MSDS TOGOCOLL F500
PU胶水MSDS英文版
PU glue of MSDS1.product name PU glue only for compositing ofman-made leather and fabricusage for compositingof man-madeleather and fabric2 Physical Description3 Chemical ContentsAppearance pale yellow andtransparencyPolyurethane Resin Odor Pungent AcetoneBoiling point 120~150℃CyclohexanonePH value 7 Butanonedecompositiontemperature300~380℃Plasticizersolubility insolubilization FillerCondition toavoidKeep away from flame Tackifying resinSubstance toavoidOxidizing agents Other Ingredients4 Health Hazards and First AidHealth Hazards First AidEye contact May cause irritation. Immed iately flus h eyes wit hlarge amo unts o f water fo r atleast 15 minutes. S eek med icalattentio n pro mp tly.Skin contact May cause irritation. Immed iately flush sk in wit hlarge amo unts o f sud s.Seekmed ical attentio n p ro mp tly.Inhalation May cause dizziness，emesis T a k e patient into the fresh ai r. Perform artificial respiration. Seek medical attention prom ptl y.Ingestion May cause dizziness，emesis,dyspnea Keep at rest. Get prompt medical attention.chronic effect Nervous systemdisorders According to the symptoms for healingSigns and symptoms headache，dizziness，tiredness5 Fire fighting measuresextinguishing media From and powder extinguisher .for large fires,use water spray,for or regular foam.Fire fighting Use water spray to cool fire exposed surfaces and to protectpersonnel.shut off”fuel”to fire.6 Accidental Release MeasuresPersonalconsiderationsWear respirator, rubber gloves, goggles and protective clothing.EnvironmentalprotectionPrevent diffusion.Methods for cleaning up Cover residues with humid absorbent material, then fill into container by shovel.7 Handling and StorageHanding Ensure efficient exhaust vent in the working area. Do not use at source ignition.Avoid contact with eyes, skin.Storage Keep in tightly closed container store between5℃ and 408 Stability and ReactivityStability StableSpecial Conditions ofHazardous Reactionat high temperature decompose to explodeCondition to avoid Storage temperature higher than 60℃or lowerthan 5℃Substance to avoid strong acid，Oxidizing agentsHazardous Decomposition Product Formation of combustible and noxious fumes during thermal decomposition9 Toxicological InformationAcute Toxicity Breathe hardlyLocal EffectsSensitiveChronic Nervous breakdownExceptional Effect10 Ecological InformationPossibility of Environmental Impact Must not enter the waters,drains or ground.11 Disposal InformationDisposal Information Should be disposed of at appropriateincineration unit observing official localregulations12Transport InformationIntemational Transport RegulationThe United Nations NumberIntemal Transport regulationSpecial Transport Way and Not Keep away form foodstuffs，acids andalkalis. Put between 5℃and 40℃13 Regulation InformationApply Regulation14 Factory emergency contactFire Alarm：119 First Aid ：120 numbersFactory Address and phone Taiwanese investment zone Quanzhou city*************。
三氧化酪(铬酸酐)MSDS
操作注意事项：
密闭操作，加强通风。操作人员必须经过专门培训，严格遵守操作规程。建议操作人员佩戴自吸过滤式防尘口罩，戴化学安全防护眼镜，穿聚乙烯防毒服，戴橡胶手套。远离火种、热源，工作场所严禁吸烟。远离易燃、可燃物。避免产生粉尘。避免与还原剂、活性金属粉末接触。搬运时要轻装轻卸，防止包装及容器损坏。配备相应品种和数量的消防器材及泄漏应急处理设备。倒空的容器可能残留有害物。
食入：
饮足量温水，催吐。用清水或 1％硫代硫酸钠溶液洗胃。给饮牛奶或蛋清。就医。
第五部分：消防措施
危险特性：
强氧化剂。与易燃物（如苯）和可燃物（如糖、纤维素等）接触会发生剧烈反应，甚至引起燃烧。与还原性物质如镁粉、铝粉、硫、磷等混合后, 经摩擦或撞击, 能引起燃烧或爆炸。具有较强的腐蚀性。
有害燃烧产物：
三氧化铬化学品安全技术说明书
说明书目录
第一部分
化学品名称
第九部分
理化特性
第二部分
成分/组成信息
第十部分
稳定性和反应活性
第三部分
危险性概述
第十一部分
毒理学资料
第四部分
急救措施
第十二部分
生态学资料
第五部分
消防措施
第十三部分
废弃处置
第六部分
泄漏应急处理
第十四部分
运输信息
第七部分
操作处置与储存
第十五部分
法规信息
第十五部分：法规信息
法规信息
化学危险物品安全管理条例 (1987年2月17日国务院发布)，化学危险物品安全管理条例实施细则 (化劳发[1992] 677号)，工作场所安全使用化学品规定 ([1996]劳部发423号)等法规，针对化学危险品的安全使用、生产、储存、运输、装卸等方面均作了相应规定；常用危险化学品的分类及标志 (GB 13690-92)将该物质划为第5.1 类氧化剂。
牛津琼脂（OXA）基础产品说明书
产品编号：026060 修订日期：2019-10-15化学品安全技术说明书第一部分化学品及企业标识产品中文名称：牛津琼脂（OXA）基础产品英文名称：Oxford Agar Base产品编号：026060企业名称：广东环凯微生物科技有限公司地址：广东省广州市黄埔区广州开发区科学城神舟路788号邮编：510663公司网址电子邮件地址：*********************传真号码：************销售热线：************-8602技术热线：************-8877/8876推荐用途和限制用途：生化研究/分析第二部分危险性概述GSH危害性类别非危险物质或混合物GSH标签要素非危险物质或混合物其它危害（健康危害、环境危害）未见报道第三部分成分/组成信息混合物化学品成分：参考培养基使用说明。
有害物质成分：无第四部分急救措施一般信息：无特殊的措施要求。
皮肤接触：立即用清水彻底清洗。
眼睛接触：立即提起眼睑，用大量流动清水冲洗15min。
如不适就医。
吸入：如果吸入，将人员移动到新鲜空气处，如果没有呼吸，进行人工呼吸操作，并联系医生。
食入：如误食，用水冲洗口腔，如不适就医。
产品编号：026060 修订日期：2019-10-15就医信息： 出示产品使用说明或者此SDS 。
第六部分 泄露应急处理个人防护： 穿个人实验服,佩戴手套和口罩,避免吸入干粉。
环境保护措施： 用湿布和地拖擦拭干净。
清洁/收集措施： 保持干燥。
迅速清洗弄脏的区域。
第七部分 操作处置与储存安全操作注意事项： 防止粉尘扬起，应提供通风设备。
储存注意事项： 贮存于避光、干燥处，用后立即旋紧瓶盖。
第八部分 接触控制/个人防护职业接触限值 没有已知的国家规定的暴露极限。
工程控制： 提供安全淋浴和洗眼设备个人保护措施 呼吸系统防护： 在通风橱里称取产品，佩戴口罩。
眼睛防护： 佩戴安全眼镜。
身体防护： 穿实验室服。
手防护： 戴防化学品手套。
溶剂型万能胶
808溶剂型万能胶msds中文.doc Post By：2010-1-29 11:19:00[广告] 您是否还在为验厂考勤软件而烦恼咨询电话：物质安全技术说明书（MSDS）（2008年修订版）一、化学品名称和制造商信息化学品名称：808溶剂型万能胶二、化学组成信息化学辩识：混合物主要成分：SBS热塑性橡胶 CAS编号：9003-55-8 10%增粘树脂 CAS编号：64742-16-1 8%特级松香 CAS编号：8050-09-7 14%醋酸乙脂 CAS编号：141-78-6 6%溶剂油 CAS编号：8030-30-6 60%执行标准：国家标准：GB18583-2001；企业标准：Q/TQ003-2008三、危害信息危险类别：3类危规号：32196侵入途径：可通过食入、吸入及皮肤接触吸收侵入人体。
健康危害：本产品蒸气有麻醉性，工作场所溶剂蒸气超标将有害人体健康。
环境危害：流入水域会造成污染。
燃爆危险：密封低温储存，忌长期暴晒，严禁接近火源、热源，防止静电发生。
四、急救措施大量吸入：立即将患者移离污染区，并深呼吸新鲜空气，如患者仍感觉不适应将患者送医院就医。
皮肤接触：立即用大量肥皂水清洗皮肤处。
脱去并隔离被污染的衣物和鞋。
若有红肿等症状持续，立即就医。
眼睛接触：以大量清水清洗被接触的眼睛不少于10分钟，如再感不适及时送医治疗。
不慎吞入：若患者尚清醒，使其喝1-2杯水以稀释药物并立即联系医院或毒物控制中心。
若患者已不清醒，不要从口给任何东西以确保呼吸道畅通，将身体平躺下，勿催吐，立即送往医院。
对急救人员之防护：戴口罩、手套、面具、防护衣。
对医师之提示：溶剂型胶粘剂。
五、消防措施危险特性：可被静电或明火点燃，加热到分解温度时释放出毒性的烟雾。
灭火器材：干粉、干砂、二氧化碳。
灭火方法：发生火灾时，请迅速切断着火点附近的燃烧途径，并穿适当的防护服，戴设备齐全的呼吸器，使用灭火剂由上风往下风的方向进行灭火。
502胶水MSDS之欧阳语创编
502胶水(MSDS)化学品安全技术说明书一．产品标识商品名：502胶水主要成分：α-氰基丙烯酸乙酯，阻聚剂、增稠剂、增强剂、加速剂二．主要组成与性状主要成分：α-氰基丙烯酸乙酯中文名称：α-氰基丙烯酸乙酯；2-氰基丙烯酸乙酯；1-氰基-2-丙烯酸乙酯；英文名称：Ethyl 2-cyanoacrylate;2-Cyano-2-propenoic acid, ethyl ester;2-Cyanoacrylic acid,ethyl ester;化学式：C6H7NO2分子量：125.0CAS登记号:7085-85-0外观与性状：无色透明液体，有刺激性气味；主要用途：适用于陶瓷、橡胶、玻璃、珠宝、塑料、家俱、广告等各类物质胶粘三.危险性概述侵入途径：吸入、食入、经皮吸收。
健康危害：接触到皮肤会引起过敏性皮肤反应。
环境危害：加热或燃烧时，该物质分解生成含氮氧化物和氰化物有毒和刺激性烟雾/气体。
燃爆危险：本品可燃。
高于75℃，可能形成爆炸性蒸气/空气混合物。
四．急救措施皮肤接触：迅速用水和肥皂清洗皮肤附着部位，如果有搔痒、炎症等症状，要立即请医生诊治；眼睛接触：立即用水清洗，至少15分钟以上。
洗完后，立即请医生诊治；就医；吸入：如果吸入蒸气后有不适感，要立即转移至空气新鲜的场所，迅速请医生诊治；食入：用水清洗口腔。
大量饮水在胃内稀释并吐出，之后立即请医生处治。
五．消防措施危险特性：该物质迅速聚合。
加热或燃烧时，该物质分解生成含氮氧化物和氰化物有毒和刺激性烟雾/气体。
灭火方法及灭火剂：灭火处理：切断火源附近的着火源，并用灭火器在上风向进行作业。
灭火剂：泡沫灭火剂、粉末灭火剂、二酸化炭灭火剂、干燥砂。
六.泄漏应急处理：迅速清除附近的着火源，准备灭火器材；用破布、纱布、砂等吸附泄露液，并回收至容器中；作业时，必须穿戴保护器具，室内要充分通风。
七.操作处置与储存操作注意事项：大量时，必要时带手套、口罩、防护眼睛操作。
MSDS TOGOCOLL F500
材料安全数据 MSDS
91/155EEC(2001/58/EC)
材料名称：TOGOCOLL F500
12. 生态学资料 生态毒性
页码：第 4 页 共 5 页 制定：2007.09.07
海产品毒性 101-68-8 4，4-二苯基甲烷二异氰酸酯 LC50 >100 mg/l (鱼) 概要注释 ： 水危害为 1 级：（德国标准）（自我评估）：对水是稍量危害的 禁止将未稀释或大量的产品倒入地下水、水资源或污水系统 13. 废弃处置 产品建议 ： 必须与普通废弃物分开，不允许流入下水道。 欧洲废料处理目录： 08 00 00 制造商在生产、设计、运输和使用中形成的废料，如相关涂料（油漆、清漆和玻璃
2．成分 /组成信息
化学特性
描述 ：下列无危害添加物的共混
CAS 编号 28553-12-0 EINECS 编号:249-079-5
邻苯二甲酸酯
25-50%
CAS 编号 1333-86-4
炭黑
25-50%
EINECS 编号:215-609-9
CAS 编号 101-68-8 EINECS 编号:202-966-0
检测值
长期数值：5mg/m3
1333-86-4 检测值
炭黑
短期数值：7mg/m3 长期数值：3.5 mg/m3
101-68-8 4，4-二苯基甲烷二异氰酸酯
检测值
短期数值：0.07mg/m3
含有 NCO 成分
长期数值：0.02 mg/m3
附加信息：制作期间有效的清单将作为基础来使用。
个人防护用品： 普通防护和卫生措施： 远离食品、饮料和粮食， 立即脱掉弄脏和污染的衣服；休息和结束工作时请立即洗手 呼吸系统保护：无 手防护： 防护手套的合适材料：橡胶手套 手套材料可渗透时间：可由防护手套的制造商观察检测 眼睛防护 ：使用时佩戴护目镜
VOCO Clip F 型号产品材料安全数据表说明书
1 Names of Material, Preparation and Companytradename:manufacturer/supplieraddress:information sector:emergency information:Clip FVOCO GmbHAnton-Flettner-Str. 1-3D - 27472 CuxhavenScientific DepartmentScientific DepartmentTel.: +49-4721/71 9 - 0Fax:+49-4721/71 9 - 109Tel.:+49-47 21/71 9 - 0emergency call: +49-47 21/71 9 - 02 Composition/Details on Componentspreparation:;ixture of diff. dimethacrylates, sodium fluoride, silicates, initiatora and additives description: Light-curing temporary filling material with fluoridehazardousingredients:nameUDMA CAS-No.41137-60-4content10-20 %danger symbolXiR-categories36-383P ossibleRisksdesignation of risk:special details of risk (R-categories): detrimental effects/symptoms:Xn, harmful20/21/22Harmful by inhalation, in contact with skin and if swallowed4 First-Aid-Measuresgeneralinformation:after inhalation:after skin contact:after eye contact:after swallowing:information for the attending physician: fresh air, in case of indisposition or nausea contact a doctor rinse thoroughly with plenty of waterrinse thoroughly with water, contact a doctorcontact immediately a physicianmaterial for dental or laboratory use only5 Fire Fighting Measuressuitable fire extinguishing agents: unsuitable fire extinguishing agents: particular hazards:fire fighting protective equipment:foam, carbon dioxide, powder fire extinguishers waternoneno data available6 Measures in Case of Unintended Releasemeasures related to persons: environmental measures: procedures of cleaning/uptake additional information:avoid eye and/or skin contactdo not let the material get in contact with sewerage systems take up mechanically, use common absorbentsnone7. Handling and Storage7.1 handling: only by qualified staff in dental offices or dental laboratories7.2instructions for safe handling:instructions on fire and explosion protectionStorage:demands on storerooms and containersindications and prohibitions of storage together with othermaterials:further details on storage conditions:see instructions for useno special measurements are requiredtightly closed at room temperaturestore in good ventilated roomsand areasdo not store together with foodkeep out of the reach of childrenEC-Safety Data Sheet page 1 of 4 according to: 91/155/EEC date: 07.07.95/01 trade name: Clip F revised on: 04/01/20068 8.1Exposition Restriction and Personal Protective Equipment additional information on the equipment of technical facilities: none8.2 components with limitating values related to place of work:CAS-No. name kind value unit additionalinformation:hazards related to place of work are not known.8.3 personal protective equipment:breathing protectionhand protection:eye protection:body protection:protective and hygiene measures: dental office or laboratory working clothes do not breeth or inhale vapour or dustuse of protective gloves is recommended use of protective glasses is recommendedwashing hands9 Physical and Chemical Properties9.1 appearance:form:colour:odour:pastepastywhite acrylate-like9.2 safety data: tested acc. to:9.3pH upon delivery:pH of 10g/l H2O and 20°C:change of state:boiling point/area:melting point/area:flash point:inflammability:ignition temperature:autoignition:fire advancing properties:explosion hazards:explosion limits: LEL:vapour pressure (°C)density (°C)bulk density:solubility in water (20°C) (°C):in (°C)solubility in fat:distribution coefficient n-octanol/water:viscosity (°C):solvent separation test:solvent content:further particulars:no data availableno data availableno data availableno data available °Cno data available °Cno data available °Cno data availableno data available °Cno data availableno data availableno data availableUEL:no data availableno data availableno data available hPano data availableno data available mg/lno data available mg/lno data availableno data availableno data availableno data available %no data available %none10 Stability and Reactivityconditions to be avoided:materials to be avoided:hazardous products of decomposition: further particulars:Influence of light, heatradical releasing agent, e. g. peroxides HCN, CyanidesnoneEC-Safety Data Sheet page 2 of 4 according to: 91/155/EEC date: 07.07.95/01 trade name: Clip F revised on: 04/01/200611. ToxicologicalData11.1 toxicological Test: no data availableacute toxicity: no data availableLD50/LC50:component kind value species method of determination11.2specific symptoms in animal test:irritant effect/corrosive action:sensitization:effects of repeated exposure or overexposure(subacute or chronic toxicity):carcinogenic and mutagenic effects hazardous to reproduction:other particulars:practical experience:observations relevant to classifications:other observations:no data availableno data availableno data availableno data availableno data availableno data availableno data availableno data availableno data availableno data available11.3 general remarks: during long-standing product application risks have not become known.12 12.1Ecological Datainformation on elimination: no data availableprocedure analytic method degree of elimination classification evaluation: no data availableadditional information: no data available12.2 behaviour in environmental compartments: no data availablemobility and bioaccumulation potential:no data availableadditional information: none12.3 environmental toxic effects: no data availableaquatic toxicity: no data availableorganism test period test method result assessment behaviour in sewage plants: no data availablerespiratory inhibition of local vitalised sludge: no data available12.4 additional information:CSB-value:BSB5-value:AOX-indication: noneno data available mg/g no data available mg/g no data availablecontains the following heavy metals and compounds (corresponding to guideline 76/464/EWG) according to preparation formula:nonegeneral information:none13 DisposalInstructions13.1 product:recommendation: obey local and governmental regulationswaste category waste name accountability13.2 uncleaned packing material:recommendation:cleaning agents: obey local and governmental regulations obey local and governmental regulations common cleansing agents for the laboratoryEC-Sate Data Sheet page 3 of 4 according to: 91/155/EEC date: 07.07.95/01 trade name: Clip F revised on: 04/01/200614 Particulars on Transport 14.1 land carriage:ADR/RID/GGVS/GGVE-class: warning label:designation of goods: remarks: figure/letter:risk no.:material no.:14.2 inland transport by ship:ADN/ADN R-class:designation of goods:remarks:figure/letter: category: 14.3 see transport:IMDG/GGV sea class: EMS:marine pollutant: correct technical name: remarks: UN-N o.:MFAG:PG:14.4 air transport:ICAO/IATA-class:correct technical name:remarks:UN/ID-No.: PG:14.5 further particulars: No hazardous goods within the meaning of transport regulations15 Regulation15.1 marking: acc. to governmental regulations concerning declaration of dangerous chemicals no marking is prescribeddanger symbol and designation: nonecontains:R-categories: noneS-categories: nonespecial marking of particular preparations: none15.2 national regulations: acc. to article 10 of Directive 66/379 EEC and 67/548 EECrestrictions of employment: noneinstructions in case of interference: noneclassification acc. VbF: not applicabletechnical instruction air: not applicablewater pollution class: no data availableother regulations, restrictions and prohibitions: Directive 91/155 EEC; medical product acc. to 93/42 EEC (medical products).16 OtherP articularsAll information above has been given according to our present state of knowledge. It has been compiled to the best of our knowledge. The above -mentioned data do not represent a guarantee on characteristics. They only describe the safety requirements with regard to our products. They do not represent an assurance of productcharacteristics in the meaning of guarantees.EC-Safety Data Sheet page 4 of 4 according to: 91/155/EEC date: 07.07.95/01 trade name:Clip F revised on: 04/01/2006。
MSDS模板和中英文对照
10mg/m3 Total dust. 5mg/m3 Respirable fraction.
15mg/m3 Total dust from OSHA PEL (TWA)
[Alumina oxide]
9. Physical and Chemical Properties理化特性
Physical State物态
Extrudate压出型材;挤塑制品;
Color
White
Critial Temperature临界温度
Not available
Odor气味
odorless
Solubility溶解度;
Not available
Boiling Point沸点
Not available
Storage储存注意事项
Keep container tightly closed. Keep container in a cool, well-ventilated area.
8. Exposure Controls/Personal Protection接触控制/个体防护
Engineering Measure
5.Fire and Explosion Data火灾和爆炸数据
Flammability of the Product产品的易燃性
Non-flammable and non-exption氧化
Not available
Fire Fighting Ways灭火方法
Personal Protection in Case of a Large Spill
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.
散装双氧水储存指南英文版
散装双氧水储存指南英文版English:When storing bulk hydrogen peroxide, it is important to follow certain guidelines to ensure safety and effectiveness. Firstly, it is crucial to store hydrogen peroxide in a cool, dry, and well-ventilated area away from direct sunlight and sources of heat. This will help prevent decomposition and ensure the stability of the chemical. Additionally, it is recommended to store hydrogen peroxide in its original container or a suitable alternative that is made of a compatible material such as high-density polyethylene. It is important to label the container clearly with the contents and the date of purchase to track its shelf life. When handling bulk hydrogen peroxide, proper personal protective equipment should be worn, including gloves, goggles, and a lab coat. It is also important to ensure proper ventilation in the storage area to prevent the build-up of potentially hazardous vapors. Regular inspections of the storage area should be conducted to check for any signs of leakage or damage to the containers. In the event of a spill or leak, appropriate measures should be taken to contain and clean up the hydrogen peroxide following established protocols. By following theseguidelines, the safe storage of bulk hydrogen peroxide can be achieved.Translated content:在储存散装双氧水时，重要的是要遵循一定的准则以确保安全性和有效性。
甲酸环己酯的理化性质及危险特性表
③运输考前须知：运输时运输车辆应配备相应品种和数量的消防器材及泄漏应急处理设 备。夏季最好早晚运输。运输时所用的槽（罐）车应有接地链，槽内可设孔隔板以减少震 荡产生静电。严禁与氧化剂、酸类、碱类、食用化学品等混装混运。运输途中应防曝晒、 雨淋，防高温。中途停留时应远离火种、热源、高温区。装运该物品的车辆排气管必须配 备阻火装置，禁止使用易产生火花的机械设备和工具装卸。公路运输时要按规定路线行驶。 铁路运输时要禁止溜放。严禁162.5
相对蒸汽密度（空气=1）：
4.4
闪点（C）：
51
饱和蒸汽压（kPa）：
无资料
引燃温度（°C）：
无资料
爆炸上限/卜.限［％（V/V）］：
无资料
临界温度（C）：
无资料
临界压力（MPa）：
无资料
溶解性：
不溶于水。
毒性
无资料
康害 健危
高浓度时有显著刺激作用。目前，未见职业中毒报道。
爆险 燃危
无资料
急救 措施
皮肤接触：
脱去污染的衣着，用肥皂水及清水彻底冲洗。
眼睛接触：
立即翻开上下眼睑，用流动清水冲洗15分钟。就医。
吸入：
迅速脱离现场至空气新鲜处。就医。
食入：
误服者给饮足量温水，催吐，就医。
烧炸险生 燃爆危十
危险特性：
遇明火、高热或与氧化剂接触，有引起燃烧爆炸的危险。其蒸气比空气 重，能在较低处扩散到相当远的地方，遇明火会引着回燃。假设遇高热， 容器内压增大，有开裂和爆炸的危险。
热熔胶MSDS英文版
PRODUCT NAME:HOT MELT ADHESIVE FOR AUTOMOBILE LAMPS1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONPRODUCTProduct Name: HOT MELT ADHESIVE FOR AUTOMOBILE LAMPSProduct Description: HOT MELT ADHESIVE,MIXTUREProduct Code:Intended Use: ADHESIVE,FOR AUTOMOBILE LAMPSCOMPANY IDENTIFICATIONHuangshan Xiuning Xindecheng Chemical Co., Ltd.SUPPLIER:Wanning Industrial Park, Huangshan, Anhui, China (245400)Telephone: 0086-559-7519970Facsimile: 0086-559-7519971This (M)SDS is a generic document with no country specific information included.2 COMPOSITION/INFORMATION ON INGREDIENTSNo Reportable Hazardous Substance(s) or Complex Substance(s).INGREDIENTS CAS No.Approx. Proportionstyrene butadiene rubber9003-55-8Med 50-60%rosin resin8050-09-7Low 50-40%PRODUCT NAME:HOT MELT ADHESIVE FOR AUTOMOBILE LAMPS3 HAZARDS IDENTIFICATIONThis material is not considered to be hazardous.PHYSICAL / CHEMICAL HAZARDSN/AHEALTH HAZARDSNo adverse effects due to inhalation are expected. When heated, the vapour/fumes given off may cause respiratory tract irritation.4 FIRST AID MEASURESINHALATIONIn case of adverse exposure to vapors and / or aerosols formed at elevated temperatures, immediately remove the affected victim from exposure. Administer artificial respiration if breathing is stopped. Keep at rest.SKIN CONTACTWash contact areas with soap and water. For hot product: Immediately immerse in or flush affected area with large amounts of cold water to dissipate heat. Cover with clean cotton sheeting or gauze and get prompt medical attention.EYE CONTACTFlush thoroughly with water. If irritation occurs, get medical assistance.INGESTIONFirst aid is normally not required. Seek medical attention if discomfort occurs.5 FIRE- FIGHTING MEASURESPRODUCT NAME:HOT MELT ADHESIVE FOR AUTOMOBILE LAMPSEXTINGUISHING MEDIAAppropriate Extinguishing Media: Use dry chemical or carbon dioxide (CO2) to extinguish flames.Inappropriate Extinguishing Media: Straight streams of waterFIRE FIGHTINGFire Fighting Instructions: Assure an extended cooling down period to prevent re-ignition. Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply.Hazardous Combustion Products: Flammable hydrocarbons, Oxides of carbon, Smoke, Fume, Incompletecombustion products6 ACCIDENTAL RELEASE MEASURESNOTIFICATION PROCEDURESIn the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.ENVIRONMENTAL PRECAUTIONSN/A7 HANDLING AND STORAGEHANDLINGAvoid elevated temperatures for prolonged periods of time. Protect material from direct sunlight. Material canaccumulate static charges which may cause an electrical spark (ignition source). Apart from the specific nature of the polymer product, conditions such as humidity, sunlight and temperature.Loading/Unloading Temperature: [Ambient]Transport Temperature: [Ambient]PRODUCT NAME:HOT MELT ADHESIVE FOR AUTOMOBILE LAMPSSTORAGEStore in a cool, dry place.Storage Temperature: 0℃—40℃Storage Pressure:[Ambient]8 EXPOSURE CONTROLS /PERSONAL PROTECTIONENGINEERING CONTROLSN/APERSONAL PROTECTIONPersonal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage.Respiratory Protection:If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:No special requirements under ordinary conditions of use and with adequate ventilation.For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded.Hand Protection:If product is hot, thermally protective gloves are recommended. If contact with forearms is likely, wear gauntlet style gloves.PRODUCT NAME:HOT MELT ADHESIVE FOR AUTOMOBILE LAMPSEye Protection:If contact is likely, safety glasses with side shields are recommended.Skin and Body Protection:If product is hot, thermally protective, chemical resistant apron and long sleeves are recommended.Specific Hygiene Measures:Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping.9 PHYSICAL AND CHEMICAL PROPERTIESTypical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional data. GENERAL INFORMATIONPhysical State: SolidForm: GrainsColour: GrayOdour: None to MildIMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATIONRelative Density (at 18 C): 0.97Density (at 18 ºC): 970 kg/m³Flash Point [method]: O.C Cleveland Open Cup ＞260℃Flammable Limits (Approximate volume % in air): LEL: N/D UEL: N/DAutoignition Temperature: N/APRODUCT NAME:HOT MELT ADHESIVE FOR AUTOMOBILE LAMPSBoiling Point / Range: ＞260℃Vapour Density (Air = 1): N/AVapour Pressure: N/AEvaporation Rate (N-Butyl Acetate = 1): N/ApH: N/ALog Pow (n-Octanol/Water Partition Coefficient): N/ASolubility in Water: Negligible10 STABILITY AND REACTIVITYSTABILITY:Material is stable under normal conditions.CONDITIONS TO AVOID:Avoid elevated temperatures for prolonged periods of time.HAZARDOUS DECOMPOSITION PRODUCTS:Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION:Will not occur.11 TOXICOLOGICAL INFORMATIONPRODUCT NAME:HOT MELT ADHESIVE FOR AUTOMOBILE LAMPSAcute ToxicityRoute of Exposure Conclusion / RemarksINHALATIONToxicity: Minimally Toxic. Based on test data for structurally similarmaterials.Irritation: Negligible hazard at ambient/normal handling temperatures. Basedon test data for structurally similar materials.INGESTIONToxicity: Minimally Toxic. Based on test data for structurally similarmaterials.SkinToxicity: Minimally Toxic. Based on test data for structurally similarmaterials.Irritation: Negligible irritation to skin at ambient temperatures. Based on testdata for structurally similar materials.EyeIrritation: May cause mild, short-lasting discomfort to eyes. Based on testdata for structurally similar materials.CHRONIC/OTHER EFFECTS12 ECOLOGICAL INFORMATIONThe information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITYPRODUCT NAME:HOT MELT ADHESIVE FOR AUTOMOBILE LAMPSMaterial -- Not expected to be harmful to aquatic organisms.Material -- Not expected to be harmful to terrestrial organisms13 DISPOSAL CONSIDERATIONSDisposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal.DISPOSAL RECOMMENDATIONSSuitable routes of disposal are supervised incineration, preferentially with energy recovery, or appropriate recycling methods in accordance with applicable regulations and material characteristics at the time of disposal.14 TRANSPORT INFORMATIONLAND : Not Regulated for Land TransportSEA (IMDG) : Not Regulated for Sea Transport according to IMDG-CodeAIR (IATA) : Not Regulated for Air Transport15 RRGULATORY INFORMATIONPRODUCT NAME:HOT MELT ADHESIVE FOR AUTOMOBILE LAMPSMaterial is not hazardous as defined by the EU Dangerous Substances/Preparations Directives.16 OTHER INFORMATIONN/D = Not determined, N/A = Not applicableTHIS SDS COVERS THE FOLLOWING MATERIALS: Petroleum hydrocarbon resin ECR 807 | Escorez 2203 LC | mixed resin dust-----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of Xindecheng’s knowledge and belief, accurate and reliable as of the date issued. You can contact Xindecheng to insure that this document is the most current available from Jinsen. The information and recommendations are offered for the user's consideration and examination. It is the user's responsibility to satisfy itself that the product is suitable for the intended use. If buyer repackages this product, it is the user's responsibility to insure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited.---------------------------------------------------------------------------------------------------------------------------。
二环庚二烯-安全技术说明书MSDS
第一部分化学品及企业标识化学品中文名：二环庚二烯化学品英文名：dicycloheptadiene；2,5-norbornadiene化学品别名：2,5-降冰片二烯CAS No.：121-46-0EC No.：204-472-0分子式：C7H8第二部分危险性概述紧急情况概述液体。
高度易燃,其蒸气与空气混合，能形成爆炸性混合物。
对水生环境可能会引起长期有害作用。
GHS危险性类别根据GB30000-2013化学品分类和标签规范系列标准（参阅第十六部分），该产品分类如下：易燃液体，类别2；危害水生环境-慢性毒性，类别3。
标签要素象形图警示词：危险危险信息：高度易燃液体和蒸气，对水生生物有害并具有长期持续影响。
预防措施：远离热源、热表面、火花、明火以及其它点火源。
禁止吸烟。
保持容器密闭。
容器和接收设备接地和等势联接。
使用不产生火花的工具。
采取措施，防止静电放电。
避免释放到环境中。
戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
事故响应：如皮肤(或头发)沾染：立即去除/脱掉所有沾染的衣服。
用水清洗皮肤或淋浴。
安全储存：存放在通风良好的地方。
保持低温。
废弃处置：按照地方/区域/国家/国际规章处置内装物/容器。
物理化学危险：高度易燃液体，其蒸气与空气混合，能形成爆炸性混合物。
健康危害：吸入该物质可能会引起对健康有害的影响或呼吸道不适。
意外食入本品可能对个体健康有害。
通过割伤、擦伤或病变处进入血液，可能产生全身损伤的有害作用。
眼睛直接接触本品可导致暂时不适。
环境危害：本品对水生生物有害并具有长期持续影响。
请参阅SDS第十二部分。
第三部分成分/组成信息√物质混合物第四部分急救措施一般性建议：急救措施通常是需要的，请将本SDS出示给到达现场的医生。
皮肤接触：立即脱去污染的衣物。
用大量肥皂水和清水冲洗皮肤。
如有不适，就医。
眼睛接触：用大量水彻底冲洗至少15分钟。
如有不适，就医。
吸入：立即将患者移到新鲜空气处，保持呼吸畅通。
危险化学品特性表
危险化学品特性表（自制）危险化学品特性表（自制） (1)（1）丙烯酸 (4)（2）甲酸 (6)（3）氢氟酸 (7)（1）N,N-二甲基甲酰胺 (8)（2）丙烯酸丁酯 (9)（1）萘 (11)（2）乌洛托品 (12)（1）氯酸钠 (14)（2）亚硝酸钠 (15)（1）四氯乙烯 (16)（2）二氯甲烷 (18)3.1.1.1丙酮 (19)3.1.1.2-丁酮 (20)3.1.1.3甲醇 (21)3.1.1.4乙醇 (23)3.1.1.5 环己酮 (24)3.1.1.6异丙醇 (25)3.1.1.7 甲苯 (27)3.1.1.8 1，2-二甲苯 (28)3.1.1.9 乙醚 (29)3.1.1.10 乙酸乙酯 (31)3.1.1.11过氧化氢 (32)3.1.1.12高锰酸钾 (34)3.1.1.13重铬酸钾 (35)3.1.1.14硝酸银 (36)3.1.1.15苯酚 (38)3.1.1.16三氯甲烷 (39)3.1.1.17四氯化碳 (40)3.1.1.18氢氧化铵水溶液 (42)3.1.1.19氢氧化钠 (43)3.1.1.20氢氧化钾 (44)3.1.1.21甲醛 (45)3.1.1.22盐酸 (47)3.1.1.23硝酸 (48)3.1.1.24硫酸 (49)3.1.1.25 乙酸 (51)3.1.1.26三氯乙酸 (52)3.1.1.27氢氟酸 (53)3.1.1.28次氯酸钠 (55)3.1.1.29亚硫酸氢钠 (56)（4）纯苯 (57)（5）1,1-二氯乙烷 (59)（7）正丁醇 (60)（10）二（正）丁醚 (61)（11）丙烯酸正丁酯 (63)（4）冰醋酸 (64)三氯乙醛 (65)硝酸钠 (67)连二亚硫酸钠 (68)石油醚 (69)对二甲苯 (70)氧 (72)乙炔 (73)⑺乙酸酐 (74)⑻2-丁酮 (75)（1）丙烯酸表3.1-1 丙烯酸简介（2）甲酸（3）氢氟酸表3.1-3氢氟酸简介（1）N,N-二甲基甲酰胺表3.1-4 N,N-二甲基甲酰胺简介（2）丙烯酸丁酯表3.1-5丙烯酸丁酯简介（1）萘表3.1-6萘简介（2）乌洛托品（1）氯酸钠表3.1-8氯酸钠简介（2）亚硝酸钠（1）四氯乙烯（2）二氯甲烷。
20200216 O型圈润滑脂MSDS 安全技术说明书
产品名称MOLYKOTE(R) 55 O-RING GREASE O型圈润滑脂企业识别略成分/组分信息➢化学类别：混合物➢物理形态：脂膏➢颜色：白色➢主要用途：润滑剂➢危险化学品名称：CAS# 无危害性成分无危险性鉴别➢危险性类别：无危害性➢危险性信息：无危害性。
避免接触皮肤及眼睛。
发生火灾和/火爆炸时，不得吸入烟雾。
只能在通风良好的环境下使用。
➢暴露途径：皮肤接触和意外吞食➢健康危害：急性影响：眼睛：直接接触可能导致轻微的不适。
皮肤：单一短时间暴露不会有重大影响。
吸入：单一短时间暴露不会有重大影响。
食入：正常使用时只具很低的摄入危害。
慢性影响：皮肤：反复或长时间接触可能导致过敏，反复皮肤接触可能导致皮肤产生过敏反应吸入：无适合的资料食入：反复摄入或吞咽大量可能造成内部伤害。
➢过分接触的影响和症状：正常使用状态下，单次暴露并不会产生危害影响。
急救措施➢眼睛：立即用水冲洗15分钟➢皮肤：擦去并立即用水冲洗15分钟，如果有过敏及不良反应加剧或持续需就医➢吸入：无需急救➢食入：立即就医➢建议：根据个人的症状和接触的情况进行医治➢对医生的建议：对症医治。
➢燃烧性：不燃➢闪点：>100℃➢引燃温度：无数据➢爆炸下限：无数据消防措施➢爆炸上限：无数据➢危险特性：无➢灭火剂：大火时使用化学品、泡沫或水雾。
小火时使用二氧化碳、干化学品或者水雾。
可以用水冷却暴露于火灾中的容器。
➢特殊的灭火程序和设备：根据当地紧急计划，决定是否需要撤离或隔离该区域，用水冷却受火灾影响暴露的容器。
扑灭涉及化学物品的大火时，应佩戴自给式呼吸器及防护衣物。
➢有害的燃烧产物：二氧化碳及微量的未完全燃烧的碳化物、二氧化硅、金属氧化物、甲醛➢禁止使用的灭火剂：未确定泄漏应急处理➢个人防护注意事项：避免眼睛及皮肤接触，不可外服。
➢环境保护注意事项：不允许大量进入排水系统或水面➢消除方法：遵守在本MSDS中所列的所有的PPE。
假如围堵的物品可以被吸起，应将其装入合适的容器内，抹去或铲起并装入容器内，以使回收利用或废弃。
体系管理MSDS物质安全资料表(大全)
MSDS大全目录表1－001 乙炔气 (1)表1－002 氧气 (2)表1－003 二氧化碳 (3)表1－004 氢气 (4)表1－005 氩气 (5)表1－006 甲烷 (6)表1－007 四氢噻吩 (7)表1－008 活性炭 (8)表1－009 三乙胺 (9)表1－010 硫代磷酰氯 (10)表1－011 硫黄 (11)表1－012 甲胺磷 (12)表1－013 多聚甲醛 (13)表1－014（附表1－3）甲缩醛 (14)表1－015 黄磷 (15)表1－016 氯 (16)表1－017 三氯化磷 (17)表1－018 甲醇 (19)表1－019 液碱 (20)表1－020 氨水 (21)表1－021 硫酸二甲酯 (22)表1－022 甲胺磷 (23)表1－023 液氨 (24)表1－024 氯仿 (25)表1－025 二氯乙烷 (26)表1－026 二硫化碳 (27)表1－027 甲苯 (28)表1－028 盐酸 (29)表1－029 氯甲烷 (30)表1－030 硫酸 (31)表1－031 二甲苯 (33)表1－032 醋酸酐 (34)表1－033 多聚甲醛 (35)表1－034 草甘膦 (36)表1－035 稻瘟灵 (37)表1－036 异丙胺 (38)表1－037 漂白粉 (39)表1－038 氯化氢 (40)表1－039 氰化氢 (41)表1－040 氰化钠 (42)表1－041 氯乙酸 (43)表1－043 丙烯腈 (45)表1－044 氧化亚铜 (46)表1－045 四氯化锡 (47)表1－046 四氧化三铅 (48)表1－047 三氯化铝（无水） (49)表1－048 松香水 (50)表1－049红丹油性防锈漆 (51)表1－050 酚醛树脂 (52)表1－051 硫磺粉(补充) (53)表1－052 一乙胺 (54)表1－053三聚氯氰 (55)表1－054 三氯乙烯 (57)表1－055 磷酸 (58)表1－056 四丁基锡 (59)表1－057 柴油 (60)表1－058 对氨基苯酚 (61)表1－059 醋酸乙酯 (62)表1－060 对氯硝基苯 (63)表1－061 氮气 (64)表1－062莠去津 (65)表1－063 扑草净 (66)表1－064 八氯二丙醚 (67)表1－065 硫化钠 (68)表１－066 异丙醇 (69)表１－067 丙酮 (70)表１－068 二氯丙烷 (71)表１－069 环己酮 (72)表１－070 乙酸异戊酯 (73)表1－071 锌粉 (74)表1－072 乙醇 (75)表1－073 次氯酸钠溶液 (76)表1－074 石脑油 (77)表1－075 双环戊二烯 (78)表1－076 乙酸丁酯 (79)表1－077 双氧水 (80)表1－078 丙烯酸丁酯 (81)表1－079 丙烯酸 (82)表1－080 苯乙烯 (83)表1－081 过硫酸铵 (84)表1－082 过硫酸钾 (85)表1－083 丙烯酰胺 (86)表1－084 甲醛 (87)表1－085 甲基丙烯酸甲酯 (88)表1－087 汽油 (90)表1－088 乙酸 (91)表1－089 丙烯酸树脂 (92)表1－090 丙烯酸清漆 (93)表1－091 丙烯酸漆稀释剂 (94)表1－092 丙烯酸磁漆 (95)表1－093 二乙醇胺 (97)表1－094 煤油 (98)表1－095 漂白粉 (99)表1－096 漂粉精 (100)表1－097 三氯异氰尿酸 (101)表1－098 松香 (102)表1－099 松节油 (103)表1－100 硫化钠 (104)表1－101 保险粉 (105)表1－102 7385聚氨酯清漆（分装） (106)表1－103 甲酸 (107)表1－104 乙酸乙二醇乙醚 (108)表1－105 H－3聚氨酯漆固化剂 (109)表1－106 聚氨酯漆稀释剂 (110)表1－107 263醇酸树脂 (111)表1－108 异噻唑啉酮 (112)表1－109 N-乙基苯胺 (113)表1－110苯胺 (114)表1－111 乙酰甲胺磷 (115)表1－112 亚磷酸 (117)表1－113 亚磷酸二甲酯 (118)表1－114 氯甲烷 (119)表1－115 乙醚 (120)表1－116 丙烯酸甲酯 (121)表1－117 一甲胺 (122)表1－118 硝酸镁 (123)表1－119 硫化氢 (124)表1－120 硫化铵 (125)表1－121 一甲胺水溶液 (126)表1－122 兔宝宝面漆 (127)表1－123 兔宝宝稀释剂 (128)表1－124 硫氢化钠 (129)表1－125丙酸 (130)表1－126乙酰氯 (131)表1－127丙酰氯 (132)表1－128 丁醇 (133)表1－129 醇酸调合漆（未列名） (134)表1－130 硝酸钠 (136)表1－131 溴甲烷 (137)表1－132 磷化铝 (138)表１－133 正丁醇 (139)表１－134 硝基木器漆 (140)表１－135 硝化棉（含氮≤12.6％） (141)表１－136 单丁醚 (142)表1－137 砷 (143)表1－138 碘化汞 (144)表1－139 氯化汞 (145)表1－140 叠氮化钠 (146)表1－141 重铬酸钠 (147)表1－142 高锰酸钾 (148)表1－143 氰化金钾 (149)表1－144丙烯酸 (150)表1－145甲基丙烯酸甲酯 (151)表1－146苯乙烯 (152)表1－147丙烯酸丁酯 (153)表1－148丁醇 (154)表1－149偶氮二异丁腈 (155)表1－150甲基丙烯酸异丁酯 (156)表1－151 甲基丙烯酸（正）丁酯 (157)表1－152 乙酰丙酮 (158)表1－153 2－丁酮 (160)表1－154 生松香 (161)表1－155 硫酸铜 (162)表1－155 硝酸 (163)表1－155 氰化钾 (164)表1－156硝基苯 (165)表1－157 氟化钠 (166)表1－158 氢氟酸 (167)表1－159蓄电池（注有酸液） (168)表1－160 环氧树脂 (169)表1－161 氯苯 (170)表1－162 乙苯 (171)表1－163 樟脑 (172)表1－164 赛璐珞 (173)表1-165 氢氧化钾 (174)表1-166 乙酸丁酯 (175)表1－001 乙炔气表1－002 氧气表1－003 二氧化碳表1－004 氢气表1－005 氩气表1－006 甲烷表1－007 四氢噻吩表1－008 活性炭活性炭 C 12.0Active carbon别名：Activated chlarcoal危规分类及编号：自燃物品。
芬欧蓝泰标签推出系列食品级标签材料
芬欧蓝泰标签推出系列食品级标签材料
佚名
【期刊名称】《今日印刷》
【年(卷),期】2016(0)8
【摘要】近期，芬欧蓝泰标签在欧洲市场上推出了一系列能确保食品安全的标签材料：PPWhiteFTC60薄膜材料和食品级的VANISH系列超薄面材。
PPWhiteFTC60是一款多用途、表面涂布的薄膜材料．专门针对苛刻的应用环境而设计．具有耐水、耐化学和耐油性。
VANISH系列超薄面材的问世，使创新的食品标签设计有了用武之地，它可以在硬质塑料、玻璃包装上使用，具有杰出的装饰效果。
与其他透明薄膜相比，VANISH系列面材可使用更少的材料．更经济，更适合可持续发展。
【总页数】1页(P10-10)
【关键词】标签设计;薄膜材料;食品级;可持续发展;食品安全;欧洲市场;表面涂布;硬质塑料
【正文语种】中文
【中图分类】TS896
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2.芬欧蓝泰推出不含APEO的标签材料 [J],
3.芬欧蓝泰标签推出新型数码印刷标签材料 [J],
4.芬欧蓝泰标签在欧洲市场推出湿纸巾市场应用的标签材料 [J],
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因版权原因，仅展示原文概要，查看原文内容请购买。
Ficoll 400产品说明书
Product Information SheetFicoll ® 400Catalog Number F4375Product DescriptionFicoll 400 is a highly branched polymer formed by the copolymerization of sucrose and epichlorohydrin. Ficoll 400 is completely non-ionic. Because of the abundance of hydroxyl groups, Ficoll 400 is veryhydrophilic and extremely water-soluble. The most common application for Ficoll 400 is as a density gradient medium for the separation and isolation of eukaryotic cells, organelles, and bacterial cells. Density ranges up to 1.2 g/ml can be attained. It has also been utilized in a variety of other applications.Precautions and DisclaimerFor R&D use only. Not for drug, household, or other uses. Please consult the Safety Data Sheet for information regarding hazards and safe handling practices.Physical PropertiesAppearance: White to off-white powder Loss on drying: Not more than 5%1 Molecular Weight: 400,000 +/- 100,000 asdetermined by intrinsic viscosity 1 Specific Rotation: +56.5 at 20 C (C=1% inwater)1 Intrinsic viscosity: approximately 0.17 dl/g 1 Dialyzable material including NaCl: less than1%1 Stokes Radius: approximately 10 nm 1Unlike sucrose, solutions of Ficoll haverelatively low osmolality. Despite this, the density of Ficoll in aqueous solutions is comparable to that of sucrose.Because of the high molecular weight and low content of dialyzable material, Ficoll has a much lower permeability towards cell membranes than sucrose. Therefore, cells can be expected to collect at a lower density in Ficoll gradients than in sucrose gradients. Because of its low membrane permeability and low osmotic pressure, separations in Ficoll normally result in better preservation of cell function and morphology.Storage/StabilityStored at room temperature, Ficoll 400 can be expected to have a shelf-life of 5 years. Concentrations of 50% (w/v) can be attained in water. Ficoll should be added slowly with constant stirring.Sigma tests the solubility of Ficoll 400 at 1 g in 10 ml of deionized water yielding a clear to slightly hazy, colorless to faint yellow solution. Ficoll is stable in alkaline andneutral solutions. At pH values below 3, it is rapidly hydrolyzed, particularly at elevated temperatures. Ficoll can be sterilized by autoclaving at a neutral pH, at 110 C for 30 minutes. Strong oxidizing and reducing agents are to be avoided.ProcedureCentrifugationFicoll 400 can be used for gradientcentrifugation in all types of centrifuge rotors and for separation at unit gravity. For centrifugation, both discontinuous and continuous gradients are possible.Discontinuous gradients offer two main advantages: First, the abrupt changes in Ficoll 400 density mean that isolated cells are found in sharp bands at the interface between layers of different densities. This allows for easy removal of the sample with a pipette. Second, cells with great differences in density can be easily isolated with as few as two density layers. This is achieved by choosing densities which will prevent one or more cell types from entering the lower phase, banding these cell types at theinterface. To estimate the densities required for a particular application, consult Table 1. The graph of densities of Ficoll as a function of concentration is also provided.Table 1Preparing a discontinuous gradient1. Prepare Ficoll 400 in buffer or isotonicsucrose solution (0.25 M) atconcentrations which should separate the material of interest. Most cells and organelles have a buoyant densitybetween 1.0 and 1.2 g/ml in Ficoll 400. Often a two-layer gradient is sufficient. Solutions made at this step may be stored in the refrigerator but should be used at room temperature.2. In standard centrifuge tubes, makelayers (approximately 1 cm deep) with the densest layer on bottom.3. Taking care not to mix the layers of thegradient, carefully layer the sample on top. Stir the sample and the uppermost Ficoll 400 layer gently with a glass rod to eliminate the interface before centrifugation.During centrifugation the various particles will collect either in or between the Ficoll layers, depending on their density. Upon completion of centrifugation, pipette off the various phases and remove the Ficoll from the fractions of interest. Ficoll may beremoved from isolated cells and organelles by repeated cycles of dilution with bufferfollowed by centrifugation. Residual amounts of Ficoll 400 in the sample can be estimated with the anthrone reaction.2In some instances, a continuous or linear density gradient may be desired. This can be easily prepared using a gradient mixer. For simple separations, a homologous Ficoll 400 solution without a gradient can be used. Fractionation is accomplished by stepwise increases in centrifugation speed. Ficoll has also been employed in zonal centrifugation studies.3Unit gravity sedimentation through a density gradient is widely used to separate cells which are sensitive to centrifugation. Cells with similar densities but different sizes can also be efficiently separated at unit gravity.4,5,6Nucleic Acid HybridizationFicoll 400 is a constituent of Denhardt’ssolution used in Northern and Southern blot analysis. Ficoll reduces non-specific binding of material to nitrocellulose membranes during nucleic acid hybridization.7Sigma offers Denhardt’s Solution, 50× concentrate (Catalog No. D2532) which is tested for use in nucleic acid hybridization. Typical hybridization solutions require a 5× concentration of Denhardt's solution.Immunological ApplicationsFicoll 400 has been employed as a hapten carrier, and has been conjugated todinitrophenol, trinitrophenol, and fluorescein isothiocyanate for the purpose of enhancing primary immune response in mice. Conjugates with a range of substitution levels and minimal toxicity are easily prepared.8,9Chemically Defined Cell Culture MediaFicoll is used with and without serum-derived growth factors to support the growth of both primary cultures and established cell lines.10,11Concentration DialysisFicoll 400 is useful for concentratingsolutions by dialysis since its high molecular weight prevents it from crossing the dialysis membrane. Osmotic pressure draws water across the membrane into the solution of Ficoll 400, effectively concentrating sensitive materials.1ElectrophoresisContinuous flow electrophoresis usually requires a stabilizer in the electrolyte. Ficoll 400 is often used for this application.12,13Phase PartitioningPhase partitioning separates cells on the basis of surface properties. Ficoll 400 is combined with polyethylene glycol in two-phase systems, and with dextran and polyethylene glycol in three phase systems.14,15Physiological Perfusion and Cell Stabilization SolutionsFicoll has been added to physiological saline perfusate during monitoring of protein excretion in vessels.Vitrified mouse embryos have been diluted with solutions containing 30% Ficoll plus 0.5 M sucrose.17 Isolated rat kidneys were perfused with Tyrode’s solution containing 4.7% Ficoll 400.18Cited References1. Supplier Data2. Scott, T.A. and Melvin, E.H., Anal.Chem ., 25, 1656 (1953). 3. Lavrenko, P. N. et al., Anal. Biochem .,166, 287 (1975). 4. Tulp, A. et al . Anal. Biochem ., 67, 11(1975). 5. Bont, W.S. et al ., J. Immunol. Methods ,29, 1 (1979). 6. Niskanen, E. et al ., Cell Tissue Kinet ., 18,399 (1985). 7. Sambrook, J. et al., Molecular Cloning: ALaboratory Manual, Cold Spring Harbor Laboratory (1989), p. 9.48 - 50, B.15. 8. McMasters, P. R. B. et al .,Immunochemistry , 14, 189 (1977). 9. Inman, J.K., J. Immunol ., 114, 704(1975).10. Clark, J., in Hormonally Defined Media,Lecture Posters, Eur. Conf. Serum-Free Cell Culture, Fisher, G. and Wieser, R.J., (eds), Springer (Berlin), 6 (1983). 11. Kao, K. N., Z. Pfanzenphysiol. Bd ., 103,437 (1981). 12. Platsoucas, C. D. and Catsimpoolas, N.,J. Immunol. Methods , 34, 31 (1980). 13. Platsoucas, C. D. et al., Cell. Immunol .,51, 238 (1980). 14. Johansson, G. and Loelsson, M.J., J.Chromat ., 464, 49 (1989). 15. Albertson, P. A. and Birkenmeier, G.,Anal. Biochem ., 175, 154 (1988). 16. Nolly, H. and Nolly, A., Biol. Res ., 31(3),169 (1998). 17. Mukaida, T. et al ., Hum. Reprod ., 13,2874 (1998). 18. Barthelmebs, M ., Arch. Mal. Coeur.Vaiss., 91, 1083 (1998).Other ReferencesCell separationGonadal primordial germ cells Hong Y.H. et al., Transgenic Res ., 7, 247(1998) Red blood cellsAtawodi, S.E. et al ., Cancer Epidemiol. Biomarkers Prev ., 7, 817 (1998) Fetal nucleated red blood cellsOosterwijk, J.C., Prenat. Diagn .,18, 1082 (1998)Peripheral blood cellsKrackhardt, A. et al ., Exp. Hematol ., 26, 1265 (1989)Peripheral blood mononuclear cellsWoods, J. A. et al., J. Gerontol. A. Biol. Sci. Med. Sci., 53, B430 (1998)Schlenke, P., Clin. Diagn. Lab. Immunol ., 5, 808 (1998)Hull. D.R., Ren. Fail ., 20, 607 (1998) LymphocytesKrieger, K. et al ., Pharmacopsychiatry ., 31, 193 (1998)Pancreatic islet cellsBrandhorst, H. et al ., Cell. Transplant ., 7, 489 (1998)Lakey, J.R., Transplant ., 7, 479 (1998) Yeast vacuolesVida, T.A., J. Cell Biol ., 111, 2871 (1990) ProteolysosomesShrishailam, Y. et al ., Proc. Natl. Acad. Sci . USA, 84, 246 (1987) Murine bone marrow cellsSchneider, E. et al., J. Immunol ., 139, 3710 (1987) CytoplastsVolloch, V. et al ., J. Cell Biol ., 105, 137 (1987)Related ProductsFicoll 70, Catalog No. F2878Ficoll solution, Type 400, 20% in H 2O,Catalog No. F5415 Ficoll 400 BioXtra, Type 400-DL, lyophilizedpowder, Catalog No. F1418 Ficoll 400 Type 400-DL, lyophilized powder,Catalog No. F9378 Ficoll 400 lyophilized powder, γ-irradiated,BioXtra, suitable for cell culture, Catalog No. F8636 Ficoll 400 BioXtra, for molecular biology,lyophilized powder, Catalog No. F2637NoticeWe provide information and advice to our customers on application technologies and regulatory matters to the best of our knowledge and ability, but without obligation or liability. Existing laws and regulations are to be observed in all cases by our customers. This also applies in respect to any rights of third parties. Our information and advice do not relieve our customers of their own responsibility for checking the suitability of our products for the envisaged purpose.The information in this document is subject to change without notice and should not be construed as a commitment by the manufacturing or selling entity, or an affiliate. We assume noresponsibility for any errors that may appear in this document.Contact InformationFor the location of the office nearest you, go to /offices.Technical ServiceVisit the tech service page on our web site at /techservice.Standard WarrantyThe applicable warranty for the products listed in this publication may be found at/terms.F4375 Product Information Sheet Rev 03/2021The life science business of Merck operatesas MilliporeSigma in the U.S. and Canada.。
甲酸烯丙酯的理化性质及危险特性表
标识
别名:
无资料
危险货物编号：
32125
英文名：
Allyl formate
UN编号：
2336
CAS号：
1838-59-1
分子式：
C4H6O2
分子量：
86.09
理化 性质
外观与性》
犬：
无色液夕
主要用途：
用于有机合成。
熔点（C）：
无资料
相对密度（水=1）：
0.95
沸点（℃）：
③运输考前须知：铁路运输时应严格按照铁道部《危险货物运输规那么》中的危险货物配装 表进行配装。运输时运输车辆应配备相应品种和数量的消防器材及泄漏应急处理设备。夏 季最好早晚运输。运输时所用的槽（罐）车应有接地链，槽内可设孔隔板以减少震荡产生 静电。严禁与氧化剂、酸类、碱类、食用化学品等混装混运。运输途中应防曝晒、雨淋， 防高温。中途停留时应远离火种、热源、高温区。装运该物品的车辆排气管必须配备阻火 装置，禁止使用易产生火花的机械设备和工具装卸。公路运输时要按规定路线行驶，勿在 居民区和人口稠密区停留。铁路运输时要禁止溜放。严禁用木船、水泥船散装运输。
83.0
相对蒸汽密度（空气=1）：
无资料
闪点（℃）：
无资料
饱和蒸汽压（kPa）：
无资料
引燃温度（℃）：
无资料
爆炸上限/下限［%（v/v）］：
无资料
临界温度（℃）：
无资料
临界压力（MPa）：
无资料
溶解性：
不溶于水，溶于乙醇。
毒性
LD50：124mg/kg（大鼠经口）;136mg/kg（小鼠经口）LC50：14000mg/m32小时（小鼠吸入）
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含有异氰酸酯，参考供应商提供的信息
分类系统
根据最近版本的欧洲联盟检测标准而分类，并以公司和文献数据扩展。
4.急救措施
吸入后：将患者移至新鲜空气区并尽快就医。 万一患者处于无意识，要侧位放置于交通工具上； 呼吸新鲜空气，咨询医生。 皮肤接触：尽快用大量的清水和肥皂水擦洗 眼睛接触：睁开眼睛并用流动水长时间冲洗 ，就医。 吞入：尽快就医 5.消防措施 合适的灭火材料：用二氧化碳，干粉或水来灭火，火大时可用水喷射。 利用适合周边环境的灭火方法。 防护装置 ：无
危害标志 ：
42/43 吸入和皮肤接触可能会导致刺激过敏
安全标志 ：
23 禁止吸入浮质（空气中弥漫的粉尘/蒸汽/烟雾）
24 避免与皮肤接触 26 如果与眼睛接触，尽快用大量清水冲洗，遵遗嘱。
37 戴防护手套 45 如发生意外或感觉不舒服，立即就医（拿出产品的标签）
60 此材料和包装物必须按照危害物处理
效的合同关系。
相关 R 值：
20 吸入有危害 36/37/38 可能刺激眼睛、皮肤和呼吸系统
42/43 吸入或皮肤接触可能会导致过敏
特定标签的准备
含有异氰酸酯：参考制造商的供应信息
国家法规：
根据现行有关危险物质的条例，该产品必须贴上标签。
技术指示（空气）：
级别
份额%
1级
1-5
对水危害级别：1 级（自我评估）：对水是稍量危害的
EU-VOC: 0.00%
16. 其他信息
此信息建立于目前的知识基础上。这并不构成对任何特定产品特性的担保并且不建立一个法律上有
材料安全数据 MSDS
91/155EEC(2001/58/EC)
材料名称：TOGOCOLL F500
12. 生态学资料 生态毒性
页码：第 4 页 共 5 页 制定：2007.09.07
海产品毒性 101-68-8 4，4-二苯基甲烷二异氰酸酯 LC50 >100 mg/l (鱼) 概要注释 ： 水危害为 1 级：（德国标准）（自我评估）：对水是稍量危害的 禁止将未稀释或大量的产品倒入地下水、水资源或污水系统 13. 废弃处置 产品建议 ： 必须与普通废弃物分开，不允许流入下水道。 欧洲废料处理目录： 08 00 00 制造商在生产、设计、运输和使用中形成的废料，如相关涂料（油漆、清漆和玻璃
2．成分 /组成信息
化学特性
描述 ：下列无危害添加物的共混
CAS 编号 28553-12-0 EINECS 编号:249-079-5
邻苯二甲酸酯
25-50%
CAS 编号 1333-86-4
炭黑
25-50%
EINECS 编号:215-609-9
CAS 编号 101-68-8 EINECS 编号:202-966-0
页码：第 2 页 共 5 页 制定：2007.09.07
储存 ：
合适 存储容器和空间要求 ：无
统一存储措施信息：无
储存条件的进一步信息：无
存储最高温度：35℃
存储最低温度：0℃ 8. 暴露控制/个人防护
有关数据设施设计的额外资料，没有进一步数据； 请参照条款 7.
工作现场需要监测成分的最小值如下：
28553-12-0 邻苯二甲酸酯
材料安全数据 MSDS
91/155EEC(2001/58/EC)
材料名称：TOGOCOLL F500
1．化学品及企业标识 产品细节 商品名称：TOGOCOLL F500 产品名称：单组份聚氨酯玻璃胶 供应商名称：长春依多科化工有限公司 进一步信息了解：请拨：+86 431 85080800
页码：第 1 页 共 5 页 制定：2007.09.07
质的珐琅等）粘接剂、密封胶和印刷油墨等。 08 04 00 从使用粘接剂和密封胶中产生的废料（包括防水产品） 08 04 09 包含有机溶剂或其他危害物质的粘接剂和密封胶的使用中产生的废料 不清洁的包装建议：必须根据官方的相关规定予以处理。 14. 运输资料 陆运 ADR/RID (转换箱) ADR/RID 级别：-----海运 IMDG： IMDG 级别：------海运污染：无 空运 ICAO-TI 与 IATA-DGR ICAO/IATA 级别：-------
反应危害性：无
危害性分解产物：无
11. 毒理学资料 急性 毒性
LD/LC50 相关数值如下：
101-68-8 4，4-二苯基甲烷二异氰酸酯
口服
LD50
4700mg/kg(鼠类)
吸入
LC50/4h 370mg/l (鼠类)
主要刺激 性影响： 对皮肤的影响：无 对眼睛的影响：无 致敏 性；通过吸入或皮肤接触可能会引起过敏 附带毒理学资料： 根据有关配制的一般欧盟分类指南的计算方法（最新版本），该产品没有多分类限制， 此产品具有以下危害： 有害性 刺激性
材料安全数据
MSDS
91/155EEC(2001/58/EC)
材料名称：TOGOCOLL F500
页码：第 5 页 共 5 页 制定：2007.09.07
15. 法规信息
EU 标签指导方针：产品根据 EU 危害化学品指示和法令规定，贴上分类等明显标记。 产品编码和危害标志：
标志 Xn：有害性
标签中危害成分描述：4，4-二苯基甲烷二异氰酸酯。
爆炸危害：
本产品无爆炸危害
爆炸极限： 气压（20℃）： 密度（20℃）：
低值：0.1Vol%; 高值：0.2Vol% 0.0hPa 1.20g/cm3
溶解性/与水： 不易溶或很难混合 有机溶剂含量： 0.0%
固含量：
99.0%
10. 稳定性及反应活性 热降解/可避免状态：如果遵照规格使用则不会分解。
材料安全数据 MSDS
91/155EEC(2001/58/EC)
材料名称：TOGOCOLL F500
6.意外疏散措施 个人安全预防：无 环境保护措施：防止渗漏入地下水、工作场所和地下室 清洁 /收集措施 ：机械性的收集；确保足够的通风 7.操作处置与储存 操作处置 ： 安全操作注意事项：无需特殊措施 火灾与爆炸的防护措施：无
4，4-二苯基甲烷二异氰酸酯 Xn， R20-36/37/38-42/43
1-5%
附加信息：关于危害标志请参考条款第 16 条。
3.危害性鉴定： 危害描述
标志：Xn— — 有害性
对人与环境危害的详细描述
根据最近有效译文：“EU 常用危险化学品的化学分类及标志”，此产品可根据计算程序贴标。
有麻醉效应
R42/43 吸入或皮肤接触可能会引起致敏性
材料安全数据 MSDS
91/155EEC(2001/58/EC)
材料名称：TOGOCOLL F500
9. 理化特性
页码：第 3 页 共 5 页 制定：2007.09.07
总体信息
形状：
流动性
颜色： 气味
黑色 特有气味
条件改变
熔点/熔点区域： 沸点/沸点区域： 闪点： 燃点： 自燃点：
未决定 2Байду номын сангаас8℃ >150℃ 375.0℃ 本产品无
检测值
长期数值：5mg/m3
1333-86-4 检测值
炭黑
短期数值：7mg/m3 长期数值：3.5 mg/m3
101-68-8 4，4-二苯基甲烷二异氰酸酯
检测值
短期数值：0.07mg/m3
含有 NCO 成分
长期数值：0.02 mg/m3
附加信息：制作期间有效的清单将作为基础来使用。
个人防护用品： 普通防护和卫生措施： 远离食品、饮料和粮食， 立即脱掉弄脏和污染的衣服；休息和结束工作时请立即洗手 呼吸系统保护：无 手防护： 防护手套的合适材料：橡胶手套 手套材料可渗透时间：可由防护手套的制造商观察检测 眼睛防护 ：使用时佩戴护目镜