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The mechanism of light-induced discoloration in surface decoration of wooden materials

木质材料表面装饰用材的光致变色机理的研究

Nowadays, the surface decoration of wooden materials have become basic demand for high-quality, high-grade life in human settlement. Most methods can be used for the surface decoration of the wooden materials. And the veneered decoration and the coated decoration are the most important between these methods. However, the problem of damaging by light can be neglected neither in veneered decoration nor in coated decoration.

In this work, the light-induced discoloration is investigated in basswood single board, decorative paper (wood-veined paper and impregnated paper) and PVC sticker (dark and light color). The spectrophotometer with the CIE chromaticity of 1976 is used to research the law of the change of color. While, we investigate the change of the surface-chemistry structure and the scientific essence of the producing of color, with surface-analysis technology such as x-ray photoelectron spectroscopy (XPS), fourier transform infrared spectroscopy (FT-IR), electron spin resonance spectroscopy (ESR), fluorescence display, etc. Furthermore, the ultraviolet spectrophotometer is also used to measure the transmission spectra of the typical paint films. In this work, we aim to provide basic and scientific theory to avoid damaging by light. The main results are shown as follow:

对木质材料表面进行装饰,在人居环境中已经成为人们追求高质量、高品位生活的基本要求。目前木质材料表面装饰的方法有很多,主要有贴面装饰和涂饰装饰两大类。但无论是哪

一类,都存在光致变色的光劣化问题。因此,本文针对典型的表面装饰材料,即椴木单板、装饰纸(木纹纸与浸渍纸)、PVC贴面(深色与浅色两种)材料进行了其光致变色的研究。利用基于CIE1976标准色度系统LAB均匀颜色空间原理的分光光度计,探究其分别在自然光和紫外光辐照下的变色规律;利用X射线光电子能谱(XPS)、傅里叶变换红外光谱(FT-IR)、电子自旋共振波谱(ESR)、荧光显微镜等多种现代表面分析技术,揭示了装饰材料的表面化学结构变化和颜色产生的理学本质,从而分析和明确了光致变色机理;用紫外可见分光光度计测量了典型漆膜的透射光光谱;本研究旨在为装饰材料表面防止光劣化提供基础理论和科学依据。主要研究结果如下:

1.The general characters of the light-induced discoloration are observed in

basswood single board, decorative paper and PVC sticker when radiate by natural and ultraviolet light. After radiating basswood single board, decorative paper and PVC sticker by ultraviolet, we observed that the lightness index decrease, the yellow and blue index increase, the red and green index change little, chromatic difference become big and visual display become yellow. In addition, the stronger change of the color is induced by the long-time ultraviolet radiation.(这句话的位置我调整了一下,您要是觉得放这不合适可以再调整)While the effect induced by natural light is smaller than induced by ultraviolet. The same light-induced discoloration phenomenon is observed in basswood single board, decorative paper and PVC sticker. The change of the chromatic difference is observed mainly in the before 20 hours, and then become steady. Furthermore, the rough index of the morphology increased (excepted PVC).

1.光变色规律的共性是:与有机物键能较接近的紫外光引起的变色明显,主要表现是明度指

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