用系统命名法命名下列化合物

Engineering, Northwest Normal University
(10) A H3C
MgBr
B + C H3C
(11) A (CH3)2CH
+ C2H5OMgBr
NO2
Cl B (CH3)2C
Br
Br
(12) A CH3CH2CH CH2
C CH3CHCH CH2 C6H5
Hale Waihona Puke Baidu
B CH3CHCH CH2 Br
5．写出下列反应的产物：
CHClCH3
(1)
+ H2O NaHCO3
Cl
(2) HOCH2CH2CH2Cl + HBr
丙酮 (3) HOCH2CH2Cl + KI
Br
(4)
+ Mg 乙醚
Cl
(5)
+ NBS
CCl4 引发剂
CH3
O
ZnCl2
(6)
+ HCH + HCl 西北师范大学化学化工学院
College of Chemistry and Chemical
CHCH3 Cl
CHBr CHCH3 CH3CHCH3
Br (3)进行SN2反应速率：
CH3CH2CH2Br
CH2CH2Cl
CH3 H3C C
西北师范大学化学化工学院 College of Chemistry and Chemical Engineering, Northwest Normal University
NO2
6．将以下各组化合物，按照不同要求排列成序： (1)水解速率：
CH3CH2
Cl
(2)与AgNO3-乙醇溶液反应难易程度
2．写出符合下列名称的构造式：
（1）叔丁基氯 （2）烯丙基溴（3）苄基氯（4）对基苄基氯
答案：
2. (1) CH3
CH3 C Cl CH3
(2) CH2 CH CH2Br
(3)
CH2Cl (4) Cl
CH2Cl
西北师范大学化学化工学院 College of Chemistry and Chemical Engineering, Northwest Normal University
Br
CHCH3 + CH3C C-Na+
Br
CHCH3 + AgNO3 C2H5OH
Br
CHCH3 + C2H5ONa
CN CHCH3
NH2 CHCH3
CH3 CHC CCH3 + NaBr ONO2 CHCH3 + AgBr
OC2H5 CHCH3
西北师范大学化学化工学院 College of Chemistry and Chemical Engineering, Northwest Normal University
4．用方程式表示a-溴代乙苯与下列化合物反应的主要产物。
(1) NaOH(水) (3) Mg、乙醚 (5) 产物（3）+CH (7) NH3 (9) AgNO3、醇
(2) KOH(醇) (4)NaI/丙酮 CH (6) NaCN (8)CH3C C-Na+ (10) C2H5ONa
西北师范大学化学化工学院 College of Chemistry and Chemical Engineering, Northwest Normal University
5. (1) Cl (4) Cl
OH
CH CH3 (2) BrCH2CH2CH2Cl (3) HOCH2CH2I
Br
MgBr
(5)
(6) H3C (8) CH4 (9) A
CH CHBr
CH2Cl
(7)
CH2CN
+ CH3C CMgI
CH3
CH3
H3C
O
Br B
C
O
Br
西北师范大学化学化工学院
O
College of Chemistry and Chemical
答案：
1. (1)2,2,4-三甲基-4-溴戊烷 (2)2-甲基-4-氯-2-溴己烷
(3)2-溴-1-己烯-4-炔 (5)顺-1-氯-3-溴环己烷
(4)(Z)-1-溴丙烯
西北师范大学化学化工学院 College of Chemistry and Chemical Engineering, Northwest Normal University
CH3 Cl 答案： 3. (1) CH3CHCH2CHCH3
C6H13-n
(3) H
Br
CH3
(2) (4) CH
Br Cl CCHCH
C2H5
CH2CH2CH3 CCH CH2
西北师范大学化学化工学院 College of Chemistry and Chemical Engineering, Northwest Normal University
3．写出下列有机物的构造式，有“＊” 的写出结构式：
(1) 4-chloro-2-methylpentane (2) ＊cis-3-bromo-1-ethylcyclohexane
(3) ＊(R)-2- bromooctane
(4) 5- chloro-3-propyl-1,3-heptadien-6-yne
HC CH 西北师范大学化学化工学院
College of Chemistry and Chemical
Engineering, Northwest Normal University
CH2CH3 + HC CMgBr
(6) (7) (8) (9) (10)
Br CHCH3 + NaCN
Br
CHCH3 + NH3
Engineering, Northwest Normal University
(7)
CH CHBr KCN CH2Cl
(8) CH3C CH + CH3MgI
O
(9)
CH3 + Br2
CH CH
C C
O
NaOH,乙醇
A
B
O
C
(10) CH3
Br Mg 无水乙醚
A C2H5OH B + C
(11) (CH3)2HC
答案：
4. (1) (2)
(3) (4)
(5)
Br CHCH3 + NaOH H2O
Br CHCH3 + KOH C2H5OH
Br CHCH3 + Mg C2H5OC2H5
Br CH3COCH3
CHCH3 + NaI
OH CHCH3
CH CH2 MgBr CHCH3
I CHCH3
MgBr
+ CHCH3
Fe
光
NO2 + Br2
A
B
Cl2
(12) CH3CH2CH2CH2OH H2SO4 A NBS B 引发剂
西北师范大学化学化工学院 College of Chemistry and Chemical Engineering, Northwest Normal University
CuLi
2
C
答案：