Nondemolition observation of a free quantum particle
大气氮沉降通量观测方法(检测)
大气氮沉降通量观测方法*盛文萍1,2于贵瑞1**方华军1姜春明1,2(1中国科学院地理科学与资源研究所生态系统网络观测与模拟重点实验室,CERN 综合研究中心,北京100101;2中国科学院研究生院,北京100039)摘 要 工农业的发展引起含氮化合物排放量日益增多,导致大气向地面输入的沉降量相应增加。
大气氮沉降是自然生态系统重要的氮素来源,沉降量的增加必然会对生态系统的生物地球化学循环产生干扰。
针对大气氮沉降组成复杂、时空变异性大、观测的技术方法不统一、研究结果之间可比较性差等关键科学问题,本文从大气氮沉降来源和组成出发,综述了过去几十年来国内外大气氮素干湿沉降在观测方法和测试手段方面的重要进展,详细描述了传统雨量计收集法、降水降尘仪法、阴阳离子交换树脂法、降尘缸收集法和沉降速率法等干、湿沉降观测方法的原理,对比不同方法存在的优点与不足;简要对比了国内外大气干、湿沉降通量状况,提供了大气氮沉降区域分布格局方面的量化信息;初步阐明了大气氮沉降观测研究的理论基础和观测原理,为对比分析不同观测方法获得的观测结果提供定性参考,并为不同生态系统氮沉降研究选择合理的观测方法提供理论依据。
关键词 湿沉降;干沉降;沉降通量;沉降速率;观测方法中图分类号 Q948.1,S718.5 文献标识码 A 文章编号 1000-4890(2010)8-1671-08Observati o n m et hods for at m ospher ic nitrogen deposition .SHENG W en ping 1,2,YU Gu i r u i 1,FANG H ua jun 1,JI A NG Chun m i n g 1,2(1Synthesis R esearch Lenter of Ch i n ese E cosyste m R esearch N et w ork ,K ey Laboratory of Ecos y ste m N et w ork Observation and M odeling,Institute of G eographic S cience and N at u ral R esources R esearch,Chinese A cade my of Sciences ,B eijing100101,China;2G radua te University o f Chinese Acade m y o f Sciences ,Beijing 100039,Ch i n a).Ch i n ese Journal of E cology ,2010,29(8):1671-1678.A bstract :A t m ospheric n itrogen deposition has i n creased dra m a tica lly in recent years ,due to the increasing d ischarge of n itrogenous co m pounds fro m industry and ag ricult u re .N itrogen depositi o n is an i m portant n itrogen source o f natura l ecosyste m,and its i n crease w ou l d disturb the ecosyste m b i o geoche m ical cycle .Because of the co m positional co m plex ity and large spatiote m pora l vari a bili ty o f at m ospheric nitrogen depositi o n as w ell as the disunity o fm easure m entm et h ods ,it is diffi cu lt to co m pare the resu lts fro m different nitrogen deposition stud i e s .A i m i n g at the sources and co m position o f at m ospheric nitrogen depositi o n ,this paper summ arized the past decades research progress at ho m e and abroad i n the observation and testm ethods o f at m ospheric n itr ogen deposi tion ,described i n deta il the pri n ciples and operations of the m ethods for m easuring w et and dr y n itr ogen deposition (trad itional ra i n co ll e ction ,auto m ati c co llection by i n str um en,t ion exchange resin colu m n co llecti o n ,dust cy li n der w et collection ,and deposition velocity m ethod),and co m pared the advantages and disadvantages of these m ethods .M eanwh ile ,based on the co mparison o f related stud ies at ho m e and abroad ,this paper a lso prov ided the reg ional quantitative i n fo r m a tion o f nitrogen depositi o n flux .Presenting a brief rev ie w of representati v e techniques for nitrogen deposition observa ti o n ,t h is paper preli m i n arily e l u cidated the theoreti c bases and pri n ciples of a t m ospheric n itrogen deposition m easure m en,t gave a qua litati v e reference for the contrastive ana l y sis o f d ifferent observati o n results ,and prov i d ed theoreti c al bases for the reasonab l e cho ice o f n itrogen deposition observation .K ey words :w et depositi o n ;dry depositi o n ;depositi o n flux ;deposition ve l o c ity ;observati o n m ethod .*国家重点基础研究项目(2010CB833500)、国家自然科学基金重大项目(30590381)和中国科学院知识创新工程重要方向性资助项目(KZCX2 YW 432)。
英汉双语化学入门汉语翻译
第十二章( 1) Chemical ThermodynamicsChemical thermodynamics is that branch of chemistry which studies theenerge transformations and transfers that accompany chemical changes .( 2) State FunctionsWhen a property of a system ( its temperature, for example ) is notdependent on how the system gets from state to state and is only dependenton the state itself , it is said to be a state function . A state function ischaracteristic of a state of matter regardless of how the state is reached .Quantities which are state functions are designated by capital letters .( 3) Enthalpy and Enthalpy ChangeEnthalpy H is the heat content of a system . The change in enthalpy, ΔHis defined as the quantity of heat absorbed when a reaction takes place atconstant pressure .( 4) Entropy and Entropy ChangeThe randomness, or the amount of disorder, of a system can bemeasured quantitatively and is referred to as the entropy, S, of the system .The entropy change for a chemical reaction, ΔS represents the sum ofentropies of the products of that reaction minus the sum of the entropies ofthe reactants . A positive value for ΔS corresponds to an increase inrandomness, a negative value for ΔS corresponds to a decrease inrandomness .( 5) Standard Molar Enthalpy of FormationFor a particular type of chemical reaction in which one mole of a puresubstance is formed from the free elements in their most stable state understandard state conditions, the enthalpy change is referred to as the standardmolar enthalpy of formation of the substance formed and is designatedbyΔHf298.The standard molar enthalpy of formation of any free element in its moststable state is zero .( 6) Standard Molar Free Energy of FormationA chemical reaction in which one mole of a pure substance is formedfrom the free elements in their most stable state under standard conditions,the free energy change is referred to as the standard molar free energy offormation of the substance formed and is designated byΔGf298.The standard molar free energy of formation of any free element in itsmost stable state is zero .( 7) Free Energy and FREE Energy ChangeEnergy that capable of doing useful work iscalled Gibbs f ree energy, andis designated as G . The maximum amount of useful work that can beaccomplished bya reaction at constant temperature and pressure is referredto as the Gibbs free energy change,ΔG, for that reaction,if ΔG < 0, the reaction occurs spontaneously;if ΔG > 0 , the reaction does not occur spontaneously at constanttemperature and pressure, but the reverse reaction is spontaneous;if ΔG = 0, the reaction is in equilibrium .1 2。
杰克逊电子气体计量仪手册说明书
FUNDAMENTAL PRINCIPLES OF GAS TURBINE METERSRobert BennettElster Meter Services2221 Industrial RoadNebraska City, NE 68410INTRODUCTIONGas measurement in the U.S. and around the world is dominated by diaphragm, rotary, turbine, and orifice meters. Each serves a different segment of the gas industry and each has its own set of advantages and disadvantages.These four main types of meters can be broken into two distinct categories: positive displacement, and inferential. Diaphragm and rotary meters fall into the positive displacement group because they have well-defined measurement compartments that alternately fill and empty as the meter rotates. By knowing the volume displaced in each meter revolution and by applying the proper gear ratio, the meter will read directly in cubic feet or cubic meters. Turbine and orifice meters have no measurement compartments to trap and then release the gas. These meters are categorized as inferential meters in that the volume passed through them is "inferred" by something else observed or measured. n the orifice meter the volumes are determined only by knowing the inlet pressure, differential pressure, plate size, and piping characteristics, all of which "infer" the flow rates that in turn can be integrated over time to provide the volume.Turbine meters, also called velocity meters, "infer" the volume of gas passing through them by measuring the velocity of the gas stream. Gas moving through the meter impinges on a bladed rotor resulting in a rotational speed that is proportional to the flow rate. The volume is determined by counting the number of meter rotations. The purpose of this paper is to provide an overview for the installation, maintenance, and proving of axial flow type turbine meters. THEORY OF OPERATIONAs defined in A.G.A. Report #7, the turbine meter consists of three basic components (See Figure 1 and 1A)1. The body which houses all of the parts andphysically contains the gas pressure.2. The measuring mechanism consisting of therotor, rotor shaft, bearings, and necessary supporting structure.3. The output and readout device which may beeither a mechanical drive to transmit the indicated meter revolutions outside the body for uncorrected volume registrations or for electrical pulse meters, it would be the pulse detector system and all electrical connections needed to transmit the pulses outside.Figure 1.Figure 1AGas entering the meter increases in velocity as it flows through the annular passage formed by the nose cone or upstream stator and the interior of the body. The movement of the gas over the angled rotor blades exerts a force to the rotor causing it to rotate. The ideal rotational speed of the rotor is directly proportional to the flow rate of the gas. The actual rotational speed is a function of the annular passageway size and shape, and rotor design. It is also dependent on the load that is imposed due to internal mechanical friction, fluid drag, external loading, and gas density.INSTALLATIONA.G.A. Report #7 was written to provide recommendations as to the correct method for installing turbine meters, using their associated corrective factors, and meeting the operating requirements that pertain to axial flow type meters. Since the turbine meter is a velocity-measuring device, consideration should be given to both the upstream and downstream piping to insure a uniform velocity distribution of the gas through the meter and the rotor by reducing jetting or swirl. Construction of the turbine meter is such so as to minimize minor flow distortions that could affect meter performance. Straightening vanes are recommended to eliminate swirls. These vanes or any type of integral flow conditioner will not remove any jetting actions and may actually enhance the jetting effect. The recommended installation (See Figure 2) for in-line turbine meters calls for a straight length of 10 pipe diameters upstream with a distance of 5 pipe diameters between the end of the straightening vanes and the meter inlet.A length of 5 pipe diameters is recommended downstream. Both inlet and outlet pipe should be the same size as the meter. Upstream piping should be clean with no obstructions from flange gaskets, pressure taps, etc. The pressure tap should come from the meter as specified by the manufacturer while the temperature well, if required, should be 2.5 pipe diameters downstream from the meter.Figure 2. AGA Recommended InstallationRestricting and/or throttling devices, such as partially opened valves or regulators, are not recommended in close proximity to the meter since they tend to increase jetting and swirl. When necessary, any such throttling device should be installed an additional 8 nominal pipe diameters upstream or 2 diameters downstream from the meter.I n addition to the recommended installation, alternative types of installations are allowed where there are space limitations with the understanding that there may be some associated loss in meter accuracy because of jetting and swirl.Short coupled installations (See Figure 3) use a minimum of 4 nominal pipe diameters upstream with the straightening vanes located at the inlet of the piping. The distance between the end of the straightening vanes and the inlet of the meter should be at least 2 nominal pipe diameters. The meter run is connected to the vertical risers with standard tees or elbows.Reducing fittings may be used at the tee or elbow but only one pipe size reduction is recommended. Valves, regulators, strainers, or filters should be installed on the risersFigure 3. Short Coupled InstallationClose-coupled installations are shown in Figure 4. The meter design must incorporate integral flow conditioners upstream of the rotor. The meter is connected to the risers with a tee or elbow and the maximum reduction recommended is one pipe size. Any valves, regulators, strainers, or filters must beinstalled on the risers.Figure 4. Close Coupled Installation Recommendations for angle body turbine meter installations are shown in Figure 5. The meter run is connected to the inlet riser with either a 90-degree elbow or tee that may be reduced by one pipe size if necessary. With straightening vanes, the length of the upstream piping may be 5 pipe diameters with at least 2 pipe diameters between the end of the straightening vanes and the inlet to the meter.Without straightening vanes, the upstream piping should be at lease 10 pipe diameters long. Any valves, regulators, strainers, or filters should be on the risersFigure 5. Angle Body InstallationINSTALLATION CONSIDERATIONSTo protect the turbine meter from the dust, dirt, and scale that may occur during certain system operations, it is important that either a strainer or filter be installed upstream of the meter to increase its bearing life. Filters can trap small dust particles down to 10 microns. A differential pressure gauge should be installed across the filter or strainers to indicate excessive pressure drops from a build up of foreign matter in the strainer screen or filter element. All foreign material in the upstream piping should be removed before installing the measuring element and placing the meter in service. Special consideration should be given to the pipe between the strainer and/or filter since it may contain debris that will not have been removed.Since upstream disturbances should be kept to a minimum, temperature wells should be installed downstream of the meter at a recommended distance of between 2 and 5 pipe diameters downstream. Because regulators or any throttling device may tend to cool the gas stream as it expands, the temperature well should be installed ahead of any valve or flow restrictor that may be downstream of the meter.Pressure taps provided by the manufacturer on the meter body should be used as pressure taps for any recording or integrating instruments and during calibration. Use of any other tap locations may change the meter's calibration curve.I n any area where liquid contaminants are suspected a separator and/or drip tank should be considered since a high velocity liquid slug can cause damage to the rotor.Figure 6. Turbine Meter InstallationOver-range protection to prevent the meter from overspeeding may be needed. Although it may be operated up to 150% of the rated capacity for short periods of time, it is a good practice to limit the meter to approximately 120% of its maximum capacity. Either a critical flow orifice or sonic venturi nozzle may be used downstream of the meter provided that adequate pressure is available to compensate for the permanent pressure loss across the flow limitor. There is about a 50% pressure drop across critical flow orifices and between 10% to 20% drop with a sonic flow nozzle.Blow down valves should be installed downstream of the meter and should be no bigger that 1/6 of the meter sizeMeter Size Blow Down Valve2"1/4"3", 4" 1/2"6", 8", 12" 1"A good design for a turbine meter installation incorporating many of these recommendations would look very similar to Figure 6.INSTALLATION CHECK LIST-Meter is sized properly for line pressure and load-Meter has been lubricated-I nstallation is in accordance with A.G.A. #7 recommendation and/or company standards-Inlet and outlet meter connections are concentric to the pipe flanges and gaskets do not protrude into the flow pattern-Filters, strainers, and associated equipment are provided where required-Meter can be isolated and by-passed if needed-Pressure blow down is sized properly and located downstream-Provisions are made for in-line testing-Pressure and/or temperature taps are provided if required-No welding should be done with the internal mechanism in the meter-I f hydrostatic testing is done, a spool piece is recommended MAINTENANCE/FIELD TESTSNormal maintenance and field tests consist of lubrication, internal inspection, and spin testing. Prior to putting the meter in service, make sure it is lubricated and perform an initial spin test that will provide a reference time to future test results.Most turbine meters have provisions for a pressurized lubrication system. This consists of an external alemite fitting and lever-type oil gun which permits lubrication without taking the meter out of service. This is a simple procedure and in addition to replenishing the oil supply, it also flushes the bearing with fresh oil. Older style gravity lubrication systems can be converted to pressure systems, check with the manufacturer for correct parts.The frequency of lubrication is a function of the operating conditions. Obviously, a meter subject to gas containing dust and/or liquid contaminants or running at elevated capacities and/or extended periods should be serviced more frequently. Manufacturers suggest monthly lubrication with the period extended as experience permits. Lubrication of the meter with an approved oil is a good, relatively inexpensive form of preventive maintenance. Periodic internal inspection of the meter should be performed to ensure that components are in good working condition. The frequency of inspection is dependent on the severity of the service but should be done annually.Follow recommended procedures for taking the meter out of service and remove any readout devices.After bypassing if necessary, and isolating the meter, relieve the internal pressure using the blow-down valve. Once the internal mechanism is removed, visually inspect the interior of the meter body checking the internal flow guides or vanes for damage and removing any liquids or debris. Check the inside of the inlet and outlet flanges along with the gaskets to make sure they are in proper alignment and not interfering with smooth gas flow. Also inspect any seal tape within the body for any cuts or tears. This seal tape prevents gas from bypassing the annular passage through the rotor. Check the internal mechanism flow passages and rotor for damage. The rotor should be checked thoroughly for accumulation of dirt, wear, missing blades, or other damage. Since it is the essential measuring element, any rotor with more than superficial damage should be replaced and the meter proved. After completing the visualinspection, the mechanism should be spin tested to determine its condition.This test determines the relative condition of the meter and is not an accuracy test. With the cartridge place in a draft-free area and in its normal operating position, place suitable material against the side away from the rotor and with a finger or air jet; spin the rotor briskly, time how long it takes the rotor to come to a complete stop, and record this time. Repeat this procedure three times to come up with an average spin time. Compare this average time with the tables provided by the manufacturer for each size meter. This average spin time should also be compared with the initial spin test done when the meter was first installed.f the spin time has not changed significantly, the meter is clean, and the internal parts show no damage; then the meter should not display any change in its accuracy. I f the mechanical friction has increased, the resultant slower spin times indicate that the accuracy of the meter at low flow rates has degraded. I f decreased spin time is encountered, the meter should be lubricated and the rotor spun-in to throw off any excess oil which can also contribute to slow spin times. The spin test should be redone to determine if acceptable times can now be achieved.Whether the spin time is acceptable or not, it is a good practice to also check the intermediate gear train for binds. If possible, another spin test should be run with the readout device in place to also check it for binds that can affect low flow accuracy.Another factor that can contribute to low spin time is low ambient temperatures. Even though the oil is a light viscosity, low temperatures affect it.MAINTENANCE CHECKLIST-Meter should be lubricated on a scheduled time period with recommended oil-Filters or strainers should be checked for differential and/or pressure drop-Before disassembly, make sure the meter is depressurized and the readout device is removed.-Check the interior of the meter including seal tape, guides, and/or vanes for damage and remove any liquids and/or debris-Check the cartridge flow passages and rotor for damage-Conduct the spin test in a draft-free area.Perform three repetitions and average the spin times.-f low spin time is encountered, lubricate the bearings, and spin the rotor several times to work the new oil in, and repeat the test-Check the intermediate gear and readout device for binds-Spin test with the readout device in place PROVINGAs stated earlier, the spin test is not an accuracy test but rather a means to determine the relative condition of the meter.I n order to determine the accuracy of any meter, it must be compared to a recognized standard. While there are several standards available such as low pressure flow proving, sonic nozzle proving, bell proving, and transfer proving, the last two are the most prevalent in the gas industry.Because of the high flow rates associated with turbine meters, bell provers are not generally used for shop proving. However, manufacturers use large bell provers, 350 cf or 500 cf for special test and establishment of master meters by a process known as cascading. In this process, an engineering curve (15 points) is established for a 4" meter. Using the 4" meter as the master meter, an engineering curve is established for a 6" meter, 8" meter, and 12" meter. All of these tests are traceable to the National Bureau of Standards. These master meters are then used to transfer prove production meters and determine the normal six (6) point curve furnished with each meter.Field or shop transfer provers are also calibrated using an accepted standard and a thoroughly defined accuracy curve which is traceable to National Bureau of Standards that has been derived and furnished with each prover.Normally a transfer prover system consists of the master meter, control console, flow rate control valve, pulse transmitter of gate switch for both master and field meters, blower with muffler, and associated pressure and temperature sensors (Figure 7). The connection between the master meter and the field prover is either fixed piping or flexible hose with quick disconnect couplings. Vacuum testing with air drawn through both master and field meters is the common method used. In this procedure, the same volume of air is passed throughboth meters. By comparing this volume and applying master meter presets, along with corrections for pressure and temperature differences, the accuracy of the field meter can be calculated.Figure 7 Transfer ProvingOne method of proving turbine meter cartridges is to start an exchange program. A cartridge is tested in the shop, then taken to the field where it is exchanged with the field meter cartridge. The field meter cartridge is returned to the shop, where an in-test (as found) is done, any necessary repairs made,cartridge retested, and a new accuracy curve is generated. This cartridge is then used for field exchange on another meter.This method offers the advantage of only having the meter out of service long enough to exchange cartridges. Meter manufacturers state maximum error for this exchange method is +/- .25%(American) and +/- .6% (Equimeter). PROVING CHECKLIST-Purge meter observing safety rules and proper procedures-I nstall pulse transmitter on field meter, place temperature sensor as close to field meter outlet as possible-Connect pressure tubing to tap provided for this purpose on the meter-Leak test piping; if in-line proving, make sure valves are not leaking through-Observe prover manufacturer's instructions for initiating prover, self-test, and actual test sequence-Record results and calculate corrected proof -Perform periodic maintenance and re-certification of the transfer proverREFERENCES-Measurement of Gas by Turbine Meters,Transmission Measurement Committee Report No. 7, American Gas Association, 2006-Gas Measurement Manual, Part 4 Gas Turbine Metering, American Gas Association, 1985 -Gas Measurement Manual, Part 12, Meter Proving, American Gas Association, 1978 -Mm-1070, Rev 2, Equimeter MK-I I and AAT Turbo-Meter I nstallation and Maintenance Instructions-A I M 4700, Maintenance of American Gas Turbine Meters, American Meter Company -AI M 4701/AIM 330.2C, Gas Turbine Lubrication Instructions, American Meter Company。
高三英语社会问题解决方案评估指标确定单选题50道
高三英语社会问题解决方案评估指标确定单选题50道1.Which aspect is the most important when evaluating a solution to social problems?A.EfficiencyB.CostC.SustainabilityD.Popularity答案:C。
本题考查社会问题解决方案评估指标中的重要性判断。
选项A“Efficiency( 效率)”很重要,但不是最重要的唯一标准。
选项B“Cost( 成本)”也只是一个方面。
选项D“Popularity( 受欢迎程度)”并非核心重要指标。
而选项C“Sustainability 可持续性)”对于长期解决社会问题至关重要,因为只有可持续的解决方案才能真正有效地解决问题而不会带来新的问题。
2.In assessing social problem solutions, what should be given top priority?A.Quick implementationB.Long-term effectivenessC.Low initial investmentD.High media attention答案:B。
选项A“Quick implementation(快速实施)”有一定好处,但如果不能长期有效也不行。
选项C“Low initial investment 低初始投资)”不是最重要的考量。
选项D“High media attention 高媒体关注度)”不是关键因素。
选项B“Long-term effectiveness(长期有效性)”在评估社会问题解决方案时应给予最高优先级,因为只有长期有效的方案才能真正解决社会问题。
3.Which factor is crucial in determining the importance of a social problem solution?A.Number of supportersB.Speed of resultsC.Impact on future generationsD.Immediate popularity答案:C。
个人所得税英文参考文献
个人所得税英文参考文献个人所得税英语参考文献一:[1]José Félix Sanz-Sanz. The Laffer curve in schedular multi-rate income taxes with non-genuine allowances: An application to Spain[J]. Economic Modelling,2019,.[2]Craig Brett,John A. Weymark. Voting over selfishly optimal nonlinear income tax schedules[J]. Games and Economic Behavior,2019,.[3]Mónica Unda Gutiérrez. A Tale of Two Taxes: the Diverging Fates of the Federal Property and Income Tax Decrees in post-Revolutionary Mexico[J]. Investigaciones de Historia Económica - Economic History Research,2019,.[4]Sim Choon Ling,Abdullah Osman,Safizal Muhammad,Sin Kit Yeng,Lim Yi Jin. Goods and Services Tax (GST) Compliance among Malaysian Consumers: The Influence of Price, Government Subsidies and Income Inequality[J]. Procedia Economics and Finance,2019,35.[5]Martin Lopez-Daneri. NIT Picking: The Macroeconomic Effects of a Negative Income Tax[J]. Journal of Economic Dynamics and Control,2019,.[6]Tad Miller,Lindsay Miller,Jeffrey Tolin. Provision for income tax expense ASC 740: A teaching note[J]. Journal of Accounting Education,2019,35.[7]Petr David,Lucie Formanová。
2022年考研考博-考博英语-煤炭科学研究总院考试预测题精选专练VII(附带答案)卷5
2022年考研考博-考博英语-煤炭科学研究总院考试预测题精选专练VII(附带答案)第1套一.综合题(共25题)1.单选题Holders of deferred shares have no rights to vote at general meetings or receive any (). 问题1选项A.divisiveB.divideC.dividendD.division【答案】C【解析】考查形近词辨析。
A项形容词divisive “分裂的、区分的”,B项动词divide “分开”,C项名词dividend “红利、股息”,D项名词division “除法、分割”;句意:递延股票的持有者在股东大会上没有投票权,也不能获得任何股息。
因此C选项正确。
2.单选题Have you winterized your horse yet? Even though global warming may have made our climate milder, many animals are still hibernating. It's too bad that humans can't hibernate. In fact, as a species, we almost did.Apparently, at times in the past, peasants in France liked a semi-state of human hibernation. So writes Graham Robb, a British scholar who has studied the sleeping habits of the French peasants. As soon as the weather turned cold people all over France shut themselves away and practiced the forgotten art of doing nothing at all for months on end.In line with this, Jeff Warren, a producer at CBC Radio's The Current, tells us that the way we sleep has changed fundamentally since the invention of artificial lighting and the electric bulb.When historians began studying texts of the Middle Ages, they noticed something referred to as “first sleep”, which was not clarified, though. No w scientists are telling us our ancestors most likely slept in separate periods. The business of eight hours' uninterrupted sleep is a modern invention.In the past, without the artificial light of the city to bathe in, humans went to sleep when it became dark and then woke themselves around midnight. The late night period was known as “The Watch”. It was when people actually kept watch against wild animals, although many of them simply moved around or visited family and neighbors.According to some sleep researchers, a short period of insomnia at midnight is not a disorder. It is normal. Humans can experience another state of consciousness around their sleeping, which occurs in the brief period before we fall asleep or wake ourselves in the morning. This period can be an extraordinarily creative time for some people. The impressive inventor, Thomas Edison, used this state to hit upon many of his new ideas.Playing with your sleep rhythms can be adventurous, as anxiety may set in. Medical science doesn't help much in this case. It offers us medicines for a full night's continuous sleep, which sounds natural; however, according to Warren's theory, it is really the opposite of what we need.1. The example of the French peasants shows the fact that ().2. The la te night was called “The Watch” because it was a time for people ().3. Thomas Edison is cited to show ().4. What does the author advise people to do?5. What is most possibly the source of this article?问题1选项A.people might become lazy as a result of too much sleepB.there were signs of hibernation in human sleeping habitsC.people tended to sleep more peacefully in cold weather问题2选项A.to set traps to catch animalsB.to wake up their family and neighborsC.to remind others of the timeD.to guard against possible dangers问题3选项A.insomnia is harmful to peopleB.human being cannot overcome insomniaC.a short period of consciousness during sleeping is normal for human beingD.great scientists must sleep less to make great inventions问题4选项A.Sleep in the way animals do.B.Consult a doctor if they can't sleep.C.Follow their natural sleep rhythm.D.Keep to the eight-hour sleep pattern.问题5选项A.scientific journalsB.history booksD.fairy tales【答案】第1题:B第2题:D第3题:C第4题:C第5题:A【解析】1.【试题解析】判断推理题。
VLA H53alpha and H92alpha line observations of the central region of NGC 253
a rXiv:as tr o-ph/6323v11Mar26VLA H53αand H92αline observations of the central region of NGC 253C.A.Rodr´ıguez-Rico 1,2c.rodriguez@astrosmo.unam.mx W.M.Goss 2mgoss@ J.-H.Zhao 3jzhao@ Y.G´o mez 1y.gomez@astrosmo.unam.mx K.R.Anantharamaiah 4ABSTRACT We present new Very Large Array (VLA)observations toward NGC 253of the recombination line H53α(43GHz)at an angular resolution of 1.′′5×1.′′0.The free-free emission at 43GHz is estimated to be ∼100mJy,implying a star formation rate of ∼1.3M ⊙yr −1in the nuclear region of this starburst galaxy.A reanalysis is made for previously reported H92αobservations carried out withangular resolution of 1.′′5×1.′′0and 0.′′36×0.′′21.Based on the line and continuum emission models used for the 1.′′5×1.′′0angular resolution observations,the RRLs H53αand H92αare tracers of the high-density (∼105cm −3)and low-density (∼103cm −3)thermally ionized gas components in NGC 253,respectively.The velocity fields observed in the H53αand H92αlines (1.′′5×1.′′0)are consistent.Thevelocity gradient in the central∼18pc of the NE component,as observed in boththe H53αand H92αlines,is in the opposite direction to the velocity gradientdetermined from the CO observations.The enclosed virial mass,as deducedfrom the H53αvelocity gradient over the NE component,is∼5×106M⊙in thecentral∼18pc region.The H92αline observations at high angular resolution(0.′′36×0.′′21)reveal a larger velocity gradient,along a P.A.∼−45◦on the NEcomponent,of∼110km s−1arcsec−1.The dynamical mass estimated using thehigh angular resolution H92αdata(∼7×106M⊙)supports the existence of anaccreted massive object in the nuclear region of NGC253.Subject headings:starburst galaxies,radio recombination lines,NGC2531.INTRODUCTIONNGC253is one of the nearest(∼2.5Mpc)and brightest starburst galaxies,catalogued as an SAB(s)c galaxy(de Vaucouleurs et al.1976).This galaxy has an inclination of∼79◦with respect to the line-of-sight with major axis located at a position angle(P.A.)of51◦, also containing a bar-like feature tilted by18◦with respect to the major axis(Pence1981). Observations of NGC253have been carried out in the radio(Turner&Ho1985;Ulvestad& Antonucci1997;Mohan,Anantharamaiah,&Goss2002;Mohan,Goss,&Anantharamaiah 2005;Boomsma et al.2005)infrared(Engelbracht et al.1998),optical(Forbes et al.2000; Arnaboldi et al.1995)and X-ray(Weaver et al.2002)wavelengths.Radio observations, which are not affected by dust absorption,are an excellent tool to study the structure and kinematics of the nuclear region of NGC253.Observations in the21-cm line(Boomsma et al.2005)reveal extra-planar motions of HI that occur at a large scale of up to12kpc.High angular resolution radio continuum observations(Ulvestad&Antonucci1997)have revealed a number(>60)of compact sources in the central300pc of this galaxy,supporting the scenario of a massive star formation episode occurring in the center of NGC253.Nearly half of these compact continuum sources are dominated by thermal radio emission from HII regions(Turner&Ho1985;Antonucci&Ulvestad1988;Ulvestad&Antonucci1997).The radio continuum and radio recombination line emission,observed at high angular resolution, have been modeled using different density components for the ionized gas(Mohan,Goss,& Anantharamaiah2005).The emission models suggest the existence of both low(∼103cm−3) and high-density(>104cm−3)ionized gas in the central region of NGC253.On the other hand,the most luminous source(5.79-0.39)is unresolved(<1pc)at22GHz suggesting the existence of an AGN in the center of this galaxy(Ulvestad&Antonucci1997).Observations of broad H2O maser line emission(≥100km s−1)near this radio continuum source hasbeen invoked as further evidence of the presence of a massive object in NGC253(Nakai et al.1995).Mohan,Anantharamaiah,&Goss(2002)modeled the VLA continuum and radio recombination line(RRL)emission for the nuclear region of NGC253and favor an AGN as the source responsible for the ionization.Observations of hard X-ray emission toward the core of NGC253were also interpreted as evidence of AGN activity(Weaver et al.2002).The bar-like structure wasfirst observed toward NGC253in the near-infrared(NIR), covering the inner150′′region of the galaxy(Scoville et al.1985;Forbes&Depoy1992). The existence of the stellar bar is supported by the observed morphology at optical and mid-infrared frequencies(Forbes&Depoy1992;Pi˜n a et al.1992).A counterpart of the stellar bar in NGC253has been found in CO(Canzian,Mundy,&Scoville1988),HCN (Paglione,Tosaki,&Jackson1995)and CS(Peng et al.1996).Observations in the RRL H92α(Anantharamaiah&Goss1996)at an angular resolution of1.′′8×1.′′0reveal a velocity field that is discrepant with the CO,CS and HCN observations.Anantharamaiah&Goss (1996)proposed that the kinematics observed in the H92αcould result from a merger of two counter-rotating disks.The observed H92αand CO line velocityfields were modeled by Das, Anantharamaiah&Yun(2001)using a bar-like potential for NGC253,which is in reasonable agreement with the observed H92αline velocityfield.However,this kinematical model can only reproduce the velocityfield of the CO and CS and does not agree with the H92αRRL observations.Based on the discrepancy of the CO and the ionized gas kinematics,Das, Anantharamaiah&Yun(2001)proposed that the accretion of a compact object(∼106M⊙) about107years ago could account for the velocityfield observed in the H92αRRL.Paglione et al.(2004)observed the CO emission at3′′angular resolution for the inner region and modeled the kinematics of the molecular gas using a bar potential,concluding that motions of the CO gas in the central150pc are consistent with a bar potential and report evidence of the existence of an inner Lindblad resonance(ILR).Previous interferometric observations of RRLs have been made at low frequencies(e.g.∼8.3GHz,H92α).VLA observations at1.′′5×1.′′0angular resolution were used by Anan-tharamaiah&Goss(1996)to study the kinematics of NGC253;Mohan et al.(2002,2005) used the VLA observations at1.′′5×1.′′0and0.′′3angular resolutions to determine the phys-ical properties of the ionized gas in NGC253.In this paper we analyse the kinematics of the ionized gas in the nuclear region of NGC253using high frequency RRL observations (∼43GHz)and the high angular resolution observations(at0.′′3)in the RRL H92α.Also we use the VLA observations in the RRL H53αand the43GHz radio continuum,along with previously reported H92αline and8.3GHz radio continuum observations(Mohan et al.2005),in order to estimate the physical properties of the ionized gas.This paper is complementary to the results summarized by Mohan et al.(2005).Section2presents the observations and data reduction,while§3presents the results for the H53αand H92αRRLs.In subsection4.1,a model for the emission of the RRLs H53αand H92αas well as for the radio continuum at43and8.3GHz is presented.Subsection4.2analyzes the kinematics for the ionized gas in the center of NGC253and§5presents the conclusions.2.VLA Observations.2.1.H53αline.The H53αline(νrest=43309.4MHz)was observed in the CnD configuration of the VLA on2003,January18,19and20.We used cycles with integration times of10min on NGC253and1min on the phase calibrator J0120-270(∼0.7Jy).Four frequency win-dows(LOs)were used to observe the RRL H53α,centered at42885.1,42914.9,42935.1,and 42964.9GHz.For each frequency window,the on-source integration time was∼2hrs,using the mode of15spectral channels with a channel separation of3.125MHz(∼22km s−1). The data calibration was carried out for each frequency window using the continuum chan-nel,consisting of the central75%of the band.Theflux density scales were determined from observations of J0137+331(3C48;0.54Jy).The bandpass response of the instrument was corrected using observations of J0319+415(3C84;∼7.5Jy).The parameters of the observations are summarized in Table1.In order to track reliably the phase variations in-troduced by the troposphere,the calibration of the data was performed correcting for the phases in afirst step and subsequently correcting for both amplitude and phase.The line data were further calibrated using the solutions obtained by self-calibrating the continuum channel of each frequency window.The radio continuum images were obtained by combining the continuum channels of each frequency window using the task DBCON from AIPS,and the self-calibration method was also applied to this combined data.The H53αline cubes and the43GHz continuum image were made using a natural weighting scheme and then convolved to obtain a Gaussian beam of1.′′5×1.′′0(P.A.=0◦).The combination of the differ-ent frequency windows was made following a similar method to that used for the H53αline observed toward M82(Rodr´ıguez-Rico et al.2004):(1)the line data from each frequency window were regridded in frequency using the GIPSY reduction package,(2)before com-bining the four LOs into a single line cube,the continuum emission was subtracted for each frequency window using the AIPS task IMLIN with a zero order polynomialfit based on the line free channels,and(3)the four line cubes(after subtraction of the continuum)were combined into a single line cube.The total line bandwidth,after combining all the windows, is about150MHz(1000km s−1).The line data cube was Hanning-smoothed using the task XSMTH in AIPS to reduce the Gibbs effect and thefinal velocity resolution is∼44km s−1.2.2.H92αline.We also present previously reported observations of the RRL H92α(νrest=8309.4MHz) at1.′′5×1.′′0,P.A.=0◦(Anantharamaiah et al.1996)and0.′′36×0.′′21,P.A.=−3◦(Mohan et al.2005,2002)angular resolutions toward NGC253.The H92αRRL images at1.′′5×1.′′0 angular resolution were produced by combining observations carried out in the B(August 31and Sept01,1990),C(May14and23,1988)and D(July01and19,1988)configurations of the VLA.In order to obtain the same HPFW beam as the H53αline cube,the H92αline cube was made using these’B+C+D’combined data applying a natural weighting scheme. Anantharamaiah&Goss(1996)have already used these’B+C+D’combined observations to analyze the kinematics of the ionized gas in the central10′′of NGC253with an angular resolution of1.′′8×1.′′0,P.A.=10◦.The higher angular resolution(0.′′36×0.′′21,P.A.=−3◦) observations of the H92αline toward NGC253were made with the VLA in the A array (July9and12,1999)and have been previously reported by Mohan,Anantharamaiah,& Goss(2002).Recently,Mohan,Goss,&Anantharamaiah(2005)used these H92αdata along with observations in the RRLs H75αand H166αdata to model the RRL and the radio continuum emission in order to determine the physical parameters of the ionized gas.In this paper we use these high angular resolution observations to study the kinematics of the ionized gas in the nuclear5′′region of NGC253.Because of the different spectral line grid of the H92αhigh angular resolution observations and the H92α’B+C+D’data,a combined dataset’A+B+C+D’was not produced.For the H92αline observations,the phase calibrator was J0118-216and the bandpass calibrator was J2253+161.A spectral mode with31channels was used.The continuum images were obtained by averaging the data in the central75%of the total band.The continuum data were processed using standard calibration and self-calibration procedures. The calibration and self-calibration used for the continuum data were then applied to the line data.All the images were made in the AIPS environment.The line images were Hanning-smoothed to reduce the Gibbs effect and the velocity resolution is56.4km s−1. Further observational details are summarized by Mohan,Anantharamaiah,&Goss(2002) and Mohan,Goss,&Anantharamaiah(2005).3.RESULTSFigure1shows the radio continuum emission of NGC253at43GHz with an angular resolution of1.′′5×1.′′0,P.A.=0◦(1′′≃12pc).The integrated43GHz continuumflux density is360±20mJy,obtained by integrating theflux density over the nuclear30′′region using the task IRING in AIPS.The radio continuum image at43GHz shows two radiocontinuum components,NE and SW,in addition to extended emission(see Figure1).The continuum peak position of the NE component,α(J2000)=00h47m33.s17±0.s01,δ(J2000)=−25◦17′17.′′4±0.′′1,coincides within0.′′2with the position of the compact source5.79-39.0 (Ulvestad&Antonucci1997).Figure2shows the H53αvelocity-channel images of NGC253with an angular resolution of1.′′5×1.′′0(P.A.=0◦).The H53αline emission is detected toward both the NE and SW continuum components above a3σlevel(∼2mJy).The ionized gas is observed in the H53αline at heliocentric velocities that range from17to345km s−1.The velocity-integrated H53αline emission(moment0)is shown in Figure3superposed on the moment0of the H92αline.There is good correspondence between the integrated line emission of the RRLs H53αand H92α.In addition,the peak position of the integrated H53αline emission is in agreement with the peak position of the43GHz radio continuum image.In the H53αline images,both the NE and SW components are spatially resolved only along the major axis.Figure4shows the H53αline spectrum integrated over the central10′′region of NGC253. Byfitting a Gaussian,the estimated central heliocentric velocity is210±10km s−1,the FWHM of the line is230±20km s−1and the peak lineflux density is21±2mJy.The resultingfit is shown in Figure4along with the residuals to thefit.The central velocity is in agreement with previous estimates in the optical(225±5km s−1;Arnaboldi et al. 1995)and IR(230±10km s−1;Prada,Guti´e rrez&McKeith1998).The velocity integrated H53αlineflux density determined from our observations is0.69±0.09×10−20W m−2,in agreement with the previous measurement of0.94±0.38×10−20W m−2derived from single-dish observations(Puxley et al.1997).A Gaussian function was also used to determine the characteristics of the spectra obtained by integrating over the NE and SW regions.Table2 lists the results for the total integrated H53αline emission profile,as well as for profiles that correspond to the NE and SW components.The values listed for the H53αline are peak flux density S L,FWHM,the heliocentric velocity V Hel and the velocity integrated H53αline emission.Figure5shows the velocityfield(moment1)of the H53αline at an angular resolution of1.′′5×1.′′0(P.A.=0◦).Figure6shows the H92αvelocityfield made using the’B+C+D’data of Anantharamaiah&Goss(1996)at the same angular resolution.The velocityfield of the ionized gas as observed in the H53αline agrees with observations of the RRL H92α(see section4.2for a detailed comparison).In the NE component of NGC253the red-shifted gas is observed toward the NW and the blue-shifted gas toward the SE.In the region located S of the radio continuum peak,there is a blue-shifted component that is more apparent in the H53αline than in the H92αline.A detailed comparison between the line profiles of the H53αand H92αin this region shows that the H53αline is broader than the H92αline by∼50km s−1and there is a relative velocity shift between these two RRLs of∼30km s−1.In the elongated SW component,the red-shifted gas is located at the SW and the blue-shifted gas is at the NE.The velocity gradient was measured,at1.′′5×1.′′0angular resolution,along the major(P.A.=52◦)and nearly along the minor(P.A.=−45◦)axis for both RRLs the H53αand H92α.The H53αvelocity gradient along the major axis of NGC253(measured over the NE component)is12±3km s−1arcsec−1,comparable to the corresponding H92αvelocity gradient(∼11km s−1arcsec−1).The velocity gradients measured in the RRLs H53αand H92α(both at1.′′5×1.′′0)along the P.A.=−45◦are42±8km s−1arcsec−1and 24±2km s−1arcsec−1,respectively.Figure7shows the H92αvelocityfield at an angular resolution of0.′′36×0.′′21(P.A.=−3◦).At this angular resolution,the H92αline emission is detected only toward the NE component with an angular size of∼0.′′6(7pc).Based on these H92αdata,a larger velocity gradient of110±20km s−1arcsec−1is measured along a P.A.≃−45◦.This velocity gradient is about a factor of four larger than the velocity gradient estimated using the lower angular resolution H92αobservations(1.′′5×1.′′0).The lower velocity gradient measured in the low angular resolution image of H92α(1.′′5×1.′′0)is due to a beam dilution effect.By convolving the high angular resolution data of the H92αwith a Gaussian beam of1.′′5×1.′′0angular resolution,the velocity gradient measured along the P.A.=−45◦is consistent with the lower angular resolution H92αdata.4.DISCUSSION4.1.Models for the radio continuum and recombination line emissionIn Table3,we summarize the43GHz continuumflux density measurement along with previous measurements(5−300GHz)for the central30′′region of NGC253.Theseflux density values have been used to determine the relative contributions from free-free,syn-chrotron and dust emission.At frequencies<50GHz,the relative contributions of free-free and non-thermal emission are dominant compared to the thermal dust emission.However, at frequencies>50GHz,the dust contribution is more significant.The estimated contri-bution of the thermal free-free emission at43GHz is∼140mJy,while the non-thermal emission accounts for∼220mJy.These values were obtained assuming that the thermal continuum free-freeflux density shows S free−free(ν)∝ν−ing the observedflux den-sity measurements of the radio continuum in the range of5−98GHz,and following the procedure used by Turner&Ho(1983),the spectral index for the non-thermal emission is αsynchrotron=−0.73±0.06.After subtracting the free-free and non-thermal emission from the total continuum emission over the5−300GHz frequency range,we obtain the spectralindex value for the dust emissionαdust=3.9±0.2.Figure8shows the contribution from thermal free-free,synchrotron and thermal dust emission along with the total radio contin-uum over the frequency range5to300GHz.The thermal free-free radio continuumflux density at43GHz may be used to estimate the ionization rate(N Lyc)from NGC253using (Schraml&Mezger1969;Rodr´ıguez et al.1980),N LycmJy T e4.9GHz0.1 Das the volume of the total line emission,assuming spherical HII regions.The models suggest that the thermally ionized gas in the NE component consists of a collection of extended(∼1−4pc)low-density(∼102−103cm−3)HII regions and compact (∼0.01−0.06pc)high-density(∼105−106cm−3)HII regions.In order to reproduce the observations,the mass of ionized gas in the low-density component must be a factor of∼103larger than the mass of ionized gas in the high-density component.The ionized gas in the SW region also consists of low-and high-density HII regions,characterized by n e≃102cm−3and n e≃105−106cm−3.Table4lists the physical parameters of these HII regions:the electron temperature(T e),electron density(n e),size,emission measure(EM), mass of ionized gas,continuum optical depth(τc)at8.3and43GHz,departure coefficients (b n andβn=1−(kT e/hνL)d ln b n/dn,where n is the quantum number)for the H53αand H92αRRLs,the contribution of free-free emission and the Lyman continuum photons rate.The second and third columns list these parameters for the low and high-density HII regions on the NE component.The fourth andfifth columns list the corresponding parameters for the SW component.Based on these models,the RRL H92αarises mainly as externally stimulated line emission from the extended low-density(∼103cm−3)HII regions, withβn<−20.The thermal free-free contribution from both the low-and high-density component to the total observed continuum emission ranges from∼30%to∼80%.The total mass of thermally ionized gas in each component(NE and the SW)is∼103M⊙.The Lyman continuum emission rate of5.9×1052s−1obtained from the RRL emission models(see Table4)is consistent with7×1052s−1,obtained from the continuum emission models (shown in Figure8).The Lyman continuum emission rates for the NE and SW components (listed in Table4)were obtained only for regions where H53αline emission was detected. On the other hand,the value of7×1052s−1was estimated by integrating over the central 30′′region,which explains the slightly different results.The results obtained for the low-density gas component for the NE component of NGC253are in agreement with the results obtained by Mohan,Goss,&Anantharamaiah(2005)for the15pc region,observed with higher angular resolution observations(∼0.′′3)and using VLA H166α,H92αand H75αline data.Even though the mass contribution of the high density HII regions is only∼1%of the total HII mass,this feature contributes∼40%of the total H53αline emission.As noted before by Mohan,Goss,&Anantharamaiah(2005),high angular resolution observations are essential in the determination of the physical parameters of both low and high-density HII regions.In addition to high angular resolution,high frequency observations (e.g.H53α)are required to determine the properties of the high-density(∼105cm−3)HII regions.Non-LTE effects are important,leading to an enhancement of the line emission by afactor of∼2.Thus,the results obtained assuming LTE conditions overestimate the number of HII regions(and also the SFR)that must exist in NGC253.4.2.KinematicsThe previous H92αline observations at1.′′8×1.′′0angular resolution(Anantharamaiah &Goss1996)revealed velocity gradients of∼11km s−1arcsec−1and∼18km s−1arcsec−1 along the major axis and minor axis,respectively.A qualitative comparison of the velocity field observed in the H53αline and the previously reported H92αline velocityfield reveals kinematical behaviors that are consistent,i.e.the regions with red-shifted and blue-shifted ionized gas coincide(see Figs.5and6).The coincidence of the red-and blue-shifted regions in the H53αand H92αvelocityfields implies that both the low-and high-density ionized gas components rotate in the same sense.In order to compare in detail the kinematics of the ionized gas as observed in the H53αand the H92αlines,we constructed PV diagrams along the major axis(P.A.=52◦)using the task SLICE in GIPSY.These PV diagrams are shown in Figure9;the white line is the resultingfit to the velocity gradient of11km s−1arcsec−1.The same procedure was used to obtain PV diagrams along the P.A.=−45◦,shown in Figure10;the white lines are the resultingfits to the H92αvelocity gradient(24km s−1arcsec−1)and the H53αvelocity gradient(42km s−1arcsec−1).In Figure10we also show the H92αand H53αspectra superimposed at different offset positions from the central source(5.79-39.0);these spectra were normalized based on the peak lineflux densities.By inspection of the different spectra obtained at the negative offset positions(between−0.′′6and−0.′′9in Figure10),a relative velocity shift(∼30±5km s−1)is observed between the peakflux density of the H53αand the H92αlines.Based on the line emission models,these two RRLs trace different density components(see section4.1).The small velocity shift between these two RRLs on the NE component suggests that each density component has slightly different kinematics.4.2.1.Gaseous bar structure,outflow or an accreted objectObservations at IR wavelengths have revealed the existence of a gaseous bar in NGC253 (Scoville et al.1985).In a bar potential the gas follows two types of orbits,x1and x2.The x1 (bar)orbits are those extended along the major axis of the bar and the x2(anti-bar)orbits are those oriented perpendicular to the bar major axis.In the case of NGC253,the x1and x2orbits would be oriented on the plane of the sky at P.A.of∼70◦and∼45◦,respectively.In the H53αand H92αRRL images(at1.′′5×1.′′0angular resolution)the orientation of the largest velocity gradient is nearly perpendicular to the orientation of the x2orbits.Since the ionized gas on the NE component rotates in an opposite sense compared to the CO (Anantharamaiah&Goss1996;Das,Anantharamaiah&Yun2001),a simple bar potential does not account for the differences observed between the velocityfields of the RRLs(H92αand H53α)and CO.A secondary bar inside the primary bar may be invoked to explain the kinematics observed in the center of NGC253.However,further observations and modeling are required to investigate the existence of this secondary bar.Weaver et al.(2002)proposed the presence of a starburst-driven nuclear outflow col-limated by a dusty torus,based on X-ray observations of NGC253.In this model,the thermally ionized gas in the center of NGC253should be distributed in both a starburst ring and a starburst-driven outflow(Weaver et al.2002).Observations of the RRL H92αtoward the starburst galaxy M82(Rodr´ıguez-Rico et al.2004),have proben that RRLs may be used to study the ionized gas associated with galactic outflows.The largest velocity gradient observed in the RRL H92αis oriented nearly along the minor axis of NGC253 (P.A.=−45◦).Based on this orientation and assuming the H92αRRL in the NE component traces the ionized gas in the outflow,the receding side of this outflow would be on the NW and the approaching side on the SE.If this is the case all the observed ionized gas would be tracing the outflow,explaining the different rotation sense between the CO and the ionized gas.However,it seems unlikely that all the ionized gas is associated with the outflow.Das,Anantharamaiah&Yun(2001)propose that the kinematics of the ionized gas traced by the H92αRRL can be explained if there is an accreted object with mass of ∼106M⊙.The CO gas which traces the galactic disk of NGC253is moving in an opposite sense compared to the ionized gas that may be associated with the compact object.Based on the H53αvelocity gradient(∼42km s−1arcsec−1)along the minor axis of the NE component (∼30pc),the inferred dynamical mass is∼5×106M⊙.This mass estimate is consistent with that of the accreted object proposed by Das,Anantharamaiah&Yun(2001).The existence of a compact object is further supported by the higher angular resolution(0.′′36×0.′′21)H92αobservations(Figure7),revealing a larger velocity gradient(∼110km s−1arcsec−1,at P.A.≃−45◦)over the central∼0.′′6(7pc).This H92αvelocity gradient of∼110km s−1arcsec−1 implies a dynamical mass of∼7×106M⊙,similar to the mass determined from the1.′′5×1.′′0 angular resolution observations of the RRLs H53αand H92α.The∼7×106M⊙dynamical mass is based on observations over a region a factor of three times smaller than that observed in the1.′′5×1.′′0angular resolution images.The estimated dynamical mass(∼7×106M⊙)for the nuclear region of NGC253is comparable to that of the compact source at the nucleus of our galaxy(∼4×106M⊙,Ghezet al.2005).This mass estimate of∼7×106M⊙for the central region of NGC253could exist in the form of a large number of stars combined with ionized gas and may also contain an AGN.If the Lyman continuum photons rate(∼7×1052s−1)is mainly due to O5stars, each emitting∼5×1048s−1,then there must be∼104O5stars in the NE component. Using Salpeter’s initial mass function and a mass range of0.1−100M⊙,the total mass in stars in the NE component is∼107M⊙.The ionized gas could be gravitationally bounded by the stars and consequently the black hole mass would be≤107M⊙.The existence of an AGN has been proposed from radio continuum observations(Turner&Ho1985;Ulvestad &Antonucci1997)and RRL H92αobservations(Mohan,Anantharamaiah,&Goss2002). Radio continuum observations(1.3to20cm),reveal that the strongest radio source5.79-39.0 has a brightness temperature>40,000K at22GHz and is unresolved(<1pc,Ulvestad and Antonucci1997).Broad(>100km s−1)H2O maser line emission is observed toward the nuclear regions supporting the existence of a massive object in the center of NGC253 (Nakai et al.1995).In order to account for the different kinematics observed for the ionized and the molec-ular gas,two possible scenarios can be proposed:(1)a dense object that is accreted into the nuclear region of NGC253,(2)the ionized gas is moving in a starburst-driven outflow and/or(3)a secondary bar exists within the primary bar,as proposed for other galaxies (Friedli&Marinet1993).The accreted object model is supported by the high angular res-olution H92αobservations;the estimated dynamical mass of∼7×106M⊙is concentrated in a≤7pc region and the ionized gas traced by the RRLs moves in the opposite direction compared to the larger scale CO.In the RRLs H53αand H92α,wefind no evidence that confirms the existence of a secondary bar.An S-shape in the velocityfield is characteristic of a bar(Anantharamaiah&Goss1996).Thus,for a secondary bar a second S-shaped pattern would be observed in the velocityfield which is not appreciated in the H92αvelocity structure(see Figure7).However,this scenario cannot be ruled out and higher angular and spectral resolution observations are necessary to discern between these three models.5.CONCLUSIONS.The H53αRRL and radio continuum at43GHz were observed at high angular resolution (1.′′5×1.′′0)towards NGC253.We have also reanalyzed previous observations of the RRL H92αmade at an angular resolutions of1.′′5×1.′′0(Anantharamaiah&Goss1996)and 0.′′36×0.′′21(Mohan,Anantharamaiah,&Goss2002).Based on the43GHz radio continuumflux density and previous measurements at lower and higher frequencies,we have estimated the contribution from free-free emission。
拉曼共振四能级原子系统中的有效交叉Kerr非线性
拉曼共振四能级原子系统中的有效交叉Kerr非线性王利强;查新未;李永放【摘要】A theoretical investigation is put forward for obtaining effective cross-Kerr nonlinearity of the four-level atom interacting with three electromagnetic ing density-matrix equations and perturbation iterative method,the variation dependence of the third-order susceptibility on the detunings of the applied electromagnetic fields is derived.The results show that a large cross-Kerr nonlinearity can be generated when the detunings of the two weak probe fields are Raman resonant,and the corresponding linear susceptibility and self-Kerr interactions vanish.The realization of the effective Kerr nonlinearity with vanishing absorption is possible in a Raman resonant four-level system.%提出了利用四能级原子系统与三个电磁场相互作用获取有效交叉Kerr非线性的方案.应用微扰理论和密度矩阵方法,得到了三阶极化率与外加电磁场失谐量的变化关系.结果表明:当两个弱探测场的失谐量达到拉曼共振时,可以获得一个大的交叉Kerr非线性磁化率,且自Kerr 非线性极化率和线性极化率为零.证明了在具有拉曼共振的四能级原子系统中获得无吸收有效交叉Kerr非线性的可行性.【期刊名称】《陕西师范大学学报(自然科学版)》【年(卷),期】2011(039)006【总页数】4页(P27-30)【关键词】非线性光学;三阶极化率;交叉Kerr非线性;拉曼共振【作者】王利强;查新未;李永放【作者单位】陕西师范大学物理学与信息技术学院,陕西西安710062;西安邮电学院理学院,陕西西安710061;西安邮电学院理学院,陕西西安710061;陕西师范大学物理学与信息技术学院,陕西西安710062【正文语种】中文【中图分类】O437.3光克尔效应是指光通过非线性光学介质时其偏振方向会随着其他光的作用而变化的现象,它反映了物质的非线性光学性能.光学克尔效应存在着广泛的应用,如纠缠浓缩[1-2]、量子传输[3]、量子门转换[4]和量子非破坏性测量[5]以及光调制器和光偏转器、光开关、光双稳态器件的制作.近年来,由于弱吸收增强的非线性极化率可以在弱光条件下研究非线性光学,其中基于电磁感应透明(Electromagnetic induced)和拉曼共振(Raman resonant)的介质来获得增强的光学克尔非线性效应引起人们极大的关注.Lukin等通过理论研究指出,利用四能级原子EIT产生的巨大交叉克尔非线性系数,有可能使一个单光子脉冲导致另一个单光子脉冲产生π相移,从而实现两个单光子脉冲的量子纠缠和量子相位门[6].Yan等在冷原子N型四能级系统中也观察到EIT增强的交叉克尔非线性效应和双光子吸收[7-8].不仅EIT过程可导致介质的线性和非线性极化率发生很大的变化[9-11],Raman跃迁也可以极大地改变介质的极化率.在Raman过程中,由于原子相干导致的强色散效应会引起强的克尔非线性效应[12-16].利用原子之间的相干性可以产生一个纯的交叉克尔效应已经被理论[17-18]和实验证实[19].但对大多数材料来说,交叉克尔效应总是伴随不可忽略的非线性效应,例如自克尔效应,差频以及和频的产生[20].本文在一个N型四能级Rb原子系统中,通过调谐探测场和泵浦场的失谐量达到Raman共振时,获得了一个较大的纯交叉克尔非线性系数,但对探测光的吸收为零.在旋波近似下,系统的密度矩阵运动方程为上式中2γ1、2γ3 分别表示能级|2〉→|1〉和|4〉→|3〉的自发衰减系数.下面讨论原子对入射光的线性和非线性响应情况.介质对两个弱的探测光ωa、ωc响应的极化强度可以表示为上式中的极化强度包括线性和非线性极化强度,例如频率为ωa的极化强度可以表示为式中的χ(1)和χ(3)表征介质对光极化特性的极化张量.而介质对光的响应是电偶极振子在光电场作用下振动所产生的极化,其极化强度是P=-Ner(t),N为单位体积内的振子数.对电偶极矩,取量子平均,得到极化强度与密度矩阵的关系式:上式中的第一项对应于介质对频率为ωa的响应,第二项对应于介质对频率为ωb 的响应,第三项对应于介质对频率为ωc的响应.本文所考虑的模型中,主要研究|1〉和|2〉之间的相干辐射作用,所以只考虑P(ωa)=N(μ21ρ12)项,即将(5)式中的反对角元ρ12按Ωa、Ωc的泰勒形式展开,得到线性极化率χ(1)、自克尔极化率和交叉克尔极化率的表达式分别为图2、3给出了线性极化率的实部Re[χ(1)]、虚部Im[χ(1)]和表示自克尔非线性效应的三阶极化率的实部 Re[χs(3 )]、虚部Im[χs(3)]随探测场Ωa 的失谐量Δa变化曲线.取参量γ1=7MHz,γ3=7MHz,Ωb=4MHz.由图2可以发现,当强泵浦场的失谐量Δb=0时,出现了类似于Λ型次能级原子系统所呈现的电磁感应透明窗口,在拉曼共振Δa=Δb=0处,系统形成一个原子暗态,极化率的实部和虚部都为零.在相同条件下,图3给出了自克尔非线性极化率随探测场失谐量的变化曲线,可以发现,自克尔非线性极化率的虚部曲线显示出三个电磁感应透明点,而且对应的电磁感应透明窗口比线性极化率所对应的窗口要窄.同时发现自克尔非线性极化率的强度要比线性极化率的强度弱好几个数量级.图4给出了在满足拉曼共振Δa=Δb=0条件下,交叉克尔非线性极化率随探测场Ωc的失谐量Ωc的变化曲线.从图中我们可以明显的发现,在远离共振区,交叉克尔非线性极化率的实部曲线衰减比虚部慢得多.因此,当选择探测场Ωc远离共振时,可以获得一个相当大的交叉克尔非线性极化率的实部,并且由图2和图3可知,在拉曼共振条件下所对应的线性极化率和自克尔非线性极化率均为零,即可以获得无吸收有效的纯交叉克尔非线性.例如在图4中,当Δc=100MHz时,通过计算交叉克尔极化率的实部大约为10-8 m2 V-2,而此时线性极化率和自克尔非线性极化率为零,并且交叉克尔非线性极化率的虚部小到可以忽略不计.而由交叉克尔效应诱导探测场Ωa的相位偏移,可以利用下式得到上式中,l为相互作用的长度,λ0为探测场Ωa在真空中的波长.由图4所给的参量可以得到Δφ=0.1rad的光学相位偏移.本文在N型四能级原子系统中,提出一个获得有效交叉克尔非线性效应的方案.利用密度矩阵方程和微扰理论,导出了线性极化率和非线性极化率的具体表达式,给出了它们随3个电磁场失谐量变化关系.在一般条件,光与物质相互作用获得的交叉克尔非线性效应总是伴随着线性和自克尔非线性效应,但是在本文所提出的模型中,在满足拉曼共振Δa=Δb=0条件下,原子对光只存有交叉克尔响应,线性极化率和自克尔非线性极化率均等于零.虽然在此条件下所对应的交叉克尔非线性吸收不可忽略,但若探测场Ωc远离共振,仍可以获得一个大的交叉克尔非线性,同时交叉克尔非线性吸收部分小到可以忽略不计.因此在拉曼共振Δa=Δb=0条件下,通过适当选择探测场Ωc的失谐量,可以获得一个无吸收的有效的纯交叉克尔非线性.【相关文献】[1]Jaromir F,Ladislav M,Radim F.Entanglement concentration of continuous-variable quantum states[J].Physical Review:A,2003,67:022304-022308.[2]David M,Natalia K.Procrustean entanglement concentration of continuous-variable states of light[J].Physical Review:A,2006,74:042315-042320.[3]David V,Mauro F,Paolo plete Quantum Teleportation with a Kerr nonlinearity[J].Physical Review Letters,2000,85:445-448.[4]Clausen J,Knoll L,Welsch D G.Quantum state conversion by cross-Kerr interaction [J].Journal of Optics Quantum and Semiclassical Optics,2002,4:155-163.[5]Munro W J,Nemoto K,Beausoleil R G,et al.High-efficiency quantum-nondemolition single-photon-mumberresolving detector[J],Physical Review:A,2003,71:033819-033822.[6]Lukin M D,Imamoglu A.Nonlinear optics and quantum entanglement of ultra-slow single photons[J].Physical Review Letters,2000,84:1419-1422.[7]Yan M,Rickey E,Zhu Y.Observation of absorptive photon switching by Quantum interference[J].Physical Review:A,2001,64:041801-041806.[8]Yan M,Rickey E,Zhu Y.Nonlinear absorption by Quantum interference in cold atoms[J].Optics Letters,2001,26:548-551.[9]Yan Xiang′an,Wang Liqiang,Yin Baoyin,et al.Enhancement of nonlinear susceptibility in a four-level tripod scheme[J].Chinese Optics Letters,2010(8):795-799.[10]Yan Xiang′an,Wang Liqiang,Yin Baoyin,et al.Enhanced self-Kerr nonlinearity in spontaneous emission[J].Journal of the Optical Society of America B-optical Physics,2009,26:1862-1868.[11]Yan Xiang′an,Wang Liqiang,Yin Baoyin,et al.Effect of spontaneously generated coherence on Kerr nonlinearity in a four-level atomic system [J].Physical Letters:A,2008,372:6456-6460.[12]武海斌,常宏,马杰,等.Λ型三能级原子系统中Raman跃迁增强的Kerr非线性效应[J].物理学报,2005,54:3632-3636.[13]任立庆,仇旭,樊荣,等.光脉冲Λ-在三能级介质中传输的解析分析[J].陕西师范大学学报:自然科学版,2009,37(3):28-32.[14]Payne M G,Deng L.Extremely slow propagation of a light pulse in an ultracold atomic vapor:A Raman scheme without electromagnetically induced transparency[J],Physics Letters:A,2001,64:031802-031805.[15]Deng L,Hagley E W,Kozuma M,et al.Achieving very-low-loss group velocity reduction without electromagnetically induced transparency[J],Applied Physics Letters,2002,81:1168-1170.[16]Wang L J,Kuzmich A,Dogariu A.Gain-assisted superluminal light propagation[J],Nature,2000,406:277-279.[17]Schmidt H,Imamoglu A.Giant Kerr nonlinearities obtained by electromagnetically induced transparency[J].Optics Letters,1996,21:1936-1938.[18]Kang H,Zhu Y.Observation of Large Kerr nonlinearity at low light intensities [J].Physics Review Letters,2003,91:093601-093604.[19]Wang Z B,Maralin K P,Sanders B rge crossphase modulation between slow copropagating weak pulses in 87Rb[J].Physical Review Letters,2006,97:063901-063904.[20]石顺祥,陈国夫,赵卫,等,非线性光学[M].北京:高等教育出版社,2003:113-197.。
考研专业英语试题及答案
考研专业英语试题及答案一、选择题(每题2分,共20分)1. The phrase "break a leg" is commonly used to mean ________.A. To cause someone to fallB. To wish someone good luckC. To cause a failureD. To cause a break in a performance答案:B2. Which of the following is NOT a characteristic of academic writing?A. Formal languageB. Clear structureC. Personal opinionsD. Evidence-based arguments答案:C3. In the context of scientific research, "hypothesis" refers to a ________.A. Final conclusionB. Tentative explanationC. Unproven theoryD. Confirmed fact答案:B4. The term "sustainability" in environmental studies usually implies ________.A. The ability to be maintainedB. The ability to be soldC. The ability to be recycledD. The ability to be ignored答案:A5. The word "disseminate" in academic context means to________.A. Spread information or knowledgeB. Gather information or knowledgeC. Hide information or knowledgeD. Analyze information or knowledge答案:A6. Which of the following is the correct way to cite a book in APA format?A. Author, A. A. (Year). Title of the book. Publisher.B. Author, A. A. (Year). Title of the book. Journal.C. Author, A. A. (Year). Title of the book. Website.D. Author, A. A. (Year). Title of the book. Conference.答案:A7. In the field of economics, "opportunity cost" refers to________.A. The cost of the next best alternativeB. The cost of the best alternativeC. The cost of the worst alternativeD. The cost of the same alternative答案:A8. The phrase "pro bono" is used to describe ________.A. Legal services provided at no costB. Legal services provided for free to friendsC. Legal services provided for a reduced feeD. Legal services provided for a profit答案:A9. In the context of literature, "allegory" is a narrative technique that ________.A. Describes a real eventB. Tells a story with a hidden meaningC. Is based on a true storyD. Is a personal account答案:B10. The term "peer review" in academic publishing refers to the process of ________.A. Reviewing by the general publicB. Reviewing by the author's peersC. Reviewing by the author's studentsD. Reviewing by the author's colleagues答案:B二、填空题(每题2分,共20分)1. The ________ of a scientific paper typically includes the research question, hypothesis, and methodology.答案:abstract2. In a research study, the ________ is the group that receives the standard treatment or no treatment at all.答案:control group3. The ________ is the process of systematically collecting and analyzing data to answer a research question.答案:research methodology4. A ________ is a type of literature review that synthesizes findings from multiple studies on a topic.答案:meta-analysis5. The ________ is the part of a research paper where the writer discusses the implications of the findings.答案:discussion6. In statistics, the ________ is a measure of the extent to which two variables are linearly related.答案:correlation coefficient7. ________ is the process of making a formal request for permission to use someone else's work.答案:copyright clearance8. A ________ is a formal statement of a problem or question that is to be solved or answered.答案:research problem9. In a research study, the ________ is the group that receives the treatment or intervention being tested.答案:experimental group10. ________ is the process of evaluating the quality of a research study based on established criteria.答案:methodological critique三、简答题(每题10分,共30分)1. Explain the difference between qualitative andquantitative research methods.答案:Qualitative research methods focus on understanding social phenomena through non-numerical data, such as interviews, observations, and documents. It aims to explore and describe complex social behaviors and experiences. On the other hand, quantitative research methods involve collecting numerical data and using statistical techniques to test hypotheses and make generalizations. It aims to measure and quantify relationships between variables.2. What is the significance of a literature review in a research paper?答案:A literature review in a research paper is significant because it provides a comprehensive overview of existing knowledge on a topic. It helps to establish the context of the research, identifies gaps in the。
公共服务的共同生产:文献综述及其启示
公共服务的共同生产:文献综述及其启示张云翔【摘要】共同生产是目前西方公共管理学在公共服务供给研究方面最为热门的研究议题之一,但在我国相关研究还很有限.本文通过回顾共同生产理论的主要内容与发展历程,分析其研究取向和基本逻辑,为推进我国共同生产研究与创新我国公共服务供给模式提出理论性的潜在路径.研究发现,共同生产是公众在公共服务各个环节中与服务提供者、管理者形成密切互动的一种参与形态,也是公共服务供给的关键所在.但过去的西方共同生产研究在共同生产中所创造的价值、共同生产中的公民角色,以及政府在共同生产的管理等方面还存在许多有待回应的问题,甚至学界对共同生产的定义依然存在争议.尽管我国现有的共同生产文献较少,但在公共服务参与、志愿服务和顾客参与等研究中都蕴含了共同生产的理念.在结合我国的社会情境的基础上,我国的共同生产研究可以在概念界定、共同生产的管理等方面为共同生产理论的发展做出重要贡献,并推动我国公共服务供给模式的实践创新.【期刊名称】《甘肃行政学院学报》【年(卷),期】2018(000)005【总页数】15页(P31-45)【关键词】共同生产理论;公共服务;公民参与;研究综述【作者】张云翔【作者单位】上海师范大学哲学与法政学院,上海 200234【正文语种】中文【中图分类】D035过去几十年世界各国的公共管理实践证明了政府、市场和社会部门都存在失灵的可能,所以在推动公共服务创新的过程中需要采用合作式、互动式的供给模式,实现政府、市场和社会部门之间的整合与协调。
党的十九大明确提出,我国社会的主要矛盾已经发生了转变,为了更好地满足人民日益增长的对美好生活的向往,创新公共服务供给模式也成为了我国公共管理的重要命题。
在促进公共服务供给多元化的过程中,公民本身也是重要的参与者和自我服务者,这一点在公共管理学界已经越来越受到认可和重视。
同时,随着市场经济和社会治理的转型,塑造一个良好的政府与公民伙伴关系对于创新公共服务供给模式而言更将是未来发展的重要方向。
Comment on ``Theorem for nonrotating singularity-free universes''
3 = lim − t1 →∞ 2
t0 →0
t1 −1/2 dt t0 t t1 3/2 dt t0 t
= 0,
()
= lim −2
t1 →∞ t0 →0
t1 t0 dt t1 2 t0 t dt
= 0.
(4)
As we can see, for both cases, the spacetime averages of the quantities in the R.H.S. of (1), including the energy 1 density average Tab − 2 gab T ξ a ξ b , vanish. For realistic closed Robertson-Walker universes (κ = 1), we do have finite spacetime averages. Nevertheless, as it was noted above, one cannot use the vanishing of the stress energy invariants to decide between singularity-free and singular descriptions of the universe. This work was supported by FAPESP and CNPq. Alberto Saa Departamento de Matem´tica Aplicada, a UNICAMP – C.P. 6065, 13081-970 Campinas, SP, Brazil
a3 dt
˙ For both realistic cases of a dust-filled universe (a(t) = Ct2/3 ) and a radiation-filled universe (a(t) = Ct1/2 ), θ vanishes. Indeed, one has ˙ θ and ˙ θ
翻译文献一
ReviewClay in cement-based materials:Critical overview ofstate-of-the-artM.L.Nehdi ⇑Department of Civil and Environmental Engineering,University of Western Ontario,London,Ontario,Canadah i g h l i g h t sCritical overview of effects of clay in cement-based materials is provided. Dimensional stability of aggregates bearing clay minerals is examined. Treatment of clays to mitigate their detrimental effects in concrete is outlined. Research on nano-clays in cement-based materials is highlighted.How to resolve ambiguity related to clays in cement-based materials is discussed.a r t i c l e i n f o Article history:Received 23May 2013Received in revised form 10October 2013Accepted 31October 2013Available online 28November 2013Keywords:Clay SandAggregate Concrete Workability Admixture Swelling Durability Nanoa b s t r a c tLimitations in guidelines and standards on the amount of clay in sand and coarse aggregate micro-fines and the influence of such micro-fines on fresh and hardened concrete properties is often ambiguous for practitioners and quality control professionals.This is compounded by conflicting related data in the open literature and the inadequacy of some standard test procedures for capturing the real problems associated with the presence of clays in cement-based materials.This paper examines the various types of clay,limitations on clays in aggregates in various standards,and the test methods used to assess the presence of clays in aggregates.A critical overview of literature on the possible effects of clay in cement-based materials is provided,including effects on water demand,workability,mechanical strength,dimensional stability and chemical admixtures dosage.The problem of dimensional stability of aggre-gates bearing clay minerals is examined.Possible chemical treatment of clays to mitigate their detrimen-tal effects in concrete is also outlined.Finally,emerging research on using nano-clays in cement-based materials is highlighted and recommendations to resolve ambiguity related to the presence of clays in cement-based materials are proposed.Ó2013Elsevier Ltd.All rights reserved.Contents 1.Introduction (373)2.Different clay minerals and their behaviour................................................................................3733.Mechanisms of clay swelling............................................................................................3744.Effects of clay on properties of concrete...................................................................................3745.Effects of clay on chemical admixtures....................................................................................3766.Expansion of aggregates with clay bearing minerals.........................................................................3767.Test methods for clay in cement-based materials ...........................................................................3767.1.Aggregate durability index ........................................................................................3777.2.Sand equivalent test .............................................................................................3777.3.Methylene blue test .............................................................................................3777.4.Grace colorimetric modified methylene blue method ..................................................................3788.Standard limitations on clay content in aggregates..........................................................................3789.Chemical treatment of aggregates to mitigate effects of clay ..................................................................37810.Nano-clay in cement-based materials....................................................................................3790950-0618/$-see front matter Ó2013Elsevier Ltd.All rights reserved./10.1016/j.conbuildmat.2013.10.059⇑Tel.:+1(519)6612111x88308.E-mail address:mnehdi@uwo.ca11.Concluding remarks (381)References (381)1.IntroductionThe Spanish proverb puts it best:‘‘clay and lime conceal much evil’’.This author sensed such perception of clay through personal involvement in high-profile international projects(e.g.two of the tallest buildings in the world,world’s deepest and second largest water pumping and treatment plant,one of the world’s largest air-ports,a world landmark bridge,etc.).Ambiguity arises when stan-dards,technical provisions and subsequently project specifications may be unnecessarily restrictive on the amount of micro-fines al-lowed in aggregates used in concrete,while locally available sands and/or coarse aggregates cannot meet such limitations at compet-itive cost.Often futile debate emerges on what exactly is the nat-ure of aggregate micro-fines at hand,is it responsible for any performance issues of the concrete produced,how such an influ-ence can be accurately quantified for various microfine contents, and can the limits on micro-fines be relaxed without short-or long-term performance problems of the concrete.The discussion can be fuelled with conflicting pieces of information sourced from the open literature or through personal communications.Therefore,this article is an attempt to demystify clay in con-crete,critically overview the state-of-the-art on this issue,and pro-vide a self-contained document that can scrutinise existing related data and the various pieces of evidence,examine the available test methods for evaluating the existence and effects of clays in ce-ment-based materials,and essentially savefort of navigating through this often2.Different clay minerals and theirDetailed information on clay mineralsin Fowden et al.[24].Clay minerals areand layered crystalline substances thatweathering of certain rock formingicates of aluminium and other metallictially two fundamental crystal layers,alumina(octahedral).It is basically theare stacked together with differentthe crystal lattice that differentiates clayite,illite and montmorillonite from onegeological conditions and prevailingmine which type of clay is formed.Clay minerals are commonly found in75l m material)of natural aggregates.ically less than2l m in size,but can be10sized clay materials and their unit cellsative charges on their surfaces.Whenbetween clay particles gets occupied byThe simultaneous presence of negativelyand the dipoles of water create electro-tract and hold the dipoles of water.Claymulti-layer formations.The chargedcharge around the particles are togetherlayer[39].The space between layers and the freeinterlayer space are the chief reasons formineral has a swelling behaviour.Theabsorption of water dipoles to theto be achieved.With decreased interlayeramong the layers become powerful and of water,so swelling does not occur.Conversely,as the interlayer space becomes more significant,interlayer forces are so that water absorption in the interlayer space can progress until interlayer bonds fail.Hence,the clay particles get separated and rearranged and swelling occurs.The extent and kinetics of the mechanisms de-scribed above depend on several other parameters acting individ-ually or in combination.These include the density of the surface charge,the type and valence of the cations,the concentration of the electrolytes and the dielectric constant.Therefore,swelling depends on the type of clay mineral.Gener-ally,smectite minerals,with montmorillonite being a chief repre-sentative of this group,are considered swelling.Such smectites encompass repeat units of silica,gibbsite(aluminium hydroxyl groups)and adjacent silica layers joined by Van der Waals bonds (Fig.1).The substitution of aluminium for magnesium in the gibb-site layer and for silicon in the silica layer results in a net negative charge in smectites,thus imparting a high cation exchange capac-ity.In addition to their high cation exchange capacity,the inter-layer spacing between silica layers can increase in smectites through water absorption,causing substantial swelling.Con-versely,clay minerals such as pyrophyllite,margarite and illite are considered non-swelling.For instance,kaolinites comprise re-peat units of silica and gibbsite and lack the inter-layer spacing found between adjacent silica layers in smectites.Hence,their cat-ion exchange capacity is less than that of smectites and is predom-1.Schematic illustration of the layered structure present in montmorillonite (courtesy of J.Plank,2013).M.L.Nehdi/Construction and Building Materials51(2014)372–382373d-spacing when exchangeable cations are hydrated by an aqueous solution[7].The presence of clay minerals in coarse andfine aggregates can have remarkable effects on the workability of fresh concrete,effec-tiveness of chemical admixtures,and on the mechanical strength, dimensional stability and durability of hardened concrete.There-fore,it is paramount to determine the type and content of clay minerals in aggregates,develop rapid and reliablefield test meth-ods to quantify deleterious clay minerals in aggregate stockpiles and recommend remedial techniques,if any,to make the clay-con-taminated aggregates adequate for use in concrete.In this article,a critical overview of the effects of clay minerals in cement-based materials is provided.The test methods used to assess the presence of clay in aggregates are examined,and inter-national standards on clay minerals in concrete are highlighted. The problem of dimensional stability of aggregates bearing clay minerals is discussed.Possible chemical treatment of clays to mit-igate their detrimental effects in concrete is also outlined.Finally, emerging research on using nano-clays in cement-based materials is highlighted.It is hoped that this critical analysis of international literature could mitigate existing ambiguity on the topic of clay in concrete among engineers and practitioners.3.Mechanisms of clay swellingThe mechanisms of clay swelling have been extensively dis-cussed in the literature.Only aspects relevant to clays in cement-based materials are considered herein.Much of this discussion is based on a review by Anderson et al.[8].In contact with water, exchangeable cations in the clay interlayer space tend to hydrate, forcing clay layers apart.Swelling can occur via two different re-gimes;crystalline and osmotic swelling.Crystalline swelling can occur in all types of clay minerals.This was shown to be a short-range swelling occurring in a discrete fashion,through the stepwise formation of mixtures of interlayer hydrates.Several layers of water molecules line up to form a qua-si-crystalline structure between unit layers resulting in an in-creased interlayer spacing.For instance,smectite clays absorb water and form one-,two-,three-and four-layer hydrates.The equilibrium layer spacing for a certain clay mineral is the state whereby the thermodynamic potential(free energy)is a global minimum given thermodynamic constraints of temperature,pres-sure,and water chemical potential(Anderson et al.[8]).Typical interlayer spacing recorded in the crystalline swelling regime ranges from9to20Å.Osmotic swelling occurs in particular clay minerals known to contain exchangeable cations in the interlayer region.When the concentration of cations in the interlayer space is higher than that in the surrounding solution,water molecules migrate into the interlayer space to restore cation equilibrium.This type of swelling can cause appreciably larger volume increases(interlayer spacing of20–130Å)than that resulting from crystalline swelling.For in-stance,smectites can swell in this osmotic fashion.Conversely, K+saturated smectite clay do not swell in this manner and form crystalline hydrates even in aqueous suspension[52].Thus,the K+ion can be used to prevent the swelling of sodium saturated clay minerals(Anderson,2010).The type,size and charge of exchangeable cations present in the clay interlayer space have a predominant effect on the magnitude of clay swelling.Water desorption isotherm measurements of montmorillonite intercalated with different monovalent exchange-able cations(Li+,Na+,K+,Rb+and Cs+)indicated that for larger cations,less water is adsorbed[40].Clay minerals incorporating monovalent cations having larger hydration energies tend to swell more than those containing cations with lower hydration energies.Furthermore,the type of substitutions present and layer charge of a clay mineral can significantly influence its swelling characteris-tics.This is discussed in greater detail in Anderson et al.[8].4.Effects of clay on properties of concreteThere has long been concern that clay particles may be harmful to concrete because of their ability to absorb water and swell, which increases the water demand in fresh concrete.As early as 1933,Parsons[48]studied the effects of partially substituting clay for either10%by volume of cement or7.5%by volume offine aggregate,on the compressive strength,absorption,and perme-ability of concrete.Three different clays were used:red surface clay from Occoquan,blue clay from Baltimore,Maryland and yellow clay from Alexandria,Virginia,It was believed the clays were free from organic matter as they were used in brick manufacturing.It was observed that substituting10%of clay for cement by volume caused around0–10%decrease in compressive strength at ages be-yond three months,but there was no appreciable effect on perme-ability.Also,substituting clay for7.5%offine aggregate increased compressive strength by up to37%.The effects of clay on the water absorption,permeability,and resistance to freezing and thawing cycles of concrete were not significant.In1934,Lyse[37]reported that experimental work at Lehigh University supported the claim that severe limits on the contents offines in concrete were unnec-essary and even could become illogical when chemical admixtures are permitted.More recently,Solomon and Ekolu[60]investigated the incor-poration of clay soil into concrete mixtures as a means of making low-cost,low-strength construction materials for infrastructure in developing countries.Four control concrete mixtures with 350kg/m3of cement and water-to-cementitious content(w/cc)ra-tio of0.70,0.75;and with280kg/m3cementitious content with w/ cc=0.80and0.85were tested.Further mixtures had10%,20%,30%, 40%,and60%partial substitution of cement with local raw clay.It was found that clay–cement concrete mixtures with a maximum w/cc=0.80and20–30%clay replacement for cement can be suited to fulfil the strength and workability requirements for low-cost, low-strength applications including housing,roads and dams.Olanitori[47]reported that the higher the clay and silt content in sand,the higher was the cement dosage increment needed to maintain the compressive strength of concrete beyond20MPa, which is the value generally specified at28-d in Nigeria for a mix-ture ratio1:2:4.He recommended carrying out a comparative cost analysis between the cement dosage increments used for sand with a particular clay/silt content,and washing the sand to reduce the clay/silt content,so as to determine which is more cost-effec-tive to maintain20-MPa compressive strength.Li et al.[32]studied the workability,strength and modulus of elasticity,drying shrinkage and creep,freeze–thaw resistance and chloride ion permeability of C60high-performance concrete (HPC)made with manufactured sand(MS)containing 3.5–14% crushed limestone dust,versus that made with river sand(RS)with clay amounts of3%and5%.The clay content in MS decreased work-ability,increased drying shrinkage and accelerated freeze–thaw damage of the C60-HPC,but did not affect its compressive strength and chloride ion permeability.It was concluded that C60-HPC can be made with MS with a high content of crushed limestone dust, but the amount of clay in MS should be controlled.Norvell et al.[46]explored the effects of clay minerals present in natural aggregates versus that of clay-sized particles present in manufacturedfine aggregates on concrete performance by‘‘dop-ing’’micro-fine aggregates with clay minerals and non-clay con-taining particles of similar size.Specifically,they investigated the effects on water demand,water-reducing admixture demand,374M.L.Nehdi/Construction and Building Materials51(2014)372–382compressive strength and drying shrinkage.It was concluded that clays do increase the water and superplasticizer demand in accor-dance with their interlayer absorption and cation exchange capac-ity,respectively(Table1).However,clay-sized particles(particles of similar size to clay but with different mineralogy)did not signif-icantly affect the water and superplasticizer demands at the levels studied.At constant w/c,only smectite(montmorillonite)clay was found to decrease compressive strength and to increase drying shrinkage.Li et al.[33]explored the effects of the clay content and charac-teristics,methylene blue value(MBV ranging from0.35to2.5)of manufactured sand(MS)and the limestonefines content on the performance of concrete.Results showed that with an increase in MBV,the workability,flexural strength and7-d compressive strength of the MS concrete decreased,while the28-d compressive strength was not affected.Also,increasing MBV enhanced plastic and drying shrinkage cracking of the concrete and remarkably accelerated its freeze–thaw damage and abrasion loss.It was con-tended that the critical MBV was1.4;a value below which the per-formance of MS concrete is not significantly compromised by the presence of clay.Since different specifications and code provisions define various limits for thefine impurities content of the concrete coarse aggre-gate,Seleem and El-Hefnawy[56]evaluated the effects of different levels offine impurities normally found in coarse aggregates in Egypt on the compressive strength and dimensional stability of concrete.Based on their test results,a higher limit offine impuri-ties(5%)in coarse aggregate was suggested,particularly when the increase in shrinkage is overcome using a superplasticizer and low-er water-to-cement-ratio.Chan and Wu[14]argued that research has shown silts and clays to be deleterious because in the mixing of concrete con-taining silts and clays more water is added to achieve adequate workability.They reasoned that the use of a superplasticizer at similar w/c ratio to that of a control OPC concrete not containing silts and clays may provide good quality concrete.They con-ducted trial concrete mixtures with particles less than150l m in size consisting of silts and clays obtained from crushed gran-ite stone along with a sulphonated naphthalene superplasticizer. They concluded that durable concrete could be made with25% partial replacement of cement with silt and clay using a w/c ra-tio of0.5.However,Chan and Wu[14]explored workability, strength and permeability of the silt and clay concrete,but did not assess its dimensional stability,abrasion and freeze–thaw resistance.Courard et al.[18]investigated the effects of various limestone fillers on the fresh and hardened properties of self-compacting mortars.Six different limestonefillers were used at15%,25%and 35%partial mass replacement of cement.Thefillers incorporated clays and had methylene blue absorption values between0.7and 5.0.Among the sixfillers,two contained swelling clays.It was found that the water requirement of limestonefillers was primar-ily affected by their content of swelling clay.The water require-ment had a direct correlation with the methylene blue absorption and the BET specific surface of thefillers.The consis-tency of fresh mortars decreased with increasing swelling clay con-tent of the limestonefillers.It was argued that despite the effect on fresh mortar properties,no major influence of clays on the behav-iour of hardened mortars was observed.Even the swelling clays did not hinder the porosity of limestonefiller modified mortars.It was contended that should superplasticizers be used to solve rheologi-cal problems,fillers from the aggregate industry and stone sawing could be used in concrete manufacturing.Fernandes et al.[22]carried out an experimental study on clay–cement–sand composites.They compared the effects of pure quartz sand to that of two synthesized sands made by dry mixing of this pure sand with either20%by mass of kaolin or20%by mass of montmorillonite.They made various mortars with Type I OPC and variable sand types,water/cement ratios and sand/cement ratios.The28-d compressive strength was measured and X-ray diffraction was employed to examine whether any reactions between the clay and cement had oc-curred.A linear relationship existed between the amount of clay and corresponding amount of water needed to maintain certain workability.XRD analysis did not identify any secondary prod-ucts forming in the presence of clay.Moreover,the mixtures incorporating kaolin clay followed similar strength-w/c relation-ship to that of normal concrete,with lower strengths attributed to increased water demand and/or increased compaction diffi-culty,while those including montmorillonite followed a different relationship,suggesting that this clay had other deleterious ef-fects beyond the increased water demand.It was postulated that for the typical w/c and strength values of building materials in developing countries,satisfactory mortar and blocks can be made from clay-contaminated sand.However,the effect of the type of clay is significant and structural concrete made with such materials needs proper durability and dimensional stability investigation.The effects of coarse aggregate coatings on concrete proper-ties were explored by Muñoz et al.[43].Seven concrete mixtures were made with coarse aggregates containing two types of coat-ings:naturalfield-coated aggregates,and manufactured coated samples of dust and clayfines.The effects of these coatings on concrete performance were examined by comparing the relative changes in physical and mechanical properties of the concrete versus that of a control concrete made with washed aggregates. It was concluded that microfine coatings on coarse aggregates can influence the properties of fresh and hardened concrete even when their amount in the passing No.200sieve is less than 1.5%.The extent and nature of such influence depend on the quantity and type of the microfine.Thus,ASTM C117,which only accounts for the quantity of micro-fines present in the aggre-gates,was not considered an adequate monitoring tool for this problem.It was suggested that the product of MBV(methylene blue value)and P200(maximum percentage of material passing the No.200sieve),referred to as the MMBV was the best overall predictor.Table1Water and admixture demand with clay minerals and non-clay sized minerals (modified after[46].Type of Mineral Waterdemand Superplasticizer dosage (w/c=0.42)Control:granite sand0.47 4.5Clay mineral1%Kaolinite0.50 6.04%Kaolinite0.608.01%Illite0.49 5.54%Illite0.5110.01%Montmorillonite0.6218.54%Montmorillonite0.90186.0Clay sized particles1%Fine calcium carbonate(60%<2l m)0.48–4%Fine calcium carbonate(60%<2l m)0.48 4.01%Ultrafine calcium carbonate(90%<2l m)0.49–4%Ultrafine calcium carbonate(90%<2l m)0.49 4.01%Ground silica(96%<5l m)0.47–1%Ground silica(96%<5l m)0.47 2.5M.L.Nehdi/Construction and Building Materials51(2014)372–3823755.Effects of clay on chemical admixturesIt is believed that their ability to readily exchange cations is the most deleterious feature of clays in concrete.Cations are ex-changed in order to balance inherent electrical charges on the sur-face of clay particles.Such cations can be readily exchanged with organic materials such as water-reducing admixtures and superp-lasticizers.This high affinity to organic substances competes with the adsorption and dispersing mechanisms of chemical admixtures at the surface of cement and supplementary cementitious materi-als particles.Subsequently,as clay particles consume part of the chemical admixture,a higher dosage will be required to achieve certain workability.This not only has cost implications,but the very high admixture dosage can lead to excessively long setting time,delays in strength gain and formwork removal.Table1exhib-its the substantial effect observed by Norvell et al.[46]of swelling clay on the superplasticizer demand of concrete.In particular,there has been growing evidence that polycarbox-ilate-based superplasticizers(PCEs)are more sensitive to clays than poly-condensate superplasticizers.This is primarily due to their incorporation into the layered clay structure via their side chains,which impedes their dispersing ability.It was observed by several researchers(e.g.[55,31]that different types of PCEs show pronounced sensitivity to clay and their dispersing force de-creases significantly in its presence.The predominantly used side chain in PCE superplasticizers is poly(ethylene oxide),which is known to easily intercalate within alumosilicate layers of clays (e.g.[36].Montmorillonite(MMT)was found to be particularly harmful to concretefluidity compared to other clay minerals such as kaolinites(e.g.[27].This is caused by the expanding lattices of MMT,allowing intercalation,swelling and cation exchange[38].Li et al.[34]studied the influence of clay on the disperse-ability of polycarboxylate superplasticizers.They investigated thefluidity and viscosity of cement paste and examined the influence of clayfiltrate on the molecular structure and kinetics of adsorption of PCE on the surface of clay particles in a simu-lated alkaline environment consisting of saturated calcium hydroxide solution.Theirfindings indicate that PCE has no dis-persing effect on cement paste once the clay content reached 15%.Increasing the PCE dosage mitigated this negative effect of clay.Moreover,it was found that the clayfiltrate did not change the molecular structure of PCE nor did it affect its disperse-abil-ity.The kinetics of clay adsorption in the simulated alkaline environment on PCE was rapid,with an adsorption capacity about4times that on cement,with clay reaching its equilibrium adsorption within6min.Ng and Plank[44]tested PCEs consisting of methacrylic acid/ MPEG methacrylate-ester with molar ratios of6:1and1.5:1.They found that the tested PCEs sorb chemically and physically onto clay by amounts about100times higher than that on cement.Chemi-sorption appeared to take place via intercalation of the poly(ethyl-ene oxide)side chains into the interlayer region between alumos-ilicate layers,while physic-sorption occurred on positively charged clay surfaces through uptake of Ca2+.The type of sorption was dos-age dependent,with side chain intercalation dominating at higher PCE dosage,while electrostatic attraction via the clay surfaces an-ionic backbone prevailed at lower dosage.Since PCEs possessing high grafting density were more vulnerable to clay effects,it was argued that poly-glycols can be utilised as sacrificial agents when highly grafted PCEs are employed at high dosages.Lei and Plank[31]asserted that new PCE superplasticizers pos-sessing modified chemical structure for enhanced robustness to-wards clay need to be developed.Hence,they synthetized modified PCEs from methacrylic acid and hydroxyl-alkyl methac-rylate esters and tested their dispersion performance in cement with and without montmorillonite clay.The new PCE was found to disperse cement effectively in the presence of clay and was much less affected by clay than conventional PCEs.A mechanistic study including adsorption and XRD experiments revealed that the new PCE only adsorbs on the surface of clay and does not incor-porate into its layered structure,which explains its tolerance to clay contamination.6.Expansion of aggregates with clay bearing mineralsThe dimensional stability of aggregates versus moisture changes has been discussed in detail by Shayan[59].Generally, dense and un-weathered aggregates are not affected by changes in moisture content.Their water absorption is generally less than 1%by mass of rock.Hence they usually retain their dimensions un-der wet or dry conditions.However,some vesicular rocks may ex-hibit high water absorption,yet can remain dimensionally stable provided they are free of expansive clay minerals.Once altered or weathered,rocks can exhibit expansive minerals,yielding high water absorption due to the ability of clay minerals to accommo-date water in its interlayer spaces.The formation of expansive clay minerals has been reported by several authors in basaltic rocks and in granophyre(e.g.in[59];its effects on the properties of the rock as a source of concrete aggregate have also been well documented.Water absorption by clay minerals in aggregates can cause expansion of the granular matrix,hence causing expansion of the concrete.Drying can exhibit excessive shrinkage,possibly leading to cracking,especially under repeated wetting/drying conditions (e.g.[16,54].Water vapour and nitrogen absorption studies and measurements of internal and external surface area of basalts (e.g.[16,58]revealed a direct relationship between the length change of rock prisms subjected to wetting/drying cycles and their clay content.Similar relationships have also been established for granophyre and basalt[58,67].The dimensional stability and moisture sensitivity of rocks can be experimentally measured on prism specimens subjected to re-peated wetting–drying cycles and monitoring the associated length changes using accurate length measurement comparators (e.g.[16,57].Some indirect methods including correlating drying shrinkage with moisture absorption of aggregate or with adsorp-tion of other polar molecules such as methylene blue dye,have been used to predict the drying shrinkage of aggregates[59].In particular,the MBV value had a reasonable correlation with the clay content of tested materials and was successfully used to eval-uate a source rock for drying shrinkage before the development of a quarry at the site[57].Using124test specimens,a correlation was developed by Sha-yan[57]between drying shrinkage of aggregate and its MBV value. It was shown that MBV levels beyond1.75ml/g were associated with unacceptable aggregate drying shrinkage.Table2lists typical ranges of moisture-induced length changes measured on different rock prisms from Australian aggregate source rocks and reported by[59].It can be observed that andesitic tuffs,grey basalts and sandstones undergo significant length changes upon wetting and drying,at times exceeding1000micro-strains.Except grey basalt, substantial dimensional instability in rocks has been linked to higher clay content.Likewise,when clay occurred in the form of an interconnected network in basalt(e.g.[17]or in the form of veins in granophyre(e.g.[57],the length change was much larger than when a similar amount of clay was present in isolated patches or in vesicles.7.Test methods for clay in cement-based materialsConsidering the significant influence of the type and content of clay on the water and chemical admixture demand,mechanical376M.L.Nehdi/Construction and Building Materials51(2014)372–382。
OBSERVATION OF THE B c MESON AT CDF VAIA PAPADIMITRIOU for the CDF Collaboration
1 Introduction
+ The Bc meson is the lowest-mass bound state of quarkonium states containing a charm quark and a bottom anti-quark 1. Since this pseudoscalar ground state has non-zero avor, it has no strong or electromagnetic decay channels. It is the last such meson predicted by the Standard Model and the only meson with two di erent heavy quarks. It decays weakly yielding a large branching fraction to nal states containing a J= 2;3;4;5. Nonrelativistic potential models predict a Bc mass in the range 6.2{6.3 GeV/c2 6;7. In these models, the c and b are tightly bound in a very compact system and have a rich spectroscopy of excited states. The production of Bc mesons has been calculated in perturbative QCD. At transverse momenta pT large compared to the Bc mass the dominant process is that in which a b is produced by gluon fusion in the hard collision and fragmentation provides the c. At lower pT a full 4 calculation 8 shows that the dominant process is one in s which both the b and c quarks are produced in the hard scattering. These and other calculations 8;9;10;11;12 provide inclusive production cross sections along with distributions in pT and other kinematic variables. We expect three major contributions to the Bc decay width: b ! cW + with the c as a spectator, leading to nal states like J= or J= ` ; c ! sW + , with the b as spectator, leading to nal states like Bs or Bs ` ; and cb ! W + annihilation, leading to nal states like D K, or multiple pions. Since these processes lead to di erent nal states, their amplitudes do not interfere. When phase space and other e ects are included, the predicted lifetime is in the range 0.4{1.4 ps 2;13;14;15;16;17. Because of the wide range of predictions, a Bc lifetime measurement is a test of the di erent assumptions made in the various calculations. Several authors have also calculated the Bc partial widths to semileptonic nal states 2;3;4;5;18. Limits on the Bc production have been placed by
自由之心无界的英语作文
The heart of freedom knows no bounds,and this concept is beautifully encapsulated in the English essay that follows.In the pursuit of freedom,the human spirit is boundless.It is a journey that transcends physical barriers,societal norms,and even the limitations of our own minds.The essay explores the essence of freedom,delving into its various dimensions and the profound impact it has on the human experience.The essay begins by examining the philosophical underpinnings of freedom.It discusses the works of great thinkers such as John Stuart Mill and JeanJacques Rousseau,who have contributed to our understanding of the ls harm principle and Rousseaus social contract theory are highlighted,showing how these ideas have shaped our perception of individual liberty and collective responsibility.Moving beyond theory,the essay then delves into the practical aspects of freedom.It discusses the importance of free speech,the right to privacy,and the freedom of movement.The essay argues that these rights are fundamental to a democratic society and are essential for the flourishing of human creativity and innovation.The essay also explores the psychological aspects of freedom.It discusses the concept of cognitive liberty,which refers to the freedom of an individual to control their own thoughts,beliefs,and emotions.The essay argues that cognitive liberty is crucial for personal growth and selfactualization,as it allows individuals to explore their own identities and make meaningful choices in their lives.Furthermore,the essay touches upon the cultural and artistic expressions of freedom.It highlights the role of art,literature,and music in challenging oppressive systems and promoting social change.The essay cites examples of works by artists such as Pablo Picasso,George Orwell,and Bob Dylan,who have used their creative talents to advocate for freedom and social justice.The essay also acknowledges the challenges and complexities associated with the pursuit of freedom.It discusses the potential for freedom to be misused or abused,leading to chaos and conflict.The essay emphasizes the importance of balancing individual liberty with social responsibility,and the need for a collective commitment to upholding the values of freedom and justice.In conclusion,the essay reaffirms the boundless nature of the heart of freedom.It argues that freedom is not just a political or legal concept,but a deeply human aspiration that drives us to seek knowledge,express ourselves,and pursue our dreams.The essayencourages readers to embrace the spirit of freedom in their own lives,and to work towards creating a world where freedom can truly flourish.In essence,the essay is a celebration of the human spirits boundless quest for freedom.It provides a comprehensive exploration of the concept,drawing from philosophy, psychology,culture,and art to present a rich and nuanced understanding of freedom.By doing so,it inspires readers to reflect on their own values and aspirations,and to consider the role they can play in advancing the cause of freedom in their own lives and in society at large.。
GMAT网络课堂阅读笔记-王昆嵩主讲7
Passage 1In choosing a method for determining climatic condi-tions that existed in the past, paleoclimatologists invoke four principal criteria. First, the material-rocks, lakes,vegetation, etc.-on which the method relies must be ( 5 )widespread enough to provide plenty of information, since analysis of material that is rarely encountered will not permit correlation with other regions or with otherperiods of geological history. Second, in the process offormation, the material must have received an environ- (10) mental signal that reflects a change in climate and thatcan be deciphered by modern physical or chemicalmeans. Third, at least some of the material must haveretained the signal unaffected by subsequent changes in the environment. Fourth, it must be possible to deter- (15) mine the time at which the inferred climatic conditionsheld. This last criterion is more easily met in datingmarine sediments, because dating of only a smallnumber of layers in a marine sequence allows the age of other layers to be estimated fairly reliably by extrapola- (20) tion and interpolation. By contrast, because sedimenta-tion is much less continuous in continental regions, esti- mating the age of a continental bed from the knownages of beds above and below is more risky.One very old method used in the investigation of past (25) climatic conditions involves the measurement of waterlevels in ancient lakes. In temperate regions, there areenough lakes for correlations between them to give us a reliable picture. In arid and semiarid regions, on theother hand, the small number of lakes and the great (30) distances between them reduce the possibilities for corre-lation. Moreover, since lake levels are controlled by rates of evaporation as well as by precipitation, the interpreta-tion of such levels is ambiguous. For instance, the factthat lake levels in the semiarid southwestern United (35) States appear to have been higher during the last ice agethan they are now was at one time attributed toincreased precipitation. On the basis of snow-line eleva-tions, however, it has been concluded that the climatethen was not necessarily wetter than it is now, but rather (40) that both summers and winters were cooler, resulting inreduced evaporation.Another problematic method is to reconstruct formerclimates on the basis of pollen profiles. The type of vege- tation in a specific region is determined by identifying (45) and counting the various pollen grains found there.Although the relationship between vegetation andclimate is not as direct as the relationship betweenclimate and lake levels, the method often works well inthe temperate zones. In arid and semiarid regions in (50) which there is not much vegetation, however, smallchanges in one or a few plant types can change thepicture dramatically, making accurate correlationsbetween neighboring areas difficult to obtain.1. Which of the following statements about the difference between marine and continental sedimentation is supported by information in the passage?(A) Data provided by dating marine sedimentation is more consistent with researchers' findings inother disciplines than is data provided by dating continental sedimentation.(B) It is easier to estimate the age of a layer in a sequence of continental sedimentation than itis to estimate the age of a layer in a sequenceof marine sedimentation.(C) Marine sedimentation is much less widespread than continental sedimentation.(D) Researchers are more often forced to rely on extrapolation when dating a layer of marine sedimentation than when dating a layer ofcontinental sedimentation.(E) Marine sedimentation is much more continuous than is continental sedimentation.2. Which of the following statements best describes the organization of the passage as a whole?(A) The author describes a method for determining past climatic conditions and then offers specificexamples of situations in which it has been used. (B) The author discusses the method of dating marine and continental sequences and then explains howdating is more difficult with lake levels than withpollen profiles.(C) The author describes the common requirements of methods for determining past climatic conditionsand then discusses examples of such methods.(D) The author describes various ways of choosing a material for determining past climatic conditionsand then discusses how two such methods have yielded contradictory data.(E) The author describes how methods for determining past climatic conditions were first developed andthen describes two of the earliest known methods.3. It can be inferred from the passage that paleoclimatologists have concluded which of the following on the basis of their study of snow-line elevations in the southwestern United States?(A) There is usually more precipitation during an ice age because of increased amounts of evaporation.(B) There was less precipitation during the last ice age than there is today.(C) Lake levels in the semiarid southwestern United States were lower during the last ice age than theyare today.(D) During the last ice age, cooler weather led to lower lake levels than paleoclimatologists had previously assumed.(E) The high lake levels during the last ice age may havebeen a result of less evaporation rather than more precipitation.4. Which of the following would be the most likely topic for a paragraph that logically continues the passage?(A) The kinds of plants normally found in arid regions(B) The effect of variation in lake levels on pollen distribution(C) The material best suited to preserving signals of climatic changes(D) Other criteria invoked by paleoclimatologists when choosing a method to determine past climatic conditions(E) A third method for investigating past climatic conditions5. The author discusses lake levels in the southwestern United States in order to(A) illustrate the mechanics of the relationship between lake level, evaporation, and precipitation(B) provide an example of the uncertainty involved in interpreting lake levels(C) prove that there are not enough ancient lakes with which to make accurate correlations(D) explain the effects of increased rates of evaporation on levels of precipitation(E) suggest that snow-line elevations are invariably more accurate than lake levels in determining ratesof precipitation at various points in the past6. It can be inferred from the passage that an environmental signal found in geological materialwould not be useful to paleoclimatologists if it(A) had to be interpreted by modern chemical means(B) reflected a change in climate rather than a long-term climatic condition(C) was incorporated into a material as the material was forming(D) also reflected subsequent environmental changes(E) was contained in a continental rather than a marine sequence7. According to the passage, the material used to determine past climatic conditions must be widespread for whichof the following reasons?Ⅰ.Paleoclimatologists need to make comparisons between periods of geological history.Ⅱ. Paleoclimatologists need to compare materials that have supported a wide variety of vegetation.Ⅲ. Paleoclimatologists need to make comparisons with data collected in other regions.(A) Ⅰonly(B) Ⅱonly(C) Ⅰand Ⅱonly(D) Ⅰand Ⅲonly(E) Ⅱand Ⅲonly8. Which of the following can be inferred from the passage about the study of past climates in arid and semiaridregions?(A) It is sometimes more difficult to determine pastclimatic conditions in arid and semiarid regions thanin temperate regions.(B) Although in the past more research has been done on temperate regions, paleoclimatologists haverecently turned their attention to arid and semiaridregions.(C) Although more information about past climates canbe gathered in arid and semiarid than in temperate regions, dating this information is more difficult.(D) It is difficult to study the climatic history of arid and semiarid regions because their climates have tendedto vary more than those of temperate regions.(E) The study of past climates in arid and semiaridregions has been neglected because temperateregions support a greater variety of plant and animallife.Passage 2Australian researchers have discovered electroreceptors (sensory organs designed to respond to electrical fields) clustered at the tip of the spiny anteater's snout. The researchers made this discovery by exposing small areas of (5) the snout to extremely weak electrical fields and recording the transmission of resulting nervous activity to the brain. While it is true that tactile receptors, another kind of Sensory organ on the anteater's snout, can also respond toelectrical stimuli, such receptors do so only in response to(10) electrical field strengths about 1,000 times greater thanthose known to excite electroreceptors.Having discovered the electroreceptors, researchers arenow investigating how anteaters utilize such a sophisticatedsensory system. In one behavioral experiment, researchers(15) successfully trained an anteaters to distinguish betweentwo troughs of water, one with a weak electrical fieldand the other with none. Such evidence is consistent withresearchers' hypothesis that anteaters use electroreceptorsto detect electrical signals given off buy prey; however,(20) researchers as yet have been unable to detect electricalsignals emanating from termite mounds, where the favoritefood of anteaters live. Still, researchers have observedanteaters breaking into a nest of ants at an oblique angleand quickly locating nesting chambers. This ability quickly(25) to locate unseen prey suggests, according to the researchers,that the anteaters were using their electroreceptors tolocate the nesting chambers.1. According to the passage, which of the following is a characteristic that distinguishes electroreceptors from tactile receptors?(A) The manner in which electroreceptors respond to electrical stimuli(B) The tendency of electroreceptors to be found in clusters(C) The unusual locations in which electroreceptors are found in most species.(D) The amount of electrical stimulation required to excite electroreceptors(E) The amount of nervous activity transmitted it the brain by electroreceptors when they are excited2. Which of the following can be inferred about experiment described in the first paragraph?(A) Researchers had difficulty verifying the existence of electroreceptors in the anteater because electroreceptors respond to such a narrow range of electrical field strengths. (B) Researchers found that the level of nervous activity in the anteater's brain increased dramatically as the strength of the electrical stimulus was increased.(C) Researchers found that some areas of the anteater's snout were not sensitive to a weak electrical stimulus.(D) Researchers found that the anteater's tactile receptors were more easily excited by a strong electrical stimulus than were the electroreceptors.(E) Researchers tested small areas of the anteater's snout in order to ensure that only electroreceptors were responding to the stimulus.3. The author of the passage most probably discussed the function of tactile receptors (lines 7-11) in order to(A) eliminate and alternative explanation of anteater's response to electrical stimuli(B) highlight a type of sensory organ that has a function identical to that of electroreceptors(C) point out a serious complication in the research on electroreceptors in anteaters(D) suggest that tactile receptors assist electroreceptors in the detection of electrical signals(E) introduce a factor that was not addressed in research on electroreceptors in anteaters4. Which of the following can be inferred about anteaters from the behavioral experiment mentioned in the second paragraph?(A) They are unable to distinguish between stimuli detected by their tactile receptors.(B) They are unable to distinguish between the electrical signals emanating from termite mounds and those emanating from ant nests.(C) They can be trained to recognize consistently the presence of a particular stimulus.(D) They react more readily to strong than to weak stimuli.(E) They are more efficient at detecting stimuli in a controlled environment than in a natural environment.5. The passage suggests that researchers mentioned in the second paragraph who observed anteaters break into a nest of ants would most likely agree with which of the following statements?(A) The event they observed provides conclusive evidence that anteaters use their electroreceptors to locate unseen prey.(B) The event they observed was atypical and may not reflect the usual hunting practices of anteaters.(C) It is likely that the anteaters located the ants' nesting chambers without the assistance of electroreceptors.(D) Anteaters possess a very simple sensory system for use in locating prey.(E) The speed with which the anteaters located their prey is greater than what might be expected on the basis of chance alone.6. Which of the following, if true, would most strengthen the hypothesis mentioned in lines 17-19?(A) Researchers are able to train anteaters to break into an underground chamber that is emitting a strong electrical signal.(B) Researchers are able detect a weak electrical signal emanating from the nesting chamber of an ant colony.(C) Anteaters are observed taking increasingly longer amounts of time to locate the nesting chambers of ants.(D) Anteaters are observed using various angles to break into nests of ants.(E) Anteaters ate observed using the same angle used with nests of ants to break into the nests of other types of prey.Passage 3Most economists in the United States seemcaptivated by the spell of the free market. Conse-quently, nothing seems good or normal that doesnot accord with the requirements of the free market. ( 5 )A price that is determined by the seller or, for that matter, established by anyone other than theaggregate of consumers seems pernicious. Accord- ingly, it requires a major act of will to think ofprice-fixing (the determination of prices by the (10) seller) as both normal and having a valuableeconomic function. In fact, price-fixing is normalin all industrialized societies because the indus-trial system itself provides, as an effortless conse-quence of its own development, the price-fixing (15) that it requires. Modern industrial planningrequires and rewards great size. Hence,a comparatively small number of large firms willbe competing for the same group of consumers.That each large firm will act with consideration of (20) its own needs and thus avoid selling its productsfor more than its competitors charge is commonlyrecognized by advocates of free-market economictheories. But each large firm will also act withfull consideration of the needs that it has in(25) common with the other large firms competing forthe same customers. Each large firm will thusavoid significant price-cutting, because price-cutting would be prejudicial to the common interestin a stable demand for products. Most economists (30) do not see price-fixing when it occurs becausethey expect it to be brought about by a number ofexplicit agreements among large firms; it is not.Moreover, those economists who argue thatallowing the free market to operate without inter- (35) ference is the most efficient method of establishingprices have not considered the economies of non-socialist countries other than the United states.These economies employ intentional price-fixing,usually in an overt fashion. Formal price-fixing (40) by cartel and informal price-fixing by agreementscovering the members of an industry are common-place. Were there something peculiarly efficientabout the free market and inefficient about price-fixing, the countries that have avoided the first (45) and used the second would have suffered drasticallyin their economic development. There is no indica-tion that they have.Socialist industry also works within a frame-work of controlled prices. In the early 1970's, (50) the Soviet Union began to give firms and industriessome of the flexibility in adjusting prices that amore informal evolution has accorded the capitalistsystem. Economists in the United States havehailed the change as a return to the free market. (55) But Soviet firms are no more subject to pricesestablished by a free market over which theyexercise little influence than are capitalist firms;rather, Soviet firms have been given the power tofix prices.1. The primary purpose of the passage is to(A) refute the theory that the free market plays auseful role in the development of industrialized societies(B) suggest methods by which economists and members of the government of the United States canrecognize and combat price-fixing by large firms(C) show that in industrialized societies price-fixing and the operation of the free market are not only compatible but also mutually beneficial(D) explain the various ways in which industrialized societies can fix prices in order to stabilize the free market(E) argue that price-fixing, in one form or another, is an inevitable part of and benefit to the economy of any industrialized society2. The passage provides information that would answer which of the following questions about price-fixing?Ⅰ.What are some of the ways in which prices can be fixed?Ⅱ. For what products is price-fixing likely to be more profitable than the operation of the free market?Ⅲ.Is price-fixing more common in socialist industrialized societies or in nonsocialist industrialized societies?(A) Ⅰonly(B) Ⅲonly(C) Ⅰand Ⅱonly(D) Ⅱand Ⅲonly(E) Ⅰ,Ⅱ,and Ⅲ3. The author's attitude toward Most economists in the United States(line 1) can best be described as(A) spiteful and envious(B) scornful and denunciatory(C) critical and condescending(D) ambivalent but deferential(E) uncertain but interested4. It can inferred from the author's argument that a price fixed by the seller seems pernicious(line 7) because(A) people do not have confidence in large firms(B) people do not expect the government toregulate prices(C) most economists believe that consumers as a group should determine prices(D) most economists associate fixed prices with communist and socialist economies(E) most economists believe that no one groupshould determine prices5. The suggestion in the passage that price-fixing in industrialized societies is normal arises from theauthor's statement that price-fixing is(A) a profitable result of economic development(B) an inevitable result of the industrial system(C) the result of a number of carefully organized decisions(D) a phenomenon common to industrialized and nonindustrialized societies(E) a phenomenon best achieved cooperatively by government and industry6. According to the author, price-fixing in nonsocialist countries is often(A) accidental but productive(B) illegal but useful(C) legal and innovative(D) traditional and rigid(E) intentional and widespread7. According to the author, what is the result of the Soviet Union's change in economic policy in the 1970's?(A) Soviet firms show greater profit.(B) Soviet firms have less control over the free market.(C) Soviet firms are able to adjust to technological advances.(D) Soviet firms have some authority to fix prices.(E) Soviet firms are more responsive to the free market.8. With which of the following statements regarding the behavior of large firms in industrialized societieswould the author be most likely to agree?(A) The directors of large firms will continue to anticipate the demand for products.(B) The directors of large firms are less interested in achieving a predictable level of profit than inachieving a large profit.(C) The directors of large firms will strive to reduce the costs of their products.(D) Many directors of large firms believe that the government should establish the prices that will be charged for products.(E) Many directors of large firms believe that the price charged for products is likely to increase annually.9. In the passage, the author is primarily concerned with(A) predicting the consequences of a practice(B) criticizing a point of view(C) calling attention to recent discoveries(D) proposing a topic for research(E) summarizing conflicting opinionsKEYSPassage 1: ECEEB DDAPassage 2: DCACE BPassage 3: EACCB EDAB。
计量经济学中英文词汇对照
Controlled experiments Conventional depth Convolution Corrected factor Corrected mean Correction coefficient Correctness Correlation coefficient Correlation index Correspondence Counting Counts Covaห้องสมุดไป่ตู้iance Covariant Cox Regression Criteria for fitting Criteria of least squares Critical ratio Critical region Critical value
Asymmetric distribution Asymptotic bias Asymptotic efficiency Asymptotic variance Attributable risk Attribute data Attribution Autocorrelation Autocorrelation of residuals Average Average confidence interval length Average growth rate BBB Bar chart Bar graph Base period Bayes' theorem Bell-shaped curve Bernoulli distribution Best-trim estimator Bias Binary logistic regression Binomial distribution Bisquare Bivariate Correlate Bivariate normal distribution Bivariate normal population Biweight interval Biweight M-estimator Block BMDP(Biomedical computer programs) Boxplots Breakdown bound CCC Canonical correlation Caption Case-control study Categorical variable Catenary Cauchy distribution Cause-and-effect relationship Cell Censoring
如何不要测量气体-孔径测量说明书
“How Not to Measure Gas - Orifice Measurement”Dee HummelTarga ResourcesTulsa, Oklahoma 74119IntroductionMeasuring natural gas is both a science and an art. Guidelines and industry practices explain how to accurately measure natural gas. The ‘art” comes in trying to minimize errors and prevent measurement problems. However, sometime it’s easier to explain “how not” to measure gas when reviewing measurement errors.Measurement errors can be caused through poor installation practices, poor measurement practices, operational changes, and human error. The purpose of this paper is to address some “real life” cases of measurement errors.Installation ProblemsIt’s imperative to follow the AGA guidelines when designing and installing a measurement station. In orifice measurement, the ANSI 2530, API 14.3 manual recommends the minimum requirements for fabrication and installation of orifice meters. These standards recommend the required upstream and downstream lengths, along with recommendations for flow conditioners.For years, we have heard the importance of the correct length of the upstream and downstream meter run. If the meter tube upstream length is too short, it causes the approach profile to become distorted. Unfortunately, it is not easy to predict if the measurement will be overstated or understated.When performing a field audit, always note the location of the first obstruction upstream and downstream on the meter tube. The approach and exit profile will be affected by the location of the obstruction. Determining the amount of error is dependent by the size of obstruction, flow rate, and location of the obstruction. Each problem is unique; the amount of error is unique in each situation.Prior to the update of the standard in 1991, the fabrication of orifice meters used either a “flanged” or “pin” type straightening vanes. While straightening vanes were an acceptable type of flow conditioner, potential problems can occur in either in straightening vanes and other flow conditioners.Straightening vanes were recommended to be fabricated out of stainless steel material. Stainless is resistant to corrosion. However, if the vanes were made from carbon steel and placed in a corrosive environment, the vanes will rust. Once this happens, the upstream profile will change, and cause a measurement error. Depending upon the location of the vanes, the error can be either positive or negative.A high carbon dioxide concentration in a wet gas stream creates a corrosive environment. After a few years in service, the vanes can look like the picture below:When a new installation is commissioned, it is always a good idea to purge the pipeline or facility prior to putting the measurement station into service. If the pipeline or measurement facility is not adequately purged, debris left in the pipe may end up in the meter tube. Any type of debris can be left in a pipeline during construction; the picture below shows a piece of plastic that was left in the upstream portion of the meter tube.The effect of the plugged orifice plate is reflected in the EFM data collected from the meter site. On the 21st, the flow was completely restricted. As the plastic pushed through the orifice bore it effectively decreased the size of the orifice bore overstating the differential pressure and the volume.It is also important to design the facility so, that the production compression equipment does not effect the measurement. Separation equipment, dump valves, and compression equipment can cause the upstream profile to become distorted. Inspection “tees” or “enclosures” are a helpful addition for performing field tube or facility inspections.Poor Measurement PracticesGood measurement practices may be defined by a “gas measurement manual”; this document will help minimize any potential errors. While it is impossible to prevent all types of errors, a good standard “document” will go a long way in preventing an oblivious error.Orifice plate inspections are a very important part of a meter station inspection. Plates can be damaged by over pressure, hydrate formation, harsh flowing conditions, and improper sealing devices.Over time, meter tubes may begin to show signs of “wear”. A good meter tube inspection schedule is beneficial in preventing potential measurement errors. The internal condition should be noted; rusty or pitted meter tubes should be replaced. This generally causes the volume to be understated.In older installations, vane bundles may become loose and move inside the meter tube. The vanes may partially block the upstream tap hole, or may hit the orifice plate. The orifice plate in the picture below was damaged after the straightening vanes came loose inside the meter tube.In extreme situations, the orifice plate can be blown completely out of the orifice plate carrier.It is not uncommon for hydrates to form in the winter months. If the vane “pin” is weak or damaged, the velocity of the gas flow may cause the hydrate to move and hit the vanes. Once the pinning device is compromised, the vanes will move downstream with the flow.Other problems occur with sealing devices. Whether the meter run is a single or dual chamber, the seal ring is always important to examine when doing a meter inspection. In extreme conditions, the seal ring can become “swelled” from exposure to rich gas streams. When that occurs, the seal ring may tear when removing it from the meter tube.The picture above illustrates the effect of extended exposure to a rich hydrocarbon gas stream. The seal ring swelled, and the seal tore as the plate was removed from the meter tube. Always be selective on the type of seal ring, and the ANSI rating of the fitting. Be sure to install the correct ANSI rating series seal ring in the meter tube. Installing the wrong ANSI rated seal ring, may not seal the orifice plate in the plate carrier or meter run.Caution should be taken to make sure that the flange gaskets do not protrude into the meter tube bore. This induced error can be either a positive or negative in nature. It is important to make sure that the proper size and ANSI rated flange gasket is used in the meter tube. The picture below illustrates the effect of the wrong size gasket upstream of the orifice plate. Note the deflection of gas, as evidenced by the shaded area of the tube and plate.Operational ChangesWhen new gas sources are added to a gathering or transmission system, it’s always a good idea to review the type and amount of gas that is added to the system. In gathering systems, it is important to confirm that any separation equipment is sized properly to handle the additional volume. If the vessels are undersized, the free water or condensate can carry over the top of the vessel and interfere with the downstream measurement. Again, the upstream flow profile is affected; the amount of the error is dependent upon the quantity of carry over liquids.If field compression is required or added, it is always a good practice to make sure that the meter station is not subject to compressor pulsation. A shift in the atmospheric and working pressure “zeros” can indicate the presence of pulsation. If the pulsation cannot be determined by this simple test, a square error test should be used to identify the possibility of a pulsation error. Because compression facilities can cause the measurement to be overstated, it always a good practice, to install vessels between the compressor discharge, and the meter tube. The vessel provides a dampening effect for the pulsation, and knocks out the “noise” from the gas stream.Changes in wellhead production techniques also need to be identified. In intermitted production wells, the meter station size, and differential ranges should be reviewed. If necessary, the differential range should be increased, to insure that the entire range of the differential flow is measured.Human ErrorHuman error can occur in both the field and in the office. Orifice plates can be installed backwards in the meter tube in the field. Plates can be filed, cut and modified to fit into orifice flange units. Incorrect meter configurations can be setup in processing office, and go undetected for long periods of time.A good “checks and balance” system should be in place between the field and the office. Each group can perform a review of the field stations, and help each other identify any potential errors.Data processing software packages currently available in the industry have many features to help identify potential errors in gas quality, or flowing parameters. A well trained editor can use these tools to identify an error, and prevent the calculation of erroneous volumes. These features can also help the field personnel to spot potential problems from the field perspective. SummaryPreventing measurement errors is a never ending process. Understanding the correct and incorrect methods of measurement can help to reduce the amount of potential errors.。
freezing point descent method
freezing point descent methodFreezing point depression is a fundamental concept in chemical engineering and biology that deals with the lowering of the freezing point of a liquid due to the addition of a solute. This phenomenon is commonly observed in natural environments, where plants and bacteria use it to conserve water in dry conditions. In this context, freezing point depression has become a widely used method in various fields, including industrial processes, water treatment, and biotechnology.一、IntroductionThe freezing point depression phenomenon refers to the lowering of the freezing point of a liquid due to the presence of a solute. This phenomenon is often exploited for various applications, such as water treatment and industrial processes. The freezing point depression method can be applied to remove impurities from water, to concentrate solutions, and even to produce valuable products from waste materials.二、Mechanism of ActionThe mechanism of freezing point depression is based on the increase in the solute concentration in the liquid, which leads to an increase in the entropy of the system. This increase in entropy causes the liquid to lose its structuralorder and transforms into a more disordered state, lowering its freezing point. The process occurs naturally as long as the temperature is above the freezing point of the liquid.三、Applications1. Water treatment: The freezing point depression method can be used to remove impurities from water by concentrating them into a solid phase that floats to the top. This technique is commonly used in wastewater treatment and water desalination plants.2. Industrial processes: The freezing point depression method can be applied to various industrial processes, such as cooling and freezing systems, where it is used to minimize ice formation and maintain product quality.3. Biotechnology: In biotechnology, the freezing point depression method can be used to concentrate solutions containing valuable biomolecules, such as proteins and enzymes. This technique can also be used to produce valuable products from waste materials by converting them into ice-free concentrates.四、Advantages and DisadvantagesThe main advantage of the freezing point depression method is its simplicity and versatility. It can be applied to a wide range of substances and conditions, making it acost-effective and environmentally friendly alternative to other techniques. However, it also has some disadvantages, including the need for high-quality refrigerants and energy consumption during the freezing process.五、Future Developments and ChallengesThe freezing point depression method is currently being used in various fields, but there is still room for further development and optimization. In the future, researchers are likely to focus on developing new methods of concentrating solutions using this technique, as well as exploring its potential for waste reduction and recycling. At the same time, ensuring the safe and sustainable use of refrigerants will be a key challenge for future research in this field.总之,冻结点下降法是一种广泛应用于各个领域的有效方法,通过增加溶质浓度来降低液体的冻结点。
ECS Pressroom Chemical Guide 指南说明书
Pressroom Chemical GuideThis document is aimed to help the reader understand how pressroom chemicals (or washes), work, what their properties are and courses of action to take in terms of recommending ways of overcoming issues on press. We shall begin by describing the different attributes of solvent washes, followed by a troubleshooting guide including commonly occurring issues on press and how to overcome them. This information is also intended to help establish the most suitable choice of wash for a given printer.Evaporation (or Drying)This is a measure of how quickly the solvent will evaporate off a given surface when applied and left to dry (such as the blanketand/or roller surface). ECS can provide a wide range of products that meet different requirements in terms of dry speed of washes. Different printers have different preferences and choosing the right chemical in terms of its evaporation can be a compromise based on a trade-off with other factors of the wash.Typically faster evaporating solvents are more hazardous to health and are more highly flammable. Using faster evaporating solvents can mean the press is ready to start again more quickly rather than having to wait longer for slower evaporating washes residues to finish drying. This would appear to be advantageous to the modern-day printer who wants to print at faster speeds to increase throughput, however, slower evaporating solvents are generally considered safer to handle and because they are slower they deep clean the blankets and rollers for longer allowing continual wiping with the same dose of wash, compared to having to wipe once and reapply a faster evaporating version.Faster evaporating washes are typically higher in VOC’s (Volatile Organic Compounds), whereas t he industry is moving towards a more environmentally friendly approach in reducing VOC’s.Temperature can also play a part on the evaporation of solvents – generally speaking solvents will visually appear to evaporate quicker on warmer days than on colder days.OdourQuite simply this refers to the smell of the liquid solvent. Harsher and faster evaporating aromatic solvents have a tendency to give off much stronger odours. Within the confines of a pressroom, particularly if ventilation is not good, odours can manifest and make the working environment a very unpleasant place to be.Higher temperatures will increase the odours given off by solvents as the volatiles evaporate into the atmosphere during use.At ECS we are able to offer a full range of products to meet customer demand regarding odours. Lower odour non-aromatic solvents are possible options in place of aromatic equivalents, it just depends on the requirements of the individual user. Always refer to what a printer is currently using and offer alternatives based on their likes and dislikes. It is also possible to add fragrances which can mask higher odour solvents making them more pleasant to work with whilst maintaining the same functionality of wash solution. Just ask our technical team for further information.Also remember that odour is very subjective, so what one printer may like another may find unpleasant, it simply depends on the individual tastes.Solvency (or strength)This is a measure of how efficient the solvents are at removing ink and other contaminants. It would seem common sense to assume that surely the printer always requires the “strongest wash available as this will clean the best”, however, that is not always the case. Stronger aromatic solvents tend to be more aggressive on blankets and rollers and can lead to swelling which damages their compounds, meaning costly replacements are required. Therefore it is important to get the right balance. Commonly a milder less aggressive chemical is used for regular wash-ups, and use of a stronger solvent is done periodically to deep clean occasionally. FlammabilityThis is a measure of the flashpoint of the chemical and is referred to in Degrees Fahrenheit or Degrees Celsius. The flashpoint is the lowest temperature at which the solvent gives off enough vapour to ignite. A lower flashpoint of a solvent suggests a more flammable product.Two common terms associated with chemicals are AII and AIII category solvents. AIII category solvents have a flashpoint >55°C. AII solvents have a flash point below this. Often “Approved products” are required as a machine manufacturer’s guideline may insist on such to maintain the machine warranty. Typically approvals are conducted by 3rd party companies – the most well known in Europe being FOGRA. They will only test and pass AIII category solvents with a flashpoint greater than 55°C, such as our C651 Elite 60, or our C805 Elite UV Wash.Automatic and Manual washing systemsMost large sheet-fed and web presses nowadays incorporate some form of automatic washing system. Each specific one will contain guidance notes on how to use them and it is always important to refer to the manufacturers guidelines on how to clean each press, to uphold any manufacturer warranties. ECS provide a range of solvents suitable for most automatic systems.Manual cleaning is usually done with a lint free cloth to avoid contaminating the system with lint from fabric. Each product will have its own specific method of use – please consult our technical datasheets for specific product usage. Most of the ECS range of pressroom chemicals can be used as both automatic and manual cleaners.Some presses do require more specific solvents. For example Heatset Web Presses are commonly fitted with heatset ovens to dry the ink and coating. These ovens are calibrated to a specific temperature, for example 100°C, and it is highly important that the wash solution recommended is compatible with the oven temperature. Typically the flashpoint of the chemical should be set higher than the oven temperature, so as to avoid the potential for combustion to occur within the oven. This highlights the importance to question the method of use and the requirements of the press before making any recommendation.Water miscible vs. Non water miscibleThe main difference between the two is that Water Miscible solvents contain emulsifiers that enable the solvent to mix and hold in solution when mixed with water. The purpose of this is to clean all desposits on the press with one solution. The solvent will act on the ink, whereas, the water helps clean water soluble deposits, along with paper lint and gum contained in the system. Some presses run with non water miscible washes and clean the system in a 2 step process, firstly with solvent, then with a separate water flush. The benefits of using a water miscible wash seem clear, however, some emulsifiers can be considered to contaminate the system and lead to issues such as roller stripping and is often why press operators choose to use a two step wash system. Also, by mixing with water the efficiency of the solvent is diluted by the water, which may mean taking longer to clean all ink residues. The pros and cons of both systems should be weighed up for individual requirements. ECS provide a full and complete range of chemicals with water miscible and non water miscible versions to accommodate most requirements.Meter Roll Cleaners are a good example where a non water miscible chemical is more suitable. These are typically fast evaporating solutions that are manually used to clean excessive ink from the dampening roller. This is quite common in continuous dampening systems, where the ink and dampening rollers are integrated. Using water miscible solvents in this case can lead to ink/water emulsification issues. The Meter roll needs to stay water receptive for the best performance, therefore slow drying solvents may repel water from its surface.Ultra Violet (UV), Wash solutionsUV inks are often employed by the printer due to the fast processing, high quality, and low environmental impact associated with them (they are typically very low in VOC content compared to conventional and solvent based inks). Due to their nature they tend to require more specific cleaning agents than offset inks for best cleaning, but also the nature of the rubber compounds used to print UV is commonly very different. The majority of UV presses are equipped with EPDM (Ethylene-Propylene-Diene-Monomer – a synthetic rubber), blankets and rollers, and these are particularly susceptible to swelling by hydrocarbons. Typically glycol ethers and such are more suitable to these compounds as they are less aggressive to the rubber and show good UV ink solvency. ECS has a range of suitable UV Washes including the FOGRA approved C800 Biograph UV Wash and C805 Elite UV Wash, which are both recommended as safe for EPDM.Occasionally UV can also be printed on Nitrile based rubber, most commonly when using mixed printing techniques (printing conventional on one run, then UV on the next), or when using Hybrid inks (which have a mixture of both types of ink properties). These again require a very specialist type of wash solution and ECS can offer various chemicals for such work, including our C842 AIII Combiwash.Volatile organic compounds (VOC’s)Most chemicals and sol vents contain at least some VOC’s, with the majority being 100% VOC containing. The trend in printing is continually moving towards environmentally friendlier options, due to the impact that VOC’s have on greenhouse gases in the Earth’s atmosphere. Many lo cal authorities have or are setting up legislations and incentives to try to influence the use of “greener” products to reduce VOC emissions within the general public as well as printing.It would appear logical to simply supply low VOC products, however, typically such chemicals are both more expensive to formulate with as well as typically slower drying, and therefore many press operators choose VOC containing products instead.Problem SolvingThere are many issues related to cleaning that have already been covered and can simply be overcome by choosing the correct chemical to use initially based on the printers’ requirements. Below are listed a few commonly occurring issues and why they occur and how to correct them.1)Rubber swellinga)This is often caused by either using an unsuitable solvent (i.e. using a hydrocarbon based chemical on EPDM rollers), orone that is too strong. To overcome this switch to a milder or more suitable chemical.b)Solvent lingers for too long on the affected area. To overcome avoid excessive use of wash, switch to a fasterevaporating version, or simply ensure the solvent is wiped clean from the surface during use.2)Roller Strippinga)Emulsifiers in water miscible wash contaminating rollers by building up. Change to different emulsifier wash system, ortry a non water miscible wash/lower concentration of emulsifier.b)Glazing of rollers. Clean with specific deglazing chemical solution.c)Calcium contamination from water, paper and ink residues. Clean with Calcium removal wash or solution, roller cleaningpaste or shampoo. Regularly using products such as our SND103 Roller Cleaning Paste, SND125 Bio Shampoo, will helpprevent both glazing and calcium contamination occurring.3)Plate Blindinga)Caused by surfactants in water miscible wash. Again look at non water miscible versions, and/or lower/differentsurfactant concentration washes.b)Caused by calcium build up. Clean with calcium removal wash or solution, roller paste or shampoo.c)Some chemicals can be too strong and may strip the plate image. It is always important to test solvents, fount solutionsand plate cleaners for compatibility. CTP plates for example are notoriously more susceptible to chemical attack and canoften require milder choice of cleaning agents.4)Inadequate cleaninga)Caused by improper set-up or dosage of wash. Consult manufacturers guidelines for automatic wash settings and ensurethese are followed. Potentially a stronger solvent may be required as an option. For manual use ensure method ofapplication as set out by the manufacturer of the wash solution is followed.b)Caused by using the incorrect or a contaminated wash. Ensure all washes when not in use have their lids replaced andlabels on the containers are not removed. Ensure the system is completely purged of all wash solution before switchingto a different chemical.c)Solvent too cold or too warm. If the solvent is too cold it will typically dry slower, whereas, if too warm it will appear todry quicker. Try and maintain at a standard pressroom temperature of 15-25°C. In reality this may not be possible soensure the press operator has an understanding of the effects temperature can have on solvents so they can adjustdosage and use as required.The information contained in this data sheet corresponds with our current knowledge and experience. The liability for the application and processing of our products lieswith the buyer, who is also responsible for observing the third party rights.。
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Nondemolition observation of a free quantum particle
V. P. Belavkin∗ and P. Staszewski† 28 May 1991 Published in: Phys. Rev. A, 45 (1992) No 3, 1347–1356
Abstract A stochastic model of a continuous nondemolition observation of a free quantum Brownian motion is presented. The nonlinear stochastic wave equation describing the posterior dynamics of the observed quantum system is solved in a Gaussian case for a free particle of mass m > 0. It is shown that the dispersion of the wave packet does not increase to infinity like for the free unobserved particle but tends to the finite limit 1/2 τ2 where λ is the accuracy coefficient of an indirect non∞ = ( /2λm) demolition measurement of the particle position, and is Planck constant.
∗ M.I.E.M., † Institute
D. Vusovsky 3/12, Moscow 109028, USSR of Physics, N. Copernicus University, Toru´ n, Poland
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not assumed [1–4] as, in general, there are non–zero (a priori) probabilities of the results of such a measurement belonging to disjoint Borel sets. The irreversible and stochastic behaviour of the continuously observed quantum system expressed by the so–called collapse or reduction of the wave function has no analogue in the classical deterministic mechanics. The Hamilton equations do not depend (for a nondemolition observation) on whether the dynamical object is observed during its motion along its trajectory. Ignoring that difference in the behaviour of classical and quantum observed objects leads to various quantum paradoxes of Zeno kind [5–11] which can be explained only in the way of a consistent investigation of the disturbed stochastic dynamics of the quantum system undergoing an observation. It is quite natural to discuss this problem in the framework of stochastic quantum mechanics of open systems [12, 13] on the basis of the theory of nondemolition measurements developed recently [14–17]. The principle of a nondemolition continuous observation of a quantum system can be formulated as follows [17]: ˆ (r), r ≤ t, which (i) for any quantum measurement there exist observables Q ˆ commute for any t with all Heisenberg operators Z (t) of the system represented in the Hilbert space corresponding to “the system–measuring apparatus”, (ii) according to the causality principle one does not impose any conditions ˆ (s), s > t, with respect to the past observables of on the future observables Q ˆ the system Z (r), r ≤ t. A non–trivial nondemolition observation in the above– mentioned sense is provided by indirect measurements which can be only realized by considering the observed quantum system as an open one. From the experimental point of view it is natural to consider indirect measurements because any measurement is taken with the help of some experimental device. The indirect measurements allow to describe the state changes resulting from the measurements of observables with continuous spectra [4] which are assumed to be nonideal. The necessity to use indirect measurements for the existence of the continual limit (with ∆t → 0) for successive instantaneous measurements taken at instants separated by ∆t is proved in Ref. [18]. In this paper we shall illustrate the approach of the continuous quantum nondemolition measurement on the example of resolving the quantum Zeno paradox for a three–dimensional free particle undergoing an observation modeling the measurement of a trajectory of a quantum particle in a bubble chamber briefly reported in Ref. [17] and for the one–dimensional case in [19]. Sec. II has a preparatory character, we present here a stochastic model of a continuous nondemolition observation of a quantum system interacting with M –dimensional Bose field reservoir modeling the measuring device, proposed in [14–17]. In Sec. III we derive the filtering equation – the stochastic differential equation describing the time–development of the wave function of the quantum system observed by means of the vector “field coordinate” process. This equation was recently obtained with the help of quantum filtration method [20, 21]. The presented derivation – via stochastic instrument in the sense of Davies and Lewis [2, 3] – generalizes the result of Ref. [22] to the case of multidimensional 2
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Introduction
The Schr¨ odinger equation describes the time–development of the wave function of a quantum system only for the time intervals between the succeeding instants of measurements. At the instant of a measurement of some observable with a discrete spectrum, Z , the quantum system makes an immediate transition (jump) from the state ψ (t) to the eigenstate ψ z (t) corresponding to the obtained eigenvalue z of Z with the probability | ψ (t)|ψ z (t) |2 . Such a stochastic time–behaviour of the system at the instant of the measurement assures the repeatability of the results of measurements, if a second measurement were taken immediately after the first one then for discrete observable Z the measurement would again give z [1]. It is intuitively obvious that if one would perform measurements with a high frequency – in a limit continuously in time – the quantum system would show a stochastic irreversible behaviour for theห้องสมุดไป่ตู้whole period of observation. Therefore the time–development of a continuously observed quantum system cannot be governed by the deterministic Schr¨ odinger equation describing the reversible motion. This statement remains true also in the case of the measurements of an observable with a continuous spectrum though for observables with continuous spectra the repeatability hypothesis is