生物柴油的傻瓜式制作方法
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water consumption. This process takes care of the free fatty acids. 生物柴油生产中必须避免成皂。皂会降低得率,因为皂会使甲酯
与水结合而损失。并且使分离困难! In one early test I used a mixture of 50% heavily used cooking oil
m is a water-soluble salt and is removed in the wash. No sulphur remains in co the biodiesel fuel product.
. 第二步生成硫酸钠,可以水洗掉。 qun 设备 Equipment 坛 un You don't need a special processor for the Foolproof method. 论 l 鼓吹傻瓜法。 油 b. Generally, a bottom-drained reactor vessel is best, closed on top. Tall, 柴 l. narrow containers work better than wide, shallow ones. 物 se 用一个底部钻孔、顶部封闭的容器。狭长的比宽矮的容器好。 生 ie Use a circulating pump for mixing rather than a mechanical stirrer. od The pump should take the mixture from near the bottom of the reactor bi and return it via the top, to splash down on the surface. For a 35-litre // reactor, a 100-W washing-machine pump will do, p: 用循环泵混合比用机械搅拌好。泵打通反应器底部和顶部,反应 htt 液由顶部喷出。35L 的反应容器可以用 100w 的洗衣机泵。
thermostat to control the temperature, but they're expensive: just use a thermometer and switch on the heater as required.
用 1.5kW 加热器加热,加热器外包不锈钢。(译者Hale Waihona Puke Baidu:我见过用 “热得快”的)温度计。
ions combine with free fatty acids present in used (and some virgin) vegetable oils and animal fats. The soaps diminish the yield because they bond the methyl esters to water. The bonded esters get washed out at the washing stage but make water separation more difficult and increase
靠,还得先把家里的洗衣机拆了!是整傻瓜的吧~~ (译者注: 可以用搅拌代替)
along with a 1.5kW washing-machine immersion heater to heat the mixture (get a heater that's coated with stainless steel). You could use a
More concentrated sulphuric acid -- 98% and above -- costs more, but 95% works just fine if you follow these directions. Other acids won't work: it must be sulphuric acid. The second stage uses lye, as usual -- but it only uses about half as much as other methods.
酯化用 95%的硫酸,98% 的较贵。老外真罗嗦! 第二步的碱用量是其它方法的一半。“其它方法”是多少?鬼才 知道! The sulfate ion in the sulphuric acid combines with the sodium ion in the lye during the second-stage reaction to form sodium sulphate, which
Ordinary iron and steel implements and containers will eventually corrode because of the acid used in this process. However, you can still use the usual 55-gal (200-litre) drum. The proportion of acid used in this process is very low -- you should be able to use an uncoated drum for a year or more before the rust gets out of control.
采用 50%的“极度”煎炸油和 50%的猪油为原料测试。产品绝对 无皂痕迹,闻起来很香。就像是用精油做的。
m ----喝一口尝尝^_^ co Aleks (background) and friend Matevz making biodiesel in Matevz's n. living room. u 家里做的。 坛 unq This is a simple procedure. The first-stage process is not 论 l transesterification, but pure and simple ESTERIFICATION. Esterification 油 b. is followed by transesterification, but under acid conditions it's much 柴 l. slower than under caustic conditions and it won't do a complete 物 se oil-to-methyl ester conversion as the reaction is much more 生 ie equilibrium-sensitive. Without methanol recovery, the alcohol overdose od required would make the price of your fuel jump, and even with recovery bi it would still be much more expensive. Hence the second base-stage. // 第一步酯化,第二步酯交换。因为化学平衡的原因,酯化步骤较 p: 慢且不完全。 htt For the first stage you'll form a compound out of an acid and an
生物柴油的“傻瓜式”制作方法
编译:smlzbb PDF 制作:eyht 生物柴油论坛版权所有 http://biodiesel.b.lunqun.com
友情推荐国外流行的家庭作坊式生产工艺,又称为生物柴油的 “傻瓜式”制作方法。本工艺最大的特定是设备简单、操作方便。工 艺来源英文资料,不提供逐句翻译,但对重要之处会一一点出。
qu 不需复杂设备!不然能叫“傻瓜式”吗? 坛 un This is a two-stage procedure, acid first-stage, base second-stage. It 论 .l is based on the highest free fatty acid (FFA) content found in used 油 .b cooking oil, but it can be used with any waste vegetable/animal oil or fat, 柴 el whether or not it has a high FFA content. The process increases yields 物 es dramatically. Use it as your standard method. 生 di 采用酸碱两步法,无论是含高 FFA 还是低 FFA 的废植物油普遍 io 适用此方法。 /b Introduction :/ To make biodiesel fuel efficiently from used vegetable oils and tp animal fats we have to avoid one major problem: soap formation. Soap is ht formed during base-catalyzed transesterification (using lye) when sodium
alcohol. The alcohol is still methanol, but instead of using lye (sodium hydroxide), the CATALYST in this reaction is sulphuric acid ("battery acid"). It needs 95% sulphuric acid (battery acid is around 50%). Sulphuric acid is one of the commonest chemicals on Earth, just like lye.
and 50% pork lard. The result was a pure product with absolutely no trace of soap! The biodiesel looked nice, and smelt nice, as if made from virgin oil.
The FOOLPROOF way to make biodiesel By Aleks Kac
m This is a FOOLPROOF way to make biodiesel. No titration is co required, and no extra equipment or special equipment -- a thermometer's n. handy, but NO pH meter!
m 由于酸存在,普通钢铁会腐蚀。不过,200-litre 的容器也可以凑 co 合着用(此时酸用量少),只是使用不要超过一年。
n. I use a polypropylene plastic reaction vessel. Any plastic that won't qu deform at 100 deg C (212 deg F) or a bit more is fine. Stainless steel is 坛 un also fine. Use an immersion heater with plastic containers. With steel 论 l containers you can use propane heaters to heat the oil, then switch to an 油 b. immersion heater before adding the methanol.