BASF光稳定剂,紫外线吸收剂的应用介绍
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BASF Innovative Benefits of polyolefin stabilisation 0703YM 2
Topics 主题
1.Light-stabilization 光稳定－光稳定能给予更多 - more than light-stabilization 2.High thermal stability, low volatility 高热稳定和低挥发性 3.High compatibility with polyolefin与聚烯烃的高相容性 4.Low water carry-over低带水性 5.High resistance to extraction对于抽提的高抵抗力 6.Low interaction to processing aids与加工助剂低的相互作用 7.Low interaction to acidic environments与酸性环境的低反应 性
0,126% HALS 1 0,084% HALS 2 Outdoor-Exposure: Limburgerhof, Germany 45° South
BASF Innovative Benefits of polyolefin stabilisation 0703YM
8
Outdoor exposure – 4 yrs in co-block PP 嵌段共聚PP经过四年户外曝晒
What additional and innovative benefits can be brought to each step of the value-chain manufacturing process to achieve optimization of - cost-performance, - environmental friendliness e.g. Responsible Care® ? 什么额外的，创新的利益可以带给价值链制造过程的每一步，从而达到最佳的价值表现 和良好环境（如责任关怀® ）
Tensile strength at break 断裂拉伸强度
120.0 % Tensile strength at break
Increase of 增加>10％ > 10%
110.0
100.0
Increase of 增加5％ 0.5%
断裂拉伸强度％
90.0 PP PP+HMW HALS
PP + Uvinul 5050H PP+Uvinul 5050H
FDA 认证 compliant
*softening temp软化温度
* +155oC – +158oC
BASF Innovative Benefits of polyolefin stabilisation 0703YM 5
Topics 主题
1.Light-stabilization 光稳定－光稳定能给予更多 - more than light-stabilization 2.High thermal stability, low volatility 高热稳定和低挥发性 3.High compatibility with polyolefin与聚烯烃的高相容性 4.Low water carry-over低带水性 5.High resistance to extraction对于抽提的高抵抗力 6.Low interaction to processing aids与加工助剂低的相互作用 7.Low interaction to acidic environments与酸性环境的低反应 性
10
Random copol-PP with HALS 加入受阻胺光稳定剂的无规共聚PP
Elongation at break断裂延伸率
160.0
增加>35％
% elongation strength at break
Increase of > 35%
120.0
80.0
40.0
0.0 PP PP+HMW HALS
polymer producer 聚合物生 产商
compounder, masterbatcher 混合物，母粒 生产商
Converter 转换商
*Automotive (exterior / interior) 汽车（内外饰件） *Agriculture 农业 *Packaging 包装 *Construction 建筑 *Textiles 纺织
BASF Innovative Benefits of polyolefin stabilisation 0703YM 7
Green pigmented garden chairs after 4 years outdoor exposure 涂有绿色颜料的花园椅经过四年户外曝晒
0,126% Uvinul 4050H 0,084% Uvinul 5050H
0.05% HALS
The information submitted in this publication is based on our current knowledge and experience. In view of the many factors that may affect processing and application, these data do not relieve processors of the responsibility of carrying out their own tests and experiments; neither do they imply any legally binding BASF Innovative Benefits of polyolefin stabilisation 0703YM assurance of certain properties or of suitability for a specific purpose. It is the responsibility of those to whom we supply our products to ensure that any proprietary rights and existing laws and legislation are observed.
BASF Innovative Benefits of polyolefin stabilisation 0703YM 6
Light-stabilisation of PP tapes PP编织带的光稳定
厚度 41微米
厚度：47微米 厚度 47微米
剩余拉伸强度（％）
厚度 43微米
小时，Xenontest 1200, DIN 53387, 旋转模式，黑板温度63-67
BASF Innovative Benefits of polyolefin stabilisation 0703YM 4
Properties of Uvinul 4050H Uvinul 4050H 的性能
*sterically hindered amine空间位阻胺
* monomeric HALS : CAS 124172-53-8 单体受阻胺光稳定剂
BASF Innovative Benefits of polyolefin stabilisation 0703YM 3
Properties of Uvinul 505H Uvinul 5050H 的性能
*sterically hindered amine空间位阻胺
* oligomeric HALS : CAS 152261-33-1 低聚受阻胺光稳定剂
在佛罗里达经过四年户外曝晒
0.5% Uvinul 5050H 0.5% Uvinul 4050H
0.5% HALS-2 0.5%HALS-1
BASF Innovative Benefits of polyolefin stabilisation 0703YM 9
Random copol-PP with HALS 加入受阻胺光稳定剂的无规共聚PP
11
Random copol PP with HALS 加入受阻胺光稳定剂的无规共聚PP
Oxidation induction time behaviour氧化诱导时间表现
120
% O IT reten tio n
90 60
100% <70%
30 0
氧化诱导剩余％
PP
PP+HMW HALS
0.05% HALS
The information submitted in this publication is based on our current knowledge and experience. In view of the many factors that may affect processing and application, these data do not relieve processors of the responsibility of carrying out their own tests and experiments; neither do they imply any legally binding BASF Innovative Benefits of polyolefin stabilisation 0703YM assurance of certain properties or of suitability for a specific purpose. It is the responsibility of those to whom we supply our products to ensure that any proprietary rights and existing laws and legislation are observed.
Innovative benefits of polyolefin stabilization 聚稀烃的稳定带来的创新利益
BASF East Asia Dr. Yvonne Mah Manager Asia-Pacific
More than light-stabilization…. 光稳定能给予更多…
*high molecular weight 高分子量
* approx. 3500 约3500
*softening temp 软化温度
* +95oC – +125oC
FDA 认证 compliant
*heat stability 热稳定性
* > +300oC
*pale yul5050H PP+Uvinul 5050H
断裂延伸率％
0.05% HALS
The information submitted in this publication is based on our current knowledge and experience. In view of the many factors that may affect processing and application, these data do not relieve processors of the responsibility of carrying out their own tests and experiments; neither do they imply any legally binding BASF Innovative Benefits of polyolefin stabilisation 0703YM assurance of certain properties or of suitability for a specific purpose. It is the responsibility of those to whom we supply our products to ensure that any proprietary rights and existing laws and legislation are observed.
Topics 主题
1.Light-stabilization 光稳定－光稳定能给予更多 - more than light-stabilization 2.High thermal stability, low volatility 高热稳定和低挥发性 3.High compatibility with polyolefin与聚烯烃的高相容性 4.Low water carry-over低带水性 5.High resistance to extraction对于抽提的高抵抗力 6.Low interaction to processing aids与加工助剂低的相互作用 7.Low interaction to acidic environments与酸性环境的低反应 性
0,126% HALS 1 0,084% HALS 2 Outdoor-Exposure: Limburgerhof, Germany 45° South
BASF Innovative Benefits of polyolefin stabilisation 0703YM
8
Outdoor exposure – 4 yrs in co-block PP 嵌段共聚PP经过四年户外曝晒
What additional and innovative benefits can be brought to each step of the value-chain manufacturing process to achieve optimization of - cost-performance, - environmental friendliness e.g. Responsible Care® ? 什么额外的，创新的利益可以带给价值链制造过程的每一步，从而达到最佳的价值表现 和良好环境（如责任关怀® ）
Tensile strength at break 断裂拉伸强度
120.0 % Tensile strength at break
Increase of 增加>10％ > 10%
110.0
100.0
Increase of 增加5％ 0.5%
断裂拉伸强度％
90.0 PP PP+HMW HALS
PP + Uvinul 5050H PP+Uvinul 5050H
FDA 认证 compliant
*softening temp软化温度
* +155oC – +158oC
BASF Innovative Benefits of polyolefin stabilisation 0703YM 5
Topics 主题
1.Light-stabilization 光稳定－光稳定能给予更多 - more than light-stabilization 2.High thermal stability, low volatility 高热稳定和低挥发性 3.High compatibility with polyolefin与聚烯烃的高相容性 4.Low water carry-over低带水性 5.High resistance to extraction对于抽提的高抵抗力 6.Low interaction to processing aids与加工助剂低的相互作用 7.Low interaction to acidic environments与酸性环境的低反应 性
10
Random copol-PP with HALS 加入受阻胺光稳定剂的无规共聚PP
Elongation at break断裂延伸率
160.0
增加>35％
% elongation strength at break
Increase of > 35%
120.0
80.0
40.0
0.0 PP PP+HMW HALS
polymer producer 聚合物生 产商
compounder, masterbatcher 混合物，母粒 生产商
Converter 转换商
*Automotive (exterior / interior) 汽车（内外饰件） *Agriculture 农业 *Packaging 包装 *Construction 建筑 *Textiles 纺织
BASF Innovative Benefits of polyolefin stabilisation 0703YM 7
Green pigmented garden chairs after 4 years outdoor exposure 涂有绿色颜料的花园椅经过四年户外曝晒
0,126% Uvinul 4050H 0,084% Uvinul 5050H
0.05% HALS
The information submitted in this publication is based on our current knowledge and experience. In view of the many factors that may affect processing and application, these data do not relieve processors of the responsibility of carrying out their own tests and experiments; neither do they imply any legally binding BASF Innovative Benefits of polyolefin stabilisation 0703YM assurance of certain properties or of suitability for a specific purpose. It is the responsibility of those to whom we supply our products to ensure that any proprietary rights and existing laws and legislation are observed.
BASF Innovative Benefits of polyolefin stabilisation 0703YM 6
Light-stabilisation of PP tapes PP编织带的光稳定
厚度 41微米
厚度：47微米 厚度 47微米
剩余拉伸强度（％）
厚度 43微米
小时，Xenontest 1200, DIN 53387, 旋转模式，黑板温度63-67
BASF Innovative Benefits of polyolefin stabilisation 0703YM 4
Properties of Uvinul 4050H Uvinul 4050H 的性能
*sterically hindered amine空间位阻胺
* monomeric HALS : CAS 124172-53-8 单体受阻胺光稳定剂
BASF Innovative Benefits of polyolefin stabilisation 0703YM 3
Properties of Uvinul 505H Uvinul 5050H 的性能
*sterically hindered amine空间位阻胺
* oligomeric HALS : CAS 152261-33-1 低聚受阻胺光稳定剂
在佛罗里达经过四年户外曝晒
0.5% Uvinul 5050H 0.5% Uvinul 4050H
0.5% HALS-2 0.5%HALS-1
BASF Innovative Benefits of polyolefin stabilisation 0703YM 9
Random copol-PP with HALS 加入受阻胺光稳定剂的无规共聚PP
11
Random copol PP with HALS 加入受阻胺光稳定剂的无规共聚PP
Oxidation induction time behaviour氧化诱导时间表现
120
% O IT reten tio n
90 60
100% <70%
30 0
氧化诱导剩余％
PP
PP+HMW HALS
0.05% HALS
The information submitted in this publication is based on our current knowledge and experience. In view of the many factors that may affect processing and application, these data do not relieve processors of the responsibility of carrying out their own tests and experiments; neither do they imply any legally binding BASF Innovative Benefits of polyolefin stabilisation 0703YM assurance of certain properties or of suitability for a specific purpose. It is the responsibility of those to whom we supply our products to ensure that any proprietary rights and existing laws and legislation are observed.
Innovative benefits of polyolefin stabilization 聚稀烃的稳定带来的创新利益
BASF East Asia Dr. Yvonne Mah Manager Asia-Pacific
More than light-stabilization…. 光稳定能给予更多…
*high molecular weight 高分子量
* approx. 3500 约3500
*softening temp 软化温度
* +95oC – +125oC
FDA 认证 compliant
*heat stability 热稳定性
* > +300oC
*pale yul5050H PP+Uvinul 5050H
断裂延伸率％
0.05% HALS
The information submitted in this publication is based on our current knowledge and experience. In view of the many factors that may affect processing and application, these data do not relieve processors of the responsibility of carrying out their own tests and experiments; neither do they imply any legally binding BASF Innovative Benefits of polyolefin stabilisation 0703YM assurance of certain properties or of suitability for a specific purpose. It is the responsibility of those to whom we supply our products to ensure that any proprietary rights and existing laws and legislation are observed.