Appearance-Mimicking Surfaces

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bml050

bml050

bml050BML050: An Introduction to a Versatile and Cutting-Edge TechnologyIntroductionIn the world of technology, advancements are taking place at an unprecedented pace. New innovations are constantly emerging, reshaping industries and revolutionizing the way we live and work. One such promising technology is BML050, a versatile and cutting-edge system that has the potential to significantly impact various sectors. In this document, we will explore the features, applications, and potential benefits of BML050.1. What is BML050?BML050 stands for Bio-inspired Micropattern-Light-Emitting Diode 050. It is a technology that combines principles from biology and materials science to produce highly efficient and dynamic light-emitting devices. By mimicking natural light-emitting structures found in nature, BML050 offers a unique and innovative approach to lighting solutions.2. How does BML050 work?At the heart of the BML050 technology lies its ability to mimic the intricate design of biological structures, such as butterfly wings and peacock feathers. These structures possess nanoscale patterns that produce vibrant colors through the phenomenon of light interference.BML050 utilizes similar principles to create artificial structures called micro-patterned light-emitting diodes (MPLEDs). These MPLEDs employ micro-patterned surfaces with precisely controlled dimensions to manipulate light and produce desired colors. By carefully designing the size, shape, and spacing of these patterns, BML050 can achieve a wide range of vibrant colors with high efficiency.3. Applications of BML050The versatility of BML050 opens up numerous possibilities for its applications across different industries. Some key areas where BML050 can make a significant impact are:a) Lighting Industry: BML050 can revolutionize the lighting industry by providing highly energy-efficient and customizable lighting solutions. The ability to produce vibrant and dynamic colors can enhance the ambiance in homes, offices, and public spaces. Additionally, due to its low power consumption and long lifespan, BML050 can contribute to reducing energy consumption and maintenance costs.b) Display Technology: The use of BML050 in display technology can lead to the development of vivid and high-resolution screens. The incorporation of micro-patterned surfaces can improve color accuracy and brightness, delivering an immersive visual experience for users.c) Biomedical Applications: BML050's bio-inspired design makes it suitable for various biomedical applications. It can be utilized in optical sensors for medical diagnostics, where accurate color detection is required. Furthermore, BML050's compatibility with biological systems makes it a potential candidate for targeted drug delivery and tissue engineering.d) Automotive Industry: BML050 can find applications in the automotive industry by enhancing vehicle lighting systems. The ability to produce vibrant and customizable colors can lead to improved visibility, increased road safety, andattractive lighting designs for both interior and exterior lighting.4. Benefits of BML050The adoption of BML050 offers several advantages compared to traditional lighting and display technologies:a) Energy Efficiency: BML050 consumes significantly less power compared to conventional lighting solutions, providing energy savings and contributing to a greener and more sustainable future.b) Customizability: BML050 allows for the customization of colors, enabling users to create personalized lighting experiences for various environments.c) Long Lifespan: The robust design of BML050 results in a longer lifespan, reducing the need for frequent replacements and maintenance.d) Cost-Effectiveness: Although the initial investment in implementing BML050 technology may be higher, the long-term cost savings related to energy consumption and maintenance can outweigh the initial costs.ConclusionBML050 represents a promising technological advancement that combines biology and materials science to produce efficient and dynamic lighting solutions. Its ability to mimic natural light-emitting structures and produce a wide range of vibrant colors opens up numerous possibilities for applications in various industries. With its energy efficiency, customizability, and long lifespan, BML050 has the potential to revolutionize the way we illuminate and interact with the world around us. As further research and development continue, BML050 is poised to shape the future of lighting, display technology, and beyond.。

昆虫的启示发明10个简单英语作文

昆虫的启示发明10个简单英语作文

昆虫的启示发明10个简单英语作文Inspirations from Insects.Insects, small creatures often overlooked by many, have a remarkable ability to adapt, survive, and thrive in various environments. Their survival strategies, unique anatomies, and remarkable behaviors have served as a source of inspiration for numerous inventions and technologies. Here are ten examples of how insects have inspired human inventions:1. Antennae-inspired Sensors: Antennae, the thin,feeler-like appendages on insects' heads, are highly sensitive to changes in their environment. This has led to the development of antennae-inspired sensors that are used in robots, aircraft, and even medical devices to detect and respond to changes in their surroundings.2. Adhesive Technology: Gecko lizards, known for their ability to climb vertical surfaces, owe their adhesion tothe microscopic hairs on their feet. These hairs, known as setae, have inspired the development of synthetic adhesives that can be used in a wide range of applications, from surgical tape to sticky notes.3. Compound Eyes for Imaging: Insects possess compound eyes, made up of thousands of individual lens units, that provide them with a wide field of view and excellent depth perception. This has led to the development of compound eye cameras, which are used in surveillance, robotics, and other fields to capture a wide range of visual information.4. Biomechanical Designs: Insect skeletons, made of lightweight but strong materials like chitin, have inspired the design of lightweight, strong, and durable materialsfor use in aircraft, automobiles, and other applications.5. Honeycomb Structures: The hexagonal honeycomb structures found in bee nests provide maximum strength with minimal material usage. This efficient structure has been adapted in human design, from aircraft wings to sandwich panels, for optimal strength and weight.6. Insect-inspired Robotics: The agile movement and precise maneuvering of insects have inspired the design of small, insect-like robots that can navigate complex environments, such as narrow spaces or dense foliage. These robots are used in search and rescue operations, environmental monitoring, and other tasks.7. Biological Control: The use of natural enemies, such as predatory insects or parasites, to control pests is an example of biological control. This eco-friendly approach has been widely adopted in agriculture to reduce the need for chemical pesticides.8. Insect-mimicking Camouflage: The ability of insects to blend into their surroundings through coloration and patterning has led to the development of insect-mimicking camouflage materials. These materials are used in military applications, hunting gear, and even fashion to conceal or disguise objects and individuals.9. Vibration Communication: Some insects use vibrationsto communicate with each other, a phenomenon that has been adapted in human technology. For example, vibration sensors and transducers are used in cell phones and other devices to provide silent alerts or feedback.10. Biological Inspiration for Algorithms: The complex behaviors exhibited by insects, such as swarm intelligence or pathfinding, have provided inspiration for the development of algorithms used in computer science and artificial intelligence. These algorithms are used in areas like routing, optimization, and machine learning.Insects, with their remarkable adaptability andsurvival strategies, continue to serve as a source of inspiration for human inventions and technologies. As we continue to study and learn from these tiny creatures, we may unlock even more innovative applications and solutions to challenges we face in the future.。

以大自然为启发的发明英语作文

以大自然为启发的发明英语作文

以大自然为启发的发明英语作文Nature has always been a source of inspiration for inventors and innovators. From the design of airplanes to the development of Velcro, many inventions have been directly inspired by the natural world. The study of nature has led to the creation of new materials, technologies, and designs that have improved our lives in countless ways.One example of nature-inspired innovation is the invention of the airplane. The Wright brothers, who are credited with building and flying the first successful airplane, studied the flight of birds to understand the principles of aerodynamics. By observing how birds usetheir wings to generate lift and maneuver through the air, the Wright brothers were able to design a flying machine that could achieve controlled, powered flight. This breakthrough in aviation has had a profound impact on transportation, commerce, and communication around the world.Another example of nature-inspired innovation is the development of Velcro. Swiss engineer George de Mestral was inspired to create Velcro after observing how burrs stuckto his dog's fur during a walk in the woods. He studied the tiny hooks on the burrs and how they attached to the loopsin the fabric of his clothes, and used this observation to develop the hook-and-loop fastening system known as Velcro. This invention has been widely used in a variety of applications, from clothing and shoes to aerospace and medical devices.In recent years, biomimicry has emerged as a field of study that seeks to apply nature's principles to solve human challenges. By studying the structures, functions,and processes of living organisms, researchers anddesigners are finding new ways to create sustainable and efficient solutions. For example, the lotus leaf's abilityto repel water has inspired the development of self-cleaning surfaces, and the structure of spider silk has inspired the design of stronger and lighter materials.Overall, nature has served as a rich source ofinspiration for inventors and innovators throughout history. By studying and mimicking the patterns, systems, anddesigns found in the natural world, humans have been ableto create new technologies and materials that have improvedour lives and the environment. As we continue to face challenges in the future, it is likely that nature will continue to provide valuable insights and inspiration for innovation.大自然一直是发明家和创新者的灵感之源。

仿生学案例英语作文模板

仿生学案例英语作文模板

仿生学案例英语作文模板Title: Biomimicry Case Study in English。

Introduction。

Biomimicry is the practice of studying and imitating nature's designs and processes to solve human problems. It involves observing and understanding how nature has already solved many of the challenges we face, and then applying those lessons to our own designs and innovations. In this article, we will explore a few case studies of biomimicry in action, showcasing how this approach has led to innovative and sustainable solutions.Case Study 1: Velcro。

One of the most well-known examples of biomimicry is the invention of Velcro. Swiss engineer George de Mestral was inspired by the way burdock seeds stuck to his dog's fur during a walk in the woods. Upon closer examination, he discovered that the seeds had tiny hooks that allowed them to cling to the dog's fur. This observation led to the development of Velcro, a fastening system that mimics the natural mechanism of burdock seeds. Today, Velcro is used in a wide range of applications, from clothing and shoes to aerospace and medical devices.Case Study 2: Self-cleaning Surfaces。

形容糖果的英语单词

形容糖果的英语单词

形容糖果的英语单词Describing candies in English can be an exciting task, as candies themselves are vibrant, diverse, and often evoke strong emotions and memories. From their vibrant colors to their sweet, sour, bitter, or umami tastes, candies are a treat for all senses. Here are some detailed English words and phrases to describe various aspects of candies:1. Flavor:Sweet: The most common flavor associated with candies, described as "sweet" or "sugary".Sour: A sharp, tangy taste described as "tart" or "acidic".Bitter: A less common flavor in candies, described as "bitter" or "astringent".Savory: A more adult-oriented flavor, oftendescribed as "savory" or "umami".Fruity: Flavors mimicking specific fruits, such as "apple," "cherry," "strawberry," etc.Chocolate: A popular flavor described as "rich," "creamy," or "chocolatey".Mint: A cooling flavor described as "minty" or "fresh".2. Texture:Chewy: A texture that is elastic and requires some chewing effort, described as "chewy" or "gummy".Crunchy: A hard and brittle texture described as "crunchy" or "crispy".Soft: A tender and smooth texture described as "soft" or "mellow".Melty: A texture that melts easily in the mouth, often described as "melt-in-your-mouth" or "silky".3. Appearance:Vibrant: Colors that are bright and lively, described as "vibrant" or "vivid".Shiny: A reflective surface described as "shiny" or "glossy".Opaque: A dull, non-transparent color described as "opaque" or "matte".Multi-colored: A candy with multiple colors, often described as "rainbow" or "multicolored".4. Shape:Round: A shape that is circular or spherical, described as "round" or "spherical".Bar: A flat, rectangular shape described as "bar" or "slab".Heart: A shape resembling a heart, often given as a romantic gift.Animal: A shape模仿动物, such as a bear, dog, or cat, described as "animal-shaped" or "character-shaped".5. Ingredients:Sugar: The main component of most candies, described as "sugar-based" or "sweetened".Chocolate: A popular ingredient, often described as "chocolate-covered" or "chocolate-filled".Fruit: Natural fruit flavors or actual fruit pieces added for flavor and texture.Nuts: Additions like almonds, peanuts, or walnutsfor a crunchy texture and nutty flavor.6. Sentiment:Nostalgic: A candy that evokes memories or associations with the past, often described as "nostalgic" or "retro".Fun: A candy that is enjoyable and playful, often targeted towards children.Luxurious: A high-end candy, often with premium ingredients and packaging, described as "luxurious" or "premium".Describing candies in English is not just about their physical attributes but also about the emotional and cultural connections they evoke. From their sweet taste to their colorful packaging, candies are a multi-faceted treat that can be enjoyed by all ages.。

怎样防止病毒侵袭英语作文

怎样防止病毒侵袭英语作文

怎样防止病毒侵袭英语作文编写一篇关于“如何防止病毒侵袭”的英语作文确实是一个既实用又紧贴时代主题的任务。

这篇文章将结合科学防护、社会行为及个人卫生三个方面,全面阐述如何防止病毒的侵袭,具体内容如下:---。

Title: How to Prevent Viral Infections: A Comprehensive Guide。

In recent years, the world has been significantly impacted by outbreaks of various viruses, highlighting the critical need for effective strategies to prevent viral infections. This essay delves into the various methods by which individuals, communities, and healthcare systems can guard against viral threats, combining scientific approaches, social strategies, and personal hygiene practices.### 1. Understanding Viruses and Their Transmission。

Viruses are microscopic pathogens that require living cells to replicate. They can be transmitted through direct contact, respiratory droplets, and sometimes, contaminated surfaces. Understanding the modes of transmission is the first step in preventing infections. For example, respiratory viruses like influenza and SARS-CoV-2 primarily spread through droplets when an infected person coughs or sneezes.### 2. Vaccination: The First Line of Defense。

金枪鱼手工粘土英语作文

金枪鱼手工粘土英语作文

金枪鱼手工粘土英语作文Tuna A Clay Sculpture Masterpiece.The allure of the ocean's depths has long captivated artists, inspiring them to capture its enigmatic beauty through various mediums. Among these, clay stands out as a versatile and expressive material, allowing skilled hands to mold and shape its pliable form into breathtaking representations of marine life. In this realm of clay sculpting, tuna, the swift and elusive predator of the open sea, emerges as a particularly captivating subject.Tuna, renowned for their sleek, torpedo-shaped bodies and incredible speed, pose a formidable challenge to clay artists seeking to translate their dynamic form into a static medium. Yet, through meticulous observation and a deep understanding of the fish's anatomy, seasoned sculptors have mastered the art of capturing the essence of this magnificent creature in clay.The creation of a tuna sculpture begins with a thorough study of its physical characteristics. The artist carefully observes the fish's overall shape, the subtle curves of its body, and the intricate details of its fins and tail. This in-depth analysis provides the foundation for thesculpture's form and proportions.With a clear understanding of the tuna's anatomy, the artist begins to mold and shape the clay. The process often starts with the creation of a basic armature, a wire or metal framework that provides support and stability to the clay sculpture. This armature ensures that the final piece will retain its shape and withstand the forces of gravity.The artist then carefully applies layers of clay to the armature, gradually building up the volume and defining the contours of the tuna's body. The clay must be pliable enough to allow for intricate sculpting, yet firm enough to hold its shape. Through a combination of carving, sculpting tools, and deft fingerwork, the artist meticulously crafts the details of the tuna's fins, tail, and scales.The creation of a realistic tuna sculpture requires a keen eye for detail and an ability to capture the subtle nuances of the fish's appearance. The artist must pay close attention to the texture and sheen of the tuna's skin, as well as the coloration and markings that vary depending on the species.When the sculpture has taken shape, the artist may choose to apply paint or other surface treatments to enhance the realism and depth of the piece. Acrylics, oils, or even metallic paints can be used to create a lifelike appearance, mimicking the iridescent scales and vibrant hues of the living tuna.The final product is a stunning tribute to the beauty and majesty of this marine predator. Whether displayed as a standalone piece or incorporated into a larger marine-themed installation, a tuna clay sculpture captures the imagination and transports viewers to the depths of the ocean.In the hands of a skilled artist, clay becomes atransformative medium, capable of capturing the grace, power, and enigmatic nature of the tuna. These sculptures serve not only as beautiful works of art but also as testaments to the boundless possibilities of artistic expression through clay.。

石墨烯动态调控太赫兹表面等离激元

石墨烯动态调控太赫兹表面等离激元

第 21 卷 第 8 期2023 年 8 月Vol.21,No.8Aug.,2023太赫兹科学与电子信息学报Journal of Terahertz Science and Electronic Information Technology石墨烯动态调控太赫兹表面等离激元张葆青,冯明明,张翼飞*,宋爱民(山东大学微电子学院,山东济南250100)摘要:太赫兹表面等离激元(SPPs)是利用亚波长周期性结构在太赫兹频段模拟的具有与可见光频段表面等离激元相似的光学特性的电磁波,分为传输型和局域型2种。

本文将石墨烯引入太赫兹表面等离激元结构作为动态激励源,通过外加偏压改变石墨烯的电导率,分别实现了对传输型表面等离激元的幅度、频率、相位和对局域表面等离激元共振强度的动态调控。

本文方法为表面等离激元的动态调控提供了新的思路,拓宽了表面等离激元在太赫兹频段的应用。

关键词:表面等离激元;太赫兹;石墨烯;动态调控中图分类号:TN29;O441.4文献标志码:A doi:10.11805/TKYDA2022163Active modulation of terahertz Surface Plasmons Polaritons with grapheneZHANG Baoqing,FENG Mingming,ZHANG Yifei*,SONG Aimin(School of Microelectronics,Shandong University,Jinan Shandong 250100,China)AbstractAbstract::Terahertz(THz) Surface Plasmons Polaritons(SPPs) can mimic optical Surface Plasmons (SPs) and obtain similar optical properties with periodic sub-wavelength structures, which typicallyconsist of propagating SPPs and Localized Surface Plasmons(LSPs). In this work, graphene is utilized asthe active stimuli to dynamically control the amplitude, frequency, and phase of SPPs and reconfigure theresonant modes of LSPs at various bias voltages. Such design provides new solutions for active control ofSPPs and LSPs at THz frequencies.KeywordsKeywords::Surface Plasmons Polaritons;terahertz;graphene;active modulation表面等离激元(SPPs)是金属和介质交界面上的自由电荷集体振荡形成的一种电磁表面波,具有局域电场增强和突破光学衍射极限的特点,在生物传感、超分辨力成像、高效光伏等领域应用广泛[1]。

来自大自然的发明作文英语80词

来自大自然的发明作文英语80词

来自大自然的发明作文英语80词The inventions from nature are truly remarkable, offering unique solutions to complex problems that humans face every day. 大自然中的发明确实非常神奇,为人类每天面临的复杂问题提供了独特的解决方案。

For example, the lotus leaf has inspired the creation of self-cleaning surfaces, as its micro-structures repel water and prevent dirt from sticking. 例如,荷叶启发了自清洁表面的发明,因为其微观结构可以排斥水并防止污垢粘附。

Additionally, the amazing properties of spider silk have influencedthe development of biodegradable materials that are lightweight, strong, and flexible. 此外,蜘蛛丝的惊人特性影响了生物降解材料的发展,这些材料既轻量又坚固,同时具有灵活性。

Nature's designs also serve as inspiration for engineering innovations, such as the aerodynamics of bird wings leading to the development of more efficient aircraft designs. 大自然的设计也成为工程创新的灵感来源,例如鸟翼的空气动力学特性促进了更高效飞行器设计的发展。

Moreover, biomimicry, the practice of emulating nature's designsand processes, has led to the creation of sustainable technologies and products that minimize environmental impact. 此外,仿生学,即模仿大自然的设计和过程,已经导致了创造出最大限度减少环境影响的可持续技术和产品。

儿茶酚及其衍生物的性质及应用

儿茶酚及其衍生物的性质及应用

儿茶酚及其衍生物的性质及应用刘蓉瑾【摘要】儿茶酚类化合物普遍存在于自然界,具有多功能性,可参与大多数生化进程.它具有较强的氧化还原性,pH响应性和显著的螯合性;而且儿茶酚中的邻位羟基可通过多种方式与不同材料相互作用,特别是与三价铁离子具有很强的螯合作用.由于儿茶酚类化合物性质的多样性,其可以存在于单分子体系、超分子体系、金属离子络合体系或通过共价键相连的聚合物.儿茶酚的多功能性使其参与多种自然过程,其作用表现在众多方面,从海洋生物的粘附性到对过渡金属的储存均得力于儿茶酚类化合物.由于儿茶酚性质的多样性,引起研究者们的广泛兴趣,近年来对其研究日益增多,旨在制备新型的功能性材料和涂层.%Catechols are found in nature taking part in a remarkably broad scope of biochemical processes and functions. They can establish reversible equilibria at moderate redox potentials and pHs and irreversibly cross-link through complex oxidation mechanisms. Their chelating properties can be greatly exemplified with the binding of Fe3+and the diverse modes of interaction of the vicinal hydroxyl groups with all kinds of surfaces of remarkably different chemical and physical nature. Thanks to this diversity, catechols are found to be present in simple molecular systems, with supramolacular struc-tures, metal ion complexing systems or polymers with covalent bonds. The versatilities, allowed cate-chols to participate in several natural processes and functions that range from the adhesive properties of marine organisms to store some transition metal ions. Therefore, catechol-based systems have in recent years beensubjected to intense research, and aimed at mimicking these natural systems in order to de-velop new functional materials and coatings.【期刊名称】《化学研究》【年(卷),期】2017(028)003【总页数】4页(P391-394)【关键词】儿茶酚基聚合物;3,4-二羟基苯丙氨酸;降解性;配位作用;氧化还原性【作者】刘蓉瑾【作者单位】煤科集团沈阳研究院有限公司,辽宁沈阳110000【正文语种】中文【中图分类】O631.3儿茶酚是一类带有邻羟基的酚类衍生物,在自然界中无处不在. 儿茶酚及其衍生物可作为活性生物质存在于多种环境中,呈现出显著的化学多样性. 设计合成儿茶酚基聚合物可应用于生物医药、分析化学、纳米技术和材料科学等领域,由于其独特的化学性质,为科学研究提供了更多的途径. 儿茶酚环的结构使其具有多功能性. 一方面,儿茶酚可作为一种弱酸具有反应活性,同时,也可作为一种氧化还原剂. 另一方面,邻位二羟基的存在使其可形成配位结构和氢键.根据儿茶酚的功能性,可概括地分为以下几类:1) 通过非共价键与多种基材表面键合,或与其他功能性基团形成共价键;2) 通过聚合或自组装作用形成2D或3D结构;3) 复合体系中,儿茶酚可作为连接位点,起到分子间的连接作用;4) 在特定条件下,含儿茶酚基的分子对外界刺激的响应具有可逆性.虽然其性质良好,但也存在缺点. 尽管从表面上看其反应条件简单、温和,但实际含儿茶酚基的化学反应具有挑战性,其化合物在反应前通常需要经过十分细致的处理.1.1 粘附性粘附性是儿茶酚及其衍生物一个非常重要的性质,其几乎可与任何化学性质的基材表面形成很强的粘附力,即使在玻璃、聚四氟乙烯等表面张力很小的材料表面也能形成较强的附着力. 儿茶酚与基材的作用形式可分为共价键和非共价键. 一些含有胺基或硫醇基团的特殊基材可通过迈克尔加成或席夫碱反应与儿茶酚基聚合物形成共价键. 另一方面,儿茶酚基聚合物还可通过与金属离子配位或螯合、氢键、π-π堆叠等非共价键[1-4]和基材相互作用. 通过对儿茶酚基的含量、附着性质和氧化条件对儿茶酚基聚合物粘附性的影响研究,发现粘附性大致随儿茶酚基的含量增加而成比例增加[5-6]. 与其他涂层材料比,牢固的粘附在有机或疏水材料表面是儿茶酚基聚合物最显著的优势.1.2 金属离子螯合性和氧化还原活性金属离子可与儿茶酚基衍生物中的醌、羧基、胺基和苯酚等多种官能团键合,而且在不同的pH下,金属离子可与不同的官能团键合形成多种络合物. FRONCISZ等报导可通过电子自旋共振光谱(ESR)检测Cu2+与儿茶酚基聚合物的螯合形式[7],结果表明:1) pH<5时,Cu2+与羧基作用形成络合物;2) pH≈7时,Cu2+与酚羟基络合;3) 若pH进一步增加,Cu2+则与3个或4个N原子发生络合.除与金属离子螯合之外,儿茶酚基衍生物还可还原一些惰性金属离子,如Au3+,Ag+,Pt3+等,其氧化还原活性较强,还原条件温和,可作为一种还原剂. 在一定条件下,儿茶酚基先氧化成醌,再触发金属阳离子的还原. 通过X射线衍射图可以看出,在还原过程中,醌的峰强增加,而儿茶酚基的峰强减弱.1.3 化学反应活性儿茶酚类衍生物中含有多个官能团,如氨基、酚羟基、羧基等,可与较多的功能性分子发生化学反应. 聚合物中的儿茶酚基氧化成醌后,可与胺基作用发生席夫碱反应. 当含巯基的分子存在时,则会与儿茶酚基聚合物发生迈克尔加成反应. 而且,儿茶酚基与亲核试剂在水溶液中发生偶合,可保持良好的稳定性,解决了N-羟基琥珀酰亚胺和顺丁烯二酰亚胺与含胺基或巯基的分子偶联时由于水解作用而导致偶联效率降低的问题.1.4 生物相容性和生物降解性生物相容性是判断一种材料是否适合应用于生物医药领域的重要因素. KU等证明儿茶酚基聚合物不会妨碍哺乳动物细胞的生长和繁殖[8]. 同时,许多研究表明含儿茶酚基的涂层可提高细胞在基材上的附着力,并促进其繁殖. 静脉注射儿茶酚基聚合物30 d后,监测实验动物的各项生理指标,结果表明在饮食、运动、消化和神经系统等多方面均未出现异常情况,而且其体重与对照组相比也有所增加. 生物降解性是生物医药领域材料的另一重要性质,外来物质在体内的长期留存必然会引起严重的不良反应. LANGER等对儿茶酚基聚合物的体内降解进行了研究,结果表明8 w后其在体内可完全降解[9]. 除此之外,微生物的存在也可使儿茶酚聚合物降解[10].2.1 生物医药方面的应用由于儿茶酚类衍生物良好的粘附性、生物相容性、生物降解性和化学反应活性,使其可用于制备聚合物膜、水凝胶、功能性支架等多种材料,广泛应用于生物医药领域.2.1.1 细胞的粘附、封装和排列在生物材料的应用中,细胞的保护和固定是非常重要的,同时实现过程也是非常复杂的. 近年来,大量文献报导,利用儿茶酚基聚合物良好的生物相容性,将细胞等生物性物质成功地固定在玻璃、聚苯乙烯、聚二甲基硅氧烷等多种基材上. YANG等在酵母细胞外涂覆一层聚多巴胺,形成壳将其封装在内部,成功实现了细胞在基材上的固定,并且控制了细胞的分裂,防止了细胞受到外界环境的影响[11]. 儿茶酚基聚合物的特殊性质使其可通过光刻法、微流控技术和微触印刷法实现细胞的有效排列,可克服体系成本高、基材受限、操作复杂、稳定性低等缺点.2.1.2 抗菌性应用细菌感染在医药、工业、食品安全等领域产生重要影响,严重威胁人类健康,甚至导致死亡. 抗菌材料的使用是防止细菌感染的有效手段,目前,已报道的抗菌材料主要有金属纳米粒子和半导体材料,虽然其具有较高的抗菌活性,但若实现应用于不同基材的表面仍然是一个挑战. 儿茶酚基聚合物对金属离子的还原性和其在多种基材表面的粘附性,使原位法制备抗菌材料成为可能. MESSERSMITH课题组在聚碳酸酯上涂覆一层儿茶酚基聚合物,并使银纳米粒子和接枝防腐蚀剂的PEG沉积在其表面,制得的复合材料不仅可以起到杀菌作用,而且能够有效防止细菌的附着[12]. MAO等用聚多巴胺修饰棉纤维,并用原位法将银离子还原成银纳米粒子,制备了抗菌性棉纤维[13].2.1.3 药物释放儿茶酚基聚合物囊泡由于良好的水溶性、生物相容性和生物降解性,可作为药物释放材料,而且其空腔和表面均可负载大量药物分子. 疏水抗癌药物可通过乳液模板法预压到囊泡中,模板除去后药物仍可完好地保存,并可通过调节聚合物囊泡的带电状态选择性负载药物,药物负载量与溶液的pH和负载分子的带电性相关.2.2 传感器方面的应用电化学生物传感器由于具有操作简单、敏感性高、选择性好和线性范围宽等优点,迅速发展. 基于多巴和多巴胺等儿茶酚基化合物的粘附性和生物相容性,可为生物分子的高密度固定提供合适的微环境,并可长期保持其生物活性. 因此,众多研究致力于制备高效的儿茶酚基生物传感器.2.2.1 有机分子检测ZHANG等通过电聚合使多巴胺在固定了辣根过氧化酶(HRP)的双层脂质膜上形成聚合物膜,制备了一种可再生传感器,用于快速检测痕量H2O2[14]. 利用儿茶酚基衍生物的氧化还原性和与金属离子的配位作用,可制备金纳米粒子/导电聚合物复合材料检测抗坏血酸,该传感器具有高敏感性、较宽的线性检测范围、长期稳定性和良好的抗干扰能力. 根据这一方法还可制备铂纳米粒子复合材料用于检测尿酸[15]. 在电泳的协助下,这种传感体系可用于同时检测小鼠体内的多巴胺、肾上腺素、去甲肾上腺素和血清素.2.2.2 生物分子检测近年来,许多文献报导儿茶酚基电化学传感器用于生物分子检测,其中一个很重要的方面就是对糖类的检测. GAO等用聚多巴胺修饰的碳纳米管制备了葡萄糖电化学生物传感器[16]. 聚多巴胺涂层不仅可以保护碳纳米管的电子结构,提高其稳定性,还可促进葡萄糖氧化酶与电极之间的电子转移. FU等首次直接使用儿茶酚基聚合物构建了聚合物-酶-金属纳米粒子复合传感体系[17]. 与其他传感器相比,酶被直接封装在聚合物内,避免了与外界的直接接触,提高了传感器的稳定性. 这种传感器可达到微摩尔级检测极限,可有效抗尿酸、抗坏血酸、扑热息痛和谷胱甘肽的干扰,在葡萄糖和半乳糖检测中具有较高的稳定性. 除了使用酶之外,基于葡萄糖与硼酸衍生物、凝集素等物质间的生物相互作用也可实现选择性检测.2.2.3 重金属离子检测WANG等基于胸腺嘧啶-Hg2+-胸腺嘧啶的配位化学作用,用聚多巴胺制备了检测Hg2+的电化学生物传感器[18]. 基于聚多巴胺对金属离子的吸附作用,ZHOU 等用聚多巴胺和Fe3O4制备了具有核壳结构的纳米粒子,用于检测Pb(II)和Ca(II)[19]. 实验证明聚多巴胺涂层可有效吸附铅离子和钙离子,而且可将金属离子还原成金属沉积在电极的表面,导致明显的电流变化,这种方法显示出更高的敏感性、更好的抗干扰能力、低成本和较好的稳定性.2.3 水处理方面的应用由于重金属、合成染料和芳香族化合物等工业污染物严重威胁自然环境和人类健康,对工业废水的净化要求与日俱增,获得一种高效的水净化方法是研究者们努力的方向. 工业中,化学沉淀、吸附、光催化降解和膜过滤等方式均可用于污染物的脱除. 在这些方法中,吸附由于其具有低成本、易操作和无副产物等优点被认为是最有效的方式而广泛应用. 吸附剂需要与污染物存在多个结合位点才能获得较高的吸附率. 儿茶酚基聚合物中存在儿茶酚基、胺基、羧基和苯环等大量官能团,作为吸附剂可提供大量的活性结合位点,通过静电作用、螯合作用、氢键或π-π堆积作用吸附重金属离子和有机污染物. 除活性位点外,表面积也是影响吸附效果的重要因素.将高表面积的石墨烯和多活性位点的儿茶酚基聚合物相结合,必然会获得较高的吸附效率[20].儿茶酚类衍生物可作为活性生物质存在于多种环境中,由于其具有粘附性、化学反应活性、金属离子螯合性、氧化还原活性、生物相容性和降解性等多种理化性质,使得其广泛的应用于功能材料的制备. 设计合成儿茶酚基聚合物可应用于生物医药、分析化学、纳米技术和材料科学等领域,显示了其独特的化学功能,也为科学研究提供了更多的途径. 由于儿茶酚基聚合物的独特性质,使其易于与其他材料相结合,以制备具有特殊功能的聚合物材料. 儿茶酚基聚合物的研究领域必将有一个光明的未来,经过长期的研究,儿茶酚基聚合物将为克服长期以来科学实践中的挑战提供新的途径.【相关文献】[1] SAIZ-POSEU J, FARAUDO J, FIGUERAS A, et al. Switchable self-assembly of a bioinspired alkyl catechol at a solid/liquid interface: Competitive interfacial, noncovalent,and solvent interactions [J]. Chemistry-A European Journal, 2012, 18(10): 3056-3063. [2] WANG L, WANG D, DONG Z, et al. Interface chemistry engineering for stable cycling of reduced GO/SnO2 nanocomposites for lithium ion battery [J]. Nano Letters, 2013, 13(4): 1711-1716.[3] KROGSGAARD M, BEHRENS M A, PEDERSEN J S, et al. Self-healing mussel-inspired multi-pH-responsive hydrogels [J]. Biomacromolecules, 2013, 14(2): 297-301.[4] SED J, SAIZ-POSEU J, BUSQU F, et al. Catechol-based biomimetic functional materials [J]. Advanced Materials, 2013, 25(5): 653-701.[5] LEE B P, CHAO C Y, NUNALEE F N, et al. Rapid gel formation and adhesion in photocurable and biodegradable block copolymers with high DOPA content [J]. Macro-molecules, 2006, 39(5): 1740-1748.[6] GUVENDIREN M, BRASS D A, MESSERSMITH P B, et al. Adhesion of DOPA-functionalized model membranes to hard and soft surfaces [J]. The Journal of Adhesion, 2009, 85(9): 631-645.[7] FRONCISZ W, SARNA T, HYDE J S. Cu2+ probe of metal-ion binding sites in melanin using electron paramagnetic resonance spectroscopy: I. Synthetic melanins [J]. Archives of Biochemistry and Biophysics, 1980, 202(1): 289-303.[8] KU S H, RYU J, HONG S K, et al. General functionalization route for cell adhesion on non-wetting surfaces [J]. Biomaterials, 2010, 31(9): 2535-2541.[9] BETTINGER C J, BRUGGEMAN J P, MISRA A, et al. Biocompatibility of biodegradable semiconducting melanin films for nerve tissue engineering [J]. Biomaterials, 2009, 30(17): 3050-3057.[10] JIA X, MA Z, ZHANG G, et al. Polydopamine film coated controlled-release multielement compound fertilizer based on mussel-inspired chemistry [J]. Journal of Agricultural and Food Chemistry, 2013, 61(12): 2919-2924.[11] YANG S H, KANG S M, LEE K B, et al. Mussel-inspired encapsulation and functionalization of individual yeast cells [J]. Journal of the American Chemical Society, 2011, 133(9): 2795-2797.[12] SILEIKA T S, KIM H D, MANIAK P, et al. Antibacterial performance of polydopamine-modified polymer surfaces containing passive and active components [J]. ACS Applied Materials & Interfaces, 2011, 3(12): 4602-4610.[13] XU H, SHI X, MA H, et al. The preparation and antibacterial effects of dopa-cotton/AgNPs [J]. Applied Surface Science, 2011, 257(15): 6799-6803.[14] ZHENG L, XIONG L, ZHENG D, et al. Bilayer lipid membrane biosensor with enhanced stability for amperometric determination of hydrogen peroxide [J]. Talanta, 2011, 85(1): 43-48.[15] LIN M, HUANG H, LIU Y, et al. High loading of uniformly dispersed Pt nanoparticleson polydopamine coated carbon nanotubes and its application in simultaneous determination of dopamine and uric acid [J]. Nanotechnology, 2013, 24(6): 065501. [16] WANG Y, LIU L, LI M, et al. Multifunctional carbon nanotubes for direct electrochemistry of glucose oxidase and glucose bioassay [J]. Biosensors and Bioelectronics, 2011, 30(1): 107-111.[17] FU Y, LI P, XIE Q, et al. One-pot preparation of polymer-enzyme-metallic nanoparticle composite films for high-performance biosensing of glucose and galactose [J]. Advanced Functional Materials, 2009, 19(11): 1784-1791.[18] WANG G, HUANG H, ZHANG X, et al. Electrically contacted enzyme based on dual hairpin DNA structure and its application for amplified detection of Hg2+ [J]. Biosensors and Bioelectronics, 2012, 35(1): 108-114.[19] SONG Q, LI M, HUANG L, et al. Bifunctional polydopamine@Fe3O4 core-shell nanoparticles for electrochemical determination of lead (II) and cadmium (II) [J]. Analytica Chimica Acta, 2013, 787: 64-70.[20] GAO H, SUN Y, ZHOU J, et al. Mussel-inspired synthesis of polydopamine-functionalized graphene hydrogel as reusable adsorbents for water purification [J]. 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荷叶的英语作文

荷叶的英语作文

荷叶的英语作文Title: The Enchanting Elegance of Lotus Leaves。

Lotus leaves, with their graceful appearance andintricate design, hold a special place in nature's tapestry. These verdant jewels floating atop tranquil waterscaptivate hearts and minds alike. Delving into the essenceof lotus leaves unveils a world of wonder and admiration.Firstly, let us explore the botanical marvel of lotus leaves. Scientifically known as Nelumbo nucifera, these leaves possess unique characteristics that distinguish them from other aquatic foliage. Their round, flat shape allows them to repel water effortlessly, keeping their surfacesdry and clean. This remarkable feature is attributed to the microscopic wax crystals covering the leaf's surface, creating a natural water-repellent barrier known as the Lotus Effect. This adaptation not only preventswaterlogging but also inhibits the growth of algae andother microorganisms, ensuring the leaf's longevity.Furthermore, the structural composition of lotus leaves contributes to their strength and resilience. Despite their delicate appearance, these leaves exhibit remarkable durability, capable of withstanding the weight of droplets and even small insects without tearing or sinking. The intricate network of veins running through the leaf provides support while facilitating the efficient transport of nutrients and water—a testament to nature's exquisite engineering.Beyond their botanical significance, lotus leaves hold profound cultural and symbolic meanings across various societies. In many Eastern cultures, including China and India, the lotus flower and its leaves symbolize purity, enlightenment, and spiritual growth. The lotus, rooted in muddy waters, emerges pristine and unblemished—a metaphor for transcending worldly challenges and achieving inner peace. Artists and poets have long drawn inspiration from this symbolism, depicting lotus leaves in paintings, literature, and religious iconography as a symbol of divine grace and enlightenment.Moreover, lotus leaves serve practical purposes beyond their aesthetic and symbolic value. In traditional Chinese cuisine, lotus leaves are utilized as natural wrappers for steamed rice and savory fillings, imparting a subtle, earthy flavor to the dish. Additionally, the medicinal properties of lotus leaves have been recognized for centuries in traditional herbal medicine. Rich in antioxidants and phytochemicals, lotus leaves are believed to promote digestion, reduce inflammation, and support overall well-being.In contemporary times, the allure of lotus leaves extends beyond cultural and culinary realms into scientific and technological domains. Researchers and engineers have looked to nature's design for inspiration in developing innovative materials and structures. Mimicking the Lotus Effect, scientists have developed self-cleaning surfaces and waterproof coatings, offering practical solutions for various industries, from architecture to healthcare.In conclusion, lotus leaves exemplify nature'singenuity and beauty, embodying a harmonious blend of form and function. From their botanical resilience to their cultural symbolism, lotus leaves continue to inspire awe and admiration across the globe. As we marvel at their elegance, let us also reflect on the profound lessons they impart—of resilience, purity, and the boundless creativity of the natural world.。

pleural disease 胸膜疾病

pleural disease 胸膜疾病
Pleural disease (胸膜疾病)
Zhou Liu Cancer Hospital of Chinese Academy of Medical Sciences, Shenzhen Center
Pleural Disease
• Epidemiology(流行病学): 300/100,000 each year
Fig. 14 (A) A soft tissue mass in a MPD case. (B) A soft-tissue mass with circumferentially pleural involvement in a MPM case.
Malignant Pleural Thickening 恶性胸膜增厚
Fig. 8 Irregular pleural thickening with pleural rind appearance in a patient caused by pleural tuberculosis.
Empyema(脓胸)
C Fig.9 B. Increased subpleural fat tissue in a case with empyema C. CT showing empyema and “split pleura” sign(胸膜分离征)
Post-talc pleurodesis 滑石粉胸腔固定术后
“Sandwich”
Fig. 11 A: CT post-talc on left circumferential nodular pleural thickening involving the mediastinal surface with high density elements (white arrows). B: PET scan demonstrating activity post-talc pleurodesis (black arrow).

写昆虫的外形和特点的英语作文

写昆虫的外形和特点的英语作文

写昆虫的外形和特点的英语作文Insects: A Myriad of Intricate Designs and Adaptations.In the vast tapestry of life on Earth, insects occupy a prominent and diverse niche, boasting a staggering array of shapes, sizes, and remarkable adaptations. Their intricate exoskeletons, specialized appendages, and complex behaviors have evolved over millions of years, enabling them tothrive in a wide range of ecological habitats.Exoskeleton: A Protective and Versatile Framework.Insects possess an exoskeleton, an external shell composed primarily of a rigid material called chitin. This exoskeleton serves as a protective barrier against predators, environmental stressors, and physical injuries. It also provides support for the body and facilitates movement through muscle attachments.The exoskeleton is composed of several segments,including the head, thorax, and abdomen. The head typically houses the antennae, eyes, and mouthparts, while the thorax bears the wings and legs, and the abdomen contains the digestive, respiratory, and reproductive organs.Specialized Appendages: Tools for Survival.Insects exhibit an astounding array of appendages, each tailored to specific functions. Antennae, which varygreatly in shape and size, are used for communication, olfaction, and tactile sensing. They can detect odors, vibrations, and chemical signals, enabling insects to navigate their environment and locate food sources, mates, and potential threats.Legs, another essential appendage, are adapted for locomotion, such as walking, running, jumping, or swimming. Each leg consists of several segments, allowing for flexibility and adaptability. Some insects possess specialized claws or spines on their legs for grasping surfaces, digging burrows, or capturing prey.Wings, a defining characteristic of many insects, have evolved for aerial movement. These delicate structures are composed of thin, lightweight membranes supported by rigid veins. The shape and size of the wings vary widely, depending on the insect's flight capabilities. Some insects, such as butterflies and moths, have large, colorful wings that enable them to flutter gracefully, while others, such as flies and mosquitoes, have smaller wings that allow for rapid and agile flight.Mouthparts: Diversity for Specialized Diets.Insects exhibit a remarkable diversity of mouthparts, each adapted to their specific feeding habits. Chewing mouthparts, found in beetles, grasshoppers, andcaterpillars, are designed to crush and grind plant matter. Piercing-sucking mouthparts, characteristic of mosquitoes and aphids, are used to penetrate plant or animal tissues and extract fluids. Siphoning mouthparts, seen inbutterflies and moths, are adapted to suck nectar from flowers.The shape, size, and arrangement of mouthparts vary tremendously across insect species, allowing them toexploit a wide range of food sources. This diversityreflects the crucial role of insects as primary consumersin ecological food webs.Complex Behaviors: Sociality and Communication.Insects exhibit complex and often fascinating behaviors, including sociality, communication, and defense mechanisms. Many insects, such as ants, bees, and termites, live in highly organized colonies, with specialized castes performing specific tasks related to food gathering, reproduction, and defense.Communication among insects is essential forcoordination and survival. Some insects use chemical signals, known as pheromones, to attract mates, mark territories, or alert other members of the colony to danger. Others, such as bees and wasps, use dances and sounds to convey information about food sources and potential threats.Defense mechanisms are crucial for insects, given their small size and vulnerability to predators. Some insects employ camouflage, mimicking the appearance of leaves, sticks, or other objects. Others have evolved chemical defenses, secreting toxins or foul-smelling substances to deter predators.Conclusion.Insects, with their intricate exoskeletons, specialized appendages, and complex behaviors, represent a remarkable testament to the diversity and adaptability of life on Earth. Their ecological importance as primary consumers, pollinators, and detritivores is undeniable. From the smallest parasitic wasp to the largest dung beetle, insects play a vital role in maintaining the balance and resilience of ecosystems worldwide. Their study continues to provide scientists with invaluable insights into the wonders of the natural world.。

高性能光伏材料的合成

高性能光伏材料的合成

74DOI:10.1021/la902110j Langmuir 2010,26(1),74–82Published on Web 08/19//Langmuir ©2009American Chemical SocietySelf-Assembly of Poly (ethylene glycol )-Poly (alkyl phosphonate )Terpolymers on Titanium Oxide Surfaces:Synthesis,InterfaceCharacterization,Investigation of Nonfouling Properties,and Long-TermStabilityVincent Zoulalian,†,‡Stefan Z €urcher,†Samuele Tosatti,†Marcus Textor,†Sophie Monge,‡and Jean-Jacques Robin*,‡†Laboratory for Surface Science and Technology,Department of Materials,ETH Zurich,Wolfgang-Pauli-Strasse 10,CH-8093Zurich,Switzerland,and ‡Institut Charles Gerhardt Montpellier UMR5253CNRS-UM2-ENSCM-UM1,Equipe Ing enierie et Architectures Macromol e culaires,Universit e Montpellier II cc1702,Place Eug ene Bataillon,34095Montpellier Cedex 5,France Received June 12,2009.Revised Manuscript Received July 29,2009This contribution deals with the self-assembling of a terpolymer on titanium oxide (TiO 2)surface.The polymerstructure was obtained by polymerization of different methacrylates,i.e.,alkyl-phosphonated,butyl and PEG methacrylate,in the presence of a chain transfer agent.The resulting PEG -poly(alkyl phosphonate)material,characterized mainly by SEC and NMR,self-organized at the interface of TiO 2.AR-XPS demonstrated the binding of phosphonate groups to TiO 2substrate and the formation of a PEG -brush layer at the outermost part of the system.The stability of this terpolymer adlayer,after exposure to solutions of pH 2,7.4,and 9up to 3weeks,was evaluated quantitatively by XPS and ellipsometry.We demonstrated an overall stability improvements of this coating against desorption in contact with aqueous solutions in comparison with reference self-assembly systems.Finally,the PEG -terpolymer adlayer proved to impart to TiO 2substrate antifouling properties when exposed to full blood serum.IntroductionThe control of the physical and chemical properties of material surfaces is of prime importance when developing medical devices and biosensors.Indeed,when no specific surface treatment is applied on artificial materials,their direct exposure to biological fluids results generally in uncontrolled processes such as non-specific adsorption of proteins followed by the formation of a biofilm.1Important modification systems based on spontaneous molecular assembly include self-assembled monolayers (SAMs)of alkanethiols on gold and alkanephosph(on)ates on metal oxides,respectively,2-4adlayers made from molecules containing biomimetic anchorage chemistry (e.g.,dihydroxyphenylalanin (DOPA)derived from mussel adhesive proteins or cyanobacteria chelators),5,6and polyelectrolyte-grafted polymer interfaces.7,8They have been extensively investigated and fine-tuned to incor-porate specific chemical structures and/or functional groups 9with the aim of eliciting specific responses at surfaces of materials incontact with biological environment,6,10-12especially the elim-ination of nonspecific adsorption of proteins.8,13,14To prevent unspecific biomolecular adsorption (e.g.,of proteins)on artificial materials,a common method consists in immobilizing on their surfaces nonfouling or protein-resistant polymers,15-18such as poly(ethylene glycol)(PEG).19-22The latter is able to prevent the adhesion of proteins once immobilized as a dense brush on surfaces.12,13,23-25High degree of hydration (more than 80%in weight),steric repulsion by the polymer chains,and ability to screen interfacial charges were believed to be the main reasons to explain its successful nonfouling property.Among the possibilities to immobilize PEG -brush structures on*Corresponding author:Tel 33-4-67-14-41-57,Fax 33-4-67-14-40-28,e-mail Jean-Jacques.Robin@univ-montp2.fr.(1)Wahlgren,M.;Arnebrant,T.Trends Biotechnol.1991,9,201–208.(2)Ulman,A.Chem.Rev.1996,96,1533–1554.(3)Spori,D.M.;Venkataraman,N.V.;Tosatti,S.G.P.;Durmaz,F.;Spencer,N.D.;Zurcher,ngmuir 2007,23,8053–8060.(4)Tosatti,S.;Michel,R.;Textor,M.;Spencer,ngmuir 2002,18,3537–3548.(5)Lee,H.;Dellatore,S.M.;Miller,W.M.;Messersmith,P.B.Science 2007,318,426–430.(6)Zurcher,S.;Wackerlin,D.;Bethuel,Y.;Malisova,B.;Textor,M.;Tosatti,S.;Gademann,K.J.Am.Chem.Soc.2006,128,1064–1065.(7)Kenausis,G.L.;Voros,J.;Elbert,D.L.;Huang,N.P.;Hofer,R.;Ruiz-Taylor,L.;Textor,M.;Hubbell,J.A.;Spencer,N.D.J.Phys.Chem.B 2000,104,3298–3309.(8)Wagner,V.E.;Koberstein,J.T.;Bryers,J.D.Biomaterials 2004,25,2247–2263.(9)Krishnan,S.;Weinman,C.J.;Ober,C.K.J.Mater.Chem.2008,18,3405–3413.(10)Gnauck,M.;Jaehne,E.;Blaettler,T.;Tosatti,S.;Textor,M.;Adler,ngmuir 2007,23,377–381.(11)Rundqvist,J.;Hoh,J.H.;Haviland,ngmuir 2005,21,2981–2987.(12)Feller,L.M.;Cerritelli,S.;Textor,M.;Hubbell,J.A.;Tosatti,S.G.P.Macromolecules 2005,38,10503–10510.(13)Li,L.Y.;Chen,S.F.;Zheng,J.;Ratner,B.D.;Jiang,S.Y.J.Phys.Chem.B 2005,109,2934–2941.(14)Dalsin,J.L.;Lin,L.J.;Tosatti,S.;Voros,J.;Textor,M.;Messersmith,ngmuir 2005,21,640–646.(15)Chang,Y.;Chen,S.F.;Zhang,Z.;Jiang,ngmuir 2006,22,2222–2226.(16)Chen,S.F.;Liu,L.Y.;Jiang,ngmuir 2006,22,2418–2421.(17)Kane,R.S.;Deschatelets,P.;Whitesides,ngmuir 2003,19,2388–2391.(18)Feng,W.;Brash,J.L.;Zhu,S.P.Biomaterials 2006,27,847–855.(19)Dalsin,J.L.;Messersmith,P.B.Mater.Today 2005,8,38–46.(20)Bretagnol,F.;Lejeune,M.;Papadopoulou-Bouraoui,A.;Hasiwa,M.;Rauscher,H.;Ceccone,G.;Colpo,P.;Rossi,F.Acta Biomater.2006,2,165–172.(21)Harris,J.M.Poly (ethylene glycol )Chemistry:Biotechnical and Biomedical Applications ;Plenum Press:New York,1992.(22)Krsko,P.;Libera,M.Mater.Today 2005,8,36–44.(23)Boulmedais,F.;Frisch,B.;Etienne,O.;Lavalle,P.;Picart,C.;Ogier,J.;Voegel,J.C.;Schaaf,P.;Egles,C.Biomaterials 2004,25,2003–2011.(24)Satomi,T.;Nagasaki,Y.;Kobayashi,H.;Otsuka,H.;Kataoka,ngmuir 2007,23,6698–6703.(25)Pasche,S.;De Paul,S.M.;Voros,J.;Spencer,N.D.;Textor,ngmuir 2003,19,9216–9225.Zoulalian et al.Articlesurfaces,one standard method is by means of a“grafting to”strategy,i.e.,by the formation of an organic interface by chemisorp-tion or physisorption of molecules presenting already grafted PEG chains as for instance PEGylated SAMs,10,13,26DOPA-functionalized molecules with PEG chains,6,14and polyelectrolyte-grafted PEG copolymers.8,25,27There is still a substantial interest to develop novel surface systems that can be cost effectively produced under mild conditions(room temperature,neutral or near neutral pH)28,29while achieving the following properties:30 long-term robustness under a variety of relevant conditions (e.g.,low/high pH and high ionic strength)and formation of a dense interfacial(brush)layer of hydrophilic polymer chains,e.g., with poly(ethylene glycol)(PEG),imparting nonfouling proper-ties to the material or device surface.Limitations of currently available self-assembly systems in-clude potential loss of adlayer adhesion under physiological or other conditions(pH and ionic strength)by molecular desorption either due to chemical modification such as oxidation of anchor-ing groups in SAMs of thiols and DOPA systems31-33or due to weak electrostatic interactions in the case of polyelectrolyte-grafted polymer adlayers.34-37A second reason,specific to ordered,close-packed SAM systems,is the loss of order and stability when functionalized with bulky terminal groups38-41 such as PEG chains.Finally,the requirement of adsorption conditions different from physiological conditions(e.g.,pH,high ionic strength,temperature)to favor binding of PEG systems at high surface density(“cloud-point grafting”)5,6,14,42may not be compatible with biological functionalities.We have recently reported43the successful development of a new polymer class for the production,by self-assembly,of non-fouling surfaces on TiO2-coated substrates(mimicking the surface properties of the important biomaterial titanium).44The polymer consisted of a terpolymer structure presenting on a backbone both grafted PEG chains and alkyl side chains carrying phosphonate end groups.Thanks to multivalent binding of the oligo-phospho-nate polymer,the coated TiO2surfaces proved to have favorable stability up to3weeks when tested in solutions of different pH and in comparison to two reference systems,dodecylphosphonate (DDPO4)SAMs4and poly(L-lysine)-grafted-poly(ethylene glycol) (PLL-g-PEG)on the same substrate.25In this present work,we reported on further investigations allowing a better characterization of the system studied.We have quantitatively proved the antifouling properties of the PEG-poly-(alkyl phosphonate)terpolymer assembled on TiO2-coated sur-faces by OWLS measurements and characterizing its interface organization using XPS and angle-resolved XPS(AR-XPS).We also investigated the longer term stability of this terpolymer surface after exposure to solutions of pH2,7.4,and9and a salt buffer with a pH=7.4up to3weeks,by XPS and ellipsometry. Such a series of experiments showed that nonstandard degradation processes such as desorption or hydrolysis reaction affected the adlayer stability but rather unusual mechanisms:PEG auto-xidation and photoreactions initiated by the substrate.In view of photochemical reactions related to photocatalytic activities of the TiO2surface,tests were also performed with samples exposed to light or stored in the dark and compared to another type of substrate material(Nb2O5).Dodecylphosphate SAMs4 and PLL-g-PEG assembled layers on TiO2surfaces25were used as reference.Experimental Part Characterization Techniques.1H NMR spectra(δ,ppm) were performed at room temperature on a250MHz Bruker spectrometer in deuterated CDCl3and CD3OD as solvents with tetramethylsilane as an internal standard.Polymerizations were carried out using standard Schlenk techniques under an inert atmosphere of nitrogen.Size exclusion chromatography(SEC) measurements were run on a“GPC220,Polymer Laboratories LTD”equipped with a triple detection system and the following conditions of analysis were used:dimethylformamide(DMF)as eluent with a flow rate of1mL/min,a DMF/LiBr mixture to dissolve the polymer,and a column temperature of80°C.Data were evaluated based on a universal calibration performed with polystyrene references.To support the SEC results about the terpolymer molecular weights,elemental analyses were performed to quantify the phosphorus(ICP-AES:inductive coupled plas-ma-atomic emission spectroscopy)and sulfur traces(LECO CHN-932:infrared detection from SO2gases produced by oxygen combustion).After assembly and stability tests,the resulting terpolymer adlayers were characterized by their thicknesses evaluated by variable angle spectroscopic ellipsometry(VASE)and comple-mented by their elemental and component surface compositions with X-ray photoelectron spectroscopy(XPS).Depth-dependent information(along the z direction)on the organization of the adsorbed terpolymer molecules was obtained by performing angle resolved-XPS(AR-XPS)measurements.Ellipsometric data were obtained with a variable angle spectro-scopic M-2000F ellipsometer(LOT Oriel GmbH,Darmstadt, Germany)instrument.The measurements were conducted in the spectral range of370-1000nm at three different angles of incidence(65°,70°,and75°)and fitted using WVASE32analysis software.For processing the results of the terpolymer-coated substrates,a multilayer model was designed.The reference sub-strate before metal oxide sputter-coating consisted of a0.5mm thick silicon wafer coated with a silicon oxide layer of2.3nm. Subsequently,by using the ellipsometric equations45and a Cau-chy’s model for the refractive indices of the metal oxide sputter-coated layers and the polymer layers,45thicknesses were evalu-ated.Finally,percent remaining adlayer thickness values were always calculated for data interpretation by referring to the initial adlayer thickness measured right after assembly.(26)Vanderah,D.J.;Valincius,G.;Meuse,ngmuir2002,18,4674–4680.(27)Malmsten,M.;Emoto,K.;Van Alstine,J.M.J.Colloid Interface Sci.1998, 202,507–517.(28)Ladd,J.;Boozer,C.;Yu,Q.M.;Chen,S.F.;Homola,J.;Jiang,S. Langmuir2004,20,8090–8095.(29)Huang,N.P.;Voros,J.;De Paul,S.M.;Textor,M.;Spencer,N.D. Langmuir2002,18,220–230.(30)Blattler,T.M.;Pasche,S.;Textor,M.;Griesser,ngmuir2006,22, 5760–5769.(31)Flynn,N.T.;Tran,T.N.T.;Cima,M.J.;Langer,ngmuir2003,19, 10909–10915.(32)Roosjen,A.;de Vries,J.;van der Mei,H.C.;Norde,W.;Busscher,H.J.J. Biomed.Mater.Res.,Part B2005,73B,347–354.(33)Guvendiren,M.;Messersmith,P.B.;Shull,K.R.Biomacromolecules2008, 9,122–128.(34)Burke,S.E.;Barrett,ngmuir2003,19,3297–3303.(35)Menchaca,J.-L.;Jachimska,B.;Cuisinier,F.;Perez,E.Colloids Surf.,A 2003,222,185–194.(36)Kharlampieva,E.;Sukhishvili,ngmuir2003,19,1235–1243.(37)Farhat,T.R.;Schlenoff,ngmuir2001,17,1184–1192.(38)Dannenberger,O.;Weiss,K.;Himmel,H.J.;Jager,B.;Buck,M.;Woll,C. Thin Solid Films1997,307,183–191.(39)Sushko,M.L.;Shluger,A.L.J.Phys.Chem.B2007,111,4019–4025.(40)Tsai,M.Y.;Lin,J.C.J.Biomed.Mater.Res.2001,55,554–565.(41)Zwahlen,M.;Tosatti,S.;Textor,M.;Hahner,ngmuir2002,18,3957–3962.(42)Rodriguez,R.;Blesa,M.A.;Regazzoni,A.E.J.Colloid Interface Sci.1996, 177,122–131.(43)Zoulalian,V.;Monge,S.;Zurcher,S.;Textor,M.;Robin,J.J.;Tosatti,S.J. Phys.Chem.B2006,110,25603–25605.(44)Brunette,D.M.Titanium in Medicine:Material Science,Surface Science, Engineering,Biological Responses,and Medical Applications;Springer:Berlin,2001.(45)Tompkins,H.G.;McGahan,W. A.Spectroscopic Ellipsometry and Reflectometry:A User’s Guide;Wiley:New York,1999.DOI:10.1021/la902110j75Langmuir2010,26(1),74–82Article Zoulalian et al.XPS spectra were recorded at a90°emission angle with aSAGE100instrument(Specs,Berlin,Germany)at a pressurebelow4Â10-8mbar using nonmonochromatized Al K R radia-tion at320W(13kV)and an electron-energy analyzer pass energyof50eV for low-resolution survey and of14eV for high-resolution element detail scans.The analyzed area was6mm2,giving therefore a lateral averaged chemical composition.AR-XPS measurements were acquired at a pressure below10-9mbaron a VG Thetaprobe spectrometer equipped with a concentrichemispherical analyzer and using a monochromatic Al K R sourceat350W with a spot size of300μm.Pass energies used were250eVfor survey and100eV for detailed scans.The two-dimensionaldetector is collecting the electrons,which are discriminated forsignal intensities in both photoelectron energy and photoemissionangle.Twelve angles equally spaced by5°and varying from25.5°to80.5°in respect to the surface normal were acquired.Theprogram CasaXPS(Version2.2.24)was used for data processing.With the SAGE XPS data,the elemental and component surfacecompositions were determined by a semiquantitative evaluationassuming a homogeneous perpendicular distribution in the over-layer(layers A-C of the model presented in Scheme1).Themeasured intensities were corrected for their correspondingphotoionization cross-section values(Scofield’s sensitivity factors).46The experimental component analysis of the C1s and O1s signals was performed based on the assignments in Tables1and2determined by an iterative peak fitting starting from referenced values of component binding energies,full width at half-maximum(fwhm),and Gaussian to Lorentzian ratio reported in the literature.4,7,47-49All binding energies of the different components were referenced to the C-C aliphatic peak for C1s detail spectrum(Table1)and Ti-O peak for O1s detail spectrum(Table2).The full width at half-maximum(fwhm) was maintained between1.6and1.8for all elements and transi-tions using the sum of40%Gaussian and60%Lorentzian function.During this processing,the relative ratio between C-C-C-O-C d O,O-C d O,C-C d O,and C-P components and between O d C,O-C d O,and O d P/P-O-Ti contributions were constrained according to the known bulk polymer structure obtained by1H NMR(Tables1and2).From evaluated XPS data, percent remaining atomic and component ratios were calculated for data interpretation by referring to the initial value obtained for the terpolymer adlayer right after assembly.AR-XPS data were processed for each angle using the binding energies and intensity constraints determined previously from the SAGE data(Tables1 and2).The fwhm was constrained differently,between1.3and1.4 for C1s components and between1.4and1.5for O1s compo-nents,due to the higher resolution obtained with the monochro-matic X-rays of this system,and the Gaussian-Lorentzian ratio was fixed to30%.Afterward,only ratios of peak areas measured at the same angle were used for data interpretation.Moreover, they were always normalized for comparison by the highest ratio of the same components(peak areas also obtained at the same angle)within the same series of AR-XPS measurements.The resistance of the terpolymer interface against the ad-sorption of proteins under biological conditions(pH=7.4and 160mM ionic strength)was measured using optical waveguide lightmode spectroscopy(OWLS).This technique allows calculat-ing“dried”adsorbed masses in the vicinity of surfaces from the changes in refractive indices upon adsorption of molecules from solution.Changes are monitored by the grating-induced incou-pling of a laser light into a waveguiding substrate,generating an evanescent field probing molecule uptake.50Adsorbed mass of proteins was calculated from the resulting thickness and refractive index of the new adlayer on the waveguide according to the de Feijter’s formula51and the referenced d n/d c value of0.182cm3/g.25The sensitivity limit of OWLS is typically 1-2ng/cm.2,50Protein adhesion test was studied in situ,using aTable1.XPS Curve-Fitting Parameters Used To Model the C1s Components of the Terpolymer Adlayer Adsorbed on TiO2C1s components binding energy difference(eV)references fwhm(eV)intensity(I)constraints C-C reference(284.9)4,7,47-49 1.6-1.7freeC-C-O-C d Oþ1.9(0.154,7,47-49 1.6-1.71ÂI(O-C d O)O-C d Oþ4.0(0.154,7,47-49 1.6-1.7freeC-C d Oþ0.65(0.14,7,47-49 1.6-1.71ÂI(O-C d O)C-C-Oþ1.7(0.154,7,47-49 1.6-1.7freeC-Pþ1.45(0.154,7,47-49 1.6-1.7I(O-C d O)/10 Table2.XPS Fitting Parameters Used To Model the O1s Components of the Terpolymer Adlayer Adsorbed on TiO2O1s components binding energy difference(eV)references fwhm(eV)intensity(I)constraints Ti-O reference(530.0)4,7,47-49free freeTi-O-Hþ1.6(0.154,7,47-49Ti-O value freeC-O-C d Oþ3.6(0.154,7,47-49 1.6-1.7freeO d Cþ2.5(0.154,7,47-49 1.6-1.71ÂI(C-O-C d O)C-O-C/P-O-Hþ2.7(0.154,7,47-49 1.6-1.7freeP-O-Ti/O d Pþ1.3(0.154,7,47-49 1.6-1.7I(C-O-C d O)/10Scheme1.Model for the Monomolecular Organization of thePEG-Poly(alkyl phosphonate)Terpolymer on a TiO2Surface in aFour-Layer(A to D)System as a Basis for the Interpretation of theAngle-Dependent XPS Studies(46)Scofield,J.H.J.Electron Spectrosc.Relat.Phenom.1976,8,129–137.(47)Huang,N.P.;Michel,R.;Voros,J.;Textor,M.;Hofer,R.;Rossi,A.; Elbert,D.L.;Hubbell,J.A.;Spencer,ngmuir2001,17,489–498. (48)Crist,B.V.Polymers and Polymers Damaged by X-rays;Wiley:Chichester,2000.(49)Moulder,J.F.;Chastain,J.Handbook of X-ray Photoelectron Spectroscopy:A Reference Book of Standard Spectra for Identification and Interpretation of XPS Data;Physical Electronics Division,Perkin-Elmer Corp.:Eden Prairie,MN,1992.(50)Voros,J.;Ramsden,J.J.;Csucs,G.;Szendro,I.;De Paul,S.M.;Textor, M.;Spencer,N.D.Biomaterials2002,23,3699–3710.(51)Defeijter,J.A.;Benjamins,J.;Veer,F.A.Biopolymers1978,17,1759–1772.76DOI:10.1021/la902110j Langmuir2010,26(1),74–82Zoulalian et al.Articleflow cell with a volume of16mL.A TiO2-coated waveguide,which has been ex situ coated with the terpolymer adlayer,was assembled in the OWLS flow cell.The system was equilibrated by immersion in 160mM HEPES buffer(10mM4-(2-hydroxyethyl)piperazine-1-ethanesulfonic acid and150mM sodium chloride aqueous solution with pH adjusted to7.4)for4h in order to condition the polymer molecules in biologicalsolutions.Afterward,theantifoulingcapability of the terpolymer-coated OWLS chip was tested by exposure to full human serum(Control Serum N,Roche Diagnostics,Switzerland) for15min,followed by several rinses with HEPES buffer. Synthesis and Bulk Characterization of Terpolymer Mo-lecules.The synthesis protocol with the references of the reac-tants,their initial molar ratios,the terpolymer purification,and the procedure of ratio calculation with1H NMR have been previously reported.43The poly(phosphonate)terpolymer was synthesized by free-radical chain-transfer polymerization of dimethyl-11-methacryloyloxyundecyl phosphonates(C11)52with poly(ethylene glycol)methyl ether methacrylate(PEG)(molecular weight of2000g/mol)and n-butyl methacrylate(BMA).The aimed and characterized ratio of polymerized monomers was1to 1to8,respectively,with a degree of polymerization(DP n)of about30monomers(Scheme1).In a typical experiment1.392g of dimethyl-(11-methacryloyloxy-undecyl)phosphonate monomer(C11)(4mmol),4g(28mmol) of freshly distilled n-butyl methacrylate monomer(BMA),8.24g (3.96mmol)of carefully dried poly(ethylene glycol)methyl ether methacrylate(PEG),and0.303g(1.5mmol)of1-dodecanethiol were dissolved in acetonitrile(360mL).The mixture was carefully degassed and saturated with nitrogen at room temperature.Benzoyl peroxide(0.087g,0.36mmol into10mL of acetonitirile)was added at85°C.Polymerization occurred for16h under reflux.Subse-quently,the solvent was evaporated and the polymer precipitated into n-pentane.The diester polymer was thus dissolved into dichloromethane(50mL),and the reaction mixture was carefully degassed and saturated under an atmosphere of argon.0.5mL (3.8mmol)of bromotrimethylsilane was added.At the end of the reaction,the solvent was evaporated and the remaining silanized intermediate was immediately dissolved in a methanol solution of NaOH(25.7mg,0.64mmol,dissolved into50mL of methanol). The mixture was stirred for an additional16h.After evaporation of the solvent,the polymer was twice purified by precipitation into acetone to afford a white powder(0.68g,yield33.11%).The molecular weights and the polydispersity of the synthesized terpolymers were determined only by analysis of the dimethyl phosphonic acid ester43due to the high probability of damages of chromatography columns with compounds containing free-phos-phonic acid functions.SEC measurements were performed of freeze-dried samples previously dialyzed.The optimal conditions of dialy-sis;2days against{Na2HPO4/KH2PO4}(4/1w/w,1.15g/L)buffer with a12-13000g/mol molecular weight cutoff membrane(Spectra-Por,Spectrum Laboratories,Inc.)followed by2days against ultra-pure water;were determined after an optimization procedure and subsequently transposed to purify as well the final terpolymer compound with free phosphonates.43By considering eq1giving access to the number of repeating primary sequences of monomers whose composition was preliminary characterized with1H NMR (1/1/8in C11/PEG/BMA),the DP n of the polymer backbone can be calculated and consequently the average molecular weight. Assembly,Stability Tests,Protein Adsorption,and Sur-face Characterizations of Terpolymer Adlayer.Both20nm thick films of TiO2and15nm thick films of Nb2O5were sputter-coated on silicon wafersÆ110æ(WaferNet GmbH,Eching, Germany)using reactive magnetron sputtering(PSI,Villigen, Switzerland)to produce substrates for the terpolymer assemblies. Before adlayer formation,surfaces were sonicated twice in 2-propanol for10min,dried with N2(5.0),and UV-cleaned for 30min(Boekel UV clean model135500).Spontaneously adsorbed terpolymer adlayers on previous cleaned surfaces were obtained by immersion of the chips for 16h in a0.5mg/mL terpolymer aqueous solution prepared with ultrapure water from a Milli-Q system.Then the samples were rinsed with ultrapure water and dried with N2before surface characterizations and stability experiments.Right after the fresh assembly of terpolymer molecules on substrates,stability of the resulting adlayers were tested by immersion in different aqueous solutions at room temperature and storage of the samples inγ-sterilized polystyrene cell-plate boxes(TPP,test plates,92024),filled with acidic(HCl solu-tion with a pH=2),basic(NaOH solution with a pH=9),or 160mM HEPES buffer(10mM4-(2-hydroxyethyl)piperazine-1-ethanesulfonic acid and150mM sodium chloride aqueous solution with pH adjusted to7.4)test solutions.When needed to protect the samples to daylight,an aluminum foil was wrapped around the cell-plate boxes.The time of immersion was varied between4h,1week,and3weeks.At the end of test periods,the samples were rinsed with ultrapure water and dried with N2prior to their characterizations of thickness(VASE)and surface composi-tion(XPS)for the detection of polymer interface modifications. The nonfouling property imparted by the terpolymer interfaces to substrates after stability experiments(i.e.,acid,basic,and HEPES electrolyte exposures)was evaluated after the following protocol: exposure for15min to full human serum solution,followed by careful rinses with HEPES buffer and ultrapure water and drying with N2.Adsorbed proteins were characterized by XPS measurements,by evaluating the presence of a nitrogen signal,which is specific for the proteins and not for the terpolymer structure(Scheme1).53Results and DiscussionPolymer Molecular Weight and Polydispersity.SEC mea-surements referenced to universal polystyrene calibration showed amonomodal peak corresponding to the terpolymer sample and aresidual peak appearing at the highest retention time.The latter wasattributed after verification with a control SEC measurement toresidual PEG monomer remaining after purification steps.Thisassignment was supported by1H NMR as weak signals specificto unreacted PEG acrylate at characteristic chemical shifts(δ≈4.3ppm:-CO-O-C H2-CH2δ≈5.5and6.1ppm:C H2d C-).The SEC data obtained from the protected terpolymer sample dialyzedagainst{Na2HPO4/KH2PO4}(4/1w/w, 1.15g/L)buffer in a12-13000g/mol molecular weight cutoff membrane can be usedto judge the molecular weight,M w,as15135g/mol,which is in goodagreement with the M w resulting from the calculation of a polymerwith30monomers(DP n)with the ratios evaluated with1H NMR(ratio of C11/PEG/BMA of1to1(1to8(2)43of around10894(850g/mol.The small difference results not only from the residualPEG monomers but also from the polystyrene standards applied inSEC evaluation.Indeed,polystyrene does not present the samehydrodynamic volumes in DMF than the brushlike terpolymer,rendering the calibration slightly out of fit.Finally,the polydisper-sity index(I p)of2.99is in agreement with the standard values usuallyobtained for chain-transfer free-radical polymerization.54,55Based on the elemental analysis,P=0.6(0.05%and S=0.23(0.05%,and in view of the monomer ratio of1to1to8forC11/PEG/BMA,a DP n of27(2is calculated for the backbone ofthe terpolymer(eq1).n¼%P%SðAt wÞSðAt wÞPð1Þ(52)Senhaji,O.;Robin,J.J.;Achchoubi,M.;Boutevin,B.Macromol.Chem. Phys.2004,205,1039–1050.(53)Golander,C.G.;Kiss,E.J.Colloid Interface Sci.1988,121,240–253.(54)Matyjaszewski,K.;Davis,Library,I;Wiley-Interscience:Hoboken, NJ,2002.(55)Odian,G.Principles of Polymerization,4th ed.;Wiley:New York,2004.DOI:10.1021/la902110j77Langmuir2010,26(1),74–82Article Zoulalian et al. This value correlates with the synthesis conditions of initial molarratio aiming at a DP n of30,confirming that chain transferoccurred as polymerization and that the targeted molecularweight was reached.Terpolymer Assembly on TiO2.The thickness measured byellipsometry of the terpolymer adlayer was30(1A .43XPSmeasurements confirmed the adsorption of the phosphorus-PEG-containing polymer on TiO2:increase of the C1s intensity anddecrease of the Ti2p intensity in comparison to a bare TiO2reference surface as well as by the presence of the P2p signal.43Moreover,strong C-C-O and C-O-C PEG components wereclearly identified in the modeled C1s and O1s spectra,respec-tively(Figure1).The determined XPS fitting parameters of the terpolymersystem are summarized in Tables1,2,and3.Assuming theaverage surface stoichiometry of the molecules like in bulk,expected and experimental surface atomic composition of terpo-lymer coating on TiO2matched closely:experimental%(andtheoretical%)were found to be71(1(72),28(1(27.5),and0.8(0.6(0.4)for C,O,and P,respectively.Given the theoreticalsulfur concentration of0.1%,XPS was not expected to besensitive enough to detect S.The very low concentration ofphosphorus in the polymer(theoretical value:0.4%),close tothe detection limit of XPS,can explain the statistical deviation(experimental value:0.8%(0.6).Otherwise,as a simplifiedmodel,a monodentate binding of the phosphonate groups onTiO2was assumed,and component experimental compositionspresented in Table3confirmed that the polymer structureadsorbed on TiO2was similar to that of the bulk polymer.A C-CA O-C d O¼ðN C-CÞThiolþðDP nÞbackboneðN C-CÞC11þðN C-CÞPEGþðN C-CÞBMA rh iðDP nÞbackbone 1þ1=gþrðN O-C d OÞC11þðN O-C d OÞPEGgþðN O-C d OÞBMA r h ið2ÞðDP nÞbackbone¼11A C-CA O-C d O-5:3ð3ÞA x is the peak area of the x component with the corresponding specific binding energy,(N y)z is the number of y components from the z monomer units,(DP n)backbone is the number of monomer (degree of polymerization in number)of the backbone,1/g is the ratio of PEG/C11monomers,and r is the ratio of BMA/C11 monomers.Additional confirmation that bulk and surface composition match was obtained by determining from the component analysis the different average degrees of polymerization(DP),for the backbone,(DP n)backbone(eqs2and3)and the PEG chains, (DP n)PEG(eqs4,5,6,and7).A C-C-OA O-C d O¼ðN C-C-OÞPEGðN O-C d OÞC11þðN O-C d OÞBMAgþðN O-C d OÞPEG rð4ÞðDP nÞPEG¼5A C-C-OA O-C d Oð5ÞA C-O-C=P-O-HA O-C¼ðN C-O-CÞPEGþðNP-O-HÞC11ðN O-CÞC11þðN O-CÞPEGgþðN O-CÞBMA rð6ÞðDP nÞPEG¼g10A C-O-C=P-O-HA O-C-1ð7ÞThe latter can be calculated based on the intensities of the following contributions,C-C,O-C d O,C-C-O,C-O-C d O, and C-O-C(Table2),and considering the monomer ratio calculated from1H NMR.Experimental DP values obtained from analytical characterizations(elemental analysis and SEC)of the bulk terpolymer and calculated DP results using XPS data of the adsorbed terpolymer system on TiO2were compared.Experi-mental DP n of bulk molecules were determined to be27(2 (backbone)and45(1(PEG)whereas calculated DP n of adsorbed molecules were32(3(backbone)and49(4(PEG) using C1s and O1s data.We concluded that no selective adsorption from specific fractions of the polydisperse terpolymer solution took place during the assembly and that the polymer layer composition is close to the one of the bulk polymer.The expected organization in four layers of the monomole-cular{terpolymerþsubstrate}system,schematically drawn in Scheme1,was compared to the results of the AR-XPS study (Figures2and3).Fitting parameters presented in Tables1and2 were used to plot Figure3.In Figure2,ratios are normalized by the highest ratio of the same components within a given series of measurements when varying the angle.C is expected to be a specific element of the top layers(A)and(B),P of the intermediateFigure1.Curve fitted and assigned C1s and O1s XPS peaks of the terpolymer adlayer using the fitting parameters of Tables1and2.Table3.Theoretical and Experimental Surface Component Compo-sition from C1s and O1s Detail Spectra for the Terpolymer Coating Assuming the Average(DP)n Values of the Adsorbed Molecules Are the Same as in Bulk(Scheme1)and Using the Fitting Parameters ofTables1and2components of the terpolymer theoretical%experimental% C-C31.930(1C-C-O-C d O 5.6 5.4(0.2O-C d O 5.6 5.4(0.2C-C d O 5.6 5.4(0.2C-C-O50.653(1.5C-P0.60.5(0.1C-O-C d O15.414.2(0.8O d C15.414.2(0.8C-O-C/P-O-H64.062(1.4P-O-Ti/O d P 5.0 5.5(0.578DOI:10.1021/la902110j Langmuir2010,26(1),74–82。

基于谐振耦合和人工表面等离激元的可调控频率选择铁电厚膜移相器

基于谐振耦合和人工表面等离激元的可调控频率选择铁电厚膜移相器

基于谐振耦合和人工表面等离激元的可调控频率选择铁电厚膜移相器娄菁;王军;马华;屈绍波【摘要】移相器作为一类重要的微波功能器件,在军事和民用领域有着重要的应用.不同于传统的铁电厚膜移相器,本文将电谐振器、人工表面等离激元(SSPP)和铁电厚膜三者结合进行设计,利用电谐振器与人工表面等离激元传输结构的耦合特性,并引入铁电厚膜的介电非线性,提出了一种具有频率选择特性的电可调铁电厚膜移相器.通过基于人工表面等离激元的铁电厚膜移相器理论分析了移相器结构设计的可行性,并通过系统仿真对设计的可行性进行了验证.通过仿真不同电谐振器结构下移相器的S参数曲线验证了本文设计的移相器具有可设计的频率选择特性.【期刊名称】《电子元件与材料》【年(卷),期】2019(038)004【总页数】5页(P101-105)【关键词】铁电厚膜移相器;人工表面等离激元;电谐振器;可调控【作者】娄菁;王军;马华;屈绍波【作者单位】空军工程大学基础部, 陕西西安 710051;空军工程大学基础部, 陕西西安 710051;空军工程大学基础部, 陕西西安 710051;空军工程大学基础部, 陕西西安 710051【正文语种】中文【中图分类】TN304移相器是一类重要的微波功能器件,可用于波束形成网络、相位调制器、相控阵天线等电子、雷达、通信系统的设计。

以相控阵天线为例,自20世纪60年代起,相控阵天线以其特有的功能和无以伦比的优势在军用和民用中都得到快速的发展。

相控阵天线利用一系列T/R组件通过控制天线阵面的幅值/相位以形成空间波束,并完成目标跟踪扫描[1]。

其中移相器作为T/R组件的重要组成部分起着至关重要的作用[2]。

传统的移相器主要是铁氧体移相器与PIN二极管移相器。

但铁氧体移相器响应速度慢,制作工艺复杂,体积大,且造价成本高,而PIN二极管移相器损耗较大,频带较窄,这些因素都限制了相控阵天线技术的进一步发展[3]。

铁电移相器的工作原理主要是利用电磁波的波速与传播媒质的介电常数有关这一规律,铁电材料的介电常数在直流偏压作用下会发生变化进而影响相速,产生移相的效果。

铝质亚波长圆孔阵列与牛眼结构的太赫兹波传输特性

铝质亚波长圆孔阵列与牛眼结构的太赫兹波传输特性

铝质亚波长圆孔阵列与牛眼结构的太赫兹波传输特性陈麟;高春梅;徐嘉明;谢乐;朱亦呜【摘要】使用太赫兹时域光谱系统(THz-TDS)对基于超常光学透射现象的铝质亚波长圆孔阵列和牛眼结构进行了实验研究.实验中,使用包含00 1~2.7 THz的入射脉冲,观察到了明显的滤波效应,且滤波峰的中心频率恰好为两种结构所设计的0.53 THz.太赫兹波的高频部分,尤其是高于1 THz的部分发生了急剧地衰减.随着大样品中圆孔数量的增加,由于更加明显的周期性,滤波峰的中心漂移到0.26 THz.使用表面等离子体激元(SPPs)的相关理论以及运用有限元算法(FEM)对实验中观察到的超常光学透射现象和滤波效应进行模拟和分析,模拟的结果与实验数据吻合得非常好.【期刊名称】《光学仪器》【年(卷),期】2013(035)006【总页数】6页(P1-6)【关键词】太赫兹滤波器;超常光学透射;有限元算法;表面等离子体激元【作者】陈麟;高春梅;徐嘉明;谢乐;朱亦呜【作者单位】上海理工大学上海市现代光学系统重点实验室,上海200093;上海理工大学光电信息与计算机工程学院,上海200093;上海理工大学上海市现代光学系统重点实验室,上海200093;上海理工大学光电信息与计算机工程学院,上海200093;上海理工大学上海市现代光学系统重点实验室,上海200093;上海理工大学光电信息与计算机工程学院,上海200093;上海理工大学上海市现代光学系统重点实验室,上海200093;上海理工大学光电信息与计算机工程学院,上海200093;上海理工大学上海市现代光学系统重点实验室,上海200093;上海理工大学光电信息与计算机工程学院,上海200093【正文语种】中文【中图分类】TN29引言近年来,太赫兹技术已越来越多地应用于通信[1]、生物化学检测[1-3]以及太赫兹成像[4-5]等,因此对太赫兹波段的窄带高性能滤波器件研究显得越来越重要。

自己被别人捉弄的英语作文

自己被别人捉弄的英语作文

自己被别人捉弄的英语作文标题,An Episode of Being Teased。

Being teased by others can be both embarrassing and frustrating. This particular incident stands out vividly in my memory, serving as a lesson in resilience and self-assertion.It was a typical school day when the incident occurred.I was engrossed in a book during recess, enjoying a moment of quiet solitude amidst the bustling playground. Suddenly, a group of my classmates approached me with mischievous grins on their faces. Without warning, they began to tease me about my appearance, mimicking my mannerisms and laughing uproariously.Initially, I was taken aback and felt a surge of humiliation wash over me. Their words stung, and I struggled to find a response amidst the onslaught of mockery. However, as their taunts persisted, I graduallyrealized that I had a choice in how I reacted to their behavior.Summoning my inner strength, I took a deep breath and calmly confronted my tormentors. I asserted myself firmly, expressing my disapproval of their actions and demanding that they cease their teasing immediately. Though my voice quivered with nervousness, I stood my ground, refusing to allow their words to diminish my self-worth.To my surprise, my assertiveness caught them off guard, momentarily silencing their laughter. Sensing my resolve, they reluctantly backed down, albeit with a few muttered apologies. As they dispersed, I felt a sense of empowerment wash over me, realizing that I had successfully stood upfor myself in the face of adversity.Reflecting on the incident later, I recognized the importance of self-confidence and assertiveness in navigating social challenges. While being teased by others can be hurtful, it is essential to remember that we have the power to control our reactions and assert ourboundaries. By refusing to internalize their hurtful words and instead asserting my self-worth, I emerged from the experience stronger and more resilient than before.In conclusion, being teased by others is an inevitable part of life, but it is how we respond to such adversity that truly defines our character. Through this episode, I learned the importance of standing up for myself and refusing to allow others to undermine my confidence. It is a lesson that I will carry with me throughout my life, empowering me to face future challenges with courage and resilience.。

Mimicking surface plasmons with structured surfaces

Mimicking surface plasmons with structured surfaces

DOI: 10.1126/science.1098999, 847 (2004);305 Science et al.J. B. Pendry Mimicking Surface Plasmons with Structured SurfacesThis copy is for your personal, non-commercial use only.clicking here.colleagues, clients, or customers by , you can order high-quality copies for your If you wish to distribute this article to othershere.following the guidelines can be obtained by Permission to republish or repurpose articles or portions of articles): September 11, 2012 (this information is current as of The following resources related to this article are available online at/content/305/5685/847.full.html version of this article at:including high-resolution figures, can be found in the online Updated information and services, /content/305/5685/847.full.html#related found at:can be related to this article A list of selected additional articles on the Science Web sites 355 article(s) on the ISI Web of Science cited by This article has been /content/305/5685/847.full.html#related-urls 6 articles hosted by HighWire Press; see:cited by This article has been/cgi/collection/physics Physicssubject collections:This article appears in the following registered trademark of AAAS.is a Science 2004 by the American Association for the Advancement of Science; all rights reserved. The title Copyright American Association for the Advancement of Science, 1200 New York Avenue NW, Washington, DC 20005. (print ISSN 0036-8075; online ISSN 1095-9203) is published weekly, except the last week in December, by the Science o n S e p t e m b e r 11, 2012w w w .s c i e n c e m a g .o r g D o w n l o a d e d f r o mMimicking Surface Plasmons withStructured SurfacesJ.B.Pendry,1*L.Martı´n-Moreno,2F.J.Garcia-Vidal 3Metals such as silver support surface plasmons:electromagnetic surfaceexcitations localized near the surface that originate from the free electrons of the metal.Surface modes are also observed on highly conducting surfaces perforated by holes.We establish a close connection between the two,showing that electromagnetic waves in both materials are governed by an effective permittivity of the same plasma form.The size and spacing of holes can readily be controlled on all relevant length scales,which allows the creation of designer surface plasmons with almost arbitrary dispersion in frequency and in space,opening new vistas in surface plasmon optics.The interaction of light with a metal surface is dominated by the free electrons that be-have like a plasma with a dielectric func-tion,εϭ1Ϫ␻p 2/␻2,which is negative below the plasma frequency,␻p .As a con-sequence,metals support collective oscilla-tions of the electrons bound to the surface (1).These are the surface plasmons,re-sponsible for a host of phenomena unique to metals.Examples are the surface-enhanced Raman scattering experiments (2),in which the Raman signal is enhanced by the surface plasmon resonances (some-times by as much as a factor of 106)and by the strong absorption of light in silver col-loids (the black parts of photographic neg-atives).Previous work has investigated waveguiding in surface plasmon polariton band gap structures (3),plasmon propaga-tion in metal stripes (4),and two-dimen-sional optics with surface plasmon polari-tons (5).A useful summary of work appears in a recent review (6).More recently,ex-periments have been performed on the trans-mission of light through subwavelength holes in metal films (7).It has been established (8)that resonant excitation of surface plasmons creates huge electric fields at the surface that force light through the holes,giving very high transmission coefficients.Other materials with quite different di-electric functions from the plasma form can also support electromagnetic surface modes.A perfect conductor is an exception,but even such a material can be induced tosupport surface modes by drilling an array of holes in the surface.We show that these structured surfaces have many more prop-erties in common with the electron plasma and that they can be described by an effec-tive dielectric function of the plasma form,provided that the structure is on a scale much smaller than the wavelength of prob-ing radiation.Reducing our description to a dielectric function of the plasma form has a conceptual elegance that unites all of these phenomena under the same umbrella.An effective response generated by the struc-ture of the medium is commonly seen at microwave frequencies (9–11).Thus,it ap-pears that surface structure may spoof sur-face plasmons,which provide an accurate paradigm for structured surfaces.Such a description allows us to unify a broad range of analogous phenomena.To illustrate these ideas,we begin with a simple model.Let us suppose that we have a surface that is a perfect conductor pierced by an array of holes.For simplicity,we shall assume a square cross section a ϫa for the holes and a square array of side d (Fig.1).We sup-pose that the holes and their spacing are much smaller that the wavelength of radi-ation,a Ͻd ϽϽ␭0.An incident wave excites several waveguide modes in the holes but the fundamental mode will dom-inate because it is the least strongly decay-ing.Both electric and magnetic fields are zero inside the conductor but in the holes the electric field has the form E ϭE 0[0,1,0]sin(␲x /a )exp(ik z z –i ␻t ),0Ͻx Ͻa ,0Ͻy Ͻa(1)where E 0is a constant,x ,y ,and z are cartesian coordinates,i ϭͱ–1,␻is the frequency,t is time,k 0is the free space wave vector,andk z ϭi ͱ␲22Ϫεh ␮h 0(2)where εh and ␮h are the permittivity and permeability,respectively,of any material that may be filling the holes.We take the z axis to be the surface normal.The magnetic fields along the x and z axes H x and H z ,follow from this equation.Externally incident radiation is insensi-tive to the details of the holes,which it cannot resolve,and sees only an average response that we shall describe by εz ,εx ϭεy and ␮z ,␮x ϭ␮y for an anisotropic effective homogeneous medium.We can easily determine εz and ␮z by observing that the dispersion of the waveguide mode is unaffected by k x or k y in either of the two possible polarizations and thereforeεz ϭ␮z ϭϱ(3)Suppose that the effective homogeneous fields in the medium areE ؅ϭE Ј0[0,1,0]exp(ik x x ϩik z z –i ␻t )(4)We require that k z is the same as in the waveguide and k x is defined by the incident direction.If this effective field is to match to the incident and reflected fields external to the surface,Eq.1and Eq.4must give the same average fields at the surface.Hence,after matching to incident and reflected waves,E y ϭE 0ad2͵asin(␲x /a )dx ϭE 02a 2␲d2ϭE Ј0(5)We argue that the instantaneous flow of en-ergy across the surface,(E ϫH )z ,must be the1Imperial College London,Department of Physics,The Blackett Laboratory,London,SW72AZ,UK.2Departamento de Fisica de la Materia Conden-sada,Instituto de Ciencia de Materiales,Univer-sidad de Zaragoza,E-50009Zaragoza,Spain.3Departamento de Fisica Teorica de la Materia Con-densada,Universidad Autonoma de Madrid,E-28049Madrid,Spain.*To whom correspondence should be addressed.E-mail:j.pendry@Fig.1.Our model system:a ϫa square holes arranged on a d ϫd lattice are cut into the surface of a perfect conductor.Our theory pre-dicts localized surface plasmon modes induced by the structure.R EPORTS SCIENCE VOL 3056AUGUST 2004847o n S e p t e m b e r 11, 2012w w w .s c i e n c e m a g .o r g D o w n l o a d e d f r o msame inside and outside the surface,both for the real and effective media,(E ؋H )z ϭϪk z E 02␻␮h ␮0ad 2͵asin 2(␲x /a )dx ϭϪk z E 02␻␮h ␮0a 22d 2ϭ(E ؅؋H ؅)z ϭϪk z E Ј02␻␮0␮x (6)Finer details of the fields around the holes are matched by strongly evanescent fields in the vacuum.Because these fields do not escape from the surface and contain little energy,we neglect them.Substituting for E Ј02,we deduce␮x ϭ␮y ϭ2d 2␮h a 2ͫ2a 2␲d 2ͬ2ϭ8a 2␮h ␲2d 2(7)We also know thatk z ϭk 0ͱεy ␮x ϭi ͱ␲2/a 2Ϫεh ␮h k 02(8)and hence if c 0is the velocity of light in a vacuoεy ϭεx ϭ1␮x ͩεh ␮h Ϫ␲2a 2k 02ͪϭ␲2d 2εh 8a 2ͩ1Ϫ␲2c 02a 2␻2εh ␮hͪ(9)which is the canonical plasmon form with a plasma frequency of␻pl ϭ␲c 01ͱεh ␮h (10)This is exactly the cut-off frequency of the wave guide.It is easy to see that this is a general result:Any array of closely spaced holes in a perfect conductor will have this form of effective response,with the plasma frequency given by the cut-off frequency of the waveguide mode.This effective medium implies a bound surface state when there is a divergence in the reflection coefficient of the surface for large values of k ࿣where k Јz ϭi ͱk ࿣2Ϫk 0is imag-inary.For the polarization where the magnet-ic field is parallel to the surfacer ϭk Јz Ϫε࿣Ϫ1k zz ϩε࿣Ϫ1zϭϱ(11)which implies a dispersion relationship typi-cal of a surface plasmon polaritonk ࿣2c2ϭ␻2ϩ1␻pl 2Ϫ␻264a 4␻4␲4d4(12)Figure 2shows a sketch of the disper-sion.Notably,at low frequencies the sur-face mode approaches the light line asymp-totically,and the fields associated with the mode expand into the vacuum.At large k ࿣the frequency of the mode approaches ␻p ,in contrast to an isotropic plasma where the asymptote is ␻p /ͱ2.Although a flat per-fectly conducting surface supports no bound states,the presence of holes,how-ever small,produces a surface plasmon polariton-like bound surface state.Indeed,almost any disturbance of the flat surface will bind a state.Bound states are found in the following circumstances:a surface with an array of holes of finite depth,however shallow;a surface with an array of grooves of finite depth;and a surface covered by a layer of dielectric,however thin.It is also possible to produce hybrid surface plasmons by cutting holes in metals such as silver that already have a surface plasmon.The holes will increase the pene-tration of fields into the metal and lower the frequency of existing surface plasmons.In this case,it is hard to distinguish between the “real ”and the spoof surface plasmons as they merge one into the other.Our theory as presented is valid when the spacing between the holes is much smaller than the wavelength,so that incident radiation can-not resolve the individual holes.However,the theory can be progressively extended to larger hole spacings by including diffracted waves,more of which appear as the spacing gets big-ger.We can do this by including Fourier com-ponents of εand ␮so that the effective medium also gives rise to diffracted beams.The main effect of diffraction is to couple the spoof plas-mons to incident radiation.Our result resolves a longstanding de-bate over transmission through subwave-length holes.As mentioned above,when the anomalously high transmission was first observed (Eq.7),it was attributed to resonant excitation of surface plasmons.Subsequent calculations (Eq.8)showed that subwavelength holes in a perfect con-ductor also gave rise to similar anomalous transmission even though the free surface of an unperforated conductor has no surface modes,leading to discussion as to the true origin of the effect.Now we can see that there are not two separate mechanisms:Theholes will spoof surface plasmons which play the same resonant role as do the real ones on silver.The ability to engineer a surface plas-mon at almost any frequency (metals are nearly perfect conductors from zero fre-quency up to the threshold of the terahertz regime)where none existed before and to modify at will the frequency of surface plasmons on metals such as silver opens opportunities to control and direct radiation at surfaces over a wide spectral range.Un-like other schemes for creating metamate-rials with a plasmalike response (9–11),the present scheme is readily implemented,given that hole drilling techniques are available over a range of length scales down to suboptical wavelengths.Invoking a picture of the surface plasmon as a wave in two dimensions,we now have the ability to control the refractive index perceived by this wave.We stress that this is not the refractive index of the underlying material but is given by the extent to which the surface plasmon wave vector deviates from the light line,n sp ϭk ࿣/␻sp .We have the option to design a lens to focus surface plasmons.Alternatively,we could contour the refractive index,n sp (x ,y ),and,adopting a particle picture of the surface plasmon,imagine it rolling like a ball over this landscape.More prosaic applica-tions such as creating channels to act as waveguides are also possible.References and Notes1.R.H.Ritchie,Phys.Rev.106,874(1957).2.M.Fleischmann et al .,Chem.Phys.Lett.26,163(1974).3.S.I.Bozhevolnyi,J.Erland,K.Leosson,P.M.Skov-gaard,J.M.Hvam,Phys.Rev.Lett.86,3008(2001).4.J.C.Weeber,A.Dereux,C.Girard,J.R.Krenn,J.R.Goudonnet,Phys.Rev.B 60,9061(1999).5.H.Ditlbacher,J.R.Krenn,G.Schider,A.Leitner,F.R.Aussenegg,Appl.Phys.Lett.79,3035(2002).6.W.L.Barnes,A.Dereux,T.W.Ebbesen,Nature 424,824(2003).7.T.W.Ebbesen,H.J.Lezec,H.F.Ghaemi,T.Thio,P.A.Woff,Nature 391,667(1998).8.L.Martin-Moreno et al .,Phys.Rev.Lett.86,1114(2001).9.J.B.Pendry,A.J.Holden,D.J.Robbins,W.J.Stewart,J.Phys.Condens.Matter 10,4785(1998).10.J.B.Pendry,A.J.Holden,D.J.Robbins,W.J.Stewart,IEEE Trans.Microw.Theory Tech.47,2075(1999).11.A.Grbic,G.V.Eleftheriades,Phys.Rev.Lett.92,117403(2004).12.We thank the European Community (EC)underproject FP6-NMP4-CT-2003-505699for financial support.Additionally,J.B.P.acknowledges support from the The Engineering and Physical Sciences Re-search Council,from the Department of Defense/Office of Naval Research Multidisciplinary University Research Initiative grant N00014-01-1-0803,and from the EC Information Societies Technology pro-gram Development and Analysis of Left-Handed Ma-terials,project number IST-2001-35511.L.M.-M.and F.J.G.-V.also acknowledge financial support from the Spanish Minesterio de Ciencia y Tecnologia under contracts MAT2002-01534,MAT2002-00139,and BFM2003-08532-C02-01.9April 2004;accepted 28June 2004Published online 8July 2004;10.1126/science.1098999Include this information when citing thispaper.Fig.2.Dispersion relation for spoof surface plasmons on a structured surface.The a-symptotes of the light line at low frequencies and the plasma frequency at large values of k ࿣are shown.R E P O R T S6AUGUST 2004VOL 305SCIENCE 848 o n S e p t e m b e r 11, 2012w w w .s c i e n c e m a g .o r g D o w n l o a d e d f r o m。

英语作文伪装模板

英语作文伪装模板

英语作文伪装模板英文回答:Disguise: A Chameleon's Technique for Survival。

Disguise, the art of altering one's appearance to resemble another, is a remarkable survival tactic employed by various organisms throughout the natural world. Among these masters of disguise, the chameleon stands out as a prime example, showcasing an extraordinary ability to change its color and texture to blend seamlessly with its surroundings.Physiological Adaptations for Disguise。

Chameleons possess a unique set of physiological adaptations that enable their exceptional camouflage skills. Their skin contains specialized chromatophores, cells that contain pigments which can be expanded or contracted to change the animal's coloration. By combining thesechromatophores in various patterns and intensities, chameleons can create a vast array of colors and patterns, mimicking the hues and textures of their environment.In addition to chromatophores, chameleons have a layer of iridophores beneath their skin, which contain tiny crystals that reflect light. By manipulating the orientation of these crystals, chameleons can further enhance their camouflage by creating iridescent effects that mimic the shimmering surfaces of leaves or water droplets.Behavioral Adaptations for Disguise。

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Appearance-Mimicking Surfaces
Christian Sch¨ uller Daniele Panozzo ETH Zurich Olga Sorkine-Hornung
Figure 1: A collection of appearance-mimicking surfaces generated with our algorithm.
image, which has a strong relation with the depth buffer used in the standard graphics pipeline. Most works have proposed to create bas-reliefs from given digital 3D scenes by either directly compressing the depth buffer of the scene’s rendering or by working in the gradient domain, where the final model is obtained by solving a Poisson equation. In this work, we define appearance-mimicking surfaces (AMS) that generalize bas-reliefs, lifting their restriction to a height field. Our generalization makes the reliefs usable at a wider range of viewing angles, while still guaranteeing self-intersection free results, which is mandatory for subsequent fabrication. Specifically, we develop a mathematical framework to compute surfaces whose normals optimally approximate the normals of a given 3D shape or scene, while strictly obeying given depth- or volume-confinement constraints. Direct fitting of normals and spatial constraints is in general a challenging, nonlinear problem, which led previous works to employ heuristics that circumvent difficult numerical optimizations. Unfortunately, giving up the constrained optimization of normals means forfeiting bounds on geometry and appearance distortion in the resulting relief. Instead, we propose a novel view-dependent surface representation which allows us to cast the optimization as a quadratic program. The resulting problem formulation is convex, and we are guaranteed to find the optimal solution under feasible constraints. Differently from previous works, our method does not rely on rasterization of the input geometry and the depth buffer. AMS are generated by deforming the input mesh without modifying its connectivity, thereby increasing the algorithm’s efficiency, details preservation and allowing to easily transfer surface attributes. As a positive side effect of our representation, we can exactly satisfy per-vertex depth constraints and we can “project” the target shapes on disconnected and arbitrarily shaped surfaces, as shown in Figure 3. Our algorithm is controllable and robust, enabling to design complicated appearance-mimicking surfaces with minimal user effort. We test our method in a variety of applications, such as the design of optical illusions in architectural settings and the creation of carving patterns on complex geometries. To verify the realism of our model and lighting assumptions, we validate our results via 3D printing.
(c) Jonty Hurwitz, 2014
Figure 2: We draw inspiration from the art of Jonty Hurwitz, building sculptures of fragmented and disconnected slices to obfuscate the shape and creating interesting optical illusions.
1
Introductቤተ መጻሕፍቲ ባይዱon
Bas-reliefs are thin surfaces whose normals resemble the normals of a different surface or a general 3D scene, giving a (false) impression of depth when observed from the right viewpoint. Bas-reliefs have been used for centuries in artistic masterpieces, and are ubiquitous on coins and medals. The most common bas-reliefs are thin layers of stone or ceramic covering a single object, but they can also be fragmented into disconnected slices to obfuscate the shape, creating interesting optical illusions (Figure 2). The design of bas-reliefs has been a subject of interest in computer graphics in the past two decades. A bas-relief is essentially a 2.5D
Abstract
We consider the problem of reproducing the look and the details of a 3D object on a surface that is confined to a given volume. Classic examples of such “appearance-mimicking” surfaces are bas-reliefs: decorations and artwork depicting recognizable 3D scenes using only a thin volumetric space. The design of bas-reliefs has fascinated humankind for millennia and it is extensively used on coins, medals, pottery and other art forms. We propose a unified framework to create surfaces that depict certain shapes from prescribed viewpoints, as a generalization of bas-reliefs. Given target shapes, viewpoints and space restrictions, our method finds a globally optimal surface that delivers the desired appearance when observed from the designated viewpoints, while guaranteeing exact, per-vertex depth bounds. We use 3D printing to validate our approach and demonstrate our results in a variety of applications, ranging from standard bas-reliefs to optical illusions and carving of complex geometries. CR Categories: I.3.5 [Computer Graphics]: Computational geometry and object modeling—Curve, surface, solid, and object repres. Keywords: bas-relief, convex optimization, spatial constraints Links: DL PDF W EB V IDEO
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