钙钛矿薄膜的形貌控制与研究进展

商丘师范学院学士学位毕业论文
钙钛矿薄膜的形貌控制与研究进展
目 录
摘要与关键词 .......................................................................II 0 引言 .............................................................................1 1 钙钛矿型太阳能电池的介绍 .........................................................1 1.1 钙钛矿晶体结构 ................................................................1 1.2 钙钛矿太阳能电池的结构 .......................................................2 1.3 钙钛矿太阳能电池工作原理 .....................................................3 2 钙钛矿薄膜的介绍及制备方法 ........................................................4 2.1 钙钛矿薄膜制备方法的演化 ......................................................4 2.1.1 一步法 ....................................................................4 2.1.2 两步法 ....................................................................4 2.1.3 双源蒸汽沉积法 ............................................................5 2.1.4 蒸汽辅助溶液加工法 ........................................................5 3 影响钙钛矿薄膜的因素 .............................................................5 3.1 退火升温速率对钙钛矿薄膜结晶性的影响 ..........................................5 3.2 溶剂对钙钛矿薄膜结晶性的影响 ..................................................6 4 总结与展望 .......................................................................6 参考文献 ...........................................................................8 致谢 ...............................................................................9
I

商丘师范学院学士学位毕业论文
钙钛矿薄膜的形貌控制与研究进展
摘 要
无机-有机钙钛矿太阳能电池因其廉价的液相制备方法和很好的光电转化性能，备受研究者们的 关注。因其具有很好的吸光性、较高的载流子迁移率，且其能带可调并能进一步地应用多种加工方 法进行改性，在近几年的研究中，其光电转化效率已从起初的 3.8%提升至 22.1%，所得模块器件的 效率高达 8.7%， 已经远高于多数其他种类的太阳能电池。 基于对相关光电材料的研究和进一步优化， 钙钛矿太阳能电池的性能还有很高的提升空间。本文基于文献调研，针对近年来钙钛矿材料应用于 太阳能电池的发展情况，重点总结了作为吸收层的钙钛矿薄膜材料的制备方法和影响因素，并分析 了其未来发展中将面临的问题和发展前景。
关键词
钙钛矿；太阳能电池；光电转化；薄膜
Research progress in morphology control of perovskite thin films
Abstract
Inorganic-organic perovskite solar cells has been taken attention by researchers due to low price of liquid preparation methods and good photoelectric conversion performance. In recent years, the photoelectric conversion efficiency of perovskite solar cells has been increased from the beginning 3.8% to 22.1%, The module device efficiency is as high as 8.7%. is much higher than most other types of solar cells, because of its good optical absorption, high carrier mobility, and the band is adjustable and the variety of processing methods for modification. Based on the related research of photoelectric materials and further optimization of perovskite solar cells, the performance of the solar cells still have a high room for improvement. In this paper, based on the literature research, aimed to the development of perovskite materials used in solar cells, the preparation methods and influence factors of perovskite thin films are emphatically summarized. We also discussed the facing problems of future development and development prospects.
Keywords
Perovskite; solar cell; photoelectric conversion; thin film
II