【信越Shin-Etsu】KE信越硅胶物性表(英文版)
信越kr-255的规格参数
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信越kr-255的规格参数
信越KR-255是一种聚氨酯密封胶,通常用于建筑、汽车和工业设备的密封和粘接。
以下是其一般规格参数:
1. 粘度,信越KR-255的粘度通常在3000-5000 mPa·s之间,这使得它在施工和涂覆时具有良好的流动性和涂覆性能。
2. 固化时间,在常温下,信越KR-255通常需要24小时左右才能完全固化。
但在高温下,固化时间会明显缩短。
3. 拉伸强度,信越KR-255的拉伸强度通常在2-3 MPa之间,这使得它能够在施工后提供良好的拉伸性能和抗拉伸能力。
4. 耐候性,信越KR-255具有良好的耐候性,能够在室内外环境下长期保持稳定的性能。
5. 耐化学性,信越KR-255对一般化学溶剂和油品具有一定的耐受性,能够在一定程度上抵抗化学腐蚀。
总的来说,信越KR-255是一种性能稳定、使用方便的聚氨酯密
封胶,适用于多种密封和粘接应用。
当然,具体的规格参数还需要根据实际使用情况和厂家提供的技术资料进行确认。
日本信越硅烷偶联剂
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日本信越硅烷偶联剂一、日本信越硅烷偶联剂简述硅烷偶联剂是由有机物以及硅构成的化合物。
硅烷偶联剂的分子中,具有能够与无机材料进行化学性结合的,和能够与有机材料进行化学性结合的两种以上的不同的反应基团。
二、产品特点高质量复合材料硅烷偶联剂改善了树脂和底涂料搅拌时候的分散性,同时提高了复合材料的机械强度,耐水性,耐寒性,透明性,粘附度及其他特性。
改性树脂通过与树脂的反应,硅烷偶联剂能提高树脂对有机材料的粘附度和赋予低温,低水分固化,和提高耐气候性,耐热性和耐酸性,耐溶剂性。
三、产品技术指标KBM-1003 KBM-403 KBM-503 KBE-903 KBM-603化学名称 乙烯基三甲氧基硅烷 (γ-环氧丙氧基丙基)三甲氧基硅烷γ-甲基丙烯酰氧丙基三甲氧基硅烷γ-氨丙基三乙氧基硅烷N-β氨乙基-γ-氨丙基三甲氧基硅烷分子量 148.2 236.3 248.4 221.4 222.4比重(25℃) 0.97 1.07 1.04 0.941.02折射率(25℃) 1.391 1.427 1.429 1.4201.442闪点(℃)23 149 125 98 128 沸点(℃)123 290 255 217 259最小覆盖面积㎡/g 515 330 314 353351四、产品应用a、KBM-1003主要用于聚乙烯交联;不饱和聚酯、聚乙烯、聚丙烯树脂等玻璃纤维增强塑料的玻纤表面处理;合成特种涂料;粘接剂;电子元器件的表面防潮处理;无机含硅填料的表面处理等;也用于复合玻璃中间层的表面处理。
本品是交联聚乙烯的重要交联剂,被广泛应用于制造电线、电缆绝缘、护套材料和交联聚乙烯管等方面。
本品还可用于乙烯一醋酸乙烯共聚物、氯化聚乙烯,乙烯—丙烯酸—乙醋共聚物的交联。
本品还适用于浸渍处理玻璃纤维及无机含硅填料,还与多种单体共聚、可制成特种涂料。
也用作处理特种橡胶填充剂;用于制备电子元器件塑封材料的密封剂;也可以作电子元件的表面防潮处理等。
CMC-Ca中文手册(日本信越Shinetsu)
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CMC-CA羧甲基纤维素钙 羧甲基纤维素CMC-Ca 羧甲纤维素钙 CMC 羧甲纤维素[CAS 9050-04-8] [CAS 9000-11-7]商品名 ECG-505 商品名: NS-300简介:羧甲基纤维素的两种不同型号最初是由 GOTOKU CHEMICAL CO.,LTD.( 五德化学株式会社 ) 研发出来的。
一种是钙型的“ ECG-505 ”而另一种是自由型“ NS-300 ”。
ECG-505 于 1962 年生产,于 1968 年3 月 26 日成功获准专利。
NS-300 的生产在 1967 年开始。
在日本 ECG505 已经获得了最高的评价。
ECG505 和 NS-300 由 NICHIRIN CHEMICAL INDUSTRIES LTD( 一个优秀的转包合同工厂 ) 在严格的控制条件下生产的。
ECG505 和 NS-300 作为片剂和颗粒剂的崩解剂和分散剂已经被广泛的应用。
这种分散剂是获得药物更高生物利用度所需要的。
ECG-500 在 1966 年被日本药典收录。
ECG-500 在 1985 年被 USP-XXI ,US-NF X VI 收录,在 1994 年被欧洲药典( EP )收录。
NS-300 也在 1986 年被日本药典收录。
1992 年,ECG-500 成为 International Harmonization Monographs (国际协调专论)的 25 种最常用的药用辅料之一,并且 NS-300 也作为 ECG-505 的补充条款被选入。
Ⅰ .ECG-505 和 NS-300 的特点ECG-505 和 NS-300 是由纤维素羧甲基化的得到的。
ECG-505 是世界上唯一一种含钙的崩解剂。
NS-300 是由羧甲基纤维素钠在低的 pH 值下酸化处理而得。
ECG-505 和 NS-300 能快速吸水膨胀因此能在短时间内快速崩解。
片剂和颗粒剂中的崩解剂使药物分散成颗粒和细粉,这在提高溶解性和生物利用度方面是很重要的。
美国科腾(Kraton)苯乙烯类热塑性橡胶产品常规牌号性能表
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美国科腾(Kraton)苯⼄烯类热塑性橡胶产品常规牌号性能表美国科腾公司(Kraton)苯⼄烯类热塑性橡胶产品SEBS牌号物性表Grade Structure% Styrene Hardness% Diblock% OIL Solution Viscosity Melt FlowG1633 E SEBS Linear30--00.3-G1640 E SEBS Linear32.9--- 1.5-G1641 H SEBS Linear3352<10>50<1G1642 H SEBS Linear2148<10>50<1G1643 M SEBS Linear2052-00.218G1645 M SEBS Linear12.535-0- 3.25G1650 E SEBS Linear3072<108<1G1650 M SEBS Linear3072<108<1G1651 E SEBS Linear31--0>50<1G1651 H SEBS Linear3360<10>50<1G1652 E SEBS Linear3070<10 1.8<1G1652 H SEBS Linear3069--4635G1652 M SEBS Linear3070<10 1.8<1G1654 E SEBS Linear3163<10>50<1G1654 H SEBS Linear3163<10>50<1G1657 M SEBS Linear1347290 4.28G1660 H SEBS Linear3072<108<1G1701 E SEP Linear37641000>50<1G1701 H SEP Linear37641000>50<1G1701 M SEP Linear37641000>50<1G1702 H SEP Linear28411000-<1G1702 M SEP Linear28411000>50<1G1726 M SEBS Linear30707000.219G1740 M SEP Star6-----G1765 M SEP Star-12-0-4G2705 GU-N SEBS Compound------G2708 GU-N SEBS Compound------G2832 GS-N SEBS Compound------G4609 H SEBS with Oil3322<14711<1G4610 H SEBS with Oil3336<131>50<1G7705 GI-B SEBS Compound-45-0--G7705 GI-N Compound-45-0--G7720 GI-B SEBS Compound-60-0--G7720 GI-N Compound------G7820 GU-B SEBS Compound-90-0--G7820 GU-N Compound-90----MD1537 H SEBS Linear6078---5A1535 H SEBS Linear58----<1A1536 H SEBS Linear4265---7盛悦TPE,科腾SEBS⾸选盛悦化⼯科技Grade Structure% Styrene Hardness% Diblock% OIL Solution Viscosity Melt FlowG1633 E SEBS Linear30--00.3-G1640 E SEBS Linear32.9--- 1.5-G1641 H SEBS Linear3352<10>50<1G1642 H SEBS Linear2148<10>50<1G1643 M SEBS Linear2052-00.218G1645 M SEBS Linear12.535-0- 3.25G1650 E SEBS Linear3072<108<1G1650 E SEBS Linear3072<108<1G1650 M SEBS Linear3072<108<1G1651 E SEBS Linear31--0>50<1G1651 H SEBS Linear3360<10>50<1G1652 E SEBS Linear3070<10 1.8<1G1652 H SEBS Linear3069--4635G1652 M SEBS Linear3070<10 1.8<1G1654 E SEBS Linear3163<10>50<1G1654 H SEBS Linear3163<10>50<1G1657 M SEBS Linear1347290 4.28G1660 H SEBS Linear3072<108<1G1701 E SEP Linear37641000>50<1G1701 H SEP Linear37641000>50<1G1701 M SEP Linear37641000>50<1G1702 H SEP Linear28411000-<1G1702 M SEP Linear28411000>50<1G1726 M SEBS Linear30707000.219G1740 M SEP Star6-----G1765 M SEP Star-12-0-4G2705 GU-N SEBS Compound------G2708 GU-N SEBS Compound------G2832 GS-N SEBS Compound------G4609 H SEBS with Oil3322<14711<1G4610 H SEBS with Oil3336<131>50<1G7705 GI-B SEBS Compound-45-0--G7705 GI-N Compound-45-0--G7720 GI-B SEBS Compound-60-0--G7720 GI-N Compound-----G7820 GU-N Compound-90---MD1537 H SEBS Linear6078---A1536 H SEBS Linear4265---Grade Structure% Styrene Hardness% Diblock% OIL Solution Viscosity Melt Flow G1633 E SEBS Linear30--00.3-G1640 E SEBS Linear32.9--- 1.5-G1641 H SEBS Linear3352<10>50<1G1642 H SEBS Linear2148<10>50<1G1643 M SEBS Linear2052-00.218G1645 M SEBS Linear12.535-0- 3.25G1650 E SEBS Linear3072<108<1G1650 M SEBS Linear3072<108<1G1651 E SEBS Linear31--0>50<1G1651 H SEBS Linear3360<10>50<1G1652 E SEBS Linear3070<10 1.8<1G1652 H SEBS Linear3069--4635G1652 M SEBS Linear3070<10 1.8<1G1654 E SEBS Linear3163<10>50<1G1654 H SEBS Linear3163<10>50<1G1657 M SEBS Linear1347290 4.28G1660 H SEBS Linear3072<108<1G1701 E SEP Linear37641000>50<1G1701 H SEP Linear37641000>50<1G1701 M SEP Linear37641000>50<1G1702 H SEP Linear28411000-<1G1702 H SEP Linear28411000-G1726 M SEBS Linear30707000.2G1740 M SEP Star6----G2705 GU-N SEBS Compound-----G2708 GU-N SEBS Compound-----G2832 GS-N SEBS Compound-----G4609 H SEBS with Oil3322<14711G4610 H SEBS with Oil3336<131>50G7705 GI-B SEBS Compound-45-0-G7720 GI-B SEBS Compound-60-0-G7720 GI-N Compound-----G7820 GU-N Compound-90---MD1537 H SEBS Linear6078---A1535 H SEBS Linear58----1、G代表Kraton G(氢化苯⼄烯嵌段共聚物),MD代表在研牌号,A代表Kraton A(氢化苯⼄烯嵌段共聚物);2、E代表产地为法国(Berre);H、M代表产地为美国(Belpre);科腾公司产品分为:1、传统的SEBS G系列 2、ERS系列(特殊⽤途,欢迎咨询)3、功能性SEBS(马来酸酐接枝SEBS )4、科腾A系列(A1535,A1536详细咨询我们⼯程师)5.科腾专⽤TPE关于科腾聚合物公司科腾聚合物公司是全球领先的⾼性能聚合物⽣产商,同时,据信是全球最⼤的苯⼄烯嵌段共聚物(SBC)⽣产商。
高端材料介绍
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TORAY
CD/DVD-ROM防尘材
橡胶薄膜
藤仓橡胶工业株式会社 FUJIKURA
橡胶薄片
入间川橡胶株式会社 IRUMA
橡胶薄片
泰賀塑化株式会社
TIGERS POLYMER 橡胶薄片
龟户橡胶工业株式会社 KAMEIDO
橡胶薄片
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NICHIAS
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SANWA SEKISUI BRIDGESTONE
三菱树脂株式会社 三菱GAS化学株式会社 中井铭板株式会社 中兴化成工业株式会社 东洋纤维株式会社 东洋纺株式会社 尾池工业株式会社
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shinetsu-rtv_e 信越有机硅
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I Sealing – Reduced low-molecular-weight siloxane types
20
I Potting (rubber)
22
I Potting (gel)
23
I Coating I Thermally conductive types
24
I Foams I Oil- and solvent-resistant types (fluorosilicone)
28
I One-component RTV rubber (heat cure types) 29
I Two-component RTV rubber (room temperature curing and heat cure types)
Directions for Usage I One-component RTV rubber - Usage
After curing, they absorb shock and vibration, which prevents damage to electrical and electronic components, glass, and other delicate objects.
2 Adhesion Suitable for heat-dissipating seals of heat pipes.
11
I Chemical resistance
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I Low-molecular-weight siloxane
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I Various additives
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I Primers
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Product Listing by Intended Use
信越化学工业株式会社KE-4961-W产品说明书
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化学品安全技术说明书按照GB/T 16483、GB/T 17519编制。
第1部分 化学品及企业标识KE-4961-W产品名称制造商公司名称信越化学工业株式会社联系部门品保部(群马事业所)地址日本群马县安中市矶部 2丁目13-1 〒379-0195电话号码+81(0)27-385-2172传真+81(0)27-385-2753供应商信息公司名称信越有机硅国际贸易(上海)有限公司联系部门业务部地址上海市徐汇区肇嘉浜路789号均瑶国际广场29楼F1室 200032电话号码+86-21-6443-5550传真+86-21-6443-5868紧急联系+86-21-3414-1011电子邮件推荐用途及限制用途RTV橡胶 导热RTV橡胶(粘结和密封)推荐用途仅限于一般工业用限制用途2013/09/12最初编制日期2018/05/15修订日期2016/04/18旧版日期第2部分 危险性概述紧急情况概述无已知的特定危害。
可能导致瞬时的刺激。
危险类别未被分类。
标签要素无。
象形图警示词无。
危险性说明无。
不适用。
物理和化学危险预计较低的食入危害。
直接接触可引起眼部暂时刺激。
健康危害不适用。
环境危害该产品与水、湿气或潮湿的空气接触,会产生以下物质:甲醇其它危害其他危害无。
第3部分 成分/组成信息混合物物质/混合物含量含量(%)(%)CAS CAS 号号化学名称1344-28-120 - 30氧化铝Aluminum oxide2768-02-71 - 3烷氧基硅烷Alkoxysilane 13463-67-70.3 - 1钛氧化物Titanium oxide 分解产物CAS CAS 号号含量含量(%)(%)甲醇67-56-1第4部分 急救措施移至空气新鲜处。
如果症状持续或恶化,联络医生。
吸入用肥皂水冲洗皮肤。
如果刺激症状持续或加重,应就医。
皮肤接触立即用大量水冲洗至少15分钟。
戴隐形眼镜时如果方便取出,请取出镜片。
信越-UL-QMFZ2-E48923(UL认定)修改后
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KE-4217RD 1.5HB40105105105———1.9HB40200105200———3.0HB40200105200050 Silicone (SI), furnished as liquid, paste.KE-1831BK0.75V-030105105105———1.5V-030105105105———3.0V-020105105105040 KE-1834GY0.75V-1——105105105———KE-1837NC 1.6V-1——105105105———3.2V-1——105105105———KE-3480GY0.75V-100105105105———1.5V-100105105105———3.0V-1001051051050210.75V-110105105105———KE-3490BK,GY1.5V-10—105105105———3.0V-0001051051050510.75V-100105105105———KE-3494BK,GY1.5V-00—105105105———3.0V-000105105105052 KE-3497T WT0.75HB——105105105———KE-3497W WT0.75HB——105105105———0.75V-000105105105———KE-402WT,GY1.5V-000105105105———3.0V-0001051051050410.75V-000105105105———KE-40RTV WT,GY1.5V-000105105105———3.0V-000105105105050 KE45&ALL 1.5HB30105105105———2.6HB30105105105———3.3HB30105105105060KE-4800WT0.75V-104105105105———0.75V-004105105105———BK,RD,NCALL 1.5V-004105105105———3.0V-004105105105040 KE-4800L WT0.75V-104105105105———0.75V-004105105105———BK,RD,NCALL 1.5V-004105105105———3.0V-004105105105040 KE-4890ALL0.75V-004105105105———1.5V-003105105105———3.0V-004105105105040 KE-4900G GY0.75V-0——105105105———1.5V-0——105105105———3.0V-0——105105105———KE-490RTV ALL0.75V-100105105105———1.5V-100105105105———2.8V-000105105105031 Sealant-N ALL 1.5HB——105105105———ALL 2.7HB——105105105———ALL 3.6HB——105105105———Silicone (SI), furnished as pellets.KE-1281NC0.8V-1——105105105———NC 1.6V-1——105105105———NC 3.2V-1——105105105———KE-66SE-S NC0.77V-1——105105105———NC0.91V-1——105105105———NC 3.2V-0——105105105———TC-xxxTHB BN0.35V-043150150150030BN 3.0V-012150150150030BN 5.0V-012150150150030TC-xxxTL GY0.35V-044150150150040GY 3.0V-023150150150040GY 5.0V-012150150150040 Silicone (SI), furnished as sheets, tape, vulcanized parts.TC-(xx)GY0.15V-100105105105———0.38V-100105105105030 TC-(xx)A GY0.15V-040150150150———0.38V-000150150150———0.75V-000150150150———1.5V-010150150150030V-0——150150150———TC-(xx)A-AV NC0.20-0.29V-1——150150150———0.30-0.45TC-(xx)AG GY0.15V-030150150150———0.38V-100150150150———0.75V-120150150150———1.5V-110150150150020 TC-(xx)AG-AV NC0.20V-0——150150150———0.30V-0——150150150———0.45V-1——150150150———0.75V-1——150150150———TC-(xx)BG ALL0.15V-000150150150———0.38V-00—150150150———0.75V-00—150150150———1.6V-000150150150030 TC-(xx)BG-AV NC0.20V-040150150150———0.30V-030150150150———0.45V-020*********———0.75V-020150150150010 TC-(xx)C ALL0.28V-020*********———1.5V-010*********———3.0V-010150150150030TC-(xx)CG ALL0.15V-000150150150———0.38V-00—150150150———0.75V-01—150150150———1.6V-000150150150030 TC-(xx)CG-AV ALL0.15V-040150150150———0.45V-020*********———0.75V-020150150150000 TC-(xx)S ALL0.15V-0——150150150———0.38V-0——150150150———1.8V-0——150150150———TC-(xx)TK GY0.35V-044150150150———0.5V-040150150150———3.1V-0101501501500405.3V-000150150150———TC(xx)TKC*GY0.35V-143150150150———1.0V-021*********———2.9V-0201501501500404.9V-010*********———TC(xx)TKM NC0.35V-1331501501500300.5V-0411501501500301.9V-0311501501500305.0V-010150150150030 X-65-324BK0.47HB——150150150———Silicone (SI), furnished as solid.AD-S BK 1.7V-1——150150150———3.0V-1——150150150———ASR-YS BK0.75V-0——150150150———1.7V-0——150150150———3.0V-0——150150150———Silicone (SI), furnished as three liquid components.KE-1212BN0.75V-000105105105———1.5V-000105105105———3.0V-000105105105001 KE-1212H BN0.75V-100105105105———3.0V-000105105105020 KE-1218BK 1.5V-020*********———3.0V-010190105105030 KE-1800WT 1.5V-100105105105———3.0V-000105105105021 KE-1802BK0.75V-110105105105———1.5V-1——105105105———3.0V-000105105105051 Silicone (SI), furnished as two liquid components.KE-1204-LTV BN0.89V-000105105105———1.5V-000105105105———3.0V-000105105105000 KE-1270RD0.75V-114105105105———1.5V-004105105105———3.0V-003105105105000 KE-1302ALL0.75V-100105105105021 KE-1302BL BK0.75V-100105105105021 KE-1302R RD0.75V-100105105105021 KE-1302W WT0.75V-100105105105021 KE-1353RD 3.0V-100105105105000 KE-1925F BK0.75V-002105105105———1.5V-00—105105105———3.0V-0011051051050410.52HB——105105105———KE-1930NC,BK3.2HB——105105105———KE-1955BK0.20V-0001051051050100.75V-0001051051050101.5V-0001051051050103.0V-000105105105010KE-1978ALL0.75HB——105105105———1.5HB——105105105———3.0HB——105105105———KE1983-BL BL0.75HB——105105105———KE1990-40ALL0.75HB——105105105———KE1990-50ALL0.75HB——105105105———KE1990-60ALL0.75HB——105105105———KE1994GY0.32V-0——105105105———KER-1195NC 5.0HB——105105105———NC13.0HB——105105105———Silicone (SI), furnished as uncured w/one or two catalysts.0.89HB——150150150———KE-1501@BL,NCKE-153@ALL0.75HB——150150150———0.84HB——150150150———KE-1601@BL,NCKE-3602@BK0.71V-0——150150150———KE-3611@BK0.38V-0——150150150———KE-3652@BK 1.5HB——150150150———BK 3.0HB——150150150———KE-3801M@BK0.38V-0——150150150———KE-5(Y)1@NC0.84HB——150150150———3.3HB——150150150———KE-5131@ALL0.75HB——150150150———KE-5140@CL0.75HB——150150150———KE-5141@NC0.75HB——150150150———3.0HB——150150150———KE-5150@CL0.75HB——150150150———KE-5152@ALL0.75HB——150150150———KE-5606@GY0.38V-100150150150———0.75V-000150150150———1.5V-000150150150———3.0V-000150150150041KE-5608@GY0.71V-1——150150150———6.0V-0——150150150———00150150150———KE-5612G@GY0.20V-0,5VB0.38V-0,00150150150———5VA00150150150———0.75V-0,5VA1.5V-0,00150150150———5VA001501501500413.0V-0,5VAKE-5614@GY0.75V-140150150150———1.5V-130150150150———3.0V-020150150150341 KE-5615@WT0.385VB——150150150—————150150150———0.75V-1,5VA1.55VA——150150150———3.05VA——150150150———KE-5616M@GY0.75V-000150150150———1.5V-000150150150041 KE-5620@BK0.38HB——150150150———ALL0.75V-000150150150———1.5V-000150150150———3.0V-000150150150001 KE-5625@BK0.38V-100150150150———0.75V-00—150150150———1.5V-00—150150150———3.0V-0001501501500540.38V-123150150150———KE-5628@RD,WTNC,0.38V-023*********———WTALL0.75V-012150150150———1.5V-003150150150———3.0V-000150150150021 KE-5630@ALL0.82V-0——150150150———3.0V-0——150150150———KE-5631@BK 3.0V-0——150150150———0.30V-0——150150150———KE-6801@DK,BLKE-7018@RD0.47HB——150150150———KE-782@NC0.38HB——150150150———KE-9(x)1@ALL0.75HB——150150150———KE-9410@ALL0.75HB——150150150———KE-9411@ALL0.75HB——150150150———KE-941U ALL 3.0V-0010150150150040 KE-9510@ALL0.75HB——150150150———KE-9511@ALL0.75HB——150150150———KE-951U ALL 3.0V-0010150150150040 KE-9610@ALL0.75HB——150150150———KE-9611@ALL0.75HB——150150150———KE-9710@ALL0.75HB——150150150———KE-971T@ALL0.75HB——150150150———KE-9810@ALL0.75HB——150150150———TSSE-13@ALL0.75HB——150150150———Silicone (SI), conductive, furnished as sheets, tape, vulcanized parts.EC-(xx)BH BK0.15V-0——150150150———0.38V-0——150150150———EC-(xx)BM BK0.15V-0——150150150———0.75V-0——150150150———EC-(xx)TC BK0.15V-0——150150150———0.38V-1——150150150———0.75V-0——150150150———1.5V-1——150150150———Silicone (SI), foam, furnished as Uncured Rubber Compound and one or two catalysts.KE-910F ** (b)RD 3.6HBF——150150150———KE-911F ** (c)RD 3.7HBF——150150150———RD 4.6HBF——150150150———Silicone (SI), foam, furnished as uncured w/one or two catalysts.KE9002F/KE904F@NC 3.0HBF——150150150———KE9002F@NC 3.0HBF——150150150———KE904F@NC 3.0HBF——150150150———Silicone (SI), two component, furnished as sheets, tape, vulcanized parts.0.80V-1——105105105———TC(xx)TKB GY,WT2.8V-0——105105105———Silicone (SI), designated "Silicone Rubber" furnished as sheets, vulcanized parts or tape.TC-xxxEG BL0.15V-003150150150———BL 1.0V-003150150150000 TC-xxxTLC*GY0.35V-004150150150———GY 3.0V-0——150150150040GY 5.0V-003150150150———TC-xxxTX(d)GY0.25V-004150150150———GY 3.0V-0——150150150020GY 5.0V-003150150150———Silicone (SI), designated "SIR" furnished as two liquid components.KE-1990-40ALL0.75HB——105105105———KE-1990-50ALL0.75HB——105105105———KE-1990-60ALL0.75HB——105105105———Silicone Molding Resin (SIR), furnished as molded parts.TC-xxxTHE NC0.50V-014150150150———NC 3.0V-0031501501500—0 TC-xxxTXE NC0.30V-004150150150———NC 5.0V-0031501501500—0 Silicone Molding Resin (SIR), furnished as one liquid component.KE-3424BK 2.0V-1——105105105———BK 3.0V-1——105105105———QMFZ2.E48923 - Plastics - Component。
3000系列-高透明高强度硅橡胶
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-4
+5
8.1
7.1
300
430
-3
+4
6.6
6.3
190
340
(非规格值)
信越有机硅国际贸易(上海)有限公司
地 址:上海市徐汇区肇嘉浜路789号均瑶国际广场29楼 电 话:+86-(0)21-64435550 传 真:+86-(0)21-64435868 联系人:李贤男 邮箱:lixiannan@
标准添加量
1.0
ห้องสมุดไป่ตู้
0.5/2.0
硬度 (硬度计A)
54
52
断裂伸 长 率 (%)
570
730
拉伸强度 Mpa
10.6
9.9
撕裂强度 半圆形kN/m
24
35
反弹性 (%)
61
55
压缩永 久 变 形( 1 8 0℃ ×22 h , % )
8.7
13.4
标注:2mm试片,固化温度 165℃×10min,200℃×4hrs.
信越有机硅国际贸易(上海)有限公司广州分公司
地 址:广州市天河区林和西路9号耀中广场B塔2409-2410室 电 话:+86-(0)20-38310212 传 真:+86-(0)20-38310207 联系人:王万勋 邮箱:wangwanxun@
这 一样本所 列 数 值 均不属于规格值.此外所记载的内容,会 加性 能提高或规格参数改变等理由,恕 不经预告更改. 使用 本产 品 之前,务 必 请贵公司预先进行测试,以便确认是不是适合使用的。此外,这一样本介绍的用途并不保证不抵触任何专利. 我 公司所列 的 有 机 硅系商品,均 为一般性工业用途开发的.如 要 用于医疗或其他特殊用途时,请 贵公司预先进行测试,以 确认该用途的安 全 性之后再 使 用.此 外,请 勿用于人体移植或注入人体. 有 关这一样 本 所 列有机硅系商品的进出口法律责任均应由客户负担.请预先查清每一国家或地区的有关规定. 要转载这 一 资 料时,务必需要我公司的有机硅事业本部的认可.
信越固晶胶说明书
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信越固晶胶说明书MATERIAL SAFETY DATA SHEETSECTION 1. COMPANY IDENTIFICATIONCOMPANY IDENTIFICATIONMANUFACTURER'S NAME: Shin-Etsu Chemical Co., Ltd.ADDRESS: 6-1, 2-Chome, Ohtemachi, Chiyodaku, Tokyo, JAPAN EMERGENCY TELEPHONE NUMBER:02-2715-0055(Shin-Etsu Silicone Taiwan Co., Ltd.)TELEPHONE NUMBER FOR INFORMATION:03-3246-5121(Tokyo, JAPAN)02-2715-0055(Shin-Etsu Silicone T aiwan Co., Ltd) DATA PREPARED : 07/02/2008LAST REVISION : 03/31/2010DATA ISSUED : 03/11/2011ISSUE NO 201103001276BASE NO 2PRODUCT NAME :KER-3000-M2PRODUCT CLASSIFICATION:One Component Silicone Rubber CompoundSECTION 2. COMPOSITIONSINGLE OR MIXTURE:MixtureCHEMICAL IDENTIFICATION:Organopolysiloxane mixtureHAZARDOUS COMPONENT(S)/(CAS No.):No hazardous materials present(See Section 8 of this MSDS for Exposure Guideline)(See Section 11 of this MSDS for Mutagenicity) SECTION 3. HAZARDS IDENTIFICATIONHAZARDS CLASSIFICATION:None (based on IMO)None (based on DOT)FIRE AND EXPLOSION:Not considered flammable, but may burn vigorously if involved in a fire.Contact with acidic, basic or oxidizing materials generates flammable and explosive hydrogen gas.POTENTIAL HEALTH EFFECT:SKIN contact ; May cause slight skin irritation and allergicskin reaction.EYES contact ; May cause slight eyes irritation. INGESTION ; Low-harmfulSECTION 4. FIRST AID MEASURESSKIN contact ; Remove product from skin with dry cloth or towel, and wash exposed area with detergent.EYES contact ; Immediately flush with water for at least15 minutes.INGESTION ; Wash out mouth with water provided person is conscious. Never give anything by mouth to an unconscious person. Call a physicianimmediately.SECTION 5. FIRE FIGHTING MEASURESFLASH POINT(method used):Not applicable(On heating it causes curing.)FLAMMABLE LIMITS:LOWER: Not measured UPPER: Not measuredEXTINGUISHING MEDIA:Foam or carbon dioxideSPECIAL FIRE FIGHTING PROCEDURE:NoneUNUSUAL FIRE AND EXPLOSION HAZARD:NoneSECTION 6. ACCIDENTAL RELEASE MEASURESSTEP TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:Contain the spill or leak.Scrape up with cardboard or rag and place in container,in such a case pay attention to generation of hydrogen gas by contaminants.SECTION 7. HANDLING AND STORAGEPRECAUTION TO BE TAKEN IN HANDLING AND STORING: Keep container closed when not in use.Vent the container properly to eliminate internal pressure.Store in a cool place(Qualitatively -10 to 10 degrees C).Keep away from heat, sparks and flame.Do not lay the container on its side.Avoid contact with eyes and prolonged or repeated skin contact.Avoid contact with acidic, basic or oxidizing materials.Contact lens wearers take appropriate precaution.Keep out of reach of children.* * * * * Information about the emptied container * * * * *Do not re-use this container.Keep away from heat, sparks and flame.Do not puncture or cut this container, and do not weld on or near this container.SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE GUIDELINES:ACGIH TLV-TWA : Not established,OSHA PEL : Not established [Epoxysiloxane]RESPIRATORY PROTECTION(specify type):See SECTION 11 of this MSDS for OTHER INFORMATIONVENTILATION:LOCAL EXHAUST: See SECTION 11 of this MSDS for OTHER INFORMATIONMECHANICAL(general): See SECTION 11 of this MSDS for OTHERINFORMATIONSPECIAL: Not requiredOTHER: Not requiredPROTECTIVE GLOVES:Plastic film or rubber glovesEYE PROTECTION:Safety glassesOTHER PROTECTIVE CLOTHING OR EQUIPMENT:Eyewash equipmentWORK/HYGIENIC PRACTICES:Keep away from heat and flame.Avoid contact with eyes and prolonged or repeated skincontact.Avoid contact with acidic, basic or oxidizing materials. Wash hands after handling.SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT:Not applicableVAPOR PRESSURE:<1mmHg (25 degrees C) [Epoxysiloxane]VAPOR DENSITY(air=1):12.2 [Epoxysiloxane]SPECIFIC GRAVITY:1.15 (25 degrees C)MELTING POINT:Not applicableEVAPORATION RATE:Negligible (Butyl Acetate=1)SOLUBILITY IN WATER:Not solubleAPPEARANCE(color):Milk-white, translucentAPPEARANCE(form):PasteODOR:Slight odorSECTION 10. STABILITY AND REACTIVITY STABILITY:UnstableCONDITION TO AVOID:Contact with acidic, basic or oxidizing materials. INCOMPATIBILITY(material to avoid):Acidic, basic or oxidizing materials.HAZARDOUS DECOMPOSITION OR BY-PRODUCT:Flammable hydrogen gasThermal breakdown of this product during fire or veryhigh heat condition may evolve the following hazardousdecomposition product: Carbon oxides and traces ofincompletely burned carbon compounds. Silicon dioxide.Formaldehyde.HAZARDOUS POLYMERIZATION:May occurCONDITION TO AVOID:Contact with acidic, basic and oxidizing materials. SECTION 11. TOXICOLOGICAL INFORMATIONCORROSIVE(SKIN)[Test by IMO]:No corrosive effect (Rabbit). [Epoxysiloxane]SKIN IRRITATION:Mild irritant with primary irritation index of 0.7[Epoxysiloxane]EYE IRRITATION:EYE-RABBIT : MILDResulted in adverse effects on the conjunctivae.The irritation of the conjunction was reversible within72 hours. [Epoxysiloxane]ACUTE TOXICITY(LD50):No information is available.ACUTE TOXICITY(LC50):No information is available.CHRONIC TOXICITY:No information is available.CARCINOGENICITY:NTP:Not listed, IARC:Not listed, OSHA REGULATED:Not listed MUTAGENICITY:Positive(Bacteria) [Epoxysiloxane]OTHER INFORMATION:This product can generate formaldehyde at approximately 150 degrees C(300'F) and above in the presence of air.Formaldehyde is a skin and respiratory sensitizer, eye andthroat irritant, acute toxicant and potential cancerhazard. So, use adequate ventilation or wear protectiveequipment such as gloves, goggles or protective clothingwhen this product is heated at approximately 150 degrees C(300'F) and above in the presence of air.SECTION 12. ECOLOGICAL INFORMATIONBIODEGRADATION:No information is available.BIOACCUMULATION:No information is available.AQUATIC TOXICITY:No information is available.OTHER INFORMATION:NoneSECTION 13. DISPOSAL CONSIDERATIONSCan be burned in a chemical incinerator equipped with an afterburner and scrubber.Do not dispose the emptied container unlawfully.Observe all federal, state, and local laws.SECTION 14. TRANSPORT INFORMATIONID No.:NoneCLASSIFICATION AND CLASS:NonePACKAGING GROUP:NonePROPER SHIPPING NAME:NoneTECHNICAL SHIPPING NAME:NoneMARINE POLLUTANT:None* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * *ID No.(49CFR 172.101):NoneHAZARD CLASS(49CFR 172.101):NonePACKING GROUP(49CFR 172.101):NonePROPER SHIPPING NAME(49CFR 172.101):NoneTECHNICAL SHIPPING NAME:NoneDOT REPORTABLE QUANTITY(49CFR 172.101, APP.) :HAZARD SUBSTANCE(S) NAME / (CAS No.), CONTENTS AND RQNot applicableSECTION 15. REGULATORY INFORMATIONTOXIC SUBSTANCES CONTROL ACT(TSCA) STATUS:Listed on the TSCA Inventory.* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * SUPERFUND AMENDMENTS AND REAUTHORIZAITION ACT OF 1986(SARA)TITLE III SECTION 313 SUPPLIER NOTIFICATION:This regulation requires submission of annual reports of toxic chemical(s) that appear in section 313 of the emergency planningand community Right-To-Know Act of 1986 and 40 CFR 372.This information must be included in all MSDS's that are copiedand distributed for the material.The toxic chemical(s) contained in this product are:CHEMICAL NAME/(CAS No.) AND CONTENTS** None *** * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * CALIFORNIA PROPOSITION 65:This regulation requires a warning for CaliforniaProposition 65 Chemical(s) under the statute.The California Proposition 65 Chemical(s) contained in this product are:CHEMICAL NAME/(CAS No.) AND CONTENTS** None **SECTION 16. OTHER INFORMATIONFor Industrial Use Only* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * This materials safety data sheet is offered solely for your information, consideration and investigation.The data described in this MSDS consist of data on literature, our acquisitional data and analogical inference by data of similar chemical substance or product.Shin-Etsu Chemical Co., Ltd. provides no warranties, either express or implied, and assumes no responsibility for theaccuracy or completeness of the data contained herein.。
日本信越硅胶资料
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信越电子硅胶:日本信越化学公司作为世界范围内著名的有机硅产品的供应商,拥有近80年的从业经验,其专业开发的产品,卓越的质量,使其拥有业界巨大的市场份额,在亚太地区更是遥遥领先。
信越RTV电子硅胶的特点:1.专业设计:该产品专门根据电子,电器及其他应用需求设计开发,品质恒定。
2.优良电气特性:该产品是最理想的电气及电子产品的绝缘密封材料,即使用于温度及湿度常有变化的场所也能保有稳定的电气特性。
3.耐热、耐寒特性:该产品使用温度范围广泛,适用于-50℃~250℃。
连续使用时从-40℃~180℃,也能保持稳定性能。
4.耐候性:该产品具有优越抗紫外线、臭氧、水分、盐雾、霉菌等特性,既使在户外使用三十年也几乎不变质。
5.抗震性:该产品具有弹性机能,吸收振动及激震,保护电气及电子零件、玻璃等易脆物质。
6.化学性能稳定:本产品和一般有机橡胶比较,抗化学物质及油剂特性特别优越。
同时,有些产品绝不腐蚀金属。
7.产品种类丰富:本产品种类颇多,有耐燃性,有超级耐热性产品,也有除去低分子量有机硅产品。
专业为电子,电器及一般工业设计的硅胶产品,获得多种国际认证,例如:保险商实验室(UL)、美军规范(MIL)等等。
单双组分硅胶的选择特性单组分硅胶双组分硅胶主要用途粘接,密封及涂覆灌封及制模粘接性可粘接各种材料,使用底漆增强粘接性粘接性较低,粘接时需用底漆固化速度取决于环境温度及湿度可通过加热或调整两组分比例改善深部固化不能能固化时副产品丙酮,肟,醇,醋酸等醇(缩合型),无(附加型)操作工艺性无须混合,脱泡作业,只需挤出管装容器,操作简单调整固化剂(缩合型)的种类及用量和加热(附加型)改变操作时间信越电子硅橡胶的典型应用粘接和密封:用于电子零件和机构的粘结与密封,具有耐高低温,抗老化,吸震缓冲,易于维修及卓越的密封防潮特性。
韩国SK物性表
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韩国SK PP B330F
SK PP B330F
原料描述部分
规格级别 嵌段共聚注塑级 外观颜色
该料用途 家庭用品、家电配件、汽车配件、电池箱
备注说明 特性:抗冲击强度
②加工条件
加工条件
③原料技术数据
性能项目 试验条件[状态] 测试方法 测试数据 数据单位 基本性能 熔体流动速率 ASTM D-1238 3.5 g/10min 物理性能 收缩率 SK 1.5-2.0 %
机械性能 断裂伸长率 ASTM D-638 >500 %
IZOD缺口冲击强度 23℃ ASTM D-256 16 kg.cm/cm
表面硬度 ASTM D-785 80 R scale
断裂拉伸强度 ASTM D-638 280 Kg/cm2
IZOD缺口冲击强度 -20℃ ASTM D-256 5 kg.cm/cm
弹性弯曲系数 ASTM D-790 14000 Kg/cm2
热性能 热变形温度 ASTM D-648 98 ℃
维卡软化点 ASTM D-1525 150 ℃
其它性能 加速老化时间 ASTM D-3012 360 hr
流动性 SK 550 mm。
L-HPC中文手册(日本信越Shinetsu)
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LH-21 是主要的测试型号。如果您遇到顶裂的问题,考虑用 LH-11( 参看 14 页 ) 。如果您需要用大量的 L-HPC (多于 25% ),考虑用 LH-B1 (高密度型号)会有好的流动性。
处方
不同 L-HPC 用 L-HPC 成效 没有 L-HPC
银杏叶提取物
20
20
片剂硬度
7.2
喷干乳糖
14
在湿法制粒中, L-HPC 在制软材过程中能起到缓释作用而适合广泛的水分含量。 LH-21 的特色被应用于 此。特别是低溶解性和低吸湿度的活性组分,可以用大量的 L-HPC 来改善崩解性。而在制片过程中用 20%-40% 的 L-HPC 也是为了此目的——如此高的含量,对于稳定性影响不大,而离子性的崩解剂就不同了。 如此应用,片剂崩解成很好的个体颗粒,这样就可以快速、完全溶解。
L-HPC(不溶于水) 摩尔取代度=0.2
L-HPC(干混合此材料可制硬片,与用微晶纤维素制得的相似。在这个应用中, L-HPC 被用作干粘合剂。
4
L-HPC 的原材料是高纯度的木浆。 L-HPC 是在 GMP* 条件下生产的。 我们的生产机构已经接受世界 50 多家客户视察。 * 基于国际药用辅料委员会提出的指标自行建立的 GMP 条件
12
L-HPC 的一大优点是解决顶裂问题,而顶裂问题是制片过程中的典型问题。许多报道指出顶裂是制片过程 中过多的模壁残留物引起的。 L-HPC 在制片过程中可以减少模壁残留物的阻力和脱模阻力。 LH-11 是高纤维型号,也是抗顶裂效果最好的,它的纤维交织在一起有效防止顶裂。 上面的结果是由于 L-HPC 纤维素的交联,和微晶纤维素相比,在 L-HPC 片的分裂处可看到纤维结构,这 样的结构阻止了片剂受各方面的破坏的影响。 L-HPC 的抗顶裂作用 (乙水杨胺片) 采用直接压片法,加入的辅料占片重的 0%-15% 。为测顶裂数量,采用 USP 脆度计测定。旋转 750 次, 统计顶裂片剂的数量。
信越偶联剂
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Silane Coupling AgentsShin-Etsu's silane coupling agents improve the functionality and quality of materials and make it possible to develop many new products.Silane coupling agents are organosilicon compounds that have two different functional groups, including one that reacts with organic materials and one that reacts withinorganic materials. This unique characteristic enables them to bond organic materials to inorganic materials.Shin-Etsu's extensive product line includes silane coupling agents with a wide variety of organic functional groups and chemical reactivities. The organic functional groups include epoxy, amino, ketimino, vinyl, methacryloxy, acryloxy, mercapto, polysulfido, isocyanato, styryl, as well as other organic groups. There are also different hydrolyzable groups available, including chloro, methoxy, and ethoxy. In addition, oligomeric organic functional coupling agents with hydrolyzable alkoxy groups are offered that provide other advantages for materials modifications.Shin-Etsu's silane coupling agents can boost the mechanical strength of compound materials, improve moisture resistance and adhesion, and provide resin modification and surface modification to improve the functionality and quality of a wide range of materials.2Without silane coupling agent treatment of filler With silane coupling agent treatment of filler Electron micrographs of cross-sections of spherical silica with unsaturated polyester resin filler.3I Functions1. Interaction with Inorganic Materials and Metals2. Interaction with Organic MaterialsStructure and FunctionsI StructureSilane coupling agents have two different types of functional groups in each molecule.Product ListI General Properties of Silane Coupling Agents(Not specified values) 4(Not specified values)I PrimersThese primers are silane coupling agents diluted in solvents. Depending upon the substrateand the application, a single silane or a combination of silanes is diluted with one or more solventsto between 1 and 20 % concentration. Silane coupling agents are soluble in most common organic solvents,including toluene, xylene, ethyl acetate, methyl ethyl ketone, acetone, alcohols, and alcohol-water mixtures.Many of the most common applications are in the construction industry where primers are used toimprove the adhesion of coatings, adhesives, and sealants.Main Primers(Not specified values)56Shin-Etsu offers a wide range of products that are used to improve interfacial interactions between materials.For example, Shin-Etsu Silicones also offers low molecular weight alkoxy oligomers that contain organic substituents and hydrolyzable alkoxy groups in the same molecule. These alkoxy oligomers consist entirely of active ingredients, and they can be used as modification feedstocks and reaction diluents. Since they contain almost no silanol groups, they also have very good storage stability. This class of Shin-Etsu products also includes products that impart water and oil repellency to the surface of inorganic substances.Related ProductsI Main Surface Treating Agents(Not specified values)(Not specified values)I Alkoxy Oligomers7I Effectiveness of Silane Coupling Agents with Inorganic MaterialsG Silane coupling agents usually work when their alkoxy groups undergo hydrolysis to formsilanol and react with inorganic materials. With metal, however, mercapto, sulfide, or other functional groups may be effective as well.Applicable ResinsE : Most effective or most common P : Effective/ Popular8How to Prepare SolutionsSilane coupling agents are usually diluted with water to a concentration of approximately 0.1 to 2.0%. With silane coupling agents that have low solubility in water, a combination of 0.1 to 2.0%of acetic acid in water or water-alcohol (acetic acid, water, and alcohol together) is recommended. Acetic acid is used to increase the hydrolysis rate and improve the stability of the silanols. Depending on the resin or on the filler treatment method,silane coupling agents are sometimes not prepared as solutions.ISolubility and Stability at Optimal pHV: Very soluble. 1% silane solution is obtained without adjusting pH of solution.M: Moderately soluble. 1% silane solution is obtained by adjusting pH of solution. This information is provided for comparison only and does not represent product specifications.Preparation Method1. Prepare water solution containing 0.1 to2.0% acetic acid.The concentration of the acetic acid can be reduced if the silane coupling agent has good solubility with water. There is no need to add acetic acid in the case of aminosilanes (except KBM-573 and KBM-575).2. Mix the acetic acid solution thoroughly while dropping the silane coupling agent.The usual concentration of silane coupling agent is between 0.1 and 2.0 %. The mixing should be done as fast as possiblewithout splashing. If the coupling agent is dropped too quickly, it will not disperse adequately in the solution and larger amounts of gel will form.3. After the coupling agent has been added, continue stirring for 30 to 60 minutes.The hydrolysis of the silane is complete when the solution has become nearly transparent.4. Filter the solution if necessary.Filtration is recommended if there are noticeable insoluble materials or suspended solids in the solution. If the silanesolution is to be used continuously, then circulating filtration by using a cartridge with a pore size of at most 0.5 µm is recommended.Solubility with WaterWhen the alkoxysilyl group in silane coupling agents dissolves in water, it forms a silanol group that is not stable and will condense over time to form a gel-like siloxane structure.A silanol group is usually unstable in the presence of water, but it is more stable in weakly acidic solutions. Aminosilanes are an exception because the amino group helps to stabilize the silane in water solutions.The storage stability of the solution can be improved by adjusting the pH to between 4 and 5, by adding alcohol, and by storing the solution below room temperature.9I Organic SolventsSilane coupling agents dissolve in most common organic solvents. Caution is required with alcohol solutions. For example, exchange reactions can occur when ethanol is used with methoxysilanes or when methanol is used with ethoxysilanes.I Stability of Silane SolutionsThe stability of a silane solution varies greatly depending on the solution'spH and the concentration of the silane. The figures below show how the stability of an epoxysilane solution (KBM-403) is affected by changes in the pH and concentration.I Hydrolysis and Condensation BehaviorCondensation Behavior ofAminosilanes in Water SolutionsStorage Stability ofMethacrylsilane and AcrylsilaneHydrolysis Rate of MethacrylsilaneThe figure below shows data on the hydrolysis rates of methacryloxysilanes as a function of the type (methoxy or ethoxy) and number of hydrolyzable groups.When the pH was adjusted with an acetic acid solution, KBM-502 had the fastest hydrolysis rate, followed by KBM-503, KBE-502, and KBE-503.Acryloxysilane (KBM-5103) was found tocondense more slowly than the corresponding methacryloxysilane (KBM-503).Aminopropyltrimethoxysilane (KBM-903) is extremely stable in a water solution.Stability of Epoxysilane Solution vs. ConcentrationStability of Epoxysilane Solution vs. pHMolar ratio , %Molar ratio , %ConditionsSilane:10%Temperature:30°C Time: 4 hrsConditionsAcetic acid 1%(pH =3)Temperature:30°C Time:48 hrsMonomersDimers Oligomers3MonomersDimers OligomersSilane:(CH 3O)3Si-C 3H 6O-CH 2-CH-CH 2OSilane:(CH 3O)3Si-C 3H 6O-CH 2-CH-CH 2O 10080604020Time, hrsInitial0.05% aceticacid solution Room temp.KBM-502KBM-503KBE-502KBE-5035% water solution of KBM-903(pH=11.1)Methacryloxysilane: KBM-503MA: CH 2=CCH 3COO-(CH 2)3 —Acryloxysilane: KBM-5103AA: CH 2=CHCOO-(CH 2)3 —Time, daysTime, daysConditionsSilane2%Acetic acid 0.3%Ethanol 50%Water48%Silane concentration , %32OSi ≡(OSi ≡)2--32OSi ≡(OSi ≡)2--≡ SiOHOSi-(CH 2)3NH 2≡ SiO ≡ SiO≡ SiOSi-(CH 2)3NH 2≡ SiO--------HO2)3NH 2HO HOHOSi-(CH 2)3NH 2≡ SiO(RO)n Si-C 3H 6OC-C =CH 2OCH 3C 10H 22 (internal standard)(CH 3)3-n--=I Surface Treatment of Inorganic Fibers and Metal FoilBefore treating inorganic fibers that will be used in textiles, clean the fibers with heat or warm water.For metal foil, choose a solvent that will provide sufficient wetting.I Change in Performance byTreatment Conditions (Polyester Laminate)The figure below shows how the performance of treated materials varied by the drying conditions. The best results were obtained when the drying was carried out for approximately 5 minutes at 110°C.Treatment of Inorganic Materials10Clean with heat or warm waterWet MethodThe surface of the material can be treated very uniformly and precisely by mixing a slurry of the inorganic material in a dilute solution of the silane coupling agent or by immersing the material directly into the solution.Addition to Organic MaterialsI Effect of Aging on Resin Blends (Polyester Resin)Aged for 24 hrs after blending Made into laminate immediately after blending Untreated11100 - 150°C30 - 60minRTMixer Charging FillerFilter runoffSilane solutionRatio of silane solution to filler: 0.5 - 1.0 wt %solution to filler: 0.5 - 1.0 wt %100 - 150°CFilter runoff1 % acetic acid solutionMixing Addition Mixing Addition Post-mixing Powder/slurryPost-mixing Drying ScreeningFiltration Drying ScreeningAttributes· Uniform treatment is possible.· Low productivity. (A large amount of heat is needed toremove the moisture.)· The silane-containing waste fluid must be treated.Attributes· Uniform treatment is possible.· This method is appropriate for large volume filler manufacturers.· The silane/organic mixed-wasteeffluent must be treated.I Treatment Example 2I Treatment Example 1122436486072Time submersed in boiling water (hr)(kg/mm 2)B e n d i n g s t r e n g t hCompared to the methods previously described for treating the surface of inorganic materials, adding a silane to organic materials is somewhat less effective. Because of itsexcellent process efficiency, however, this method is used widely in industry.Integral BlendingThis method involves the simple blending of the silane coupling agents into the composite formula while the inorganic and organic materials are mixed together.When aminosilanes (such as KBM-602, KBM-603, KBE-603, KBM-903, KBE-903, and KBM-573) are added to resins such asepoxy or phenol, the viscosity may increase or gelation may occur.So the pot life must be considered.Master BatchWith this method, the silane coupling agent is first added to a small amount of the organic resin to form what is referred to as a "master batch," from which the composite is made.In many cases, when a coupling agent is added by integral blending, room temperature aging can allow the coupling agent to migrate to the surface of the inorganic material. As a result, the bending strength may approach that of pretreated glass fiber.12I Applications to Resin CompositesApplicationsSilane coupling agents can greatly improve filler dispersion in resins, as well as increasethe strength, moisture and heat resistance, transparency, and adhesion of the resulting composites. They are especially effective for improving the chemical bonding and polymer compatibility with thermosetting resins. They can also be effective for improving the compatibilityand wetting with thermoplastic resins.Glass Fiber Reinforced Epoxy ResinsOne of the most thoroughly studied applications for silane coupling agents is epoxy resin laminated plate. These composites require outstanding electrical properties and resistance to the heat of soldering. In such cases, the glass fibers are first pretreated in an aqueous silane solution and then dipped in a resin varnish.Coated SandCasting molds are made from fire-resistant sand aggregates and adhesives. The quality of the casting is determined by the strength of the adhesives coated on the surfaces of the sand particles. For shell molding, which uses thermosetting resin binders, silane coupling agents can play an important role in boosting strength and reducing the fragility that is caused by moisture absorption. In most cases, the coupling agents are pre-added directly to the resin.Paints, Adhesives, and SealantsSilane coupling agents are used to improve the adhesion and durability of a wide range of paints and adhesives as well as to improve the dispersion of pigments and fillers.Elastomer TiresSilane coupling agents are also used in elastomers that are made with silica. A common application is for automobile tires. The coupling agents improve the dispersion of silica and boost the strength of the resulting SBR or other rubber.Encapsulating SemiconductorsThe most common use for coupling agents in epoxy molding compounds is as a semiconductor sealing agent, improving the moisture resistance and electrical characteristics of the resulting composites. The coupling agent forms an interfacial bond between the resins and the filler that is stronger and more hydrolytically stable, thereby yielding a more moisture-resistant interface. When an epoxysilane coupling compound is used, the volume resistivity andbending strength are also greatly improved.13I Resin ModificationThe uses of silane coupling agents are not limited to the interfaces of composite materials. Resin modification with silanes can create high performance resins with unique andsuperior characteristics. Typically, resins modified with silanes display improved adhesion to inorganic materials and moisture curable properties at low temperature, as well as superior resistance to weathering, acid, heat, and solvents.Applications include polyolefins for electrical wire coatings, acrylic resins for paints, and modified sealants.The following reactions are possible for resin modification with silane coupling agents.GraftingGrafting is widely used to produce polyolefin-based materials for sealing electrical wires. Polyolefins that incorporate an unsaturated silane coupling agent (e.g., vinyltrimethoxysilane, 3-methacryloxypropyltrimethoxysilane, etc.) have asilyltrimethoxy group grafted to the polyolefin backbone Chemical ReactionsGiven the variety of silane coupling agents that are available bearing different organic functional groups as well as the many different types of organic resins produced, a large number of chemical reactions can be developed. Examples of applications for this type of silane modified resins include modified sealants, where polyoxyalkylene resins bearing a terminal aryl group react with a hydrosilane in the presence of platinum catalyst, and moisture curable urethane resins, where a thermoplastic urethane resin has been modified by an amino silane coupling agent. These and other methods for resin modification are expected to continue to produce many new resins in the future.CopolymerizationCopolymerization of an unsaturated silane monomer along with one or more organic monomers is widely used to modify acrylic resins for paints. This method often uses a silane coupling agent bearing a methacrylic functional group and compatible co-monomers.Containers(1) Please contact Shin-Etsu Chemical Co., Ltd. (Tokyo, Japan) in advance if you wish to purchase KA-1003.(2) 2-liter plastic bottles.(3) 20-liter pails.G These products are also available in drums. Please contact a sales representative for further information. 14s Quality, Storage, and Handlings Safety15s Other Informationhttp://www.silicone.jp/e/silane/Handling PrecautionsThe products described in this catalog should be kept in a dark, dry location that is cooler than room temperature and is not exposed to direct sunlight.Silane coupling agents may deteriorate when in contact with water or moisture, producing byproducts such as hydrogen chloride or methanol. These products should be handled with special care when kept in the open air. After opening, they should be tightly sealed to limit exposure to water or moisture. It is recommended that dry nitrogen be used to replace the air in opened containers.Please contact our Sales Department if you needproducts with especially high purity for use in electronic materials or other applications.Please read the Material Safety Data Sheet (MSDS)before use. MSDS can be obtained from our Sales Department.rmation on Shin-Etsu silanes is available on our Web site. You may obtain information about our products, inquire about purchasing them, request samples, and download catalogs.1.Catalogs of Shin-Etsu's silanes, silylating agents, silane compounds for organic synthesis, and other products are also available. Please contact our Sales Department.2.These products should be handled with adequate ventil-ation to avoid inhalation or contact with their vapor or the vapor of their hydrolytic byproducts. For example, when KA-1003 reacts with water or moisture in the air, it may generate corrosive hydrogen chloride gas, which is harmful to skin and membranes.To avoid contact with skin or membranes, wear rubber gloves, goggles, and other protective gear. If contact occurs, flush the affected area immediately with large amounts of water. When using KA-1003, ventilate the work area well and, if necessary, wear a respirator for protection from acidic gases.If eye contact occurs, flush the eyes immediately with large amounts of water and consult a doctor if necessary. Special and prompt care is required in the case of KA-1003 and aminosilanes.If contact with clothes occurs, flush the exposed clothing with water and then wash the clothes immediately.After using silanes, wash your hands very thoroughly before eating, drinking, or smoking.If silane fluids are spilled, either flush the exposed area with large amounts of water or clean it with rags or sand, which should be promptly disposed of by burning. If large amounts of KA-1003 are spilled, dike to contain spill.Cover with any medium expansion AFFF foam. Clean only under supervision of an expert; do not use water under any circumstances.1.2.3.4.5.6.http://www.silicone.jp/The data and information presented in this catalog may not be relied upon to represent standard values. Shin-Etsu reserves the right to change such data and information, in whole or in part, in this catalog, including product performance standards and specifications without notice.Users are solely responsible for making preliminary tests to determine the suitability of products for their intended use. Statements concerning possible or suggested uses made herein may not be relied upon, or be construed, as a guaranty of no patent infringement.The silicone products described herein have been designed, manufactured and developed solely for general industrial use only; such silicone products are not designed for, intended for use as, or suitable for, medical, surgical or other particular purposes. Users have the sole responsibility and obligation to determine the suitability of the silicone products described herein for any application, to make preliminary tests, and to confirm the safety of such products for their use.Users must never use the silicone products described herein for the purpose of implantation into the human body and/or injection into humans.Users are solely responsible for exporting or importing the silicone products described herein, and complying with all applicable laws, regulations, and rules relating to the use of such products. Shin-Etsu recommends checking each pertinent country's laws, regulations, and rules in advance, when exporting or importing, and before using, the products.Please contact Shin-Etsu before reproducing any part of this catalog.Copyright belongs to Shin-Etsu Chemical Co., Ltd.Silicone Division Sales and Marketing Department 2 < Silanes and Resins >6-1, Ohtemachi 2-chome, Chiyoda-ku, Tokyo, Japan Phone : +81-(0)3-3246-5131 Fax : +81-(0)3-3246-5361Shin-Etsu Silicones of America, Inc.1150 Damar Drive, Akron, OH 44305, U.S.A.Phone : +1-330-630-9860 Fax : +1-330-630-9855Shin-Etsu Silicones Europe B. V .Bolderweg 32, 1332 A V , Almere, The NetherlandsPhone : +31-(0)36-5493170 Fax : +31-(0)36-5326459Shin-Etsu Silicone Taiwan Co., Ltd.Hung Kuo Bldg. 11F-D, No. 167, Tun Hua N. Rd.,Taipei, 10549 Taiwan, R.O.C.Phone : +886-(0)2-2715-0055 Fax : +886-(0)2-2715-0066Shin-Etsu Silicone Korea Co., Ltd.Danam Bldg., 9F, 120, Namdaemunno5(o)-ga,Jung-gu, Seoul 100-704, KoreaPhone : +82-(0)2-775-9691 Fax : +82-(0)2-775-9690Shin-Etsu Singapore Pte. Ltd.4 Shenton Way, #10-03/06, SGX Centre 2, Singapore 068807Phone : +65-6743-7277 Fax : +65-6743-7477Shin-Etsu Silicones (Thailand ) Ltd.7th Floor, Harindhorn Tower, 54 North Sathorn Road,Bangkok 10500, ThailandPhone : +66-(0)2-632-2941 Fax : +66-(0)2-632-2945Shin-Etsu Silicone International Trading (Shanghai ) Co., Ltd.3214 Shanghai Central Plaza, 381 Huaihai Zhong Road, Shanghai, ChinaPhone : +86-(0)21-6391-5111 Fax: +86-(0)21-6391-5296。
硅脂材料安全数据表(英文)
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SHENZHEN XUSHENG3E TECHNOLOGY CO.,LTDMaterial Safety Data SheetMaterial: High insulating silicone grease1. Identification of the substance/preparation and company1.1 Name of substance/preparationCommercial product name: High insulating silicone grease1.2 Use of substance / preparation: Industrial.Auxiliary agent for: electronic, Coating.1.3 Company nameManufacturer/distributor: Bulg 3#, Xifa Industrial Zone (B), Yintian, Xixiang Town, Bao'an District, Shenzhen, China.Information about the Safety Data Sheet: Telephone +86 755 27449733Telefax +86 755 27449633Email info@2. Hazards identification2.1 Classification:R-Phrase DescriptionR3. Composition/information on ingredients3.1 Chemical characterization (preparation):Polydimethylsiloxane + filler(SiO2)4. First-aid measures4.1 General information:In case of accident or if you feel unwell seek medical advice (show label or SDSwhere possible).4.2 After inhalation:Material cannot be inhaled under normal conditions.4.3 After contact with the skin:Wipe off excess material with clothe or paper. Wash with plenty of water or waterand soap. In the event of a visible skin change or other complaints, seek medical advice (show label or SDS where possible).4.4 After contact with the eyes:Rinse immediately with plenty of water. Seek medical advice in case of continuous irritation. 4.5 After swallowing:Give several small portions of water to drink. Do not induce vomiting.5. Fire-fighting measures5.1 Suitable extinguishing media:water spray , extinguishing powder , alcohol-resistant foam , carbon dioxide,sand .5.2 Extinguishing media which must not be used for safety reasons:water jet .5.3 Special exposure hazards arising from the substance or preparation itself, combustionproducts, resulting gases: -5.4 Special protective equipment for fire fighting:Use respiratory protection independent of recirculated air.6. Accidental release measures6.1 Personal precautions:No special measures required.6.2 Environmental precautions:Prevent material from entering sewers or surface waters.6.3 Methods for cleaning up: Scoop up large quantities after dusting surfaces with sand or Fuller'searth to prevent sticking. Sweep or scrape up the spilled material and place in an appropriate chemical waste container. Clean any slippery coating that remains using a detergent / soap solution or another biodegradable cleaner. Apply sand or other inert granular material to improve traction.7. Handling and storage7.1 Handling Precautions for safe handling:No special protective measures required.Precautions against fire and explosion:No special precautions against fire and explosion required.7.2 Storage Conditions for storage rooms and vessels:none knownAdvice for storage of incompatible materials:not applicableFurther information for storage:Keep container tightly closed. Store in a dry and cool place.8. Exposure controls and personal protection equipment8.1 Exposure limitsMaximum airborne concentrations at the workplace: not applicable8.2 Exposure limited and controlled8.2.1 Exposure in the work place limited and controlledGeneral protection and hygiene measures:Observe standard industrial hygiene practices for the handling of chemical substances. Do not eat or drink when handling.Personal protection equipment Respiratory protection:not required .Hand protection:Recommendation: Protective gloves made of butyl rubber . Gloves suitable for up to 60 minutes' use.Eye protection:Recommendation: protective goggles .8.2.2 Exposure to the environment limited and controlled:Prevent material from entering surface waters and soil.8.3 Further information for system design and engineering measures: -9. Physical and chemical properties9.1 General informationPhysical state / form pasteColour translucentOdour odourless9.2 Important information about the protection of health, safety and the environment Method(67/548/EEC):Melting point / melting range:not applicable Boilingpoint / boiling range: not applicableFlash point: not applicableIgnition temperature: > 400 °CLower explosion limit (LEL): not applicableUpper explosion limit (UEL): not applicableDensity: approx. 1.1 g/cm³ at 25 °CWater solubility / miscibility: virtually insolublepH-Value: not applicableViscosity (dynamic): not applicable9.3 Other informationThermal decomposition: > 250 °C10. Stability and reactivity10. Stability and reactivity10.0 General information: If stored and handled in accordance with standard industrial practicesno hazardous reactions are known.10.1 Conditions to avoid:none known10.2 Materials to avoid:none known10.3 Hazardous decomposition products: If stored and handled in accordance with standardindustrial practices and local regulations where applicable: none known . Measurements have shown the formation of small amounts of formaldehyde at temperatures above about 150 °C (302 °F) through oxidation.11. Toxicological information11.0 General information: According to our present state of knowledge no damaging effectexpected when treated in accordance with standard industrial practices and local regulations where applicable.11.1 Toxicological testsSpecific symptoms in animal test:By-product: Low molecular cyclic siloxanes with at least one silicon atom, which carries a methyl and dimethyl group, display oestrogenic properties in animal test.Further information: -11.2 Experience with man: -11.3 Further toxicological information: -12. Ecological information12.1 EcotoxicityAccording to past experience toxicity to fish is improbable.Effects in sewage treatment plants (bacteria toxicity: respiration-/reproduction inhibition):According to current knowledge adverse effects on water purification plants are notexpected.12.2 Mobility-12.3 Persistence and degradabilityBiodegradation / further information: Biologically not degradable.Further information: Insoluble in water.12.4 Bio-accumulation potentialBioaccumulation is not expected to occur.12.5 Other harmful effects-12.6 Additional informationGeneral information: No environmental problems expected if handled and treated in accordance with standard industrial practices and local regulations where applicable.13. Disposal considerations13.1 MaterialRecommendation:Material that cannot be used or chemically reprocessed should be disposed of atan approved facility in accordance with any applicable governmental regulations.13.2 Uncleaned packagingRecommendation:Containers should be completely emptied before recycling as specified in government regulations. Empty containers should be sent to an approved recycling facility.14 Transport information14.1 Land transportRoad:Valuation:Not regulated for transportRailway:Valuation:Not regulated for transport14.2 Inland navigationValuation:Not regulated for transport14.3 Transport by seaValuation:Not regulated for transportMarine Pollutant:no14.4 Air transportValuation:Not regulated for transport14.5 Transport/further information:-15. Regulatory information15.1 Warning Label(EU)R-Phrase DescriptionRS-Phrase DescriptionS15.2 National regulations:16. Other information16.1 MaterialThe above information describes exclusively the safety requirements of the product(s) and is based on our present-day knowledge. It does not represent a guarantee for the properties of the product(s) described in terms of the legal warranty regulations.Properties of the product are to be found in the respective product leaflet.。
信越化学工业硅橡胶
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比重 2.1
粒径 (mμ)
7~15
1.95~2.0
15~22
表面积 (m2/g)
100~300
产品名称
性能
补强 AEROSIL (高强度)
150~240
NIPSIL (疲劳性好)
2.15~2.3
3000
5
Celite
2.7
5000~30000
<5
Minusil
辅料 辅料
ShinEtsu Chemical R&D
16
结构用垫圈 耐候性
电气绝缘性 电线(内部配线、电热器线等) 家电(高压帽)
休闲用 游泳眼镜
透明性
应用
食品用 垫圈 饮料管子
耐蒸汽性
安全性
耐热性、耐寒性
低永久压缩变形
商用机器 按键材料 OA胶辊
耐油性
汽车 油封 各种管子材料等
ShinEtsu Chemical R&D
17
液态硅橡胶注射成型系统
CH3 HC CH2
CH3 O Si O Si O
CH3
表涂
标准
耐低温性
CH3 CH3 O Si O Si O
CH3
CH2 CH2 CF3
耐油、耐溶剂
MQ
VMQ
PVMQ
FVMQ
ShinEtsu Chemical R&D
3
环体的聚合
-催化剂 : 碱 / KOH, (CH3)4NOH, (nC4H9)4POH 酸 / H2SO4, HCl, HNO3
ShinEtsu Chemical R&D
各种不同橡胶的耐热数据
橡胶
天然橡胶 NR 丁苯橡胶 SBR 氯丁橡胶 Chloroprene Rubber 丁腈橡胶 Nitrile Rubber 氨基橡胶 Uretane Rubber 异丁橡胶 Butyl Rubber 丙烯酸橡胶 Acryllic Rubber 氟橡胶 Fluororubber 有机硅橡胶 Silicone Rubber
硅脂材料安全数据表(英文)
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SHENZHEN XUSHENG3E TECHNOLOGY CO.,LTDMaterial Safety Data SheetMaterial: High insulating silicone grease1. Identification of the substance/preparation and company1.1 Name of substance/preparationCommercial product name: High insulating silicone grease1.2 Use of substance / preparation: Industrial.Auxiliary agent for: electronic, Coating.1.3 Company nameManufacturer/distributor: Bulg 3#, Xifa Industrial Zone (B), Yintian, Xixiang Town, Bao'an District, Shenzhen, China.Information about the Safety Data Sheet: Telephone +86 755 27449733Telefax +86 755 27449633Email info@2. Hazards identification2.1 Classification:R-Phrase DescriptionR3. Composition/information on ingredients3.1 Chemical characterization (preparation):Polydimethylsiloxane + filler(SiO2)4. First-aid measures4.1 General information:In case of accident or if you feel unwell seek medical advice (show label or SDSwhere possible).4.2 After inhalation:Material cannot be inhaled under normal conditions.4.3 After contact with the skin:Wipe off excess material with clothe or paper. Wash with plenty of water or waterand soap. In the event of a visible skin change or other complaints, seek medical advice (show label or SDS where possible).4.4 After contact with the eyes:Rinse immediately with plenty of water. Seek medical advice in case of continuous irritation. 4.5 After swallowing:Give several small portions of water to drink. Do not induce vomiting.5. Fire-fighting measures5.1 Suitable extinguishing media:water spray , extinguishing powder , alcohol-resistant foam , carbon dioxide,sand .5.2 Extinguishing media which must not be used for safety reasons:water jet .5.3 Special exposure hazards arising from the substance or preparation itself, combustionproducts, resulting gases: -5.4 Special protective equipment for fire fighting:Use respiratory protection independent of recirculated air.6. Accidental release measures6.1 Personal precautions:No special measures required.6.2 Environmental precautions:Prevent material from entering sewers or surface waters.6.3 Methods for cleaning up: Scoop up large quantities after dusting surfaces with sand or Fuller'searth to prevent sticking. Sweep or scrape up the spilled material and place in an appropriate chemical waste container. Clean any slippery coating that remains using a detergent / soap solution or another biodegradable cleaner. Apply sand or other inert granular material to improve traction.7. Handling and storage7.1 Handling Precautions for safe handling:No special protective measures required.Precautions against fire and explosion:No special precautions against fire and explosion required.7.2 Storage Conditions for storage rooms and vessels:none knownAdvice for storage of incompatible materials:not applicableFurther information for storage:Keep container tightly closed. Store in a dry and cool place.8. Exposure controls and personal protection equipment8.1 Exposure limitsMaximum airborne concentrations at the workplace: not applicable8.2 Exposure limited and controlled8.2.1 Exposure in the work place limited and controlledGeneral protection and hygiene measures:Observe standard industrial hygiene practices for the handling of chemical substances. Do not eat or drink when handling.Personal protection equipment Respiratory protection:not required .Hand protection:Recommendation: Protective gloves made of butyl rubber . Gloves suitable for up to 60 minutes' use.Eye protection:Recommendation: protective goggles .8.2.2 Exposure to the environment limited and controlled:Prevent material from entering surface waters and soil.8.3 Further information for system design and engineering measures: -9. Physical and chemical properties9.1 General informationPhysical state / form pasteColour translucentOdour odourless9.2 Important information about the protection of health, safety and the environment Method(67/548/EEC):Melting point / melting range:not applicable Boilingpoint / boiling range: not applicableFlash point: not applicableIgnition temperature: > 400 °CLower explosion limit (LEL): not applicableUpper explosion limit (UEL): not applicableDensity: approx. 1.1 g/cm³ at 25 °CWater solubility / miscibility: virtually insolublepH-Value: not applicableViscosity (dynamic): not applicable9.3 Other informationThermal decomposition: > 250 °C10. Stability and reactivity10. Stability and reactivity10.0 General information: If stored and handled in accordance with standard industrial practicesno hazardous reactions are known.10.1 Conditions to avoid:none known10.2 Materials to avoid:none known10.3 Hazardous decomposition products: If stored and handled in accordance with standardindustrial practices and local regulations where applicable: none known . Measurements have shown the formation of small amounts of formaldehyde at temperatures above about 150 °C (302 °F) through oxidation.11. Toxicological information11.0 General information: According to our present state of knowledge no damaging effectexpected when treated in accordance with standard industrial practices and local regulations where applicable.11.1 Toxicological testsSpecific symptoms in animal test:By-product: Low molecular cyclic siloxanes with at least one silicon atom, which carries a methyl and dimethyl group, display oestrogenic properties in animal test.Further information: -11.2 Experience with man: -11.3 Further toxicological information: -12. Ecological information12.1 EcotoxicityAccording to past experience toxicity to fish is improbable.Effects in sewage treatment plants (bacteria toxicity: respiration-/reproduction inhibition):According to current knowledge adverse effects on water purification plants are notexpected.12.2 Mobility-12.3 Persistence and degradabilityBiodegradation / further information: Biologically not degradable.Further information: Insoluble in water.12.4 Bio-accumulation potentialBioaccumulation is not expected to occur.12.5 Other harmful effects-12.6 Additional informationGeneral information: No environmental problems expected if handled and treated in accordance with standard industrial practices and local regulations where applicable.13. Disposal considerations13.1 MaterialRecommendation:Material that cannot be used or chemically reprocessed should be disposed of atan approved facility in accordance with any applicable governmental regulations.13.2 Uncleaned packagingRecommendation:Containers should be completely emptied before recycling as specified in government regulations. Empty containers should be sent to an approved recycling facility.14 Transport information14.1 Land transportRoad:Valuation:Not regulated for transportRailway:Valuation:Not regulated for transport14.2 Inland navigationValuation:Not regulated for transport14.3 Transport by seaValuation:Not regulated for transportMarine Pollutant:no14.4 Air transportValuation:Not regulated for transport14.5 Transport/further information:-15. Regulatory information15.1 Warning Label(EU)R-Phrase DescriptionRS-Phrase DescriptionS15.2 National regulations:16. Other information16.1 MaterialThe above information describes exclusively the safety requirements of the product(s) and is based on our present-day knowledge. It does not represent a guarantee for the properties of the product(s) described in terms of the legal warranty regulations.Properties of the product are to be found in the respective product leaflet.。
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T echnical data Rubber CompoundsPerformance Test ResultsContents■Silicone rubberGeneralproperties 2properties 5 Other■Fluorosilicone rubber 6■SEP rubber 7■Curing agentsTypes 8 Suitability by application 8 Standard addition quantity 9■Standard conditions for compression molding 10■Primers 10■Coloring agents 10■Application examples by industry 1121. Silicone rubber: general propertiesMeasurement: in accordance with JIS K 6249 Test pieces: 165°C/10 min (press cure), 200°C/4 h (post cure)✽1 Standard addition quantity is the quantity of curing agent added to 100 parts compound.✽2 Linear shrinkage values differ according to the curing agent used.✽3 Angle piece✽4 Measured values at 150°C/22 h.✽5 The data below linear shrinkage is based on measurements on a product by compression molding at 170°C/10 min (with no post cure).[Unit conversion] tensile strength: 10 kgf/cm2 = 0.98 MPa; tear strength: 1 kgf/cm = 0.98 kN/m; volume resistivity: 1014 Ω·cm = 1 TΩ·cm.(Not specified values)(Not specified values)3Measurement: in accordance with JIS K 6249 Test pieces: 165°C/10 min (press cure), 200°C/4 h (post cure)✽1 Standard addition quantity is the quantity of curing agent added to 100 parts compound.✽2 Linear shrinkage values differ according to the curing agent used.✽3 Test pieces: 120°C/10 min (press cure), 200°C/4 h (post cure)✽4 For addition quantities, refer to Standard Addition Quantity of curing agents on p. 9.✽5 Measured values at 100°C/22 h ✽6 Measured values at 150°C/22 h ✽7 X-93-1609 is a flame retardant.[Unit conversion] tensile strength: 10 kgf/cm 2 = 0.98 MPa; tear strength: 1 kgf/cm = 0.98 kN/m; volume resistivity: 1014 Ω·cm = 1 T Ω·cm.(Not specified values)(Not specified values)4Silicone rubber: General properties (cont.)Measurement: in accordance with JIS K 6249 Test piece: 165°C/10 min (press cure), 200°C/4 h (post cure)✽1 Standard addition quantity is the quantity of curing agent added to 100 parts compound.✽2 Linear shrinkage values differ according to the curing agent used.✽3 Test pieces: 120°C/10 min (press cure), 200°C/4 h (post cure)✽4 Test pieces: 120°C/10 min (press cure), 150°C/1 h + 250°C/24 h (post cure)✽5 Test pieces: 120°C/10 min (press cure), 150°C/1 h (post cure)✽6 Angle piece ✽7 Measured values at 150°C/22 h ✽8 Ω·m ✽9 Measured values at 150°C/70 h ✽10 Measured values at 105°C/70 h[Unit conversion] tensile strength: 10 kgf/cm2 = 0.98 MPa; tear strength: 1 kgf/cm = 0.98 kN/m; volume resistivity: 1014 Ω·cm = 1 TΩ·cm.(Not specified values)(Not specified values)5(Not specified values)(Not specified values)Measurement: in accordance with JIS K 6249 Test pieces: 165°C/10 min (press cure), 200°C/4 h (post cure)✽1 Measured values at 200°C/72 h ✽2 Measured values at 230°C/72 h ✽3 Test pieces: 120°C/10 min (press cure), 200°C/4 h (post cure)✽4 Measured values at 300°C/72 h ✽5 Relevant data is for addition cure (C-25A/B=0.5/2.0)✽6 Data for the product in question was measured based on a pressure-cure product cured at 170°C/10 min (with no post cure).(Not specified values)Measurement: in accordance with JIS K 6249 Test pieces: 165°C/10 min (press cure), 200°C/4 h (post cure)(Not specified values)6Fluorosilicone rubber is highly resistant to high and lowtemperatures and solvents, and has excellent workability. InIRM 903, a standard oil, there is less than 5% swelling(150°C/70 h). Fluorosilicone rubber also has excellent resistanceto silicone fluid. Shin-Etsu’s fluorosilicone rubber productsinclude the FE-201-U Series for general molding (hardness:25-80), and the FE-301-U Series of high strength rubbers(hardness: 40-80). We also produce FE-451-U, a copolymertype that exhibits oil resistance midway between that ofdimethyl silicone rubber and fluorosilicone rubber. Thiscopolymer material has oil resistance while also having superiorcold resistance, and maintains a greater degree of rubberelasticity at low temperatures than typical silicone rubbers.Applications : Rubber parts including diaphragms, check valves,and connectors, specifically in applications requiring oil andsolvent resistance.Measurement: based on JIS K 6249 Test pieces: 165°C/10 min (press cure), 200°C/4 h (post cure)✽1 Measured values at 180°C/22 h ✽2 FE-451-U is produced in response to orders received.(Not specified values) 2. Fluorosilicone rubber7SEP rubber is produced by modifying ethylene propylene rubber (EPDM) with silicone. This improves EPDM’s properties of heat resistance and weather resistance, and low temperature characteristics. These performance characteristics lie between those of EPDM and silicone rubber, but SEP rubber has the additional favorable properties of chlorine resistance and sponge foaming characteristics. In high temperature conditions over 100°C, SEP rubber has higher mechanical strength, in particular tear strength, than EPDM, and is comparable to high-strength silicone rubber. In terms of resistance to steam, hot water, acids and alkalis, SEP rubber is more durable than silicone rubbers. SEP rubbers are available in several grades: general grade (SEP-1711-U), heat-resistant grade (SEP-1721-U), extrusion grade (SEP-1731-U) and flame-resistant grade (SEP-363-U).Applications : Rubber parts for high-temperature applications requiring high strength, including plug boots.3. SEP Rubber (silicone-modified EPDM)Measurement: based on JIS K 6249 Test pieces: 170°C/10 min (press cure), 150°C/2 h (post cure)✽ Measured values at 150°C/22 h● We also offer a range of trial products in grades other than those listed above.(Not specified values)8Shin-Etsu’s silicone rubber compounds typically do notinclude a curing agent. These are called “U-types,” andexpressed such as KE-951-U. With U-type products, choose asuitable curing agent (from C-1A to C-25A/B) in accordancewith the curing method. We also offer curing agents otherthan those listed here. Please contact Shin-Etsu for details. 4. Curing agents✽ Use sponge curing agents as a combination of C-1A with C-3, or C-23 with C-3.9★ Note: Please contact Shin-Etsu separately for information regarding Hot Air Vulcanization (HAV).✽1 In summer (June-September), add curing agents at 0.2-0.4 parts greater than the standard addition quantity;in winter (December-March), add at 0.1-0.3 parts less than the standard addition quantity.✽2 C-4 is volatile, so the rubber compound should be used soon after mixing.✽3 C-8 has qualities nearly identical to C-4, but has the advantage of lower volatility than C-4.Standard addition quantity is the quantity of curing agent added to 100 parts compound.105. Standard conditions for compression molding7. Coloring agents✽1 Curing may be uneven in molded items thicker than 5 mm. Shin-Etsu recommends C-3, C-8, or C-8A for molding items over 5 mm thick.✽2 Molding possible at temperatures as low as 120°C-150°C.By applying the primer in advance, better adhesion will be obtained.6. Primers● We offer other primers in addition to those listed above. Contact our Sales Department for details.✽1 Electrically conductive products such as KE-3711-U✽2 For information about these products, please contact one of the Sales Departments listed on the back cover.11http://www.silicone.jp/C Shin-Etsu 2004.9/2011.9 1 2.B.P. Printed in Japan.Shin-Etsu Silicones Europe B. V.Bolderweg 32, 1332 A V , Almere, The Netherlands Phone : +31-(0)36-5493170 Fax : +31-(0)36-5326459Germany BranchRheingaustrasse 190-196, 65203 Wiesbaden, Germany Phone : +49-(0)611-962-5366 Fax : +49-(0)611-962-9266Shin-Etsu Silicone Taiwan Co., Ltd.Hung Kuo Bldg. 11F-D, No. 167, Tun Hua N. Rd.,Taipei, 10549 Taiwan, R.O.C.Phone : +886-(0)2-2715-0055 Fax : +886-(0)2-2715-0066Shin-Etsu Silicone Korea Co., Ltd.GT Tower 15F, 1317-23, Seocho-Dong, Seocho-Gu, Seoul 137070, KoreaPhone : +82-(0)2-590-2500 Fax : +82-(0)2-590-2501Shin-Etsu Singapore Pte. Ltd.4 Shenton Way, #10-03/06, SGX Centre 2, Singapore 068807Phone : +65-6743-7277 Fax : +65-6743-7477India BranchFlat No. 712, 7F, 24 Ashoka Estate, Barakhamba Road, New Delhi, 110001, IndiaPhone : +91-11-43623081 Fax : +91-11-43623084Shin-Etsu Silicones (Thailand ) Ltd.7th Floor, Harindhorn Tower, 54 North Sathorn Road,Bangkok 10500, ThailandPhone : +66-(0)2-632-2941 Fax : +66-(0)2-632-2945Shin-Etsu Silicone International Trading (Shanghai ) Co., Ltd.29F Junyao International Plaza, No.789,Zhao Jia Bang Road, Shanghai 200032, ChinaPhone : +86-(0)21-6443-5550 Fax : +86-(0)21-6443-5868Guangzhou BranchB-2409, 2410, Shine Plaza, 9 Linhexi Road, Tianhe, Guangzhou, Guangdong 510610, ChinaPhone : +86-(0)20-3831-0212 Fax : +86-(0)20-3831-0207Silicone Division Sales and Marketing Department 3 < HTV Rubbers and LIMS >6-1, Ohtemachi 2-chome, Chiyoda-ku, Tokyo, Japan Phone: +81-(0)3-3246-5151 Fax: +81-(0)3-3246-5362● The data and information presented in this catalog may not be relied upon to represent standard values. Shin-Etsu reserves the right to change such data and information, in whole or in part, in this catalog, including product performance standards and specifications without notice.● Users are solely responsible for making preliminary tests todetermine the suitability of products for their intended use. Statements concerning possible or suggested uses made herein may not be relied upon, or be construed, as a guaranty of no patent infringement.● The silicone products described herein have been designed,manufactured and developed solely for general industrial use only; such silicone products are not designed for, intended for use as, or suitable for, medical, surgical or other particular purposes. Users have the sole responsibility and obligation to determine the suitability of the silicone products described herein for any application, to make preliminary tests, and to confirm the safety of such products for their use.● Users must never use the silicone products described hereinfor the purpose of implantation into the human body and/orinjection into humans.● Users are solely responsible for exporting or importing thesilicone products described herein, and complying with all applicable laws, regulations, and rules relating to the use of such products. Shin-Etsu recommends checking each pertinent country's laws, regulations, and rules in advance, when exporting or importing, and before using the products.● Please contact Shin-Etsu before reproducing any part of thiscatalog.Copyright belongs to Shin-Etsu Chemical Co., Ltd.。