New Effective Optical Brightener KCB (荧光增白剂KCB)
5.2_W_高重频257_nm_深紫外皮秒激光器
文章编号 2097-1842(2023)06-1318-065.2 W 高重频257 nm 深紫外皮秒激光器范灏然1,陈 曦1 *,郑 磊1,谢文侠1,季 鑫1,郑 权1,2(1. 长春新产业光电技术有限公司, 吉林 长春 130012;2. 中国科学院长春光学精密机械与物理研究所, 吉林 长春 130033)摘要:为了提高半导体检测用深紫外激光器的检测效率,需要搭建高功率、高重频257 nm 深紫外皮秒激光器实验平台。
本文以光子晶体光纤放大器和腔外四倍频结构为基础,进行了257 nm 深紫外激光器的实验研究。
种子源采用中心波长为1 030 nm 、脉冲宽度为50 ps 的光纤激光器,输出功率为20 mW ,重复频率为19.8 MHz 。
通过两级掺镱双包层(65 μm/275 μm )光子晶体光纤棒放大结构,获得了1 030 nm 高功率基频光。
利用二倍频晶体LBO 、四倍频晶体BBO ,采用腔外倍频方式获得了257 nm 深紫外激光。
种子源通过两级光子晶体光纤放大器输出的1 030 nm 基频光,输出功率为86 W ,经过激光聚焦系统后,倍频得到二次谐波515 nm 激光输出功率为47.5 W ,四次谐波257 nm 深紫外激光输出功率为5.2 W ,四次谐波转换效率为6.05%。
实验结果表明,该结构可获得高功率257 nm 深紫外激光输出,为提高半导体检测用激光器的检测效率提供了新思路。
关 键 词:深紫外皮秒激光器;高重频;光子晶体光纤放大器;四次谐波产生中图分类号:TP394.1;TH691.9 文献标志码:A doi :10.37188/CO.2023-0026High repetition frequency 257 nm deep ultraviolet picosecondlaser with 5.2 W output powerFAN Hao-ran 1,CHEN Xi 1 *,ZHENG Lei 1,XIE Wen-xia 1,JI Xin 1,ZHENG Quan 1,2(1. Changchun New Industries Optoelectronics Technology Co., Ltd , Changchun 130012, China ;2. Changchun Institute of Optics , Fine Mechanics and Physics ,Chinese Academy of Sciences , Changchun 130033, China )* Corresponding author ,E-mail : *******************Abstract : To improve the detection efficiency of deep ultraviolet laser for semiconductor detection, it is necessary to develop 257 nm deep ultraviolet picosecond laser with high power and high repetition frequency. In this study, a 257 nm deep ultraviolet laser was experimentally investigated based on photonic fiber amplifier and extra-cavity frequency quadrupling. The seed source uses a fiber laser with a central wavelength of 1 030 nm and a pulse width of 50 ps, delivering a power output of 20 mW and a repetition frequency of 19.8 MHz. High power 1 030 nm fundamental frequency light was obtained through a two-stage ytterbium-doped double cladding (65 μm/275 μm) photonic crystal fiber rod amplification structure, and收稿日期:2023-02-11;修订日期:2023-03-13基金项目:长春市科技发展计划重点研发专项(No. 21ZGG15)Supported by the Key R & D Projects of Changchun Science and Technology Development Plan (No.21ZGG15)第 16 卷 第 6 期中国光学(中英文)Vol. 16 No. 62023年11月Chinese OpticsNov. 2023257 nm deep ultraviolet laser was generated using double frequency crystal LBO and quadruple frequency crystal BBO. The seed source uses a two-stage photonic crystal fiber amplifier to get a 1 030 nm laser with output power of 86 W. After the laser focusing system and frequency doubling, a second harmonic output power of 47.5 W at 515 nm and a fourth harmonic output power of 5.2 W at 257 nm were obtained.The fourth harmonic conversion efficiency was 6.05%. The experimental results show that this structure can ob-tain high power 257 nm deep ultraviolet laser output, providing a novel approach to improve the detection ef-ficiency of the lasers for semiconductor detection.Key words: deep ultraviolet picosecond laser;high repetition frequency;photonic crystal fiber amplifier;fourth harmonic generation1 引 言高重频深紫外皮秒激光器,因具有分辨率高、加工速率快、热损伤低等特性,被广泛应用于半导体检测、光刻以及精密材料加工等工业领域[1-6]。
紫外线吸收剂不同厂家牌号对比
Chimassorb 90
Uvinul D49 Tinuvin P Uvinul 3030 Uvinul 3035 Uvinul 3039
LA-32
Tinuvin 5151 Tinuvin 928 Tinuvin 312 Tinuvin 111
Irganox 168
2112
PEP-8
Irganox 245
UV Absorbers Antioxidants
ICG CHINA OMNISTAB UV 1 OMNISTAB UV 234 OMNISTAB UV 320 OMNISTAB UV 326 OMNISTAB UV 327 OMNISTAB UV 328 OMNISTAB UV 329 OMNISTAB UV 360 OMNISTAB UV 1084NQ OMNISTAB UV 1130 OMNISTAB UV 1164 OMNISTAB UV 1577 OMNISTAB UV 384-2 OMNISTAB UV BP1 OMNISTAB UV BP12 OMNISTAB UV BP2 OMNISTAB UV BP3 OMNISTAB UV BP4 OMNISTAB UV BP6 OMNISTAB UV P OMNISTAB UV 3030 OMNISTAB UV 3035 OMNISTAB UV 3039 OMNISTAB UV Q21 OMNISTAB UV 51515 OMNISTAB UV 928 OMNISTAB UV 312 OMNISTAB UV 111
Cyasorb UV-1164
Cyasorb UV-531 Hostavin ARO 8 Lowilite 22
Cyasorb UV-9
Lowilite 20
蔡斯美电子产品说明书
Simple and Easy-to-Use Amplifiers with a Sensitivity AdjusterProvided as a Standard Feature■Intuitive LED bar display shows light levels at a glance.■Utilizes OMRON’s innovative wire-saving connector.■Reduced wiring and space requirements for power lines.■Optical communications prevents mutual interference for up to 5 amplifiers■High-speed detection, mark-detecting, and water-resistant models also available.Be sure to readSafety Precautionsonpage 10.Ordering InformationAmplifier UnitsAmplifier Units with Cables (2m)Amplifier Units with ConnectorsAmplifier Unit Connectors (Order Separately) Note: Stickers for Connectors are included as accessories.ItemAppearanceControl outputModelNPN outputPNP outputStandard modelsON/OFF outputE3X-NA11 2M E3X-NA41 2M With self-diagnosis function E3X-NA21 2M E3X-NA51 2M High-speed detection models E3X-NA11F 2M E3X-NA41F 2M Mark-detecting modelsE3X-NAG11 2ME3X-NAG41 2MWater-resistant models E3X-NA11V 2M E3X-NA41V 2MItemAppearanceApplicable Connector (order separately)Control outputModelNPN outputPNP outputStandard modelsMasterE3X-CN11ON/OFF outputE3X-NA6E3X-NA8SlaveE3X-CN12Water-resistant models(M8 connectors)XS3F-M421-40@-A XS3F-M422-40@-AE3X-NA14VE3X-NA44VItem AppearanceCable lengthNo. of conductorsModelMaster Connector2 m3E3X-CN11Slave Connector1E3X-CN12E3X-NASensor I/O Connectors (Order Separately)Note:Refer to Introduction to Sensor I/O Connectors for details.Accessories (Order Separately)Combining Amplifier Units and ConnectorsAmplifier UnitsApplicable Connectors (Order Separately)Refer to the following tables when placing an order.Type NPN PNP +Master Connector Slave Connector Basically, Amplifier Units and Connectors are sold separately.Standard modelsE3X-NA6E3X-NA8E3X-CN11 (3-wire)E3X-CN12 (1-wire)When Using 5 Amplifier Units5 Amplifier Units+ 1 Master Connector + 4 Slave ConnectorsSizeCable specificationsAppearanceCable typeModelM8Standard cable2 mFour-conductorcable XS3F-M421-402-A 5 mXS3F-M421-405-A 2 m XS3F-M422-402-A 5 mXS3F-M422-405-AStraight connectorL-shaped connectorMounting BracketsAppearanceApplicable models Model QuantityE3X-NA @E3X-NA @F E3X-NAG @E39-L1431E3X-NA @VE39-L148End PlateAppearanceModel QuantityPFP-M1E3X-NARatings and SpecificationsAmplifier Units*1.When there are 8 or more Units mounted side-by-side, the response time will be 350 P s max.*2.High-speed detection models do not have the mutual interference prevention function.*3.The dielectric strength for water-resistant models with M8 connectors is 500 VAC.*4.Add 10 g to the weight for water-resistant models.Amplifier Unit ConnectorsType Standard modelsHigh-speed detection modelsMark-detecting modelsWater-resistant modelsModelNPN output E3X-NA @E3X-NA @F E3X-NAG @E3X-NA @VItemPNP outputLight source (wavelength)Red LED (680 nm)Green LED (520nm)Red LED (680 nm)Power supply voltage 12 to 24 VDC 10%, ripple (p-p): 10% max.Currentconsumption35 mA max.35 mA max.(for 24-VDC power supply)35 mA max.Control output Load current: 50 mA max.; residual voltage: 1 V max.; NPN/PNP (depends on model) open collector; Light-ON/Dark-ON mode selector Self-diagnosis outputNoneYesNoneResponse time Operate or reset: 200 P s max. *1Operate: 20 P s max.Reset: 30 P s max.Operate or reset: 200 P s max. *1Sensitivity adjustment 8-turn sensitivity adjuster (with indicator)Protection circuits Reverse polarity, output short-circuit, mutual interference prevention (optically synchronized) *2Timer functionOFF-delay timer: 40 ms (fixed)Ambient illumination (Receiver side)Incandescent lamp: 10,000 lux max.Sunlight:20,000 lux max.Ambienttemperature range Operating:Groups of 1 to 3 Amplifiers: 25 C to 55 CGroups of 4 to11 Amplifiers: 25 C to 50 C Groups of 12 to16 Amplifiers: 25 C to 45 CStorage: 30 C to 70 C (with no icing or condensation)Ambient humidity rangeOperating and storage: 35% to 85% (with no condensation)Insulation resistance 20 M : min. (at 500 VDC)Dielectric strength 1,000 VAC at 50/60 Hz for 1 minute *3Vibration resistance Destruction: 10 to 55 Hz with a 1.5-mm double amplitude for 2 hrs each in X, Y and Z directions Shock resistance Destruction: 500 m/s 2, for 3 times each in X, Y and Z directions Degree of protection IEC 60529 IP50 (with Protective Cover attached)IEC 60529 IP66 (with Pro-tective Cover attached)Connection method Pre-wired (standard cable length: 2 m) or connectorWeight(packed state)Pre-wired models: approx. 100 g, Connector models: approx. 55 g (See note 4.) *4Material Case Polybutylene terephthalate (PBT)CoverPolycarbonate Polyethersulfone (PES)Accessories Instruction manualItemModelE3X-CN11E3X-CN12Rated current 2.5 A Rated voltage 50 VContact resistance 20 m : max. (20 mVDC max., 100 mA max.)(The above figure is for connection to the Amplifier Unit and the adjacent Connector. It does not include the conductor resistance of the cable.)Number of inser-tions Destruction: 50 times (for connection to the Amplifier Unit and the adjacent Connector)MaterialHousing Polybutylene terephthalate (PBT)ContactPhosphor bronze/gold-plated nickel Weight(packed state)Approx. 55 gApprox. 25 gE3X-NA Sensing DistanceThrough-beam Models(Unit: mm)Model E3X-NA@E3X-NA@FType General-purposemodelsHigh-speedmodelsStandard modelsFlexible(new standard)E32-T11R/E32-T12R/E32-T15XR/E32-TC200BR(B4R)28080E32-T14LR/E32-T15YR/E32-T15ZR11033E32-T21R/E32-T22R/E32-T222R/E32-T25XR/E32-TC200FR(F4R)6018 E32-T24R/E32-T25YR/E32-T25ZR309StandardE32-TC200/E32-T12/E32-T15X/E32-TC200B(B4)400120E32-T14L/E32-T15Y/E32-T15Z24070E32-TC200A360100E32-TC200E/E32-T22/E32-T222/E32-T25X/E32-TC200F(F4)10030E32-T24/E32-T25Y/E32-T25Z9027 Break resistantE32-T11/E32-T12B/E32-T15XB360100E32-T21/E32-T221B/E32-T22B10030E32-T25XB7520 Fluorine coating E32-T11U360100Special-beam modelsLong distance,high powerE32-T17L140004200E32-TC200 + E39-F13000900E32-T11R + E39-F12100630E32-T11 + E39-F12000600E32-T141800540E32-T11L/E32-T12L700210E32-T11L + E39-F2500150E32-T11R + E39-F222065E32-T11 + E39-F2360100E32-T21L/E32-T22L20060Ultracompact,ultrafine sleeveE32-T223R6018E32-T33-S5206E32-T333-S55 1.5E32-T334-S5 2.50.8 Fine beam (nar-row vision field)E32-T22S1000300E32-T24S700210 Area sensingE32-T16PR450130E32-T16P600180E32-T16JR390110E32-T16J520150E32-T16WR690200E32-T16W920270E32-T161500450E32-M2130090Environment-resistivemodels Heat resistantE32-T51400120E32-T5413035E32-T81R-S18050E32-T61-S + E39-F2390130E32-T61-S + E39-F13000900E32-T84S-S700210E32-T61-S30090ChemicalresistantE32-T11F1050380E32-T12F1600480E32-T14F20060E32-T51F700200E32-T81F-S350100VacuumresistantE32-T51V100---E32-T51V + E39-F1V600---E32-T54V65---E32-T54V + E39-F1V390---E32-T84SV250---E3X-NAReflective Models(Unit: mm)Model E3X-NA@E3X-NA@FType General-purposemodels High-speed modelsStandard modelsFlexible(new standard)E32-D11R/E32-D12R/E32-D15XR/E32-DC200BR(B4R)9030E32-D14LR165E32-D15YR/E32-D15ZR205E32-D211R/E32-D21R/E32-D22R/E32-D25XR/E32-DC200FR(F4R)155E32-D24R7 2.3E32-D25YR/E32-D25ZR4 1.2 StandardE32-DC200/E32-D15X/E32-DC200B(B4)15050E32-D1212040E32-D14L4013E32-D15Y/E32-D15Z5015E32-D211/E32-DC200E/E32-D22/E32-D25X/E32-DC200F(F4)3612E32-D24155E32-D25Y/E32-D25Z10 3.3 Break resistantE32-D11/E32-D15XB9030E32-D21B/E32-D221B3510E32-D21/E32-D22B155E32-D25XB258 Fluorine coating E32-D11U9030Special-beam models Long distance,high powerE32-D1640 to 40055 to 70E32-D11L20065E32-D21L/E32-D22L5017 Ultracompact,ultrafine sleeveE32-D3310 3.3E32-D331 1.50.5Coaxial,small spotE32-CC200R7525E32-CC20015050E32-D32L8025E32-C31/E32-D324013E32-C42 + E39-F3A Spot diameter of 0.1 to 0.6 mm at 6 to 15 mm.E32-D32 + E39-F3A Spot diameter of 0.5 to 1mm at 6 to 15 mm.E32-C41 + E39-F3A-5Spot diameter of 0.1 mm at 7 mmE32-C31 + E39-F3A-5Spot diameter of 0.5 mm at 7 mm.E32-C41 + E39-F3B Spot diameter of 0.2 mm at 17 mm.E32-C31 + E39-F3B Spot diameter of 0.5 mm at 17 mm.E32-C31 + E39-F3C Spot diameter of 4 mm max. at 0 to 20 mm. Area sensing E32-D36P17525 Retro-reflectiveE32-R21 + E39-R3 (provided)10 to 250E32-R16 + E39-R1 (provided)150 to 1500150 to 1000Convergent-reflectiveE32-L25/E32-L25A 3.3E32-L24S0 to 4E32-L24L 2 to 6 (center 4)E32-L25L 5.4 to 9 (center 7.2)E32-L86 4 to 10E32-L160 to 150 to 13Environment-resistive models Heat resistantE32-D5112040E32-D81R/E32-D614515E32-D733010 ChemicalresistantE32-D12F5016E32-D14F20 6.5E3X-NAApplication-specific Models(Unit: mm)Green Light Source Models(Unit: mm)ModelE3X-NA @E3X-NA @F TypeGeneral-purposemodelsHigh-speed modelsApplication-specific ModelsLabel detectionE32-G1410E32-T141800540Liquid-level detectionE32-L25TApplicable tube: Transparent tube with a diameter in the range 8 to 10 mm and a recommended wall thickness of 1 mm E32-D36T Applicable tube: Transparent tube (no diameter restrictions )E32-D82F1(F2)Liquid-contact modelModelE3X-NAG @TypeMark-detecting ModelsThrough-beammodelsStandard E32-T11R/E32-T12R/E32-T15XR/E32-TC200BR(B4R)50E32-T14LR/E32-T15YR/E32-T15ZR20E32-TC200/E32-T12/E32-T15X/E32-TC200B(B4)75E32-T14L/E32-T15Y/E32-T15Z45Special beam E32-T11L/E32-T12L130Reflective StandardE32-D11R/E32-D12R/E32-D15XR/E32-DC200BR(B4R)15E32-D14LR3.5E32-D15YR/E32-D15ZR3.3E32-DC200/E32-D15X/E32-DC200B(B4)25E32-D14L10E32-D15Y/E32-D15Z8Special beam E32-D11L 35E32-CC200R12E32-CC20025E32-D32L12E32-C31/E32-D326Applicationspecific Label detectionE32-T14330E32-G1410Refer to E32 Series for details on Fiber Units.E3X-NAEngineering Data (Typical)Number of Turns of Sensitivity Adjuster vs. Sensing Distance E32-T11LE32-D11LSensing Distance vs. Differential Travel E32-T11LE32-D11LD i s t a n c e (m )Number of turnsD i s t a n c e (m m )Number of turnsD i f f e r e n t i a l t r a v e l (m m )Distance (mm)D i f f e r e n t i a l t r a v e l (m m )Distance (mm)E3X-NA I/O Circuit DiagramsE3X-NAPNP OutputPlug (Sensor I/O Connector)NomenclatureAmplifier UnitsBlue XS3F-M421-402-A XS3F-M421-405-A XS3F-M422-402-A XS3F-M422-405-ANote:Pin 2 is not used.Classification Wire color Connection pinApplication DCBrown1Power supply(+V)White 2---Blue 3Power supply(0 V)Black4OutputON: Timer function is ON.OFF: Timer function is OFF.E3X-NA Safety PrecautionsRefer to Warranty and Limitations of Liability.This product is not designed or rated for ensuringsafety of persons either directly or indirectly.Do not use it for such purposes.Do not use the product in atmospheres or environments that exceed product ratings.Amplifier Units● DesigningCommunications HoleThe hole on the side of the Amplifier Unit is a communications hole for preventing mutual interference when Amplifier Units are mounted side-by-side. The E3X-MC11 Mobile Console (order separately) cannot be used.If an excessive amount of light is received via the Sensor, the mutual interference prevention function may not work. In this case, make the appropriate adjustments using the sensitivity adjuster.The mutual interference prevention function will not operate when the E3X-NA is used side-by-side with E3X-DA-N models.● MountingDIN Track Mounting/RemovalMounting Amplifier Units1. Mount the Amplifier Units one at a time onto the DIN track.2. Slide the Amplifier Units together, line up the clips, and press theAmplifier Units together until they click into place.Removing Amplifier UnitsSlide Amplifier Units away from each other, and remove from the DIN track one at a time. (Do not attempt to remove Amplifier Units from the DIN track without separating them first.)Fiber Connection and DisconnectionThe E3X Amplifier Unit has a lock lever. Connect or disconnect the fibers to or from the E3X Amplifier Unit using the following procedures:1. ConnectionOpen the Protective Cover, insert the fibers according to the fiber insertion marks on the side of the Amplifier Unit, and lower the lock lever.2. DisconnectionRemove the Protective Cover and raise the lock lever to pull out the fiber.Note:To maintain the fiber properties, confirm that the lock is released before removing the fiber.3. Precautions for Fiber Connection/DisconnectionBe sure to lock or unlock the lock lever within an ambient temperature range between 10 C and 40C.● Operating EnvironmentAmbient ConditionsIf dust or dirt adhere to the hole for optical communications, it mayprevent normal communications. Be sure to remove any dust or dirtbefore using the Units.● OtherProtective CoverBe sure to mount the Protective Cover before use.WARNINGPrecautions for Correct UseNote:1.The specifications for ambient temperature will vary according to thenumber of Amplifier Units used together. For details, refer to Ratingsand Specifications.2.Always turn OFF the power supply before mounting or removingAmplifier Units.E3X-NAAmplifier Units with Connectors● MountingMounting Connectors1. Insert the Master or Slave Connector into the Amplifier Unit until it clicks into place.2. Join Amplifier Units together as required after all the Master and Slave Connectors have been inserted.3. Attach the seals (provided as accessories) to the sides of Master and Slave Connectors that are not connected to other Connectors.Note:Attach the stickers to the sides with grooves.Removing Connectors1.Slide the slave Amplifier Unit for which the Connector is to be removed away from the rest of the group.2.After the Amplifier Unit has been separated, press down on the lever on the Connector and remove it. (Do not attempt to remove Connectors without separating them from other Amplifier Units first.)Mounting End Plate (PFP-M)Depending on how it is mounted, an Amplifier Unit may move during operation. In this case, use an End Plate.Before mounting an End Plate, remove the clip from the master Amplifier Unit using a nipper or similar tool.The clip can also be removed using the following mechanism, which is incorporated in the construction of the section underneath the clip.1. Insert the clip to be removed into the slit underneath the clip on another Amplifier Unit.2. Remove the clip by rotating the Amplifier Unit.Pull Strengths for Connectors (Including Cables)E3X-CN11: 30 N max.E3X-CN12: 12 N max.E3X-NADimensions(Unit: mm)Amplifier Units4-dia. vinyl-insulated round cable with 3 conductors (Conductor cross section: 0.2 Amplifier Units with Cables E3X-NA11E3X-NA11F E3X-NA41E3X-NA41F E3X-NAG11E3X-NAG41E3X-NA21E3X-NA51With Mounting Bracket Attachedside A.2. 4-dia. vinyl-insulated round cable with 3conductors (Conductor cross section: 0.45 mm 2, Insulator diameter: 1.1 mm), Standard length: 2 m.Amplifier Units with Cables, Water-resistant Models E3X-NA11VE3X-NAAmplifier Units with Connectors E3X-NA6E3X-NA8Dimensions with Master Connector ConnectedDimensions with Slave Connector ConnectedE3X-NAAmplifier Unit Connectors Sensor I/O ConnectorsAccessories (Order Separately)Mounting BracketsEnd Plates* The mounting bracket can also be used on this side.Amplifier Units with Connectors, Water-resistant ModelsE3X-NA14VE3X-NA44VWith Mounting Bracket AttachedRefer to E32 Series for details on Fiber Units.。
光光转换效率英文
光光转换效率英文介绍光光转换效率英文是指太阳能电池将光能转化为电能的效率。
在太阳能领域,光光转换效率是一个重要的指标,影响着太阳能电池的实际应用和经济效益。
光光转换效率的提高可以有效地提高太阳能电池的性能和产能,加速太阳能产业的发展。
本文将详细探讨光光转换效率的英文表达,包括相关术语和常用表述。
术语及表述在讨论光光转换效率英文之前,先介绍一些与光光转换效率相关的术语: 1. Photovoltaic conversion efficiency:光伏转换效率 2. Incident light:入射光 3. Absorption:吸收 4. Electron-hole pair:电子空穴对 5. Exciton:激子 6. Charge carrier:载流子 7. Energy band gap:能带间隙 8. Open-circuit voltage:开路电压 9. Short-circuit current:短路电流 10. Fill factor:填充因子 11. Power conversion efficiency:功率转换效率光光转换效率的影响因素光光转换效率受多种因素的影响,下面将逐一介绍这些因素及其英文表述。
材料选择1.Band gap engineering:能带调控2.Semiconducting material:半导体材料3.Absorption coefficient:吸收系数4.Doping concentration:掺杂浓度结构设计1.Surface texture:表面处理2.Anti-reflection coating:抗反射涂层3.Tandem structure:串联结构4.Multi-junction solar cells:多结太阳能电池光学特性1.Quantum efficiency:量子效率2.Reflectance:反射率3.Transmittance:透过率4.Light trapping:光捕获电子输运1.Mobility:迁移率2.Diffusion length:扩散长度3.Recombination:复合4.Tunneling effect:隧穿效应界面特性1.Heterojunction:异质结2.Contact resistance:接触电阻3.Interface trap density:界面态密度4.Passivation:表面钝化设备参数1.Open-circuit voltage:开路电压2.Short-circuit current:短路电流3.Fill factor:填充因子4.Power conversion efficiency:功率转换效率提高光光转换效率的方法在太阳能电池领域,提高光光转换效率是一个持续的研究方向。
包含羟基磷灰石作为物理日光滤光剂的防晒组合物[发明专利]
(10)申请公布号 CN 102361623 A(43)申请公布日 2012.02.22C N 102361623 A*CN102361623A*(21)申请号 201080012629.8(22)申请日 2010.03.22MI2009A000448 2009.03.23 ITA61K 8/04(2006.01)A61K 8/24(2006.01)A61Q 17/04(2006.01)A61K 8/19(2006.01)A61K 8/26(2006.01)A61K 8/27(2006.01)A61K 8/36(2006.01)A61K 8/362(2006.01)A61K 8/368(2006.01)(71)申请人意大利嘉利化工有限责任公司地址意大利布雷西亚(72)发明人路易吉·里加诺 詹卡洛·加扎尼加詹巴蒂斯塔·拉斯特列利(74)专利代理机构北京安信方达知识产权代理有限公司 11262代理人杨淑媛 郑霞(54)发明名称包含羟基磷灰石作为物理日光滤光剂的防晒组合物(57)摘要本发明涉及与至少一种化学防晒剂协同地联合作为物理防晒剂的羟基磷灰石在设计用于施用到皮肤以保护皮肤不受日光UV 辐射的产品中的用途。
特别地,描述了包含具有遮蔽能力、高皮肤耐受性和皮肤上低的增白效应的物理防晒剂的化妆品组合物。
(30)优先权数据(85)PCT申请进入国家阶段日2011.09.20(86)PCT申请的申请数据PCT/IB2010/051226 2010.03.22(87)PCT申请的公布数据WO2010/109400 EN 2010.09.30(51)Int.Cl.(19)中华人民共和国国家知识产权局(12)发明专利申请权利要求书 2 页 说明书 18 页 附图 1 页1.一种防晒产品,其包含羟基磷灰石或其盐和至少一种化学防晒剂,其中所述至少一种化学防晒剂和所述羟基磷灰石或其盐的比例是10∶1至1∶3。
提升可见光响应的方法-概述说明以及解释
提升可见光响应的方法-概述说明以及解释1.引言1.1 概述本文旨在探讨提升可见光响应的方法。
在当今科技发展日新月异的背景下,光响应的提升对于许多领域至关重要,特别是在能源、环境和光学等领域。
本文将首先概述可见光响应及其重要性,随后介绍本文的结构和目的。
可见光响应是指材料对可见光波长范围内的光线的吸收和响应能力。
在许多应用中,如太阳能电池、光催化、光电子器件等,提高材料的可见光响应是实现高效能源转换和高性能器件的关键。
因此,研究人员一直致力于开发各种方法,以提高材料对可见光的光吸收能力和响应效率。
在本文中,我们将重点介绍两种提升可见光响应的方法。
首先,我们将讨论提高材料的光吸收能力的方法,包括材料结构设计、光吸收剂引入和材料组分优化等。
其次,我们将探讨表面改性增强光吸收的方法,通过改变材料表面结构和性质来提高光线与材料的相互作用强度。
通过研究不同的方法和技术,我们可以更好地理解并掌握提升可见光响应的原理和途径。
本文的目的是为读者提供一个全面的概述,并为今后的研究方向提供指导。
希望通过本文的阅读,读者能够深入了解可见光响应的机制,以及如何应用不同的方法来提升材料的可见光响应能力。
在结论部分,我们将总结本文中介绍的方法,并展望未来的研究方向。
我们相信,通过持续的努力和创新,我们能够不断提升材料的可见光响应能力,推动相关领域的发展和进步。
总之,本文将对提升可见光响应的方法进行深入研究和探讨,希望能够为相关领域的科研人员和技术工作者提供有益的指导和启示。
文章结构部分应该是介绍全文的组织架构,告诉读者本文将会涉及哪些内容和主要论点。
以下是一个可能的内容:"1.2 文章结构本文将会分为三个主要部分,分别是引言、正文和结论。
引言部分包括概述、文章结构和目的。
首先,我们将对提升可见光响应的方法进行概述,说明该领域的重要性和研究意义。
然后,我们会详细介绍本文的组织结构,以帮助读者更好地理解文章内容。
最后,我们会明确本文的目的,即通过分析和讨论不同方法来提高可见光响应。
New Effective Optical Brightener KCB (荧光增白剂KCB)
New Effective Optical Brightener KCB (荧光增白剂KCB)Chemical Component:Benzoxazolyl Naphthalene Optical BrightenerTypical Properties:Appearance: Yellowish Crystal PowderEffective Assay: 99%minAsh Content: 0.5%maxV olatile: 0.3%maxCharacters:New effective optical brightener SP-KCB is an improved product of current widely used normal KCB(Hostalux KCB), whose temperature and weather resistance capability is much better than normal KCB. It’s extremely effective in brightening and present blue optical light when mixed in synthetic fiber and plastics, especially in colorful plastics. Much convenient, less dosage, better whiteness and lower price are the superior characters.Application :SP-KCB can be widely used in EV A, PET, and is the best choice for making sports shoes material. It is also good at applying into plastic films such as PE, PP, PVC, PS, ABS, and extrude molding material, injection molding material. The whiteness of coating and natural painting could also be greatly improved by SP-KCB.Safety and stock:Keeping in stock as ordinary chemicals. Wear protective goggles and gloves while applying.A void direct contact with skin and eyes. Soap clean if skin contaminated.Packing:25kg / fiber drum with PE linerOptical Brightener Odyssey OB-1 (荧光增白剂OB-1)Optical brighteners are added to many materials to reduce yellowing, improve whiteness, and to enhance the brightness of a product. Odyssey OB-1 is used widely in the plastic market. Because of its excellent brightening ability,good thermal stability,and compatibility with many polymers. Typical PropertiesChemical name: 2,2-(1,2-Ethenediyldi-4, 1-phenylene) bisbenzoxazoleMolecular weight: 414.4CAS No.: 1533-45-5C.I.: 393Specifications:Ash %Empirical FormulaMelting Point(DTA),CAppearanceOdorV olatile Content %Assay %Particle Size0.3maxC28H18N2O2353-359Y ellowish Green PowderFree of odor0.3max99min200 meshesEffect of Optical Brighteners on the Whiteness of PolymersOptical brighteners function by absorbing ultraviolet radiation and remitting blue light. The emitted blue light will reduce the yellow color of a polymer. In the presence of a whitening agent, such as TiO2, the use of Odyssey OB-1 will produce a brilliant white o r “white than white” appearance.Two primary factors affect the whiteness/yellowness of a formulation. They are the color of the base polymer and the level of brightener added. If no whitening agent, such as TiO2, is used, the level of Odyssey OB-1 required will likely be lower than when a whitening agent is preset. This level might be as little as 25-50 ppm. In determining the optimum concentration of brightener, the effect of any other UV-absorbing materials in the plastic should be considered. It is important that users perform sufficient evaluations to determine the optimum level of Odyssey OB-1 for their specific end uses.Methods of AdditionTo be effective, an optical brightener must dissolve in the polymer to which it is added. Since the typical addition levels for Odyssey OB-1 in the range of 100-400 ppm, the use of a concentrate, or masterbatch, is recommended. Concentrates are containing 1%-10% by weight of Odyssey OB-1 typical.The concentrate can be produced on an extruder using normal processing conditions for the polymer, including drying if necessary. The concentrate is then let down to typical use levels in the final formulation. Plastics compounding equipment is normally adequate for producing Odyssey OB-1 brightener formulations. The key requirement is to thoroughly disperse the brightener so that it will dissolve uniformly throughout the molten polymer. This is usually achieved most readily with a concentrate.Improving Whiteness of Recycled PolymerThe business of processing post consumer plastics and waste polymer continue to grow. These materials can be recycled into a variety of useful products, from plastic lumber to synthetic fiber. Polyester bottle polymer, polyester plastic waste, and waste fiber polymer can be recycled into polyester fiber that can be used in carpets, filling and insulation material, nonwovens, and apparel. One of the shortcomings of processing these materials is the uncertainty of the color of the source material.By using optical brighteners, the value of the recycled materials can be significantly enhanced by providing a more uniform white. Odyssey OB-1 will greatly improve the whiteness, Normal fiber applications require only 200-300 ppm in new polymer, but recycled material may require as much as 300-450 ppm. Optical brighteners are very effective in improving the appearance of the polymer or fiber. Off-class or second-quality nylon polymer can also be improved in the same way.Food Industry ApplicableOdyssey OB-1 complies with regulations for indirect food additives. Odyssey OB-1 is restricted to use as an optical brightener for all polymers at a level not to exceed 0.025% by weight of polymer and at the temperatures not to exceed 135"C(275"F).Packing:25kg / fiber drum with PE linerHomepage Chinese V ersionWelcome you to visit the website of Beijing Odyssey Chemicals Co.,Ltd.© Beijing Odyssey Chemicals Co.,Ltd. All Rights Reserved.Optical Brightener Odyssey OB (荧光增白剂OB)Odyssey OB is a high molecular weight optical bright ener of the thiophenediyl benzoxazole class, suitable for the optical brightener of polymers at all stage of processing.Typical PropertiesChemical Name: 2,2-(2,5-Thiophenediyl) Bis[5-(1,1-dimethylethy)]BenzoxazoleMolecular Formula: C27H27O2N2SMolecular Weight: 443CAS No.: 7128-64-5C.I.: 184Specifications:Appearance: Yellowish or yellowish green crystal powderAssay: 99% min.Melting Point: 196-203?Ash: 0.3% max.V olatile Content: 0.3%max.Particle size: 200 meshesMax. Absorption Wavelength: 375nm(in ethanol)Properties:Optical Brightener Odyssey OB is highly effective in polymer substrates such as engineering plastics, e.g. PE, PC, PVC, PS, ABS, and PP, adhesive and other organic substrates.Main applications include fibers, molded articles, films and sheets. And also can be used in clear lacquers, pigmented lacquers, paints, printing ink and synthetic leather. It will produce brilliant brightness with dyestuff, which is very efficient in directions for multicolor.Optical Brightener Odyssey OB can be used as a tracer in a variety of applications.Odyssey OB features excellent resistance to heat, exceptional whitening properties, good light fastness and low volatility. It is readily soluble in organic solvents and features good compatibility in various substrates. The product is especially suitable for applications such as films and fiber. Odyssey OB enhances the whiteness of the substrate. In combination with dyes, the product produces particularly bright shades. Its excellent heat resistance renders Odyssey OB suitable for all relevant processing conditions. It is suitable for packing applications but local regulations must be observed.Application (in each 100kg polymer):PVC: White 0.01-0.05 (10g-50g)Transparent 0.0001-0.001% (0.1g-1g)PS: White 0.001% (1g)Transparent 0.0001-0.001% (0.1g-1g)ABS: Primitive color 0.01-0.05% (10g-50g)(effectively eliminate the intrinsic yellow color in ABS)White 0.01-0.05% (10g-50g)PE, PP: Achromaticity 0.0005-0.001% (0.5g-1g)White 0.005-0.05% (5g-50g)Other Plastics: Refer to the directions given above.When Odyssey OB is used in PMMA polymerization, take care that the polymerization is conducted to full completion since interaction with residual monomer can cause discoloration in the final application.Attention:Please mix thoroughly to obtain best effect. OB concentrated master batch can be even better mixed.Safety and Stock:Keeping in stock as ordinary chemicals. Wear protective goggles and gloves while applying.A void direct contact with skin and eyes. Soap clean if skin contaminated.Packing:25kg / fiber drum with PE linerProduct name: Optical Brightening Agent PF (荧光增白剂PF)·Chemical name: 1.2 di(5-mythyl-benziazolyl)ethylene·Structural No: C.i 135·CAS NO: 12224-12-3·Structural formula:·Molecular formula: C18H14N2O2·Molecular weight: 290·Technical index: Appearance:Light yellow crystal powderMelting Point:184~186°CPurity:≥98.0%·Uses: It is mainly used in increasing the brightening and beauty of PVC,PS,PP,polyester film, high or low voltage PE,ABS, organic glass, business card,high quality paper,etc.. ·Precaution: The information of our products is for reference only. We are not responsible for any unexpected results or patent dispute caused by it.Product name: Optical Brightening Agent PF-3 (荧光增白剂PF-3)·Chemical name: 1.2 di(5-mythyl-benziazolyl)ethylene·Structural No: C.i 135·CAS NO: 12224-12-3·Structural formula:·Molecular formula: C18H14N2O2·Molecular weight: 290·Technical index: Appearance:Light yellow crystal powderMelting Point:188~190°CPurity:≥99.0%·Uses: It is mainly used in increasing the brightening and beauty of PVC,PS,PP,polyester film, high or low voltage PE,ABS, organic glass, business card,high quality paper,etc..·Precaution: The information of our products is for reference only. We are not responsible for any unexpected results or patent dispute caused by it.Product name: Optical Brightening Agent ER-1(荧光增白剂ER-1)·Chemical name: 1,4'-bis(2-cyanostyryl) Benzene·Structural No: C.i 199·CAS NO: 13001-40-6·Structural formula:·Molecular formula: C24H16N2·Molecular weight: 332·Properties: It has high whitening brightening effect and excellent fastness to sublimation. ·Technical index: Appearance:greenish yellow crystalline powder Melting Point:230-232°C Purity:≥98.0% Maximum UV Absorption Spectrum:365nm·Uses: Mainly be used in whitening of polyester fiber and as the raw material of paste form brightening agent in textile dyeing.·Precaution: The information of our products is for reference only. We are not responsible for any unexpected results or patent dispute caused by it.Product name: Optical Brightening Agent ER-Ⅱ(荧光增白剂ER-11)·Chemical name: 1,4'-bis(2,4'-cyano-phenlene)-benzene·Structural No: C.i 199:1·CAS NO: 13001-40-6·Molecular formula: C24H16N2·Molecular weight: 332·Properties: bluish color shade with high whitening brightening effect and excellent fastness to sublimation.·Technical index: Appearance:slight yellow powder Melting Point:183~185°C Purity:≥98.0% Maximum UV Absorption Spectrum:369nm·Uses: mainly be used as whitening agent for polyester fiber, as well the raw material of makingpaste form brightening agent in textile dyeing.·Precaution: The information of our products is for reference only. We are not responsible forany unexpected results or patent dispute caused by it.Product name: Optical Brightening Agent KSN (荧光增白剂KSN)·Chemical name: 4.4-bis(5-methyl-2-benzoxoazol)-ethylene·Structural formula:·Properties: 1. being highly whiteness with small usage.2. multipurpose used for whitening of polyester fiber and plastic.3. having a good compatibility and good fastness to light and sublimation. Can be used for high temperature process.·Treating Process: Overlay plastic:0.5-2g/100kgPolyester fiber:10-20g·Package: 20kg cardboard drum·Technical index: Appearance: greenish yellow powderMelting process: 275~280°CAsh content:≤0.5%Purity:≥98.0%V olatile content:≤0.5%Fineness(300 mesh):100%·Uses: mainly be used in whitening of polyester, polyamide, polyacrylonitrile fiber, the plastic film and all plastic pressing process. Can suitable for synthesizing high polymer including polymeric process.·Precaution: The information of our products is for reference only. We are not responsible for any unexpected results or patent dispute caused by itFLUORESCENT BRIGHTENER CBS-X(洗涤用荧光增白剂CBS-X)MOLECULAR FORMULA: C28H20S2O6Na2MOLECULAR WEIGHT: 562.60(As International relative Atom Mass 1997)EXCUTIVE STANDARD: Q/LQH005-2002PARAMETERS:APPEARANCE: Pistachio granuleSMELL: No special smellMAX UV ABSORPTION SPECTRUM: 348nm±1nmEXTINCTION V ALUE: 0.829-0.8851% EXTINCTION INDEX: 1105-1181PROPERTY:Optical Brightener CBS-X is a disulfonic distyrylbiphenyl biphenyl compound, which is the most excellent brightener used in detergent industry. It can soluble in water easily and has betterwhitener effect on cellulose fiber, polyamide and proteinic fiber at room temperature. It has high brighten intensity on cotton cloth as much 2.7times diphenylethylene tristriazine derivatives, and has well optical blue color moniter, dissolve and disperse properties. It has extremely high stability with hypochloride sodium, it is a bleaching resistenct optical brightener.APPLICA TION:Used in detergent industry and soap industry.PROCEDURE:1. It can be added in any procedure of the process of synthetic detergent and soap. It can get excellent and soap. It can get excellent effect if used together with optical brightener 31#.2. Recommended dosage:Common washing powder: 0.005-0.03% Soap: 0.01-0.05%Concentrated washing powder: 0.01-0.05% Soften agent of fabric fiber: 0.01-0.05%Liquid detergent: 0.02-0.06% Washing syrup: 0.005-0.02% PACKAGE: Packed per 25kg in cardboard bucket or cardboard box after being packed in plastic bag first.TRANSPORTA TION: A void upside down, sunlight, wet and crash, avoide damage the package. STORAGE: Should be stored in cool, dry and ventilate place, stored term shouldn’t exceed 2 yearsProduct name: Optical Brightening Agent EBF (荧光增白剂EBF)·Chemical name: 2.5-bis-(benzoxazol-2-)thiophene·Structural No: C.i 185·CAS NO: 12224-40-6·Structural formula:·Molecular formula: C18H10N2O2S·Molecular weight: 318·Technical index: Appearance:Bright-colored light yellowist crystal powderMelting Point:216~220°CPurity:≥98.0%·Uses: It is used in making commercialized Brightener-EB,and can also be used in various polyolefing plastics,ABS engineering plastics and organic glass to make their color brighter. ·Precaution: The information of our products is for reference only. We are not responsible for any unexpected results or patent dispute caused by it.Product name: Optical Brightening Agent FP-127 (荧光增白剂FP-127)·Chemical name: 1,1'-biphenyl-4,4'-bis-benzoxazole·Structural No: C.i 378·CAS NO: 40470-68-6·Structural formula:·Molecular formula: C30H26O2·Molecular weight: 418·Technical index: Appearance:slight yellow powderMelting Point:219-221°CPurity:≥98.0%Maximum UV Spectrum Absorption:359nm·Uses: Mainly be used in whitening of plastics such as PVC,PS,ABS,TPR,etc. ·Precaution: The information of our products is for reference only. We are not responsible for any unexpected results or patent dispute caused by it.Fluorescent Whitening Agent HW A(荧光增白剂HW A二磺酸型)1.Properties:Appearance:yellow-brown clear viscous liquidStructure:a compound of diphenylethylene triazine typeIonicity:anionicPH V alue:8-10Resistance to acid and alkali:suitable for PH5-13Solubility:soluble in water in any ratio2.Applications:Fluorescent whitening agent(FWA) for cotton/cellulose fibres,nylon fibres,rayon fibres,wool and silk and their blends.High affinity,extremely suitable for exhaust application.Extremely good light and wet fastness properties.Good stability in peroxide and reductive bleaching liquors.Can be used in boiling-off baths.Extremely suitable for fluorescent whitening of viscose and modal fibres3.Amounts required:Cotton and bast fibres:0.18-0.7%HW A;Viscose and bast fibres:0.4-1.5% HWA,3-5 g/l sodium sulphate calc.Polyamide fibres:0.5-2% HWA,2-4 g/L hydrosulphite-based reducing agent.Wool,silk:0.5-1.5%HWA,2-4 g/L hydrosulphite-based reducing agent4.Packaging and storing:20/25/50/220KGS plastic drums.Stored in cool place and prevented it from being shone by sunlight.Fluorescent Whitening Agent HPE(荧光增白剂HPE四磺酸型)1.Properties:Appearance:amber clear viscous liquidStructure:a compound of diphenylethylene triazine typeIonicity:anionicResistance to acid and alkali:suitable for PH2-12Solubility:soluble in water in any ratio.2.Applications:This product is especially suitable for whitening and brightening paper pulp,knitted goods and cotton fabrics.The whitening effect of VBL will decrease remarkably when the PH value is lower than 6,while NT-3,since more water-soluble groups have been introduced into its structure,does not only have a very good water solubility,but also has a much higher resistance to acid,and thus has a very good whitening effect on cellulose fiber even if the PH value is only 3-4.3.Directions for use and dosage:Since HPE is a liquid,not so hard to dissolve as VBL and will not cause dust pollution,it is only necessary to weigh out it according to the whitenes required and dilute it in water in any ratio.The dosage recommended is as follow:1)For whitening paper pulp:3-10‰ on weight of dry paper pulp.2)For whitening knitted goods:4-8g/l when using paddyeing process,and if 2-4g anhydrous sodium sulfate is added in the padding bath,the whiteness of fabric will be greatly increased.0.4-1.2% O.W.F..when using dipdyeing process.4.Packaging and storing:Packaged in plastic barrels,25kg or 50kg each.Stored in dry room.Fluorescent Whitening Agent HST(荧光增白剂HST六磺酸型)1.Properties:Appearance:slight yellow liquidStructure:a compound of diphenylethylene triazine typeIonicity:anionicResistance to acid and alkali:suitable for PH2-12Solubility:soluble in water in any ratio.2.Applications:This product is especially suitable for whitening and brightening paper pulp,knitted goods and cotton fabrics.The whitening effect of VBL will decrease remarkably when the PH value is lower than 6,while HST,since more water-soluble groups have been introduced into its structure,does not only have a very good water solubility,but also has a much higher resistance to acid,and thus has a very good whitening effect on cellulose fiber even if the PH value is only 3-4.This product has very excellent resistance to disturbance of cation,it is more superior to common fluorescent whitening agents,so it is specially suitable to coating and sizing press in paper-making when cation auxiliaries is necessary.3.Directions for use and dosage:Since RSB is a liquid,not so hard to dissolve as VBL and will not cause dust pollution,it is only necessary to oweigh out it according to the whiteners required and dilute it in water in any ratio.The dosage recommended is as follows:1)For whitening paper pulp:3-10‰ on weight of dry paper pulp.2) For whitening knitted goods:4-8g/l when using pad-dyeing process,and if 2-4g anhydrous sodium sulfate is added in the padding bath,the whiteness of fabric will be greatly increased.0.4-1.2% O.W.F.when using dip-dyeing process.4.Packaging and storing:Packaged in plastic barrels,25kg or 50kg each.Stored in dry room.Fluorescent Whitening Agent HS(荧光增白剂HS特殊型)1.Properties:Appearance:light yellow transparent clear liquid.Structure:a compound of diphenylethylene xenene type.Solubility:soluble in water,alcohol,ether,DMF,etc.Fluorescence tone:slight greenish blue.Resistance to chlorine-bleaching and oxygen-bleaching:extremely strong resistance to chlorine-and oxygen-bleaching,and having very good whitening effect even if under strong acidic or alkalic conditions.2.Applications:Because of its extremely strong resistance to chlorine-and oxygen-bleaching,HS is the best whitening agent for natural fibres,and could be widely used in detergent,dyeing & printing and paper-making industries,etc.It is also the most excellent whitening agent for washing powder,washing cream and liquid detergent.As its solvent is polyhydric alcohol,preventing pollution of liquid detergent by bacteria propagation,so it is specially suitable for liquid detergent.3.Directions for use and dosage:Since HS has a very good affinity for cellulose fiber and is soluble in water,it can be used at room temperature for whitening cellulose fiber,polyamide fiber and protein fiber.For whitening textiles,the dosage should normally be 0.1-1.0% O.W.F.When used in detergents,it can be added at any stage of production process and the dosage should be 0.15-1.2% on weight of detergent.4.Packaging and storing:Packaged in plastic barrels,25kg or 50kg each.Stored in dry room.。
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New Effective Optical Brightener KCB (荧光增白剂KCB)Chemical Component:Benzoxazolyl Naphthalene Optical BrightenerTypical Properties:Appearance: Yellowish Crystal PowderEffective Assay: 99%minAsh Content: 0.5%maxV olatile: 0.3%maxCharacters:New effective optical brightener SP-KCB is an improved product of current widely used normal KCB(Hostalux KCB), whose temperature and weather resistance capability is much better than normal KCB. It’s extremely effective in brightening and present blue optical light when mixed in synthetic fiber and plastics, especially in colorful plastics. Much convenient, less dosage, better whiteness and lower price are the superior characters.Application :SP-KCB can be widely used in EV A, PET, and is the best choice for making sports shoes material. It is also good at applying into plastic films such as PE, PP, PVC, PS, ABS, and extrude molding material, injection molding material. The whiteness of coating and natural painting could also be greatly improved by SP-KCB.Safety and stock:Keeping in stock as ordinary chemicals. Wear protective goggles and gloves while applying.A void direct contact with skin and eyes. Soap clean if skin contaminated.Packing:25kg / fiber drum with PE linerOptical Brightener Odyssey OB-1 (荧光增白剂OB-1)Optical brighteners are added to many materials to reduce yellowing, improve whiteness, and to enhance the brightness of a product. Odyssey OB-1 is used widely in the plastic market. Because of its excellent brightening ability,good thermal stability,and compatibility with many polymers. Typical PropertiesChemical name: 2,2-(1,2-Ethenediyldi-4, 1-phenylene) bisbenzoxazoleMolecular weight: 414.4CAS No.: 1533-45-5C.I.: 393Specifications:Ash %Empirical FormulaMelting Point(DTA),CAppearanceOdorV olatile Content %Assay %Particle Size0.3maxC28H18N2O2353-359Y ellowish Green PowderFree of odor0.3max99min200 meshesEffect of Optical Brighteners on the Whiteness of PolymersOptical brighteners function by absorbing ultraviolet radiation and remitting blue light. The emitted blue light will reduce the yellow color of a polymer. In the presence of a whitening agent, such as TiO2, the use of Odyssey OB-1 will produce a brilliant white o r “white than white” appearance.Two primary factors affect the whiteness/yellowness of a formulation. They are the color of the base polymer and the level of brightener added. If no whitening agent, such as TiO2, is used, the level of Odyssey OB-1 required will likely be lower than when a whitening agent is preset. This level might be as little as 25-50 ppm. In determining the optimum concentration of brightener, the effect of any other UV-absorbing materials in the plastic should be considered. It is important that users perform sufficient evaluations to determine the optimum level of Odyssey OB-1 for their specific end uses.Methods of AdditionTo be effective, an optical brightener must dissolve in the polymer to which it is added. Since the typical addition levels for Odyssey OB-1 in the range of 100-400 ppm, the use of a concentrate, or masterbatch, is recommended. Concentrates are containing 1%-10% by weight of Odyssey OB-1 typical.The concentrate can be produced on an extruder using normal processing conditions for the polymer, including drying if necessary. The concentrate is then let down to typical use levels in the final formulation. Plastics compounding equipment is normally adequate for producing Odyssey OB-1 brightener formulations. The key requirement is to thoroughly disperse the brightener so that it will dissolve uniformly throughout the molten polymer. This is usually achieved most readily with a concentrate.Improving Whiteness of Recycled PolymerThe business of processing post consumer plastics and waste polymer continue to grow. These materials can be recycled into a variety of useful products, from plastic lumber to synthetic fiber. Polyester bottle polymer, polyester plastic waste, and waste fiber polymer can be recycled into polyester fiber that can be used in carpets, filling and insulation material, nonwovens, and apparel. One of the shortcomings of processing these materials is the uncertainty of the color of the source material.By using optical brighteners, the value of the recycled materials can be significantly enhanced by providing a more uniform white. Odyssey OB-1 will greatly improve the whiteness, Normal fiber applications require only 200-300 ppm in new polymer, but recycled material may require as much as 300-450 ppm. Optical brighteners are very effective in improving the appearance of the polymer or fiber. Off-class or second-quality nylon polymer can also be improved in the same way.Food Industry ApplicableOdyssey OB-1 complies with regulations for indirect food additives. Odyssey OB-1 is restricted to use as an optical brightener for all polymers at a level not to exceed 0.025% by weight of polymer and at the temperatures not to exceed 135"C(275"F).Packing:25kg / fiber drum with PE linerHomepage Chinese V ersionWelcome you to visit the website of Beijing Odyssey Chemicals Co.,Ltd.© Beijing Odyssey Chemicals Co.,Ltd. All Rights Reserved.Optical Brightener Odyssey OB (荧光增白剂OB)Odyssey OB is a high molecular weight optical bright ener of the thiophenediyl benzoxazole class, suitable for the optical brightener of polymers at all stage of processing.Typical PropertiesChemical Name: 2,2-(2,5-Thiophenediyl) Bis[5-(1,1-dimethylethy)]BenzoxazoleMolecular Formula: C27H27O2N2SMolecular Weight: 443CAS No.: 7128-64-5C.I.: 184Specifications:Appearance: Yellowish or yellowish green crystal powderAssay: 99% min.Melting Point: 196-203?Ash: 0.3% max.V olatile Content: 0.3%max.Particle size: 200 meshesMax. Absorption Wavelength: 375nm(in ethanol)Properties:Optical Brightener Odyssey OB is highly effective in polymer substrates such as engineering plastics, e.g. PE, PC, PVC, PS, ABS, and PP, adhesive and other organic substrates.Main applications include fibers, molded articles, films and sheets. And also can be used in clear lacquers, pigmented lacquers, paints, printing ink and synthetic leather. It will produce brilliant brightness with dyestuff, which is very efficient in directions for multicolor.Optical Brightener Odyssey OB can be used as a tracer in a variety of applications.Odyssey OB features excellent resistance to heat, exceptional whitening properties, good light fastness and low volatility. It is readily soluble in organic solvents and features good compatibility in various substrates. The product is especially suitable for applications such as films and fiber. Odyssey OB enhances the whiteness of the substrate. In combination with dyes, the product produces particularly bright shades. Its excellent heat resistance renders Odyssey OB suitable for all relevant processing conditions. It is suitable for packing applications but local regulations must be observed.Application (in each 100kg polymer):PVC: White 0.01-0.05 (10g-50g)Transparent 0.0001-0.001% (0.1g-1g)PS: White 0.001% (1g)Transparent 0.0001-0.001% (0.1g-1g)ABS: Primitive color 0.01-0.05% (10g-50g)(effectively eliminate the intrinsic yellow color in ABS)White 0.01-0.05% (10g-50g)PE, PP: Achromaticity 0.0005-0.001% (0.5g-1g)White 0.005-0.05% (5g-50g)Other Plastics: Refer to the directions given above.When Odyssey OB is used in PMMA polymerization, take care that the polymerization is conducted to full completion since interaction with residual monomer can cause discoloration in the final application.Attention:Please mix thoroughly to obtain best effect. OB concentrated master batch can be even better mixed.Safety and Stock:Keeping in stock as ordinary chemicals. Wear protective goggles and gloves while applying.A void direct contact with skin and eyes. Soap clean if skin contaminated.Packing:25kg / fiber drum with PE linerProduct name: Optical Brightening Agent PF (荧光增白剂PF)·Chemical name: 1.2 di(5-mythyl-benziazolyl)ethylene·Structural No: C.i 135·CAS NO: 12224-12-3·Structural formula:·Molecular formula: C18H14N2O2·Molecular weight: 290·Technical index: Appearance:Light yellow crystal powderMelting Point:184~186°CPurity:≥98.0%·Uses: It is mainly used in increasing the brightening and beauty of PVC,PS,PP,polyester film, high or low voltage PE,ABS, organic glass, business card,high quality paper,etc.. ·Precaution: The information of our products is for reference only. We are not responsible for any unexpected results or patent dispute caused by it.Product name: Optical Brightening Agent PF-3 (荧光增白剂PF-3)·Chemical name: 1.2 di(5-mythyl-benziazolyl)ethylene·Structural No: C.i 135·CAS NO: 12224-12-3·Structural formula:·Molecular formula: C18H14N2O2·Molecular weight: 290·Technical index: Appearance:Light yellow crystal powderMelting Point:188~190°CPurity:≥99.0%·Uses: It is mainly used in increasing the brightening and beauty of PVC,PS,PP,polyester film, high or low voltage PE,ABS, organic glass, business card,high quality paper,etc..·Precaution: The information of our products is for reference only. We are not responsible for any unexpected results or patent dispute caused by it.Product name: Optical Brightening Agent ER-1(荧光增白剂ER-1)·Chemical name: 1,4'-bis(2-cyanostyryl) Benzene·Structural No: C.i 199·CAS NO: 13001-40-6·Structural formula:·Molecular formula: C24H16N2·Molecular weight: 332·Properties: It has high whitening brightening effect and excellent fastness to sublimation. ·Technical index: Appearance:greenish yellow crystalline powder Melting Point:230-232°C Purity:≥98.0% Maximum UV Absorption Spectrum:365nm·Uses: Mainly be used in whitening of polyester fiber and as the raw material of paste form brightening agent in textile dyeing.·Precaution: The information of our products is for reference only. We are not responsible for any unexpected results or patent dispute caused by it.Product name: Optical Brightening Agent ER-Ⅱ(荧光增白剂ER-11)·Chemical name: 1,4'-bis(2,4'-cyano-phenlene)-benzene·Structural No: C.i 199:1·CAS NO: 13001-40-6·Molecular formula: C24H16N2·Molecular weight: 332·Properties: bluish color shade with high whitening brightening effect and excellent fastness to sublimation.·Technical index: Appearance:slight yellow powder Melting Point:183~185°C Purity:≥98.0% Maximum UV Absorption Spectrum:369nm·Uses: mainly be used as whitening agent for polyester fiber, as well the raw material of makingpaste form brightening agent in textile dyeing.·Precaution: The information of our products is for reference only. We are not responsible forany unexpected results or patent dispute caused by it.Product name: Optical Brightening Agent KSN (荧光增白剂KSN)·Chemical name: 4.4-bis(5-methyl-2-benzoxoazol)-ethylene·Structural formula:·Properties: 1. being highly whiteness with small usage.2. multipurpose used for whitening of polyester fiber and plastic.3. having a good compatibility and good fastness to light and sublimation. Can be used for high temperature process.·Treating Process: Overlay plastic:0.5-2g/100kgPolyester fiber:10-20g·Package: 20kg cardboard drum·Technical index: Appearance: greenish yellow powderMelting process: 275~280°CAsh content:≤0.5%Purity:≥98.0%V olatile content:≤0.5%Fineness(300 mesh):100%·Uses: mainly be used in whitening of polyester, polyamide, polyacrylonitrile fiber, the plastic film and all plastic pressing process. Can suitable for synthesizing high polymer including polymeric process.·Precaution: The information of our products is for reference only. We are not responsible for any unexpected results or patent dispute caused by itFLUORESCENT BRIGHTENER CBS-X(洗涤用荧光增白剂CBS-X)MOLECULAR FORMULA: C28H20S2O6Na2MOLECULAR WEIGHT: 562.60(As International relative Atom Mass 1997)EXCUTIVE STANDARD: Q/LQH005-2002PARAMETERS:APPEARANCE: Pistachio granuleSMELL: No special smellMAX UV ABSORPTION SPECTRUM: 348nm±1nmEXTINCTION V ALUE: 0.829-0.8851% EXTINCTION INDEX: 1105-1181PROPERTY:Optical Brightener CBS-X is a disulfonic distyrylbiphenyl biphenyl compound, which is the most excellent brightener used in detergent industry. It can soluble in water easily and has betterwhitener effect on cellulose fiber, polyamide and proteinic fiber at room temperature. It has high brighten intensity on cotton cloth as much 2.7times diphenylethylene tristriazine derivatives, and has well optical blue color moniter, dissolve and disperse properties. It has extremely high stability with hypochloride sodium, it is a bleaching resistenct optical brightener.APPLICA TION:Used in detergent industry and soap industry.PROCEDURE:1. It can be added in any procedure of the process of synthetic detergent and soap. It can get excellent and soap. It can get excellent effect if used together with optical brightener 31#.2. Recommended dosage:Common washing powder: 0.005-0.03% Soap: 0.01-0.05%Concentrated washing powder: 0.01-0.05% Soften agent of fabric fiber: 0.01-0.05%Liquid detergent: 0.02-0.06% Washing syrup: 0.005-0.02% PACKAGE: Packed per 25kg in cardboard bucket or cardboard box after being packed in plastic bag first.TRANSPORTA TION: A void upside down, sunlight, wet and crash, avoide damage the package. STORAGE: Should be stored in cool, dry and ventilate place, stored term shouldn’t exceed 2 yearsProduct name: Optical Brightening Agent EBF (荧光增白剂EBF)·Chemical name: 2.5-bis-(benzoxazol-2-)thiophene·Structural No: C.i 185·CAS NO: 12224-40-6·Structural formula:·Molecular formula: C18H10N2O2S·Molecular weight: 318·Technical index: Appearance:Bright-colored light yellowist crystal powderMelting Point:216~220°CPurity:≥98.0%·Uses: It is used in making commercialized Brightener-EB,and can also be used in various polyolefing plastics,ABS engineering plastics and organic glass to make their color brighter. ·Precaution: The information of our products is for reference only. We are not responsible for any unexpected results or patent dispute caused by it.Product name: Optical Brightening Agent FP-127 (荧光增白剂FP-127)·Chemical name: 1,1'-biphenyl-4,4'-bis-benzoxazole·Structural No: C.i 378·CAS NO: 40470-68-6·Structural formula:·Molecular formula: C30H26O2·Molecular weight: 418·Technical index: Appearance:slight yellow powderMelting Point:219-221°CPurity:≥98.0%Maximum UV Spectrum Absorption:359nm·Uses: Mainly be used in whitening of plastics such as PVC,PS,ABS,TPR,etc. ·Precaution: The information of our products is for reference only. We are not responsible for any unexpected results or patent dispute caused by it.Fluorescent Whitening Agent HW A(荧光增白剂HW A二磺酸型)1.Properties:Appearance:yellow-brown clear viscous liquidStructure:a compound of diphenylethylene triazine typeIonicity:anionicPH V alue:8-10Resistance to acid and alkali:suitable for PH5-13Solubility:soluble in water in any ratio2.Applications:Fluorescent whitening agent(FWA) for cotton/cellulose fibres,nylon fibres,rayon fibres,wool and silk and their blends.High affinity,extremely suitable for exhaust application.Extremely good light and wet fastness properties.Good stability in peroxide and reductive bleaching liquors.Can be used in boiling-off baths.Extremely suitable for fluorescent whitening of viscose and modal fibres3.Amounts required:Cotton and bast fibres:0.18-0.7%HW A;Viscose and bast fibres:0.4-1.5% HWA,3-5 g/l sodium sulphate calc.Polyamide fibres:0.5-2% HWA,2-4 g/L hydrosulphite-based reducing agent.Wool,silk:0.5-1.5%HWA,2-4 g/L hydrosulphite-based reducing agent4.Packaging and storing:20/25/50/220KGS plastic drums.Stored in cool place and prevented it from being shone by sunlight.Fluorescent Whitening Agent HPE(荧光增白剂HPE四磺酸型)1.Properties:Appearance:amber clear viscous liquidStructure:a compound of diphenylethylene triazine typeIonicity:anionicResistance to acid and alkali:suitable for PH2-12Solubility:soluble in water in any ratio.2.Applications:This product is especially suitable for whitening and brightening paper pulp,knitted goods and cotton fabrics.The whitening effect of VBL will decrease remarkably when the PH value is lower than 6,while NT-3,since more water-soluble groups have been introduced into its structure,does not only have a very good water solubility,but also has a much higher resistance to acid,and thus has a very good whitening effect on cellulose fiber even if the PH value is only 3-4.3.Directions for use and dosage:Since HPE is a liquid,not so hard to dissolve as VBL and will not cause dust pollution,it is only necessary to weigh out it according to the whitenes required and dilute it in water in any ratio.The dosage recommended is as follow:1)For whitening paper pulp:3-10‰ on weight of dry paper pulp.2)For whitening knitted goods:4-8g/l when using paddyeing process,and if 2-4g anhydrous sodium sulfate is added in the padding bath,the whiteness of fabric will be greatly increased.0.4-1.2% O.W.F..when using dipdyeing process.4.Packaging and storing:Packaged in plastic barrels,25kg or 50kg each.Stored in dry room.Fluorescent Whitening Agent HST(荧光增白剂HST六磺酸型)1.Properties:Appearance:slight yellow liquidStructure:a compound of diphenylethylene triazine typeIonicity:anionicResistance to acid and alkali:suitable for PH2-12Solubility:soluble in water in any ratio.2.Applications:This product is especially suitable for whitening and brightening paper pulp,knitted goods and cotton fabrics.The whitening effect of VBL will decrease remarkably when the PH value is lower than 6,while HST,since more water-soluble groups have been introduced into its structure,does not only have a very good water solubility,but also has a much higher resistance to acid,and thus has a very good whitening effect on cellulose fiber even if the PH value is only 3-4.This product has very excellent resistance to disturbance of cation,it is more superior to common fluorescent whitening agents,so it is specially suitable to coating and sizing press in paper-making when cation auxiliaries is necessary.3.Directions for use and dosage:Since RSB is a liquid,not so hard to dissolve as VBL and will not cause dust pollution,it is only necessary to oweigh out it according to the whiteners required and dilute it in water in any ratio.The dosage recommended is as follows:1)For whitening paper pulp:3-10‰ on weight of dry paper pulp.2) For whitening knitted goods:4-8g/l when using pad-dyeing process,and if 2-4g anhydrous sodium sulfate is added in the padding bath,the whiteness of fabric will be greatly increased.0.4-1.2% O.W.F.when using dip-dyeing process.4.Packaging and storing:Packaged in plastic barrels,25kg or 50kg each.Stored in dry room.Fluorescent Whitening Agent HS(荧光增白剂HS特殊型)1.Properties:Appearance:light yellow transparent clear liquid.Structure:a compound of diphenylethylene xenene type.Solubility:soluble in water,alcohol,ether,DMF,etc.Fluorescence tone:slight greenish blue.Resistance to chlorine-bleaching and oxygen-bleaching:extremely strong resistance to chlorine-and oxygen-bleaching,and having very good whitening effect even if under strong acidic or alkalic conditions.2.Applications:Because of its extremely strong resistance to chlorine-and oxygen-bleaching,HS is the best whitening agent for natural fibres,and could be widely used in detergent,dyeing & printing and paper-making industries,etc.It is also the most excellent whitening agent for washing powder,washing cream and liquid detergent.As its solvent is polyhydric alcohol,preventing pollution of liquid detergent by bacteria propagation,so it is specially suitable for liquid detergent.3.Directions for use and dosage:Since HS has a very good affinity for cellulose fiber and is soluble in water,it can be used at room temperature for whitening cellulose fiber,polyamide fiber and protein fiber.For whitening textiles,the dosage should normally be 0.1-1.0% O.W.F.When used in detergents,it can be added at any stage of production process and the dosage should be 0.15-1.2% on weight of detergent.4.Packaging and storing:Packaged in plastic barrels,25kg or 50kg each.Stored in dry room.。