615EN (MSDS)-中文版
Benzene_MSDS_EN(苯的技术说明书)
Material Safety Data SheetMaterial Name: Benzene MSDS ID: NOVA-0011 Section 1 - Product and Company IdentificationSynonyms: Benzene, benzolChemical Name: BenzeneChemical Family: Aromatic hydrocarbonsMaterial Use: Petrochemical industry: Solvent, raw material for petrochemicalsChemical Formula: (C6H6)NOVA Chemicals EMERGENCY Telephone Numbers:P.O. Box 2518, Station M North America (Canada and US):Calgary, Alberta, Canada T2P 5C6 1-800-561-6682, 1-403-314-8767 (NOVA Chemicals) (24 hours)(CHEMTREC-USA) (24 hours)1-800-424-9300 Product Information: 1-412-490-4063 1-613-996-6666 (Canutec-Canada) (24 hours)Mexico and South America: +44 208 762 8322 (NCEC) (24 hours) MSDS Information Email:msdsemail@Section 2 - Hazards IdentificationHMIS Ratings: Health: 2* Fire: 3 Physical Hazard: 0 Personal Protection: chemical goggles, gloves, respirator,coverallsHazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazardNFPA Ratings: Health: 2 Fire: 3 Reactivity: 0Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = SevereEmergency OverviewDANGER! TOXIC! FLAMMABLE! CANCER HAZARD! Product is a clear liquid at room temperature with asweet, solvent-like odor. Vapor is heavier than air and may spread long distances. Distant ignition and flashbackare possible. Flammable liquid and vapor can accumulate static charge. Product will float on water and maytravel to distant locations and/or spread fire. This product is considered harmful by inhalation, by skin contact, andif it is swallowed. This product is irritating to the eyes and skin. Excessive inhalation may result in heartbeatirregularities and adverse central nervous system effects including headache, sleepiness, dizziness, nausea, lossof coordination, tremors, and in extreme conditions, coma and death. Systemic absorption effects may includelong-term damage to the blood-forming system, kidney and liver damage, and/or cancer (leukemia). Ingestionmay also cause adverse central nervous system effects, blood disorders, kidney and/or liver damage. Smallamounts, if aspirated into the lungs, may cause mild to severe pulmonary injury.Potential Health Effects: EyeContact with liquid and high concentrations of this product's vapors are irritating to the eyes.Potential Health Effects: SkinProduct may be rapidly absorbed through the skin. Prolonged and/or repeated skin contact may cause mild tosevere irritation/dermatitis and chemical blistering. Prolonged contact may also cause skin sensitization andsecondary skin infections.Potential Health Effects: IngestionThis product may be harmful if swallowed. Ingestion of this product may result in adverse central nervous systemeffects including headache, sleepiness, dizziness, nausea, loss of coordination, and in extreme conditions comaand/or death. Ingestion may also cause kidney and liver damage and blood disorders. Small amounts of thisproduct, if aspirated into the lungs, may cause mild to severe pulmonary injury.Potential Health Effects: InhalationThis product may be harmful if inhaled. Excessive inhalation may result in heartbeat irregularities and adversecentral nervous system effects including headache, sleepiness, dizziness, nausea, loss of coordination, and inextreme conditions, coma and death. Additional adverse inhalation effects may also include long-term damage toblood-forming system, kidney and liver damage, and/or cancer (leukemia). Small amounts of this product, ifaspirated into the lungs, may cause mild to severe pulmonary injury.Material Name: Benzene MSDS ID: NOVA-0011 Section 3 - Composition/Information on IngredientsCAS # Component Percent by Wt.71-43-2 Benzene 99.87-99.99Not Available Other hydrocarbons 0.01-0.10Not Available Other hydrocarbons 0.10-0.13 Additional Information* May include cyclohexane (CAS # 110-82-7), cyclohexene (CAS # 110-83-8) and/or toluene (CAS # 108-88-3) as impurities.The actual components and weight % concentrations vary based on operating conditions.This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).This material is a controlled product under Canadian WHMIS regulations.This material is regulated as a hazardous material / dangerous goods for transportation.See Section 8 for applicable exposure limits. See Section 11 for applicable toxicity data.Section 4 - First Aid MeasuresFirst Aid: EyesRemove contact lenses, if it can be done safely. Immediately flush eyes with water for at least 15 minutes, while holding eyelids open. Seek medical if symptoms develop or persist.First Aid: SkinRemove contaminated clothing and shoes. Wash immediately with soap and water. Seek medical attention if symptoms develop or persist. Completely decontaminate clothing, shoes and other protective equipment before reuse or discard.First Aid: InhalationMove affected individual to non-contaminated air. Loosen tight clothing such as a collar, tie, belt or waistband to facilitate breathing. Seek immediate medical attention if the individual is not breathing, is unconscious or if any other symptoms persist. WARNING: Contact through mouth-to-mouth resuscitation may pose a secondary risk to the rescuer. Avoid mouth-to-mouth contact by using a mouth shield or guard to perform artificial respiration.First Aid: IngestionDO NOT INDUCE VOMITING. Loosen tight clothing such as a collar, tie, belt or waistband. Seek immediatemedical attention.First Aid: Notes to PhysicianFor more detailed medical emergency support information call 1-800-561-6682 or 1-403-314-8767 (24 hours,NOVA Chemicals Emergency Response). Ensure thorough eye and skin decontamination. Treatunconsciousness, nausea, hypotension, seizures and cardiac arrhythmias in the conventional manner.Aspiration of this product during induced emesis can result in lung injury. If evacuation of stomach contents isconsidered necessary use the method least likely to cause aspiration, such as gastric lavage after protecting the airway. Observe hospitalized patients for delayed chemical pneumonia, acute tubular necrosis, encephalopathy and dysrhythmias. Monitor for urinary phenol within 72 hours of acute exposure.Section 5 - Fire Fighting MeasuresSee Section 9: Physical Properties for flammability limits, flash point and auto-ignition information.General Fire HazardsFire and container explosion hazards are serious when this product is exposed to heat or flame. Vapors areheavier than air and may travel along the ground to some distant source of ignition and flash back. Considerneed for immediate emergency isolation and evacuation for at least 300 meters (984 feet). If tank is involved in a fire, ISOLATE for 800 meters (1/2 miles) in all directions.Explosion HazardsVapors may form explosive mixture with air. Keep containers away from source of heat or fire. Containers may explode when involved in a fire. Evacuate personnel to a distance of at least 0.8 to 1.6 kilometers (1/2 mile) if a fire or rail car, tank car, or major vessel rupture is possible. This product may be a static accumulator which can form an ignitable vapor-air mixture in a storage tank.Material Name: Benzene MSDS ID: NOVA-0011 Hazardous Combustion ProductsUpon combustion, this product emits carbon monoxide, carbon dioxide, and/or low molecular weighthydrocarbons.Extinguishing MediaDry chemical, foam, carbon dioxide, and water spray or fog. Use water to cool fire-exposed containers and to protect personnel. Water may be an ineffective extinguishing medium. Use of an inert foam extinguishingmaterial may also assist in short term flammable vapor suppression. Monitor water run-off for flammability, and prevent entry into ditches, sewers, drains and, waterways, or other confined or underground spaces.Fire Fighting Equipment/InstructionsReference 2008 Emergency Response Guidebook, Guide # 130. Position upwind. Keep unnecessary personnel away. Move containers from fire area if you can do so without risk. Fight fire from maximum distance or useunmanned holders or monitor nozzles. Immediately withdraw in case of fire and container venting or heatdiscoloration of a container. Fire fighters should wear full-face, self-contained breathing apparatus and thermal protective clothing. Avoid inhaling any smoke and combustion materials. Remove and clean or destroy anycontaminated clothing. Cool containers with flooding quantities of water until well after the fire is out. Controlrunoff waters to prevent entry into ditches, sewers, drains, underground or confined spaces and waterways. Section 6 - Accidental Release MeasuresEvacuation ProceduresIsolate area. Keep unnecessary personnel away. Alert stand-by emergency and fire fighting personnel. Monitor surrounding area for build-up of flammable concentrations in air.Small SpillsEliminate ignition sources. Spill or leak area should be isolated immediately for 25 to 50 meters (82 to 164 feet) in all directions. Keep upwind and out of low areas. Stop discharge if safe to do so. Contain discharge by booming on water or diking on ground. Spills on water will volatilize rapidly, making containment or recovery difficult.Remove liquid material with non-sparking approved pumps, skimmers or vacuum equipment. Absorb/adsorbresidual materials and clean up with non-sparking tools. Prevent entry into ditches, sewers, drains, underground or confined spaces, water intakes and waterways. Shovel material with non-sparking tools into appropriatecontainer for disposal.Large SpillsConsider downwind evacuation for 300 meters (984 feet). Eliminate ignition sources. Keep upwind and out of low areas. Stop discharge if safe to do so. Contain liquids by booming on water or by diking on land to prevent entry into ditches, sewers, drains or waterways. Spills on water will volatilize rapidly, making containment or recovery difficult. Recover any pooled liquid material with approved, non-sparking pumps, skimmers or vacuumequipment. An inert foam cover material may assist in short term vapor suppression. Absorb with DRY earth, sand or other non-combustible material and clean up with non-sparking tools. Soil remediation may be required. Special ProceduresContact local police/emergency services and appropriate emergency telephone numbers provided in Section 1.Ensure that statutory and regulatory reporting requirements in the applicable jurisdiction are met. Wearappropriate protective equipment and clothing during cleanup. Individuals without appropriate protectiveequipment should be excluded from area of spill until cleanup has been completed.See Section 8 for recommended Personal Protective Equipment and see Section 13 for waste disposal considerations.Section 7 - Handling and StorageHandling ProceduresKeep locked up or secured. Handle in fully grounded, properly designed and approved equipment systems that are suitable for flammable liquids. Use with adequate ventilation. Do not ingest or inhale. Keep away from heat and ignition sources. No smoking or open flames permitted in storage, use, or handling areas. Dissipate static electricity during transfer by grounding and bonding containers and equipment. Bonding and grounding may be insufficient to eliminate the hazard from static-accumulating flammable liquids. For additional information onequipment bonding and grounding, refer to the American Petroleum Institute (API) Recommended Practice 2003, "Protection Against Ignitions Arising out of Static, Lightning, and Stray Currents" or National Fire ProtectionAssociation (NFPA) 77, "Recommended Practice on Static Electricity". Avoid draining or venting to atmosphere ifMaterial Name: Benzene MSDS ID: NOVA-0011 possible. Take special precautions when cold cutting or breaking into lines, or when cleaning and disposing of empty containers. Do not breathe product gas, fumes, vapor, or spray. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately. Avoid contact with skin and eyes.Keep away from incompatible materials such as oxidizing agents and acids. After handling, always wash hands thoroughly with soap and water.Storage ProceduresStorage area should be clearly identified, well-illuminated, clear of obstruction and accessible only to trained and authorized personnel. Adequate security must be provided so that unauthorized personnel do not have access to material. Store in grounded, properly designed vessels and away from incompatible materials. Store and use away from heat, sparks, open flame, or any other ignition source. Store according to applicable regulations for flammable materials for storage tanks, containers, piping, buildings, rooms, cabinets, allowable quantities and minimum storage distances. Use non-sparking ventilation systems, approved explosion-proof equipment, and intrinsically safe electrical systems. Have appropriate extinguishing capability in storage area (e.g. portable fire extinguishers (dry chemical, foam or carbon dioxide)) and flammable gas detectors. Keep absorbents for leaks and spills readily available. Consider use of internal floating roof tanks or flame arrestors. Inspect vents during winter conditions for vapor ice build-up. Storage tanks should be above ground and diked to hold entire contents.A refrigerated room is generally recommended for warehouse storage of materials with a flash point lower than37.8°C (100°F).See Section 8: Exposure Controls/Personal Protection for appropriate Personal Protective Equipment. See Section 10 for information onIncompatibilities.Section 8 - Exposure Controls / Personal ProtectionExposure GuidelinesA: General Product InformationRefer to published exposure limits - use effective control measures and PPE to maintain worker exposure toconcentrations that are below these limits. Ensure that eyewash stations and safety showers are in closeproximity to work locations.B: Component Exposure LimitsACGIH, OSHA, NIOSH, EPA, Alberta, and Ontario exposure limit lists have been checked for major components listed with CAS registry numbers. Other exposure limits may apply, check with proper authorities.*Note: The Vacated OSHA Permissible Exposure Limits (PELs) are those provided in the 1989 update to OSHA's Air Contaminants Standard 29 CFR 1910.1000. These limits were vacated by the U.S. Court of Appeals,Eleventh Circuit but may be enforceable in some states.Benzene (71-43-2)ACGIH: 0.5 ppm TWA; 1.6 mg/m3 TWA; 2.5 ppm STEL; 8 mg/m3 STEL; BEISkin - potential significant contribution to overall exposure by the cutaneous route OSHA (Vacated)*: 0.5 ppm Action Level; 1 ppm TWA; 5 ppm STEL (Cancer hazard, Flammable - see 29 CFR1910.1028)OSHA Final: 0.5 ppm Action Level; 1 ppm TWA; 5 ppm STEL (Cancer hazard, Flammable - see 29 CFR1910.1028); 1 ppm TWA; 10 ppm TWA (applies to industry segments exempt from the benzenestandard at 29 CFR 1910.1028); 5 ppm STEL (see 29 CFR 1910.1028); 25 ppm Ceiling (appliesto industry segments exempt from the 1 ppm TWA and 5 ppm STEL of the benzene standard) NIOSH: 0.1 ppm TWA; 0.32 mg/m3 TWA; 1 ppm STEL; 3.2 mg/m3 STEL500 ppm IDLHAlberta: 0.5 ppm TWA; 1.6 mg/m3 TWA; 2.5 ppm STEL; 8 mg/m3 STELSubstance may be readily absorbed through intact skinOntario: 0.5 ppm TWAEV (applies to workplaces to which the designated substance regulation does notapply); 0.5 ppm TWAEV (designated substance regulation)2.5 ppm STEV (applies to workplaces to which the designated substance regulation does notapply); 2.5 ppm STEV (designated substances regulation)Material Name: Benzene MSDS ID: NOVA-0011 Cyclohexane (110-82-7)ACGIH: 100 ppm TWA; 344 mg/m3 TWAOSHA (Vacated)*: 300 ppm TWA; 1050 mg/m3 TWAOSHA Final: 300 ppm TWA; 1050 mg/m3 TWANIOSH: 300 ppm TWA; 1050 mg/m3 TWA1300 ppm IDLHAlberta: 300 ppm TWA; 1030 mg/m3 TWAOntario: 100 ppm TWAEVCyclohexene (110-83-8)ACGIH: 300 ppm TWA; 1010 mg/m3 TWAOSHA (Vacated)*: 300 ppm TWA; 1015 mg/m3 TWAOSHA Final: 300 ppm TWA; 1015 mg/m3 TWANIOSH: 300 ppm TWA; 1015 mg/m3 TWA2000 ppm IDLHAlberta: 300 ppm TWA; 1010 mg/m3 TWAOntario: 300 ppm TWAEV; 1010 mg/m3 TWAEVToluene (108-88-3)ACGIH: 20 ppm TWA; 75 mg/m3 TWA; BEIOSHA (Vacated)*: 100 ppm TWA; 375 mg/m3 TWA; 150 ppm STEL; 560 mg/m3 STELOSHA Final: 200 ppm TWA; 300 ppm CeilingNIOSH: 100 ppm TWA; 375 mg/m3 TWA; 150 ppm STEL; 560 mg/m3 STEL500 ppm IDLHAlberta: 50 ppm TWA; 188 mg/m3 TWASubstance may be readily absorbed through intact skinOntario: 20 ppm TWAEV (also known as methylbenzene)ENGINEERING CONTROLSEngineering methods to reduce hazardous exposure are preferred controls. Methods include mechanicalventilation (dilution and local exhaust) process or personal enclosure, remote and automated operation, control of process conditions, leak detection and repair systems, and other process modifications. Ensure all exhaustventilation systems are discharged to outdoors, away from air intakes and ignition sources. Supply sufficientreplacement air to make up for air removed by exhaust systems. Administrative (procedure) controls and use of personal protective equipment may also be required.PERSONAL PROTECTIVE EQUIPMENTPersonal Protective Equipment: Eyes/FaceWear safety glasses; chemical goggles are recommended to prevent eye irritation or injury from splashing orvapors.Personal Protective Equipment: Skin/Hands/FeetUse chemically resistant gloves when handling product. Wear chemical-resistant safety footwear with goodtraction to prevent slipping. Work clothing that sufficiently prevents skin contact should be worn, such as coveralls and/or long sleeves and pants. If splashing or contact with liquid material is possible, consider the need for an impervious overcoat. Fire resistant (i.e., Nomex) or natural fiber clothing (i.e., cotton or wool) is recommended.Synthetic clothing can generate static electricity and is not recommended where a flammable vapor release may occur. Static Dissipative (SD) rated footwear is recommended.Personal Protective Equipment: RespiratoryIf engineering controls and ventilation are not sufficient to control exposure to below the allowable limits then an appropriate NIOSH/MSHA approved air-purifying respirator or self-contained breathing apparatus (SCBA) should be used. Supplied air breathing apparatus must be used when oxygen concentrations are low or if airborneconcentrations exceed the limits of the air-purifying respirators.Personal Protective Equipment: GeneralPersonal protective equipment (PPE) should not be considered a long-term solution to exposure control.Employer programs to properly select, fit, maintain, and train employees to use equipment must accompany PPE.Consult a competent industrial hygiene resource, the PPE manufacturer's recommendation, and/or applicable regulations to determine hazard potential and ensure adequate protection.Material Name: Benzene MSDS ID: NOVA-0011 Section 9 - Physical & Chemical PropertiesPhysical State andAppearance:Liquid Color: ColorlessOdor: Sweet, solvent-like Odor Threshold: 1.5 to 5 ppmpH: Not applicable Vapor Pressure: 75 mm Hg at 20°C (68°F)Vapor Density @ 0°C(Air=1): 2.8 Dispersion Properties: Is not dispersed in cold or hotwater.Boiling Point: 80°C (176°F) Melting Point: 5.5°C (41.9°F) Solubility (H2O): Slightly soluble (0.1- 0.3%),rapidly volatilizesSpecific Gravity (Water=1): 0.88 at 15°C (59°F)Ionicity (in water): Not applicable Evaporation Rate (n-ButylAcetate=1):Not availableOctanol/H2O Coeff.: Kow = 2.13 Percent Volatile: 100% Auto Ignition: 498°C (928°F) (benzene) Flash Point: -11°C (12°F) (benzene)Flash Point Method: Closed cup Upper Flammable Limit(UFL): 7.8% (volume/volume) (benzene)Lower Flammable Limit(LFL): 1.2 % (volume/volume)(benzene)Flammability Classification: FlammableSection 10 - Stability & Reactivity InformationChemical StabilityThis product is stable under normal use conditions for shock, vibration, pressure, or temperature.Chemical Stability: Conditions to AvoidKeep away from heat, sparks, or open flame.IncompatibilityReactive with oxidizing agents, acids and halogens. May attack some forms of plastics, rubbers and coatings.Vapors may form explosive mixture with air.Hazardous PolymerizationNot likely to occur.CorrosivityNot considered to be corrosive.Hazardous DecompositionUpon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weighthydrocarbons.Section 11 - Toxicological InformationA: Acute Toxicity - General Product InformationBenzene may cause corneal injury to the eye. It is also a skin irritant that may be absorbed through the skin in harmful amounts. Inhalation of benzene can irritate the respiratory tract and may result in central nervous system (CNS) depression and possible death due to respiratory failure. Ingestion and subsequent aspiration into thelungs may cause chemical pneumonitis.B: Component Analysis - LD50/LC50Benzene (71-43-2)Inhalation LC50 Rat: 13,050-14,380 ppm/4H; Oral LD50 Rat: 1800 mg/kgCyclohexane (110-82-7)Inhalation LC50 Rat: 13.9 mg/L/4H; Oral LD50 Rat: >5000 mg/kg; Dermal LD50 Rabbit: >2000 mg/kgCyclohexene (110-83-8)Oral LD50 Rat: 2400 µL/kgToluene (108-88-3)Inhalation LC50 Rat: 12.5 mg/L/4H; Inhalation LC50 Rat: >26,700 ppm/1H; Oral LD50 Rat: 636 mg/kg; Dermal LD50 Rabbit: 8390 mg/kg; Dermal LD50 Rat: 12,124 mg/kgMaterial Name: Benzene MSDS ID: NOVA-0011 C: Chronic Toxicity - General Product InformationProlonged and/or repeated exposure can cause drying and scaling of the skin. Long-term exposure has been associated with certain types of leukemia in humans. IARC and OSHA consider benzene to be a humancarcinogen. EPA has classified benzene as a Group A, known human carcinogen. Chronic exposure to benzene has been reported to cause bone marrow abnormalities and adverse blood effects including anemia. Progressive deterioration of hematopoietic function expressed as a decrease in absolute lymphocyte count is the mostsensitive indicator of benzene exposure. Benzene may cause fetotoxicity and teratogenicity. Chromosomalaberrations have been noted in animal tests.D: Chronic Toxicity – Carcinogenic EffectsACGIH, EPA, IARC, OSHA, and NTP carcinogen lists have been checked for selected similar materials or those components with CAS registry numbers.Benzene (71-43-2)ACGIH: A1 - Confirmed Human CarcinogenOSHA: 0.5 ppm Action Level; 1 ppm TWA; 5 ppm STEL (Cancer hazard, Flammable - see 29 CFR1910.1028)EPA: Classification: known human carcinogen for all routes of exposureNTP: Known Human Carcinogen (Select Carcinogen)IARC: Supplement 7 [1987], Monograph 29 [1982] (Group 1 (carcinogenic to humans))Toluene (108-88-3)ACGIH: A4 - Not Classifiable as a Human CarcinogenEPA: Classification: under the Guidelines for Carcinogen Risk Assessment (U.S. EPA, 2005), there isinadequate information to assess the carcinogenic potential of toluene.IARC: Monograph 71 [1999], Monograph 47 [1989] (Group 3 (not classifiable))E: Special Remarks on Chronic EffectsBenzene may pose a cancer hazard and may cause adverse birth and reproductive effects. Bone marrowabnormalities, leukemia, multiple myelomas, fetotoxicity, teratogenicity (ex. encephaly, angulated ribs and dilated brain ventricles) have been linked to benzene exposure.Section 12 - Ecological InformationEcotoxicityA: General Product InformationProduct is largely insoluble in water, and evaporates rapidly. Product has moderate absorption into soil andsediment. It is considered toxic to fish.B: Component Analysis - Ecotoxicity - Aquatic ToxicityBenzene (71-43-2)Test & Species Conditions96 Hr LC50 Pimephales promelas 12.6 mg/L flow-through96 Hr LC50 Oncorhynchus mykiss 5.3 mg/L flow-through96 Hr LC50 Lepomis macrochirus 22 mg/L static96 Hr LC50 Poecilia reticulata 28.6 mg/L static72 Hr EC50 Selenastrum capricornutum 29 mg/L48 Hr EC50 water flea 356 mg/L static48 Hr EC50 Daphnia magna 10 mg/LCyclohexane (110-82-7)Test & Species Conditions96 Hr LC50 Pimephales promelas 4.53 mg/L flow-through96 Hr LC50 Lepomis macrochirus 34.72 mg/L96 Hr LC50 Poecilia reticulata 48.0 mg/L72 Hr EC50 Scenedesmus subspicatus >500 mg/L5 min EC50 Photobacterium phosphoreum 85.5 mg/L10 min EC50 Photobacterium phosphoreum 93 mg/L48 Hr EC50 water flea 400.0 mg/LMaterial Name: Benzene MSDS ID: NOVA-0011 Toluene (108-88-3)Test & Species Conditions96 Hr LC50 Pimephales promelas 25 mg/L 1 day old96 Hr LC50 Oncorhynchus mykiss 24.0 mg/L flow-through96 Hr LC50 Lepomis macrochirus 24.0 mg/L static96 Hr LC50 Lepomis macrochirus 13 mg/L static96 Hr EC50 Selenastrum capricornutum >433 mg/L30 min EC50 Photobacterium phosphoreum 19.7 mg/L48 Hr EC50 water flea 11.3 mg/L48 Hr EC50 water flea 310 mg/L48 Hr EC50 Daphnia magna 11.3 mg/LEnvironmental Fate/MobilityWhen released to soil or water, product will rapidly begin to volatilize. At 20°C (68°F) and moderate wind speeds, the evaporation rate for benzene is calculated to be over 2 g per m2 per sec. At 0°C (32°F) and moderate wind speeds, the evaporation rate is calculated to drop to below 0.1 g per m2 per sec. And at a warmer temperature of 30°C, the evaporation rate increases to over 3 g per m2 per sec. Benzene migrates in soils and in ground waters.Its airborne levels of benzene can be reduced by rain or water spray.Persistence/DegradabilityBenzene in air will photo-degrade with a calculated half-life of 13.4 days. This is accelerated in pollutedatmospheres containing nitrogen or sulfur oxides. By-products include phenol, nitrophenols, nitrobenzene, formic acid and peroxyacetyl nitrate. Benzene will biodegrade in soils and ground waters (half-life 16-28 days) underaerobic conditions. Limited degradation occurs under anaerobic conditions. Sewage treatment plants have been shown to remove 44-100%.Bioaccumulation/AccumulationBenzene has a reported Kow = 2.13. Metabolites may partially bioaccumulate in fatty fish tissues liver and brain. Ecological SummaryThe high volatility and water solubility of benzene suggests that readily available benzene will partition to theatmosphere from the surface of water and soil within seven days. Estimated volatization half-life of benzene for soil was 7.2 to 38.4 days (Jury, WA et al., 1984). Benzene that does not evaporate will be highly to very highlymobile in the soil and may leach down into the ground water. Benzene may be subject to biodegradation based on reported biodegradation of 24% and 47% of the initial 20 ppm benzene in a base-rich, para-brownish soilwithin 1 to 10 weeks. Half-life of volatization from a model river 1m deep, was 2.7 hours at 20°C (68°F). In theatmosphere, benzene will exist predominantly in the vapor phase. It will react with oxygen photochemically toproduce hydroxyl radicals with a half-life of 13.4 days. Products of photo-oxidation include phenol, nitrophenols, nitrobenzene, formic acid and peroxyacetyl nitrate. Based on the reported and estimated BCF, benzene is notexpected to bioconcentrate in aquatic organisms.Section 13 - Disposal ConsiderationsU.S./Canadian Waste Number & DescriptionsA: General Product InformationThis product is known to be a hazardous waste according to US RCRA and Canadian regulations. The use,mixing or processing of this product may alter this product. Contact federal, provincial/state and local authorities in order to generate or ship a waste material associated with this product to ensure materials are handledappropriately and meet all criteria for disposal of hazardous waste. DO NOT ATTEMPT TO DISPOSE OF BYUNCONTROLLED IGNITION. Since emptied containers retain product/material residue, follow safehandling/label warnings even after container is emptied.See Section 7: Handling and Storage and Section 8: Exposure Controls/Personal Protection for additional handling information that may be applicable for safe handling and the protection of employees.Waste generator is advised to carefully consider hazardous properties and control measures needed for othermaterials that may be found in the waste.。
MSDS危险化学品安全技术说明书——61629--己腈、戊基腈
化学品安全技术说明书第一部分化学品及企业标识化学品中文名：己腈；戊基氰化学品英文名：hexanenitrile；amyl cyanide企业名称：生产企业地址：邮编: 传真:企业应急电话：电子邮件地址：技术说明书编码:第二部分成分/组成信息√纯品混合物有害物成分浓度CAS No.己腈628-73-9第三部分危险性概述危险性类别：第6.1类毒害品侵入途径：吸入、食入、经皮吸收健康危害：腈类化合物能析出氰离子，抑制细胞呼吸，造成组织缺氧。
蒸气或雾对眼、粘膜和上呼吸道有刺激性。
环境危害：对环境有害。
燃爆危险：易燃，其蒸气与空气混合，能形成爆炸性混合物。
第四部分急救措施皮肤接触：立即脱去污染的衣着，用流动清水或5%硫代硫酸钠溶液彻底冲洗。
如出现中毒症状给予吸氧和吸入亚硝酸异戊酯，将亚硝酸异戊酯的安瓿放在手帕里或单衣内打碎放在面罩内使伤员吸入15秒，然后移去15秒，重复5-6次。
口服4-DMAP（4-二甲基氨基苯酚）1片（180毫克）和PAPP（氨基苯丙酮）1片（90毫克）。
如有不适感，就医。
眼睛接触：提起眼睑，用流动清水或生理盐水冲洗。
如有不适感，就医。
吸入：迅速脱离现场至空气新鲜处。
保持呼吸道通畅。
如呼吸困难，给输氧。
呼吸、心跳停止，立即进行人工呼吸（勿用口对口）和胸外心脏按压术。
如果出现中毒症状，处理同皮肤接触。
食入：如伤者神志清醒，催吐，洗胃。
如果出现中毒症状，处理同皮肤接触。
第五部分消防措施危险特性：遇明火能燃烧。
遇高热分解释出剧毒的气体。
与氧化剂可发生反应。
有害燃烧产物：一氧化碳、氮氧化物。
灭火方法：用泡沫、干粉、二氧化碳、砂土灭火。
灭火注意事项及措施：消防人员必须佩戴空气呼吸器、穿全身防火防毒服，在上风向灭火。
喷水冷却容器，可能的话将容器从火场移至空旷处。
处在火场中的容器若已变色或从安全泄压装置中产生声音，必须马上撤离。
禁止使用酸碱灭火剂。
第六部分泄漏应急处理应急行动：根据液体流动和蒸气扩散的影响区域划定警戒区，无关人员从侧风、上风向撤离至安全区。
(完整版)MSDS-多元醇-中文版
多元醇聚合物产品/化学名称: 多元醇聚合物(99.5%)别名: 聚醇毒性分级:低毒。
急性毒性：口服- 大鼠LD50: 34900 毫克/ 公斤; 口服-小鼠LD50: 20700 毫克/公斤刺激数据:皮肤- 兔500 毫克中度; 眼睛-兔60 毫克中度可燃性危险特性:遇明火、高温、强氧化剂可燃; 燃烧排放刺激烟雾皮肤接触：脱去污染的衣着，用流动清水冲洗。
如有不适感，就医。
眼睛接触：提起眼睑，用流动清水或生理盐水冲洗。
如有不适感，就医。
吸入：脱离现场至空气新鲜处。
如呼吸困难，给输氧。
就医。
食入：饮足量温水，催吐。
就医危险特性：遇明火、高热可燃。
有害燃烧产物：一氧化碳。
灭火方法：用雾状水、泡沫、干粉、二氧化碳、砂土灭火。
灭火注意事项及措施：消防人员须佩戴防毒面具、穿全身消防服，在上风向灭火。
尽可能将容器从火场移至空旷处。
喷水保持火场容器冷却，直至灭火结束。
处在火场中的容器若已变色或从安全泄压装置中产生声音，必须马上撤离。
总说明：需用第8 部分所述合适的个人保护装备。
溢出/泄漏: 用一些惰性材料吸附（例如蛭石、是沙子或土）到适当的容器中，并用不产生火花的工具移走所有的火源.。
抑制蒸汽泡沫可以降低蒸汽挥发。
处理方法: 处理完毕，在通风良好的地方用水冲洗。
避免接触到眼睛、皮肤以及衣物。
空储罐内有残留的产品（气体或液体或者是两者皆有），十分危险。
采取提前预警的办法来避免静电产生的放电火化。
保证储罐密封，避免同热、火花以及火焰接触。
同时避免提取和吸入。
不要对储罐加压、切割、焊接、钻孔、碾磨或是是指暴露在热、火花和明火下。
储藏: 远离热源、火花和火焰。
储存在密闭的容器中，存放在干燥的通风良好并远离反应物质的地方。
工程控制因素:使用大量的总体通风或者局域防爆通风装置来保持其浓度在可接受等级内。
个人防护设备：眼睛: 配戴OSHA中29 CFR 1910.133条和《欧洲标准》中EN166条里《眼睛和面部防护规则》中所述一般作业保护镜或护目镜。
MSDS 中文
MSDS 中文模块 1. 化学品1.1 产品标识符: 3-氨基-1-金刚烷醇产品名称1.2 鉴别的其他方法无数据资料1.3 有关的确定了的物质或混合物的用途和建议不适合的用途仅用于研发。
不作为药品、家庭或其它用途。
模块 2. 危险性概述2.1 GHS-分类皮肤刺激(类别2)眼睛刺激(类别2A)特异性靶器官系统毒性（一次接触）(类别3)2.2 GHS 标记要素，包括预防性的陈述象形图警示词警告危险申明H315 造成皮肤刺激。
H319 造成严重眼刺激。
H335 可能引起呼吸道刺激。
警告申明预防措施P261 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾.P264 操作后彻底清洁皮肤。
P271 只能在室外或通风良好之处使用。
P280 穿戴防护手套/ 眼保护罩/ 面部保护罩。
事故响应P302 + P352 如果皮肤接触：用大量肥皂和水清洗。
P304 + P340 如吸入: 将患者移到新鲜空气处休息，并保持呼吸舒畅的姿势。
P305 + P351 + P338 如与眼睛接触，用水缓慢温和地冲洗几分钟。
如戴隐形眼镜并可方便地取出，取出隐形眼镜，然后继续冲洗.P312 如感觉不适，呼救中毒控制中心或医生.P321 具体处置（见本标签上提供的急救指导）。
P332 + P313 如觉皮肤刺激：求医/就诊。
P337 + P313 如仍觉眼睛刺激：求医/就诊。
P362 脱掉沾污的衣服，清洗后方可再用。
安全储存P403 + P233 存放于通风良的地方。
保持容器密闭。
P405 存放处须加锁。
废弃处置P501 将内容物/ 容器处理到得到批准的废物处理厂。
2.3 其它危害物- 无模块 3. 成分/组成信息3.1 物质: C10H17NO分子式: 167.25 g/mol分子量组分浓度或浓度范围1-Amino-3-hydroxy adamantane<=100%化学文摘登记号(CAS 702-82-9No.)模块 4. 急救措施4.1 必要的急救措施描述一般的建议请教医生。
铝锭MSDS 中文
安全技术说明书(MSDS)第1部分产品及企业标识产品名称:铝锭HS编码：型号：无资料。
商标: 无资料。
制造商:平阴鑫盛铝业有限公司???地址:中国山东省平阴县榆山街道科技孵化园邮编:250400电话:+传真：+紧急情况联系联系人:孔祥明电话：+传真：+手机：+第2部分危险标识物质或混合物的分类：GHS分类根据化学品分类和标签系列规范（GB30000.2-29），该产品本品不是危险物质或混合物。
正常使用下，对健康或环境无显着的危害。
标签要素危险性象形图：无。
信号词：无。
危险说明：无。
防范说明：无。
其他危害：不能与水混合。
火灾产生有毒烟雾。
第3部分成分/组成信息化学品名称CAS号含量%铝7429-90-5 100第4部分急救措施皮肤接触: 用流动清水（如果可能，用肥皂）冲洗皮肤和头发。
如有刺激感，请教医生。
眼睛接触: 不要尝试去除黏附于或已包埋于眼睛里的微粒。
立即寻求紧急医疗协助或急送医院救治。
吸入: 如果吸入烟气，气溶胶或燃烧产物，将患者转移出污染区。
食入: 一般不适用。
第5部分消防措施适当的灭火介质：金属粉尘引起的火灾需要用沙子、惰性干粉灭火器灭火。
禁止用水、二氧化碳(CO2)或泡沫灭火器灭火。
产生的具体危害：虽然通常认为金属粉是不可燃的，但当粉末很细且提供高能量时都能燃烧。
与水接触可能发生爆炸性反应。
可以被摩擦、热、火星或明火点燃。
金属粉尘火灾的移动速度慢，但火势强烈且难以扑救。
强热下会燃烧。
不得扰动正在燃烧的粉尘。
如果粉尘被搅动形成云雾状，可能引起爆炸，应避免使氧(气)窜到大的热金属表面。
当加热(受热)时，容器可能爆炸。
粉尘和烟雾可与空气形成爆炸性混合物。
火灾扑灭后可能会复燃。
火灾中产生的气体可能是有毒的、腐蚀性的或刺激性的。
不得用水或泡沫灭火，因为可能产生爆炸性的氢气。
消防人员的特殊防护：佩戴自给正给式呼吸器和全副防护工具。
第6部分泄露应急处理个人防护措施，防护用具，紧急措施：避免吸入粉尘，避免接触皮肤和眼睛。
欧盟 MSDS中文模板
安全数据表名称XXX第1部分：化学品及企业标识1.1 产品标识符：产品名称：SDS编号：原料：商品条形码编号：产品类型：产品使用：客户供应商：中国制造商: XX公司地址:邮编:电话:传真:网址:毒物信息联系：第2部分：危害识别2.1 物质或混合物分类物质/混合物：根据（EC）No 1272/2008[CLP/GHS]规定分类急性毒性 4，H302皮肤过敏 2，H315眼睛刺激 2，H319有关以上声明的R短语或H陈述的全文，请参见第16节。
有关健康影响和症状的更多详细信息，请参见第11节。
2.2 标记组成危险象形图：标志词：危险说明：防范说明：总体：如果需要医药方面的建议，请随手带上产品和标签。
请将本品放在儿童不能接触到的地方预防措施：事故响应：误吞：进入眼睛：如果眼睛刺激持续存在：贮存条件：不适用处置方式：不适用危险成分：补充信息：不适用特殊包装要求：装有儿童安全紧固件的容器：不适用接触危险警告：适用2.3 其他危害其他不在分类内的危害：未知附加信息：第3部分：成分/组成信息物质/混合物：混合物欧盟法规（REACH）1907/2006附件14-需授权的物质清单附件14没有列出任何组件高度关注的物质没有列出任何组件附件17-限制生产、销售和使用某些危险物质，混合物和物品：不适用。
在供应商当前的知识范围内，没有适用的浓度范围内的其他成分被分类为对健康或环境有害，为PBT或vPvB物质，或已被指定为工作场所暴露极限，因此需要在本节中进行报告。
类型[1]具有健康或环境危害的物质[2]具有工作场所暴露极限的物质[3]物质符合法规（EC）第1907/2006号附件XIII的PBT标准。
[4]物质符合法规（EC）第1907/2006号附件XIII的vPvB标准[5]同等影响的物质职业暴露限制（如果有的话）在第8部分中列出。
第4部分：急救措施4.1急救措施说明眼睛接触：吸入后：皮肤接触：食入：保护急救人员：4.2 最重要的症状和影响，包括急性的和延迟的潜在的急性健康影响眼睛接触：吸入：皮肤接触：食入：过度接触征兆/症状眼睛接触：不良症状可能包括以下几种：吸入：皮肤接触：不良症状可能包括以下几种：食入：4.3 指示需要立即就医和特殊治疗措施给医生的说明：特殊治疗措施：第5部分：消防措施5.1 灭火剂适合的灭火剂：不适合的灭火剂：5.2 物质或混合物产生的特殊危害：物质或混合物的危害：有害的热分解产物：分解产物可能包括以下物质：5.3 给消防员的建议消防人员的特殊防护措施：发生火灾时，应将所有人员撤离事故现场，以迅速隔离现场。
甲基庚烯酮-安全技术说明书MSDS
第一部分化学品及企业标识化学品中文名：甲基庚烯酮化学品英文名：6-methylhept-5-en-2-oneCASNo.：110-93-0分子式：C8H14O产品推荐及限制用途：主要用以配制香蕉、梨、柑橘和浆果类香精。
但很少直接作为香料,而用来作为合成香料的原料。
第二部分危险性概述紧急情况概述易燃液体和蒸气。
GHS危险性类别易燃液体类别3标签要素：象形图：警示词：警告危险性说明：H226 易燃液体和蒸气●预防措施：——P210 远离热源/火花/明火/热表面。
禁止吸烟。
——P233 保持容器密闭。
——P240 容器和装载设备接地/等势联接。
——P241 使用防爆的电气/通风/照明/设备。
——P242 只能使用不产生火花的工具。
——P243 采取防止静电放电的措施。
——P280 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
●事故响应：——P303+P361+P353 如皮肤(或头发)沾染：立即脱掉所有沾染的衣服。
用水清洗皮肤/淋浴。
——P370+P378 火灾时：使用灭火器灭火。
●安全储存：——P403+P233 存放在通风良好的地方。
保持容器密闭。
——P405 存放处须加锁。
●废弃处置：—— P501按当地法规处置内装物/容器。
物理和化学危险：无资料。
健康危害：吞咽会中毒。
造成皮肤刺激。
造成严重眼刺激。
可引起呼吸道刺激。
环境危害：无资料。
第三部分成分/组成信息√物质混合物第四部分急救措施急救：吸入：如果吸入，请将患者移到新鲜空气处。
皮肤接触：脱去污染的衣着，用肥皂水和清水彻底冲洗皮肤。
如有不适感，就医。
眼睛接触：分开眼睑，用流动清水或生理盐水冲洗。
立即就医。
食入：漱口，禁止催吐。
立即就医。
对保护施救者的忠告：将患者转移到安全的场所。
咨询医生。
出示此化学品安全技术说明书给到现场的医生看。
对医生的特别提示：无资料。
第五部分消防措施灭火剂：用水雾、干粉、泡沫或二氧化碳灭火剂灭火。
避免使用直流水灭火，直流水可能导致可燃性液体的飞溅，使火势扩散。
苊安全技术说明书MSDS
化学品安全技术说明书第一部分化学品及企业标识化学品中文名：苊化学品英文名：acenaphthylene|1,2-dihydroacenaphthylene化学品别名：萘乙环CAS No.：83-32-9EC No.：201-469-6分子式：C12H10产品推荐用途：请咨询生产商。
产品限制用途：请咨询生产商。
第二部分危险性概述| 紧急情况概述固体。
易燃，其粉体与空气混合，能形成爆炸性混合物。
对水生物有剧毒, 使用适当的容器, 以预防污染环境。
对水生环境可能会引起长期有害作用。
使用适当的容器, 以预防污染环境。
| GHS 危险性类别根据 GB 30000-2013 化学品分类和标签规范系列标准（参阅第十六部分），该产品分类如下：易燃固体，类别 2；危害水生环境-急性毒性，类别 1；危害水生环境-慢性毒性，类别 1。
| 标签要素象形图警示词：警告危险信息：易燃固体，对水生生物毒性极大，对水生生物毒性极大并具有长期持续影响。
防范说明预防措施：远离热源、热表面、火花、明火以及其它点火源。
禁止吸烟。
容器和接收设备接地和等势联接。
避免释放到环境中。
戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
事故响应：收集溢出物。
安全储存：不适用。
废弃处置：按照地方/区域/国家/国际规章处置内装物/容器。
| 危害描述物理化学危险遇火或摩擦可被引燃，其粉体与空气混合，能形成爆炸性混合物。
健康危害吸入该物质可能会引起对健康有害的影响或呼吸道不适。
意外食入本品可能对个体健康有害。
通过割伤、擦伤或病变处进入血液，可能产生全身损伤的有害作用。
眼睛直接接触本品可导致暂时不适。
环境危害本品对水生生物毒性极大。
本品对水生生物毒性极大并具有长期持续影响。
请参阅 SDS 第十二部分。
第三部分成分/组成信息第四部分急救措施| 急救措施描述一般性建议：急救措施通常是需要的，请将本 SDS 出示给到达现场的医生。
皮肤接触：立即脱去污染的衣物。
用大量肥皂水和清水冲洗皮肤。
DANSUK稳定剂MSDS中文翻译
化学品安全说明书第一部分化学品与企业标识-公司：DANSUK 工业有限公司705, DA-SHIWHA INDUSTRIAL COMPLEX 1239-5 JEONGWANG-DONG SHIHEUNG-CITY KYONGGI-DO 韩国-电话 : 82-31-488-0740-传真: 82-31-499-3909-电子邮件-化学物品名称 : LGK16N (PVC稳定剂)-产品类型及用途 : 粉末状-生产日期 : 2015年1月30号-修订日期：无第二部分危险性概述有害风险分类：无可用信息标签元素：有害不导致分类的其他有害危险:无可用信息第三部分成分/组成信息化学物品名称：LGK16N (PVC稳定剂)成分：100%第四部分急救措施吸入：如果吸入，去除新鲜空气。
如果呼吸变得困难，请医生。
皮肤接触：在接触的情况下，立即清洗皮肤，用肥皂和大量的水。
眼睛接触：如接触眼睛，用大量的水冲洗至少15分钟。
用手指将眼睑分开，保证充分的冲洗。
打电话给医师。
摄入：如果吞下,用水冲洗口若人是有意识的。
打电话给医生。
第五部分消防措施-火灾和爆炸危险粉尘潜力:这种材料,像大多数材料粉末形式一样,能够创造一个粉尘爆炸-灭火介质适合:喷水。
二氧化碳、干粉粉或适当的泡沫-消防戴自给式呼吸器和防护服,以防止与皮肤和眼睛接触第六部分泄露应急处理-个人预防措施过程找到适当的措施,尽量减少与皮肤或眼睛直接接触,防止吸入的尘埃。
-处理方法打扫，放在一个袋子里，把垃圾处理掉。
避免扬起灰尘。
处理完成后通风和处理泄露的现场第七部分操作处置与储存-处理：安全操作说明:避免吸入。
避免接触眼睛、皮肤和衣服。
避免长时间或反复接触。
-贮存：储存条件:保持密封状态。
第八部分接触控制/个体防护工程控制：安全淋浴和洗眼器。
机械排风。
一般卫生措施：接触后彻底洗净个人防护装备：呼吸防护：使用政府测试和批准下适当的呼吸器和组件。
标准如NIOSH（美国）或CEN（欧盟）。
化学品安全技术说明书(MSDS)中英文对照及翻译完整版
化学品安全技术说明书(MSDS)中英文对照及翻译完整版各位读友大家好，此文档由网络收集而来，欢迎您下载，谢谢篇一：化学品安全技术说明MSDS-亚硫酸氢钠(中英文对照版本)Sodium Bisulfite1) Chemical Product and Company IdentificationMSDS Name: Sodium Sulfite, AnhydrousCatalog Numbers: S80195, 1MSS44-20, 1MSS4420, BP355 500, BP355-500, BP355500, S430 10, S430 3, S430 500, S430-10, S430-3, S430-500, S43010, S4303, S430500, S447 3, S447 500, S447-3, S447-500, S4473, S447500 Synonyms: Sulfurous acid, disodium saltRisk Phrases: 22 36/37/383) Hazards IdentificationEMERGENCY OVERVIEWAppearance: white. Air sensitive. Moisture sensitive. Warning! Causes eye and skin irritation. May cause digestive tract irritation. Causes respiratory tract irritation. May be harmful if swallowed.Target Organs: Central nervous system.Potential Health EffectsEye: Causes eye irritation. May cause chemical conjunctivitis.Skin: Causes skin irritation.Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed.Inhalation: Causes respiratory tract irritation. Can produce delayed pulmonary edema.Chronic: Effects may be delayed.4) First Aid MeasuresEyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively.5) Fire Fighting MeasuresGeneral Information: As in any fire,wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products.Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Do NOT get water inside containers. Use water spray, dry chemical, carbon dioxide, or appropriate foam.6) Accidental Release MeasuresGeneral Information: Use proper personal protective equipment as indicated in Section 8.Spills/Leaks: Vacuum or sweep upmaterial and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Place under an inert atmosphere. Do not get water inside containers.7) Handling and StorageHandling: Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Handle under an inert atmosphere. Store protected from air. Do not allow contact with water. Wash clothing before reuse. Keep from contact with moist air and steam.Storage: Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry,well-ventilated area away from incompatible substances. Keep away from strong acids. Do not expose to air. Store protected from moisture. Store under an inert atmosphere.8) Exposure Controls, Personal ProtectionEngineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.listed for this chemical.Personal Protective EquipmentEyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA’s eye and face protection regulations in 29 CFR or European Standard EN166.Skin: Wear appropriate protective gloves to prevent skin exposure.Clothing: Wear appropriate protectiveclothing to prevent skin exposure.Respirators: A respiratory protection program that meets OSHA’s 29 CFR and ANSI requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator’s use. Follow the OSHA respirator regulations found in 29CFR or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.9) Physical and Chemical PropertiesPhysical State: SolidAppearance: whiteOdor: odorlesspH: Not available.Vapor Pressure: Not available.Vapor Density: Not available.Evaporation Rate: Not available.Viscosity: Not available.Boiling Point: Not available.Freezing/Melting Point: Notavailable.Autoignition Temperature: Not available.Flash Point: Not available.Decomposition Temperature: > 500 deg CNFPA Rating: (estimated) Health: 2; Flammability: 0; Reactivity: 0Explosion Limits, Lower: Not available.Upper: Not available.Solubility: 23 g/100 mL water (20°C)Specific Gravity/Density: /cm3Molecular Formula: Na2O3SMolecular Weight:10) Stability and ReactivityChemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions.Conditions to Avoid: Incompatible materials, dust generation, moisture,exposure to air, excess heat.Incompatibilities with Other Materials: Strong oxidizing agents, acids, organics, moisture, air, combustible materials.Hazardous Decomposition Products: Oxides of sulfur.Hazardous Polymerization: Has not been reported.11) Toxicological InformationRTECS#:CAS# 7757-83-7: WE2150000LD50/LC50:CAS# 7757-83-7:Oral, mouse: LD50 = 820 mg/kg;Carcinogenicity:CAS# 7757-83-7: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.Epidemiology: No information available.Teratogenicity: No information available.Reproductive Effects: No information available.Neurotoxicity: No information available.Mutagenicity: No information available.Other Studies: No data available.12) Ecological InformationEcotoxicity: No data available. No information available.Environmental: No information found.Physical: No information found.Other: No information available.13) Disposal ConsiderationsChemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts Additionally, waste generators must consult state and local hazardous wasteregulations to ensure complete and accurate classification. RCRA P-Series: None listed.RCRA U-Series: None listed.US FEDERALTSCACAS# 7757-83-7 is listed on the TSCA inventory.Health & Safety Reporting ListNone of the chemicals are on the Health & Safety Reporting List.Chemical Test RulesNone of the chemicals in this product are under a Chemical Test Rule.Section 12bNone of the chemicals are listed under TSCA Section 12b.TSCA Significant New Use RuleNone of the chemicals in this material have a SNUR under TSCA.SARASection 302 (RQ)None of the chemicals in this material have an RQ.Section 302 (TPQ)None of the chemicals in this product have a TPQ.SARA CodesCAS # 7757-83-7: acute.Section 313No chemicals are reportable under Section 313.Clean Air Act:This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2Ozone depletors.Clean Water Act:None of the chemicals in this product are listed as Hazardous Substances under the CW A. None of the chemicals in this product are listed as Priority Pollutantsunder the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.OSHA:None of the chemicals in this product are considered highly hazardous by OSHA. STATECAS# 7757-83-7 is not present on state lists from CA, PA, MN, MA, FL, or NJ.California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC DirectivesHazard Symbols:XNRisk Phrases:R 22 Harmful if swallowed.R 36/37/38 Irritating to eyes, respiratory systemand skin.Safety Phrases:S 24/25 Avoid contact with skin and eyes.WGK (Water Danger/Protection)CAS# 7757-83-7: 1CanadaCAS# 7757-83-7 is listed on Canada’s DSL List. CAS# 7757-83-7 is listed on Canada’s DSL List.This product has a WHMIS classification of D2B.CAS# 7757-83-7 is not listed on Canada’s Ingredient Disclosure List.Exposure Limits16) Additional InformationMSDS Creation Date: 7/15/1999Revision #1 Date: 8/02/2000The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty,express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.亚硫酸氢钠1）化学品名称化学品中文名称：亚硫酸氢钠化学品英文名称：sodium bisulfite篇二：化学品安全技术说明书(MSDS)篇三：详细化学品安全技术说明书(MSDS)化学品安全技术说明书二〇〇六年二月目录表1－001 乙炔气............ 1 表1－002 表1－003 表1－004 表1－005 表1－006 表1－007 表1－008 表1－009 表1－010 表1－011 表1－012 表1－013 氧气.............. 二氧化碳......... 氢气............. 氩气............. 甲烷............. 四氢噻吩......... 活性炭........... 三乙胺........... 硫代磷酰氯....... 硫黄............ 甲胺磷........... 多聚甲醛........ 5 11 13 15 17 19 21 23 25 27 30 32表1－014（附表1－3）甲缩醛34 表1－015 黄磷............ 36 表1－016 氯.............. 38 表1－017 表1－018 表1－019 表1－020 表1－021 表1－022 表1－023 表1－024 表1－025 表1－026 表1－027 表1－028 三氯化磷......... 甲醇............. 液碱............. 氨水............. 硫酸二甲酯....... 甲胺磷........... 液氨............. 氯仿............. 二氯乙烷......... 二硫化碳......... 甲苯............. 盐酸............. 41 45 47 49 52 54 57 59 61 64 66 68表1－029 氯甲烷........... 71 表1－030 硫酸............. 73 表1－031 二甲苯........... 76 表1－032 表1－033 表1－034 表1－035 表1－036 表1－037 表1－038 表1－039 表1－040 表1－041 表1－042 表1－043 醋酸酐........... 多聚甲醛......... 草甘膦........... 稻瘟灵........... 异丙胺........... 漂白粉........... 氯化氢........... 氰化氢........... 氰化钠........... 氯乙酸........... 甲缩醛........... 丙烯腈..........78 81 82 84 86 88 90 93 95 97 99 102《化学品安全技术说明书(MSDS)中英文对照及翻译完整版》各位读友大家好，此文档由网络收集而来，欢迎您下载，谢谢。
氟乙烷安全技术说明书MSDS
第一部分化学品及企业标识化学品中文名：氟乙烷化学品英文名：fluoroethane；freon 161；ethyl fluoride化学品别名：R161；乙基氟CAS No.：353-36-6EC No.：206-531-6分子式：C2H5F第二部分危险性概述| 紧急情况概述气体。
极端易燃,有爆炸危险。
高压，遇热有爆炸危险。
| GHS 危险性类别根据《危险化学品分类信息表》（2015）危险性类别判定，该产品分类如下：易燃气体，类别1；高压气体，压缩气体。
| 标签要素象形图警示词：危险危险信息：极端易燃气体，内装高压气体；遇热可能爆炸。
防范说明预防措施：远离热源、热表面、火花、明火以及其它点火源。
禁止吸烟。
事故响应：漏气着火：切勿灭火，除非漏气能够安全地制止。
一旦发生泄漏，除去所有点火源。
安全储存：存放在通风良好的地方。
防日晒。
存放于通风良好处。
废弃处置：不适用。
| 危害描述物理化学危险极端易燃气体，有爆炸危险。
高压压缩气体，遇热有爆炸危险。
健康危害吸入该物质可能会引起对健康有害的影响或呼吸道不适。
由于本品的物理状态，一般没有危害。
在商业/工业场合中，认为本品不太可能进入体内。
通过割伤、擦伤或病变处进入血液，可能产生全身损伤的有害作用。
眼睛直接接触本品可导致暂时不适。
环境危害请参阅 SDS 第十二部分。
第三部分成分/组成信息第四部分急救措施| 急救措施描述一般性建议：急救措施通常是需要的，请将本 SDS 出示给到达现场的医生。
皮肤接触：立即脱去污染的衣物。
用大量肥皂水和清水冲洗皮肤。
如有不适，就医。
眼睛接触：用大量水彻底冲洗至少 15 分钟。
如有不适，就医。
吸入：立即将患者移到新鲜空气处，保持呼吸畅通。
如果呼吸困难，给于吸氧。
如患者食入或吸入本物质，不得进行口对口人工呼吸。
如果呼吸停止。
立即进行心肺复苏术。
立即就医。
食入：禁止催吐，切勿给失去知觉者从嘴里喂食任何东西。
立即呼叫医生或中毒控制中心。
对保护施救者的忠告：清除所有火源，增强通风。
MSDS物质危险有害特性识别表184种
184种物质危险有害特性识别表MSDS大全目录表1－001 乙炔气 (1)表1－002 氧气 (2)表1－003 二氧化碳 (3)表1－004 氢气 (4)表1－005 氩气 (5)表1－006 甲烷 (6)表1－007 四氢噻吩 (7)表1－008 活性炭 (8)表1－009 三乙胺 (9)表1－010 硫代磷酰氯 (10)表1－011 硫黄 (11)表1－012 甲胺磷 (12)表1－013 多聚甲醛 (13)表1－014（附表1－3）甲缩醛 (14)表1－015 黄磷 (15)表1－016 氯 (16)表1－017 三氯化磷 (17)表1－018 甲醇 (19)表1－019 液碱 (20)表1－020 氨水 (21)表1－021 硫酸二甲酯 (22)表1－022 甲胺磷 (23)表1－023 液氨 (24)表1－024 氯仿 (25)表1－025 二氯乙烷 (26)表1－026 二硫化碳 (27)表1－027 甲苯 (28)表1－028 盐酸 (29)表1－029 氯甲烷 (30)表1－030 硫酸 (31)表1－031 二甲苯 (33)表1－032 醋酸酐 (34)表1－033 多聚甲醛 (35)表1－034 草甘膦 (36)表1－035 稻瘟灵 (37)表1－036 异丙胺 (38)表1－037 漂白粉 (39)表1－038 氯化氢 (40)表1－039 氰化氢 (41)表1－040 氰化钠 (42)表1－041 氯乙酸 (43)表1－043 丙烯腈 (45)表1－044 氧化亚铜 (46)表1－045 四氯化锡 (47)表1－046 四氧化三铅 (48)表1－047 三氯化铝（无水） (49)表1－048 松香水 (50)表1－049红丹油性防锈漆 (51)表1－050 酚醛树脂 (52)表1－051 硫磺粉(补充) (53)表1－052 一乙胺 (54)表1－053三聚氯氰 (55)表1－054 三氯乙烯 (57)表1－055 磷酸 (58)表1－056 四丁基锡 (59)表1－057 柴油 (60)表1－058 对氨基苯酚 (61)表1－059 醋酸乙酯 (62)表1－060 对氯硝基苯 (63)表1－061 氮气 (64)表1－062莠去津 (65)表1－063 扑草净 (66)表1－064 八氯二丙醚 (67)表1－065 硫化钠 (68)表１－066 异丙醇 (69)表１－067 丙酮 (70)表１－068 二氯丙烷 (71)表１－069 环己酮 (72)表１－070 乙酸异戊酯 (73)表1－071 锌粉 (74)表1－072 乙醇 (75)表1－073 次氯酸钠溶液 (76)表1－074 石脑油 (77)表1－075 双环戊二烯 (78)表1－076 乙酸丁酯 (79)表1－077 双氧水 (80)表1－078 丙烯酸丁酯 (81)表1－079 丙烯酸 (82)表1－080 苯乙烯 (83)表1－081 过硫酸铵 (84)表1－082 过硫酸钾 (85)表1－083 丙烯酰胺 (86)表1－084 甲醛 (87)表1－085 甲基丙烯酸甲酯 (88)表1－087 汽油 (90)表1－088 乙酸 (91)表1－089 丙烯酸树脂 (92)表1－090 丙烯酸清漆 (93)表1－091 丙烯酸漆稀释剂 (94)表1－092 丙烯酸磁漆 (95)表1－093 二乙醇胺 (97)表1－094 煤油 (98)表1－095 漂白粉 (99)表1－096 漂粉精 (100)表1－097 三氯异氰尿酸 (101)表1－098 松香 (102)表1－099 松节油 (103)表1－100 硫化钠 (104)表1－101 保险粉 (105)表1－102 7385聚氨酯清漆（分装） (106)表1－103 甲酸 (107)表1－104 乙酸乙二醇乙醚 (108)表1－105 H－3聚氨酯漆固化剂 (109)表1－106 聚氨酯漆稀释剂 (110)表1－107 263醇酸树脂 (111)表1－108 异噻唑啉酮 (112)表1－109 N-乙基苯胺 (113)表1－110苯胺 (114)表1－111 乙酰甲胺磷 (115)表1－112 亚磷酸 (117)表1－113 亚磷酸二甲酯 (118)表1－114 氯甲烷 (119)表1－115 乙醚 (120)表1－116 丙烯酸甲酯 (121)表1－117 一甲胺 (122)表1－118 硝酸镁 (123)表1－119 硫化氢 (124)表1－120 硫化铵 (125)表1－121 一甲胺水溶液 (126)表1－122 兔宝宝面漆 (127)表1－123 兔宝宝稀释剂 (128)表1－124 硫氢化钠 (129)表1－125丙酸 (130)表1－126乙酰氯 (131)表1－127丙酰氯 (132)表1－128 丁醇 (133)表1－129 醇酸调合漆（未列名） (134)表1－130 硝酸钠 (136)表1－131 溴甲烷 (137)表1－132 磷化铝 (138)表１－133 正丁醇 (139)表１－134 硝基木器漆 (140)表１－135 硝化棉（含氮≤12.6％） (141)表１－136 单丁醚 (142)表1－137 砷 (143)表1－138 碘化汞 (144)表1－139 氯化汞 (145)表1－140 叠氮化钠 (146)表1－141 重铬酸钠 (147)表1－142 高锰酸钾 (148)表1－143 氰化金钾 (149)表1－144丙烯酸 (150)表1－145甲基丙烯酸甲酯 (151)表1－146苯乙烯 (152)表1－147丙烯酸丁酯 (153)表1－148丁醇 (154)表1－149偶氮二异丁腈 (155)表1－150甲基丙烯酸异丁酯 (156)表1－151 甲基丙烯酸（正）丁酯 (157)表1－152 乙酰丙酮 (158)表1－153 2－丁酮 (160)表1－154 生松香 (161)表1－155 硫酸铜 (162)表1－155 硝酸 (163)表1－155 氰化钾 (164)表1－156硝基苯 (165)表1－157 氟化钠 (166)表1－158 氢氟酸 (167)表1－159蓄电池（注有酸液） (168)表1－160 环氧树脂 (169)表1－161 氯苯 (170)表1－162 乙苯 (171)表1－163 樟脑 (172)表1－164 赛璐珞 (173)表1-165 氢氧化钾 (174)表1-166 乙酸丁酯 (175)表1－001 乙炔气表1－002 氧气表1－003 二氧化碳表1－004 氢气表1－005 氩气表1－006 甲烷表1－007 四氢噻吩表1－008 活性炭活性炭 C 12.0Active carbon别名：Activated chlarcoal危规分类及编号：自燃物品。
欧盟 MSDS中文模板
安全数据表名称XXX第1部分：化学品及企业标识1.1 产品标识符：产品名称：SDS编号：原料：商品条形码编号：产品类型：产品使用：客户供应商：中国制造商: XX公司地址:邮编:电话:传真:网址:毒物信息联系：第2部分：危害识别2.1 物质或混合物分类物质/混合物：根据（EC）No 1272/2008[CLP/GHS]规定分类急性毒性 4，H302皮肤过敏 2，H315眼睛刺激 2，H319有关以上声明的R短语或H陈述的全文，请参见第16节。
有关健康影响和症状的更多详细信息，请参见第11节。
2.2 标记组成危险象形图：标志词：危险说明：防范说明：总体：如果需要医药方面的建议，请随手带上产品和标签。
请将本品放在儿童不能接触到的地方预防措施：事故响应：误吞：进入眼睛：如果眼睛刺激持续存在：贮存条件：不适用处置方式：不适用危险成分：补充信息：不适用特殊包装要求：装有儿童安全紧固件的容器：不适用接触危险警告：适用2.3 其他危害其他不在分类内的危害：未知附加信息：第3部分：成分/组成信息物质/混合物：混合物欧盟法规（REACH）1907/2006附件14-需授权的物质清单附件14没有列出任何组件高度关注的物质没有列出任何组件附件17-限制生产、销售和使用某些危险物质，混合物和物品：不适用。
在供应商当前的知识范围内，没有适用的浓度范围内的其他成分被分类为对健康或环境有害，为PBT或vPvB物质，或已被指定为工作场所暴露极限，因此需要在本节中进行报告。
类型[1]具有健康或环境危害的物质[2]具有工作场所暴露极限的物质[3]物质符合法规（EC）第1907/2006号附件XIII的PBT标准。
[4]物质符合法规（EC）第1907/2006号附件XIII的vPvB标准[5]同等影响的物质职业暴露限制（如果有的话）在第8部分中列出。
第4部分：急救措施4.1急救措施说明眼睛接触：吸入后：皮肤接触：食入：保护急救人员：4.2 最重要的症状和影响，包括急性的和延迟的潜在的急性健康影响眼睛接触：吸入：皮肤接触：食入：过度接触征兆/症状眼睛接触：不良症状可能包括以下几种：吸入：皮肤接触：不良症状可能包括以下几种：食入：4.3 指示需要立即就医和特殊治疗措施给医生的说明：特殊治疗措施：第5部分：消防措施5.1 灭火剂适合的灭火剂：不适合的灭火剂：5.2 物质或混合物产生的特殊危害：物质或混合物的危害：有害的热分解产物：分解产物可能包括以下物质：5.3 给消防员的建议消防人员的特殊防护措施：发生火灾时，应将所有人员撤离事故现场，以迅速隔离现场。
化学品安全技术说明书(MSDS)中英文对照及翻译完整版
Material Safety Data Sheet化学品安全技术说明书SECTION 1: PRODUCT AND COMPANY IDENTIFICATION化学品及企业标识PRODUCT NAME:产品名CAS NO.:SUPPLIER:供应商：企业应急电话：Emergency TelephoneSECTION 2: Hazards identification危险性概述无毒：2.1 Classification of the substance or mixture物质分类Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008据(EC) No 1272/2008规定不属于有害物质This substance is not classified as dangerous according to Directive 67/548/EEC.根据67/548/EEC号文件此物质不属于危险品2.2 Label elements标记要素The product does not need to be labelled in accordance with EC directives or respective national laws.此产品不需要按照欧共体法则或各国法规进行特殊标签2.3 Other hazards – none其他危害有毒：In-taking Pathways: drug abuse, skin or eyes contact侵入途径：吸入、皮肤、眼、误服Health hazards健康危害Eye contact: May cause eye irritation, redness, tearing or blurred vision眼接触：可引起眼睛刺激、发红、流泪、视力模糊。
N,N-六亚甲基硫代氨基甲酸-S-乙酯-危险化学品安全技术说明书MSDS
第1部分化学品及企业标识化学品中文名：N,N-六亚甲基硫代氨基甲酸-S-乙酯化学品英文名：MolinateCAS号：2212-67-1分子式：C9H17NOS分子量：187.3产品推荐及限制用途：工业及科研用途。
第2部分危险性概述紧急情况概述：吞咽有害。
可能导致皮肤过敏反应。
吸入有害。
怀疑会致癌。
长期或反复接触可能对器官造成伤害。
对水生生物毒性极大并具有长期持续影响。
GHS危险性类别：急性经口毒性类别4皮肤致敏物类别1急性吸入毒性类别4致癌性类别2特异性靶器官毒性反复接触类别2危害水生环境——急性危险类别1危害水生环境——长期危险类别1生殖毒性类别2标签要素：象形图：警示词：警告危险性说明：H302吞咽有害H317可能导致皮肤过敏反应H332吸入有害H351怀疑会致癌H373长期或反复接触可能对器官造成伤害H410对水生生物毒性极大并具有长期持续影响防范说明：•预防措施：——P264作业后彻底清洗。
——P270使用本产品时不要进食、饮水或吸烟。
——P261避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
——P272受沾染的工作服不得带出工作场地。
——P280戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
——P271只能在室外或通风良好处使用。
——P201使用前取得专用说明。
——P202在阅读并明了所有安全措施前切勿搬动。
——P260不要吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
——P273避免释放到环境中。
•事故响应：——P301+P312如误吞咽：如感觉不适，呼叫解毒中心/医生——P330漱口。
——P302+P352如皮肤沾染：用水充分清洗。
——P333+P313如发生皮肤刺激或皮疹：求医/就诊。
——P362+P364脱掉沾染的衣服，清洗后方可重新使用——P304+P340如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。
——P312如感觉不适，呼叫解毒中心/医生——P308+P313如接触到或有疑虑：求医/就诊。
msds测试
MSDS测试|MSDS测试流程｜MSDS测试报告MSDS 中文名称即化学品安全说明书(Material Safety Data Sheet)，也可译为化学品安全技术说明书或化学品安全数据说明书。
是化学品生产商和进口商用来阐明化学品的理化特性(如PH值，闪点，易燃度，反应活性等)以及对使用者的健康(如致癌，致畸等)可能产生的危害的一份文件。
亿博检测机构(EBO)，是具有第三方公正地位的独立检验机构，在产品检测与认证服务领域已有超过十年的丰富经验，是集电磁兼容性，安全规格测试，化学检测，玩具检测，纺织品检测，食品检测，可靠性检测，性能检测及代客户修改对策的实验室。
实验室质量体系和设备及技术能力得到CNAS、NVLAP、TUV、FCC、VCCI、IC、UL等授权认可实验室。
EBO严格按照ISO17025：2005标准建立、实施并保持实验室管理体系，以及GUIDE 25与EN45001的品质标准进行管理，成为认证与检测行业中的佼佼者，在长期的产品认证、检测工作中，与CQC、CEMC、CEPREI、EMCC、Nemko、KEMA、TIMCO、TUV、VDE、SET、SMQ、SGS、BV等认证检测机构建立良好的合作伙伴关系。
MSDS简要说明了一种化学品对人类健康和环境的危害性并提供如何安全搬运、贮存和使用该化学品的信息。
作为提供给用户的一项服务，生产企业应随化学商品向用户提供安全说明书，使用户明了化学品的有关危害，使用时能主动进行防护，起到减少职业危害和预防化学事故的作用。
目前美国、日本、欧盟等发达国家已经普遍建立并实行了MSDS制度，要求危险化学品的生产厂家在销售、运输或出口其产品时，同时提供一份该产品的安全说明书。
亿博检测以MSDS(化学品安全技术说明书)为核心，为企业提供化学品安全领域的专业服务。
我们与国家重点实验室合作，聘用国内化学品安全领域专家为公司技术顾问，其中有资深的化工专家、职业卫生专家、毒理学专家、危险化学品管理专家。
化学品安全技术说明MSDS-次氯酸钠(中英文对照版本)
5。
3.3 Sodium hypochlorite1）Chemical Product and Company IdentificationMSDS Name: Sodium Hypochlorite Solution, 4—6％Catalog Numbers：S80183，S801831，CRNSS2904，NC9828282, SS290 1, SS290 4, SS2901，SS2904Synonyms: NoneRisk Phrases: 31 343) Hazards IdentificationEMERGENCY OVERVIEWAppearance: clear light yellow green. Corrosive。
Danger!Causes eye and skin burns。
Causes digestive and respiratory tract burns。
May cause methemoglobinemia。
Target Organs：Blood。
Potential Health EffectsEye：May cause irreversible eye injury。
Contact with liquid is corrosive to the eyes and causes severe burns.Skin：Causes skin burns.Ingestion：May cause methemoglobinemia, cyanosis (bluish discoloration of skin due to deficient oxygenation of the blood), convulsions，and death。
Causes severe digestive tract burns with abdominal pain, vomiting, and possible death. Methemoglobinemia is characterized by dizziness，drowsiness, headache, breath shortness, cyanosis with bluish skin，rapid heart rate and chocolate-brown colored blood。
MSDS危险化学品安全技术说明书——61558--六氯乙烷
化学品安全技术说明书第一部分化学品及企业标识化学品中文名：六氯乙烷；全氯乙烷；六氯化碳化学品英文名：hexachloroethane；carbon hexachloride企业名称：生产企业地址：邮编: 传真:企业应急电话：电子邮件地址：技术说明书编码:第二部分成分/组成信息√纯品混合物有害物成分浓度CAS No.六氯乙烷67-72-1第三部分危险性概述危险性类别：第6.1类毒害品侵入途径：吸入、食入、经皮吸收健康危害：本品对中枢神经系统具有麻醉作用，对肝、肾有损害；对皮肤粘膜有轻度刺激作用。
误服出现眩晕、呕吐、肝区痛、血中胆红素增高、心率减慢、肾炎及无尿。
动物实验见软弱无力、嗜睡、步态不稳、后肢轻瘫；亦可见痉挛、心率加快、昏睡、腹泻、食欲减退等。
环境危害：对水体、土壤和大气可造成污染。
燃爆危险：不燃，无特殊燃爆特性。
第四部分急救措施皮肤接触：脱去污染的衣着，用肥皂水和清水彻底冲洗皮肤。
如有不适感，就医。
眼睛接触：提起眼睑，用流动清水或生理盐水冲洗。
如有不适感，就医。
吸入：迅速脱离现场至空气新鲜处。
保持呼吸道通畅。
如呼吸困难，给输氧。
呼吸、心跳停止，立即进行心肺复苏术。
就医。
食入：禁止催吐，口服活性碳，洗胃。
避免饮牛奶、油类，避免饮酒精。
就医。
第五部分消防措施危险特性：高热时能分解出剧毒的光气。
有害燃烧产物：氯化氢、光气。
灭火方法：用雾状水、泡沫、二氧化碳、砂土灭火。
灭火注意事项及措施：消防人员须佩戴防毒面具、穿全身消防服，在上风向灭火。
尽可能将容器从火场移至空旷处。
喷水保持火场容器冷却，直至灭火结束。
第六部分泄漏应急处理应急行动：隔离泄漏污染区，限制出入。
建议应急处理人员戴防尘口罩，穿防毒服。
穿上适当的防护服前严禁接触破裂的容器和泄漏物。
尽可能切断泄漏源。
用塑料布覆盖泄漏物，减少飞散。
勿使水进入包装容器内。
用洁净的铲子收集泄漏物，置于干净、干燥、盖子较松的容器中，将容器移离泄漏区。
第七部分操作处置与储存操作注意事项：密闭操作，局部排风。
MSDS-多元醇-中文版
多元醇聚合物产品/化学名称: 多元醇聚合物(99.5%)别名: 聚醇毒性分级:低毒。
急性毒性：口服- 大鼠LD50: 34900 毫克/ 公斤; 口服-小鼠LD50: 20700 毫克/公斤刺激数据:皮肤- 兔500 毫克中度; 眼睛-兔60 毫克中度可燃性危险特性:遇明火、高温、强氧化剂可燃; 燃烧排放刺激烟雾皮肤接触：脱去污染的衣着，用流动清水冲洗。
如有不适感，就医。
眼睛接触：提起眼睑，用流动清水或生理盐水冲洗。
如有不适感，就医。
吸入：脱离现场至空气新鲜处。
如呼吸困难，给输氧。
就医。
食入：饮足量温水，催吐。
就医危险特性：遇明火、高热可燃。
有害燃烧产物：一氧化碳。
灭火方法：用雾状水、泡沫、干粉、二氧化碳、砂土灭火。
灭火注意事项及措施：消防人员须佩戴防毒面具、穿全身消防服，在上风向灭火。
尽可能将容器从火场移至空旷处。
喷水保持火场容器冷却，直至灭火结束。
处在火场中的容器若已变色或从安全泄压装置中产生声音，必须马上撤离。
总说明：需用第8 部分所述合适的个人保护装备。
溢出/泄漏: 用一些惰性材料吸附（例如蛭石、是沙子或土）到适当的容器中，并用不产生火花的工具移走所有的火源.。
抑制蒸汽泡沫可以降低蒸汽挥发。
处理方法: 处理完毕，在通风良好的地方用水冲洗。
避免接触到眼睛、皮肤以及衣物。
空储罐内有残留的产品（气体或液体或者是两者皆有），十分危险。
采取提前预警的办法来避免静电产生的放电火化。
保证储罐密封，避免同热、火花以及火焰接触。
同时避免提取和吸入。
不要对储罐加压、切割、焊接、钻孔、碾磨或是是指暴露在热、火花和明火下。
储藏: 远离热源、火花和火焰。
储存在密闭的容器中，存放在干燥的通风良好并远离反应物质的地方。
工程控制因素:使用大量的总体通风或者局域防爆通风装置来保持其浓度在可接受等级内。
个人防护设备：眼睛: 配戴OSHA中29 CFR 1910.133条和《欧洲标准》中EN166条里《眼睛和面部防护规则》中所述一般作业保护镜或护目镜。