GHS分类测试报告---丁酮肟 甲乙酮肟 防结皮剂

化学品分类检验记录单样品名称：丁酮肟报验编号：21201303407 样品编号：201338722检验项目：化学品分类&GHS检验依据：联合国《关于危险货物运输的建议书》(UN)；国际海事组织《国际海运危险货物规则》(IMO)；国际航空运输协会《危险品规则》(IATA)；《危险化学品名录》(2002年版)记录见附页：湖北出入境检验检疫局技术中心货物运输条件鉴定书Hubei Entry-Exit Inspection and Quarantine Bureau of P.R.CCertification for Safe Transport of Dangerous Goods样品编号(Sample Number)：201338722申报品名Name of Goods中文Chinese丁酮肟(甲乙酮肟)英文EnglishEthyl methyl ketone oxime分子式Molecular formulaC4H9NO申请单位Applicant湖北仙粼化工有限公司Hubei Xianlin Chemical Industry Co., Ltd.生产单位Manufacturer湖北仙粼化工有限公司Hubei Xianlin Chemical Industry Co., Ltd.样品外观与性状Appearance and property无色透明液体Colorless transparent liquid主要危险性Main Danger3 次要危险性Subsidiary Danger无正确运输名称Proper Shipping Name易燃液体，未另列名(丁酮肟) Flammable liquid, n.o.s. (Ethyl methyl ketone oxime)CAS登记号CAS Register NumberC4H9NO : 96-29-7危险性类别Class or Division3联合国编号UN NumberUN 1993包装类别Packing GroupⅢ检测鉴定依据Warranty of Test 联合国《关于危险货物运输的建议书》，《Recommendations on the Transport of Dangerous Goods》(UN)；国际海事组织《国际海运危险货物规则》，《International Maritime Dangerous Goods》(IMO)；国际航空运输协会《危险品规则》，《Dangerous Goods Regulation》(IATA)；《危险化学品名录》(2002年版)，《The List of Dangerous Chemicals》(2002 Edition)。

特别声明Special Statements 委托人自送样品。

本鉴定书适用于货物的公路运输、航空运输和海洋运输，原件有效期至2014年12月13日The client submits the sample. Certification for Safe Transport of Dangerous Goods applies to cargo road transport, air transport and marine transport, the term of validity to Dec.13 2014爆炸危险性鉴定Determination for Explosive Danger 该货物无爆炸危险性NONE易燃危险性鉴定Determination for Flammable Danger该货物有易燃危险性The goods have Flammable Danger氧化危险性鉴定Determination for Oxidizing Danger 该货物无氧化危险性NONE毒害与感染危险性鉴定Determination for Toxic & Infectious Danger 该货物无毒害性，无感染危险性NONE放射性危险性鉴定Determination for Radioactive Danger 该货物无放射性危险性NONE腐蚀危险性鉴定Determination for Corrosive Danger 该货物无腐蚀危险性NONE其它危险性鉴定Determination for Other Dangers 该货物无其它危险性NONE理化性质Physical & ChemicalProperties 样品主要成份为丁酮肟(≥99.5%)(The sample main ingredient is Ethyl methyl ketone oxime)；分子式(Molecular Formula)：C4H9NO；分子量(Molecular Weight)：87.12g/mol；熔点(Melting Point)：-30°C；沸点(Boiling Point)：152°C；闪点(Flash point)：60°C(闭杯法Closed Cup)；密度(Density)：0.92g/ml(20°C)；折射率(Refractive index)n20/D：1.44；水溶性(Water Solubility)：110g/L(20°C)；敏感性(Sensitive)：对热敏感(Sensitivity to heat)；稳定性(Stability)：常温常压下稳定，易燃液体，按照规定使用和储存不会发生反应，与强氧化剂、强酸、强碱和过氧化物等不相容，与强酸混合可能发生爆炸，与硫酸反应生成易爆物质(This material is stable under normal temperatures and pressures. Flammable liquid. No reaction if used and stored according to specifications. Incompatible with strong oxidizing agents, strong acids, strong bases, peroxides etc. Mixtures with strong acids may explode. Reacts with sulfuric acid to form an explosive product.)；无色透明液体。

可溶于水，混溶于醇类和醚类等。

广泛用于涂料、油漆及油墨防结皮剂，异氰酸酯封闭剂，有机硅交联剂，有机合成中间体等。

Colorless transparent liquid. Soluble in water. Miscible with alcohol and ether. Widely used in coating, paint and ink anti skinning agent, cross-linking agent, isocyanate sealant, silicone intermediates in organic synthesis etc.鉴定货物在贮存、运输中的危险性分析Analysis of Dangerous Properties For Goods in storage and Transport 处理措施：不使用时保持容器密闭，避免与眼睛、皮肤和衣物相接触。

防止吸入蒸汽和烟雾。

避免摄取和吸入。

使用前需要获得专门的指导，仅按照指导使用。

确保工作区有良好的通风或排气装置，仅在通风良好之处使用。

一般性的防火保护措施。

严禁烟火。

切勿靠近热源和火源。

采取措施防止静电积聚。

空容器可能含有残留物，不要重新使用或损坏空容器。

处理及打开容器时，必须小心。

根据工业卫生和安全使用规则来操作。

物质转移时容器应接地。

使用防火花和防爆工具。

不要把空容器暴露在热、火花或明火中。

禁止增压、切割、焊接、铜焊、焊锡、钻、研磨或使空容器暴露于热、火花、明火中或接触着火源。

防范蒸汽达到可爆炸的浓度。

严禁沾染到皮肤或进入眼睛，避免直接或长期反复接触皮肤和眼睛。

储藏方法：正常条件下运输和处置稳定。

不使用时保持容器密封。

储存于阴凉、干燥、通风的远离不能共存物质的防火区域。

在正常状态下储存与使用不会发生危险化学反应。

惰性气体下操作和储存。

避免阳光直射和水分或潮湿。

远离热源、火焰、火花和极端的温度储存。

远离强酸、强氧化剂、强碱、过氧化物、易燃物质、有机材料、活泼非金属等。

应与食用化学品分开存放。

打开了的容器必须仔细重新封口并保持竖放位置以防止泄漏。

储区应备有合适的材料收容泄漏物。

配备相应品种和数量的消防器材及泄漏应急处理设备。

运输信息：运输时运输车辆应配备相应品种和数量的消防器材及泄漏应急处理设备。

夏季最好早晚运输。

运输时所用的槽(罐)车应有接地链，槽内可设孔隔板以减少震荡产生静电。

严禁与强酸、强碱、氧化剂、易燃物质、活泼非金属、食用化学品等混装混运。

运输途中应防曝晒、雨淋，防高温。

中途停留时应远离火种、热源、高温区。

装运该物品的车辆排气管必须配备阻火装置，禁止使用易产生火花的机械设备和工具装卸。

公路运输时要按规定路线行驶，勿在居住区和人口稠密区停留。

Handing: Keep containers closed when not in use. Avoid contact with skin, eyes and clothing. Avoid inhalation of vapor or mist. Avoidingestion and inhalation. Obtain special instructions before use, useonly as directed. Ensure good ventilation at the workplace, use onlyin a well ventilated area. Normal measures for preventive fireprotection. No smoking. Keep away from heat and sources ofignition. Take measures to prevent the buildup of electrostaticcharge. Empty containers may contain product residue. Do notreuse and damage empty container. Handle and open container withcare. Handle in accordance with good industrial hygiene and safetypractice. Ground and bond containers when transferring material.Use spark-proof tools and explosion proof equipment. Do notexpose empty containers to heat, sparks or open flames. Do notpressurize, cut, weld, braze, solder, drill, grind, or expose emptycontainers to heat, sparks, open flames or sources of ignition.Prevent build up of vapors to explosive concentration. Do not geton skin or in eyes. Avoid direct, prolonged or repeated contact withskin and eyes.Storage: Stable under normal shipping and handling conditions. Keep container tightly sealed when not in use. Store in a cool, dry, well-ventilatedand fireproof storage place away from incompatible substances.Under normal conditions of storage and use, hazardous or reactionswill not occur. Handle and store under inert gas. Avoid directsunlight and damp or water/moisture. Store away from heat, flames,sparks and extremes of temperature. Keep away from strong acids;strong oxidizers, strong bases, peroxides, flammable substances,organic materials, active nonmetal etc. Stored away from foodchemicals. Containers which are opened must be carefully resealedand kept upright to prevent leakage. Storage areas should beequipped with appropriate materials containing leakage. Equippedwith suitable variety and quantity of firefighting equipment andemergency leakage treatment equipment.Transport: Transport vehicles shall be equipped with suitable variety and quantity of firefighting equipment and emergency leakage treatmentequipment. It is recommended to transport in the morning andevening in summer months. The tank truck should be equipped witha grounding chain. Install orifice plate in tank to reduce staticcaused by shock. Do not transport with strong acids, strong bases,strong oxidizers, flammable substances, active nonmetal, foodchemicals etc. Keep away from sun, rain and high temperatureduring transport. Keep away from ignition, heat sources and hotplaces during rest stops. The exhaust pipe on the vehicle must be equipped with a fireproof device. Do not load and unload with mechanical equipment and tools which create sparks easily. Use major routes when transporting by road. Do not travel though residential and densely-populated areas.急救措施First-aid Measures 一般建议：请教医生。