有机化学中的官能团缩写

LIST OF COMMON ABBREVIATIONS

aminohydroxylation

AA asymmetric

Ac acetyl

Acac acetylacetonate

Ad adamantyl

dihydroxylation

AD Asymmetic

Adoc adamantyloxycarbonyl

AIBN azoisobutyronitrile

Alloc or AOC allyloxycarbonyl

An p-anisyl

anh. anhydrous

aq. aqueous

atm atmosphere

triphosphate

ATP adenosine

9-BBN 9-borabicyclo[3.3.1]nonane

BINAP 2,2'-(bisphenylphosphino)-1,1'-binaphthyl bipy 2,2'-bipyridine

diisopropylamide BMDA bromomagnesium

sulfide

BMS borane-dimethyl

Bn benzyl

BOC (or Boc) tert-butoxycarbonyl

BOM benzyloxymethyl

BOP reagent benzotriazol-1-yloxytris (dimethylamino)phosphonium

hexafluorophosphate

chloride BOP-Cl bis(2-oxo-3-oxazolidinyl)phosphinic

Bt benzotriazol-1-yl

n-Bu n-butyl

s-Bu sec-butyl

t-Bu tert-butyl

Bz benzoyl

18C6 18-crown-6

CA chloroacetyl

CAL Candida antarctica lipase

CAN ceric ammonium nitrate

amount

cat catalytic

CB catecholborane

oxazaborolidine CBS Corey-Bakshi-Shibata

Cbz or Z benzyloxycarbonyl (carbobenzyloxy)

CDI 1,1'-carbonyldiimidazole

cHex cyclohexyl

iodide CMPI 2-chloro-1-methylpyridinium

Cod cyclooctadiene

Cp cyclopentadienyl

Cp* pentamethylcyclopentadienyl

CSA camphorsulfonic

acid

Cy cyclohexyl

DABCO 1,4-diazabicyclo[2.2.2]octane

DAIB 3-exo-(dimethylamino)isoborneol

DAST diethylamino sulfur trifluoride

dba dibenzylideneacetone

DBAD di-t-butyl azodicarboxylate

DBN 1,5-diazabicyclo[4.3.0]non-5-ene

DBU 1,8-diazabicyclo[5.4.0]undec-7-ene

DCC dicyclohexylcarbodiimide

DDQ 2,3-dichloro-5,6-dicyano-1,4-benzoquinone

azodicarboxylate

DEAD diethyl

DEIPS diethylisopropylsilyl

DET diethyl

tartrate

DHP 3,4-dihydro-2H-pyran

azodicarboxylate

DIAD diisopropyl

hydride

DIBAL-H diisobutylaluminum

DIPEA diisopropylethylamine (Hünig's base)

DIPT diisopropyl

tartrate

DMA dimethylacetamide

azodicarboxylate

DMAD dimethyl

DMAP 4-N,N-dimethylaminopyridine

DME 1,2-dimethoxyethane

DMF N,N-dimethylformamide

periodinane

DMP Dess-Martin

DMPU N,N'-dimethylpropyleneurea

sulfide

DMS dimethyl

DMSO dimethyl

sulfoxide

or

DMTr or DMT di-(p-methoxyphenyl)phenylmethyl

dimethoxytrityl

DNP 2,4-dinitrophenyl

DNs 2,4-dinitrobenzenesulfonyl

DPIPS diphenylisopropylsilyl

DPM or Dpm diphenylmethyl

Dpp diphenylphosphinyl

azide

DPPA diphenylphosphoryl

dppb 1,4-bis(diphenylphosphino)butane

dppe 1,2-bis(diphenylphosphino)ethane

dppf 1,1’-bis(diphenylphosphanyl)ferrocene DTBMS di-t-butylmethylsilyl

DTT dthiothreitol

EDC or EDCI 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide

acid

EDTA ethylenediaminetetraacetic

EE 1-ethoxyethyl

Et ethyl

Fmoc 9-fluorenylmethoxycarbonyl

HATU O-(7-azabenzotriazol-1-yl)-N,N,N’,N’-

hexafluorophosphate tetramethyluronium

HBTU O-benzotriazol-1-yl-N,N,N’,N’-

tetramethyluronium

hexafluorophosphate HMDS hexamethyldisilazane