ACGIH
ACGIH的工作场所物理因素TLVs概述
激光辐射 TLVs 是指几乎所有劳动者可以反复 接触而不引起不良健康效应的接触水平 。 6. 4 非电离辐射 TL Vs
非电离辐射 ,包括静磁场 、亚射频 (30 千赫及以 下) 磁场 、亚射频 (30 千赫及以下) 电场及静电场 、射 频和微波辐射 、可见光和近红外辐射 、紫外辐射 。在 不同辐射光谱 TLVs 下 ,劳动者可以反复接触相应辐 射光谱的物理因素 ,不引起不良健康效应 。为了详 细说明这些 TLVs ,辐射光谱划分的区域见图 1 。
由于个体易感性的差异性很大 ,机体接触等于 甚至 小 于 TLV 的 物 理 因 素 后 便 可 能 导 致 烦 燥 (annoyance) ,使原有病情恶化 ,偶尔也可能造成生理 性损害 。由于多种因素的影响 ,诸如遗传易感性 、年
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国外医学卫生学分册 2007 年 第 34 卷 第 1 期
龄 、个人习惯 (如吸烟 、饮酒或药物滥用) 、服药 、既往 或同时接触多种因素等 ,某些个体也可能对工作场 所中的一些物理因素高度易感或产生异常反应 。这 些劳动者在接触某种等于或小于 TLV 的物理因素 时 ,可能不足以避免不良健康效应 。这类劳动者所 需的额外保护的程度应由职业病医师评估 。
3 2006 年采纳 。 见 NIC。
班末
BEI
400mgΠg 肌酐 0. 2mgΠL
5ppm 0. 5mgΠL 3. 5mgΠL
(8mgΠL)
0. 5mgΠL 1. 6gΠg 肌酐
0. 05mgΠL
100mgΠg 肌酐 300mgΠg 肌酐
美国ACGIH和我国职业接触限值(容许浓度)对照表
TWA1乙醇甲胺磷 Acephate 2乙醛 Acetaldehyde 3乙酸 Acetic acid10ppm 4乙酐 Acetic anhydride 5ppm 5丙酮 Acetone500ppm 6丙酮氰醇 Acetone cyanohydrin 7乙腈 Acetonitrile 40ppm 8乙酰苯 Acetophenone 10ppm 9乙炔 Acetylene10四溴乙烷 Acetylene tetrabromide 1ppm 11乙酰水杨酸 Acetylsalicylic acid 5mg/m 312丙烯醛 Acrolein 13丙烯酰胺 Acrylamide 0.03mg/m 314丙烯酸 Acrylic acid 2ppm 15丙烯腈 Acrylonitrile 2ppm 16活性炭粉尘(总尘)17己二酸 Adipic acid 5mg/m 318己睛 Adiponitrile 2ppm 19艾氏剂 Aldrin0.25mg/m 320丙烯醇 Allyl alcohol 0.5ppm 21氯丙烯 Allyl chloride1ppm 22烯丙基缩水甘油醚 Allyl glycidyl ether 1ppm 23烯丙基二硫化物 Allyl propyl disulfide 2ppm 铝 Aluminum 铝尘10mg/m 3焦粉木，以铝计5mg/m 3熔烟，以铝计5mg/m 3可溶性盐，以铝计2mg/m 3烷基铝，以铝计2mg/m 3铝、铝合金总尘氧化铝 Aluminum oxide 10mg/m 3总尘264-氨基联苯 4-Aminodiphenyl美国No 2425化合物名称3.由ppm 换算为 mg/m 3的公式为：mg/m 3 = (ppm * 分子量)/22.454.表中符号说明：TWA -时间加权平均容许浓度；STEL -短时间接触容许浓度；C (在数值前)-最高容许浓度 A2-可疑人致癌物；A3-确定动物致癌物；A4-证据不足的人致癌物一.工作场所空气中有害物质容许浓度美国ACGIH和我国职业接触限值说明：1.本附录列出了我国GBZ 2 - 2002和美国的ACGIH的2002 TLVs and BELs 中有害2.本附录按英文字母排列272-氨基吡啶 2-Aminopyridine0.5ppm 283-氨基-1,2,4-三唑 3-Amino-1,2,4-triazole0.2mg/m3 29氨 Ammonia25ppm 30氯化铵烟 Ammonium chloride fume10mg/m3 31全氟辛酸铵 Ammonium perfluorooctanoate0.01mg/m3 32氨基磺酸铵 Ammonium sulamate10mg/m3 33戊醇 Amyl alcohol34苯胺和同系物 Aniline2ppm35邻茴香胺 o-Anisidine0.1ppm 36对茴香胺 p-Anisidine0.1ppm 37锑及其化合物，以Sb计 Antimony0.5mg/m3 38锑化氢 Antimony hydride(Stibine)0.1ppm 39三氧化锑 Antimony trioxide40安妥 ANTU0.3mg/m3 41砷及其无机化合物，以As计 Arsenic0.01mg/m3 42砷化氢 Arsine0.05ppm 石棉 Asbestos总尘纤维0.1f/cc 44石油沥青烟，以苯溶物计 Asphalt fume0.5mg/m3 45阿特拉津 Atrazine5mg/m3 46谷硫磷 Azinphos-methyl0.2mg/m3 47重晶石粉尘(总尘) Barite48钡及其可溶性化合物，以钡计 Barium0.5mg/m3 49硫酸钡 Barium sulfate10mg/m3 50白僵蚕孢子 Beauveria bassiana51苯菌灵 Benomyl10mg/m3 52膨润土粉尘 Bentonite dust53苯并蒽 Benz[a] anthracene54苯 Benzene0.5ppm 55联苯胺 Benzidine56苯并荧蒽 Benzo[b] fluoranthene57苯并(a)芘 Benzo[a] phrene58三氯苯 Benzotrichloride59苄酰氯 Benzoyl chloride60过氧化苯甲酰 Benzoyl peroxide5mg/m3 61乙酸苄酯 Benzyl acetate10ppm 62苄基氯 Benzyl chloride1ppm63铍及其化合物，按Be计 Beryllium0.002mg/m3 64联苯 Biphenyl0.2ppm双2-二甲基胺乙基醚Bis(2-dimethylaminoethyl) etherE双(巯基乙酸)二辛基锡Bis(mercaptoacetate) dioctyltin 67双氯甲醚 Bis(chloromethyl) ether 0.05ppm65 66 43碲化铋 Bismuh telluride 按Bi 2Te 3计不含Se 10mg/m 3含Se5mg/m 3四硼酸钠 Borates,tatra,sodium salt 无水化合物 1mg/m 3十水化合物5mg/m 3五水化合物1mg/m 370氧化硼 Boron oxide10mg/m 371三溴化硼 Boron tribromide 72三氟化硼 Boron trifluoride 73除草定 Bromacil 10mg/m374溴 Bromine0.1ppm 75五氟化溴 Bromine pentafluoride 0.1ppm 76溴仿 Bromoform0.5ppm 771,3-丁二烯 1,3-Butadiene 2ppm 78丁烷 Butane800ppm 79正丁醇 n-Butanol 80仲丁醇 sec-Butanol 100ppm 81特丁醇 tert-Butanol100ppm 822-丁氧基乙醇 2-Butoxyethanol 20ppm 83乙酸正丁酯 n-Butyl acetate 150ppm 84乙酸仲丁酯 sec-Butyl acetate 200ppm 85乙酸特丁酯 tert-Butyl acetate 200ppm 86丙烯酸正丁酯 n-Butyl acrylate 2ppm87丁醛 Butylaldehyde 88正丁胺 n-Butylamine89丁基羟基甲苯(BHT) Butylated hydroxytoluene2mg/m 390铬酸特丁酯 tert-Butyl chromate 以CrO 3计91丁烯 Butylene92正丁基缩水甘油醚 n-Butyl glycidyl ether 25ppm 93乳酸正丁酯 n-Butyl lactate 5ppm 94正丁基硫醇 n-Butyl mercaptan 0.5ppm 95邻仲丁基苯酚 O-sec-Butylphenol 5ppm 96对特丁基甲苯 p-tert-Butyl toluene 1ppm 镉,Cadmium元素和化合物0.01mg/m 3按Cd计0.002mg/m 398碳酸钙 Calcium carbonate10mg/m 399铬酸盐 Calcium chromate 按Cr计0.001mg/m 3100氰氨化钙 Calcium cyanamide 0.5mg/m 3101氢氧化钙 Calcium hydroxide 5mg/m 3102氧化钙 Calcium oxide2mg/m 3103硅酸钙(合成) Calcium silicate10mg/m 3976869104硫酸钙 Calcium sulfate 10mg/m 3105樟脑(合成) Camphor 2ppm 己内酰胺 Caprolactam 粒子1mg/m 3蒸汽5ppm 107敌菌丹 Captafol 0.1mg/m 3108克菌丹 Captan 5mg/m 3109西维因 Carbaryl 5mg/m 3110呋喃丹 Carbofuran 0.1mg/m 3炭黑 Carbon black 3.5mg/m 3总尘112二氧化碳 Carbon dioxide 5000ppm 113二硫化碳 Carbon disulfide 10ppm114碳纤维粉尘(总尘) Carbon fiber 一氧化碳 Carbon monoxide 非高原25ppm高原海拔2000米海拔>3000米116四溴化碳 Carbon tetrabromide 0.1ppm 117四氯化碳 Carbon tetrachloride 5ppm 118羰酰氟 Carbonyl fluoride 2ppm 119儿茶酚(邻苯二酚) Catechol 5ppm 120纤维素 Cellulose10mg/m 3121氢氧化铯 Cesium hydroxide 2mg/m 3122氯丹 Chlordane0.5mg/m 3123氯代莰烯(毒杀芬) Chlorinated camphene 0.5mg/m 3124邻氯代联苯醚 O-Chlorinated diphenyl oxide 0.5mg/m 3125氯 Chlorine0.5ppm 126二氧化氯 Chlorine dioxide 0.1ppm127三氟化氯 Chlorine trifluoride 128氯乙醛 Chloroacetaldehyde 129氯丙酮 Chloroacetone1302-氯乙酰苯 2-Chloroacetophenone 0.05ppm 131氯乙酰氯 Chloroacetyl chloride 0.05ppm 132氯苯 Chlorobenzene 10ppm邻氯苄叉丙二腈o-Chlorobenzylidine alononitrile 134氯溴甲烷 Chlorobromomethane200ppm 135二氟氯甲烷 Chlorodifluoromethane 1000ppm 136氯联苯 Chlorodiphenyl(42%氯)1mg/m 3137氯联苯 Chlorodiphenyl(54%氯)0.5mg/m 3138氯仿(三氯甲烷)Chloroform(Trichloromethane)10ppm 139双氯甲醚 bis(Chloromethyl) ether 0.001ppm140氯甲甲醚 Chloromethyl methyl ether133106111115141氯萘 Chloronaphthalene1421-氯-1-硝基丙烷 1-Chloro-1-nitropropane 2ppm 143五氟氯乙烷 Chloropentafluoroethane 1000ppm 144氯化苦 Chloropicrin0.1ppm 145β-氯丁二烯 β-Chloroprene10ppm 1462-氯丙酸 2-Chloropropionic acid 0.1ppm 147邻氯苯乙烯 o-Chlorostyrene 50ppm 148百菌清 Chlorothalonile 149邻氯甲苯 o-Chlorotoluene 50ppm 150毒死蜱 Chlorpyrifos 0.2mg/m 3铬铁矿石加工(铬酸盐)Chromite ore processing(Chromate) 以Cr计铬 Chromiun 及其无机化合物,以Cr计金属和三价化合物0.5mg/m 3水溶性六价化合物0.05mg/m 3不可溶性六价化合物0.01mg/m 3153铬酰氯 Chromyl chloride 0.025ppm 154屈 Chrysene155二氯二甲吡啶粉 Clopidol 10mg/m 3煤尘 Coal dust 无烟煤 Anthracite 0.4mg/m 3烟煤 Bituminous 0.9mg/m 3总尘呼尘煤焦油沥青挥发物,按苯溶物计Coal tar pitch volatiles158钴及其无机化合物,按Co计 Cobalt 0.02mg/m 3159羰基钴,按Co计 Cobalt carbonyl0.1mg/m 3160羰基氢钴,按Co计 Cobalt hydrocarbonyl 0.1mg/m 3161焦炉逸散物,按苯溶物计 Coke over emission 凝聚SiO 2粉尘 Condensed silica 总尘呼尘铜 Copper 烟0.2mg/m 3尘和雾，以Cu计1mg/m 3164考的松 Cortisone165棉尘 Cotton dust,raw(总尘)0.2mg/m 3166甲酚,所有异构体 Cresol 5ppm 167巴豆醛 Crotonaldehyde 168育畜磷 Crufomate 5mg/m 3169异丙苯(枯烯) Cumene 50ppm 170氨基氰 Cyanamide 2mg/m 3171氰化物 Cyanogen10ppm0.05mg/m 30.2mg/m 3157162163151152156172氯化氰 Cyanogen chloride173环己烷 Cyclohexane300ppm 174环己醇 Cyclohexanol50ppm 175环己酮 Cyclohexanone25ppm 176环己烯 Cyclohexene300ppm 177环己胺 Cyclohexylamine10ppm 178三次甲基三硝基胺(黑索金) Cyclonite(RDX)0.5mg/m3 179环戊二烯 Cyclopentadiene75ppm 180环戊烷 Cyclopentane600ppm 181杀螨锡 Cyhexatin5mg/m3 1822,4-D10mg/m3183滴滴涕 DDTDichlorodiphenyltrichloroethane1mg/m3184癸硼烷 Decaborane0.05ppm 185萘烷 Decalin186溴氰菊酯 Deltamethrin187内吸磷 Demeton0.01ppm 188洗衣粉混合尘 Detergent mixed dust189双丙酮醇 Diacetone alcohol50ppm 190二嗪农 Diazinon0.1mg/m3 191重氮甲烷 Diazomethane0.2ppm 192二硼烷 Diborane0.1ppm 1932-N-二丁氨基乙醇 2-N-Dibutylaminoethanol0.5ppm 194磷酸二丁基苯酯 Dibutyl phenyl phosphate0.3ppm 195磷酸二丁酯 Dibutyl phosphate1ppm 196邻苯二甲酸二丁酯 Dibutyl phthalate5mg/m3 197二月桂酸二丁基锡 Dibutyltin dilaurate198二氯代乙炔 Dichloroacetylene199邻二氯苯 o-Dichlorobenzene25ppm 200对二氯苯 p-Dichlorobenzene10ppm 2013,3,-二氯联苯胺 3,3,-Dichlorobenzidine2021,4-二氯-2-丁烯 1,4-Dichloro-2-butene0.005ppm 203二氯二氟甲烷 Dichlorodifluoromethane1000ppm 1,3-二氯-5,5-二甲基乙内酰脲1,3-Dichloro-5,5-dimethyl hydantoin2051,1-二氯乙烷 1,1-Dichloroethane100ppm 2061,2-二氯乙烷 1,2-Dichloroethane1,2-二氯乙烯,所有异构体1,2-Dichloroethylene208二氯乙醚 Dichloroethyl ether4ppm 209二氯氟甲烷 Dichlorofluoromethane10ppm 210二氯甲烷 Dichloromethane50ppm2111-二氯-1-硝基乙烷 1-Dichloro-1-nitroethane2ppm2121,2-二氯丙烷 1,2-Dichloropropane 2131,3-二氯丙醇 1,3-Dichloropropanol 0.2mg/m3 200ppm207 2042141,3-二氯丙烯 1,3-Dichloropropene1ppm 2152,2-二氯丙酸 2,2-Dichloropropionic acid 5mg/m 3216二氯四氟乙烷 Dichlorotetrafluoroethane 1000ppm 217敌敌畏(DDVP) Dichlorvos 0.9mg/m 3218百治磷 Dicrotophos0.25mg/m 3219二聚环戊二烯 Dicyclopentadiene 5ppm 220二戊铁 Dicyclopentadienyl iron 10mg/m 3221狄氏剂 Dieldrin0.25mg/m 3222二乙醇胺 Diethanolamine 2mg/m 3223二乙胺 Diethylamine5ppm 2242-二乙胺基乙醇 2-Diethylaminoethanol 2ppm 225二乙撑三胺 Diethylene triamine 1ppm 226邻苯二2-乙基己酯 Di(2-ethylhexyl)phthalate5mg/m 3227二乙基甲酮 Diethyl ketone 200ppm 228酞酸二乙酯 Diethyl phthalate5mg/m 3229二氟二溴甲烷 Difluorodibromomethane 100ppm 230二缩水甘油醚 Diglycidyl ether 0.1ppm 231二异丁基甲酮 Diisobutyl ketone 25ppm 232二异丙胺 Diisopropylamie5ppm 233N,N-二甲基乙酰胺 N,N-Dimethylacetamide 10ppm 234二甲胺 Dimethylamine5ppm 235N,N-二甲基苯胺 N,N-Dimethylaniline 5ppm2363,3-二甲基联苯胺 3,3-Dimethylbenzidine 237二甲基氨基甲酰氯 Dimethyl carbamoyl chloride238二甲基二氯硅烷 Dimethyl dichlorosilane 239二甲基乙氧基硅烷 Dimethylethoxysilane 0.5ppm 240二甲基甲酰胺 Dimethylformamide 10ppm 1,1-二甲基肼(偏二甲基肼)1,1-Dimethylhydrazine242邻苯二甲酸二甲酯 Dimethyphthalate 5mg/m 3243硫酸二甲酯 Dimethyl sulfate 0.1ppm 244Dinitolmide5mg/m 3245二硝基苯,全部异构体 Dinitrobenzene 0.15ppm 246二硝基氯苯 Dinitrochlorobenzene2474,6-二硝基邻苯甲酚 4,6-Dinitro-o-cresol 0.2mg/m 3248二硝基甲苯 Dinitrotoluene 0.2mg/m 32491,4-二噁烷 1,4-Dioxane 20ppm 250二噁磷 Dioxathion 0.2mg/m 3251二苯胺 Diphenylamine 10mg/m 3二丙烯基乙二醇甲基醚Dipropylene glycol methyl ether 253二丙基甲酮 Dipropyl ketone 50ppm杀草快 Diquat0.01ppm 100ppm 241252可吸入从0.5mg/m 3呼吸性0.1mg/m 3255双硫醒 Disulfiram 2mg/m 3256乙拌磷 Disulfoton 0.1mg/m 3257敌草隆 Diuron10mg/m 3258二乙烯基苯 Divinyl benzene 10ppm白云石粉尘 Dolomite dust 总尘呼尘260金刚砂 Emery 10mg/m 3261硫丹 Endosulfan 0.1mg/m 3262异狄氏剂 Endrin 0.1mg/m 3263安氟醚 Enflurane75ppm 264环氧氯丙烷 Eqichlorohydrin 0.5ppm 265苯硫磷 EPN 0.1mg/m 3266乙醇 Ethanol1000ppm 267乙醇胺 Ethanolamine 3ppm 268乙硫磷 Ethion0.4mg/m 32692-乙氧基乙醇 2-Ethoxyethanol5ppm 2702-乙氧基乙基乙酸酯 2-Ethoxyethyl acetate 5ppm 271乙酸乙酯 Ethyl acetate 400ppm 272丙烯酸乙酯 Ethyl acrylate 5ppm 273乙胺 Ethylamine5ppm 274乙基戊基甲酮 Ethyl amyl ketone 25ppm 275乙苯 Ethyl benzene 100ppm 276溴乙烷 Ethyl bromide5ppm 277乙基特丁基醚 Ethyl tert-butyl ether 5ppm 278乙基丁基甲酮 Ethyl butyl ketone 50ppm 279氯乙烷 Ethyl chloride100ppm 280氰基丙烯酸乙酯 Ethyl cyanoacrylate 0.2ppm281乙烯 Ethylene2822-氯乙醇 Ethylene chlorohydrin 283乙二胺 Ethylenediamine10ppm 2841,2-二溴乙烷 Ethylene dibromide 2851,2-二氯乙烷 Ethylene dichloride 10ppm 286乙二醇气溶胶 Ethylene glycol287乙二醇二硝酸酯 Ethylene glycol dinitrate 0.05ppm 288环氧乙烷 Ethylene oxide 1ppm 289乙撑亚胺 Ethylenmine 0.5ppm 290乙醚 Ethyl ether400ppm 291甲酸乙酯 Ethyl formate100ppm292N-乙基吗啉 N-Ethylmorpholine293乙叉降冰生烯 Ethylidene norbornene 294乙硫醇 Ethyl mercaptan0.5ppm 295N-乙基吗啉 N-Ethylmorpholine5ppm259254296硅酸乙酯 Ethyl silicate 10ppm 297丰索磷 Fenamiphos 0.1mg/m 3298辛索磷 Fensulfothion 0.1mg/m 3299倍硫磷 Fenthion 0.2mg/m 3300氰戊菊酯 Fenvlerate 301福美铁 Ferbam10mg/m 3302铁钒(合金)尘 Ferrovanadium dust 1mg/m 3玻璃钢粉尘(总尘)Fiberglass einforced plastic dust 麻尘(游离SiO 2含量<10%)亚麻 Flax(总尘)黄麻 Jute(总尘)苎麻 Ramie(总尘)305面粉尘 Flour dust0.5mg/m 3306氟化物,按F计 Fluorides 2.5mg/m 3307氟 Fluorine1ppm 308萤石混合性粉尘(总尘) Fluorspar mixed dust 309地虫磷 Fonofos0.1mg/m 3310皮毛粉尘(总尘) Fur dust 311甲醛 Formaldehyde 312甲酰胺 Formamide 10ppm 313甲酸 Formic acid 5ppm 314呋喃 Furan 315糠醛 Furfural2ppm 316糠醇 Furfuryl alcohol 10ppm 317汽油 Gasoline300ppm 318四氢化锗 Germanium tetrahydride 0.2ppm 319戊二醛,活性和非活性 Glutaraldehyde 320甘油雾 Glycerin mist 10mg/m 3321缩水甘油 Glycidol2ppm322甲基丙烯酸缩水甘油酯 Glycidyl methacrylate 323乙二醛 Glyoxal0.1mg/m 3324谷物粉尘(像小麦,大麦等) Grain dust(总尘)4mg/m 3石墨(除石墨纤维以外) Graphite 总尘2mg/m3呼尘326砂轮磨尘(总尘) Grinding wheel dust 石膏粉尘 Gypsum dust 总尘呼尘328合及其化合物,按Hf计 Hafnium 0.5mg/m 3329庚烷 Halothane 50ppm 七氯和七氯环氧化物Heptachlor and Heptachlor epoxide0.05mg/m 3327330303304325331正庚烷 Heptane400ppm 332六氯苯 Hexachlorobenzene0.002mg/m 3333六氯丁二烯 Hexachlorobutadiene 0.02ppm334六六六 Hexachlorocyclohexane 335γ-六六六 Hexachlorocyclohexane336六氯环戊二烯 Hexachlorocyclopentadiene 0.01ppm 337六氯乙烷 Hexachloroethane 1ppm 338六氯萘 Hexachloronaphthalene 0.2ppm 339六氟丙酮 Hexafluoroacetone 0.1ppm 340六氟丙烯 Hexapropylene3411,6-已二异氰酸酯 Hexamethylene diisocyanate0.005ppm 342六甲基磷酰胺 Hexamethyl phosphoramide 343正己烷 n-Hexane50ppm 344己烷,其他异构体 Hexane500ppm 3451,6-二胺基己烷 1,6-Hexanediamine 0.5ppm 3462-己酮 2-Hexanone 3471-己烯 1-Hexene30ppm 348乙酸仲己酯 sec-Hexyl acetate 50ppm 349己二醇 Hexylene glycol 350肼 Hydrazine 0.01ppm叠氮酸和叠氮化钠Hydrazoic acid & Sodium azide 叠氮酸蒸汽叠氮化钠352氢化三联苯 Hydrogenated terphenyl 0.5ppm353溴化氢 Hydrogen bromide 354氯化氢 Hydrogen chloride 氰化氢和氰化物,按CN计氰化氢Hydrogen cyanide 氰化物356氟化氢 Hydrogen fluoride 357过氧化氢 Hydrogen peroxide 1 ppm 358硒化氢 Hydrogen selenide 0.05ppm 359硫化氢 Hydrogen sulfide 10ppm 360氢醌 Hydroquinone2mg/m 3361丙烯酸2-羟基丙酯 2-Hydroxypropyl acrylate 0.5ppm 362茚 Indene10ppm 363铟及其化合物,按In计 Indium 0.1mg/m 3364碘 Iodine365碘仿 Iodoform0.6ppm 366氧化铁烟尘,按Fe计 Iron oxide5mg/m3367五羰基铁,按Fe计 Iron pentacarbonyl 0.1ppm 368可溶性铁盐,按Fe计 Iron salt 1mg/m 3369异戊醇 Isoamyl alcohol100ppm 370丁酸异丁酯 Isobutyl acetate 150ppm 371异丁醇 Isobutyl alcoho150ppm351355372异辛醇 Isooctyl alcohol 50ppm 373异佛尔酮 Isophrone374异佛尔酮二异氰酸酯 Isoprorone diisocyanate0.005ppm 3752-异丙氧乙醇 2-Isopropoxyethanol 25ppm 376乙酸异丙酯 Isopropyl acetate 250ppm 377异丙醇 Isopropyl alcohol 400ppm 378异丙胺 Isopropylamine5ppm 379N-异丙基苯胺 N-Isopropyl aniline 2ppm 380异丙醚 Isopropyl ether250ppm 381异丙基缩水甘油醚 Isopropyl glycidyl ether 50ppm 382陶土,高岭土 Kaolin 2mg/m 3383乙烯酮 Ketene0.5ppm 384异稻瘟净 Kitazin o-p铅及无机化合物,按Pb计 Lead 0.05mg/m 3铅烟铅尘386砷酸铅,以Pb 3(AsO 4)2计 Lead arsenate 0.15mg/m 3铬酸铅,以Pb计 Lead chromate 0.05mg/m 3按Cr计0.012mg/m 3石灰石粉尘 Limestone dust 总尘呼尘389林丹 Lindane0.5mg/m 3390氢化锂 Lithiun hydride0.025mg/m 3391液化石油气 Liquefied petroleum gas 1000ppm 392菱镁矿 Magnesite10mg/m 3393氧化镁烟 Magnesium oxide fume 10mg/m 3394马拉硫磷 Malathion10mg/m 3395马来酸酐 Maleic anhydride0.1ppm 396锰及无机化合物,按Mn计 Manganese 0.2mg/m 3环戊二烯三羰基锰,按Mn计Manganese cyclopentadienyl tricarbonyl 大理石粉尘 Marble dust 总尘呼尘汞,以Hg计 Mercyry烷基汞 Alkyl compounds 0.01mg/m 3芳基汞 Aryl compounds 0.1mg/m 3汞及无机化合物0.025mg/m 3400异亚丙基丙酮 Mesityl oxide 15ppm 401甲基丙烯酸 Methacrylic acid 20ppm 402甲醇 Methanol 200ppm 403灭多虫 Methomyl2.5mg/m 30.1mg/m 3398399385387388397404甲氧氯 Methoxychlor10mg/m 34052-甲氧基乙醇 2-Methoxyethanol5ppm 406乙酸2-甲氧基乙酯 2-Methoxyethyl acetate 5ppm 4074-甲氧基苯酚 4-Methoxyphenol 5mg/m 34081-甲氧基-2-丙醇 1-Methoxy-2-丙醇100ppm 双-(2-甲氧基丙基)醚bis-(2-Methoxypropyl) ether 410乙酸甲酯 Methyl acetate 200ppm 411丙炔 Methyl acetylene 1000ppm 丙炔-丙二烯混合物Methyl acetylene-propadiene mixture 413丙烯酸甲酯 Methyl acrylate 2ppm 414甲基丙烯晴 Methylacrylonitrile 1ppm 415甲缩醛 Methylal 1000ppm 416一甲胺 Methylamine5ppm 417甲基正戊基甲酮 Methyl n-amyl ketone 50ppm 418N-甲基苯胺 N-Methyl aniline 0.5ppm 419溴甲烷 Methyl bromide1ppm 420甲基特丁醚 Methyl tert-butyl ether 40ppm 421甲基正丁基甲酮 Methyl n-butyl ketone 5ppm 422氯甲烷 Methyl chloride50ppm 4232-氰基丙烯酸甲酯 Methyl 2-cyanoacrylate 0.2ppm 424甲基环己烷 Methylcyclohexane 400ppm 425甲基环己醇 Methylcyclohexanol50ppm 426邻甲基环己酮 o-Methylcyclohexanone50ppm 2-甲基环戊二烯三羰基锰,按Mn计 2-Methylcy-clopentadienyl manganese tricarbonyl 428甲基内吸磷 Methyl demeton 0.5mg/m 3二苯基甲烷二异氰酸酯Methylene bisphenyl isocaynate 4,4,-亚甲基双(2-氯苯胺)4,4,-Methylene bis(2-chloroaniline)亚甲基双(4-环己基异氰酸酯)Methylene bis(4-cyclohexylisocyanate)4324,4,-亚甲基联苯胺 4,4,-Methylene dianiline0.5ppm 433甲基乙基甲酮(丁酮) Methyl ethyl ketone 200ppm甲基乙基甲酮过氧化物Methyl ethyl ketone peroxide 435甲酸甲酯 Methyl formate 100ppm 436甲基肼 Methyl hydrazine 0.01ppm 437碘甲烷 Methyl iodide2ppm 438甲基异戊基甲酮 Methyl isoamyl ketone 50ppm 439甲基异戊醇 Methyl isobutyl carbinol 25ppm 440甲基异丁基甲酮 Methyl isobutyl ketone 50ppm 441异氰酸甲酯 Methyl isocyanate0.02ppm0.005ppm 1000ppm 0.2mg/m 30.005ppm 0.01ppm 200ppm 434427429430431409412442甲基异丙基甲酮 Methyl isopropyl ketone 200ppm 443甲硫醇 Methyl mercaptan0.5ppm 444甲基丙烯酸甲酯 Methyl methacrylate 50ppm44518-甲基炔诺酮(炔诺孕酮)18-Methyl norgestrel446Methyl parathion 甲基对硫磷0.2mg/m 3447甲基丙基甲酮 Methyl propyl ketone 200ppm 448硅酸甲酯 Methyl silicate1ppm 449α-甲基苯乙烯 α-Methyl styrene 50ppm 450丁烯酮 Methyl vinyl ketone 451嗪草酮 Metribuzin 5mg/m 3452速灭磷 Mevinphos 0.09mg/m 3云母粉尘 Mica 总尘3mg/m 3呼尘钼,以Mo计 Molybdenum 可溶性化合物0.5mg/m 3金属和不溶性化合物10mg/m 3455久效磷 Monocrotophos 0.25mg/m 3456吗啉 Morpholine20ppm 457桑蚕丝尘(总尘) Mulberry silk dust 458二溴磷 Naled 3mg/m 3459萘 Naphthalene10ppm460β-萘胺 β-Naphthylamine 镍 Nickel 金属镍1.5mg/m 3可溶性化合物,按Ni计0.1mg/m 3不可溶性化合物,按Ni计0.2mg/m 3462羰基镍 Nickel carbonyl 0.05ppm 463亚硫酸镍 Nickel subsulfide 0.1mg/m 3464烟碱 Nicotine0.5mg/m 3465硝基黄铁矿 Nitrapyrin 10mg/m 3466硝酸 Nitric acid2ppm 467一氧化氮 Nitric oxide 25ppm 468对硝基苯胺 p-Nitroaniline 3mg/m 3469硝基苯 Nitrobenzene1ppm 470对硝基氯苯 p-Nitrochlorobenzene 0.1ppm 4714-硝基联苯 4-Nitrodiphenyl 472硝基乙烷 Nitroethane100ppm 473二氧化氮 Nitrogen dioxide 3ppm 474三氟化氮 Nitrogen trifluoride 10ppm 475硝化甘油 Nitroglycerin 0.05ppm 476硝基甲烷 Nitromethane 20ppm 4771-硝基丙烷 1-Nitropropane 25ppm 4782-硝基丙烷 2-Nitropropane10ppm453454461479N-亚硝基二甲胺 N-Nitrosodimethylamine 480硝基甲苯 Nitrotoluene 2ppm 481氧化亚氮 Nitrous oxide 50ppm 482壬烷,全部异构体 Nonane200ppm 483八氯萘 Octachloronaphthalene 0.1mg/m 3484辛烷,全部异构体 Octane 300ppm 485奥克托今 Octogen486矿物油雾 Oil mist,mineral 5mg/m 3487氧化乐果 Omethoate488四氧化锇 Osmium tetroxide 0.0002ppm 489草酸 Oxalic acid1mg/m 3p,p ,-羟苯(苯磺酰基)p,p ,-Oxybis(benzenesulfonyl hydrazide)491二氟化氧 Oxygen difluoride 臭氧 Ozone 重体力工作0.05ppm 中等体力工作0.08ppm 轻体力工作0.10ppm 重、中或轻度体力负荷(<2h)0.20ppm 493石蜡烟 Paraffin Wax fume 2mg/m 30.5mg/m 30.1mg/m 3495对硫磷 Parathion 0.1mg/m 3其他粉尘Particles not otherwise regulated 不溶性微粒 Particulates 可吸入微粒10mg/m 3呼吸性微粒3mg/m 3498戊硼烷 Pentaborane0.005ppm 499五氯萘 Pentachloronaphthalene0.5mg/m 3500五氯硝基苯 Pentachloronitrobenzene 501五氯酚及其钠盐 Pentachlorophenol 0.5mg/m 3502季戊四醇 Pentaerythritol 10mg/m 3503戊烷，全部异构体 Pentane600ppm 504乙酸戊酯,全部异构体 Pentyl acetate 50ppm 505全氯甲硫醇 Perchloromethyl mercaptan 0.1ppm 506氟化全氯氧 Perchloryl fluoride 3ppm 507全氟异丁烯 Perfluoroisobutylene 珍珠岩粉尘 Perlite 10mg/m 3总尘呼尘509过硫酸盐 Persulfates 0.1mg/m 3510酚 Phenol5ppm酚醛树脂粉尘(总尘)Phenolic aldehyde resin dust0.1mg/m 3百草枯 Paraquat497508511490492494496512吩噻嗪 Phenothiazine5ppm513N-苯基-β-萘胺 N-Phenyl-beta-naphthylamine514邻苯二胺 o-Phenylenediamine 0.1mg/m 3515间苯二胺 m-Phenylenediamine 0.1mg/m 3516对苯二胺 p-Phenylenediamine 0.1mg/m 3517苯醚,蒸汽 Phenyl ether1ppm 518缩水甘油苯醚 Phenyl glycidyl ether 0.1ppm 519苯肼 Phenylhydrazine 0.1ppm 520苯硫醇 Phenyl mercaptan 0.5ppm 521苯膦 Phenylphosphine 522甲拌磷 Phorate 0.05mg/m 3523光气 Phosgene 0.1ppm 524磷胺 Phosphamidon 525磷化氢 Phosphine 0.3ppm 526磷酸 Phosphoric acid 1mg/m 3527黄磷 Phosphorus0.02ppm 528三氯氧磷 Phosphorus oxychloride 0.1ppm 529五氯化磷 Phosphorus pentachloride 0.1ppm 530五硫化二磷 Phosphorus pentasulfide 1mg/m 3531五氧化二磷 Phosphorus pentoxide 532三氯硫磷 Phosphorus thiochloride 533三氯化磷 Phosphorus trichloride 0.2ppm 534邻苯二甲酸酐 Phthalic anhydride 1 ppm 535间酞二腈 m-Phthalodinitrile 5mg/m 3536毒秀定 Picloram 10mg/m 3537苦味酸 Picric acid 0.1mg/m 3538杀鼠酮 Pindone0.1mg/m 3539哌嗪二盐酸盐 Piperazine dihydrochloride 5mg/m 3铂 Platinmu 金属1mg/m 3可溶性铂盐,按Pt计0.002mg/m 3聚丙烯腈纤维粉尘(总尘)Polycrylonitrile fiber dust542聚乙烯粉尘(总尘) Polyethylene dust 多次甲基多苯基多异氰酸酯Polymethylene polyphenyl isocyanate 544聚丙烯粉尘(总尘) Polyprpylene dust545聚四氟乙烯分解物 Polytetrafluoroethylene 546聚氯乙烯粉尘(总尘)Polyvinyl chloride dust 硅配酸盐水泥 Portland cement 10mg/m 3总尘(游离SiO 2含量<10%)呼尘(游离SiO 2含量<10%)548氢氧化钾 Potassium hydroxide541543547540沉淀SiO 2(白碳黑)(总尘)Precipitated silica dust 550丙烷 Propane2500ppm 551丙烷磺内酯 Propane sultone552正丙醇 n-Propanol(n-Propyl alcohol)200ppm 553炔丙醇 Propargyl alcohol 1ppm 554β-丙炔内酯 β-Propiolactone 0.5ppm 555丙酸 Propionic acid 10ppm 556残杀威 Propoxur0.5mg/m 3557乙酸正丙酯 n-Propyl acetate 200ppm 558丙烯 Propylene559二氯丙烷 Propylene dichloride 75ppm 丙(撑)二醇二硝酸酯Propylene glycol dinitrate 561丙烯亚胺 Propylene imine 2ppm 562环氧丙烷 Propylene oxide 2ppm 563硝酸正丙酯 n-Propyl nitrate 25ppm 564除虫菊 Pyrethrum 5mg/m 3565吡啶 Pyridine 5ppm 566苯醌 Quinone0.1ppm567抽余油(60-220o C) Raffinate稀土粉尘(游离SiO 2含量<10%)(总尘)Rare-earth dust 569间苯二酚 Resorcinol 10ppm 铑,按Rh计 Rhodium 金属和不可溶性化合物1mg/m 3可溶性化合物0.01mg/m 3571乐果 Rogor 572皮蝇磷 Ronnel10mg/m 3松香焊锡分解产物 Rosin core solderthermal decomposition products(colophony)574鱼藤酮 Rotenone 5mg/m 3575红铁粉 Rouge10mg/m 3576橡胶溶剂(石脑油) Rubber solvent(Naphtha)400ppm 硒及其化合物,除六氟化硒和硒化氢外按Se计 Selenium578六氟化硒 Selenium hexafluoride 0.05ppm 579Sesone10mg/m 3无定形二氧化硅 Silica 硅藻土(游离SiO 2含量<10%)可吸入尘10mg/m 3呼吸性尘3mg/m 3沉淀的二氧化硅和硅胶10mg/m 3二氧化硅烟 Silica,fume2mg/m 30.05ppm 致敏剂0.2mg/m 3577580560568570573549熔化的二氧化硅 Silica,fused 0.1mg/m 3晶体形二氧化硅 Silica 方石英 Cristalline 0.05mg/m 3石英 Quartz0.05mg/m 3鳞石英 Tridymite 0.05mg/m 3板状硅藻岩 Tripoli 0.1mg/m 3矽尘 Silica dust 总尘含10%-50%游离SiO 2含50%-80%游离SiO 2含80%以上游离SiO 2呼尘含10%-50%游离SiO 2含50%-80%游离SiO 2含80%以上游离SiO 2583硅 Silicon10mg/m 3碳化硅粉尘 Silicon carbide 总尘10mg/m 3呼尘585四氢化硅 Silicon tetrahydride 5ppm 银 Silver 金属0.1mg/m 3可溶性化合物,按Ag计0.01mg/m 3皂石 Soapstone 可吸入尘6mg/m 3呼吸性尘3mg/m 3588亚硫酸氢钠 Sodium bisulfite 5mg/m 3589碳酸钠 Sodium carbonate590氟乙酸钠 Sodium fluoroacetate 0.05mg/m 3591氢氧化钠 Sodium hydroxide592偏亚硫酸氢钠 Sodium metabisulfite 5mg/m 3593溶剂汽油 Solvent gasolines 594淀粉 Starch10mg/m 3595硬脂酸盐 Stearates10mg/m 3596洗毛织品用汽油类溶剂 Stoddard solvent 100ppm 597铬酸锶,按Cr计 Strontium chromate 0.0005mg/m 3598马钱子碱 Strychnine 0.15mg/m 3599苯乙烯 Styrene20ppm 600枯草杆菌蛋白酶(活性晶体酶) Subtilisins 601蔗糖 Sucrose10mg/m 3602甲嘧磺隆 Sulfometuron methyl 5mg/m 3603治螟磷 Sulfotep0.2mg/m 3584586587581582604二氧化硫 Sulfur dioxide2ppm 605六氟化硫 Sulfur hexafluoride 1000ppm 606硫酸 Sulfuric acid及三氧化硫1mg/m 3607一氯化硫 Sulfur monochloride 608五氟化硫 Sulfur pentafluoride 609四氟化硫 Sulfur tetrafluoride 610硫酰氟 Sulfuryl fluoride 5ppm 611硫丙磷 Sulprofos 1mg/m 3612杀螟松 Sumithion 合成玻璃纤维Synthetic Vitreou Fibers 长丝玻璃纤维1f/cc 玻璃棉纤维5mg/m 3岩棉纤维1f/cc 矿渣棉纤维1f/cc 特殊用途玻璃纤维1f/cc 难熔的陶器用品的玻璃纤维1f/cc 0.2f/cc 6142,4,5-涕 2,4,5-T10mg/m 3滑石粉尘 Talc(游离SiO 2含量<10%)总尘2mg/m 3呼尘616钽金属及其氧化,按Ta计 Tanatalum 5mg/m 3617茶尘(总尘) Tea dust618碲及其化合物,以Te计,除碲化氢外 Tellurium 0.1mg/m 3619六氟化碲 Tellurium hexafluoride 0.02ppm 620双硫磷 Temephos 10mg/m 3621特普 TEPP0.05mg/m 3622对苯二甲酸 Terephthalic acid 10mg/m 3623三联苯 Terphenyl1,1,1,2-四氯-2,2-二氟乙烷1,1,1,2-Tetrachloro-2,2-difluoro ethane 1,1,2,2-四氯-1,2-二氟乙烷1,1,2,2-Tetrachloro-1,2-difluoro ethane 6261,1,2,2-四氯乙烷 1,1,2,2-Tetrachloroethane1ppm 627四氯乙烯 Tetrachloroethylene 25ppm 628四氯萘 Tetrachloronaphthalene 2mg/m 3629四乙基铅,按Pb计 Tetraethyl lead 0.1mg/m 3630四氟乙烯 Tetrafluoroethylene 2ppm 631四氢呋喃 Tetrahydrofuran200ppm 632四甲基铅,按Pb计 Tetramethyl lead0.15mg/m 3633四甲基琥珀腈 Tetramethyl succinonitile 0.5ppm 634四硝基甲烷 Tetranitromethane0.005ppm500ppm 500ppm 615624625613635焦磷酸四钠 Tetrasodium pyrophosphate 5mg/m 3636特屈儿(2,4,6-三硝基苯甲硝胺) Tetrl 1.5mg/m 3637铊及其可溶性化合物,按Tl计 Thallium 0.1mg/m 3638甲拌磷 Thimet4,4,-硫代双(6-特丁基间甲酚)4,4,-Thiobis(6-tert-butyl-m-cresol)640巯基醋酸 Thioglycolic acid 1ppm 641亚硫酰(二)氯 Thionyl chloride 642福美双 Thiram 1mg/m 3锡 Tin金属、氧化物和无机化合物(除氢化锡),按Sn计2mg/m 3有机化合物,按Sn计0.1mg/m 3644二氧化钛粉尘 Titanium dioxide 10mg/m 3645烟草尘(总尘) Tobacco dust 646邻联甲苯胺 o-Tolidine 647甲苯 Toluene50ppm 648二异氰酸甲苯酯 Toluene-2,4-diisocyanate 0.005ppm 649邻甲苯胺 o-Toluidine 2ppm 650间甲苯胺 m-Toluidine 2ppm 651对甲苯胺 p-Toluidine2ppm 652磷酸三丁酯 Tributyl phosphate 0.2ppm653敌百虫 Trichlorfon654三氯乙醛 Trichloroacetaldehyde 655三氯乙酸 Trichloroacetic acid1 ppm 6561,2,4-三氯苯 1,2,4-Trichlorobenzene 1,1,1-三氯乙烷(甲基氯仿)1,1,1-Trichloroethane(Methyl chloroform)6581,1,2-三氯乙烷 1,1,2-Trichloroethane 10ppm 659三氯乙烯 Trichloroethylene50ppm 660三氯氟甲烷 Trichlorofluoronethane 661三氯萘 Trichloronaphthalene5mg/m 36621,2,3-三氯丙烷 1,2,3-Trichloropropane 10ppm 663三氯氢硅 Trichlorosilane 1,1,2-三氯-1,2,2-三氟乙烷1,1,2-Trichloro-1,2,2-trifluoroethane 665三甲苯磷酸酯 Tricresyl phosphate 666三乙醇胺 Triethanolamine 5mg/m 3667三乙胺 Triethylamine1ppm 668三乙基氯化锡 Triethyltin chloride 669三氟溴甲烷 Trifluobromomethane 1000ppm三氟甲基次氟酸酯Trifluoromethyl hypofluorite 1,3,5-三缩水甘油-s-三嗪三酮1,3,5-Triglycidyl-s-triazinetrione 672偏苯三酸酐 Trimellitic anhydride1000ppm 0.05mg/m 310mg/m 3350ppm 643657664670671639673三甲胺 Trimethylamine5ppm 674三甲基苯 Trimethyl benzene25ppm 675亚磷酸三甲酯 Trimethyl phosphite2ppm 676三硝基甲苯(TNT) 2,4,6-Trinitrotoluene 0.1mg/m 3677磷酸三邻甲苯酯 Triorthocresyl phosphate 0.1mg/m 3678三苯胺 Triphenyl amine5mg/m 3679磷酸三苯酯 Triphenyl phosphate 3mg/m 3钨,按W计 Tungsten金属钨及其不溶性化合物5mg/m 3可溶性化合物1mg/m 3681松节油 Turpentine100ppm 铀(天然的) Uranium,按U计0.2mg/m 3可溶性及不可溶性化合物683尿素 Urin684(正)戊醛 n-Valeraldehyde50ppm 五氧化二钒 Vanadium pentoxide 烟或尘,以V 2O 5计0.05mg/m 3烟或尘，以V计686植物油雾 Vegetable oil mists 10mg/m 3687蛭石粉尘(总尘) Vermiculite dust 688乙酸乙烯酯 Vinyl acetate 10ppm 689溴乙烯 Vinyl bromide 0.5ppm 690氯乙烯 Vinyl chloride1ppm 6914-乙烯基环己烯 4-Vinyl cyclohexene 0.1ppm 二氧化乙烯基环己烯Vinyl cyclohexene dioxide 693氟乙烯 Vinyl fluoride1ppm 694偏二氯乙烯 Vinylidene chloride 5ppm 695偏二氟乙烯 Vinylidene fluoride 500ppm 696乙烯基甲苯 Vinyl toluene 50ppm 697VM&P 石脑油 VM&P Naphtha 300ppm 698杀鼠灵 Warfarin0.1mg/m 3699电焊烟尘 Welding fumes(总尘)5mg/m 3700硅灰石粉尘(总尘) Wollastonite dust 木粉尘 Wood dust(总尘)1mg/m 3某些硬木如栎木和山毛榉软木5mg/m 3702二甲苯 Xylene(邻,间,对异构体)100ppm间二甲苯α,α,-二胺m-Xylene-α，α，-diamine704二甲代苯胺 Xylidine(异构体混合物)0.5ppm 705钇及其化合物，按Y计1mg/m 3706沸石粉尘(总尘) Zeolite dust 707氯化锌烟 Zinc chloride fume 1mg/m 3708铬酸锌盐类,按Cr计0.01mg/m 30.1ppm 692701703680682685氧化锌烟5mg/m3 709尘10mg/m3 710锆及其化合物,以Zr计 Zirconium5mg/m3分子量STELTWA STEL 0.30.9C 25ppmC 4544.05 A315ppm1020601632102.09750ppm30045058.05 A4C 5mg/m 3C 385.160ppm102541.05 A4120.1526.02 窒息剂345.7512.5180.15C 0.1ppmC 0.356.06 A40.30.971.08 A361572.06 A41253.05 A3510146.14108.1364.93 A32358.08 A42ppm2476.50 A3114.14 A43ppm 148.1626.9834A446169.23 A1美国中国5触容许浓度；C (在数值前)-最高容许浓度；A1-确定人致癌物；癌物触限值(容许浓度)对照表中有害物质(包括毒物、粉尘和生物因素)的容许浓度和域限值2591.1184.08 A335ppm203017.0320ppm 102053.5431.00 A3615114.1310020037.593.12 A30.5 1.5123.15 A30.5 1.5123.15 A40.50.5121.75124.78171.50 A20.30.9202.27 A40.010.0274.92 A1C 0.0377.95 A10.8 1.50.8f/ml 1.5f/ml 512.5 A4216.06 A4317.34 A4510137.30 A41025233.43290.32 A4610228.30 A22.5ppm61078.11 A1184.23 A1252.30 A2252.30 A2C 0.1ppm195.50 A2C 0.5ppm140.57 A4512.5242.22 A4150.18 A4C 5126.58 A30.01mg/m 30.00050.0019.01 A11.5 3.75154.2C 0.005160.260.20.10.15ppm C 6*107 孢子数/m 3800.83 A4512.5201.2769.64C 1ppm250.57C 1ppm C 367.82261.11 A3 0.2ppm0.62159.81174.92252.80 A3512.554.09 A258.12C 50ppm10020074.1210020074.1210020074.12 A4118.17200ppm200300116.16200300116.16200300116.162550128.17 A4510C 5ppm C 1573.14220.34 A4C 0.1mg/m3230.2210020060120130.21146.192590.193060150.22148.180.010.02112.40 A2100.09156.09 A21380.11 A474.12556.08A4136.144ppm152.23 A4512.5113.16 A43mg/m 310ppm 349.06 A4300.60 A3201.20 A4221.30 A4A44830000ppm90001800044.0151076.143628.012030C 20C 150.3ppm1.54331.6510ppm1525153.84 A25ppm51066.01110.11 A3102525149.92409.80 A31mg/m 3414.00 A33771ppmC 170.91 A40.3ppm0.30.867.46C 0.1ppmC 0.4292.46C 1ppmC 378.5C 1ppmC 492.530.30.9154.59 A40.15ppm0.20.6112.9550100112.56 A3129.393500525086.47 A4266.50.5 1.5328.40 A32040119.38 A3114.96 A1C 0.005188.61 A4C 0.4C 0.05ppm0.51.580.50 A2123.5450007500154.47C 1164.39 A441088.54108.5375ppm250400138.6C 1126.59 A40.050.15 A1 A1154.92228.30 A3192.06 A4 A4 A4462.5 3.50.050.158.93 A3341.94171.980.10.31.530.5163.550.20.61 2.51 2.5131025108.14C 0.3ppm C 1270.09 A3291.71 A4120.192542.04C 152.040.60.2C 0.3ppm61.4825037584.16100200100.165010094.18 A482.14102099.17 A41.5 3.75222.26 A466.170.13385.16 A4221.04 A40.20.6354.50 A30.15ppm0.250.75122.31601200.030.090.050.15258.3412240360116.16304.36 A40.350.742.04 A20.10.327.69410173.293.58.75286.262ppm210.212.5 6.25278.340.10.2C 0.1ppmC 0.494.93 A350ppm50100147.0 A43060147.01 A3253.13 A3124.99 A25000750098.97 A498.97 A471510ppm 143.02 A4102.9220030084.93 A31224143.96350500512.5197.0396.9512008000.4mg/m 3410110.98 A4142.97 A4170.93 A4220.98 A4237.21 A42550132.21186.03380.93 A4105.1415ppm73.14 A450100117.19410103.17390.54 A3300ppm70090086.13222.23 A4209.83130.14145218142.23101.19204087.1215ppm51045.08 A410ppm510121.18C 0.02107.54 A2C 21.5ppm104.2204073.09 A4194.19126.10 A3225.16 A41 2.5168.110.30.50.20.6198.130.20.6182.15 A388.10 A3456.54 A41025169.24 A4114.8344.70 A460.12 A3148.21.59000.5600150ppm。
有害气体临界值
0~25
对眼睛和呼吸道的最小刺激
25
允许的暴露浓度(OSHA、ACGIH)
50~100
眼脸肿起，结膜炎，呕吐、刺激喉部
100~500…
高浓度时危险，刺激变得更强烈，稍长时间会引起死亡
用户可根据此数据结合现场实际情况，选择适合的气体报警器(气体探测器),气体检测仪测量范围，避免选择不当给造成人员和财产的损失。(以上数据仅供参考)
3,200
5至10分钟内头痛、头晕。30分钟无知觉，有死亡危险。
6,400
1至2分钟内头痛、头晕。10至15分钟无知觉，有死亡危险。
12,800
马上无知觉。1至3分钟内有死亡危险。
H2S
0.13
最小的可感觉到的臭气味浓度。
4.60
易察觉的有适度的臭味的浓度。
10
开始刺激眼球，可允许的暴露浓度，可暴露8小时(OSHA、ACGIH)。
27
强烈的不愉快的臭味，不能忍受。
100
咳嗽、刺激眼球，2分钟后可能失去嗅觉。
200~300
暴露1小时后，明显的结膜炎(眼睛发炎)呼吸道受刺激。
500~700
失去知觉，呼吸停止(中止或暂停)，以至于死亡。
1,000~2,000
马上失去知觉，几分钟内呼吸停止并死亡，即使个别的马上搬到新鲜空气中，也可能死亡。
附：OSHA:美国职业安全与健康管理局(Occupational Safety and Health Administration)
PEL :允许暴光极限( OSHA_PEL)
ACGIH:在北美,绝大多数的有关空气质量标准都是基予由美国政府工业卫生协会起草的准则的基础上建立起来的.被称为ACGIH
TLV: ACGIH规定对污染排放物临界值限定(ACGIH_TLV)
职业接触限值
法规信息：
化学危险物品安全管理条例(1987年2月17日国务院发布)，化学危险物品安全管理条例实施细则（化劳发『1992』677号），工作场所安全使用化学品规定([1996]劳部发423号)等法规，针对化学危险品的安全使用、生产、储存、运输、装卸等方面均作了相应规定；常用危险化学品的分类及标志（GB13690-92）将该物质划为第3.1类低闪点易燃液体；车间空气中溶剂汽油卫生标准（GB11719-89）,规定了车间空气中该物质的最高荣许浓度及检测方法。
LC50:103000mg/m3,2小时（小鼠吸入）（120号溶剂汽油）
亚急性和慢性毒性：刺激来自：入经眼：140ppm/8小时，轻度刺激。
致敏性：
致突变性：
致畸性：
致癌性：
第十二部分：生态学资料
生态毒理毒性：
生物降解性：
非生物降解性：
生物富集或生物积累性：
其他有害作用：
该物质对环境可能有危害，对水体应给予特别注意。
40~200
相对密度（水=1）：
0.70～0.79
相对蒸气密度（空气=1）：
3.5
饱和蒸气压（kPa）:
无资料
燃烧热（KJ/mol）:
无资料
临界温度（。C）
无资料
临界压力（MPa）:
无资料
辛醇/水分配系数的对数值：
无资料
闪点（。C）：
-50
引燃温度（。C）
415~530
爆炸上限%（V/V）:
6.0
爆炸下限%（V/V）:
眼睛防护：
一般不需要特殊防护，高浓度接触时可戴化学安全防护眼镜。
身体防护：
穿防静电工作服。
手防护：
戴橡胶耐油手套。
吹吸式排风罩的计算
L2 (1800 ~ 2750) A
式中： A——液面面积，m2； L2——排风量，m3/h；
吹吸式排风罩的计算
吹吸式排风罩的计算
1、美国联邦工业卫生委员会（ACGIH）推荐的方法
3）吹风量L1按下式计算
L1
1 BE
吹吸式排风罩的计算
吹吸式排风罩的计算
1、美国联邦工业卫生委员会（ACGIH）推荐的方法
假设吹出气流的扩展角 10o ，如下图所示。
1）排风口高度H按下式计算
H B tan 0.18B
式中： H——排风口高
度，m； B——吹、吸风口
间距（槽宽） ，m。
吹吸式排风罩的计算
吹吸式排风罩的计算
L2
式中：
L1——吹风量，m3/h； E——修正系数，见
下表。
B 0~2. 2.4~ 4.9~ 7.3 4 4.9 7.3 ~
E 6.6 4.6 3.3 2.3
吹吸式排风罩的计算
吹吸式排风罩的计算
1、美国联邦工业卫生委员会（ACGIH）推荐的方法 4）吹风口尺寸h 按出口流速5~10m/s确定。
吹吸式排风罩的计算
1）对于有一定温度的工业槽，吸风口前必须的射流平均速度按下列经
验数值确定：
槽温 t=70～95℃ v1=H m/s （H为吹、吸风口间距离 m）
t=60℃ຫໍສະໝຸດ v1=0.85H m/st=40℃ t=20℃
vv11==00..755HHmm/s/s
2）为了避免吹出气流溢出吸风口
外，吸风口的排风量应大于吸风
吹吸式排风罩的计算
2、巴杜林速度控制法： 只要吸风口前射流末端的平均速度保持一定数值（通常要求不小于 0.75～1 m/s），就能保证对有害物的有效控制。这种方法只考虑吹出 气流的控制和输送作用，不考虑吸风口的作用，把它看作是一种安全 因素。
ACGIH 2014年化学性物质接触阈限值介绍
ACGIH 2014年化学性物质接触阈限值介绍朱志良胡建辉我国职业卫生接触限值，大多参照美国政府工业卫生家协会（ACGIH）的接触阈限值(TLV)。
ACGIH每年对有害因素TLV进行一次修订，2014年的修订版本最近已经出版[1]，本文拟对其化学性物质TLV做一个介绍。
化学性物质TLV包括了化学物质与粉尘，合计698种，其中有无烟煤尘、烟煤尘、棉尘、面粉尘、谷物粉尘（燕麦、小麦、大麦）、金属粉尘、西方红松粉尘、其他树种粉尘等8种，化学物质690种。
一、致癌物质肯定的人类致癌物(A1) 19种（有流行病学证据），见表1。
怀疑人类致癌物31种（试验动物致癌，但缺乏流行病学证据），见表2。
肯定的动物致癌但对人类致癌尚未证明有关联的A3化学物质114种，其他两个致癌性分类的A4(尚不能分类为人类致癌物，研究表明一定的致癌性，但缺乏结论性的证据)207种、A5(长期的流行病学研究表明不具致癌性，或动物试验也不支持)2种（元素镍、己内酰胺）。
二、致敏物质致敏化学性物质有41种，其中7种呼吸过敏，32种物质皮肤过敏。
他们是草胺、烯丙基丙基二硫化物、谷硫磷、苯菌灵、丙烯酸正丁酯、正丁基缩水甘油醚、克菌丹、柠檬醛、S-甲基内吸磷、敌敌畏、二甲胺、十二烷基硫醇、异氰酸乙酯、面粉、甲醛、戊二醛、乙二醛、六氢邻苯二甲酸酐,、氢醌、丙烯酸2-羟丙酯、马来酸酐、丙烯酸甲酯、异氰酸甲酯、甲基丙烯酸甲酯、丁烯酮、二溴磷、天然橡胶胶乳、苯基缩水甘油醚、邻苯二甲酸酐、哌嗪及其盐、二氯丙烷、环氧丙烷、松香焊接剂的热分解产物、氯化四羟甲基鏻、四羟甲基鏻硫酸盐、福美双、甲苯-2,4(或2,6)-二异氰酸酯(或混合物)、偏苯三酸酐、松节油及精制单萜类、西方红松。
三、皮肤吸收物质标注为SKIN（可经皮肤吸收）的物质214种，包括：丙酮氰醇、乙腈、丙烯醛、丙烯酰胺、丙烯酸、丙烯腈、己二腈、艾氏剂、丙烯醇、烯丙基溴、氯丙烯、4-氨基联苯、全氟辛酸铵、苯胺、邻茴香胺、对茴香胺、安妥、谷硫磷、苯、联苯胺、三氯苯、正丁胺、叔丁基铬酸酯、正丁基缩水甘油醚、邻仲丁基苯酚、敌菌丹、西维因、二硫化碳、四氯化碳、儿茶酚、氯丹、氯代莰烯(毒杀芬)、氯丙酮、氯乙酰氯、邻氯苄叉丙二腈、氯联苯(42%氯)、氯联苯(54%氯)、1-氯-2-异丙醇和2-氯-1-异丙醇、β-氯丁二烯、2-氯丙酸、毒死蜱、柠檬醛、蝇毒磷、甲酚,所有异构体、巴豆醛、环己醇、环己酮、三次甲基三硝基胺、2,4-滴、癸硼烷、内吸磷、S-甲基内吸磷、二嗪农、2-N-二丁氨基乙醇、磷酸二丁基苯酯、磷酸二丁酯、二氯乙酸、3,3’-二氯联苯胺、1,4-二氯-2-丁烯、二氯乙醚、1,3-二氯丙烯、敌敌畏、百治磷、氧桥氯甲桥萘、柴油机燃料、二乙醇胺、二乙胺、2-二乙氨基乙醇、二乙烯三胺、二异丙胺、N,N-二甲基乙酰胺、二甲胺基乙氧基乙醇、二甲基苯胺、二甲基氨基甲酰氯、二甲基二硫醚、二甲基甲酰胺、偏二甲基肼、硫酸二甲酯、二硝基苯,所有异构体、二硝基邻甲酚、二硝基甲苯、1,4-二噁烷、敌恶磷、敌草快、乙拌磷、硫丹、异狄氏剂、环氧氯丙烷、苯硫磷、乙硫磷、2-乙氧基乙醇、2-乙氧基乙酸乙酯、乙胺、溴乙烷、氯乙烷、氯乙醇、乙二胺、二溴乙烯、乙二醇二硝酸酯、氯丙啶、异氰酸乙酯、N-乙基吗啉、苯线磷、丰索磷、倍硫磷、地虫磷、甲酰胺、糠醛、糠醇、七氯和、六氯苯、六氯丁二烯、六氯乙烷、六氯萘、六氟丙酮、六甲基磷酰胺、正己烷、肼、氰化氢、氰化物、氟化氢、丙烯酸2-羟丙酯、异辛醇、2-异丙氧基乙醇、N-异丙基苯胺、煤油/飞机燃料、林丹、马拉硫磷、环戊二烯三羰基锰、汞（烷基化合物、金属及无机态）、甲醇、灭多虫、2-甲氧基乙醇、乙酸2-甲氧基乙酯、2-甲氧基甲乙氧基丙醇、丙烯酸甲酯、甲基丙烯腈、N-甲基苯胺、溴甲烷、甲基正丁基甲酮、氯甲烷、邻甲基环己酮、2-甲基环戊二烯基三羰基锰、甲基内吸磷、4,4’-亚甲基双(2-氯苯胺)、4,4’-二苯氨基甲烷、甲基肼、碘甲烷、甲基异丁基甲醇、异氰酸甲酯、1-甲基萘和2-甲基萘、甲基对硫磷、丁烯酮、速灭磷、氯乙酸、久效磷、吗啉、二溴磷、萘、天然橡胶胶乳、烟碱、对硝基苯胺、硝基苯、对硝基氯苯、4-硝基联苯、硝化甘油、N-亚硝基二甲胺、硝基甲苯,所有异构体、八氯萘、对硫磷、五氯萘、五氯酚、2,4-乙酰基丙酮、苯酚、吩噻嗪、苯基缩水甘油醚、苯肼、苯硫醇、甲拌磷、炔丙醇、丙二醇二硝酸酯、丙烯亚胺、氟乙酸钠、治螟磷、硫丙磷、双硫磷、特丁硫磷、1,1,2,2-四氯乙烷、四乙基铅、焦磷酸盐、四氢呋喃、四甲基铅、四甲基琥珀腈、铊、巯基乙酸、锡的有机化合物、邻联甲苯胺、邻甲苯胺、间甲苯胺、对甲苯胺、1,1,2-三氯乙烷、三氯萘、1,2,3-三氯丙烷、三乙胺、偏苯三酸酐、2,4,6-三硝基甲苯(TNT)、磷酸三邻甲苯酯、二氧化环己烯乙烯、间二甲苯α,α’-二胺、二甲苯胺(混合异构体)。
各国SDS报告有哪些法规要求 SDS最新法规详细介绍
SDS报告编写法规介绍SDS是化学品生产或销售企业按法律要求向客户提供的有关化学品特征的一份综合性法律文件。
它提供化学品的理化参数、燃爆性能、对健康的危害、安全使用贮存、泄漏处置、急救措施以及有关的法律法规等十六项内容。
也叫做化学品安全技术说明书/化学品安全数据说明书。
SDS是应产品进口国的法律规定与要求编写的。
编写时，要考虑到各国，甚至美国的各州，对化学产品管理的法律法规要求的不同。
那么，SDS报告编写的法规有哪些呢？下面，临安科达认证的小编就给大家介绍几个常见的法规。
（扣扣：三五二二二零贰零肆三，contact me if you have any questions）1：EINECS-European Inventory of Existing Commercial Chemical Substances欧洲现有商业化学品目录(EINECS编号)是一套给予每一种于1971年7月1日至1981年9月18日间在欧洲联盟作商业用途的化学物质的注册号码。
这个制度是由依据危险物质指令67/548/EEC 所创立的。
该指令规定危险品的标签和包装上必须注明EINECS编号。
由1981年9月19日起，该目录被欧洲申报化学物质名录(ELINCS)所取代,所有的进入欧洲市场的"新"物质于知会欧洲委员会后会被分配一个ELIINCS编号。
包装和标签上必须印有ELIINCS编号。
其实在SDS中EC号和CAS号的作用是一样的。
也是为了区分每个物质之间的不同而单独设立一个物质“身份证号”。
在GHS法规的SDS制作指导规范中，除了CAS是必须体现的外，EC号也可以用来区分其他物质的一个物质身份识别号。
大部分国家的GHS法规都是这么要求的。
2：ACGIH-American Conference of Governmental Industrial Hygienists美国政府工业卫生医师协会（ACGIH）是非政府的法人机构，设立有委员会，目标是对已经发表的、经过同行评议的科学文献进行评述后，制定发布阈限值（TLVs）和生物接触指数（BELs），为作业场所的物理和化学因素的安全接触水平提供参考。
ACGIH时间加权平均WBGT指数计算方法
IH for the CSP 6: Wet Bulb Globe Temperature IndexMichael Dean Taggart, PhD, MPH, CIH, CSPAbstractIn the year 2000 alone, OSHA recorded 21 workplace fatalities due to heat stress. There were an additional 2,554 heat stress injuries sufficiently serious to require days away from work. OSHA noted that heat stress-related injuries are likely under-reported as many employers fail to recognize the symptoms of heat-related illness. It should further be recognized that heat stress will impair the metal and physical abilities of employees. There is no way to estimate the number of fatalities and injuries in which heat stress may have plated a significant role.There are many methods for evaluating the hazard due to conditions of heat stress. The American Conference of Governmental Industrial Hygienists, ACGIH, publishes a method known as the Wet Bulb Globe Temperature Index (WBGT). Currently OSHA has no heat stress standard and is enforcing the WBGT recommendations of the ACGIH under section 5(a)(1) of the OSH Act, the General Duty Clause.Heat Stress and Heat Strain"Heat stress" refers to adverse conditions to which employees are exposed. Stressors include air temperature, humidity, radiant energy (e.g. infra-red radiation), clothing worn, air movement, and others. "Heat strain" refers to the response of the body to heat stress, i.e. heat related illness.The human body cannot tolerate even small changes (+ 1 O C or + 2 O F) in body core temperature without adverse effect. Fortunately we are equipped with remarkable systems to regulate body temperature. These systems are largely controlled by the hypothalamus area of the brain. In hot environments the body removes heat through two main systems, evaporation of perspiration and dilation (opening) of peripheral blood vessels.The most serious form of heat strain is heat stroke. In heat stroke, the hypothalamus simply stops functioning. The body ceases to produce perspiration and core temperatures can increase rapidly. Heat stroke is characterized by hot, dry skin. It can cause mental confusion, convulsions, or unconsciousness. Heat stroke will be fatal if not treated promptly. Treatment should include cooling the body as rapidly as possible. Treat for shock by opening restrictive clothing and raising the feet. Emergency medical services should be summoned immediately.Much more common than heat stroke is heat exhaustion. Heat exhaustion is usually caused by water deficiency. It can also be caused by a lack of salt. However this is rare, especially in acclimatized workers. When heat exhaustion is related to salt depletion it is usually accompanied by heat cramps due to a build up of lactic acid. Heatexhaustion is characterized by moist, clammy skin. Symptoms may include giddiness, headache, nausea, or fatigue. Treat by moving the employee to a cooler area. Give water orally. Never give anything orally to an unconscious individual. Water should include at most 0.9% salt. In the past, salt tablets were given to individuals suffering heat exhaustion, especially when related to outdoor sports activities. Today, this practice is no longer advised. If not taken for medical treatment, sufferers of heat exhaustion should be carefully watched. Heat exhaustion is often a precursor to heat stroke discussed above.Miliaria (a.k.a. prickly heat or heat rash) can result if the shin surface is occluded (i.e. covered by impermeable materials). This includes not only clothing, but also other surfaces (e.g. seating) if contact is continuous. Miliaria will quickly resolve without medical treatment once the occlusion is removed (i.e. once the skin is allowed to "breathe").The final heat stress concern is chronic heat fatigue. It is characterized by reduced performance, especially in vigilance tasks. Physical and mental errors are simply more likely in hot environments. Employees suffering chronic heat fatigue may exhibit a lowering of self-imposed behavioral standards, such as removing all clothing or drinking excessively during working hours.WBGTThe WBGT method uses two indices, one for conditions indoors or outdoors with no solar load (no sun shining on the employees), and one for conditions outdoors with a solar load. The indoor index, WBGT in , is,WBGT in = 0.7 NWB + 0.3 GT . 1The index outdoors with a solar load, WBGT out, is,WBGT out = 0.7 NWB + 0.2 GT + 0.1 DB , 2where NWB is the natural wet-bulb temperature (the temperature of a wet thermometer with no forced air flow), GT is the globe temperature (the temperature within a 6-in hollow copper globe with a flat black finish), and DB is the dry bulb temperature (the temperature measured by a conventional thermometer).A WBGT index of greater than 26 O C (79 O F) is considered a "hot environment." If the WBGT measures less than 26 O C everywhere and at all times, then the workplace is relatively safe for most workers and no further analysis need be done.All three of these temperatures can be measured simultaneously with a device called the WiBGeT. In addition, the WiBGeT will calculate both the indoor and outdoor indices. Most WiBGeT's can be set to read in either O C or O F. It should be noted that for the sake of convenience, the globe temperature is measured using a globeapproximately 3-cm in diameter.Measurement ProtocolLike all instruments used in industrial hygiene measurements, the heat stress monitor must be calibrated according to manufacturer’s instructions. Usually the instrument will be factory calibrated, often every two years, and field calibrated before and after each day’s use.Field calibration is performed by the industrial hygienist using a calibration key. The temperature sensor array, or a single temperature sensing element, is detached from the monitor. The key is then inserted in place of the array or the element and the output of the monitor is recorded. The manufacturer will specify the temperature or temperatures that should be displayed, and the tolerance allowed. Often the desired readings are printed on the key itself. For example, the key may be inserted in place of the globe temperature sensor. If the manufacturer specifies the globe temperature should read 25.0 O C + 0.2 O C, and it indicates above 25.2 O C or below 24.8 O C with the key inserted, the instrument fails the calibration test, and must be returned to the manufacturer for servicing before use. If the key is to be inserted in place of the entire sensor array, the required readings for all three temperatures (globe, dry bulb, and natural wet bulb) are usually specified. If any one of the temperatures is observed to fall outside the specified range, the monitor must be returned to the manufacturer for servicing and factory calibration before it may be used.A significant period of time, often 15 minutes, is required for the device to equilibrate,i.e. come to equilibrium with the surroundings. The main reason for this delay is the globe temperature sensor. It simply takes some time to heat up (or cool down) the air inside the hollow sphere. If employees move from area to area in times less than 15 minutes, additional monitors may be required.ClothingThe primary mechanism for removing heat from the body in hot conditions is evaporation of perspiration. Obviously, the effect of heat stress will depend on the clothing worn by the employee. For example, the air within a totally encapsulating, vapor-protective suit (Level A worn by emergency spill responder) will quickly become saturated with moisture. This will prevent any evaporation of perspiration. Emergency responders may face life-threatening heat stress conditions even on a cool day.The ACGIH recommends correcting the WBGT based on the clothing worn. For a normal work uniform (long sleeve shirt and pants) or cotton coveralls (with only undergarments, not another set of outerwear) no correction is needed. For double-layered woven clothing (such as coveralls over a work uniform) 3 O C Celsius is added to the WBGT. The correction factors for SMS polypropylene, and polyolefin coveralls are 0.5 and 1.0 O C, respectively. For limited-use vapor-barrier coveralls, a correction factor of 11 is recommended. Your author interprets "vapor-barrier coveralls" to meangarments such as chemical splash protective suits (Level B).Time-Weighted AverageIn industry, employees usually move from area to area. Since heat stress conditions may differ greatly even in relatively close locations, a method of averaging the WBGT indices is required. The ACGIH recommends a one-hour time-weighted average WBGT. The time-weighted average is calculated for hottest continuous 60-minute period. A two-hour time-weighted average may be used if the employee moves frequently in and out of heat stress areas. The one-hour average is used in stead of an eight-hour average (as for air contaminants) because one hour is all it takes for the heat to affect you. It won’t matter that you plan to spend the rest of the afternoon in a cool place if you are already dead by noon. The time-weighted average WBGT is given by,WBGT TWA =WBGT1 (t1) + WBGT2 (t2) + .... + WBGT n (t n)t1 + t2 + .... + t n, 3where WBGT i is either the indoor or outdoor (as required) wet bulb globe temperature index during the i th time period, and t i is the time the employee is exposed to WBGT i.If employees wear the same clothes throughout the day, the time-weighted average may be calculated based on the direct WiBGeT readings and then corrected for the clothing worn. If different clothes are worn in different areas, each WiBGeT reading must be corrected individually and the time-weighted average calculated using the corrected values. This is often the case if coveralls are donned in areas exposed to chemical contamination and removed before exiting the area to prevent the spread of contamination.Metabolic RateAccording to the WBGT method of heat stress assessment, the maximum time-weighted average WBGT to which employees should be exposed will depend on their average metabolic rate, or the rate at which the body generates heat due to the work being performed. There are many ways to estimate metabolic rate, monitoring heart rate, measuring oxygen consumption, etc. The ACGIH method for estimating metabolic heat rate (M) as published in the 2008 TLV and BEI booklet is quite simple.The work done during the hottest 60-minute period is estimated using professional judgment and the benchmark four (4) categories shown in the table below.Category M(Watts, W)ExamplesRest 115 Sitting, relatively inactiveLight 180 Sitting with light hand and arm work,occasionally walkingModerate 300 Moderate work with hand arm and body,pushing or pulling, normal walkingHeavy 415 Intense work with hands arms and body;carrying, shoveling, sawing, pushing or pullingheavy loads, walking at a fast paceVeryHeavy520 Very intense activity at fast to maximum pace.Table 1: ACGIH guidelines for estimating the metabolic rateThe above values are representative of an employee weighing 70 kg (154 lb). Obviously, a larger employee will expend more energy doing the same tasks. The WBGT method assumes the metabolic rate will be proportional to weight or mass. The metabolic rate corrected for weight, M COR, is given by,M COR = M weight154 lb= Mmass70 kg.TLVThe maximum recommended WBGT for a given metabolic rate is called the "Threshold Limit Value" or "TLV." It is given as a function of corrected metabolic rate in the figure below. For example, the TLV for a metabolic rate of 200 W, is a WBGT = 30O C.Figure 1: ACGIH Threshold Limit Values for Heat StressIf the data point falls below the dotted line, nearly all fit employees should not sufferheat-related illnesses under these conditions, and no action is recommended.If the data point falls anywhere above the dotted line, we are above the action level. It is likely that some employees may experience heat-related illness; and a heat stress management program is recommended.If the data point falls above the solid line, we have exceeded the TLV, or maximum recommended WBGT. Engineering controls (e.g. increased ventilation or insulation), administrative controls (e.g. a work/rest or employee rotation regiment), or personal protective equipment (PPE) such as reflective clothing or ice-pack vests should be considered in addition to the implementation of a heat stress management program. Care must be taken when implementing abatement methods. Proper abatement requires an understanding of the nature of the heat load. For example, if the air is very humid (wet bulb temperature close to dry bulb temperature) and the dry bulb temperature exceeds that of the surface of the skin (35O C or 95O F) increasing air velocity will actually worsen heat stress conditions. A certified industrial hygienist (CIH) knowledgeable about heat stress should be consulted. For very high heat stress loads, the Heat Stress Index (HSI) method of evaluation is preferred over the WBGT method. The HSI method requires much more complicated calculations, but gives a better understanding of the nature of the heat load. The HSI method also allows calculation of the maximum allowable exposure time (AET) for very high heat stress levels. AcclimatizationIn previous editions of the Threshold Limit Values and Biological Exposure Indices handbook, the ACGIH referred to the dotted line as "the TLV for unacclimatized workers." Workers who have not been acclimatized are likely to suffer heat strain under heat stress conditions above the action limit, even if they are still below the TLV. Acclimatization is defined by the ACGIH as "a gradual physiological adaptation that improves an individual's ability to tolerate heat stress." Employees are considered "acclimatized" if they have spent two consecutive hours during five (5) out of seven (7) consecutive days in the hot environment. In order to become acclimatized, employees must be doing the work expected under the heat stress condition they will encounter. Some employees may require ten (10) out of 14 consecutive days to become fully acclimatized.Noticeable loss of acclimatization can occur in as little as four (4) days without working in the hot environment. Acclimatization can be lost completely in three (3) to four (4) weeks. Employees returning from vacation or from shift rotations with more than four (4) days off, should be given the opportunity to again become acclimatized before returning to full work expectations in hot environments.ExampleIn practice, the employee is followed throughout the day. The time spent in eachlocation is recorded along with the WBGT in that location. The WBGT is then averaged for the hottest continuous 60 minute period. Suppose the following were observed,WBGTLocation Time(min)O C O F1. Bench Grinder 20 29.4 84.92. Office 15 27.7 81.93. Heat Treat 20 32.2 90.04. Bench Grinder 30 28.9 84.05. Heat Treat 20 33.3 91.96. Bench Grinder 20 30.6 87.1On inspection, it is seen that the hottest continuous 60 minutes were spent in locations 3, 4, and 5. Locations 3, 5, and 6 were the hottest observed, however, exposure at these temperatures was not continuous. The time spent at 84 O F can not simply be ignored. The total time spent in locations 3, 4, and 5 was 70 minutes. A 60-minute average is required. Therefore ten minutes of this total time must be excluded from the calculation. Since the period averaged must be continuous, the ten minutes must be "shaved off" either the beginning or the end of the time period, not from the middle. Since location 3 is observed to be cooler than location 5, the time excluded from the average must be the first ten minutes spent in period 3. Suppose the employee entered location 1 at 10:20 am. The hottest one-hour period of the day was 11:05 am to 12:05 pm. The time-weighted average Wet Bulb Globe Temperature, WBGT TWA, is therefore,WBGT TWA = WBGT3 (t3) + WBGT4 (t4) + WBGT5 (t5) t3 + t4 + t5= 32.2 O C (10 min) + 28.9 O F (30 min) + 33.3 O F (20 min) 10 min + 30 min + 20 min= 30.9 O C .Notice the denominator in the above expression adds to 60 minutes. This must always be the case when using the WBGT method of heat stress assessment.Our employee moved between the grinding bench and heat treat. After observing the work done in these areas, we characterize the work as moderate, 300 W. If our employee weighs approximately 180 lb, the corrected metabolic rate is given byM COR = M weight154 lb= 300 W180 lb154 lb= 351 W .The data for our example (WBGT = 30.9 O C and M = 351 W) are plotted on Figure 1 above. The point for our example is well above the TLV, engineering controls andprogram implementation are recommended.Heat Stress Management ProgramsUnfortunately, there are no standards detailing the elements of an effective heat stress program. OSHA has however, prepared a Safety and Health Guide for Heat Stress. It can be found at /SLTC/emergencypreparedness/guides/heat.html.A program should include, at a minimum, employee training on heat stress and its effect on the body, a buddy system, a mandatory rehydration schedule, and regular monitoring of the WBGT. Emergency responses for employees suffering heat stress should be included in the employer's Emergency Response Program.The importance of the buddy system and a rehydration schedule cannot be over stressed. The buddy system means that someone trained in the effects of heat stress is watching every employee for signs of heat strain. This can be pairing of employees to watch each other, or assignment of one individual to watch over a number of employees. Remember, however, the watchers also need watching. Loss of mental faculty is among the earliest symptoms of heat stress. Employees suffering even severe heat strain are likely not to be aware of their condition. A rehydration schedule usually includes a requirement to drink at least one cup of water ever 20 minutes. Thirst is not a good indicator of dehydration. Adherence to the mandatory rehydration schedule should be confirmed by the buddy.。
美国政府工业卫生学家会议_ACGIH_1998年生产环境化学物质阈限值
【编者按】 美国政府工业卫生学家会议(ACGIH)1998年公布了“关于化学物质和物理因素的阈限值和/或生物接触限值”;其中化学物质阈限值部分与以往历年所公布的内容相比有不少改动:增添了“阈限值依据”即关键性效应(T LV Basis-Critical effects);改变了以往浓度一律用m g/m3和ppm双重表示的方法,而对粉尘、雾烟等物质用mg/m3,气体类物质用ppm表示;列“附注”,将毒物能经皮吸收、已制订生物接触限值以及致癌程度划分等均予以标出。
为此,我们认为有必要将该“化学物质阈限值”部分有重点地予以译出,供大家在实际工作中参考。
美国政府工业卫生学家会议(ACGIH)1998年生产环境化学物质阈限值名称(化学文摘登记号)时间加权平均浓度短时间接触限值/上限值(C)附注阈限值依据(关键性效应) 乙醛Acetald ehydc(75-07-0)-C25ppm A3刺激 乙酸Acctic acid(64-19-7)10ppm15p pm-刺激 乙酸酐Acctic anhyd ride(108-24-7)5ppm--刺激 丙酮Aceton e(67-64-1)500ppm750pp m A4BEI刺激 丙酮氰醇,以(CN计)Acctonc cyan oh ydrin(75-86-5)-C4.7ppm皮中枢神经系统;缺氧 乙腈Aceton itr ile(75-05-8)40ppm60p pm A4肺;缺氧 苯乙酮Acctoph cnone(98-86-2)10ppm--刺激;眼 四溴化乙炔Acctylcnc tctrabromide(79-27-6)1ppm--刺激;肝 乙酰水杨酸Acctylsalicylic acid(Aspirin)(50-78-2)5mg/m3--血液 丙烯醛Acrolcin(107-02-8)-C0.1ppm皮,A4刺激;肺水肿 丙烯酰胺Acrylamide(79-06-1)0.03mg/m3-皮,A3中枢神经系统;皮炎 丙烯酸Acrylic acid(79-10-7)2ppm-皮,A4刺激;生殖作用 丙烯腈Acrylon itr ile(107-13-1)2ppm-皮,A2癌 己二酸Adipic acid(124-04-9)5mg/m3--神经毒性;胃肠;刺激 己二腈Adiponitrile(111-69-3)2ppm-皮肺 艾氏剂Aldrin(309-00-2)0.25mg/m3-皮,A3肝#烯丙醇Allyl alcohol(107-18-6)2ppm4pp m皮刺激 烯丙基氯Allyl chloride(107-05-1)1ppm2pp m A3肝*烯丙基缩水甘油醚Allyl glycidyl eth er(106-92-3)1ppm-A4刺激;皮炎;致敏 烯丙基二丙二硫Allyl propyl dis ulfide(2179-59-1)2ppm3pp m-刺激 铝Alum inum(7429-90-5) 铝尘mctal dust10mg/m3--刺激 铝焦粉pyro pow dcrs5mg/m3--肺 铝焊接烟wclding fumcs5mg/m3--刺激 可溶性铝盐solub lc salts2mg/m3--刺激 烷基铝alkyls2mg/m3--刺激 氧化铝Aluminum oxide(1344-28-1)10mg/m3-A4肺,刺激 4-氨基二苯4-Aminodiphcnyl(92-67-1)--A1癌(膀胱) 2-氨基吡啶2-Am inopyridine(504-29-0)0.5ppm--中枢神经系统 3-氨基-1,2,4-三唑3-amin o-1,2,4-triazole(61-82-5)0.2mg/m3-A3生殖;甲状腺 氨Ammonia(7664-41-7)25ppm35p pm-刺激 氯化铵烟Ammonium chloridc fume(12125-02-9)10mg/m320mg/m3-刺激 全氟辛酸铵Ammonium perfluorootanoate(3825-26-1)0.01mg/m3-皮,A3肝 氨基磺酰胺Ammonium s ulfam ate(7773-06-0)10mg/m3--刺激 乙胺正戊酯n-Amyl acetate(628-63-7)100ppm--刺激 乙胺另戊酯Sec-Amyl acetate(626-38-0)125ppm--刺激 苯胺及其同系物Anilinc&homologucs(62-53-3)2ppm-皮,A3,BEI缺氧 邻氨基苯甲醚o-An isidine(90-04-0)0.1ppm-皮,A3缺氧 对氨基苯甲醚p-Anisidin e(104-94-9)0.1ppm-皮,A4缺氧 锑及其化合物(以锑计)Antimony&compou nds,(7440-36-0)0.5mg/m3--刺激;肺;心血管系统 三氧化锑产物Antimony triox ide production(1309-64-4)--A2癌(肺);尘肺 安妥( -萘硫脲)ANT U(86-88-4)0.3mg/m3-A4肺;刺激 氩Argon(7440-37-1)---窒息 砷,元素砷Arscnic,clcm cntal&(7440-38-2) 及其无机化合物(以砷计)inorganic compounds,as As0.01mg/m3-A1;BEI癌(肺,皮肤);肺 砷化氢Arsinc(7784-42-1)0.05ppm--血液;肾 石棉,所有形式,Asbestos,all forms(1332-21-4)0.1纤维/ml-A1石棉沉着病,癌#沥青(石油)烟Asphalt(pctroleum)fumes(8052-42-4)(5mg/m3)-(A4)刺激;肺;灼伤 阿特拉津Atrazin e(1912-24-9)5mg/m3-A4刺激 保棉磷Azinph os-mcthyl(86-50-0)0.2mg/m3-皮;A4;BEI胆碱能作用 钡,可溶性化合物(按钡计)Bariu m solu ble compounds,as Ba(7440-39-3)0.5mg/m3-A4刺激;肠胃作用;灼伤;肌毒性 硫酸钡Bariu m s ulfate(7727-43-7)10mg/m3--尘肺(钡尘肺) 苯茵灵Bcnomyl(17804-35-2)10mg/m3-A4皮炎;刺激 苯井蒽Bcnz(a)anth raccne(56-55-3)--A2癌 苯Bcnzcne(71-43-2)0.5ppm 2.5pp m皮;A1;BEI癌 联苯胺Bcnzidine(92-87-5)--皮,A1癌(膀胱) 苯井(b)荧蒽Bcnzo(b)fluoranth ene(205-99-2)--A2癌 3,4-苯并芘Benzo( )pyren e(50-32-8)--A2癌 三氯甲苯Benzotrichloride(98-07-7)-C0.1ppm皮,A2刺激,癌 苯酰氮Bcnzoyl chloride(98-88-4)-C0.5ppm A4刺激 过氧化苯甲酰Bcnzoyl peroxide(94-36-0)5mg/m3-A4刺激 乙酸苄酯Bcnzyl acetate(140-11-4)10ppm-A4刺激 苄基氯Benzyl chloride(100-44-7)1ppm-A3刺激;肺 铍及其化合物Bcryllium&compou nds(7440-41-7)0.002mg/m30.01mg/m3A1癌(肺);铍肺 联苯Biphenyl(92-52-4)0.2ppm--肺 锑化铋 Bismuth tclluride 无掺杂物undoped(1304-82-1)10mg/m3-A4刺激 含硒掺杂物Sc-dopcd5mg/m3-A4刺激;肺 四硼酸钠Bor atcs,tctra,s odium salts(1303-96-4)刺激 无水硼酸盐Anhydrous1mg/m3-- 十水硼酸盐Dccahydrate5mg/m3-- 五水硼酸盐Pentahydrate1mg/m3-- 氧化硼Bor on oxide(1303-86-2)10mg/m3--刺激 三溴化硼Bor on tribrom ide(10294-33-4)-C1ppm-刺激;灼伤 三氟化硼Bor on trifluoride(7637-07-2)-C1ppm-刺激 除草定Bromacil(314-40-9)10mg/m3-A3刺激 溴Bromine(7726-95-6)0.1ppm0.2pp m-刺激 五氟化溴Brominc pcn tafluoride(7789-30-2)0.1ppm--刺激 溴仿Bromoform(75-25-2)0.5ppm-皮;A3刺激;肝 1,3-丁二烯1,3-Bu tadicne(106-99-0)2ppm-A2癌 丁烷Butanc(106-97-8)800ppm--麻醉#正丁醇n-Butanol(71-36-3)-(C50ppm)(皮)刺激;耳毒性;眼作用 另丁醇sec-Butan ol(78-92-2)100ppm--刺激;麻醉;耳毒性 特丁醇tcrt-Butanol(75-65-0)100ppm -A4麻醉;刺激#2-丁氧基乙醇2-Bu tox ycthanol(111-76-2)(25ppm)-皮血液*乙酸正丁酯n -Butyl acctate (123-86-4)150ppm 200pp m -刺激 乙酸另丁酯sec-Butyl acctate(105-46-4)200ppm --刺激#乙酸特丁酯tert-Butyl acctate(540-88-5)200ppm --刺激#丙烯酸正丁酯n -Butyl acrylate (141-32-2)(10ppm )-A 4刺激;致敏 正丁胺n-Butylamine(109-73-9)-C 5ppm 皮刺激 铬酸特丁酯tert-Butyl chromate(CrO 3计)(1189-85-1)-C 0.1m g/m 3皮刺激,肺 正丁基缩水甘油醚n -Butyl g lycidyl ether (2426-08-6)25ppm --刺激;致敏 乳酸正丁酯n-Butylactate(138-22-7)5ppm --刺激,头痛#丁硫醇n-Butyl mcrcaptan(109-79-5)(0.5ppm)--中枢神经系统;刺激;生殖作用 邻另丁基酚o-scc-Bu tylphcnol(89-72-5)5ppm -皮刺激 对特丁基甲苯p-tcrl-Butyl tolucne(98-51-1)1ppm --刺激;中枢神经系统;心血管系统 镉,元素镉及其化合物(以Cd 计)Cadm ium ,elementaland compounds (7440-43-9)0.01mg /m 3-A 2;BEI 癌;肾;金属烟雾热 0.002mg /m 3-A2;BEI 碳酸钙Calcium carb on ate (1317-65-3)10mg /m 3--刺激 铬酸钙Calcium chromate(13765-19-0)0.001mg /m 3-A 2癌 氰氨化钙Calcium cyanamide(156-62-7)0.5mg /m 3-A4刺激;皮炎 氢氧化钙Calcium hyd roxide (1305-62-0)5mg /m 3--刺激 氧化钙Calcium oxide(1305-78-8)2mg /m 3--刺激 硅酸钙Calcium s ilicate(1344-95-2)10mg /m 3-A4刺激 硫酸钙Calcium s ulfate (7778-18-9)10mg /m 3--刺激 樟脑,人工合成Cam phor,synthetie(76-22-2)2ppm 4pp mA 4刺激;哮喘#己内酰胺Cap rolactam (105-60-2)刺激;中枢神经系统 己内酰胺尘dust(1mg /m3)(3mg /m3)A4 己内酰胺蒸气Vapor(5ppm )(10p pm )A 4 敌菌丹Cap tafol(2425-06-1)0.1mg /m 3-皮;A4皮炎;致敏 灭菌丹Cap tan (133-06-2)5mg /m 3-A3刺激西维丹Car baryl(63-25-2)5mg /m 3-A 4胆硷能作用;生殖作用 呋喃丹Car bofu ran(1563-66-2)0.1mg /m 3-A4胆硷能作用 炭黑Carbon b lack (1333-86-4)3.5mg /m 3-A4肺二氧化碳Car bon diox ide(124-38-9)5000ppm 30,000pp m-窒息 二硫化碳Car bon disulfide(75-15-0)10ppm -皮;BEI 心血管系统;中枢神经系统;神经病 一氧化碳Car bon m on oxide(630-08-0)25ppm -BEI 缺氧;心血管系统;中枢神经系统;生殖作用 四溴化碳Car bon tetrabrom ide(558-13-4)0.1ppm 0.3pp m -刺激;肝 四氯化碳Car bon tetrachloride (56-23-5)5ppm 10p pm 皮;A2肝;癌碳酰氟Car bonyl fluoride(353-50-4)2ppm 5pp m -刺激;肺;氟中毒 几茶酚Catcchol(120-80-9)5ppm -皮;A3刺激;中枢神经系统;皮炎 纤维素Cellulos e (9004-34-6)10mg /m3--刺激 氢氧化铯Ces ium hydroxide(21351-79-1)2mg /m 3--刺激 氯丹Chlor dane(57-74-9)0.5mg /m 3-皮;A3癫痫发作,肝 氯化茨烯Chlorin atcd camph ene (8001-35-2)0.5mg /m 3-皮;A3癫痫发作,肝 氯化二苯基氧chlor inated diphen yl ox ide(31242-93-0)0.5mg /m 3--氯痤疮,肝 氯Chlor ine(7782-50-5)0.5ppm 1pp m A4刺激 二氧化氯Chlorin e dioxide (10049-04-4)0.1ppm 0.3pp m -刺激;支气管炎 三氟化氯Chlorin e trifluoride(7790-91-2)-C 0.1ppm -刺激;肺 氯乙醛Chloroacetaldehyde(107-20-0)-C 1ppm-刺激 氯丙酮Chloroaccton e(78-95-5)-C1ppm-刺激 氯苯乙酮2-chloroacetophenone(532-27-4)0.05ppm-A4刺激;致敏 氯乙酰氯Chloroacctyl chlorid e(79-04-9)0.05ppm0.15pp m皮刺激;肺 氯苯Chlor ob enzene(108-90-7)10ppm-A3;BEI肝 邻氨苄又丙二腈o-C hlorobenzylid ene malononitrile(2698-41-1)-C0.05ppm皮,A4刺激 氯溴甲烷Chlorobr om omcthane(74-97-5)200ppm--中枢神经系统;肝 一氯二氟甲烷Chlorodiflu or om cthane(75-45-6)1000ppm-A4心血管系统 氯联苯(42%氯)Chlorodiphenyl(42%chlorine)(53469-21-9)1mg/m3-皮刺激;氯痤疮;肝 氯联苯(54%氯)Chlorodiph enyl(54%chlorine)(11097-69-1)0.5mg/m3-皮;A3刺激;氟痤疮;肝 氯仿Chlor oform(67-66-3)10ppm-A3心血管系统;肝,肾;中枢神经系统;生殖作用 双氯甲醚bis-(Ch loromcth yl)ether(542-88-1)0.001ppm-A1癌(肺) 氯甲甲醚Chlorom ethyl methyl ether(107-30-2)--A2癌(肺);刺激 1-氯-1-硝基丙烷1-Chlo ro-l-nitropropane(600-25-9)2ppm--刺激;心血管系统;肝;肾 一氯五氟乙烷Chloropcntafluorocthan e(76-15-3)1000ppm--心血管系统 氯化苦Chloropicin(76-06-2)0.1ppm-A4刺激;肺 -氯丁二烯 -Chlorprene(126-99-8)10ppm-皮刺激;中枢神经系统;肝、血液 2-氯丙酸2-Chloropropionic acid(598-78-7)0.1ppm-皮刺激;生殖作用 邻氯苯乙烯o-Chloros tyrene(2039-87-4)50ppm75p pm-肝;肾;中枢神经系统 邻氯甲苯o-Chlorotoluene(95-49-8)50ppm--刺激 毒死俾Chlorp yritos(2921-88-2)0.2mg/m3-皮;A4;BEI胆硷能作用 铬铁矿处理(铬酸盐)按Cr计Ch romitc ore proccss ing(Chromatc)asCr0.05mg/m3-A1癌(肺) 铬,金属铬及其无机化合物,按Cr计C hromium,mclaland inorgan ic compoun ds(7440-47-3) 金属铬及其三价化合物m clal an d Cr lllcompounds0.5mg/m3-A4刺激;皮炎 水溶性铬六价化合物w atcr-s oluble CrVl compoun ds0.05mg/m3-A1;BEI癌;肝;肾 不溶性铬六价化合物in solub lc Cr VI compounds0.01mg/m3A1癌;刺激 铬酰氯Chromyl chloride(14977-61-8)0.025ppm--刺激;肾;肝 艹屈C hryscne(218-01-9)--A3皮肤 二氯二甲吡啶酚Clopidol(2971-90-6)10mg/m3-A4刺激#煤尘Coal du st*#烟煤(Bitu minous)0.9mg/m3-(A4)肺纤维化;尘肺;肺功能*#无烟煤(Anthracite)0.4mg/m3-(A4)肺纤维化;尘肺;肺功能 煤焦油沥青挥发物,按苯溶解物计Coal tar pitchvolatilcs(65996-93-2)0.2mg/m3-A1癌 钴,无素钴及其无机化合物,按Co计Cobalt,clcm cntaland in organic compounds,as C o(7440-48-4)0.02mg/m3-A3;BEI哮喘;肺;心血管系统 羰基钴,按Co计Cobalt carbonyl,as Co(10210-68-1)0.1mg/m3--肺水肿 氢羟基钴(按Co计)Cobalt hydrocarbonyl(as Co),(16842-03-8)0.1mg/m3--肺水肿 铜Copper(7440-50-8)刺激;肠胃系统;金属烟雾热 铜烟Fumc0.2mg/m3-- 铜尘及铜雾,按Cu计Dus t&m ists1mg/m3-- 棉尘,原棉Cotton dus t,r aw0.2mg/m3--肺,肺屑沉着病 甲酚(各种异构体)Crcs ol(1319-77-3)5ppm-皮皮炎;刺激;中枢神经系统 丁烯醛Crotonaldeh yd e(4170-30-3)-C0.3ppm皮,A3刺激 育畜磷Crufomate(299-85-5)5mg/m3-A4;BEI胆硷能作用#异丙基苯Cumcne(98-82-8)50ppm-(皮)麻醉 氨基氰Cyan amid e(420-04-2)2mg/m3--刺激 氰Cyanogcn(460-19-5)10ppm--刺激 氯化氰Cyan ogcn chloride(506-77-4)-C0.3ppm-刺激;肺功能#环己烷Cycloh cxane(110-82-7)(300ppm)--刺激 环己醇Cycloh exanol(108-93-0)50ppm-皮;刺激;中枢神经系统 环己酮Cycloh cxanone(108-94-1)25ppm-皮;A4刺激;肝 环己烯Cycloh cxcne(110-83-8)300ppm--刺激 环己胺Cycloh cxylamin e(108-91-8)10ppm-A4刺激 三次甲基三硝基胺Cyclonite(121-82-4)0.5mg/m3-皮,A4刺激,中枢神经系统,肝,血液 环戊二烯Cyclop cntad icne(542-92-7)75ppm--刺激 环戊烷Cyclop cntane(287-92-3)600ppm--刺激,麻醉 环己锡,杀蟥锡Cyhcx atin(13121-70-5)5mg/m3-A4刺激 2,4-滴2,4-D(94-75-7)10mg/m3-A4刺激 滴滴涕DDT(50-29-3)1mg/m3-A3癫痫发作,肝 癸硼烷Dccaboran e(17702-41-9)0.05ppm0.15pp m皮中枢神经系统;肺功能 内吸磷Dcmcton(8065-48-3)0.01ppm-皮,BEI胆硷能作用 双丙酮醇Diaccton c alcohol(123-42-2)50ppm--刺激 二嗪农Diazinon(333-41-5)0.1mg/m3-皮;A4;BEI胆硷能作用 重氮甲烷Dcazom cthane(334-88-3)0.2ppm-A2刺激;癌(肺) 乙硼烷Diborane(19287-45-7)0.1ppm--中枢神经系统;肺功能 二丁氨基乙醇2-N-Dibu tylaminocthanol(102-81-8)0.5ppm-皮刺激;胆硷能作用 2,6-二特丁基一对一甲酚2,6-Di-tert-butyl-p-3-A4刺激cresol(128-37-0)10mg/m 磷酸二丁一苯酯Dibu tyl phcn yl phos phale(2528-36-0.3ppm-皮;BEI刺激;胆硷能作用1) 磷酸二丁酯Dibu tyl ph osphate(107-66-4)1ppm2pp m-刺激 邻苯二甲酸二丁酯Dibutyl ph th alate(84-74-2)5mg/m3--生殖作用;刺激 二氮乙炔Dichloroacctylene(7572-29-4)-C0.1ppm A3肠胃作用;神经毒性;刺激 邻二氮苯o-Dichlorobenzcn e(95-50-1)25ppm50p pm A4刺激;肝 对二氯苯p-Dichlorobcnzcne(106-46-7)10ppm-A3刺激;肾 3,3 -二氯联苯胺3,3 -Dich lorobenzidine(91-94-1)--皮,A3刺激;皮炎 1,4-二氯-2-丁烯1,4-Dichloro-2-butcne(764-41-0)0.005ppm-皮,A2癌;刺激 二氯二氟甲烷Dichlorodifluoromethane(75-71-8)1000ppm-A4心血管系统 1,3-二氯-5,5-二甲基海因1,3-Dichloro-5,5-dimcthyl0.2mg/m30.4mg/m3-刺激hydantoin(118-52-5) 1,1-二氯乙烷1,1-Dichlorocth ane(75-34-3)100ppm-A4肝;肾;刺激 1,2-二氯乙烯1,2-Dichlorocthylcne(540-59-0)200ppm--肝 二氯乙醚Dichlorocth yl cther(111-44-4)5ppm10p pm皮,A4刺激;肺 二氯一氟甲烷Dichlorofluoromethane(75-43-4)10ppm--肝 1,1-二氯-1-1硝基乙烷1,1-Dichloro-1-n itr oc-2ppm--刺激th ane(594-72-9) 1,3-二氯丙烯1,3-Dich loropropene(542-75-6)1ppm-皮,A4刺激 2,2-二氯丙酸2,2-Dich loropropionic acid(75-99-0)1ppm--刺激 二氯四氟乙烷Dichlorotetrafluorocthane(76-14-2)1000ppm-A4心血管系统;麻醉;窒息 敌敌畏Dichlorvos(62-73-7)0.9mg/m3-皮;A4;BEI胆硷能作用 百治磷Dicrotoph os(141-66-2)0.25mg/m3-皮,A4;BEI胆硷能作用 二聚环戊二烯Dicyclopentadicne(77-73-6)5ppm--刺激 二茂基铁Dicyclopcntadienyl iron(102-54-5)10mg/m3--血液;肝 狄氏剂Dicldrin(60-57-1)0.25mg/m3-皮;A4肝;中枢神经系统 二乙醇胺Dicth an olam ine(111-42-2)2mg/m3-皮肝;肾;血液 二乙胺Diethylamine(109-89-7)5ppm15p pm皮;A4刺激 2-二乙氨基乙醇,2-Dieth yamin octhanol(100-37-8)2ppm-皮刺激;中枢神经系统 二乙撑三胺dicthylcne triamine(111-40-0)1ppm-皮刺激;致敏#邻一苯二甲酸二-2-乙基己酯Di(2-eth ylthexyl)p h-5mg/m3(10mg/m3)A3刺激th alate(DEHP)(117-81-7)*二乙基甲酮Diethyl ketone(96-22-0)200ppm300pp m-刺激;麻醉#邻苯二甲酸二乙酯Dieth yl phthalate(84-66-2)5mg/m3-(-)刺激;神经毒性 二氟二溴甲烷Difluorodib romomcthane(75-61-6)100ppm--刺激;肝;中枢神经系统 缩水甘油醚Diglycidyl cth er(DGE)(2238-07-5)0.1ppm-A4刺激;生殖作用;血液 二异丁基甲酮Diis obutyl ketone(108-83-8)25ppm--刺激 二异丙胺diisopropylamin e(108-18-9)5ppm-皮视觉;刺激 N,N-二甲基乙酰胺N,N-Dimethylaeetamid e(127-19-5)10ppm-皮;A4;BEI生殖作用;肝 二甲胺Dim cthylamine(124-40-3)5ppm15p pm A4刺激 二甲基苯胺Dimcthylanilin e(121-69-7)5ppm10p pm皮;A4;BEI缺氧;神经毒性 二甲基甲氨酰氯Dimcthyl carbamoyl chloride(79-44-7)--A2癌(肺) 二甲基乙氧基硅烷Dimeth ylethox ysilane(14857-34-0.5ppm 1.5pp m-刺激;头痛2) 二甲基甲酰胺Dimethylformamide(68-12-2)10ppm-皮;A4;BEI肝 1,1-二甲基肼1,1-d imcthylhydrazine(57-14-7)0.01ppm-皮,A3刺激,瘤形成 邻苯二甲酸二甲酯Dimcthylphth alate(131-11-3)5mg/m3--刺激 硫酸二甲酯Dimcthyl sulfate(77-78-1)0.1ppm-皮,A3刺激 二硝基甲苯酰胺Dinitolm ide(148-01-6)5mg/m3-A4刺激;肝 二硝基苯(各种异构体)d initrobenz ene(all is om crs)(528-29-0;99-65-0;100-25-4)0.15ppm-皮;BEI缺氧 二硝基邻甲苯酚dinitrol-o-cresol(534-52-1)0.2mg/m3-皮代谢紊乱 二硝基甲苯dinitrotolucn e(25321-14-6)0.2mg/m3-皮;A3;BEI心血管系统;生殖作用;缺氧;肝 敌恶磷Dioxathion(78-34-2)0.2mg/m3-皮;A4;BEI胆硷能作用 二苯胺Diph enylamin e(122-39-4)10mg/m3-A4肝;肾;血液#二烷1,4-Dioxane(123-91-1)(25ppm)-皮;A3肝;肾 二丙二醇甲醚Dipropylcne glycol methyl cth er(34590-100ppm150pp m皮刺激;中枢神经系统94-8) 二丙基甲酮Dipropyl k ctone(123-19-3)50ppm--刺激;肝;肾;神经毒性 杀草快Diquat(2764-72-9)0.5/0.1mg/m3-皮;A4刺激,眼 四乙基秋兰姆Dis ulfiram(97-77-8)2mg/m3--肠胃道系统;心血管系统 乙拌磷Dis ulfoton(298-04-4)0.1mg/m3-皮,BEI胆硷能作用 敌草隆Diur on(330-54-1)10mg/m3-A4刺激,血液 二乙烯苯Divinyl benzene(1321-74-0)10ppm--刺激 金刚砂Emcr y(1302-74-5)10mg/m3--刺激 硫丹Endosu lfan(115-29-7)0.1mg/m3-皮;A4肝;中枢神经系统 异狄氏剂Endrin(72-20-8)0.1mg/m3-皮,A4中枢神经系统;肝 安氟醚Enflurane(13838-16-9)75ppm-A4中枢神经系统;心血管系统 环氧氯丙烷Epich lorohydrin(106-89-8)0.5ppm-皮;A3刺激;肝;肾 伊皮恩EPN(2104-64-5)0.1mg/m3-皮;A4:BEI胆硷能作用 乙醇Ethanol(64-17-5)1000ppm-A4刺激 乙醇胺Ethanolamine(141-43-5)3ppm6pp m-刺激 乙硫磷Ethion(563-12-2)0.4mg/m3-皮;BEI胆硷能作用 2-乙氧基乙醇2-Eth oxycthanol(EGEE)(110-80-5)5ppm-皮;BEI生殖作用 乙酸-2-乙氧乙酯2-Ethoxyethyl acetate(EGEEA)(111-15-9)5ppm-皮;BEI生殖作用 乙酸乙酯Ethyl acctate(141-78-6)400ppm--刺激 丙烯酸乙酯Ethyl acrylate(140-88-5)5ppm15p pm A4刺激;癌;致敏 乙胺Ethylamine(75-04-7)5ppm15p pm皮刺激 乙基戊基甲酮Ethyl am yl ketone(541-85-5)25ppm--刺激#乙苯Ethyl benzen e(100-41-4)100ppm125pp m(-),BEI刺激;中枢神经系统 溴乙烧,乙基溴Ethyl bromide(74-96-4)5ppm-皮;A3肝;肾;心血管系统 乙基丁基甲酮Ethyl butyl ketone(106-35-4)50ppm75p pm-刺激;麻醉 氯乙烷Ethyl ch loride(75-00-3)100ppm-皮;A3肝;中枢神经系统 乙基氰基丙烯酸酯Eth yl cyanoacrylate(7085-85-0)0.2ppm--刺激;麻醉 乙烯Ethylene(74-85-1)--A4窒息 2-氯乙醇Ethylcne ch lorohydrin(107-07-3)-C1ppm皮;A4刺激;肝;肾;肠胃道;心血管系统;中枢神经系统 乙二胺Ethylcncdiamine(107-15-3)10ppm-皮;A4刺激;哮喘;致敏 二溴乙烷Ethylene dibrom ide(106-93-4)--皮;A3刺激;肝;肾 二氯乙烷Ethylene dichloride(107-06-2)10ppm-A4肝;麻醉 乙二醇氯溶胶Ethylene glycol aerosol(107-21-1)-C100mg/m3A4刺激 乙二醇二硝酸酯Ethylene glycol d initrate(628-96-6)0.05ppm-皮心血管系统 环氧乙烷Ethylcne oxide(75-21-8)1ppm-A2肺;肝;肾;血液;中枢神经系统;癌 乙撑亚胺Ethylcnimine(151-56-4)0.5ppm-皮;A3刺激;支气管炎 乙醚Ethyl eth er(60-29-7)400ppm500pp m-刺激;麻醉 甲酸乙酯Ethyl for mate(109-94-4)100ppm--刺激 亚乙基降冰片烯Ethylidene norbornene(16219-75-3)-C5ppm-刺激#乙硫醇Ethyl mercaptan(75-08-1)(0.5ppm)--刺激 N-乙基吗啉N-Ethylmorph oline(100-74-3)5ppm-皮刺激;眼 硅酸乙酯Ethyl silicate(78-10-4)10ppm--刺激;肾 克线磷Fenamiphos(22224-92-6)0.1mg/m3-皮;A4;BEI胆硷能作用 克索磷Fens ulfothion(115-90-2)0.1mg/m3-A4,BEI胆硷能作用 倍硫磷Fenthion(55-38-9)0.2mg/m3-皮;A4;BEI胆硷能作用 福美铁Febram(14484-64-1)10mg/m3-A4刺激 钒铁尘Ferrovanadium dust(12604-58-9)1mg/m33mg/m3-刺激 氟化物,以氟计Fluorides,asF 2.5mg/m3-A4;BEI刺激;骨;氟中毒 氟Fluorine(7782-41-4)1ppm2pp m-刺激 地虫磷Fon ofos(944-22-9)0.1mg/m3-皮;A4;BEI胆硷能作用 甲醛Formaldch yd e(50-00-0)-C0.3ppm A2刺激;癌(鼻) 甲酰铵For mam ide(75-12-7)10ppm-皮刺激;肝 甲酸Formic acid(64-18-6)5ppm10p pm-刺激 糠醛Furfural(98-01-1)2ppm-皮;A3;BEI刺激 糠醇Furfuryl alcohol(98-00-0)10ppm15p pm皮刺激 汽油Gas oline(8006-61-9)300ppm500pp m A3刺激;中枢神经系统 四氢化锗Germanium tetrahydride(7782-65-2)0.2ppm--血液#戊二醛,激活的和非激活的Glutaraldch yd c,activatadand inactivated(111-30-8)-C0.05ppm(-)刺激;致敏 甘油雾Glycerin mist(56-81-5)10mg/m3--刺激 缩水甘油Glycidol(556-52-5)2ppm-A3刺激;瘤形成 谷物尘(燕麦、小麦、大麦)Grain dust(oat,w h eat barley)4mg/m3--刺激;支气管炎,肺功能 石墨(石墨纤维外所有类型)Grap hite(7782-42-5)(allform s exccpt graph ite fib ers)2mg/m3--尘肺 铪 Hafniu m(7740-58-6)0.5mg/m3--肝;刺激 氟烷Haloth ane(151-67-7)50ppm-A4中枢神经系统;心血管系统;肝;生殖作用 氦Helium(7440-59-7)---窒息 七氯Heptachlor和环氧七氯Heptachlor epoxide(1024-57-3)C0.5mg/m3皮;A3中枢神经系统;肝;血液 庚烷(正庚烷)Heptane(n-Hcptan c)(142-82-5)400ppm500pp m-刺激;麻醉 六氯苯Hexach lorobenzen e(118-74-1)0.002mg/m3-皮,A3肝,代谢紊乱 六氯丁二烯Hexach lorobutadiene(87-68-3)0.02ppm-皮,A3刺激;肾 六氯环戊二烯Hexach lorocyclopcntadicne(77-47-4)0.01ppm-A4刺激;肺水肿 六氯乙烷Hcxach lorocthane(67-72-1)1ppm-皮,A3刺激;肝;肾 六氯代萘Hexach loronaphthalen e(1335-87-1)0.2mg/m3-皮肝;氯痤疮 六氟丙酮Hexafluoroacetone(684-16-2)0.1ppm-皮生殖作用;肾 六甲撑二异氰酸酯Hex amethylene diis ocyanate(822-06-0)0.005ppm--刺激;致敏 六甲基磷酸酰胺Hexameth yl phosph or amide(680-31-9)--皮;A3肺 正己烷n-Hex ane(110-54-3)50ppm-皮神经病变;中枢神经系统;刺激 己烷,其它异构体Hexane,othar isomers500ppm1000pp m-中枢神经系统;刺激 1,6-己二胺1,6-Hcxancdiamine(124-90-4)0.5ppm--刺激 1-己烯1-Hexene(592-41-6)30ppm--中枢神经系统;刺激 乙酸另己酯scc-Hexyl acctate(108-84-9)50ppm--刺激 己二醇Hexylene glycol(107-41-5)-C25ppm-刺激 肼Hydrazine(302-01-2)0.01ppm-皮;A3刺激;肝 氢Hgdrogen(1333-74-0)---窒息 氢化三联苯Hydrogcnated terph enyls(61788-32-7)0.5ppm--刺激;肝 溴化氢Hydrogcn bromid e(10035-10-6)-C3ppm-刺激 氯化氢Hrdrogen chloride(7647-01-0)-C5ppm-刺激;腐蚀 氰化氢及氰酸盐类,以氰计Hydrogcn cyanide andcyanide salts as CN 中枢神经系统;刺激;缺氧;肺;甲状腺 氰化氢Hydrogen cyanide(74-90-8)-C4.7ppm皮 氰化钙Calcium cyanide(592-01-8)-C5mg/m3皮 氰化钾Potass ium cyanide(151-50-8)-C5m g/m3皮 氰化钠Sodium cyanide(143-33-9)-C5m g/m3皮 氟化氢(以氟计)Hydrogcn fluoride as F(7664-39-3)-C3ppm-刺激;灼伤;骨;牙;氟中毒 过氧化氢Hydrogcn pcr ox ide(7722-84-1)lppm--刺激;肺水肿;中枢神经系统 硒化氢(以硒计)Hydrogen selenide as Se(7783-07-5)0.05ppm--刺激;肠胃系统#硫化氢Hydrogcn su lfide(7783-06-4)(10ppm)(15p pm)-猝死;刺激;中榴神经系统 氢醌Hydroquinonc(123-31-9)2mg/m3-A3中枢神经系统;皮炎;眼 2-羟丙基丙烯酸酯2-Hydroxypropyl acrylate(999-61-1)0.5ppm-皮刺激 茚Indcnc(95-13-6)10ppm--刺激;肝;肾 铟及其化合物(以In计)Indiu m&compoun ds,as In(7440-74-6)0.1mg/m3--肺水肿;骨;肠胃作用 碘Iodinc(7553-56-2)-C0.1ppm-刺激 磺仿Iod oform(75-47-8)0.6ppm--中枢神经系统;肝;肾;心血管系统 氧化铁尘和烟(Fe2O3)(以铁计)Iron oxide du st&fumc(Fe2O3)as Fe(1309-37-1)5mg/m3-A4尘肺 五羰基铁(以铁计)Iron p entacarbonyl as Fe(13463-40-6)0.1ppm0.2pp m-肺水肿;中枢神经系统 可溶性铁盐(以铁计)Iron s alts,solub le,as Fe1mg/m3--刺激 乙酸异戊酯Is oam yl acetate(123-92-2)100ppm--刺激 异戊醇Isoam yl alcohol(123-51-3)100ppm125pp m-刺激 乙酸异丁醇Is obutyl acctate(110-19-0)150ppm--刺激 异丁醇Isobutyl alcohol(78-83-1)50ppm--刺激;眼 异辛醇Isooctyl alcohol(26952-21-6)50ppm-皮刺激 异佛尔酮Isophorone(78-59-1)-C5ppm A3刺激;麻醉 异佛尔酮二异氰酸酯Is op horonc diisocyanate(4098-71-9)0.005ppm--皮炎;气喘;致敏 异丙氧基乙醇2-Is opropoxyethanol(109-59-1)25ppm-皮血液 乙酸异丙酯Is opropyl acctate(108-21-4)250ppm310pp m-刺激#异丙醇Isopropyl alcohol(67-63-0)(400ppm)(500pp m)-刺激 异丙胺Isopropylaminc(75-31-0)5ppm10p pm-刺激 N-异丙基苯胺N-Isopropylanilin e(768-52-5)2ppm-皮血液 异丙醚Isopropyl cther(108-20-3)250ppm310pp m-刺激 异丙基缩水甘油醚Isopropyl glycidyl ether(IGE)(4016-14-2)50ppm75p pm-刺激;皮炎 高岭土Kaolin(1332-58-7)2mg/m3-A4尘肺 乙烯酮Kcten e(463-51-4)0.5ppm 1.5pp m-肺刺激;肺水肿 铅,无素铅及其无机化合物(以铅计)Lcad,clcmen tal and Inorgan ic compound s,as Pb(7439-92-1)0.05mg/m3-A3;BEI中枢神经系统;肠胃道;血液,肾;生殖作用 砷酸铅(以Pb3(As O4)2计),Lead arsenatc as pb3 (As O4)2(7784-40-9)0.15mg/m3-BEI肠胃道;中枢神经系统;肾;生殖作用 铬黄(以铅计)Lead chromatc as p b(7758-97-6)0.05mg/m3-A2;BEI癌;心血管系统;生殖作用 (以铬计)as Cr0.012mg/m3-A2 林丹Lindanc(58-89-9)0.5mg/m3-皮,A3中枢神经系统;肝 氢化锂Lithium hydridc(7580-67-8)0.025mg/m3--刺激 液化石油气L,P,G,(Liquified pctr oleum gas)(68476-85-7)1000ppm--窒息 碳酸镁M agncs ite(546-93-0)10mg/m3--刺激;尘肺 氧化镁烟雾M agncs ium ox ide fume(1309-48-4)10mg/m3--刺激;金属烟雾热 马拉硫磷M alath ion(121-75-5)10mg/m3-皮;A4;BEI,胆硷能作用;中枢神经系统;神经病;视力 马来酸酐M aleic anhyd ride(108-31-6)0.25ppm--刺激;哮喘 锰,元素锰及其无机化合物(以锰计)M angancse,elemeatal an d lnorgan ic compound s,as M n(7439-96-5)0.2mg/m3--中枢神经系统(锰中毒);肺;生殖作用 茂基三羰基锰(以锰计)M anganes c cyclopen tadienyl tri-carbonyl as M n(12079-65-1)clopen la-dionyl tricarbonyl as M n 0.1mg/m3-皮中枢神经系统;肺水肿 汞(以Hg计)M ercury as H g(7439-97-6) 烷基化合物Alkyl com pounds0.01mg/m30.03mg/m3皮中枢神经系统 芳香基化合物Aryl compounds0.1mg/m3-皮中枢神经系统;神经病;视力;肾 无机形式,包括金属汞inorganic form s in clud ingmetallic mercury 0.025mg/m3-皮;A4;BEI中枢神经系统;肾;神经病;视觉;生殖作用;肠胃道 异丙叉丙酮M es ityl ox ide(141-79-7)15ppm25p pm-刺激;麻醉;肝;肾 甲基丙烯酸M cthacr ylic acid(79-41-4)20ppm--刺激#甲醇M eth anol(67-56-1)200ppm250pp m皮;BEI神经病;视力;中枢神经系统 灭多虫M eth om yl(16752-77-5) 2.5mg/m3-A4;BEI胆硷能作用 甲氧氯M eth ox ychlor(72-43-5)10mg/m3-A4中枢神经系统;肝 2-甲氧基乙醇2-M ethox yethanol(EGM E)(109-86-4)5ppm-皮;BEI 血液;生殖作用;中枢神经系统 2-甲氧基乙基醋酸酯2-M ethoxyethyl acetate(EGM E A)(110-49-6)5ppm-皮;BEI血液;生殖作用;中枢神经系统 4-甲氧基苯酚4-M cthoxyp hcnol(150-76-5)5mg/m3--眼;去色素作用 乙酸甲酯M cthyl acctate(79-20-9)200ppm250pp m-刺激;麻醉;神经病(眼) 甲基乙炔methyl acctylen e(74-99-7)1000ppm--麻醉 甲基乙炔-丙二烯混合物M ethyl acctylene-propadienemix tu re(M APP)1000ppm1250pp m-麻醉 丙烯酸甲酯M eth yl acr ylate(96-33-3)2ppm-皮;A4刺激 甲基丙烯腈mcthylacrylonitrile(126-98-7)1ppm-皮刺激;中枢神经系统 甲缩醛M eth ylal(109-87-5)1000ppm--刺激;中枢神经系统 甲胺M eth ylamine(74-89-5)5ppm15p pm-刺激 甲基正戊基甲酮M ethyl n-amyl ketone(110-43-0)50ppm--刺激 N-甲基苯胺N-M eth yl aniline(100-61-8)0.5ppm-皮;BEI缺氧;血液 溴甲烷M eth yl bromide(74-83-9)1ppm-皮肺水肿;神经毒性;中枢神经系统 甲氧基特丁烷M cthyl-tert b utyl ether(1634-04-4)40ppm-A3刺激;肾;生殖作用 甲基正丁基甲酮M ethyl n-b utyl ketone(591-78-6)5ppm10p pm皮神经病 氯甲烷M eth yl chlor ide(74-87-3)50ppm100pp m皮,A4肾;中枢神经系统;生殖作用 三氯乙烷M cthyl chloroform(71-55-6)350ppm450pp m A4;BEI 麻醉;中枢神经系统;肝;肾;心血管系统;皮炎 甲基2-氰基丙烯酸酯M ethyl2-cyanoacrylatc(137-05-3)0.2ppm--刺激;皮炎 甲基环己烷M eth ylcyclohexan e(108-87-2)400ppm--麻醉;刺激 甲基环己醇M eth ylcyclohexan ol(25639-42-3)50ppm--刺激;麻醉;肝;肾 邻甲基环己酮O-M ethylcyclohexanone(583-60-8)50ppm75p pm皮刺激;麻醉 2-甲基茂基三茂羰基锰(以锰计)(12108-13-3)0.2mg/m3-皮中枢神经系统;肝;肾 2-M cth ylcyclopentadienyl mangan es e tr icarbonyl as M n 甲基内吸磷M eth yl d emeton(8022-00-2)0.5mg/m3-皮;BEI刺激;胆硷能作用 甲叉双苯基异氰酸酯M eth ylen e bisp henyl is ocyanate(M DI)(101-68-8)0.005ppm--刺激;肺水肿;致敏 二氯甲烷M ethylcne chloride(Dichloromethane)(75-09 -2)50ppm-A3中枢神经系统;缺氧 4,4 -甲叉双-(2-氯苯胺)4,4 M cthylene bis(2-chloroaniline)(M BOCA) (101-14-4)0.01ppm-皮,A2;BEI缺氧;肾;癌(膀胱) 甲叉双(4-环己基异氰酸酯)M ethylene b is(4-cyclo)hex ylisocyanate)(5124-30-1)0.005ppm--刺激;致敏 4,4 -亚甲基二苯胺4,4 M ethylene dianiline(101-77-9)0.1ppm-皮,A3肝 甲基乙基甲酮M ethyl ethyl keton e(M EK)(78-93-3)200ppm300pp m BEI刺激;中枢神经系统 甲乙酮过氧化物M ethyl cthyl ketone peroxide(1338-23-4)-C0.2ppm-刺激;肝;肾 甲酸甲酯M eth yl formate(107-31-3)100ppm150pp m-刺激;麻醉;肺水肿 甲基肼M eth yl hydrazine(60-34-4)0.01ppm-皮;A3刺激;肝 甲基碘(碘甲烷)M ethyl iodid e(74-88-4)2ppm-皮中枢神经系统;刺激 甲基异戊基甲酮M ethyl is oamyl k ctone(110-12-3)50ppm--刺激;麻醉;肝;肾 甲基异丁基甲醇M ethyl is obutyl carbinol(108-11-2)25ppm40p pm皮刺激;感觉缺失 甲基异丁基甲酮M ethyl is obutyl ketone(108-10-1)50ppm75p pm BEI刺激;麻醉;肝;肾 异氰酸甲酯M eth yl is ocyanate(624-83-9)0.02ppm -皮刺激;肺水肿;致敏 甲基异丙基甲酮M ethyl is opropyl ketone (563-80-4)200ppm --刺激;麻醉#甲硫醇M eth yl mercaptan(74-93-1)(0.5ppm )--刺激,中枢神经系统 甲基丙烯酸甲酯M ethyl m ethacrylate(80-62-6)100ppm -A4刺激;皮炎 甲基1605M cthyl parathion (298-00-0)0.2mg /m 3-皮;A4;BEI 胆硷能作用 甲基正丙基甲酮M ethyl pr opyl k etone(107-87-9)200ppm 250pp m -刺激;麻醉 硅酸甲酯M eth yl s ilicate (681-84-5)1ppm --眼(严重);肺 -甲基苯乙烯 -M eth yl styren e(98-83-9)50ppm 100pp m -刺激;皮炎;中枢神经系统 赛克津M etrib uzin(21087-64-9)5mg /m 3-A4贫血 速灭磷M evin phos(7786-34-7)0.09mg /m 30.27mg/m 3皮;BEI 胆硷能作用 云母M ica(12001-26-2)3mg /m 3--尘肺 钼(按钼计)M olybdenum as M o (7439-98-7) 可溶性化合物Soluble comp ou nds 5mg /m 3--刺激;代谢紊乱 不溶性化合物insolu ble com pounds10mg /m 3--刺激 久效磷M onocrotophos (6923-22-4)0.25mg /m 3-皮;A4;BEI 胆硷能作用 吗啉M orpholine(110-91-8)20ppm -皮,A4刺激;视力 二溴磷Naled (300-76-5)3mg /m 3-皮;A 4;BEI 胆硷能作用;皮炎 萘Nap hthalene(91-20-3)10ppm 15p pm A 4刺激;眼;血液 -萘胺 -Nphthylamine(91-59-8)--A1癌(膀胱) 镍Nick cl*金属镍M etal(7440-02-0)1.5mg /m 3-A5皮炎;尘肺;肾*不溶性化合物(以镍计)insolub le com pounds as Ni 0.2mg /m 3-A 1癌(肺);刺激;皮炎*可溶性化合物(以镍计)soluble comopoun ds as Ni 0.1mg /m 3-A 4中枢神经系统;刺激;皮炎 羰基镍(以镍计)Nickel carbonyl as Ni(13463-39-3)0.05ppm --刺激;中枢神经系统 烟碱Nicotine (54-11-5)0.5mg /m 3-皮心血管系统;肠胃道功能,中枢神经系统 四氯草定Nitrapyrin (1929-82-4)10mg /m 320mg/m 3A4肝 硝酸Nitric acid(7697-37-2)2ppm 4pp m -刺激;腐蚀;肺水肿 一氧化氮Nitric oxide(10102-43-9)25ppm -BEI 缺氧;刺激;发绀 对硝基苯胺p-Nitroaniline(100-01-6)3mg /m 3-皮;A4;BEI 发绀,缺氧,贫血,肝;刺激硝基苯Nitrobenz ene(98-95-3)1ppm -皮;A 3;BEI发绀;缺氧;肝;神经毒性;刺激;皮炎 对硝基氯苯p-Nitrochlor ob enzene(100-00-5)0.1ppm -皮,A3;BEI 缺氧;血液;肝 4-硝基二苯4-Nitrodiphen yl (92-93-3)--皮,A 2癌(膀胱) 硝基乙烷Nitroethane(79-24-3)100ppm --刺激;麻醉;肝 氮Nitrogcn(7727-37-9)---窒息 二氧化氮Nitrogen dioxide(10102-44-0)3ppm 5pp m A4刺激;肺水肿 三氟化氮Nitrogen trifluoride(7783-54-2)10ppm -BEI 缺氧;血液;肝;肾 硝化甘油Nitroglycerin (NG )(55-63-0)0.05ppm -皮心血管系统 碱式硫化镍(以镍计)Nick el subs ulfide (asNi )(12035-72-2)0.1mg /m 3-A1癌(肺);刺激;皮炎 硝基甲烷Nitromethane (75-52-5)20ppm --刺激;麻醉;肝;甲状腺;血液;神经病 1-硝基丙烷1-Nitropropane(108-03-2)25ppm -A 4刺激;肝 2-硝基丙烷2-Nitropropane(79-46-9)10ppm -A3刺激;肝 N-亚硝基二甲胺N-Nitrosodimcth ylamine(62-75-9)--皮;A3肝 硝基甲苯Nitrotolucne(88-72-2) (99-08-1) (99-99-0)2ppm-皮;BEI缺氧;发绀 一氧化二氮Nitrous oxide(10024-97-2)50ppm-A4生殖作用;血液;神经病;窒息 壬烷(所有异构体)Non anc,all isomcrs(111-84-2)200ppm--中枢神经系统;麻醉;皮炎;肺 八氯化萘Octachloronaphthalcne(2234-13-1)0.1mg/m30.3mg/m3皮肝;皮炎#辛烷Octan c(111-65-9)300ppm(375pp m)-刺激;麻醉#矿物油雾Oil M ist,mincral5mg/m3(10mg/m3)-肺 四氧化钺(以钺计)Os mium tetroxide,as Os(20816-12-0)0.0002ppm0.0006pp m-刺激;视力 草酸Oxalic acid(144-62-7)1mg/m32mg/m3-刺激;灼伤 二氟化氧Oxygen difluoride(7783-41-7)-C0.05ppm-刺激;肺水肿;肾 臭氧Ozonc(10028-15-6)---肺功能;刺激;头痛 重劳动0.05ppm- 中等劳动0.08ppm-- 轻劳动0.1ppm-- 石蜡烟雾Paraffin w ax fume(8002-74-2)2mg/m3--刺激 百草枯Paraquat(4685-14-7)肺水肿;肾;肝;肺纤维化 百草枯总尘量total dust0.5mg/m3-- 呼吸性粉尘res pirab le fraction0.1mg/m3-- 对硫磷Parathion(56-38-2)0.1mg/m3-皮;A4;BEI胆硷能作用 未分类的颗粒Particulatcs Not Otherw is e Classified(PNDC) 可吸入性颗粒lnhalablc particu late10mg/m3--肺 呼吸性颗粒Rcspirablc particulate3mg/m3--肺 戊硼烷Pentaboran e(19624-22-7)0.005ppm0.015pp m-中枢神经系统 五氯化萘Pentachloron aph th alene(1321-64-8)0.5mg/m3-皮氯痤疮;肝;中枢神经系统 五氯硝基苯Pcntachloron itrob enzene(82-68-8)0.5mg/m3-A4肝 五氯苯酚Pentachlorop hen ol(87-86-5)0.5mg/m3-皮;A3;BEI 刺激;心血管系统;中枢神经系统 季戊四醇Pcntacrythritol(115-77-5)10mg/m3--刺激 戊烷(所有异构体)Pcntan e(all isomers)(78-78-4)600ppm--刺激;麻醉 四氯乙烯Tetrachlorocth ylen e(127-18-4)25ppm100pp m A3;BEI刺激;中枢神经系统 全氯甲硫醇Pcrch lorometh yl mcrcaptan(594-42-3)0.1ppm--刺激;肺水肿 过氯酰氟Perchloryl fluoride(7616-94-6)3ppm6pp m-刺激;血液 全氟异丁烯Perfluorois obutylen e(382-21-8)-C0.01ppm-刺激;肺水肿 珍珠岩Perlite(93763-70-3)10mg/m3-A4刺激 过硫酸盐Pers ulfates刺激;皮炎 过硫酸铵Ammonium persulfate(7727-54-0)0.1mg/m3 过硫酸钾Potass ium pers ulfate(7727-21-1)0.1mg/m3 过硫酸钠sodium persulfato(7775-27-1)0.1mg/m3 酚Phen ol(108-95-2)5ppm-皮;BEI刺激;中枢神经系统;血液 吩噻嗪Phen oth iazin e(92-84-2)5mg/m3-皮刺激;眼;肝;肾 N-苯基 -萘胺N-plenyl-beta-n aph th ylamine(135-88-6)--A4刺激 邻苯二胺o-Ph enylencdiam ine(94-54-5)0.1mg/m3-A3刺激;肝 间苯二胺m-Phen ylcn cdiamine(108-45-2)0.1mg/m3-A4刺激;肝 对苯二胺p-phenylencdiamine(106-50-3)0.1mg/m3-A4皮炎;尊麻疹;刺激;血液;致敏 苯基酰(蒸气)Phenyl ether(Vapor)(101-84-8)1ppm2pp m-刺激;恶心 苯基缩水甘油醚Ph enyl glycidyl eth er(PGE)(122-60-1)0.1ppm-皮刺激;皮炎;致敏 苯肼Phen ylhydrazine(100-63-0)0.1ppm-皮,A3皮炎;贫血#苯硫醇Phen yl m crcaptan(108-98-5)0.5ppm(-)-刺激;皮炎 苯膦Phen ylphos phine(638-21-1)-C0.05ppm-刺激;皮炎;血液 甲拌磷Phorate(298-02-2)0.05mg/m30.2mg/m3皮;BEI胆硷能作用 光气Phosgcne(75-44-5)0.1ppm--刺激;缺氧;肺水肿 磷化氢Phosphine(7803-51-2)0.3ppm1pp m-刺激;中枢神经系统;肠胃道 磷酸Phosph or ic acid(7664-38-2)1mg/m33mg/m3-刺激 磷(黄磷)Phosph oru s(ycllow)(7723-14-0)0.02ppm--刺激;肝;肾;心血管系统;胃肠道作用 磷酰氯Phosphoru s oxychloride(10025-87-3)0.1ppm--刺激;肾 五氯化磷Phosphoru s pentachloride(10026-13-8)0.1ppm--刺激 五硫化二磷Phosphoru s pentasulfide(1314-80-3)1mg/m33mg/m3-刺激 三氯化磷Phosphoru s tr ichlor ide(7719-12-2)0.2ppm0.5pp m-刺激 邻苯二甲酸酐Ph thalic an hydride(85-44-9)1ppm-A4刺激;致敏 间苯二腈m-Phthalodinitrile(626-17-5)5mg/m3--刺激 毒莠定Picloram(1918-02-1)10mg/m3-A4刺激;肝;肾 苦味酸Picric acid(88-89-1)0.1mg/m3--皮炎;刺激;眼;致敏 杀鼠酮Pindone(83-26-1)0.1mg/m3--肝;肾;出血;皮炎 二盐酸哌嗪Piperazinc dih ydrochloride(142-64-3)5mg/m3--刺激;灼伤;气喘;致敏 铂Platin um(7440-06-4) 金属铂M etal1mg/m3--刺激 可溶性盐类(以铂计)Soluble salts,as Pt0.002mg/m3--哮喘;刺激;致敏 (卜特兰)水泥Portland cement(65997-15-1)10mg/m3--刺激;皮炎 氢氧化钾Potass ium hydroxide(1310-58-3)-C2m g/m3-刺激;腐蚀 丙烷Propane(74-98-6)2500ppm--窒息 丙磺内酯Propane s ultone(1120-71-4)--A3瘤形成 正丙醇n-propanol(71-23-8)200ppm250pp m皮刺激;麻醉 炔丙醇Propargyl alcohol(107-19-7)1ppm-皮刺激;肝;肾 -丙内酯 -Pr opiolacton e(57-57-8)0.5ppm-A3刺激 丙酸Propionic acid(79-09-4)10ppm--刺激 残杀威Propoxur(114-26-1)0.5mg/m3-A3胆硷能作用 乙酸正丙酯n-Propyl acctate(109-60-4)200ppm250pp m-刺激 二氯丙烯Propylcne dichloride(78-87-5)75ppm110pp m A4刺激;中枢神经系统;肝;肾 丙二醇二硝酸酯propylen e glycol dinitrate(6423-43-4)0.05ppm-皮;BEI心血管系统,头痛;中枢神经系统;缺氧 丙二醇单甲醚Propylen e glycol mon om cthyl cth er(107-98-2)100ppm150pp m-刺激;中枢神经系统 丙撑亚胺Propylen e imine(75-55-8)2ppm-皮,A3刺激;中枢神经系统 氧化丙烯propylene oxide(75-56-9)20ppm-A3刺激;中枢神经系统;皮炎 硝酸正丙酯n-Propyl nitrate(627-13-4)25ppm40p pm BEI血液;发绀;缺氧 除虫菊Pyrcthrum(8003-34-7)5mg/m3-A4皮炎;中枢神经系统;肝;致敏 吡啶Pyridine(110-86-1)5ppm--刺激;中枢神经系统;肝;肾;血液 苯醌Quinone(106-51-4)0.1ppm--刺激;视力 间苯二酚Resorcinol(108-46-3)10ppm20p pm A4刺激;皮炎;血液。
职业卫生检测工作相关问题
职业卫生检测工作相关问题1.基本概念1．职业卫生定义：职业卫生是一门致力于对引起疾病和伤害的职业环境进行辨识、评价和控制的学科。
1.2 接触限值1.2.1 TLVs：ACGIH针对大量的化学药剂建立的极限剂量成为域限值，指空气中的浓度低于该值时，在整个生命周期内都不会受到任何副作用的影响。
暴露仅仅发生在日常工作的时间内，即每天8小时，每周5天。
域限值分为如下三种。
1.2.2 PEL：OSHA定义的极限剂量，称为允许暴露水平。
PEL与ACGIH的TLV-TWA值很接近。
然而，PEL数据不多，并且不是经常更新。
TLV-TWA数据通常有些保守。
美国职业安全与健康管理局（OSHA）公布了几百种空气中有害物质的允许接触限值（PELs）和时间加权平均浓度（TWAs），TWAs 和PELs均是强制性标准，分别规定了8h和４０h工作周的时间加权平均浓度。
浓度单位是ppm/mg/m3ACGIH在其年刊《化学物质和物理因素、生物预限值》上公布了几百种化学物质的TLV-TWAs（ACGIH,1995）。
虽然不是强制性标准，但仍被作为工业标准使用。
对于一些化学物质，ACGIH和OSHA的标准中还规定了另外的接触浓度，包括短时间接触限值(STEL)和上限值(C)。
STEL是指15min的时间加权平均接触限值，必须包含在8h 时间加权平均值内。
STEL通常用来表示引起慢性中毒的物质浓度限值，而不是引起急性中毒的物质的。
AICGH推荐的STEL指每天接触不得超过４次，而且前后两次接触至少要间隔60min的时间加权平均值。
(环境安全与健康工程P252)上限值即使是瞬间也不得超过的最高浓度。
上限值适用于在瞬间接触一定浓度可产生急性中毒的化学物质。
1.2.3 IDLH：导致暴露于空气污染物的威胁，此时暴露很可能引起死亡，或直接的或延时的永远不可逆的健康影响，或妨碍工人从这样的环境中逃离。
(NIOSH)1.2.4 EEGLs：美国国家科学院建立的标准。
美国ACGIH和我国职业接触限值(容许浓度)对照表
TWA1乙醇甲胺磷 Acephate 2乙醛 Acetaldehyde 3乙酸 Acetic acid10ppm 4乙酐 Acetic anhydride 5ppm 5丙酮 Acetone500ppm 6丙酮氰醇 Acetone cyanohydrin 7乙腈 Acetonitrile 40ppm 8乙酰苯 Acetophenone 10ppm 9乙炔 Acetylene10四溴乙烷 Acetylene tetrabromide 1ppm 11乙酰水杨酸 Acetylsalicylic acid 5mg/m 312丙烯醛 Acrolein 13丙烯酰胺 Acrylamide 0.03mg/m 314丙烯酸 Acrylic acid 2ppm 15丙烯腈 Acrylonitrile 2ppm 16活性炭粉尘(总尘)17己二酸 Adipic acid 5mg/m 318己睛 Adiponitrile 2ppm 19艾氏剂 Aldrin0.25mg/m 320丙烯醇 Allyl alcohol 0.5ppm 21氯丙烯 Allyl chloride1ppm 22烯丙基缩水甘油醚 Allyl glycidyl ether 1ppm 23烯丙基二硫化物 Allyl propyl disulfide 2ppm 铝 Aluminum 铝尘10mg/m 3焦粉木，以铝计5mg/m 3熔烟，以铝计5mg/m 3可溶性盐，以铝计2mg/m 3烷基铝，以铝计2mg/m 3铝、铝合金总尘氧化铝 Aluminum oxide 10mg/m 3总尘264-氨基联苯 4-Aminodiphenyl3.由ppm 换算为 mg/m 3的公式为：mg/m 3 = (ppm * 分子量)/22.454.表中符号说明：TWA -时间加权平均容许浓度；STEL -短时间接触容许浓度；C (在数值前)-最高容许浓度 A2-可疑人致癌物；A3-确定动物致癌物；A4-证据不足的人致癌物一.工作场所空气中有害物质容许浓度美国ACGIH和我国职业接触限值说明：1.本附录列出了我国GBZ 2 - 2002和美国的ACGIH的2002 TLVs and BELs 中有害2.本附录按英文字母排列美国No 2425化合物名称272-氨基吡啶 2-Aminopyridine0.5ppm 283-氨基-1,2,4-三唑 3-Amino-1,2,4-triazole 0.2mg/m 329氨 Ammonia25ppm 30氯化铵烟 Ammonium chloride fume10mg/m 331全氟辛酸铵 Ammonium perfluorooctanoate 0.01mg/m 332氨基磺酸铵 Ammonium sulamate 10mg/m 333戊醇 Amyl alcohol 34苯胺和同系物 Aniline 2ppm 35邻茴香胺 o-Anisidine 0.1ppm 36对茴香胺 p-Anisidine0.1ppm 37锑及其化合物，以Sb计 Antimony 0.5mg/m 338锑化氢 Antimony hydride(Stibine)0.1ppm 39三氧化锑 Antimony trioxide 40安妥 ANTU0.3mg/m 341砷及其无机化合物，以As计 Arsenic 0.01mg/m 342砷化氢 Arsine 0.05ppm石棉 Asbestos 总尘纤维0.1f/cc 44石油沥青烟，以苯溶物计 Asphalt fume 0.5mg/m 345阿特拉津 Atrazine5mg/m 346谷硫磷 Azinphos-methyl 0.2mg/m 347重晶石粉尘(总尘) Barite48钡及其可溶性化合物，以钡计 Barium 0.5mg/m 349硫酸钡 Barium sulfate10mg/m 350白僵蚕孢子 Beauveria bassiana 51苯菌灵 Benomyl10mg/m 352膨润土粉尘 Bentonite dust 53苯并蒽 Benz[a] anthracene 54苯 Benzene0.5ppm55联苯胺 Benzidine56苯并荧蒽 Benzo[b] fluoranthene 57苯并(a)芘 Benzo[a] phrene 58三氯苯 Benzotrichloride 59苄酰氯 Benzoyl chloride60过氧化苯甲酰 Benzoyl peroxide 5mg/m 361乙酸苄酯 Benzyl acetate 10ppm 62苄基氯 Benzyl chloride1ppm 63铍及其化合物，按Be计 Beryllium 0.002mg/m 364联苯 Biphenyl0.2ppm 双2-二甲基胺乙基醚Bis(2-dimethylaminoethyl) etherE 双(巯基乙酸)二辛基锡Bis(mercaptoacetate) dioctyltin 67双氯甲醚 Bis(chloromethyl) ether4365660.05ppm碲化铋 Bismuh telluride 按Bi 2Te 3计不含Se 10mg/m 3含Se5mg/m 3四硼酸钠 Borates,tatra,sodium salt 无水化合物 1mg/m 3十水化合物5mg/m 3五水化合物1mg/m 370氧化硼 Boron oxide10mg/m 371三溴化硼 Boron tribromide 72三氟化硼 Boron trifluoride 73除草定 Bromacil 10mg/m374溴 Bromine0.1ppm 75五氟化溴 Bromine pentafluoride 0.1ppm 76溴仿 Bromoform0.5ppm 771,3-丁二烯 1,3-Butadiene 2ppm 78丁烷 Butane800ppm 79正丁醇 n-Butanol 80仲丁醇 sec-Butanol 100ppm 81特丁醇 tert-Butanol100ppm 822-丁氧基乙醇 2-Butoxyethanol 20ppm 83乙酸正丁酯 n-Butyl acetate 150ppm 84乙酸仲丁酯 sec-Butyl acetate 200ppm 85乙酸特丁酯 tert-Butyl acetate 200ppm 86丙烯酸正丁酯 n-Butyl acrylate 2ppm87丁醛 Butylaldehyde 88正丁胺 n-Butylamine89丁基羟基甲苯(BHT) Butylated hydroxytoluene 2mg/m 390铬酸特丁酯 tert-Butyl chromate 以CrO 3计91丁烯 Butylene92正丁基缩水甘油醚 n-Butyl glycidyl ether 25ppm 93乳酸正丁酯 n-Butyl lactate 5ppm 94正丁基硫醇 n-Butyl mercaptan 0.5ppm 95邻仲丁基苯酚 O-sec-Butylphenol 5ppm 96对特丁基甲苯 p-tert-Butyl toluene 1ppm镉,Cadmium元素和化合物0.01mg/m 3按Cd计0.002mg/m 398碳酸钙 Calcium carbonate10mg/m 399铬酸盐 Calcium chromate 按Cr计0.001mg/m 3100氰氨化钙 Calcium cyanamide 0.5mg/m 3101氢氧化钙 Calcium hydroxide 5mg/m 3102氧化钙 Calcium oxide2mg/m 3103硅酸钙(合成) Calcium silicate 10mg/m 3104硫酸钙 Calcium sulfate10mg/m 3976869105樟脑(合成) Camphor 2ppm 己内酰胺 Caprolactam 粒子1mg/m 3蒸汽5ppm 107敌菌丹 Captafol 0.1mg/m 3108克菌丹 Captan 5mg/m 3109西维因 Carbaryl 5mg/m 3110呋喃丹 Carbofuran 0.1mg/m 3炭黑 Carbon black 3.5mg/m 3总尘112二氧化碳 Carbon dioxide 5000ppm 113二硫化碳 Carbon disulfide 10ppm114碳纤维粉尘(总尘) Carbon fiber 一氧化碳 Carbon monoxide 非高原25ppm高原海拔2000米海拔>3000米116四溴化碳 Carbon tetrabromide 0.1ppm 117四氯化碳 Carbon tetrachloride 5ppm 118羰酰氟 Carbonyl fluoride 2ppm 119儿茶酚(邻苯二酚) Catechol 5ppm 120纤维素 Cellulose10mg/m 3121氢氧化铯 Cesium hydroxide 2mg/m 3122氯丹 Chlordane0.5mg/m 3123氯代莰烯(毒杀芬) Chlorinated camphene 0.5mg/m 3124邻氯代联苯醚 O-Chlorinated diphenyl oxide 0.5mg/m 3125氯 Chlorine0.5ppm 126二氧化氯 Chlorine dioxide 0.1ppm127三氟化氯 Chlorine trifluoride 128氯乙醛 Chloroacetaldehyde 129氯丙酮 Chloroacetone1302-氯乙酰苯 2-Chloroacetophenone 0.05ppm 131氯乙酰氯 Chloroacetyl chloride 0.05ppm 132氯苯 Chlorobenzene 10ppm邻氯苄叉丙二腈o-Chlorobenzylidine alononitrile 134氯溴甲烷 Chlorobromomethane200ppm 135二氟氯甲烷 Chlorodifluoromethane 1000ppm 136氯联苯 Chlorodiphenyl(42%氯)1mg/m 3137氯联苯 Chlorodiphenyl(54%氯)0.5mg/m 3138氯仿(三氯甲烷) Chloroform(Trichloromethane)10ppm 139双氯甲醚 bis(Chloromethyl) ether 0.001ppm140氯甲甲醚 Chloromethyl methyl ether 141氯萘 Chloronaphthalene1421-氯-1-硝基丙烷 1-Chloro-1-nitropropane2ppm106111115133143五氟氯乙烷 Chloropentafluoroethane 1000ppm 144氯化苦 Chloropicrin0.1ppm 145β-氯丁二烯 β-Chloroprene10ppm 1462-氯丙酸 2-Chloropropionic acid 0.1ppm 147邻氯苯乙烯 o-Chlorostyrene 50ppm 148百菌清 Chlorothalonile 149邻氯甲苯 o-Chlorotoluene 50ppm 150毒死蜱 Chlorpyrifos 0.2mg/m 3铬铁矿石加工(铬酸盐)Chromite ore processing(Chromate) 以Cr计铬 Chromiun 及其无机化合物,以Cr计金属和三价化合物0.5mg/m 3水溶性六价化合物0.05mg/m 3不可溶性六价化合物0.01mg/m 3153铬酰氯 Chromyl chloride 0.025ppm 154屈 Chrysene155二氯二甲吡啶粉 Clopidol 10mg/m 3煤尘 Coal dust 无烟煤 Anthracite 0.4mg/m 3烟煤 Bituminous 0.9mg/m 3总尘呼尘煤焦油沥青挥发物,按苯溶物计 Coal tar pitch volatiles158钴及其无机化合物,按Co计 Cobalt 0.02mg/m 3159羰基钴,按Co计 Cobalt carbonyl0.1mg/m 3160羰基氢钴,按Co计 Cobalt hydrocarbonyl 0.1mg/m 3161焦炉逸散物,按苯溶物计 Coke over emission 凝聚SiO 2粉尘 Condensed silica 总尘呼尘铜 Copper 烟0.2mg/m 3尘和雾，以Cu计1mg/m 3164考的松 Cortisone165棉尘 Cotton dust,raw(总尘)0.2mg/m 3166甲酚,所有异构体 Cresol 5ppm 167巴豆醛 Crotonaldehyde 168育畜磷 Crufomate 5mg/m 3169异丙苯(枯烯) Cumene 50ppm 170氨基氰 Cyanamide 2mg/m 3171氰化物 Cyanogen10ppm 172氯化氰 Cyanogen chloride 173环己烷 Cyclohexane300ppm1571621631511521560.05mg/m 30.2mg/m 3174环己醇 Cyclohexanol 50ppm 175环己酮 Cyclohexanone 25ppm 176环己烯 Cyclohexene 300ppm 177环己胺 Cyclohexylamine10ppm 178三次甲基三硝基胺(黑索金) Cyclonite(RDX)0.5mg/m 3179环戊二烯 Cyclopentadiene 75ppm 180环戊烷 Cyclopentane 600ppm 181杀螨锡 Cyhexatin 5mg/m 31822,4-D10mg/m 3183滴滴涕 DDT Dichlorodiphenyltrichloroethane 1mg/m 3184癸硼烷 Decaborane 0.05ppm185萘烷 Decalin186溴氰菊酯 Deltamethrin 187内吸磷 Demeton0.01ppm 188洗衣粉混合尘 Detergent mixed dust 189双丙酮醇 Diacetone alcohol 50ppm 190二嗪农 Diazinon0.1mg/m 3191重氮甲烷 Diazomethane 0.2ppm 192二硼烷 Diborane0.1ppm 1932-N-二丁氨基乙醇 2-N-Dibutylaminoethanol 0.5ppm 194磷酸二丁基苯酯 Dibutyl phenyl phosphate 0.3ppm 195磷酸二丁酯 Dibutyl phosphate1ppm 196邻苯二甲酸二丁酯 Dibutyl phthalate 5mg/m 3197二月桂酸二丁基锡 Dibutyltin dilaurate 198二氯代乙炔 Dichloroacetylene 199邻二氯苯 o-Dichlorobenzene 25ppm 200对二氯苯 p-Dichlorobenzene10ppm 2013,3,-二氯联苯胺 3,3,-Dichlorobenzidine 2021,4-二氯-2-丁烯 1,4-Dichloro-2-butene 0.005ppm 203二氯二氟甲烷 Dichlorodifluoromethane 1000ppm 1,3-二氯-5,5-二甲基乙内酰脲1,3-Dichloro-5,5-dimethyl hydantoin 2051,1-二氯乙烷 1,1-Dichloroethane 100ppm 2061,2-二氯乙烷 1,2-Dichloroethane 1,2-二氯乙烯,所有异构体 1,2-Dichloroethylene208二氯乙醚 Dichloroethyl ether 4ppm 209二氯氟甲烷 Dichlorofluoromethane 10ppm 210二氯甲烷 Dichloromethane50ppm 2111-二氯-1-硝基乙烷 1-Dichloro-1-nitroethane 2ppm2121,2-二氯丙烷 1,2-Dichloropropane 2131,3-二氯丙醇 1,3-Dichloropropanol 2141,3-二氯丙烯 1,3-Dichloropropene1ppm 2152,2-二氯丙酸 2,2-Dichloropropionic acid 5mg/m 3216二氯四氟乙烷 Dichlorotetrafluoroethane 1000ppm 217敌敌畏(DDVP) Dichlorvos0.9mg/m 32042070.2mg/m 3200ppm218百治磷 Dicrotophos0.25mg/m 3219二聚环戊二烯 Dicyclopentadiene 5ppm 220二戊铁 Dicyclopentadienyl iron 10mg/m 3221狄氏剂 Dieldrin0.25mg/m 3222二乙醇胺 Diethanolamine 2mg/m 3223二乙胺 Diethylamine5ppm 2242-二乙胺基乙醇 2-Diethylaminoethanol 2ppm 225二乙撑三胺 Diethylene triamine1ppm 226邻苯二2-乙基己酯 Di(2-ethylhexyl)phthalate 5mg/m 3227二乙基甲酮 Diethyl ketone 200ppm 228酞酸二乙酯 Diethyl phthalate5mg/m 3229二氟二溴甲烷 Difluorodibromomethane 100ppm 230二缩水甘油醚 Diglycidyl ether 0.1ppm 231二异丁基甲酮 Diisobutyl ketone 25ppm 232二异丙胺 Diisopropylamie5ppm 233N,N-二甲基乙酰胺 N,N-Dimethylacetamide 10ppm 234二甲胺 Dimethylamine5ppm 235N,N-二甲基苯胺 N,N-Dimethylaniline 5ppm2363,3-二甲基联苯胺 3,3-Dimethylbenzidine237二甲基氨基甲酰氯 Dimethyl carbamoyl chloride 238二甲基二氯硅烷 Dimethyl dichlorosilane 239二甲基乙氧基硅烷 Dimethylethoxysilane 0.5ppm 240二甲基甲酰胺 Dimethylformamide 10ppm 1,1-二甲基肼(偏二甲基肼)1,1-Dimethylhydrazine242邻苯二甲酸二甲酯 Dimethyphthalate 5mg/m 3243硫酸二甲酯 Dimethyl sulfate 0.1ppm 244Dinitolmide5mg/m 3245二硝基苯,全部异构体 Dinitrobenzene 0.15ppm 246二硝基氯苯 Dinitrochlorobenzene2474,6-二硝基邻苯甲酚 4,6-Dinitro-o-cresol 0.2mg/m 3248二硝基甲苯 Dinitrotoluene 0.2mg/m 32491,4-二噁烷 1,4-Dioxane 20ppm 250二噁磷 Dioxathion 0.2mg/m 3251二苯胺 Diphenylamine 10mg/m 3二丙烯基乙二醇甲基醚Dipropylene glycol methyl ether 253二丙基甲酮 Dipropyl ketone 50ppm 杀草快 Diquat 可吸入从0.5mg/m 3呼吸性0.1mg/m 3255双硫醒 Disulfiram 2mg/m 3256乙拌磷 Disulfoton 0.1mg/m 3257敌草隆 Diuron10mg/m 32412522540.01ppm 100ppm258二乙烯基苯 Divinyl benzene10ppm 白云石粉尘 Dolomite dust259总尘呼尘260金刚砂 Emery10mg/m3 261硫丹 Endosulfan0.1mg/m3 262异狄氏剂 Endrin0.1mg/m3 263安氟醚 Enflurane75ppm 264环氧氯丙烷 Eqichlorohydrin0.5ppm 265苯硫磷 EPN0.1mg/m3 266乙醇 Ethanol1000ppm 267乙醇胺 Ethanolamine3ppm 268乙硫磷 Ethion0.4mg/m3 2692-乙氧基乙醇 2-Ethoxyethanol5ppm 2702-乙氧基乙基乙酸酯 2-Ethoxyethyl acetate5ppm 271乙酸乙酯 Ethyl acetate400ppm 272丙烯酸乙酯 Ethyl acrylate5ppm 273乙胺 Ethylamine5ppm 274乙基戊基甲酮 Ethyl amyl ketone25ppm 275乙苯 Ethyl benzene100ppm 276溴乙烷 Ethyl bromide5ppm 277乙基特丁基醚 Ethyl tert-butyl ether5ppm 278乙基丁基甲酮 Ethyl butyl ketone50ppm 279氯乙烷 Ethyl chloride100ppm 280氰基丙烯酸乙酯 Ethyl cyanoacrylate0.2ppm 281乙烯 Ethylene2822-氯乙醇 Ethylene chlorohydrin283乙二胺 Ethylenediamine10ppm 2841,2-二溴乙烷 Ethylene dibromide2851,2-二氯乙烷 Ethylene dichloride10ppm 286乙二醇气溶胶 Ethylene glycol287乙二醇二硝酸酯 Ethylene glycol dinitrate0.05ppm 288环氧乙烷 Ethylene oxide1ppm 289乙撑亚胺 Ethylenmine0.5ppm 290乙醚 Ethyl ether400ppm 291甲酸乙酯 Ethyl formate100ppm 292N-乙基吗啉 N-Ethylmorpholine293乙叉降冰生烯 Ethylidene norbornene294乙硫醇 Ethyl mercaptan0.5ppm 295N-乙基吗啉 N-Ethylmorpholine5ppm 296硅酸乙酯 Ethyl silicate10ppm 297丰索磷 Fenamiphos0.1mg/m3 298辛索磷 Fensulfothion0.1mg/m3 299倍硫磷 Fenthion0.2mg/m3 300氰戊菊酯 Fenvlerate301福美铁 Ferbam10mg/m3302铁钒(合金)尘 Ferrovanadium dust 1mg/m 3玻璃钢粉尘(总尘)Fiberglass einforced plastic dust 麻尘(游离SiO 2含量<10%)亚麻 Flax(总尘)黄麻 Jute(总尘)苎麻 Ramie(总尘)305面粉尘 Flour dust0.5mg/m 3306氟化物,按F计 Fluorides 2.5mg/m 3307氟 Fluorine1ppm 308萤石混合性粉尘(总尘) Fluorspar mixed dust 309地虫磷 Fonofos0.1mg/m 3310皮毛粉尘(总尘) Fur dust 311甲醛 Formaldehyde 312甲酰胺 Formamide 10ppm 313甲酸 Formic acid 5ppm 314呋喃 Furan 315糠醛 Furfural2ppm 316糠醇 Furfuryl alcohol 10ppm 317汽油 Gasoline300ppm 318四氢化锗 Germanium tetrahydride 0.2ppm 319戊二醛,活性和非活性 Glutaraldehyde 320甘油雾 Glycerin mist 10mg/m 3321缩水甘油 Glycidol2ppm 322甲基丙烯酸缩水甘油酯 Glycidyl methacrylate 323乙二醛 Glyoxal0.1mg/m 3324谷物粉尘(像小麦,大麦等) Grain dust(总尘)4mg/m 3石墨(除石墨纤维以外) Graphite 总尘2mg/m 3呼尘326砂轮磨尘(总尘) Grinding wheel dust 石膏粉尘 Gypsum dust 总尘呼尘328合及其化合物,按Hf计 Hafnium 0.5mg/m 3329庚烷 Halothane50ppm 七氯和七氯环氧化物Heptachlor and Heptachlor epoxide 331正庚烷 Heptane400ppm 332六氯苯 Hexachlorobenzene0.002mg/m 3333六氯丁二烯 Hexachlorobutadiene 0.02ppm334六六六 Hexachlorocyclohexane 335γ-六六六 Hexachlorocyclohexane336六氯环戊二烯 Hexachlorocyclopentadiene 0.01ppm 337六氯乙烷 Hexachloroethane1ppm3033043253273300.05mg/m 3338六氯萘 Hexachloronaphthalene 0.2ppm 339六氟丙酮 Hexafluoroacetone 0.1ppm 340六氟丙烯 Hexapropylene3411,6-已二异氰酸酯 Hexamethylene diisocyanate 0.005ppm 342六甲基磷酰胺 Hexamethyl phosphoramide 343正己烷 n-Hexane50ppm 344己烷,其他异构体 Hexane500ppm 3451,6-二胺基己烷 1,6-Hexanediamine 0.5ppm 3462-己酮 2-Hexanone 3471-己烯 1-Hexene30ppm 348乙酸仲己酯 sec-Hexyl acetate 50ppm 349己二醇 Hexylene glycol 350肼 Hydrazine0.01ppm叠氮酸和叠氮化钠Hydrazoic acid & Sodium azide 叠氮酸蒸汽叠氮化钠352氢化三联苯 Hydrogenated terphenyl 0.5ppm353溴化氢 Hydrogen bromide 354氯化氢 Hydrogen chloride 氰化氢和氰化物,按CN计氰化氢Hydrogen cyanide 氰化物356氟化氢 Hydrogen fluoride 357过氧化氢 Hydrogen peroxide 1 ppm 358硒化氢 Hydrogen selenide 0.05ppm 359硫化氢 Hydrogen sulfide 10ppm 360氢醌 Hydroquinone2mg/m 3361丙烯酸2-羟基丙酯 2-Hydroxypropyl acrylate 0.5ppm 362茚 Indene10ppm 363铟及其化合物,按In计 Indium 0.1mg/m 3364碘 Iodine365碘仿 Iodoform0.6ppm 366氧化铁烟尘,按Fe计 Iron oxide5mg/m3367五羰基铁,按Fe计 Iron pentacarbonyl 0.1ppm 368可溶性铁盐,按Fe计 Iron salt 1mg/m 3369异戊醇 Isoamyl alcohol100ppm 370丁酸异丁酯 Isobutyl acetate 150ppm 371异丁醇 Isobutyl alcoho 150ppm 372异辛醇 Isooctyl alcohol 50ppm 373异佛尔酮 Isophrone374异佛尔酮二异氰酸酯 Isoprorone diisocyanate 0.005ppm 3752-异丙氧乙醇 2-Isopropoxyethanol 25ppm 376乙酸异丙酯 Isopropyl acetate 250ppm 377异丙醇 Isopropyl alcohol 400ppm 378异丙胺 Isopropylamine5ppm 379N-异丙基苯胺 N-Isopropyl aniline2ppm351355380异丙醚 Isopropyl ether250ppm 381异丙基缩水甘油醚 Isopropyl glycidyl ether 50ppm 382陶土,高岭土 Kaolin 2mg/m 3383乙烯酮 Ketene0.5ppm 384异稻瘟净 Kitazin o-p铅及无机化合物,按Pb计 Lead 0.05mg/m3铅烟铅尘386砷酸铅,以Pb 3(AsO 4)2计 Lead arsenate 0.15mg/m 3铬酸铅,以Pb计 Lead chromate 0.05mg/m 3按Cr计0.012mg/m 3石灰石粉尘 Limestone dust 总尘呼尘389林丹 Lindane0.5mg/m 3390氢化锂 Lithiun hydride0.025mg/m 3391液化石油气 Liquefied petroleum gas 1000ppm 392菱镁矿 Magnesite10mg/m 3393氧化镁烟 Magnesium oxide fume 10mg/m 3394马拉硫磷 Malathion10mg/m 3395马来酸酐 Maleic anhydride0.1ppm 396锰及无机化合物,按Mn计 Manganese 0.2mg/m 3环戊二烯三羰基锰,按Mn计Manganese cyclopentadienyl tricarbonyl 大理石粉尘 Marble dust 总尘呼尘汞,以Hg计 Mercyry烷基汞 Alkyl compounds 0.01mg/m 3芳基汞 Aryl compounds 0.1mg/m 3汞及无机化合物0.025mg/m 3400异亚丙基丙酮 Mesityl oxide 15ppm 401甲基丙烯酸 Methacrylic acid 20ppm 402甲醇 Methanol 200ppm 403灭多虫 Methomyl 2.5mg/m 3404甲氧氯 Methoxychlor10mg/m 34052-甲氧基乙醇 2-Methoxyethanol5ppm 406乙酸2-甲氧基乙酯 2-Methoxyethyl acetate 5ppm 4074-甲氧基苯酚 4-Methoxyphenol 5mg/m 34081-甲氧基-2-丙醇 1-Methoxy-2-丙醇100ppm 双-(2-甲氧基丙基)醚bis-(2-Methoxypropyl) ether 410乙酸甲酯 Methyl acetate 200ppm 411丙炔 Methyl acetylene1000ppm3853873883973983994090.1mg/m 3200ppm丙炔-丙二烯混合物Methyl acetylene-propadiene mixture 413丙烯酸甲酯 Methyl acrylate 2ppm 414甲基丙烯晴 Methylacrylonitrile 1ppm 415甲缩醛 Methylal 1000ppm 416一甲胺 Methylamine5ppm 417甲基正戊基甲酮 Methyl n-amyl ketone 50ppm 418N-甲基苯胺 N-Methyl aniline 0.5ppm 419溴甲烷 Methyl bromide1ppm 420甲基特丁醚 Methyl tert-butyl ether 40ppm 421甲基正丁基甲酮 Methyl n-butyl ketone 5ppm 422氯甲烷 Methyl chloride50ppm 4232-氰基丙烯酸甲酯 Methyl 2-cyanoacrylate 0.2ppm 424甲基环己烷 Methylcyclohexane 400ppm 425甲基环己醇 Methylcyclohexanol50ppm 426邻甲基环己酮 o-Methylcyclohexanone50ppm 2-甲基环戊二烯三羰基锰,按Mn计 2-Methylcy-clopentadienyl manganese tricarbonyl 428甲基内吸磷 Methyl demeton 0.5mg/m 3二苯基甲烷二异氰酸酯Methylene bisphenyl isocaynate 4,4,-亚甲基双(2-氯苯胺)4,4,-Methylene bis(2-chloroaniline)亚甲基双(4-环己基异氰酸酯)Methylene bis(4-cyclohexylisocyanate)4324,4,-亚甲基联苯胺 4,4,-Methylene dianiline 0.5ppm 433甲基乙基甲酮(丁酮) Methyl ethyl ketone 200ppm甲基乙基甲酮过氧化物Methyl ethyl ketone peroxide 435甲酸甲酯 Methyl formate 100ppm 436甲基肼 Methyl hydrazine 0.01ppm 437碘甲烷 Methyl iodide2ppm 438甲基异戊基甲酮 Methyl isoamyl ketone 50ppm 439甲基异戊醇 Methyl isobutyl carbinol 25ppm 440甲基异丁基甲酮 Methyl isobutyl ketone 50ppm 441异氰酸甲酯 Methyl isocyanate0.02ppm 442甲基异丙基甲酮 Methyl isopropyl ketone 200ppm 443甲硫醇 Methyl mercaptan0.5ppm 444甲基丙烯酸甲酯 Methyl methacrylate50ppm 44518-甲基炔诺酮(炔诺孕酮)18-Methyl norgestrel 446Methyl parathion 甲基对硫磷0.2mg/m 3447甲基丙基甲酮 Methyl propyl ketone 200ppm 448硅酸甲酯 Methyl silicate1ppm 449α-甲基苯乙烯 α-Methyl styrene 50ppm 450丁烯酮 Methyl vinyl ketone 451嗪草酮 Metribuzin5mg/m 34274294304314124340.005ppm 1000ppm 0.2mg/m 30.005ppm 0.01ppm452速灭磷 Mevinphos 0.09mg/m 3云母粉尘 Mica 总尘3mg/m 3呼尘钼,以Mo计 Molybdenum 可溶性化合物0.5mg/m 3金属和不溶性化合物10mg/m 3455久效磷 Monocrotophos 0.25mg/m 3456吗啉 Morpholine20ppm 457桑蚕丝尘(总尘) Mulberry silk dust 458二溴磷 Naled 3mg/m 3459萘 Naphthalene10ppm460β-萘胺 β-Naphthylamine 镍 Nickel 金属镍1.5mg/m 3可溶性化合物,按Ni计0.1mg/m 3不可溶性化合物,按Ni计0.2mg/m 3462羰基镍 Nickel carbonyl 0.05ppm 463亚硫酸镍 Nickel subsulfide 0.1mg/m 3464烟碱 Nicotine0.5mg/m 3465硝基黄铁矿 Nitrapyrin 10mg/m 3466硝酸 Nitric acid2ppm 467一氧化氮 Nitric oxide 25ppm 468对硝基苯胺 p-Nitroaniline 3mg/m 3469硝基苯 Nitrobenzene1ppm 470对硝基氯苯 p-Nitrochlorobenzene 0.1ppm 4714-硝基联苯 4-Nitrodiphenyl 472硝基乙烷 Nitroethane100ppm 473二氧化氮 Nitrogen dioxide 3ppm 474三氟化氮 Nitrogen trifluoride 10ppm 475硝化甘油 Nitroglycerin 0.05ppm 476硝基甲烷 Nitromethane 20ppm 4771-硝基丙烷 1-Nitropropane 25ppm 4782-硝基丙烷 2-Nitropropane10ppm 479N-亚硝基二甲胺 N-Nitrosodimethylamine 480硝基甲苯 Nitrotoluene 2ppm 481氧化亚氮 Nitrous oxide 50ppm 482壬烷,全部异构体 Nonane200ppm 483八氯萘 Octachloronaphthalene 0.1mg/m 3484辛烷,全部异构体 Octane 300ppm 485奥克托今 Octogen486矿物油雾 Oil mist,mineral 5mg/m 3487氧化乐果 Omethoate488四氧化锇 Osmium tetroxide 0.0002ppm 489草酸 Oxalic acid1mg/m 3453454461p,p ,-羟苯(苯磺酰基)p,p ,-Oxybis(benzenesulfonyl hydrazide)491二氟化氧 Oxygen difluoride 臭氧 Ozone 重体力工作0.05ppm 中等体力工作0.08ppm 轻体力工作0.10ppm 重、中或轻度体力负荷(<2h)0.20ppm 493石蜡烟 Paraffin Wax fume 2mg/m 30.5mg/m 30.1mg/m 3495对硫磷 Parathion 0.1mg/m 3其他粉尘Particles not otherwise regulated 不溶性微粒 Particulates 可吸入微粒10mg/m 3呼吸性微粒3mg/m 3498戊硼烷 Pentaborane0.005ppm 499五氯萘 Pentachloronaphthalene0.5mg/m 3500五氯硝基苯 Pentachloronitrobenzene 501五氯酚及其钠盐 Pentachlorophenol 0.5mg/m 3502季戊四醇 Pentaerythritol 10mg/m 3503戊烷，全部异构体 Pentane600ppm 504乙酸戊酯,全部异构体 Pentyl acetate 50ppm 505全氯甲硫醇 Perchloromethyl mercaptan 0.1ppm 506氟化全氯氧 Perchloryl fluoride 3ppm 507全氟异丁烯 Perfluoroisobutylene 珍珠岩粉尘 Perlite 10mg/m 3总尘呼尘509过硫酸盐 Persulfates 0.1mg/m 3510酚 Phenol5ppm酚醛树脂粉尘(总尘)Phenolic aldehyde resin dust 512吩噻嗪 Phenothiazine5ppm 513N-苯基-β-萘胺 N-Phenyl-beta-naphthylamine 514邻苯二胺 o-Phenylenediamine 0.1mg/m 3515间苯二胺 m-Phenylenediamine 0.1mg/m 3516对苯二胺 p-Phenylenediamine 0.1mg/m 3517苯醚,蒸汽 Phenyl ether1ppm 518缩水甘油苯醚 Phenyl glycidyl ether 0.1ppm 519苯肼 Phenylhydrazine 0.1ppm 520苯硫醇 Phenyl mercaptan 0.5ppm521苯膦 Phenylphosphine490492494496497508511百草枯 Paraquat0.1mg/m 3522甲拌磷 Phorate 0.05mg/m 3523光气 Phosgene 0.1ppm 524磷胺 Phosphamidon 525磷化氢 Phosphine 0.3ppm 526磷酸 Phosphoric acid 1mg/m 3527黄磷 Phosphorus0.02ppm 528三氯氧磷 Phosphorus oxychloride 0.1ppm 529五氯化磷 Phosphorus pentachloride 0.1ppm 530五硫化二磷 Phosphorus pentasulfide 1mg/m 3531五氧化二磷 Phosphorus pentoxide 532三氯硫磷 Phosphorus thiochloride 533三氯化磷 Phosphorus trichloride 0.2ppm 534邻苯二甲酸酐 Phthalic anhydride 1 ppm 535间酞二腈 m-Phthalodinitrile 5mg/m 3536毒秀定 Picloram 10mg/m 3537苦味酸 Picric acid 0.1mg/m 3538杀鼠酮 Pindone0.1mg/m 3539哌嗪二盐酸盐 Piperazine dihydrochloride 5mg/m 3铂 Platinmu 金属1mg/m 3可溶性铂盐,按Pt计0.002mg/m 3聚丙烯腈纤维粉尘(总尘)Polycrylonitrile fiber dust542聚乙烯粉尘(总尘) Polyethylene dust 多次甲基多苯基多异氰酸酯Polymethylene polyphenyl isocyanate 544聚丙烯粉尘(总尘) Polyprpylene dust545聚四氟乙烯分解物 Polytetrafluoroethylene 546聚氯乙烯粉尘(总尘)Polyvinyl chloride dust 硅配酸盐水泥 Portland cement 10mg/m 3总尘(游离SiO 2含量<10%)呼尘(游离SiO 2含量<10%)548氢氧化钾 Potassium hydroxide 沉淀SiO 2(白碳黑)(总尘)Precipitated silica dust 550丙烷 Propane2500ppm 551丙烷磺内酯 Propane sultone552正丙醇 n-Propanol(n-Propyl alcohol)200ppm 553炔丙醇 Propargyl alcohol 1ppm 554β-丙炔内酯 β-Propiolactone 0.5ppm 555丙酸 Propionic acid 10ppm 556残杀威 Propoxur0.5mg/m 3557乙酸正丙酯 n-Propyl acetate 200ppm558丙烯 Propylene541543547549540559二氯丙烷 Propylene dichloride 75ppm 丙(撑)二醇二硝酸酯Propylene glycol dinitrate 561丙烯亚胺 Propylene imine 2ppm 562环氧丙烷 Propylene oxide 2ppm 563硝酸正丙酯 n-Propyl nitrate 25ppm 564除虫菊 Pyrethrum 5mg/m 3565吡啶 Pyridine 5ppm 566苯醌 Quinone0.1ppm567抽余油(60-220o C) Raffinate稀土粉尘(游离SiO 2含量<10%)(总尘)Rare-earth dust 569间苯二酚 Resorcinol 10ppm 铑,按Rh计 Rhodium 金属和不可溶性化合物1mg/m 3可溶性化合物0.01mg/m 3571乐果 Rogor 572皮蝇磷 Ronnel10mg/m 3松香焊锡分解产物 Rosin core solderthermal decomposition products(colophony)574鱼藤酮 Rotenone 5mg/m 3575红铁粉 Rouge10mg/m 3576橡胶溶剂(石脑油) Rubber solvent(Naphtha)400ppm 硒及其化合物,除六氟化硒和硒化氢外按Se计 Selenium578六氟化硒 Selenium hexafluoride 0.05ppm 579Sesone10mg/m 3无定形二氧化硅 Silica 硅藻土(游离SiO 2含量<10%)可吸入尘10mg/m 3呼吸性尘3mg/m 3沉淀的二氧化硅和硅胶10mg/m 3二氧化硅烟 Silica,fume2mg/m 3熔化的二氧化硅 Silica,fused 0.1mg/m 3晶体形二氧化硅 Silica 方石英 Cristalline 0.05mg/m 3石英 Quartz0.05mg/m 3鳞石英 Tridymite 0.05mg/m 3板状硅藻岩 Tripoli 0.1mg/m 3矽尘 Silica dust 总尘含10%-50%游离SiO 2含50%-80%游离SiO 25775805815605685705730.05ppm 致敏剂0.2mg/m3含80%以上游离SiO 2呼尘含10%-50%游离SiO 2含50%-80%游离SiO 2含80%以上游离SiO 2583硅 Silicon10mg/m 3碳化硅粉尘 Silicon carbide 总尘10mg/m 3呼尘585四氢化硅 Silicon tetrahydride 5ppm 银 Silver 金属0.1mg/m 3可溶性化合物,按Ag计0.01mg/m 3皂石 Soapstone 可吸入尘6mg/m 3呼吸性尘3mg/m 3588亚硫酸氢钠 Sodium bisulfite 5mg/m 3589碳酸钠 Sodium carbonate590氟乙酸钠 Sodium fluoroacetate 0.05mg/m 3591氢氧化钠 Sodium hydroxide592偏亚硫酸氢钠 Sodium metabisulfite 5mg/m 3593溶剂汽油 Solvent gasolines 594淀粉 Starch10mg/m 3595硬脂酸盐 Stearates10mg/m 3596洗毛织品用汽油类溶剂 Stoddard solvent 100ppm 597铬酸锶,按Cr计 Strontium chromate 0.0005mg/m 3598马钱子碱 Strychnine 0.15mg/m 3599苯乙烯 Styrene20ppm 600枯草杆菌蛋白酶(活性晶体酶) Subtilisins 601蔗糖 Sucrose10mg/m 3602甲嘧磺隆 Sulfometuron methyl 5mg/m 3603治螟磷 Sulfotep0.2mg/m 3604二氧化硫 Sulfur dioxide2ppm 605六氟化硫 Sulfur hexafluoride 1000ppm 606硫酸 Sulfuric acid及三氧化硫1mg/m 3607一氯化硫 Sulfur monochloride 608五氟化硫 Sulfur pentafluoride 609四氟化硫 Sulfur tetrafluoride 610硫酰氟 Sulfuryl fluoride 5ppm 611硫丙磷 Sulprofos 1mg/m 3612杀螟松 Sumithion 合成玻璃纤维Synthetic Vitreou Fibers582584586587长丝玻璃纤维1f/cc 玻璃棉纤维5mg/m 3岩棉纤维1f/cc 矿渣棉纤维1f/cc 特殊用途玻璃纤维1f/cc 难熔的陶器用品的玻璃纤维1f/cc 0.2f/cc 6142,4,5-涕 2,4,5-T10mg/m 3滑石粉尘 Talc(游离SiO 2含量<10%)总尘2mg/m 3呼尘616钽金属及其氧化,按Ta计 Tanatalum 5mg/m 3617茶尘(总尘) Tea dust618碲及其化合物,以Te计,除碲化氢外 Tellurium 0.1mg/m 3619六氟化碲 Tellurium hexafluoride 0.02ppm 620双硫磷 Temephos 10mg/m 3621特普 TEPP0.05mg/m 3622对苯二甲酸 Terephthalic acid 10mg/m 3623三联苯 Terphenyl1,1,1,2-四氯-2,2-二氟乙烷1,1,1,2-Tetrachloro-2,2-difluoro ethane 1,1,2,2-四氯-1,2-二氟乙烷1,1,2,2-Tetrachloro-1,2-difluoro ethane 6261,1,2,2-四氯乙烷 1,1,2,2-Tetrachloroethane 1ppm 627四氯乙烯 Tetrachloroethylene 25ppm 628四氯萘 Tetrachloronaphthalene 2mg/m 3629四乙基铅,按Pb计 Tetraethyl lead 0.1mg/m 3630四氟乙烯 Tetrafluoroethylene 2ppm 631四氢呋喃 Tetrahydrofuran200ppm 632四甲基铅,按Pb计 Tetramethyl lead0.15mg/m 3633四甲基琥珀腈 Tetramethyl succinonitile 0.5ppm 634四硝基甲烷 Tetranitromethane0.005ppm 635焦磷酸四钠 Tetrasodium pyrophosphate 5mg/m 3636特屈儿(2,4,6-三硝基苯甲硝胺) Tetrl 1.5mg/m 3637铊及其可溶性化合物,按Tl计 Thallium 0.1mg/m 3638甲拌磷 Thimet4,4,-硫代双(6-特丁基间甲酚)4,4,-Thiobis(6-tert-butyl-m-cresol)640巯基醋酸 Thioglycolic acid 1ppm 641亚硫酰(二)氯 Thionyl chloride 642福美双 Thiram 1mg/m 3锡 Tin金属、氧化物和无机化合物(除氢化锡),按Sn计2mg/m 3615624625639613643500ppm 500ppm 10mg/m 3有机化合物,按Sn计0.1mg/m 3644二氧化钛粉尘 Titanium dioxide 10mg/m 3645烟草尘(总尘) Tobacco dust 646邻联甲苯胺 o-Tolidine 647甲苯 Toluene50ppm 648二异氰酸甲苯酯 Toluene-2,4-diisocyanate 0.005ppm 649邻甲苯胺 o-Toluidine 2ppm 650间甲苯胺 m-Toluidine 2ppm 651对甲苯胺 p-Toluidine2ppm 652磷酸三丁酯 Tributyl phosphate 0.2ppm653敌百虫 Trichlorfon654三氯乙醛 Trichloroacetaldehyde 655三氯乙酸 Trichloroacetic acid1 ppm 6561,2,4-三氯苯 1,2,4-Trichlorobenzene 1,1,1-三氯乙烷(甲基氯仿)1,1,1-Trichloroethane(Methyl chloroform)6581,1,2-三氯乙烷 1,1,2-Trichloroethane 10ppm 659三氯乙烯 Trichloroethylene50ppm 660三氯氟甲烷 Trichlorofluoronethane 661三氯萘 Trichloronaphthalene5mg/m 36621,2,3-三氯丙烷 1,2,3-Trichloropropane 10ppm 663三氯氢硅 Trichlorosilane 1,1,2-三氯-1,2,2-三氟乙烷1,1,2-Trichloro-1,2,2-trifluoroethane 665三甲苯磷酸酯 Tricresyl phosphate 666三乙醇胺 Triethanolamine 5mg/m 3667三乙胺 Triethylamine1ppm 668三乙基氯化锡 Triethyltin chloride 669三氟溴甲烷 Trifluobromomethane 1000ppm三氟甲基次氟酸酯Trifluoromethyl hypofluorite 1,3,5-三缩水甘油-s-三嗪三酮1,3,5-Triglycidyl-s-triazinetrione 672偏苯三酸酐 Trimellitic anhydride 673三甲胺 Trimethylamine5ppm 674三甲基苯 Trimethyl benzene25ppm 675亚磷酸三甲酯 Trimethyl phosphite2ppm 676三硝基甲苯(TNT) 2,4,6-Trinitrotoluene 0.1mg/m 3677磷酸三邻甲苯酯 Triorthocresyl phosphate 0.1mg/m 3678三苯胺 Triphenyl amine5mg/m 3679磷酸三苯酯 Triphenyl phosphate 3mg/m 3钨,按W计 Tungsten金属钨及其不溶性化合物5mg/m 3可溶性化合物1mg/m 3681松节油 Turpentine100ppm6716806436576646701000ppm 0.05mg/m 3350ppm铀(天然的) Uranium,按U计0.2mg/m 3可溶性及不可溶性化合物683尿素 Urin684(正)戊醛 n-Valeraldehyde50ppm 五氧化二钒 Vanadium pentoxide 烟或尘,以V 2O 5计0.05mg/m 3烟或尘，以V计686植物油雾 Vegetable oil mists 10mg/m 3687蛭石粉尘(总尘) Vermiculite dust 688乙酸乙烯酯 Vinyl acetate 10ppm 689溴乙烯 Vinyl bromide 0.5ppm 690氯乙烯 Vinyl chloride1ppm 6914-乙烯基环己烯 4-Vinyl cyclohexene 0.1ppm 二氧化乙烯基环己烯Vinyl cyclohexene dioxide 693氟乙烯 Vinyl fluoride1ppm 694偏二氯乙烯 Vinylidene chloride 5ppm 695偏二氟乙烯 Vinylidene fluoride 500ppm 696乙烯基甲苯 Vinyl toluene 50ppm 697VM&P 石脑油 VM&P Naphtha 300ppm 698杀鼠灵 Warfarin0.1mg/m 3699电焊烟尘 Welding fumes(总尘)5mg/m 3700硅灰石粉尘(总尘) Wollastonite dust 木粉尘 Wood dust(总尘)1mg/m 3某些硬木如栎木和山毛榉软木5mg/m 3702二甲苯 Xylene(邻,间,对异构体)100ppm间二甲苯α,α,-二胺m-Xylene-α，α，-diamine704二甲代苯胺 Xylidine(异构体混合物)0.5ppm 705钇及其化合物，按Y计1mg/m 3706沸石粉尘(总尘) Zeolite dust 707氯化锌烟 Zinc chloride fume 1mg/m 3708铬酸锌盐类,按Cr计0.01mg/m 3氧化锌烟5mg/m 3尘10mg/m 3710锆及其化合物,以Zr计 Zirconium5mg/m 37037096826856927010.1ppm分子量STELTWA STEL 0.30.9C 25ppmC 4544.05 A315ppm1020601632102.09750ppm30045058.05 A4C 5mg/m 3C 385.160ppm102541.05 A4120.1526.02 窒息剂345.7512.5180.15C 0.1ppmC 0.356.06 A40.30.971.08 A361572.06 A41253.05 A3510146.14108.1364.93 A32358.08 A42ppm2476.50 A3114.14 A43ppm 148.1626.9834A446169.23 A15触容许浓度；C (在数值前)-最高容许浓度；A1-确定人致癌物；癌物触限值(容许浓度)对照表中有害物质(包括毒物、粉尘和生物因素)的容许浓度和域限值美国中国2591.1184.08 A335ppm203017.0320ppm 102053.5431.00 A3615114.1310020037.593.12 A30.5 1.5123.15 A30.5 1.5123.15 A40.50.5121.75124.78171.50 A20.30.9202.27 A40.010.0274.92 A1C 0.0377.95 A10.8 1.50.8f/ml 1.5f/ml 512.5 A4216.06 A4317.34 A4510137.30 A41025233.43290.32 A4610228.30 A22.5ppm61078.11 A1184.23 A1252.30 A2252.30 A2C 0.1ppm195.50 A2C 0.5ppm140.57 A4512.5242.22 A4150.18 A4C 5126.58 A30.01mg/m 30.00050.0019.01 A11.5 3.75154.2C 0.005C 6*107 孢子数/m 30.15ppm 0.10.2160.26800.83 A4512.5201.2769.64C 1ppm250.57C 1ppm C 367.82261.11 A3 0.2ppm0.62159.81174.92252.80 A3512.554.09 A258.12C 50ppm10020074.1210020074.1210020074.12 A4118.17200ppm200300116.16200300116.16200300116.162550128.17 A4510C 5ppm C 1573.14220.34 A4C 0.1mg/m3230.2210020060120130.21146.192590.193060150.22148.180.010.02112.40 A2100.09156.09 A21380.11 A474.12556.08A4136.144ppm152.23 A4512.5113.16 A4 3mg/m310ppm349.06 A4300.60 A3201.20 A4221.30 A4A44830000ppm90001800044.0151076.143628.012030C 20C 150.3ppm 1.54331.6510ppm1525153.84 A2 5ppm51066.01110.11 A3102525149.92409.80 A3 1mg/m3414.00 A33771ppm C 170.91 A40.3ppm0.30.867.46C 0.1ppm C 0.4292.46C 1ppm C 378.5C 1ppm C 492.530.30.9154.59 A4 0.15ppm0.20.6112.9550100112.56 A3 C 0.05ppm C 0.4188.61 A4129.393500525086.47 A4266.50.5 1.5328.40 A32040119.38 A3114.96 A1C 0.0050.5 1.580.50 A2123.5450007500154.47C 1164.39 A441088.54108.5375ppm250400138.6C 1126.59A40.050.15 A1A1154.92228.30 A3192.06 A4A4A4462.53.50.20.60.050.158.93 A3341.94171.980.10.31.530.5163.550.20.61 2.51 2.5131025108.14C 0.3ppm C 1270.09 A3291.71 A4120.192542.04C 152.04C 0.3ppm61.4825037584.16100200100.165010094.18 A482.14102099.17 A41.5 3.75222.26 A466.170.13385.16 A4221.04 A40.20.6354.50 A30.15ppm0.250.75122.31601200.030.090.050.15258.3412240360116.16304.36 A40.350.742.04 A20.10.327.69410173.293.58.75286.262ppm210.212.5 6.25278.340.10.2C 0.1ppmC 0.494.93 A350ppm50100147.0 A43060147.01 A3253.13 A3124.99 A25000750098.97 A498.97 A471510ppm 143.02 A4102.9220030084.93 A31224143.96350500512.5410110.98 A4142.97 A4170.93 A4220.98 A40.4mg/m 38001200197.0396.95。
有害气体临界值
200~700
即使短时间暴露也会死亡
NO2
0.2~1
可察觉的有刺激的酸味。
1
允许的暴露浓度(OSHA、ACGIH)
5~10
对鼻子和喉部有刺激
20
对眼睛有刺激
50
30分钟内最大的暴露浓度
100~200
肺部有压迫感，急性支气管炎，暴露稍长一会将引起死亡
SO2
0.3~1
可察觉的最初的SO2
2
允许的暴露浓度(OSHA、ACGIH)
3
非常容易察觉的气味
6~12
对鼻子和喉部有刺激
20
对眼睛有刺激
50~100
30分钟内最大的暴露浓度
400~500
引起肺积水和声门
350～450
同一般室外环境
350～1000
空气清新，呼吸顺畅
Cl2
0.5
允许的暴露浓度(OSHA、ACGIH)。
3
刺激黏膜、眼睛和呼吸道
3.5
产生一种易觉察的臭味。
15
马上刺激喉部。
30
30分钟内最大的暴露浓度
100~150
肺部疼痛、压感，暴露稍长一会将引起死亡。
NO
25
允许的暴露浓度(OSHA)
0~50
较低的水溶性，因此超过TWA浓度，对粘膜也有轻微刺激
60~150
NH3
0~25
对眼睛和呼吸道的最小刺激
25
允许的暴露浓度(OSHA、ACGIH)
50~100
眼脸肿起，结膜炎，呕吐、刺激喉部
100~500…
高浓度时危险，刺激变得更强烈，稍长时间会引起死亡
木尘可致癌
木尘可致癌1．木尘的致癌性。
有两种意见：一种是ACGIH（2014），橡木和山毛榉A1，桦木、桃、柚和胡桃木A2，所有其他木粉尘A4（可能对人不致癌）。
另外一种是不分品种的，认为木尘均可致癌，比如IARC（2012）、GBZ 2.1-2007、NIOSH。
致癌部位为鼻窦癌。
2、木尘的限值分三种：一是ACGIH（2014），以可吸入颗粒物采样，西方红松0.5mg/m3可吸入性颗粒物，其他树种1mg/m3可吸入性颗粒物。
二是OSHA：TWA 15mg/m3(总颗粒物)，5mg/m3（可吸入颗粒物）。
三是GBZ 2.1-2007，只有总尘PC-TWA 3mg/m3。
3、除致癌性外，美国出版的《危险化学品手册》认为，木尘尚可致：眼睛刺激；鼻出血；皮炎；呼吸器官超敏反应；肉芽肿肺炎；哮喘，咳嗽，喘鸣，鼻窦炎；持续感冒。
（国家CDC网站翻译）4、木材加工厂的主要职业病危害因素1）美国CDC网站：可能接触的危害因素：砷，甲醛，五氯酚，木榴油，溶剂（二氯甲烷、甲苯、松节油、干洗溶剂），胶水（环氧树脂、酚醛树脂、氰基丙烯酸盐、对叔丁基苯酚甲醛树脂），煤焦油沥青挥发物，木粉尘等。
2）职业病危害因素行业举例（2002）：下料、锯料、刨料：木粉尘、振动、噪声拼接、压边、封边、修边：甲醛、苯酚、挥发性有机物、噪声等镂铣、砂光、钻孔、机械打磨：木粉尘、振动、噪声手工打磨、精整：木粉尘、振动、噪声涂胶、擦色、调漆、喷漆、晾漆：苯、甲苯、二甲苯、乙酸乙酯、乙酸丙酯、乙酸丁酯、丙酮、丁酮、苯胺、甲苯二异氰酸酯、甲醛、苯酚、其他挥发性有机物、噪声等组装：苯、甲苯、二甲苯、乙酸乙酯、乙酸丙酯、乙酸丁酯、丙酮、丁酮、苯胺、甲苯二异氰酸酯、甲醛、苯酚、其他挥发性有机物、噪声等3）AQ/T 4267-2015 木制家具制造业建设项目职业病危害控制效果评价细则配料：开料、锯料、粗刨料-噪声、振动-木粉尘；干燥-高温零部件制造：拼接、压边、封边、修边-噪声-甲醛、苯酚、挥发性有机物；砂光、钻孔-噪声-木粉尘；打磨、精整-噪声、振动-木粉尘、胶黏剂挥发物弯曲件制造：软化处理-高温、微波辐射-氨、尿素等；机械弯曲-噪声；干燥-高温雕刻：镂铣、雕刻-振动、噪声-木粉尘表面装饰：苯、甲醛、苯胺、二异氰酸甲苯酯、甲苯、二甲苯、正己烷、丙酮、乙酸乙酯、二氯乙烷、二氯丙烷、乙苯、丁酮、苯乙烯、甲醇、乙醇等；胶合、涂漆-噪声；晾漆、覆膜-噪声、高温；装配：组装-噪声-胶黏剂挥发物(甲醛、苯、甲苯、二甲苯等为主)。
acgih标准
acgih标准
ACGIH (American Conference of Governmental Industrial Hygienists) 是一个非营利性组织，致力于提供职业健康和安全方面的指导和标准。
ACGIH 发布的标准主要涵盖了职业暴露限值（Occupational Exposure Limits，OELs）和生物监测指导值（Biological Exposure Indices，BEIs）等方面，旨在保护工作场所从业人员的健康与安全。
ACGIH 发布的标准被广泛用于评估和管理职业环境中的化学物质、物理因素和生物学因素对工人的潜在健康影响。
这些标准通常基于最新的科学研究和风险评估，并且经过专家评审和公众讨论。
ACGIH 的标准是指导性的，虽然不具备法律强制力，但被广泛接受并在职业健康和安全管理中被采用。
请注意，ACGIH 的标准可能根据不同的年份和地区而有所变化。
如果您需要具体的标准内容或更多信息，请参考ACGIH的官方网站或与相关机构进行咨询。
ACGIH 与 Z 标准对比
175
异丙胺
Isopropyiamine
24
24
1.000
177
烯酮
Ketene
2.6
2.5
0.962
186
烷基化合物（以Hg计） 芳基化合物 元素态和无机态
Mercury,alkyl compounds Aryl compounds Elemental and inorganic forms
0.03
Chlorine dioxide
0.83
0.8
0.964
62
氯乙酰氯
89
癸硼烷
Chloroacetyl chloride Decaborane
0.7 0.75
0.6
0.857
0.75
1.000
98
邻二氯苯
o-Dichlorobenzene
300
100
0.333
108
戊酮-3
Diethyl ketone
2
2
1.000
284
氧化锌
Zinc oxide
10
5
0.500
285
锆及其化合物（以Zr计） Zirconium and compounds, as Zr 10
10
1.000
* Toluene diisocyanate, 2,4- or 2,6- (or as a mixture)
0.036
0.2
（或两者混合物）
5.556
279
醋酸乙烯酯
Vinyl acetate
52.7
15
0.285
281
二甲苯及其同分异构体
Xylene
651
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TWA1乙醇甲胺磷 Acephate 2乙醛 Acetaldehyde 3乙酸 Acetic acid10ppm 4乙酐 Acetic anhydride 5ppm 5丙酮 Acetone500ppm 6丙酮氰醇 Acetone cyanohydrin 7乙腈 Acetonitrile 40ppm 8乙酰苯 Acetophenone 10ppm 9乙炔 Acetylene10四溴乙烷 Acetylene tetrabromide 1ppm 11乙酰水杨酸 Acetylsalicylic acid 5mg/m 312丙烯醛 Acrolein 13丙烯酰胺 Acrylamide 0.03mg/m 314丙烯酸 Acrylic acid 2ppm 15丙烯腈 Acrylonitrile 2ppm 16活性炭粉尘(总尘)17己二酸 Adipic acid 5mg/m 318己睛 Adiponitrile 2ppm 19艾氏剂 Aldrin0.25mg/m 320丙烯醇 Allyl alcohol 0.5ppm 21氯丙烯 Allyl chloride1ppm 22烯丙基缩水甘油醚 Allyl glycidyl ether 1ppm 23烯丙基二硫化物 Allyl propyl disulfide 2ppm 铝 Aluminum 铝尘10mg/m 3焦粉木，以铝计5mg/m 3熔烟，以铝计5mg/m 3可溶性盐，以铝计2mg/m 3烷基铝，以铝计2mg/m 3铝、铝合金总尘氧化铝 Aluminum oxide 10mg/m 3总尘264-氨基联苯 4-Aminodiphenyl美国No 2425化合物名称3.由ppm 换算为 mg/m 3的公式为：mg/m 3 = (ppm * 分子量)/22.454.表中符号说明：TWA -时间加权平均容许浓度；STEL -短时间接触容许浓度；C (在数值前)-最高容许浓度 A2-可疑人致癌物；A3-确定动物致癌物；A4-证据不足的人致癌物一.工作场所空气中有害物质容许浓度美国ACGIH和我国职业接触限值说明：1.本附录列出了我国GBZ 2 - 2002和美国的ACGIH的2002 TLVs and BELs 中有害2.本附录按英文字母排列272-氨基吡啶 2-Aminopyridine0.5ppm 283-氨基-1,2,4-三唑 3-Amino-1,2,4-triazole0.2mg/m3 29氨 Ammonia25ppm 30氯化铵烟 Ammonium chloride fume10mg/m3 31全氟辛酸铵 Ammonium perfluorooctanoate0.01mg/m3 32氨基磺酸铵 Ammonium sulamate10mg/m3 33戊醇 Amyl alcohol34苯胺和同系物 Aniline2ppm35邻茴香胺 o-Anisidine0.1ppm 36对茴香胺 p-Anisidine0.1ppm 37锑及其化合物，以Sb计 Antimony0.5mg/m3 38锑化氢 Antimony hydride(Stibine)0.1ppm 39三氧化锑 Antimony trioxide40安妥 ANTU0.3mg/m3 41砷及其无机化合物，以As计 Arsenic0.01mg/m3 42砷化氢 Arsine0.05ppm 石棉 Asbestos总尘纤维0.1f/cc 44石油沥青烟，以苯溶物计 Asphalt fume0.5mg/m3 45阿特拉津 Atrazine5mg/m3 46谷硫磷 Azinphos-methyl0.2mg/m3 47重晶石粉尘(总尘) Barite48钡及其可溶性化合物，以钡计 Barium0.5mg/m3 49硫酸钡 Barium sulfate10mg/m3 50白僵蚕孢子 Beauveria bassiana51苯菌灵 Benomyl10mg/m3 52膨润土粉尘 Bentonite dust53苯并蒽 Benz[a] anthracene54苯 Benzene0.5ppm 55联苯胺 Benzidine56苯并荧蒽 Benzo[b] fluoranthene57苯并(a)芘 Benzo[a] phrene58三氯苯 Benzotrichloride59苄酰氯 Benzoyl chloride60过氧化苯甲酰 Benzoyl peroxide5mg/m3 61乙酸苄酯 Benzyl acetate10ppm 62苄基氯 Benzyl chloride1ppm63铍及其化合物，按Be计 Beryllium0.002mg/m3 64联苯 Biphenyl0.2ppm双2-二甲基胺乙基醚Bis(2-dimethylaminoethyl) etherE双(巯基乙酸)二辛基锡Bis(mercaptoacetate) dioctyltin 67双氯甲醚 Bis(chloromethyl) ether 0.05ppm65 66 43碲化铋 Bismuh telluride 按Bi 2Te 3计不含Se 10mg/m 3含Se5mg/m 3四硼酸钠 Borates,tatra,sodium salt 无水化合物 1mg/m 3十水化合物5mg/m 3五水化合物1mg/m 370氧化硼 Boron oxide10mg/m 371三溴化硼 Boron tribromide 72三氟化硼 Boron trifluoride 73除草定 Bromacil 10mg/m374溴 Bromine0.1ppm 75五氟化溴 Bromine pentafluoride 0.1ppm 76溴仿 Bromoform0.5ppm 771,3-丁二烯 1,3-Butadiene 2ppm 78丁烷 Butane800ppm 79正丁醇 n-Butanol 80仲丁醇 sec-Butanol 100ppm 81特丁醇 tert-Butanol100ppm 822-丁氧基乙醇 2-Butoxyethanol 20ppm 83乙酸正丁酯 n-Butyl acetate 150ppm 84乙酸仲丁酯 sec-Butyl acetate 200ppm 85乙酸特丁酯 tert-Butyl acetate 200ppm 86丙烯酸正丁酯 n-Butyl acrylate 2ppm87丁醛 Butylaldehyde 88正丁胺 n-Butylamine89丁基羟基甲苯(BHT) Butylated hydroxytoluene 2mg/m 390铬酸特丁酯 tert-Butyl chromate 以CrO 3计91丁烯 Butylene92正丁基缩水甘油醚 n-Butyl glycidyl ether 25ppm 93乳酸正丁酯 n-Butyl lactate 5ppm 94正丁基硫醇 n-Butyl mercaptan 0.5ppm 95邻仲丁基苯酚 O-sec-Butylphenol 5ppm 96对特丁基甲苯 p-tert-Butyl toluene 1ppm 镉,Cadmium元素和化合物0.01mg/m 3按Cd计0.002mg/m 398碳酸钙 Calcium carbonate10mg/m 399铬酸盐 Calcium chromate 按Cr计0.001mg/m 3100氰氨化钙 Calcium cyanamide 0.5mg/m 3101氢氧化钙 Calcium hydroxide 5mg/m 3102氧化钙 Calcium oxide2mg/m 3103硅酸钙(合成) Calcium silicate 10mg/m 3104硫酸钙 Calcium sulfate10mg/m3976869105樟脑(合成) Camphor 2ppm 己内酰胺 Caprolactam 粒子1mg/m 3蒸汽5ppm 107敌菌丹 Captafol 0.1mg/m 3108克菌丹 Captan 5mg/m 3109西维因 Carbaryl 5mg/m 3110呋喃丹 Carbofuran 0.1mg/m 3炭黑 Carbon black 3.5mg/m 3总尘112二氧化碳 Carbon dioxide 5000ppm 113二硫化碳 Carbon disulfide 10ppm114碳纤维粉尘(总尘) Carbon fiber 一氧化碳 Carbon monoxide 非高原25ppm高原海拔2000米海拔>3000米116四溴化碳 Carbon tetrabromide 0.1ppm 117四氯化碳 Carbon tetrachloride 5ppm 118羰酰氟 Carbonyl fluoride 2ppm 119儿茶酚(邻苯二酚) Catechol 5ppm 120纤维素 Cellulose10mg/m 3121氢氧化铯 Cesium hydroxide 2mg/m 3122氯丹 Chlordane0.5mg/m 3123氯代莰烯(毒杀芬) Chlorinated camphene 0.5mg/m 3124邻氯代联苯醚 O-Chlorinated diphenyl oxide 0.5mg/m 3125氯 Chlorine0.5ppm 126二氧化氯 Chlorine dioxide 0.1ppm127三氟化氯 Chlorine trifluoride 128氯乙醛 Chloroacetaldehyde 129氯丙酮 Chloroacetone1302-氯乙酰苯 2-Chloroacetophenone 0.05ppm 131氯乙酰氯 Chloroacetyl chloride 0.05ppm 132氯苯 Chlorobenzene 10ppm邻氯苄叉丙二腈o-Chlorobenzylidine alononitrile 134氯溴甲烷 Chlorobromomethane200ppm 135二氟氯甲烷 Chlorodifluoromethane 1000ppm 136氯联苯 Chlorodiphenyl(42%氯)1mg/m 3137氯联苯 Chlorodiphenyl(54%氯)0.5mg/m 3138氯仿(三氯甲烷) Chloroform(Trichloromethane)10ppm 139双氯甲醚 bis(Chloromethyl) ether 0.001ppm140氯甲甲醚 Chloromethyl methyl ether 141氯萘 Chloronaphthalene1421-氯-1-硝基丙烷 1-Chloro-1-nitropropane2ppm133106111115143五氟氯乙烷 Chloropentafluoroethane 1000ppm 144氯化苦 Chloropicrin0.1ppm 145β-氯丁二烯 β-Chloroprene10ppm 1462-氯丙酸 2-Chloropropionic acid 0.1ppm 147邻氯苯乙烯 o-Chlorostyrene 50ppm 148百菌清 Chlorothalonile 149邻氯甲苯 o-Chlorotoluene 50ppm 150毒死蜱 Chlorpyrifos 0.2mg/m 3铬铁矿石加工(铬酸盐)Chromite ore processing(Chromate) 以Cr计铬 Chromiun 及其无机化合物,以Cr计金属和三价化合物0.5mg/m 3水溶性六价化合物0.05mg/m 3不可溶性六价化合物0.01mg/m 3153铬酰氯 Chromyl chloride 0.025ppm 154屈 Chrysene155二氯二甲吡啶粉 Clopidol 10mg/m3煤尘 Coal dust 无烟煤 Anthracite 0.4mg/m 3烟煤 Bituminous 0.9mg/m 3总尘呼尘煤焦油沥青挥发物,按苯溶物计 Coal tar pitch volatiles158钴及其无机化合物,按Co计 Cobalt 0.02mg/m 3159羰基钴,按Co计 Cobalt carbonyl0.1mg/m 3160羰基氢钴,按Co计 Cobalt hydrocarbonyl 0.1mg/m 3161焦炉逸散物,按苯溶物计 Coke over emission 凝聚SiO 2粉尘 Condensed silica 总尘呼尘铜 Copper 烟0.2mg/m 3尘和雾，以Cu计1mg/m 3164考的松 Cortisone165棉尘 Cotton dust,raw(总尘)0.2mg/m 3166甲酚,所有异构体 Cresol 5ppm 167巴豆醛 Crotonaldehyde 168育畜磷 Crufomate 5mg/m 3169异丙苯(枯烯) Cumene 50ppm 170氨基氰 Cyanamide 2mg/m 3171氰化物 Cyanogen10ppm 172氯化氰 Cyanogen chloride 173环己烷 Cyclohexane 300ppm 174环己醇 Cyclohexanol50ppm0.05mg/m 30.2mg/m 3157162163151152156175环己酮 Cyclohexanone 25ppm 176环己烯 Cyclohexene 300ppm 177环己胺 Cyclohexylamine10ppm 178三次甲基三硝基胺(黑索金) Cyclonite(RDX)0.5mg/m 3179环戊二烯 Cyclopentadiene 75ppm 180环戊烷 Cyclopentane 600ppm 181杀螨锡 Cyhexatin 5mg/m 31822,4-D10mg/m 3183滴滴涕 DDT Dichlorodiphenyltrichloroethane 1mg/m 3184癸硼烷 Decaborane 0.05ppm185萘烷 Decalin186溴氰菊酯 Deltamethrin 187内吸磷 Demeton0.01ppm 188洗衣粉混合尘 Detergent mixed dust 189双丙酮醇 Diacetone alcohol 50ppm190二嗪农 Diazinon0.1mg/m 3191重氮甲烷 Diazomethane 0.2ppm 192二硼烷 Diborane0.1ppm 1932-N-二丁氨基乙醇 2-N-Dibutylaminoethanol 0.5ppm 194磷酸二丁基苯酯 Dibutyl phenyl phosphate 0.3ppm 195磷酸二丁酯 Dibutyl phosphate1ppm196邻苯二甲酸二丁酯 Dibutyl phthalate 5mg/m3197二月桂酸二丁基锡 Dibutyltin dilaurate 198二氯代乙炔 Dichloroacetylene 199邻二氯苯 o-Dichlorobenzene 25ppm 200对二氯苯 p-Dichlorobenzene10ppm 2013,3,-二氯联苯胺 3,3,-Dichlorobenzidine 2021,4-二氯-2-丁烯 1,4-Dichloro-2-butene 0.005ppm 203二氯二氟甲烷 Dichlorodifluoromethane 1000ppm 1,3-二氯-5,5-二甲基乙内酰脲1,3-Dichloro-5,5-dimethyl hydantoin 2051,1-二氯乙烷 1,1-Dichloroethane 100ppm 2061,2-二氯乙烷 1,2-Dichloroethane 1,2-二氯乙烯,所有异构体 1,2-Dichloroethylene208二氯乙醚 Dichloroethyl ether 4ppm 209二氯氟甲烷 Dichlorofluoromethane 10ppm 210二氯甲烷 Dichloromethane50ppm 2111-二氯-1-硝基乙烷 1-Dichloro-1-nitroethane 2ppm2121,2-二氯丙烷 1,2-Dichloropropane 2131,3-二氯丙醇 1,3-Dichloropropanol 2141,3-二氯丙烯 1,3-Dichloropropene1ppm 2152,2-二氯丙酸 2,2-Dichloropropionic acid 5mg/m 3216二氯四氟乙烷 Dichlorotetrafluoroethane 1000ppm 217敌敌畏(DDVP) Dichlorvos 0.9mg/m 3218百治磷 Dicrotophos0.25mg/m 30.2mg/m 3200ppm 207204219二聚环戊二烯 Dicyclopentadiene 5ppm 220二戊铁 Dicyclopentadienyl iron 10mg/m 3221狄氏剂 Dieldrin0.25mg/m 3222二乙醇胺 Diethanolamine 2mg/m 3223二乙胺 Diethylamine5ppm 2242-二乙胺基乙醇 2-Diethylaminoethanol 2ppm 225二乙撑三胺 Diethylene triamine1ppm 226邻苯二2-乙基己酯 Di(2-ethylhexyl)phthalate 5mg/m 3227二乙基甲酮 Diethyl ketone 200ppm228酞酸二乙酯 Diethyl phthalate5mg/m 3229二氟二溴甲烷 Difluorodibromomethane 100ppm 230二缩水甘油醚 Diglycidyl ether 0.1ppm 231二异丁基甲酮 Diisobutyl ketone 25ppm 232二异丙胺 Diisopropylamie5ppm 233N,N-二甲基乙酰胺 N,N-Dimethylacetamide 10ppm 234二甲胺 Dimethylamine5ppm 235N,N-二甲基苯胺 N,N-Dimethylaniline 5ppm2363,3-二甲基联苯胺 3,3-Dimethylbenzidine237二甲基氨基甲酰氯 Dimethyl carbamoyl chloride 238二甲基二氯硅烷 Dimethyl dichlorosilane 239二甲基乙氧基硅烷 Dimethylethoxysilane 0.5ppm 240二甲基甲酰胺 Dimethylformamide 10ppm 1,1-二甲基肼(偏二甲基肼)1,1-Dimethylhydrazine242邻苯二甲酸二甲酯 Dimethyphthalate 5mg/m 3243硫酸二甲酯 Dimethyl sulfate 0.1ppm 244Dinitolmide5mg/m 3245二硝基苯,全部异构体 Dinitrobenzene 0.15ppm 246二硝基氯苯 Dinitrochlorobenzene2474,6-二硝基邻苯甲酚 4,6-Dinitro-o-cresol 0.2mg/m 3248二硝基甲苯 Dinitrotoluene 0.2mg/m 32491,4-二噁烷 1,4-Dioxane 20ppm 250二噁磷 Dioxathion 0.2mg/m 3251二苯胺 Diphenylamine 10mg/m 3二丙烯基乙二醇甲基醚Dipropylene glycol methyl ether 253二丙基甲酮 Dipropyl ketone 50ppm 杀草快 Diquat 可吸入从0.5mg/m 3呼吸性0.1mg/m 3255双硫醒 Disulfiram 2mg/m 3256乙拌磷 Disulfoton 0.1mg/m 3257敌草隆 Diuron10mg/m 3258二乙烯基苯 Divinyl benzene 10ppm白云石粉尘 Dolomite dust0.01ppm 100ppm 259241252254259总尘呼尘260金刚砂 Emery10mg/m3 261硫丹 Endosulfan0.1mg/m3 262异狄氏剂 Endrin0.1mg/m3 263安氟醚 Enflurane75ppm 264环氧氯丙烷 Eqichlorohydrin0.5ppm 265苯硫磷 EPN0.1mg/m3 266乙醇 Ethanol1000ppm 267乙醇胺 Ethanolamine3ppm 268乙硫磷 Ethion0.4mg/m3 2692-乙氧基乙醇 2-Ethoxyethanol5ppm 2702-乙氧基乙基乙酸酯 2-Ethoxyethyl acetate5ppm 271乙酸乙酯 Ethyl acetate400ppm 272丙烯酸乙酯 Ethyl acrylate5ppm 273乙胺 Ethylamine5ppm 274乙基戊基甲酮 Ethyl amyl ketone25ppm 275乙苯 Ethyl benzene100ppm 276溴乙烷 Ethyl bromide5ppm 277乙基特丁基醚 Ethyl tert-butyl ether5ppm 278乙基丁基甲酮 Ethyl butyl ketone50ppm 279氯乙烷 Ethyl chloride100ppm 280氰基丙烯酸乙酯 Ethyl cyanoacrylate0.2ppm 281乙烯 Ethylene2822-氯乙醇 Ethylene chlorohydrin283乙二胺 Ethylenediamine10ppm 2841,2-二溴乙烷 Ethylene dibromide2851,2-二氯乙烷 Ethylene dichloride10ppm 286乙二醇气溶胶 Ethylene glycol287乙二醇二硝酸酯 Ethylene glycol dinitrate0.05ppm 288环氧乙烷 Ethylene oxide1ppm 289乙撑亚胺 Ethylenmine0.5ppm 290乙醚 Ethyl ether400ppm 291甲酸乙酯 Ethyl formate100ppm 292N-乙基吗啉 N-Ethylmorpholine293乙叉降冰生烯 Ethylidene norbornene294乙硫醇 Ethyl mercaptan0.5ppm 295N-乙基吗啉 N-Ethylmorpholine5ppm 296硅酸乙酯 Ethyl silicate10ppm 297丰索磷 Fenamiphos0.1mg/m3 298辛索磷 Fensulfothion0.1mg/m3 299倍硫磷 Fenthion0.2mg/m3 300氰戊菊酯 Fenvlerate301福美铁 Ferbam10mg/m3 302铁钒(合金)尘 Ferrovanadium dust1mg/m3玻璃钢粉尘(总尘)Fiberglass einforced plastic dust 麻尘(游离SiO 2含量<10%)亚麻 Flax(总尘)黄麻 Jute(总尘)苎麻 Ramie(总尘)305面粉尘 Flour dust0.5mg/m 3306氟化物,按F计 Fluorides 2.5mg/m 3307氟 Fluorine1ppm 308萤石混合性粉尘(总尘) Fluorspar mixed dust 309地虫磷 Fonofos0.1mg/m 3310皮毛粉尘(总尘) Fur dust 311甲醛 Formaldehyde 312甲酰胺 Formamide 10ppm 313甲酸 Formic acid 5ppm 314呋喃 Furan 315糠醛 Furfural2ppm 316糠醇 Furfuryl alcohol 10ppm 317汽油 Gasoline300ppm 318四氢化锗 Germanium tetrahydride 0.2ppm 319戊二醛,活性和非活性 Glutaraldehyde 320甘油雾 Glycerin mist 10mg/m 3321缩水甘油 Glycidol2ppm322甲基丙烯酸缩水甘油酯 Glycidyl methacrylate 323乙二醛 Glyoxal0.1mg/m 3324谷物粉尘(像小麦,大麦等) Grain dust(总尘)4mg/m 3石墨(除石墨纤维以外) Graphite 总尘2mg/m 3呼尘326砂轮磨尘(总尘) Grinding wheel dust 石膏粉尘 Gypsum dust 总尘呼尘328合及其化合物,按Hf计 Hafnium 0.5mg/m 3329庚烷 Halothane50ppm 七氯和七氯环氧化物Heptachlor and Heptachlor epoxide 331正庚烷 Heptane400ppm 332六氯苯 Hexachlorobenzene0.002mg/m 3333六氯丁二烯 Hexachlorobutadiene 0.02ppm334六六六 Hexachlorocyclohexane 335γ-六六六 Hexachlorocyclohexane336六氯环戊二烯 Hexachlorocyclopentadiene 0.01ppm 337六氯乙烷 Hexachloroethane 1ppm 338六氯萘 Hexachloronaphthalene0.2ppm0.05mg/m 3327330303304325339六氟丙酮 Hexafluoroacetone 0.1ppm 340六氟丙烯 Hexapropylene3411,6-已二异氰酸酯 Hexamethylene diisocyanate 0.005ppm 342六甲基磷酰胺 Hexamethyl phosphoramide 343正己烷 n-Hexane50ppm 344己烷,其他异构体 Hexane500ppm 3451,6-二胺基己烷 1,6-Hexanediamine 0.5ppm 3462-己酮 2-Hexanone 3471-己烯 1-Hexene30ppm 348乙酸仲己酯 sec-Hexyl acetate 50ppm 349己二醇 Hexylene glycol 350肼 Hydrazine0.01ppm叠氮酸和叠氮化钠Hydrazoic acid & Sodium azide 叠氮酸蒸汽叠氮化钠352氢化三联苯 Hydrogenated terphenyl 0.5ppm353溴化氢 Hydrogen bromide 354氯化氢 Hydrogen chloride 氰化氢和氰化物,按CN计氰化氢Hydrogen cyanide 氰化物356氟化氢 Hydrogen fluoride 357过氧化氢 Hydrogen peroxide 1 ppm 358硒化氢 Hydrogen selenide 0.05ppm 359硫化氢 Hydrogen sulfide 10ppm 360氢醌 Hydroquinone2mg/m 3361丙烯酸2-羟基丙酯 2-Hydroxypropyl acrylate 0.5ppm 362茚 Indene10ppm 363铟及其化合物,按In计 Indium 0.1mg/m 3364碘 Iodine365碘仿 Iodoform0.6ppm 366氧化铁烟尘,按Fe计 Iron oxide5mg/m3367五羰基铁,按Fe计 Iron pentacarbonyl 0.1ppm368可溶性铁盐,按Fe计 Iron salt 1mg/m 3369异戊醇 Isoamyl alcohol100ppm 370丁酸异丁酯 Isobutyl acetate 150ppm 371异丁醇 Isobutyl alcoho 150ppm 372异辛醇 Isooctyl alcohol 50ppm 373异佛尔酮 Isophrone374异佛尔酮二异氰酸酯 Isoprorone diisocyanate 0.005ppm 3752-异丙氧乙醇 2-Isopropoxyethanol 25ppm 376乙酸异丙酯 Isopropyl acetate 250ppm 377异丙醇 Isopropyl alcohol 400ppm 378异丙胺 Isopropylamine5ppm 379N-异丙基苯胺 N-Isopropyl aniline 2ppm 380异丙醚 Isopropyl ether250ppm351355381异丙基缩水甘油醚 Isopropyl glycidyl ether 50ppm 382陶土,高岭土 Kaolin 2mg/m 3383乙烯酮 Ketene0.5ppm 384异稻瘟净 Kitazin o-p铅及无机化合物,按Pb计 Lead 0.05mg/m 3铅烟铅尘386砷酸铅,以Pb 3(AsO 4)2计 Lead arsenate 0.15mg/m 3铬酸铅,以Pb计 Lead chromate 0.05mg/m 3按Cr计0.012mg/m 3石灰石粉尘 Limestone dust 总尘呼尘389林丹 Lindane0.5mg/m 3390氢化锂 Lithiun hydride0.025mg/m 3391液化石油气 Liquefied petroleum gas 1000ppm 392菱镁矿 Magnesite10mg/m 3393氧化镁烟 Magnesium oxide fume 10mg/m 3394马拉硫磷 Malathion10mg/m 3395马来酸酐 Maleic anhydride0.1ppm396锰及无机化合物,按Mn计 Manganese 0.2mg/m 3环戊二烯三羰基锰,按Mn计Manganese cyclopentadienyl tricarbonyl 大理石粉尘 Marble dust 总尘呼尘汞,以Hg计 Mercyry烷基汞 Alkyl compounds 0.01mg/m 3芳基汞 Aryl compounds 0.1mg/m 3汞及无机化合物0.025mg/m 3400异亚丙基丙酮 Mesityl oxide 15ppm 401甲基丙烯酸 Methacrylic acid 20ppm 402甲醇 Methanol 200ppm 403灭多虫 Methomyl 2.5mg/m 3404甲氧氯 Methoxychlor10mg/m 34052-甲氧基乙醇 2-Methoxyethanol5ppm 406乙酸2-甲氧基乙酯 2-Methoxyethyl acetate 5ppm 4074-甲氧基苯酚 4-Methoxyphenol 5mg/m 34081-甲氧基-2-丙醇 1-Methoxy-2-丙醇100ppm 双-(2-甲氧基丙基)醚bis-(2-Methoxypropyl) ether 410乙酸甲酯 Methyl acetate 200ppm 411丙炔 Methyl acetylene 1000ppm 丙炔-丙二烯混合物1000ppm0.1mg/m 3200ppm 398399409412385387388397Methyl acetylene-propadiene mixture 413丙烯酸甲酯 Methyl acrylate 2ppm 414甲基丙烯晴 Methylacrylonitrile 1ppm 415甲缩醛 Methylal 1000ppm 416一甲胺 Methylamine 5ppm 417甲基正戊基甲酮 Methyl n-amyl ketone 50ppm 418N-甲基苯胺 N-Methyl aniline 0.5ppm 419溴甲烷 Methyl bromide 1ppm 420甲基特丁醚 Methyl tert-butyl ether 40ppm 421甲基正丁基甲酮 Methyl n-butyl ketone 5ppm 422氯甲烷 Methyl chloride 50ppm 4232-氰基丙烯酸甲酯 Methyl 2-cyanoacrylate 0.2ppm 424甲基环己烷 Methylcyclohexane 400ppm 425甲基环己醇 Methylcyclohexanol 50ppm 426邻甲基环己酮 o-Methylcyclohexanone 50ppm 2-甲基环戊二烯三羰基锰,按Mn计 2-Methylcy-clopentadienyl manganese tricarbonyl 428甲基内吸磷 Methyl demeton 0.5mg/m 3二苯基甲烷二异氰酸酯Methylene bisphenyl isocaynate 4,4,-亚甲基双(2-氯苯胺)4,4,-Methylene bis(2-chloroaniline)亚甲基双(4-环己基异氰酸酯)Methylene bis(4-cyclohexylisocyanate)4324,4,-亚甲基联苯胺 4,4,-Methylene dianiline0.5ppm 433甲基乙基甲酮(丁酮) Methyl ethyl ketone 200ppm 甲基乙基甲酮过氧化物Methyl ethyl ketone peroxide 435甲酸甲酯 Methyl formate 100ppm 436甲基肼 Methyl hydrazine 0.01ppm 437碘甲烷 Methyl iodide 2ppm 438甲基异戊基甲酮 Methyl isoamyl ketone 50ppm 439甲基异戊醇 Methyl isobutyl carbinol 25ppm 440甲基异丁基甲酮 Methyl isobutyl ketone 50ppm 441异氰酸甲酯 Methyl isocyanate 0.02ppm 442甲基异丙基甲酮 Methyl isopropyl ketone 200ppm 443甲硫醇 Methyl mercaptan 0.5ppm 444甲基丙烯酸甲酯 Methyl methacrylate 50ppm 44518-甲基炔诺酮(炔诺孕酮)18-Methyl norgestrel 446Methyl parathion 甲基对硫磷0.2mg/m 3447甲基丙基甲酮 Methyl propyl ketone 200ppm 448硅酸甲酯 Methyl silicate 1ppm 449α-甲基苯乙烯 α-Methyl styrene 50ppm 450丁烯酮 Methyl vinyl ketone451嗪草酮 Metribuzin 5mg/m3452速灭磷 Mevinphos 0.09mg/m30.005ppm1000ppm0.2mg/m30.005ppm0.01ppm 434427429430431412云母粉尘 Mica 总尘3mg/m 3呼尘钼,以Mo计 Molybdenum 可溶性化合物0.5mg/m 3金属和不溶性化合物10mg/m 3455久效磷 Monocrotophos 0.25mg/m 3456吗啉 Morpholine20ppm 457桑蚕丝尘(总尘) Mulberry silk dust 458二溴磷 Naled 3mg/m 3459萘 Naphthalene10ppm460β-萘胺 β-Naphthylamine 镍 Nickel 金属镍1.5mg/m 3可溶性化合物,按Ni计0.1mg/m 3不可溶性化合物,按Ni计0.2mg/m 3462羰基镍 Nickel carbonyl 0.05ppm 463亚硫酸镍 Nickel subsulfide 0.1mg/m 3464烟碱 Nicotine0.5mg/m 3465硝基黄铁矿 Nitrapyrin 10mg/m 3466硝酸 Nitric acid2ppm 467一氧化氮 Nitric oxide 25ppm 468对硝基苯胺 p-Nitroaniline 3mg/m 3469硝基苯 Nitrobenzene1ppm 470对硝基氯苯 p-Nitrochlorobenzene 0.1ppm 4714-硝基联苯 4-Nitrodiphenyl 472硝基乙烷 Nitroethane100ppm 473二氧化氮 Nitrogen dioxide 3ppm 474三氟化氮 Nitrogen trifluoride 10ppm 475硝化甘油 Nitroglycerin 0.05ppm 476硝基甲烷 Nitromethane 20ppm 4771-硝基丙烷 1-Nitropropane 25ppm 4782-硝基丙烷 2-Nitropropane10ppm 479N-亚硝基二甲胺 N-Nitrosodimethylamine 480硝基甲苯 Nitrotoluene 2ppm 481氧化亚氮 Nitrous oxide 50ppm 482壬烷,全部异构体 Nonane200ppm 483八氯萘 Octachloronaphthalene 0.1mg/m 3484辛烷,全部异构体 Octane 300ppm 485奥克托今 Octogen486矿物油雾 Oil mist,mineral 5mg/m 3487氧化乐果 Omethoate488四氧化锇 Osmium tetroxide 0.0002ppm489草酸 Oxalic acid 1mg/m 3p,p ,-羟苯(苯磺酰基)0.1mg/m 3490453454461p,p ,-Oxybis(benzenesulfonyl hydrazide)491二氟化氧 Oxygen difluoride 臭氧 Ozone 重体力工作0.05ppm 中等体力工作0.08ppm 轻体力工作0.10ppm 重、中或轻度体力负荷(<2h)0.20ppm 493石蜡烟 Paraffin Wax fume 2mg/m 30.5mg/m 30.1mg/m 3495对硫磷 Parathion 0.1mg/m 3其他粉尘Particles not otherwise regulated 不溶性微粒 Particulates 可吸入微粒10mg/m 3呼吸性微粒3mg/m 3498戊硼烷 Pentaborane0.005ppm 499五氯萘 Pentachloronaphthalene0.5mg/m 3500五氯硝基苯 Pentachloronitrobenzene 501五氯酚及其钠盐 Pentachlorophenol 0.5mg/m 3502季戊四醇 Pentaerythritol 10mg/m 3503戊烷，全部异构体 Pentane600ppm 504乙酸戊酯,全部异构体 Pentyl acetate 50ppm 505全氯甲硫醇 Perchloromethyl mercaptan 0.1ppm 506氟化全氯氧 Perchloryl fluoride 3ppm 507全氟异丁烯 Perfluoroisobutylene 珍珠岩粉尘 Perlite 10mg/m 3总尘呼尘509过硫酸盐 Persulfates 0.1mg/m 3510酚 Phenol5ppm酚醛树脂粉尘(总尘)Phenolic aldehyde resin dust 512吩噻嗪 Phenothiazine5ppm 513N-苯基-β-萘胺 N-Phenyl-beta-naphthylamine 514邻苯二胺 o-Phenylenediamine 0.1mg/m 3515间苯二胺 m-Phenylenediamine 0.1mg/m 3516对苯二胺 p-Phenylenediamine 0.1mg/m 3517苯醚,蒸汽 Phenyl ether1ppm 518缩水甘油苯醚 Phenyl glycidyl ether 0.1ppm 519苯肼 Phenylhydrazine 0.1ppm 520苯硫醇 Phenyl mercaptan 0.5ppm 521苯膦 Phenylphosphine 522甲拌磷 Phorate 0.05mg/m 3523光气 Phosgene0.1ppm0.1mg/m 3百草枯 Paraquat497508511490492494496524磷胺 Phosphamidon 525磷化氢 Phosphine 0.3ppm 526磷酸 Phosphoric acid 1mg/m 3527黄磷 Phosphorus0.02ppm 528三氯氧磷 Phosphorus oxychloride 0.1ppm 529五氯化磷 Phosphorus pentachloride 0.1ppm 530五硫化二磷 Phosphorus pentasulfide 1mg/m 3531五氧化二磷 Phosphorus pentoxide 532三氯硫磷 Phosphorus thiochloride 533三氯化磷 Phosphorus trichloride 0.2ppm 534邻苯二甲酸酐 Phthalic anhydride 1 ppm 535间酞二腈 m-Phthalodinitrile 5mg/m 3536毒秀定 Picloram 10mg/m 3537苦味酸 Picric acid 0.1mg/m 3538杀鼠酮 Pindone0.1mg/m 3539哌嗪二盐酸盐 Piperazine dihydrochloride 5mg/m 3铂 Platinmu 金属1mg/m 3可溶性铂盐,按Pt计0.002mg/m 3聚丙烯腈纤维粉尘(总尘)Polycrylonitrile fiber dust542聚乙烯粉尘(总尘) Polyethylene dust 多次甲基多苯基多异氰酸酯Polymethylene polyphenyl isocyanate 544聚丙烯粉尘(总尘) Polyprpylene dust545聚四氟乙烯分解物 Polytetrafluoroethylene 546聚氯乙烯粉尘(总尘)Polyvinyl chloride dust 硅配酸盐水泥 Portland cement 10mg/m 3总尘(游离SiO 2含量<10%)呼尘(游离SiO 2含量<10%)548氢氧化钾 Potassium hydroxide 沉淀SiO 2(白碳黑)(总尘)Precipitated silica dust 550丙烷 Propane2500ppm 551丙烷磺内酯 Propane sultone552正丙醇 n-Propanol(n-Propyl alcohol)200ppm 553炔丙醇 Propargyl alcohol1ppm 554β-丙炔内酯 β-Propiolactone 0.5ppm 555丙酸 Propionic acid 10ppm 556残杀威 Propoxur0.5mg/m 3557乙酸正丙酯 n-Propyl acetate 200ppm 558丙烯 Propylene559二氯丙烷 Propylene dichloride 75ppm 丙(撑)二醇二硝酸酯0.05ppm560541543547549540Propylene glycol dinitrate 561丙烯亚胺 Propylene imine 2ppm 562环氧丙烷 Propylene oxide 2ppm 563硝酸正丙酯 n-Propyl nitrate 25ppm 564除虫菊 Pyrethrum 5mg/m 3565吡啶 Pyridine 5ppm 566苯醌 Quinone0.1ppm567抽余油(60-220o C) Raffinate稀土粉尘(游离SiO 2含量<10%)(总尘)Rare-earth dust 569间苯二酚 Resorcinol 10ppm 铑,按Rh计 Rhodium 金属和不可溶性化合物1mg/m 3可溶性化合物0.01mg/m 3571乐果 Rogor 572皮蝇磷 Ronnel10mg/m 3松香焊锡分解产物 Rosin core solderthermal decomposition products(colophony)574鱼藤酮 Rotenone 5mg/m 3575红铁粉 Rouge10mg/m 3576橡胶溶剂(石脑油) Rubber solvent(Naphtha)400ppm 硒及其化合物,除六氟化硒和硒化氢外按Se计 Selenium578六氟化硒 Selenium hexafluoride 0.05ppm 579Sesone10mg/m 3无定形二氧化硅 Silica 硅藻土(游离SiO 2含量<10%)可吸入尘10mg/m 3呼吸性尘3mg/m 3沉淀的二氧化硅和硅胶10mg/m 3二氧化硅烟 Silica,fume2mg/m 3熔化的二氧化硅 Silica,fused 0.1mg/m 3晶体形二氧化硅 Silica 方石英 Cristalline 0.05mg/m 3石英 Quartz0.05mg/m 3鳞石英 Tridymite 0.05mg/m 3板状硅藻岩 Tripoli 0.1mg/m 3矽尘 Silica dust 总尘含10%-50%游离SiO 2含50%-80%游离SiO 2含80%以上游离SiO 2呼尘0.05ppm 致敏剂0.2mg/m 3577580581582560568570573含10%-50%游离SiO 2含50%-80%游离SiO 2含80%以上游离SiO 2583硅 Silicon10mg/m 3碳化硅粉尘 Silicon carbide 总尘10mg/m 3呼尘585四氢化硅 Silicon tetrahydride 5ppm 银 Silver 金属0.1mg/m 3可溶性化合物,按Ag计0.01mg/m 3皂石 Soapstone 可吸入尘6mg/m 3呼吸性尘3mg/m 3588亚硫酸氢钠 Sodium bisulfite 5mg/m 3589碳酸钠 Sodium carbonate590氟乙酸钠 Sodium fluoroacetate 0.05mg/m 3591氢氧化钠 Sodium hydroxide592偏亚硫酸氢钠 Sodium metabisulfite 5mg/m 3593溶剂汽油 Solvent gasolines 594淀粉 Starch10mg/m 3595硬脂酸盐 Stearates10mg/m 3596洗毛织品用汽油类溶剂 Stoddard solvent 100ppm 597铬酸锶,按Cr计 Strontium chromate 0.0005mg/m 3598马钱子碱 Strychnine 0.15mg/m 3599苯乙烯 Styrene20ppm 600枯草杆菌蛋白酶(活性晶体酶) Subtilisins 601蔗糖 Sucrose10mg/m 3602甲嘧磺隆 Sulfometuron methyl 5mg/m 3603治螟磷 Sulfotep0.2mg/m 3604二氧化硫 Sulfur dioxide2ppm 605六氟化硫 Sulfur hexafluoride 1000ppm 606硫酸 Sulfuric acid及三氧化硫1mg/m 3607一氯化硫 Sulfur monochloride 608五氟化硫 Sulfur pentafluoride 609四氟化硫 Sulfur tetrafluoride 610硫酰氟 Sulfuryl fluoride 5ppm 611硫丙磷 Sulprofos 1mg/m 3612杀螟松 Sumithion 合成玻璃纤维Synthetic Vitreou Fibers 长丝玻璃纤维1f/cc584586587玻璃棉纤维5mg/m 3岩棉纤维1f/cc 矿渣棉纤维1f/cc 特殊用途玻璃纤维1f/cc 难熔的陶器用品的玻璃纤维1f/cc 0.2f/cc 6142,4,5-涕 2,4,5-T10mg/m 3滑石粉尘 Talc(游离SiO 2含量<10%)总尘2mg/m 3呼尘616钽金属及其氧化,按Ta计 Tanatalum 5mg/m 3617茶尘(总尘) Tea dust618碲及其化合物,以Te计,除碲化氢外 Tellurium 0.1mg/m 3619六氟化碲 Tellurium hexafluoride 0.02ppm 620双硫磷 Temephos 10mg/m 3621特普 TEPP0.05mg/m 3622对苯二甲酸 Terephthalic acid 10mg/m 3623三联苯 Terphenyl1,1,1,2-四氯-2,2-二氟乙烷1,1,1,2-Tetrachloro-2,2-difluoro ethane 1,1,2,2-四氯-1,2-二氟乙烷1,1,2,2-Tetrachloro-1,2-difluoro ethane 6261,1,2,2-四氯乙烷 1,1,2,2-Tetrachloroethane 1ppm 627四氯乙烯 Tetrachloroethylene 25ppm 628四氯萘 Tetrachloronaphthalene 2mg/m 3629四乙基铅,按Pb计 Tetraethyl lead 0.1mg/m 3630四氟乙烯 Tetrafluoroethylene 2ppm 631四氢呋喃 Tetrahydrofuran200ppm 632四甲基铅,按Pb计 Tetramethyl lead0.15mg/m 3633四甲基琥珀腈 Tetramethyl succinonitile 0.5ppm 634四硝基甲烷 Tetranitromethane0.005ppm 635焦磷酸四钠 Tetrasodium pyrophosphate 5mg/m 3636特屈儿(2,4,6-三硝基苯甲硝胺) Tetrl 1.5mg/m 3637铊及其可溶性化合物,按Tl计 Thallium 0.1mg/m 3638甲拌磷 Thimet4,4,-硫代双(6-特丁基间甲酚)4,4,-Thiobis(6-tert-butyl-m-cresol)640巯基醋酸 Thioglycolic acid 1ppm 641亚硫酰(二)氯 Thionyl chloride 642福美双 Thiram 1mg/m 3锡 Tin金属、氧化物和无机化合物(除氢化锡),按Sn计2mg/m 3有机化合物,按Sn计0.1mg/m 3644二氧化钛粉尘 Titanium dioxide10mg/m 3500ppm 500ppm 10mg/m 3643615624625639613645烟草尘(总尘) Tobacco dust 646邻联甲苯胺 o-Tolidine 647甲苯 Toluene50ppm 648二异氰酸甲苯酯 Toluene-2,4-diisocyanate 0.005ppm 649邻甲苯胺 o-Toluidine 2ppm 650间甲苯胺 m-Toluidine 2ppm 651对甲苯胺 p-Toluidine2ppm 652磷酸三丁酯 Tributyl phosphate 0.2ppm653敌百虫 Trichlorfon654三氯乙醛 Trichloroacetaldehyde 655三氯乙酸 Trichloroacetic acid1 ppm 6561,2,4-三氯苯 1,2,4-Trichlorobenzene 1,1,1-三氯乙烷(甲基氯仿)1,1,1-Trichloroethane(Methyl chloroform)6581,1,2-三氯乙烷 1,1,2-Trichloroethane 10ppm 659三氯乙烯 Trichloroethylene50ppm 660三氯氟甲烷 Trichlorofluoronethane 661三氯萘 Trichloronaphthalene5mg/m 36621,2,3-三氯丙烷 1,2,3-Trichloropropane 10ppm 663三氯氢硅 Trichlorosilane 1,1,2-三氯-1,2,2-三氟乙烷1,1,2-Trichloro-1,2,2-trifluoroethane 665三甲苯磷酸酯 Tricresyl phosphate 666三乙醇胺 Triethanolamine 5mg/m 3667三乙胺 Triethylamine1ppm 668三乙基氯化锡 Triethyltin chloride 669三氟溴甲烷 Trifluobromomethane 1000ppm三氟甲基次氟酸酯Trifluoromethyl hypofluorite 1,3,5-三缩水甘油-s-三嗪三酮1,3,5-Triglycidyl-s-triazinetrione 672偏苯三酸酐 Trimellitic anhydride 673三甲胺 Trimethylamine5ppm 674三甲基苯 Trimethyl benzene25ppm 675亚磷酸三甲酯 Trimethyl phosphite2ppm 676三硝基甲苯(TNT) 2,4,6-Trinitrotoluene 0.1mg/m 3677磷酸三邻甲苯酯 Triorthocresyl phosphate 0.1mg/m 3678三苯胺 Triphenyl amine5mg/m 3679磷酸三苯酯 Triphenyl phosphate 3mg/m 3钨,按W计 Tungsten金属钨及其不溶性化合物5mg/m 3可溶性化合物1mg/m 3681松节油 Turpentine100ppm 铀(天然的) Uranium,按U计0.2mg/m 3可溶性及不可溶性化合物683尿素 Urin1000ppm 0.05mg/m 3350ppm 657664670671680682684(正)戊醛 n-Valeraldehyde50ppm 五氧化二钒 Vanadium pentoxide 烟或尘,以V 2O 5计0.05mg/m 3烟或尘，以V计686植物油雾 Vegetable oil mists 10mg/m 3687蛭石粉尘(总尘) Vermiculite dust 688乙酸乙烯酯 Vinyl acetate 10ppm 689溴乙烯 Vinyl bromide 0.5ppm 690氯乙烯 Vinyl chloride1ppm 6914-乙烯基环己烯 4-Vinyl cyclohexene 0.1ppm 二氧化乙烯基环己烯Vinyl cyclohexene dioxide 693氟乙烯 Vinyl fluoride1ppm 694偏二氯乙烯 Vinylidene chloride 5ppm 695偏二氟乙烯 Vinylidene fluoride 500ppm 696乙烯基甲苯 Vinyl toluene 50ppm 697VM&P 石脑油 VM&P Naphtha 300ppm 698杀鼠灵 Warfarin0.1mg/m 3699电焊烟尘 Welding fumes(总尘)5mg/m 3700硅灰石粉尘(总尘) Wollastonite dust 木粉尘 Wood dust(总尘)1mg/m 3某些硬木如栎木和山毛榉软木5mg/m 3702二甲苯 Xylene(邻,间,对异构体)100ppm间二甲苯α,α,-二胺m-Xylene-α，α，-diamine704二甲代苯胺 Xylidine(异构体混合物)0.5ppm 705钇及其化合物，按Y计1mg/m 3706沸石粉尘(总尘) Zeolite dust 707氯化锌烟 Zinc chloride fume 1mg/m 3708铬酸锌盐类,按Cr计0.01mg/m 3氧化锌烟5mg/m 3尘10mg/m 3710锆及其化合物,以Zr计 Zirconium5mg/m 30.1ppm 692701703709685分子量STELTWA STEL 0.30.9C 25ppmC 4544.05 A315ppm1020601632102.09750ppm30045058.05 A4C 5mg/m 3C 385.160ppm102541.05 A4120.1526.02 窒息剂345.7512.5180.15C 0.1ppmC 0.356.06 A40.30.971.08 A361572.06 A41253.05 A3510146.14108.1364.93 A32358.08 A42ppm2476.50 A3114.14 A43ppm 148.1626.9834A446169.23 A1美国中国5触容许浓度；C (在数值前)-最高容许浓度；A1-确定人致癌物；癌物触限值(容许浓度)对照表中有害物质(包括毒物、粉尘和生物因素)的容许浓度和域限值2591.1184.08 A335ppm203017.0320ppm 102053.5431.00 A3615114.1310020037.593.12 A30.5 1.5123.15 A30.5 1.5123.15 A40.50.5121.75124.78171.50 A20.30.9202.27 A40.010.0274.92 A1C 0.0377.95 A10.8 1.50.8f/ml 1.5f/ml 512.5 A4216.06 A4317.34 A4510137.30 A41025233.43290.32 A4610228.30 A22.5ppm61078.11 A1184.23 A1252.30 A2252.30 A2C 0.1ppm195.50 A2C 0.5ppm140.57 A4512.5242.22 A4150.18 A4C 5126.58 A30.01mg/m 30.00050.0019.01 A11.5 3.75154.2C 0.005160.260.20.10.15ppm C 6*107 孢子数/m 3800.83 A4512.5201.2769.64C 1ppm250.57C 1ppm C 367.82261.11 A3 0.2ppm0.62159.81174.92252.80 A3512.554.09 A258.12C 50ppm10020074.1210020074.1210020074.12 A4118.17200ppm200300116.16200300116.16200300116.162550128.17 A4510C 5ppm C 1573.14220.34 A4 C 0.1mg/m3230.2210020060120130.21146.192590.193060150.22148.180.010.02112.40 A2100.09156.09 A21380.11 A474.12556.08A4136.144ppm152.23 A4512.5113.16 A43mg/m 310ppm 349.06 A4300.60 A3201.20 A4221.30 A4A44830000ppm90001800044.0151076.143628.012030C 20C 150.3ppm1.54331.6510ppm1525153.84 A25ppm51066.01110.11 A3102525149.92409.80 A31mg/m 3414.00 A33771ppmC 170.91 A40.3ppm0.30.867.46C 0.1ppmC 0.4292.46C 1ppmC 378.5C 1ppmC 492.530.30.9154.59 A40.15ppm0.20.6112.9550100112.56 A3129.393500525086.47 A4266.50.5 1.5328.40 A32040119.38 A3114.96 A1C 0.0050.5 1.580.50 A2123.54188.61 A4C 0.4C 0.05ppm50007500154.47C 1164.39 A441088.54108.5375ppm250400138.6C 1126.59 A40.050.15 A1 A1154.92228.30 A3192.06 A4 A4 A4462.5 3.50.050.158.93 A3341.94171.980.10.31.530.5163.550.20.61 2.51 2.5131025108.14C 0.3ppmC 1270.09 A3291.71 A4120.192542.04C 152.04C 0.3ppm 61.4825037584.16100200100.160.60.25010094.18 A482.14102099.17 A41.5 3.75222.26 A466.170.13385.16 A4221.04 A40.20.6354.50 A30.15ppm0.250.75122.31601200.030.090.050.15258.3412240360116.16304.36 A40.350.742.04 A20.10.327.69410173.293.58.75286.262ppm210.212.5 6.25278.340.10.2C 0.1ppmC 0.494.93 A350ppm50100147.0 A43060147.01 A3253.13 A3124.99 A25000750098.97 A498.97 A471510ppm 143.02 A4102.9220030084.93 A31224143.96350500512.5410110.98 A4142.97 A4170.93 A4220.98 A4237.21 A4197.0396.9512008000.4mg/m 3。