the top right corner of the collimator to activate different lasermodes. You will see the projecting laser patterns on the wall activating at various positions.Mode 0: Unit off.Mode 1: Crosshair laser ON.Mode 2: Crosshair laser and three alignment lasers ON.Mode 3: Crosshair laser, three alignment lasers, and target backlight ON for night use.Other modes:DT: Three alignment lasers ON.BL: Backlight ON.1L: Crosshair laser and backlight ON.CL: Three alignment lasers and backlight ON.This is a logic switch. Other modes are for visual preferences that will not affect the collimation process. Please use the recommended mode in each procedure for best result.2.3. Gross pointing adjustmentSwitch the laser to Mode 2, lift the tripod and move the collimator with the tripod at variousdistances from the wall to see how the crosshair expands and reduces in size in reference todifferent distances.2.4. Fine adjustment stage adjustmentPlace the tripod with collimator back on the ground. Find and adjust the corresponding knob onthe stage in the following.Vertical Adjustment:- The large knob, on right, is for quick rough adjustment in the vertical direction. You can loosenthe large knob and level the laser first.- The forward small knob is for fine adjustment in the vertical (up/down) direction. You must lockthe large knob first in order to make the fine adjustment with the forward knob.Horizontal Adjustment:- The left side small knob is for fine adjustment in the horizontal (left/right) direction.3.0. Adapting the SCA Reflector Mirror:3.1. Adapting the SCA Reflector Mirror on your focuserIf the purpose of the night is visual observation, you may adapt the SCA Reflector with the diagonal,on the condition that it does not introduce optical aberrations (center of the field is not shifted if thediagonal rotates in the drawtube). However, if photography or CCD imaging is planned, it is best toadapt the SCA Reflector without the diagonal.For an installation video guide of the SCA mechanism, please review our YouTube videos at/hotechusa under Installing and Uninstalling HOTECH SCA Laser Collimator.4.0. Do You Need the External Alignment Tabs?- It is very critical to have the lasers co-aligned with your primary mirror optical axis for an accurate diagnosis of your telescope. To achieve this, you use the projecting crosshair on the collimator to center point your primary mirror byreferencing the 4 corners on the mirror to the crosshair lines. Then you use the reflected crosshair lines projected on the primary mirror to center point back to the target.- The crosshair lines from the collimator are precisely 90 degrees apart. You will have to find or create the 90 degrees markings on or close proximity to your primary mirror for collimator aiming reference.- It is ideal to edge-mark the 4 corners (90 degrees apart) on the primary mirror or the cell holder if it is accessible. For those scopes that do not have accessible open truss configuration, please refer to the following solutions.4.1. Visible components close to the primary cell – no Alignment Tabs neededMost Meade SCT telescopes have at least 4 visible mounting screws at the base of the telescope 90 degrees apart, protrude into the OTA. Identify the position of these 4 screws by looking from the front of your telescope. You will rely on these screwsas your collimator aiming guide. You will not need the external Alignment Tabs for your telescope if the mounting screws arevisible. Please proceed to step 5.0.4.2. No visible components close to the primary cell – require Alignment TabsIf there are no visible markings or objects in close proximity to the primary mirror that are 90 degreesapart, use the included Alignment Tabs as your alternative external aiming guide.4.3. Setting up the Alignment Tabs4.3.1. Measure and mark the 4-corner distance on your OTAa). Use the included paper strip ruler and wrap it onthe OTA closest to the primary mirror position.b). Mark the position where the paper strip interceptsto a full diameter wrap.c). Remove the paper strip. Line up the start of thestrip with the marked position and fold it twice tofind the ¼ length of your OTA diameter. d). Wrap the paper strip back on your OTA, and use amarker or pencil to mark three consecutivepositions 90 degrees apart on your OTA.ab c d 4.3.2. Installing the Alignment Tabsa). Wrap and tighten the black strap around the OTA next to the 3indexed markers on the OTA.b). Insert the base of three Alignment Tabs at the correspondingpre-marked position.c). Pre-adjust the Alignment Tabs to make it tangent to the OTA.A b c4.3.3. Lining up the Alignment Tabs normal to the OTAIt is important to keep the Alignment Tabs tangent to the OTA at eachmarked position for an accurate aiming reference. Use the crosshairlaser on the collimator to help you achieve this step.a). Position the laser collimator at about the same center height of yourtelescope. Switch to Mode 1 to activate the crosshair laser.b). Aim the crosshair directly at the visual back of your telescope toproject the crosshair on the 4-edge marks. Check the reflection ofthe crosshair laser on the target from the SCA reflector and adjustboth pointing of the collimator and the telescope to bring thereflected crosshair back to the center of the target on the collimator.c). Iterate the process until both the projecting crosshair on yourtelescope is on the 4-edge marks and the reflected crosshair is inthe center of the target.d). Adjust the Alignment Tabs to line up with the crosshair to the end ofthe Alignment Tab. This will ensure the tabs are pointingnormal/tangent to the OTA. You will rely on these tabs duringcollimation. Switch to Mode 0 to turn off the laser collimator.a &b b &c b & cd d5.0. Positioning the Laser Collimator at the Proper DistanceThe distance between the laser collimator and yourtelescope varies depending on the diameter and focaldistance of your telescope. In general, the longer thedistance away from your telescope, the higher accuracy youwill achieve. And in practice, any distance beyond the focaldistance will be sufficient for your calibration for both visualand practical adjustment purposes. In this procedure, wewill help you identify the best collimating distance for yourtelescope.5.1. Determine the distance between the laser collimator and your telescopea). Position the collimator in front of the scope to about equal length of the OTAwith the target display facing the telescope (photo above).b). Switch the collimator to Mode 1 (crosshair laser only).c). Roughly aim the crosshair toward the telescope.d). Experiment with the proper distance by slightly lifting the tripod, with thecollimator on it, and move the collimator slowly toward and away from thetelescope while keeping the reflected crosshair on the target plate. Don’t worryabout getting the crosshair perfectly concentric in the center of the target at thispoint. You will see how the crosshair contract and expands in size on the targetplate in relation to the distance adjustments.e). Move the collimator to where the crosshair converges to the smallest size. Thisis the back focal point of the primary mirror. Now begin to move the targettowards the telescope until the crosshair expands to the size of the first ring? onthe target.f). Firmly position the tripod at this distance. This will be your collimating distance.6.0. Achieving Co-Alignment on the Collimator and Your TelescopeThis is the critical stage where you must co-align the collimator and your telescope for an accurate reading of your optics alignment. DO NOT use the center of the secondary mirror assembly as your crosshair centering reference because the secondary mirror might not be center positioned on the corrector plate, and the telescope might not be pointing straight at the collimator at this point. You can use it as a quick gross adjustment, but not for final aiming adjustment.6.1.1. For telescopes using the internal screws as the aiming referencea). Check if the crosshair is visible on the internal screws.b). Aim the crosshair emitting from the collimator on your telescope’s 4-corner referencingedges (the internal screws). Us the fine adjustment stage to refine the collimator aiming.c). Go to step 6.2 (next page).6.1.2. For telescopes using the Alignment Tabs as the aiming referencea). Check if the crosshair is visible on the three tabs.b). Point the crosshair as close to the center of the primary mirror, and wave your hand behindthe Alignment Tabs to find the crosshair. If the crosshair is cropped beyond the tip of thestick, move your collimator further away from the telescope until you can see a portion of thecrosshair projecting on the tip of the Alignment Tabs.c). Us the fine adjustment knob to refine the collimator aiming to line up with the threeAlignment Tabs.6.2. Aim your telescope back to the collimatora). Use the telescope’s fine adjustment knob or the motor remote control to aim the reflectedcrosshair from your telescope back to the center of the target. You will need to line up thevertical and horizontal cropped crosshair lines with the cross line on the target plate. When itpoints square, the vertical and horizontal cropped crosshair lines will have symmetry length.6.3. Co-alignment confirmationIterate step 6.0 until both conditions are met. This means both telescope and the collimator are pointing square at each other like looking at a distant star. Lock your telescope and you are ready to diagnose your optics.7.0. How to Read the Diagnostic Result on the CollimatorWith proper aiming in step 6, the collimator can accurately reveal any errors in your optical system by reading the center deviation of the three returning laser dots on the target plate.7.1. Locate the three laser dotsa). Switch to Mode 2 or Mode 3 (three lasers and the crosshair, or Mode 3 with backlight).b). Verify if the crosshair is still center pointed on both the target plate and the Alignment Tabs or screw markers?.c). Locate the three laser dots on the target plate.d). If the three laser dots are visible on the target plate, go to step 8 to collimate your telescope.e). If the three laser dots are not visible or partially visible on the target plate, please continue to the following possiblescenarios.7.2. The SCA Reflector is not properly adapteda). The SCA Reflector represents the axial alignment of your drawtube (eyepiece holder). You must install it correctly (squarein your drawtube) in order to represent the axial position of your eyepiece or CCD camera position. This axial position of your drawtube is directly related to the alignment axis of your entire optical system (telescope). Please refer to step 3 for proper SCA Reflector installation guide.b). If you have verified the correct installation, and still exhibit the same condition, continue to the next step, otherwise go tostep 8.7.3. The SCA Reflector is not positioned at the focal planea). This can happen if you were initially using the diagonal for viewing, thus the focal plane is at the diagonal extensiondistance. After you remove the diagonal for collimation, without any focusing adjustment, it will move the three laser dots out of the target screen. If you do not use the diagonal, continue to the 7.4.b). Adjust the focus to bring at least two laser dots into the full view of the target plate. Adjust the focus in one direction first tosee if any of the laser dots are moving toward the center direction of the target. If the laser(s) is moving or expanding away from the center of the target, reverse the focusing direction to bring at least two laser dots into the full view of the target plate. Go to step 8 to collimate your telescope.7.4. Your telescope is grossly out of alignmentWhen your telescope is grossly out of alignment, the laser dots may be completely out of the target screen. You may start the collimation process to see if you can bring the three laser dots into the target screen. Proceed to step 8.0.8.0. Collimating Your TelescopeThe main objective in this step is to bring the three laser dots on the same track on the target. You will need to constantly check the crosshair laser (step 6) for both telescope and collimator aiming on each iterated adjustment. Here are few simple precautions you need to follow while adjusting the secondary mirror alignment screws located on the back of the secondary mirror assembly or front center of the telescope.a. Never touch the central screw which holds the secondary mirror.b. The three screws must be turned in moderation, no screw being over-tightened or totally unscrewed.c. When a screw is turned, the other two must be tightened. Never keep more than one screw loose.d. Each turn on the screws must be small. Reference the screw adjustment to the displacement of the three laser dots on the target plate to determine your adjustment level.8.1. Collimate your telescopea). Adjust the alignment screws to bring the three reflected laser dots on the same track on the target.b). If you cannot bring all three laser dots into the target view because the dots are too far apart, adjust the focus to merge thethree laser dots at approximate distance between track 4 & 5. c). Check for proper aiming of the collimator and the telescope in step 6.The telescope might shift in position if you put too much pressure during secondary mirror adjustment. You must doublecheck if you have nudged the telescope pointing out of the co-alignment.d). Iterate step 8.1 until both the three laser dots are on the same track on the target and the aiming of both the collimator andtelescope are still co-aligned.9.0. Verifying and Fine Tuning Your Collimation9.1. Star test to verify the adjustmenta). On your first observing session, star test the telescope to verify the adjustments.The Advanced CT Laser Collimator should bring excellent collimation to your telescope. Minor adjustment might berequired due to temperature variation during a long observing session.b). Use the intra-focal and extra-focal technique with a high magnification eyepiece on a magnitude 0 to 1 star to determinethe result. Fine tune the collimation if necessary. Please refer to the Star Collimation manual for detail. You are ready for observing after final touch up. 10.0. Possible Scenarios if the Laser Collimation Does Not Agree with Star Collimation10.1. Both the collimator and the telescope were not co-aligned during adjustmentIt is possible that during collimation (step 8), the co-alignment of the collimator and the telescope were slightly off causing an incorrect diagnosis. It is very critical to ensure both the collimator and the telescope are co-aligned to simulate the light path entering the telescope.Do not adjust the collimation screws. Go to step 6 to verify the co-alignment of the collimator and the telescope and check if three laser dots still fall on the same track. If both conditions are met, your optical system is in good condition meaning they’re all lined up well on the same optical axis. If not, continue to the next step.10.2. The mirror-flop on your primary mirror focusing mechanism is causing the miscollimationDue to machining tolerances on the primary mirror and improper greasing on the baffle, some telescopes exhibit more mirror-flop then others. A slight loose tolerance will cause major axial alignment deviation. The Advanced CT Laser Collimator is sensitive enough to pick up any deviation in step 6. Prior adjusting the secondary alignment screw, observe the shiftingposition of the three laser dots on the target by making two full turns clockwise on the focus knob, then reverse half turn. The shifting of the laser dots during the reverse turn tells how much mirror flop you have on your focusing mechanism.If the displacement is more than 2 tracks spacing distance, we recommend attaching a higher grade focuser on your visual back for focusing adjustment and leave the built-in focus mechanism untouched.10.3. The eyepiece drawtube or the visual back is not square to your primary mirrorWe recommend replacing a new higher grade eyepiece drawtube or a focuser that has tip/tilt adjustment to correct the axial error. E.g. MoonLite CS model, /cgi-bin/dman.cgi?page=productdetail&plugin=dstore.cgi&product=CS . We have found several older SCT scopes having poorly machined eyepiece/drawtube which is not square to the OTA. This may cause serious problem for imagers where the focal plane are also not parallel to the primary.。

and

and
Mon. Not. R. Astron. Soc. 000, 000{000 (1996)
Printed 11 November 1996
A (MN L TEX style le v1.4)
Is the rapid radio variability seen in PKS 0537-441 due to microlensing ?
Within our own galaxy, microlensing by individual halo stars can amplify the light from stars in the Galactic bulge and the LMC (Paczynski 1986b; Alcock et al. 1995). Due to the low optical depth of microlensing stars in the Galactic halo, such events are rare and tend to be very simple in form. At cosmological distances, however, the action of stars in an intervening galaxy can induce violent uctuations in the observed light curve of a high redshift quasar, resulting in complex variability (Wambsganss 1990). Such variability was rst observed in Q2237+0305, the Einstein Cross Lens (Irwin et al. 1989). Microlensing has also been cited as a source of the residuals seen between the light curves of the Double Quasar, Q0957+561 (Schild and Thomson 1994), and as a mechanism to explain all of quasar variability (Hawkins 1993; Hawkins 1996). Recently, Romero et al. (1995) have analyzed the radio variability seen in the BL Lac object PKS 0537-441. They concluded, from time-scale arguments, that the variability seen in this system is consistent with microlensing by stars in a foreground galaxy. This subject is the focus of this paper. The paper begins with a review of the theory of microlensing, followed by its applicability to BL Lac systems.

类星体3C 446的光变周期分析

类星体3C 446的光变周期分析

类星体3C 446的光变周期分析郭飞;张雄;毕雄伟【摘要】收集了类星体3C446天体1977年到2006年射电波段4.8 GHz的观测数据.通过对数据的处理获得了长期光变曲线,可以从光变曲线看出其活动是剧烈的.并且利用小波分析方法对3C 446的4.8 GHz波段的数据进行了周期分析,研究结果表明,其射电波段的流量周期约为(7.2±1.2)年.通过其长周期得出其黑洞质量为M=0.9×106M⊙.【期刊名称】《天文研究与技术-国家天文台台刊》【年(卷),期】2013(010)004【总页数】4页(P329-332)【关键词】小波分析方法;周期;光变;射电流量;类星体3C446【作者】郭飞;张雄;毕雄伟【作者单位】云南师范大学物理与电子信息学院,云南昆明650500;云南师范大学物理与电子信息学院,云南昆明650500;云南红河学院理学院,云南蒙自661100【正文语种】中文【中图分类】P158活动星系是一类特殊的星系,其上存在着猛烈的活动现象或剧烈的物理过程[1]。

观测和研究其光变周期是获得天体各种特性的一个重要方法[2]。

天体的长周期特征可以帮助我们研究其轨道和转动[3]。

轨道和转动可以帮我们研究天体的中心黑洞质量、内部结构、辐射区域等[4]。

对此类天体周期的研究现已有几种常用的方法[5-6],比如结构函数法、离散相关函数法、功率谱、Jurkevich和本文用到的小波分析方法[7-10]。

前面的方法在分析周期时都有一定的限制要求,而天体的实际观测中会受到天气等因数的影响,得到的数据很难满足前面几种方法的要求,所以之前的方法在周期分析中不是特别精准。

小波分析方法是基于傅里叶变换分析非平稳信号周期的方法,但小波分析方法也有和傅里叶变换分析不同的地方。

傅里叶变换分析能获得频域和时域的功率谱[8],功率谱主要分析信号的频域信息,小波方法则分析频域和时域的局部信息。

傅里叶变换将信号分解后再根据正弦函数进行叠加,小波分析是把信息分解后按照小波函数进行叠加。

Progress on all-solid-state deep ultraviolet laser with KBe2BO3F2 crystal

Progress on all-solid-state deep ultraviolet laser with KBe2BO3F2 crystal

Progress on All Solid State Deep-ultraviolet Laser withKBe2BO3F2 CrystalQinjun PENG,1 Xiaoyang WANG, 2 Yong ZHOU, 1 Yong ZHU,2 Chengming LI,1 Zhanggui HU,2 Dafu CUI,1 Chuangtian CHEN,2 and Zuyan XU11Laboratory of Optical Physics, Institute of Physics, Chinese Academy of Sciences, P.O. Box 603,Beijing 100080, China,2Beijing Center for Crystal R&D, Technical Institute of Physics and Chemistry, Chinese Academy ofSciences, P.O. Box 2711, Beijing 100080, China(Received January 25, 2008)General review for the progress on all solid state deep ultraviolet (DUV) laser with aKBe2BO3F2 (KBBF) crystal was given in the paper. The frequency-conversion characteristicsof KBBF crystal and the comparison between this crystal and other borate nonlinear opticalcrystals were simply described. A special prism coupling technique (PCT) for DUV lasergeneration and some excellent experimental results from the application of this crystal werecommented. At last, we believe that the output power and conversion efficiency could begreatly increased in the future if the thicker KBBF crystal with good optical quality is grownand the application technique of solid state DUV laser is further developed.Key Words: DUV, KBBF, Solid state laser, Nonlinear optics, SHG1. IntroductionDeep ultraviolet (DUV) sources can be applied to many areas, such as semiconductor photolithography, micro-machining, laser spectroscopy, photoemission spectroscopy and photochemical synthesis.1) The DUV sources can be synchrotron light sources, gas-discharge sources or laser sources. Synchrotrons offer unparalleled flexibility in wavelength tenability (1-1000eV), but they cause low energy resolution (10 meV) and small photon flux (1012-1013 photons/Second). Although gas-discharge sources offers better energy resolution (1.2 meV), it has drawbacks like large beam size (2~3 mm) and small photon flux (1012 photons/second). The DUV lasers, including the excimer laser, solid state laser and so on, are highly desirable for many applications. The excimer lasers can emit coherent light with a high average power output, however, their wavelength tunability and beam quality were poor. So, the compact, efficient solid-state lasers are more attractive, because of their narrower spectral bandwidth, better beam quality and easier maintenance etc. In the past, the solid state DUV lasers are generated by use of sum-frequency method, however, the need for two beams which are one short wavelength and the other long wavelength can be an inconvenience. So far, only KBe2BO3F2 (KBBF) crystals can be used to achieve the DUV laser light through second harmonic generation (SHG). Similarly, the shorter wavelength can be also obtained by the sum-frequency generation (SFG) method in KBBF crystal. In the report, we made a general review for the progress on high power and high efficient DUV laser with a KBBF crystal.2. Characteristics of KBBF CrystalKBBF crystal 2) was first synthesized by the former Soviet Union scientists in 1968. The crystal structure was re-determined by C. Chen, and the results showed that KBBF crystallizes in the space group R32 (not C2). KBBF is an excellent nonlinear optical (NLO) crystal with relatively larger SHG coefficients, wide transparent region from 152 to 3664 nm, moderate birefringence, out of hygroscopy, good optical uniformity with δn ≈ 10−4 /cm, high damage threshold as high as 4×1012W/cm2 at 532 nm with 7-ns pulse width and 10 Hz, high thermal conductivity of ~2.5W/mK, a wide band gap of ~8.2 eV. The melting point of KBBF is estimated to be above 1100C and it volatilizes severely and decomposes above 800C. Therefore, KBBF crystals is mainly grown from a flux melt, not hydrothermal method above 800 0C. Crystals showed a plate-like growth habit due to layered structure of KBBF. At present, KBBF can be grown with its thickness restricted to 3 mm only,the length along the z axis has not exceeded 2.5mm till now. Although the hydrothermal method below 750 0C condition can be used to grow the large size KBBF of ~10mm, the Phi degree was confusable at present. The plate-like crystals were still too thin to be cut along the phase-matching direction. A special prism coupling technique (PCT) 3) was invented to solve the question in cutting the crystal. The invention was a sandwich structure and KBBF crystal is placed in between two prisms (UV fused silica or CaF2 crystal). The two interfaces between the KBBF and CaF2 (or fused silica) were brought into optical contact for reducing the interface losses of the laser beam, or the interfaces were filled with matching oil or deionized water. When the fundamental wave is input along the normal direction of the prism, the angle of refraction in KBBF is equal to the apex angle of the prism. The phase matching of the wavelength can be automatically achieved in KBBF when the special fundamental wave is input along the normal direction and the polarization direction of the fundamental wave is along the aaxis of KBBF, if the apex angle of the prism is equal to the phase-matching angle of KBBF at a special wavelength. It can be seen that this crystal can produce very short wavelength from second to harmonic output from the above narration. The KBBF-PCT setup and the transmittance of KBBF device were shown in Fig. 1 and 2, respectively.3. All Solid State DUV Laser Generation3.1 Phase Matching of KBBF and Other Borate Crystals 3) So far, only KBBF crystal can be use to obtain the DUV laser below 200nm by the SHG generation from Fig 3. Inaddition, although some crystals such as LBO, BBO, CLBO, CBO, SBBO, TBO, KABO, BABO, KB5 etc, also can generate the DUV through SFG technique, at present, the obtained wavelength is shortest in DUV region by KBBF SFG technique.The birefringence of LBO is only about 0.045, which is too small to achieve deep-UV harmonic generation. The same situation also occurs in the other borate crystals of the LBO family such as CBO and CLBO. It is known that even though CBO, CLBO KB5 can achieve DUV output, two different wavelength beams must be included as input, which is obviously not convenient for practical applications. From Fig. 3, we immediately knew that the capability of BBO to produce the DUV coherent light below 200 nm was limited by the absorption edge (189 nm). The SBBO structure has macroscopic order but microscopic disorder, which could be a reason why the optical uniformity of SBBO is very poor. As a result, the phase-matching angles of the crystal at the different wavelengths cannot be determined accurately till now, which heavily limits its applications in various frequency-conversion devices. TBO crystal seems to have the same structure problem as SBBO. Conversely, the space structure of KABO can be determined exactly, so high optical quality crystals of KABO in large size can be grown. KABO can also achieve fourth and fifth-harmonic generation of a Nd:Y AG laser and 193-nm wavelength output with sum-frequency generation. In addition, this crystal is not hygroscopic and has good mechanical properties for cutting, polishing, and coating. Therefore, KABO is a good potential UV and deep-UV NLOcrystal, and further research is deserved. The BABO crystalFig.1 Scheme of the KBBF-PCT and the optical contactprism-coupled setup.Fig.3 SHG and SFG limit for some typical borate crystalsFig.2 Curves A, B, C, and D represent the transmissionspectra of KBBF crystal plus two CaF 2 prisms, a single CaF 2 prism, two CaF 2 prisms, and a single KBBF crystal, respectivelyshould have the same optical properties as KABO, but a crystal large enough have not been yet obtained to measure its linear and nonlinear optical properties.3.2 DUV Laser Generation in Typical Borate Crystals3)LBO was used to generate the DUV in the range of 172.7-187 nm by phase-matched sum-frequency mixing of the Ti:sapphire's (1kHz 0.3mJ, 740-850 nm, 150-200fs) fourth harmonic (ω+3ω) and a parametrically generated infrared pulse which was generate by an optical parametric generator/amplifier scheme with the same Ti:sapphire laser as the pump source.4) A similar experimental setup as LBO was used to generate the DUV from 172 down to 166nm in a KB5 crystal.5) In addition, the KB5 was the first borate crystal to achieve 194-nm coherent light output with the sum-frequency mixing method (792nm+515nm→194nm). 177.4nm DUV laser in KB5 was provided by the harmonic generation of a Nd:YAG laser (ω+5ω). BBO crystal was the first borate crystal which obtained the 193nm effective output by the SFG of a linearly polarized picosecond KrF excimer laser at 248.5nm and a a tunable dye laser at 950–800 nm. Recently, The fourth-harmonic generation (ω+3ω) of a Ti:sapphire laser in BBO was used to obtained 22-mW power output at 193.5 nm. Using the same method in CBO, 193.3nm was obtained the effective output. Also, CBO was used to generate 193-nm coherent light output through a sum-frequency mixing process (2.0um+213nm to193 nm),meanwhile, over 5mJ/pulse energy has been obtained. CLBO crystal was used to generate 193nm output though an eighth-harmonic generation (ω+7ω process) of an Er-doped fiber amplifier system. Thereinto, the 2ω, 3ω, and 4ω harmonics were produced in LBO crystal, BBO was used to SFG (3ω+ 4ω) for 7ω generation. KABO crystal can generate 193 nm with a SFG procedure (1064 nm+236 nm to 193.2 nm).3.3 DUV Generation in KBBF CrystalIn order to produce wavelengths below 200 nm, only KBBF so far has enough birefringence and sufficient transparency range to achieve directly fourth or fifth-harmonic generation of a Ti: sapphire laser. It also can be used to generate the fourth harmonic of the entire tunable spectral region of the Ti: sapphire laser. The crystal can further achieve sixth-harmonic generation of a Nd:YVO4 (or Nd:YAG) laser (3ω+3ωprocedure) to produce 177.3-nm coherent light output. The shortest SHG wavelength of KBBF is 162 nm and the shortest theoretical SHG wavelength obtained experimentally so far is 170 nm.6) In addition, at present, the shortest wavelength has been obtained by SFG in KBBF crystal.In 2007, our lab 7) employ a frequency-tripled Nd:YVO4 laser with a passive-mode-locking technique based on a saturable Bragg reflector as the pumping source of a 2.1mm thick KBBF-PCT with a phase matching angle of 68.6 degree, the high power sixth harmonic generation (3ω+3ω)of an Nd:YVO4 laser is obtained at 177.3nm. For the input power of 3.5 W, the maximum output power is 12.9mW in a hermetic chamber filled with N2, and this is the highest output power ever obtained in deep ultraviolet region by means of the direct harmonic generation. Moreover, the output power is not saturated yet and higher power should be obtained if more power density at 355 nm is applied. The experimental setup and the power curve are shown in Fig. 4. Also, in our lab,7) the fourth harmonic generation of a Ti: sapphire laser system (150fs) at wavelength 200 nm with a high conversion efficiency of 26.1% has been also obtained using the KBBF-PCT with a KBBF size of 10.5×6×2.3mm3 and a phase matching angle of 55 degree. The maximum output at 200nm is 10.7mW when the input power at 400nm is 40.9mW. This is the highest conversion efficiency ever obtained in deep ultraviolet region with KBBF-CaF2 prism-coupled device. Meantime, the conversion efficiency is not saturated yet and higher conversion efficiency could be obtained if higher power intensity at 400 nm is applied. During the experiment, no damage is found in either KBBF or CaF2 prisms. The conversion efficiency curve is shown in Fig. 5.Our lab7) has developed a ns widely tunable t DUV laser in the wavelength range from 175 to 210nm by the fourthharmonic generation of Ti:Sapphire laser with KBBF crystal.Fig.5 The conversion efficiency curve.Fig.4 The experiment setup for 12.9mW at 177.3nm and the output power and in power curse.The highest output power is 2.23mW at 193nm and the power of the DUV laser is more than 2mW from 185nm to 200nm. It is the first demonstration of mW-level ns continuously tunable DUV all-solid-state laser in such a wide wavelength range. The experimental setup and tunable curve are shown in Fig. 6. The output power of Ti:Sapphire laser is more than 3W during the whole tuning range from 690 to 840nm. At the maximum output power at 780nm, the beam quality factor is M2~3. The bandwidth (FWHM) is less than 2nm and the pulse width (FWHM) is 24ns.Tunable UV output power higher than 1.5W in most tuning range is achieved by this walk-off compensated double BBO configuration. Phase-matching angle of KBBF in type-I SHG changes from 68.3o to 48.9o with fundamental wavelength from 345 to 420nm. Two KBBF PCT devices with thicknesses of 0.65mm and 0.69mm along Z axis are used in the wide tunable DUV light generation for the large difference of phase matching angles. One PCT (PCT1) device with KBBF cut at θ=66.4°is best suited for frequency doubling of 354.7nm beam to 177.3nm. The other KBBF PCT device (PCT2) with KBBF cut at θ=56.4°is optimized for producing 193nm light.Cooperation with Tokyo university8), an important progress, over 350mW DUV laser at 193nm and a stable power of 150mW are obtained by KBBF crystal, and this is a highest result at 193nm by use of the borate crystals. The KBBF–CaF2 PCT device was also used to generate the fifth harmonic (from 157 to 160 nm) of a Ti:sapphire laser system at 1-kHz repetition rate and 16-ns pulse width at 800–785 nm wavelength range. This process was achieved by sum-frequency mixing of the fourth harmonic with the fundamental (4ω+ω→5ω). The 5ωspectral width is estimated to be 0.01 pm and the pulse width was 9.7 ns at 157.6 nm. The output power decreased around 158–159 nm, as shown in Fig. 7, but the reason for this is not clear.4. Conclusions and AcknowledgementsThe DUV laser generation in our lab and Tokyo university has obtained great progress in KBBF crystal. The merits of KBBF have been demonstrated through these good results. At last, we believe that the output power and conversion efficiency can be greatly increased in the future if the thicker KBBF crystal with good optical quality is grown and the application technique of KBBF crystal is further developed. In addition, BPO crystal9) whose characteristics are currently still under investigation has a large transparent range from 130 to 4300nm and its birefringence index is 0.0045. It may be a promising NLO material candidate as DUV laser generation. This work was supported by the State Key Program for Basic Research of China, the National High Technology Research and Development Program of China, the National Natural Science Foundation of China, and the Knowledge Innovation program of Chinese Academy of Sciences.References1) J. D. Koralek, J. F. Douglas,N. C. Plumb,Z. Sun,A.V. Fedorov,M. M. Murnane,H. C. Kapteyn,S. T. Cundiff,Y. Aiura,K. Oka,H. Eisaki,and D. S. Dessau: Phys. Rew. Lett. 96 (2006) 017005.2) DY Tang, YN Xia1, BC Wu, C Chen. J. .Crystal Growth. 222 (2001) 125; ZG Hu, M.Yoshimurab, Y. Morib, T. Sasakib: J. .Crystal Growth. 275 (2005) 232.3) C. Chen, Z. Lin, Z.Wang: Appl. Phys. B. 80 (2005) 1–25. C. Chen: Opt. Mater. 26 (2004) 425.4) F. Seifert, J. Ringling, F. Noack, V. Petrov, and 0. Kittelmann: Opt. Lett. 19 (1994) 1538.5) V. Petrov, F. Rotermund and F. Noack: Electron. Lett. 34 (1998) 1748.6) T. Togashi, T. Kanai, T. Sekikawa, S. Watanabe, C.T. Chen, C.Q. Zhang, Z.Y. Xu, J.Y. Wang: Opt. Lett. 28 (2003) 254.7) G.L Wang et. al: submitted to Appl. Phys. B. G.L. Wang, et.al submitted to Appl. Opt. HB. Zhang et. al: submitted to Appl.Phys. Lett.8) T. Kanai, T. Kanda, T. Sekikawa, S. Watanabe, T. Togashi, C.T. Chen, C.Q. Zhang, Z.Y. Xu, J.Y. Wang: J. Opt. Soc. Am. B. 21 (2004) 370.9) Z.H. Li, Z.S. Lin, Y.C. Wu, P.Z. Fu, Z.Z. Wang, C. Chen: Chem. Mater. 16 (2004) 2906.Fig.6 The experiment setup for tunable DUV laser and thetunable wavelength curve.Fig.7 The tunable curve.。

单分子综述-NATURE NANOTECHNOLOGY-Single-molecule junctions beyond electronic transport-2013

单分子综述-NATURE NANOTECHNOLOGY-Single-molecule junctions beyond electronic transport-2013

Stimulated by the initial proposal that molecules could be used as the functional building blocks in electronic devices 1, researchers around the world have been probing transport phenomena at the single-molecule level both experimentally and theoretically 2–11. Recent experimental advances include the demonstration of conductance switching 12–16, rectification 17–21, and illustrations on how quantum interference effects 22–26 play a critical role in the electronic properties of single metal–molecule–metal junctions. The focus of these experiments has been to both provide a fundamental understanding of transport phenomena in nanoscale devices as well as to demonstrate the engineering of functionality from rational chemical design in single-molecule junctions. Although so far there are no ‘molecular electronics’ devices manufactured commercially, basic research in this area has advanced significantly. Specifically, the drive to create functional molecular devices has pushed the frontiers of both measurement capabilities and our fundamental understanding of varied physi-cal phenomena at the single-molecule level, including mechan-ics, thermoelectrics, optoelectronics and spintronics in addition to electronic transport characterizations. Metal–molecule–metal junctions thus represent a powerful template for understanding and controlling these physical and chemical properties at the atomic- and molecular-length scales. I n this realm, molecular devices have atomically defined precision that is beyond what is achievable at present with quantum dots. Combined with the vast toolkit afforded by rational molecular design 27, these techniques hold a significant promise towards the development of actual devices that can transduce a variety of physical stimuli, beyond their proposed utility as electronic elements 28.n this Review we discuss recent measurements of physi-cal properties of single metal–molecule–metal junctions that go beyond electronic transport characterizations (Fig. 1). We present insights into experimental investigations of single-molecule junc-tions under different stimuli: mechanical force, optical illumina-tion and thermal gradients. We then review recent progress in spin- and quantum interference-based phenomena in molecular devices. I n what follows, we discuss the emerging experimentalSingle-molecule junctions beyond electronic transportSriharsha V. Aradhya and Latha Venkataraman*The id ea of using ind ivid ual molecules as active electronic components provid ed the impetus to d evelop a variety of experimental platforms to probe their electronic transport properties. Among these, single-molecule junctions in a metal–molecule–metal motif have contributed significantly to our fundamental understanding of the principles required to realize molecular-scale electronic components from resistive wires to reversible switches. The success of these techniques and the growing interest of other disciplines in single-molecule-level characterization are prompting new approaches to investigate metal–molecule–metal junctions with multiple probes. Going beyond electronic transport characterization, these new studies are highlighting both the fundamental and applied aspects of mechanical, optical and thermoelectric properties at the atomic and molecular scales. Furthermore, experimental demonstrations of quantum interference and manipulation of electronic and nuclear spins in single-molecule circuits are heralding new device concepts with no classical analogues. In this Review, we present the emerging methods being used to interrogate multiple properties in single molecule-based devices, detail how these measurements have advanced our understanding of the structure–function relationships in molecular junctions, and discuss the potential for future research and applications.methods, focusing on the scientific significance of investigations enabled by these methods, and their potential for future scientific and technological progress. The details and comparisons of the dif-ferent experimental platforms used for electronic transport char-acterization of single-molecule junctions can be found in ref. 29. Together, these varied investigations underscore the importance of single-molecule junctions in current and future research aimed at understanding and controlling a variety of physical interactions at the atomic- and molecular-length scale.Structure–function correlations using mechanicsMeasurements of electronic properties of nanoscale and molecu-lar junctions do not, in general, provide direct structural informa-tion about the junction. Direct imaging with atomic resolution as demonstrated by Ohnishi et al.30 for monoatomic Au wires can be used to correlate structure with electronic properties, however this has not proved feasible for investigating metal–molecule–metal junctions in which carbon-based organic molecules are used. Simultaneous mechanical and electronic measurements provide an alternate method to address questions relating to the struc-ture of atomic-size junctions 31. Specifically, the measurements of forces across single metal–molecule–metal junctions and of metal point contacts provide independent mechanical information, which can be used to: (1) relate junction structure to conduct-ance, (2) quantify bonding at the molecular scale, and (3) provide a mechanical ‘knob’ that can be used to control transport through nanoscale devices. The first simultaneous measurements of force and conductance in nanoscale junctions were carried out for Au point contacts by Rubio et al.32, where it was shown that the force data was unambiguously correlated to the quantized changes in conductance. Using a conducting atomic force microscope (AFM) set-up, Tao and coworkers 33 demonstrated simultaneous force and conductance measurements on Au metal–molecule–metal junc-tions; these experiments were performed at room temperature in a solution of molecules, analogous to the scanning tunnelling microscope (STM)-based break-junction scheme 8 that has now been widely adopted to perform conductance measurements.Department of Applied Physics and Applied Mathematics, Columbia University, New York, New York 10027, USA. *e-mail: lv2117@DOI: 10.1038/NNANO.2013.91These initial experiments relied on the so-called static mode of AFM-based force spectroscopy, where the force on the canti-lever is monitored as a function of junction elongation. I n this method the deflection of the AFM cantilever is directly related to the force on the junction by Hooke’s law (force = cantilever stiff-ness × cantilever deflection). Concurrently, advances in dynamic force spectroscopy — particularly the introduction of the ‘q-Plus’ configuration 34 that utilizes a very stiff tuning fork as a force sen-sor — are enabling high-resolution measurements of atomic-size junctions. In this technique, the frequency shift of an AFM cantilever under forced near-resonance oscillation is measuredas a function of junction elongation. This frequency shift can be related to the gradient of the tip–sample force. The underlying advantage of this approach is that frequency-domain measure-ments of high-Q resonators is significantly easier to carry out with high precision. However, in contrast to the static mode, recover-ing the junction force from frequency shifts — especially in the presence of dissipation and dynamic structural changes during junction elongation experiments — is non-trivial and a detailed understanding remains to be developed 35.The most basic information that can be determined throughsimultaneous measurement of force and conductance in metalThermoelectricsSpintronics andMechanicsOptoelectronicsHotColdFigure 1 | Probing multiple properties of single-molecule junctions. phenomena in addition to demonstrations of quantum mechanical spin- and interference-dependent transport concepts for which there are no analogues in conventional electronics.contacts is the relation between the measured current and force. An experimental study by Ternes et al.36 attempted to resolve a long-standing theoretical prediction 37 that indicated that both the tunnelling current and force between two atomic-scale metal contacts scale similarly with distance (recently revisited by Jelinek et al.38). Using the dynamic force microscopy technique, Ternes et al. effectively probed the interplay between short-range forces and conductance under ultrahigh-vacuum conditions at liquid helium temperatures. As illustrated in Fig. 2a, the tunnel-ling current through the gap between the metallic AFM probe and the substrate, and the force on the cantilever were recorded, and both were found to decay exponentially with increasing distance with nearly the same decay constant. Although an exponential decay in current with distance is easily explained by considering an orbital overlap of the tip and sample wavefunctions through a tunnel barrier using Simmons’ model 39, the exponential decay in the short-range forces indicated that perhaps the same orbital controlled the interatomic short-range forces (Fig. 2b).Using such dynamic force microscopy techniques, research-ers have also studied, under ultrahigh-vacuum conditions, forces and conductance across junctions with diatomic adsorbates such as CO (refs 40,41) and more recently with fullerenes 42, address-ing the interplay between electronic transport, binding ener-getics and structural evolution. I n one such experiment, Tautz and coworkers 43 have demonstrated simultaneous conduct-ance and stiffness measurements during the lifting of a PTCDA (3,4,9,10-perylene-tetracarboxylicacid-dianhydride) molecule from a Ag(111) substrate using the dynamic mode method with an Ag-covered tungsten AFM tip. The authors were able to follow the lifting process (Fig. 2c,d) monitoring the junction stiffness as the molecule was peeled off the surface to yield a vertically bound molecule, which could also be characterized electronically to determine the conductance through the vertical metal–molecule–metal junction with an idealized geometry. These measurements were supported by force field-based model calculations (Fig. 2c and dashed black line in Fig. 2d), presenting a way to correlate local geometry to the electronic transport.Extending the work from metal point contacts, ambient meas-urements of force and conductance across single-molecule junc-tions have been carried out using the static AFM mode 33. These measurements allow correlation of the bond rupture forces with the chemistry of the linker group and molecular backbone. Single-molecule junctions are formed between a Au-metal sub-strate and a Au-coated cantilever in an environment of molecules. Measurements of current through the junction under an applied bias determine conductance, while simultaneous measurements of cantilever deflection relate to the force applied across the junction as shown in Fig. 2e. Although measurements of current throughzF zyxCantileverIVabConductance G (G 0)1 2 3Tip–sample distance d (Å)S h o r t -r a n g e f o r c e F z (n N )10−310−210−11110−110−210−3e10−410−210C o n d u c t a n c e (G 0)Displacement86420Force (nN)0.5 nm420−2F o r c e (n N )−0.4−0.200.20.4Displacement (nm)SSfIncreasing rupture forcegc(iv)(i)(iii)(ii)Low HighCounts d9630−3d F /d z (n N n m −1)(i)(iv)(iii)(ii)A p p r o a chL i ft i n g110−210−4G (2e 2/h )2051510z (Å)H 2NNH 2H 2NNH 2NNFigure 2 | Simultaneous measurements of electronic transport and mechanics. a , A conducting AFM set-up with a stiff probe (shown schematically) enabled the atomic-resolution imaging of a Pt adsorbate on a Pt(111) surface (tan colour topography), before the simultaneous measurement of interatomic forces and currents. F z , short-range force. b , Semilogarithmic plot of tunnelling conductance and F z measured over the Pt atom. A similar decay constant for current and force as a function of interatomic distance is seen. The blue dashed lines are exponential fits to the data. c , Structural snapshots showing a molecular mechanics simulation of a PTCDA molecule held between a Ag substrate and tip (read right to left). It shows the evolution of the Ag–PTCDA–Ag molecular junction as a function of tip–surface distance. d , Upper panel shows experimental stiffness (d F /d z ) measurements during the lifting process performed with a conducting AFM. The calculated values from the simulation are overlaid (dashed black line). Lower panel shows simultaneously measured conductance (G ). e , Simultaneously measured conductance (red) and force (blue) measurements showing evolution of a molecular junction as a function of junction elongation. A Au point contact is first formed, followed by the formation of a single-molecule junction, which then ruptures on further elongation. f , A two-dimensional histogram of thousands of single-molecule junctionrupture events (for 1,4-bis(methyl sulphide) butane; inset), constructed by redefining the rupture location as the zero displacement point. The most frequently measured rupture force is the drop in force (shown by the double-headed arrow) at the rupture location in the statistically averaged force trace (overlaid black curve). g , Beyond the expected dependence on the terminal group, the rupture force is also sensitive to the molecular backbone, highlighting the interplay between chemical structure and mechanics. In the case of nitrogen-terminated molecules, rupture force increases fromaromatic amines to aliphatic amines and the highest rupture force is for molecules with pyridyl moieties. Figure reproduced with permission from: a ,b , ref. 36, © 2011 APS; c ,d , ref. 43, © 2011 APS.DOI: 10.1038/NNANO.2013.91such junctions are easily accomplished using standard instru-mentation, measurements of forces with high resolution are not straightforward. This is because a rather stiff cantilever (with a typical spring constant of ~50 N m−1) is typically required to break the Au point contact that is first formed between the tip and sub-strate, before the molecular junctions are created. The force reso-lution is then limited by the smallest deflection of the cantilever that can be measured. With a custom-designed system24 our group has achieved a cantilever displacement resolution of ~2 pm (com-pare with Au atomic diameter of ~280 pm) using an optical detec-tion scheme, allowing the force noise floor of the AFM set-up to be as low as 0.1 nN even with these stiff cantilevers (Fig. 2e). With this system, and a novel analysis technique using two-dimensional force–displacement histograms as illustrated in Fig. 2f, we have been able to systematically probe the influence of the chemical linker group44,45 and the molecular backbone46 on single-molecule junction rupture force as illustrated in Fig. 2g.Significant future opportunities with force measurements exist for investigations that go beyond characterizations of the junc-tion rupture force. In two independent reports, one by our group47 and another by Wagner et al.48, force measurements were used to quantitatively measure the contribution of van der Waals interac-tions at the single-molecule level. Wagner et al. used the stiffness data from the lifting of PTCDA molecules on a Au(111) surface, and fitted it to the stiffness calculated from model potentials to estimate the contribution of the various interactions between the molecule and the surface48. By measuring force and conductance across single 4,4’-bipyridine molecules attached to Au electrodes, we were able to directly quantify the contribution of van der Waals interactions to single-molecule-junction stiffness and rupture force47. These experimental measurements can help benchmark the several theoretical frameworks currently under development aiming to reliably capture van der Waals interactions at metal/ organic interfaces due to their importance in diverse areas includ-ing catalysis, electronic devices and self-assembly.In most of the experiments mentioned thus far, the measured forces were typically used as a secondary probe of junction prop-erties, instead relying on the junction conductance as the primary signature for the formation of the junction. However, as is the case in large biological molecules49, forces measured across single-mol-ecule junctions can also provide the primary signature, thereby making it possible to characterize non-conducting molecules that nonetheless do form junctions. Furthermore, molecules pos-sess many internal degrees of motion (including vibrations and rotations) that can directly influence the electronic transport50, and the measurement of forces with such molecules can open up new avenues for mechanochemistry51. This potential of using force measurements to elucidate the fundamentals of electronic transport and binding interactions at the single-molecule level is prompting new activity in this area of research52–54. Optoelectronics and optical spectroscopyAddressing optical properties and understanding their influence on electronic transport in individual molecular-scale devices, col-lectively referred to as ‘molecular optoelectronics’, is an area with potentially important applications55. However, the fundamental mismatch between the optical (typically, approximately at the micrometre scale) and molecular-length scales has historically presented a barrier to experimental investigations. The motiva-tions for single-molecule optoelectronic studies are twofold: first, optical spectroscopies (especially Raman spectroscopy) could lead to a significantly better characterization of the local junction structure. The nanostructured metallic electrodes used to real-ize single-molecule junctions are coincidentally some of the best candidates for local field enhancement due to plasmons (coupled excitations of surface electrons and incident photons). This there-fore provides an excellent opportunity for understanding the interaction of plasmons with molecules at the nanoscale. Second, controlling the electronic transport properties using light as an external stimulus has long been sought as an attractive alternative to a molecular-scale field-effect transistor.Two independent groups have recently demonstrated simulta-neous optical and electrical measurements on molecular junctions with the aim of providing structural information using an optical probe. First, Ward et al.56 used Au nanogaps formed by electromi-gration57 to create molecular junctions with a few molecules. They then irradiated these junctions with a laser operating at a wavelength that is close to the plasmon resonance of these Au nanogaps to observe a Raman signal attributable to the molecules58 (Fig. 3a). As shown in Fig. 3b, they observed correlations between the intensity of the Raman features and magnitude of the junction conductance, providing direct evidence that Raman signatures could be used to identify junction structures. They later extended this experimental approach to estimate vibrational and electronic heating in molecu-lar junctions59. For this work, they measured the ratio of the Raman Stokes and anti-Stokes intensities, which were then related to the junction temperature as a function of the applied bias voltage. They found that the anti-Stokes intensity changed with bias voltage while the Stokes intensity remained constant, indicating that the effective temperature of the Raman-active mode was affected by passing cur-rent through the junction60. Interestingly, Ward et al. found that the vibrational mode temperatures exceeded several hundred kelvin, whereas earlier work by Tao and co-workers, who used models for junction rupture derived from biomolecule research, had indicated a much smaller value (~10 K) for electronic heating61. Whether this high temperature determined from the ratio of the anti-Stokes to Stokes intensities indicates that the electronic temperature is also similarly elevated is still being debated55, however, one can definitely conclude that such measurements under a high bias (few hundred millivolts) are clearly in a non-equilibrium transport regime, and much more research needs to be performed to understand the details of electronic heating.Concurrently, Liu et al.62 used the STM-based break-junction technique8 and combined this with Raman spectroscopy to per-form simultaneous conductance and Raman measurements on single-molecule junctions formed between a Au STM tip and a Au(111) substrate. They coupled a laser to a molecular junction as shown in Fig. 3c with a 4,4’-bipyridine molecule bridging the STM tip (top) and the substrate (bottom). Pyridines show clear surface-enhanced Raman signatures on metal58, and 4,4’-bipy-ridine is known to form single-molecule junctions in the STM break-junction set-up8,15. Similar to the study of Ward et al.56, Liu et al.62 found that conducting molecular junctions had a Raman signature that was distinct from the broken molecu-lar junctions. Furthermore, the authors studied the spectra of 4,4’-bipyridine at different bias voltages, ranging from 10 to 800 mV, and reported a reversible splitting of the 1,609 cm–1 peak (Fig. 3d). Because this Raman signature is due to a ring-stretching mode, they interpreted this splitting as arising from the break-ing of the degeneracy between the rings connected to the source and drain electrodes at high biases (Fig. 3c). Innovative experi-ments such as these have demonstrated that there is new physics to be learned through optical probing of molecular junctions, and are initiating further interest in understanding the effect of local structure and vibrational effects on electronic transport63. Experiments that probe electroluminescence — photon emis-sion induced by a tunnelling current — in these types of molec-ular junction can also offer insight into structure–conductance correlations. Ho and co-workers have demonstrated simultaneous measurement of differential conductance and photon emissionDOI: 10.1038/NNANO.2013.91from individual molecules at a submolecular-length scale using an STM 64,65. Instead of depositing molecules directly on a metal sur-face, they used an insulating layer to decouple the molecule from the metal 64,65 (Fig. 3e). This critical factor, combined with the vac-uum gap with the STM tip, ensures that the metal electrodes do not quench the radiated photons, and therefore the emitted photons carry molecular fingerprints. Indeed, the experimental observation of molecular electroluminescence of C 60 monolayers on Au(110) by Berndt et al.66 was later attributed to plasmon-mediated emission of the metallic electrodes, indirectly modulated by the molecule 67. The challenge of finding the correct insulator–molecule combination and performing the experiments at low temperature makes electro-luminescence relatively uncommon compared with the numerous Raman studies; however, progress is being made on both theoretical and experimental fronts to understand and exploit emission pro-cesses in single-molecule junctions 68.Beyond measurements of the Raman spectra of molecular junctions, light could be used to control transport in junctions formed with photochromic molecular backbones that occur in two (or more) stable and optically accessible states. Some common examples include azobenzene derivatives, which occur in a cis or trans form, as well as diarylene compounds that can be switched between a conducting conjugated form and a non-conducting cross-conjugated form 69. Experiments probing the conductance changes in molecular devices formed with such compounds have been reviewed in depth elsewhere 70,71. However, in the single-mol-ecule context, there are relatively few examples of optical modula-tion of conductance. To a large extent, this is due to the fact that although many molecular systems are known to switch reliably in solution, contact to metallic electrodes can dramatically alter switching properties, presenting a significant challenge to experi-ments at the single-molecule level.Two recent experiments have attempted to overcome this chal-lenge and have probed conductance changes in single-molecule junctions while simultaneously illuminating the junctions with visible light 72,73. Battacharyya et al.72 used a porphyrin-C 60 ‘dyad’ molecule deposited on an indium tin oxide (I TO) substrate to demonstrate the light-induced creation of an excited-state mol-ecule with a different conductance. The unconventional transpar-ent ITO electrode was chosen to provide optical access while also acting as a conducting electrode. The porphyrin segment of the molecule was the chromophore, whereas the C 60 segment served as the electron acceptor. The authors found, surprisingly, that the charge-separated molecule had a much longer lifetime on ITO than in solution. I n the break-junction experiments, the illuminated junctions showed a conductance feature that was absent without1 μm Raman shift (cm –1)1,609 cm –1(–)Source 1,609 cm–1Drain (+)Low voltage High voltageMgPNiAl(110)STM tip (Ag)VacuumThin alumina 1.4 1.5 1.6 1.701020 3040200400Photon energy (eV)3.00 V 2.90 V 2.80 V 2.70 V 2.60 V2.55 V 2.50 VP h o t o n c o u n t s (a .u .)888 829 777731Wavelength (nm)Oxideacebd f Raman intensity (CCD counts)1,5001,00050000.40.30.20.10.01,590 cm −11,498 cm −1d I /d V (μA V –1)1,609 cm –11,631 cm–11 μm1 μmTime (s)Figure 3 | Simultaneous studies of optical effects and transport. a , A scanning electron micrograph (left) of an electromigrated Au junction (light contrast) lithographically defined on a Si substrate (darker contrast). The nanoscale gap results in a ‘hot spot’ where Raman signals are enhanced, as seen in the optical image (right). b , Simultaneously measured differential conductance (black, bottom) and amplitudes of two molecular Raman features (blue traces, middle and top) as a function of time in a p-mercaptoaniline junction. c , Schematic representation of a bipyridine junction formed between a Au STM tip and a Au(111) substrate, where the tip enhancement from the atomically sharp STM tip results in a large enhancement of the Raman signal. d , The measured Raman spectra as a function of applied bias indicate breaking of symmetry in the bound molecule. e , Schematic representation of a Mg-porphyrin (MgP) molecule sandwiched between a Ag STM tip and a NiAl(110) substrate. A subnanometre alumina insulating layer is a key factor in measuring the molecular electroluminescence, which would otherwise be overshadowed by the metallic substrate. f , Emission spectra of a single Mg-porphyrin molecule as a function of bias voltage (data is vertically offset for clarity). At high biases, individual vibronic peaks become apparent. The spectra from a bare oxide layer (grey) is shown for reference. Figure reproduced with permission from: a ,b , ref. 56, © 2008 ACS; c ,d , ref. 62, © 2011 NPG; e ,f , ref. 65, © 2008 APS.DOI: 10.1038/NNANO.2013.91light, which the authors assigned to the charge-separated state. In another approach, Lara-Avila et al.73 have reported investigations of a dihydroazulene (DHA)/vinylheptafulvene (VHF) molecule switch, utilizing nanofabricated gaps to perform measurements of Au–DHA–Au single-molecule junctions. Based on the early work by Daub et al.74, DHA was known to switch to VHF under illumina-tion by 353-nm light and switch back to DHA thermally. In three of four devices, the authors observed a conductance increase after irradiating for a period of 10–20 min. In one of those three devices, they also reported reversible switching after a few hours. Although much more detailed studies are needed to establish the reliability of optical single-molecule switches, these experiments provide new platforms to perform in situ investigations of single-molecule con-ductance under illumination.We conclude this section by briefly pointing to the rapid pro-gress occurring in the development of optical probes at the single-molecule scale, which is also motivated by the tremendous interest in plasmonics and nano-optics. As mentioned previously, light can be coupled into nanoscale gaps, overcoming experimental chal-lenges such as local heating. Banerjee et al.75 have exploited these concepts to demonstrate plasmon-induced electrical conduction in a network of Au nanoparticles that form metal–molecule–metal junctions between them (Fig. 3f). Although not a single-molecule measurement, the control of molecular conductance through plas-monic coupling can benefit tremendously from the diverse set of new concepts under development in this area, such as nanofabri-cated transmission lines 76, adiabatic focusing of surface plasmons, electrical excitation of surface plasmons and nanoparticle optical antennas. The convergence of plasmonics and electronics at the fundamental atomic- and molecular-length scales can be expected to provide significant opportunities for new studies of light–mat-ter interaction 77–79.Thermoelectric characterization of single-molecule junctions Understanding the electronic response to heating in a single-mole-cule junction is not only of basic scientific interest; it can have a tech-nological impact by improving our ability to convert wasted heat into usable electricity through the thermoelectric effect, where a temper-ature difference between two sides of a device induces a voltage drop across it. The efficiency of such a device depends on its thermopower (S ; also known as the Seebeck coefficient), its electric and thermal conductivity 80. Strategies for increasing the efficiency of thermoelec-tric devices turned to nanoscale devices a decade ago 81, where one could, in principle, increase the electronic conductivity and ther-mopower while independently minimizing the thermal conductiv-ity 82. This has motivated the need for a fundamental understandingof thermoelectrics at the single-molecule level 83, and in particular, the measurement of the Seebeck coefficient in such junctions. The Seebeck coefficient, S = −(ΔV /ΔT )|I = 0, determines the magnitude of the voltage developed across the junction when a temperature dif-ference ΔT is applied, as illustrated in Fig. 4a; this definition holds both for bulk devices and for single-molecule junctions. If an addi-tional external voltage ΔV exists across the junction, then the cur-rent I through the junction is given by I = G ΔV + GS ΔT where G is the junction conductance 83. Transport through molecular junctions is typically in the coherent regime where conductance, which is pro-portional to the electronic transmission probability, is given by the Landauer formula 84. The Seebeck coefficient at zero applied voltage is then related to the derivative of the transmission probability at the metal Fermi energy (in the off-resonance limit), with, S = −∂E ∂ln( (E ))π2k 2B T E 3ewhere k B is the Boltzmann constant, e is the charge of the electron, T (E ) is the energy-dependent transmission function and E F is the Fermi energy. When the transmission function for the junction takes on a simple Lorentzian form 85, and transport is in the off-resonance limit, the sign of S can be used to deduce the nature of charge carriers in molecular junctions. In such cases, a positive S results from hole transport through the highest occupied molecu-lar orbital (HOMO) whereas a negative S indicates electron trans-port through the lowest unoccupied molecular orbital (LUMO). Much work has been performed on investigating the low-bias con-ductance of molecular junctions using a variety of chemical linker groups 86–89, which, in principle, can change the nature of charge carriers through the junction. Molecular junction thermopower measurements can thus be used to determine the nature of charge carriers, correlating the backbone and linker chemistry with elec-tronic aspects of conduction.Experimental measurements of S and conductance were first reported by Ludoph and Ruitenbeek 90 in Au point contacts at liquid helium temperatures. This work provided a method to carry out thermoelectric measurements on molecular junctions. Reddy et al.91 implemented a similar technique in the STM geome-try to measure S of molecular junctions, although due to electronic limitations, they could not simultaneously measure conductance. They used thiol-terminated oligophenyls with 1-3-benzene units and found a positive S that increased with increasing molecular length (Fig. 4b). These pioneering experiments allowed the iden-tification of hole transport through thiol-terminated molecular junctions, while also introducing a method to quantify S from statistically significant datasets. Following this work, our group measured the thermoelectric current through a molecular junction held under zero external bias voltage to determine S and the con-ductance through the same junction at a finite bias to determine G (ref. 92). Our measurements showed that amine-terminated mol-ecules conduct through the HOMO whereas pyridine-terminatedmolecules conduct through the LUMO (Fig. 4b) in good agree-ment with calculations.S has now been measured on a variety of molecular junctionsdemonstrating both hole and electron transport 91–95. Although the magnitude of S measured for molecular junctions is small, the fact that it can be tuned by changing the molecule makes these experiments interesting from a scientific perspective. Future work on the measurements of the thermal conductance at the molecu-lar level can be expected to establish a relation between chemical structure and the figure of merit, which defines the thermoelec-tric efficiencies of such devices and determines their viability for practical applications.SpintronicsWhereas most of the explorations of metal–molecule–metal junc-tions have been motivated by the quest for the ultimate minia-turization of electronic components, the quantum-mechanical aspects that are inherent to single-molecule junctions are inspir-ing entirely new device concepts with no classical analogues. In this section, we review recent experiments that demonstrate the capability of controlling spin (both electronic and nuclear) in single-molecule devices 96. The early experiments by the groups of McEuen and Ralph 97, and Park 98 in 2002 explored spin-depend-ent transport and the Kondo effect in single-molecule devices, and this topic has recently been reviewed in detail by Scott and Natelson 99. Here, we focus on new types of experiment that are attempting to control the spin state of a molecule or of the elec-trons flowing through the molecular junction. These studies aremotivated by the appeal of miniaturization and coherent trans-port afforded by molecular electronics, combined with the great potential of spintronics to create devices for data storage and quan-tum computation 100. The experimental platforms for conducting DOI: 10.1038/NNANO.2013.91。

Lopsided Galaxies, Weak Interactions and Boosting the Star Formation Rate

Lopsided Galaxies, Weak Interactions and Boosting the Star Formation Rate

a rXiv:as tr o-ph/3109v18Mar2Lopsided Galaxies,Weak Interactions and Boosting the Star Formation Rate Gregory Rudnick,Hans-Walter Rix 1,2,Robert C.Kennicutt,Jr.Steward Observatory,University of Arizona,Tucson AZ 85721ABSTRACT To investigate the link between weak tidal interactions in disk galaxies and the boosting of their recent star formation,we obtain images and spatially integrated spectra (3615˚A ≤λ≤5315˚A )for 40late-type spiral galaxies (Sab-Sbc)with varying degrees of lopsidedness (a dynamical indicator of weak interactions).We quantify lopsidedness as the amplitude ˜A 1 ,of the m =1Fourier component of the azimuthal surface brightness distribution,averaged over a range of radii.The median spectrum of the most lopsided galaxies shows strong evidence for a more prominent young stellar population (i.e.strong Balmer absorption,strong nebular emission,a weak 4000˚A break and a blue continuum)when compared to the median spectrum of the most symmetric galaxies.We compare the young stellar content,quantified by EW (Hδabs )and the strength of the 4000˚A break (D 4000),with lopsidedness and find a 3−4σcorrelation between the two.We also find a 3.2σcorrelation between EW (Hβemission )and ing the evolutionary population synthesis code of Bruzual &Charlot we model the spectra as an “underlying population”and a superimposed “boost population”with the aim of constraining the fractional boost in the SFR averaged over the past 0.5Gyr (the characteristic lifetime of lopsidedness).From the difference in both EW (Hδabs )and thestrength of the 4000˚A break (D 4000)between the most and least symmetric thirds of our sample,we infer that ∼1×109M ⊙of stars are formed over the duration of a lopsided event in addition to the “underlying”SFH (assuming a final galactic stellar mass of 1010M ⊙).This corresponds to a factor of 8increase in the SFR over the past 5×108years.For the nuclear spectra,all of the above correlations except D 4000vs. ˜A 1 are weaker than for the disk,indicating that in lopsided galaxies,the SF boost is not dominated by the nucleus.Subject headings:galaxies:evolution—galaxies:interaction—galaxies:kinematics and dynamics—galaxies:spiral—galaxies:structure—stars:formation1.INTRODUCTIONGalaxies do not live isolated lives,but exist in the tidalfields of their environment. Arp(1966),in his Atlas of Peculiar Galaxies,lay the observational groundwork for the modern study of interacting galaxy systems by identifying many”peculiar”systems,later interpreted as various stages of major galaxy mergers.Strong galaxy-galaxy interactions may dramatically alter the stellar populations(rson&Tinsley1978;Kennicutt et al. 1987;Turner1998;Kennicutt1998),morphology(e.g.Toomre&Toomre1972;Hernquist, Heyl&Spergel1993)and kinematics of galaxies(e.g.Toomre&Toomre1972;Barnes& Hernquist1992)driving evolution along the Hubble sequence.Massive mergers are also capable of funneling gas into the center of galaxies causing nuclear starbursts(Barnes& Hernquist1991;Mihos,Richstone&Bothun1992;Barnes&Hernquist1996)and QSO activity(e.g.Sanders et al.1988).At the present epoch,however,major mergers are fairly rare events(e.g.Kennicutt et al.1987)and their broad evolutionary importance is unclear.Minor mergers and,in general,weak tidal interactions between galaxies occur with much higher frequency than major ones(cey&Cole1993).By weak interactions we mean those which do not destroy the disk of the“target”spiral.Hierarchical structure formation models(e.g.cold dark matter)predict that the merging histories for high mass objects today contained multiple low mass accretion events in their past(cey&Cole 1993).The specific roles which weak interactions play in the evolution of galaxies,however, is uncertain.Weak interactions may cause disk heating(e.g.Toth&Ostriker1992;Quinn, Hernquist&Fullagar1993)and satellite remnants may build up the stellar halo(e.g.Searle &Zinn1978;Johnston,Hernquist&Bolte1996).Kennicutt et al.(1987)studied the relation between interaction strength and star formation by making a comparison between isolated galaxies,close pairs,and galaxies from the Arp Atlas.They found that close pairs have larger values of EW(Hαem),i.e.higher star formation rates(SFR)than isolated galaxies.While pair spacing is weakly correlated with the SFR,they could not determine the specific role of interaction strength on the SFR.Hashimoto et al.(1998)and Allam et al.(1999)both studied the Hubble type specific effects of environment on the SFR in galaxies.They found that the SFR/mass of existing stars was inversely proportional to the local galaxy density.They postulate that the anti-correlation is due partly to gas stripping and due partly to the anti-correlation of the merger cross-section with the galaxy-galaxyvelocity dispersion.There is also evidence that interactions excite nuclear activity.In their close pair and strongly interacting sample Kennicutt et al.(1987)found a strong correlation betweenHαemission in the disk and that in the nucleus.Such a correlation between disk and nuclear emission is supported by theoretical work;Mihos&Hernquist(1994)and Hernquist &Mihos(1995)demonstrated that minor interactions form bar instabilities in the disk which in turn funnel large amounts of gas into the nucleus.The effectiveness of this process is suppressed by the presence of a dense bulge,which prevents bar formation. Due to the numerical expense in computing high resolution N-body/SPH(collisionless particle/smoothed particle hydrodynamics)models,the exact interaction parameters which result in such activity are uncertain.Weak interactions may also manifest themselves as kinematic or structural irregularities. Roughly50%of all spiral galaxies have asymmetric HI profiles and rotation curves(Baldwin, Lynden-Bell&Sancisi1980;Richter&Sancisi1994;Haynes et al.1998).Baldwin et al. (1980)postulated that these asymmetries are caused by weak interactions in the galaxy’s past or by lopsided orbits.Barton et al.(1999)examined the optical rotation curves of a set of observed and simulated interacting disk galaxies.They showed that interactions can cause large scale,time dependent asymmetries in the rotation curves of their sample galaxies.Swaters et al.(1999)studied the kinematic asymmetries present in two galaxies lopsided in their optical and HI distributions.They qualitatively reproduced the kinematic asymmetries by placing closed orbits in mildly lopsided potential.A dynamical indicator of weak interactions may be“lopsidedness.”In the context of this paper(following Rudnick&Rix1998;hereafter RR98),lopsidedness is defined as a bulk asymmetry in the mass distribution of a galactic disk.Surveys for lopsidedness in the stellar light of galaxies werefirst carried out by Rix&Zaritsky(1995;hereafter RZ95) and Zaritsky&Rix(1997;hereafter ZR97).Using near-IR surface photometry of face-on spiral galaxies(spanning all Hubble types)they examined the magnitude of the m=1 azimuthal Fourier component of the I and K-band surface brightness,thus characterizing the global asymmetry of the stellar light.RZ95and ZR97found that a quarter of the galaxies in their sample were significantly ing a larger,magnitude limited sample restricted to early type disks(S0to Sab)and imaged in the R-band,RR98found that the fraction of significantly lopsided early type disks is identical to that for late-type disks.RR98convincingly demonstrated that lopsidedness is not an effect of dust,but is in fact the asymmetric distribution of the light from old stars and hence from the stellar mass in the disk.Some theoretical work has been done in examining long lived m=1modes(Syer&Tremaine1996;Zang&Hohl1978;Sellwood&Merritt1994),little convincing evidence however has been put forth to show that isolated galaxies will form stable m=1modes without external perturbations or significant counter-rotating populations.Without invoking the special cases above,long lived lopsidedness is possible if the disk residesin a lopsided potential.The question remains however:how is a lopsided potential created/maintained?Numerical simulations of hyperbolic encounters between disk galaxies fail to produce m=1modes of amplitude>10%without destroying the pre-existing stellar disk(Naab,T.;private communication).Minor mergers and possibly some weak interactions therefore remain as the most probable cause of lopsidedness(RR98).Recent work has shown that perturbations in the outer halo of a galaxy may be amplified and even transmitted down into the disk(Weinberg1994).Work by Walker,Mihos&Hernquist (1996)and ZR97showed that the type and magnitude of lopsidedness seen in RZ95,ZR97 and RR98is comparable to the result of the accretion of a small satellite,if the mass ratio with the main galaxy is≈1/10.In a preliminary study(i.e.a rigid halo with no dynamical friction)Levine and Sparke(1998)showed that lopsided galaxies may be formed by disks orbiting offcenter and retrograde in aflat-cored,dark matter dominated halo. They postulated that a galaxy may be pushed offcenter by a satellite accretion.Using phase mixing arguments(Baldwin et al.1980;RZ95)and analysis of N-body simulations(Walker et al.1996;ZR97)the lifetime of lopsided features has been estimated at t lop≈1Gyr.That lopsidedness is transient(t lop≪t Hubble)yet common,requires that it must be recurring and therefore lopsidedness may have significant evolutionary consequences.The current paper focuses on the impact that minor mergers(observed as lopsidedness) may have on boosting the SFR and the recent star formation history(SFH)of disk galaxies.For the purpose of this discussion,we will assume that lopsidedness is caused by minor mergers.Regardless of what causes lopsidedness however,the perturbation in the gravitational potential manifestly exists and therefore may affect the gas in the galaxy to such a degree as to boost the SFR.Indeed,ZR97find that lopsidedness is correlated (at≥96%confidence)with the“excess”of blue luminosity(over what is predicted by the Tully-Fisher relation).Modeling the integrated spectral evolution of starbursts using evolutionary population synthesis(EPS)codes has been been well studied(e.g.Couch and Sharples1987;Barger et al.1996;Turner1998)and despite its limitations,is a useful tool in determining the relative SFH over the past1Gyr.The same techniques used to probe the SFH in massive starbursts should also work to probe the recent SFH in the putative mini-bursts which we seek to study.By comparing measured indicators of recent SF(e.g. EW(Hδabs),4000˚A break strength,A star content),to the same indicators derived from the EPS models,we will place limits on the mini-burst mass and duration.We have obtained spatially integrated spectra of a sample of40late type spiral galaxies (Sab-Sbc)of varying degrees of lopsidedness with the intent of using their relative stellar populations(as determined from stellar templatefitting and EPS models)to determine their recent SF histories.Unlike the mass-normalized blue light excess,∆B used in ZR97, our method operates independently of assumptions about a galaxy’s mass,inclination or luminosity.In addition to probing the recent(≤1Gyr)SFH with studies of the stellar continuum we probe the current SFR by measuring the integrated Balmer line emission strengths(e.g.Kennicutt et al.1994).The layout of the paper is as follows.In§2we discuss the sample selection,observations, data reduction and determination of galaxy lopsidedness;In§3we examine our methods for determining the current SFR and recent SFH via the measurement of emission and stellar continuum properties as a function of lopsidedness.The discussion of the significance of these results,including the correlation of the boost parameters with other galaxy characteristics and the impact of our results on previous works(i.e.RZ95,ZR97&RR98)is contained in§4.In§5we present a summary and possible directions for future work.2.THE DATA2.1.Sample SelectionTo build a sample of galaxies with varying degrees of lopsidedness,we imaged a large number of galaxies(N gal≥100)taken from the RC3catalog(De Vaucouleurs et al.1991), selected according to the following criteria:apparent blue magnitude m B≤14,redshift cz≤10,000km/s,axis ratio b/a≥0.64(50◦≤i≤0◦),de Vaucouleurs type ab→bc,and a maximum diameter of4′.The median diameter of the galaxies in our sample was1.8′. The magnitude and redshift limits were chosen to minimize the required exposure times. The axis ratio of the galaxies was constrained because it is hard to measure an azimuthal m=1component in a highly inclined galaxy.Once imaging was obtained and lopsidedness determined for each galaxy(see§2.2.1),we constructed a sample for spectroscopy consisting of40of our imaged galaxies(see Table1).These were selected to give the sample equal numbers of lopsided and symmetric targets.Our sample is partially selected according to Hubble type,and we must explore the effects which morphological evolution induced by lopsidedness may have on our conclusions. Walker et al.(1996)suggested that minor mergers increase bulge size,heat the galactic disk vertically and consume a large fraction of the galaxy’s gas,eventually resulting in a low post-merger SFR.These two effects may drive galaxies towards earlier Hubble typeafter they experience minor mergers.Evolutionary processes such as these however become dominant either after the expected lifetime of lopsidedness(t≥1Gyr),or after repeated merger events(Walker et al.1996).During the interaction itself the irregularity in structure made manifest by lopsidedness as well as the creation of spiral arms via tidal perturbations will temporarily move a galaxy later in Hubble type.This will effectively push lopsided early type disk galaxies into our sample while pushing those of later type out of it.Due to their lower gas masses(Roberts&Haynes1994),early type spirals have less potential for a large absolute increase in their SFR than late types.Small boosts,however,may be easily noticeable against the typically older stellar population of early type disks.The exact interplay of these two effects may bias our measurement of the relation between SFR and lopsidedness.2.2.Observations2.2.1.ImagingOur imaging data were obtained during runs at Steward Observatory’s2.3-m Bokreflector on Kitt Peak(1997November6-7and1998February1-2)and at its61-inch (1.5-m)reflector on Mt.Bigelow(1998May15-18).The CCD pixel scales at the Bokreflector and Bigelow reflector were0.′′4pixel−1withfields of view6.′8×6.′8and3.′4×3.′4 respectively.The median seeing at the2.3-m for the November and February runs were1.′′3 and1.′′5,respectively,while the median seeing at the1.5-m in May was1.′′3.A Nearly-Mould R−bandfilter(λcenter=650nm)was used at the2.3-m and a Kron-Cousins R-bandfilter withλcenter=650nm was used at the1.5-m.The effects of wavelength on observed lopsidedness are discussed in§2.1of RR98,and found not to be critical.To determine the lopsidedness of a galaxy we perform an azimuthal Fourier decomposition of the R-band surface brightness,as in RR98:I(R m,φ)=a o{1+Nj=1a j e−i[j(φj−φo j)]},(1)where for each radius,|a o|(R)is the average intensity and|a1|(R)describes the lopsidedness. We define the luminosity normalized quantities A1≡a1/a0.Instead of A1(R),we use ˜A1(R)(the error corrected value which accounts for the positive definite nature of our measurements and the presence of errors;see RR98for details)as our measure of asymmetry. We calculate the mean asymmetry of each galaxy, ˜A1 (see Table2),from1.5to2.5disk scale lengths using the weighted average described in RR98.2.2.2.SpectroscopySpectra were obtained with the Bollers&Chivens Spectrograph at the2.3-m Bokreflector during the nights,1998March22-25,1998May25-28,and1998June29.We used a400gmm−1in2nd order,blazed at3753˚A,and a2.5′′slit,resulting in a resolution of≈1500and a wavelength range of3600˚A∼<λ∼<5300˚A.This range includes the entire Balmer series redward to Hβ,the4000˚A break,Ca H+K doublet,[O II]λλ3726,3729˚A and [O III]λλ4959,5007˚A.To reduce read noise,the CCD was binned in the spatial direction; on22March we binned by2for a resultant pixel scale of1.67′′pixel−1while on all other nights we binned by4for a pixel scale of3.33′′pixel−1.A CuSO4filter was used to block 1st order light.Aside from using standard stars to calibrate the relative spectral response of the instrument,no absoluteflux calibration was attempted.This was done partly because of the non-photometric conditions of some of our nights and partly due to the independence of our analysis methods on absoluteflux levels.Following Kennicutt(1992),we obtained spatially integrated spectra of the galaxies by repeatedly scanning the slit across the galaxy between−2.5R exp≤x≤2.5R exp.For each galaxy we obtained2exposures of25minutes each.To isolate the disk contributions to the integrated spectra,we also obtained a5minute exposure of the nucleus for each galaxy for later subtraction.2.3.Reduction2.3.1.ImagesThe basic image reduction was carried out with standard IRAF3routines.The total dark current was≤1e−/exposure/pixel and so it was ignored.The images wereflat-fielded with a combination of twilight and smoothed night skyflats.High S/N twilightflats (N≈5)were used to take out small-scale variations and the lower S/N smoothed night skyflats(N≈6)were used to take out large-scale sensitivityfluctuations.The large-scale flat-field quality was determined by measuring variance in the median sky level at the four corners of the images.In all images where the galaxy was small in thefield of view, the images were found to beflattened to better than1%.In some cases,the large size of the galaxies in comparison to thefield of view at the1.5-m telescope precluded such an estimate.Point sources in the images were selected using DAOFIND,and surrounding pixels were excised in the subsequent analysis to a radius where the stellar point spread function declined to the level of the sky.2.3.2.SpectraThe basic spectral reduction was carried out with IRAF routines.The measured dark current from multiple25minute dark exposures was≤2e−/exp/pixel and so was not accounted for.Small-scale variations were removed with a combined series of2min.dome flats.Twilightflats werefit in the spatial direction with a5−7th order cubic spline at several different positions in the spectral direction to construct a map of the slit response as a function of wavelength.Non-linear pixels were interpolated over using a bad pixel mask generated from the ratio between a combined series of2minute and10second domeflats.Removing cosmic rays from spectra without accidently removing emission lines is best automated by using the shape of the spectrum itself in the cleaning process:for a given column(spatial direction),we medianed together the target column with the eight columns on either side to construct a slit profile,I ingχ2minimization,wefit the target column with the the following function:I model(y)=a1I slit(y)+a2y+a3.(2) where the a3term accounts for the sky background.Pixels deviating by more than7σfrom the bestfit are replaced with the value of the bestfit model at that point.Flagged segments larger than the spectral resolution of the instrument were not removed so as to avoid the accidental cleaning of emission lines.This algorithm is very efficient and,once a suitable set of parameters(i.e.N med,threshold)has been chosen,can remove almost all of the cosmic rays on the chip.After cosmic ray removal,the spectra were rectified using He-Ar lamps taken at various times during the night.Background contributions were then subtracted.To extract the spectra,we summed the number of center rows which corresponded to±2.5R exp for the disk spectra and extracted the center row only for the nuclear ing standard stars taken during the night,we then removed the spectral response of the system from the 1D,extracted spectra.Finally,the wavelength scale of each spectra was shifted to the rest frame of the galaxy.The guided nuclear exposures were scaled by the effective exposure times on the nucleus during the drift scanning.These scaled exposures were then subtracted from thedrift spectra.In this way,we separated the disk and nuclear contributions.Finally,all spectra were scaled to their medianflux level.2.4.ErrorsThe error calculation for ˜A1 is described in RR98;it accounts for both photon statistics and systematicflat-fielding uncertainties.Using Poisson statistics to describe the error in a raw spectrum we created an“error spectrum”and performed on it all of the standard reduction steps discussed in§2.3.2except for the cosmic ray cleaning.After normalizing the“science spectra,”the“error spectra”were scaled by the median of the“science spectra”to form a detailed representation of the error at each pixel.The“error spectra”were used in all of the following analysis steps.3.SPECTRAL ANALYSIS&STAR FORMATION HISTORYDIAGNOSTICSBy examining spatially integrated spectral characteristics as a function of ˜A1 ,we can determine whether lopsidedness affects the SF histories of galaxies.It is difficult, even in major mergers,to invert optical spectrophotometry into a SFH estimate(e.g. Turner1998).However,the relative strength of the current and recent SFR in different galaxies may be studied with moderate S/N,nonflux-calibrated spectra(e.g.Couch& Sharples1987;Barger et al.1996).The equivalent width of Hαin emission(EW(Hαem)) integrated over the whole disk is a robust measure of the current global SFR in terms of the previously formed stars(Kennicutt et al.1994).Much of the Balmer emission inn a galactic disk comes from the HII regions seen in SFR regions.In this regime,the Balmer decrement relates the emissionflux in Hβto that in Hα.If the continuum level at these two wavelengths is similar,then the decrement will also relate the EW s of the two lines. Therefore,the absorption corrected EW(Hβem)(see§3.2)serves as an indirect indicator of the current SFR in the disk.The likely lifetime of lopsidedness has been estimated as t lop≈1Gyr(Baldwin et al.1980;RZ95;ZR97).To examine SF on these timescales,we need a SF tracer with a comparable lifetime.Main sequence A-stars have lifetimes of≈0.5Gyr(Clayton1983), have strong spectral signatures(e.g.strong Balmer lines,a blue continuum,and a weak 4000˚A break),and so serve as appropriate probes of the recent SFH.3.1.Fitting Stellar TemplatesFitting population synthesis models(e.g.Bruzual&Charlot1993)to our spectra can give us a measure of the recent SFH.However for four reasons we choose to simplyfit with empirical stellar templates(Jacoby et al.1984):1)The spectral resolution of available population synthesis models(≈10˚A)is significantly less than that of our spectra(3˚A).2) The empirical templates of Jacoby et al.(1984)have a spectral resolution(4.5˚A)slightly less than that of our spectra.3)An adequatefit to the spectra can be obtained with a small number of high S/N stellar templates.To estimate the recent,relative SFH,we therefore need not deal with the complexities of the IMF and metallicity of the stellar populations.As a qualitative measure of the relative contributions to our spectra from young and old stars,we synthesize the global absorption spectra of the galaxies in our sample with a linear combination of two stellar templates,an A0V and a G0III spectra from the Jacoby et al.(1984)stellar library.We also individuallyfit and subtract a3rd order polynomial of zero mean from the spectra and from each stellar template to correct for color terms(e.g. from calibration errors,from approximating the spectra with only two stellar templates). The spectra(with the polynomial subtracted)arefit byχ2minimization with the following model:I model(λ)=(C A0V I A0V(λ))⊗G(σ)+(C G0III I G0III(λ))⊗G(σ)−I poly,(3) where G(σ)and the weights,C were determined iteratively.C A0V and C G0III are the weights for the normalized stellar template spectra,I A0V and I G0III.I poly is the sum of the weighted template polynomial components,G(σ)represents the Doppler broadening of the stars which is convolved with the stellar templates,and⊗is the convolution operator.For more details on thefitting procedure see Rix et al.(1995)and Turner(1998).Independent of continuum slope,there is a unique set of line shapes and strengths for stars of each spectral type.The polynomialfit minimizes the effects of a global continuum slope on our bestfit solution so that we are instead performing a globalfit to the spectral features(4000˚A break,Ca H+K,Balmer series,etc.)Wefind that with only two,polynomial subtracted,stellar templates,we are able to consistently achievefits with χ2ν≤2.3.2.Emission LinesOur templatefit to the galaxy spectra should reflect only the stellar populations in the galaxy,not interstellar emission.Therefore,wefirstfit all portions of spectra,omittingexpected emission regions,and use the residual of the best modelfit to construct an emission spectrum.We remove the large scale variations in the residual byfitting it with a high order polynomial(≈50)at all locations where no emission is expected.We thenfit each emission feature with a Gaussian.To isolate the stellar continuum,we subtract these gaussian components from the original spectra.We then re-fit our I model(λ)to this cleaned,(λ).This process is illustrated in Figure1. pure absorption spectrum to determine I bestmodelWe measure EW(Hβem)(see Table2)from the complementary absorption corrected emission line spectra for all of our galaxies.A linear continuum wasfit on either side of Hβ(4720˚A≤λB≤4800˚A;4900˚A≤λR≤4940).We then measured the equivalent width of the emission line integrating from4843˚A≤λline≤4883˚A.The boundaries of our integration were chosen by visual inspection to minimize noise contributions from the continuum while maximizing the amount of lineflux.3.3.Quantifying the A-star FractionWe can quantify the relative A star abundances by simply using the value of C A0V(see (λ).Because the basis templates are normalized to their medianfluxes(as Table2)in I bestmodelare the data,)the scaling factor of the individual templates gives a measure of how much A-stars contribute to the integrated spectra.Balmer absorption lines are strongest in A-stars,the4000˚A break is weak,and so we may also use these two features to measure the recent SFH(Couch&Sharples1987; Barger et al.1996).We use the equivalent width of Hδin absorption(EW(Hδabs))as our indicator of Balmer line strength in order to minimize emission contamination and sample a relatively isolated region of the spectrum.A linear continuum wasfit on either side of Hδ(4000˚A≤λB≤4050˚A;4150˚A≤λR≤4250˚A).We measure the EW itself from 4080˚A≤λline≤4120˚A.Instead of measuring EW(Hδabs)directly from the spectrum,we decide to measure(λ).These EW mod(Hδabs)(see Table2)of the best matching template spectrum,I bestmodeltemplate spectra are in general a good match to the data and provide an essentially noiseless estimate of EW(Hδabs)with a value derived from the bestfit to a broad wavelength range. When measuring EW(Hδabs)directly from the spectra,the relation between EW(Hδabs) and ˜A1 (see§4.3)clearly remains,but the scatter in EW(Hδabs)at a given ˜A1 is slightly larger.To further parameterize the recent SFH,we use the strength of the4000˚A break(D4000)(see Table2).Our measure of the break strength is defined as:D4000= 42504050fλdλOur sample is not large enough to study these correlations separately for different Hubble types;instead we analyze the change in spectral properties of the sample as a whole.Figure 5shows that the data are differentiated by lopsidedness in the EW mod(Hδabs)vs.D4000 plane.The large scatter is not surprising,as even within a single Hubble type there is a considerable variation in the specific SFHs(Kennicutt et al.1994).Between the most lopsided and symmetric1/3of our galaxies the median values of EW mod(Hδabs)and D4000 differ by,∆EW mod(Hδabs)=2.1±1.0˚A and∆D4000=0.24±0.01,respectively.This defines a boost vector(Fig.5)whose direction and magnitude characterize the difference in spectral indices between a symmetric and lopsided galaxy in our sample.4.4.Constraining the Boost MassA number of efforts have shown that the detailed SFH,even over the last109years, cannot be determined unambiguously from integrated spectra(e.g.Turner1998and references therein;Leonardi&Rose1996).Instead,we restrict ourselves to a set of model SFHs consisting of a“normal”or“underlying”spiral galaxy SFH,which in lopsided galaxies has been boosted in the past by a factor C boost.We then attempt to characterize the boost strength,C boost,and an associated ing the EPS code of Bruzual &Charlot,(GISSEL1995;in preparation)we construct SEDs representing the light from the underlying stellar populations of galaxies in our sample.We specify the SFH by the birthrate parameter b(Scalo1986),whereSFR currentb=τ(b) −1=t gal b,(6) with t gal as the age of the galaxy.We adopt an age of t gal≈10Gyr and a metallicity of Z=Z⊙.We also use the Salpeter(1955)IMF with a mass range of0.1M⊙−125M⊙.This IMF provides a betterfit than does the Scalo IMF(1986)to the global photoionization rates and to the colors of galactic disks(Kennicutt et al.1994).Applying the Scalo IMF results in slightly lower fractional boost masses than the Salpeter IMF,but the IMF choice does not qualitatively affect our conclusions.The model SED is then given by the integral:F τ(b),λ = t gal0S(t′,λ)r τ(b),t′ dt′,(7)。

活动星系

活动星系
In type II Seyfert galaxies the denser gas is missing or obscured.
Brightness varies on timescale of months → compact nucleus
3C 84的射电变化
The activity of some Seyfert galaxies may result from galaxy interactions.
Radio emission is produced by high-speed electrons in magnetic fields through synchrotron radiation.
Movement of radio galaxies causes different appearance.
Radiation power ~γ2B2β2, whereβ= v/c, γ= (1-β2)-1/2.
Beamed radiation along the particle’s motion with
half-opening angleα≈1/γ.
Power-law spectrum
(3) Unusual structure Bright nucleus, jets and irregular appearance
non-thermal radiation, with peak energy at far-infrared wavelength.
Synchrotron Radiation 同步加速辐射
Continuum radiation from high-speed charged particles, such as electrons, as they are accelerated in a strong magnetic field.

热红外传感史

热红外传感史

History of infrared detectorsA.ROGALSKI*Institute of Applied Physics, Military University of Technology, 2 Kaliskiego Str.,00–908 Warsaw, PolandThis paper overviews the history of infrared detector materials starting with Herschel’s experiment with thermometer on February11th,1800.Infrared detectors are in general used to detect,image,and measure patterns of the thermal heat radia−tion which all objects emit.At the beginning,their development was connected with thermal detectors,such as ther−mocouples and bolometers,which are still used today and which are generally sensitive to all infrared wavelengths and op−erate at room temperature.The second kind of detectors,called the photon detectors,was mainly developed during the20th Century to improve sensitivity and response time.These detectors have been extensively developed since the1940’s.Lead sulphide(PbS)was the first practical IR detector with sensitivity to infrared wavelengths up to~3μm.After World War II infrared detector technology development was and continues to be primarily driven by military applications.Discovery of variable band gap HgCdTe ternary alloy by Lawson and co−workers in1959opened a new area in IR detector technology and has provided an unprecedented degree of freedom in infrared detector design.Many of these advances were transferred to IR astronomy from Departments of Defence ter on civilian applications of infrared technology are frequently called“dual−use technology applications.”One should point out the growing utilisation of IR technologies in the civilian sphere based on the use of new materials and technologies,as well as the noticeable price decrease in these high cost tech−nologies.In the last four decades different types of detectors are combined with electronic readouts to make detector focal plane arrays(FPAs).Development in FPA technology has revolutionized infrared imaging.Progress in integrated circuit design and fabrication techniques has resulted in continued rapid growth in the size and performance of these solid state arrays.Keywords:thermal and photon detectors, lead salt detectors, HgCdTe detectors, microbolometers, focal plane arrays.Contents1.Introduction2.Historical perspective3.Classification of infrared detectors3.1.Photon detectors3.2.Thermal detectors4.Post−War activity5.HgCdTe era6.Alternative material systems6.1.InSb and InGaAs6.2.GaAs/AlGaAs quantum well superlattices6.3.InAs/GaInSb strained layer superlattices6.4.Hg−based alternatives to HgCdTe7.New revolution in thermal detectors8.Focal plane arrays – revolution in imaging systems8.1.Cooled FPAs8.2.Uncooled FPAs8.3.Readiness level of LWIR detector technologies9.SummaryReferences 1.IntroductionLooking back over the past1000years we notice that infra−red radiation(IR)itself was unknown until212years ago when Herschel’s experiment with thermometer and prism was first reported.Frederick William Herschel(1738–1822) was born in Hanover,Germany but emigrated to Britain at age19,where he became well known as both a musician and an astronomer.Herschel became most famous for the discovery of Uranus in1781(the first new planet found since antiquity)in addition to two of its major moons,Tita−nia and Oberon.He also discovered two moons of Saturn and infrared radiation.Herschel is also known for the twenty−four symphonies that he composed.W.Herschel made another milestone discovery–discov−ery of infrared light on February11th,1800.He studied the spectrum of sunlight with a prism[see Fig.1in Ref.1],mea−suring temperature of each colour.The detector consisted of liquid in a glass thermometer with a specially blackened bulb to absorb radiation.Herschel built a crude monochromator that used a thermometer as a detector,so that he could mea−sure the distribution of energy in sunlight and found that the highest temperature was just beyond the red,what we now call the infrared(‘below the red’,from the Latin‘infra’–be−OPTO−ELECTRONICS REVIEW20(3),279–308DOI: 10.2478/s11772−012−0037−7*e−mail: rogan@.pllow)–see Fig.1(b)[2].In April 1800he reported it to the Royal Society as dark heat (Ref.1,pp.288–290):Here the thermometer No.1rose 7degrees,in 10minu−tes,by an exposure to the full red coloured rays.I drew back the stand,till the centre of the ball of No.1was just at the vanishing of the red colour,so that half its ball was within,and half without,the visible rays of theAnd here the thermometerin 16minutes,degrees,when its centre was inch out of the raysof the sun.as had a rising of 9de−grees,and here the difference is almost too trifling to suppose,that latter situation of the thermometer was much beyond the maximum of the heating power;while,at the same time,the experiment sufficiently indi−cates,that the place inquired after need not be looked for at a greater distance.Making further experiments on what Herschel called the ‘calorific rays’that existed beyond the red part of the spec−trum,he found that they were reflected,refracted,absorbed and transmitted just like visible light [1,3,4].The early history of IR was reviewed about 50years ago in three well−known monographs [5–7].Many historical information can be also found in four papers published by Barr [3,4,8,9]and in more recently published monograph [10].Table 1summarises the historical development of infrared physics and technology [11,12].2.Historical perspectiveFor thirty years following Herschel’s discovery,very little progress was made beyond establishing that the infrared ra−diation obeyed the simplest laws of optics.Slow progress inthe study of infrared was caused by the lack of sensitive and accurate detectors –the experimenters were handicapped by the ordinary thermometer.However,towards the second de−cade of the 19th century,Thomas Johann Seebeck began to examine the junction behaviour of electrically conductive materials.In 1821he discovered that a small electric current will flow in a closed circuit of two dissimilar metallic con−ductors,when their junctions are kept at different tempera−tures [13].During that time,most physicists thought that ra−diant heat and light were different phenomena,and the dis−covery of Seebeck indirectly contributed to a revival of the debate on the nature of heat.Due to small output vol−tage of Seebeck’s junctions,some μV/K,the measurement of very small temperature differences were prevented.In 1829L.Nobili made the first thermocouple and improved electrical thermometer based on the thermoelectric effect discovered by Seebeck in 1826.Four years later,M.Melloni introduced the idea of connecting several bismuth−copper thermocouples in series,generating a higher and,therefore,measurable output voltage.It was at least 40times more sensitive than the best thermometer available and could de−tect the heat from a person at a distance of 30ft [8].The out−put voltage of such a thermopile structure linearly increases with the number of connected thermocouples.An example of thermopile’s prototype invented by Nobili is shown in Fig.2(a).It consists of twelve large bismuth and antimony elements.The elements were placed upright in a brass ring secured to an adjustable support,and were screened by a wooden disk with a 15−mm central aperture.Incomplete version of the Nobili−Melloni thermopile originally fitted with the brass cone−shaped tubes to collect ra−diant heat is shown in Fig.2(b).This instrument was much more sensi−tive than the thermometers previously used and became the most widely used detector of IR radiation for the next half century.The third member of the trio,Langley’s bolometer appea−red in 1880[7].Samuel Pierpont Langley (1834–1906)used two thin ribbons of platinum foil connected so as to form two arms of a Wheatstone bridge (see Fig.3)[15].This instrument enabled him to study solar irradiance far into its infrared region and to measure theintensityof solar radia−tion at various wavelengths [9,16,17].The bolometer’s sen−History of infrared detectorsFig.1.Herschel’s first experiment:A,B –the small stand,1,2,3–the thermometers upon it,C,D –the prism at the window,E –the spec−trum thrown upon the table,so as to bring the last quarter of an inch of the read colour upon the stand (after Ref.1).InsideSir FrederickWilliam Herschel (1738–1822)measures infrared light from the sun– artist’s impression (after Ref. 2).Fig.2.The Nobili−Meloni thermopiles:(a)thermopile’s prototype invented by Nobili (ca.1829),(b)incomplete version of the Nobili−−Melloni thermopile (ca.1831).Museo Galileo –Institute and Museum of the History of Science,Piazza dei Giudici 1,50122Florence, Italy (after Ref. 14).Table 1. Milestones in the development of infrared physics and technology (up−dated after Refs. 11 and 12)Year Event1800Discovery of the existence of thermal radiation in the invisible beyond the red by W. HERSCHEL1821Discovery of the thermoelectric effects using an antimony−copper pair by T.J. SEEBECK1830Thermal element for thermal radiation measurement by L. NOBILI1833Thermopile consisting of 10 in−line Sb−Bi thermal pairs by L. NOBILI and M. MELLONI1834Discovery of the PELTIER effect on a current−fed pair of two different conductors by J.C. PELTIER1835Formulation of the hypothesis that light and electromagnetic radiation are of the same nature by A.M. AMPERE1839Solar absorption spectrum of the atmosphere and the role of water vapour by M. MELLONI1840Discovery of the three atmospheric windows by J. HERSCHEL (son of W. HERSCHEL)1857Harmonization of the three thermoelectric effects (SEEBECK, PELTIER, THOMSON) by W. THOMSON (Lord KELVIN)1859Relationship between absorption and emission by G. KIRCHHOFF1864Theory of electromagnetic radiation by J.C. MAXWELL1873Discovery of photoconductive effect in selenium by W. SMITH1876Discovery of photovoltaic effect in selenium (photopiles) by W.G. ADAMS and A.E. DAY1879Empirical relationship between radiation intensity and temperature of a blackbody by J. STEFAN1880Study of absorption characteristics of the atmosphere through a Pt bolometer resistance by S.P. LANGLEY1883Study of transmission characteristics of IR−transparent materials by M. MELLONI1884Thermodynamic derivation of the STEFAN law by L. BOLTZMANN1887Observation of photoelectric effect in the ultraviolet by H. HERTZ1890J. ELSTER and H. GEITEL constructed a photoemissive detector consisted of an alkali−metal cathode1894, 1900Derivation of the wavelength relation of blackbody radiation by J.W. RAYEIGH and W. WIEN1900Discovery of quantum properties of light by M. PLANCK1903Temperature measurements of stars and planets using IR radiometry and spectrometry by W.W. COBLENTZ1905 A. EINSTEIN established the theory of photoelectricity1911R. ROSLING made the first television image tube on the principle of cathode ray tubes constructed by F. Braun in 18971914Application of bolometers for the remote exploration of people and aircrafts ( a man at 200 m and a plane at 1000 m)1917T.W. CASE developed the first infrared photoconductor from substance composed of thallium and sulphur1923W. SCHOTTKY established the theory of dry rectifiers1925V.K. ZWORYKIN made a television image tube (kinescope) then between 1925 and 1933, the first electronic camera with the aid of converter tube (iconoscope)1928Proposal of the idea of the electro−optical converter (including the multistage one) by G. HOLST, J.H. DE BOER, M.C. TEVES, and C.F. VEENEMANS1929L.R. KOHLER made a converter tube with a photocathode (Ag/O/Cs) sensitive in the near infrared1930IR direction finders based on PbS quantum detectors in the wavelength range 1.5–3.0 μm for military applications (GUDDEN, GÖRLICH and KUTSCHER), increased range in World War II to 30 km for ships and 7 km for tanks (3–5 μm)1934First IR image converter1939Development of the first IR display unit in the United States (Sniperscope, Snooperscope)1941R.S. OHL observed the photovoltaic effect shown by a p−n junction in a silicon1942G. EASTMAN (Kodak) offered the first film sensitive to the infrared1947Pneumatically acting, high−detectivity radiation detector by M.J.E. GOLAY1954First imaging cameras based on thermopiles (exposure time of 20 min per image) and on bolometers (4 min)1955Mass production start of IR seeker heads for IR guided rockets in the US (PbS and PbTe detectors, later InSb detectors for Sidewinder rockets)1957Discovery of HgCdTe ternary alloy as infrared detector material by W.D. LAWSON, S. NELSON, and A.S. YOUNG1961Discovery of extrinsic Ge:Hg and its application (linear array) in the first LWIR FLIR systems1965Mass production start of IR cameras for civil applications in Sweden (single−element sensors with optomechanical scanner: AGA Thermografiesystem 660)1970Discovery of charge−couple device (CCD) by W.S. BOYLE and G.E. SMITH1970Production start of IR sensor arrays (monolithic Si−arrays: R.A. SOREF 1968; IR−CCD: 1970; SCHOTTKY diode arrays: F.D.SHEPHERD and A.C. YANG 1973; IR−CMOS: 1980; SPRITE: T. ELIOTT 1981)1975Lunch of national programmes for making spatially high resolution observation systems in the infrared from multielement detectors integrated in a mini cooler (so−called first generation systems): common module (CM) in the United States, thermal imaging commonmodule (TICM) in Great Britain, syteme modulaire termique (SMT) in France1975First In bump hybrid infrared focal plane array1977Discovery of the broken−gap type−II InAs/GaSb superlattices by G.A. SAI−HALASZ, R. TSU, and L. ESAKI1980Development and production of second generation systems [cameras fitted with hybrid HgCdTe(InSb)/Si(readout) FPAs].First demonstration of two−colour back−to−back SWIR GaInAsP detector by J.C. CAMPBELL, A.G. DENTAI, T.P. LEE,and C.A. BURRUS1985Development and mass production of cameras fitted with Schottky diode FPAs (platinum silicide)1990Development and production of quantum well infrared photoconductor (QWIP) hybrid second generation systems1995Production start of IR cameras with uncooled FPAs (focal plane arrays; microbolometer−based and pyroelectric)2000Development and production of third generation infrared systemssitivity was much greater than that of contemporary thermo−piles which were little improved since their use by Melloni. Langley continued to develop his bolometer for the next20 years(400times more sensitive than his first efforts).His latest bolometer could detect the heat from a cow at a dis−tance of quarter of mile [9].From the above information results that at the beginning the development of the IR detectors was connected with ther−mal detectors.The first photon effect,photoconductive ef−fect,was discovered by Smith in1873when he experimented with selenium as an insulator for submarine cables[18].This discovery provided a fertile field of investigation for several decades,though most of the efforts were of doubtful quality. By1927,over1500articles and100patents were listed on photosensitive selenium[19].It should be mentioned that the literature of the early1900’s shows increasing interest in the application of infrared as solution to numerous problems[7].A special contribution of William Coblenz(1873–1962)to infrared radiometry and spectroscopy is marked by huge bib−liography containing hundreds of scientific publications, talks,and abstracts to his credit[20,21].In1915,W.Cob−lentz at the US National Bureau of Standards develops ther−mopile detectors,which he uses to measure the infrared radi−ation from110stars.However,the low sensitivity of early in−frared instruments prevented the detection of other near−IR sources.Work in infrared astronomy remained at a low level until breakthroughs in the development of new,sensitive infrared detectors were achieved in the late1950’s.The principle of photoemission was first demonstrated in1887when Hertz discovered that negatively charged par−ticles were emitted from a conductor if it was irradiated with ultraviolet[22].Further studies revealed that this effect could be produced with visible radiation using an alkali metal electrode [23].Rectifying properties of semiconductor−metal contact were discovered by Ferdinand Braun in1874[24],when he probed a naturally−occurring lead sulphide(galena)crystal with the point of a thin metal wire and noted that current flowed freely in one direction only.Next,Jagadis Chandra Bose demonstrated the use of galena−metal point contact to detect millimetre electromagnetic waves.In1901he filed a U.S patent for a point−contact semiconductor rectifier for detecting radio signals[25].This type of contact called cat’s whisker detector(sometimes also as crystal detector)played serious role in the initial phase of radio development.How−ever,this contact was not used in a radiation detector for the next several decades.Although crystal rectifiers allowed to fabricate simple radio sets,however,by the mid−1920s the predictable performance of vacuum−tubes replaced them in most radio applications.The period between World Wars I and II is marked by the development of photon detectors and image converters and by emergence of infrared spectroscopy as one of the key analytical techniques available to chemists.The image con−verter,developed on the eve of World War II,was of tre−mendous interest to the military because it enabled man to see in the dark.The first IR photoconductor was developed by Theodore W.Case in1917[26].He discovered that a substance com−posed of thallium and sulphur(Tl2S)exhibited photocon−ductivity.Supported by the US Army between1917and 1918,Case adapted these relatively unreliable detectors for use as sensors in an infrared signalling device[27].The pro−totype signalling system,consisting of a60−inch diameter searchlight as the source of radiation and a thallous sulphide detector at the focus of a24−inch diameter paraboloid mir−ror,sent messages18miles through what was described as ‘smoky atmosphere’in1917.However,instability of resis−tance in the presence of light or polarizing voltage,loss of responsivity due to over−exposure to light,high noise,slug−gish response and lack of reproducibility seemed to be inhe−rent weaknesses.Work was discontinued in1918;commu−nication by the detection of infrared radiation appeared dis−tinctly ter Case found that the addition of oxygen greatly enhanced the response [28].The idea of the electro−optical converter,including the multistage one,was proposed by Holst et al.in1928[29]. The first attempt to make the converter was not successful.A working tube consisted of a photocathode in close proxi−mity to a fluorescent screen was made by the authors in 1934 in Philips firm.In about1930,the appearance of the Cs−O−Ag photo−tube,with stable characteristics,to great extent discouraged further development of photoconductive cells until about 1940.The Cs−O−Ag photocathode(also called S−1)elabo−History of infrared detectorsFig.3.Longley’s bolometer(a)composed of two sets of thin plati−num strips(b),a Wheatstone bridge,a battery,and a galvanometer measuring electrical current (after Ref. 15 and 16).rated by Koller and Campbell[30]had a quantum efficiency two orders of magnitude above anything previously studied, and consequently a new era in photoemissive devices was inaugurated[31].In the same year,the Japanese scientists S. Asao and M.Suzuki reported a method for enhancing the sensitivity of silver in the S−1photocathode[32].Consisted of a layer of caesium on oxidized silver,S−1is sensitive with useful response in the near infrared,out to approxi−mately1.2μm,and the visible and ultraviolet region,down to0.3μm.Probably the most significant IR development in the United States during1930’s was the Radio Corporation of America(RCA)IR image tube.During World War II, near−IR(NIR)cathodes were coupled to visible phosphors to provide a NIR image converter.With the establishment of the National Defence Research Committee,the develop−ment of this tube was accelerated.In1942,the tube went into production as the RCA1P25image converter(see Fig.4).This was one of the tubes used during World War II as a part of the”Snooperscope”and”Sniperscope,”which were used for night observation with infrared sources of illumination.Since then various photocathodes have been developed including bialkali photocathodes for the visible region,multialkali photocathodes with high sensitivity ex−tending to the infrared region and alkali halide photocatho−des intended for ultraviolet detection.The early concepts of image intensification were not basically different from those today.However,the early devices suffered from two major deficiencies:poor photo−cathodes and poor ter development of both cathode and coupling technologies changed the image in−tensifier into much more useful device.The concept of image intensification by cascading stages was suggested independently by number of workers.In Great Britain,the work was directed toward proximity focused tubes,while in the United State and in Germany–to electrostatically focused tubes.A history of night vision imaging devices is given by Biberman and Sendall in monograph Electro−Opti−cal Imaging:System Performance and Modelling,SPIE Press,2000[10].The Biberman’s monograph describes the basic trends of infrared optoelectronics development in the USA,Great Britain,France,and Germany.Seven years later Ponomarenko and Filachev completed this monograph writ−ing the book Infrared Techniques and Electro−Optics in Russia:A History1946−2006,SPIE Press,about achieve−ments of IR techniques and electrooptics in the former USSR and Russia [33].In the early1930’s,interest in improved detectors began in Germany[27,34,35].In1933,Edgar W.Kutzscher at the University of Berlin,discovered that lead sulphide(from natural galena found in Sardinia)was photoconductive and had response to about3μm.B.Gudden at the University of Prague used evaporation techniques to develop sensitive PbS films.Work directed by Kutzscher,initially at the Uni−versity of Berlin and later at the Electroacustic Company in Kiel,dealt primarily with the chemical deposition approach to film formation.This work ultimately lead to the fabrica−tion of the most sensitive German detectors.These works were,of course,done under great secrecy and the results were not generally known until after1945.Lead sulphide photoconductors were brought to the manufacturing stage of development in Germany in about1943.Lead sulphide was the first practical infrared detector deployed in a variety of applications during the war.The most notable was the Kiel IV,an airborne IR system that had excellent range and which was produced at Carl Zeiss in Jena under the direction of Werner K. Weihe [6].In1941,Robert J.Cashman improved the technology of thallous sulphide detectors,which led to successful produc−tion[36,37].Cashman,after success with thallous sulphide detectors,concentrated his efforts on lead sulphide detec−tors,which were first produced in the United States at Northwestern University in1944.After World War II Cash−man found that other semiconductors of the lead salt family (PbSe and PbTe)showed promise as infrared detectors[38]. The early detector cells manufactured by Cashman are shown in Fig. 5.Fig.4.The original1P25image converter tube developed by the RCA(a).This device measures115×38mm overall and has7pins.It opera−tion is indicated by the schematic drawing (b).After1945,the wide−ranging German trajectory of research was essentially the direction continued in the USA, Great Britain and Soviet Union under military sponsorship after the war[27,39].Kutzscher’s facilities were captured by the Russians,thus providing the basis for early Soviet detector development.From1946,detector technology was rapidly disseminated to firms such as Mullard Ltd.in Southampton,UK,as part of war reparations,and some−times was accompanied by the valuable tacit knowledge of technical experts.E.W.Kutzscher,for example,was flown to Britain from Kiel after the war,and subsequently had an important influence on American developments when he joined Lockheed Aircraft Co.in Burbank,California as a research scientist.Although the fabrication methods developed for lead salt photoconductors was usually not completely under−stood,their properties are well established and reproducibi−lity could only be achieved after following well−tried reci−pes.Unlike most other semiconductor IR detectors,lead salt photoconductive materials are used in the form of polycrys−talline films approximately1μm thick and with individual crystallites ranging in size from approximately0.1–1.0μm. They are usually prepared by chemical deposition using empirical recipes,which generally yields better uniformity of response and more stable results than the evaporative methods.In order to obtain high−performance detectors, lead chalcogenide films need to be sensitized by oxidation. The oxidation may be carried out by using additives in the deposition bath,by post−deposition heat treatment in the presence of oxygen,or by chemical oxidation of the film. The effect of the oxidant is to introduce sensitizing centres and additional states into the bandgap and thereby increase the lifetime of the photoexcited holes in the p−type material.3.Classification of infrared detectorsObserving a history of the development of the IR detector technology after World War II,many materials have been investigated.A simple theorem,after Norton[40],can be stated:”All physical phenomena in the range of about0.1–1 eV will be proposed for IR detectors”.Among these effects are:thermoelectric power(thermocouples),change in elec−trical conductivity(bolometers),gas expansion(Golay cell), pyroelectricity(pyroelectric detectors),photon drag,Jose−phson effect(Josephson junctions,SQUIDs),internal emis−sion(PtSi Schottky barriers),fundamental absorption(in−trinsic photodetectors),impurity absorption(extrinsic pho−todetectors),low dimensional solids[superlattice(SL), quantum well(QW)and quantum dot(QD)detectors], different type of phase transitions, etc.Figure6gives approximate dates of significant develop−ment efforts for the materials mentioned.The years during World War II saw the origins of modern IR detector tech−nology.Recent success in applying infrared technology to remote sensing problems has been made possible by the successful development of high−performance infrared de−tectors over the last six decades.Photon IR technology com−bined with semiconductor material science,photolithogra−phy technology developed for integrated circuits,and the impetus of Cold War military preparedness have propelled extraordinary advances in IR capabilities within a short time period during the last century [41].The majority of optical detectors can be classified in two broad categories:photon detectors(also called quantum detectors) and thermal detectors.3.1.Photon detectorsIn photon detectors the radiation is absorbed within the material by interaction with electrons either bound to lattice atoms or to impurity atoms or with free electrons.The observed electrical output signal results from the changed electronic energy distribution.The photon detectors show a selective wavelength dependence of response per unit incident radiation power(see Fig.8).They exhibit both a good signal−to−noise performance and a very fast res−ponse.But to achieve this,the photon IR detectors require cryogenic cooling.This is necessary to prevent the thermalHistory of infrared detectorsFig.5.Cashman’s detector cells:(a)Tl2S cell(ca.1943):a grid of two intermeshing comb−line sets of conducting paths were first pro−vided and next the T2S was evaporated over the grid structure;(b) PbS cell(ca.1945)the PbS layer was evaporated on the wall of the tube on which electrical leads had been drawn with aquadag(afterRef. 38).。

X-ray Emission from Haloes of Simulated Disc Galaxies

X-ray Emission from Haloes of Simulated Disc Galaxies

a r X i v :a s t r o -p h /0201529v 1 31 J a n 2002Mon.Not.R.Astron.Soc.000,1–8(2001)Printed 1February 2008(MN L A T E X style file v2.2)X-ray Emission from Haloes of Simulated Disc GalaxiesS.Toft,1⋆,J.Rasmussen 1,J.Sommer-Larsen 2and K.Pedersen,11Astronomical Observatory,Copenhagen University,Juliane Maries Vej 30,DK-2100Copenhagen Ø,Denmark2TheoreticalAstrophysics Center,Juliane Mariesvej 30,DK-2100Copenhagen Ø,DenmarkABSTRACTBolometric and 0.2-2keV X-ray luminosities of the hot gas haloes of simulated disc galaxies have been calculated at redshift z =0.The TreeSPH simulations are fully cosmological and the sample of 44disc galaxies span a range in characteristic circular speeds of V c =130-325km s −1.The galaxies have been obtained in simulations with a considerable range of physical parameters,varying the baryonic fraction,the gas metallicity,the meta-galactic UV field,the cosmology,the dark matter type,and also the numerical resolution.The models are found to be in agreement with the (few)relevant X-ray observations available at present.The amount of hot gas in the haloes is also consistent with constraints from pulsar dispersion measures in the Milky Way.Forthcoming XMM and Chandra observations should enable much more stringent tests and provide constraints on the physical parameters.We find that simple cooling flow models over-predict X-ray luminosities by up to two orders of magnitude for high (but still realistic)cooling efficiencies relative to the models presented here.Our results display a clear trend that increasing cooling efficiency leads to decreasing X-ray luminosities at z =0.The reason is found to be that increased cooling efficiency leads to a decreased fraction of hot gas relative to total baryonic mass inside of the virial radius at present.At gas metal abundances of a third solar this hot gas fraction becomes as low as just a few percent.We also find that most of the X-ray emission comes from the inner parts (r <∼20kpc)of the hot galactic haloes.Finally,we find for realistic choices of the physical parameters that disc galaxy haloes possibly were more than one order of magnitude brighter in soft X-ray emission at z ∼1,than at present.Key words:methods:N-body simulations –cooling flows –galaxies:evolution –galaxies:formation –galaxies:halos –galaxies:spiral –X-rays:galaxies1INTRODUCTIONIn disc galaxy formation models infall of halo gas onto the disc due to cooling is a generic feature.However,the gas accretion rate and hot gas cooling history are at best uncer-tain in all models so far.It is thus not clear to which extent the gas cooling out from the galaxy’s halo is replenishing that which is consumed by star formation in the disc.Such continuous gas infall is essential to explain the extended star formation histories of isolated spiral galaxies like the Milky-Way and the most likely explanation of the “G-dwarf prob-lem”—see,e.g.,Rocha-Pinto &Marciel (1996)and Pagel (1997).At the virial temperatures of disc galaxy haloes the dominant cooling mechanism is thermal bremsstrahlung plus atomic line emission.The emissivity,increasing strongly with halo gas density,is expected to peak fairly close to the disc and decrease outwards,and if the cooling rate is signif-⋆E-mail:toft@astro.ku.dkicant the X-ray flux may be visible well beyond the optical radius of a galaxy.Recently,Benson et al.(2000)compared ROSAT ob-servations of three massive,nearby and highly inclined disc galaxies with predictions of simple cooling flow models of galaxy formation and evolution.They showed that these models predict about an order of magnitude more X-ray emission from the galaxy haloes (specifically from a 5-18arcmin annulus around the galaxies)than observational de-tections and upper limits.In this paper we present global X-ray properties of the haloes of a large,novel sample of model disc galaxies at red-shift z =0.The galaxies result from physically realistic grav-ity/hydro simulations of disc galaxy formation and evolution in a cosmological context.We find that our model predic-tions of X-ray properties of disc galaxy haloes are consistent with observational detections and upper limits.Given the results of the theoretical models of Benson et al.we list the most important reasons why simple cooling flow modelsc2001RAS2S.Toft et al.-60-40-200204060x [kpc]34567l o g T [K]Figure 1.The figure shows the temperature of the SPH gas particles in a typical disc galaxy from our simulations versus their x coordinate (one of the axes in the disc).The “cold”(log T <4.5)gas which is primarily situated in the disc is removed from the catalogues since it does not contribute to the X-ray flux.over-predict the present day X-ray emission of disc galaxy haloes.In section 2we give a very short description of the disc galaxy simulations.In section 3we briefly describe the X-ray halo emission calculations and in section 4the results obtained.Section 5constitutes the discussion and section 6the conclusion.2DISC GALAXY SIMULATIONSWe have in recent years developed novel models of formation and evolution of disc galaxies.The model disc galaxies result from ab initio ,fully cosmological (ΩM =1or ΩM +ΩΛ=1),gravity/hydro simulations.These simulations are started at a sufficiently high redshift (z i =20-40)that the density per-turbations are still linear and are then evolved through the entire non-linear galaxy formation regime to the present epoch (z =0).The code uses a gridless,fully Lagrangian,3-D TreeSPH code incorporating the effects of radiative cooling and heating (including the effects of a meta-galactic UV field),inverse Compton cooling,star formation,and ener-getic stellar feedback processes.A major obstacle in forming realistically sized disc galaxies in such simulations is the so-called “angular mo-mentum problem”(e.g.,Navarro &White 1994,Sommer-Larsen et al.1999).We overcome this problem in two dif-ferent ways:a)Using cold dark matter (CDM)+stellar feedback processes (Sommer-Larsen et al.2002)or b)Us-ing warm dark matter (WDM)(Sommer-Larsen &Dolgov 2001).A total of 44such disc galaxy models with charac-teristic circular velocities in the range V c =130–325km s −1form the basis of the predictions presented in this paper.The simulations initially consist of 30000-400000SPH+DM particles and in the majority of them some of the SPH par-ticles are turned into star particles over the course of theFigure 2.Bolometric luminosity as a function of characteristic circular speed.Small symbols :Flat ΩM =1.0cosmology:Open symbols:baryon fraction f b =0.05,filled circles f b =0.1.Triangles:without UV field,non-triangles:with a UV field of the Efstathiou (1992)type.Connected symbols are the same galaxies run with medium (open circles)and high (open circles with crosses)res-olution.All simulations represented by small symbols have pri-mordial rge symbols :Flat (ΩΛ,ΩM )=(0.7,0.3)cosmology:Open symbols:f b =0.05,filled symbols f b =0.1.Cir-cles correspond to primordial abundance and with a Haardt &Madau (1996)UV field,squares correspond to Z =1/3Z ⊙(us-ing the cooling function of Sutherland &Dopita 1993,which does not include effects of a UV field).The curves are the L X,bol -V c relationship for the simple cooling flow models (for ΛCDM NFW haloes)described in Sec.5.The curves represent different bary-onic fractions (solid curves have f b =0.1,dotted curves have f b =0.05)and abundances (thick curves:primordial abundances,thin curves:Z =1/3Z ⊙).simulation —for details about the TreeSPH simulations we refer the reader to the above quoted references.Most of the simulations were run with primordial gas composition (76%H and 24%He by mass)under the as-sumption that the inflowing,hot gas is fairly unenriched in heavy elements.To test the effects of metal abundance eight ΛCDM simulations (four with “universal”baryonic fraction f b =0.05and four with f b =0.10)were run with a gas abundance of 1/3solar (specifically [Fe/H]=-0.5).This is the metal abundance of the intracluster medium and can probably be considered a reasonable upper limit to the metal abundance of the hot gas in disc galaxy haloes.3X-RAY HALO EMISSION CALCULATIONFor each of the simulated galaxies at z =0we create a cata-logue of SPH gas particle positions,densities,temperatures and masses.For each catalogue a box of size (1000kpc)3centered on the galaxy is retained and all gas particles with temperatures log(T)<4.5are cut away (see Fig.1)sincec2001RAS,MNRAS 000,1–8X-ray Emission from Haloes of Simulated Disc Galaxies3Figure 3.0.2-2keV band luminosity as a function of character-istic circular speed.Symbols as in Fig.2.they will not contribute to the X-ray flux (these are mainly gas particles which have cooled onto the disc).The density and temperature of each particle is then averaged over itself and its five nearest neighbors using a spherical smoothing kernel proposed by Monaghan &Lattanzio (1985)1,and a volume is assigned to the particle given its mass and ing the average temperatures and densities,each SPH particle is treated as an optically thin thermal plasma,and the associated X-ray luminosity is calculated at the rele-vant position in a given photon energy band with the meka plasma emissivity code (Mewe et al.1986).X-ray luminosi-ties are then computed by summation over all particles in the volume of interest.The bolometric X-ray luminosity is calculated using the 0.012−12.4keV band.4RESULTSIn Fig.2the total bolometric X-ray luminosities L X,bol of the 44simulated disc galaxies in our sample are plotted versus their characteristic circular speed V c ,defined as the circu-lar velocity in the disc at R 2.2=2.2R d ,where R d is the disc scale length –see Sommer-Larsen &Dolgov (2001)for details.The X-ray luminosities derived from the simulations are up to two orders of magnitude below values derived from simple cooling flow models which are described in Sec.5.1.As can be seen from the figure L X,bol ∼1040erg s −1for a Milky Way sized galaxy.As expected from the simple models,the simulated1It is important to note that we average over the original den-sities from the TreeSPH simulations.One can show that if the cold gas particles are cut away and the densities of the remaining gas particles are then recalculated using the full SPH procedure the X-ray luminosities will be underestimated due to resolution problems at the disc–halo interface.1020304050|z| [kpc]10-1810-1710-1610-1510-1410-1310-12S (z ) [ e r g s -1 a r c m i n -2 c m -2]305 < V C < 325202 < V C < 240Figure 4.Mean bolometric X-ray surface brightness profiles per-pendicular to the plane of the disc of three high V c galaxies (solid curve)and four Milky Way sized galaxies (dashed curve).The physically most important parameters for these galaxies are f b =0.10and primordial gas abundance.The profiles were calcu-lated by binning the emission in 40kpc wide,5kpc high slices parallel to the disc.galaxies display an L X,bol -V c relation,but with a significant scatter.Part of this scatter arises from the different condi-tions under which the simulations have been run (see Sec.5.3)and part of it is a “real”scatter arising from the differ-ent geometries and cooling histories of the individual galaxy haloes.This “real”scatter can be estimated by inspection of the large filled circles in Fig.2which represent simulations run with the same,physically important parameters (see the figure caption).These data points display a rms dispersion of about 50%around the mean.There is a tendency for galaxies formed in simulations with baryon fraction f b =0.05and primordial gas abundance to have systematically higher L X,bol (by about a factor of two)than galaxies formed in similar simulations with f b =0.10.Also,galaxies formed in simulations with gas abun-dance Z =1/3Z ⊙tend to have systematically lower L X,bol than the ones with primordial gas.We discuss these trends in Sec.5.Fig.3shows the 0.2-2keV band X-ray luminosities of the 44sample disc galaxies versus V c .The systematic trends mentioned above are also seen in this plot,in particular is the difference between the f b =0.05and 0.10simulations (with primordial gas)even more pronounced than in Fig.2.We also discuss this in Sec.5.Most (but not all)of the X-ray emission originates from regions of the hot gas halo fairly close to the disc:95%of the emission typically originates within about 20kpc of the disc.This is illustrated in Fig.4where we plot the mean surface brightness profiles perpendicular to the disc of three high V c galaxies and four Milky Way sized galaxies.5DISCUSSIONc2001RAS,MNRAS 000,1–84S.Toft et al.5.1Comparison to simple coolingflow modelsIn order to compare our results with previous work,we cal-culated a family of simple coolingflow models similar to those considered by Benson et al.(2000).In these models it is assumed that the cooling occurs in a static potential and that the gas initially was in place and traced the dark matter(DM).Gas is assumed toflow from the cooling radius(at which the cooling time equals the age of the universe)to the disc(settling there as cold gas)on a time-scale much shorter than the Hubble time.The bolo-metric X-ray luminosity can then be approximated simply as the mass accretion rate,˙M cool=4πr2coolρgas(r cool)˙r cool, times the gravitational potential difference,soL X,bol=˙M cool(r cool) r cool r optical V2c(r)X-ray Emission from Haloes of Simulated Disc Galaxies5L X=45±4.4×1040erg s−1for NFW haloes(and even more for isothermal sphere haloes).However,the above result is in excellent agreement with the expectation from our simu-lations,as illustrated in Fig.5where we plot the bolometric luminosity in the considered annulus(assuming a distance of13.8Mpc)of all the galaxies in our simulation sample ver-sus V c.We note that our three“data”points at V c=300-325 km s−1are for simulations with baryon fraction f b=0.10and primordial gas abundance.For a given V c we would expect the bolometric luminosities to be about twice as much for simulations with f b=0.05-see section5.3.4.Such a low f b is unlikely given determinations of the“universal”baryon fraction,f b≈0.10(h/0.7)−3/2,derived from galaxy clusters (Ettori&Fabian1999)and galaxy clustering(Percival et al. 2001),but in any case the X-ray luminosities would still be consistent with the NGC2841measurement.Moreover,the (more realistic)inclusion of some level of enrichment in the gas and the use of the more realistic meta-galactic UVfield of Haardt&Madau(1996)would tend to lower the X-ray lu-minosities.We also note that the total X-ray luminosities of our three galaxies at V c=300-325km s−1are“only”a factor of3-5lower than the predictions of the simple coolingflow models of Benson et al.and ours(the latter for f b=0.10and primordial gas).Hence an important part of the reason why our models match the observed bolometric luminosity of the 5-18arcmin annulus around NGC2841is that most of the X-rays are emitted from the inner20kpc of our model disc galaxy haloes(5arcmin correspond to20kpc at a distance of13.8Mpc).In other words our“geometric correction”is considerably larger than the one used by Benson et al.The observational constraints on the bolometric lumi-nosity of NGC4594and NGC5529are weaker than for NGC 2841.The upper limits on these are again about an order of magnitude less than expected from the simple models,but in agreement with the expectation from our simulations.The diffuse X-ray luminosity of the Milky Way’s hot halo has recently been estimated:Pietz et al.(1998)es-timate a0.1-2keV luminosity of7·1039erg s−1and Wang (1997)a0.5-2keV luminosity of3·1039erg s−1.Assuming a temperature of0.15keV(Georgantopoulus et al.1996;Par-mar et al.1999)this translates into0.2-2keV luminosities of5and7·1039erg s−1respectively.These estimates(which should probably be seen as upper limits)are consistent with ourfindings from the simulations for V c≃220km s−1—see Fig.3.5.3Effects of numerical resolution and physicalparametersThe galaxies in our sample have been compiled from a number of simulations which have been run with differ-ent cosmological and environmental parameters.These in-homogeneities in our simulation sample may introduce some scatter in the L X−V c diagram.On the other hand,this allows us to investigate trends when varying the physical parameters.In general,varying a parameter has impact on the present day X-ray luminosity of a given galaxy if it signif-icantly alters the ability of the hot halo gas to cool during its life time.In the simple coolingflow models,increasing the cooling efficiency leads to an increase in L X,while this is not necessarily the case in more realistic simulations.If the cooling efficiency is increased,more gas has cooled out on the disc at z=0.This results in an increase of the char-acteristic circular speed of the disc as its dynamics become more baryon(and less DM)dominated,and usually a de-crease in the X-ray luminosity of the halo since there is less hot gas left in the halo to cool and contribute to the X-ray emission.In the following we briefly discuss how the derived re-sults depend on the resolution of the simulation,the pres-ence of an external UVfield,the assumed gas metallicity, the baryon fraction f b,the cosmology,the dark matter type and whether or not star formation is incorporated in the simulations.5.3.1Effects of resolutionAn important test of all numerical simulations is to check whether the results depend on the resolution.This can be done from Fig.2by comparing the connected symbols. These represent the same galaxy,run with normal(open symbols)and8times higher mass+2times higher force resolution(open symbols with crosses).It can be seen that this significant increase in resolution only leads to a very modest increase of19±64%in the X-ray luminosity rela-tive to the mean L X−V c relation(i.e.taking the effect of the change of V c with resolution into account).A similar result is inferred from Fig.3.5.3.2Effects of a meta-galactic UVfieldThe main effects of a hard UV photonfield is to ionize the gas,significantly reducing its ability to cool by colli-sional excitation(line-cooling)mechanisms(Vedel,Hellsten and Sommer-Larsen1994).This effect is evident in Fig.2 where the set of4small triangles and the set of4small open circles represent the same4haloes,run under exactly the same conditions,except that for the latter effects of a meta-galactic,redshift-dependent UVfield were included in the cooling/heating function.There is a tendency for the galaxies without an external UV-field to have lower L X,bol and higher V c than the galaxies with external UV-field:The former have a median bolometric luminosity of55±16%of the latter(again taking into account the change of V c).So in this case an increase in the cooling rate leads to a decrease in L X,bol at the present epoch since a smaller amount of hot gas is left in the halo to produce the emission –see Fig.6.Note however that in the above simulations with UVfield we used afield of the Efstathiou(1992)type which is too hard and intense compared to the more realistic one of Haardt&Madau(1996)—see also Sec.5.3.5.Hence,the suppression in cooling efficiency and the related increase in L X,bol for disc galaxy haloes formed in simulations with a Efstathiou type UVfield is somewhat too large.5.3.3Effects of gas metallicityThe effects of the metallicity of the gas on the derived L X,bol can be investigated by comparing the squares in Fig.2(which have Z=1/3Z⊙)with the rest of the symbols(which have primordial abundance).In the simple coolingflow models, an increase of the metal abundance leads to an increase inc 2001RAS,MNRAS000,1–86S.Toft etal.Figure 6.Bolometric luminosity relative to the one expected for the simple cooling flow models versus hot gas fraction -see text for details.Symbols as in Fig.2.the cooling rate and L X,bol (compare the thick and thin curves in Fig.2);however this is not what we find from our simulations.The galaxies with Z =1/3Z ⊙have systemat-ically lower L X,bol than the galaxies with primordial abun-dance,by about a factor of 3-4for the same f b .This is in agreement with the argument that increasing the cooling ef-ficiency leads to a decrease in L X,bol at z =0.Note that for the Z =1/3Z ⊙simulations we used the cooling function of Sutherland &Dopita (1993)which does not include the effect of a UV field.So we can not completely disentangle the effects of gas metal abundance versus lack of UV field on the X-ray luminosities,but Fig.6strongly hints that the former is the most important.5.3.4Effects of baryon fractionComparing in Fig.2L X,bol for simulations run with primor-dial gas and with f b =0.05and 0.10,respectively,the former are more luminous on average by about a factor of two.Yet again we see how increased cooling efficiency leads to a de-creased L X,bol at z =0.Summarizing the above results we find no statistically sig-nificant dependence of the X-ray luminosities of the simu-lated galaxies on numerical resolution.With respect to cool-ing efficiency there is a general trend of higher cooling ef-ficiency over the course of the simulation to result in less hot gas left in the halo at z =0to cool,yielding a lower X-ray luminosity.This is qualitatively demonstrated in Fig.6,which shows the bolometric luminosity relative to the one expected for the simple cooling flow models versus the hot gas fraction f (hot gas )=M (hot gas )(<r vir )/(f b M vir ),where M (hot gas )(<r vir )is the mass of hot gas (log(T )>4.5)insideof the virial radius r vir and M vir is the total mass (baryonic +DM)inside r vir .It is seen that only for hot gas frac-tions f (hot gas )>∼0.4-0.5,requiring a physically implausible parameter combination of f b =0.05,primordial gas and an unrealistically hard and intense UV field,can our models match the L X,bol predicted by the simple cooling flow mod-els.Pulsar dispersion measures can be used to place ob-servational upper limits on the amount of hot gas in the halo of the Milky Way.We find from our simulations that Milky Way sized galaxies formed in primordial gas simu-lations have about 109M ⊙of hot gas inside of 50kpc at z =0and the ones from the Z =1/3Z ⊙simulations about 108M ⊙.Both values are consistent with the observational upper limits of about 2·109M ⊙from pulsar dispersion mea-sures to the Magellanic Clouds and the globular cluster M53(Moore &Davis 1994;Rasmussen 2000).The difference between the f b =0.05and 0.10cases is even more pronounced for the 0.2-2keV X-ray luminosities,as shown in Fig.3.The reason is that at a given charac-teristic circular speed V c the dynamics of the inner galaxy (where V c is determined)are more baryon dominated for f b =0.10than for f b =0.05.This in turn means that the hot halo is smaller and cooler for the f b =0.10case than for the f b =0.05case.This is demonstrated in Fig.7,which shows the average temperature of the central hot halo gas (inside of 20h −1kpc)for the 44simulations.At a given V c the tem-perature of the inner,hot halo is systematically shifted to lower values for f b =0.10as compared to f b =0.05.Hence for the relevant,relatively low temperatures (T <∼0.3keV,orequivalently,V c <∼300km s −1)less of the emitted radia-tion has energies above 0.2keV for the former than for the latter case.On the issue of baryon dominance of the inner galaxy dynamics note that for a given DM halo,f b =0.10(as compared to f b =0.05)leads to a larger V c and a smaller d v c (R )/d R in the outer parts of the disc,where v c (R )is the rotation curve –this is in line with the findings of Persic,Salucci &Stel (1996)on the basis of a large observational sample of disc galaxy rotation curves.Finally,as mentioned in Sec.5.2,the temperature of the Milky Way’s inner halo is about 0.15keV corresponding to 1.5-2·106K in agreement with Fig.7.5.3.5Effects of dark matter type,cosmology and star formationWe do not find any dependence on the DM type,i.e.whether the simulations are of the WDM or CDM +feedback type.Neither do we find any indications of systematic trends with cosmology (SCDM/WDM versus ΛCDM/WDM)although more overlap in figures 2and 3between the two cosmologies would have been desirable (the reason for this lack of overlap is that rather different cosmological volumes were sampled in the two cosmologies —the box size was ∼40h −1Mpc for the ΩM =1cosmology and 10h −1Mpc for the Λ-cosmology).Note also that in Fig.6the results for the different cosmolo-gies fall along the same continuous sequence.The reason why the disc galaxies formed in primordial gas simulations for the Ωm =1cosmology tend to have slightly higher relative bolometric luminosity and f (hot gas )than the Λ-cosmology ones is most likely due to the two different models of thec2001RAS,MNRAS 000,1–8X-ray Emission from Haloes of Simulated Disc Galaxies7Figure 7.Average inner halo hot gas temperature versus char-acteristic circular speed -see text for details.Symbols as in Fig.2.meta-galactic UV field used:For the former we used the one suggested by Efstathiou (1992)(see Vedel et al.1994),whereas for the latter we used the more realistic one from Haardt &Madau (1996).The former has z reionization =∞and is considerably harder and,at z >∼2,more intense than the latter which has z reionization ≃6.Finally,we do not find any dependence on whether star formation is included or not in the simulations.5.4Mass accretion ratesIn Sommer-Larsen et al.(2002)disc gas accretion rates due to cooling-out of hot gas are determined for the ΛCDM +feedback model disc galaxies considered there (a sub-set of the sample considered here obtained in simulations with f b =0.10,primordial gas composition and the Haardt &Madau UV field).For Milky-Way sized galaxies accretion rates in the range 0.3-0.6h −1M ⊙yr −1(h =0.65)are found at z =0.One can show that the rate at which hot halo gas cools out is proportional to L X ,bol ·<1T>is the emissivity weighted inverse temperature of the hot gas.As mentioned previously we find in the current work that L X ,bol is proportional to about the fifth power of V c ,so asT ∝V 2c we would expect ˙M∝V 3c .This is indeed found by Sommer-Larsen et al.(2002)and is sensible since the I -band (and hence approximately mass)Tully-Fisher relation has a logarithmic slope of about three (Giovanelli et al.1997).Given the trends of L X with various environmental pa-rameters discussed in section 5.3we would expect galaxies formed in simulations with f b =0.05and primordial abun-dance to have about twice as large mass accretion rates,whereas galaxies formed in Z =1/3Z ⊙simulations will have accretion rates 3-4times lower than the similar primor-dial gas ones.Hence we expect at z =0a fairly strong trend of the ratio of present to average past accretion rate decreas-ing with increasing cooling efficiency.Indeed Sommer-Larsen et al.(2002)find for their ΛCDM simulations accretion rates at z =1which are an order of magnitude larger than the ones at z =0,so disc galaxies may have been considerably more X-ray luminous in the past than they are today.A detailed analysis of mass accretion rates and high-z X-ray properties of our sample of simulated disc galaxies will be presented in a forthcoming paper.5.5Future X-ray observational testsFrom the predicted X-ray surface brightness profiles (Fig.4)and the halo temperatures (Fig.7)we have estimated the feasibility for detecting halo emission with XMM-Newton and Chandra using the most recent instrument responses.In order to avoid confusion with X-ray emission originating in the disc we aim at detecting halo emission from nearly edge-on disc galaxies at (vertical)disc heights of 10-15kpc.Count rates for a 5kpc high and 40kpc wide slice (parallel to the disc)at such disc heights were calculated assuming a column density of absorbing neutral hydrogen in the disc of the Milky Way of n H =2.5·1020cm −2(corresponding to the typical value for galactic latitudes of |b |∼60◦).For galaxies with circular speeds in excess of 300km s −1and distances d <∼50Mpc XMM-Newton,should be able to obtain a 5σde-tection at such disc heights in a 10ksec exposure.Although Chandra has a smaller collecting area than XMM-Newton the Chandra background is generally lower and its superior spatial resolution allows for more efficient removal of con-taminating point sources.We thus expect that only slightly longer exposures are required for Chandra detection of halo emission than for XMM-Newton.However,the curve in Fig.4for the V c >300km s −1galaxies represents an optimistic case since the underly-ing simulations were run with primordial abundances and a strong external UV-field,both increasing the present day X-ray luminosity.As mentioned in sections 5.3.2and 5.3.3,in more realistic simulations,including metals and a weaker external UV-field,the halo flux is lower by a factor of about 3.In this case,XMM-Newton as well as Chandra should still obtain a 5σdetection for V c >300km s −1galaxies within 25Mpc in about 25ksecs.For Milky Way sized galaxies,due to their much lower surface brightness (e.g.Fig.4)and lower halo temperature (the latter making these more sensitive to absorption)the predicted XMM-Newton and Chandra halo count rates are two orders of magnitude lower than for the V c >300km s −1galaxies.Detection of X-ray haloes for Milky Way sized galaxies at vertical disc heights of 10-15kpc will thus have to await future X-ray observatories with much larger collecting areas (Constellation-X and XEUS).6CONCLUSIONWe have presented X-ray properties of the hot gas haloes of disc galaxies derived from a large sample of physically realistic gravity/hydro simulations of galaxy formation and evolution.The simulated galaxies follow an L X,bol -V c relation with approximately the same slope as expected from simple cool-ing flow models (L X,bol ∝V 5c ),but shifted to lower L X,bol ,c2001RAS,MNRAS 000,1–8。

Laserspecklecont...

Laserspecklecont...

Laser speckle contrast imaging of blood flow in rat retinas using an endoscopeAdrien PonticorvoDamon CardenasAndrew K.DunnDaniel Ts’oTimothy Q.DuongLaser speckle contrast imaging of blood flow in rat retinas using an endoscopeAdrien Ponticorvo,a*Damon Cardenas,a*Andrew K.Dunn,b Daniel Ts’o,c and Timothy Q.Duong a,d a University of Texas Health Science Center,Research Imaging Institute, San Antonio,Texas78229b University of Texas at Austin,Department of Biomedical Engineering, Austin,Texas78712c SUNY Upstate Medical University,Departments of Neurosurgery and Neuroscience,Syracuse,New York13210d South Texas Veterans Health Care System,Department of Veterans Affairs,San Antonio,Texas78229ser speckle contrast imaging(LSCI)offers a cost-effective means to image blood flow in vivo.However,it is not commonly used to image rodent retinas because of the challenges associated with imaging through the curved cor-nea and delivering light through the highly scattering lens.A solution to overcome these problems by using LSCI in con-junction with an endoscope to obtain high spatiotemporal blood flow images is described.Its utility is demonstrated by imaging blood flow changes in rat retinas using hyper-oxic,hypercapnic,and visual(flicker)stimulations. Hypercapnia increases blood flow,hyperoxia decreases blood flow,and visual stimulation increases blood flow in the retina relative to basal conditions.The time-to-peak of the LSCI response to visual stimulation is also measured. This approach may prove useful to investigate dysregulation in blood flow-evoked responses in retinal diseases and to evaluate treatment strategies in rodents.©The Authors. Published by SPIE under a Creative Commons Attribution 3.0Unported License.Distribution or reproduction of this work in whole or in part requires full attribution of the original publication,including its DOI.[DOI:10.1117/1 .JBO.18.9.090501]Keywords:laser speckle imaging;retinal imaging;gas challenge;flicker stimulation.Paper130502LR received Jul.16,2013;revised manuscript received Aug.30,2013;accepted for publication Sep.4,2013;published online Sep.24,2013.Blood flow in the retina can be noninvasively imaged using Doppler optical coherent tomography,1scanning laser-Doppler flowmetry,2–4laser speckle contrast imaging(LSCI),5 and magnetic resonance imaging(MRI),6–8among others. LSCI,in particular,offers a cost-effective means to measure instantaneous blood flow with high-spatiotemporal resolu-tion.9,10The majority of LSCI retinal applications are in humans,11,12with few rodent applications,13,14despite this, rodents are widely used for models of retinal diseases.This is in part due to the difficulties in dealing with the refractive properties of the curved cornea and the poor quality of the rodent lens,which results in challenges in delivering and receiv-ing light to generate good images of the retina.A common approach to overcome some of these problems is to use a contact lens to be placed over the cornea.13–15While this approach helps to reduce refractive error,delivering coherent light to the eye remains challenging in that it requires a difficult and time-con-suming alignment of the camera to find the correct angle.14,15 We implemented a solution to overcome these problems by using an endoscope to obtain images and to deliver light.16,17 The optics of the endoscope help to correct the refraction of the cornea without the need for a contact lens.Additionally, the fiber-optic guide built into the endoscope is in a ring struc-ture around the edge of the endoscope,which is very efficient in delivering uniform light to the retina without obstructing the reflected light.This same fiber-optic guide could be used to deliver laser light for generating a speckle pattern,while a cam-era can easily be placed on the end of the endoscope.There is also no need to align optics for the camera sensor,as the endo-scope connects directly to it.We demonstrated the utility of this approach by imaging blood flow changes in the rat retina using hyperoxia,hypercapnia,and visual(flicker)stimulations.A schematic of the imaging instrument is shown in Fig.1(a). The animal was secured in a stereotaxis to eliminate motion,and mineral oil was placed on the surface of the cornea to prevent dryness.The endoscope(5-mm diameter,11.5-cm length,Karl Storz67260AA,Tuttlingen,Germany),depicted from different angles in Figs.1(c)and1(d),was then placed directly in contact with the mineral oil,carefully avoid pressuring the corneal sur-face.A laser diode(785nm,Thorlabs,Newton,New Jersey) connected to the fiber-optic input was used to deliver light through the endoscope onto the eye using a ring-shaped illumi-nation pattern.We would not expect the light to affect the optical properties or the physiology of the eye.The scattered laser light was captured by the CMOS camera(Basler602f, 655×490pixels,Basler,Ahrensburg,Germany)connected to the endoscope using a custom lens adapter(SN#OY620143-A).For green-light reflectance images,the laser diode was replaced with a green LED and delivered using a fiber-optic guide.Images from the camera were collected at a rate of70 frames per second and an exposure time of5ms using custom written software.During functional activation,a slightly altered setup was used,as shown in Fig.1(b).The530-nm light from a green LED was combined with the laser diode out-put using a dual-branch light guide(Edmund Optics, Barrington,New Jersey).Figure1(e)shows a photograph of the system in use.All animal experiments were approved by the Institutional Animal Care and Use Committee and in accordance with the Association for Research in Vision and Ophthalmology Statement for the Use of Animals in Ophthalmic and Visual Research.Adult male Sprague-Dawley rats(∼300g,N¼3) were anesthetized with1%isoflurane,paralyzed with 3.5mg∕kg pancuronium bromide to prevent eye motion,18 and mechanically ventilated.End-tidal CO2,heart rate,and oxy-gen saturation were monitored continuously and maintained within normal physiological ranges.Gas challenges were used to induce blood-flow changes in the eye.Inhalation gas was switched to either hyperoxia(100%O2)or hypercapnia (7.5%CO2in air)for5min,and then back to breath normal air.For functional activation studies,a green LED(530nm, Thorlabs)was used as a stimulus source and modulated at a rate of10Hz for10s.*These authors contributed equally.Address all correspondence to:Timothy Q.Duong,University of Texas Health Science Center,Research Imaging Institute,San Antonio,Texas78229.Tel: 2105678100;Fax:2105678152;E-mail:******************The image of scattered laser light from the tissue surface,often referred to as a raw speckle image,is generated from a random static interference pattern that results from coherent light reflecting off of a rough surface.If an object consists of moving particles,as in the case with red blood cells in tissue,then the speckle pattern will fluctuate at a frequency due to the Doppler shift created by the moving particle.While other factors can affect this,these fluctuations are mainly caused by the changes in blood flow.The speckle contrast image (K )is defined as the ratio of the standard deviation (σ)to the mean intensity (h I i )in a small region of the raw speckle image.Each raw speckle image was converted to a speckle contrast map in real time using optimized algorithms,19and each set of 10speckle contrast images was averaged together to reduce the image-to-image variations to less than 1%.This averaged speckle contrast image was then converted to an image of rel-ative correlation times using Eq.(1):K ¼σh I i¼ffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiτ2Tf e −2Tτg r ;(1)where T is the exposure time of the camera and τis the auto-correlation time,which was estimated from the speckle contrast value.These correlation times were then used to calculate rel-ative blood-flow changes,as the two are inversely proportional.Green-light reflectance images were initially used to confirm the retinal vessel locations.The green-light reflectance image[Fig.2(a)]showed the larger retinal vessels branching from the optic nerve head as well as a smaller meshwork of choroidal vasculature throughout the pared with the reflectance images,the LSCI images [Fig.2(b)]showed better contrast of the retinal and choroidal vessels as well as relatively higher flow in the posterior ciliary artery.During the gas challenge,ocular blood flow increased from 11%to 31%during hypercapnia [Fig.2(c)]and decreased from 23%to 40%during hyperoxia [Fig.2(d)].These changes are particularly apparent in the retinal vessels.There are also blood-flow changes in the “background,”due to the dense vascular meshwork of the choroidal vessels.These results are consistent with blood-flow changes reported by using laser Doppler flowmetry 20and MRI.21LSCI was then used to investigate visual stimulation in the rat retina.Time-course data from several regions of interest showed increased blood flow during visual stimulation (Fig.3).While blood flow from a given region would have sig-naled contributions from both the retina and the choroid,select-ing regions with large identifiable retinal vessels were likely heavily weighted toward retinal bloodflow.Fig.1Schematic of imaging setup used for (a)gas challenge experi-ments and (b)functional activation experiments.Side (c)and front (d)views of the endoscope used in the experiments.A photograph of the imaging system in use (e)is alsoshown.Fig.2(a)Green-light reflectance and (b)speckle contrast images at baseline conditions.The arrow denotes the long posterior ciliary artery.Relative blood-flow images during (c)hypercapnic and (d)hyperoxicconditions.Fig.3During a visual stimulus experiment,regions of interest are selected in the speckle contrast image,and the time courses for those regions are shown.The maximum blood-flow response was10%and15% depending on the region of interest,and the time to reach 50%of the peak blood-flow response from stimulus onset was3.2s in the retinal vessels,consistent with those reported previously in rats(2.25s)13and humans(3.4s).22Given that it is difficult to compare relative blood-flow changes across animals, the time-to-peak measurements may offer advantages in the study of retinal diseases.While it is possible to measure hemodynamic responses by reflectance imaging,the commonly used visible light for neu-rological studies interferes with retinal measurement,because it stimulates the retina.23Moreover,the reflectance changes (which have complex signal sources)are difficult to interpret with respect to physiological parameters.By contrast,an advan-tage of LSCI is that it uses infrared light,which should not vis-ually stimulate the retina,22and provides a single physiological parameter(ca.blood flow).In conclusion,this study demonstrated the feasibility of per-forming LSCI via an endoscope to generate images of blood flow in the rat retina.Because rodents are common animal mod-els for human retinal diseases,this approach may prove useful to investigate retinal disease pathophysiology and novel treatment strategies in rodent models.Future studies will focus on integrat-ing interleaving LSCI and oximetric acquisition,applying this approach to study retinal diseases,and evaluating novel treatments.AcknowledgmentsThis work was supported in part by the Department of Veterans Affairs(V A MERIT Award)and NIH(R01EY018855and R01 EY014211).References1.O.Tan et al.,“Doppler optical coherence tomography of retinal circu-lation,”J.Visualized Exp.(67),e3524(2012).2.G.T.Feke,“Laser Doppler instrumentation for the measurement ofretinal blood flow:theory,and practice,”Bull.Soc.Belge Ophtalmol.(302),171–184(2006).3.C.E.Riva“Sub-foveal choroidal blood flow by LDF:measurement andapplication to the physiology and pathology of the choroidal circula-tion,”Bull.Soc.Belge Ophtalmol.(302),185–194(2006).4.C.E.Riva and B.Falsini,“Functional laser Doppler flowmetry of theoptic nerve:physiological aspects,and clinical applications,”Prog.Brain Res.173,149–163(2008).5.J.D.Briers and A.F.Fercher,“Retinal blood-flow visualization bymeans of laser speckle photography,”Invest.Ophthalmol.Visual Sci.22(2),255–259(1982).6.Y.Li,H.Cheng,and T.Q.Duong,“Blood-flow magnetic resonanceimaging of the retina,”Neuroimage39(4),1744–1751(2008).7.E.R.Muir and T.Q.Duong,“MRI of retinal and choroid blood flowwith laminar resolution,”NMR Biomed.24(2),216–223(2011).8.Q.Peng et al.,“MRI of blood flow of the human retina,”Magn.Reson.Med.65(6),1768–1775(2011).9.D.A.Boas and A.K.Dunn,“Laser speckle contrast imaging in bio-medical optics,”J.Biomed.Opt.15(1),011109(2010).10.A.K.Dunn et al.,“Dynamic imaging of cerebral blood flow using laserspeckle,”J.Cereb.Blood Flow Metab.21(3),195–201(2001).11.T.Sugiyama et al.,“Use of laser speckle flowgraphy in ocular bloodflow research,”Acta Ophthalmol.88(11),723–729(2010).12.G.Watanabe,H.Fujii,and S.Kishi,“Imaging of choroidal hemo-dynamics in eyes with polypoidal choroidal vasculopathy using laser speckle phenomenon,”Jpn.J.Ophthalmol.52(3),175–181(2008).13.A.I.Srienc,Z.L.Kurth-Nelson,and E.A.Newman,“Imaging retinalblood flow with laser speckle flowmetry,”Front.Neuroenergetics 2(128)(2010).14.H.Cheng,Y.Yan,and T.Q.Duong,“Temporal statistical analysis oflaser speckle images and its application to retinal blood-flow imaging,”Opt.Express16(14),10214–10219(2008).15.H.Cheng and T.Q.Duong,“Simplified laser-speckle-imaging analysismethod and its application to retinal blood flow imaging,”Opt.Lett.32(15),2188–2190(2007).16.J.L.Guyomard et al.,“A low-cost and simple imaging technique ofthe anterior and posterior segments:eye fundus,ciliary bodies,iridocor-neal angle,”Investig.Ophthalmol.Visual Sci.49(11),5168–5174 (2008).17.M.Paques et al.,“Panretinal,high-resolution color photography of themouse fundus,”Investig.Ophthalmol.Visual Sci.48(6),2769–2774 (2007).18.G.Nair et al.,“Effects of common anesthetics on eye movement andelectroretinogram,”Adv.Ophthalmol.122(3),163–176(2011).19.W.J.Tom,A.Ponticorvo,and A.K.Dunn,“Efficient processing oflaser speckle contrast images,”IEEE Trans.Med.Imaging27(12), 1728–1738(2008).20.C.E.Riva,C.J.Pournaras,and M.Tsacopoulos,“Regulation of localoxygen tension and blood flow in the inner retina during hyperoxia,”J.Appl.Physiol.61(2),592–598(1986).21.Y.Li,H.Cheng,and T.Q.Duong,“Blood-flow magnetic resonanceimaging of the retina,”NeuroImage39(4),1744–1751(2008).22.C.E.Riva,E.Logean,and B.Falsini,“Visually evoked hemodynamicalresponse and assessment of neurovascular coupling in the optic nerve and retina,”Prog.Ret.Eye Res.24(2),183–215(2005).23.J.Schallek and D.Ts’o,“Blood contrast agents enhance intrinsic signalsin the retina:evidence for an underlying blood volume component,”Investig.Ophthalmol.Visual Sci.52(3),1325–1335(2011).。

双层石墨烯的到点特性和透光特性

双层石墨烯的到点特性和透光特性

Optical conductance and transmission in bilayer grapheneH. M. Dong, J. Zhang, F. M. Peeters, and W. XuCitation: J. Appl. Phys. 106, 043103 (2009); doi: 10.1063/1.3200959View online: /10.1063/1.3200959View Table of Contents: /resource/1/JAPIAU/v106/i4Published by the American Institute of Physics.Related ArticlesElectrical modulation of the optical properties of mid-infrared metamaterialsAppl. Phys. Lett. 101, 251109 (2012)Optical properties of metal-dielectric based epsilon near zero metamaterialsAppl. Phys. Lett. 101, 241107 (2012)Modeling of LbL multilayers with controlled thickness, roughness, and specific surface areaJ. Chem. Phys. 137, 214706 (2012)Growth analysis of (Ag,Cu)InSe2 thin films via real time spectroscopic ellipsometryAppl. Phys. Lett. 101, 231910 (2012)Significant increase in conduction band discontinuity due to solid phase epitaxy of Al2O3 gate insulator films on GaN semiconductorAppl. Phys. Lett. 101, 231607 (2012)Additional information on J. Appl. Phys.Journal Homepage: /Journal Information: /about/about_the_journalTop downloads: /features/most_downloadedInformation for Authors: /authorsOptical conductance and transmission in bilayer grapheneH.M.Dong,1J.Zhang,2F.M.Peeters,3and W.Xu1,2,a͒1Key Laboratory of Materials Physics,Institute of Solid State Physics,Chinese Academy of Sciences,Hefei230031,China2Department of Physics,Yunnan University,Kunming610015,China3Department of Physics,University of Antwerp,Groenenborgerlaan171,B-2020Antwerpen,Belgium͑Received5May2009;accepted10July2009;published online20August2009͒We present a theoretical study of the optoelectronic properties of bilayer graphene.The optical conductance and transmission coefficient are calculated using the energy-balance equation derived from a Boltzmann equation for an air/graphene/dielectric-wafer system.For short wavelengths͑␭Ͻ0.2␮m͒,we obtain the universal optical conductance␴=e2/͑2ប͒.Interestingly,there exists an optical absorption window in the wavelength range10–100␮m,which is induced by different transition energies required for inter-and intra-band optical absorptions in the presence of the Moss–Burstein effect.As a result,the position and width of this absorption window depend sensitively on temperature,carrier density,and sample mobility of the system.These results are relevant for applications of recently developed graphene devices in advanced optoelectronics such as the infrared photodetectors.©2009American Institute of Physics.͓DOI:10.1063/1.3200959͔I.INTRODUCTIONGraphene is the basis of a new class of nanostructureswhere conduction occurs in single or few layers of carbonatoms arranged in a hexagonal lattice.1Owing to its uniqueelectronic band structure and the corresponding quasirelativ-istic features,graphene has attracted a great attention in re-cent years.Furthermore,graphene can have a high carrierdensity and exhibits high electronic mobility even at roomtemperature.One of the major advantages of a graphene de-vice is that the carrier density in the graphene layer can becontrolled very effectively through a gate voltage.1Hence,graphene has been proposed as a“building block”for ad-vanced electronic devices2such as graphene p-n and p-n-pjunctions,3transistors,4etc.In recent years,the study of theelectronic transport properties of Dirac quasiparticles ingraphene has rapidly become an important research topic innanomaterial science,condensed matter physics,andnanoelectronics,5which is partly motivated by the possibleapplications of graphene in advanced electronic devices.6Recently,the optical and optoelectronic properties of dif-ferent graphene systems have been investigated.In particu-lar,it was found experimentally that the optical conductanceper graphene layer is given by a universal value␴=e2/͑4ប͒in the visible frequency and UV range.7As a con-sequence,the light transmittance of monolayer and bilayergraphene devices are about0.98and0.96,respectively,in thevisible bandwidth.8This important discovery has resulted inthe proposal that graphene can be used to replace conven-tional indium tin oxide electrodes for making better andcheaper optical displays.9Kuzmenko et al.7recently foundexperimentally that for photon energy smaller than0.2eV,there is an optical absorption window.The width and depthof this window depend strongly on temperature.This inter-estingfinding implies that graphene may also be applied for infrared detection in ambient condition.Very recent experi-mental work showed that graphene can have strong intra-and inter-band transitions which can be substantially modi-fied through electrical gating,similar to resistance tuning ingraphenefield-effect transistors.10These experimental resultsshow clearly that graphene can be used not only as advancedelectronic devices but also as optical devices for various ap-plications.In conjunction with experimental investigations into op-toelectronic properties of graphene systems,theoretical studyin this area has been quite active.The universal optical con-ductance in the visible regime,␴0=e2/4បper graphene layer, has been obtained theoretically.7,11The features of graphenesystems under far-infrared͑FIR͒or terahertz radiation havealso been investigated theoretically using variousapproaches.12,13The results obtained from these theoreticalinvestigations have indicated that͑i͒in the short wavelengthsuch as visible regime,inter-band transition is the principalchannel for optical absorption and conductance ingraphene;7,11͑ii͒in the FIR or terahertz bandwidth,both inter-and intra-band transitions play important roles to cause optical absorption and conductance in graphene;12,13and͑iii͒the optoelectronic properties for graphene in the FIR or tera-hertz regime depend strongly on temperature and carrier den-sity in the system.12The optical and optoelectronic properties of monolayergraphene has been well documented.7,8,10In contrast to anearly linear energy spectrum in monolayer graphene,bi-layer graphene has a quadratic energy spectrum in low en-ergy regime.14,15Thus,the density of states in a bilayergraphene system differs significantly from that in monolayergraphene.It has been realized that bilayer graphene is ofequal importance as monolayer graphene for both techno-logical applications and fundamental science.4,16In this pa-per we present a detailed theoretical study of the optoelec-tronic properties of bilayer graphene.In Sec.II,thetheoretical approach is developed to calculate the optoelec-a͒Electronic mail:wenxu_issp@.JOURNAL OF APPLIED PHYSICS106,043103͑2009͒0021-8979/2009/106͑4͒/043103/6/$25.00©2009American Institute of Physics106,043103-1tronic coefficients in bilayer graphene.The main results ob-tained from this study are presented and discussed in Sec.III. Our conclusions drawn from this work are summarized in Sec.IV.II.THEORETICAL APPROACHIn this study,we consider a configuration where the bi-layer graphene sheet is in the xy-plane on top of a dielectric wafer such as SiO2substrate.Bilayer graphene is formed by the Bernal stacking of two graphene layers.Both sublattices are displaced from each other along an edge of the hexagons by a distance of a0=1.42Å.Under the usual effective-mass approximation,the effective Hamiltonian to describe a car-rier͑electron or hole͒in the␲-bands near the K-point is given by17,18H0=ប22mءͫ0k−2−k0k+k+2−k0k−0ͬ,͑1͒where kϮ=k xϮik y=keϮi␾with k=͑k x,k y͒being the wavevector or wavevector operator for a carrier and␾is the angle between k and the x-axis,mء=2ប2␥1/͑3a0␥0͒2Ϸ0.033m e is the effective mass for a carrier in bilayer graphene with m e being the free-electron mass and␥0 =3.16eV and␥1=0.39eV being the direct intra-and inter-layer coupling constants,respectively,k0=3a0␥3mء/ប2Ϸ106/ͱ3cm−1with␥3=0.315eV being the indirect inter-layer coupling constant.19The warping of the band is ignored which is only important near zero energy.The corresponding Schrödinger equation can be solved analytically and the ei-genvalue and eigenfunction for a carrier in bilayer graphene are given,respectively,asE␭͑k͒=␭ប2kK2mء,͑2͒with K=ͱk2+k2−2kkcos͑3␾͒and␭=+1refers to an elec-tron and␭=−1to a hole,and␺␭k͑r͒=͉k,␭͘=2−1/2͓e i␺,␭͔e i k·r͑3͒in the form of a row matrix,with r=͑x,y͒and e i␺=͑k0e i␾−ke−2i␾͒/K.Next we apply a lightfield perpendicular to the graphene sheet which is polarized linearly along the x-direction of the graphene system.Including the effect of the radiationfield within the usual Coulomb gauge,the carrier-photon interac-tion Hamiltonian in a bilayer graphene isHЈ͑t͒=បeA͑t͒2mͫ0k0−2k−k0−2k+0ͬ,͑4͒where A͑t͒=͑F0/␻͒sin͑␻t͒is the vector potential of the ra-diationfield with F0and␻being the electricfield strength and the frequency of the lightfield,respectively.We limit ourselves to the case of weak radiationfield and neglect the contribution from the F02term.Using Fermi’s golden rule,thefirst-order steady-state electronic transition rate induced by carrier-photon interac-tion is obtained asW␭␭Ј͑k,kЈ͒=2␲បͩបeF04mء␻ͪ2͉U␭␭Ј͑k͉͒22K2␦kЈ,kϫ␦͓E␭͑k͒−E␭Ј͑kЈ͒+ប␻͔,͑5͒which measures the probability for scattering of a carrier from a state͉k,␭͘to a state͉kЈ,␭Ј͘,with͉U␭␭Ј͑k͉͒2=͑k04+4k4͒͑1+␭␭Јcos͑2␾͒͒−2kk0͑k02+2␭␭Јk2͓͒2cos␾+cos͑3␾͒+␭␭Ј͑cos␾+2cos͑3␾͔͒͒+k2k02͓5+4͑cos͑4␾͒+cos͑2␾͒͒+␭␭Ј͑8+5cos͑4␾͔͒͒.In this work,we employ the Boltzmann equation as the gov-erning transport equation to study the response of the carriers in bilayer graphene to the applied radiationfield.In the case of a nondegenerate statistics,the semiclassical Boltzmann equation can be written asץf␭͑k͒ץt=g s g v͚␭Ј,kЈ͓F␭␭Ј͑k,kЈ͒−F␭Ј␭͑kЈ,k͔͒,͑6͒where g s=2and g v=2count for spin and valley degeneracy, respectively,f␭͑k͒is the momentum-distribution function for a carrier at a state͉k,␭͘,and F␭␭Ј͑k,kЈ͒=f␭͑k͓͒1−f␭Ј͑kЈ͔͒W␭␭Ј͑k,kЈ͒.Because the radiationfield has been included within the electronic transition rate,the force term induced by thisfield does not appear in the drift term on the left-hand side of the Boltzmann equation to avoid double counting.There is no simple and analytical solution to Eq.͑6͒with W␭␭Ј͑k,kЈ͒given by Eq.͑5͒.In the present study, we employ the usual balance-equation approach to approxi-mately solve the problem.20For thefirst moment the energy-balance equation can be derived by multiplying g s g v͚k E␭͑k͒to both sides of the Boltzmann equation.From the energy-balance equation,we can obtain the energy transfer rate for a carrier:P␭=g s g v͚k E␭͑k͒ץf␭͑k͒/ץt and the total energy transfer rate of the systemP=P++P−=P+++P+−+P−++P−−,͑7͒withP␭␭Ј=16ប␻͚kЈ,kF␭␭Ј͑k,kЈ͒.With the energy transfer rate P,we can calculate the optical coefficients of the sample such as the optical conductance, absorption coefficient,and transmission coefficient.Note that the optical conductance␴͑␻͒can be obtained from P =␴͑␻͒F02and we have␴͑␻͒=͚␭,␭ЈP␭␭Ј/F02=͚␭,␭Ј␴␭␭Ј͑␻͒,͑8͒which is independent on the radiation intensity F0when F0is sufficiently weak.Moreover,the transmission coefficient for an air/bilayer-graphene/dielectric-wafer͑SiO2͒system can be evaluated through21T͑␻͒=ͱ⑀2⑀14͑⑀1⑀0͒2͉͑ͱ⑀1⑀2+⑀1͒⑀0+ͱ⑀1␴͑␻͒/c͉2,͑9͒where⑀1and⑀2=⑀ϱare the dielectric constants of free space and the effective high-frequency dielectric constant of the SiO2substrate,respectively,and c is the speed of light in vacuum.One of the advantages of the balance-equation approach is that we can circumvent the difficulties of solving the Bolt-zmann equation directly by using a specific form of the dis-tribution function.In this study,we assume that the momen-tum distribution of a carrier in bilayer graphene can be described by a statistical energy distribution such as the Fermi–Dirac function f␭͑k͒Ӎf␭͓E␭͑k͔͒,where f␭͑x͒=͓1 +e͑x−␮␭ء͒/k B T͔−1with␮␭ءbeing the chemical potential͑or Fermi energy E F␭at T→0͒for electrons or holes.We note that for a doped or gated graphene device subjected to a radiationfield,the chemical potentials for electrons and holes can be different.After considering the effect of the broadening of the scattering states due to energy relaxation, we have␴␭␭͑␻͒=␴0␲2A␻2␻␶͑␻␶͒2+1͵␲d␾͵0ϱdkk K2ϫG+͑k,␾͒f␭͓E+͑k͔͕͒1−f␭͓E+͑k͔͖͒͑10͒for the case of intraband transition,where␭=␭Ј=Ϯ,␶is the corresponding energy relaxation time,␴0=e2/͑2ប͒is the uni-versal conductance,A␻=mء␻/ប,and G+͑k,␾͒=2͑k04 +4k4͒cos2␾−6kk0͑k02+2k2͓͒cos␾+cos͑3␾͔͒+k2k02͓13+9cos͑4␾͒+4cos͑2␾͔͒.For interband transition,we have ␴+−͑␻͒Ӎ0and␴−+͑␻͒=␴0␻␶␲2A␻2Sͩប␻2ͪ͵␲d␾͵0ϱdkk K2ϫG−͑k,␾͒␶2͑␻−បkK/mء͒2+1,͑11͒with G−͑k,␾͒=͑k02−2k2−2kk0cos␾͒2sin2␾and S͑x͒=f−͑−x͓͒1−f+͑x͔͒.Using Eqs.͑10͒and͑11͒we can evaluate the contributions from different transition channels to the optical absorption and transmission in bilayer graphene.It should be noted that when the radiationfield is sufficiently weak,the optical conductance and absorption and transmission coefficients do not depend on the radiation intensity.III.RESULTS AND DISCUSSIONSFor our numerical calculations we consider a typical bi-layer graphene device in which the conducting carriers are electrons.If n0ϳ1012cm−2is the electron density in the absence of the radiationfield͑or dark density͒,the electron density in the presence of the radiation is n e=n0+⌬n e,where ⌬n eϳ5ϫ1011cm−2is the density of photoexcited electrons. Under the condition of the charge number conservation ⌬n e=n h is the hole density in the presence of radiationfield.At afinite temperature,the chemical potential␮␭ءfor elec-trons and holes in bilayer graphene can be determined,re-spectively,throughn e=2␲2͵␲d␾͵0ϱdkkfͩប2kK2mءͪ͑12͒andn h=2␲2͵␲d␾͵0ϱdkkͫ1−fͩ−ប2kK2mءͪͬ.͑13͒In the calculation,we take⑀1=1and⑀2=2.25for an air/bilayer-graphene/SiO2-wafer system,where the effect of the dielectric mismatch between the bilayer graphene and the substrate has been taken into account.22Furthermore,it has been obtained experimentally23that in a graphene device,the energy relaxation time is about␶ϳ1ps for high-density samples.Thus,we take␶ϳ1ps in the calculation.In Fig.1we show the contributions from different elec-tronic transition channels to the optical conductance͑or ab-sorption spectrum͒in bilayer graphene.We notice the fol-lowing features.͑i͒The interband transition contributes to the optical absorption in the short-wavelength regime, whereas the intraband transitions give rise to the long-wavelength optical absorption.͑ii͒Optical absorption varies very weakly with increasing radiation frequency in the short-wavelength regime͑␭Ͻ0.2␮m͒,whereas the absorption coefficient depends strongly on radiation wavelength in the long-wavelength regime͑␭Ͼ0.5␮m͒.͑iii͒The optical con-ductance in the short-wavelength regime is a universal value ␴0=e2/͑2ប͒for bilayer graphene,in contrast to␴0 =e2/͑4ប͒observed for monolayer grapheme.7,8͑iv͒In the intermediate radiation wavelength regime͑0.2Ͻ␭Ͻ5␮m͒, optical conductance increases with radiation wavelength.͑v͒More interestingly,there is an absorption window in between 10and100␮m wavelength regimes.This absorption win-dow is induced by the completing absorption channels due to inter-and intra-band scattering events.͑vi͒In the very long-wavelength regime␭Ͼ100␮m,optical absorption in-creases sharply with radiation wavelength.These interesting features can be understood with the help of Fig.2.When the radiationfield is absent,there is a single Fermi level in the conduction band in a n-type bilayer graphene͑or in thepres-FIG.1.Contributions from different transition channels͑␴␭Ј␭͒to optical conductance at thefixed temperature T=150K and carrier densities n e =1.5ϫ1012cm−2and n h=5ϫ1011cm−2.Here the solid curve is the total optical conductance and␴0=e2/͑2ប͒.ence of a positive gate voltage ͒.In this case all states below E Feare occupied by electrons,as shown in Fig.2͑a ͒.When a light field is applied to the system ͓see Fig.2͑b ͔͒,the elec-trons in the valence band are excited into the conduction band via absorption of photons.Thus,the electron density inthe conduction band increases and the Fermi level E Fefor electrons in this band is also higher.Meanwhile,the holesare left in the valence band and a Fermi level E Fhis estab-lished in the valence band for holes.As shown in Fig.2͑b ͒,in the presence of a radiation field the intraband electronic transition accompanied by the absorption of photons can be achieved not only in the conduction band via a channel ␣++but also in the valence band via a channel ␣−−.The intraband transitions are a direct consequence of the broadening of the scattering states in the conduction and valence bands.Be-cause bilayer graphene is a gapless semiconductor,the elec-trons in the valence band can be more easily excited into the conduction band in contrast to a conventional semiconductor.Thus,there is a strong interband optical transition channel ͓i.e.,␣−+in Fig.2͑b ͔͒in bilayer graphene.Since optical ab-sorption is achieved for transition from occupied states to empty states,together with the presence of the Moss–Burstein effect 24or the Pauli blockade effect 25͑shown in Fig.2͒,intraband transitions require less photon energy whereas a relatively larger photon energy is needed for interband tran-sition.Consequently,an optical absorption window can be induced through different energy requirements for inter-and intra-band transition channels.In Fig.3,we show optical conductance ␴͑␻͒and trans-mission coefficient T ͑␻͒as a function of radiation wave-length for fixed carrier densities at different temperatures.As can be seen,optical conductance and transmission depend sensitively on temperature,in line with the experimental finding.7It should be noted that for the fixed electron and hole densities,the chemical potential for electrons/holes decreases/increases with increasing temperature.Thus,due to the Moss–Burstein effect,the optical absorption window shifts to higher energy ͑or shorter wavelength ͒regime,as shown in Fig.3.We note that the strength of the optical absorption is proportional to the optical conductance.There-fore,the height of the optical absorption window decreaseswith increasing temperature.A sharper cutoff of the optical absorption at the window edge can be observed at lower temperature.The optical conductance and transmission coefficient are shown in Fig.4as a function of radiation wavelength at a fixed temperature T =150K and a fixed hole density n h for different electron densities n e .Because the chemical poten-tial for electrons in the conduction band increases with elec-tron density,the optical absorption window shifts to higher energy ͑or shorter wavelength ͒regime with increasing elec-tron density,as shown in Fig.4.The height of the absorption window increases with electron density and a sharper cutoff of the optical absorption at the window edge can be observed for larger electron density.For a gate-controlled bilayer graphene placed on a dielectric SiO 2wafer,the positive ͑negative ͒voltage across the gate can pull the electrons ͑holes ͒out from the SiO 2wafer and inject them into the graphene layer.By doing so,the electron density in the graphene layer can be varied by the gate voltage and the corresponding optoelectronic properties of the device system depend on the gate voltage applied.This mechanism has been verified by the recent experiments.10In the calculation we take the energy relaxation time ␶as an input parameter to count the effect of the broadeningofFIG.2.͑a ͒A bilayer graphene system in the absence of the radiation field ͑i.e.,F 0=0͒.Here we show the case where the conducting carriers are elec-trons with a Fermi energy E F e in the conducting band.The shaded area refers to the occupied states.͑b ͒Optical absorption channels in the presence of theradiation field ͑i.e.,F 0 0͒.Here E F e and E F hare the Fermi energies for electrons and holes,respectively,and there are three optical absorption chan-nels:␣−+,␣++and ␣−−.FIG.3.Optical conductance and transmission as a function of radiation wavelength at the fixed carrier densities n e =1.5ϫ1012cm −2and n h =5ϫ1011cm −2for different temperatures T =10K ͑solid curve ͒,77K ͑dashed curve ͒,150K ͑dotted curve ͒,and 300K ͑dotted-dashed curve ͒.The corre-sponding transmission coefficients are shown in theinset.FIG.4.Optical conductance and transmission coefficient,␴/␴0and T ͑␻͒,as a function of radiation wavelength at a fixed temperature T =150K and a fixed hole density n h =5ϫ1011cm −2for different electron densities n e =1ϫ1012cm −2͑solid curve ͒, 1.5ϫ1012cm −2͑dashed curve ͒,and 2.5ϫ1012cm −2͑dotted curve ͒.The corresponding transmission coefficients are shown in the inset.theabsorp-tion and time is shown and holeto a to a sample and deeper observed for asampleThe opticalvery little on of the sample.e2/͑2ប͒␮m͒is a universal that the universal e2/͑4ប͒. Thus,should from7In the in the bilayerAs long we canfind matter what the be pointedre-gimeis often obtained from the of Eq.͑9͒.7,8The ab-sorption can of-ten be26The strong bilayer graphene that bilayer͑MIR͒con-ductancein the Fig.3͒.This suggests that graphene devices can be applied for high-speed MIR detection at ambient temperature for variousapplications.27IV.CONCLUSIONSIn this paper,we conducted a detailed theoretical studyof the optical and optoelectronic properties of bilayergraphene.Our theoretical approach is based on the energy-balance equation derived from the semiclassical Boltzmannequation.By considering a coupled bilayer graphene systemand including the intra-and interband transition channels,westudied the dependence of optical absorption/transmission ontemperature,electron density,and energy relaxed time.Themain conclusions drawn from this study are summarized asfollows.In the short-wavelength regime͑␭Ͻ0.2␮m for bilayer graphene͒the optical conductance is induced mainly throughinterband electronic transition and depends very little ontemperature,electron density,and sample mobility.There-fore,the optical conductance in the short-wavelength regimeis a universal value e2/͑2ប͒.We have found that such phe-nomenon can be observed no matter whether the couplingbetween two graphene layers is present or not in a bilayergraphene system.Thisfinding confirms a recent theoreticalprediction7that the universal optical conductance pergraphene layer is e2/͑4ប͒.In such wavelength regime,the optical transmission coefficient is about0.96,in agreement with the experimental data.8In the intermediate wavelength regime͑0.2Ͻ␭Ͻ5␮m for bilayer graphene͒the optical conductance increases slightly with radiation wavelength.There is an optical ab-sorption window in between10and100␮m wavelength regimes.This absorption window is induced by different en-ergies required for intra-and inter-band transition channels. Therefore,the width,height,and position of such window depend sensitively on temperature,electron density,and mo-bility of the sample.Wefind that the strong cutoff of the optical absorption can be observed at the edge of the absorp-tion window.Such effect can be utilized for MIR detection. The results obtained from this study confirm that the graphene systems can be used as advanced optical and opto-electronic devices working in the visible and infrared band-widths.ACKNOWLEDGMENTSThis work was supported by the Chinese Academy of Sciences,the National Natural Science Foundation of China ͑Grant No.10664006͒,the Department of Science and Tech-nology of Yunnan Province via the Special Funds for Distin-guished Professorship and the Project for the Promotion of Science and Technology͑Grant No.2007A0017z͒,and by the Flemish Science Foundation͑FWO-Vl͒.1K.S.Novoselov,A.K.Geim,S.V.Morozov,D.Jiang,M.I.Katsnelson, I.V.Grigoreva,S.V.Dubonos,and A.A.Firsov,Nature͑London͒438, 197͑2005͒;Y.B.Zhang,Y.W.Tan,H.L.Stormer,and P.Kim,ibid.438, 201͑2005͒.2K.S.Novoselov,A.K.Geim,S.V.Morozov,D.Jiang,Y.Zhang,S.V. 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第十章 次级键及超分子结构化学

第十章 次级键及超分子结构化学
化学的核心是合成,这是化学区别于所有其他学科的特色。美国著名
化学家 Stephen J. Lippard 1998在讨论化学的未来25年时有一段精彩的讲话:
“化学最重要的是制造新物质。化学不但研究自然界的本质,而且 创造出新分子、新催化剂以及具有特殊反应的新化合物。化学学 科通过合成优美而对称的分子,赋予人们创造的艺术;化学以新 方式重排原子的能力,赋予我们从事创造性劳动的机会,而这正 是其他学科所不能媲美的。”化学创造了一个人造世界”。
化学的内涵
化学是这样一门科学,茫茫宇宙中浩瀚的物质世界,在化学家看来,不过 是千百万种化合物的存在与组合,而且是由为数不多的几十种常见的元素所组 成。它们之间的差别仅在于元素的种类、原子的数目和原子构成分子或晶体时 方式的不同而已。
化学是这样一门科学,化学反应,其机理几乎是各有千秋,而且对反应条 件又极其敏感,以致对于一些化学现象,人们有时不免众说纷纭,莫衷一是。但 是化学反应所遵循的最基本的物质定律,却屈指可数,简单明了。
异 性 相 互 反 应 的 分 子, 而 共 获 得 1987 年 诺 贝
尔化学奖
Charles J. Pedersen (1904-1989, USA)
Charles J. Pedersen: Crown Ethers
“For their development and use of molecules with structurespecific interactions of high selectivity”
z 美 国 化 学 家克 拉 姆、佩 德 森与 法 国 化 学
家 莱 恩 因 开 发 和 使 用 具 高 选 择 性、 结 构 特
通过对分子间相互作用的精确调控,超分子化学已逐渐发展成为了一门 新兴的分子信息化学。它包括在分子水平和结构特征上的信息存储,以 及通过特异性分子识别过程,来实现的超分子尺寸上的修正、传输和处 理。未来超分子体系的特征应体现为:信息性和程序性的统一,流动性 和可逆性的统一,组合性和结构多样性的统一。

First-principles study of the structural, vibrational, phonon and thermodynamic

First-principles study of the structural, vibrational, phonon and thermodynamic

1. Introduction Ultra-high temperature ceramics (UHTCs) with melting temperatures in excess of 3000 K are usually composed by the refractory borides, carbides and nitrides of early transition metals [1–7]. Among the UHTCs, transition metal carbides (TMC) such as TiC, ZrC and HfC are metallic compounds with unique physical and chemical properties including an extremely high melting point and hardness, chemical stability, corrosion resistance combined with metallic electrical and thermal conductivities [5–10]. These features give transition metal carbides the capability to withstand high temperatures in oxidizing environments, making them candidates for applications in the atmosphere of extreme thermal and chemical environments [6,7]. The structural, vibrational, phonon and thermodynamic properties of IVb group transition metal carbides have been investigated experimentally [10–17] and theoretically [13,18–28] in the earlier reports. In the 1970s, the phonon dispersion relations of TiC, ZrC and HfC were measured using inelastic neutron scattering by Pintschovius et al. [10] and Smith et al. [15–17]. Lattice dynamics calculation and the phonon dispersion relations of transition metal carbides such as ZrC and HfC were reported using a phenomenological ‘‘double-shell’’ model theory [18] where long-range interatomic interactions were taken into account in order to get a
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a r X i v :a s t r o -p h /9706203v 1 19 J u n 1997A&A manuscript no.(will be inserted by hand later)1.IntroductionVery soon after their discovery BL Lac objects were noted for their fast variability.As early as in 1970,Racine ob-served BL Lac with a time resolution of 15s and recorded2S.Paltani et al.:Very rapid optical variability of PKS2155-304between the different light curves.On the basis of our results,we make some inferences on the emission mecha-nism of the optical radiation in this object(and possibly in other BL Lac objects).A preliminary analysis of the data discussed here have been presented in Paltani et al. (1996).2.Observations2.1.The campaignAll observations were made with the70-cm Geneva tele-scope at the European Southern Observatory in La Silla, Chile.The telescope is equipped with a CCD camera using a thick front-illuminated UV-coated GEC P8603 416x578device(Blecha et al.1990).Besides the usual im-ager mode,the CCD camera can be operated as a multi-channel photometer.Thefilters that have been used in this campaign are thefilters U,B and V from the Geneva photometric system(hereafter U G,B G and V G to avoid confusion with Johnson’sfilters;they are however compa-rable both in central wavelength and in width),afilter close to Gunn’s Rfilter(hereafter R G)and afilter close to Cousins’Ifilter(hereafter I C).The campaign started on July26,1995,and was sup-posed to last for3weeks.However,a bad-weather pe-riod prevented us to observe after Aug9.This resulted in15consecutive nights of observation.We observed PKS 2155-304as often as possible,with a rate strongly depen-dent on thefilter.Filters V G and R G have been most frequently used.As the U G observations were difficult to obtain,only one or two of them were performed each night to increase the spectral coverage.The exposure times have been estimated a priori to obtain a1%accuracy on the flux(without taking into account the absoluteflux cali-bration),which led us to make2-min exposures in the V G filter.The pointing and tracking limitations of the tele-scope reduced the operation period to about5hours per night,with a gap of about45min when PKS2155-304 was too close to the zenith.Table1summarizes the ob-servations performed during this campaign.2.2.Data reductionOnly the relevant–user specified–areas of the CCD are read out,which enabled us to reduce significantly the delay between two observations.Images of repeated ex-posures are stored in a single structure and reprocessed off-line as follows.The rawflux of the object is obtained by integration within an aperture of∼20pixels(8arc-seconds).The synthetic aperture is centered using a2D profilefitting.The sky background is determined individ-ually for each measurement using an average of theflux outside the integration zone.The(very rare)cosmic rays are detected and removed using the comparison with a fitted profile.Theflat-field correction is made on the inte-gratedflux rather than on the raw images(this is equiv-alent to thefiltering of theflatfields).The data acquisi-tion and image processing are carried out within the stan-dard Geneva software called INTER(Weber1993).We perform differential photometry with a comparison star, which frees us from the problem of atmospheric extinction (the object and the comparison star are processed in ex-actly the same way).The parameters of the comparison star,which has been well measured in Geneva photome-try,are:V G=12.036,B G−V G=0.104,U G−V G=1.263, R G−V G=−0.367and I C−V G=−0.752.Its coordinates areα2000=21h59m02.35s,δ2000=−30◦10′46.5”.In order to take advantage of the differential photometry we centred thefield so that both the object and the compari-son star lie in the same frame.Unfortunately,many obser-vations had to be rejected,because one of the two sources had partially disappeared from thefield of view during the observation,the angular distance between PKS2155-304 and the comparison star being close to the size of thefield of view.2.3.Flux calibrationThe absoluteflux calibration of the Geneva photomet-ric system(Rufener&Nicolet1988)was not intended to be used for active galactic nuclei.Spectrophotometric ob-servations of PKS2155-304show that its spectrum is a featureless power-law(e.g.1991-III).To obtain absolute flux calibration for PKS2155-304,we estimate the most probable power-law spectrum,given by a least-squareslin-Fig.1.Meanfive-colour spectrum.The empty circles are the fluxes from the standard calibration,and the black squares are thefluxes corrected to obtain a power-law spectrum.The slope of the line is−0.73S.Paltani et al.:Very rapid optical variability of PKS2155-3043 Table1.General information on the sampling.n(∆t<10min)and n(∆t<5min)are the number of consecutive observations separated by less than10min and5min respectively.f Norm is the correction factor applied to theflux calibration(see Sect.2.3). The basic statistics of the observations are also given.σis the standard deviation of the light curves in physical units and˜σis the standard deviation in percentage of the meanflux.εSF is the uncertainty on theflux obtained from the structure functions (see Sect.4)U G3002600 1.03713.3 2.115.4-B G1801104900.95815.5 2.314.70.12V G120262188860.96818.9 2.714.00.13R G6022414470 1.05221.8 2.712.20.09I C801306280.98924.6 3.112.60.144S.Paltani et al.:Very rapid optical variability of PKS2155-304Fig.2.Light curves in the 5filters in arbitrary units.The light curves are plotted in logarithm of the flux with an arbitrary normalization.The ticks on the y axis indicate an increase in flux by a factor 1.5.The x axis is not toscaleFig.3.Examples of nights where very-short-term variability is clearly detected.The filter and the night number aregivenFig.4.Spectral index of PKS 2155-304as a function of the flux in the V G filter.The empty circles are the observations from the 1991campaign (1991-III)by (t j ,x j ),j =1,...,n with arbitrary t j ,we estimate the SF in a bin of width δfor a lag τusing the relation:S x (τ,δ)=1S.Paltani et al.:Very rapid optical variability of PKS2155-3045 Fig.5.a and b.Structure functions of the B G,V G,R G,and I C light curves:a SFs for very shortτ,withδ=5min.b SFs for longτ,withδ=10min.The solid lines are the mean SFs of the simulated light curves,and the dashed lines show the±1σlimits.The SF of the U G light curve has not been calculated because of the very poor samplingthe SFs.Thefirst feature is the presence of a horizontal branch at shortτ.This is due to the fact that the vari-ability of the time series on very short time scales is dom-inated by the white noise introduced by the measurement errors on thefluxes.As the amplitude of a white noise is independent of the lag between the two observations,the SF of a pure white noise process is constant,with a value equal to twice the variance of the white noise.Thus the SF at very shortτgives an experimental estimation of the uncertainties on theflux,εSF.These are given in Table1. The R G light curve,which has the largest accuracy,shows variability on time scales as short as15min(0.01days).The second feature is a roughly linear increase of the logarithms of the SFs with logτwith a slope about1.3. An important property of the SF is that the SF of a time series whose Fourier power spectrum follows a power-law also follows a power-law.As afirst approximation,we as-sume that the light curves have power-law shaped Fourier power spectra.As we cannot correct our SFs from the ef-fect of the sampling,we use the opposite approach:we simulate100continuous time series whose Fourier power spectra follow a power-law with different indices.To con-struct the time series,we simply add together sine func-tions with random phases,with the constraint that the6S.Paltani et al.:Very rapid optical variability of PKS2155-304 power in each frequency bin decreases as specified.Thisis a discrete approximation of a continuous process,but, owing to the very large number of sine functions added together,we expect that no serious discrepancy will result from this method.We then project the simulated light curves onto the sampling obtained for the differentfilters, and calculate their SFs.As a result,we obtain the mean SF for our sampling of a light curve that is character-ized by a power-law-shaped Fourier power spectrum with a specified index.The power-spectrum index that matches most closely the observed SFs of the4light curves is−2.4,the indices between−2.2and−2.7being acceptable(we normalized the simulated light curves so that their standard devia-tion are identical to the one of the observed light curves; therefore the SFs of the simulated light curves match the one of the real light curve at largeτfor all indices).We can also remark that the features in the SF of the light curves(e.g.the relative drop aroundτ∼2days)are not at all significant when one considers the dispersion in the SFs of the simulated light curves.5.Delay between the light curvesThe existence of a delay between the light curves at dif-ferent wavelengths is an important issue,since it has im-plications on the emission mechanism.We test this point using two methods.5.1.Cross-correlationThe cross-correlation is the most standard way to obtain a lag between two time series.We use the interpolated cor-relation function(ICF)introduced in Gaskell&Peterson (1987).This method is more appropriate to our sampling than the discrete correlation function(DCF,Edelson& Krolik1988),provided that we calculate the correlations for lags smaller than0.2days.The reason is that the inter-polation between two observations made during the same night is a very good approximation of the actualflux,be-cause of the small amplitude of variability for very short lags(see Sect.4).Note that Litchfield et al.(1995)have found that the ICF method was more efficient than the DCF one when dealing with simulatedflaring light curves.The cross-correlations of the different light curves with the V G and R G light curves obtained with the ICF method all show a very broad peak that wefitted with a Gauss profile tofind its centre(Table2and Fig.6).The peak values are in all cases very close to1,which indicates an excellent correlation.It appears that the shorter wave-lengths are leading the longer ones.To check whether we have really detected a lag,we use the set of100simulated light curves with an index−2.4described in Sect.4,that we projected onto the samplings of the real light curves. About10%of the correlations produced a central peak that could not befitted by a Gauss profile.Thisproduced Fig. 6.ICF correlation between the R G and the B G light curves(solid line).The dashed line is thefit by a Gauss profile. Its centre is indicated by a dotted line atτ=−44.8min aberrant values for the location of the correlation peak. Instead of analyzing each of these correlations to obtain a correct value for the lag,we simply discarded all the values of the lag outside the range[−0.1;0.1]days.The distribution of the remaining lags is compatible with a Gauss distribution.The statistics of the location of the peaks are given in Table2.As the dispersions of the dis-tributions are about8times smaller than the width of the domain where we considered the lags as valid,we can conclude that the rejection of the values out of the do-main is justified.The mean lags of the simulations are different from0,but significantly smaller than the dis-persion,and are thus neglected.Fig.7shows the results of the cross-correlation analysis.The significances of the individual lags are small(<2σ).However two points in-dicate that the lags are most probably real.First,the lag increases monotonously from the B G to the I Cfilters.The probability that this happens by chance is the probability to obtain a100%correlation with a Spearman’s test on4 points,which is about2%.Moreover,this has been real-ized twice independently,since the same observation can be made for the lags with the R G light curve.The second point is that the lags between the B G light curve and the V G and R G light curves are compatible.This is also true for the lags between the I C light curve and the V G and R G light curves.S.Paltani et al.:Very rapid optical variability of PKS 2155-3047Table 2.Results of the cross-correlations of the observed and simulated light curves.A negative lag means that the second light curve is leading.The last two columns refer to the simu-lated light curvesV G –B G –28.2+14.737.9V G –R G 43.5–9.536.9V G –I C 58.2–1.432.3R G –B G –44.8+12.740.4R G –I C 23.2+7.038.2FiltersLag Best χ2/∆χ2=Significance(min)d.o.f.1 2.512.5g between the light curves.The black squares are the lags with the V G light curves (the dotted line is the zero lag line).The error bars are the dispersions of the lag in the simulations.The black triangles are the analogous of the black squares,but with respect to the R G light curves,except that a lag of 43.5min has been added (the lag between the V G and the R G light curves).The dashed line is the zero lag line for the R G light curve.The empty circles are the results of the global χ2minimization method,and give the lag with the V G light curve.The thick error bars correspond to ∆χ2=1,and the thin ones to ∆χ2=2.55.2.Global χ2minimizationThe global χ2minimization method has been introduced by Press et al.(1992)to determine the delay between two images of a gravitationally-lensed quasar.The princi-ple of the method is as follows:Assuming two unevenly-sampled time series (t x i ,x i ),i =1,...,n and (t yj ,y j ),j =1,...,m ,we concatenate them to form a new time series (t z τ0,i ,z τ0,i ),i =1,...,n +m ,one of the two time series being shifted in time by an arbitrary lag τ0.If the covari-ance properties of the initial time series are known,one can check whether the concatenated time series has the same covariance properties.This can be made by calcu-lating:χ2=(z τ0−αE )T (C −1)(z τ0−αE ),(3)where C is the total covariance matrix of the process (in-cluding measurement noise),in analogy with the usual χ2definition:χ2= ni =1(x i /σi )2.The term z −αE mean that we subtract a constant αto all components of the z τ0vector (E is the vector unity).αis the value that min-imizes the χ2in the above equation for an assumed lag,and is given by:α=E T (C −1)8S.Paltani et al.:Very rapid optical variability of PKS2155-304light curves.But,contrarily to the situation encountered by Press et al.(1992),the values of the lag that we have found are in the range where the method should work well; therefore we believe that the∆χ2=2.5assumption is very conservative.The uncertainties are in any case much smaller than in the previous case.The significances are quite high for all the lags,even if one uses the conservative assumption.The probability to obtain suchχ2values are respec-tively12%,0.8%,and0.07%.The last two values are very improbable.This may be due to the fact that this method compares only identical time series.We used experimen-tal relationships to transform thefluxes in thefilters into “equivalent V Gfluxes”.This can explain easily the high χ2values.6.DiscussionEmission of BL Lac objects is generally supposed to orig-inate from synchrotron radiation(at least at low fre-quency).Other mechanisms for variability have been pro-posed,like gravitational micro-lensing or geometrical vari-ations.We are not going to compare detailed models with the results obtained here,because of their complexity and of the number of free parameters involved.However our re-sults are strong enough to constrain the qualitative prop-erties of the models.6.1.Time-series properties of the light curvesWe have obtained a very good description of the Fourier power spectra of the optical light curves of PKS2155-304.We can check the compatibility of our result with the observations from the1991campaign.Fig.8shows the two SFs of the V(considered identical to V G)light curve from the1991campaign and of our V G light curves.We see that both SFs are compatible,apart from the effect of the measurement white noise,which has an amplitude 10times lower in our data.This comparison may indicate that the light curves of PKS2155-304are stationary time series,or at least that the spectral properties observed in the present campaign are not completely peculiar.Another comparison can be made with the result of Tagliaferri et al.(1991).They found that the Fourier power spectrum of EXOSAT observations of PKS2155-304follows a power-law with an index−2.5±0.2,fully compatible with our result.Even after the removal of the linear trend,the index(−1.9±0.4)is still compatible with our result.This shows that the X-ray and optical emission are strongly related,and that they have probably the same origin.However,even in this case,many models predict that the optical power spectrum will decrease more rapidly than the X-ray one,the short-time scale variability be-ing attenuated at large wavelength,mostly because of the longer cooling time(e.g.,in synchrotron radiation).This is not observed in our campaign.These effects,if they ex-ist,must take place on time scales even shorter than those investigated here,i.e.about15min.At least down to this limit,variability is produced by a wavelength-independent mechanism,for instance geometrical.This possibility will be rediscussed below.6.1.1.Power-spectrum at very high frequenciesThe structure functions of Fig.5are all dominated by the white noise introduced by the measurement uncertainties forτ<10min.It means that we can only put an upper limit to the minimum variability time scale in this object. In addition,the structure function analysis tells us that,if the time between two consecutive observations isτ0,the variability in the V G band from thefirst observation to the second one is:στ≃ 1.4·10−4S.Paltani et al.:Very rapid optical variability of PKS 2155-3049Fig.8.Structure functions of the light curves in the V band from our campaign (black squares),the 1991campaign (crosses),the Harvard data set (empty squares),and the com-plete photographic data set (black circles).The solid line is a power-law with an index 1.3with a break around 20days and a contamination with a white noise with a standard deviation of 0.13mJy.The dashed line is the same power-law,but con-taminated by a white noise with a standard deviation of 1.34mJy.This clearly shows the increase of the accuracy reached in our campaignthe variability.Taking this point into account,this SF is compatible with the SF of the Harvard data.The tentative SF drawn on Fig.8indicates that the longest variability time scales in PKS 2155-304lies between 10and 40days,apart perhaps from time scales longer than 100years.6.1.3.Origin of the power spectrumThe variability of PKS 2155-304is small,and the light curves are very different from what is observed in,for in-stance,OJ 287(e.g.Sillanp¨a ¨a et al.1996),which has an amplitude of variability of at least 4mag,i.e.a factor 40.Actually the variability of OJ 287appears in sudden bright “flares”,which could show that the mechanisms that pro-duce the essential of the variability are very different from those at work in PKS 2155-304(e.g.the binary black hole model Sillanp¨a ¨a et al.1996).Apart from the distinction between “flaring”and “non-flaring”objects,we do not know whether the Fourier properties of PKS 2155-304are typical of BL Lac objects.We have indeed here the most extensive (in term of spectral coverage)study of the power spectrum of any active galactic nucleus.The most important point is that all the data are compatible witha power-law-shaped power spectrum with an index −2.4,and and low-frequency cut-offat frequencies as high as (10-40days)−1.Many other time series in the physical world have a power-law-shaped Fourier spectrum (e.g.in electronic systems,or,most surprisingly,in the first Brandenburg Concerto from J.S.Bach,Voss &Clarke 1975),but no convincing physical mechanism has ever been proposed (Press 1978).Several physical processes have been pro-posed for X-ray light curves of Seyfert galaxies.The un-derlying idea of most of them can be formulated by the “mechanical model”of Halford (1968).He has shown an-alytically that a superimposition of any “reasonable”(as defined in his paper)time-dependent perturbations with different time scales and amplitude can generate any spec-tral index in the Fourier domain.As our index is smaller than −2,it means that we can constrain the properties of the perturbations.It requires indeed that the Fourier power spectrum of the perturbations decreases with an index at most −2.4.Therefore exponential pulses,whose Fourier power spectrum decreases with an index −2,are excluded.A candidate for the events could be the injec-tion of packets of relativistic electrons,which cool by emit-ting synchrotron radiation.Variations in the parameters of the packets (size,energy distribution of the electrons,...)could produce the diversity of amplitudes and time scales required to obtain a power-law-shaped Fourier spec-trum (but see Sect.6.2for the problem of spectral index variation).In this case the low-frequency cut-offis related to the maximum cooling time of the packets,if the “birth times”of the packets are completely independent from each other.Another possibility of producing a power-law-shaped Fourier spectrum is by summing many periodic functions with different periods.Following the idea of Camenzind &Krockenberger (1992),a “knot”can have a helical mo-tion around the magnetic field,which produces periodic flares,because of the periodic variation of the Doppler am-plification towards the observer.A large enough number of knots with different gyration radii could fill the power spectrum to produce a power-law.Camenzind &Krocken-berger (1992)found that the typical time scales induced around a 108M ⊙black hole should be of the order of 1day.However it seems plausible that smaller time scales can be obtained with modifications of the geometry of the system,like the angle between the jet and the observer,the velocity of the knot,or the mass of the black hole.We can further add that it seems rather improbable to us that gravitational micro-lensing can explain the light curves observed in our campaign.Even though Kayser et al.(1989)have shown that the light curves generated by a micro-lensing foreground galaxy can be very com-plex and have broad Fourier power spectra,their shapes show successions of sharp flares,which do not appear in the light curves from this campaign or from the 1991cam-paign (1991-I,1991-II,1991-III).10S.Paltani et al.:Very rapid optical variability of PKS2155-304Because variability is essentially geometrical(provided that the cooling times of the packets are significantly longer that the time scale of the geometrical variability), these last two models predict a power spectrum mostly independent of the frequency,as observed.6.2.Spectral behaviour of PKS2155-304A correlation between spectral index andflux is clearly seen in our data.It has however not always been the case in other studies on D optical observa-tions from Zhang&Xie(1996)indicate that there is no correlation between the B-V colour index and the V mag-nitude.The complete archive of IUE spectra shows that the variability increases when the wavelength decreases (Paltani&Courvoisier1994),but Edelson(1992)found using a large part of this archive that theflux and the spectral index were not correlated.On the other hand he found a(not very clear)correlation in MRK421.In the 1991campaign the constant spectral index hypothesis was favoured in the optical data(1991-III),while a hardening of the spectrum when the source brightens was the gen-eral behaviour observed in the ultraviolet domain(Urry et al.1993),but the details were very complex and do not support the clear correlation found in our data.In other BL Lac objects,the correlation has been found to be very significant(e.g.,OJ287:Gear et al.1986;AO0235+164, PKS0735+178,1308+326:Brown et al.1989).On the other hand,in a study of6BL Lac objects,Massaro et al. (1995)found only two cases of positive correlations.Examining Fig.4,it appears that the spectral index is compatible with a constant as soon as theflux in the V G band is larger than18mJy.An explanation for the drop of spectral index at lowfluxes could be that thefluxes are contaminated by a constant emission,e.g.from the host galaxy,that is fainter and steeper than the BL Lac com-ponent.PKS2155-304was rather weak during this cam-paign.Indeed the mean Vflux obtained here is about15% smaller than the one obtained during the1991campaign. Moreover the Vflux was below18mJy during about the half of the campaign,while it was below this value dur-ing about only20%of the1991campaign.This,together with the much better signal-to-noise ratio obtained in our campaign,could explain why the drop of the spectral in-dex at smallflux has not been observed during the1991 campaign.A further argument in favour of the existence of an underlying component comes from the remark made in Sect.5.2:The best way that we have found to transform aflux into a V Gflux is through a linear relationship with a constant that increases with the wavelength;a compara-ble observation in Seyfert galaxies has been interpreted by Paltani&Walter(1996)as the signature of an underlying component.Therefore we cannot exclude the possibility of a constant(or weakly varying)spectral index,and it is the interpretation that we favour.A few optical observations from the1991campaign are in disagreement with the above interpretation that the variations are achromatic(apart from the existence of an underlying component).It is also the case for several of the campaigns on PKS2155-304cited above.However in the two optical campaigns,most of the observations are com-patible with the constant spectral index hypothesis(note that a drop of the colour index can be marginally observed in Zhang&Xie(1996)).It suggests that the variability is mostly achromatic(or weakly chromatic),with some ca-sual significant excursions of the spectral index from the average value.Achromatic variability cannot be easily accounted for in terms of synchrotron radiation,because it would require a veryfine tuning between injection terms and electron losses.On the other hand small variations of the angle be-tween the jet and the observer,or of the bulk Lorenz factor can generate achromatic variability.Gravitational micro-lensing by the stars of a foreground galaxy has already been invoked to explain the variability of BL Lac objects (Schneider&Weiss1987;Kayser et al.1989).However,as mentioned above,variability is not really achromatic,but rather the spectral index has little variations,which are uncorrelated with theflux.This cannot be easily explained either by geometrical variations alone or by micro-lensing. As theflux variability is rather small,it may be that spec-tral index variation is small,if a large number of packets of electrons with different energy distributions participate in the optical emission.Moreover a campaign performed in May1994that included ASCA observations showed that the variability in the hard X-ray domain(above the range covered by ROSAT in1991-II)was quite different both in amplitude and in time scales from what has been observed with IUE(Urry1996).6.3.Delay between the light curvesIn1991-IV,Edelson et al.already observed a lag of2–3hours between the ROSAT X-ray light curve and the IUE1400˚A light curve.We confirm the existence of lags between the different wavelengths,in the sense that the light curves at shorter wavelengths lead the light curves at longer wavelengths.The delays between the optical light curves are about40min for a factor2in frequency.This value is actually very close(and compatible,owing to the large uncertainties on these values)to the amplitude of the lag between the ROSAT X-ray light curve and the IUE1400˚A light curve(a factor∼50in frequency).Inhomogeneous jets,i.e.where electrons are injected at the base of the jet and emit most of the synchrotron ra-diation at frequencies decreasing with the distance to the base,naturally produce a lag in the sense observed here (but see Sects6.2and7).It has however been noted in 1991-IV that the amplitude of the X-ray–ultraviolet lag is inconsistent with models where electrons are injected and not reaccelerated,because the life time of a X-ray-emitting。

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