亨斯迈-聚醚胺-产品综述
亨斯迈产品介绍及其颜料改性
▪ L系列，B系列为胺，与酸性物质有一定的中和反应。应避 免与酸类物质共同加入，以避免反应失效。
路漫漫其悠远
▪
谢
谢！
路漫漫其悠远
亨斯迈产品介绍及其颜 料改性
路漫漫其悠远 2020/4/15
大纲 ▪ 公司简介 ▪ 部门及产品简介 ▪ 颜料改性剂介绍 —— SURFONAMINE ® 胺 ▪ 有机颜料分散剂介绍 —— JEFFSPERSE®分散剂 ▪ 润湿剂 —— 非离子型润湿剂及阴离子型润湿剂 ▪ 胺中和剂 —— APMMEA-WB
● >酞菁(举例，美国专利号 6,284,816)
● >蒽醌(举例，美国专利号 6,022,9440)
●
路漫漫其悠远
>碳黑 (举例，美国专利号 6,685,818)
黄色颜料范围
Pigment Type PY 12 PY 13 PY 14 PY 63 PY 83
REPRESENTATIVE DIARYLIDE YELLOW PIGMENTS
PR 22
PR 23
PR 112
PR 170
REPRESENTATIVE MONOAZO PIGMENTS
Monoazo Component o-nitro, p-toluidine o-nitro, p-chloroaniline o-nitro, p-anisidine o-nitro, p-chloroaniline p-nitro, o-chloroaniline 2,4-dinitroaniline 2,5-dichloroaniline
【免费下载】亨斯迈公司生产的表面活性剂
亨斯迈公司 （HUNTSMAN）的 TERICR OF，BIONICR 和 SURFONICR 脂肪酸聚氧 乙烯醚表面活性剂系列在乳化油和合成液配方中，可以同时提供润滑功能和乳化功能 之组合。推荐产品包括：
化学 组成 外观 25°C 色泽
密度 g/cm3
粘度 cps
HLB
浊点°C 10% 水溶液 DBG
亨斯迈公司 （HUNTSMAN）表面活性剂
低泡沫脂肪醇聚氧乙烯醚（Low Foam Fatty Alcohol Ethoxylates）
亨斯迈公司 （HUNTSMAN）的 TERICR 160 和 SURFONICR LF 系列脂肪醇聚
氧乙烯醚表面活性剂可用于金属表面清洗配方中，以提供优异的清洗功能，润滑功能
化学 组成 外观， 25°C 色泽 分子量中间值 浊点°C 水溶液
密度，g/cm3
粘度 cps
TERIC® PE61
EO/PO 嵌段共聚物
清澈液体
无色 2000 17@1%
1.02@20°C
388@20°C
TERIC® PE62
EO/PO 嵌 段共聚物 清澈液体
无色
2500
23@1%
1.03@20°C
1.00
400
9.0
58
SURFONIC® T-10
动物油脂胺 +10EO
清澈或混浊 液体
SURFONIC® POA-17R2 EO/PO 嵌 段共聚物
清澈液体
无色
——
36@10%
1.03@25°C
205@38°C
1.02
700
10.5
66
EMPILAN® AMT11 动物油脂 胺+11EO 清澈液体
亨斯迈用废旧塑料瓶生产聚氨酯原料
第47卷 第2期·62·CHINA RUBBER/PLASTICS TECHNOLOGY AND EQUIPMENT （PLASTICS ）橡塑技术与装备（塑料）(2)山东滨华新材料有限公司碳三碳四综合利用项目山东滨华新材料有限公司碳三碳四综合利用项目位于山东省滨州市北海经济开发区滨州临港高端石化产业园，为国内首套自主研发共氧化法环氧丙烷技术产业化项目，项目采用轻质原料，绿色生产过程，产品面向高增长性新能源和新材料，主要建设60万t/年丙烷脱氢制丙烯装置、80万t/年丁烷异构化装置、30万t/年环氧丙烷（联产78万t/年叔丁醇）装置、15万t/年合成氨装置。
2020年8月5日，该项目公用工程开工。
摘编自“山东滨化”正大聚氨酯端氨基聚醚技术工艺装备国内领先Zhengda polyurethane amino-terminated polyether technologyand equipment are in a leading position in China2020年12月18日，中国聚氨酯工业协会组织专家在淄博对淄博正大聚氨酯有限公司完成的“临氢催化胺化法合成端氨基聚醚(聚醚胺)关键技术”项目进行了科技成果鉴定。
山东大学冯圣玉教授任主任委员的鉴定委员会认为，该项目工艺技术拥有自主知识产权，填补国内空白，工艺装备水平居国内领先，产品质量达国际先进水平。
正大聚氨酯开发的“临氢催化胺化法合成端氨基聚醚(聚醚胺)关键技术”项目以聚醚多元醇、液氨、氢气为原料，采用临氢催化胺化法合成端氨基聚醚(聚醚胺)的关键技术，生产高品质端氨基聚醚(聚醚胺)，开发了新型催化剂和桨叶设备，催化剂使用寿命长，性能稳定；同时降低了反应温度和压力，副反应少，合成转化率高。
据了解，正大聚氨酯采用临氢催化胺化法开发了不同分子量的端氨基聚醚(聚醚胺)合成技术，并实现了产业化，填补了国内空白，打破了国外垄断，目前主导产品市场占有率国内第一。
聚醚胺——高性能环氧树脂固化剂
聚醚胺——高性能环氧树脂固化剂什么是聚醚胺聚醚胺是一类主链为聚醚结构，末端活性官能团为胺基的聚合物。
通过聚乙二醇、聚丙二醇或者乙二醇/丙二醇共聚物在高温高压下氨化得到的。
通过选择不同的聚氧化烷基结构，可调节聚醚胺的反应活性、韧性、粘度以及亲水性等一系列性能，而胺基提供给聚醚胺与多种化合物反应的可能性。
其特殊的分子结构赋予了聚醚胺优异的综合性能，目前商业化的聚醚胺包括单官能、双官能、三官能，分子量从230到5000的一系列产品。
聚醚胺合成工艺聚醚胺的合成工艺包括间歇法和连续法两种工艺，Huntsman采用的生产工艺为连续的固定床工艺，利用负载在载体上的金属催化剂，其生产设备和工艺先进，催化剂效率高，因此产品转化率高，副反应少，生产成本低而且性能稳定，但是设备投资巨大。
相比于连续式生产，间歇式工艺设备投资小，可以方便的切换不同产品种类，但是生产效率较低，成本较高，同时产品质量与连续法相比也存在一定差距。
聚醚胺应用聚醚胺在聚脲喷涂、大型复合材料制成以及环氧树脂固化剂和汽车汽油清净剂等众多领域得到了广泛应用。
高性能复合材料：聚醚胺可以作为环氧树脂的高性能固化剂，用于生产高强度、高韧性的复合材料。
聚脲材料：聚醚胺为聚脲材料的关键组分，聚脲弹性体独特的防水、透气双重功能，在高铁桥梁、跨海大桥、水坝、大型场馆等混凝土结构的防水体系有很多应用实例，并表现出了优异的性能。
聚脲是异氰酸酯组份和氨基化合物组份反应生成的一种弹性体物质，也叫聚脲弹性体。
聚脲分为纯聚脲和半聚脲，性能不同，聚脲最基本的特性是防腐，防水，耐磨，抗冲击，抗老化性能优越。
可能很多小伙伴对聚脲材料不是太了解，老编特意找了一则关于聚脲材料与普通铁板防水性能比较的视频，一起来学习一下吧涂料：具有较低的粘度，应用于环氧地坪或者防腐涂料时，可以减少溶剂用量，降低体系粘度。
胶黏剂：作为环氧树脂固化剂，完全固化后具有极佳的韧性和耐疲劳性能，在胶黏剂和结构胶中应用广泛。
亨斯迈TPU介绍
IROGRAN 阻燃级TPU具有以下特点：◆IROGRAN阻燃TPU：不含卤素，不含重金属，不含邻苯二甲酸盐◆IROGRAN阻燃TPU可以达到： UL94VO◆IROGRAN阻燃可以满足以下标准：◇FMVSS302◇DIN EN50267-2-1（燃烧气体卤素含量）◇DIN EN 57472-813→DIN EN50267-2-2（燃烧气体的腐蚀性）详细介绍：IROGRAN TPU具有：高耐磨耐候性好抗撕裂强度高高弹性表面粘性低加工性能优异耐微生物侵袭熔体流动性好耐低温耐水性优异高阻燃性（无卤，低烟）耐油雾面所有这些特性都增加了TPU电缆的耐用性和使用寿命。
IROGRAN TPU更是一种环保的产品，IROGRAN不仅可以做到在无卤阻燃，同时也能达到雾面效果，并且硬度可以达到65A，部分产品已取得黄卡，达到厚度1.0-2.2 mm UL 94 V0等级，从而更大的满足客户的需求。
IROGRAN非阻燃级产品也能达到HB等级。
1、P系列产品是HUNTSMAN产品,中性能很高的的一个聚醚TPU产品系列，适用于挤出和注塑应用。
产品优点：高耐磨，高撕裂强度，耐气候性好，抗细菌侵袭，低温流动性好，高生产率，高弹性/高软性，表面粘性低，出色的抗水解性。
典型用途，输送带，电线，电缆，喉管。
目前已有较多产品得到UL0，UL2等产品认证。
* 具体牌号：A65P4324N，A75P4581，A78P4740，A78P4766，A80P4409，A80P4699，A85P4240，A85P4350，A85P4380，A85P4394，A85P4441，A85P4759，A92P4207，A92P4637，A92P4851，A95P4139，A95P4657，A98P4772，D64P4777，D74P4742，D74P4778 * 目前已经应用项目有：目前已经制造的产品有：手表带，手提电话、电脑用电线，数传电缆护套，弱电电缆护套，电缆用接插件，喉管，汽车配件，特殊用途电梯轮等。
亨斯迈公司生产的表面活性剂共6页
亨斯迈公司 （HUNTSMAN ）表面活性剂低泡沫脂肪醇聚氧乙烯醚（Low Foam Fatty Alcohol Ethoxylates ）亨斯迈公司 （HUNTSMAN ）的TERIC R 160和SURFONIC R LF 系列脂肪醇聚氧乙烯醚表面活性剂可用于金属表面清洗配方中，以提供优异的清洗功能，润滑功能和低泡沫特征。
这些表面活性剂也可作为水基系统中的抗泡剂。
乙氧基脂肪醇可以将羧酸系腐蚀抑制剂溶于水中。
这些表面活性剂最适合于全合成和半合成配方。
推荐产品包括：亨斯迈公司 （HUNTSMAN ）的SURFONIC R L4表面活性剂可作为界面润滑剂应亨斯迈公司 （HUNTSMAN ）的TERIC R OF ，BIONIC R 和SURFONIC R 脂肪酸聚氧乙烯醚表面活性剂系列在乳化油和合成液配方中，可以同时提供润滑功能和乳化功能之组合。
推荐产品包括：亨斯迈公司（HUNTSMAN）的TERMUL R，SURFONIC R CO和DEHSCOFIX R CO 蓖麻油聚氧乙烯醚表面活性剂系列可作为乳化剂用于矿物油，植物油和酯类乳化油和半合成液中。
推荐产品包括：亨斯迈公司（HUNTSMAN）的TERIC®PE和SURFONIC®POA 环氧乙烷/环氧丙烷嵌段共聚物表面活性剂系列广泛应用于乳化油，半合成液和全合成液中，以提供优异的组合功能效应，包括润滑，乳化，溶解，增粘，润湿和分散功能等，同时具有低泡沫/消泡沫特征。
推荐产品：亨斯迈公司（HUNTSMAN）的TERIC®，EMPILAN® AMT，SURFONIC®和TERMET®胺聚氧乙烯醚可作为乳化剂用于乳化油和半合成液中，并可以提供腐蚀抑制功能。
推荐产品包括：亨斯迈公司（HUNTSMAN）的TERIC®X和N系列CO烷基酚聚氧乙烯醚表面活性剂是高效能表面活性剂，用于配制乳化油，半合成液和金属清洗剂。
亨斯迈产品
亨斯迈产品–分散剂，润湿剂，中和剂JEFFSPERSE® X3204和JEFFSPERSE®X3503能有效的提高有机颜料和炭黑水性体系中的分散和分散稳定性特殊特性：适用于水性体系不含APEO，不含VOC ，广泛的树脂体系兼容性，降低研磨能耗和粘度，展色性优异应用实例：水性油墨，喷墨，水性涂料，色浆JEFFSPERSE® X3204 分散剂JEFFSPERSE® X3204是一款新型的用于水性油墨，水性涂料和色浆中有机颜料和炭黑的分散剂JEFFSPERS E® X3204聚合型分散剂具有竞争力在分散性及稳定性，适用于有机颜料和碳黑。
尤其适合于分散碳黑。
JEFFSPERSE® X3204聚合型分散剂非常有竞争力在色强和指研表现中。
附加值：JEFFSPERSE® X3204聚合型分散剂具有杰出的流变性能（低粘度和低触变性）。
提供丰富的色彩体系提升高颜添量JEFFSPERSE® X3204聚合型分散剂能够提供给最终涂料的附加值还有高光泽。
JEFFSPERSE® X3503 分散剂JEFFSPERSE® X3503聚合型分散剂具有竞争力在稳定性，适用于宽范围的有机颜料和碳黑中。
JEFFSPERSE® X3503聚合型分散剂非常有竞争力在色强和指研表现中。
附加值：JEFFSPERSE® X3503聚合型分散剂具有杰出的流变性能（低粘度和低触变性）提供丰富的色彩体系提升高的颜添加量JEFFSPERSE® X3503聚合型分散剂能够提供给最终涂料的附加值还有高光泽和低雾影。
HUNTSMAN 润湿剂OT-75 相比于市场上青特OT-75 和德固赛的DO-75，亨斯迈的产品性价比更高，产品批次稳定性也好HUNTSMAN 胺中和剂APMMEA-WB,亨斯迈是专业做胺类产品的化学公司，WB可以完全取代AMP-95，而且性价比高，产品气味低，颜色和稳定性好。
【2019年整理】亨斯迈产品介绍
Corporate
使用特点 L系列，B系列和颜料表面的颜料表面的羟酸、磺酸或其它 羰基或磺酰基衍生物反应。所以有一定的加热及加热时间 的要求。要在偶合或别的加热反应前加入。 L系列为水性颜料改性剂，所以溶剂以水为主。B系列为溶 剂型颜料改型剂，在水中的溶解性没有L系列好，建议以 醇类溶剂溶解后再加入。 L系列，B系列为胺，与酸性物质有一定的中和反应。应避 免与酸类物质共同加入，以避免反应失效。
3,000
17.1
100%
B-100 B-30 Chemical Intermediate
R’--[OCH2CH(CH3)]X-NH2 R’-OCH2CH(CH3)-OCH2CH(CH3)-NH2
1004
<1.0
100%
325
--
100%
Corporate
选用
有多种EO/PO比率和多种HLB值可供选择
Corporate
谢
谢！
Corporate
Corporate
亨斯迈商业范围
部门 聚氨酯 纺织 无机类 功能产品部
先进材料
颜料
粘胶剂，涂料及弹 性体 应用 汽车 配方体系 衣物及家庭纺织品
胺类 碳酸脂 钛白粉 特殊纺织品 基础树脂 表面活性剂 马来酸酐
复合板材产品
鞋材 家具 保温层 TPU
特殊组成
Corporate
产品及市场
功能产品部
市场包括:
* R= H, CH3
以乙氧基（EO），丙氧基（PO）为主链，以单胺封端的结构
聚氧化亚烷基一元胺
Corporate
产品特性 特性
>活性单元胺 >不同的 EO/PO 比率
亨斯曼聚醚胺在复合材料中的应用
Technical BulletinJEFFAMINE® Amines as Curing Agents for EpoxyResins in CompositesComposites are defined as those materials which consist of two phases, a reinforcing phase and a stress transfer phase, or matrix. Fibrous reinforcing phases may be chopped, woven, or continuous. Advanced composites, in which reinforcement is provided by continuous fibers, provide high strength/weight ratios and are increasingly used in commercial applications.In addition to the high strength/weight ratio, advantages of composites can include lower maintenance, improved corrosion resistance, and automated part fabrication. Epoxy resins are the matrix polymers of choice in many of these applications because of their relatively low cost and high performance.Important considerations for matrix resin selection are processing and performance. Several processing techniques are used in composites manufacture. Among them are pultrusion, compression molding, resin transfer molding, and filament winding.Processing criteria include:• Reactivity--the resin system must be slow enough to avoid inconvenient viscosity increase and premature cure, yet it should cure at a reasonable rate when fabrication of the item is complete.• Viscosity--the resin system must be of sufficiently low viscosity to allow adequate fiber wet-out. Performance criteria include:• Strength/Modulus • Toughness • Corrosion resistance• Temperature resistance (T g, HDT)Epoxy resins are the well-suited to many of these applications because of their relatively low cost and high performance. In general epoxy resins may offer:• Good mechanical properties • Low formulation viscosity • Low shrinkage •Good adhesion to the reinforcement •Good chemical resistance.Their processing properties and performance depend, of course, on which specific resin/curing agent combination is used.A variety of curing agents for epoxy resins are available. Anhydrides provide good processing and mechanical properties but elongation is relatively low and the cure is rather slow. Aromatic amines present these problems as well as serious toxicity concerns in some cases. For many applications polyetheramines provide a good balance of processing and performance properties, and the JEFFAMINE amines are therefore finding wider use in composites.JEFFAMINE® Amines in Epoxy Curing Composite ApplicationsFeatures: • Flexible polyether backbone• Low viscosity• Moderatereactivity • Low volatility • Low exothermThe JEFFAMINE polyetheramines have a proven history in composite applications. One key structural charac-teristic is the steric hindrance (and resulting slower cure) provided by the presence of a methyl group on the amine-bearing carbon. As a result, these amines cure epoxy resins more slowly than do other aliphatic amines such as ethyleneamines. Another important structural feature is the flexible polyether backbone, which gives reduced brittleness in the cured resins. Good toughness, impact resistance, elongation, and low-temperature properties result from this flexibility.Formulated viscosities of the JEFFAMINE amines with typical epoxy resins at room temperature are in the 500-1500 cP range, allowing for good wet-out of fibers in processes such as filament winding. The products are virtually colorless as well.Features: • Tough cured resins:Higher elongationsImproved impact resistanceGood low-temperature properties•Good fiber wet-out •Balanced curing properties: Good working timeConvenient cure rates •Lower toxicity concerns •Lower safety concernsSince these amines are higher in molecular weight and lower in vapor pressure than other aliphatic amines, safety concerns are reduced.Molecular weights of the JEFFAMINE amines range from 148 to 5000, polyether backbones are based on ethylene glycol or propylene glycol, and amine functionality is one, two, or three. Products include•D-230, T-403, D-400•EDR-148•D-2000, T-5000.Of most interest for matrix resins are the diamines and triamines with molecular weights in the 200-500 range, the products known as JEFFAMINE D-230, T-403, and D-400 amines. In this product terminology the number gives the approximate molecular weight and the D- and T- denote diamine and triamine, respectively. The JEFFAMINE T-403 and D-230 amines have been the most widely used in composite applications. They are polypropylene glycol-based and are particularly well-suited because of their combination of moderate reactivity and good cured resin properties.Useful epoxy resins for this application include Dow's D.E.R. 383 and Shell's Epon 825 and 826; these have somewhat lower viscosities than the more commonly used resins. As shown in the Table, the working times for these formulations are adequate for most filament winding applications.Other properties are generally suitable as well. Elongation values of 10% or higher, tensile strengths in the 8,000-10,000 psi range, and flexural modulus values of around 400,000 psi or higher are typical. These high elongations lead to exceptional toughness and ductility which gives good damage tolerance, reducing the risk of catastrophic failure that might occur with more brittle systems. Cures with JEFFAMINE amines in general give lower T g values than some other curing agents--with T-403, for example, and a standard liquid bisphenol A resin, the T g is around 92°C (198°F). If a higher T g is required, other amines can be blended with the JEFFAMINE amines (see Table).Other members of the JEFFAMINE curing agent family include the ED- and EDR- series amines, which are poly ethylene glycol-based. The ED-series amines start at 600 molecular weight and have found little use in composites; XTJ-504 (prepared by amination of triethylene glycol diamine) is the lowest molecular weight amine in the series and may be suitable in some cases. This curing agent is more reactive than the amines mentioned earlier, because of its unhindered amine groups. High thermal shock resistance is a key feature of resins cured with this curing agent. The JEFFAMINE D-2000 and T-5000 curing agents, while not useful as sole curing agents for this application, may be included in blends with the other JEFFAMINE amines to increase flexibility and toughness. In some cases phase-separated systems are produced which may provide improved fracture resistance.SummaryThe JEFFAMINE polyetheramines are useful curing agents for composite matrix resins because of their curing characteristics and the cured resin properties they give. Their low viscosity, low volatility, and moderate cure rates make processing easier; the cured resins have good flexibility and toughness because of the amines' flexible polyether backbones. Compared with anhydride curing agents, these amines may give better composite matrices at lower cost.References:Morgan, Kong, Walkup Polymer 1984, 25, 375-386. "Structure-Property Relations of Polyethertriamine-Cured Bisphenol A-Diglycidyl Ether Epoxies"Morgan, Walkup J. Appl. Polymer Sci. 1987, 34, 37-46. "Epoxy Matrices for Filament-Wound Carbon Fiber Composites"。
亨斯迈公司生产的表面活性剂-推荐下载
亨斯迈公司（HUNTSMAN）表面活性剂低泡沫脂肪醇聚氧乙烯醚（Low Foam Fatty Alcohol Ethoxylates）亨斯迈公司（HUNTSMAN）的TERIC R 160和SURFONIC R LF系列脂肪醇聚氧乙烯醚表面活性剂可用于金属表面清洗配方中，以提供优异的清洗功能，润滑功能和低泡沫特征。
这些表面活性剂也可作为水基系统中的抗泡剂。
乙氧基脂肪醇可以将羧酸系腐蚀抑制剂溶于水中。
这些表面活性剂最适合于全合成和半合成配方。
推荐产品包括：TERIC® 168TERIC® 169SURFONIC®LF-17SURFONIC®LF-18SURFONIC®LF-37外观25°C 清澈液体清澈液体清澈液体清澈液体清澈或混浊液体色泽无色无色无色无色琥珀色密度g/cm30.99@20°C 1.00@20°C 1.00@25°C 1.01@ 25°C0.99@ 40°C 粘度cps70@20°C115@20°C96@25°C240@ 25°C96@ 25°C浊点°C1%水溶液3341341717醇聚氧乙烯醚（Alcohol Ethoxylates）亨斯迈公司（HUNTSMAN）的SURFONIC R L4表面活性剂可作为界面润滑剂应用于全合成液配方中。
推荐产品包括：SURFONIC R L4-29X表面活性剂化学组成脂肪醇EO/PO共聚物外观， 25°C白色蜡固体密度g/cm3 1.02粘度， 20°C——熔点，°C37浊点°C 1%水溶液DBG74脂肪酸聚氧乙烯醚 (Fatty Acid Ethoxylates)亨斯迈公司（HUNTSMAN）的TERIC R OF，BIONIC R和SURFONIC R脂肪酸聚氧乙烯醚表面活性剂系列在乳化油和合成液配方中，可以同时提供润滑功能和乳化功能之组合。
亨斯曼聚醚胺D2000
1Technical BulletinCopyright © 1987, 19941020-1194Huntsman CorporationHuntsman Corporation warrants only that its products meet the specifications stated herein. Typical properties, where stated, are to be considered as represen-tative of current production and should not be treated as specifications. While all the information presented in this document is believed to be reliable and to represent the best available data on these products, NO GUARANTEE, WARRANTY, OR REPRESENTATION IS MADE, INTENDED, OR IMPLIED AS TO THE CORRECTNESS OR SUFFICIENCY OF ANY INFORMATION, OR AS TO THE SUITABILITY OF ANY CHEMICAL COMPOUNDS FOR ANY PARTICULAR USE, OR THAT ANY CHEMICAL COMPOUNDS OR USE THEREOF ARE NOT SUBJECT TO A CLAIM BY A THIRD PARTY FOR INFRINGEMENT OF ANY PATENT OR OTHER INTELLECTUAL PROPERTY RIGHT. EACH USER SHOULD CONDUCT A SUFFICIENT INVESTIGATION TO ESTABLISH THE SUITABILITY OF ANY PRODUCT FOR ITS INTENDED USE. Products may be toxic and require special precautions in handling. For all products listed, user should obtain detailed information on toxicity, together with proper shipping, handling, and storage procedures, and comply with all applicable safety and environmental standards.Main Offices: Huntsman Corporation / P.O. Box 27707 / Houston, Texas 77227-7707 / 713/235-6000Technical Services Section: P.O. Box 15730 / Austin, Texas 78761 / 512/459-6543JEFFAMINE ® D-2000 POL YOXYPROPYLENEDIAMINE[CAS 9046-10-0]TYPICAL PHYSICAL PROPERTIES Color, Pt-Co 100Brookfield viscosity, cps, 25°C (77°F)247Specific gravity, 20/20°C 0.9964Density, lb/gal, 20°C 8.3Refractive index, n D 20 1.4514Flash point, PMCC, °C (°F)185 (365)Water, wt. %0.1Total acetylatables, meq/g 1 .05Total amine, meq/g 1.0Primary amine, meq/g 0.97Vapor pressure, mm Hg/°C 0.93/2354.95/254pH, 5% aqueous solution 10.5Equivalent weight with epoxies (“Amine hydrogen equivalent weight,” or AHEW)514AVAILABILITYD-2000 is available in tank cars, tank wagons,55-gallon drums of 440 pounds net weight, and 5-gal-lon cans. Samples are available from any Huntsman Corporation sales office.APPLICATIONSJEFFAMINE D-2000 polyoxypropylenedi-amine undergoes reactions typical of primary amines.Because of its unique structure, D-2000 has found wide use in epoxy systems. In such applications, it is rarely used alone, but rather in conjunction with other curing agents, particularly other JEFFAMINE prod-ucts. The flexibility and toughness of epoxy systems can be enhanced very efficiently through the inclu-sion of D-2000.STRUCTUREH 2N-CH-CH 2[O-CH 2CH]x NH 2CH 3CH 3x = 33.1DESCRIPTIONJEFFAMINE D-2000 polyoxypropylenedi-amine is one member of a family of Huntsman Corporation’s polyamines having as their backbones repeated oxypropylene units. As shown by the above structure, D-2000 is a difunctional primary amine having an average molecular weight of approxi-mately 2000. Its amine groups are located on secondary carbon atoms at the ends of an aliphatic polyether chain.D-2000 is fairly light in color and reasonably low in viscosity. Its vapor pressure is extremely low.D-2000 is completely miscible in a wide variety of solvents. It is, however, only slightly soluble in wa-ter.SALES SPECIFICATIONS AppearanceLight yellow with slight haze Color, Pt-Co100 max.Total acetylatables, meq/g 0.98 min.1.1 max.Primary amine, % of total amine 97 min.Total amine, meq/g 0.95 min.1.05 max.Water, %0.25 max.Again in conjunction with other JEFFAMINE polyamines, D-2000 is used in epoxy adhesives which are characterized by high peel strengths.An intriguing application for D-2000 is in epoxy systems for metal priming via cathodic electrodepo-sition (Eur. Pat. 70-550).Nonepoxy uses for D-2000 include oil recovery chemicals and polyamide fibers. D-2000 salts make good cutting fluids.STORAGE AND HANDLINGMaterials of Construction:At temperatures of 75-100°FTanks Carbon steelLines, valves Carbon steelPumps Carbon steelHeat exchangesurfaces Stainless steelHoses Stainless steel, polyethylene,polypropylene, Teflon Gaskets, packing Asbestos or Teflon; elastomerssuch as neoprene, Buna N, andViton should be avoided Atmosphere Nitrogen or dry airAt temperatures above 100°FTanks Stainless steel or aluminum Lines, valves Stainless steelPumps Stainless steel or Carpenter 20equivalentAtmosphere NitrogenWhile D-2000 may be stored under air at ambi-ent temperatures for extended periods, a nitrogen blanket is suggested for all storage in case of acci-dental high temperatures. It should be noted that pronounced discoloration is likely to occur at tem-peratures above 140°F, whatever the gaseous pad.Clean-out of lines and equipment containing D-2000 is relatively easy. Since it is at least partiallysoluble in water, warm water and steam is all that is required.In the event of spillage of this product, the area should be thoroughly flushed with water. The proper method of disposal of waste material is by incinera-tion with strict observance of all federal, state, and local regulations.SAFETY AND TOXICITYJEFFAMINE D-2000 should be considered haz-ardous, having the potential to cause skin burns and eye irritation. Chemical-type goggles with face shield and impervious gloves must be worn when handling the product. Should accidental contact occur, flush the eyes thoroughly with water for at least 15 min-utes and get immediate medical attention. In case of skin contact, immediately wash the exposed area with soap and plenty of water. If drenched, remove con-taminated clothing under a safety shower. Wash clothing before reuse.JEFFAMINE D-2000 is considered moderately toxic if swallowed or absorbed through the skin. The single oral dose LD50value in rats is 0.58 g/kg and the single dermal LD50value in rabbits is 0.67 g/kg.The Draize score for skin irritation in rabbits is 8.0/8.0 and the product has been determined to be corro-sive to the skin by the DOT 4-hour test. The Draize score for eye irritation in the rabbit is estimated to be 50-80/110.0.In normal operations, the vapor pressure of JEFFAMINE D-2000 is too low to present any sig-nificant exposure concentration. However, supplied air respiratory protection is recommended for clean-ing up large spills or for entry into confined spaces.JEFFAMINE D-2000 was found to be inactive in the Ames Salmonella/microsome plate test for mu-tagenicity.For futher information, request the Material Safety Data Sheet.2。
亨斯曼乳液聚合乳化剂——产品手册
三、非离子表面活性剂
产品
HLB
倾 点。
浊点。
表面张力%mN/m
应用信息
烷基苯酚乙氧基化物
TERIC® N2 surfactant
<0
比较廉价，能在大多数系统中作为一种主体乳化剂， 他的性能使其常作为一种有效的专用乳化剂，尤其推 荐用于纯丙、乙丙、丁苯和苯丙合物的乳液聚合体系。 通常与一些别的阴离子和非离子表面活性剂结合着 使用，以使最终乳液得到性能的平衡。
（NP系列产品）
TERIC® N4 surfactant
<0
TERIC® N5 surfactant
<0
TERIC® N6 surfactant
<0
TERIC® N8 surfactant
<0
30-34
TERIC® N9 surfactant
<0
50-55
TERIC® N10 surfactant
5
液体
28
EMPIMIN® PCA078 surfactant
液体
31
EMPIMIN® PCA130 surfactant
液体
26
EMPIMIN® PCA169 surfactant
液体
30
烷基酚醚硫酸盐
EMPIMIN® 3508 surfactant
液体
壬基酚醚硫酸钠
34
在乳液聚合作为一种多功能乳化剂和 稳定剂，可广泛应用于纯丙、」丙、醋 丙和苯丙体系的优良乳化剂，有相应的 钠盐产品.（替代co436）
DEHSCOFIX® 107 surfactant
液体
45
DEHSCOFIX® 153 surfactant
亨斯迈产品目录--中文
聚氨酯添加剂亨斯迈亨斯迈——功能产品部亚太地区亚太地区手册手册手册（（通用篇通用篇））JEFFCAT®胺类催化剂亨斯迈公司强大和不断发展的独特胺JEFFCAT®催化剂家族为聚氨酯的应用提供了强而有力并飞快发展的广阔空间。
这些催化剂在聚酯类、聚醚类泡沫、涂料、弹性体、高模量聚氨酯塑料中获得广泛应用，正体现了我们领先的技术和在聚氨酯化学品方面历经40年积累的经验和价值。
*最初沸点理论OH值包含多羟基化合物、胺、酸和水等官能团 n.d. 暂无数据‡* 最初沸点◇分解理论OH值包含多羟基化合物、胺、酸和水等官能团 n.d. 暂无数据胺类催化剂对照表DABCO, POLYCAT和 CURITHANE是美国气体化工产品有限公司的注册商标. NIAX®是迈图高新材料集团的注册商标TOYOCAT ®是日本东曹公司(Tosoh Corp) 的注册商标辅助产品JEFFAMINE®Polyetheramines聚醚胺在RIM工艺里,使用JEFFAMINE® 聚醚胺可以提高各种物理特性，如：耐热性，耐磨损性，抗冲击力，撕裂强度，溶解稳定性和动力性疲劳。
在很多标准聚氨酯类泡沫系统中这些类似的特性依然可以看见。
通常使用的材料有JEFFAMINE® D-2000 和JEFFAMINE® T-5000 .由于JEFFAMINE® 聚醚胺可以与异氰酸酯快速反应，并在泡沫中急速产生非催化的热量, 这种现象被称做为thermo-kick.在寒冷低温的环境或者那些热量流失十分严重的地方，如寒冷的衬底，冷模和高填充的体系，这种效应将非常有帮助。
这种伯胺与异氰酸酯高速反应有益于体系增加交联和加快触变性，thermo-kick 在低分子量的二元胺，如JEFFAMINE® D-230 和JEFFAMINE® D-400 最为显著。
同时JEFFAMINE® T-403将提供更好的交联度和更快的触变性，这是因为形成了三官能度和高支化度的结果。
(整理)亨斯迈公司生产的表面活性剂.
亨斯迈公司（HUNTSMAN）表面活性剂低泡沫脂肪醇聚氧乙烯醚（Low Foam Fatty Alcohol Ethoxylates）亨斯迈公司（HUNTSMAN）的TERIC R 160和SURFONIC R LF系列脂肪醇聚氧乙烯醚表面活性剂可用于金属表面清洗配方中，以提供优异的清洗功能，润滑功能和低泡沫特征。
这些表面活性剂也可作为水基系统中的抗泡剂。
乙氧基脂肪醇可以将羧酸系腐蚀抑制剂溶于水中。
这些表面活性剂最适合于全合成和半合成配方。
推荐产品包括：醇聚氧乙烯醚（Alcohol Ethoxylates）亨斯迈公司（HUNTSMAN）的SURFONIC R L4表面活性剂可作为界面润滑剂应用于全合成液配方中。
推荐产品包括：脂肪酸聚氧乙烯醚 (Fatty Acid Ethoxylates)亨斯迈公司（HUNTSMAN）的TERIC R OF，BIONIC R和SURFONIC R脂肪酸聚氧乙烯醚表面活性剂系列在乳化油和合成液配方中，可以同时提供润滑功能和乳化功能之组合。
推荐产品包括：蓖麻油聚氧乙烯醚 (Castor Oil Ethoxylates)亨斯迈公司（HUNTSMAN）的TERMUL R，SURFONIC R CO和DEHSCOFIX R CO 蓖麻油聚氧乙烯醚表面活性剂系列可作为乳化剂用于矿物油，植物油和酯类乳化油和半合成液中。
推荐产品包括：环氧乙烷/环氧丙烷嵌段共聚物 (EO/PO Block Copolymers)亨斯迈公司（HUNTSMAN）的TERIC®PE和SURFONIC®POA 环氧乙烷/环氧丙烷嵌段共聚物表面活性剂系列广泛应用于乳化油，半合成液和全合成液中，以提供优异的组合功能效应，包括润滑，乳化，溶解，增粘，润湿和分散功能等，同时具有低泡沫/消泡沫特征。
推荐产品：脂肪胺聚氧乙烯醚 (Fatty Amine Ethoxylates)亨斯迈公司（HUNTSMAN）的TERIC®，EMPILAN® AMT，SURFONIC®和TERMET®胺聚氧乙烯醚可作为乳化剂用于乳化油和半合成液中，并可以提供腐蚀抑制功能。
亨斯迈公司生产的表面活性剂
表面活性剂HUNTSMAN）亨斯迈公司（低泡沫脂肪醇聚氧乙烯醚（Low Foam Fatty Alcohol Ethoxylates）R R LFSURFONIC系列脂肪醇聚160和亨斯迈公司（HUNTSMAN）的TERIC氧乙烯醚表面活性剂可用于金属表面清洗配方中，以提供优异的清洗功能，润滑功能和低泡沫特征。
这些表面活性剂也可作为水基系统中的抗泡剂。
乙氧基脂肪醇可以将羧酸系腐蚀抑制剂溶于水中。
这些表面活性剂最适合于全合成和半合成配方。
推荐产品包括：Alcohol Ethoxylates）（醇聚氧乙烯醚R L4SURFONIC表面活性剂可作为界面润滑剂应（HUNTSMAN）的亨斯迈公司用于全合成液配方中。
推荐产品包括：R表面活性剂SURFONICL4-29X共聚物EO/PO脂肪醇化学组成白色蜡固体C外观，25°31.02g/cm密度—— C 20°粘度，37C°熔点，74DBG水溶液C 1%°浊点．(Fatty Acid Ethoxylates)脂肪酸聚氧乙烯醚R RR脂肪酸聚氧和OF，BIONIC亨斯迈公司（HUNTSMAN）的TERICSURFONIC乙烯醚表面活性剂系列在乳化油和合成液配方中，可以同时提供润滑功能和乳化功能之组合。
推荐产品包括：(Castor Oil Ethoxylates)蓖麻油聚氧乙烯醚RRR CODEHSCOFIX COTERMUL（HUNTSMAN）的和，SURFONIC亨斯迈公司蓖麻油聚氧乙烯醚表面活性剂系列可作为乳化剂用于矿物油，植物油和酯类乳化油和半合成液中。
推荐产品包括：3(EO/PO Block Copolymers)/环氧丙烷嵌段共聚物环氧乙烷??亨斯迈公司 （HUNTSMAN ）的TERICPE 和SURFONICPOA 环氧乙烷/环氧丙烷嵌段共聚物表面活性剂系列广泛应用于乳化油，半合成液和全合成液中，以提供优异的组合功能效应，包括润滑，乳化，溶解，增粘，润湿和分散功能等，同时具有低消泡沫特征。
亨斯曼聚醚胺牌号的区别
亨斯曼聚醚胺牌号的区别亨斯曼聚醚胺是一种常用的工业化学品，根据不同的牌号，其性质和用途也会有所不同。
本文将介绍亨斯曼聚醚胺的几种常见牌号及其区别。
【亨斯曼聚醚胺牌号的区别】亨斯曼聚醚胺是一类聚醚胺类化合物，以其优异的性能在各个工业领域得到广泛应用。
根据其特定功能和用途需求，亨斯曼公司开发了多个牌号的聚醚胺产品，下面将介绍其中几个常见的牌号以及它们的区别。
1. 亨斯曼聚醚胺A-1亨斯曼聚醚胺A-1是一种具有高度透明性和优异耐候性的产品。
它通常被用于制作高性能树脂，如可塑剂、涂料和粘合剂。
与其他牌号相比，A-1具有更好的耐化学腐蚀性能，可在恶劣环境下使用。
2. 亨斯曼聚醚胺B-2亨斯曼聚醚胺B-2是一种具有优异的机械强度和热稳定性的聚醚胺。
它在制造工程塑料和纺织品等领域得到广泛应用。
与其他牌号相比，B-2具有更高的耐磨性和耐高温性能，适用于要求耐久性和可靠性的应用。
3. 亨斯曼聚醚胺C-3亨斯曼聚醚胺C-3是一种用于涂料和表面活性剂等领域的聚醚胺。
它具有良好的成膜性和抗水化性能，在各种涂料中有广泛应用。
与其他牌号相比，C-3具有更高的粘度和更好的固化性能，可为涂料提供更佳的抗腐蚀性能。
4. 亨斯曼聚醚胺D-4亨斯曼聚醚胺D-4是一种具有优异弹性和柔韧性的聚醚胺。
它通常被用于制造弹性体、密封材料和医疗用品等。
与其他牌号相比，D-4具有更低的粘度和更好的流动性，可为产品提供更好的加工性能。
以上只是亨斯曼聚醚胺的几个常见牌号的区别，实际上亨斯曼公司还开发了多种其他牌号的产品，以满足不同行业的需求。
每个牌号都有其独特的性能特点，根据具体应用需求选择适合的产品十分重要。
总结：亨斯曼聚醚胺牌号的区别主要体现在其性能差异和适用领域的不同。
不同的牌号具有不同的特性，如耐化学腐蚀性、机械强度、热稳定性等。
根据具体应用需求，选择合适的牌号可以提高产品的性能和可靠性。
亨斯曼作为一家拥有丰富经验和创新能力的化工公司，不断推出新产品来满足市场需求，为各行各业提供更加优质的解决方案。
聚醚胺促进剂
Technical Bulletin ACCELERATOR 399Epoxy Curing Promoter for use with JEFFAMINE ® Curing AgentsAccelerator 399 is a superior epoxy curing promoter designed for use with amine hardeners. The product wasdeveloped specifically for use with JEFFAMINE ® curing agents, but it is compatible with most amines and may be used in most amine-cured epoxy systems.SALES SPECIFICATIONSProperty SpecificationsTest Method* Appearance Clear, pale yellow, slightly viscous liquid ST-30.1free of suspended matter Color, Pt-Co 200 max. ST-30.12 Water, wt%0.40 max.ST-31.53, 6*Methods of Test are available from Huntsman Corporation upon request.ADDITIONAL INFORMATIONRegulatory Information DOT Classification Not regulated for drums Regulated in containers in excess of 119 gal. (Bulk): Combustible liquid, n.o.s. (Piperazine) TDG Classification Not regulated HMIS Code 3-2-0 WHMIS Classification D2B: Irritant B3: Combustible liquid Chemical Control Laws Australia, AICS Listed Canada, DSL Listed Europe, EINECS/ELINCS ListedJapan, METI ListedUnited States, TSCA ListedTypical Physical Properties AHEW (Amine hydrogen equivalent wt.) 145Amine equivalent weight 126 Density, g/cc, 77°C1.089 Flash point, PMCC, °C (°F) 90 (194)pH12.3 Pour Point, °F 5 Viscosity, cSt, 25°C (77°F)810AVAILABILITYAccelerator 399 is available in 55-gallon drums of 500 pounds net weight and in 5-gallon pails. Samples are available through any Huntsman Corporation sales office.USE IN EPOXY FORMULATIONSAccelerator 399 is typically used at levels of 2 to 20 parts per 100 parts of epoxy resin, depending upon which amine curing agents is used and the degree of cure acceleration desired.The accelerator is blended with the curing agent before use. Mixtures with JEFFAMINE hardeners are stable indefinitely, even at temperatures as low as 0°C. It should be emphasized that formulations in which high amounts of Accelerator 399 (10 to 20 phr) are used may blush and form a surface haze on curing under conditions of high humidity (>75% R. H.). Under conditions of normal humidity (~50% R.H.), surface blushing should not appear.EFFECT ON CURE RATES AND PROPERTIES OF CURED PRODUCTSTables I through VIII show properties obtained by curing an epoxy resin with JEFFAMINE D-230, JEFFAMINE D-400, JEFFAMINE T-403, or blends of JEFFAMINE D-400 • JEFFAMINE D-2000 amines, either alone or in combination with Accelerator 399. Tables I, III, V, and VII indicate exothermic and coating properties of a number of formulationsthat the given data be used as a guide to establish general limitations of various reactive epoxy-JEFFAMINE product combinations.All formulations used a liquid bisphenol A-based epoxy resin of equivalent weight 185 to 192. Compensation for the AHEWof the accelerator was not done for these formulations. As with amines, Accelerator 399 is best maintained under dry nitrogen.SAFETY AND TOXICITYAccelerator 399 should be handled with caution as it has the potential to cause severe eye irritation. Chemical-type gogglesmust be worn when handling this product. Should accidental contact with the eyes occur, flush thoroughly with water for atleast 15 minutes and get immediate medical attention.Accelerator 399 is moderately irritating to the skin and protective clothing, including impervious gloves, is recommendedwhen working with the product. This product is rated slightly toxic by swallowing, based on a single oral dose LD50 value inthe rat of 3.3 g/kg. The Draize score for skin irritation in the rabbit is 3.25/8.0 and the Draize score for eye irritation in therabbit is 41.5/110.0.Accelerator 399 did not cause skin sensitization when tested in the guinea pig. However, certain individuals may be sensitiveto some of the components of this product and users should be alert to this possibility.In normal operations, the vapor pressure of this material is sufficiently low that no significant concentrations would be presentin the workplace atmosphere. However, supplied air respiratory protection is recommended for cleaning up large spills or forentry into confined spaces. For further information, request the Material Safety Data Sheet.Table IJEFFAMINE® D-230 AMINE/ACCELERATOR 399 CURING DATA IEXOTHERMIC AND CLEAR COATING PROPERTIESFormulation, pbw A B C DEpoxy resin (EEW 188) 100 100 100 100 JEFFAMINE® D-230 amine 32 32 32 32 Accelerator 399 — 2 5 10Exothermic dataBrookfield viscosity (approx.), cP, 25°C 600 700 700 700Gel time, minutes (200-g mass) 2801 193165 25Peak exothermic temperature, °C 64 92 191 213Time to peak temperatures, minutes 396 244 72 30Coating properties, 6-mil draw downDrying time, hrSet-to-touch 8.9 8.1 7.6 5.0Surface-dry 12.6 11.0 9.9 8.5 Through-dry 16.2 14.9 13.6 12.5Pencil hardnessCure: 24 hr ~25°C B HB HB HB24 hr ~25°C + 1 hr 110°C H H H H48 hr ~25°C H H H H7 days ~25°C H H H HReverse impact, in-lb to failCure: 24 hr ~25°C <4 <4 <4 1624 hr ~25°C + 1 hr 110°C >160 >160 >160 >16048 hr ~25°C <4 <4 <4 <47 days ~25°C <4 <4 <4 6Direct impact, in-lb to failCure: 24 hr ~25°C 14 28 22 3024 hr ~25°C + 1 hr 110°C >160 >160 >160 >16048 hr ~25°C 16 20 20 287 days ~25°C 24 40 36 30Gloss, 60°, 7 days ~25°C 108 110 107 106Table IIJEFFAMINE D-230 AMINE/ACCELERATOR 399 CURING DATA IIPHYSICAL PROPERTIES OF UNFILLED CASTINGSAMBIENT AND ELEVATED TEMPERATURE CURESFormulation, pbw A B C D Epoxy resin (EEW 188) 100 100 100 100 JEFFAMINE® D-230 amine 32 32 32 32 Accelerator 399 — 2 5 10 Properties of cured 1/8-inch castings,cure: 7 days ~25°CShore D hardness, 0-10 sec 89-87 84-82 84-81 83-79 Elongation at break, % 2 2 2 2HDT, °C, 264 psi 46 46 45 47 Izod impact strength, ft-lb/in 0.23 0.28 0.33 0.32 Tensile strength, psi 8,750 9,500 9,900 10,200 Flexural strength, psi l0,800 13,900 13,300 15,500 Flexural modulus, psi 477,000 560,000 530,000 534,000 % wt. gain, 24-hr water boil 2.4 2.5 3.3 2.7 3-hr acetone boil 30.8 32.0 26.4 16.4 Compressive strength1, psi, at yield 12,500 13,400 13,300 13,100at failure 34,000 27,000 27,000 25,900 Properties of cured 1/8-inch castings,cure: 2 hr 80°C + 3 hr 125°CShore D hardness, 0-10 sec 78-75 76-73 76-73 76-73 Elongation at break, % 8 9 7 8HDT, °C, 264 psi 80 76 69 58 Izod impact strength, ft-lb/in 1.1 1.4 1.4 2.3 Tensile strength, psi 9,400 9,900 10,200 9,600 Flexural strength, psi 14,900 16,000 17,200 16,500 Flexural modulus, psi 429,000 467,000 491,000 488,000 % wt. gain, 24-hr water boil 2.4 2.6 3.2 3.2 3-hr acetone boil 6.9 6.2 6.7 10.8 Compressive strength1, psi, at yield — — — 12,200at failure 46,700 47,400 42,000 40,000 11-inch tall cylinders, 1/2-inch diameterTable IIIJEFFAMINE® D-400 AMINE/ACCELERATOR 399 CURING DATA IEXOTHERMIC AND CLEAR COATING PROPERTIESFormulation, pbw A B C D Epoxy resin (EEW 188) 100 100 100 100 JEFFAMINE® D-400 amine 55 55 55 55 Accelerator 399 — 2 5 10 Exothermic dataBrookfield viscosity (approx.), cP, 25°C 600 600 500 600 Gel time, minutes (200-g mass) 48012871136154 Peak exothermic temperature, °C 35 36 67 140 Time to peak temperature, minutes ~700 ~430 182 68 Coating properties, 6-mil draw downDrying time, hrSet-to-touch 15.0 12.0 11.0 9.2 Surface-dry 18.7 14.8 12.5 10.5 Through-dry 24.8 21.0 16.4 14.5 Pencil hardnessCure: 24 hr ~25°C 2 <3B <3B <3B24 hr ~25°C + 1 hr 110°C F F F F48 hr ~25°C 2B B B-HB B-HB7 days ~25°C F F F F Reverse impact, in-lb to failCure: 24 hr ~25°C 2>160 >160 >16024 hr ~25°C + 1 hr 110°C >160 >160 >160 >16048 hr ~25°C >160 >160 >160 >1607 days ~25°C 20 140 150 >160 Direct impact, in-lb to failCure: 24 hr ~25°C 2>160 >160 >16024 hr ~25°C + 1 hr 110°C >160 >160 >160 >16048 hr ~25°C >160 >160 >160 >1607 days ~25°C >160 >160 >160 >160 Gloss, 60°, 7 days ~25°C 104 104 105 109 Crosshatch adhesion, %, 7 days ~25°C 100 100 100 100 1No definite gel; time to reach 10,000 cP2Coating too tacky to testTable IVJEFFAMINE® D-400 AMINE/ACCELERATOR 399 CURING DATA IIPHYSICAL PROPERTIES OF UNFILLED CASTINGSAMBIENT AND ELEVATED TEMPERATURE CURESFormulation, pbw A B C D Epoxy resin (EEW 188) 100 100 100 100 JEFFAMINE® D-400 amine 55 55 55 55 Accelerator 399 — 2 5 10 Properties of cured 1/8-inch castings,cure: 7 days 25°CShore D hardness, 0-10 sec 75-71 76-72 79-75 79-74 Elongation at break, % 65 65 53 65 HDT, °C, 264 psi 28 32 34 36 Izod impact strength, ft-lb/in 0.90 0.88 1.0 2.1 Tensile strength, psi 5,200 5,800 6,400 6,150 Flexural strength, psi 8,750 9,500 8,600 8,700 Flexural modulus, psi 310,000 330,000 310,000 286,000 % wt. gain, 24-hr water boil 2.7 2.7 4.4 2.3 3-hr acetone boil 28.1 23.7 22.1 19.7 Compressive strength1, psi, at yield 6,100 7,200 8,500 8,300at failure 34,000 40,000 41,000 44,000 Properties of cured 1/8-inch castings,cure: 2 hr 80°C + 3 hr 125°CShore D hardness, 0-10 sec 80-75 80-77 81-76 79-74 Elongation at break, % 6.5 7.0 6.0 10.0 HDT, °C, 264 psi 43 45 45 38 Izod impact strength, ft-lb/in 0.17 0.15 0.12 0.18 Tensile strength, psi 7,800 7,300 7,300 7,000 Flexural strength, psi 12,900 13,400 13,800 10,500 Flexural modulus, psi 460,000 500,000 460,000 350,000 % wt. gain, 24-hr water boil 2.8 2.7 3.4 0.6 3-hr acetone boil 24.2 24.0 17.4 21.8 Compressive strength1, psi, at yield 8,200 8,400 8,800 8,000at failure 42,000 41,000 47,000 41,000 11-inch tall cylinders, 1/2-inch diameterTable VJEFFAMINE® T-403 AMINE/ACCELERATOR 399 CURING DATA IEXOTHERMIC AND CLEAR COATING PROPERTIESFormulation, pbw A B C DEpoxy resin (EEW 188) 100 100 100 100 JEFFAMINE® T-403 amine 42 42 42 42 Accelerator 399 — 2 5 10 Exothermic dataBrookfield viscosity (approx.), cP, 25°C 1,600 1,500 1,600 1,500Gel time, minutes (200-g mass) 28011601 81 27 Peak exothermic temperature, °C 38 49 163 193Time to peak temperature, minutes 450 274 90 34Coating properties, 6-mil draw downDrying time, hrSet-to-touch 8.6 7.0 5.5 4.9Surface-dry 13.0 9.9 7.1 6.8Through-dry 16.3 13.2 11.7 10.0Pencil hardnessCure: 24 hr ~25°C 2B HB F F24 hr ~25°C + 1 hr 110°C H H H H48 hr ~25°C H H F F7 days ~25°C H H H HReverse impact, in-lb to failCure: 24 hr ~25°C <4 6 6 6 24hr ~25°C + 1 hr 110°C >160 >160 140 >16048 hr ~25°C <4 <4 6 67 days ~25°C 6 6 10 10Direct impact, in-lb to failCure: 24 hr ~25°C 20 34 34 3424 hr ~25°C + 1 hr 110°C 130 140 120 14048 hr ~25°C 26 26 40 547 days ~25°C 30 50 120 >130 Gloss, 60°, 7 days ~25°C 110 109 109 109 Crosshatch adhesion, %, 7 days ~25°C 100 100 100 1001No definite gel; time to reach 10,000 cPTable VIJEFFAMINE® T-403 AMINE/ACCELERATOR 399 CURING DATA IIPHYSICAL PROPERTIES OF UNFILLED CASTINGSAMBIENT AND ELEVATED TEMPERATURE CURESFormulation, pbw A B C DEpoxy resin (EEW 188) 100 100 100 100 JEFFAMINE® T-403 amine 42 42 42 42 Accelerator 399 — 2 5 10Properties of cured 1/8-inch castings,cure: 7 days 25°CShore D hardness, 0-10 sec 73-65 80-77 80-77 82-78 Elongation at break, % 3.0 3.0 4.5 4.5 HDT, °C, 264 psi 44 42 41 47 Izod impact strength, ft-lb/in 0.16 0.20 0.40 0.70 Tensile strength, psi 9,200 9,900 10,000 10,000 Flexural strength, psi 14,400 14,200 15,600 16,400 Flexural modulus, psi 500,000 533,000 536,000 520,000 % wt. gain, 24-hr water boil 2.0 1.9 2.4 2.9 3-hr acetone boil 26.3 28.4 23.4 16.4 Compressive strength1, psi, at yield 11,500 13,600 13,400 13,500at failure 24,000 16,800 17,000 23,000 Properties of cured 1/8-inch castings,cure: 2 hr 80°C + 3 hr 125°CShore D hardness, 0-10 sec 78-75 85-82 84-81 81-78 Elongation at break, % 7.0 9.0 9.0 7.5 HDT, °C, 264 psi 83 80 72 62 Izod impact strength, ft-lb/in 0.90 0.80 0.90 0.20 Tensile strength, psi 9,500 9,700 9,700 9,700 Flexural strength, psi 15,500 15,700 15,300 16,400 Flexural modulus, psi 437,000 450,000 453,000 480,000 % wt. gain, 24-hr water boil 2.0 0.9 2.6 3.1 3-hr acetone boil 5.6 4.8 5.6 6.7 Compressive strength1, psi, at yield 10,900 10,500 10,300 10,200at failure 44,500 46,000 41,100 40,000 11-inch tall cylinders, 1/2-inch diameterTable VIIJEFFAMINE® D-400 AMINE • JEFFAMINE D-2000 AMINE BLENDS/ACCELERATOR 399CURING DATA IEXOTHERMIC AND CLEAR COATING PROPERTIESFormulation, pbw A B C DEpoxy resin (EEW 188) 100 100 100 100 JEFFAMINE D-400 amine 50 50 50 50JEFFAMINE D-2000 amine 25 25 25 25Accelerator 399 — 2 5 10Exothermic dataBrookfield viscosity (approx.), cP, 25°C 600 500 500 600Gel time, minutes (200-g mass) 1~4442~2622~100Peak exothermic temperature, °C 33 34 36 58Time to peak temperature, minutes ~960 780 316 108Coating properties, 6-mil draw downDrying time, hrSet-to-touch 22.4 17.7 16.8 13.7Surface-dry 26.1 20.6 18.2 15.1Through-dry 37.0 27.1 23.9 22.6Pencil hardnessCure: 24 hr ~25°C 33 3 324 hr ~25°C, + 1 hr 110°C <3B <3B 2B B48 hr ~25°C 3 3<3B <3B7 days ~25°C 3B 3B 2B 2BReverse impact, in-lb to failCure: 24 hr ~25°C 3 33324 hr ~25°C + 1 hr 110°C >160 >160 >160 >160>16048 hr ~25°C 3 3 >1607 days ~25°C >160 >160 >160 >160Direct impact, in-lb to failCure: 24 hr ~25°C 3 3 3324 hr ~25°C + 1 hr 110°C >160 >160 >160 >16048 hr ~25°C 33>160 >1607 days ~25°C >160 >160 >160 >160Gloss, 60°, 7 days ~25°C 106 103 105 102Crosshatch adhesion, %, 7 days ~25°C 100 100 100 1001Reached 2,060 cP in ~480 minutes2No definite gel; time to reach 10,000 cP3Coating too tacky to testTable VIIIJEFFAMINE® D-400 AMINE• JEFFAMINE D-2000 AMINE BLENDS/ACCELERATOR 399 CURING DATA IIPHYSICAL PROPERTIES OF UNFILLED CASTINGSAMBIENT AND ELEVATED TEMPERATURE CURESFormulation, pbw A B C D Epoxy resin (EEW 188) 100 100 100 100 JEFFAMINE D-400 amine 50 50 50 50 JEFFAMINE D-2000 amine 25 25 25 25 Accelerator 399 — 2 5 10 Properties of cured 1/8-inch castings,cure: 7 days 25°C1Shore D hardness, 0-10 sec 68-55 52-35 55-36 55-37 Elongation at break, % 109 70 79 73 Tensile strength, psi 1,200 1,400 1,900 1,700 Tear strength, pli 85 140 150 160 % wt. gain, 24-hr water boil 2.6 2.7 4.0 1.2 3-hr acetone boil 30.3 37.2 32.7 32.7 Compressive strength2, psi, at yield — — — —at failure 39,000 46,000 38,000 40,000 Properties of cured 1/8-inch castings,cure: 2 hr 80°C + 3 hr 125°CShore D hardness, 0-10 sec 62-58 61-49 62-50 56-39 Elongation at break, % 86 86 80 75 HDT, °C, 264 psi ~25 26 23 24 Izod impact strength, ft-lb/in 2.81 0.73 1.13 7.31 Tensile strength, psi 1,700 2,300 2,100 1,200 Flexural strength, psi 970 1,300 1,200 200 Flexural modulus, psi 42,000 47,000 43,000 6,400 % wt. gain, 24-hr water boil 2.6 2.7 3.5 1.2 3-hr acetone boil 33.3 32.0 33.4 35.1 Compressive strength2, psi, at yield — — — —at failure 47,000 47,000 44,000 47,000 1Because of softness, samples were stamped out instead of cut21-inch tall cylinders, 1/2-inch diameterFOR MORE LITERATURE OR INFORMATIONPlease call the nearest Huntsman Corporation office.HUNTSMAN CORPORATION10003 Woodloch Forest Drive The Woodlands, TX 77830 Tel: 281-719-6000Fax: 281-719-6416Research and Development Advanced Technology Center 8600 Gosling RoadThe Woodlands, TX 77381 Tel: 281-719-7780Fax: 281-719-7755 REGIONALCUSTOMER SERVICE REPRESENTATIVESTel: 1-800-852-4957 Huntsman (Singapore) Pte Ltd150 Beach Road#14-05/08 Gateway WestSingapore 189720Tel: +65-6390-0370Fax: +65-6296-3368Huntsman do Brazil doParticipacoes LtdaRua Andre de Leao, 21004762-030 -- Sau Paulo --SPBrazilTel: +55-11-5696-9311/9312Fax: +55-11-5524-9933Huntsman PerformanceChemicalsc/o Huntsman Polyurethanes(China) Ltd452 Wen Jing RoadMinhang Econ. & Tech. Dev. ZoneShanghai 200245P R ChinaTel:+(86-21) 6462 6868Fax: +(86-21) 6462 1234Huntsman (Taiwan) Ltd.No. 19 Industrial Third RoadKuan Yin, Taoyuan CountyTaiwan, R.O.C.Tel: +888-3-4838616Fax: + 886-3-4839324Huntsman Belgium BVAEverslaan, 453078 EverbergBelgiumTel: +32-2-758-92 11Tech. Service: +32-2-758-93-92Fax: +32-2-758-92 12Huntsman Polyurethanes2795 Slough StreetMississauga, Ontario, Canada L4T1 G2Tel: 905-678-9150Fax: 905-678-9350Huntsman de Mexico, S.A. deC.V.Montecito 38 Piso 21 Ofna. 38Col. Napoles.03810 Mexico, D.F.Tel: +5255-5488-2911/2912Tel: +5255-5488-2913Fax: +255-5488-2910Emergency AssistanceFor transportation emergencies only,call CHEMTREC 1-800-424-9300.For all other emergencies,call 409-722-8381, our 24-houremergency number in Port Neches,Texas.th5188-0108Copyright © 2005, 2008 Huntsman Corporation or an affiliate ereof. All rights reserved.JEFFAMINE® is a registered trademark of Huntsman Corporation or an affiliate thereof in one or more, but not all countries.Huntsman Corporation warrants only that its products meet the specifications stated herein. Typical properties, where stated, are to be considered as representative of current production and should not be treated as specifications. While all the information presented in this document is believed to be reliable and to represent the best available data on these products, HUNTSMAN MAKES NO WARRANTY OR GUARANTEE OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING BUT NOT LIMITED TO ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, NON-INFRINGEMENT OF ANY INTELLECTUAL PROPERTY RIGHT OF ANY THIRD PARTY, OR WARRANTIES AS TO QUALITY OR CORRESPONDENCE WITH PRIOR DESCRIPTION OR SAMPLE, AND ANY USER OF PRODUCTS DESCRIBED HEREIN SHOULD CONDUCT A SUFFICIENT INVESTIGATION TO ESTABLISH THE SUITABILITY OF ANY PRODUCT FOR ITS INTENDED USE AND ASSUMES ALL RISK AND LIABILITY WHATSOEVER RESULTING FROM THE USE OF SUCH PRODUCT, WHETHER USED SINGLY OR IN COMBINATION WITH OTHER SUBSTANCES. Product(s) described in this publication may be hazardous and/or toxic and require special precautions in handling. For。
聚醚胺页岩抑制剂的性能评价及现场应用
聚醚胺页岩抑制剂的性能评价及现场应用郭文宇;彭波【摘要】Performances of various polyetheramines as shale inhibitors in drilling fluids were investigated.The results showed that lower average molecular weight,hydrophobic oxypropylene segment,and plentiful amino group of polyetheramines favored the improvement of inhibitive properties.Among the polyetheramines,D230 possessed optimal inhibitive capabilities as well as well fluid loss properties.Its application temperature was able to reach 150 ℃.D230 had not biological toxi city and could mitigate the corrosion of drilling tools.It had been applied successfully in jiangsha 33-8 well.%考察了各种聚醚胺作为钻井液用页岩抑制剂的性能.结果表明,较低平均相对分子质量、亲油环氧丙烷重复结构单元和丰富的氨端基等结构均有利于聚醚胺抑制性能的提高.在所有聚醚胺牌号中,D230具有最优抑制性并兼顾良好的滤失性能.抗150℃高温,无生物毒性,能缓解钻具腐蚀.该聚醚胺已在江沙33-8井中得到成功应用.【期刊名称】《精细石油化工》【年(卷),期】2017(034)003【总页数】5页(P48-52)【关键词】钻井液;聚醚胺;抑制剂;性能;应用【作者】郭文宇;彭波【作者单位】绵阳师范学院化学与化学工程学院,四川绵阳621000;四川仁智油田技术服务股份有限公司,四川绵阳621000【正文语种】中文【中图分类】TE254+.4在水基钻井液中添加3%～20%的KCl，是抑制页岩水化膨胀的传统方法[1]。