杜邦尼龙增韧剂产品应用介绍
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DuPont P&IP Modifiers
Nylon Modification
Oct 22, 2002
g
Polymer Modification - Selection Guide
Polymer System Toughener Polyamides MODIFIER FUNCTION Compatibilizer Coupling Processibility
350.0 7500 7000 6500 250.0 6000 200.0 5500 150.0 5000 100.0 4500 4000 0 15 25
300.0
50.0
Wt% FUS N MN-493D
Flex Modulus - Mpa (psi)
NI at 23C - J/m (ft-lb/in)
Fusabond Surlyn ElvaloyAC ElvaloyPTW ElvaloyAC ElvaloyAC ElvaloyHP ElvaloyAC
Fusabond ElvaloyPTW
Fusabond
Selar PA (melt strength)
Polyesters Polyolefins ABS
NI
Flex Modulus
g
PA6 Modified with Surlyn® 9320
Notched Izod - DAM (J/m)
900 800 700 600 500 400 300 200 100 0 10% Surlyn 9320 15%Surlyn 9320 23C 0C -40C
50
6000 5000
0 0% 5% 7% 10% 20% Fusabond 493D (wt% ) %Elongation Flex Mod (Mpa) Tensile (psi)
4000
Tensile (psi)
10000
g
Apparent Viscosity vs Shear Rate at 260°C PA6 Modified with Fusabond® N MN-493D
ElvaloyPTW Fusabond Fusabond Fusabond Fusabond
Surlyn (nucleation)
ElvaloyHP (flow)
g
Impact Strength (DAM) of PA6 Modified with Fusabond® MN-493D at Various Levels
15
20
25
30
wt% SUR 9320
g
Notched Izod for PA6,6 Modified with Surlyn® and Fusabond® at 6.5 wt% Level
160
150
140
Surlyn® 9020N.I.来自- J/m (ft-lb/in)
130
Fusabond® MN-493D
600
400
200
0
0
2% 5% ® Wt% Fusabond MZ 203 D (PP-g-MAH)
10%
g
10 10 100 Shear Rate (1/s) 1000 10000
g
Impact Strength of PA6,6 with Fusabond® MF-416D
1200 1000
Notched Izod (J/m)
800 600 400 200 0 0 0.05 0.1 0.15 0.2 0.25 Wt% FUS 416D
g
General Toughener Notched Izod of PA6 with 6.5 wt% Impact Modifier
250
200
Notched Izod - DAM (J/m)
150
100
50
0 N.I. (RT) J/m N.I. (0C) (J/m) N.I. (-40C) (J/m)
600
400
200
0
No Comp. 5% Fusabond® 203 5% Fusabond® 353 5% EPDM-g-MAH
g
Property 800
Compatibilisation of PA6 / PP PA6/PP (50%/50%)
Tensile Str. (MPa) Elongation @ Break (%) Gd. Impact (10 x J/m)
PA6 Toughening with 20 wt% FUSABOND®MN-493D
1µ m
g
PA6 Modified with Fusabond® 493D
250
13000 12000
% Elongation, Flex Mod (Mpa)
200
11000
150
9000 8000 7000
100
1000 900 800
Notched Izod (J/m)
700 600 500 NI@ 0° C 400 300 200 100 0 0% 5% 10% 15% 20% 25% Wt% of Fusabond MN 493D NI@ -30° C NI@ 23° C
g
Applications - Automotive
NI@23° C NI@0° C NI@-40° C
g
PA6,6 Modified with Fusabond® MF-416D
90 80
Tensile, % Elongation
3500 3000
Flex Modulus
70 60 50 40 30 20 10 0 3 6.5 Wt% FUS 416D Tensile (Mpa) % Elongation @ Break Flex Modulus (Mpa) 10 20 500 0 2500 2000 1500 1000
N.I. (J/m) at 23 deg C
300
250
200
150
100
50
0 PA6 5% EMAH Terpolymer 5% Fusabond® A EB 560D 10% EMAH Terpolymer 10% Fusabond® A EB 560D 15% EMAH Terpolymer 15% Fusabond® A EB 560D 20% EMAH Terpolymer
g
Impact Strength of PA6,6 Modified with Surlyn® 9320
1000 900 800
Notched Izod (J/m)
700 600 500 400 300 200 100 0
N.I. @23° C N.I. @0° C N.I. @-20° C
0
5
10
None
Fusabond® MN493D
Fusabond® MF416D
Surlyn® 9020
Surlyn® 1705
g
General Toughener Flex Modulus of PA6 with 6.5 wt% Impact Modifier
300 290
Flex Modulus (MPa)
280 270 260 250 240 230
Flex Mod (10MPa)
None
Fusabond® MF416D
Fusabond® MN493D
Surlyn® 9020
Surlyn® 1705
g
PA6 (Ultramid B3) Blends at 280° C
1000
Apparent Viscosity (Pa.s)
10000
Viscosity Pa-sec
1000
0 Wt% 100 15 Wt% 20 Wt%
10 1 10 100 1000 10000
Shear Rate sec-1
g
Notched Izod & Flex Modulus 33% Glass Filled PA6 Modified with Fusabond® MN-493D
20% Fusabond® A EB 56)D
g
Apparent Viscosity at 280C PA6 with 10wt% Modifiers
1000
Apparant Viscosity (Pa*s)
100
#REF! xxxxxx 10% Fusabond A EB PA6
10% EMAH Terpolym
120
110
Surlyn® 9950
100
90 -50 -40 -30 -20 -10 Temperature (° C) 0 10 20
g
30
Property 800
Compatibilisation of PA6/PP PA6/PP 50%/50%
Tensile Str. (MPa) Elong. @ Break(%) Gd. Impact (J/m)
20% Fusabond® A EB 56)D
g
Performance of Fusabond® A EB 560D
N.I. (J/m) at -20 deg C
180
160
140
120
100
80
60
40
20
0 PA6 5% EMAH Terpolymer 5% Fusabond® A EB 560D 10% EMAH Terpolymer 10% Fusabond® A EB 560D 15% EMAH Terpolymer 15% Fusabond® A EB 560D 20% EMAH Terpolymer
100
100% PA6 10% LOY 3427AC 10% LOY 1125AC 10% FUSA 493D 20% FUSA 493D 20% SUR 93210
10 10 100 1000
Apparent Shear Rate (1/s)
g
10000
Performance of Fusabond® A EB 560D
Nylon Modification
Oct 22, 2002
g
Polymer Modification - Selection Guide
Polymer System Toughener Polyamides MODIFIER FUNCTION Compatibilizer Coupling Processibility
350.0 7500 7000 6500 250.0 6000 200.0 5500 150.0 5000 100.0 4500 4000 0 15 25
300.0
50.0
Wt% FUS N MN-493D
Flex Modulus - Mpa (psi)
NI at 23C - J/m (ft-lb/in)
Fusabond Surlyn ElvaloyAC ElvaloyPTW ElvaloyAC ElvaloyAC ElvaloyHP ElvaloyAC
Fusabond ElvaloyPTW
Fusabond
Selar PA (melt strength)
Polyesters Polyolefins ABS
NI
Flex Modulus
g
PA6 Modified with Surlyn® 9320
Notched Izod - DAM (J/m)
900 800 700 600 500 400 300 200 100 0 10% Surlyn 9320 15%Surlyn 9320 23C 0C -40C
50
6000 5000
0 0% 5% 7% 10% 20% Fusabond 493D (wt% ) %Elongation Flex Mod (Mpa) Tensile (psi)
4000
Tensile (psi)
10000
g
Apparent Viscosity vs Shear Rate at 260°C PA6 Modified with Fusabond® N MN-493D
ElvaloyPTW Fusabond Fusabond Fusabond Fusabond
Surlyn (nucleation)
ElvaloyHP (flow)
g
Impact Strength (DAM) of PA6 Modified with Fusabond® MN-493D at Various Levels
15
20
25
30
wt% SUR 9320
g
Notched Izod for PA6,6 Modified with Surlyn® and Fusabond® at 6.5 wt% Level
160
150
140
Surlyn® 9020N.I.来自- J/m (ft-lb/in)
130
Fusabond® MN-493D
600
400
200
0
0
2% 5% ® Wt% Fusabond MZ 203 D (PP-g-MAH)
10%
g
10 10 100 Shear Rate (1/s) 1000 10000
g
Impact Strength of PA6,6 with Fusabond® MF-416D
1200 1000
Notched Izod (J/m)
800 600 400 200 0 0 0.05 0.1 0.15 0.2 0.25 Wt% FUS 416D
g
General Toughener Notched Izod of PA6 with 6.5 wt% Impact Modifier
250
200
Notched Izod - DAM (J/m)
150
100
50
0 N.I. (RT) J/m N.I. (0C) (J/m) N.I. (-40C) (J/m)
600
400
200
0
No Comp. 5% Fusabond® 203 5% Fusabond® 353 5% EPDM-g-MAH
g
Property 800
Compatibilisation of PA6 / PP PA6/PP (50%/50%)
Tensile Str. (MPa) Elongation @ Break (%) Gd. Impact (10 x J/m)
PA6 Toughening with 20 wt% FUSABOND®MN-493D
1µ m
g
PA6 Modified with Fusabond® 493D
250
13000 12000
% Elongation, Flex Mod (Mpa)
200
11000
150
9000 8000 7000
100
1000 900 800
Notched Izod (J/m)
700 600 500 NI@ 0° C 400 300 200 100 0 0% 5% 10% 15% 20% 25% Wt% of Fusabond MN 493D NI@ -30° C NI@ 23° C
g
Applications - Automotive
NI@23° C NI@0° C NI@-40° C
g
PA6,6 Modified with Fusabond® MF-416D
90 80
Tensile, % Elongation
3500 3000
Flex Modulus
70 60 50 40 30 20 10 0 3 6.5 Wt% FUS 416D Tensile (Mpa) % Elongation @ Break Flex Modulus (Mpa) 10 20 500 0 2500 2000 1500 1000
N.I. (J/m) at 23 deg C
300
250
200
150
100
50
0 PA6 5% EMAH Terpolymer 5% Fusabond® A EB 560D 10% EMAH Terpolymer 10% Fusabond® A EB 560D 15% EMAH Terpolymer 15% Fusabond® A EB 560D 20% EMAH Terpolymer
g
Impact Strength of PA6,6 Modified with Surlyn® 9320
1000 900 800
Notched Izod (J/m)
700 600 500 400 300 200 100 0
N.I. @23° C N.I. @0° C N.I. @-20° C
0
5
10
None
Fusabond® MN493D
Fusabond® MF416D
Surlyn® 9020
Surlyn® 1705
g
General Toughener Flex Modulus of PA6 with 6.5 wt% Impact Modifier
300 290
Flex Modulus (MPa)
280 270 260 250 240 230
Flex Mod (10MPa)
None
Fusabond® MF416D
Fusabond® MN493D
Surlyn® 9020
Surlyn® 1705
g
PA6 (Ultramid B3) Blends at 280° C
1000
Apparent Viscosity (Pa.s)
10000
Viscosity Pa-sec
1000
0 Wt% 100 15 Wt% 20 Wt%
10 1 10 100 1000 10000
Shear Rate sec-1
g
Notched Izod & Flex Modulus 33% Glass Filled PA6 Modified with Fusabond® MN-493D
20% Fusabond® A EB 56)D
g
Apparent Viscosity at 280C PA6 with 10wt% Modifiers
1000
Apparant Viscosity (Pa*s)
100
#REF! xxxxxx 10% Fusabond A EB PA6
10% EMAH Terpolym
120
110
Surlyn® 9950
100
90 -50 -40 -30 -20 -10 Temperature (° C) 0 10 20
g
30
Property 800
Compatibilisation of PA6/PP PA6/PP 50%/50%
Tensile Str. (MPa) Elong. @ Break(%) Gd. Impact (J/m)
20% Fusabond® A EB 56)D
g
Performance of Fusabond® A EB 560D
N.I. (J/m) at -20 deg C
180
160
140
120
100
80
60
40
20
0 PA6 5% EMAH Terpolymer 5% Fusabond® A EB 560D 10% EMAH Terpolymer 10% Fusabond® A EB 560D 15% EMAH Terpolymer 15% Fusabond® A EB 560D 20% EMAH Terpolymer
100
100% PA6 10% LOY 3427AC 10% LOY 1125AC 10% FUSA 493D 20% FUSA 493D 20% SUR 93210
10 10 100 1000
Apparent Shear Rate (1/s)
g
10000
Performance of Fusabond® A EB 560D