二000年重大事记

二000年重大事记
一. 完成2000－2001年基金申请
共资助了27个项目，其中有机所12个，外单位17个，资助总额72.6
万。

二．实验室换届工作
根据中国科学院厅局文件关于印发<<中国科学院开放实验室主任、学术委员会主任聘任办法>>的通知和关于2000年开放实验室换届工作的通知，在院、所领导支持下和上一届全体学术委员的配合下，我们顺利地完成了今年的换届工作。

本届实验室主任为麻生明研究员，学术委员会主任为钱长涛研究员。

三. 引进年轻的跨世纪学术带头人
为了建立一支稳定流动的高水平的青年人才队伍, 开放室在人才引进工作上一直采取专家推荐与实验室主动联系的方式积极引进人才。

为了实验室的进一步发展，今年又分别从国外和国内引进2名青年学术带头人张兆国博士和许旭博士。

四.知识创新工程的实施和检查
我室今年在有机所领导的支持下, 知识创新工程的各项工作进展良好。

为了进一步推进知识创新工程全面、深入的开展，中科院高技术局实验室处邢如云处长、李刚同志于9月7日到有机所，调研我们所金属有机化学开放实验室在创新工程中有关科技目标的凝练和改革方案中节点目标的执行情况。

到会的有有机所所长郑崇直、副所长吕龙、科研处处长姚祝军、副处长陈维明、财务处处长傅丽英以及金属有机开放室的陆熙炎院士、戴立信院士等全体学科带头人。

首先实验室主任麻生明研究员汇报了开放实验室知识创新工程执行情况。

接着全体到会人员就实验室的知识创新工作进行了热烈具体的讨论。

所领导肯定了实验
室全体人员的努力，同时表明有机所在知识创新工程中将继续支持开放室的进一步发展。

院领导主要了解了开放室知识创新工作中科技目标的凝练和结构的调整，了解我们开放室创新经费的使用情况，尤其是如何建立合适的分配激励制度，最大限度发挥每个学术带头人的专长和工作积极性。

大家就目前遇到的问题进行充分的交流，达成共识，为下一步知识创新工作的更好完成打下扎实的基础。

10月18日, 侯雪龙副主任又到北京参加中科院召开的“重点实验室试点工作
总结交流会”, 并代表金属开放室在会上作了实验室工作汇报。

会上到会的各进入
知识创新工程的实验室进行了充分交流, 讨论如何做好下一步的知识创新工作。

五. 973项目的启动
经过努力, 由我室麻生明研究员作为首席科学家之一的973项目“创造新物质的分子工程学研究”于今年正式启动, 11月4-5日在上海有机所召开了项目的启动
会议, 年底由我们开放室成员参与的两个子课题的经费已经到位。

我们将努力高质量的完成我们承担的任务。

六.添置大型仪器设备
去年8月份, 由于我们99年全国实验室评估中被评为优秀实验室, 中科院批
文中国科学院将投资400万元建设金属有机化学国家重点实验室, 今年经费已到位。

按照我们在1999年11月份召开的升为国家重点实验室的升级论证会上的计划, 我们将利用这笔经费购置300兆核磁共振仪(DPX300)一台, Weissenberg面探仪一台, 手套箱两套。

目前经过紧张的商谈招标, 就这些仪器与供应商的订购签订了合同, 将于今年年底明年年初到货安装调试。

为实验室升级为国家重点实验室的验收会作好准备。

七.实验室及走廊的装修
在院和所的大力支持下，开放室今年对3号楼4楼实验室进行了全面装修, 将4楼的剩余未装修的15间实验室进行了装修。

这样3号楼3楼4楼已全部装修完毕, 成为金属有机化学实验室的一块实验基地，为实验室的升级验收做好了硬件准备。

金属有机化学开放实验室学术委员会
第四届第一次会议简报
金属有机化学开放实验室学术委员会第四届第一次会议于今年12月4－5日在上海有机所召开。

十六位委员中有两位因另有会议等原因未能到会，会议还邀请了国家基金委化学部有机化学学科杜灿屏主任参加。

会议由学术委员会主任钱长涛教授主持。

首先由有机所郑崇直所长讲话，他代表所领导欢迎各位委员的到来，并感谢全体委员对开放室工作的一贯支持、配合和指导，感谢国家基金委对我们基础学科的大力支持, 他认为开放室现在的成绩是所内外各界人士共同努力的结果，希望今后继续得到各位的指导和支持。

然后钱长涛研究员介绍了本次学委会换届的原因和整个换届过程, 感谢退下来的三位老委员多年来对实验室工作的支持和帮助, 希望本次换届后新老委员继续支持实验室的发展。

这次会议的议程是1) 室主任汇报实验室一年来的工作情况，2) 专家学术报告和交流，3) 部分课题组工作进展汇报，4) 国际学术会议介绍，5)今后工作讨论。

一.实验室主任麻生明研究员汇报了开放室一年来的工作
麻生明主任首先欢迎并感谢各位专家的到会，指出我们实验室的学术委员会会议不仅是各位专家对实验室工作的指导和督促，也是国内金属有机化学界同行的一次聚合和交流，起到团结全国金属有机化学界同行的作用。

会上麻生明主任从实验室一年来如何筹建国家重点实验室和承担中科院知识创新试点工程项目两方面向与会专家汇报了实验室一年来在研究方向、队伍建设与人才培养、运行机制、对外开放等方面所进行的主要工作。

二．专家学术报告和交流
会上由南京大学忻新泉教授作了题目为“室温固相合成化学”的学术报告，在探讨固－固相化学反应机理的同时，着重从原子簇与三阶非线性光学；纳米材料及组装和绿色化学三个方面介绍了室温的固相合成化学。

结合自己课题组的大量工作，讲述了室温固相反应的发生及特点。

三. 课题组工作进展汇报和讨论
这次会上共有五个课题组进行工作汇报，分别由施敏研究员(不对称催化反应)、唐勇研究员(主族元素化合物化学)、张兆国研究员(手性配体的设计与合成)、江焕峰研究员(超临界流体中自由基参与的羰基化反应)、席振峰教授(新一代物质转化途径)到会汇报。

委员们认真听取了他们的进展情况和今后工作设想，并就研究工作中的问题提出了中肯的意见，参加汇报的同志都认为收益非浅。

与会同志认为这不仅仅是课题检查，更是学术交流，对汇报的课题组今后工作帮助很大。

四．国际学术会议介绍和讨论
本次会上共介绍了五个国际会议的内容：
1. 上海有机所的唐勇、张兆国研究员介绍了2000年7月在上海召开的第6届华人有机会议的情况, 此会由有机所主办，世界各地的华人均可参加，会上还颁发了“华人青年有机化学奖”。

本次会议共有五个大会报告、十六个邀请报告和十一个口头报告，会上来自世界各地的青年华人有机化学家进行了充分的交流。

2. 上海有机所的麻生明研究员介绍了今年5月在美国Boston召开的Inductrical Synthesis of Optically Active Compounds和Chiral USA 2000的会议，前一个会议主要讨论了手性的起源、合成方法学，主要是工业上的一些手性合成问题；后一个会议是学术交流性质的。

麻生明还介绍了今年7月在波兰华沙召开的13th International Conference on Organic Synthesis，会上有多位著名有机化学科学家做了精彩的大会报告。

3. 上海有机所的钱长涛研究员介绍了今年7月在上海召开的第19届IUPAC国际金属有机化学会议的情况。

此次会议由上海有机所及金属有机化学开放实验室联合主办。

钱老师先介绍了大会的概况，然后指出此次会议的学术交流重点是：1.烯烃聚合催化剂新发展；2.金属有机催化的不对称合成方法；3.金属有机用于材料科学。

着重介绍了6个大会特邀报告的内容
通过这些介绍和讨论，使到会委员们及时了解国际上金属有机化学研究的热点，掌握目前文献还来不及报道的热门资料，大家一致认为收益非浅。

五．今后工作讨论
会上大家结合目前国内外科学研究的趋势，联系我们实验室的学科发展方向进行了热烈的讨论。

大家认为基础研究必须要深入扎实，要长期坚持才能出大成果。

学科方向应该面对新的形势不断调整，但又必须立足于自己的特长，发扬优势。

各专业之间要真正交叉，必须要有导向性的强强联合型合作，而不是名义上或某些学术名词上的交叉。

总之，本次学委会会议讨论热烈，交流充分，学术气氛浓厚，与会者都认为收获较大。

最后大家一致希望金属开放室在新世纪成为一个一流的国家重点实验室，成为中国的金属有机化学研究基地，为国家解决重大科学问题，发展金属有机化学，在世界金属有机化学研究领域占有一定的地位。

2000～2001资助课题一览表
序号姓名单位题目
2000-01 陆熙炎上海有机所二价钯的不对称催化反应
2000-02 钱长涛上海有机所单原子桥联芴基环戊二烯基稀土配合物的
合成、结构及催化活性研究
2000-03 麻生明上海有机所金属参与的碳-碳键形成反应研究
2000-04 侯雪龙上海有机所氮杂环丙烷化合物的去对称化反应及在有
机合成中的应用
2000-05 沈延昌上海有机所金属有机参与的高选择性合成方法学研究2000-06 陈家碧上海有机所(杂)烯炔配位的金属卡宾和卡拜络合物及其
在合成中应用
2000-07 邓敏智上海有机所手性环丙基硼化物的新反应及其在天然产
物合成中的应用
2000-08 姜标上海有机所手性配体的制备及其在不对称反应中的应用2000-09 施敏上海有机所膦酰胺类手性配体的设计合成及其在不对称
催化反应中的应用
2000-10 丁奎岭上海有机所基于NOB衍生物为配体的金属络合物催化的
不对称反应研究
2000-11 唐勇上海有机所可溶性高聚物负载叶立德的合成及其在有机
合成中的应用
2000-12 廖世键大化所 1、通过金属有机中间体合成纳米尺寸的稀土
金属和稀土氢化物粉末
2、高选择性有机合成反应中双金属催化的协
同效应
2000-13 宋礼成南开大学两类单蝶状铁硫络盐的新反应及其在合成多蝶
状簇合物中的应用研究
2000-14 黄宪浙江大学β-杂原子或金属取代的α、β-不饱和砜及膦酸
脂的合成及其在立体选择合成反应中的应用2000-15 沈琪苏州大学稀土和后过渡金属化合物的合成及催化聚合活
性的研究
2000-16 康北笙中山大学含咪唑基三角架型氮杂化合物的亲金属性研究2000-17 沈之荃浙江大学钐化合物催化极性单体聚合研究
2000-18 张永敏浙江大学稀土金属和过渡金属试剂在有机合成中的应用2000-19 张良辅成都有机所多相不对称催化反应的研究
2000-20 刘汉范北化所纳米金属簇催化酮酸酯及二酮的不对称氢化
其对催化反应的影响
2000-21 王积涛南开大学金属有机试剂在α-氨基酸手性合成中的的应用2000-22 徐善生南开大学单桥及双桥连二环戊二烯基双核过渡金属
化合物的研究
2000-23 周其林南开大学螺旋型手性催化剂的设计合成及其应用
性研究
2000-24 曹卫国上海大学胂叶立德在高选择性合成中的应用――立体
选择性合成γ-丁内酯及γ-丁内酰胺类化合物2000-25 周锡庚复旦大学炔丙基稀土金属有机物的合成、结构及其反应2000-26 席振峰北京大学过渡金属促进的利用二氧化碳作为碳源的新型
碳－碳键形成反应
2000-27 江焕峰广化所过渡金属化合物在超临界二氧化碳介质中的
催化行为研究
2000-28 庞震复旦大学含半活性配位基团的金属有机配合物的合成及
其对催化反应的影响
2000-29 张兆国上海有机所亚胺及烯胺的氢甲酰化反应
二000年论文目录
课题负责人：陆熙炎课题编号：2000-01
1. An Efficient Preparation of α-Alkylidene-β-formylmethyl-γ-lactams via Pd(II)-
Catalyzed Intramolecular Alkyne-α,β-Unsaturated Carbonyl Coupling
Xie, X.; Lu, X.*
Synlett2000, 707-709. 32
2. Role of Halide Ions in Palladium(II) Catalyzed Nucleophile Alkyne-a,b-Unsaturated
Carbonyl Coupling Reactions
Lu, X.; Wang, Z.
Polyhderon 2000, 19, 577-579. 35
3. Effect of Halide Ligands on the reactivity of Carbon-Palladium Bonds: Implications
for Designing Catalytic Reactions
Wang, Z.; Zhang, Z.; Lu, X.*
Organometallics2000, 19, 775-780. 38
4. A Facile Highly Regio- and Stereo-selective Preparation of N-Tosyl Allylic Amines
from Allylic Alcohols and Tosyl Isocyanate via Palladium(II)-Catalyzed
Aminopalladation-β-Heteroatom Elimination
Lei, A.; Lu, X.*
Org. Lett. 2000, 2, 2357-2360. 44
5. Palladium(II)-Catalyzed Tandem Intramolecular Aminopalladation of Alkynes and
Conjugate Addition. Synthesis of Oxazolidinones, Imidazolidinones and Lactams Lei, A.; Lu, X.*
Org. Lett. 2000, 2, 2699-2702. 48
6. Highly Enantioselective Palladium(II)-Catalyzed Cyclization of (Z)-4'-Acetoxy-2'-
butenyl 2-Alkynoates. An Efficient Synthesis of Optically Active -Butyrolactones
Zhang, Q.; Lu, X.*
J. Am. Chem. Soc. 2000, 122, 7604-7605. 52
课题负责人：钱长涛课题编号：2000-02
1. Coordinatively Unsaturated Neodymium Hydrides,Stability in Solution
Visseaux Marc, Baudry Denise, Dormond Alain, Qian Changtao
J. Organomet. Chem., 1999,574(2), 213-218 54
2. [2+2] Cycloaddition Reactions of Imines with Alkynyl Selenides Catalyzed by
Scandium Triflate
Yun Ma and Changtao Qian
Tetrahedron Letters, 2000, 41, 945-947 60
3.Asymmetric Hetero-Diels-Alder Reaction of Glyoxylate Esters and Danishefsky's
Diene Catalyzed by Chiral Bis(oxazoline)-Lanthanide Complexes
Changtao Qian and Longcheng Wang
Tetrahedron Letters, 2000, 41, 2203-2206 63
4. First Application of Amino-TADDOL Derivatives in Enantioselective Addition of
Diethylzinc to Aryl Aldehydes: Effect of Substituents on the Nitrogen Atom
Changtao Qian, Fei-Feng Gao and Sun Jie
Tetrahedron: Asymmetry,2000, 11, 1733-1740 67
5. Asymmetric Glyoxylate-Ene Reaction Catalyzed by C2-symmetric Chiral
Bis(Oxazoline)- Lanthanide Complexes.
Changtao Qian and Longcheng Wang
Tetrahedron: Asymmetry, 2000, 11, 2347-2357 75
6. Addition of Silyl Ketene Acetals to Nitrones Catalyzed by Lanthanide Triflates
Changtao Qian and Longcheng Wang
Tetrahedron, 2000, 56, 7193-7197 86
7. Lanthanide Triflate Catalyzed Biginelli Reaction. One-Pot Synthesis of
Dihydropyrimidinones under Solvent-Free Conditions.
Yun Ma, Changtao Qian, Limin Wang and Min Yang
J. Org. Chem., 2000, 65, 3864-3868 91
8. C s-Symmetric ansa-Lanthanocenes Designed for Stereospecific Polymerization of Methyl Methacrylate, Synthesis and Structural Characterization of Silylene-Bridged Fluorenyl Cyclopentadienyl Lanthanide Halides, Amides and Hydrocarbyls.
Changtao Qian, Wanli Nie and Jie Sun
Organometallic, 2000, 19, 4134-4140 96
9.Stereoselective Synthesis and Structural Characterization of rac-Planar Chiral Bis(2- methoxyethylindenyl)lanthanum and Yttrium Tetrahydroborates.
Chang-Tao Qian, Gang Zou, Wan-Li Nie, Jie Sun, Dmitri A. Lemenovskii and Maxim V. Borzov
Polyhedron, 2000, 19, 1955-1959 103
10.Synthesis and Strcture of Barium Complex Containing 2,2,6,6-Tetramethyl-3,5-
heptanedionate and 1,10-Phenanthroline Ligands
Xie Mei-Hua,Qian Chang-Tao,Gao Li-Jun,Sun Jie
Chinese J.Struct.Chem.,2000, 19, 419-422 108
11. Synthesis of Furo[3,2-c]and Pyrano[3,2-c] Quinolines by Lanthanide Triflate
Catalyzed Imino-Diels-Alder Reaction
Yun Ma, Changtao Qian, Mei-Hua Xie and Sun Jie
Chin. J. Chem., 2000, 18, 377-383 112
12. 后过渡金属催化剂催化乙烯聚合
邹丰楼，李阳，邹晓天，宋玉春，钱长涛，陈瑞芳，陆汉章
合成树脂及塑料，2000，17(1), 60 119
课题负责人：麻生明课题编号：2000-03
1. Stepwise -Bromination of 1,1-Dihaloalkenes
Shengming Ma*, Bin Xu, and Shimin Zhao
Synthesis2000, 139-143. 121
2. Pd(0)-catalyzed Cyclization Reaction of Aryl or 1-Alkenyl Halides with 1,2-Dienyl Ketones. A General and Efficient Synthesis of Polysubstituted Furans
Shengming Ma* and Junliang Zhang
Chem. Commun.2000, 117-118. 126
3．Unusual Regioselectivity of Pd(0)-Catalyzed Coupling Reaction of Electron-deficient Alkenyl Halides with Allenic/Propargylic Zinc Reagents. Highly Selective Synthesis of 6-Phenylhex-5-yn-2(or 3)-enoates/enitriles and 4-Phenyl-6-substitutedhexa-2,4,5- trienoates
Shengming Ma*, Aibin Zhang, Yihua Yu, and Wei Xia
J. Org. Chem. 2000, 65, 2287-2291. 128
4. AlX3-H2O-promoted Hydrohalogenation Reaction of 1,2-Allenic Sulfoxides
Shengming Ma* and Qi Wei
Eur. J. Org. Chem.2000, 1939-1943. 133
5. Palladium(II)-Catalyzed Cyclization Reaction of Allylic Bromides with 1,2-Dienyl
Ketones. An Efficient Synthesis of 3-Allylic Polysubstituted Furans
Shengming Ma* and Lintao Li
Organic Letters2000, 2, 941-944. 138
6. Palladium(0)-catalyzed Cyclization Reaction of Polymer-Supported Aryl Iodides with 1,2-Allenyl Carboxylic Acids. A Facile Solid Phase Synthesis of Butenolides
Shengming Ma,*Dehui Duan, and Zhangjie Shi
Organic Letters2000, 2, 1419-1422. 142
7．Reverse of Regioselectivity in Intramolecular Nucleophilic Substitution of π–Allyl Palladium Species. Highly Selective Formation of Vinylic Cyclopropanes via the
Pd(0)–Catalyzed Coupling-Cyclization Reaction of Organic Iodides with 2-(2’,3’- Dienyl)malonates
Shengming Ma* and Shimin Zhao
Organic Letters2000, 2, 2495-2497. 146
8. Efficient Synthesis of 4-(2'-Alkenyl)-2,5-dihydrofurans via PdCl2-catalyzed
Coupling-Cyclization Reaction of 2,3-Allenols with Allylic Halides
Shengming Ma* and Wenzhong Gao
Tetrahedron Lett. 2000, 41, 8933-8936. 149
9. Studies on the Oxidative Addition Reaction of 1,1-Dibromo-1-alkenes, α-
Dehalopalladation, and the Intramolecular Bis(carbopalladation) Reaction of Alkenes. An Efficient Entry to Fused Bicycles
Shengming Ma*, Bin Xu, and Bukuo Ni
J. Org. Chem.2000, 65, 8532-8543. 153
10. Unique Selectivity of Iodohydroxylation Reaction of Allenyl Phenyl Sulfoxides in
Aqueous MeCN. A Stereodefined Synthesis of (E)-2-Iodo-3-hydroxy-1-alkenyl
Sulfoxides
Shengming Ma*, Qi Wei, and Haiming Wang
Organic Letters2000, 2, 3893-3895. 165
11. Unexpected Facile Sequential Halolactamization-Hydroxylation of 2,3-Allenamides with CuX2 for the Efficient Synthesis of 4-Halo-5-hydroxypyrrol-2(5H)-ones
Shengming Ma* and Hexin Xie
Organic Letters2000, 2, 3801-3803. 168
12. Review: Recent Progress in Carbolithiation Reaction
(碳锂化反应的研究进展)
Bin Xu and Shengming Ma*
Chin. J. Org. Chem. (有机化学)2000, 20, 54-63. 171
13. Synthesis and Structure of the First Propeller-shaped Helical Coordination Polymer of Ag+ with Bis(oxazoline) Ligands
Shengming Ma* and Shulin Wu
Chin. J. Chem.2000, 18, 444-446. 181
14. Review: Recent Advances in Meta-mediated Synthesis of Substituted Furans
(金属催化合成呋喃衍生物的最新进展)
Lintao Li and Shengming Ma*
Chin. J. Org. Chem.(有机化学)2000, 20, 701-711. 184
15. Synthesis and Reaction of 1,2-Allenyl Ketones
(1,2-联烯基酮的合成与反应)
Lintao Li and Shengming Ma*
Chin. J. Org. Chem.(有机化学)2000, 20, 850-860. 195
课题负责人：侯雪龙课题编号：2000-04
1. Ring-opening of N-Tosylaziridines with TMSN3 and TMSCN Triggered by TBAF:
An Efficient and Convenient Route to Vicinal Diamines and -Aminoacid
Jie Wu, Xue-Long Hou and Li-Xin Dai
J. Org. Chem. 2000, 65, 1344-1348. 206
2.On the Role of Planar Chirality: a Tunable Enantioselectivity in Palladium-Catalyzed
Allylic Alkylation with Planar C hiral 1,1’-P,N-ferrocene Ligands
Wei-Ping Deng, Xue-Long Hou, Li-Xin Dai, Yi-Hua Yu and Wei Xia
Chem. Commun. 2000, 285-286. 211
3.Synthesis of 2-( -Substituted N-Tosylaminomethyl)-2,5-Dihydrofurans by Reaction
of N-Sulfonylimines with Arsonium or Sulfonium 4-Hydroxyl-cis-2-butenylides Wei-Ping Deng, An-Hu Li, Li-Xin Dai , and Xue-Long Hou
Tetrahedron2000, 56, 2967-2974. 213
4.Synthesis of Planar Chiral Selenide Derivatives of Ferrocenyl-oxazoline and Their
Application in Enantioselective Palladium Catalyzed Allylic Substitution Reaction Shu-Li You, Xue-Long Hou and Li-Xin Dai
Tetrahedron: Asymmetry 2000, 11, 1495-1500. 221
5. A Stereoselective Michael-imino Aldol Tandem Reaction Triggered by Thiolate
Anions
Xiao-Fang Yang, Xue-Long Hou and Li-Xin Dai
Tetrahedron Lett.2000, 41, 4431-4434. 227
6.Novel N,S- and N,Se-Planar Chiral [2,2]Paracyclophane Ligands: Synthesis and
Application in Pd-Catalyzed Allylic Alkylation
Xue Long Hou, Xun Wei Wu and Li Xin Dai
Chem. Commun.2000, 1195-1196. 231
7.Efficient Planar Chiral 1,1’-P,N-2-Substituted Ferrocene Ligands for Asymmetric
Heck Reaction: Control of Enantioselectivity and Configuration by Planar Chiral Substituent
Wei Ping Deng, Xue Long Hou and Li Xin Dai
Chem. Commun.2000, 1483-1484. 233
8. Novel Bis-N-[2-(diphenylphosphino)ferrocenylcarbonyl]-diaminocyclohexane
Ligands: Application in Asymmetric Allylic Alkylation of Imino Ester with Simple Allyl Carbonate
Shu-Li You, Xue-Long Hou, Li-Xin Dai, Bo-Xun Cao and Jie Sun
Chem. Commun.2000, 1933-1934. 235
9. 硫叶立德途径立体控制合成乙烯基型环氧化合物
周永贵，李安虎，戴立信，侯雪龙
化学学报2000, 58, 473-480. 237
10.Fructose Derived Pyridyl Alcohol Ligands: Synthesis and Application in the
Asymmetric Diethylzinc Addition to Aldehydes
Yong-Gui Zhou, Li-Xin Dai and Xue Long Hou
Chinese J. Chem. 2000, 18, 121-123. 245
课题负责人：沈延昌课题编号：2000-05
1. Novel Base-catalyzed Olefination Methodology. Stereoselective Synthesis of
(E)- -benzenesulfinyl Vinylphosphonates
Yanchang Shen, Guo-Fang Jiang
Synthesis, 2000, 99-102. 248
2. Sequential Transformations of Phosphonates. "One-pot Synthesis of Ethoxycarbonyl Allyl Substituted Oxime Ethers
Yanchang Shen, Guo-Fang Jiang
Synthesis, 2000, 502-504. 252
3. Stereocontrolled Synthesis of Fluorinated E- or Z- Allylic Phosphonates
Yanchang Shen, Yuming Zhang, Zenghong Zhang
Synthesis, 2000, 1535-1538. 255
4. Stereoselective Synthesis (E)-4-Cyano-γ,δ-Unsaturated Nitriles
Yanchang Shen, Zenghong Zhang
Synth. Commun. 2000, 30, 445-453. 259
5. A Convenient Synthesis of (E)-α-Cyano and (E)-α-ethoxycarbonyl
vinylphosphonates
Yanchang Shen, Guo-Fang Jiang
J. Chem. Res. (s)2000, 140-141. 268
6. New Synthetic Methodologies for Carbon-Carbon Multiple Bond Formation
Shen Yan-chang
Acta Chimica Sinica, 2000, 58, 253-261. 270
课题负责人：陈家碧课题编号：2000-06
1．Reactions of Cationic Carbyne Complexes of Manganese and Rhenium with Carbonylmetal Anions Containing Cyclopentadienyl, PPh3, and NO Ligands. A Route to Dimetal Bridging Carbene and Carbyne Complexes
Yongjun Tang, Jie Su, Jiabi Chen*
Organometallics, 2000, 19, 72-80. 279
2．Reactions of Cationic Bridging Carbyne Complexes of Bis(η-cyclopenta-
dienyl)diiron Tricarbonyl with Nucleophiles. A Route to Diiron Bridging
Carbene Complexes
Yajun Liu, Ruito Wang,, Jie Su, Jiabi Chen*
Organometallics,2000, 19, 3498-3506. 288
3. Unusual Reactions of Cationic Bridging Carbyne Complexes of Bis(η5- cyclopentadienyl)diiron Tricarbonyl with Carbonylmetal Anions. A Route to
Diiron Bridging Carbyne Complexes
Yajun Liu, Ruitao Wang, Jie Sun, and Jiabi Chen*
Organometallics, 2000, 19, 3784-3791. 297
4.Remarkable Transformtion of Thiophene Ligands in Their Pentamethyl-
cyclopentadienyl Iridium (Cp*Ir) Coplexes
Jiabi Chen,* Robert J. Angelici
Coordination Chemistry Reviews, 2000, 206, 63-99. 304
5.Reactions of Di-μ-carbonyl-cis-μ-(1-5-η:1'-5'-η-dicyclopentadienyl-
dimethylsilane)bis(carbonyliron) with Aryllithium Reagents. Crystal
Structures of [Fe2(μ-CO){μ-C(OC2H5)C6H5}(CO)2{(η5-C5H4)2Si(CH3)2}]
and [Fe2(μ-CO){μC(OC2H5)C6H4OCH3-p}(CO)2{(η5-C5H4)2Si(CH3)2}]
Ruitao Wang, Jie Sun, Jiabi Chen*
J. Organomet. Chem., 2000,617, 1-9. 341
课题负责人：邓敏智课题编号：2000-07
1. Silver Oxide Mediated Palladium-catalyzed Cross-coupling Reaction of
Cyclopropylboronic Acids with Allylic Bromides
Han Chen and Min-zhi Deng
J. Org. Chem. 2000, 65, 4444 ~ 4446. 350
2. Facile Approach to 4-substituted 2(5)H-furanones
Min-Liang Yao and Min-zhi Deng
J. Org. Chem.2000, 5034 ~ 5036. 353
3. A Novel Stereocontrolled Synthesis of 1,2-trans Cyclopropyl Ketones via Suzuki-type Coupling of Acids Chlorides with Cyclopylboronic Acids
Han Chen and Min-zhi Deng
Organic Letters2000, 2 (12), 1649 ~ 1651. 356
4. A Practical Approach to Stereodefined Cyclopropyl-substituted Heteroarenes using
Suzuki-type Reaction
Min-Liang Yao and Min-zhi Deng
New. J. Chem.2000, 24, 425 ~428. 359
5.Palladium-catalyzed Cross-coupling Reaction of Cyclopropylboronic Acids with Aryl Triflates
Min-Liang Yao and Min-zhi Deng.
Synthesis 2000, 8, 1095 ~ 1100. 363
6. A Novel Route to Stereodefined Cyclopropyl-substituted Alkenes
Shao-Man Zhou and Min-zhi Deng
Tetrahedron Letters2000, 41, 3951 ~ 3954. 369
7. Palladium-catalyzed Cross-coupling of Cyclopropylboronic Acids with Alkenyl Triflates Min-Liang Yao and Min-zhi Deng
Tetrahedron Letters2000, 41, 9083 ~ 9087. 373
8. A Novel and Convenient Method to 4-Substituted Coumarins
Min-Liang Yao and Min-zhi Deng
Heteroatom Chemistry2000, 11 (6), 380 ~ 382. 378
9. A Novel Suzuki-type Cross-coupling Reaction of Cyclopropylboronic Esters with Benzyl bromides
Han Chen and Min-zhi Deng
J. Chem. Soc. Perkin Trans I 2000, 1609 ~ 1613. 381
10. Nickle-catalyzed Allylation of Lithium 1-Alkynyl(trialkoxy)borates with 1,3-
Substituted Allyl Carbonates
Han Chen and Min-zhi Deng
J. Organomet. Chem.2000,603, 189 ~ 193. 386
课题负责人：姜标课题编号：2000-08
1.Stereocontrolled Synthesis 22E, 24(S)-Trifluoromethyl Sidechain of Steroid and Its
Application in Synthessis of Fluorinated Analugues Natural Occuring Sterols
B. Jiang, Y. Liu, Zhou Weishang,
J. Org. Chem, 2000, 65, 6231-6236. 391
2.1,3-Dipolar Cyloaddtion of Chially Modified Vinylboronic Ester with Ntrile Oxides
Biao Jiang, Ao Zhang, Ying Kan, Gui-ling Zhao and Biao Jiang
Tetrahedron, 2000, 56, 965-970. 397
3.C2-Symmetric Bisphoshoine and a Bisaminophosphine as New Chiral Ligands for
Pd-catalyzed Asymmetric Allylic Substitution
Ao Zhang, Yan Feng, Biao Jiang
Tetrahedron: Asymmetry, 2000, 11, 3123-3130. 403
4.Solid Phase Asymmtric Synthesis of 2-Isoxazoline
Ning Zhou, Biao Jiang,
J. Com.. Chem., 2000, 2(1), 6-7 411
5.Syntheses and Cytotoxicity Evaluation of Bis(indolyl)thiazole,
Bis(indoly)pyrazinone and Bis(indolyl)pyrazine: Analogues of Cytotoxic Marine Bis(indole) Alkaloid
Biao Jiang* and Xiao-Hui Gu
Bioorganic & Medicinal Chemistry, 2000, 8, 363-371. 413
6.Syntheses of Indoylpyrimidine via Cross Coupling of Indolylboronic Acid with
Chloropyrimidines: Facile Synthesis of Merdianin D
Biao Jiang, Caiguang Yang
Heterocycles, 2000, 53(7), 1559-1568. 422
7.Syntheses of Bis(3-indolyl)pyrazinone
Biao Jiang, Xiao-Hui Gu
Heterocycles, 2000, 53(7), 1489-1498. 432
8.Highly Enatiooselective Reduction of Achral with NaBH4/Me3SiCl Catalyyzed by
(S)-diphenylpyrrolidinemethyanol
Biao Jiang, Yan Feng, Jian Zheng
Tetrahedron Letters,2000, 52, 10281-10283. 442
9.Synthesis of Novel Compatibilizers and Their Application in PP/nylon-66 Blends.I.
Synthesis and Characterization
De-Liang Xie a,*, Da Chen b, Biao Jiang a, Chang-Zheng Yang c
Polymer, 2000, 41, 3599-3607. 445
10.In situ NMR Study of Asymmetric Borane Reduction Reaction-an Abnormal Factor
in the Temperature Effect on the Bis-oxazaborolidine Catalust and the Relationship between the Catalyst Structure and Selectivity
Jinkai Zhao,a Xinhe Bao,a,* Xiumei Liu,a and Biao Jiang b
Tetrahedron: Asymmetry, 2000, 11, 3351-3359. 454
11.Asymmetric 1,3-dipolar Cyloaddtion of Nitrile Oxides to Acryloyl Esters Dearing
Glucofuranose as Auxiliary
Biao Jiang, Ao Zhang,Ying Kan,
Chin. J. Chem., 2000, 18(2), 200-224. 463
12.新型海洋双吲哚类生物碱的研究进展
谷晓辉姜标*
有机化学, 2000, 20, 168-177. 468
13.羟基酸引发 -己内酯开环聚合的研究
解德良,姜标
高分子学报, 2000, 5, 532-537. 478
14.The Mechanism of Asymmetric Reduction of by Catalytyzed by A C2-Symmetric is
Amino Alcohol Catalyst
Jinkai Zhao, Xiuwen Han, Xiumaei Liu, Xinhe Bao, Jian Feng Hang,and Biao Jiang Science in China, 2000, 43, 1 41-150. 484
课题负责人：施敏课题编号：2000-09
1. An Unexpected Carbon Dioxide Insertion in the Reaction of Trans-2,4-Disubstituted Azetidine, Trans-2,5-Disubstituted Pyrrolidine, or Trans-2,6-Disubstituted Piperidine with Diphenylthiophosphinic Chloride and Diphenylselenophosphinic Chloride.
Min Shi,* Jian-Kang Jiang, Yu-Mei Shen, Yan-Shu Feng, and Gui-Xin Lei
J. Org. Chem., 2000, 65, 3443-3448. 495
2. The Crystallographic Structure of a Novel Camphanic Amide.
Min Shi* and Gui-Xin Lei
J. Chem. Crystallography, 1999, 29, 1211-1213. 501
3. Chiral Diphenylthiophosphoramides: A New Class of Chiral Ligands for the Silver (I)- Promoted Enantioselective Allylation of Aldehydes.
Min Shi* and Wen-Sheng Sui
Tetrahedron:Asymmetry, 2000, 11, 773-779. 504
4. Chiral Diphenylselenophosphoramides: a New Class of Chiral Ligands for the
Titanium(IV) Alkoxide-promoted Addition of Diethylzinc to Aldehydes.
Min Shi* and Wen-Sheng Sui
Tetrahedron:Asymmetry, 2000, 11, 835-841. 511
5. A Facile Route to Bulladecin Type Acetogenins. Total Synthesis of Asimilobin and
Correction of Its Tetrahydrofuran Segment' s Configuration.
Zhi-Min Wang,* Shi-Kai Tian and Min Shi*
Eur. J. Org. Chem., 2000, 349-356. 518
6. Amendment in Titanium(IV) Chloride and Chalcogenide-Promoted Baylis-Hillman
Reaction of Aldehydes with -Unsaturated Ketones.
Min Shi* and Jian-Kang Jiang
Tetrahedron, 2000, 56, 4793-4797 . 526
7. Synthesis of a Novel Chiral Ruthenium Complex and Its Crystal Structure.
Min Shi,* Kazuya Kobiro, Tomomi Fujita
J. Organometal. Chem., 2000, 605, 134-138. 531
8. Titanium(IV) Chloride and Amine-promoted Baylis-Hillman Reaction.
Min Shi,* Jian-Kang Jiang and Yan-Shu Feng
Org. Lett., 2000, 2, 2397-2400. 536
9. A Simple Synthetic Method for Chiral 1,2-Epoxides and the Total Synthesis of a
Chiral Pheromone Epoxide.
Zhi-Bo Zhang, Zhi-Min Wang,* Yu-Xiu Wang, Huan-Quan Liu, Gui-Xin Lei and
Min Shi,
J. Chem. Soc., Perkin Trans 1, 2000, 53-57. 540
10. Total Synthesis of Gigantetrocin A.
Zhi-Min Wang,* Shi-Kai Tian and Min Shi.*
Chirality, 2000, 12, 581-589. 545
11. Trifluoromethanesulfonamide, Diphenylphosphoramide and Diphenyl-thiophosphor- amide of (R)-(+)-1,1'-Binaphthyl-2,2'-diamine as Chiral Catalyst Ligands for the
Titanium(IV) Alkoxide-Promoted Addition of Diethylzinc to Aldehydes.
Min Shi* and Wen-Sheng Sui
Chirality, 2000, 12, 574-580. 554
12. The Crystallographic Structure of 4-hydroxy-3-methylene-4-(p-nitrophenyl)butan-2- one.
Min Shi* and Jian-Kang Jiang
J. Chem. Crystallography, 1999, 29, 1295-1297. 561
13. A New Class of Chiral Pyrrolidine Ligands for Homogeneous Catalytic
Enantioselective Cyclopropanation of Styrene
Min Shi* and Jian-Kang Jiang
Chin. J. Chem., 2000, 3, 407-410. 564
课题负责人：丁奎岭课题编号：2000-10
1. Reduction of 1,1’-Binaphthyls to Octahydro-1,1’-binaphthyl Derivatives with
Raney Ni-Al alloy in Aqueous Solution
Hui Guo, Kuiling Ding
Tetrahedron Lett., 2000, 41, 10061-10064 568
2.Practical Method and Novel Mechanism for Optical Resolution of BINOL by
Molecular Complexation with N-benzylcinchonium Chloride
Y. Wang, J. Sun, Kuiling Ding
Tetrahedron, 2000, 56，4447-4451 572
3.Synthesis of Novel N, P Chiral Ligands for Palladium-catalyzed Asymmetric
Allylation: The Effect of Binaphthyl Backbone on the Enantioselectivity
Yi Wang, Hui Guo, Kuiling Ding
Tetrahedron: Asymmetry, Lett. 2000, 11,4153-4162. 577
4.The Synthesis of Novel Non-C2 Symmetric H4-BINOL Ligand and Its Application to
Titanium-catalyzed Enantioselective Addition of Diethylzinc to Aldehydes
X. Shen, H. Guo, K. Ding
Tetrahedron: Asymmetry, 2000, 11, 4321-4327. 587
5.催化不对称反应新进展—不对称活化（综述与进展）
丁奎岭、林国强
有机化学，2000，20， 1-10 594
6.催化不对称反应新进展—组合化学方法之应用（综述与进展）
丁奎岭
有机化学，2000，20，613-622 604
课题负责人：唐勇课题编号：2000-11
1.Switching of Stereoselectivity: Dramatic Effects of HMPA on the Stereoselectiviy of
Cyclopropanation Reaction of Silylated Tellronium Allylide with α,β-Unsaturated Esters and Amides
Ye, S.; Tang, Y.*; Dai, L. X
J. Org. Chem., 2000, 6257-6260. 614
课题负责人：廖世健课题编号：2000-12
1. 水滑石选择性催化合成三乙二醇单丁醚
刘金龙，王永杰，廖世健, 王复东, 徐杰，魏同成
催化学报. 2000,21, 283-285. 618
2.PVP-Pd催化六氯苯加氢脱氯中两种氢源的贡献
高燕，廖世健, 徐杰, 上官勇刚, 顾志祥，蹇锡高
催化学报. 2000, 21, 378-380. 621
课题负责人：宋礼成课题编号：2000-13
1. Synthesis of Double and Quadruple Butterfly Fe/SCluster Complexes via a Novel
Type of Reaction of Anions (μ-RS)(μ-S-)[Fe2(CO)6]2(μ4-S) with Succinyl Chloride.
Li-Cheng Song , Guo-Liang Lu, Qing-Mei Hu, and Jie Sun
Organmetallics1999, 18, 5429-5431. 624
课题负责人：黄宪课题编号：2000-14
1. Hydrozirconation of Alkynyl Sulfoxides: the Reactions of Zirconated Vinyl Sulfoxide
Intermediates
Ping Zhong, Xian Huang, Meng-Ping Guo
Tetrahedron, 2000, 56, 8921-8925. 627
课题负责人：沈琪课题编号：2000-15
1. Synthesis of Indenyllanthanide Amides: the Effective Initiators for Polymerization of Methyl Methacrylate.
Zhao Qun, Yao Ying-Ming, Shen Qi
Chin. J. Chem., 2000, 18(6), 877-881. 632
课题负责人：康北笙课题编号：2000-16
1. Chemistry of Aroylhydrazones II. Enol-form Coordination of 4,5-Diazafluorene-9-one salicyloylhydrazone (H2L) to Transition Metals and Crystal Structures of H2L,
Mn(HL)2(H2O)2 and Co(HL)2(DMF)2
Xiao, W., Lu, Z. L., Wang, X. J., Su, C. Y., Yu, K. B., Liu, H. Q., Kang, B. S.
Polyhedron, 2000, 19(13), 1295-1304. 637
2. 4,5-Diazafluorene-9-one Acylhydrazones and their Lead Complexes and the Crystal
Structure of Hydrated 4,5-Diazafluorene-9-one 3-methoxybenzoylhydrazone Supported by Extensive Hydrogen Bonds and Aromatic Ring Stacking Interactions
Xiao, W., Lu, Z. L., Deng, L. R., Su, C. Y., Tong, Y. X., Liu, H. Q., Kang, B. S. Polish J. Chem., 2000,74, 1211-1220. 647
3. Bivalent Transition Metal Complexes of 4,5-Diazofluorenone Benzoylhydrazone (HL) and the Characterization of Weak Interactions in CoL2 . 2H2O
Xiao, W., Lu, Z. L., Su, C. Y., Yu, K. B., Deng, L. R., Liu, H. Q., Kang, B. S.
J. Mol. Stru., 2000,553, 91-99. 657
4. NMR Studies on 4,5-Diazafluorenone 2-Naphthalylhydrazone and its Lead Complex Xiao, W., Lu, Z. L., Kang, B. S., Liu,, H. Q., Su, C. Y.
J. Chi. Magnetic Resonance, 2000, 17(4), 265-269. 666
课题负责人：沈之荃课题编号：2000-17
课题负责人：张永敏课题编号：2000-18
1.Samarium Diiodide Induced Reductive Cyclization of Nitro Compounds with
Ketones: A Novel Synthesis of 3,4-Dihydro-(2H)-1,2,4-Benzothiadiazine-1,1-
Dioxides.
Weihui Zhong, Xiaoyuan Chen, Yongmin Zhang*
J. Chem. Res. (S), 2000, (6), 292-293. 671
2. A New Route to 2,3-Dihydro-1,5-Benzothiazepines from Niteodisulfides and α,β-
Unsaturated Ketones by SmI2.
Xiaoyuan Chen, Weihui Zhong, Yongmin Zhang
J. Chem. Res. (S), 2000, (8), 386-387. 673
3. Samarium Diiodide Mediated Simultaneous reduction of Nitro Group and the Azide。