溴化钠安全技术说明书英文
溴化钾危险化学品安全技术说明书
溴化钾危险化学品安全技术说明书第一部分化学品名称化学品中文名称：溴化钾化学品英文名称：potassium bromide中文名称：英文名称：bromide salt of potassium技术说明书编码：1575CAS No.：7758-02-3第二部分成分/组成信息第三部分危险性概述危险性类别：侵入途径：健康危害：吸入对呼吸道有刺激性。
对眼和皮肤有刺激性。
摄入后引起头痛、头晕、恶心、呕吐、胃肠道刺激症状。
环境危害：燃爆危险：本品不燃，具刺激性。
第四部分急救措施皮肤接触：立即脱去污染的衣着，用大量流动清水冲洗至少15分钟。
就医。
眼睛接触：立即提起眼睑，用大量流动清水或生理盐水彻底冲洗至少15分钟。
就医。
吸入：脱离现场至空气新鲜处。
如呼吸困难，给输氧。
就医。
食入：饮足量温水，催吐。
就医。
第五部分消防措施危险特性：受高热分解产生有毒的溴化物气体。
有害燃烧产物：溴化氢、氧化钾。
灭火方法：消防人员必须穿全身防火防毒服，在上风向灭火。
灭火时尽可能将容器从火场移至空旷处。
第六部分泄漏应急处理应急处理：隔离泄漏污染区，限制出入。
建议应急处理人员戴防尘面具（全面罩），穿防毒服。
避免扬尘，小心扫起，置于袋中转移至安全场所。
也可以用大量水冲洗，洗水稀释后放入废水系统。
若大量泄漏，用塑料布、帆布覆盖。
收集回收或运至废物处理场所处置。
第七部分操作处置与储存操作注意事项：密闭操作，加强通风。
操作人员必须经过专门培训，严格遵守操作规程。
建议操作人员佩戴自吸过滤式防尘口罩，戴化学安全防护眼镜，穿防毒物渗透工作服，戴橡胶手套。
避免产生粉尘。
避免与氧化剂、酸类、金属盐类接触。
搬运时要轻装轻卸，防止包装及容器损坏。
配备泄漏应急处理设备。
倒空的容器可能残留有害物。
储存注意事项：储存于阴凉、通风的库房。
远离火种、热源。
应与氧化剂、酸类、金属盐类分开存放，切忌混储。
储区应备有合适的材料收容泄漏物。
第八部分接触控制/个体防护监测方法：工程控制：生产过程密闭，加强通风。
溴化学品安全技术说明书
化学品安全技术说明书产品名称: 溴按照GB/T 16483、GB/T 17519 编制修订日期: 最初编制日期:版本:第1部分化学品及企业标识化学品中文名：溴化学品英文名：dibromine企业名称：企业地址：传真：联系电话：企业应急电话：产品推荐及限制用途：For industry use only.。
第2部分危险性概述紧急情况概述：造成严重皮肤灼伤和眼损伤。
吸入致命。
GHS危险性类别：皮肤腐蚀/ 刺激类别1A急性吸入毒性类别 2危害水生环境——急性危险类别 1标签要素：象形图：警示词：危险危险性说明：H314 造成严重皮肤灼伤和眼损伤。
H330 吸入致命。
H400 对水生生物毒性极大。
防范说明：•预防措施：•P260 不要吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
•P264 作业后彻底清洗。
•P280 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
•P271 只能在室外或通风良好处使用。
•P284 [在通风不足的情况下] 戴呼吸防护装置•P273 避免释放到环境中。
•事故响应：•P301+P330+P331 如误吞咽：漱口。
不要诱导呕吐。
•P303+P361+P353 如皮肤(或头发)沾染：立即脱掉所有沾染的衣服。
用水清洗皮肤/淋浴。
•P363 沾染的衣服清洗后方可重新使用。
•P304+P340 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。
•P310 立即呼叫解毒中心/医生•P321 具体治疗 ( 见本标签上的…… )。
•P305+P351+P338 如进入眼睛：用水小心冲洗几分钟。
如戴隐形眼镜并可方便地取出，取出隐形眼镜。
继续冲洗。
•P320 紧急具体治疗 ( 见本标签上的…… )。
•P391 收集溢出物。
•安全储存：•P405 存放处须加锁。
•P403+P233 存放在通风良好的地方。
保持容器密闭。
•废弃处置：•P501 按当地法规处置内装物/容器。
物理和化学危险：无资料健康危害：造成严重皮肤灼伤和眼损伤。
溴素安全技术说明书
溴安全技术说明书第一部分化学品及企业标识化学品中文名称：溴化学品英文名称：Bromine企业名称：地址：邮编：电子邮件地址：联系电话：传真号码：企业应急电话：技术说明书编码：产品推荐用途：石油工业中，溴用于制造燃烧防爆剂及完井液；农业上，是制造高效农药、粮库灭虫灭鼠的熏蒸剂及农田杀虫剂的原料；医药工业中广泛应用于制造溴化钾、溴化钠、溴化铵、氯霉素、奈普生及TMP等药物；溴素是制造某些染料的重要原料；在塑料工业及建材工业中，是生产阻燃剂的重要原料；国防、军工及消防工业中，溴是制造高效低毒灭火剂的原料；同时溴也是制造感光器材的主要材料。
产品限制用途：禁止用于食品加工。
第二部分危险性概述物理化学危险：强氧化剂，与易燃物（如苯）和可燃物（如糖、纤维素等）接触会发生剧烈反应，甚至引起燃烧。
对大多数金属及有机组织有腐蚀性，遇氢、甲烷、硫磺、锑、砷、磷、钠、钾及其他金属粉末剧烈反应，有爆炸危险。
健康危害：对皮肤、粘膜有强烈刺激作用和腐蚀作用。
吸入较低浓度，很快发生眼呼吸道粘膜的刺激症状，并有头痛、眩晕、全身无力、胸部发紧、干咳、恶心和呕吐等症状；吸入高浓度时有剧咳、呼吸困难、哮喘。
严重时可发生窒息、肺炎、肺水肿。
可出现中枢神经系统紊乱症状。
皮肤接触高浓度溴蒸气或液态溴可造成严重灼伤。
长期吸入，除粘膜刺激症状外，还伴有神经衰弱综合症。
眼睛接触造成眼睛烧伤，引起化学性结膜炎和角膜损伤。
误服可造成消化道的永久性损害，可能造成消化道穿孔，引起恶心、呕吐、腹泻和便血等。
环境危害：对环境有危害，对水体、土壤和大气可造成污染。
GHS危险性类别：根据《化学品分类和危险性公示通则》（GB 13690-2009）及化学品分类、警示标签和警示性说明规范系列标准，该产品属于金属腐蚀物，类别1；急性毒性（经口），类别4；急性毒性（兔吸入），类别2；皮肤腐蚀刺激，类别1；严重眼睛损伤/眼睛刺激性，类别1；特异性靶器官系统毒性单次接触，类别1；特异性靶器官系统毒性反复接触，类别1；对水环境的危害（急性），类别1；对水环境的危害（慢性），类别1。
溴酸钠
信号词：危险。 危险说明： 可能加剧燃烧；氧化剂。吞咽有害。造成皮肤刺激。造成严重眼刺激。可能引起呼吸道刺激。 防范说明： 预防：远离热源/火花/明火/热表面——禁止吸烟。保持远离/贮存处远离服装/可燃材料。采取一切防 范措施，避免与可燃物混合。在使用前获取特别指示。在读懂所有安全防范措施之前切勿搬动。戴 防护手套/穿防护服/戴防护眼罩/戴防护面具。使用所需的个人防护设备。使用本产品时不得进食、 饮水或吸烟。不要吸入粉尘/烟/气体/烟雾/蒸气/喷雾。作业后彻底清洗。 反应：如误吞咽：如感觉不适，呼叫解毒中心或医生。漱口。如皮肤沾染：用大量肥皂和水清洗。 脱掉沾染的衣服，清洗后方可重新使用。如发生皮肤刺激：求医/就诊。如进入眼睛：用水小心冲洗 几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。如接触到或有疑虑：求医/就诊。 火灾时：使用水雾，抗醇性泡沫，干粉或二氧化碳等灭火。 贮存：存放处须加锁。 处置：按照相关规定处置内装物和容器。 不导致分类的其他危险（例如尘爆危险）或不为全球统一制度覆盖的其他危险：/
參考文献 制表日期
十六、其它信息
联合国《关于危险货物运输的建议书.规章范本》 联合国《全球化学品统一分类和标签制度》 2014 年 01 月 04 日
注 1：当产品为含有两种以上危险物质的混合物时，应依据其混合后的危险性，制作安全数据单。 注 2：制造商/供应商应根据实际情况确保安全数据单所含信息的正确性，并适时更新。 注 3：如由于产品特性而不存在或不可得某些信息时（如固体不存在沸点），应在表格中以“/”标识。
/ / / / 3.34 g/cm3。 与水混溶。 / / / /
第 3 页，共 4 页
十、稳定及反应性
反应性：/ 化学稳定性：在正常操作条件下，物质被认为是稳定的。 危险反应的可能性：/ 应避免的条件：可引发猛烈爆炸。 不相容的物质和材料：强酸，强还原剂，粉末状金属，有机材料，碱金属，碱土金属，氰化物，硫 氰酸盐等。 危险的分解产物：/
溴素安全技术说明书
溴安全技术说明书第一部分化学品及企业标识化学品中文名称：溴化学品英文名称：Bromine企业名称：地址：邮编：电子邮件地址：联系电话：传真号码：企业应急电话：技术说明书编码：产品推荐用途：石油工业中，溴用于制造燃烧防爆剂及完井液；农业上，是制造高效农药、粮库灭虫灭鼠的熏蒸剂及农田杀虫剂的原料；医药工业中广泛应用于制造溴化钾、溴化钠、溴化铵、氯霉素、奈普生及TMP等药物；溴素是制造某些染料的重要原料；在塑料工业及建材工业中，是生产阻燃剂的重要原料；国防、军工及消防工业中，溴是制造高效低毒灭火剂的原料；同时溴也是制造感光器材的主要材料。
产品限制用途：禁止用于食品加工。
第二部分危险性概述物理化学危险：强氧化剂，与易燃物（如苯）和可燃物（如糖、纤维素等）接触会发生剧烈反应，甚至引起燃烧。
对大多数金属及有机组织有腐蚀性，遇氢、甲烷、硫磺、锑、砷、磷、钠、钾及其他金属粉末剧烈反应，有爆炸危险。
健康危害：对皮肤、粘膜有强烈刺激作用和腐蚀作用。
吸入较低浓度，很快发生眼呼吸道粘膜的刺激症状，并有头痛、眩晕、全身无力、胸部发紧、干咳、恶心和呕吐等症状；吸入高浓度时有剧咳、呼吸困难、哮喘。
严重时可发生窒息、肺炎、肺水肿。
可出现中枢神经系统紊乱症状。
皮肤接触高浓度溴蒸气或液态溴可造成严重灼伤。
长期吸入，除粘膜刺激症状外，还伴有神经衰弱综合症。
眼睛接触造成眼睛烧伤，引起化学性结膜炎和角膜损伤。
误服可造成消化道的永久性损害，可能造成消化道穿孔，引起恶心、呕吐、腹泻和便血等。
环境危害：对环境有危害，对水体、土壤和大气可造成污染。
GHS危险性类别：根据《化学品分类和危险性公示通则》（GB 13690-2009）及化学品分类、警示标签和警示性说明规范系列标准，该产品属于金属腐蚀物，类别1；急性毒性（经口），类别4；急性毒性（兔吸入），类别2；皮肤腐蚀刺激，类别1；严重眼睛损伤/眼睛刺激性，类别1；特异性靶器官系统毒性单次接触，类别1；特异性靶器官系统毒性反复接触，类别1；对水环境的危害（急性），类别1；对水环境的危害（慢性），类别1。
FLUX RMA 258-15R化学品安全技术说明书
GHS047固体。
[粘贴]INFOTRACNorth America: (800) 535-5053International: (352) 323-3500化学品安全技术说明书参考号码产品类型应急咨询电话（带值班时间）:::企业标识:International:AIM9100 Henri Bourassa East Montreal, QC H1E 2S4(514) 494-2000In China:AIM Solder (CHANGXING) Company Limited No.1208-D Chenwang Rd., Taihu St.Changxing County, Huzhou, Zhejiang In Malaysia:AIM Solder (Malaysia)No. 2A, Jalan Industri Seri Juru,Taman Industri Seri Juru, 14000 Bukit Mertajam,Pulau Pinang, Malaysia +6012 800 1936FLUX RMA 258-15R不适用。
推荐用途安全技术说明书根据 GB/ T 16483-2008 和 GB/ T 17519-2013皮肤致敏物 - 类别 1危害水生环境一长期危险 - 类别 3GHS危险性类别:警示词:警告危险性说明:可能造成皮肤过敏反应。
对水生生物有害并具有长期持续影响。
象形图:防范说明预防措施:戴防护手套。
避免释放到环境中。
避免吸入粉尘。
受沾染的工作服不得带出工作场地。
事故响应:脱掉所有沾染的衣服，清洗后方可重新使用。
如皮肤沾染： 用水充分清洗/。
如发生皮肤刺激或皮疹： 求医要么就诊。
安全储存:不适用。
标签要素其他危害:没有已知信息。
其他标识手段:无资料。
CAS号码:不适用。
物质／混合物美国化学文摘社(CAS)编号/其它标识号EC 号:混合物。
:职业暴露限制, 如果有的话, 列在第 8 节中。
硫化钠化学品安全技术说明书
硫化钠化学品安全技术说明书第一部分化学品名称化学品中文名：硫化钠化学品英文名：sodium sulfide中文名称2：臭碱英文名称2：技术说明书编码：950CAS号：7757-83-7分子式：Na2S分子量：78.04第二部分成分/组成信息危险性类别：第8.2类碱性腐蚀品侵入途径：健康危害：本品在胃肠道中能分解出硫化氢，口服后能引起硫化氢中毒。
对皮肤和眼睛有腐蚀作用。
环境危害：对环境有危害。
燃爆危险：本品易燃，具强腐蚀性、刺激性，可致人体灼伤。
第四部分急救措施皮肤接触：立即脱去污染的衣着，用大量流动清水冲洗至少15分钟。
就医。
眼睛接触：立即提起眼睑，用大量流动清水或生理盐水彻底冲洗至少15分钟。
就医。
吸入：迅速脱离现场至空气新鲜处。
保持呼吸道通畅。
如呼吸困难，给输氧。
如呼吸停止，立即进行人工呼吸。
就医。
食入：用水漱口，给饮牛奶或蛋清。
就医。
第五部分消防措施危险特性：无水物为自燃物品，其粉尘易在空气中自燃。
遇酸分解, 放出剧毒的易燃气体。
粉体与空气可形成爆炸性混合物。
其水溶液有腐蚀性和强烈的刺激性。
100℃时开始蒸发，蒸气可侵蚀玻璃。
有害燃烧产物：硫化氢、氧化硫。
灭火方法：采用水、雾状水、砂土灭火。
第六部分泄漏应急处理应急处理：隔离泄漏污染区，限制出入。
建议应急处理人员戴防尘面具（全面罩），穿防酸碱工作服。
从上风处进入现场。
小量泄漏：避免扬尘，用洁净的铲子收集于干燥、洁净、有盖的容器中。
也可以用大量水冲洗，洗水稀释后放入废水系统。
大量泄漏：收集回收或运至废物处理场所处置。
第七部分操作处置与储存操作注意事项：密闭操作。
操作人员必须经过专门培训，严格遵守操作规程。
建议操作人员佩戴自吸过滤式防尘口罩，戴化学安全防护眼镜，穿橡胶耐酸碱服，戴橡胶耐酸碱手套。
远离火种、热源，工作场所严禁吸烟。
使用防爆型的通风系统和设备。
避免产生粉尘。
避免与氧化剂、酸类接触。
搬运时要轻装轻卸，防止包装及容器损坏。
配备相应品种和数量的消防器材及泄漏应急处理设备。
KRONES hydrocare 1902化学品安全技术说明书
化学品安全技术说明书KRONES hydrocare 1902依据GB/T 16483、GB/T 17519编制最初编制日期: 2021/4/21 修订日期: 2021/4/21 版本: 1.0化学品中文名称: KRONES hydrocare 1902化学品英文名称: KRONES hydrocare 1902企业名称: KIC KRONES Internationale Cooperationsgesellschaft mbH 地址: Böhmerwaldstraße 5, 93073, Neutraubling邮政编码: 93073电话号码: +49-9401-70-3020传真: +49-9401-70-3696电子邮件地址: ******************进口商KRONES Trading (Taicang) Co. Ltd.地址No. 9 Ning Bo Dong Lu邮编215400 Taicang Jiangsu Suzhou电话号码+86 512 5373 9300电子邮件地址**************.com应急咨询电话: +86 400 120 6011 (NCEC, National Chemical EmergencyService)0532-8388-9090 (NRCC National Registration Centre for Chemicals) 推荐用途: 膜清洁剂。
限制用途: 无可用信息。
紧急情况概述GHS 危险性类别物理性危险: 金属腐蚀物类别1健康危害: 急性毒性（经口）类别4: 急性毒性（经皮）类别5: 皮肤腐蚀/刺激类别1A: 严重眼损伤/眼刺激类别1上述未涉及的其他危险性，分类不适用或无法分类。
标签要素象形图 (GHS CN) :警示词 (GHS-CN) : 危险。
危险性说明 (GHS-CN) : H290 - 可能腐蚀金属。
DONOR-C安全技术说明书英文版2
Material: 60003427SILANE CHM-DIMETHOXYVersion: 1.3 (AU) Date of print: 03.11.2009 Date of last alteration: 02.02.20091 Identification of the material and supplier1.1 Name of substance/preparationCommercial product name:SILANE CHM-DIMETHOXY1.2 Use of substance / preparation:Industrial.Intermediate chemical1.3 Company nameManufacturer:Wacker Chemie AGStreet/POB-No.:Hanns-Seidel-Platz 4State/postal code/city: D 81737 MünchenTelephone:+498962790Telefax: +498962791770Distributor:Wacker Chemie AGCare of Wacker Chemicals Australia Pty Ltd Street/POB-No.:Unit 1 / 35 Dunlop RoadState/postal code/city:Mulgrave, Victoria 3170Telephone:+61 3 9541 8900Telefax: +61 3 9541 8989Information about the Safety Data Sheet:Telephone+49/(0) 8677/83-4888Telefax+49/8677/83-5590eMail WLCP-MSDS@1.4 Emergency telephone numberEmergency information:Regulatory Compliance Manager +61 3 9541 8900 Emergency response service only (24h):Orica Australia SH&E Shared Services 1800 033 1112 Hazards identification2.1 Classification:HAZARDOUS SUBSTANCE (according to the criteria of NOHSC).DANGEROUS GOOD (according to the ADG Code).R-Phrase DescriptionR38Irritating to skin.R51/53Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.2.2 Further hazards to man and environment:Inhalation of aerosol spray may damage health.Product hydrolyses under formation of methanol (CAS no. 67-56-1). Methanol is toxic if inhaled, swallowed or comes into contact with the skin (T, R23/24/25), leads to irreversible damage if inhaled, comes into contact with the skin or is swallowed (T, 39/23/24/25) and is highlyflammable (F, R11).3 Composition/information on ingredients3.1 Chemical characterization (substance):EC-No.CAS No.Chemical characteristics402-140-117865-32-6organosilane3.2 Hazardous ingredients:EC-No.CAS No.Material Content%Warning Label (EC)from to Symbol R-PhrasesCyclohexyldimethoxymethylsil>98.0 Xi, N 38-51/53 17865-32-6402-140-1aneMaterial: 60003427SILANE CHM-DIMETHOXYVersion: 1.3 (AU) Date of print: 03.11.2009 Date of last alteration: 02.02.2009 If the sum of ingredients is less than 100%, the material consists of further ingredientsdetermined not to be hazardous or below their cut-off limits.R-Phrase DescriptionR51/53Irritating to skin. Toxic to aquatic organisms, may cause long-term adverseR38effects in the aquatic environment.4 First-aid measures4.1 General information:Take persons to a safe place. Observe self-protection for first aid.4.2 After inhalation:Keep the patient calm. If unconscious place in stable sideways position. Protect against loss of body heat. In cases of sickness seek medical advice (show label or SDS if possible).4.3 After contact with the skin:Remove contaminated or soaked clothing. Immediately rinse with plenty of soap and water. In the event of a visible skin change or other complaints, seek medical advice (show label or SDSwhere possible).4.4 After contact with the eyes:Rinse immediately with plenty of water for 10-15 minutes. Seek medical advice in case ofcontinuous irritation.4.5 After swallowing:If conscious, give several small portions of water to drink. Do not induce vomiting. Seekmedical advice immediately and clearly identify substance.4.6 Advice for the doctor:In case of contact with water material splits off (also in gastrointestinal tract) methanol in larger amounts; therefore consider poisoning on methanol and also observe known period oflatency of several days!5 Fire-fighting measures5.1 Suitable extinguishing media:water mist , extinguishing powder , alcohol-resistant foam , carbon dioxide , sand .5.2 Extinguishing media which must not be used for safety reasons:water spray , water jet .5.3 Special exposure hazards arising from the substance or preparation itself, combustion products,resulting gases:-5.4 Special protective equipment for fire fighting:Use respiratory protection independent of recirculated air.6 Accidental release measures6.1 Personal precautions:Wear personal protection equipment (see section 8). Keep unprotected persons away. Avoidcontact with eyes and skin. Avoid inhaling mists and vapours. If material is released indicate risk of slipping.6.2 Environmental precautions:Prevent material from entering surface waters, drains or sewers and soil. Contain any fluid that runs out using suitable material (e.g. earth). Retain contaminated water/extinguishing water. Dispose of in prescribed marked containers.6.3 Methods for cleaning up:Do not flush away with water. For small amounts: Absorb with a liquid binding material such as diatomaceous earth and dispose of according to local/state/federal regulations. Contain larger amounts and pump up into suitable containers. Clean any slippery coating that remains using a detergent / soap solution or another biodegradable cleaner. Exhaust vapours.Material: 60003427SILANE CHM-DIMETHOXYVersion: 1.3 (AU) Date of print: 03.11.2009 Date of last alteration: 02.02.20096.4 Further information:Eliminate all sources of ignition.7 Handling and storage7.1 HandlingPrecautions for safe handling:Ensure adequate ventilation. Keep away from incompatible substances in accordance with section10.2. Spilled substance increases risk of slipping.Precautions against fire and explosion:Product can separate methanol. Flammable vapors may accumulate and form explosive mixtures with air in containers, process vessels, including partial, empty and uncleaned containers andvessels, or other enclosed spaces. Keep away from sources of ignition and do not smoke. Take precautionary measures against electrostatic charging. Cool endangered containers with water. 7.2 StorageConditions for storage rooms and vessels:Make sure there is no possibility of entering the ground.Advice for storage of incompatible materials:applicablenotFurther information for storage:Protect against moisture. Store in original container only. Keep container tightly closed and store in a cool, well ventilated place.7.3 Regulations and standards (Australia):Store in accordance with Dangerous Goods (Storage & Handling) Regulations and AS/NZS 4681 The Storage and Handling of Class 9 (miscellaneous) Dangerous Goods and Articles.Also classified asa C1 Combustible Liquid which should be stored in accordance with AS 1940 Storage & Handling ofFlammable & Combustible Liquids.8 Exposure controls/personal protection8.1Exposure limitsMaximum airborne concentrations at the workplace:CAS No. Material Type mg/m3ppm Dust fract.Fibre/m3 67-56-1 Methanol AGW 270.0 200.067-56-1 Methanol OEL 266.0 200.067-56-1 Methanol ES_AU 262.0 200.0-Methanol (CAS no. 67-56-1): Refer to Technical Rules for Hazardous Substances "TRGS 900" for more details on the German AGW.8.2 Exposure limited and controlled8.2.1 Exposure in the work place limited and controlledGeneral protection and hygiene measures:Avoid contact with eyes and skin. Do not inhale gases/vapours/aerosols. Do not eat, drink or smoke when handling.Personal protection equipmentRespiratory protection:In case of long or strong exposure: gas mask filter ABEK .Hand protection:Protective gloves made of butyl rubber . Gloves suitable for up to 60 minutes' use.Eye protection:tight fitting protective goggles .Skin protection:protective clothing .Material: 60003427SILANE CHM-DIMETHOXYVersion: 1.3 (AU) Date of print: 03.11.2009 Date of last alteration: 02.02.20098.2.2 Exposure to the environment limited and controlled: Prevent material from entering surface waters, drains or sewers and soil.8.2.3 Specific notes (Australia): Select and use respirators in accordance with AS1715/1716.8.3 Further information for system design and engineering measures: Observe information in section 7.9Physical and chemical properties9.1 General information Physical state / form................: liquidColour...............................: colourless Odour................................: slight9.2 Important information about the protection of health, safety and the environment Method(67/548/EEC): Melting point / melting range........: < -50 °C Boiling point / boiling range........: 198 °C at 1013 hPaFlash point..........................: 76 °C (DIN 51758) Sustained combustibility.............: 78 °C (ISO 9038) Ignition temperature ................: 235 °C (DIN 51794) Lower explosion limit (LEL)..........: not applicable Upper explosion limit (UEL)..........: not applicable Vapour pressure......................: 0.48 hPa at 20 °C Vapour pressure......................: 1.7 hPa at 38 °CDensity..............................: 0.94 g/cm³ at 25 °C, at 1013 hPa (DIN 51757) Water solubility / miscibility.......: 0.28 g/l at 20 °C Solubility in organic solvent........: totally miscible with common organicsolventspH-Value.............................: not applicableViscosity (dynamic)..................: 1.6 mPa.s at 25 °C (DIN 51562) Viscosity (kinematic)................: 1.7 mm²/s at 25 °C9.3 O ther information Re 9.2 solubility in water: Hydrolytic decomposition occurs. Explosion limits for released methanol: 5.5 - 44%(V). Re 9.2 pH Value: Product displays neutral reaction.Thermal decomposition................: No decomposition when used according toregulations.10 Stability and reactivity10.0 General information: If stored and handled in accordance with standard industrial practices no hazardous reactionsare known.10.1 Conditions to avoid: moisture10.2 Materials to avoid: Reacts with: water , basic substances and acids . Reaction causes the formation of: methanol .10.3 Hazardous decomposition products: If stored and handled in accordance with standard industrial practices and local regulationswhere applicable: none known . By hydrolysis: methanol .Material: 60003427SILANE CHM-DIMETHOXYVersion: 1.3 (AU) Date of print: 03.11.2009 Date of last alteration: 02.02.200911 Toxicological information11.0 General information:Note indications of danger and safety advice (R- and S-phrases) in section 15.11.1 Toxicological testsAcute toxicity (LD50/LC50-values relevant to classification):Exposition Value/value range Species Sourceoral 4071 mg/kg rat test report dermal > 2000 mg/kg rat (Limit Test) test report by inhalation > 5.03 mg/l/4h (spray / dust) rat (Limit Test) test report Specific symptoms in animal test:Acute inhalation: No mortality with the given dose.Primary irritation:Exposition Effect Species/Testsystem Sourceto skin irritating rabbit test report to eyes mildly irritating rabbit test report Sensitization:Exposition Effect Test method Species Sourceto skin not sensitizing Magnusson-Kligmann guinea-pig testreportFurther information:-Subacute to chronic toxicity:Species Test method End point Value Sourcerat Repeated Dose 28-dayOral Toxicity Study inRodentsNOAEL 756 mg/kg/d test reportReference points for mutagenic potential:Test system Effect SourceGenetic Toxicology: Rodent Dominant Lethal Test not mutagenic test report Mammalian Erythrocyte Micronucleus Test mutagenic test report Bacterial Reverse Mutation Test not mutagenic test report 11.2Experience with man:-11.3Further toxicological information:Product(s) of hydrolysis: Attention! Product may hydrolyse in gastro-intestinal tract and produce methanol. According to literature methanol (67-56-1) irritates mucuous membranes, has skin drying and narcotic effects up to coma or death. Absorption by the skin is possible.Possibility of damage to heart, kidneys, liver and optic nerves (blindness) over a period of time.12 Ecological information12.1 EcotoxicitySpecies Test method Exp. time Result SourceDaphniamagna acute48 h 2.3 - 48 mg/l(EC50)test reportrainbow trout (Oncorhynchusmykiss)acute96 h 75 mg/l (LC50) test report Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. 12.2 Mobility-Material: 60003427SILANE CHM-DIMETHOXYVersion: 1.3 (AU) Date of print: 03.11.2009 Date of last alteration: 02.02.200912.3 Persistence and degradabilityBiodegradation:Method Degree of elimination Classification Sourcetest report Test17 %, in 28 day(s)Not readilyBottleClosedbiodegradable.Hydrolysis:Method Classification SourceHydrolysis as a function of pH. Hydrolytically instable. test report Further information:Contact with water liberates: Methanol and silanol- and/or siloxanol-compounds .12.4 Bio-accumulation potential-12.5 Other harmful effects-12.6 Additional informationGeneral information:Prevent material from entering surface waters, drains or sewers and soil.13 Disposal considerations13.1 MaterialRecommendation:Dispose of according to regulations by incineration in a special waste incinerator. Observe local/state/federal regulations.13.2 Uncleaned packagingRecommendation:Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used. Observe local/state/federal regulations.14 Transport information14.1 Land transport ADG Code (road and rail):productHazardousValuation....................:9Class........................:Packaging Group..............: IIIUN no. ......................: 3082Proper Shipping Name.........: Environmentally hazardous substance, liquid, n.o.s.(Cyclohexyldimethoxymethylsilane)Technicalname...............:Code.................:3ZHazChemFurther information..........: Environmentally Hazardous Substances meeting the descriptions ofUN 3077 or UN 3082 are not subject to the ADG Code whentransported by road or rail in (a) packagings; (b) IBCs; or (c)any other receptacle not exceeding 500 kg(L).14.2 Transport by sea IMDG-CodeproductHazardousValuation....................:9Class........................:IIIGroup..............:PackagingUN no. ......................: 3082Proper Shipping Name.........: Environmentally hazardous substance, liquid, n.o.s.(Cyclohexyldimethoxymethylsilane)name...............:TechnicalyesMarinePollutant.............:14.3 Air transport ICAO-TI/IATA-DGRproductHazardousValuation....................:9Class........................:Material: 60003427SILANE CHM-DIMETHOXYVersion: 1.3 (AU) Date of print: 03.11.2009 Date of last alteration: 02.02.2009Packaging Group..............: III UN no. ......................: 3082 Proper Shipping Name.........: Environmentally hazardous substance, liquid, n.o.s. Technical name...............: (Cyclohexyldimethoxymethylsilane) 15Regulatory information15.1 Warning Label (EC)XiIrritantNDangerous for the environmentR-Phrase DescriptionR38 Irritating to skin.R51/53Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.S-Phrase DescriptionS24 Avoid contact with skin.S61Avoid release to the environment. Refer to special instructions / safety data sheets.EC-No.:402-140-1Hazard ingredients (labelling EC): CAS No. MaterialHazard symbols Risk phrases(EC)17865-32-6 CyclohexyldimethoxymethylsilaneXi, N 38-51/5315.2 National regulations:15.2.1 Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) Australia:Poisons Schedule number:No Poisons Schedule number allocated.15.3 O ther international regulationsDetails of international registration statusListed on or in accordance with the following inventories: IECSC - ChinaPICCS - Philippines ENCS - Japan ELINCS - Europe ECL - Korea DSL - Canada AICS - Australia TSCA - USA16 Other information16.1 MaterialThe above information describes exclusively the safety requirements of the product(s) and is based on our present-day knowledge. It does not represent a guarantee for the properties of the product(s) described in terms of the legal warranty regulations.Properties of the product are to be found in the respective product leaflet.16.2 Further information:Vertical lines in the left-hand margin indicate changes compared with the previous version. This version supersedes all previous versions.Material: 60003427SILANE CHM-DIMETHOXYVersion: 1.3 (AU) Date of print: 03.11.2009 Date of last alteration: 02.02.200916.3 Glossary of Terms:CAS No. - Chemical Abstracts Service Registry NumberUN No. - United Nations Dangerous Goods NumberADG Code - Australian Dangerous Goods Code for the Transport of Dangerous Goods by Road & RailIMDG Code - International Maritime Dangerous Goods CodeIATA Regs - International Air Transport Association (IATA) Dangerous Goods RegulationsNOHSC - Australian National Occupational Health and Safety Commission (Note: NOHSC documents are now published by the ASCC)ASCC - Australian Safety & Compensation CouncilOEL - Occupational exposure limit in Great BritainAGW - Occupational exposure limit in GermanyES_AU - Occupational exposure limit in Australia- End of Safety Data Sheet -。
安全技术说明书-Buehler,anITWCompany
此安全技术说明书根据以下要求生成： 第1907/2006(EC)号法规和欧盟第1272/2008号法规
签发日期 26-8月-2016
修订日期 13-11月-2017
修订编号 3
EGHS / 简体中文 (ChineseSimplified)
_____________________________________________________________________________________________
一般卫生注意事项
避免接触皮肤、眼睛或衣物.佩戴适当的手套和眼睛/面部防护设备.使用本产品时
_____________________________________________________________________________________________
页码 5 / 17
1346828 - PhenoCure Powder & PreMolds
1346828 - PhenoCure Powder & PreMolds
修订日期 13-11月-2017
_____________________________________________________________________________________________
Global Access Code: 334545 Asia Pacific: +1 760 476 3960 Middle East/Africa: +1 760 476 3959 China local: +86 4001 2001 74
6.4.参考其他部分
参考其他部分
更多信息参见第8部分.更多信息参见第13部分.
溴素安全技术说明书
溴安全技术说明书第一部分化学品及企业标识化学品中文名称：溴化学品英文名称：Bromine企业名称：地址：邮编：电子邮件地址：联系电话：传真号码：企业应急电话：技术说明书编码：产品推荐用途：石油工业中，溴用于制造燃烧防爆剂及完井液；农业上，是制造高效农药、粮库灭虫灭鼠的熏蒸剂及农田杀虫剂的原料；医药工业中广泛应用于制造溴化钾、溴化钠、溴化铵、氯霉素、奈普生及TMP等药物；溴素是制造某些染料的重要原料；在塑料工业及建材工业中，是生产阻燃剂的重要原料；国防、军工及消防工业中，溴是制造高效低毒灭火剂的原料；同时溴也是制造感光器材的主要材料。
产品限制用途：禁止用于食品加工。
第二部分危险性概述物理化学危险：强氧化剂，与易燃物（如苯）和可燃物（如糖、纤维素等）接触会发生剧烈反应，甚至引起燃烧。
对大多数金属及有机组织有腐蚀性，遇氢、甲烷、硫磺、锑、砷、磷、钠、钾及其他金属粉末剧烈反应，有爆炸危险。
健康危害：对皮肤、粘膜有强烈刺激作用和腐蚀作用。
吸入较低浓度，很快发生眼呼吸道粘膜的刺激症状，并有头痛、眩晕、全身无力、胸部发紧、干咳、恶心和呕吐等症状；吸入高浓度时有剧咳、呼吸困难、哮喘。
严重时可发生窒息、肺炎、肺水肿。
可出现中枢神经系统紊乱症状。
皮肤接触高浓度溴蒸气或液态溴可造成严重灼伤。
长期吸入，除粘膜刺激症状外，还伴有神经衰弱综合症。
眼睛接触造成眼睛烧伤，引起化学性结膜炎和角膜损伤。
误服可造成消化道的永久性损害，可能造成消化道穿孔，引起恶心、呕吐、腹泻和便血等。
环境危害：对环境有危害，对水体、土壤和大气可造成污染。
GHS危险性类别：根据《化学品分类和危险性公示通则》（GB 13690-2009）及化学品分类、警示标签和警示性说明规范系列标准，该产品属于金属腐蚀物，类别1；急性毒性（经口），类别4；急性毒性（兔吸入），类别2；皮肤腐蚀刺激，类别1；严重眼睛损伤/眼睛刺激性，类别1；特异性靶器官系统毒性单次接触，类别1；特异性靶器官系统毒性反复接触，类别1；对水环境的危害（急性），类别1；对水环境的危害（慢性），类别1。
溴化钠msds
第一部分化学品及企业标识化学品中文名称：溴化钠化学品英文名称：Sodium bromide企业名称：广东光华化学厂有限公司地址：广东汕头市光华北四路26号邮编：515021电子邮件地址：service@,sales@传真号码：（86）（754）（8115161）企业应急电话：（86）（754）（8101881）技术说明书编码：生效日期：年月日第二部分成分/组成信息纯品■混合物□化学品名称：溴化钠化学品分子式：NaBr分子量：102.90有害物成分含量CAS号溴化钠１００％7647-15-6第三部分危险性概述危险性类别：侵入途径：吸入、食入、经皮吸收。
健康危害：无资料。
环境危害：无资料。
燃爆危险：几乎不燃。
第四部分急救措施皮肤接触：脱去被污染的衣着，用清水彻底冲洗。
眼睛接触：立即提起眼睑，用大量流动清水冲洗至少10分钟。
吸入：迅速脱离现场至空气新鲜处。
食入：让受害者饮足量水，催吐，就医。
第五部分消防措施危险特性：几乎不燃。
如果燃烧可产生有毒气体。
有害燃烧产物：溴化氢灭火方法及灭火剂：根据周围环境选择合适的灭火器。
灭火注意事项：没有配备化学防护衣和供氧设备请不要待在危险区。
喷水降低蒸气危害，防止化学品进入地表水和地下水。
第六部分泄漏应急处理个人防护：避免产生和吸入其粉尘。
当粉尘浓度过高时，应急处理人员须穿戴安全防护用具进入现场。
环境保护措施：化学品未经处理不允许向环境排放。
清洁/吸收措施：采用安全的方法将泄漏物收集回收或运至废物处理场所处理，根据化学品性质进一步处置。
清理污染区，洗液排入废水处理池。
第七部分操作处置与储存操作注意事项：无特殊要求。
储存注意事项：干燥，密封。
避光。
按常温储存。
第八部分接触控制/个体防护最高容许浓度：中国MAC(mg/m3)：无资料。
监测方法：工程控制：密闭操作，局部排风。
提供安全淋浴和洗眼设备。
呼吸系统防护：当空气中粉尘浓度过高时，建议佩戴过滤式防尘呼吸器。
必要时，佩戴空气呼吸器。
溴酸钠危险化学品安全技术说明书
溴酸钠危险化学品安全技术说明书第一部分化学品名称化学品中文名称：溴酸钠化学品英文名称：sodium bromate中文名称2：英文名称2：bromic acid sodium salt技术说明书编码：603CAS No.：7789-38-0第二部分成分/组成信息第三部分危险性概述危险性类别：侵入途径：健康危害：粉尘对眼睛和呼吸道有刺激性。
环境危害：燃爆危险：本品助燃，具刺激性。
第四部分急救措施皮肤接触：脱去污染的衣着，用肥皂水和清水彻底冲洗皮肤。
眼睛接触：提起眼睑，用流动清水或生理盐水冲洗。
就医。
吸入：迅速脱离现场至空气新鲜处。
保持呼吸道通畅。
如呼吸困难，给输氧。
如呼吸停止，立即进行人工呼吸。
就医。
食入：饮足量温水，催吐。
就医。
第五部分消防措施危险特性：强氧化剂。
与铵盐、金属粉末、可燃物、有机物或其它易氧化物形成爆炸性混合物，经摩擦或受热易引起燃烧或爆炸。
与硫酸接触容易发生爆炸。
能与铝、砷、铜、碳、金属硫化物、有机物、磷、硒、硫剧烈反应。
有害燃烧产物：溴化氢、氧化钠。
灭火方法：喷水冷却容器，可能的话将容器从火场移至空旷处。
灭火剂：雾状水、砂土。
第六部分泄漏应急处理应急处理：隔离泄漏污染区，限制出入。
建议应急处理人员戴防尘面具（全面罩），穿防毒服。
小量泄漏：用砂土、干燥石灰或苏打灰混合。
大量泄漏：用塑料布、帆布覆盖。
然后收集回收或运至废物处理场所处置。
第七部分操作处置与储存操作注意事项：密闭操作，局部排风。
操作人员必须经过专门培训，严格遵守操作规程。
建议操作人员佩戴自吸过滤式防尘口罩，戴化学安全防护眼镜，穿聚乙烯防毒服，戴橡胶手套。
远离火种、热源，工作场所严禁吸烟。
远离易燃、可燃物。
避免产生粉尘。
避免与还原剂接触。
搬运时要轻装轻卸，防止包装及容器损坏。
配备相应品种和数量的消防器材及泄漏应急处理设备。
倒空的容器可能残留有害物。
储存注意事项：储存于阴凉、通风的库房。
远离火种、热源。
包装密封。
应与易（可）燃物、还原剂等分开存放，切忌混储。
新版次氯酸钠安全技术说明书英文
SAFETY DATA SHEETSAccording to Globally Harmonized System of Classification andLabelling of Chemicals (GHS) - Sixth revised edition1.1GHS Product identifierProduct name sodium hypochlorite1.2Other means of identificationProduct number-Other names milton1.3Recommended use of the chemical and restrictions on useIdentified uses For industry use only.Uses advised against no data available1.4Supplier's detailsCompanyAddressTelephoneFax1.5Emergency phone numberEmergency phone numberService hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMThours).2.1Classification of the substance or mixtureSkin corrosion, Category 1BHazardous to the aquatic environment, short-term (Acute) - Category Acute 12.2GHS label elements, including precautionary statementsPictogram(s)Signal word DangerHazard statement(s)H314 Causes severe skin burns and eye damageH400 Very toxic to aquatic lifePrecautionarystatement(s)Prevention P260 Do not breathe dust/fume/gas/mist/vapours/spray.P264 Wash ... thoroughly after handling.P280 Wear protective gloves/protective clothing/eyeprotection/face protection.P273 Avoid release to the environment.Response P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT inducevomiting.P303+P361+P353 IF ON SKIN (or hair): Take off immediately allcontaminated clothing. Rinse skin with water [or shower].P363 Wash contaminated clothing before reuse.P304+P340 IF INHALED: Remove person to fresh air and keepcomfortable for breathing.P310 Immediately call a POISON CENTER/doctor/…P321 Specific treatment (see ... on this label).P305+P351+P338 IF IN EYES: Rinse cautiously with water for severalminutes. Remove contact lenses, if present and easy to do. Continuerinsing.P391 Collect spillage.Storage P405 Store locked up.Disposal P501 Dispose of contents/container to ...2.3Other hazards which do not result in classificationnone3.1Substances4.1Description of necessary first-aid measuresGeneral adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaledIf breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult aphysician.In case of skin contactWash off with soap and plenty of water. Consult a physician.In case of eye contactRinse thoroughly with plenty of water for at least 15 minutes and consult a physician.If swallowedNever give anything by mouth to an unconscious person. Rinse mouth with water. Consult aphysician.4.2Most important symptoms/effects, acute and delayedno data available4.3Indication of immediate medical attention and special treatment needed, if necessaryno data available5.1Extinguishing mediaSuitable extinguishing mediaUse water spray, alcohol-resistant foam, dry chemical or carbon dioxide.5.2Specific hazards arising from the chemicalno data available5.3Special protective actions for fire-fightersWear self-contained breathing apparatus for firefighting if necessary.6.1Personal precautions, protective equipment and emergency proceduresUse personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas.Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Forpersonal protection see section 8.6.2Environmental precautionsPrevent further leakage or spillage if safe to do so. Do not let product enter drains. Dischargeinto the environment must be avoided.6.3Methods and materials for containment and cleaning upPick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers fordisposal.7.1Precautions for safe handlingAvoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure -obtain special instructions before use.Provide appropriate exhaust ventilation at places wheredust is formed. For precautions see section 2.2.7.2Conditions for safe storage, including any incompatibilitiesStore in cool place. Keep container tightly closed in a dry and well-ventilated place.8.1Control parametersOccupational Exposure limit valuesno data availableBiological limit valuesno data available8.2Appropriate engineering controlsHandle in accordance with good industrial hygiene and safety practice. Wash hands beforebreaks and at the end of workday.8.3Individual protection measures, such as personal protective equipment (PPE)Eye/face protectionSafety glasses with side-shields conforming to EN166. Use equipment for eye protection testedand approved under appropriate government standards such as NIOSH (US) or EN 166(EU).Skin protectionWear impervious clothing. The type of protective equipment must be selected according to theconcentration and amount of the dangerous substance at the specific workplace. Handle withgloves. Gloves must be inspected prior to use. Use proper glove removal technique(withouttouching glove's outer surface) to avoid skin contact with this product. Dispose of contaminatedgloves after use in accordance with applicable laws and good laboratory practices. Wash anddry hands. The selected protective gloves have to satisfy the specifications of EU Directive89/686/EEC and the standard EN 374 derived from it.Respiratory protectionWear dust mask when handling large quantities.Thermal hazardsno data availablePhysical state colourless liquid with strong odour Colour no data availableOdour no data availableMelting point/ freezing-16ºCpoint111°CBoiling point or initialboiling point and boilingrangeFlammability no data availableno data availableLower and upper explosionlimit / flammabilitylimitFlash point no data availableAuto-ignitionno data availabletemperatureno data availableDecompositiontemperaturepH no data availableKinematic viscosity no data availableSolubility In water:decomposes.no data availablePartition coefficientn-octanol/water (logvalue)Vapour pressure no data available1.097g/mLat 25°CDensity and/or relativedensityRelative vapour density no data availableParticle characteristics n o data available10.1Reactivityno data available10.2Chemical stabilityStable under recommended storage conditions.10.3Possibility of hazardous reactionsno data available10.4Conditions to avoidno data available10.5Incompatible materialsno data available10.6Hazardous decomposition productsno data availableAcute toxicity•Oral: no data available•Inhalation: no data available•Dermal: no data availableSkin corrosion/irritationno data availableSerious eye damage/irritationno data availableRespiratory or skin sensitizationno data availableGerm cell mutagenicityno data availableCarcinogenicityno data availableReproductive toxicityno data availableSTOT-single exposureno data availableSTOT-repeated exposureno data availableAspiration hazardno data available12.1Toxicity•Toxicity to fish: no data available•Toxicity to daphnia and other aquatic invertebrates: no data available•Toxicity to algae: no data available•Toxicity to microorganisms: no data available12.2Persistence and degradabilityno data available12.3Bioaccumulative potentialno data available12.4Mobility in soilno data available12.5Other adverse effectsno data available13.1Disposal methodsProductThe material can be disposed of by removal to a licensed chemical destruction plant or bycontrolled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed orseed by storage or disposal. Do not discharge to sewer systems.Contaminated packagingContainers can be triply rinsed (or equivalent) and offered for recycling or reconditioning.Alternatively, the packaging can be punctured to make it unusable for other purposes and thenbe disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possiblefor combustible packaging materials.14.1UN NumberADR/RID: UN3082IMDG: UN3082IATA: UN3082 14.2UN Proper Shipping NameADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.IATA: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.14.3Transport hazard class(es)ADR/RID: 9IMDG: 9IATA: 9 14.4Packing group, if applicableADR/RID: III IMDG: III IATA: III14.5Environmental hazardsADR/RID: yes IMDG: yes IATA: yes14.6Special precautions for userno data available14.7Transport in bulk according to Annex II of MARPOL 73/78 andthe IBC Codeno data available15.1Safety, health and environmental regulations specific for the product in questionInformation on revisionCreation Date Aug 16, 2017Revision Date Aug 16, 2017Abbreviations and acronyms•CAS: Chemical Abstracts Service•ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road•RID: Regulation concerning the International Carriage of Dangerous Goods by Rail•IMDG: International Maritime Dangerous Goods•IATA: International Air Transportation Association•TWA: Time Weighted Average•STEL: Short term exposure limit•LC50: Lethal Concentration 50%•LD50: Lethal Dose 50%•EC50: Effective Concentration 50%。
溴化钠安全技术说明书
溴化钠安全技术说明书溴化钠（Sodium bromide）是一种常见的无机化合物，其化学式为NaBr。
它是一种无色结晶固体，在常温下稳定。
溴化钠被广泛应用于医药、冶金、石油等领域，但其使用需要遵循一定的安全注意事项，以确保人员和环境的安全。
溴化钠应储存在干燥、通风良好的地方，远离火源和易燃材料。
避免与氧化剂、酸类物质接触，以免产生危险反应。
同时，储存区域应标明“易燃物品”标识，并设立相应的安全设施，如防火设备和泄漏应急处理措施。
在使用溴化钠时，应佩戴个人防护装备，如防护眼镜、防护服和化学手套，以防止溶液或粉末对眼睛、皮肤和呼吸系统造成伤害。
同时，应注意避免吸入、摄入或接触溴化钠溶液，以免引起中毒或刺激。
溴化钠的溶液具有一定的腐蚀性，因此在使用过程中应避免溅入眼睛或皮肤。
如果不慎接触到溶液，应立即用大量清水冲洗，并及时就医。
对于溶液的泄漏或溅洒，应采取应急处理措施，如用吸收剂吸附溶液，将溶液转移到密闭容器中，以避免对环境造成污染。
在制备溴化钠溶液时，应遵循正确的操作规程。
首先，将适量的溴化钠加入水中，搅拌至溶解。
在此过程中，应注意向水中缓慢加入溴化钠，以避免剧烈反应产生的溶液喷溅。
制备好的溴化钠溶液应经过过滤或离心等处理，以去除杂质和不溶物。
溴化钠在医药领域具有一定的应用价值。
它常被用作消毒剂和抗菌剂，能有效杀灭细菌和病毒。
然而，在使用时应注意控制溴化钠的浓度和用量，避免对人体产生不良影响。
溴化钠在石油工业中也有广泛应用。
它常被用作钻井液的添加剂，具有增加钻井液密度、抑制井壁塌陷和稳定井眼等作用。
然而，在使用过程中应遵循相关规定，控制溴化钠的浓度和用量，以确保钻井作业的安全进行。
溴化钠作为一种常见的无机化合物，在医药、石油等领域具有广泛应用。
然而，对于溴化钠的使用需要遵循一定的安全技术要求，以确保人员和环境的安全。
在储存、使用和处理溴化钠时，应注意个人防护、避免溅洒和泄漏，以及正确控制溶液的浓度和用量。
溴酸钠安全技术说明书(MSDS)
溴酸钠安全技术说明书（MSDS）一：标识【危化品名称】：溴酸钠【中文名】：溴酸钠【英文名】：sodium bromate【分子式】：NaBrO3【相对分子量】：150.91【CAS号】：7789-38-0?【危险性类别】：二：主要组成与性状【主要成分】：含量≥98.5％。
【外观与性状】：白色结晶或晶状粉末, 无味。
【主要用途】：用作分析试剂和氧化剂、烫发药剂，与溴化钠混合用作金的溶解剂。
三：健康危害【侵入途径】：【健康危害】：粉尘对眼睛和呼吸道有刺激性。
?四：急救措施【皮肤接触】：脱去污染的衣着，用肥皂水和清水彻底冲洗皮肤。
【眼睛接触】：提起眼睑，用流动清水或生理盐水冲洗。
就医。
【吸入】：迅速脱离现场至空气新鲜处。
保持呼吸道通畅。
如呼吸困难，给输氧。
如呼吸停止，立即进行人工呼吸。
就医。
【食入】：饮足量温水，催吐。
就医。
五：燃爆特性与消防【闪点】：无意义【燃爆下限】：无意义【引燃温度】：无意义【爆炸上限】：无意义【危险特性】：强氧化剂。
与铵盐、金属粉末、可燃物、有机物或其它易氧化物形成爆炸性混合物，经摩擦或受热易引起燃烧或爆炸。
与硫酸接触容易发生爆炸。
能与铝、砷、铜、碳、金属硫化物、有机物、磷、硒、硫剧烈反应。
【灭火方法】：喷水冷却容器，可能的话将容器从火场移至空旷处。
灭火剂：雾状水、砂土。
六：泄漏应急处理【泄漏应急处理】：隔离泄漏污染区，限制出入。
建议应急处理人员戴防尘面具（全面罩），穿防毒服。
小量泄漏：用砂土、干燥石灰或苏打灰混合。
大量泄漏：用塑料布、帆布覆盖。
然后收集回收或运至废物处理场所处置。
七：储运注意事项【储运注意事项】：储存于阴凉、通风的库房。
远离火种、热源。
包装密封。
应与易（可）燃物、还原剂等分开存放，切忌混储。
储区应备有合适的材料收容泄漏物。
八：防护措施【中国MAC】：未制定标准【前苏联MAC】：未制定标准【检测方法】：【工程控制】：密闭操作，局部排风。
【呼吸系统防护】：空气中粉尘浓度超标时，作业工人应该佩戴自吸过滤式防尘口罩。
溴化铵安全技术说明书英文
SAFETY DATA SHEETSAccording to Globally Harmonized System of Classification andLabelling of Chemicals (GHS) - Sixth revised edition1.1GHS Product identifierProduct name ammonium bromide1.2Other means of identificationProduct number-Other names Ammonium bromide1.3Recommended use of the chemical and restrictions on useIdentified uses For industry use only. Flame retardants,Oxidizing/reduciagentsUses advised against no data available1.4Supplier's detailsCompanyAddressTelephoneFax1.5Emergency phone numberEmergency phone numberService hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMThours).2.1Classification of the substance or mixtureEye irritation, Category 22.2GHS label elements, including precautionary statementsPictogram(s)Signal word WarningHazard statement(s)H319 Causes serious eye irritationPrecautionarystatement(s)Prevention P264 Wash ... thoroughly after handling.P280 Wear protective gloves/protective clothing/eyeprotection/face protection.Response P305+P351+P338 IF IN EYES: Rinse cautiously with water for severalminutes. Remove contact lenses, if present and easy to do. Continuerinsing.P337+P313 If eye irritation persists: Get medical advice/attention. Storage noneDisposal none2.3Other hazards which do not result in classificationnone3.1Substances4.1Description of necessary first-aid measuresGeneral adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaledIf breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult aphysician.In case of skin contactWash off with soap and plenty of water. Consult a physician.In case of eye contactRinse thoroughly with plenty of water for at least 15 minutes and consult a physician.If swallowedNever give anything by mouth to an unconscious person. Rinse mouth with water. Consult aphysician.4.2Most important symptoms/effects, acute and delayedINHALATION: Dust irritating - disturbed behavior, sedation. EYES: Slight irritation. SKIN:Slight irritation only with repeated or prolonged contact. INGESTION: Weakness, nervousness, anorexia, confusion, hallucinations, drowsiness, irritability, ataxia, vertigo, skin rash. (USCG,1999)4.3Indication of immediate medical attention and special treatment needed, if necessaryImmediate first aid: Ensure that adequate decontamination has been carried out. If patient is notbreathing, start artificial respiration, preferably with a demand-valve resuscitator,bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediatelyflush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs,lean patient forward or place on left side (head-down position, if possible) to maintain an openairway and prevent aspiration. Keep patient quiet and maintain normal body temperature.Obtain medical attention. /Bromine, methyl bromide, and related compounds/5.1Extinguishing mediaSuitable extinguishing mediaSuitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbondioxide.5.2Specific hazards arising from the chemicalSpecial Hazards of Combustion Products: Material decomposes into N 2 and HBr or Br 2 underextreme temperatures. (USCG, 1999)5.3Special protective actions for fire-fightersWear self-contained breathing apparatus for firefighting if necessary.6.1Personal precautions, protective equipment and emergency proceduresUse personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas.Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Forpersonal protection see section 8.6.2Environmental precautionsPrevent further leakage or spillage if safe to do so. Do not let product enter drains. Dischargeinto the environment must be avoided.6.3Methods and materials for containment and cleaning upAccidental Release Measures: Personal precautions, protective equipment and emergencyprocedures Use personal protective equipment. Avoid dust formation. Avoid breathing vapors,mist or gas. Ensure adequate ventilation. Avoid breathing dust. Environmental precautions: Donot let product enter drains. Methods and materials for containment and cleaning up: Pick upand arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closedcontainers for disposal.7.1Precautions for safe handlingAvoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure -obtain special instructions before use.Provide appropriate exhaust ventilation at places wheredust is formed. For precautions see section 2.2.7.2Conditions for safe storage, including any incompatibilitiesKeep well closed.8.1Control parametersOccupational Exposure limit valuesno data availableBiological limit valuesno data available8.2Appropriate engineering controlsHandle in accordance with good industrial hygiene and safety practice. Wash hands beforebreaks and at the end of workday.8.3Individual protection measures, such as personal protective equipment (PPE)Eye/face protectionSafety glasses with side-shields conforming to EN166. Use equipment for eye protection testedand approved under appropriate government standards such as NIOSH (US) or EN 166(EU).Skin protectionWear impervious clothing. The type of protective equipment must be selected according to theconcentration and amount of the dangerous substance at the specific workplace. Handle withgloves. Gloves must be inspected prior to use. Use proper glove removal technique(withouttouching glove's outer surface) to avoid skin contact with this product. Dispose of contaminatedgloves after use in accordance with applicable laws and good laboratory practices. Wash anddry hands. The selected protective gloves have to satisfy the specifications of EU Directive89/686/EEC and the standard EN 374 derived from it.Respiratory protectionWear dust mask when handling large quantities.Thermal hazardsno data availablePhysical state white crystalsColour White tetragonal crystalsOdour OdorlessMelting point/ freezing452ºC (subl.)point396°C/1atm(lit.)Boiling point or initialboiling point and boilingrangeFlammability no data availableno data availableLower and upper explosionlimit / flammabilitylimitFlash point no data availableAuto-ignitionNot flammable (USCG, 1999)temperatureno data availableDecompositiontemperaturepH Slightly acid to litmusKinematic viscosity no data availableSolubility In water:97 g/100 mL (25 ºC)no data availablePartition coefficientn-octanol/water (logvalue)Vapour pressure 1 mm Hg ( 198.3 °C)2.43g/mLat 25°C(lit.)Density and/or relativedensityRelative vapour density no data availableParticle characteristics n o data available10.1Reactivityno data available10.2Chemical stabilitySlowly becomes yellow in air.10.3Possibility of hazardous reactionsBromine trifluoride reacts explosively with AMMONIUM BROMIDE [Mellor 2 Supp. 1:1651956].10.4Conditions to avoidno data available10.5Incompatible materialsIncompatible materials: Strong oxidizing agents, strong acids, strong bases, heavy metals,silver salts, potassium.10.6Hazardous decomposition productsno data availableAcute toxicity•Oral: LD50 Rat oral 2714 mg/kg bw•Inhalation: no data available•Dermal: no data availableSkin corrosion/irritationno data availableSerious eye damage/irritationno data availableRespiratory or skin sensitizationno data availableGerm cell mutagenicityno data availableCarcinogenicityno data availableReproductive toxicityno data availableSTOT-single exposureno data availableSTOT-repeated exposureno data availableAspiration hazardno data available12.1Toxicity•Toxicity to fish: LC50; Species: Lepomis macrochirus (Bluegill) weight 1.2 g; Conditions:freshwater, flow through; Concentration: 290 ug/L for 96 hr (95% confidence interval: 250-350ug/L) /99.9% purity•Toxicity to daphnia and other aquatic invertebrates: EC50; Species: Daphnia magna (Water Flea)age <24 hr; Conditions: freshwater, flow through; Concentration: 23 ug/L for 48 hr (95%confidence interval: 17-27 ug/L); Effect: intoxication, immobilization /99.9% purity•Toxicity to algae: EC50; Species: Pseudokirchneriella subcapitata (Green Algae); Conditions:freshwater, static; Concentration: 28 ug/L for 72 hr (95% confidence interval: 26-29 ug/L);Effect: decreased population abundance•Toxicity to microorganisms: no data available12.2Persistence and degradabilityno data available12.3Bioaccumulative potentialno data available12.4Mobility in soilno data available12.5Other adverse effectsno data available13.1Disposal methodsProductThe material can be disposed of by removal to a licensed chemical destruction plant or bycontrolled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed orseed by storage or disposal. Do not discharge to sewer systems.Contaminated packagingContainers can be triply rinsed (or equivalent) and offered for recycling or reconditioning.Alternatively, the packaging can be punctured to make it unusable for other purposes and thenbe disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possiblefor combustible packaging materials.14.1UN NumberADR/RID: Not dangerous goods.I MDG: Not dangerous goods.I ATA: Not dangerous good 14.2UN Proper Shipping NameADR/RID: unknownIMDG: unknownIATA: unknown14.3Transport hazard class(es)ADR/RID: Not dangerous goods.I MDG: Not dangerous goods.I ATA: Not dangerous good 14.4Packing group, if applicableADR/RID: Not dangerous goods.I MDG: Not dangerous goods.I ATA: Not dangerous good 14.5Environmental hazardsADR/RID: no IMDG: no IATA: no14.6Special precautions for userno data available14.7Transport in bulk according to Annex II of MARPOL 73/78 andthe IBC Codeno data available15.1Safety, health and environmental regulations specific for theproduct in questionInformation on revisionCreation Date Aug 12, 2017Revision Date Aug 12, 2017Abbreviations and acronyms•CAS: Chemical Abstracts Service•ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road•RID: Regulation concerning the International Carriage of Dangerous Goods by Rail•IMDG: International Maritime Dangerous Goods•IATA: International Air Transportation Association•TWA: Time Weighted Average•STEL: Short term exposure limit•LC50: Lethal Concentration 50%•LD50: Lethal Dose 50%•EC50: Effective Concentration 50%Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.。
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SAFETY DATA SHEETSAccording to Globally Harmonized System of Classification andLabelling of Chemicals (GHS) - Sixth revised edition1.Identification1.1GHS Product identifierProduct name sodium bromide1.2Other means of identificationProduct number-Other names Sodiumbomide1.3Recommended use of the chemical and restrictions on useIdentified uses For industry use only.Uses advised against no data available1.4Supplier's detailsCompanyAddressTelephoneFax1.5Emergency phone numberEmergency phone numberService hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMThours).2.1Classification of the substance or mixtureNot classified.2.2GHS label elements, including precautionary statementsPictogram(s)No symbol.Signal word No signal word.Hazard statement(s)nonePrecautionarystatement(s)Prevention noneResponse noneStorage noneDisposal none2.3Other hazards which do not result in classificationnone3.1Substances4.1Description of necessary first-aid measuresGeneral adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaledIf breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult aphysician.In case of skin contactWash off with soap and plenty of water. Consult a physician.In case of eye contactRinse thoroughly with plenty of water for at least 15 minutes and consult a physician.If swallowedNever give anything by mouth to an unconscious person. Rinse mouth with water. Consult aphysician.4.2Most important symptoms/effects, acute and delayedno data available4.3Indication of immediate medical attention and specialtreatment needed, if necessaryno data available5.1Extinguishing mediaSuitable extinguishing mediaUse water spray, alcohol-resistant foam, dry chemical or carbon dioxide.5.2Specific hazards arising from the chemicalno data available5.3Special protective actions for fire-fightersWear self-contained breathing apparatus for firefighting if necessary.6.1Personal precautions, protective equipment and emergency proceduresUse personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas.Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Forpersonal protection see section 8.6.2Environmental precautionsPrevent further leakage or spillage if safe to do so. Do not let product enter drains. Dischargeinto the environment must be avoided.6.3Methods and materials for containment and cleaning upPick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers fordisposal.7.1Precautions for safe handlingAvoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure -obtain special instructions before use.Provide appropriate exhaust ventilation at places wheredust is formed. For precautions see section 2.2.7.2Conditions for safe storage, including any incompatibilitiesStore in cool place. Keep container tightly closed in a dry and well-ventilated place.8.1Control parametersOccupational Exposure limit valuesno data availableBiological limit valuesno data available8.2Appropriate engineering controlsHandle in accordance with good industrial hygiene and safety practice. Wash hands beforebreaks and at the end of workday.8.3Individual protection measures, such as personal protectiveequipment (PPE)Eye/face protectionSafety glasses with side-shields conforming to EN166. Use equipment for eye protection testedand approved under appropriate government standards such as NIOSH (US) or EN 166(EU).Skin protectionWear impervious clothing. The type of protective equipment must be selected according to theconcentration and amount of the dangerous substance at the specific workplace. Handle withgloves. Gloves must be inspected prior to use. Use proper glove removal technique(withouttouching glove's outer surface) to avoid skin contact with this product. Dispose of contaminatedgloves after use in accordance with applicable laws and good laboratory practices. Wash anddry hands. The selected protective gloves have to satisfy the specifications of EU Directive89/686/EEC and the standard EN 374 derived from it.Respiratory protectionWear dust mask when handling large quantities.Thermal hazardsno data availablePhysical state white powderColour no data availableOdour no data availableMelting point/ freezing755°C(lit.)point200°C(lit.)Boiling point or initialboiling point and boilingrangeFlammability no data availableno data availableLower and upper explosionlimit / flammabilitylimitFlash point62°C(lit.)no data availableAuto-ignitiontemperatureDecompositionno data availabletemperaturepH no data availableKinematic viscosity no data availableSolubility In water:905 g/L (20 ºC) Partition coefficientno data availablen-octanol/water (logvalue)Vapour pressure 1 mm Hg ( 806 °C)3.203（25ºC）Density and/or relativedensityRelative vapour density no data available Particle characteristics n o data available10.1Reactivityno data available10.2Chemical stabilityStable under recommended storage conditions.10.3Possibility of hazardous reactionsno data available10.4Conditions to avoidno data available10.5Incompatible materialsno data available10.6Hazardous decomposition productsno data availableAcute toxicity•Oral: no data available•Inhalation: no data available•Dermal: no data availableSkin corrosion/irritationno data availableSerious eye damage/irritationno data availableRespiratory or skin sensitizationno data availableGerm cell mutagenicityno data availableCarcinogenicityno data availableReproductive toxicityno data availableSTOT-single exposureno data availableSTOT-repeated exposureno data availableAspiration hazardno data available12.1Toxicity•Toxicity to fish: no data available•Toxicity to daphnia and other aquatic invertebrates: no data available•Toxicity to algae: no data available•Toxicity to microorganisms: no data available12.2Persistence and degradabilityno data available12.3Bioaccumulative potentialno data available12.4Mobility in soilno data available12.5Other adverse effectsno data available13.1Disposal methodsProductThe material can be disposed of by removal to a licensed chemical destruction plant or bycontrolled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.Contaminated packagingContainers can be triply rinsed (or equivalent) and offered for recycling or reconditioning.Alternatively, the packaging can be punctured to make it unusable for other purposes and thenbe disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possiblefor combustible packaging materials.14.1UN NumberADR/RID: Not dangerous goods.I MDG: Not dangerous goods.I ATA: Not dangerous good 14.2UN Proper Shipping NameADR/RID: unknownIMDG: unknownIATA: unknown14.3Transport hazard class(es)ADR/RID: Not dangerous goods.I MDG: Not dangerous goods.I ATA: Not dangerous good 14.4Packing group, if applicableADR/RID: Not dangerous goods.I MDG: Not dangerous goods.I ATA: Not dangerous good 14.5Environmental hazardsADR/RID: no IMDG: no IATA: no14.6Special precautions for userno data available14.7Transport in bulk according to Annex II of MARPOL 73/78 andthe IBC Codeno data available15.1Safety, health and environmental regulations specific for theproduct in questionInformation on revisionCreation Date Aug 12, 2017Revision Date Aug 12, 2017Abbreviations and acronyms•CAS: Chemical Abstracts Service•ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road •RID: Regulation concerning the International Carriage of Dangerous Goods by Rail •IMDG: International Maritime Dangerous Goods•IATA: International Air Transportation Association•TWA: Time Weighted Average•STEL: Short term exposure limit•LC50: Lethal Concentration 50%•LD50: Lethal Dose 50%•EC50: Effective Concentration 50%Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.。