钛白粉 物质安全数据表 MSDS
钛白粉安全说明书
Right to Know Hazardous Substance Fact SheetCommon Name: TITANIUM DIOXIDESynonyms: Rutile; Anatase; Brookite Chemical Name: Titanium OxideDate: July 2011 Revision: May 2016 CAS Number:Anatase Titanium DioxideRutile Titanium Dioxide13463-67-71317-70-0 (powder form)1317-80-2 (powder form) RTK Substance Number: 1861DOT Number: NoneDescription and UseTitanium Dioxide is an odorless, white powder. It is used in paints, cosmetics, plastics, paper and food.Reasons for Citation④Titanium Dioxide is on the Right to Know Hazardous Substance List because it is cited by OSHA, ACGIH, NIOSH and IARC.④This chemical is on the Special Health Hazard Substance List.S EE G LOSSARY ON PAGE 5.FIRST AIDEye Contact④Immediately flush with large amounts of water for at least 15 minutes, lifting upper and lower lids. Remove contact lenses, if worn, while rinsing.Skin Contact④Remove contaminated clothing and wash contaminated skin with soap and water.Inhalation④Remove the person from exposure.④Begin rescue breathing (using universal precautions) if breathing has stopped and CPR if heart action has stopped.④Transfer promptly to a medical facility.EMERGENCY NUMBERSPoison Control: 1-800-222-1222CHEMTREC: 1-800-424-9300NJDEP Hotline: 1-877-927-6337National Response Center: 1-800-424-8802EMERGENCY RESPONDERS >>>> SEE LAST PAGEHazard SummaryHazard Rating NJDOH NFPA HEALTH 2 - FLAMMABILITY0 - REACTIVITY0 - CARCINOGENPOISONOUS GASES ARE PRODUCED IN FIRE.DOES NOT BURNHazard Rating Key: 0=minimal; 1=slight; 2=moderate; 3=serious;4=severe④Titanium Dioxide can affect you when inhaled.④Titanium Dioxide should be handled as a CARCINOGEN--WITH EXTREME CAUTION.④Exposure can irritate the eyes, nose and throat.④Titanium Dioxide can irritate the lungs. Repeated exposure may cause bronchitis to develop with coughing, phlegm,and/or shortness of breath.Workplace Exposure Limits OSHA: The legal airborne permissible exposure limit (PEL) is15 mg/m3 averaged over an 8-hour workshift.NIOSH: The recommended airborne exposure limit (REL) is2.4 mg/m3 for fine Titanium Dioxide, and 0.3 mg/m3for ultrafine Titanium Dioxide, averaged over a 10-hour workshift.ACGIH: The threshold limit value (TLV) is 10 mg/m3 averaged over an 8-hour workshift.④Titanium Dioxide may be a CARCINOGEN in humans. There may be no safe level of exposure to a carcinogen, so all contact should be reduced to the lowest possible level.Determining Your Exposure④Read the product manufacturer’s Material Safety DataSheet (MSDS) and the label to determine productingredients and important safety and health informationabout the product mixture.④For each individual hazardous ingredient, read the NewJersey Department of Health Hazardous Substance FactSheet, available on the RTK website(/health/eoh/rtkweb) or in your facility’s RTKCentral File or Hazard Communication Standard file.④You have a right to this information under the New JerseyWorker and Community Right to Know Act and the Public Employees Occupational Safety and Health (PEOSH) Act if you are a public worker in New Jersey, and under thefederal Occupational Safety and Health Act (OSHA) if you are a private worker.④The New Jersey Right to Know Act requires mostemployers to label chemicals in the workplace andrequires public employers to provide their employees with information concerning chemical hazards and controls.The federal OSHA Hazard Communication Standard (29CFR 1910.1200) and the PEOSH Hazard Communication Standard (N.J.A.C. 12:100-7) require employers to provide similar information and training to their employees.This Fact Sheet is a summary of available information regarding the health hazards that may result from exposure. Duration of exposure, concentration of the substance and other factors will affect your susceptibility to any of the potential effects described below.Health Hazard InformationAcute Health EffectsThe following acute (short-term) health effects may occur immediately or shortly after exposure to Titanium Dioxide:④Exposure can irritate the eyes, nose and throat.Chronic Health EffectsThe following chronic (long-term) health effects can occur at some time after exposure to Titanium Dioxide and can last for months or years:Cancer Hazard④Titanium Dioxide may be a CARCINOGEN in humans since it has been shown to cause lung cancer in animals.④Many scientists believe there is no safe level of exposure toa carcinogen. Such substances may also have the potential for causing reproductive damage in humans.Reproductive Hazard④According to the information presently available to the New Jersey Department of Health, Titanium Dioxide has not been tested for its ability to affect reproduction.Other Effects④Titanium Dioxide can irritate the lungs. Repeated exposure may cause bronchitis to develop with coughing, phlegm,and/or shortness of breath.MedicalMedical TestingFor frequent or potentially high exposure (half the REL or greater), the following are recommended before beginning work and at regular times after that:④Lung function testsAny evaluation should include a careful history of past and present symptoms with an exam. Medical tests that look for damage already done are not a substitute for controlling exposure.You have a legal right to request copies of your medical testing under the OSHA Access to Employee Exposure and Medical Records Standard (29 CFR 1910.1020).Mixed Exposures④Smoking can cause heart disease, lung cancer, emphysema, and other respiratory problems. It may worsen respiratory conditions caused by chemical exposure. Even if you have smoked for a long time, stopping now will reduce your risk of developing health problems.Workplace Controls and Practices Very toxic chemicals, or those that are reproductive hazards or sensitizers, require expert advice on control measures if a less toxic chemical cannot be substituted. Control measures include: (1) enclosing chemical processes for severely irritating and corrosive chemicals, (2) using local exhaust ventilation for chemicals that may be harmful with a single exposure, and (3) using general ventilation to control exposures to skin and eye irritants. For further information on workplace controls, consult the NIOSH document on Control Banding at /niosh/topics/ctrlbanding/.The following work practices are also recommended:④Label process containers.④Provide employees with hazard information and training.④Monitor airborne chemical concentrations.④Use engineering controls if concentrations exceed recommended exposure levels.④Provide eye wash fountains and emergency showers.④Wash or shower if skin comes in contact with a hazardous material.④Always wash at the end of the workshift.④Change into clean clothing if clothing becomes contaminated.④Do not take contaminated clothing home.④Get special training to wash contaminated clothing.④Do not eat, smoke, or drink in areas where chemicals are being handled, processed or stored.④Wash hands carefully before eating, smoking, drinking, applying cosmetics or using the toilet.In addition, the following may be useful or required:④Use a vacuum or a wet method to reduce dust during clean-up. DO NOT DRY SWEEP.④Use a high efficiency particulate air (HEPA) filter when vacuuming. Do not use a standard shop vacuum.Personal Protective EquipmentThe OSHA Personal Protective Equipment Standard (29 CFR 1910.132) requires employers to determine the appropriate personal protective equipment for each hazard and to train employees on how and when to use protective equipment. The following recommendations are only guidelines and may not apply to every situation.Gloves and Clothing④Avoid skin contact with Titanium Dioxide. Wear personal protective equipment made from material that can not be permeated or degraded by this substance. Safety equipment suppliers and manufacturers can provide recommendations on the most protective glove and clothing material for your operation.④The recommended glove materials for Titanium Dioxide are Nitrile, Neoprene and Natural Rubber.④The recommended protective clothing material for Titanium Dioxide is Tyvek®, or the equivalent.④All protective clothing (suits, gloves, footwear, headgear) should be clean, available each day, and put on before work. Eye Protection④Wear direct vent goggles when airborne particles or dust are present.Respiratory ProtectionImproper use of respirators is dangerous. Respirators should only be used if the employer has implemented a written program that takes into account workplace conditions, requirements for worker training, respirator fit testing, and medical exams, as described in the OSHA Respiratory Protection Standard (29 CFR 1910.134).④Where the potential exists for exposure over 2.4 mg/m3 for fine Titanium Dioxide, or 0.3 mg/m3 for ultrafine Titanium Dioxide, use a NIOSH approved supplied-air respirator with a full facepiece operated in a pressure-demand or other positive-pressure mode. For increased protection use in combination with an auxiliary self-contained breathing apparatus or an emergency escape air cylinder.Fire HazardsIf employees are expected to fight fires, they must be trained and equipped as stated in the OSHA Fire Brigades Standard (29 CFR 1910.156).④Extinguish fire using an agent suitable for type of surrounding fire. Titanium Dioxide itself does not burn.④POISONOUS GASES ARE PRODUCED IN FIRE.Spills and EmergenciesIf employees are required to clean-up spills, they must be properly trained and equipped. The OSHA Hazardous Waste Operations and Emergency Response Standard (29 CFR 1910.120) may apply.If Titanium Dioxide is spilled, take the following steps:④Evacuate personnel and secure and control entrance to the area.④Eliminate all ignition sources.④Moisten spilled material first or use a HEPA-filter vacuum for clean-up and place into sealed containers for disposal.④It may be necessary to contain and dispose of Titanium Dioxide as a HAZARDOUS WASTE. Contact your state Department of Environmental Protection (DEP) or your regional office of the federal Environmental Protection Agency (EPA) for specific recommendations.For more information, please contact: New Jersey Department of Health Right to Know PO Box 368Trenton, NJ 08625-0368 Phone: 609-984-2202 Fax: 609-984-7407E-mail:*************Web address: /health/eoh/rtkweb The Right to Know Hazardous Substance Fact Sheets are not intended to be copied and soldfor commercial purposes . Handling and StoragePrior to working with Titanium Dioxide you should be trained on its proper handling and storage.④ Titanium Dioxide powders or dusts may react violently with CHEMICALLY ACTIVE METALS (such as POTASSIUM, SODIUM, MAGNESIUM and ZINC).④ Titanium Dioxide powders or dusts are not compatible with OXIDIZING AGENTS (such as PERCHLORATES, PEROXIDES, PERMANGANATES, CHLORATES,NITRATES, CHLORINE, BROMINE and FLUORINE) and STRONG ACIDS (such as HYDROCHLORIC, SULFURIC and NITRIC).④ Store in tightly closed containers in a cool, well-ventilated area.Occupational Health InformationResourcesThe New Jersey Department of Health offers multiple services in occupational health. These services include providing informational resources, educational materials, public presentations, and industrial hygiene and medical investigations and evaluations.GLOSSARYACGIH is the American Conference of Governmental Industrial Hygienists. They publish guidelines called Threshold Limit Values (TLVs) for exposure to workplace chemicals.Acute Exposure Guideline Levels (AEGLs) are established by the EPA. They describe the risk to humans resulting from once-in-a lifetime, or rare, exposure to airborne chemicals.Boiling point is the temperature at which a substance can change its physical state from a liquid to a gas.A carcinogen is a substance that causes cancer.The CAS number is unique, identifying number, assigned by the Chemical Abstracts Service, to a specific chemical.CFR is the Code of Federal Regulations, which are the regulations of the United States government.A combustible substance is a solid, liquid or gas that will burn.A corrosive substance is a gas, liquid or solid that causes destruction of human skin or severe corrosion of containers. The critical temperature is the temperature above which a gas cannot be liquefied, regardless of the pressure applied.DEP is the New Jersey Department of Environmental Protection.DOT is the Department of Transportation, the federal agency that regulates the transportation of chemicals.EPA is the Environmental Protection Agency, the federal agency responsible for regulating environmental hazards. ERG is the Emergency Response Guidebook. It is a guide for emergency responders for transportation emergencies involving hazardous substances.Emergency Response Planning Guideline (ERPG) values provide estimates of concentration ranges where one reasonably might anticipate observing adverse effects.A fetus is an unborn human or animal.A flammable substance is a solid, liquid, vapor or gas that will ignite easily and burn rapidly.The flash point is the temperature at which a liquid or solid gives off vapor that can form a flammable mixture with air. IARC is the International Agency for Research on Cancer, a scientific group.Ionization Potential is the amount of energy needed to remove an electron from an atom or molecule. It is measured in electron volts.IRIS is the Integrated Risk Information System database on human health effects that may result from exposure to various chemicals, maintained by federal EPA. LEL or Lower Explosive Limit, is the lowest concentration of a combustible substance (gas or vapor) in the air capable of continuing an explosion.mg/m3means milligrams of a chemical in a cubic meter of air. It is a measure of concentration (weight/volume).A mutagen is a substance that causes mutations. A mutation is a change in the genetic material in a body cell. Mutations can lead to birth defects, miscarriages, or cancer.NFPA is the National Fire Protection Association. It classifies substances according to their fire and explosion hazard.NIOSH is the National Institute for Occupational Safety and Health. It tests equipment, evaluates and approves respirators, conducts studies of workplace hazards, and proposes standards to OSHA.NTP is the National Toxicology Program which tests chemicals and reviews evidence for cancer.OSHA is the federal Occupational Safety and Health Administration, which adopts and enforces health and safety standards.PEOSHA is the New Jersey Public Employees Occupational Safety and Health Act, which adopts and enforces health and safety standards in public workplaces.Permeated is the movement of chemicals through protective materials.ppm means parts of a substance per million parts of air. It is a measure of concentration by volume in air.Protective Action Criteria (PAC) are values established by the Department of Energy and are based on AEGLs and ERPGs. They are used for emergency planning of chemical release events.A reactive substance is a solid, liquid or gas that releases energy under certain conditions.STEL is a Short Term Exposure Limit which is usually a 15-minute exposure that should not be exceeded at any time during a work day.A teratogen is a substance that causes birth defects by damaging the fetus.UEL or Upper Explosive Limit is the highest concentration in air above which there is too much fuel (gas or vapor) to begin a reaction or explosion.Vapor Density is the ratio of the weight of a given volume of one gas to the weight of another (usually Air), at the same temperature and pressure.The vapor pressure is a force exerted by the vapor in equilibrium with the solid or liquid phase of the same substance. The higher the vapor pressure the higher concentration of the substance in air.Common Name: TITANIUM DIOXIDESynonyms: Rutile; Titanium Oxide; Anatase; BrookiteCAS No: 13463-67-7; 1317-70-0 (powder form); 1317-80-2 (powder form) Molecular Formula: TiO 2RTK Substance No: 1861Description: Odorless, white powderHAZARD DATA Hazard Rating Firefighting Reactivity2 - Health0 - Fire0 - ReactivityDOT#: NoneERG Guide #: None Hazard Class: None Extinguish fire using an agent suitable for type ofsurrounding fire. Titanium Dioxide itself doesnot burn.POISONOUS GASES ARE PRODUCED IN FIRE.Titanium Dioxide powders or dusts may react violentlywith CHEMICALLY ACTIVE METALS (such asPOTASSIUM, SODIUM, MAGNESIUM and ZINC).Titanium Dioxide powders or dusts are not compatiblewith OXIDIZING AGENTS (such as PERCHLORATES,PEROXIDES, PERMANGANATES, CHLORATES,NITRATES, CHLORINE, BROMINE and FLUORINE) andSTRONG ACIDS (such as HYDROCHLORIC,SULFURIC and NITRIC).SPILL/LEAKS PHYSICAL PROPERTIESIsolation Distance:Spill: 25 meters (75 feet)Fire: 800 meters (1/2 mile)Moisten spilled material first or use a HEPA-filtervacuum for clean-up and place into sealed containers for disposal. Odor Threshold:Flash Point:Vapor Pressure:Specific Gravity:Water Solubility:Boiling Point:Melting Point:Molecular Weight:OdorlessNoncombustible0 mm Hg at 68o F (20o C)3.9 to4.2 (water = 1)Insoluble4,532o to 5,432o F (2,500o to 3,000o C)3,326o to 3,362o F (1,830o to 1,850o C)79.9EXPOSURE LIMITS PROTECTIVE EQUIPMENTOSHA: 15 mg/m3, 8-hr TWANIOSH: 2.4 mg/m3 (fine) and 0.3 mg/m3 (ultrafine), 10-hr TWAACGIH: 10 mg/m3, 8-hr TWAIDLH: 5,000mg/m3The Protective Action Criteria values are:PAC-1 = 30 mg/m3 PAC-2 = 330 mg/m3PAC-3 = 2,000 mg/m3Gloves:Coveralls:Respirator:Nitrile, Neoprene and Natural RubberTyvek®Spill - Full facepiece APR with P100 filters>0.3 mg/m3 (ultrafine) or Fire – SCBA>2.4 mg/m3 (fine) or Fire - SCBA>10 mg/m3 or Fire - SCBAHEALTH EFFECTS FIRST AID AND DECONTAMINATIONEyes: Skin: Inhalation: Chronic: IrritationNo information availableNose and throat irritationCancer (lung) in animalsRemove the person from exposure.Flush eyes with large amounts of water for at least 15 minutes. Removecontact lenses if worn.Remove contaminated clothing and wash contaminated skin with soap andwater.Begin artificial respiration if breathing has stopped and CPR if necessary.Transfer promptly to a medical facility.May 2016 Right to Know Hazardous Substance Fact Sheet。
钛白粉 MSDS ---NEW(1)
SHANGHAI YAOFEN CHEMCIAL CO., LTD.Tel: 86-21-65750911 Fax: 86-21-65070521Add: Ouyang Mansion 16D, Ouyang Road, Shanghai ,ChinaMATERIAL SAFETY DATA SHEET (M.S.D.S)Part One：Chemical Product and Company IdentificationChemical Product Name：Titanium DioxideCode of Technology Specification：1349Molecular Formula：TiO2Molecular Weight：79.9Manufacturer: JiangHu Titanium White Product FactoryPart Two：Composition/Information on IngredientsMain Ingredient：TiO2Content：93%MINCAS No.13463-67-7Part Three：Hazards SummarizingHarmful to Health: No any chance in lungs of the workers who inhale titanium dioxide dusts for long periods. Also, no contagious dermatitis and allergic reaction happened.Risk of Burning & Exploding: Non-burning.Part Four：First-aid MeasuresContact of Skins: Take off the polluted clothes and wash the skins with running water.Contact of Eyes: Lift the eyelids and wash the eyes with running water or physiological saline. Be sent to hospital.Inhalant: Leave the spot immediately to the place with fresh air.Eating: Drink plenty of warm water, or drink emetic to vomit. Be sent to hospital.Part Five：Fire-fighting MeasuresFeature of Risk: No special burning and exploding features.Pernicious Burning Material: Natural decomposition material unknown.Method of Extinguishing: Move the container from the scene of a fire to open place as soon as possible.Part Six：Accidental Release MeasuresEntrance Treatment: Isolate the leakage polluted area and limit on the entrance and exit of irrelevant persons. Persons for emergency treatment are suggested to put on dustproof masks and ordinary clothes. Sweep the polluted dusts carefully to avoid spreading everywhere. Put the polluted dusts into bags and move them to safe place. If the leakage is serious, cover the polluted area in plastic cloth and canvas, and collect them or move to waste-treatment place.SHANGHAI YAOFEN CHEMICAL CO., LTD.Tel: 86-21-65750911 Fax: 86-21-65070521Add: Ouyang Mansion 16D, Ouyang Road, Shanghai ,ChinaPart Seven：Handling and StorageMatters Needing Attention for Operation: Operating in airtight condition and exhausting in some areas. The operators must pass special training and must abide by rules of operation strictly. The operators are suggested to wear filtered dustproof gauze masks with self-inhaling function, to wear safety chemical protection glasses and to wear ordinary work protection gloves. Avoid creating dusts and avoid contacting with acid material. Load and unload with care to avoid breaking of the package. Emergency treatment equipments for leakage must be fitted. Empty containers may have pernicious materials inside.Matters Needing Attention for Storage: Be stored in cool and ventilated warehouse. Be far away from fire and heat sources. Be stored separately from acid materials. Suitable materials for the collection of leakage material should be prepared in storage areas.Part Eight：Exposure Controls/Personal ProtectionProfessional Contact Limitation ValueChina MAC(mg/m3): 10TLVTN: ACGIH 10mg/m3Project Control: Operating in airtight condition and exhausting in some areas.Protection of Breath System: When dust density in the air is in a bit high value, filtered dustproof gauze masks with self-inhaling function are suggested to be worn.Protection of Eyes: Wear safety chemical protection glasses.Protection of Body: Wear ordinary work protection clothes.Protection of Hands: Wear ordinary work protection gloves.Other Protection: Change work clothes in time. Be aware of personnel hygiene.Part Nine：Physical and Chemical PropertiesMain Composition: Content of TiO2:93%MINAppearance & Character：White PowderPH：6.5-8.0Melting Point (℃)：1560Relative Density (water=1)：3.9Solubility: Unsolvable in water, diluents alkali, and diluents acid; solvable in hot concentrated sulpl\huric acid, hydrochloric acid and nitric acid.Main Use：An important white pigment and glaze of porcelain.Part Ten：Stability and ReactivityChemical Stability：Stable.Incompatibility：Strong acid.Polymerization Harmfulness: non-polymerization.Decomposition Meterial: non-decomposition.SHANGHAI YAOFEN CHEMICAL CO., LTD.Tel: 86-21-65750911 Fax: 86-21-65070521Add: Ouyang Mansion 16D,Ouyang Road, Shanghai ,ChinaPart Eleven：Toxicological InformationAcute Toxicity：Non-toxicPart Twelve：Ecological InformationOther Harmful Function: no datum.Part Thirteen：DisposalDisposal Method: Before disposal, read national and local laws and regulations first. Dispose in safe buried method.Part Fourteen：Transport InformationHazards identification: NoneSuggestion according to IMO: The substance subject to IMO IMDG CODE 2008 EDITION. Packaging requirements: Inner package: Bag; Outer package: /Part Fifteen：Regulation InformationRegulation Information: Safety Management Regulation for Dangerous Chemical Goods (issued by the State COUNCIL, Feb, 17th, 1987), Implement Detailed Rules of Safety Management Regulation for Dangerous Chemical Goods (Chemical Labor Issuance[1992]No.677), Rules for Safety Use of Chemical Goods in Work Site ([1996]Labor MINISTRY Issuance No.423), etc. All of them make relevant stipulations in safe use, production, storage, transportation. Loading and unloading, etc. Hygienic Standard for Titanium Dioxide Dust in Air in Workshop (GB 11522-89) stipulates the maximum allowed density and check-and-test method for dust in air in the workshop.Part Sixteen：Other InformationFilled-in Unit: JiangHu Titanium White Product Factory。
钛白粉MSDS
1.化学品及企业信息
化学品中文名称
二氧化钛
编 码
073
俗名/商品名
钛白粉
生效日期
化学品英文名称
titanium dioxide
企 业 名 称
重庆市巴南区渝钛白厂
企业应急电话
地 址
重庆市巴南区新工地
邮 编
国家应急电话
传真
电子邮件地址
2.成分/组成信息
主要成分
■纯品 □混合物
危害成分
二氧化钛
废弃注意事项
14.运输信息
危险货物编号
无资料
UN编号
无资料
包装标志
无资料
包装类别
Z01
包装方法
无资料
运输注意事项
起运时包装要完整，装载应稳妥。运输过程中要确保容器不泄漏、不倒塌、不坠落、不 损坏。严禁与酸类等混装混运。运输途中应防曝晒、雨淋，防高温。
15.法规信息
法规信息
《化学危险物品安全管理条例》(1987年2月17日国务院发布)，
《化学危险物品安全管理条例实施细则》(化劳发[1992] 677号)，
《工作场所安全使用化学品规定》([1996]劳部发423号)等法规，针对化学危险品的安全使用、生产、储存、运输、装卸等方面均作了相应规定；
《车间空气中二氧化钛粉尘卫生标准》(GB 11522-89)，规定了车间空气中该物质的最高容许浓度及检测方法。
穿一般作业防护服。
手防护
戴一般作业防护手套。
其他防护
及时换洗工作服。注意个人清洁卫生。
9.理化特性
临界温度（℃）
无意义
临界压力（Mpa）
无意义
燃烧热（KJ/mol）
钛白粉安全技术说明书
钛白粉MSDS第一部分化学品及企业标识化学品中文名称：二氧化钛化学品英文名称：titanium(IV)o xide中文名称2：钛白粉英文名称2：titanium dioxide第二部分：成分/组成信息二氧化钛含量≥90％CAS No. 13463-67-7第三部分：危险性概述健康危害：长期吸入氧化钛粉尘的工人，肺部无任何变化，亦未发生接触性皮炎、过敏反应。
燃爆危险：本品不燃。
第四部分：急救措施皮肤接触：脱去污染的衣着，用流动清水冲洗。
眼睛接触：提起眼睑，用流动清水或生理盐水冲洗。
就医。
吸入：脱离现场至空气新鲜处。
食入：饮足量温水，催吐。
就医。
第五部分：消防措施危险特性：未有特殊的燃烧爆炸特性。
有害燃烧产物：自然分解产物未知。
灭火方法：尽可能将容器从火场移至空旷处。
第六部分：应急处理泄漏应急处理:隔离泄漏污染区，限制出入。
建议应急处理人员戴防尘面具（全面罩），穿一般作业工作服。
避免扬尘，小心扫起，置于袋中转移至安全场所。
若大量泄漏，用塑料布、帆布覆盖。
收集回收或运至废物处理场所处置。
第七部分：操作处置与储存操作注意事项：密闭操作，局部排风。
操作人员必须经过专门培训，严格遵守操作规程。
建议操作人员佩戴自吸过滤式防尘口罩，戴化学安全防护眼镜，戴一般作业防护手套。
避免产生粉尘。
避免与酸类接触。
搬运时轻装轻卸，防止包装破损。
配备泄漏应急处理设备。
倒空的容器可能残留有害物。
储存注意事项：储存于阴凉、通风的库房。
远离火种、热源。
应与酸类分开存放，切忌混储。
储区应备有合适的材料收容泄漏物。
第八部分：接触控制/个体防护职业接触限值中国MAC(mg/m3)：10前苏联MAC(mg/m3)：10TLVTN：ACGIH 10mg/m3TLVWN：未制定标准工程控制：密闭操作，局部排风。
呼吸系统防护：空气中粉尘浓度较高时，建议佩戴自吸过滤式防尘口罩。
眼睛防护：戴化学安全防护眼镜。
身体防护：穿一般作业防护服。
手防护：戴一般作业防护手套。
物质安全数据表MSDS
密度:
1.34g/cm3
维卡软化点
80C
结晶温度:
125
表面电阻
10-12
外观和气味:
透明,无味
表在电阻:
?.m108-12
三、火灾及爆炸危害数据
闪点：
不适用
爆炸极限
爆炸下限
灭火器：
干冰
灭火程序：
火灾时以干冰灭火最为有效
特殊灭火和爆炸危险：
避免接触烟雾，无爆炸危险
四、稳定性与反应性
稳定性与反应性：
废弃物处理方式：
弃置方法须依从国家式地区环境条例和限制
储存方式：
处于阴凉干燥之处，通风，发透气，避免与火源直接接触
其它措施：
避免与化工等其他油性物质接触
该产品在正常情况下储存及处理是稳定的
分解产品：
在高温高压下可分解无害物质
危险性聚合反应：
无
五、身体危害数据
腐蚀性和刺激特性
皮肤接触
不刺激
眼睛接触
不刺激
敏感影响
皮肤敏感
不会引致敏感
身体危害
急性
不会引致敏感
慢性
不会引致敏感
致癌物质
不含有
六、安全操作和使用的防范措施
安全作业：
长期与该产品直接接触对身体没有伤害
物质安全数据表（MSDS）
一、产品成份信息
产品名称：
PET透明片
组成物质
化学成份
含量(g)
含有环境管理物质
含量
检测机构
Cd
Pb
Hg
Cr
ND
(ND=<5ppm)
二甘醇含量
SGS
乙醛含量
C
SGS
钛白粉MSDS
操作注意事项：
密闭操作，局部排风。操作人员必须经过专门培训，严格遵守操作规程。建议操作人员佩戴自吸过滤式防尘口罩，戴化学安全防护眼镜，戴一般作业防护手套。避免产生粉尘。避免与酸类接触。搬运时轻装轻卸，防止包装破损。配备泄漏应急处理设备。倒空的容器可能残留有害物。
储存注意事项：
Z01
包装方法：
无资料。
运输注意事项：
起运时包装要完整，装载应稳妥。运输过程中要确保容器不泄漏、不倒塌、不坠落、不损坏。严禁与酸类等混装混运。运输途中应防曝晒、雨淋，防高温。
第十五部分：法规信息
法规信息
化学危险物品安全管理条例 (1987年2月17日国务院发布)，化学危险物品安全管理条例实施细则 (化劳发[1992] 677号)，工作场所安全使用化学品规定 ([1996]劳部发423号)等法规，针对化学危险品的安全使用、生产、储存、运输、装卸等方面均作了相应规定；车间空气中二氧化钛粉尘卫生标准 (GB 11522-89)，规定了车间空气中该物质的最高容许浓度及检测方法。
呼吸系统防护：
空气中粉尘浓度较高时，建议佩戴自吸过滤式防尘口罩。
眼睛防护：
戴化学安全防护眼镜。
身体防护：
穿一般作业防护服。
手防护：
戴一般作业防护手套。
其他防护：
及时换洗工作服。注意个人清洁卫生。
第九部分：理化特性
主要成分：
含量:≥98％ 。
外观与性状：
白色粉末。
pH：
熔点(℃)：
1560
沸点(℃)：
不溶于水，不溶于稀碱、稀酸，溶于热浓硫酸、盐酸、硝酸。
主要用途：
是一种重要的白色颜料和瓷器釉料。
其它理化性质：
第十部分：稳定性和反应活性
金属钛粉[干的]安全技术说明书MSDS
![金属钛粉[干的]安全技术说明书MSDS](https://img.taocdn.com/s3/m/a8ba19ac77232f60dccca1d4.png)
第一部分化学品及企业标识化学品中文名：金属钛粉[干的]化学品英文名：titanium metal powder，dryCAS No.：7440-32-6EC No.：241-036-9分子式：Ti产品推荐及限制用途：工业及科研用途。
第二部分危险性概述紧急情况概述：固体。
在空气中容易自身燃烧，有引发火灾的危险。
GHS危险性类别：根据GB30000-2013化学品分类和标签规范系列标准（参阅第十六部分），该产品分类如下：发火固体，类别1。
标签要素象形图：警示词：危险危险信息：暴露在空气中会自燃。
预防措施：远离热源、热表面、火花、明火以及其它点火源。
禁止吸烟。
不得与空气接触。
防潮。
保持容器密闭。
戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
事故响应：如皮肤沾染：掸掉皮肤上的细小颗粒。
浸入冷水中或用湿绷带包扎。
安全储存：不适用。
废弃处置：不适用。
物理化学危险：即使数量很少，在与空气接触五分钟内即可自燃。
健康危害：吸入该物质可能会引起对健康有害的影响或呼吸道不适。
意外食入本品可能对个体健康有害。
通过割伤、擦伤或病变处进入血液，可能产生全身损伤的有害作用。
眼睛直接接触本品可导致暂时不适。
环境危害：请参阅SDS第十二部分。
第三部分成分/组成信息第四部分急救措施一般性建议：急救措施通常是需要的，请将本SDS出示给到达现场的医生。
皮肤接触：立即脱去污染的衣物。
用大量肥皂水和清水冲洗皮肤。
如有不适，就医。
眼睛接触：用大量水彻底冲洗至少15分钟。
如有不适，就医。
吸入：立即将患者移到新鲜空气处，保持呼吸畅通。
如果呼吸困难，给于吸氧。
如患者食入或吸入本物质，不得进行口对口人工呼吸。
如果呼吸停止。
立即进行心肺复苏术。
立即就医。
食入：禁止催吐，切勿给失去知觉者从嘴里喂食任何东西。
立即呼叫医生或中毒控制中心。
对保护施救者的忠告：清除所有火源，增强通风。
避免接触皮肤和眼睛。
避免吸入粉尘。
使用防护装备，包括呼吸面具。
对医生的特别提示：根据出现的症状进行针对性处理。
MSDS物质安全数据表
—recommended restrictions on use关于用途的推荐性限制
— sources of key data used to compile the Safety Data Sheet.该安全资料表的关键数据源
9.3Other information
其它信息
SECTION10. STABILITY AND REACTIVITY
第十部分稳定性和反应活性
10.1Conditions to avoid
应避免的情况
10.2Materials to avoid
应避免接触的物质
10.3Hazardous decomposition products
环境暴露控制
SECTION9. PHYSICAL AND CHEMICAL PROPERTIES
第九部分理化特性
9.1General information
常规信息
Appearance外观:
Odour气味:
9.2Important health, safety and environmental information
Skin皮肤接触
Eye contact眼睛接触
Ingestion食入
4.2Advice to doctor
医生注意
SECTION5. FIRE-FIGHTING MEASURES
第五部分消防措施
5.1 Suitablefire-fightingequipment
合适的消防设备
Suitable适合
Unsuitable不适合
钛白粉性质说明书
1、钛白粉的性质1.1、钛白粉成份钛白粉的化学名称：二氧化钛，分子式TiO2，分子量79.9，其质量组成中59.95%为Ti，O 占40.05%。
英文名：Titanic anhydride；Titanic oxide；Titanium dioxide；Titanium white；Titania；Titanium dioxide pigment。
别名：钛白，钛白粉通常人们把在涂料、油墨、塑料、橡胶、造纸、化纤、美术颜料和日用化妆品等行业中以白色颜料为主要使用目的的二氧化钛称为钛白粉、二氧化钛颜料或钛白，而把在搪瓷、电焊条、陶瓷、电子、冶金等工业部门以纯度为主要使用目的的二氧化钛称为二氧化钛或非颜料级钛白粉、非涂料用钛白粉。
1.2、钛白粉物理性质1.2.1、晶型结构比较二氧化钛是多晶型化合物，自然界中存在有三种晶型型态，分别为板钛型、锐钛型、金红石型两种。
板钛型不稳定，目前没有工业用途。
锐钛型、金红石型两种有广泛的工业用途，具体的对比见下表表1、金红石型和锐钛型二氧化钛结构和物理性质对比序号物性金红石锐钛型1 结晶系四方晶系四方晶系2 相对密度 4.2 3.93 折射率 2.71 2.524 莫氏硬度6~7 5.5~65 电容率114 316 熔点1858 700度以上转化为金红石型7 晶格常数a 4.58 3.788 晶格常数c 2.95 9.499 线膨胀系数（25）A轴C轴10 7.19×10-6/℃ 2.88×10-6/℃11 9.94×10-6/℃ 6.64×10-6/℃12 导热率（cal/cm/s/℃）与a轴平行与c轴平行13 0.0200×0.021614 0.0124×0.113615 比热（cal/mol/℃）（200~1000℃）13.2 12.9616 摩尔热容量（25℃）cal/℃13.1617 电导率（空气中Ω/cm）室温10-13~10-1418 1000℃0.12 500℃ 5.5×10-8晶胞图如下:1.2.2、相对密度二氧化钛的相对密度随其结晶形态、粒径大小、化学组分、特别是与表面处理量大小有关，在制造过程中，随煅烧温度的提高和煅烧时间的延长而增长。
金属钛(钛粉)理化性质及危险特性表MSDS
金属钛（钛粉）理化性质及危险特性表MSDS标识英文名：titanium分子式：Ti分子量：47.90危险货物编号：金属钛粉[含水≥25%]41504金属钛粒41505金属钛粉[干燥的]42007UN编号：1352RTECS号：--IMDG规则页码：CAS号：7440-32-6理化性质外观与性状：深灰色或黑色发亮的无定形粉末。
主要用途：用于合金制造等。
钛粉用作焰火材料。
熔点（℃）1720相对密度（水=1） 4.5沸点（℃）3530相对密度（空气=1）--饱和蒸汽压（Kpa）--临界温度（℃）--燃烧热（kJ/mol）--临界压力（Mpa）--引燃温度（℃）460溶解性：不溶于水，溶于氢氟酸、硝酸、浓硫酸。
毒性与健康危害及急救措施接触限值（mg/m3）中国MAC：未制定标准美国TLVTN：未制定标准前苏联MAC：未制定标准美国TLVWN：未制定标准侵入途径吸入毒性：LD50：--LC50：--健康危害吸入后对上呼吸道有刺激性，引起咳嗽、胸部紧束感或疼痛。
急救措施皮肤接触：脱去污染的衣着，用肥皂水和清水彻底冲洗皮肤。
眼睛接触：提起眼睑，用流动清水或生理盐水冲洗。
就医。
吸入：迅速脱离现场至空气新鲜处。
保持呼吸道通畅。
如呼吸困难，给输氧。
如呼吸停止，立即进行人工呼吸。
就医。
食入：饮足量温水，催吐。
就医。
燃烧爆炸危险性燃烧性本品易燃，具刺激性。
闪点无意义自燃温度（℃）1200（金属块）250（粉末）爆炸极限（v%）爆炸上限%（V/V）：--爆炸下限%（V/V）：40mg/m3危险特性金属钛粉尘具有爆炸性，遇热、明火或发生化学反应会燃烧爆炸。
其粉体化学活性很高,在空气中能自燃。
金属钛不仅能在空气中燃烧,也能在二氧化碳或氮气中燃烧。
高温时易与卤素、氧、硫、氮化合。
燃烧分解产物氧化钛。
稳定性稳定聚合危害不聚合禁忌物氧、卤素、铝、强酸、强氧化剂、二氧化碳。
灭火方法采用干粉、干砂灭火。
严禁用水、泡沫、二氧化碳扑救。
高热或剧烈燃烧时，用水扑救可能会引起爆炸。
钛白粉化学品安全技术说明书MSDS
标识
中文名：
二氧化钛；钛白粉
英文名：
Titanium dioxide；Titanium oxide
分子式：
TiO2分子量：79.90
CAS号：
13463—67—7RTECS号：XR2275000
理化性质
外观与性状：
白色无定形粉末。
主要用途：
是重要的白色颜料如瓷器釉药，也用于冶金工业制造金属钛及其合金；并用于橡胶，造纸和人造纤维等工业。
其他
工作后，淋浴更衣。保持良好的卫生习惯。
侵入途径：
吸入食入
毒性：
属低毒类
健康危害：
长期吸入二氧化钛粉尘的工人，未发现肺部病理变化。多数学者认为钛粉尘不会引起肺纤Biblioteka 化。本品对皮肤有刺激作用。急救
皮肤接触：
用肥皂水及清水彻底冲洗。就医。
眼睛接触：
拉开眼睑，用流动清水冲洗15分钟。就医。
吸入：
脱离现场至空气新鲜处。就医。
食入：
误服者，饮适量温水，催吐。就医。
防护措施
工程控制：
生产过程密闭，加强通风。
呼吸系统防护：
作业工人应该佩戴防尘口罩。
眼睛防护：
必要时戴安全防护眼镜。
防护服：
穿工作服。
手防护：
必要时戴防护手套。
泄漏处置
隔离泄漏污染区，周围设警告标志，建议应急处理人员戴好口罩和手套。用砂土、干燥石灰或苏打灰混合，收集于一个密闭的容器中，运至废物处理场所。用水刷洗泄漏污染区，经稀释的污水放入废水系统。如大量泄漏，收集回收或无害处理后废弃。
储运注意事项：
储存于阴凉、通风仓间内。包装密封。不可与酸类物品共储混运。操作现场不得吸烟、饮水、进食。搬运时轻装轻卸，保持包装完整，防止洒漏。分装和搬运作业要注意个人防护。
钛白粉 MSDS
Material Safety Data SheetTITANIUM DIOXIDE1. Product IdentificationSynonyms: Titanium (IV) Oxide; C.I. 77891; TitaniaCAS No.: 13463-67-7Molecular Weight: 79.87Chemical Formula: TiO22. Composition/Information on Ingredients Ingredient CAS No Percent Hazardous--------------------------------------- ------------ ------------ ---------Titanium Dioxide 13463-67-7 90 - 100% Yes3. Hazards IdentificationEmergency Overview--------------------------WARNING! MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. MAY AFFECT LUNGS. SUSPECT CANCER HAZARD. CONTAINS TITANIUM DIOXIDE, WHICH MAY CAUSE CANCER. Risk of cancer depends on level and duration of exposure.SAF-T-DATA(tm) Ratings (Provided here for your convenience)-----------------------------------------------------------------------------------------------------------Health Rating: 2 - Moderate (Cancer)Flammability Rating: 0 - NoneReactivity Rating: 1 - SlightContact Rating: 1 - SlightLab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPERGLOVESStorage Color Code: Green (General Storage)-----------------------------------------------------------------------------------------------------------Potential Health Effects----------------------------------Inhalation:May cause mild irritation to the respiratory tract.Ingestion:Not expected to be a health hazard via ingestion.Skin Contact:May cause mild irritation and redness.Eye Contact:May cause mild irritation, possible reddening.Chronic Exposure:Titanium Dioxide may cause cancer in humans. Long-term exposure to titanium dioxide dust may result in mild fibrosis (scarring of the lungs). Aggravation of Pre-existing Conditions:Persons with pre-existing lung disease may be more susceptible to the effects of this substance.4. First Aid MeasuresInhalation:Remove to fresh air. Get medical attention for any breathing difficulty. Ingestion:Not expected to require first aid measures. If large amounts were swallowed, give water to drink and get medical advice.Skin Contact:Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation develops.Eye Contact:Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention if irritation persists. 5. Fire Fighting MeasuresFire:Not considered to be a fire hazard.Explosion:Not considered to be an explosion hazard.Fire Extinguishing Media:Use any means suitable for extinguishing surrounding fire.Special Information:In the event of a fire, wear full protective clothing and NIOSH-approvedself-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.6. Accidental Release MeasuresVentilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. 7. Handling and StorageKeep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.8. Exposure Controls/Personal ProtectionAirborne Exposure Limits:Titanium Dioxide:- OSHA Permissible Exposure Limit (PEL) -15 mg/m3 (TWA).- ACGIH Threshold Limit Value (TLV) -10 mg/m3 (TWA), A4 - Not classifiable as a human carcinogen.Ventilation System:A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please referto the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.Personal Respirators (NIOSH Approved):If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use afull-facepiece positive-pressure, air-supplied respirator. WARNING:Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.Skin Protection:Wear protective gloves and clean body-covering clothing.Eye Protection:Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.9. Physical and Chemical PropertiesAppearance:White Powder.Odor:Odorless.Solubility:Insoluble in water.Specific Gravity:4.26pH:ca. 6 - 7% Volatiles by volume @ 21C (70F):Boiling Point:2500 - 3000C (4532 - 5432F)Melting Point:1855C (3371F)Vapor Density (Air=1):Not applicable.Vapor Pressure (mm Hg):Not applicable.Evaporation Rate (BuAc=1):No information found.10. Stability and ReactivityStability:Stable under ordinary conditions of use and storage.Hazardous Decomposition Products:No information found.Hazardous Polymerization:Will not occur.Incompatibilities:For Titanium Dioxide: A violent reaction with lithium occurs around 200C (392F) with a flash of light; the temperature can reach 900C. Violent or incandescent reaction may also occur with other metals such as aluminum, calcium, magnesium, potassium, sodium, and zinc.Conditions to Avoid:Dusting and incompatibles.11. Toxicological InformationToxicological Data:No LD50/LC50 information found relating to normal routes of occupational exposure. Investigated as a tumorigen and mutagen.Carcinogenicity:IARC classification: Group 2B - Possibly carcinogenic to humans.NIOSH considers this substance to be a potential occupational carcinogen.--------\Cancer Lists\---------------------------------------------------------NTP Carcinogen--- Ingredient Known Anticipated IARC Category------------------------------------ ----- ----------- -------------Titanium Dioxide (13463-67-7) No No2B12. Ecological InformationEnvironmental Fate:No information found.Environmental Toxicity:No information found.13. Disposal ConsiderationsWhatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.14. Transport InformationNot regulated.15. Regulatory Information--------\Chemical Inventory Status - Part 1\--------------------------------- Ingredient TSCA EC Japan Australia----------------------------------------------- ---- --- ----- ---------Titanium Dioxide (13463-67-7) Yes Yes Yes Yes--------\Chemical Inventory Status - Part 2\-----------------------------------Canada-- Ingredient Korea DSLNDSL Phil.----------------------------------------------- ----- --- ---- -----Titanium Dioxide (13463-67-7) Yes Yes NoNo--------\Federal, State & International Regulations - Part 1\-----------------SARA 302- ------SARA 313------Ingredient RQ TPQ List Chemical Catg.----------------------------------------- --- ----- ---- --------------Titanium Dioxide (13463-67-7) No No NoNo--------\Federal, State & International Regulations - Part 2\-----------------RCRA--TSCA-Ingredient CERCLA 261.338(d)----------------------------------------- ------ ------ ------Titanium Dioxide (13463-67-7) No No NoChemical Weapons Convention: No TSCA 12(b): No CDTA: No SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No Reactivity: No (Pure / Solid)Australian Hazchem Code: None allocated.Poison Schedule: None allocated.WHMIS:This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.16. Other InformationNFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0Label Hazard Warning:WARNING! MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. MAY AFFECT LUNGS. SUSPECT CANCER HAZARD. CONTAINS TITANIUM DIOXIDE, WHICH MAY CAUSE CANCER. Risk of cancer depends on level and duration of exposure.Label Precautions:Avoid contact with eyes, skin and clothing.Wash thoroughly after handling.Avoid breathing dust.Keep container closed.Use with adequate ventilation.Label First Aid:In case of contact, immediately flush eyes or skin with plenty of water for atleast 15 minutes. Get medical attention if irritation develops or persists. If inhaled, remove to fresh air. Get medical attention for any breathing difficulty. Product Use:Laboratory Reagent.Revision Information:No Changes.Disclaimer:ISSUED BY: SHIJIAZHUANG BAOYUJIA CHEMICALS CO., LTDANY AMENDMENT WILL BE ADDED IF NEEDED。
钛白粉成分表
titanium dioxide 钛白粉Rutile 金红石94%Product name: titanium dioxideMolecular formula: TiO2CAS No.: 13463-67-7Appearance: white powderUse: paint, ink etc.Parameters Analysis resultTiO 94.5% White degree ( contrast to the standard sample )99%Tint reducing power ( contrast to the standard sample )100% Volatile content ( 105°C after 23°C, 24h )0.45%Water soluble matter0.4%Oil absorption22g/100gpH vaule7.0 Resistivity in water extraction32Residue on sieve 45 μm0.8%98%Specifications:Item SpecificationTiO2Content /% ≥ 98.0Volatile at 105 /% ≤0.5Water Soluble Objects /% ≤0.6Tint Reducing Power ≥100PH Value of Aqueous Suspension 6.58.5Oil Absorption (g/100g) ≤24Scattering power ≥105Color with no less than than the standard sampleHiding power ≤ 30 Achromatic, and with thestandard≥ 100Specification 金红石98%Rutile Titanium Dioxide(Normal use): 金红石 Surface treament:Silicon,Aluminium and Organic Index Name:Grade oneTiO2%min:92.50%Rutile conversion rate min: 97% Color(compared with sample): Not lower Whiteness min: 96 Achromaticity(compared with sample), % min: 100Dispersion(hagerman number)min: 6.0 105 centidegree Volatile matter, % max: 0.5 Sileve Residue per 45um mesh, % max: 0.02 Water Solubles, % max:0.5 pH of Suspension Solution: 6.5-8.5 Oil Absorption g/100g max: 22ItemIndex Titanium Dioxide Content, %≥95.0 Rutile Content, % ≥98.0 Whiteness, %≥ Tinter reducing power, compared with standard samples≥98 105°C volatile matter, %≤0.5 Water solubles, %≤0.3 pH-value of aqueous suspension6.5-7.5 Oil absorption, g/ 100g ≤22 Residue on sieve 45μm, %≤0.05 Resistivity of aqueous extract, ¦¸.cm≥8000锐太Anatase Titanium Dioxide(Normal use):IndexName: GradeoneTiO2%min:98.00%Color(compared with sample): Not lowerAchromaticity(compared with sample), % min: 100105 centidegree Volatile matter, %max:0.5Water Solubles, %max:0.5pH of SuspensionSolution:6.5-8.0Oil Absorption g/100gmax:26Sileve Residue per 45um mesh, % max: 0.1Water extract resistivity Ω Mmin.:20锐太B101-BITEM : anatase titanium dioxide B101-BPackage : 25 kg/ woven bag2. SpecificationNo item Unit Results1 Content of Active TiO2 and Assistant % 982 White degree (contrast to the standard sample) % similar3 Tint reducing power(contrast to the standard sample) % 1004 Oil absorption g/100g 235 PH Value of aqueous suspension 6.5~8.06 Residue on sieve 45u(%)max % 0.077 Water soluble matter % 0.458 105 °CVolatile content % 0.5。
钛白粉MSDS
Clean up immediately with wetting of absorbent material avoiding dusting
7. Handling and storage
Handing:
Usual precautions for nuisance dust should be observed
Water risk class: WGK 0 (self-assessment,acc to7a19,19a1 ofGermanyWater Utilization Act(WHG)
16. Further information:
Vertical marking at left margin denote alterations of previous issue.
Check re-use as alternative
Contaminated packages and container:
Emptied, but contaminated packages and containers may be recycled
Waste Code No: 18715(Germany)
Chemical characterization:
TiO2Pigmentwhite
Dangerous component:
None
3. Hazards identificatБайду номын сангаасon
No hazard effects known
The product is not substance subject to mandatory marking in goordance with the EEC Directive 67/584/EEC or amendments
钛白粉安全技术说明书
钛白粉MSDS第一部分化学品及企业标识化学品中文名称：二氧化钛?化学品英文名称：titanium(IV)o xide中文名称2：钛白粉英文名称2：titanium dioxide第二部分：成分/组成信息二氧化钛含量≥90％CAS No. 13463-67-7第三部分：危险性概述健康危害：长期吸入氧化钛粉尘的工人，肺部无任何变化，亦未发生接触性皮炎、过敏反应。
燃爆危险：本品不燃。
第四部分：急救措施皮肤接触：脱去污染的衣着，用流动清水冲洗。
眼睛接触：提起眼睑，用流动清水或生理盐水冲洗。
就医。
吸入：脱离现场至空气新鲜处。
食入：饮足量温水，催吐。
就医。
第五部分：消防措施危险特性：未有特殊的燃烧爆炸特性。
有害燃烧产物：自然分解产物未知。
灭火方法：尽可能将容器从火场移至空旷处。
第六部分：应急处理泄漏应急处理:隔离泄漏污染区，限制出入。
建议应急处理人员戴防尘面具（全面罩），穿一般作业工作服。
避免扬尘，小心扫起，置于袋中转移至安全场所。
若大量泄漏，用塑料布、帆布覆盖。
收集回收或运至废物处理场所处置。
第七部分：操作处置与储存操作注意事项：密闭操作，局部排风。
操作人员必须经过专门培训，严格遵守操作规程。
建议操作人员佩戴自吸过滤式防尘口罩，戴化学安全防护眼镜，戴一般作业防护手套。
避免产生粉尘。
避免与酸类接触。
搬运时轻装轻卸，防止包装破损。
配备泄漏应急处理设备。
倒空的容器可能残留有害物。
储存注意事项：储存于阴凉、通风的库房。
远离火种、热源。
应与酸类分开存放，切忌混储。
储区应备有合适的材料收容泄漏物。
第八部分：接触控制/个体防护职业接触限值中国MAC(mg/m3)：10前苏联MAC(mg/m3)：10TLVTN：ACGIH 10mg/m3TLVWN：未制定标准工程控制：密闭操作，局部排风。
呼吸系统防护：空气中粉尘浓度较高时，建议佩戴自吸过滤式防尘口罩。
眼睛防护：戴化学安全防护眼镜。
身体防护：穿一般作业防护服。
手防护：戴一般作业防护手套。
纤维用钛白粉母粒安全技术说明书(MSDS)
注意勿使纸袋或容器破裂，以防止溢出。
储存注意事项：
储存于阴凉、通风的库房、远离火种、热源。
第八部分：接触控制/个体防护
监测方法：
气相色谱法
工程控制：
不适用。
呼吸系统防护：
不适用。
眼睛防护：
戴侧护罩的安全眼镜
身体防护：
穿一般作业防护服。
手防护：
手套。
皮肤防护：
通常没有个人身体保护需要。
第九部分：理化特性
包装类别：
包装方法：
无资料。
运输注意事项：
起运时包装要完整，装载应稳妥。运输过程中要确保容器不泄漏、不倒塌、不坠落、不损坏。严禁与酸类等混装混运。运输途中应防曝晒、雨淋，防高温。
第十五部分：法规信息
法规信息
化学危险物品安全管理条例(1987年2月17日国务院发布)，化学危险物品安全管理条例实施细则(化劳发[1992] 677号)，工作场所安全使用化学品规定([1996]劳部发423号)等法规，针对化学危险品的安全使用、生产、储存、运输、装卸等方面均作了相应规定；车间空气中二氧化钛粉尘卫生标准(GB 11522-89)，规定了车间空气中该物质的最高容许浓度及检测方法。
第八部分
接触控制/个体防护
第十六部分
其他信息
第一部分：化学品名称
化学品中文名称：
二氧化钛母粒
化学品俗名：
钛白粉母粒
化学品英文名称：
titanium（IV）oxidemasterbatc
英文名称：
Titanium dioxidemasterbatc
技术说明书编码：
CAS No.：
生产企业名称：
地址：
生效日期：
第六部分：泄漏应急处理
道恩牌2295钛白粉MSDS报告表v参考模板
物质安全资料表(MSDS)
道恩牌二氧化钛颜料
一、产品与厂商资料
二、成份辨识数据
三、危害辨识数据
四、急救措施
五、灭火措施
六、泄漏处理方法
七、安全处置与储存方法
八、暴露预防措施
九、物理及化学性质
十、安定性及反应性
十一、毒性资料
十二、生态资料
十三、废弃处置方法
十四、运送资料
十五、法规资料
十六、其它数据
本物质安全资料表中的数据仅与本资料指定的牌号有关；和与任何其它材料或任何工艺过程中的组合应用无关。
友情提示：范文可能无法思考和涵盖全面，供参考!最好找专业人士起草或审核后使用，感谢您的下载！。
金属钛粉(钛粉)的理化性质及危险特性表
相对蒸汽密度（空气=1）：
无资料
闪点（℃）：
无意义
饱和蒸汽压（k Pa）：
无资料
引燃温度(℃)：
460
爆炸上限/下限[％(V/V)]：
无资料
临界温度(℃)：
无资料
临界压力(MPa)：
无资料
溶解性：
不溶于水，溶于氢氟酸、硝酸、浓硫酸。
毒性
属低毒类
健康危害
吸入后对上呼吸道有刺激性，引起咳嗽、胸部紧束感或疼痛。
泄漏处置
隔离泄漏污染区，限制出入。切断火源。建议应急处理人员戴防尘面具（全面罩），穿防毒服。不要直接接触泄漏物。小量泄漏：避免扬尘，用洁净的铲子收集于干燥、洁净、有盖的容器中。转移回收。大量泄漏：用塑料布、帆布覆盖。使用无火花工具转移回收。
储运注意事项
①操作注意事项：密闭操作，局部排风。操作人员必须经过专门培训，严格遵守操作规程。建议操作人员佩戴自吸过滤式防尘口罩，戴安全防护眼镜，穿透气型防毒服，戴防毒物渗透手套。远离火种、热源，工作场所严禁吸烟。使用防爆型的通风系统和设备。避免产生粉尘。避免与氧化剂、酸类、卤素接触。在氩气中操作处置。搬运时要轻装轻卸，防止包装及容器损坏。配备相应品种和数量的消防器材及泄漏应急处理设备。倒空的容器可能残留有害物。
金属钛粉尘具有爆炸性，遇热、明火或发生化学反应会燃烧爆炸。其粉体化学活性很高,在空气中能自燃。金属钛不仅能在空气中燃烧,也能在二氧化碳或氮气中燃烧。高温时易与卤素、氧、硫、氮化合。
建规火险分级：
乙
有害燃烧产物：
氧化钛。
灭火方法：
采用干粉、干砂灭火。严禁用水、泡沫、二氧化碳扑救。高热或剧烈燃烧时，用水扑救可能会引起爆炸。
金属钛（钛粉）的理性质及危险特性表
钛白粉各项指标分析
钛白粉的指标1、含量锐钛型≧ 98%金红石型≧ 92%2、白度白度标注大都采用和标样进行比较或采用L、a、 b 表示。
几乎所有的应用行业都要求良好的白度。
钛白粉的杂质和粒子对白度有显著的影响。
CIE（ commission internationals de eclairage）是国际照明协会的简称CIE 制定了L* ， a* 和 b* 值来测量色值，这种测量方法称为CIELAB。
L* 代表着明度，从明亮( 此时L*=100) 到黑暗 ( 此时 L*=0) 之间变化。
A*值表示颜色从绿色(-a*)到红色(+a*)之间变化，而b* 值表示颜色从黄色 (+b*) 到蓝色 (-b*) 之间变化。
影响白度的主要因素：良好的粒径分布是产品白度色相稳定的基本条件。
它包括两个方面:1) 适中的力度大小，一般情况下颜料粒径的直径为可见光的波长的一半时，可以达到最好的白度，即 0.15-0.35um 2 ）集中的力度X围，颜料颗粒直径的分布X围要小。
表示在图像上就是要窄。
3、消色力钛白粉与其他颜料混合后显示他本身颜色的能力，一般是同标样比较或用雷诺数来表示：和标样比较的是相对消色力。
雷诺数是利用色差计（CR-300 色差仪）测得各个光学数据后计算而得。
雷诺数没有国标，一般金红石≧1700,1900 左右的产品才是好产品。
（越大越好）※消色力是侧面反映遮盖力的高低；※消色力的高低，会影响到肉眼对色相的判断；※对消色力的判断，相对消色力受底相影响较大；※中高 PVC涂料配方中，填料 ( 体质颜料 ) 用量较大，细粒径填料使二氧化钛分布更均匀；大粒径填料使二氧化钛聚集，降低了二氧化钛的遮盖力。
4、吸油量100g 钛白粉达到完全润湿时需要用油的最低量。
溶剂涂料和粉末涂料、橡胶、油墨等要求吸油量低，高 PVC的涂料比较喜欢高吸油量的产品；※吸油量的高低会影响到在同样的使用量下，使用体系的黏度；※吸油量会影响到在油性介质里的分散性。