Method of preparing ammonia and ammonia synthesis

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专利名称:Method of preparing ammonia and ammonia synthesis catalysts

发明人:Larry M. Cirjak,Richard P. Schmidt, Jr.

申请号:US07/074736

申请日:19870717

公开号:US04789538A

公开日:

19881206

专利内容由知识产权出版社提供

摘要:A process for producing ammonia comprising selecting a catalyst precursor characterized by the formula: ##EQU1## wherein A is an alkali or alkaline earth metal or mixture thereof;

M is La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Sc, Lu and Y or mixtures;

M' is a group VIII metal, preferably Fe, Co, Ni or Ru or mixtures;

a=0.1 to 4;

b=0.1 to 4;< P>

c=4 to 6; and

provided that the catalyst is free or substantially free of Al or the combination of Al and U, activating the precursor by heating in a non-oxidizing atmosphere and pass N.sub.2 and H.sub.2 over the activated catalyst to produce ammonia.

申请人:STANDARD OIL

代理人:Larry W. Evans,David J. Untener,Michael F. Esposito

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