叠氮化物

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Acyl Azides
Acyl Azides
Heteroazides and Azide Reagents

Silyl azides Sulfonyl Azides Iodoazide Phosphoryl azides(such as DPPA) tert-butoxycarbonyl azide (Boc azide)
Alkenyl Azides
Alkenyl Azides
Alkyl Azides:Classic Nucleophilic Substitution
Alkyl Azides: The Mitsunobu R: Polar 1,2- and 1,4-Addition Reactions
有机叠氮化合物结构和性质
叠氮化合物的安全性

有毒,高度爆炸性 (NC + NO)/NN≥3 NaN3 剧烈反应(CS2,Br2,HNO3,DMS,Cu,Pb, 等) NaN3与重金属或其盐接触形成重金属叠氮化物-高度 爆炸性(压力、震摇) 重金属叠氮化物会累积。
Synthesis of Organic Azides
Alkyl Azides: C–H Activation
Alkyl Azides:Diazo Transfer( A Simple Synthesis of Alkyl Azides from Amines)
Alkyl Azides:Azide Addition to Palladium Complexes(Synthesis of Allyl Azides)
Click Chemistry
Click Chemistry
Nitrene Chemistry
Nucleophilic Addition to Organoazides: Aza Ylides
Applications of Azides

Use as Protecting Groups Biologically Active Compounds and in Natural Products Synthesis Photoaffinity Labeling
Reactions of Organic Azides

Huisgen Reaction ( Click Chemistry ) Nitrene Chemistry Nucleophilic Addition to Organoazides: Aza Ylides ( Staudinger Reaction ) Other Reactions of Organoazides with Nucleophiles Reactions of Azides with Electrophiles Radical Additions to Organoazides [3,3] Rearrangements and Electrocyclizations of Organoazides Azide Ions as Leaving Groups
Aryl Azides by Diazo Transfer
Aryl Azides

Aryl Azides from Nitrosoarenes Diazotization of Hydrazines

Modification of Triazenes and Related Compounds
Organic Azides
------An Exploding Diversity of a Unique Class of Compounds
CONTENTS

Physicochemical Properties of Organic Azides Synthesis of Organic Azides Reactions of Organic Azides Application of Azides Summary and Outlook

芳基叠氮化物 烯基叠氮化物 烷基叠氮化物 酰基叠氮化物 杂叠氮化物和叠氮试剂
Aryl Azides from Diazonium Compounds
Aryl Azides from SNAr Reactions
Aryl Azides from Organometallic Reagents
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