硝酸铁安全技术说明书英文

SAFETY DATA SHEETSAccording to Globally Harmonized System of Classification andLabelling of Chemicals (GHS) - Sixth revised edition1.Identification1.1GHS Product identifierProduct name iron(3+),trinitrate1.2Other means of identificationProduct number-Other names UNII-N8H8402XOB1.3Recommended use of the chemical and restrictions on useIdentified uses For industry use only. Agricultural chemicals(non-pesticidal),Intermediates,Plating agents and surfatreating agentsUses advised against no data available1.4Supplier's detailsCompanyAddressTelephoneFax1.5Emergency phone numberEmergency phone numberService hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMThours).2.1Classification of the substance or mixtureSkin corrosion, Category 1BSerious eye damage, Category 12.2GHS label elements, including precautionary statementsPictogram(s)Signal word DangerHazard statement(s)H314 Causes severe skin burns and eye damagePrecautionarystatement(s)Prevention P260 Do not breathe dust/fume/gas/mist/vapours/spray.P264 Wash ... thoroughly after handling.P280 Wear protective gloves/protective clothing/eyeprotection/face protection.Response P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT inducevomiting.P303+P361+P353 IF ON SKIN (or hair): Take off immediately allcontaminated clothing. Rinse skin with water [or shower].P363 Wash contaminated clothing before reuse.P304+P340 IF INHALED: Remove person to fresh air and keepcomfortable for breathing.P310 Immediately call a POISON CENTER/doctor/…P321 Specific treatment (see ... on this label).P305+P351+P338 IF IN EYES: Rinse cautiously with water for severalminutes. Remove contact lenses, if present and easy to do. Continuerinsing.Storage P405 Store locked up.Disposal P501 Dispose of contents/container to ...2.3Other hazards which do not result in classificationnone3.1Substances4.1Description of necessary first-aid measuresGeneral adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaledIf breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.In case of skin contactWash off with soap and plenty of water. Consult a physician.In case of eye contactRinse thoroughly with plenty of water for at least 15 minutes and consult a physician.If swallowedNever give anything by mouth to an unconscious person. Rinse mouth with water. Consult aphysician.4.2Most important symptoms/effects, acute and delayedInhalation of dust irritates nose and throat. Ingestion causes irritation of mouth and stomach.Dust irritates eyes and can irritate skin on prolonged contact. (USCG, 1999)4.3Indication of immediate medical attention and special treatment needed, if necessaryBasic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at10 to 15 L/min. Monitor for shock and treat if necessary ... . For eye contamination, flush eyesimmediately with water. Irrigate each eye continuously with normal saline during transport ... .Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. /Iron and related compounds/5.1Extinguishing mediaSuitable extinguishing mediaPersonnel protection: ... Wear positive pressure self-contained breathing apparatus whenfighting fires involving this material.5.2Specific hazards arising from the chemicalSpecial Hazards of Combustion Products: Toxic oxides of nitrogen and nitric acid vapor mayform in fires. Behavior in Fire: In contact with combustible materials, will increase the intensity of a fire. Apply water to cool containers or spilled material. (USCG, 1999)5.3Special protective actions for fire-fightersWear self-contained breathing apparatus for firefighting if necessary.6.1Personal precautions, protective equipment and emergency proceduresUse personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas.Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Forpersonal protection see section 8.6.2Environmental precautionsPrevent further leakage or spillage if safe to do so. Do not let product enter drains. Dischargeinto the environment must be avoided.6.3Methods and materials for containment and cleaning upEnvironmental considerations: Water spill: Neutralize with agricultural lime (CaO), crushedlimestone (CaCO3), or sodium bicarbonate (NaHCO3). Adjust pH to neutral (pH+ 7). Usemechanical dredges or lifts to remove immobilized masses of pollutants and precipitates.7.1Precautions for safe handlingAvoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure -obtain special instructions before use.Provide appropriate exhaust ventilation at places wheredust is formed. For precautions see section 2.2.7.2Conditions for safe storage, including any incompatibilitiesStore in cool place. Keep container tightly closed in a dry and well-ventilated place.8.1Control parametersOccupational Exposure limit valuesno data availableBiological limit valuesno data available8.2Appropriate engineering controlsHandle in accordance with good industrial hygiene and safety practice. Wash hands beforebreaks and at the end of workday.8.3Individual protection measures, such as personal protective equipment (PPE)Eye/face protectionSafety glasses with side-shields conforming to EN166. Use equipment for eye protection testedand approved under appropriate government standards such as NIOSH (US) or EN 166(EU).Skin protectionWear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.Respiratory protectionWear dust mask when handling large quantities.Thermal hazardsno data availablePhysical state A violet crystalline solidColour no data availableOdour no data available47.2ºCMelting point/ freezingpointBoiling point or initial83ºC at 760 mmHgboiling point and boilingrangeFlammability no data availableno data availableLower and upper explosionlimit / flammabilitylimitFlash point no data availableno data availableAuto-ignitiontemperatureno data availableDecompositiontemperaturepH no data availableKinematic viscosity no data availableSolubility no data availableno data availablePartition coefficientn-octanol/water (logvalue)Vapour pressure49.8mmHg at 25°C1.684Density and/or relativedensityRelative vapour density no data availableParticle characteristics n o data available10.1Reactivityno data available10.2Chemical stabilityStable under recommended storage conditions.10.3Possibility of hazardous reactionsDangerous fire risk in contact with organic material. /Ferric nitrate nonahydrate/FERRICNITRATE is an oxidizing agent. Mixtures with alkyl esters may explode, owing to theformation of alkyl nitrates. Mixtures with phosphorus, tin(II) chloride or other reducing agents may react explosively [Bretherick, 1979 p. 108-109].10.4Conditions to avoidno data available10.5Incompatible materialsThey are powerful oxidizing agents which may cause violent reaction with reducing materials./Nitrates/10.6Hazardous decomposition productsToxic oxides of nitrogen & nitric acid vapor may form in fires. /ferric nitrate nonahydrate/Acute toxicity•Oral: LD50 Rat oral 3,250 mg/kg /Nonahydrate/•Inhalation: no data available•Dermal: no data availableSkin corrosion/irritationno data availableSerious eye damage/irritationno data availableRespiratory or skin sensitizationno data availableGerm cell mutagenicityno data availableCarcinogenicityno data availableReproductive toxicityno data availableSTOT-single exposureno data availableSTOT-repeated exposureno data availableAspiration hazardno data available12.1Toxicity•Toxicity to fish: no data available•Toxicity to daphnia and other aquatic invertebrates: no data available•Toxicity to algae: no data available•Toxicity to microorganisms: no data available12.2Persistence and degradabilityno data available12.3Bioaccumulative potentialno data available12.4Mobility in soilno data available12.5Other adverse effectsno data available13.1Disposal methodsProductThe material can be disposed of by removal to a licensed chemical destruction plant or bycontrolled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed orseed by storage or disposal. Do not discharge to sewer systems.Contaminated packagingContainers can be triply rinsed (or equivalent) and offered for recycling or reconditioning.Alternatively, the packaging can be punctured to make it unusable for other purposes and thenbe disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.14.1UN NumberADR/RID: UN3264IMDG: UN3264IATA: UN3264 14.2UN Proper Shipping NameADR/RID: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.IMDG: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.IATA: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.14.3Transport hazard class(es)ADR/RID: 8IMDG: 8IATA: 8 14.4Packing group, if applicableADR/RID: III IMDG: III IATA: III 14.5Environmental hazardsADR/RID: no IMDG: no IATA: no 14.6Special precautions for userno data available14.7Transport in bulk according to Annex II of MARPOL 73/78 andthe IBC Codeno data available15.1Safety, health and environmental regulations specific for theproduct in questionInformation on revisionCreation Date Aug 12, 2017Revision Date Aug 12, 2017Abbreviations and acronyms•CAS: Chemical Abstracts Service•ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road •RID: Regulation concerning the International Carriage of Dangerous Goods by Rail •IMDG: International Maritime Dangerous Goods•IATA: International Air Transportation Association•TWA: Time Weighted Average•STEL: Short term exposure limit•LC50: Lethal Concentration 50%•LD50: Lethal Dose 50%•EC50: Effective Concentration 50%Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product.。