色素炭黑说明书MSDS - 360文档中心

炭黑MSDS

blacks. The foregoing are registered trade names of Cabot Corporation, and denote
physical differences in carbon black grades.
Manufacturer抯 Product Code: Not applicable.
MSDS
Page 2 of 6
MATERIAL SAFETY DATA SHEET
Swallowed: None expected.
Eye: Mechanical irritant with no adverse effects.
Skin: None expected but may dry skin with prolonged exposures. Use of quality barrier cream can prevent skin dryness.
Inhaled: None expected. Temporary discomfort to the upper respiratory tract may occur due to inhalation of dust concentrations above the OEL.
Human Studies: Epidemiological studies of workers in the carbon black producing industries of North America and Western Europe show no evidence of clinically significant, adverse health effects due to occupational exposure to carbon black.

炭黑MSDS of carbon black

SECTION 6 ACCIDENTAL RELEASE MEASURES Spill Management: Clean up spills immediately, observing precautions in Exposure Controls/Personal Protection section. Sweep up material and place in a disposable container. Reporting: This product is neither listed as a hazardous waste nor does it exhibit any of the characteristics that would cause it to be classified or disposed of as a RCRA hazardous waste.
SECTION 2 COMPOSITION/ INFORMATION ON INGREDIENTS COMPONENT CAS NUMBER AMOUNT CARBON BLACK 1333-86-4 100.00 % weight Occupational Exposure Limits: Component Limit TWA STEL Ceiling Notation CARBON BLACK ACGIH_TLV 3.5 mg/m3 NA NA NA CARBON BLACK OSHA_PEL 3.5 mg/m3 NA NA NA
SECTION 3 HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Odorless black powder. - MAY CAUSE RESPIRATORY TRACT IRRITATION IF INHALED IMMEDIATE HEALTH EFFECTS: Eye: Not expected to cause prolonged or significant eye irritation. Skin: Not expected to be harmful to internal organs if absorbed through the skin. Contact with the skin is not expected to cause prolonged or significant irritation. Ingestion: Not expected to be harmful if swallowed. Inhalation: The dust from this material may cause respiratory irritation. Symptoms of respiratory irritation may include coughing and difficulty breathing. DELAYED OR OTHER HEALTH EFFECTS: Cancer: May cause cancer in laboratory animals, but the available information is inadequate to determine if this material can cause cancer in humans. See Section 11 for additional information. Risk depends on duration and level of exposure

炭黑msds.doc

材料安全数据表1.化学品及企业信息化学品中文名称炭黑编码 111俗名/商品名炭黑生效日期化学品英文名称 calcium hypochlorite企业名称上海卡博特化工有限公司企业应急电话地址邮编国家应急电话传真电子邮件地址2.成分 / 组成信息□混合物主要成分■纯品危害成分浓度CAS No. 1333-86-43.危险性概述危险性类别不是危险品侵入途径呼吸，眼睛接触，皮肤接触。

吸入刺激鼻腔、嘴、喉；接触刺激皮肤和眼睛；长期暴露，会损伤皮肤和指甲，造成暂时或永健康危害久性损伤，伤害肺和呼吸道，并对心脏产生不良影响。

慢性接触引起咳嗽、咳痰、烦燥、胸痛、头痛、肺损害、气管炎、皮疹。

健康危害 ( 蓝色 ) ：1环境危害燃烧危险4.急救措施皮肤接触用肥皂和水清洗，如果皮肤发红，水肿，发痒或灼伤。

就医。

眼睛接触用大量的水立即冲洗眼睛15 分钟。

如果发红，水肿，发痒，灼伤或视觉模糊就医。

吸入不必催吐。

如果清醒的，饮几杯水。

不要通过嘴给不清醒的人任何东西。

食入5.消防措施燃烧会产生刺激烟雾。

本品不溶于水并浮于水。

如可能，除去漂浮物，原因是漂浮物构成流动危险特性火灾的危险。

有害燃烧物一氧化碳，二氧化碳硫的氧化物灭火方法使用与所在地环境情况相适合的灭火方法。

如果用水，建议用喷雾水。

不能用强力的直流水，及灭火剂直流水会分散火源。

注意事项粉尘爆炸的粉尘与空气混合可能形成爆炸混合物，禁止使用掸，拂或者高压空气吹扫粉尘，避免形成粉尘风险团。

6.泄露应急处理应急处理须穿戴防护用具进入现场；排除一切火情隐患；用简便、安全的方法收集粉尘于密闭的容器内，待处理。

环境信息：应急计划和社区知情权法：款313 表 R，最低应报告浓度0 ． 1％。

消除方法7.操作处置与储存操作注意事项储存避免接触禁忌物，严禁烟火。

须贴“自燃”标签，严禁航空、铁路运输。

ERG 指南： 133 ERG 注意事项指南分类：易燃固体8.接触控制 / 个体防护最高容许浓度3 3监测方法4mg/mTWA 8mg/mSTEL工程控制保证正确的通风，控制暴露在职业卫生允许值以下。

炭黑英文msds

﹡﹡﹡MATERIAL SAFETY DATA SHEET﹡﹡﹡1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THECOMPANY/UNDERTAKINGProduct Name: CARBON BLACK N330Synonyms: Carbon Black, Furnace BlackUse of the Substance/Preparation: Various, Industrial ProductsSupplier:Carbon Black Co. ,Ltd.City, ChinaTEL: FAX:02. HAZARDS IDENTIFICATIONIndication of danger: Hazardous according to the Worksafe Australia designated list of hazardous substances.Xn - Harmful.C3 - Carcinogen Category 3.Principle Routes of Exposure: Inhalation, Eye contact, Skin contactPOTENTIAL HEALTH EFFECTSEye Contact:May cause mechanical irritation. Irritating, but will not permanently injure eye tissue.Low hazard for usual industrial or commercial handling.Skin Contact:No adverse effects expected.Inhalation:Dust may be irritating to respiratory tract. Provide appropriate exhaust ventilation at machinery and at places where dust can be generated. See also Section 8.Ingestion:Health injuries are not known or expected under normal use. Low hazard for usual industrial or commercial handling.Carcinogenic Effects:Substance listed by IARC (International Agency for Research on Cancer). See also Section 9.Target Organ Effects:LungsMedical Conditions Aggravated by Exposure:Asthma, Respiratory disorder1Potential Environmental Effects:No special environmental precautions required. Not soluble in water. See also Section 12.4. FIRST AID MEASURESSkin Contact:Wash thoroughly with soap and water. Seek medical attention if symptoms develop.Eye Contact:Flush eyes immediately with large amounts of water for 15 minutes. Seek medical attention if symptoms develop.Inhalation:If cough, shortness of breath or other breathing problems occur, move to fresh air.Seek medical attention if symptoms persist. If necessary, restore normal breathing through standard first aid measures.Notes to Physician:Treat symptomatically.5. FIRE-FIGHTING MEASURESExtinguishing Media:Use foam, carbon dioxide (CO2), dry chemical or water spray. A fog is recommended if water is used. DO NOT USE a solid water stream as it may scatter and spread fire.Special Protective Equipment for Firefighters:Wear suitable protective equipment. In the event of fire, wear self-contained breathing apparatus.Specific Hazards:It may not be obvious that carbon black is burning unless the material is stirred and sparks are apparent. Carbon black that has been on fire should be observed closely for at least 48 hours to ensure no smoldering material is present. Burning produces irritant fumes. The product is insoluble and floats on water. If possible, try to contain floating material. This material creates a fire hazard because it floats on water.Hazardous Decomposition and/or Combustion Products:Carbon monoxide, Carbon dioxide, Oxides of sulphur, Organic products of decomposition.Risk of Dust Explosion:Do not create a dust cloud by using a brush or compressed air.26. HANDLING AND STORAGEHandling:Avoid contact with skin and eyes. Do not breathe dust. Provide appropriate exhaust ventilation at machinery and at places where dust can be generated. Do not create adust cloud by using a brush or compressed air. Fine dust is capable of penetratingelectrical equipment and may cause electrical shorts. Take precautionary measuresagainst static discharge.Storage:Keep in a dry, cool and well-ventilated place. Keep away from heat and sources of ignition. Do not store together with strong oxidizing agents. Do not store together with volatile chemicals as they may be adsorbed onto product. Keep in properly labeled containers.7. PHYSICAL AND CHEMICAL PROPERTIESAppearance: Black PelletsOdor: NonepH: 7-10（non-oxidized carbon black）Density: 1.7 - 1.9 g/cm³ @ 20°CBulk Density: 20 - 550 kg/m3Specific Gravity: Not determinedBoiling Point/Range: Not applicableMelting Point/Range: Not applicableVapor Pressure: Not determinedWater Solubility: Soluble% Volatile (by Weight): < 2.5% @ 950°C (non-oxidized carbon black)Evaporation Rate: Not applicableViscosity: Not determinedPartition Coefficient (n-octanol/water): Not determinedFlash Point: Not applicableMethod: Not applicableExplosion Limits in Air - Upper (%): Not determinedExplosion Limits in Air - Lower (%): 50 g/m3 (dust)Autoignition Temperature: > 140°C (transport)3Method: IMDG-CodeMinimum Ignition Temperature: > 350°C (BAM Furnace)Burn Velocity: > 45 seconds(Not cl assifiable as "Highly Flammable” or "Easily Ignitable") Flammability Classification: Not applicable8. STABILITY AND REACTIVITYStability: Stable.Reactivity: May react exothermically upon contact with strong oxidizersIncompatible Materials: Strong oxidizers such as chlorates, bromates, and nitrates.Hazardous Polymerization: Hazardous polymerization does not occur.Mechanical Sensitivity (shock): Not sensitive to mechanical impact.Conditions to Avoid: Do not expose to temperatures above 300°C. Keep away from oxidizing agents in order to avoid exothermic reactions.Hazardous Decomposition and/or Combustion Products:Carbon monoxide, Carbon dioxide, Oxides of sulphur, Organic products ofdecomposition.Static Discharge Effects: Take precautionary measures against static discharges. Avoid dust formation. All metal parts of the mixing and processing equipment must be earthed/grounded. Ensure all equipment is electrically earthed/grounded before beginning transfer operations.9. TOXICOLOGICAL INFORMATIONACUTE TOXICITYOral LD50: LD50/oral/rat = > 8000 mg/kg.Eye Irritation: Rabbit. Draize score 10-17/110 @ 24 hr. Non-irritating.Skin Irritation: Rabbit. 0.6/8. Slight irritation.SUBCHRONIC TOXICITYRat, inhalation, duration 90 daysNOAEL = 1.0 mg/m3Target organ: lungsEffect: inflammation, hyperplasia, fibrosis.CHRONIC TOXICITYRat, oral, duration: 2 yearsEffect: no tumorsMouse, oral, duration: 2 years4Effect: no tumorsMouse, dermal, duration: 18 monthsEffect: no skin tumorsRat, inhalation, duration: 2 yearsTarget organ: lungsEffect: inflammation, fibrosis, tumorsNote: Tumors in the rat lung are related to the fine particle overload phenomenon rather than to a specific chemical effect of the dust particles in the lung. These effects in rats have been reported in studies on other inorganic insoluble particles and appear to be species specific. Tumors have not been observed in other species (i.e., mouse and hamster) for other insoluble particles under similar circumstances and study conditions.Carcinogenic Effects: Substance listed by IARC (International Agency for Research on Cancer). Does not contain any substances listed by NTP (National Toxicology Program), OSHA (Occupational Safety and Health Administration), ACGIH (American Conference for Governmental Industrial Hygienists) or EU (European Union).Carbon Black IARC Statement: In 1995 International Agency for Research on Cancer (IARC) concluded, "There is inadequate evidence in humans for the carcinogenicity of carbon black." Based on rat inhalation studies, IARC concluded that there is "sufficient evidence in experimental animals for the carcinogenicity of carbon black", resulting in their classifying carbon black as "possibly carcinogenic to humans (Group 2B)".Carbon black is not designated a carcinogen by the U.S. National Toxicology Program (NTP), the U.S. Occupational Safety and Health Administration (OSHA), the American Conference of Governmental Industrial Hygienists (ACGIH) or the European Union (EU).The U.S. National Institute of Occupational Safety and Health (NIOSH) 1978 criteria document on carbon black recommends that only carbon blacks with polycyclic aromatic hydrocarbon (PAH) levels greater than 0.1% require the measurement of PAHs in air. As some PAHs are possible human carcinogens, NIOSH recommends an exposure limit of 0.1 mg/m3 for PAHs in air, measured as the cyclohexane-extractable fraction.Epidemiology: Results of epidemiological studies of carbon black production workers suggest that cumulative exposure to carbon black may result in small decrements in lung function, as measured by FEV1. In addition to normal age related decline in the FEV1 of approximately 1200 ml over 40 years, according to a European investigation, exposure to 1 mg/m3 (inhalable fraction) of carbon black over a 40-year lifetime will result in an additional 48 milliliter (ml) decline in FEV1. Asimilar morbidity study in the United States suggested a 27 ml decline in FEV1 from a 1mg/m3 exposure over a 40-year period. The relationship between symptoms and exposure to carbon black is less clear. In the U.S. study, 9% of the highest exposure group (in contrast to 5% of the unexposed group) reported symptoms consistent with chronic bronchitis. In the European study, methodological limitations in the administration of the questionnaire limit the drawing of definitive conclusions about symptoms. This study, however, indicated a link between carbon black and small opacities on the chest films, with negligible effects on lung function. A study of carbon black workers in the UK showed an elevated incidence of lung cancer but it was not considered to be related to carbon black exposure. A study of workers at a large German carbon black manufacturing facility found increased lung cancer mortality among German carbon black workers, but found no apparent dose-response relationship between lung cancer mortality and several indicators of occupational exposure, including years of employment and carbon black exposure. The study concluded that the high lung cancer mortality could not be fully explained by selection, smoking, or other occupational risk factors, but the results also provided little evidence for an effect from carbon black exposure. A recent mortality study of US carbon black workers found no association between employment in carbon black production and lung cancer or any other type of cancer.Mutagenic Effects: A dimethylsulfoxide (DMSO) suspension of carbon black produced negative results in an Ames test. Organic solvent extracts of carbon black, however, can contain traces of5polycylic aromatic hydrocarbons (PAH), which may affect the results in different in-vitro test systems. In an experimental investigation, mutational changes in the hprtgene were reported in alveolar epithelial cells in the rat following inhalation exposure to carbon black. This observation is believed to be rat specific and a consequence of "lung overload" (see Chronic Toxicity above).Reproductive Toxicity: Did not show effects in animal experiments.Sensitizing Effects: Contains no known sensitizers.Synergistic Materials: None reasonably foreseeable.10. ECOLOGICAL INFORMATIONAquatic Toxicity:Fish (Brachydanio rerio): LC50 (96hr) > 1,000 mg/L. (Method: OECD 203).Daphnia magna: EC50 (24hr) > 5,600 mg/L. (Method: OECD 202).Algae (Scenedesmus subspicatus): EC50 (72hr) > 10,000 mg/L.Algae (Scenedesmus subspicatus): NOEC >= 10,000 mg/L.Activated sludge: EC0 (3hr) >= 800 mg/L. (Method: DEV L3 TTC test).ENVIRONMENTAL FATEMobility: Not expected to migrate. Insoluble.Bioaccumulation: Not expected due to physicochemical properties of the substance.Persistence / Degradability: Not expected to degrade.Distribution to Environmental Compartments: Insoluble. Expected to remain on soil surface.11. DISPOSAL CONSIDERATIONSProduct, as supplied, should be disposed of in accordance with the regulations issued by the appropriate federal, state and local authorities. Same consideration should be given to containers and packaging.12. TRANSPORT INFORMATIONThe following organizations do not classify carbon black as a "hazardous cargo" if it is "carbon,non-activated, mineralorigin". Cabot carbon blacks meets this definition.- Canadian Transport of Dangerous Goods Regulation- European Transport of Dangerous Goods Regulation- GGVS, GGVE, RID, ADR, IMDG Code, ICAO-TI- United Nations (no UN number)- US Department of TransportationCAS NO 1333-86-4UN Number: 1361UN Proper Shipping Name: Not classifiedUN Shipping Class: Not classified6UN Packing Group: Not classifiedInternational TransportationIdentification:"Carbon black, non-activated, mineral origin".Not dangerous according to IMDG-Code.Not dangerous according to ICAO-TI.US Rail Regulations: Not classified13. ACCIDENTAL RELEASE MEASURESPersonal Precautions: CAUTION: Wet carbon black produces slippery walking surfaces. Avoid dust formation. Ensure adequate ventilation. Use personal protective equipment. See alsoSection 8.Methods for Cleaning Up: Clean up promptly by vacuum. Use of a vacuum with high efficiency particulate air(HEPA) filtration is recommended. Do not create a dust cloud by using a brush orcompressed air. Pick up and transfer to properly labelled containers. See Section 13.Environmental Precautions: Do not allow material to contaminate ground water system. The product is insolubleand floats on water. If possible, try to contain floating material. Local authoritiesshould be advised if significant spillages cannot be contained.14. EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE LIMITSThe table below is a summary. Please see the specific legislation for complete information.Carbon Black, CAS RN 1333-86-4: Australia: 3.0 mg/m3, TWABelgium - OEL: 3.6 mg/m3, TWACanada: 3.5 mg/m3, TWAChina: 4.0 mg/m3, TWA8.0 mg/m3, STELFinland: 3.5 mg/m3, TWA7.0 mg/m3, STELFrance - INRS: 3.5 mg/m3, TWA/VMEGermany - TRGS 900: 3.0 mg/m3, respirable TWA10.0 mg/m3, inhalable TWAGermany - MAKs: 1.5 mg/m3, respirable TWA4.0 mg/m3, inhalable TWAIreland: 3.5 mg/m3, TWA7.0 mg/m3, STELItaly - OEL: 3.5 mg/m3, TWAKorea: 3.5 mg/m3, TWANetherlands - MAC: 3.5 mg/m3, TWA7Norway: 3.5 mg/m3, TWASpain: 3.5 mg/m3, TWASweden - TLV: 3.0 mg/m3, TWAUnited Kingdom - WEL: 3.5 mg/m3, inhalable TWA (a)7.0 mg/m3, inhalable STELUS ACGIH - TLV: 3.5 mg/m3, TWAUS OSHA - PEL: 3.5 mg/m3, TWANote: Unless otherwise indicated as "respirable" or "inhalable", the exposure limitrepresents a "total" value. The inhalable exposure limit has been demonstrated to bemore restrictive than the total exposure limit, by a factor of approximately 3.15. STABILITY AND REACTIVITYStability: Stable.Reactivity: May react exothermically upon contact with strong oxidizers.Cabot Corporation___________________________________________________________________ ______Product Name: REGAL 250R Product Code: R250R Revision Date: 18/June/2007 Page 6 of 10 Incompatible Materials: Strong oxidizers such as chlorates, bromates, and nitrates.Hazardous Polymerization: Hazardous polymerization does not occur.Mechanical Sensitivity (shock): Not sensitive to mechanical impact.Conditions to Avoid: Do not expose to temperatures above 300°C. Keep away from oxidizing agents inorder to avoid exothermic reactions.Hazardous Decomposition and/orCombustion Products:Carbon monoxide, Carbon dioxide, Oxides of sulphur, Organic products ofdecomposition.Static Discharge Effects: Take precautionary measures against static discharges. Avoid dust formation. Allmetal parts of the mixing and processing equipment must be earthed/grounded.Ensure all equipment is electrically earthed/grounded before beginning transferoperations.16. OTHER INFORMATIONCarbon Black Extracts:Manufactured carbon blacks generally contain less than 0.1% of solvent extractable polycyclic aromatic hydrocarbons(PAH). Solvent extractable PAH content depends on numerous factors including, but not limited to, the manufacturingprocess, desired product specifications, and the analytical procedure used to measure and identify solvent extractable8materials. Questions concerning PAH content of carbon black and analytical procedures should be addressed to yourcarbon black supplier.General Information:The carbon black industry continues to sponsor research designed to identify adverse health effects from long termexposure to carbon black. This MSDS will be updated as new safety and health information may become available.9。

色素炭黑colrblack在油墨

色素炭黑colrblack在油墨————————————————————————————————作者：————————————————————————————————日期：色素炭黑color black 在油墨、油漆、涂料、塑料等制品中作着色颜料用的炭黑。

按着色强度（或黑度）和粒子大小一般分为高色素炭黑、中色素炭黑、普通色素炭黑和低色素炭黑四种。

主要是油炉法生产和槽法生产。

目录1用途2种类3特性4应用5制备6选购7原理8技术参数1用途编辑色素炭黑一般都能较好的给塑料着色，可根据着色特性或物化性能选用色素炭黑，着色用炭黑的品种的选择基本上都是随成品必须达到的黑度而定。

用极细的色素炭黑可以完成黑度要求特别高的着色；PE垃圾袋，塑料袋，电缆材料之类产品只需中等水平黑度，可以用比表面积较低，结构较高的炭黑品种；塑料调色时，炭黑称量和配料时出现的微小误差，均会导致明显的色差，因此，宜采用粒径较大，着色力较差的低色素炭黑，这样炭黑用量可以稍大，称量误差相对小些，并有分散性较好、价格较低的优点。

对于灰色塑料，采用细粒色素炭黑往往呈现棕相灰色，而采用粗粒子色素炭黑可产生蓝相灰色。

2种类编辑因为色素炭黑作为一种黑色颜料，在市场上有着较为广泛的应用，现将其用途详细明细；密封胶类：汽车密封胶专用、建筑密封胶专用、船舶密封胶专用，集装箱密封胶，工业密封胶胶专用，防水密封胶用，热熔胶用，中空玻璃密封胶用，色素碳黑中空玻璃丁基胶用，中性防霉硅酮密封胶用，铜密封胶用，聚氨脂密封胶用，中性玻璃密封胶用,密封胶条用，酸性硅酮密封胶用，丁基密封胶用。

色浆类：黑合成革色浆用，印花色浆用，水性色浆用，造纸色色素碳黑(2张)浆用，苹果袋纸用，PVC色浆专用，PU色浆用，油性色浆专用。

色母类：色素碳黑(鞋材EVA发泡用) ,色素碳黑无卤电缆料专用,（塑料发泡专用）色素炭黑，色素碳黑吹膜色母用，色素碳黑塑料色母用，色素碳黑PVC电缆料用，色素碳黑PVC 胶粒用，色素碳黑涤纶母粒用,色素碳黑高光泽蓝相色母用，色素碳黑化纤色母用，色素碳黑短纤色母用，色素碳黑压延膜用，色素碳黑PE电缆料用。

炭黑msds

呼吸系统防护
如果工作地通风不良，需配备合适的呼吸保护设备。
眼睛防护
使用眼部和面部防护：有两侧防护的安全眼镜。
身体防护
穿着合适的防护服，每天清洗服装。污染的工作服不允许带出厂。
手防护
戴手套防止手弄脏，反复接触可能造成皮肤干燥或开裂。在处理本产品前可用油膏护手。
其他防护
用良好工业卫生及安全实践相一致的处理/操作方法进行日常的操作。附近可设置京戏急洗眼和冲洗设备。
强氧化剂
分解产物
聚合危害
避免接触的条件
11.毒理学资料
急性毒性
LD50：致癌。 IARC评价：3组，未分类物质；人类资料不足；动物证据不充分 IDLH：1750mg／m3 OSHA表Z—1空气污染物：以炭黑提取物计 NIOSH标准文件：NIOSH 78—204LC50：
其他
12.生态学资料
其他有害作用
燃烧危险
4.急救措施
皮肤接触
用肥皂和水清洗，如果皮肤发红，水肿，发痒或灼伤。就医。
眼睛接触
用大量的水立即冲洗眼睛15分钟。如果发红，水肿，发痒，灼伤或视觉模糊就医。
吸入
不必催吐。如果清醒的，饮几杯水。不要通过嘴给不清醒的人任何东西。
食入
5.消防措施
危险特性
燃烧会产生刺激烟雾。本品不溶于水并浮于水。如可能，除去漂浮物，原因是漂浮物构成流动火灾的危险。
消除方法
7.操作处置与储存
操作
注意事项
储存
注意事项
避免接触禁忌物，严禁烟火。须贴“自燃”标签，严禁航空、铁路运输。 ERG指南：133 ERG指南分类：易燃固体
8.接触控制/个体防护
最高容许浓度
4mg/m3TWA 8mg/m3STEL

色素碳黑的介绍

平均原生粒径
表面化学
结构
Page | 15
不同颜料的平均粒径大小比较
酞氰蓝
LB 101
钛白粉 FW 200
汉沙黄
氧化铁红
Page | 16
原生粒径对碳黑性能的影响
100 nm 100 纳米
10 nm
主色
黑度色相
10 纳米
较低红相
较高蓝相
调色
较弱蓝相较容易较低较高着色力色相分散性吸油量颜料添加量较强
红相较困难
较高较低
Page | 17
原生粒径对黑度的影响
(醇酸氨基烤漆, 5% 碳黑基于树脂固含)
Page | 18
原生粒径对着色力的影响
粒径, nm
120 100 80 60 40
13nm 25nm 50nm 30 65 110 101 95nm
相对着色力, %
20 0 Colour Black FW2 Special Black 4 Special Black 100 Lamp Black 101
250 200 150 100 50 0
6 Pr 4 in te x U U SA 3 U SA 4 Ja 1 pa n 1 U SA 2 1 20 0 2 SS FW FW FW U SA SS
Haze
Page | 42
议程
色素炭黑一般介绍色素碳黑的生产工艺色素碳黑的特性对涂料的影响其它影响碳黑性能的因素色素碳黑的推荐
特黑 6, 5
高色素气黑，有很高的蓝相
特黑 4, 4A
普通色素气黑，易于分散
Page | 45
用于涂料工业的未氧化气黑

炭黑 MSDS

材料安全数据表
1.化学品及企业信息
化学品中文名称
炭黑
编码
111
俗名/商品名
炭黑
生效日期
化学品英文名称
calcium hypochlorite
企业名称
上海卡博特化工有限公司
企业应急电话
地址
邮编
国家应急电话
传真
电子邮件地址
2.成分/组成信息
主要成分
■纯品 □混合物
危害成分
浓度
CASNo.
1333-86-4
填表时间
2010-07-27
修改说明
重新编码
有害燃烧物
一氧化碳，二氧化碳硫的氧化物
灭火方法
及灭火剂
注意事项
使用与所在地环境情况相适合的灭火方法。如果用水，建议用喷雾水。不能用强力的直流水，直流水会分散火源。
粉尘爆炸的风险
粉尘与空气混合可能形成爆炸混合物，禁止使用掸，拂或者高压空气吹扫粉尘，避免形成粉尘团。
6.泄露应急处理
应急处理
须穿戴防护用具进入现场；排除一切火情隐患；用简便、安全的方法收集粉尘于密闭的容器内，待处理。环境信息：应急计划和社区知情权法：款313表R，最低应报告浓度 0．1％。
呼吸系统防护
如果工作地通风不良，需配备合适的呼吸保护设备。
眼睛防护
使用眼部和面部防护：有两侧防护的安全眼镜。
身体防护
穿着合适的防护服，每天清洗服装。污染的工作服不允许带出厂。
手防护
戴手套防止手弄脏，反复接触可能造成皮肤干燥或开裂。在处理本产品前可用油膏护手。
其他防护
用良好工业卫生及安全实践相一致的处理/操作方法进行日常的操作。附近可设置京戏急洗眼和冲洗设备。

炭黑MSDS通用安全技术说明书

化学品安全技术说明书1、企业资质认证产品名称：N炭黑别名：炭黑，炉法炭黑材料应用：各种工业产品供应商：炭黑有限公司地址：中国68号联系电话： 666 传真： 8882、炭黑的组成成分3、危险性概述危害显示：本品为非危险物品主要接触途径：吸入，眼睛接触，皮肤接触。

潜在的健康影响：眼睛接触：可能引起机械刺激。

但是不会永久的伤害眼膜。

对于平常的工业或商业接触有较低的危害。

皮肤接触：无已知的不良反应。

吸入：粉尘可能刺激呼吸道。

应对机器设备和能够产生灰尘的地方提供适当的排气通风。

另请参阅第8部分。

食入：正常使用下不会出现已知的健康损伤。

对于平常的工业或商业接触只有较低的危害。

致癌影响：国际癌症研究机构列出的物品。

另请参阅第9部分。

主要影响器官：肺。

暴露恶化的疾病：哮喘，呼吸障碍潜在的环境影响：不需要特别的环境预防措施。

不溶解于水。

另请参阅第12部分。

4、急救措施皮肤接触：应用肥皂和水彻底清洗。

若症状加重，请就医。

眼睛接触：应立即用大量的水冲洗眼睛15分钟。

若症状加重，请就医。

吸入：如果咳嗽，呼吸急促或者发生其他呼吸问题，请移到其他地方呼吸新鲜空气。

若症状无好转，请就医。

如果有必要的话，请通过标准的急救措施来恢复正常呼吸。

食入：不要催吐，如清醒，给予几杯水，千万不要给休克的人通过口腔喂任何东西。

医生提示：请根据症状处理。

5、消防措施灭火器：应使用泡沫，二氧化碳，干粉或者水喷雾。

如果已经使用过水，推荐使用水雾。

不要使用强直流水，因为它可能溅射扩散火苗。

消防员的特殊防护装备：要穿戴合适的防护装备。

发生火灾时，应佩带独立的呼吸设备。

具体危害：炭黑燃烧时可能不明显，除非搅拌时出现火花。

对已经着火的炭黑，我们应该严密地观察至少48小时以确保无隐燃存在。

燃烧会产生刺激性的烟气。

该产品不能溶解的，并且漂浮在水上。

如果可能，设法控制悬浮物质。

该物质会产生火灾隐患，因为它漂浮在水上。

分解或燃烧产生的危害物：一氧化碳，二氧化碳，硫的氧化物，分解的有机产物。

炭黑说明书

色素炭黑的安全技术说明书（MSDS）第一部分：化学品名称和公司中文名称1：色素炭黑英文名称1：color pigment carbonCAS No.：1333-86-4分子式：C 分子量：12第二部分：成分/组成信息主要成分：碳（C）元素含量（Wt%）≥93%；含氧基团含量（Wt%）≤7%。

有害物成分：多环芳烃（PAH）（CAS No.¡ ）含量（Wt%）≤0.001%砷（As）（CAS No.7440-38-2）含量（Wt%）≤0.0001%镉（Cd）（CAS No.7440-43-9）含量（Wt%）≤0.00001%汞（Hg）（CAS No.7439-97-6）含量（Wt%）≤0.0001%铅（Pb）（CAS No.7439-92-1）含量（Wt%）≤0.0001%铬（Cr）（CAS No.7440-47-3）含量（Wt%）≤0.001%（资讯来源：昊客云台，上面更多产品知识，行业资讯热点）第三部分：危险性概述危险性类别：未列入侵入途径：呼吸道吸入、眼睛、皮肤健康危害：长期大量地由呼吸道吸入炭黑粉尘，可能最终造成对肺部的损伤。

目前，没有明确的医学报道证明炭黑会引起癌变的结果。

但可以列入如人类的可能致癌的物质。

对眼睛的损伤主要症状是异物刺激感、流泪。

对皮肤主要是皮肤的弄脏和刺激环境危害：炭黑的外泄暴露，除了会弄脏周围环境外没有发现会对环境造成严重的影响或损害。

燃爆危险：在本品工作场所若形成纯炭黑的粉尘环境，可能造成粉尘爆炸。

本品不是易燃物，一般不会被点燃，若较长时间地处于30０℃以上则可能会无明火地缓慢燃烧，同时释出一氧化碳、二氧化碳或极少量的含氮、硫氧化物。

第四部分：急救措施据昊客云台产品经理安全介绍：吸入：1. 立即将被污染的患者转移到有大量新鲜空气的场所。

眼睛接触：1. 立即撑开患者被污染眼睛的眼皮用缓和流动的温水冲洗至少5 分钟以上。

2. 用医用¡ 金霉素¡ 眼药膏涂抹患者眼睛。

色素炭黑面面观

色素炭黑面面观色素炭黑：在涂料、油墨、塑料、化纤和皮革化工中作为着色剂使用，其主要功能是着色，这类碳黑都可称作为色素碳黑。

中国国家标准GB/T 7044—1993《色素炭黑技术条件》规定了色素炭黑的分类和品种名称及其代号。

一般分为高、中、低色素三类。

如按其黑度和制造方法则可分为：高色素槽黑（HCC）、高色素炉黑（HCF）、中色素槽黑（MCC）、中色素炉黑（MCF）、普通色素槽黑（RCC）、普通色素炉黑（RCF）和低色素炉黑（LCF）。

色素炭黑color black 在油墨、油漆、涂料等制品中作着色颜料用的炭黑。

按着色强度(或黑度)和粒子大小一般分为高色素炭黑、中色素炭黑、普通色素炭黑和低色素炭黑四种。

主要由接触法和油炉法生产。

主要的生产工艺有：炉法、槽法和热裂解法。

90%的炭黑作为橡胶的补强材料使用，约有10%的色素炭黑产品用于塑料改性。

炭黑的几个典型参数黑度（反射率）—炭黑黑度通常以“反射率测定仪”测定的数据来表示，在大部分情况下也反映了该炭黑的原始粒径，是衡量该炭黑市场价格的重要参数之一。

反射率越低，炭黑黑度越高，粒径也越小。

反之亦然。

挥发份—炭黑表面携带含氧基团的数量，反映了炭黑的表面物理性能、电化学性能和应用性能，也是衡量该炭黑市场价格的重要参数之一。

结构—炭黑结构是炭黑微粒子聚集体形成的链枝程度的表征值，它表示了炭黑内部的空隙程度。

通常以吸油值（DBP吸收值）表示。

炭黑分散的重要的意义颜料在应用过程中都必须分散到符合光学性能的微粒子状态，炭黑是所有颜料中最难分散的一种颜料之一，因此炭黑分散的好坏会直接影响到炭黑的黑度、色相和遮盖能力，直接影响到用户最终的使用效果。

色素炭黑分散不好易出现的情况色素炭黑分散的目的是使其在载体中处于一种均匀的分布状态，这种分布程度的不同，会直接影响到制品的色相、黑度和遮盖力。

炭黑的分散主要受制于三个因素：色素炭黑原始粒子的大小，结构的高低等性能；载体或分散介质的类型，加入分散剂后，会涂覆在炭黑粒子的表面，从而在一定程度上降低炭黑粒子之间的内聚力，有助于炭黑的分散；所使用的分散设备类型。

色素炭黑的安全注意事项

色素炭黑的安全注意事项
色素炭黑是一种黑色颜料，常用于化妆品、食品、药品等领域。

虽然在这些领
域中得到广泛应用，但是我们在接触和使用色素炭黑时，也需要注意一些安全事项。

1. 使用前的检查
在使用色素炭黑之前，我们需要仔细检查产品标签和说明书。

如果有任何质量
问题或者过期，均不得使用。

2. 避免过敏
有些人可能对色素炭黑过敏，尤其是在化妆品领域，因此在使用前需要先做一
次皮肤测试。

将少量的产品涂抹在耳后或者手腕内侧，观察它是否会导致过敏反应。

如有过敏反应，应立即停止使用。

3. 避免接触眼睛
色素炭黑如果接触到眼睛，会导致疼痛、眼红或者视力模糊等情况。

因此在使
用时，一定要避免接触到眼睛。

如有不慎接触到眼睛，应立即用大量清水冲洗，如情况严重应及时就医。

4. 避免吸入
使用色素炭黑时，应该避免且预防吸入。

为了减少吸入风险，应在操作时佩戴
防护口罩。

5. 避免误食
色素炭黑看起来与咖啡和可可粉非常相似，但是如果误食会导致严重健康危害。

因此，在存储和使用时，应将其远离儿童和宠物，以免误食。

6. 注意存储
色素炭黑应该存放在阴凉、干燥的地方，并且避免受到阳光直射。

同时，要注
意防潮、防火和防爆。

总结
使用色素炭黑时，需要注意以上安全事项。

遵循这些安全措施，能够减少事故
发生的风险，同时确保您的健康和安全。

炭黑英文msds

﹡﹡﹡MATERIAL SAFETY DATA SHEET﹡﹡﹡1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THECOMPANY/UNDERTAKINGProduct Name: CARBON BLACK N330Synonyms: Carbon Black, Furnace BlackUse of the Substance/Preparation: Various, Industrial ProductsSupplier:Carbon Black Co. ,Ltd.City, ChinaTEL: FAX:02. HAZARDS IDENTIFICATIONIndication of danger: Hazardous according to the Worksafe Australia designated list of hazardous substances.Xn - Harmful.C3 - Carcinogen Category 3.Principle Routes of Exposure: Inhalation, Eye contact, Skin contactPOTENTIAL HEALTH EFFECTSEye Contact:May cause mechanical irritation. Irritating, but will not permanently injure eye tissue.Low hazard for usual industrial or commercial handling.Skin Contact:No adverse effects expected.Inhalation:Dust may be irritating to respiratory tract. Provide appropriate exhaust ventilation at machinery and at places where dust can be generated. See also Section 8.Ingestion:Health injuries are not known or expected under normal use. Low hazard for usual industrial or commercial handling.Carcinogenic Effects:Substance listed by IARC (International Agency for Research on Cancer). See also Section 9.Target Organ Effects:LungsMedical Conditions Aggravated by Exposure:Asthma, Respiratory disorder1Potential Environmental Effects:No special environmental precautions required. Not soluble in water. See also Section 12.4. FIRST AID MEASURESSkin Contact:Wash thoroughly with soap and water. Seek medical attention if symptoms develop.Eye Contact:Flush eyes immediately with large amounts of water for 15 minutes. Seek medical attention if symptoms develop.Inhalation:If cough, shortness of breath or other breathing problems occur, move to fresh air.Seek medical attention if symptoms persist. If necessary, restore normal breathing through standard first aid measures.Notes to Physician:Treat symptomatically.5. FIRE-FIGHTING MEASURESExtinguishing Media:Use foam, carbon dioxide (CO2), dry chemical or water spray. A fog is recommended if water is used. DO NOT USE a solid water stream as it may scatter and spread fire.Special Protective Equipment for Firefighters:Wear suitable protective equipment. In the event of fire, wear self-contained breathing apparatus.Specific Hazards:It may not be obvious that carbon black is burning unless the material is stirred and sparks are apparent. Carbon black that has been on fire should be observed closely for at least 48 hours to ensure no smoldering material is present. Burning produces irritant fumes. The product is insoluble and floats on water. If possible, try to contain floating material. This material creates a fire hazard because it floats on water.Hazardous Decomposition and/or Combustion Products:Carbon monoxide, Carbon dioxide, Oxides of sulphur, Organic products of decomposition.Risk of Dust Explosion:Do not create a dust cloud by using a brush or compressed air.26. HANDLING AND STORAGEHandling:Avoid contact with skin and eyes. Do not breathe dust. Provide appropriate exhaust ventilation at machinery and at places where dust can be generated. Do not create adust cloud by using a brush or compressed air. Fine dust is capable of penetratingelectrical equipment and may cause electrical shorts. Take precautionary measuresagainst static discharge.Storage:Keep in a dry, cool and well-ventilated place. Keep away from heat and sources of ignition. Do not store together with strong oxidizing agents. Do not store together with volatile chemicals as they may be adsorbed onto product. Keep in properly labeled containers.7. PHYSICAL AND CHEMICAL PROPERTIESAppearance: Black PelletsOdor: NonepH: 7-10（non-oxidized carbon black）Density: 1.7 - 1.9 g/cm³ @ 20°CBulk Density: 20 - 550 kg/m3Specific Gravity: Not determinedBoiling Point/Range: Not applicableMelting Point/Range: Not applicableVapor Pressure: Not determinedWater Solubility: Soluble% Volatile (by Weight): < 2.5% @ 950°C (non-oxidized carbon black)Evaporation Rate: Not applicableViscosity: Not determinedPartition Coefficient (n-octanol/water): Not determinedFlash Point: Not applicableMethod: Not applicableExplosion Limits in Air - Upper (%): Not determinedExplosion Limits in Air - Lower (%): 50 g/m3 (dust)Autoignition Temperature: > 140°C (transport)3Method: IMDG-CodeMinimum Ignition Temperature: > 350°C (BAM Furnace)Burn Velocity: > 45 seconds(Not cl assifiable as "Highly Flammable” or "Easily Ignitable") Flammability Classification: Not applicable8. STABILITY AND REACTIVITYStability: Stable.Reactivity: May react exothermically upon contact with strong oxidizersIncompatible Materials: Strong oxidizers such as chlorates, bromates, and nitrates.Hazardous Polymerization: Hazardous polymerization does not occur.Mechanical Sensitivity (shock): Not sensitive to mechanical impact.Conditions to Avoid: Do not expose to temperatures above 300°C. Keep away from oxidizing agents in order to avoid exothermic reactions.Hazardous Decomposition and/or Combustion Products:Carbon monoxide, Carbon dioxide, Oxides of sulphur, Organic products ofdecomposition.Static Discharge Effects: Take precautionary measures against static discharges. Avoid dust formation. All metal parts of the mixing and processing equipment must be earthed/grounded. Ensure all equipment is electrically earthed/grounded before beginning transfer operations.9. TOXICOLOGICAL INFORMATIONACUTE TOXICITYOral LD50: LD50/oral/rat = > 8000 mg/kg.Eye Irritation: Rabbit. Draize score 10-17/110 @ 24 hr. Non-irritating.Skin Irritation: Rabbit. 0.6/8. Slight irritation.SUBCHRONIC TOXICITYRat, inhalation, duration 90 daysNOAEL = 1.0 mg/m3Target organ: lungsEffect: inflammation, hyperplasia, fibrosis.CHRONIC TOXICITYRat, oral, duration: 2 yearsEffect: no tumorsMouse, oral, duration: 2 years4Effect: no tumorsMouse, dermal, duration: 18 monthsEffect: no skin tumorsRat, inhalation, duration: 2 yearsTarget organ: lungsEffect: inflammation, fibrosis, tumorsNote: Tumors in the rat lung are related to the fine particle overload phenomenon rather than to a specific chemical effect of the dust particles in the lung. These effects in rats have been reported in studies on other inorganic insoluble particles and appear to be species specific. Tumors have not been observed in other species (i.e., mouse and hamster) for other insoluble particles under similar circumstances and study conditions.Carcinogenic Effects: Substance listed by IARC (International Agency for Research on Cancer). Does not contain any substances listed by NTP (National Toxicology Program), OSHA (Occupational Safety and Health Administration), ACGIH (American Conference for Governmental Industrial Hygienists) or EU (European Union).Carbon Black IARC Statement: In 1995 International Agency for Research on Cancer (IARC) concluded, "There is inadequate evidence in humans for the carcinogenicity of carbon black." Based on rat inhalation studies, IARC concluded that there is "sufficient evidence in experimental animals for the carcinogenicity of carbon black", resulting in their classifying carbon black as "possibly carcinogenic to humans (Group 2B)".Carbon black is not designated a carcinogen by the U.S. National Toxicology Program (NTP), the U.S. Occupational Safety and Health Administration (OSHA), the American Conference of Governmental Industrial Hygienists (ACGIH) or the European Union (EU).The U.S. National Institute of Occupational Safety and Health (NIOSH) 1978 criteria document on carbon black recommends that only carbon blacks with polycyclic aromatic hydrocarbon (PAH) levels greater than 0.1% require the measurement of PAHs in air. As some PAHs are possible human carcinogens, NIOSH recommends an exposure limit of 0.1 mg/m3 for PAHs in air, measured as the cyclohexane-extractable fraction.Epidemiology: Results of epidemiological studies of carbon black production workers suggest that cumulative exposure to carbon black may result in small decrements in lung function, as measured by FEV1. In addition to normal age related decline in the FEV1 of approximately 1200 ml over 40 years, according to a European investigation, exposure to 1 mg/m3 (inhalable fraction) of carbon black over a 40-year lifetime will result in an additional 48 milliliter (ml) decline in FEV1. Asimilar morbidity study in the United States suggested a 27 ml decline in FEV1 from a 1mg/m3 exposure over a 40-year period. The relationship between symptoms and exposure to carbon black is less clear. In the U.S. study, 9% of the highest exposure group (in contrast to 5% of the unexposed group) reported symptoms consistent with chronic bronchitis. In the European study, methodological limitations in the administration of the questionnaire limit the drawing of definitive conclusions about symptoms. This study, however, indicated a link between carbon black and small opacities on the chest films, with negligible effects on lung function. A study of carbon black workers in the UK showed an elevated incidence of lung cancer but it was not considered to be related to carbon black exposure. A study of workers at a large German carbon black manufacturing facility found increased lung cancer mortality among German carbon black workers, but found no apparent dose-response relationship between lung cancer mortality and several indicators of occupational exposure, including years of employment and carbon black exposure. The study concluded that the high lung cancer mortality could not be fully explained by selection, smoking, or other occupational risk factors, but the results also provided little evidence for an effect from carbon black exposure. A recent mortality study of US carbon black workers found no association between employment in carbon black production and lung cancer or any other type of cancer.Mutagenic Effects: A dimethylsulfoxide (DMSO) suspension of carbon black produced negative results in an Ames test. Organic solvent extracts of carbon black, however, can contain traces of5polycylic aromatic hydrocarbons (PAH), which may affect the results in different in-vitro test systems. In an experimental investigation, mutational changes in the hprtgene were reported in alveolar epithelial cells in the rat following inhalation exposure to carbon black. This observation is believed to be rat specific and a consequence of "lung overload" (see Chronic Toxicity above).Reproductive Toxicity: Did not show effects in animal experiments.Sensitizing Effects: Contains no known sensitizers.Synergistic Materials: None reasonably foreseeable.10. ECOLOGICAL INFORMATIONAquatic Toxicity:Fish (Brachydanio rerio): LC50 (96hr) > 1,000 mg/L. (Method: OECD 203).Daphnia magna: EC50 (24hr) > 5,600 mg/L. (Method: OECD 202).Algae (Scenedesmus subspicatus): EC50 (72hr) > 10,000 mg/L.Algae (Scenedesmus subspicatus): NOEC >= 10,000 mg/L.Activated sludge: EC0 (3hr) >= 800 mg/L. (Method: DEV L3 TTC test).ENVIRONMENTAL FATEMobility: Not expected to migrate. Insoluble.Bioaccumulation: Not expected due to physicochemical properties of the substance.Persistence / Degradability: Not expected to degrade.Distribution to Environmental Compartments: Insoluble. Expected to remain on soil surface.11. DISPOSAL CONSIDERATIONSProduct, as supplied, should be disposed of in accordance with the regulations issued by the appropriate federal, state and local authorities. Same consideration should be given to containers and packaging.12. TRANSPORT INFORMATIONThe following organizations do not classify carbon black as a "hazardous cargo" if it is "carbon,non-activated, mineralorigin". Cabot carbon blacks meets this definition.- Canadian Transport of Dangerous Goods Regulation- European Transport of Dangerous Goods Regulation- GGVS, GGVE, RID, ADR, IMDG Code, ICAO-TI- United Nations (no UN number)- US Department of TransportationCAS NO 1333-86-4UN Number: 1361UN Proper Shipping Name: Not classifiedUN Shipping Class: Not classified6UN Packing Group: Not classifiedInternational TransportationIdentification:"Carbon black, non-activated, mineral origin".Not dangerous according to IMDG-Code.Not dangerous according to ICAO-TI.US Rail Regulations: Not classified13. ACCIDENTAL RELEASE MEASURESPersonal Precautions: CAUTION: Wet carbon black produces slippery walking surfaces. Avoid dust formation. Ensure adequate ventilation. Use personal protective equipment. See alsoSection 8.Methods for Cleaning Up: Clean up promptly by vacuum. Use of a vacuum with high efficiency particulate air(HEPA) filtration is recommended. Do not create a dust cloud by using a brush orcompressed air. Pick up and transfer to properly labelled containers. See Section 13.Environmental Precautions: Do not allow material to contaminate ground water system. The product is insolubleand floats on water. If possible, try to contain floating material. Local authoritiesshould be advised if significant spillages cannot be contained.14. EXPOSURE CONTROLS / PERSONAL PROTECTIONEXPOSURE LIMITSThe table below is a summary. Please see the specific legislation for complete information.Carbon Black, CAS RN 1333-86-4: Australia: 3.0 mg/m3, TWABelgium - OEL: 3.6 mg/m3, TWACanada: 3.5 mg/m3, TWAChina: 4.0 mg/m3, TWA8.0 mg/m3, STELFinland: 3.5 mg/m3, TWA7.0 mg/m3, STELFrance - INRS: 3.5 mg/m3, TWA/VMEGermany - TRGS 900: 3.0 mg/m3, respirable TWA10.0 mg/m3, inhalable TWAGermany - MAKs: 1.5 mg/m3, respirable TWA4.0 mg/m3, inhalable TWAIreland: 3.5 mg/m3, TWA7.0 mg/m3, STELItaly - OEL: 3.5 mg/m3, TWAKorea: 3.5 mg/m3, TWANetherlands - MAC: 3.5 mg/m3, TWA7Norway: 3.5 mg/m3, TWASpain: 3.5 mg/m3, TWASweden - TLV: 3.0 mg/m3, TWAUnited Kingdom - WEL: 3.5 mg/m3, inhalable TWA (a)7.0 mg/m3, inhalable STELUS ACGIH - TLV: 3.5 mg/m3, TWAUS OSHA - PEL: 3.5 mg/m3, TWANote: Unless otherwise indicated as "respirable" or "inhalable", the exposure limitrepresents a "total" value. The inhalable exposure limit has been demonstrated to bemore restrictive than the total exposure limit, by a factor of approximately 3.15. STABILITY AND REACTIVITYStability: Stable.Reactivity: May react exothermically upon contact with strong oxidizers.Cabot Corporation___________________________________________________________________ ______Product Name: REGAL 250R Product Code: R250R Revision Date: 18/June/2007 Page 6 of 10 Incompatible Materials: Strong oxidizers such as chlorates, bromates, and nitrates.Hazardous Polymerization: Hazardous polymerization does not occur.Mechanical Sensitivity (shock): Not sensitive to mechanical impact.Conditions to Avoid: Do not expose to temperatures above 300°C. Keep away from oxidizing agents inorder to avoid exothermic reactions.Hazardous Decomposition and/orCombustion Products:Carbon monoxide, Carbon dioxide, Oxides of sulphur, Organic products ofdecomposition.Static Discharge Effects: Take precautionary measures against static discharges. Avoid dust formation. Allmetal parts of the mixing and processing equipment must be earthed/grounded.Ensure all equipment is electrically earthed/grounded before beginning transferoperations.16. OTHER INFORMATIONCarbon Black Extracts:Manufactured carbon blacks generally contain less than 0.1% of solvent extractable polycyclic aromatic hydrocarbons(PAH). Solvent extractable PAH content depends on numerous factors including, but not limited to, the manufacturingprocess, desired product specifications, and the analytical procedure used to measure and identify solvent extractable8materials. Questions concerning PAH content of carbon black and analytical procedures should be addressed to yourcarbon black supplier.General Information:The carbon black industry continues to sponsor research designed to identify adverse health effects from long termexposure to carbon black. This MSDS will be updated as new safety and health information may become available.9。

炭黑MSDS通用安全技术说明书

化学品安全技术说明书1、企业资质认证产品名称：N炭黑别名：炭黑，炉法炭黑材料应用：各种工业产品供应商：炭黑有限公司地址：中国68号联系电话： 666 传真： 8882、炭黑的组成成分3、危险性概述危害显示：本品为非危险物品主要接触途径：吸入，眼睛接触，皮肤接触。

潜在的健康影响：眼睛接触：可能引起机械刺激。

但是不会永久的伤害眼膜。

对于平常的工业或商业接触有较低的危害。

皮肤接触：无已知的不良反应。

吸入：粉尘可能刺激呼吸道。

应对机器设备和能够产生灰尘的地方提供适当的排气通风。

另请参阅第8部分。

食入：正常使用下不会出现已知的健康损伤。

对于平常的工业或商业接触只有较低的危害。

致癌影响：国际癌症研究机构列出的物品。

另请参阅第9部分。

主要影响器官：肺。

暴露恶化的疾病：哮喘，呼吸障碍潜在的环境影响：不需要特别的环境预防措施。

不溶解于水。

另请参阅第12部分。

4、急救措施皮肤接触：应用肥皂和水彻底清洗。

若症状加重，请就医。

眼睛接触：应立即用大量的水冲洗眼睛15分钟。

若症状加重，请就医。

吸入：如果咳嗽，呼吸急促或者发生其他呼吸问题，请移到其他地方呼吸新鲜空气。

若症状无好转，请就医。

如果有必要的话，请通过标准的急救措施来恢复正常呼吸。

食入：不要催吐，如清醒，给予几杯水，千万不要给休克的人通过口腔喂任何东西。

医生提示：请根据症状处理。

5、消防措施灭火器：应使用泡沫，二氧化碳，干粉或者水喷雾。

如果已经使用过水，推荐使用水雾。

不要使用强直流水，因为它可能溅射扩散火苗。

消防员的特殊防护装备：要穿戴合适的防护装备。

发生火灾时，应佩带独立的呼吸设备。

具体危害：炭黑燃烧时可能不明显，除非搅拌时出现火花。

对已经着火的炭黑，我们应该严密地观察至少48小时以确保无隐燃存在。

燃烧会产生刺激性的烟气。

该产品不能溶解的，并且漂浮在水上。

如果可能，设法控制悬浮物质。

该物质会产生火灾隐患，因为它漂浮在水上。

分解或燃烧产生的危害物：一氧化碳，二氧化碳，硫的氧化物，分解的有机产物。

Pigmentcarbonblack（色素炭黑）

Pigment carbon black（色素炭黑）色素炭黑色素炭黑颜色黑色在油墨、油漆、涂料等制品中作着色颜料用的炭黑。

按着色强度（或黑度和粒子大小一般分为高色素炭黑、中色素炭黑、普通色素炭黑和低色素炭黑四种主要由接触法和油炉法生产）。

1）炭黑的几个典型参数黑度（反射率）--炭黑黑度通常以”反射率测定仪”测定的数据来表示，在大部分情况下也反映了该炭黑的原始粒径，是衡量该炭黑市场价格的重要参数之一。

反射率越低，炭黑黑度越高，粒径也越小。

反之亦然。

挥发份--炭黑表面携带含氧基团的数量，反映了炭黑的表面物理性能、电化学性能和应用性能，也是衡量该炭黑市场价格的重要参数之一。

结构--炭黑结构是炭黑微粒子聚集体形成的链枝程度的表征值，它表示了炭黑内部的空隙程度。

通常以吸油值（DBP吸收值）表示。

高、低结构炭黑与应用性能之间地关系示意图2）炭黑分散的重要的意义颜料在应用过程中都必须分散到符合光学性能的微粒子状态，炭黑是所有颜料中最难分散的一种颜料之一，因此炭黑分散的好坏会直接影响到炭黑的黑度、色相和遮盖能力，直接影响到用户最终的使用效果。

炭黑的分散过程主要受到三个因素的影响一）炭黑的本质特性：炭黑的原始粒径、结构和表面各种基团都会对分散产生很大的影响通常情况下炭黑的原始粒径小、结构低、挥发份低分散困难，反之则相对容易些。

b）使用者的配方：炭黑使用者的配方，基料、溶剂和树脂的性能都会非常显著地影响炭黑的最终分散情况，尤其是炭黑用树脂的选择。

C）分散设备：不同的分散设备在相同条件下的分散效果是完全不同的。

正确选用分散设备是使用者必须重视的。

3）选择炭黑的基本思路使用者在选择炭黑前首先要考虑的是：你想用炭黑来达到什么要求？着色、调色、抗紫外线还是起导电作用。

最重要的是一定要和炭黑的专业技术工程师进行沟通，共同对物料体系进行技术评价，选择比较合适的炭黑品种。

通常情况是：着色用--选择黑度高、粒径小的炭黑，但一定要保证炭黑经过合理的、完全的分散，否则反而会背道而驰，达不到原来要求。

炭黑msds

呼吸系统防护
如果工作地通风不良，需配备合适的呼吸保护设备。
眼睛防护
使用眼部和面部防护：有两侧防护的安全眼镜。
身体防护
穿着合适的防护服，每天清洗服装。污染的工作服不允许带出厂。
手防护
戴手套防止手弄脏，反复接触可能造成皮肤干燥或开裂。在处理本产品前可用油膏护手。
其他防护
用良好工业卫生及安全实践相一致的处理/操作方法进行日常的操作。附近可设置京戏急洗眼和冲洗设备。
有害燃烧物
一氧化碳，二氧化碳硫的氧化物
灭火方法
及灭火剂
注意事项
使用与所在地环境情况相适合的灭火方法。如果用水，建议用喷雾水。不能用强力的直流水，直流水会分散火源。
粉尘爆炸的风险
粉尘与空气混合可能形成爆炸混合物，禁止使用掸，拂或者高压空气吹扫粉尘，避免形成粉尘团。
6.泄露应急处理
应急处理
须穿戴防护用具进入现场；排除一切火情隐患；用简便、安全的方法收集粉尘于密闭的容器内，待处理。环境信息：应急计划和社区知情权法：款313表R，最低应报告浓度 0．1％。
消除方法
7.操作处置与储存
操作
注意事项
储存
注意事项
避免接触禁忌物，严禁烟火。须贴“自燃”标签，严禁航空、铁路运输。 ERG指南：133 ERG指南分类：易燃固体
8.接触控制/个体防护
最高容许浓度
4mg/m3TWA 8mg/m3STEL
监测方法
工程控制
保证正确的通风，控制暴露在职业卫生允许值以下。在产生粉尘的设备旁及工作地，提供合适的通风。
填表时间
2010-07-27
修改说明
重新编码
理化特性临界温度临界压力mpa相对密度水1爆炸上限vv饱和蒸汽压kpa爆炸下限vvph中性相对蒸汽密度外观与性状黑的粉末辛醇水分配系数的聚合危害避免接触的条件11