炭黑MSDS
炭黑MSDS of carbon black
SECTION 2 COMPOSITION/ INFORMATION ON INGREDIENTS COMPONENT CAS NUMBER AMOUNT CARBON BLACK 1333-86-4 100.00 % weight Occupational Exposure Limits: Component Limit TWA STEL Ceiling Notation CARBON BLACK ACGIH_TLV 3.5 mg/m3 NA NA NA CARBON BLACK OSHA_PEL 3.5 mg/m3 NA NA NA
SECTION 3 HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Odorless black powder. - MAY CAUSE RESPIRATORY TRACT IRRITATION IF INHALED IMMEDIATE HEALTH EFFECTS: Eye: Not expected to cause prolonged or significant eye irritation. Skin: Not expected to be harmful to internal organs if absorbed through the skin. Contact with the skin is not expected to cause prolonged or significant irritation. Ingestion: Not expected to be harmful if swallowed. Inhalation: The dust from this material may cause respiratory irritation. Symptoms of respiratory irritation may include coughing and difficulty breathing. DELAYED OR OTHER HEALTH EFFECTS: Cancer: May cause cancer in laboratory animals, but the available information is inadequate to determine if this material can cause cancer in humans. See Section 11 for additional information. Risk depends on duration and level of exposure
炭黑msds.doc
材料安全数据表1.化学品及企业信息化学品中文名称炭黑编码 111俗名/商品名炭黑生效日期化学品英文名称 calcium hypochlorite企业名称上海卡博特化工有限公司企业应急电话地址邮编国家应急电话传真电子邮件地址2.成分 / 组成信息□混合物主要成分■纯品危害成分浓度CAS No. 1333-86-43.危险性概述危险性类别不是危险品侵入途径呼吸，眼睛接触，皮肤接触。
吸入刺激鼻腔、嘴、喉；接触刺激皮肤和眼睛；长期暴露，会损伤皮肤和指甲，造成暂时或永健康危害久性损伤，伤害肺和呼吸道，并对心脏产生不良影响。
慢性接触引起咳嗽、咳痰、烦燥、胸痛、头痛、肺损害、气管炎、皮疹。
健康危害 ( 蓝色 ) ：1环境危害燃烧危险4.急救措施皮肤接触用肥皂和水清洗，如果皮肤发红，水肿，发痒或灼伤。
就医。
眼睛接触用大量的水立即冲洗眼睛15 分钟。
如果发红，水肿，发痒，灼伤或视觉模糊就医。
吸入不必催吐。
如果清醒的，饮几杯水。
不要通过嘴给不清醒的人任何东西。
食入5.消防措施燃烧会产生刺激烟雾。
本品不溶于水并浮于水。
如可能，除去漂浮物，原因是漂浮物构成流动危险特性火灾的危险。
有害燃烧物一氧化碳，二氧化碳硫的氧化物灭火方法使用与所在地环境情况相适合的灭火方法。
如果用水，建议用喷雾水。
不能用强力的直流水，及灭火剂直流水会分散火源。
注意事项粉尘爆炸的粉尘与空气混合可能形成爆炸混合物，禁止使用掸，拂或者高压空气吹扫粉尘，避免形成粉尘风险团。
6.泄露应急处理应急处理须穿戴防护用具进入现场；排除一切火情隐患；用简便、安全的方法收集粉尘于密闭的容器内，待处理。
环境信息：应急计划和社区知情权法：款313 表 R，最低应报告浓度0 ． 1％。
消除方法7.操作处置与储存操作注意事项储存避免接触禁忌物，严禁烟火。
须贴“自燃”标签，严禁航空、铁路运输。
ERG 指南： 133 ERG 注意事项指南分类：易燃固体8.接触控制 / 个体防护最高容许浓度3 3监测方法4mg/mTWA 8mg/mSTEL工程控制保证正确的通风，控制暴露在职业卫生允许值以下。
帝斯曼 9 碳黑 化学品安全技术说明书
化学品安全技术说明书根据中国国务院591号令：危险化学品安全管理条例，应为危险物质或混合物编制安全技术说明书(S D S )。
本产品不符合危险化学品国标的分类标准。
因此，此产品不在危险化学品安全管理条例的管辖范围内，国标对安全技术说明书各部分的规定均不适用该产品.1. 化学品及企业标识产品名称产品名称：：VULCAN Ò 9 Carbon Black 产品代码产品代码：：V9同义词同义词：：炭黑, 炉黑该S D S 对下列品种是有效的:炭黑品种系列 : B L A C K P E A R L S ®, E L F T E X ®, M O G U L ®, M O N A R C H ®, R E G A L ®,S P H E R O N ®, S T E R L I N G ®, V U L C A N ®, C S X ™, C R X ™, I R X ™, F C X Ô, SHOBLACK Ô,DL Ô, PROPEL Ò, LITX Ò, and PBX Ò carbon black. Oxidized grades include:BLACK PEARLS® / MOGUL® L, BLACK PEARLS® / MOGUL® E, MOGUL® H, and REGAL® 400/400R carbon black. *不包括 : B L A C K P E A R L S ® / M O N A R C H ®1000, 1300, 1400, 1500; BLACK PEARLS® 1300B1; Monarch® 4750; and Black P e a r l s ® 4350/4750 c a r b o n b l a c k ; 以及所有油性颗粒品种。
导电炭黑msds化学品安全说明书
文件编号
标准文件
版本
A/0
文件名称: MSDS（导电炭黑－SP）
页码
1of2
第一部分：化学品名称
化学品中文名称：导电炭黑
化学品英文名称：ElectricBlack Carbon
英文名称2：
技术说明书编码：无相关资料
分子式.：C
分子量：12.01
第二部分：成分/组成信息源自成分:碳第三部分：危险性概述
操作注意事项：密闭操作。密闭操作，提供良好的自然通风条件。操作人员必须经过专门培训，严格遵守操作规程。建议操作人员佩戴自吸过滤式防尘口罩。避免产生粉尘。储存于阴凉、干燥、通风的库房内，远离火种、热源，保持容器密封，应与氧化剂，食用化学品开存放。
第八部分：接触控制/个体防护
前苏联MAC(mg/m3)：10
急性毒性：无
第十二部分：生态学资料
无
第十三部分：废弃处置
废弃处置方法：处置前应参阅国家和地方有关法规。建议用焚烧法处置.
第十四部分：运输信息
包装类别：Z01
运输注意事项：起运时包装要完整，装载应稳妥。运输过程中要确保容器不泄漏、不倒塌、不坠落、不损坏。严禁与氧化剂等混装混运。运输途中应防曝晒、雨淋，防高温。
第十五部分：法规信息
法规信息：化学危险物品安全管理条例(1987年2月17日国务院发布)，化学危险物品安全管理条例实施细则(化劳发[1992] 677号)，工作场所安全使用化学品规定([1996]劳部发423号)等法规，针对化学危险品的安全使用、生产、储存、运输、装卸等方面均作了相应规定。
TLVTN：无
工程控制：密闭操作。提供良好的自然通风条件。
呼吸系统防护：必要时，戴化学安全防护眼镜。身体防护：穿一般作业防护服。
炭黑msds
如果工作地通风不良，需配备合适的呼吸保护设备。
眼睛防护
使用眼部和面部防护：有两侧防护的安全眼镜。
身体防护
穿着合适的防护服，每天清洗服装。污染的工作服不允许带出厂。
手防护
戴手套防止手弄脏，反复接触可能造成皮肤干燥或开裂。在处理本产品前可用油膏护手。
其他防护
用良好工业卫生及安全实践相一致的处理/操作方法进行日常的操作。附近可设置京戏急洗眼和冲洗设备。
强氧化剂
分解产物
聚合危害
避免接触的条件
11.毒理学资料
急性毒性
LD50：致癌。 IARC评价：3组，未分类物质；人类资料不足；动物证据不充分 IDLH：1750mg／m3 OSHA表Z—1空气污染物：以炭黑提取物计 NIOSH标准文件：NIOSH 78—204LC50：
其他
12.生态学资料
其他有害作用
燃烧危险
4.急救措施
皮肤接触
用肥皂和水清洗，如果皮肤发红，水肿，发痒或灼伤。就医。
眼睛接触
用大量的水立即冲洗眼睛15分钟。如果发红，水肿，发痒，灼伤或视觉模糊就医。
吸入
不必催吐。如果清醒的，饮几杯水。不要通过嘴给不清醒的人任何东西。
食入
5.消防措施
危险特性
燃烧会产生刺激烟雾。本品不溶于水并浮于水。如可能，除去漂浮物，原因是漂浮物构成流动火灾的危险。
消除方法
7.操作处置与储存
操作
注意事项
储存
注意事项
避免接触禁忌物，严禁烟火。须贴“自燃”标签，严禁航空、铁路运输。 ERG指南：133 ERG指南分类：易燃固体
8.接触控制/个体防护
最高容许浓度
4mg/m3TWA 8mg/m3STEL
炭黑的安全环保标准
炭黑的安全环保标准炭黑作为一种重要的工业原料，广泛应用于橡胶、塑料、油墨、涂料等领域。
其生产和使用过程中的安全环保标准是确保产品性能符合应用要求及环境保护的重要保障。
以下是中国及其他国家针对炭黑在安全和环保方面的一些关键性标准和要求：中国国家标准1. 安全生产标准：炭黑生产设施需遵循《石油化工企业设计防火标准》（GB50160）等系列安全生产标准，确保工厂的设计、建设和运营符合防火防爆要求。
符合《工业企业设计卫生标准》（如GBZ1），以保证工人的职业健康和安全。
2. 环保排放标准：根据2023年的信息，炭黑行业烟气排放应达到《环境空气质量标准》（GB3095-2023）的要求，对二氧化硫（SO2）和其他污染物有严格的排放限值，比如规定了SO2的排放量不得超过一定浓度。
应当遵守固体废物污染防治法律法规，并按照《危险废物处理处置技术规范》进行危废处理，确保炭黑生产过程中产生的废弃物得到妥善处理。
3. 能源消耗限额：生产装置需要满足《炭黑单位产品能源消耗限额》的标准规定，限制单位产量的能耗，鼓励节能降耗。
4. 产品质量与检测：炭黑产品的质量指标应符合国家标准，如GB/T 6435-1995或更新版本，涵盖了炭黑的物理化学性质、颗粒大小分布、多环芳烃含量等具体参数。
对于特殊用途的色素炭黑，例如GB/T 7044-2022，可能涉及更为详细的技术要求和测试方法。
国际标准与要求美国标准：按照美国国家职业安全与卫生研究院的相关文件，如果炭黑中含有多环芳烃且其含量超过0.1%，则需测定空气中的多环芳烃含量，并采取措施减少工人接触。
MSDS（Material Safety Data Sheet）：炭黑的安全技术说明书提供了详细的化学品安全信息，包括危害成分、应急措施、储存运输条件以及个人防护设备的要求等。
总之，在全球范围内，炭黑的安全环保标准不仅关注其作为产品本身的性能指标，更注重从生产源头到废弃处理全生命周期的环境影响控制，同时强化了对工作场所安全的监管力度，确保产业可持续发展。
色素炭黑说明书MSDS之欧阳道创编
色素炭黑的妾全技术说朗书fMSDSJ一部分：化学品名称和公司中丈名称1：色素炭黒藝丈名称1: color pigment carbonCAS No.： 1333-86-4分子式：C分子量：12第二部分：成分/组成信息主要成分：碳(C)元素含量(Wt%) >93%；令氧基团含量fWt%) <7%o有害杨成分：多环芳蛭CPAHJ (CASNo.j丿含量(Wt%J <0.001%冲(As丿fCAS NO.7440-38-2J 含量(Wt%J <0.0001%镉fed) fCAS No.7440-43-9；含量CWt%J <0.00001%汞(HgJ (CAS No.7439-97-6)含量(Wt%) <0.0001% 铅(Pb丿CCAS No.7439-92-1)含量(Wt%丿<0.0001% 珞(Cr) (CAS No.7440-47-3；含量CWt%) <0.001%第三部分：危险性概述危险性类别：未刊入侵入變径：呼吸道吸入、眼睛、皮肤健康危害：长期丸量地由呼吸道浹入炭黑粉尘，可能最终凌成对肺部的损伤。
目前，没有朗确的医学报道证朗炭黒会引起癌变的结果。
但可以列入如人类的可能致癌的扬质。
对眼睛的损伤主要癌状是异杨刺激感、流汨。
对皮肤主要是皮肤的弄脏和剌激环境危害：炭黒的外址暴獴，除了会弄脏周谢环境外没有发现会对环境凌成严重的影响或损害。
燃爆危险：柱本％工作场所若形成纯炭黒的粉尘环境，可能凌成粉尘爆炸。
本烙不是易燃物，一般不会彼点燃，若较长时间地处于30 0 °C以上则可能会无朗犬地缓慢燃烧，同时猝出一氧化碳、二氧化碳或极少量的含氮、硫氧化扬。
第叨部分：急救措施安全介绍：吸入：1.立即将彼污染的患者转移到有丸量新鮮空毛的场所。
眼睛接触：1.立即撐开患者彼污染眼睛的眼皮用缓和流动的温水冲冼至少5分钟以上。
2.用因用i金霉素i眼跖青涂抹患者眼睛。
皮肤接触：1.及时用大量水及温和性肥皂缓和但彻底的请洗。
炭黑 MSDS
1.化学品及企业信息
化学品中文名称
炭黑
编 码
111
俗名/商品名
炭黑
生效日期
化学品英文名称
calcium hypochlorite
企 业 名 称
上海卡博特化工有限公司
企业应急电话
地 址
邮 编
国家应急电话
传真
电子邮件地址
2.成分/组成信息
主要成分
■纯品 □混合物
危害成分
浓 度
CASNo.
1333-86-4
填表时间
2010-07-27
修改说明
重新编码
有害燃烧物
一氧化碳，二氧化碳硫的氧化物
灭火方法
及灭火剂
注意事项
使用与所在地环境情况相适合的灭火方法。如果用水，建议用喷雾水。不能用强力的直流水，直流水会分散火源。
粉尘爆炸的风险
粉尘与空气混合可能形成爆炸混合物，禁止使用掸，拂或者高压空气吹扫粉尘，避免形成粉尘团。
6.泄露应急处理
应急处理
须穿戴防护用具进入现场；排除一切火情隐患；用简便、安全的方法收集粉尘于密闭的容器内，待处理。 环境信息： 应急计划和社区知情权法：款313表R，最低应报告浓度 0．1％。
呼吸系统防护
如果工作地通风不良，需配备合适的呼吸保护设备。
眼睛防护
使用眼部和面部防护：有两侧防护的安全眼镜。
身体防护
穿着合适的防护服，每天清洗服装。污染的工作服不允许带出厂。
手防护
戴手套防止手弄脏，反复接触可能造成皮肤干燥或开裂。在处理本产品前可用油膏护手。
其他防护
用良好工业卫生及安全实践相一致的处理/操作方法进行日常的操作。附近可设置京戏急洗眼和冲洗设备。
导电炭黑msds报告模板
导电炭黑 MSDS 报告模板1. 文档信息项目内容文档名称导电炭黑 MSDS 报告模板文档版本 1.0作者***（公司/单位名称）日期****年月日2. 产品信息项目内容产品名称导电炭黑化学名称Carbon black分子式 C分子量12CAS 号码1333-86-4外观黑色粉末密度 1.8-2.1 g/cm3熔点3550 ℃沸点4200 ℃溶解性不溶于水，溶于醇，酸和碱性溶液主要成分含量碳（C）3. 危险性概述3.1 主要危害吸入此物质可能会导致呼吸系统的刺激和损伤，短期接触可能会造成腹泻，恶心和呕吐等症状。
长期暴露可能导致肺部疾病，例如煤工尘肺和肺癌。
3.2 急救措施3.2.1 吸入将受害者移到空气新鲜处，保持呼吸通畅。
如呼吸急促，就医治疗。
3.2.2 眼部接触立即用大量清水冲洗，持续15分钟。
如有必要，及时就医治疗。
3.2.3 摄入不要让受害者吃东西或喝水。
如有呕吐，将头面向下方，以免呕吐物吸入肺部。
3.3 防范措施3.3.1 储存储存在干燥和通风良好的区域中。
防止火源和高温。
避免接触酸和碱性物质。
3.3.2 操作在操作时，请佩戴防护手套、眼镜和口罩等个人防护装备(e.g. PPE)。
排放进入周围环境的物质时，必须配备足够的排气装置。
3.3.3 废弃物处理根据当地法规，将废弃物处理为特定垃圾(e.g. hazardous waste)。
4. 制造商信息制造商名称****（公司/单位名称）地址****（公司/单位地址）电话****（公司/单位电话）网站****（公司/单位网站）5. 其他信息项目内容吸入的限值限制职业接触量（TLV）： 3.5 mg/m³眼部沾染的限值限制职业接触量：可吹落；不适用摄入的限值限制职业接触量：可吹落；不适用急救人员应携带物品呼吸系统防护装设备；眼睛防护装备；洗眼设备；防护手套。
50%压缩比导电乙炔炭黑材料安全数据MSDS中英文
炭黑的外泄暴露,除了会弄脏周围环境外没有发现会对环境造成严重的影响或损害。Exposure to carbon black leakage will not only dirty the surrounding environment but also has not been found to have a serious impact or damage on the environment.
皮肤接触Skin Contact:
及时用大量水及温和性肥皂缓和但彻底的清洗,若仍有刺激感，立即就医。
Cleanse promptly with a lot of water and mild soap, but thoroughly.If there is still irritation, seek medical attention immediately.
特殊灭火程序
Special fire extinguishing procedures:
1.炭黑储区火灾时，建议采用二氧化碳灭火器。
When there is a fire in the carbon black storage area, it is recommended to use a carbon dioxide fire extinguisher.
吸入Inhalation:
长期大量地由呼吸道吸入炭黑粉尘，可能最终造成对肺部的损伤。目前，没有明确的医学报道证明炭黑会引起癌变的结果。但可以列入人类的可能致癌的物质。
Long-term inhalation of carbon black dust in large quantities may eventually cause lung damage. Currently, there are no clear medical reports to prove that carbon black can cause cancer. However, it can be listed as a possible carcinogen.
炭黑MSDS通用安全技术说明书
化学品安全技术说明书1、企业资质认证产品名称：N炭黑别名：炭黑，炉法炭黑材料应用：各种工业产品供应商：炭黑有限公司地址：中国68号联系电话： 666 传真： 8882、炭黑的组成成分3、危险性概述危害显示：本品为非危险物品主要接触途径：吸入，眼睛接触，皮肤接触。
潜在的健康影响：眼睛接触：可能引起机械刺激。
但是不会永久的伤害眼膜。
对于平常的工业或商业接触有较低的危害。
皮肤接触：无已知的不良反应。
吸入：粉尘可能刺激呼吸道。
应对机器设备和能够产生灰尘的地方提供适当的排气通风。
另请参阅第8部分。
食入：正常使用下不会出现已知的健康损伤。
对于平常的工业或商业接触只有较低的危害。
致癌影响：国际癌症研究机构列出的物品。
另请参阅第9部分。
主要影响器官：肺。
暴露恶化的疾病：哮喘，呼吸障碍潜在的环境影响：不需要特别的环境预防措施。
不溶解于水。
另请参阅第12部分。
4、急救措施皮肤接触：应用肥皂和水彻底清洗。
若症状加重，请就医。
眼睛接触：应立即用大量的水冲洗眼睛15分钟。
若症状加重，请就医。
吸入：如果咳嗽，呼吸急促或者发生其他呼吸问题，请移到其他地方呼吸新鲜空气。
若症状无好转，请就医。
如果有必要的话，请通过标准的急救措施来恢复正常呼吸。
食入：不要催吐，如清醒，给予几杯水，千万不要给休克的人通过口腔喂任何东西。
医生提示：请根据症状处理。
5、消防措施灭火器：应使用泡沫，二氧化碳，干粉或者水喷雾。
如果已经使用过水，推荐使用水雾。
不要使用强直流水，因为它可能溅射扩散火苗。
消防员的特殊防护装备：要穿戴合适的防护装备。
发生火灾时，应佩带独立的呼吸设备。
具体危害：炭黑燃烧时可能不明显，除非搅拌时出现火花。
对已经着火的炭黑，我们应该严密地观察至少48小时以确保无隐燃存在。
燃烧会产生刺激性的烟气。
该产品不能溶解的，并且漂浮在水上。
如果可能，设法控制悬浮物质。
该物质会产生火灾隐患，因为它漂浮在水上。
分解或燃烧产生的危害物：一氧化碳，二氧化碳，硫的氧化物，分解的有机产物。
PA66_GF40%_MSDS_中文版
第九部分：物理和化学特性
外观： 气味： 物理状态： 气压： 熔点（树脂）： 溶解性： 比重： 挥发率：
颗粒状物 轻微的典型气味 固态 不适用 265 ℃ （509℉ሻ 可忽略不计 < 0.1% （水）
1.40~1.50 < 0.5 按重量计
____________________________________________________________________________________________
____________________________________________________________________________________________
第十一部分：毒物学信息
本产品没有相关的具体资料。
____________________________________________________________________________________________
第五部分：救火措施
闪点: 危险燃烧产物： 灭火介质： 灭火指南：
不适用 一氧化碳、二氧化碳和氮氧化物 水、泡沫材料、二氧化碳或 干化学制剂 消防人员应携带自给式呼吸器和全套防护服。消防人员避免逆 风救火。水应该用来给火灾中各种容器的降温。水、泡沫和干 化学制剂可能会对电气设备造成损伤。
____________________________________________________________________________________________
第六部分：意外泄漏对策
详细情况参见第十五部分
泄漏处理程序：
用适当工具清扫泄漏场所，收集泄漏物料，以便恢复和处理。
炭黑说明书
色素炭黑的安全技术说明书（MSDS）第一部分：化学品名称和公司中文名称1：色素炭黑英文名称1：color pigment carbonCAS No.：1333-86-4分子式：C 分子量：12第二部分：成分/组成信息主要成分：碳（C）元素含量（Wt%）≥93%；含氧基团含量（Wt%）≤7%。
有害物成分：多环芳烃（PAH）（CAS No.¡ ）含量（Wt%）≤0.001%砷（As）（CAS No.7440-38-2）含量（Wt%）≤0.0001%镉（Cd）（CAS No.7440-43-9）含量（Wt%）≤0.00001%汞（Hg）（CAS No.7439-97-6）含量（Wt%）≤0.0001%铅（Pb）（CAS No.7439-92-1）含量（Wt%）≤0.0001%铬（Cr）（CAS No.7440-47-3）含量（Wt%）≤0.001%（资讯来源：昊客云台，上面更多产品知识，行业资讯热点）第三部分：危险性概述危险性类别：未列入侵入途径：呼吸道吸入、眼睛、皮肤健康危害：长期大量地由呼吸道吸入炭黑粉尘，可能最终造成对肺部的损伤。
目前，没有明确的医学报道证明炭黑会引起癌变的结果。
但可以列入如人类的可能致癌的物质。
对眼睛的损伤主要症状是异物刺激感、流泪。
对皮肤主要是皮肤的弄脏和刺激环境危害：炭黑的外泄暴露，除了会弄脏周围环境外没有发现会对环境造成严重的影响或损害。
燃爆危险：在本品工作场所若形成纯炭黑的粉尘环境，可能造成粉尘爆炸。
本品不是易燃物，一般不会被点燃，若较长时间地处于30０℃以上则可能会无明火地缓慢燃烧，同时释出一氧化碳、二氧化碳或极少量的含氮、硫氧化物。
第四部分：急救措施据昊客云台产品经理安全介绍：吸入：1. 立即将被污染的患者转移到有大量新鲜空气的场所。
眼睛接触：1. 立即撑开患者被污染眼睛的眼皮用缓和流动的温水冲洗至少5 分钟以上。
2. 用医用¡ 金霉素¡ 眼药膏涂抹患者眼睛。
炭黑英文msds
﹡﹡﹡MATERIAL SAFETY DATA SHEET﹡﹡﹡1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THECOMPANY/UNDERTAKINGProduct Name: CARBON BLACK N330Synonyms: Carbon Black, Furnace BlackUse of the Substance/Preparation: Various, Industrial ProductsSupplier:Carbon Black Co. ,Ltd.City, ChinaTEL: FAX:02. HAZARDS IDENTIFICATIONIndication of danger: Hazardous according to the Worksafe Australia designated list of hazardous substances.Xn - Harmful.C3 - Carcinogen Category 3.Principle Routes of Exposure: Inhalation, Eye contact, Skin contactPOTENTIAL HEALTH EFFECTSEye Contact:May cause mechanical irritation. Irritating, but will not permanently injure eye tissue.Low hazard for usual industrial or commercial handling.Skin Contact:No adverse effects expected.Inhalation:Dust may be irritating to respiratory tract. Provide appropriate exhaust ventilation at machinery and at places where dust can be generated. See also Section 8.Ingestion:Health injuries are not known or expected under normal use. Low hazard for usual industrial or commercial handling.Carcinogenic Effects:Substance listed by IARC (International Agency for Research on Cancer). See also Section 9.Target Organ Effects:LungsMedical Conditions Aggravated by Exposure:Asthma, Respiratory disorder1Potential Environmental Effects:No special environmental precautions required. Not soluble in water. See also Section 12.4. FIRST AID MEASURESSkin Contact:Wash thoroughly with soap and water. Seek medical attention if symptoms develop.Eye Contact:Flush eyes immediately with large amounts of water for 15 minutes. Seek medical attention if symptoms develop.Inhalation:If cough, shortness of breath or other breathing problems occur, move to fresh air.Seek medical attention if symptoms persist. If necessary, restore normal breathing through standard first aid measures.Notes to Physician:Treat symptomatically.5. FIRE-FIGHTING MEASURESExtinguishing Media:Use foam, carbon dioxide (CO2), dry chemical or water spray. A fog is recommended if water is used. DO NOT USE a solid water stream as it may scatter and spread fire.Special Protective Equipment for Firefighters:Wear suitable protective equipment. In the event of fire, wear self-contained breathing apparatus.Specific Hazards:It may not be obvious that carbon black is burning unless the material is stirred and sparks are apparent. Carbon black that has been on fire should be observed closely for at least 48 hours to ensure no smoldering material is present. Burning produces irritant fumes. The product is insoluble and floats on water. If possible, try to contain floating material. This material creates a fire hazard because it floats on water.Hazardous Decomposition and/or Combustion Products:Carbon monoxide, Carbon dioxide, Oxides of sulphur, Organic products of decomposition.Risk of Dust Explosion:Do not create a dust cloud by using a brush or compressed air.26. HANDLING AND STORAGEHandling:Avoid contact with skin and eyes. Do not breathe dust. Provide appropriate exhaust ventilation at machinery and at places where dust can be generated. Do not create adust cloud by using a brush or compressed air. Fine dust is capable of penetratingelectrical equipment and may cause electrical shorts. Take precautionary measuresagainst static discharge.Storage:Keep in a dry, cool and well-ventilated place. Keep away from heat and sources of ignition. Do not store together with strong oxidizing agents. Do not store together with volatile chemicals as they may be adsorbed onto product. Keep in properly labeled containers.7. PHYSICAL AND CHEMICAL PROPERTIESAppearance: Black PelletsOdor: NonepH: 7-10（non-oxidized carbon black）Density: 1.7 - 1.9 g/cm³ @ 20°CBulk Density: 20 - 550 kg/m3Specific Gravity: Not determinedBoiling Point/Range: Not applicableMelting Point/Range: Not applicableVapor Pressure: Not determinedWater Solubility: Soluble% Volatile (by Weight): < 2.5% @ 950°C (non-oxidized carbon black)Evaporation Rate: Not applicableViscosity: Not determinedPartition Coefficient (n-octanol/water): Not determinedFlash Point: Not applicableMethod: Not applicableExplosion Limits in Air - Upper (%): Not determinedExplosion Limits in Air - Lower (%): 50 g/m3 (dust)Autoignition Temperature: > 140°C (transport)3Method: IMDG-CodeMinimum Ignition Temperature: > 350°C (BAM Furnace)Burn Velocity: > 45 seconds(Not cl assifiable as "Highly Flammable” or "Easily Ignitable") Flammability Classification: Not applicable8. STABILITY AND REACTIVITYStability: Stable.Reactivity: May react exothermically upon contact with strong oxidizersIncompatible Materials: Strong oxidizers such as chlorates, bromates, and nitrates.Hazardous Polymerization: Hazardous polymerization does not occur.Mechanical Sensitivity (shock): Not sensitive to mechanical impact.Conditions to Avoid: Do not expose to temperatures above 300°C. Keep away from oxidizing agents in order to avoid exothermic reactions.Hazardous Decomposition and/or Combustion Products:Carbon monoxide, Carbon dioxide, Oxides of sulphur, Organic products ofdecomposition.Static Discharge Effects: Take precautionary measures against static discharges. Avoid dust formation. All metal parts of the mixing and processing equipment must be earthed/grounded. Ensure all equipment is electrically earthed/grounded before beginning transfer operations.9. TOXICOLOGICAL INFORMATIONACUTE TOXICITYOral LD50: LD50/oral/rat = > 8000 mg/kg.Eye Irritation: Rabbit. Draize score 10-17/110 @ 24 hr. Non-irritating.Skin Irritation: Rabbit. 0.6/8. Slight irritation.SUBCHRONIC TOXICITYRat, inhalation, duration 90 daysNOAEL = 1.0 mg/m3Target organ: lungsEffect: inflammation, hyperplasia, fibrosis.CHRONIC TOXICITYRat, oral, duration: 2 yearsEffect: no tumorsMouse, oral, duration: 2 years4Effect: no tumorsMouse, dermal, duration: 18 monthsEffect: no skin tumorsRat, inhalation, duration: 2 yearsTarget organ: lungsEffect: inflammation, fibrosis, tumorsNote: Tumors in the rat lung are related to the fine particle overload phenomenon rather than to a specific chemical effect of the dust particles in the lung. These effects in rats have been reported in studies on other inorganic insoluble particles and appear to be species specific. Tumors have not been observed in other species (i.e., mouse and hamster) for other insoluble particles under similar circumstances and study conditions.Carcinogenic Effects: Substance listed by IARC (International Agency for Research on Cancer). Does not contain any substances listed by NTP (National Toxicology Program), OSHA (Occupational Safety and Health Administration), ACGIH (American Conference for Governmental Industrial Hygienists) or EU (European Union).Carbon Black IARC Statement: In 1995 International Agency for Research on Cancer (IARC) concluded, "There is inadequate evidence in humans for the carcinogenicity of carbon black." Based on rat inhalation studies, IARC concluded that there is "sufficient evidence in experimental animals for the carcinogenicity of carbon black", resulting in their classifying carbon black as "possibly carcinogenic to humans (Group 2B)".Carbon black is not designated a carcinogen by the U.S. National Toxicology Program (NTP), the U.S. Occupational Safety and Health Administration (OSHA), the American Conference of Governmental Industrial Hygienists (ACGIH) or the European Union (EU).The U.S. National Institute of Occupational Safety and Health (NIOSH) 1978 criteria document on carbon black recommends that only carbon blacks with polycyclic aromatic hydrocarbon (PAH) levels greater than 0.1% require the measurement of PAHs in air. As some PAHs are possible human carcinogens, NIOSH recommends an exposure limit of 0.1 mg/m3 for PAHs in air, measured as the cyclohexane-extractable fraction.Epidemiology: Results of epidemiological studies of carbon black production workers suggest that cumulative exposure to carbon black may result in small decrements in lung function, as measured by FEV1. In addition to normal age related decline in the FEV1 of approximately 1200 ml over 40 years, according to a European investigation, exposure to 1 mg/m3 (inhalable fraction) of carbon black over a 40-year lifetime will result in an additional 48 milliliter (ml) decline in FEV1. Asimilar morbidity study in the United States suggested a 27 ml decline in FEV1 from a 1mg/m3 exposure over a 40-year period. The relationship between symptoms and exposure to carbon black is less clear. In the U.S. study, 9% of the highest exposure group (in contrast to 5% of the unexposed group) reported symptoms consistent with chronic bronchitis. In the European study, methodological limitations in the administration of the questionnaire limit the drawing of definitive conclusions about symptoms. This study, however, indicated a link between carbon black and small opacities on the chest films, with negligible effects on lung function. A study of carbon black workers in the UK showed an elevated incidence of lung cancer but it was not considered to be related to carbon black exposure. A study of workers at a large German carbon black manufacturing facility found increased lung cancer mortality among German carbon black workers, but found no apparent dose-response relationship between lung cancer mortality and several indicators of occupational exposure, including years of employment and carbon black exposure. The study concluded that the high lung cancer mortality could not be fully explained by selection, smoking, or other occupational risk factors, but the results also provided little evidence for an effect from carbon black exposure. A recent mortality study of US carbon black workers found no association between employment in carbon black production and lung cancer or any other type of cancer.Mutagenic Effects: A dimethylsulfoxide (DMSO) suspension of carbon black produced negative results in an Ames test. Organic solvent extracts of carbon black, however, can contain traces of5polycylic aromatic hydrocarbons (PAH), which may affect the results in different in-vitro test systems. In an experimental investigation, mutational changes in the hprtgene were reported in alveolar epithelial cells in the rat following inhalation exposure to carbon black. This observation is believed to be rat specific and a consequence of "lung overload" (see Chronic Toxicity above).Reproductive Toxicity: Did not show effects in animal experiments.Sensitizing Effects: Contains no known sensitizers.Synergistic Materials: None reasonably foreseeable.10. ECOLOGICAL INFORMATIONAquatic Toxicity:Fish (Brachydanio rerio): LC50 (96hr) > 1,000 mg/L. (Method: OECD 203).Daphnia magna: EC50 (24hr) > 5,600 mg/L. (Method: OECD 202).Algae (Scenedesmus subspicatus): EC50 (72hr) > 10,000 mg/L.Algae (Scenedesmus subspicatus): NOEC >= 10,000 mg/L.Activated sludge: EC0 (3hr) >= 800 mg/L. (Method: DEV L3 TTC test).ENVIRONMENTAL FATEMobility: Not expected to migrate. Insoluble.Bioaccumulation: Not expected due to physicochemical properties of the substance.Persistence / Degradability: Not expected to degrade.Distribution to Environmental Compartments: Insoluble. Expected to remain on soil surface.11. DISPOSAL CONSIDERATIONSProduct, as supplied, should be disposed of in accordance with the regulations issued by the appropriate federal, state and local authorities. Same consideration should be given to containers and packaging.12. TRANSPORT INFORMATIONThe following organizations do not classify carbon black as a "hazardous cargo" if it is "carbon,non-activated, mineralorigin". Cabot carbon blacks meets this definition.- Canadian Transport of Dangerous Goods Regulation- European Transport of Dangerous Goods Regulation- GGVS, GGVE, RID, ADR, IMDG Code, ICAO-TI- United Nations (no UN number)- US Department of TransportationCAS NO 1333-86-4UN Number: 1361UN Proper Shipping Name: Not classifiedUN Shipping Class: Not classified6UN Packing Group: Not classifiedInternational TransportationIdentification:"Carbon black, non-activated, mineral origin".Not dangerous according to IMDG-Code.Not dangerous according to ICAO-TI.US Rail Regulations: Not classified13. ACCIDENTAL RELEASE MEASURESPersonal Precautions: CAUTION: Wet carbon black produces slippery walking surfaces. Avoid dust formation. Ensure adequate ventilation. Use personal protective equipment. See alsoSection 8.Methods for Cleaning Up: Clean up promptly by vacuum. Use of a vacuum with high efficiency particulate air(HEPA) filtration is recommended. Do not create a dust cloud by using a brush orcompressed air. Pick up and transfer to properly labelled containers. See Section 13.Environmental Precautions: Do not allow material to contaminate ground water system. The product is insolubleand floats on water. If possible, try to contain floating material. Local authoritiesshould be advised if significant spillages cannot be contained.14. EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE LIMITSThe table below is a summary. Please see the specific legislation for complete information.Carbon Black, CAS RN 1333-86-4: Australia: 3.0 mg/m3, TWABelgium - OEL: 3.6 mg/m3, TWACanada: 3.5 mg/m3, TWAChina: 4.0 mg/m3, TWA8.0 mg/m3, STELFinland: 3.5 mg/m3, TWA7.0 mg/m3, STELFrance - INRS: 3.5 mg/m3, TWA/VMEGermany - TRGS 900: 3.0 mg/m3, respirable TWA10.0 mg/m3, inhalable TWAGermany - MAKs: 1.5 mg/m3, respirable TWA4.0 mg/m3, inhalable TWAIreland: 3.5 mg/m3, TWA7.0 mg/m3, STELItaly - OEL: 3.5 mg/m3, TWAKorea: 3.5 mg/m3, TWANetherlands - MAC: 3.5 mg/m3, TWA7Norway: 3.5 mg/m3, TWASpain: 3.5 mg/m3, TWASweden - TLV: 3.0 mg/m3, TWAUnited Kingdom - WEL: 3.5 mg/m3, inhalable TWA (a)7.0 mg/m3, inhalable STELUS ACGIH - TLV: 3.5 mg/m3, TWAUS OSHA - PEL: 3.5 mg/m3, TWANote: Unless otherwise indicated as "respirable" or "inhalable", the exposure limitrepresents a "total" value. The inhalable exposure limit has been demonstrated to bemore restrictive than the total exposure limit, by a factor of approximately 3.15. STABILITY AND REACTIVITYStability: Stable.Reactivity: May react exothermically upon contact with strong oxidizers.Cabot Corporation___________________________________________________________________ ______Product Name: REGAL 250R Product Code: R250R Revision Date: 18/June/2007 Page 6 of 10 Incompatible Materials: Strong oxidizers such as chlorates, bromates, and nitrates.Hazardous Polymerization: Hazardous polymerization does not occur.Mechanical Sensitivity (shock): Not sensitive to mechanical impact.Conditions to Avoid: Do not expose to temperatures above 300°C. Keep away from oxidizing agents inorder to avoid exothermic reactions.Hazardous Decomposition and/orCombustion Products:Carbon monoxide, Carbon dioxide, Oxides of sulphur, Organic products ofdecomposition.Static Discharge Effects: Take precautionary measures against static discharges. Avoid dust formation. Allmetal parts of the mixing and processing equipment must be earthed/grounded.Ensure all equipment is electrically earthed/grounded before beginning transferoperations.16. OTHER INFORMATIONCarbon Black Extracts:Manufactured carbon blacks generally contain less than 0.1% of solvent extractable polycyclic aromatic hydrocarbons(PAH). Solvent extractable PAH content depends on numerous factors including, but not limited to, the manufacturingprocess, desired product specifications, and the analytical procedure used to measure and identify solvent extractable8materials. Questions concerning PAH content of carbon black and analytical procedures should be addressed to yourcarbon black supplier.General Information:The carbon black industry continues to sponsor research designed to identify adverse health effects from long termexposure to carbon black. This MSDS will be updated as new safety and health information may become available.9。
炭黑MSDS通用安全技术说明书
化学品安全技术说明书1、企业资质认证产品名称：N炭黑别名：炭黑，炉法炭黑材料应用：各种工业产品供应商：炭黑有限公司地址：中国68号联系电话： 666 传真： 8882、炭黑的组成成分3、危险性概述危害显示：本品为非危险物品主要接触途径：吸入，眼睛接触，皮肤接触。
潜在的健康影响：眼睛接触：可能引起机械刺激。
但是不会永久的伤害眼膜。
对于平常的工业或商业接触有较低的危害。
皮肤接触：无已知的不良反应。
吸入：粉尘可能刺激呼吸道。
应对机器设备和能够产生灰尘的地方提供适当的排气通风。
另请参阅第8部分。
食入：正常使用下不会出现已知的健康损伤。
对于平常的工业或商业接触只有较低的危害。
致癌影响：国际癌症研究机构列出的物品。
另请参阅第9部分。
主要影响器官：肺。
暴露恶化的疾病：哮喘，呼吸障碍潜在的环境影响：不需要特别的环境预防措施。
不溶解于水。
另请参阅第12部分。
4、急救措施皮肤接触：应用肥皂和水彻底清洗。
若症状加重，请就医。
眼睛接触：应立即用大量的水冲洗眼睛15分钟。
若症状加重，请就医。
吸入：如果咳嗽，呼吸急促或者发生其他呼吸问题，请移到其他地方呼吸新鲜空气。
若症状无好转，请就医。
如果有必要的话，请通过标准的急救措施来恢复正常呼吸。
食入：不要催吐，如清醒，给予几杯水，千万不要给休克的人通过口腔喂任何东西。
医生提示：请根据症状处理。
5、消防措施灭火器：应使用泡沫，二氧化碳，干粉或者水喷雾。
如果已经使用过水，推荐使用水雾。
不要使用强直流水，因为它可能溅射扩散火苗。
消防员的特殊防护装备：要穿戴合适的防护装备。
发生火灾时，应佩带独立的呼吸设备。
具体危害：炭黑燃烧时可能不明显，除非搅拌时出现火花。
对已经着火的炭黑，我们应该严密地观察至少48小时以确保无隐燃存在。
燃烧会产生刺激性的烟气。
该产品不能溶解的，并且漂浮在水上。
如果可能，设法控制悬浮物质。
该物质会产生火灾隐患，因为它漂浮在水上。
分解或燃烧产生的危害物：一氧化碳，二氧化碳，硫的氧化物，分解的有机产物。
carbonblack-MSDS
Revision date: September 5, 2013Safety Data Sheet(Carbon Black)According to the Globally Harmonized System of Classification and Labeling of Chemicals (GHS)1.1Product name Carbon Black (all grades)1.2Manufacturer/supplier Sid Richardson Carbon & Energy Co.3560 W. Market Street, Suite 420Akron, OH 443331.3Emergency numbers for spills, leak, fire, exposure, or accidentCHEMTREC: 1-800-424-9300 (US)CANUTEC: 613-996-6666 (Canada)For all other inquiries about this product(330) 666-2777 – Day(800) 767-2227 – Night/Weekend1.4 Regulation (EC) No. 1907/2006 REACH Registration Number 01-2119384822-32-XXXX1.5 Use of substance/preparation Additive and filler for plastics, rubber, pigments, and other specialtyproducts2.1Globally Harmonized System of Classification and Labeling of Chemicals hazard identificationNot a hazardous substance or preparation under GHS. Not a hazardous substance or preparation under EC-directives 67/548/EEC or 1999/45/EC and their various amendments and adaptations. Not hazardoussubstance or preparation under CLP-Regulation (EC) No 1272/2008. Does not contain any of the“Candidate List of Substances of Very High Concern” (SVHC) at levels >0.1 % as defined in the REACH legislation.In 1995 IARC concluded, “There is inadequate evidence in humans for the carcinogenicity of carbonblack.” Based on rat inhalation studies IARC concluded that there is “sufficient evidence in exp erimental animals for the carcinogenicity of carbon black,” IARC’s overall evaluation was that “Carbon black ispossibly carcinogenic to humans (Group 2B).” This conclusion was based on IARC’s guidelines, whichrequire such a classification if one animal species exhibits carcinogenicity in two or more studies. Lungtumors in rats are the result of exposure under “lung overload” conditions. The development of lung tumors in rats is specific to this species. Mouse and hamster showed no carcinogenicity in similar studies.In 2006 IARC re-affirmed its 1995 classification of carbon black as, Group 2B (possibly carcinogenic tohumans).Overall, as a result of the detailed epidemiological investigations, no causative link between carbon black exposure and cancer risk in humans has been demonstrated. This view is consistent with the IARCevaluation in 2006. Furthermore, several epidemiological and clinical studies of workers in the carbonblack production industries show no evidence of clinically significant adverse health effects due tooccupational exposure to carbon black. No dose response relationship was observed in workers exposed to carbon black.Applying the rules of the Globally Harmonized System of Classification and Labeling (GHS, e.g. UN`Purple Book´ , EU CLP Regulation) the results of repeated dose toxicity and carcinogenicity studies inanimals do not lead to classification of Carbon Black for Specific target organ toxicity (Repeated exposure) and carcinogenicity. UN GHS says that even if adverse effects are seen in animal studies or in-vitro tests, no classification is needed if the mechanism or mode of action is not relevant to humans. The EuropeanCLP Regulation also mentions, that no classification is indicated if the mechanism is not relevant tohumans. Furthermore, the CLP guidance on classification and labeling states, that “lung overload” inanimals is listed under mechanism not relevant to humans.2.2 Emergency OverviewA black, odorless powder, which can burn or smolder at temperatures greater than 572ºF (>300ºC).Hazardous products of decomposition can include carbon monoxide, carbon dioxide, and oxides of sulfur.May cause mechanical irritation to the eyes and the respiratory tract especially at concentrations above the occupational exposure limit. Some grades of carbon black are sufficiently electrically non-conductive to allow a buildup of static charge during handling. Take measures to prevent the build up of electrostaticcharge.2.3 Routes of Exposure: Inhalation, eye and skin2.4 Potential Health EffectsInhalation: Temporary discomfort to upper respiratory tract may occur due to mechanical irritation when exposures are well above the occupational exposure limit. Long-term exposure may result in a small non-clinically significant increase in normal loss in one aspect of lung function (FEV1).(See Section 11)Ingestion: No evidence of adverse effects from available data.Eye: High dust concentrations may cause mechanical irritation to eye.Skin: May cause mechanical irritation, soiling and drying of skin.Sensitization: No cases of sensitization in humans have been reportedChronic: IARC listed; Group 2B (possibly carcinogenic to humans). Not listed as a carcinogen by NTP,ACGIH, OSHA or the European Union. (See Section 11)There are no known human carcinogenic effects related to the PAH content of carbon blacks. Recentresearch has shown that the PAH content of carbon blacks is not released from carbon black in biological fluids and thus not available for biological activity.2.5 Potential Environmental EffectsNo significant environmental hazards are associated with carbon black release to the environment. Carbon black is not soluble in water. (See Section 12)3.1 Component(s)Carbon Black, amorphous (100%)Chemical formula: CCAS number: 1333-86-4EINECS number: 215-609-94.1 First aid proceduresInhalation: Take affected persons out in fresh air, if necessary.Skin: Wash skin with mild soap and water. If symptoms develop, seek medical attention.Eye: Rinse eyes thoroughly with plenty of water keeping eyelid open. If symptoms develop, seek medicalattention.Ingestion: Do not induce vomiting. If conscious, rinse mouth with water.4.2Note to physicians: Treat symptomatically5.1 Extinguishing MediaUse foam, carbon dioxide (CO2), dry chemical, or water spray. Avoid high-pressure water stream as this may spread burning powder (burning powder will float). A fog spray is recommended if water is used.NOTE: It may not be obvious that carbon black is burning unless the material is stirred and sparks are apparent. Carbon black that has been on fire should be observed closely for at least 48 hours to ensure no smoldering material is present.5.2 Protection of FirefightersProducts of combustion include carbon monoxide (CO), carbon dioxide (CO2), and oxides of sulfur. Wear full protective fire fighting gear including self-contained breathing apparatus (SCBA).NOTE: Wet carbon black produces dangerously slippery walking surfaces. Small spills should be vacuumed when possible. Dry sweeping is not recommended. A vacuum equipped with HEPA (high efficiency particulate air) filtration is recommended. If necessary, light water spray will reduce dust for dry sweeping. Large spills may be shoveled into containers. (See Section 13) Wear appropriate personal protective equipment and respiratory protection. (See Section 8)Carbon black poses no significant environmental hazards. As a matter of good practice, minimize contamination of sewage water, soil, groundwater, drainage systems, or bodies of water.7.1 HandlingAvoid dust exposures above the occupational exposure limit. Wash exposed skin daily. Use local exhaust ventilation to control exposures to below occupational exposure limit. Fine dust may cause electrical shorts and is capable of penetrating electrical equipment unless tightly sealed. If hot work (welding, torch cutting, etc.) is required the immediate work area must be cleared of carbon black product and dust.7.2 StorageStore in dry place away from ignition sources and strong oxidizers. Before entering closed vessels andconfined spaces containing carbon black test for adequate oxygen, flammable gases and potential toxic air contaminants (e.g., CO). Follow safe practices when entering confined spaces.8.1 Exposure guidelinesOES = occupational exposure standardPEL = permissible exposure limitREL = recommended exposure limitSTEL = short-term exposure limitTWA = 8-hour time weighted average8.2 Engineering controlsUse process enclosures and/or exhaust ventilation to keep airborne dust concentrations below theoccupational exposure limit.8.3 Personal Protective Equipment (PPE)No special PPE required. Gloves may be used to protect hands from carbon black soiling. Work clothesshould not be taken home and should be washed daily. Eye protection recommended as a matter of goodindustrial safety practice.Skin Protection: Wash hands and other exposed skin with mild soap and use skin cream to prevent skin drying.Respiratory Protection: An approved air-purifying respirator (APR) may be used where airborneconcentrations are expected to exceed occupational exposure limits. Protection provided by APRs islimited. Use a positive-pressure, air supplied respirator if there is any potential for uncontrolled release,exposure levels are not known, or any circumstances where air-purifying respirators may not provideadequate protection. A complete respiratory protection program in accordance with national standards and current best practices must accompany use of any respirator.8.4General Hygiene ConsiderationsWash hands and face thoroughly with mild soap before eating and drinking. Frequent skin washing maydry skin. Application of a skin lotion is recommended.Appearance: powder or pelletColor: blackOdor: odorlessMolecular formula: CMolecular weight (as carbon): 12Melting point/range: not applicableBoiling point/range: not applicableVapor pressure : not applicableDensity: (20ºC) 1.7 – 1.9 g/cm3Bulk density: 20 – 550 kg/m3Solubility: insoluble in waterpH value: >7 [50 g/l water, 68ºF (20ºC)]Partition coefficient: not applicableViscosity: not applicableFlammable and Explosive PropertiesFlashpoint not applicableSpontaneous Ignition (transport): >284ºF (>140ºC)Explosive Limits (dust):Furnace black1Lower 50 g/m3Upper not determinedMaximum Absolute Explosion Pressure110 barMaximum Rate of Pressure Rise130-100 bar/sec.Dust Explosion Class2ST 1Ignition Energy1Furnace black >1 kJMinimum Ignition Temperature1Method: VDI 2263 (BAM Furnace) >932ºF (>500ºC)Goldberg-Greenwald Furnace >600ºF (>315ºC)Minimum Ignition Energy1>10 JBurn Velocity2(not clas sifiable as “Highly Flammable”, or “Easily Ignitable”)>45 secondsFlammability Classification (as defined by OSHA 1910.1200): not applicable1German VDI Guideline 2263, Test Methods for the Determination of the Safety Characteristics of Dusts.2German VDI Guideline 2263 and EC Directive 84/449Stability: stable under normal ambient conditionsDecomposition: >572ºF (>300ºC)Conditions to avoid: exposure to high temp. >572ºF (>300ºC) and open flamesMaterials to avoid: strong oxidizers such as chlorates, bromates, and nitratesHazardous decomposition products: carbon monoxide, carbon dioxide, organic products of decomposition, oxides or sulfur (sulfoxides) form if heated above decomposition temperatureHazardous polymerization: will not occur11.1 Acute ToxicityAcute oral toxicity: LD50 (rat), > 8000 mg/kgPrimary skin irritation:rabbit: non-irritative, index score 0.6/8 (4.0 = severe edema)Primary eye irritation:rabbit: non-irritative, Draize score 10-17/110(100 = maximally irritating)11.2 Subchronic toxicityRat, inhalation, duration 90 days, NOAEL – 1.0 mg/m3 (respirable)Target organ: lungs;Effect: inflammation, hyperplasia, fibrosis11.3 Chronic toxicityRat, oral, duration 2 yearsEffect: no tumorsMouse, oral, duration 2 yearsEffect: no tumorsMouse, derma, duration 18 monthsEffect: no skin tumorsRat, inhalation, duration 2 yearsTarget organ: lungsEffect: inflammation, fibrosis, tumorsNote: Tumors in the rat lung are considered to be related to the “particle overload phenomenon” ratherthan to a specific chemical effect of carbon black itself in the lung. These effects in rats have been reported in many studies on other poorly soluble inorganic particles and appear to be rat specific. Tumors have not been observed in other species (i.e., mouse and hamster) for carbon black or other poorly soluble particles under similar circumstances and study conditions.11.4 SensitizationNo evidence of sensitization was found in animals.No cases of sensitization in humans have been reported.11.5 CarcinogenicityTumor development in Rats caused by lung overload, no epidemiological evidence for lung tumors inHumans.Lung tumors in rats are the result of exp osure under “lung overload” conditions. The development of lung tumors in rats is specific to this species. Mouse and hamster do not develop lung tumors under similar test conditions. The CLP guidance on classification and labeling states, that “lung overl oad“ in animals is listed under mechanism not relevant to humans.IARC listed: Group 2B (possibly carcinogenic to humans). Not listed as a human carcinogen by NTP,ACGIH, OSHA, or the European Union. ACGIH listed as A3 Confirmed animal carcinogen with unknown relevance to humans: The agent is carcinogenic in experimental animals at a relatively high dose, byroute(s) of administration, at site(s), of histological type(s), or by mechanism(s) that may not be relevant to worker exposure. Available epidemiologic studies do not confirm an increased risk of cancer in exposedhumans. Available evidence does not suggest that the agent is likely to cause cancer in humans exceptunder uncommon or unlikely routes or levels of exposure.11.6 Mutagenic effectsIn VitroCarbon black is not suitable to be tested in bacterial (Ames test) and other in vitro systems because of itsinsolubility. When tested, however, results for carbon black showed no mutagenic effects. Organic solvent extracts of carbon black can, however, contain traces of polycyclic aromatic hydrocarbons (PAHs). Astudy to examine the bioavailability of these PAHs showed that PAHs are very tightly bound to carbonblack and not bioavailable.In VivoIn an experimental investigation, mutational changes in the hprt gene were reported in alveolar epithelialcells in the rat following inhalation exposure to carbon black. This observation is believed to be rat specific and a consequence of “lung overload” which led to chronic inflammation and release of oxy gen species.(see Chronic toxicity above). This is considered to be a secondary genotoxic effect and, thus, carbon black itself would not be considered to be mutagenic.11.7 Reproductive effectsNo effects have been reported in long-term animal studies.11.8 EpidemiologyResults of epidemiological studies of carbon black production workers suggest that cumulative exposure to carbon black may result in small decrements in lung function. A recent U.S. respiratory morbidity studysuggested a 27 ml decline in FEV1 from a 1 mg/m3 (inhalable fraction) exposure over a 40-year period. An older European investigation suggested that exposure to 1 mg/m3 (inhalable fraction) of carbon black over a 40-year working lifetime would result in a 48 ml decline in FEV1. However, the estimates from bothstudies were only of borderline statistical significance. Normal age-related decline over a similar period of time would be approximately 1200 ml.The relationship between other respiratory symptoms and exposure to carbon black is even less clear. Inthe U.S. study, 9% of the highest exposure group (in contrast to 5% of the unexposed group) reportedsymptoms consistent with chronic bronchitis. In the European study, methodological limitations in theadministration of the questionnaire limit the conclusions that can be drawn about reported symptoms. This study, however, indicated a link between carbon black and small opacities on chest films, with negligibleeffects on lung function.A study on carbon black production workers in the UK (Sorahan et al 2001) found an increased risk of lungcancer in two of the five plants studied; however, the increase was not related to the dose of carbon black.Thus, the authors did not consider the increased risk in lung cancer to be due to carbon black exposure. A German study of carbon black workers at one plant (Wellmann et al. 2006, Morfeld et al. 2006(a), Buechte et al. 2006, Morfeld et al. 2006(b)) found a similar increase in lung cancer risk but, like the 2001 UK study, found no association with carbon black exposure. In contrast, a large US study (Dell et al. 2006) of 18plants showed a reduction in lung cancer risk in carbon black production workers. Based upon thesestudies, the February 2006 Working Group at IARC concluded that the human evidence for carcinogenicity was inadequate (Baan et al. 2006).Since this IARC evaluation of carbon black, Sorahan and Harrington (2007) re-analyzed the UK study data using an alternative exposure hypothesis and found a positive association with carbon black exposure intwo of the five plants. The same exposure hypothesis was applied by Morfeld and McCunney (2007) to the German cohort; in contrast, they found no association between carbon black exposure and lung cancer risk and, thus, no support for the alternative exposure hypothesis used by Sorahan and Harrington. Overall, as a result of these detailed investigations, no causative link between carbon black exposure and cancer risk in humans has been demonstrated. This view is consistent with the IARC evaluation in 2006.EcotoxicityAquatic toxicity: Acute fish toxicity: LC50 (96 h) > 1000mg/l, Brachydanio rerio (zebrafish), (OECD Guideline 203).Acute water flea toxicity: EC50 (24 h) > 5600 mg/l. Daphnia magna (waterflea), (OECD Guideline 202).Acute algae toxicity: EC 50 (72 h) >10,000 mg/l NOEC 50 >10,000 mg/l (Scenedesmus subspicatus), (OECD Guideline 201)Behavior in water treatment plants: Activated sludge, EC0 (3 h) >= 800 mg/l. DEV L3 (TTC test)Mobility: Not soluble in water.Bioaccumulation: Potential bioaccumulation is not expected because of physio-chemical properties of thesubstance.Product can be burned in suitable incineration plants or disposed of in a suitable landfill in accordance with the regulations of the appropriate federal, provincial, state and local authorities.EU - See European Waste Catalogue (Council Directive 75/422/EEC).U.S. - Not a hazardous waste under U.S. RCRA, 40 CFR 261.Canada - Not a hazardous waste under provincial regulations.Container/Packaging - Return reusable containers to manufacturer. Paper bags may be incinerated, recycled, ordisposed of in an appropriate landfill in accordance with national and local laws.Carbon black is not classified as a hazardous material by the following country regulations/agencies:Canadian Transport of Dangerous Goods RegulationEuropean Transport of Dangerous Goods RegulationsGGVS, GGVE, RID, ADR, IMDG Code, ICAO-TIUnited Nations ( no UN number)U.S. Department of TransportationInternational transportation identification:“Carbon black, non-activated, mineral origin”Not dangerous according to IMDG-CodeNot dangerous according to ICAO-TIUN Shipping Class: Not classified.UN Packing Group: Not classified.U.S. Rail Regulations: Not classified.15.1 European Union (EU)Classification: Not defined as a dangerous substance or preparation according to Council Directive67/548/EEC and its various amendments and adaptations.Symbol: None required15.2Germany: water classification.WGK Number (Kenn-Nr): 1742. WGK Class (Wassergefährdungsklasse):nwg (non-hazardous to waters). Not a hazardous substance as defined by the Chemicals Act or HazardousSubstance Ordinance.15.3Canada: WHMIS Classification: D2AStatement of Equivalence: "This product has been classified in accordance with the hazard criteria of theControlled Products Regulations and the MSDS contains all the information required by the ControlledProducts Regulations." Ingredient Disclosure List: Contains carbon black. See Section 2.15.4United StatesFederal RegulationsSuperfund Amendments and Reauthorization Act (SARA) Title IIISection 313 Toxic Substances: Does not contain any components subject to this section.Toxic Release Inventory (TRI): Under EPA’s Toxics Release Inventory (TRI) program the reporting threshold for21 Polycyclic Aromatic Compounds (PACs) has been lowered to 100 pounds per year manufactured, processed, orotherwise used. (64 CFR 58666, Oct. 29, 1999) The 100 pounds/yr applies to the cumulative total of 21 specific PACs. Carbon black may contain certain of these PACs and the user is advised to evaluate their own TRI reporting responsibilities.State RegulationsCalifornia Safe Drinking Water and Toxics Enforcement Act of 1986(Proposition 65): "Carbon black (airborne, unbound particles of respirable size)" is a CaliforniaProposition 65 listed substance. All three listing qualifiers (airborne, unbound (not bound within a matrix),and respirable size (10 micrometers or less in diameter)) must be met for this substance to be considered aProposition 65 listed substance.15.5 Inventory StatusAll components either are listed on or exempt from the following inventories:Australia: Australian Inventory of Chemical Substances (AICS)Canada: Domestic Substances List (DSL)China: Inventory of Existing Chemical SubstancesEuropean Union: European Inventory of Existing Commercial Chemical Substances (EINECS) No. 215-609-9.Japan: Existing and New Chemical Substances (ENCS) No. 5-3328.Korea: Existing Chemical Substances List (ECL) No. KE-04882New Zealand: Hazardous Substances and New Organisms Act, approval code HSR002801 (New ZealandInventory of ChemicalsPhilippines: Philippine Inventory of Chemicals and Chemical Substances (PICCS)United States: Toxic Substances Control Act (TSCA)16.1Polycyclic Aromatic Hydrocarbon (PAH) Content. Manufactured carbon blacks generally contain less than0.1% of solvent extractable polycyclic aromatic hydrocarbons (PAH). Solvent extractable PAH contentdepends on numerous factors including, but not limited to, the manufacturing process, desired productspecifications, and the analytical procedure used to measure and identify solvent extractable materials.Questions concerning PAH content of carbon black and analytical procedures should be addressed to yourcarbon black supplier.16.2National Fire Protection Association (NFPA) Rating:Health: 0Flammability: 1Reactivity: 00 = minimal, 1 = slight, 2 = moderate, 3 = serious, 4 = severe[Note: Chronic effects are not taken into consideration in the NFPA rating ]16.3 Hazardous Materials Identification System® (HMIS®) Rating:Health: 1*Flammability: 1Physical Hazard: 00 = minimal, 1 = slight, 2 = moderate, 3 = serious, 4 = severeHMIS® is a registered trademark of the National Paint and Coatings Association[Note: the Health rating is a "1*". The asterisk must be added to represent the chronic hazard (carbonblack listed on IARC)]DisclaimerThe data and information presented herein corresponds to the present state of our knowledge and experience andis intended to describe our product with respect to possible occupational safety and health concerns. The user ofthis product has sole responsibility to determine the suitability of the product for any use and manner of use intended, and for determining the regulations applicable to such use in the relevant jurisdiction. This MSDS is updated on a periodic basis in accordance with applicable health and safety standards.。
安全周知卡(炭黑)
安全周知卡
危险性提示词品名危险性标志
可燃有毒炭黑用焦化原料油
危险性理化数据：中闪点；密度：1.21 ；
颜色：棕黑色气味：味中
燃烧爆炸危险特性：蒸汽可引起眼及上呼吸道刺激；吸入液态可引起吸入性肺炎；摄入可引起口腔、咽喉和胃肠道刺激慢性影响：神经衰弱、眼及呼吸道刺激症状，接触性皮炎，干燥等皮肤损害。
接触后表现：损害一般无特异性，症状取决于接触物物理化学性质、浓度，接触方式，接触时间长短。
轻者仅局部出现水肿性红斑和豆疹，重者发展到形成水疱，大疮，糜烂、溃疡、坏死。
自觉瘙痒、灼热、肿痛，严重者头痛、恶心、发热、畏寒。
现场急救措施：
皮肤接触：脱去污染衣着，用肥皂水或清水彻底冲洗。
眼睛接触：立即提起眼睑，用流动清水冲洗10分钟或2%碳酸氢钠溶液冲洗。
吸入：迅速脱离现场到空气新鲜处。
呼吸困难时输氧。
呼吸停止时进行人工呼吸。
就医。
食入：患者清醒时立即漱口，如发生呕吐，使其取侧卧位，防止呕吐物进入气管。
就医。
身体防护措施：
泄漏处置：
消防措施：
容许浓度mg/m3当地应急救援单位名称当地营救救援电话。
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blacks. The foregoing are registered trade names of Cabot Corporation, and denote
physical differences in carbon black grades.
Manufacturer抯 Product Code: Not applicable.
MSDS
Page 2 of 6
MATERIAL SAFETY DATA SHEET
Swallowed: None expected.
Eye: Mechanical irritant with no adverse effects.
Skin: None expected but may dry skin with prolonged exposures. Use of quality barrier cream can prevent skin dryness.
Inhaled: None expected. Temporary discomfort to the upper respiratory tract may occur due to inhalation of dust concentrations above the OEL.
Human Studies: Epidemiological studies of workers in the carbon black producing industries of North America and Western Europe show no evidence of clinically significant, adverse health effects due to occupational exposure to carbon black.
Animal Toxicity Studies: Cabot carbon black contains less than 0.1% of adsorbed PAHs (polynuclear aromatic hydrocarbons). In non-adsorbed form, some PAHs have been found to be carcinogens in animal studies. No correlating carcinogenic effect, however, has been observed in humans due to exposure to carbon black. Chronic inflammation, lung fibrosis, and lung tumours have been observed in some rats experimentally exposed, for long periods of time, to excessive concentrations of carbon black and several other insoluble fine dust particles. Tumors have not been observed in other animal species (i.e. mouse and hamster) under similar circumstances and study conditions. Many researchers conducting rat inhalation studies believe that these effects most likely result from the massive accumulation of small dust particles in the lung which overwhelm the natural lung clearance mechanisms, known as the 搇 ung overload” phenomenon, rather than from a specific chemical effect of the dust particles in the lung.
MATERIAL SAFETY DATA SHEET
PHYSICAL DESCRIPTION / PROPERTIES:
Appearance: Odourless, amorphous black inert solids, pellets or powder.
Boiling Point / Melting Point: Nallocated.
Dangerous Goods Class and Subsidiary Risk: No listed in <Dangerous Goods list GB 12268-90>
Hazchem Code: No listed in <Dangerous Goods list GB 12268-90>
IDENTIFICATION
Product Name: Carbon black.
Other Names:
ACARB®, STERLING®, TINTACARB®, BLACK PEARLS®
VULCAN®, REGAL®, ELFTEX®, MOGUL®, MONARCH®, IRX®, CRX® and CSX® carbon
IARC Classifications:
Class 1 substances are known human carcinogens, Class 2a substances are probable human carcinogens, Class 2b substances are possible human carcinogens, Class 3 substances have insufficient data to determine whether they might be human carcinogens, Class 4 substances are probably not human carcinogens.
Early studies in the former USSR and Eastern Europe report respiratory diseases among workers exposed to carbon black, including bronchitis, pneumoconiosis, emphysema and rhinitis. Such studies are of questionable validity, due to inadequate study design and methodology, lack of appropriate controls for cigarette smoking and other confounding factors, such as concurrent exposures to carbon monoxide, coal oil and petroleum vapours. Moreover, review of these studies indicates that concentrations of carbon black were greater than current occupational exposure standards. In its Monograph Volume 65, issued in April 1996, the International Agency for Research on Cancer (IARC) re-evaluated carbon black and concluded that 搕here is inadequate evidence in humans for the carcinogenicity of carbon black”.
Solubility in Water: Insoluble. Recommended Occupational Exposure Limit: 8.0 mg / m3 (Black powder sanitation
standard in the air of workshop GB-10330-89) Reference to China National Standard
COMPANY DETAILS:
Company:
Shanghai Cabot Chemical Co., Ltd.
Address:
15 Shuang Bai Road, Shanghai, China 201108
Telephone:
(86)21-64345809
Facsimile:
(86)21-64345532
英文根据上海卡博特的需要更正 Date of Issue: 22 November, 1996
Shanghai Cabot Chemical Co., Ltd.
MATERIAL SAFETY DATA SHEET
STATEMENT OF HAZARDOUS NATURE Currently under review.
Chronic:
NOTE: In April 1996, IARC (International Agency for Research on Cancer) issued a Monograph that changed its evaluation of carbon black from a Class 3 substance - that is, a substance with inadequate information to determine if it is carcinogenic to a Class 2b substance - that is, a substance that is a possible human carcinogen. It is now classified in Class 2b with other well known items such as coffee, saccharin and petrol.