Material Data Sheet TN26

合集下载

MATERIAL SAFETY DATA SHEET

Page MATERIAL SAFETY DATA SHEET1. Product IdentificationTrade Name: BioCon ；保康Product Name: Bacillus thuringiensis Wettable Powder ；蘇雲金桿菌可濕性粉劑2. Hazardous Components and CompositionBacillus thuringiensisFine solid powder3. Typical Physical and Chemical PropertiesAppearance: Light yellow powder Odor: Not significant pH: 5.5 Solubility in water : dispersiblein water4. Health Effects and Toxicity DataOral toxicity:Practically Non-ToxicDermal toxicity:Non-ToxicInhalation toxicity:Non-ToxicSkin irritation:cause mild skin irritationEye irritation:cause mild eye irritationPage 5. First Aid ProcedureEye contact:A flush eye with large amount of water until irritation subsides. If irritation persists, get medical attention.Skin contact:Flush with large amount of water; use soap or detergent if available.Remove grossly contaminated clothing, including shoes, and launder before reuse.Inhalation:Wearing proper respiratory protection before rescues. Immediately remove the affected victim from exposure to an area of fresh air. Administer artificial respiration if breathing is stopped. Keep at rest. Call for prompt medical attention.Ingestion:If swallowed, DO NOT induces vomiting. Keep at rest. Get prompt medical attention6. Fire and Explosion HazardFire and explosion hazard:Low hazard,Firefighting media:Foam, dry chemical or water spray to extinguish fireFirefighting precaution:Prevent contaminated liquid from entering sewers watercourses, or low area.7. Stability ReactivityChemical Stability:StableConditions to Avoid:Nothing unusualPage Incompatibilities:Avoid mixing with nitric acid, sulfuric acid ands strong oxidizing agent. Decomposition:N/APolymerization:This product should not occurred any hazardous polymerization8. Spill and Leak Control ProcedurePrevent additional discharge of material, if possible to do so without hazard. For spills in public area, keep public away and advise local authorities. Control procedure:• Contain spilled liquid with sand or earth• Recover by pumping or with a suitable absorbent.• Consult an expert on disposal of recovered material and ensureconformity to local disposal regulations.9. Protective EquipmentFor open system where contact is likely, wear safety glasses, long sleeves, and gloves.10. Storage and TransportationStorage:• Ambient temperature• Atmospheric pressureTransportation:N/A。

Material Safety Data Sheet(Thioctic acid)

Material Safety Data Sheet1PRODUCT AND COMPANY IDENTIFICATIONProduct name: (±)-α-Lipoic AcidCompany:Telephone:Fax:2COMPOSITION / INFORMATION ON INGREDIENTSSynonyms: (±)-1, 2-Dithiolane-3-pentanoic acidDL-6, 8-Thioctic acidLip (S2)6, 8-Dithiooctanoic acid5-(Dithiolan-3-yl) valeric acidFormula: C8H14O2S2Molecular Weight: 206.30g/mol3HAZARDS IDENTIFACATIONEmergency OverviewOSHA HazardHarmful by ingestionHIMS ClassificationHealth Hazard: 1Flammability:0Physical hazards: 0NFPA RatingHealth Hazard: 1Fire: 0Reactivity Hazard:0Potential Health EffectsInhalation May be harmful if inhaled. May cause respiratory tract irritationSkin May be harmful if absorbed through skin. May cause skin irritation.Eyes May cause eye irritation.Ingestion Harmful if swallowed.4FIRST AID MEASURESGeneral adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaledIf breathed in, move person into fresh air. If not breathing give artificial respiration Consult aphysician.In case of skin contactWash off with soap and plenty of water. Consult a physician.In case of eye contactRinse thoroughly with plenty of water for at least 15 minutes and consult a physician.If swallowedNever give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.5FIRE-FIGHTING MEASURESFlammable propertiesFlash point no data availableIgnition temperature no data availableSuitable extinguishing mediaUse water spray, alcohol-resistant foam, dry chemical or carbon dioxide.Special protective equipment for fire-fightersWear self contained breathing apparatus for fire fighting if necessary.6ACCIDENTIAL RELEASE MEASURESPersonal precautionsUse personal protective equipment. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation.Environmental precautionsDo not let product enter drains.Methods for cleaning upPick up and arrange disposal without creating dust. Keep in suitable, closed containers for disposal.7HANDLING AND STORAGEHandlingAvoid formation of dust and aerosolsProvide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire protection.StorageKeep container tightly closed in a dry and well-ventilated place.Recommended storage temperature:2-8℃Keep in a dry place.8EXPOSURE CONREOLS/PERSONAL PROTECTIONContains no substances with occupational exposure limit values.Personal protective equipmentRespiratory protectionWhere risk assessment shows air-purifying respirators are appropriate use a dust mask type N95 (US) or type P1 (EN 143) respirator. Use respirators and components tested andapproved under appropriate government standards such as NIOSH (US) or CEN (EU).Hand protectionHandle with gloves. For prolonged or repeated contact use protective gloves.Eye protectionSafety glasses with side-shields conforming to EN166.Skin and body protectionChoose body protection according to the amount and concentration of the dangerous substance at the work place.Hygiene measuresHandle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.9 PHYSICAL AND CHEMCAL PROPERTIESAppearanceForm powderColour light yellowSafety datapH no data availableMelting point 60℃(140℉)Boiling point 160-165℃(320-329℉)Flash point no data availableIgnition temperature no data availableLower explosion limit no data availableUpper explosion limit no data availableWater solubility no data availableSolubility 50g/l at 20℃(68℉)Ethanol10STABILITY AND REACTIVITYStorage stabilityStable under recommended storage conditions.Material to avoidStrong oxidizing agentsHazardous decomposition productsHazardous decomposition products formed under fire conditions.-Carbon oxides, Sulphur oxides.11TOXICOLOGICAL INFORMATIONAcute toxicityLD50 Intraperitoneal-mouse-235mg/kgIrritation and corrosionno data availableSensitisationno data availableChronic exposureIARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.Potential Health EffectsInhalation May be harmful if inhaled. May cause respiratory tract irritation.Skin May be harmful if absorbed through skin. May cause skin irritation.Eyes May cause eye irritation.Ingestion Harmful if swallowed.Additional InformationRTECS: JP119200012ECOLOGICAL INFORMATIONElimination information (persistence and degradability)No data availableEcotoxicity effectsNo data availableFurther information on ecologyNo data available13DISPOSAL CONSIDERATIONSProductObserve all federal, state, and local environmental regulations.Contaminated packagingDispose of as unused product.14TRANSPORT INFORMATIONDOT(US)Not dangerous goodsIMDGNot dangerous goodsIATANot dangerous goods15REGULATORY INFORMATIONA-Lipoic Acid is recorded in EP as a nutritional supplement.16OTHER INFORAMATIONFurther informationThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product.。

HACH分光光度法分析体系

41
可以从那些渠道获知试剂的测试量程？
实验室与便携仪器卷
42
PFA
43
PFA Lange
44
45 46
4、干扰
一般情况下，用户的水体中除了待测参数，总会有其它化合物、离子等。其中有些会干扰待测样品的测量。因此，在帮助用户选择合适试剂的时候，一定要问清楚他们的水体中有些什么成分，然后作出进一步的分析、选型。例如测试COD，氯离子是主要的干扰，一定要问清楚用户的水体中是否含有氯离子，浓度是多少。如果氯离子浓度超过了我们COD预制试剂能掩蔽的范围，那么就要考虑一下稀释样品到掩蔽范围内，但同时也要考虑样品的COD 也被稀释了，这时就要根据稀释后的COD量程来选择预制试剂
2
一次典型的HACH光度法分析流程
准备相应量程的COD预制试剂滴加待测样品到预制试剂中，经过一系列简单操作（如加入粉枕包、显色、消解等）
分光光度法检测
3
一、哈希的光度计产品
4
二、哈希分析方法
• 哈希的分光光度分析方法，大多数都是根据USEPA和Standard Methods for Water and Wastewater，经过长期的市场检验。
• 标准溶液：如常见的COD、总磷、氨氮等参数的标准溶液等
• 电化学产品用：如pH缓冲溶液，电导率标准溶液、电极电解液等
24
Hale Waihona Puke 枕包分析用试剂安培瓶
TNT试剂管
25
TNT plus试剂管
试验预制试剂的好处
• 最大限度地减少废液处理问题 • 节约时间,便捷性 • 稳定性好，存放时间较长 • 试剂生产符合美国国家环保局(USEPA)和美国国家实验
MDL，LOQ？

GMP认证仓库人员应掌握的主要问题,药品仓库管理原则

仓库人员应掌握的主要问题一、保管员发货的原则？答：先进先出二、摆放的原则是什么？（1）仓库区应防潮，待检、合格、不合格物料及产品应分库存放或严格分开码跺储存，并有易于识别的明显标记。

（2）对温、湿度有特殊要求的物料或产品应置于阴凉库储存。

（3）易燃易爆的危险品、废品应分别在特殊的或隔离的仓库内保存。

（4）仓库区应有符合规定的消防间距和交通通道三、中药保管员怎样进行收货？答：检查包装是否完整，外标签是否正确无误，药材是否霉变虫蛀，品名、规格、数量是否与合同一致。

如符合要求同意收货，放在饮片待验区，填写请验单请化验室检验，经检验合格，收到合格报告书后办理正式入库手续，并放在饮片合格区。

四、标签、说明书怎样管理？（1）标签、说明书应均按品种、规格有专柜或专库存放，由专人验收、保管、发放、领用，并凭批包装指令发放，按实际需要量领取。

（2）标签要计数发放，领用人核对、签名，使用数、残损数及剩余数之和应与领用数相符，印有批号的残损或剩余标签及包装材料应由专人负责计数销毁。

（3）标签发放、使用、销毁应有记录。

五、仓管员怎样发料？答：（1）领料员持生产指令或包装指令、领料单到仓库，仓库管理员根据生产指令或包装指令核对领料单，将物料准备好，由车间领料。

（2）物料的发放应严格遵守先进先出的原则，前一批发放完，再发新的一批。

（3）称量、核对物料，确认无误后，仓库管理员、领料员在领料单上签字，仓库管理员登记货位卡、物料的发放记录。

六、仓库管理中最重要的内容：仓库是否干燥，温度是否合适，账物卡是否一致，分区是否明确以防混淆。

七、你管理那么多库房，对不同的物料怎样贮存清楚否？仓库“五防”：防火、防潮、防盗、防鼠、防虫答：（1）入库物料分区、分类、分库存放，物料总账、分类账、库位卡齐全。

（2）同一物料不同供应商分开存放，不同生产批号分开存放。

（3）剧毒化学品等特殊物料应分别专库（柜）存放。

（4）易燃易爆品、强腐蚀性物料存放在专门的特殊品库。

产品Material Safety Data Sheet (MSDS)表格模版

Resistor First
RuO2
Pd Glass (Bi,Pb,Si,etc.) Glass
encapsulating Cr2O3
Overcoat Resin
7440-22-4 9003-36-5 7440-02-0 7440-31-5 NA NA
1344-28-1
7631-86-9
1309-48-4 7440-22-4 7440-22-4 7440-22-4
0.25
40.96 0.11% 40.96 Yes Yes
14.51 15.44 7.67 4.13
0.34
80
0.43% 160 Yes Yes
17.52 38.28
MLCC (1812); 2pcs
TDK
POSCAP SANYO
EDlieecletrcotdrice (Terminal) Electrode (Terminal) Electrode (Internal terminal) Dielectric Dielectric Tantalum Conductive Polymer
100%
100% 90% 10% 90% 10% 52.80% 38.20% 0.50% 5.55% 2.77% 0.14% 0.04% 75% 12%
7%
3% 3% 100% 100% 4.00% 8.00% 68.00% 20.00% 99.53% 0.17%
19.73 5.1
0.42
144 0.78% 288 Yes Yes
Carbon Silver Silver
42 Alloy
Epoxy resin
UV ink Silicon Die
die metallization

MATERIALSAFETYDATASHEET原材料安全性数据表-CPOOutlets

COMPONENTS DENSITY
成份
密度
Lead 铅
11.34
Lead Sulfate 硫酸铅 Lead Dioxide 氧化铅 Sulfuric Acid 硫酸 Fiberglass Sep. 玻璃纤维隔板 ABS or PP
6.2 9.4 About 1.3 N/A N/A
MELTING POINT 化点
COMPONENTS 成分
Lead 铅(Pb, PbO2, PbSO4) Sulfuric Acid 硫酸 Fiberglass Separator 纤维玻璃隔板 ABS or PP ABS 或 PP
%WEIGHT 所占比重 About 大约
70% About 20% About 5%
About 5%
SECTION 6: CONTROL MEASURES 第 6 部分：控制方法 1. Store lead/acid batteries with adequate ventilation. Room ventilation is required for batteries utilized for standby
WASTE DISPOSAL METHOD:废物外理方法 Neutralized acid may be flushed down the sewer. Spent batteries must be treated as hazardous waste and disposed of according to local state, and federal regulations. A copy of this material safety data must be supplied to any scrap dealer or secondary smelter with battery.中和的酸可能会被冲至下水道。失效的电池必须作为有毒废品，根据当地的要求进行处理。提供一份原材料安全性数据给废物处理经销商或电池二级炼外 ELECTRICAL SAFETY 电安全性 Due to the battery’s low internal resistance and high power density. High levels of short circuit can be developed across the battery terminals. Do not rest tools or cables on the battery. Use insulated tools only. 由于电池的底内阻、高能量密度。高水平的短路能发展到电池端子上。不要将工具和线放在电池上。只使用绝缘工具。 Follow all installation instruction and diagrams when installing or maintaining battery systems. 安装或维护电池系统时，参考安装说明书和图

M-120 Material data sheets for structural steel (Rev. 4, June 2004)

NORSOK STANDARD M-120Rev. 4, June 2004 Material data sheets for structural steelThis NORSOK standard is developed with broad petroleum industry participation by interested parties in the Norwegian petroleum industry and is owned by the Norwegian petroleum industry represented by The NorwegianOil Industry Association (OLF) and Federation of Norwegian Manufacturing Industries (TBL). Please note that whilst every effort has been made to ensure the accuracy of this NORSOK standard, neither OLF nor TBL or any of their members will assume liability for any use thereof. Standards Norway is responsible for the administration and publication of this NORSOK standard.Standards Norway Telephone: + 47 67 83 86 00Strandveien 18, P.O. Box 242 Fax: + 47 67 83 86 01Foreword 2 Introduction 2 1Scope 3 2Normative references 3 3Definitions and abbreviations 33.1Definitions 33.2Abbreviations 3 4Collection of material data sheets 34.1General 34.2Selection criteria 4ForewordThe NORSOK standards are developed by the Norwegian petroleum industry to ensure adequate safety, value adding and cost effectiveness for petroleum industry developments and operations. Furthermore, NORSOK standards are as far as possible intended to replace oil company specifications and serve as references in the authorities’ regulations.The NORSOK standards are normally based on recognised international standards, adding the provisions deemed necessary to fill the broad needs of the Norwegian petroleum industry. Where relevant, NORSOK standards will be used to provide the Norwegian industry input to the international standardisation process. Subject to development and publication of international standards, the relevant NORSOK standard will be withdrawn.The NORSOK standards are developed according to the consensus principle generally applicable standards work and according to established procedures defined in NORSOK A-001.The NORSOK standards are prepared and published with support by The Norwegian Oil Industry Association (OLF) and Federation of Norwegian Manufacturing Industries (TBL).NORSOK standards are administered and published by Standards Norway.IntroductionThe reference document for grade specifications is the August 2001 edition of EN 10225The main changes in Rev. 4 are as follows: (not marked)For MDS’s:−MDS-Y01 is split into Y01, Y02 and Y03 for SMYS 235 MPa, 275 MPa and 355 MPa respectively−Thickness limitation is extended for MDS-Y05,Y06, Y07, Y15−S355J2G3 with additional requirement to impact energy (same as for S355K2G3) and P and S is included in MDS-Y05−Reference to the final EN 10225−Requirement for CTOD for thicknesses above 40 mm−Requirement to stain age tests deleted for sections and tubulars with SMYS below 500 MPa−Min. Ni content of 0,50 for MDS-Y50 and Y55−MDS-Y70 is deletedNote: It should be observed that the requirement to fabrication tolerances in M-101 may be more strict than the manufacturing tolerances for steel products according to this standard.1 ScopeThis standard includes a collection of Material Data Sheets (MDS) applicable to selected material standards and grades for use in steel structures.references2 NormativeThe following standards include provisions and guidelines which, through reference in this text, constitute provisions and guidelines of this NORSOK standard. Latest issue of the references shall be used unless otherwise agreed. Other recognized standards may be used provided it can be shown that they meet or exceed the requirements and guidelines of the standards referenced below.Normative references are given in the individual data sheets.The reference document for grade specifications is the August 2001-edition of EN 10225.3 Definitions and abbreviations3.1 Definitions3.1.1shallverbal form used to indicate requirements strictly to be followed in order to conform to the standard and from which no deviation is permitted, unless accepted by all involved parties3.1.2shouldverbal form used to indicate that among several possibilities one is recommended as particularly suitable, without mentioning or excluding others, or that a certain course of action is preferred but not necessarily required3.1.3mayverbal form used to indicate a course of action permissible within the limits of the standard3.1.4canverbal form used for statements of possibility and capability, whether material, physical or casual.3.2 AbbreviationsCTOD Crack Tip Opening DisplacementDFT Dry Film ThicknessMDS Material Data SheetPWHT Post Weld Heat Treatment4 Collection of material data sheets4.1 GeneralThe materials shall be delivered in accordance with the standard referred to in the MDS. In addition the MDS specifies the selected options in the referred standard and modified requirements which shall supersede the corresponding requirements in the referred standard. Ref. also Note in the introduction.The material selection menu for the actual strength levels and grades is shown in table 1.All listed MDS’ are enclosed.4.2 SelectioncriteriaThe number of steel grades used in a project should be limited to the practical minimum. An evaluation should be carried out to determine the optimum grades.Table 1 - Material Data Sheets for Structural SteelMDS No.Rev.No.Standard Steel Grade Product Type SteelQualityLevelFormerdesignationY01 4 EN 10025EN 10210EN 10219S235JRG2S235JRHS235JRHPlates and SectionsHot finished tubularsCold formed tubularsIVY02 3 EN 10025EN 10210EN 10219S275JRS275J0HS275J0HPlates and SectionsHot finished tubularsCold formed tubularsIVY04 1 EN 10025EN 10210EN 10219S355J0S355J0HS355J2HPlates and SectionsHot finished tubularsCold formed tubularsIV EN 10025 S355J2G3 Plates and sections IIIY05 2EN 10113 S355N/M Plates and sections III Y06 2 EN 10225 S355G1+N Hot finished tubulars IIIY07 2 EN 10210 S355/NH Hot finished tubulars IIIY08 2 EN 10219 S355MLH Cold formed tubulars IIIY15 2 EN 10113 S420NL/ML Plates and sections IIIY16 2 EN 10219 S420MLH Cold formed tubulars IIIY20 4 EN 10225 S355G10+N/G10+M Plates I S355N4z/M4z Y21 4 EN 10225 S355G12+N/G12+M Rolled Sections I S355N3z/M3z Y22 4 EN 10225 S355G15+Q/G15+N Seamless Tubulars I S355Q3z/N3z Y25 4 EN 10225 S355G9+N/G9+M Plates II S355N4/M4 Y26 3 EN 10225 S355G11+N/G11+M Rolled Sections II S355N3/M3 Y27 4 EN 10225 S355G14+Q/G14+N Seamless Tubulars II S355Q3/N3 Y28 2 EN 10225 S355G13+N Welded Tubulars IIY30 4 EN 10225 S420G2+Q/G2+M Plates I S420Q3z/M3z Y31 4 EN 10225 S420G4+M Rolled Sections I S420M3zY32 4 EN 10225 S420G6+Q(mod) Seamless Tubulars I S420Q3 (z mod) Y35 4 EN 10225 S420G1+Q/G1+M Plates II S420Q3/M3 Y36 4 EN 10225 S420G3+M Rolled Sections II S420M3Y37 4 EN 10225 S420G6+Q Seamless Tubulars II S420Q3Y40 4 EN 10225 S460G2+Q/G2+M Plates I S460Q3z/M3z Y41 4 EN 10225 S460G4+M Rolled Sections I S460M3zY42 4 EN 10225 S460G6+Q (mod) Seamless Tubulars I S460Q3 (z mod) Y45 4 EN 10225 S460G1+Q/G1+M Plates II S460Q3/M3 Y46 4 EN 10225 S460G3+M Rolled Sections II S460M3Y47 4 EN 10225 S460G6+Q Seamless Tubulars II S460Q3Y50 4 EN 10225 S500G2+Q/G2+M 1) Plates I S500Q3z/M3z 1) Y51 4 EN 10225 S500G4+M 1) RolledSections IS500M3z1) Y52 4 EN 10225 S500G6+Q (mod) 1)Seamless Tubulars I S500Q3 (z mod) 1) Y55 4 EN 10225 S500G1+Q/G1+M 1) Plates II S500Q3/M3 1) Y56 4 EN 10225 S500G3+M 1) RolledSections IIS500M31)Y57 4 EN 10225 S500G6+Q 1) SeamlessTubulars IIS500Q31)Note 1): This steel grade designation is not included in EN 10225.All references in the MDS are to the relevant material standard unless otherwise specified.NORSOK StandardY01 Rev.4-SHEET MDSMATERIALDATATYPE OF MATERIAL: Structural Steel,PRODUCT STANDARDGRADEPlates and sections EN 10025 S235JRG2Hot finished tubulars EN 10210 S235JRHCold formed tubulars EN 10219 S235JRHSCOPE This MDS specifies the selected options in the referred standard and modifiedrequirements which shall supersede the corresponding requirements in the referredstandard. These grades shall not be used for thicknesses above 25 mm.STEEL GRADE The grades listed represent the minimum requirements for Y01. Other “higher” gradesfrom the referred standards are acceptable as substitutes.QUALIFICATIONFor steel grade S235JRG2 the steel shall comply with type “FN”, ref. option 3.HEAT TREATMENT/DELIVERY CONDITIONCHEMICALCOMPOSITIONTENSILE TESTINGIMPACT TESTINGEXTENT OF TESTINGSURFACE CONDITION The surface of the material shall comply to Rustgrade A or B or better according to ISO8501-1.NON DESTRUCTIVETESTING (NDT)SURFACE PROTECTIONMARKINGCERTIFICATE EN 10 204 Type 2.2NORSOK StandardMATERIAL DATA SHEET MDS - Y02 Rev. 3 TYPE OF MATERIAL: Structural Steel,PRODUCT STANDARDGRADEPlates and sections EN 10025 S275JRHot finished tubulars EN 10210 S275J0HCold formed tubulars EN 10219 S275J0HSCOPE This MDS specifies the selected options in the referred standard and modifiedrequirements which shall supersede the corresponding requirements in the referredstandard. These grades shall not be used for thicknesses above 25 mm.STEEL GRADE The grades listed represent the minimum requirements for Y02. Other “higher” gradesfrom the referred standards are acceptable as substitutes.QUALIFICATIONHEAT TREATMENT/DELIVERY CONDITIONCHEMICALCOMPOSITIONTENSILE TESTINGIMPACT TESTINGEXTENT OF TESTINGSURFACE CONDITION The surface of the material shall comply to Rustgrade A or B or better according to ISO8501-1.NON DESTRUCTIVETESTING (NDT)SURFACE PROTECTIONMARKINGCERTIFICATE EN 10 204 Type 2.2NORSOK StandardY04 Rev.1-SHEET MDSMATERIALDATATYPE OF MATERIAL: Structural Steel,PRODUCT STANDARDGRADEPlates and sections EN 10025 S355J0Hot finished tubulars EN 10210 S355J0HCold formed tubulars EN 10219 S355J2HSCOPE This MDS specifies the selected options in the referred standard and modifiedrequirements which shall supersede the corresponding requirements in the referredstandard. These grades shall not be used for thicknesses above 25 mm.STEEL GRADE The grades listed represent the minimum requirements for Y04. Other “higher” gradesfrom the referred standards are acceptable as substitutes.QUALIFICATIONHEAT TREATMENT/DELIVERY CONDITIONCHEMICALCOMPOSITIONTENSILE TESTINGIMPACT TESTINGEXTENT OF TESTINGSURFACE CONDITION The surface of the material shall comply to Rustgrade A or B or better according to ISO8501-1.NON DESTRUCTIVETESTING (NDT)SURFACE PROTECTIONMARKINGCERTIFICATE EN 10 204 Type 2.2. For EN 10219 S355J2H Type 3.1B.TYPE OF MATERIAL: Structural Steel,GRADEPRODUCT STANDARDEN 10025 S355J2G3PlatesS355K2G3EN 10113 S355N/MEN 10025 S355J2G3/G4SectionsS355K2G3/G4EN 10113 S355N/MSCOPE This MDS specifies the selected options in the referred standard and modifiedrequirements which shall supersede the corresponding requirements in the referredstandard. The thickness is limited to 50 mm.QUALIFICATIONSHEAT TREATMENT/DELIVERY CONDITIONCHEMICAL COMPOSITION EN 10025: Option 5, CEV Max 0,43 %, P max 0,025 %, S max 0,025 % TENSILE TESTINGIMPACT TESTING For S355J2G3/G4, flat and long products, min. energy requirement is 40 J EXTENT OF TESTINGSURFACE CONDITION The surface of the material shall comply to Rustgrade A or B or better according toISO 8501-1.NON DESTRUCTIVETESTING (NDT)SURFACE PROTECTIONMARKINGCERTIFICATE EN 10 204 Type 3.1B.TYPE OF MATERIAL: Structural Steel,GRADEPRODUCT STANDARDEN 10 225 S355G1+NHot finished tubularsseamless or weldedSCOPE This MDS specifies the selected options in the referred standard and modifiedrequirements which shall supersede the corresponding requirements in the referredstandard. The thickness is limited to 40 mm.QUALIFICATIONSHEAT TREATMENT/DELIVERY CONDITIONCHEMICALCOMPOSITIONTENSILE TESTINGIMPACT TESTINGEXTENT OF TESTINGSURFACE CONDITION The surface of the material shall comply to Rustgrade A or B or better according to ISO8501-1.NON DESTRUCTIVETESTING (NDT)SURFACE PROTECTIONMARKINGCERTIFICATE EN 10 204 Type 3.1B.TYPE OF MATERIAL: Structural Steel,GRADEPRODUCT STANDARDEN 10 210-1 S355NHHot finished tubularsseamless or weldedSCOPE This MDS specifies the selected options in the referred standard and modifiedrequirements which shall supersede the corresponding requirements in the referredstandard. The thickness is limited to 40 mm.QUALIFICATIONSHEAT TREATMENT/DELIVERY CONDITIONOption 1.4, CEV max 0.43 for all thicknessesCHEMICALCOMPOSITIONTENSILE TESTINGIMPACT TESTINGEXTENT OF TESTINGSURFACE CONDITION The surface of the material shall comply to Rustgrade A or B or better according to ISO8501-1.NON DESTRUCTIVETESTING (NDT)SURFACE PROTECTIONMARKINGCERTIFICATE EN 10 204 Type 3.1B.TYPE OF MATERIAL: Structural Steel,GRADEPRODUCT STANDARDCold formed tubulars EN 10 219-1 S355MLHSCOPE This MDS specifies the selected options in the referred standard and modifiedrequirements which shall supersede the corresponding requirements in the referredstandard. The thickness is limited to 25 mm.QUALIFICATIONSHEAT TREATMENT/DELIVERY CONDITIONOption 1.4, S max 0,015, P max 0,025CHEMICALCOMPOSITIONTENSILE TESTINGIMPACT TESTINGEXTENT OF TESTINGSURFACE CONDITION The surface of the material shall comply to Rustgrade A or B or better according to ISO8501-1.NON DESTRUCTIVETESTING (NDT)SURFACE PROTECTIONMARKINGCERTIFICATE EN 10 204 Type 3.1B.TYPE OF MATERIAL: Structural Steel,GRADEPRODUCT STANDARDPlates, sections EN 10113 S420NLS420MLSCOPE This MDS specifies the selected options in the referred standard and modifiedrequirements which shall supersede the corresponding requirements in the referredstandard. The thickness is limited to 50 mm.QUALIFICATIONSHEAT TREATMENT/DELIVERY CONDITIONCHEMICALCOMPOSITIONTENSILE TESTINGIMPACT TESTINGEXTENT OF TESTINGSURFACE CONDITION The surface of the material shall comply to Rustgrade A or B or better according to ISO8501-1.NON DESTRUCTIVETESTING (NDT)SURFACE PROTECTIONMARKINGCERTIFICATE EN 10 204 Type 3.1B.TYPE OF MATERIAL: Structural Steel,GRADEPRODUCT STANDARDCold formed tubulars EN 10 219-1 S420MLHSCOPE This MDS specifies the selected options in the referred standard and modifiedrequirements which shall supersede the corresponding requirements in the referredstandard. The thickness is limited to 16 mm.QUALIFICATIONSHEAT TREATMENT/DELIVERY CONDITIONOption 1.4, S max 0,015, P max 0,025, CEV max 0,39CHEMICALCOMPOSITIONTENSILE TESTINGIMPACT TESTING The Charpy V-value to be min 50 JEXTENT OF TESTINGSURFACE CONDITION The surface of the material shall comply to Rustgrade A or B or better according to ISO8501-1.DESTRUCTIVE TESTING(NDT)SURFACE PROTECTIONMARKINGCERTIFICATE EN 10 204 Type 3.1BTYPE OF MATERIAL: Structural Steel with documented through thickness propertiesGRADEPRODUCT STANDARDPlates EN 10225 S355G10+N/G10+MSCOPE This MDS specifies the selected options in the referred standard and modifiedrequirements which shall supersede the corresponding requirements in the referredstandard.QUALIFICATIONS Base material information, shall be submitted with the bid/ be established prior todelivery.The documentation of base material shall cover both delivered and PWHT conditionand shall include strain ageing tests (ref. option 12), typical tensile test results forplates and weldability tests according to Annex E (option 18) within each of thefollowing thickness ranges that are relevant for the order:25<t ≤ 40mm40<t ≤ 63mm63<t ≤ 100mm100<t ≤ 150mmOther thickness ranges related to same chemistry and manufacturing process mayapply. In such cases the thickest material in the range shall be tested. The results fromPWHT condition shall also meet the specified requirements.CTOD testing shall be included for weldability testing for t > 40 mm and shall meeta requirement of min. 0,25 mm in as welded condition, and min 0,20 in PWHTcondition unless lower values have been accepted by the purchaser. CTOD testingfor thicknesses below 40 mm may be required on the basis of special design criteria.HEAT TREATMENT/Quenched and Tempered is also accepted.DELIVERY CONDITIONCHEMICALOption 6COMPOSITIONTENSILE TESTINGIMPACT TESTINGEXTENT OF TESTING Option 13SURFACE CONDITIONNON DESTRUCTIVETESTING (NDT)SURFACE PROTECTION All surfaces shall receive a preliminary protective primer coat. Blast cleaning shallcomply with ISO 8501-1 Sa 2½ and the surface shall remain at Sa 2½ untilapplication of the primer. The primer shall consist of 1 coat zinc ethyl silicate primerwith 15 microns. Measured on a plane polished steel or glass test plate the DFT shallbe maximum 25 microns.CERTIFICATE EN 10 204 Type 3.1BTYPE OF MATERIAL: Structural Steel with documented through thickness propertiesGRADEPRODUCT STANDARDRolled Sections EN 10225 S355G12+N/G12+MSCOPE This MDS specifies the selected options in the referred standard and modifiedrequirements which shall supersede the corresponding requirements in the referredstandard.QUALIFICATIONS Base material information, shall be submitted with the bid/ be established prior todelivery.The documentation of base material shall include typical tensile test results andCharpy V results at various thicknesses and for Charpy V also various temperatures.Weldability tests shall be documented according to Annex E, option 18.CTOD testing shall be included for weldability testing for thickness above 40 mm andshall meet a requirement of min. 0,25 mm in as welded condition unless lower valueshave been accepted by the purchaser.HEAT TREATMENT/DELIVERY CONDITIONCHEMICAL COMPOSITION Option 6 and 9TENSILE TESTINGIMPACT TESTINGEXTENT OF TESTING Option 13SURFACE CONDITIONOption 21, Class 2.1NON DESTRUCTIVETESTING (NDT)SURFACE PROTECTION All surfaces shall receive a preliminary protective primer coat. Blast cleaning shallcomply with ISO 8501-1 Sa 2½ and the surface shall remain at Sa 2½ until applicationof the primer. The primer shall consist of 1 coat zinc ethyl silicate primer with 15microns. Measured on a plane polished steel or glass test plate the DFT shall bemaximum 25 microns.CERTIFICATE EN 10 204 Type 3.1BMATERIAL DATA SHEET MDS - Y22 Rev. 4 TYPE OF MATERIAL: Structural Steel with documented through thickness propertiesGRADEPRODUCT STANDARDSeamless tubularsEN 10225 S355G15+Q/G15+N(Seamless hollow sections)SCOPE This MDS specifies the selected options in the referred standard and modifiedrequirements which shall supersede the corresponding requirements in the referredstandard.QUALIFICATIONS Base material information, shall be submitted with the bid/ be established prior todelivery.The documentation of base material shall include typical tensile test results andCharpy V results at various thicknesses and for Charpy V also various temperatures.Weldability tests shall be documented according to Annex E, option 18.CTOD testing shall be included for weldability testing for thickness above 40 mm andshall meet a requirement of min. 0,25 mm in as welded condition unless lower valueshave been accepted by the purchaser.HEAT TREATMENT/DELIVERY CONDITIONCHEMICAL COMPOSITION Option 6The chemical composition in Table 10 shall be modified as follows: C max : 0.16%(option 7)TENSILE TESTINGIMPACT TESTINGEXTENT OF TESTING Option 13SURFACE CONDITIONNON DESTRUCTIVEOption 22.TESTING (NDT)SURFACE PROTECTION All surfaces shall receive a preliminary protective primer coat. Blast cleaning shallcomply with ISO 8501-1 Sa 2½ and the surface shall remain at Sa 2½ untilapplication of the primer. The primer shall consist of 1 coat zinc ethyl silicate primerwith 15 microns. Measured on a plane polished steel or glass test plate the DFT shallbe maximum 25 microns.CERTIFICATE EN 10 204 Type 3.1BMATERIAL DATA SHEET MDS - Y25 Rev. 4 TYPE OF MATERIAL: Structural SteelGRADEPRODUCT STANDARDPlates EN 10225 S355G9+N/G9+MSCOPE This MDS specifies the selected options in the referred standard and modifiedrequirements which shall supersede the corresponding requirements in the referredstandard.QUALIFICATIONS Base material information, shall be submitted with the bid/ be established prior todelivery.The documentation of base material shall cover both delivered and PWHT condition andshall include strain ageing tests (ref. option 12), typical tensile test results for plates andweldability tests according to Annex E (option 18) within each of the followingthickness ranges that are relevant for the order:25<t ≤ 40mm40<t ≤ 63mm63<t ≤ 100mm100<t ≤ 150mmOther thickness ranges related to same chemistry and manufacturing process may apply.In such cases the thickest material in the range shall be tested. The results from PWHTcondition shall also meet the specified requirements.CTOD testing shall be included for weldability testing for t > 40 mm and shall meet arequirement of min. 0,25 mm in as welded condition, and min 0,20 in PWHT conditionunless lower values have been accepted by the purchaser. CTOD testing forthicknesses below 40 mm may be required on the basis of special design criteria.Quenched and Tempered is also accepted.HEAT TREATMENT/DELIVERY CONDITIONCHEMICALOption 6.COMPOSITIONTENSILE TESTINGIMPACT TESTINGEXTENT OF TESTINGSURFACE CONDITIONNON DESTRUCTIVETESTING (NDT)SURFACE PROTECTION All surfaces shall receive a preliminary protective primer coat. Blast cleaning shallcomply with ISO 8501-1 Sa 2½ and the surface shall remain at Sa 2½ until applicationof the primer. The primer shall consist of 1 coat zinc ethyl silicate primer with 15microns. Measured on a plane polished steel or glass test plate the DFT shall bemaximum 25 microns.CERTIFICATE EN 10 204 Type 3.1BTYPE OF MATERIAL: Structural SteelGRADEPRODUCT STANDARDRolled Sections EN 10225 S355G11+N/G11+MSCOPE This MDS specifies the selected options in the referred standard and modifiedrequirements which shall supersede the corresponding requirements in the referredstandard.QUALIFICATIONS Base material information, shall be submitted with the bid/ be established prior todelivery.The documentation of base material shall include typical tensile test results and CharpyV results at various thicknesses and for Charpy V also various temperatures.Weldability tests shall be documented according to Annex E, option 18.CTOD testing shall be included for weldability testing for thickness above 40 mm andshall meet a requirement of min. 0,25 mm in as welded condition unless lower valueshave been accepted by the purchaser.HEAT TREATMENT/DELIVERY CONDITIONCHEMICAL COMPOSITION Option 6 and 9TENSILE TESTINGIMPACT TESTINGEXTENT OF TESTINGSURFACE CONDITIONNON DESTRUCTIVETESTING (NDT)SURFACE PROTECTION All surfaces shall receive a preliminary protective primer coat. Blast cleaning shallcomply with ISO 8501-1 Sa 2½ and the surface shall remain at Sa 2½ untilapplication of the primer. The primer shall consist of 1 coat zinc ethyl silicate primerwith 15 microns. Measured on a plane polished steel or glass test plate the DFT shallbe maximum 25 microns.CERTIFICATE EN 10 204 Type 3.1BTYPE OF MATERIAL: Structural SteelGRADEPRODUCT STANDARDEN 10225 S355G14+Q/G14+NSeamless tubulars(Seamless hollow sections)SCOPE This MDS specifies the selected options in the referred standard and modifiedrequirements which shall supersede the corresponding requirements in the referredstandard.QUALIFICATIONS Base material information, shall be submitted with the bid/ be established prior todelivery.The documentation of base material shall include typical tensile test results andCharpy V results at various thicknesses and for Charpy V also various temperatures.Weldability tests shall be documented according to Annex E, option 18.CTOD testing shall be included for weldability testing for thickness above 40 mm andshall meet a requirement of min. 0,25 mm in as welded condition unless lower valueshave been accepted by the purchaser.HEAT TREATMENT/DELIVERY CONDITIONCHEMICAL COMPOSITION Option 6The chemical composition in Table 10 shall be modified as follows: C max 0.16%(option 7)TENSILE TESTINGIMPACT TESTINGEXTENT OF TESTINGSURFACE CONDITIONNON DESTRUCTIVETESTING (NDT)SURFACE PROTECTION All surfaces shall receive a preliminary protective primer coat. Blast cleaning shallcomply with ISO 8501-1 Sa 2½ and the surface shall remain at Sa 2½ untilapplication of the primer. The primer shall consist of 1 coat zinc ethyl silicate primerwith 15 microns. Measured on a plane polished steel or glass test plate the DFT shallbe maximum 25 microns.CERTIFICATE EN 10 204 Type 3.1BTYPE OF MATERIAL: Structural SteelPRODUCT STANDARDGRADEWelded tubulars(Welded hollow sections)EN 10225 S355G13+NSCOPE This MDS is applicable for high frequency electric resistance welded hollow sectionsup to and including 20 mm thick.This MDS specifies the selected options in the referred standard and modifiedrequirements which shall supersede the corresponding requirements in the referredstandard.QUALIFICATIONS Establishment of WPS, qualification of welding procedures and qualification ofwelding operators shall be in accordance with the NORSOK standard M-101,"Structural Steel Fabrication".W ith regard to charpy impact testing the following modifications to M-101 shallapply:- Test temperature: -40ºC- Notch positions: Fusion Line (FL), FL+2 mm, FL+5 mm- Minimum average energy value: 36 J- Minimum individual energy value: 26 JQ ualified thickness range shall be in accordance with EN 288-3,Table 5Base material information, with typical results from chemical composition andmechanical testing, shall be submitted with the bid/ be established prior to delivery. HEAT TREATMENT/DELIVERY CONDITIONCHEMICAL COMPOSITION Option 6TENSILE TESTINGIMPACT TESTINGEXTENT OF TESTINGSURFACE CONDITIONNON DESTRUCTIVE TESTING (NDT) In accordance with section 8.5.3.3 of the standard, modified as follows: - Thickness equal to and above 10 mm: EN 10246-8/U4- Thickness less than 10 mm: EN 10246-3/E4 or EN 10246-8/U4SURFACE PROTECTION All surfaces shall receive a preliminary protective primer coat. Blast cleaning shallcomply with ISO 8501-1 Sa 2½ and the surface shall remain at Sa 2½ untilapplication of the primer. The primer shall consist of 1 coat zinc ethyl silicate primerwith 15 microns. Measured on a plane polished steel or glass test plate the DFT shallbe maximum 25 microns.CERTIFICATE EN 10 204 Type 3.1B。

Material Safety Data Sheet

Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. No additional information is available regarding the risks of explosion. SMALL FIRE: Use DRY chemicals, CO 2, water spray or foam. LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet.
Page 2
Keep away from heat and sources of ignition. Mechanical exhaust required. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. DO NOT get water inside container. DO NOT touch spilled material. Use water spray curtain to divert vapor drift. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all sources of ignition. Consult federal, state, and/or local authorities for assistance on disposal.

Materialsafetydatasheet材料安全数据表

Personal Protective Equipment for Routine Handling
Respiratory Protection
No respiratory protection is required under normal usage
Hand Protection
No special protection needed.
3. Hazards Identification（危险性鉴别）
Overall Hazard Classification危害级别
Not hazardous (无危害性成份)
Route of Exposure暴露途径
Skin contact and accidental ingestion皮肤接触和意外吞食
Inhalation吸入
No volatile, No first aid should be needed.不挥发,无需急救
Ingestion食入
If swallowed large amount, get medical attention immediately if ill effects occur.如大量吞食并出现不适症状，请立即求医
Chronic慢性
Skin皮肤
Prolonged skin contact may cause irritation长时期的皮肤接触可能引起过敏
Inhalation吸入
No volatile No Known applicable information无
Ingestion食入
Repeated ingestion or swallowing large amount may injure internally.重复或大量摄入或吞食可能会造成内部伤害

易粘胶带 Easy-sticking Tape物质安全资料表MSDS

物質安全資料表Material Safety Data Sheet1.物品與廠商資料（Product and Company Identification）物品中（英）文名稱（Product Name）易粘胶带Easy-sticking Tape化學分類（Chemical Classification）塑料产品Plastic Product公司介紹（Manufacture）(1)製造商/供應商名稱（Name）(2)製造商/供應商地址（Address）(3)電話（Phone Number）(4)傳真（Fax Number）(5)緊急聯絡電話（Emergency Phone No.）(6)聯絡人（Contact Person）2.成份辨識資料（Composition, Information on Ingredients）部件材料名称Component-Chemical Name & Common Names含量Percentage供应商名称Supply company nameCAS-NO.分子式structuralformulaKD32 PET膜 PET film 50% 欧亚Europe & Asia 25038-59-9 (C10H8O4)n KD31PET膜 PET film 25% 欧亚Europe & Asia 25038-59-9 (C10H8O4)n导电膜Electric film 25% 欧亚Europe & Asia 7782-42-5 C 丙烯酸丁酯Butyl acrylate24% 新世纪New century 141-32-2C7H12O2丙烯酸异辛酯Vinyl acetate14% 新世纪New century 29590-42-9 C11H20O2丙烯酸Acrylic acid12% 新世纪New century 79-10-7C3H4O23.危害辨識資料（Hazard Identification）最重要危害效應（Most Important Health Hazards and Reactions）(1)緊急概要(Emergency Overview)无None(2)健康危害效應(Health Hazards and Reactions)无健康危险与反应No Health Hazards and Reactions(3)環境影響(Environmental Hazards)无环境影响No Effects to the Environment(4)物理性及化學性危害(Physical and Chemical Hazards)无No Physical and Chemical Hazards (5)特殊危害(Specific Hazards)无No Specific Hazards.主要症狀(Cardinal Symptoms) 无None危害物質分類(Hazard Classification) 无None4.急救措施（First Aid Measures）不同暴露途徑之急救方法（First Aid Measures for Different Kinds of Exposures(1)眼睛接觸(Eye Contact)无None(2)皮膚接觸(Skin Contact)清洗Washing(3)吸入(Inhalation)无None(4)食入(Ingestion)无None最重要症狀及危害效應概要(Most ImportantSymptoms and Hazard Reactions)无None對急救人員之防護(Protection to First-AidAttendants)无None對醫師之提示(Suggestions to Doctors) 清水清洗Cleaning with clean water 5.滅火措施（Fire Fighting Measures）適用滅火劑(Suitable Extinguishing Media)干粉Powder滅火時可能遭遇之特殊危害(Special Hazards in Fire) 会产生一定烟雾It will produce the certain smoke特殊滅火程式(Special Fire-Fighting Procedures)无None消防人員之特殊防護設備(Required SpecialProtective Equipment for Fire-Fighters)消防衣Fire Protective Clothing 6.泄漏處理方法（Accidental Release Measures）The metal is in a solid condition. No spillage issue.個人應注意事項(Personal Precautions) 无None環境注意事項(Environmental Precautions) 无None清理方法(Methods for Cleaning) 无None7.安全處置與儲存方法（Handling and Storage）處置(Handling) 无None儲存(Storage) 防高温、烟火，在通风干燥场合储存Keep off the heat, fire, saving in the well ventilated and dry place.8.暴露預防措施（Exposure Controls, Personal Protection）工程控制(Engineering Measures) 无None控制參數(Cotrol Parmeters) 无None個人防護設備(Personal Protection Equipment)无None衛生措施(Hygiene Measures) 无None9.物理及化學性質（Physical and Chemical Properties）成份(Component)（1）物質型態(State of Substance)固体Solid（2）顔色(Color)茶色tawny/透明Clarity/雾状roridous （3）外觀(Appearance)圆环状Cirque（4）氣味(Odor)无None（5）PH值(PH Value) 6.8~7.2（6）沸點(Boiling Point)无None（7）閃火點(Flashpoint ℉/℃)无None（8）分解溫度(Decomposing Temperature)300℃以上 Above 300℃（9）自然溫度(Self-Igniting Temperature)无None（10）蒸氣壓(Vapor Pressure)无None10.安全性及反應性（Stability and Reactivity）安定性(Stability) ■Stable稳定□Unstable不稳定特殊狀況下可能之危害反應(Possible HazardReaction Under Special Conditions)无None應避免之狀況(Conditions to Avoid) 无None應避免之物質(Materials to Avoid) 无None危害分解物(Hazardous Decomposition Products)无None11.毒性資料（Toxicological Information）急毒性(Acute Toxicity) 无毒性No noxious effects during normal handling and use.局部效應(Local Effects) 无None致敏感性(Sensitivity) 无None慢毒性或長期毒性(Chronic or Long Term Toxicity)无None特殊效應(Special Reactions) 无None12.生態資料（Ecological Information）可能之環境影響/環境流布(Possible Environmental Impact/Environments Run-offs)无None 13.廢棄處理方式（Disposal Considerations）産品廢棄處理(Product Discard Disposal Method) 1.按当地或国家法律Comply with local ornational legislation.2.用可再生材料储存Store in a recycleequipment.3.循环使用Recycling.包裝廢棄處理(Packing Discard Disposal Method)如上处理Same as above items.14.運送資料（Transport Information）國際運送規定(International Transportation Regulations)（1）美國交通部、49CFR分級无None（2）海運、IMDG分級无None（3）航運、TATA分級无None聯合國編號(UN Reference No.) 无None國內運送規定(Domestic TransportationMethods and Precautions)安全运输规定Road Safety Regulations. 特殊運送方法及注意事項(SpecialTransportation Methods and Precautions)无None15.法規資料（Regulatory Information）適用法規(Applicable Regulation) 1.劳动法和健康规定Labors Safety &Health Rules2.产品废弃处理办法和标准ProductDiscard Disposal Method & Standard of Facilities16.其他資料（Other Information）參考文獻(Reference Document) Hazardous Chemical Substance Chinese Data bank, Bureau of Environment.製表單位(Department) 体系部System Department 製造商及供應商地址(Add.)電話(Tel)製錶者(Made By)製錶日期(Data Prepared)。

Materialsafedatasheet(材料安全数据表)

Material safe data sheet（材料安全数据表）The first minute（第一部分）: Product name and company's information（产品名称及公司信息）Product name（产品名称）: Luminescent pigment （发光颜料）Product mode（产品型号）：ZnSWCompany's information（公司信息）: Guangzhou tianyu limited company （广州田宇贸易有限公司）Address:No.28 Hhamei Street,LongDong,Tianhe,Guanzhou,China（广州市天河区龙洞华美路28号）Tel: 86-20-87210918FAX: 86-20-87065181It is second and partial（第二部分）: Dangerousness is general to stat（危险性概述）Dangerousness classification（危险性类别）: It is not dangerous article（不是危险品）Invade channel:（侵入途径）Suck in and eat to enter（吸入、食入）Healthy harm（健康危害）: For skin and respiratory tract, mucous membrane has stimulate（对皮肤、呼吸道粘膜有刺激）Environmental harm（环境危害）: This material dust has light pollutive harm for environment（该物质粉尘对环境有轻微污染危害）Burn Bao danger（燃爆危险）: It is not inflammable to burn and explode（不易燃烧、爆炸）3th is partial: （第三部分）Product mix and chemistry form information（产品结构及化学组成信息）Molecular formula（分子式）: ZnS:Cu4th is partial（第四部分）: The measure of first aid急救措施Suck in and eat to enter:(吸入/食入)If suck in this article dust carelessly, please wash nasal cavity and oral cavity with plenty of waters, if have , it is improper, please go to hospital as soon as possible to treat. （如不小心吸入本品粉尘，请用大量水冲洗鼻腔、口腔，如有不适，请尽快就医治疗。

化学危险品信息一览表(Material Safety Data Sheet)

可车运、空运避免接触到眼睛和皮配防护镜、防护衣、手套、脚套、防护面具
肤,不得吸入粉末. 禁。皮肤及眼睛接触后立即用水清洗；若吸入
止有皮肤病、肺病病立即到通风处，如果发昏或过敏或感觉不
史的人使用此产品。良，立即就医。发生泄漏用沙土围堵，防止
流入下水道或河流中。
Alpha助焊剂 FLS0016T-5
不可空运.
请在搅拌后使用.
误入眼内时,请用干净的水清洗干净,并就医治疗;皮肤接触易引发炎症,请用水和肥皂冲洗;若误食不要勉强催吐,请立即就医治疗.
为防止垃圾,水分等的混入, 使用后请密封.避免阳光直射,在常温下,保存于室内.
同上
同上
同上
№
名称
皮模润滑剂 CD-A7
24
Page 4
化学危险品信息一览表(Material Safety Data Sheet)
及换气设备. 作业人流通之处,首先须移开所有的火源;少量的泄漏
员须有个人防护设备, 可用纸张或吸附物吸去漏液再移至通风处自
作业后,饮食前需漱然挥发.大量泄漏须抽取至储存桶.处理人员须
洗.
配戴充分的个人防护设备.
17 Alpha425稀释剂 18 K901P稀释剂
同上异丙醇等
同上同上
同上同上
能形成长期不利影响
。
同上。
同上。
Page 6
化学危险品信息一览表(Material Safety Data Sheet)
update MSDS
№
名称
焊丝NERTALIC 70S
化学成份
危险性质
储存
运输
铁、锰、硅、鉻铜色固体，无味，干燥存放，避免潮湿。不同上。

镀铁氧体磁芯FERRITE CORE WITH PLATING物质安全资料表MSDS

物質安全資料表Material safety data sheet1.化學品與廠商資料Information of goods and manufacturers化學品名稱 Chemicals Name：FERRITE CORE WITH PLATING (M SERIES MATERIAL) 其它名稱 Other Names：-建議用途及限制使用：-製造商或供應商名稱 Manufacturer or supplier：製造商或供應商地址 Manufacturer or supplier address：製造商或供應商電話 Phone number：傳真 Fax：緊急聯絡電話/傳真電話 Emergency call number：傳真 Fax：2.危害辨識資料Hazard identification information化學品危害分類Chemicals hazard class：-標示內容Label content：-其他危害Other hazards：-3.成分辨識資料Component identification information化學物質Chemical Substances 化學文摘社登記號碼CAS No.化學式Chemical formula主要用途Main Purposes比率Weight (%)FERRITE CORE 1309-37-11313-99-11314-13-21317-38-0Fe²O³NiOZnOCuOMagnet material95-99%Ag 7440-22-4 Ag Terminal 3-5%Ni 7440-02-0 Ni Terminal 0.0010-0.0020%Sn 53408-94-9 Sn Terminal 0.0010-0.0020%4.急救措施First-aid measures不同暴露途徑之急救方法Different exposure routes of first aid methods：˙吸入Inhalation：移除污染源或將患者移至新鮮空氣處Remove sources of pollution or moved to fresh air in patients with Department˙食入Ingestion：若有不適立即就醫Immediate medical treatment最重要症狀及危害效應Against the most important symptoms and effects：無法提供boiling point range對急救人員之防護Protection of first aid personnel：無法提供boiling point range對醫師之提示Tips for physicians：無法提供boiling point range5.滅火措施Fire-fighting measures適用滅火劑Application of extinguishing agents：儲存區應備用隨時可用之適當滅火器材storage area should be readily available back-up of appropriate fire-fighting equipment滅火時可能遭遇之特殊危害Fire may encounter special hazards：非易燃物質Non-flammable material特殊滅火程序Special fire fighting procedures：若無著防護衣及呼吸器不得進入危險區域If there are no protective clothing and breathing apparatus are not allowed to enter the hazardous area消防人員之特殊防護設備Special protective equipment for firefighters：消防人員必須配戴全身式化學防護衣及自攜式空氣呼吸器(必要時外加抗閃火鋁質被覆外套) firefighters must wearfull-body chemical protective clothing and breathing apparatus to bring their own air(If necessary plus a fire resistant aluminum coating flash jacket)6.洩漏處理方法Leakage treatment個人應注意事項Personal attention：使用手套等防護用具to use gloves or other protective equipment環境注意事項Environmental Notes：避免進入地表或地下水系統avoid entering surface or groundwater systems清理方法Clean-up methods：用水沖洗洩漏區域Wash with water leakage region7.安全處置與儲存方法Safe disposal and storage methods1、操作與儲存注意事項operation and storage Note：儲存場所應維持溫度＜30℃及溼度＜70%RH之條件下storage sites should maintain the temperature ＜30℃and humidity ＜70% RH conditions。

NUCO INTUMESCENT FIRESTOP CAULK SELF SEAL GG-266 产

MATERIAL SAFETY DATA SHEET SECTION 01 – CHEMICAL PRODUCT AND COMPANY IDENTIFICATION:Chemical Name: Manufacturer:Date:Prepared by:WHMIS Classification: Product Use: SELF SEAL®GG-266 INTUMESCENT FIRESTOP CAULKNUCO INC.150 Curtis DriveGuelph, Ontario N1K 1N5Tel: (519)-823-4994Fax: (519)-823-1099Infotrac 24 Hour Emergency Tel: (800)-535-5053July 1, 2023Technical Services DepartmentD2BIntumescent Silicone Caulk for FirestoppingSECTION 02 – COMPOSITION / INFORMATION ON INGREDIENTS:Ingredients________________________ CAS No.______ %________ LD50(Oral-Rat) LC50(Inhalation-Rat) Methyl Tri(methylethylketoxime)silane 22984-54-9 3.0 - 7.0 2 – 3 ml/kg >50 mg/L (4 hr) Amorphous Silica 7631-86-9 1.0 – 5.0 3,160 mg/kg >0.139 mg/L (4 hr) 1,3,5-Triazine - 2,4,6,-Triamine 108-78-115.0 – 40.0 3,100 mg/kg Not availableNatural Graphite 7782-42-510.0 – 30.0 Not available Not availableThe ingredients listed above are controlled products as defined in CPR, am. SOR/88-555 or 29 CFR 1910.1200 SECTION 03 – HAZARDS INDENTIFICATION:ROUTES OF ENTRY INTO THE BODY (ACUTE EFFECTS):Eyes: Direct contact may cause mild irritation.Skin: May cause moderate irritation. Repeated skin contact may cause allergicskin reaction.Inhalation: Irritates respiratory passages very slightly. Vapor overexposure maycause drowsiness and prolonged overexposure may injure blood and liver. Ingestion: Low ingestion hazard in normal use. Repeated ingestion may injureinternally.WHMIS HAZARD SYMBOL(S):SECTION 04 - FIRST AID MEASURES:Eyes: Flush with copious quantities of lukewarm water. Do not attempt tophysically remove the solids or gums from the eye. Seek medical attentionimmediately.Skin: Remove contaminated clothing. Wash thoroughly with warm water andnon-abrasive soap. Seek medical attention if you feel ill or a reactiondevelops.Inhalation: Remove to fresh air and provide water. Seek medical attention if you feelill or a reaction develops.Ingestion: Get medical attention.SECTION 05 - FIRE FIGHTING MEASURES:Flammable Conditions: Avoid direct sources of heat or ignition in uncured state.Extinguishing Media: Carbon dioxide, dry chemical, water fog or foam. Water can be used tocool fire exposed containers.Fire Fighting Measures: Self-contained breathing apparatus and protective clothing should be wornin fighting large fires involving chemicals. Determine the need to evacuateor isolate the area according to your local emergency plan.Flash Point: Not applicableFlammability Limits: Lower Explosion Limit – not availableUpper Explosion Limit – not availableAutoignition Temperature: Not availableHazardous Decomposition Products: Carbon dioxide, carbon monoxide, silicone dioxide, sulfur oxides, nitrogenoxides, formaldehyde, and other potentially toxic fumes.Sensitivity - Impact: NoneStatic: NoneSECTION 06 – ACCIDENTAL RELEASE MEASURES:Containment / Clean Up: Restrict access to the area of the spill. Provide ventilation, NIOSH / MSHAapproved respirator and protective clothing. Scrape up caulk and place incontainer for disposal. Clean area as appropriate since silicone materialscan represent a slip hazard. Cleaning may require steam or detergents.Dispose of saturated absorbent or cleaning materials appropriately, sincespontaneous heating may occur. Local, state, provincial, federal laws andregulations may apply to releases and disposal of this material, as well asthose materials and items employed in the cleanup.SECTION 07 – HANDLING AND STORAGE:Handling and Storage: Store in an adequately ventilated area under dry conditions between 50︒F(10︒C) to 77︒F (25︒C) and keep container tightly sealed when not in use. SECTION 08 – EXPOSURE CONTROL / PERSONAL PROTECTION:Component Exposure Limits: Methyl Tri(methylethylketoxime)silane (CAS# 22984-54-9) forms MethylEthyl Ketoxime (CAS# 96-29-7) upon contact with atmospheric moisture.Provide adequate ventilation to control exposures within the followingexposure guidelines: Vendor Guide TWA: 3 ppm, STEL: 10 ppm; AIHAWEEL TWA: 10 ppm.Amorphous Silica (CAS# 7631-86-9): Although the silica is coated with thesilicone caulk observe the particulate limits.OSHA PEL: TWA 80 mg/m3 /SiO2 . NIOSH REL: TWA 6 mg/m3.1,3,5-Triazine –2,4,6,-Triamine (CAS# 108-78-1): Although the amine iscoated with the silicone caulk observe the particulate limits. AIHA WEEL:10 mg/m3 inhalable fraction, 5 mg/m3 respirable fraction.Natural Graphite (CAS# 7782-42-5): Although the graphite is coated withthe silicone caulk observe the particulate limits. OSHA PEL: 2.5 mg/m3respirable fraction. ACGIH TLV: 2 mg/m3 respirable particulate. Respiratory: Wear an organic vapor NIOSH / MSHA approved respirator.Ventilation: In indoor applications, passive ventilation (opening of doors and windows)is recommended. Local exhaust as necessary to keep exposure levelswithin guidelines.Personal Protective Equipment: Safety glasses with side-protection, impermeable gloves (e.g., neoprene,nitrile, silver shield®), coveralls or apron are important in preventingcontamination of eyes, skin and clothing. Wash thoroughly after handling. SECTION 09 – PHYSICAL AND CHEMICAL PROPERTIES:Physical State: Red paste with black particlesOdor and Appearance: Thixotropic caulkOdor Threshold: Not availableSpecific Gravity: 1.25Vapor Pressure: Less than 5 mm HgVapor Density: Greater than 1Evaporation Rate: Not availableBoiling Point: Not applicableFreezing Point: Not applicablePh: Not availableCoeff. Oil/Water Distribution: Not availableSECTION 10 – STABILITY AND REACTIVITY:Chemical Stability: Stable but will begin to intumesce above 300︒F (150︒C)Incompatible Materials: Strong oxidizing agents or electrophiles (e.g. ferric chloride).Concentrated acids or bases can degrade the silicone polymer.Reactive Conditions: High temperature, moisture and incompatible materials.Hazardous Polymerization: Will not occur.SECTION 11 - TOXICOLOGICAL INFORMATION:Effects of overexposure: The curing vapor, Methyl Ethyl Ketoxime (CAS# 96-29-7), may causedrowsiness, injure blood, liver and may irritate or harm nose, throat, lungsand eyes. Direct contact with eyes will irritate. Direct contact with skinmay irritate.Sensitization: Allergic skin sensitization possible through repeated direct contact withthe ketoxime in the uncured caulk.Carcinogenicity: No ingredients considered by IARC, NTP or OSHA to be carcinogens. Malerodents exposed to Methyl Ethyl Ketoxime (CAS# 96-29-7) vaporthroughout their lifetime developed liver carcinomas. These carcinomaswere statistically increased at a concentration of 375 ppm.Reproductive Toxicity: Methyl Ethyl Ketoxime (CAS# 96-29-7) is not considered a reproductive ordevelopmental toxin based on studies on rats.Teratogenicity: No known applicable information.Mutagenicity: Methyl Ethyl Ketoxime (CAS# 96-29-7) is not considered mutagenic orgenotoxic based on in vivo and in vitro studies.Synergistic Products: No known applicable information.SECTION 12 – ECOLOGICAL INFORMATION:Air: Complete information is not yet available.Water: The 1,3,5-Triazine - 2,4,6,-Triamine (CAS# 108-78-1) is slightly soluble inwater, inherently biodegradable with low toxicity to aquatic life (e.g., 96 hLC50 (for fish): >3,000 mg/L, 48 h EC50 (for Daphnia): >2,000 mg/L).Natural Graphite (CAS# 7782-42-5) is insoluble in water.Soil: Complete information is not yet available.SECTION 13 – DISPOSAL CONSIDERATIONS:Waste Disposal: Dispose in accordance with Federal, State / Provincial and localregulations.SECTION 14 - TRANSPORT INFORMATION:Shipping Information: Not subject to DOT, TDG, IMDG Code or IATA Regulations.SECTION 15 - REGULATORY INFORMATION:TSCA Inventory Status: Chemical components listed on TSCA inventory except as exempted. NFPA Profile: Health 2, Flammability 1, Reactivity 0SARA TITLE III Chemical Listings: Section 302 Extremely Hazardous Substances (40 CFR 355): NoneSection 304 CERCLA Hazardous Substances (40 CFR 302): NoneSection 311/312 Hazard Class (40 CFR 370): Acute: Yes; Chronic: Yes; Fire:No; Pressure: No; Reactive: NoSection 313 Toxic Chemicals (40 CFR 372): The nitric and sulfuric acidsencapsulated within the graphite matrix do not pose a hazard duringnormal use but are subject to the reporting requirements of Section 313 ofTitle III (40 CFR Part 372): 2.9% nitric acid (CAS# 7697-37-2) and 4.75%sulfuric acid (CAS# 7664-93-9).State Substance List: This product contains a listed substance(s) that appears on one or more ofthe Substance Lists for Pennsylvania, Massachusetts and New Jersey:amorphous silica (CAS# 7631-86-9); 1,3,5-triazine-2,4,6-triamine (CAS#108-78-1); graphite (CAS# 7782-42-5); methyl tri(methylethylketoxime)silane(CAS# 22984-54-9); dimethylsiloxane, hydroxy terminated (CAS# 70131-67-8); and dimethylsiloxane, trimethylsiloxy terminated (CAS# 63148-62-9). California Proposition 65 List: Strong inorganic acid mists containing sulfuric acid (not released undernormal conditions of use).Volatile Organic Content: 25 grams per liter (0.21 lb/gallon), 2.0% by weight (CARB Method 310). Domestic Substance List: Chemical components listed on DSL except as exempted.SECTION 16 – OTHER INFORMATION:The information herein is given in good faith, but no warranty, express or implied, is made. Product users should make independent judgements of the suitability of this information to ensure proper use and to protect the health and safety of employees. Form: MSDSSELFSEALGG-266 Rev.: 6 Date: 07/08。

MaterialSafetyDataSheet-GORYOCHEMICAL,INC

Material Safety Data SheetMSDS Updated: April 1, 20151. CHEMICAL PRODUCT & COMPANY IDENTIFICATIONIdentification of productCat. No. Product Name PackageSK2002-01 ZnAF-2 DA 5 mmol/L ( 1 mg)Company identificationCompany name Goryo Chemical, Inc.Department Product development div.Address Business spring 2F, Kita 21 jou Nishi 12 tyoume2,Kita-ku, Sapporo, Hokkaido, Japan Tel: +81-11-214-9422Fax: +81-11-351-1822E-mail: ******************2. COMPOSITION/INFORMATION ON INGREDIENTSingle Component or Mixture: MixtureMain Ingredients: See the table belowChemical name:6-[N-[N’,N’-bis(2-pyridinylmethyl)-2-aminoethyl]amino-3’,6’-bis(acetyloxy)-spiro[isobenzofuran-1(3H),9’-[9H]xanthen]-3-one3. HAZARDS IDENTIFICATIONDimethyl SulfoxidePhysical Description: Flammable LiquidHazardous Nature:∙Highly flammable contact with heat or flame∙Risk of explosive reactions by acetyl chloride, chlorotoluene, chlorobenzene, tetrachlorosilane, or phosphorus trichloride∙Risk of explosion by sodium hydride or magnesium perchlorate depend on conditionsHazardous Property: By heating at the boiling point, Dimethyl Sulfoxide is decomposed slightly and forms formaldehyde. Formaldehyde causes eye irritation and mucosal irritation. Additionally, it forms offensive substance such as methyl sulfide and methyl mercaptan by pyrolysis. Methyl sulfide and methyl mercaptan liberates hazardous sulfer dioxide gas by inflammation.4. FIRST AID MEASURESEye Contact: Immediately wash thoroughly with plenty of water for at least 15 minutes.Immediately obtain medical attention. (an eye doctor, ophthalmologist.)Skin Contact: Wash affected area thoroughly with soap and plenty of water, and get medical attention.Inhalation: Remove to fresh air immediately, give a rest and keep warm covering the body with blanket and such, and obtain medical attention.Ingestion: Rinse out mouth thoroughly with water and obtain medical attention immediately5. FIRE FIGHTING MEASURESFire Extinguishing Measures:∙In case of the fire near containers, move them from the fire area to the safety place swiftly. If it is impossible, cool containers and the surroundings with water spray until well after the fire is out.∙In case of fire in itself, extinguish origins of the fire and keep away people all but the concerned from the site to the safety place. In an early phase of fire, extinguish with powder extinguisher and CO2 extinguisher. Go to the windward to avoid inhalation of toxic fumes and do fire fighting. Wearing protective clothing during the fire fighting is imperative.Suitable Extinguishing Media:Water, CO2 extinguisher, Powder extinguisher, Foam extinguisher6. ACCIDENTAL RELEASE MEASURES①Go to the windward, and wearing protective clothing during procedures isimperative. Also, keep away the people under lee and seal off by roping spillsite. Keep away near inflammables swiftly and prepare fire-fightingequipments.②Absorb with dry sand, dry earth, sawdust, and waste cloth and such, andcollect spilled material into closed containers. Wash spill site with copiousamount of water after material pickup was complete.③Do not allow the substance of product to reach rivers through sewage systemdue to avoiding effect on the environment. In case of diluting with large volumeof water, do not allow contaminated water to affect the environment withoutproper processing.7. HANDLING & STORAGEHandling: Before processing, switch on ventilating fans or local ventilating equipments.Wear protective mask to avoid inhalation and protective gloves to avoid contacting directly. If heated, liberates offensive odor such as methyl sulfide or methylmercaptanafter pyrolysis. Keep on the appropriate temperature; Avoid prolonged exposure and handle only in well-ventilated areas during handling.Storage: Keep containers tightly sealed due to very strong hygroscopicity. Store at 2~8℃. Inflammables. Inspect to detect the leakage occasionally.8. EXPOSURE CONTROLS / PERSONAL PROTECTIONPersonal Protecting Equipment: Wear gas mask for organic gas, respiratory protective device that is independent of circulating air, air inhaler, protective glass, protective gloves, and protective boots depending on the situation.9. PHYSICAL AND CHEMICAL PROPERTIESAppearance: Transparent liquid with colorless or slightly reddish violetStrong hygroscopicity（Dimethyl Sulfoxide）Odor: Odorless/Irritating odor faintly（Dimethyl Sulfoxide）Boiling point: 189℃（Dimethyl Sulfoxide）Melting point: 18.5℃（Dimethyl Sulfoxide）Density: 1.100～1.105(20/20℃)（Dimethyl Sulfoxide）Flash point: 95℃（Dimethyl Sulfoxide）Firing point: 270℃（Dimethyl Sulfoxide）Vapor pressure: 100 mmHg (27℃)（Dimethyl Sulfoxide）Solubility: Miscibility with water, ethanol and chloroformOther Information: ZnAF-2 DA forms a complex with Zn2+.10. STABILITY AND REACTIVITYExplosion limits: Maximum 28.5vol% Minimum 2.6vol%（Dimethyl Sulfoxide）Combustibility: Flammable（Dimethyl Sulfoxide）Ignition Hazardous Property: Ignites with potassium permanganate（DimethylSulfoxide）Thermal Decomposition: Unstable（Dimethyl Sulfoxide）Stability/Reactivity: Dimethyl Sulfoxide absorbs various gases. It can be oxidized to dimethylsulfon by strong oxidizing agent and can be reduced to dimethylsulfide by reductant. It forms various reactants by reacting with chloride and composite compounds by reacting with concentrated sulfide acid. It reacts vigorously with halide in acyl or aryl groups, bromobenbenzyl acetanilide, chloride of cyanuric acid, methyl bromide, NIO4, P2O3, and AgF. Reacts with oxidized compounds.11. TOXICOLOGICAL INFORMATION （Dimethyl Sulfoxide）Skin Corrosivety: Permeates into skin. By contacting with skin constantly, skinbecomes red by dermal respiration and has squamate dermabrasion. Maycause nausea, vomiting, ague, convulsion, decreased vision, and allergicreaction occasionally.Mutagenicity: Positive12. ECOLOGICAL INFORMATIONNot available13. DISPOSAL CONSIDERATIONS∙In the case of small quantity, absorb with diatomite∙Dilute with other flammable organic solvent and burn by incinerator in limited amounts∙Hand over to licensed hazardous waste disposers14. TRANSPORT INFORMATIONWhen aiming transporting on a vehicle, load into a container to prevent from falling, damaging or dismantling.UN-No.: Non Class: Non15. REGURATORY INFORMATIONNot available16. OTHER INFORMATIONAlthough the information above is based on comprehensive investigation, it may not cover all the necessary data. Please verify its safety according to the purpose of each use. Goryo Chemical assumes no responsibility resulting from the use or handling of this compound.。

MATERIALSAFETYDATASHEET1.CHEMICAL…

SDS: 0021138Date Prepared: 01/31/2014MATERIAL SAFETY DATA SHEET_____________________________________________________________________________1.CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONProduct Name:TMPTA Synonyms:None Chemical Family:Acrylated resin Molecular Formula:Mixture Molecular Weight:MixtureAllnex USA Inc., 9005 Westside Parkway, Alpharetta, Georgia 30009, USAFor Product and all Non-Emergency Information call your local Allnex contact point or contact us at/contactEMERGENCY PHONE (24 hours/day) - For emergency only involving spill, leak, fire, exposure or accident call:Asia Pacific:Australia: +61 2801 44558 (Carechem 24)China (PRC): +86(0)532-8388-9090 (NRCC)Japan: +81 345 789 341 (Carechem 24)New Zealand: +64 9929 1483 (Carechem 24)All Others: +65 3158 1074 (Carechem 24)Europe/Africa/Middle East (Carechem 24):Europe, Middle East, Africa, Israel: +44 (0) 1235 239 670Middle East, Africa (Arabic speaking countries): +44 (0) 1235 239 671Latin America (Carechem 24):Brazil: +55 113 711 9144Mexico and all others: +52-555-004-8763Canada and USA (Carechem 24 - Allnex29003-NCEC): +1-866-928-0789 (toll free) or +1-215-207-0061_____________________________________________________________________________2. HAZARDS IDENTIFICATIONEMERGENCY OVERVIEWAPPEARANCE AND ODOR:Color:clear colorless to pale yellow Appearance:liquid Odor:ester acrylateSTATEMENTS OF HAZARD:POTENTIAL HEALTH EFFECTSEFFECTS OF EXPOSURE:The acute oral (rat) LD50 and dermal (rabbit) LD50 values are both >2000 mg/kg. Direct contact with this material may cause moderate eye and skin irritation. Repeated or prolonged dermal contact may cause allergic skinreactions. The toxicological properties of this material have not been fully investigated. Refer to Section 11 fortoxicology information on the regulated components of this product._____________________________________________________________________________3. COMPOSITION/INFORMATION ON INGREDIENTSCAUSES EYE AND SKIN IRRITATIONMAY CAUSE ALLERGIC SKIN REACTIONWARNING!3. COMPOSITION/INFORMATION ON INGREDIENTSOSHA REGULATED COMPONENTSComponent / CAS No.%Carcinogen99 - 100-Trimethylolpropane triacrylate15625-89-5−⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−− 4. FIRST AID MEASURESEye Contact:Rinse immediately with plenty of water for at least 15 minutes. Obtain medical attention immediately.Skin Contact:Remove contaminated clothing and shoes without delay. Wash immediately with plenty of water. Do not reuse contaminated clothing without laundering. Get medical attention if pain or irritation persists after washing or if signs and symptoms of overexposure appear.Ingestion:If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person.Inhalation:Remove to fresh air. If breathing is difficult, give oxygen. Obtain medical advice if there are persistent symptoms.−⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−− 5. FIRE-FIGHTING MEASURESSuitable Extinguishing Media:Use water spray, alcohol foam, carbon dioxide or dry chemical to extinguish fires. Water stream may be ineffective. Extinguishing Media to Avoid:high pressure water jet.Protective Equipment:Firefighters, and others exposed, wear self-contained breathing apparatus. Wear full firefighting protective clothing. See MSDS Section 8 (Exposure Controls/Personal Protection).Special Hazards:Keep containers cool by spraying with water if exposed to fire.−⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−− 6. ACCIDENTAL RELEASE MEASURESPersonal precautions:Where exposure level is not known, wear approved, positive pressure, self-contained respirator. Where exposure level is known, wear approved respirator suitable for level of exposure. In addition to the protective clothing/equipment in Section 8 (Exposure Controls/Personal Protection), wear impermeable boots.Methods For Cleaning Up:Remove sources of ignition. Cover spills with some inert absorbent material; sweep up and place in a waste disposal container. Flush spill area with water.Environmental Precautions:None known−⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−−7. HANDLING AND STORAGEHANDLINGPrecautionary Measures: Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Keep container tightly closed. Use with adequate ventilation. Wash thoroughly after handling.Special Handling Statements: Product exposed to sunlight will slowly polymerize.STORAGEContainers which are opened must be carefully resealed and kept upright to prevent leakage. Prevent unauthorised access. Storage in stainless steel, amber glass, amber polyethylene or baked phenolic lined container. Keep containers tightly closed. Keep away from heat.Storage Temperature: Store at 4 - 40 °C 39.2 - 104 °FReason: Safety._____________________________________________________________________________ 8. EXPOSURE CONTROLS/PERSONAL PROTECTIONEngineering Measures:Utilize a closed system process where feasible. Where this material is not used in a closed system, good enclosure and local exhaust ventilation should be provided to control exposure.Respiratory Protection:For operations where inhalation exposure can occur use an approved respirator. Recommendations are listed below. Other protective respiratory equipment may be used based on user's own risk assessment.Recommended respirators include those certified by NIOSH.Recommended:Full Face Mask with organic vapor cartridge, Type A filter (BP >65°C)Eye Protection:Prevent eye and skin contact. Provide eye wash fountain and safety shower in close proximity to points of potential exposure. Wear eye/face protection such as chemical splash proof goggles or face shield.Skin Protection:Prevent contamination of skin or clothing when removing protective equipment. Wear impermeable gloves and suitable protective clothing.Hand Protection:Wear protective gloves. Recommendations are listed below. Other protective materials may be used based on user's own risk assessment. Barrier creams may help to protect the exposed areas of the skin, they should however not be applied once exposure has occurred. Replace gloves immediately when torn or any change in appearance (dimension, color, flexibility etc.) is noticed.Gloves for short term exposure:Laminated multilayer gloves, break through time: > 60 minNitrile rubber (NBR), thickness: > 0.56 mm, break through time: < 60 minThe chemical resistance depends on the type of product and amount of product on the glove. Therefore gloves need to be changed when in contact with chemicals.Not suitable gloves:Latex glovesDue to many conditions (e.g. temperature, abrasion) the practical usage of a chemical protective glove in practice may be much shorter than the permeation time determined through testing.Additional Advice:Food, beverages, and tobacco products should not be carried, stored, or consumed where this material is in use. Before eating, drinking, or smoking, wash face and hands thoroughly with soap and water.−⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−− Exposure Limit(s)No values have been established.−⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−− 9. PHYSICAL AND CHEMICAL PROPERTIESColor:clear colorless to pale yellowAppearance:liquidOdor:ester acrylateBoiling Point:>100 °CMelting Point:Not availableVapor Pressure:<1.33hPa @ 20 °CSpecific Gravity/Density: 1.11 g/cm3Vapor Density:Not availablePercent Volatile (% by wt.):<0.3 %pH: Not availableSaturation In Air (% By Vol.):Not availableEvaporation Rate:Not availableSolubility In Water:Not availableVolatile Organic Content:Not availableFlash Point:>100 °C 212 °F Cleveland Open CupFlammable Limits (% By Vol):Not applicableAutoignition Temperature:Not availableDecomposition Temperature:Not availablePartition coefficient (n-octanol/water):Not availableOdor Threshold:Not available_____________________________________________________________________________ 10. STABILITY AND REACTIVITYStability:StableConditions To Avoid:Avoid exposure to strong UV sources. Avoid friction with temperature increase asresult. Avoid direct contact with heat sources. Avoid temperatures higher than 60°C.Protect from direct sunlight.Polymerization:May occurConditions To Avoid:Hazardous polymerization can occur when exposed to direct sunlight. Hazardousexothermic polymerization can occur when heated. Uncontrolled polymerization maycause rapid evolution of heat and increase in pressure that could result in violentrupture of sealed storage vessels or containersMaterials To Avoid:Avoid contact with oxidizing agents.Avoid contact with acids and alkali''s.Avoid free radical producing initiators.Avoid contact with reactive metals.Avoid contact with peroxides.Unintentional contact with them should be avoided.They give an exothermic reaction with the product.Hazardous Decomposition Products:oxides of carbon hydrocarbons−⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−− 11. TOXICOLOGICAL INFORMATION11. TOXICOLOGICAL INFORMATIONToxicological information for the product is found under Section 2. HAZARDS IDENTIFICATION.Toxicological information on the regulated components of this product is as follows:Trimethylolpropane triacrylate has acute oral (rat) LD50 and acute dermal (rabbit) LD50 values of 5760 mg/kg and 7050 mg/kg, respectively. Direct contact with this material may cause moderate eye and skin irritation. Repeated or prolonged skin contact may cause allergic skin reactions. Results of in vitro mutagenicity testing for trimethylolpropane triacrylate are mixed with both positive and negative findings. Trimethylolpropane triacrylate may cause mutagenic eefects based on in vitro studies. However, a more definitive in vivo study indicates trimethylolpropane triacrylate is not mutagenic (non-genotoxic). Additionally, in a long-term bioassay in which trimethylolpropane triacrylate was applied dermally to mice, trimethylolpropane triacrylate was determined to be non-carcinogenic. Therefore, the weight of the evidence of various genotoxicity (mutagenicity) test results leads to the conclusion that trimethylolpropane triacrylate is not mutagenic.In January 2013, the National Toxicology Program (NTP) released their final report regarding the toxicology and carcinogenesis studies of Trimethylolpropane triacrylate (TMPTA). The report indicates that there was some evidence of carcinogenic activity of TMPTA in a 2-year dermal study that was conducted in rodents. At least one or more of the findings are notably specific to rodents and should have no relevance to humans. The other findings are believed by some experts to be inappropriately related to the treatment with TMPTA. Further investigation of the findings in this study is ongoing.California Proposition 65 Warning (applicable in California only) - This product contains (a) chemical(s) known to the State of California to cause birth defects or other reproductive harm._____________________________________________________________________________ 12. ECOLOGICAL INFORMATIONThe ecological properties of this material have not been fully investigated.ECOTOXICITYNot availableBIOACCUMULATIVE POTENTIALNot availablePERSISTENCE AND DEGRADABILITYNot availableMOBILITY IN SOILNot availableOTHER ADVERSE EFFECTSHAZARD TO THE OZONE LAYERNot available13. DISPOSAL CONSIDERATIONS13. DISPOSAL CONSIDERATIONSThe information on RCRA waste classification and disposal methodology provided below applies only to the product, as supplied. If the material has been altered or contaminated, or it has exceeded its recommended shelf life, the guidance may be inapplicable. Hazardous waste classification under federal regulations (40 CFR Part 261 et seq) is dependent upon whether a material is a RCRA "listed hazardous waste" or has any of the four RCRA "hazardous waste characteristics." Refer to 40 CFR Part 261.33 to determine if a given material to be disposed of is a RCRA "listed hazardous waste"; information contained in Section 15 of this MSDS is not intended to indicate if the product is a "listed hazardous waste." RCRA Hazardous Waste Characteristics: There are four characteristics defined in 40 CFR Section 261.21-61.24: Ignitability, Corrosivity, Reactivity, and Toxicity. To determine Ignitability, see Section 9 of this MSDS (flash point). For Corrosivity, see Sections 9 and 14 (pH and DOT corrosivity). For Reactivity, see Section 10 (incompatible materials). For Toxicity, see Section 3 (composition). Federal regulations are subject to change. State and local requirements, which may differ from or be more stringent than the federal regulations, may also apply to the classification of the material if it is to be disposed. The Company encourages the recycle, recovery and reuse of materials, where permitted, as an alternate to disposal as a waste. The Company recommends that organic materials classified as RCRA hazardous wastes be disposed of by thermal treatment or incineration at EPA approved facilities.The Company has provided the foregoing for information only; the person generating the waste is responsible for determining the waste classification and disposal method.−⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−− 14. TRANSPORT INFORMATIONThis section provides basic shipping classification information. Refer to appropriate transportation regulations for specific requirements.US DOTDangerous Goods? Not applicable/Not regulatedTRANSPORT CANADADangerous Goods? Not applicable/Not regulatedICAO / IATADangerous Goods? Not applicable/Not regulatedIMODangerous Goods? Not applicable/Not regulated_____________________________________________________________________________ 15. REGULATORY INFORMATIONInventory InformationUnited States (USA): All components of this product are included on the TSCA Chemical Inventory or are not required to be listed on the TSCA Chemical Inventory.Canada: All components of this product are included on the Domestic Substances List (DSL) or are not required to be listed on the DSL.European Economic Area (including EU): When purchased from an Allnex legal entity based in the EEA (EU or Norway), this product is compliant with the registration of the REACH Regulation (EC) No. 1907/2006 as all its components are either excluded, exempt, pre-registered and/or registered.Australia: All components of this product are included in the Australian Inventory of Chemical Substances (AICS) or are not required to be listed on AICS.China: All components of this product are included on the Chinese inventory or are not required to be listed on the Chinese inventory.Japan: All components of this product are included on the Japanese (ENCS) inventory or are not required to be listed on the Japanese inventory.Korea: All components of this product are included on the Korean (ECL) inventory or are not required to be listed on the Korean inventory.Philippines: All components of this product are included on the Philippine (PICCS) inventory or are not required to be listed on the Philippine inventory.Switzerland: All components of this product are exempt from the new substance notification requirements for Switzerland (SR 813.11 art. 16-17).OTHER ENVIRONMENTAL INFORMATIONThe following components of this product may be subject to reporting requirements pursuant to Section 313 of CERCLA (40 CFR 372), Section 12(b) of TSCA, or may be subject to release reporting requirements (40 CFR 307, 40 CFR 311, etc.) See Section 13 for information on waste classification and waste disposal of this product.This product does not contain any components regulated under these sections of the EPAPRODUCT HAZARD CLASSIFICATION UNDER SECTION 311 OF SARA•Acute•Reactivity_____________________________________________________________________________ 16. OTHER INFORMATIONNFPA Hazard Rating (National Fire Protection Association)Health: 2 - Materials that, under emergency conditions, can cause temporary incapacitation or residual injury.Fire: 1 - Materials that must be preheated before ignition can occur.Instability: 1 - Materials that in themselves are normally stable, but that can become unstable at elevatedtemperatures and pressures.Reasons For Issue:Company address changedDate Prepared:01/31/2014Date of last significant revision:06/01/2013−⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−−Prepared By: Product Stewardship & Regulatory Affairs Department, /contact −⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−− This information is given without any warranty or representation. We do not assume any legal responsibility for same, nor do we give permission, inducement, or recommendation to practice any patented invention without a license. It is offered solely for your consideration, investigation, and verification. Before using any product, read its label.−⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯−−。

材料员、仓管员必懂知识问答指南,仓库管理的基础知识 - 仓库管理员

材料员、仓管员必懂知识问答指南（除把握一般员工和治理人员需知内容外，仓管员还需把握以下内容）1、仓库有哪些易燃、易爆物品，是如何进行治理的？答：有气瓶、油漆和煤气、柴油等危险品，按照公司的《危险化学品治理规定》进行治理的，常常进行例行检查。

2、仓库防火有哪些要求？答：（1）、库房的危险品应分类存放，存放量不宜过多，且应有专用库房。

（2）、仓库内设备包装用的易燃物应及时进行清理。

（3）、仓库电源线路应常常进行检查，下班时应断开总电源。

（4）、仓库区域应有明显的禁火标志，仓库内应禁止烟火。

（5）、仓库区应有足够的灭火器材，并摆放在明显、易取处。

（6）、仓库人员应进行消防知识的学习培训。

3、怎样使用灭火器？答：（1）、二氧化碳灭火器：不导电，适用于扑救电气、精密仪器、油类和酸类火灾。

不能扑救钾、钠、镁等物质火灾；使用方法：使用时拿好喇叭筒对着火源（手不能直接抓住喷嘴以免冻伤），另一只手打开开关即可；注重事项：二氧化碳有窒息作用在室外使用时，应该选择在上风方向喷射，在室内使用时，灭火后要迅速离开；（2）、干粉灭火器：不导电，扑救电气设备火灾，而不宜扑救旋转电机火灾。

可扑救石油、石油产品、有机溶剂、天然气和天然气设备火灾；使用方法：提起拉环对准火源即可；注重事项：不能在离火源很远的地方就开启灭火器，要尽可能在靠近火源时开启；（3）、泡沫灭火器：因为有一定的水分因此具有导电性，适用于扑救油类或其他易燃液体火灾，不适用于扑灭电气火灾；使用方法：倒过来稍加摇摆或打开开关，药剂即喷出；注重事项：在使用时筒盖和筒底不能朝人身，防止发生意外爆炸时时筒盖、筒底飞出伤人。

4、仓库产品的防护治理要求有哪些？答：具体见《仓储和产品防护控制程序》中的要求。

5、废弃物品是如何进行治理的？答：按照公司《环境和职业健康安全运行控制程序》中固态废弃物控制和《危险化学品治理规定》的要求进行控制，具体翻阅这两份文件的要求。

6、仓库帐物卡是否一致？答：要做好物质的盘点工作，帐和物要对的上，有变化时要及时更新。

EM Science SUPRAPUR

MATERIAL SAFETY DATA SHEET (MSDS)Click here for the French version / Appuyer ici pour la version françaiseMaterial Safety Data Sheet Section 1. Product and Company Identification Product Name Ammonium Dihydrogen Phosphate, SUPRAPUR ®Product Code 1440Manufacturer EM Science A Division of EM IndustriesP.O. Box 70480 Democrat RoadGibbstown, N.J. 08027Effective Date10/29/2001For More Information Call In Case of Emergency Call 856-423-6300 Technical Service Monday-Friday: 8:00 AM - 5:00 PM 800-424-9300 CHEMTREC (USA)613-996-6666 CANUTEC (Canada)24 Hours/Day: 7 Days/Week Synonym AMMONIUM DIHYDROGEN PHOSPHATE Material Uses Analytical reagent.Chemical Family Inorganic salt.Section 2. Composition and Information on Ingredients ComponentCAS #% by Weight AMMONIUM PHOSPHATE, MONOBASIC 7722-76-1100Section 3. Hazards Identification Physical State and Appearance Solid. (Crystals solid. Granular solid.)Emergency Overview CAUTION!Handling care generally in keeping with safe laboratory practices is recommended.Routes of Entry Inhalation. Ingestion.Potential Acute Health Effects Eyes No known acute effects of this product resulting from eye contact.Skin No known acute effects of this product resulting from skin contact.Inhalation No known acute effects of this product resulting from inhalation.Ingestion No known acute effects of this product resulting from ingestion.Potential Chronic Health Effects Carcinogenic Effects This material is not known to cause cancer in animals or humans.Additional information See Toxicological Information (section 11)Medical Conditions Aggravated byOverexposure:Repeated or prolonged exposure is not known to aggravate medical condition.Section 4. First Aid Measures Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plentyof water for at least 15 minutes. Cold water may be used. Get medical attention.Skin Contact In case of contact, immediately flush skin with plenty of water. Remove contaminated clothingand shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes beforereuse. Get medical attention.Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing isdifficult, give oxygen. Get medical attention.Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything bymouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband.Section 5. Fire Fighting MeasuresFlammability of theProduct Non-flammable.Auto-ignitionTemperature Not applicable.Flash Points Not applicable.Flammable Limits Not applicable.Products of Combustion Not available.Fire Hazards inPresence of VariousSubstances Not applicable.Explosion Hazards inPresence of VariousSubstances Risks of explosion of the product in presence of static discharge: No.Risks of explosion of the product in presence of mechanical impact: No.Fire Fighting Mediaand Instructions Not applicable.Protective Clothing(Fire)Not applicable.Special Remarks on FireHazards Not available.Special Remarks onExplosion Hazards Not available.Section 6. Accidental Release Measures Small Spill and Leak Use appropriate tools to put the spilled solid in a convenient waste disposal rge Spill and Leak Use a shovel to put the material into a convenient waste disposal container. Finish cleaning byspreading water on the contaminated surface and allow to evacuate through the sanitary system.Spill Kit Information No specific spill kit required for this product.Section 7. Handling and Storage Handling Avoid breathing dust. Do not ingest. Do not get in eyes, on skin, or on clothing.Storage Keep container in a cool, well-ventilated area.Section 8. Exposure Controls/Personal Protection Engineering Controls Use process enclosures, local exhaust ventilation, or other engineering controls to keep airbornelevels below recommended exposure limits. If user operations generate dust, fume or mist, useventilation to keep exposure to airborne contaminants below the exposure limit.Personal Protection Eyes Safety glasses.Body Lab coat.Respiratory Not applicable.Hands Not applicable.Feet Not applicable.Personal Protection in Case of a Large Spill Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient;consult a specialist BEFORE handling this product.Product Name Exposure Limits AMMONIUM PHOSPHATE,MONOBASIC Not available.Section 9. Physical and Chemical Properties Odor Odorless.Color White.Physical State and Appearance Solid. (Crystals solid. Granular solid.)Molecular Weight Not available.Molecular Formula H3N.H3O4P pH Not available.Boiling/Condensation Point Not available.Melting/Freezing Point Not available.Specific Gravity Not available.Vapor Pressure Not available.Vapor Density Not available.Odor Threshold Not available.Evaporation Rate Not available.LogKow Not available.Solubility Soluble in water.Section 10. Stability and Reactivity Stability and Reactivity The product is stable.Conditions of Instability Not available.Incompatibility with Various Substances Not available.Rem/Incompatibility Not available.Hazardous Decomposition Products Not available.Hazardous Polymerization Will not occur.Section 11. Toxicological Information Ammonium Phosphate, Monobasic, GR Not available.RTECS Number:Toxicity LD50: Not available.LC50: Not available.Chronic Effects on Humans Not available.Acute Effects on Humans Not available.Synergetic Products (Toxicologically)Not available.Irritancy Draize Test: Not available.Sensitization Not available.Carcinogenic Effects This material is not known to cause cancer in animals or humans.Toxicity to Reproductive System Not available.Teratogenic Effects Not available.Mutagenic Effects Not available.Section 12. Ecological Information Ecotoxicity Not available.BOD5 and COD Not available.Toxicity of the Products of Biodegradation The product itself and its products of degradation are not toxic.Section 13. Disposal Considerations EPA Waste Number Not available.Treatment Material does not have an EPA Waste Number and is not a listed waste, however consultationwith a permitted waste disposal site (TSD) should be accomplished. Always contact a permitted waste disposal (TSD) to assure compliance with all current local, state, and Federal Regulations.Section 14. Transport Information DOT Classification Not available.TDG Classification Not available.IMO/IMDG Classification Not available.ICAO/IATA Classification Not available.Section 15. Regulatory Information U.S. Federal Regulations TSCA 8(b) inventory: AMMONIUM PHOSPHATE, MONOBASICSARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: No products were found.SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No productswere found.SARA 313 toxic chemical notification and release reporting: AMMONIUM PHOSPHATE,MONOBASICClean Water Act (CWA) 307: No products were found.Clean Water Act (CWA) 311: No products were found.Clean air act (CAA) 112 accidental release prevention: No products were found.Clean air act (CAA) 112 regulated flammable substances: No products were found.Clean air act (CAA) 112 regulated toxic substances: No products were found.WHMIS (Canada)Not controlled under WHMIS (Canada).CEPA DSL: AMMONIUM PHOSPHATE, MONOBASICInternationalRegulationsEINECS AMMONIUM PHOSPHATE, MONOBASIC 231-764-5DSCL (EEC)This product is not classified according to the EU regulations.InternationalListsAustralia (NICNAS): AMMONIUM PHOSPHATE, MONOBASICJapan (MITI): AMMONIUM PHOSPHATE, MONOBASICKorea (TCCL): AMMONIUM PHOSPHATE, MONOBASICPhilippines (RA6969): AMMONIUM PHOSPHATE, MONOBASICChina: No products were found.State Regulations No products were found.California prop. 65: No products were found.Section 16. Other InformationNational FireProtection Association(U.S.A.)Health0Fire Hazard00ReactivitySpecific HazardChanged Since Last Revision +Notice to ReaderThe statements contained herein are based upon technical data that EM Industries believes to be reliable, are offered for information purposes only and as a guide to the appropriate precautionary and emergency handling of the material by a properly trained person having the necessary technical skills. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use, storage and disposal of these materials and the safety and health of employees and customers and the protection of the environment. EM INDUSTRIES MAKES NO REPRESENTATION OR WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE, WITH RESPECT TO THE INFORMATION HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS.。

Sentry MSDS 112613 - Norac Concepts Inc. - 农业非离子表面

Material Safety Data SheetSentryDate issued: 11/26/2013 (m/d/y) 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONProduct name: SentryNorac Concepts Inc.P.O. Box 31097, Guelph, ON N1H 8K1519-821-3633Emergency telephone number: All hours, 613-787-5620, ONLY for health and environmental information.2. COMPOSITION/INFORMATION ON INGREDIENTSSynonyms: None knownChemical name: Nonyl phenol ethoxylatesProduct use: Agricultural non-ionic surfactantRegistration number: 28343Pest Control Products Act3. HAZARDS IDENTIFICATIONSummary: Hazardous properties of all ingredients have been considered in the preparation of this MSDS. Read the entire MSDS for the complete hazard evaluation of this product.Emergency overview: May cause eye damage. May cause mild irritation to the skin and respiratory system.4. FIRST AID MEASURESInhalation: Move victim to fresh air. Give artificial respiration ONLY if breathing has stopped. Give cardiopulmonary resuscitation (CPR) if there is no breathing AND no pulse. Obtain medical advice IMMEDIATELY.Skin contact: Flush skin with running water for a minimum of 20 minutes. Start flushing while removing contaminated clothing. If irritation persists, repeat flushing. Obtain medical attention IMMEDIATELY.Eye contact: Immediately flush eyes with running water for a minimum of 20 minutes. Hold eyelids open during flushing. If irritation persists, repeat flushing. Obtain medical attention IMMEDIATELY.Ingestion: If victim is alert and not convulsing, rinse mouth out and give 200-300 mL (1 cup) of water to dilute material. If spontaneous vomiting occurs, have victim lean forward with head down to avoid breathing in of vomitus, rinse mouth and administer more water. Obtain medical attention IMMEDIATELY.5. FIRE AND EXPLOSION HAZARD DATAFlash point: >42°C (TCC)Autoignition temperature: >360°CFlammable limits (lower): 1.8%Flammable limits (upper): 10.6%Extinguishing media: For large fires, apply aqueous film-forming foam or water in the form of a fog. For small fires, use carbon dioxide or dry chemical. Water stream may spread flames.Fire-fighting procedures: Wear self-contained breathing apparatus and impervious clothing. Minimize the amount of water used and contain the run-off from entering water supplies or the environment by dyking. Fire-exposed containers should be kept cool by spraying with water to reduce pressure.Other fire and explosion hazards: None known.T 519-821-3633 F 519-821-20836. ACCIDENTAL RELEASE MEASURESSpills, leaks or releases: Wear personal protective equipment. For release to land, stop any further release and spread of contamination and absorb spilled material with a suitable absorbent. Wash hard surfaces with detergent and water, then absorb with suitable absorbent. For release to water, stop any further release and utilize damming and/or water diversion to minimize the spread of contamination. Collect the spilled material, any contaminated soil, water and absorbent, then place in a waste container for proper disposal. Notify applicable government authority if release is reportable or could adversely affect the environment.Deactivating chemicals: None known.7. HANDLING AND STORAGE INFORMATIONHandling procedures: Use only with adequate ventilation and avoid contact with eyes, skin and clothing. Wear appropriate personal protective equipment. Wash thoroughly after use. If clothing becomes contaminated, wash thoroughly before reuse. Spilled material maybe slippery, clean up spills immediately before walking in spill area. Storage requirements: Store in a cool, dry and well-ventilated area. Keep away from heat, sparks and flame. Keep containers closed. Keep out of reach of children and pets.Storage temperature: Do not expose to temperatures above 40°C. Keep from freezing.8. EXPOSURE CONTROLS/PERSONAL PROTECTIONEye protection: Chemical safety goggles.Skin protection: Chemical-resistant gloves and protective clothing should be impervious under conditions of use Respiratory protection: If misting conditions exist, use NIOSH/MSHA-approved respirator for organic vapours. Other protective equipment: None required.Engineering controls: Provide local exhaust or ventilation.9. PHYSICAL AND CHEMICAL PROPERTIESAppearance: Clear colourless liquidOdour: Mild sweet odourSpecific gravity: 0.975 at 20°CBoiling point: No dataMelting point: >20°CSolubility (water): Slightly solubleSolubility (other): No datapH: 6.0 to 6.5% volatile: <10%Evaporation rate (ether=1): Not determinedVapour pressure (mm Hg at 20°C): No dataVapour density (air=1): No data10. STABILITY AND REACTIVITY DATAChemical stability: Stable under normal conditions.Hazardous polymerization: Will not occur.Conditions to avoid: Sources of extreme heat or ignition and prolonged storage at temperatures above 40°C. Incompatibility with other substances: Strong oxidizing agents.Hazardous decomposition products: Oxides of carbon and possibly irritating gases.11. TOXICOLOGICAL INFORMATIONSummary: May cause eye damage. May cause mild irritation to the skin and respiratory system.Toxicological dataIsobutanolOral LD50 (rat) = 2460 mg/kgDermal LD50 (rabbit) = 4240 mg/kgInhalation LC50 (rat) = 8000 ppm for 4hrInhalation: High concentrations of mist may cause slight irritation of the nose, throat and respiratory system.Skin contact: Prolonged and repeated exposure may cause irritation.Eye contact: May cause eye damage. Can cause redness and tissue damage.Ingestion: Low acute oral toxicity. May cause irritation to the gastrointestinal tract.Chronic effects: Skin contact may aggravate pre-existing skin conditions. Inhalation of mists may aggravate pre-existing respiratory conditions.Carcinogenicity: The ingredients in this product are not classified as carcinogenic by the ACGIH, IARC, OSHA and the NTP.12. ECOLOGICAL INFORMATIONEcotoxicological information: May be harmful to aquatic life.Environmental effects: Do not contaminate domestic or irrigation water supplies, lakes, streams, ponds, or rivers. Persistence and degradation: The product is substantially biodegradable in water.13. DISPOSAL CONSIDERATIONSDispose of waste material at an approved (hazardous) waste treatment/disposal facility in accordance with applicable local, provincial and federal regulations. Do not dispose of waste with normal garbage or to sewer systems.14. TRANSPORT INFORMATIONTDG classification: Not regulated.Transportation emergency telephone number: 613-787-5620.15. REGULATORY INFORMATIONWHMIS classification: This product is registered under the Pest Control Product Act and is exempt from the requirements of WHMIS.16. OTHER INFORMATIONThe information contained herein is offered only as a guide to the handling of this specific material and has been prepared in good faith by technically knowledgeable personnel. It is not intended to be all-inclusive and the manner and conditions of use and handling may involve other and additional considerations. No warranty of any kind is given or implied and Norac Concepts Inc. will not be liable for any damages, losses, injuries or consequential damages which may result from the use of or reliance on any information contained herein. This Material Safety Data Sheet is valid for three years.Prepared by: Norac Concepts Inc.。