Strongly Asymmetric Tricriticality of Quenched Random-Field Systems
强形变收缩核英语
强形变收缩核英语
使用强形变收缩核英语(Strongly Contracting Nuclide English,简称 SCNE)可以突破普通英语语言表达的局限,为跨文化和语言交流提供更为有效的沟通管道。
SCNE最大的特点是可以使用高度简缩的现代原子物理术语来描述原子的大小、结构和属性,这在跨文化背景下显得尤为重要。
SCNE旨在创建一种可以跨越语言障碍的内容标准,它利用对原子有效率解释
的符号、缩写和词汇,不仅缩减了传统英语所面临的文字混乱,而且更容易让读者把握核物理学的相关内容。
另外,使用 SCNE 可以缩短文字的表达长度,加快文字的沟通速度,保持语义的完整性。
若是将SCNE 用于电子邮件和社交媒体,就可以更加容易的传达内容,把更多的信息通过较少的字符进行传播,特别适用于工程师和媒体行业。
SCNE 并不适用于所有的专业领域,大多数准确性要求较高的行业,例如法律、财税和社会学,不适宜使用它。
尽管如此,SCNE 在原子物理学上仍然显得很有用,包括短篇小说、专业著作以及技术文件,可以使这些类型的文本更容易理解、传播和沟通。
总而言之,SCNE 作为一种跨文化交流技能,在现代社会发挥着极为重要的作用,无论是在现代通讯技术发展的速度加快,以及跨文化交流的需求不断增加的情况下,它的重要性都会变的愈发突出。
沃森和克里克发表的文章的翻译
核酸的分子结构——脱氧核糖核酸的结构我们希望证明脱氧核糖核酸盐(DNA)的结构,这种结构具有相当的生物感兴趣的新的特点。
Plauling和Corey已经提出了一种核酸结构。
他们非常友好的在其出版之前将手稿提供给我们。
他们的模型包括三个缠绕的链,与附近的糖磷酸骨架和外面的碱基。
我们认为,这种结构不理想,原因有二(1)我们相信,该材料赋予的透视图是盐,。
没有酸性氢原子,目前还不清楚是什么力量将持有的结构在一起,尤其是会互相排斥。
(2)有些距离显得有些过于小。
另三链结构也已由弗雷泽提出(在印刷中)。
在他的模型磷酸盐是在外面和内部的基础上通过氢键连接在一起。
这种结构的描述是相当不明确的,基于这个原因,我们不会对此发表评论。
我们希望提出根本不同的结构的脱氧核苷酸盐,这种结构有双螺旋且每个圈都有相同的轴线(看图)。
我们已经做出一般的化学假设,即核苷酸之间通过3'到5'磷酸二酯键连接到β- d-脱氧核糖核酸残基上。
这两条链都是右手螺旋。
但是由于这两个沿链相反的方向运行,这两条链是非常相似的。
每个链松耦合类似于Furberg的1号模型,这就是,碱基位于双螺旋的内部而磷酸盐位于外部。
糖及附近的原子结构接近Furberg 的标准配置,糖是大致垂直于与之接触的碱基。
在Z方向每一个链每隔3.4A就有一个碱基。
我们假设在同一链中相邻的核苷酸夹角为36 °,所以每条链的结构每十个核苷酸即每34A就重复一次。
一个磷原子到纵轴的间距为10A,由于磷在外面的,阳离子容易接触到他们。
其结构是一个开放的,它的水分含量是相当高的,在较低的水含量,我们希望碱基能够倾斜,这样的结构可能变得更加紧凑。
该结构新颖特点是这两条链的嘌呤和嘧啶碱基连接在一起的方式。
碱基的平面垂直于纵轴。
碱基配对,一条链的碱基和另一条链的碱基以氢键连接,因此两个碱基能够完全一致吻合,为了氢键的生成一对碱基中必须是一个是嘌呤另一个是嘧啶,碱基是如下生成的:嘌呤的1位置和嘧啶的1位置,嘌呤的6位置和嘧啶的6位置。
专业英语
Definition of polymers A simple understanding of polymers can be gained by imaging them to be like a chain or, perhaps, a string of pearls, where the individual pearl represent small molecules that are chemically bonded together. Therefore, a polymer is a molecule made up of smaller molecules that are joined together by chemical bonds. The word polymer means „many parts or units.‟ The parts or units are the small molecules that combine. The result of the combination is, of course, a chainlike molecule (polymer). Usually the polymer chains are long, often consisting of hundreds of units, but polymers consisting of only a few units linked together are also known and can be commercially valuable.
Figure 1.1 Diagram illustrating the definition of plastics.
As Figure 1.1 shows, all materials can be classified as gases, simple liquids, or solids, with the understanding that most materials can be converted from one state to another through heating or cooling. If only materials that are structural solids at normal temperatures are examined, three major types of materials are encountered: metals, polymers, and ceramics. The polymer materials can be further divided into synthetic polymers and natural polymers. Most synthetic polymers are those that do not occur naturally and are represented by materials such as nylon, polyethylene, and polyester. Some synthetic polymers could be manufactured copies of naturally occurring materials (such as
CISSP ALL in One 生词汇总
CISSP ALL in One 生词汇总speculation n. 思索interpret v.解释,说明,口译,mitigation n. 缓解、减轻、平静methodology n.方法学synthesize v.合成,综合surveillance n.监视iris 【物】(锁)光圈, 可变光阑[光圈]innocent v.无知的;清白的prerequisite n.先决条件;adj.首要必备的subsequent adj.后来的,并发的preventive adj.预防的stability n.稳定性after-the-factcost of qualitydeviation n.背离deviate v.偏离,背离facilitate v.使方便specialist n.专家coaches n.长途汽车;教练v.训练,指导rigid adj.刚硬的,严格的senior adj.高级的approve v.赞成,满意;批准,通过interpersonal adj.人际间的subordinate adj.次要的;n.下属;v.服从briefing n.简报memorandum n.备忘录periodically adv.周期的,定时的overlap v.与…..交迭enforcement n.执行,强制appraisal n.评估,估价,鉴定sensitivity n.敏感criteria n.标准presentationconvincesophisticatetailored adj.剪裁讲究的residual risk 残留风险potential adj.潜在的,可能的n.潜能,潜力,电压encroachment n.侵蚀,侵犯collusion n.共谋,勾结contingency n.偶然,可能性;意外事故vague adj.含糊的,不清楚的proprietary n.所有者,所有权adj.所有的,私有的consortia n.协会,公会,银行团auspice n.预兆,前兆De facto standard n.事实上De jure standardSpeculation n.思索, 做投机买卖rationale n.基本原则consensus n.一致同意,舆论scenario n.想定,特定情节comparison n.比较, 对照, 比喻, 比较关系expectancy n.期望catastrophic adj.悲惨的,灾难的actual adj.实际的,真实的,现行的,目前的undesirable adj.不受欢迎的,不合需要的,令人不不快的monetary adj.金钱的prudent adj.谨慎的mitigation n.减轻,缓解,平静prioritization n.优先次序reputation n.名誉,声望inventory n.存货清单riot n.暴乱, 骚动, (植物, 疾病等)蔓延, 放荡, 暴动v.骚乱, 放纵, 挥霍, 参加骚动disruption 分[碎, 断]裂, 破裂[溃, 坏]爆炸, 中断.击穿.瓦解disgruntle adj.不满的,不高兴的sabotage n/v.阴谋破坏,怠工equipment n.装备,设备,器材,固定资产adequate adj.适当的,足够的labeling n.标签vt.贴标签,分类accreditation n.委派,信赖,鉴定合格spectrum n.光谱,频谱tolerate v.忍受,容忍intrinsic adj.固有的,内在的,本质的acquisition n.获得,获得物issue-specificabsolute assuranceimproper adj.不适当的custodian n.管理人predictable adj.可预言的premise n.前提v.假定,作出前提hierarchical adj.分等级的omission n.冗长ascertain v.确定,探知morale-boosting 振奋士气slogan n.口号,标语exhort v.劝戒,忠告accredit v.信任,授权,归于accredit ation n.委派,信任,鉴定合格constraint n.约束,强制,局促competitive positio adj.易犯错的mandatory adj.命令的,强制的sufficient adj.充分的,足够的penalty n.处罚tangible adj.切实的intangible adj.无形的,不切实的procurement n.获得,取得periodic adj.周期的flux n.涨潮,变迁v.熔化,流出redesign v/n.重新设计foster v.养育,培养,鼓励,报(希望)n.抚养者,鼓励者disseminate v.散布realistic adj.现实(主义)的tactical adj.战术的summary n.摘要,概要revenue n.收入align v.排列,结盟empowerment n.授权perpetuate v.使永存,使不朽sensitivity n.敏感,灵敏度renegotiate v.重新谈判proximity n.接近,亲近impede v.阻止magnetic adj.磁的, 有磁性的, 有吸引力的granularity n.间隔尺寸, 粒度compulsory adj.必须的,被强迫的mandatory adj.强制的,命令的modular adj.模的vague adj.含糊的,暧昧的,不清楚的spell out 清楚的说明negligence n.疏忽diligence n.勤奋ramification n.分支,衍生pornographic adj.色情的gauge n.标准尺,规格v.测量sophisticate n.久经世故的人, 老油条, 精于...之道的人vt.篡改, 曲解, 使变得世故, 掺合, 弄复杂vi.诡辩hiring n.租金, 工钱, 租用, 雇用vt.雇请, 出租vi.受雇holistic adj.整体的, 全盘的espionage n.间谍, 侦探collusion n.共谋, 勾结caliber n.口径, 才干, 器量nondisclosure agreement 保密协议Job rotation n.工作轮换vengeful adj.复仇心重的, (利于)报复的lash out v.猛击, 急速甩动tangible adj.切实的explicit adj.外在的, 清楚的, 直率的, (租金等)直接付款的liaison n.联络, (语音)连音sabotage n.(不满的职工或敌特等的)阴谋破坏, 怠工, 破坏vi.从事破坏活动vt.对...采取破坏行动, 妨害, 破坏stifle vt.使窒息, 抑制vi.窒息, 闷死intangible adj.难以明了的, 无形的intangible asset n.无形资产regulatory adj.调整的violation n.违反, 违背, 妨碍, 侵害, [体]违例, 强奸incentive n.动机adj.激励的custodian n.管理人verbatim adj.逐字的be doable 可做的, 可行的enforceable adj.可强行的, 可强迫的,可实施的phase in v.逐步采用humidity n.湿度terrorist n.恐怖分子circumstance n.环境,详情,境况environmental adj.周围的, 环境的n.环境论circumvent vt.围绕, 包围, 智取tornado n.龙卷风avalanche n/v.雪崩liquid leakage 液体泄漏ego n.自我violation n.违反, 违背, 妨碍, 侵害rebellion n.谋反, 叛乱, 反抗, 不服从magnitude n.大小, 数量, 巨大, 广大, 量级questionnaire n.调查表, 问卷blackmail n.勒索, 勒索所得之款vt.勒索alteration n.变更, 改造fraudulent adj.欺诈的, 欺骗性的, 骗得的bribery n.行贿, 受贿, 贿赂revenge n.报仇, 复仇vt.替...报仇, 复仇espionage n.间谍, 侦探curiosity n.好奇心disgruntle vt.使不高兴negligent adj.疏忽的, 粗心大意的falsify v.伪造herein adv.于此, 在这里statutory adj.法令的, 法定的ballot n.选举票, 投票, 票数vi.投票custody 监管监管的行为或权利,尤指由法庭授予的监护权:warrant 授权给予(某人)授权或批准;授权或给予权力allegation n断言;宣称指控substantiate vt.使实体化, 证实revision n.修订, 修改, 修正, 修订本participate vi.参与, 参加, 分享, 分担criteria n.pl.标准observation n.观察, 观测, [pl.] 观察资料(或报告)critical adj.评论的, 鉴定的, 批评的, 危急的, 临界的sensitive adj.敏感的, 灵敏的, 感光的criticality n.危险程度sensitivity n.敏感, 灵敏(度), 灵敏性restrain vt.抑制, 制止journal n.日报,杂志;日志revocation n.撤回revoke vt.撤回, 废除, 宣告无效vi.n.有牌不跟encompass v.包围, 环绕, 包含或包括某事物facsimile n.摹写, 传真eavesdrop v.偷听n.屋檐水jargon n.行话volatile adj.飞行的, 挥发性的, 可变的, 不稳定的, 轻快的, 爆炸性的sequential adj.连续的, 相续的, 有继的, 有顺序的, 结果的hoax v.愚弄n.愚弄phreak 盗用电话线路cram v.填满disguise v.假装, 伪装, 掩饰n.伪装algorithm n.[数]运算法则hierarchical adj.分等级的hierarchy n.层次electro-magneticretention 保持力due caredue diligencepornography n.色情文学, 色情描写harassment n.折磨espionage n.间谍, 侦探breach n.违背, 破坏, 破裂, 裂口vt.打破, 突破partial adj.部分的, 局部的, 偏袒的, 偏爱的n.泛音vaulting n.拱形圆顶, 圆屋顶adj.跳的, 跳过的, 夸大的electronic vaultingreciprocal adj.互惠的, 相应的, 倒数的, 彼此相反的n.倒数, 互相起作用的事物logistics n.后勤学, 后勤vital adj.生死攸关的, 重大的, 生命的, 生机的, 至关重要的, 所必需的appropriate adj.适当的mitigation n.缓解, 减轻, 平静spill n.溢出, 溅出, 摔下, 木片, 小塞子, 暴跌, 溢出量vt.使溢出, 使散落, 洒, 使流出, 使摔下, 倒出vi.溢出, 涌流, 充满dilemmas n.进退两难的局面, 困难的选择forensics n.辩论练习, 辩论术privacy n.独处而不受干扰, 秘密confiscate vt.没收, 充公, 查抄, 征用adj.被没收的liability n.责任, 义务, 倾向, 债务, 负债, 与assets相对interrogation n.审问, 问号escort n.护卫(队), 护送, 陪同(人员), 护卫队v.护卫, 护送, 陪同mantrap n.(给入侵私人领地者设的)捕人陷阱turnstile n.十字转门volcano n.火山sabotage 怠工,破坏行动vandal 文化艺术的破坏者,野蛮人vandalism n.故意破坏艺术的行为toxic adj.有毒的, 中毒的suppression n.镇压, 抑制tempest n.暴风雨, 骚乱, 动乱vt.使狂怒, 扰乱, 使激动vi.起大风暴, 小题大作propagate v.繁殖, 传播, 宣传ignition n.点火, 点燃succinct adj.简洁的, 紧身的, 压缩在小范围内的badge n.徽章,像章;标志crux n.症结nomenclature n.命名法, 术语kerberizesurveillance n.监视, 监督ultimate adj.最后的, 最终的, 根本的n.最终anonymity n.匿名, 作者不明(或不详)affiliation n.联系, 从属关系emanation n.散发, 发出remnance n.残余, 剩余, 零料, 残迹adj.剩余的, 残留的degauss vt.消磁, 消除(船)四周磁场以防御磁雷reveal vt.展现, 显示, 揭示, 暴露buddy n.<美口>;密友, 伙伴lucifer n.魔鬼, 撒旦rijndaelinrush current n.涌入trap door n.[建]地板或屋顶上的活门preset vt.事先调整n.边框形式gossip n.闲话, 闲谈inconsistent adj.不一致的, 不协调的, 矛盾的veracity n.说真实话, 老实, 诚实, (感觉, 衡量等)准确性, 精确性triad n.三个一组, 三幅一组, [音]三和音tamper vi.干预, 玩弄, 贿赂, 损害, 削弱, 篡改vt.篡改n.捣棒, 夯, 填塞者ness n.海角arithmetic n.算术, 算法ciphony n.[电信]密码电话学crypto-cipher- n.密码vt, vi用密码书写(把电文等)译成密码(亦作:cypher)clipper chipencipher vt.把(电文)译成密码, 编码elliptic curve cryptosystem(ECC) 椭圆曲线密码系统systematically adv.系统地, 有系统地computationally infeasible 计算上的不可行symmetric adj.相称性的, 均衡的asymmetric adj.不均匀的, 不对称的repudiation 否认steganography 信息与档案室alphabet n.字母表monoalphabetic 单码代替,单一字母替换法polyalphabetic (密码学用语)多码代替,多字母替换法substitution n.代替, 取代作用, 代入法, 置换transposition n.调换, 变换, [数学] 移项scytaleenigma n.谜, 不可思议的东西permutation n.改变, 交换, [数]排列, 置换scramble n.爬行, 攀缘, 抢夺, 混乱vi.攀缘, 杂乱蔓延, 争夺, 拼凑, 匆忙vt.攀登, 搅乱, 使混杂concealment n.隐藏, 隐蔽, 隐蔽处escrow n.由第三者保存附带条件委付盖印的契约diffusion n.扩散, 传播, 漫射confusion n.混乱, 混淆logarithm n.[数] 对数synonymous adj.同义的permutationlarge prime numberfinite fieldcurvessusceptible adj.易受影响的, 易感动的, 容许...的n.(因缺乏免疫力而)易得病的人infeasible adj.不可实行的arbitrary adj.任意的, 武断的, 独裁的, 专断的conventional adj.惯例的, 常规的, 习俗的, 传统的repository n.贮藏室, 智囊团, 知识库, 仓库participate vi.参与, 参加, 分享, 分担tuple 元组,数组(row)attribute n.属性,数据库中包含有某个实体信息的字段(column)schema n.模式semantic adj.[语]语义的meta datapoly n.多(聚)instantiation n.实例化,例示anomaly n.不规则(变态,近点角.距平)aggregation n.集合, 集合体, 聚合inference n.推论n.推理(结论,论断axiom n.[数]公理reference n.提及, 涉及, 参考, 参考书目, 证明书(人), 介绍信(人)abductivedeductiveexplicitly adv.明白地, 明确地cell suppressionpartition n.分割, 划分, 瓜分, 分开, 隔离物vt.区分, 隔开, 分割noise and perturbation n.动摇, 混乱accumulate v.积聚, 堆积portray v.描绘distractible adj.易于分心的, 不专心的scavenge v.打扫, 以(腐肉)为食, 从废物中提取experience n.vt.经验, 体验, 经历, 阅历autonomous adj.自治的postmortem adj.死后的, 死后发生的n.尸体检查, 验尸miscellaneous adj.各色各样混在一起, 混杂的, 多才多艺的nomenclature n.命名法, 术语Slackn.松弛, 静止, 淡季, 闲散, 家常裤adj.松弛的, 不流畅的, 疏忽的, 软弱的, 漏水的, 呆滞的, 懒散的adv.马虎地, 缓慢地vt.使松弛, 使缓慢, 马虎从事vi.松懈, 减弱, 松驰obligation n.义务, 职责, 债务egocentric adj.自我中心的, 利己主义的n.利己主义者ideological adj.意识形态的psychotic adj.精神病的n.精神病患者preliminary adj.预备的, 初步的forensic adj.法院的, 适于法庭的, 公开辩论的n.辩论术obfuscate vt.使模糊, 使迷乱dynamic adj.动力的, 动力学的, 动态的polymorphic adj.多形的, 多态的, 多形态的permeability n.渗透性devastate vt.毁坏infrastructure n.下部构造, 基础下部组织collateral adj.间接的propagate v.繁殖, 传播, 宣传saturation n.饱和(状态), 浸润, 浸透.饱和度reconnaissance n.侦察, 搜索, 勘测mitigate v.减轻asynchronous adj.不同时的,[电]异步的blackoutdeception n.欺骗, 诡计jamperpetrator n.犯罪者, 作恶者conjunctionradiationacronym n.只取首字母的缩写词spurious adj.伪造的, 假造的, 欺骗的emanation n.散发, 发出clearance 证明书无过失、可靠或称职的官方证明dedicate 专门用于dictate v.口述, 口授, 使听写, 指令, 指示, 命令, 规定n.指示(指理智,变心) indicate vt.指出, 显示, 象征, 预示, 需要, 简要地说明clipping levelrotationkick offbogus adj.<美>;假的, 伪造的deviation n.背离recalibratefacsimile n.摹写, 传真preamble n.导言canon n.教规inevitable adj.不可避免的, 必然的dilemmas n.进退两难的局面, 困难的选择mentor 贤明的顾问, 导师, 指导者unwarranted adj.无根据的, 未获保证的, 无保证的, 未获承认的reassurance n.放心consent vi.同意, 赞成, 答应n.同意, 赞成, 允诺amateur n.业余爱好者, 业余艺术家prudent adj.谨慎的jurisdiction n.权限render vt.呈递, 归还, 着色, 汇报, 致使, 放弃, 表演, 实施vi.给予补偿n.交纳, 粉刷, 打底reputation n.名誉, 名声fiduciary adj.基于信用的, 信托的, 受信托的n.被信托者, 受托人disrupt v.使中断, 使分裂, 使瓦解, 使陷于混乱, 破坏negligence n.疏忽grudge v.不给予pertinent adj.有关的, 相干的, 中肯的dissemination n.分发garble vt.断章取义, 混淆replicate n.复制品encapsulation 包装,封装polymorphism n.多形性, 多态现象instantiation n.实例化,例示neural adj.神经系统的, 神经中枢的, 背的mainframe n.大型机garbage n.垃圾,污物,废料vigilance n.警戒, 警惕, 失眠症, 警惕性prudent adj.谨慎的burnt-out adj.(=burned-out)竭尽的, 因过度使用而损坏的evidence n.明显, 显著, 明白, 迹象, 根据, [物]证据, 证物purge n.净化, 清除, 泻药v.(使)净化, 清除, 肃清, (使)通便tapuncover vt.揭开, 揭露v.揭示transparency n.透明, 透明度, 幻灯片, 有图案的玻璃coercive adj.强制的, 强迫的dumpster 垃圾罐accreditation n.委派, 信赖, 鉴定合格certification n.证明pertain v.适合, 属于cross-examine examine grill question quiz test cohesion n.结合, 凝聚, [物理]内聚力coupling n.联结, 接合, 耦合collusionfurniture n.家具, 设备, 储藏物punitive adj.刑罚的, 惩罚性的inherit vt.继承inheritance 继承hiding n.隐匿, 隐藏之事, 痛打, 隐匿之所hierarchical adj.分等级的hierarchy n.层次drastically adv.激烈地, 彻底地prototype n.原型;模型;典型;榜样embedding n.嵌入wrapprevalent adj.普遍的, 流行的schema n.计划mimic adj.模仿的, 假装的, [生]拟态的n.效颦者, 模仿者, 小丑, 仿制品vt.模仿, 摹拟negatively adv.否定地, 消极地overhead 用于系统操作而不是用于用户作业的时间或操作。
SCI写作句型汇总
S C I论文写作中一些常用的句型总结(一)很多文献已经讨论过了一、在Introduction里面经常会使用到的一个句子:很多文献已经讨论过了。
它的可能的说法有很多很多,这里列举几种我很久以前搜集的:A.??Solar energy conversion by photoelectrochemical cells?has been intensively investigated.?(Nature 1991, 353, 737 - 740?)B.?This was demonstrated in a number of studies that?showed that composite plasmonic-metal/semiconductor photocatalysts achieved significantly higher rates in various photocatalytic reactions compared with their pure semiconductor counterparts.C.?Several excellent reviews describing?these applications are available, and we do not discuss these topicsD.?Much work so far has focused on?wide band gap semiconductors for water splitting for the sake of chemical stability.(DOI:10.1038/NMAT3151)E.?Recent developments of?Lewis acids and water-soluble organometalliccatalysts?have attracted much attention.(Chem. Rev. 2002, 102, 3641?3666)F.?An interesting approach?in the use of zeolite as a water-tolerant solid acid?was described by?Ogawa et al(Chem.Rev. 2002, 102, 3641?3666)G.?Considerable research efforts have been devoted to?the direct transition metal-catalyzed conversion of aryl halides toaryl nitriles. (J. Org. Chem. 2000, 65, 7984-7989) H.?There are many excellent reviews in the literature dealing with the basic concepts of?the photocatalytic processand the reader is referred in particular to those by Hoffmann and coworkers,Mills and coworkers, and Kamat.(Metal oxide catalysis,19,P755)I. Nishimiya and Tsutsumi?have reported on(proposed)the influence of the Si/Al ratio of various zeolites on the acid strength, which were estimated by calorimetry using ammonia. (Chem.Rev. 2002, 102, 3641?3666)二、在results and discussion中经常会用到的:如图所示A. GIXRD patterns in?Figure 1A show?the bulk structural information on as-deposited films.?B.?As shown in Figure 7B,?the steady-state current density decreases after cycling between 0.35 and 0.7 V, which is probably due to the dissolution of FeOx.?C.?As can be seen from?parts a and b of Figure 7, the reaction cycles start with the thermodynamically most favorable VOx structures(J. Phys. Chem. C 2014, 118, 24950?24958)这与XX能够相互印证:A.?This is supported by?the appearance in the Ni-doped compounds of an ultraviolet–visible absorption band at 420–520nm (see Fig. 3 inset), corresponding to an energy range of about 2.9 to 2.3 eV.B. ?This?is consistent with the observation from?SEM–EDS. (Z.Zou et al. / Chemical Physics Letters 332 (2000) 271–277)C.?This indicates a good agreement between?the observed and calculated intensities in monoclinic with space groupP2/c when the O atoms are included in the model.D. The results?are in good consistent with?the observed photocatalytic activity...E. Identical conclusions were obtained in studies?where the SPR intensity and wavelength were modulated by manipulating the composition, shape,or size of plasmonic nanostructures.?F.??It was also found that areas of persistent divergent surfaceflow?coincide?with?regions where convection appears to be consistently suppressed even when SSTs are above 27.5°C.(二)1. 值得注意的是...A.?It must also be mentioned that?the recycling of aqueous organic solvent is less desirable than that of pure organic liquid.B.?Another interesting finding is that?zeolites with 10-membered ring pores showed high selectivities (>99%) to cyclohexanol, whereas those with 12-membered ring pores, such as mordenite, produced large amounts of dicyclohexyl ether. (Chem. Rev. 2002, 102,3641?3666)C.?It should be pointed out that?the nanometer-scale distribution of electrocatalyst centers on the electrode surface is also a predominant factor for high ORR electrocatalytic activity.D.?Notably,?the Ru II and Rh I complexes possessing the same BINAP chirality form antipodal amino acids as the predominant products.?(Angew. Chem. Int. Ed., 2002, 41: 2008–2022)E. Given the multitude of various transformations published,?it is noteworthy that?only very few distinct?activation?methods have been identified.?(Chem. Soc. Rev., 2009,?38, 2178-2189)F.?It is important to highlight that?these two directing effects will lead to different enantiomers of the products even if both the “H-bond-catalyst” and the?catalyst?acting by steric shielding have the same absolute stereochemistry. (Chem. Soc. Rev.,?2009,?38, 2178-2189)G.?It is worthwhile mentioning that?these PPNDs can be very stable for several months without the observations of any floating or precipitated dots, which is attributed to the electrostatic repulsions between the positively charge PPNDs resulting in electrosteric stabilization.(Adv. Mater., 2012, 24: 2037–2041)2.?...仍然是个挑战A.?There is thereby an urgent need but it is still a significant challenge to?rationally design and delicately tail or the electroactive MTMOs for advanced LIBs, ECs, MOBs, and FCs.?(Angew. Chem. Int. Ed.2 014, 53, 1488 – 1504)B.?However, systems that are?sufficiently stable and efficient for practical use?have not yet been realized.C.??It?remains?challenging?to?develop highly active HER catalysts based on materials that are more abundant at lower costs. (J. Am. Chem.Soc.,?2011,?133, ?7296–7299)D.?One of the?great?challenges?in the twenty-first century?is?unquestionably energy storage. (Nature Materials?2005, 4, 366 - 377?)众所周知A.?It is well established (accepted) / It is known to all / It is commonlyknown?that?many characteristics of functional materials, such as composition, crystalline phase, structural and morphological features, and the sur-/interface properties between the electrode and electrolyte, would greatly influence the performance of these unique MTMOs in electrochemical energy storage/conversion applications.(Angew. Chem. Int. Ed.2014,53, 1488 – 1504)B.?It is generally accepted (believed) that?for a-Fe2O3-based sensors the change in resistance is mainly caused by the adsorption and desorption of gases on the surface of the sensor structure. (Adv. Mater. 2005, 17, 582)C.?As we all know,?soybean abounds with carbon,?nitrogen?and oxygen elements owing to the existence of sugar,?proteins?and?lipids. (Chem. Commun., 2012,?48, 9367-9369)D.?There is no denying that?their presence may mediate spin moments to align parallel without acting alone to show d0-FM. (Nanoscale, 2013,?5, 3918-3930)(三)1. 正如下文将提到的...A.?As will be described below(也可以是As we shall see below),?as the Si/Al ratio increases, the surface of the zeolite becomes more hydrophobic and possesses stronger affinity for ethyl acetate and the number of acid sites decreases.(Chem. Rev. 2002, 102, 3641?3666)B. This behavior is to be expected and?will?be?further?discussed?below. (J. Am. Chem. Soc.,?1955,?77, 3701–3707)C.?There are also some small deviations with respect to the flow direction,?whichwe?will?discuss?below.(Science, 2001, 291, 630-633)D.?Below,?we?will?see?what this implies.E.?Complete details of this case?will?be provided at a?later?time.E.?很多论文中,也经常直接用see below来表示,比如:The observation of nanocluster spheres at the ends of the nanowires is suggestive of a VLS growth process (see?below). (Science, 1998, ?279, 208-211)2. 这与XX能够相互印证...A.?This is supported by?the appearance in the Ni-doped compounds of an ultraviolet–visible absorption band at 420–520 nm (see Fig. 3 inset), corresponding to an energy range of about 2.9 to 2.3 eVB.This is consistent with the observation from?SEM–EDS. (Chem. Phys. Lett. 2000, 332, 271–277)C.?Identical conclusions were obtained?in studies where the SPR intensity and wavelength were modulated by manipulating the composition, shape, or size of plasmonic nanostructures.?(Nat. Mater. 2011, DOI: 10.1038/NMAT3151)D. In addition, the shape of the titration curve versus the PPi/1 ratio,?coinciding withthat?obtained by fluorescent titration studies, suggested that both 2:1 and 1:1 host-to-guest complexes are formed. (J. Am. Chem. Soc. 1999, 121, 9463-9464)E.?This unusual luminescence behavior is?in accord with?a recent theoretical prediction; MoS2, an indirect bandgap material in its bulk form, becomes a direct bandgapsemiconductor when thinned to a monolayer.?(Nano Lett.,?2010,?10, 1271–1275)3.?我们的研究可能在哪些方面得到应用A.?Our ?ndings suggest that?the use of solar energy for photocatalytic watersplitting?might provide a viable source for?‘clean’ hydrogen fuel, once the catalyticef?ciency of the semiconductor system has been improved by increasing its surface area and suitable modi?cations of the surface sites.B. Along with this green and cost-effective protocol of synthesis,?we expect that?these novel carbon nanodots?have potential applications in?bioimaging andelectrocatalysis.(Chem. Commun., 2012,?48, 9367-9369)C.?This system could potentially be applied as?the gain medium of solid-state organic-based lasers or as a component of high value photovoltaic (PV) materials, where destructive high energy UV radiation would be converted to useful low energy NIR radiation. (Chem. Soc. Rev., 2013,?42, 29-43)D.?Since the use of?graphene?may enhance the photocatalytic properties of TiO2?under UV and visible-light irradiation,?graphene–TiO2?composites?may potentially be usedto?enhance the bactericidal activity.?(Chem. Soc. Rev., 2012,?41, 782-796)E.??It is the first report that CQDs are both amino-functionalized and highly fluorescent,?which suggests their promising applications in?chemical sensing.(Carbon, 2012,?50,?2810–2815)(四)1. 什么东西还尚未发现/系统研究A. However,systems that are sufficiently stable and efficient for practical use?have not yet been realized.B. Nevertheless,for conventional nanostructured MTMOs as mentioned above,?some problematic disadvantages cannot be overlooked.(Angew. Chem. Int. Ed.2014,53, 1488 – 1504)C.?There are relatively few studies devoted to?determination of cmc values for block copolymer micelles. (Macromolecules 1991, 24, 1033-1040)D. This might be the reason why, despite of the great influence of the preparation on the catalytic activity of gold catalysts,?no systematic study concerning?the synthesis conditions?has been published yet.?(Applied Catalysis A: General2002, 226, ?1–13)E.?These possibilities remain to be?explored.F.??Further effort is required to?understand and better control the parameters dominating the particle surface passivation and resulting properties for carbon dots of brighter photoluminescence. (J. Am. Chem. Soc.,?2006,?128?, 7756–7757)2.?由于/因为...A.?Liquid ammonia?is particularly attractive as?an alternative to water?due to?its stability in the presence of strong reducing agents such as alkali metals that are used to access lower oxidation states.B.?The unique nature of?the cyanide ligand?results from?its ability to act both as a σdonor and a π acceptor combined with its negativecharge and ambidentate nature.C.?Qdots are also excellent probes for two-photon confocalmicroscopy?because?they are characterized by a very large absorption cross section?(Science ?2005,?307, 538-544).D.?As a result of?the reductive strategy we used and of the strong bonding between the surface and the aryl groups, low residual currents (similar to those observed at a bare electrode) were obtained over a large window of potentials, the same as for the unmodified parent GC electrode. (J. Am. Chem. Soc. 1992, 114, 5883-5884)E.?The small Tafel slope of the defect-rich MoS2 ultrathin nanosheets is advantageous for practical?applications,?since?it will lead to a faster increment of HER rate with increasing overpotential.(Adv. Mater., 2013, 25: 5807–5813)F. Fluorescent carbon-based materials have drawn increasing attention in recent years?owing to?exceptional advantages such as high optical absorptivity, chemical stability, biocompatibility, and low toxicity.(Angew. Chem. Int. Ed., 2013, 52: 3953–3957)G.??On the basis of?measurements of the heat of immersion of water on zeolites, Tsutsumi etal. claimed that the surface consists of siloxane bondings and is hydrophobicin the region of low Al content. (Chem. Rev. 2002, 102, 3641?3666)H.?Nanoparticle spatial distributions might have a large significance for catalyst stability,?given that?metal particle growth is a relevant deactivation mechanism for commercial catalysts.?3. ...很重要A.?The inhibition of additional nucleation during growth, in other words, the complete separation?of nucleation and growth,?is?critical(essential, important)?for?the successful synthesis of monodisperse nanocrystals. (Nature Materials?3, 891 - 895 (2004))B.??In the current study,?Cys,?homocysteine?(Hcy) and?glutathione?(GSH) were chosen as model?thiol?compounds since they?play important (significant, vital, critical) roles?in many biological processes and monitoring of these?thiol?compounds?is of great importance for?diagnosis of diseases.(Chem. Commun., 2012,?48, 1147-1149)C.?This is because according to nucleation theory,?what really matters?in addition to the change in temperature ΔT?(or supersaturation) is the cooling rate.(Chem. Soc. Rev., 2014,?43, 2013-2026)(五)1. 相反/不同于A.?On the contrary,?mononuclear complexes, called single-ion magnets (SIM), have shown hysteresis loops of butterfly/phonon bottleneck type, with negligiblecoercivity, and therefore with much shorter relaxation times of magnetization. (Angew. Chem. Int. Ed., 2014, 53: 4413–4417)B.?In contrast,?the Dy compound has significantly larger value of the transversal magnetic moment already in the ground state (ca. 10?1?μB), therefore allowing a fast QTM. (Angew. Chem. Int. Ed., 2014, 53: 4413–4417)C.?In contrast to?the structural similarity of these complexes, their magnetic behavior exhibits strong divergence.?(Angew. Chem. Int. Ed., 2014, 53: 4413–4417)D.?Contrary to?other conducting polymer semiconductors, carbon nitride ischemically and thermally stable and does not rely on complicated device manufacturing. (Nature materials, 2009, 8(1): 76-80.)E.?Unlike?the spherical particles they are derived from that Rayleigh light-scatter in the blue, these nanoprisms exhibit scattering in the red, which could be useful in developing multicolor diagnostic labels on the basis not only of nanoparticle composition and size but also of shape. (Science 2001,? 294, 1901-1903)2. 发现,阐明,报道,证实可供选择的词包括:verify, confirm, elucidate, identify, define, characterize, clarify, establish, ascertain, explain, observe, illuminate, illustrate,demonstrate, show, indicate, exhibit, presented, reveal, display, manifest,suggest, propose, estimate, prove, imply, disclose,report, describe,facilitate the identification of?举例:A. These stacks appear as nanorods in the two-dimensional TEM images, but tilting experiments?confirm that they are nanoprisms.?(Science 2001,? 294, 1901-1903)B. Note that TEM?shows?that about 20% of the nanoprisms are truncated.?(Science 2001,? 294, 1901-1903)C. Therefore, these calculations not only allow us to?identify?the important features in the spectrum of the nanoprisms but also the subtle relation between particle shape and the frequency of the bands that make up their spectra.?(Science 2001,? 294, 1901-1903)D. We?observed?a decrease in intensity of the characteristic surface plasmon band in the ultraviolet-visible (UV-Vis) spectroscopy for the spherical particles at λmax?= 400 nm with a concomitant growth of three new bands of λmax?= 335 (weak), 470 (medium), and 670 nm (strong), respectively. (Science 2001,? 294, 1901-1903)E. In this article, we present data?demonstrating?that opiate and nonopiate analgesia systems can be selectively activated by different environmental manipulationsand?describe?the neural circuitry involved. (Science 1982, 216, 1185-1192)F. This?suggests?that the cobalt in CoP has a partial positive charge (δ+), while the phosphorus has a partial negative charge (δ?),?implying?a transfer of electron density from Co to P.?(Angew. Chem., 2014, 126: 6828–6832)3. 如何指出当前研究的不足A. Although these inorganic substructures can exhibit a high density of functional groups, such as bridging OH groups, and the substructures contribute significantly to the adsorption properties of the material,surprisingly little attention has been devoted to?the post-synthetic functionalization of the inorganic units within MOFs. (Chem. Eur. J., 2013, 19: 5533–5536.)B.?Little is known,?however, about the microstructure of this material. (Nature Materials 2013,12, 554–561)C.?So far, very little information is available, and only in?the absorber film, not in the whole operational devices. (Nano Lett.,?2014,?14?(2), pp 888–893)D.?In fact it should be noted that very little optimisation work has been carried out on?these devices. (Chem. Commun., 2013,?49, 7893-7895)E. By far the most architectures have been prepared using a solution processed perovskite material,?yet a few examples have been reported that?have used an evaporated perovskite layer. (Adv. Mater., 2014, 27: 1837–1841.)F. Water balance issues have been effectively addressed in PEMFC technology through a large body of work encompassing imaging, detailed water content and water balance measurements, materials optimization and modeling,?but very few of these activities have been undertaken for?anion exchange membrane fuel cells,? primarily due to limited materials availability and device lifetime. (J. Polym. Sci. Part B: Polym. Phys., 2013, 51: 1727–1735)G. However,?none of these studies?tested for Th17 memory, a recently identified T cell that specializes in controlling extracellular bacterial infections at mucosal surfaces. (PNAS, 2013,?111, 787–792)H. However,?uncertainty still remains as to?the mechanism by which Li salt addition results in an extension of the cathodic reduction limit. (Energy Environ. Sci., 2014,?7, 232-250)I.?There have been a number of high profile cases where failure to?identify the most stable crystal form of a drug has led to severe formulation problems in manufacture. (Chem. Soc. Rev., 2014,?43, 2080-2088)J. However,?these measurements systematically underestimate?the amount of ordered material. ( Nature Materials 2013, 12, 1038–1044)(六)1.?取决于a.?This is an important distinction, as the overall activity of a catalyst will?depend on?the material properties, synthesis method, and other possible species that can be formed during activation.?(Nat. Mater.?2017,16,225–229)b.?This quantitative partitioning?was determined by?growing crystals of the 1:1 host–guest complex between?ExBox4+?and corannulene. (Nat. Chem.?2014,?6177–178)c.?They suggested that the Au particle size may?be the decisive factor for?achieving highly active Au catalysts.(Acc. Chem. Res.,?2014,?47, 740–749)d.?Low-valent late transition-metal catalysis has?become indispensable to?chemical synthesis, but homogeneous high-valent transition-metal catalysis is underdeveloped, mainly owing to the reactivity of high-valent transition-metal complexes and the challenges associated with synthesizing them.?(Nature2015,?517,449–454)e.?The polar effect?is a remarkable property that enables?considerably endergonic C–H abstractions?that would not be possible otherwise.?(Nature?2015, 525, 87–90)f.?Advances in heterogeneous catalysis?must rely on?the rational design of new catalysts. (Nat. Nanotechnol.?2017, 12, 100–101)g.?Likely, the origin of the chemoselectivity may?be also closely related to?the H?bonding with the N or O?atom of the nitroso moiety, a similar H-bonding effect is known in enamine-based nitroso chemistry. (Angew. Chem. Int. Ed.?2014, 53: 4149–4153)2.?有很大潜力a.?The quest for new methodologies to assemble complex organic molecules?continues to be a great impetus to?research efforts to discover or to optimize new catalytic transformations. (Nat. Chem.?2015,?7, 477–482)b.?Nanosized faujasite (FAU) crystals?have great potential as?catalysts or adsorbents to more efficiently process present and forthcoming synthetic and renewablefeedstocks in oil refining, petrochemistry and fine chemistry. (Nat. Mater.?2015, 14, 447–451)c.?For this purpose, vibrational spectroscopy?has proved promising?and very useful.?(Acc Chem Res. 2015, 48, 407–413.)d.?While a detailed mechanism remains to be elucidated and?there is room for improvement?in the yields and selectivities, it should be remarked that chirality transfer upon trifluoromethylation of enantioenriched allylsilanes was shown. (Top Catal.?2014,?57: 967.?)e.?The future looks bright for?the use of PGMs as catalysts, both on laboratory and industrial scales, because the preparation of most kinds of single-atom metal catalyst is likely to be straightforward, and because characterization of such catalysts has become easier with the advent of techniques that readily discriminate single atoms from small clusters and nanoparticles. (Nature?2015, 525, 325–326)f.?The unique mesostructure of the 3D-dendritic MSNSs with mesopore channels of short length and large diameter?is supposed to be the key role in?immobilization of active and robust heterogeneous catalysts, and?it would have more hopeful prospects in?catalytic applications. (ACS Appl. Mater. Interfaces,?2015,?7, 17450–17459)g.?Visible-light photoredox catalysis?offers exciting opportunities to?achieve challenging carbon–carbon bond formations under mild and ecologically benign conditions. (Acc. Chem. Res.,?2016, 49, 1990–1996)3. 因此同义词:Therefore, thus, consequently, hence, accordingly, so, as a result这一条比较简单,这里主要讲一下这些词的副词词性和灵活运用。
Tricritical point in strongly coupled U(1) gauge theory with fermions and scalars
a r X i v :h e p-l a t /9509038v 1 13 S e p 19951HLRZ 54/95hep-lat/9509038Tricritical point in strongly coupled U(1)gauge theory with fermions and scalars ∗W.Franzki a and J.Jers´a k aaInstitute of Theoretical Physics E,RWTH Aachen,D-52056Aachen,GermanyWe investigate the tricritical point in the lattice fermion–gauge–scalar model with U(1)gauge symmetry.In the vicinity of this point,in the phase with the broken chiral symmetry,we observe the scaling behavior of the chiral condensate and of the masses of composite fermion and composite scalar,indicating the existence of an interesting continuum limit of the model at this point.1.IntroductionThe lattice 4D fermion-gauge scalar (χUφ4)model with U(1)gauge symmetry has at quite strong gauge coupling,β≃0.64,a tricritical point [1,2].The nature of the continuum limit taken at this point is not known.When this point (point E in fig.1)is approached from the phase with spontaneously broken global chiral symme-try and a massive fermion F (Nambu phase),the mass am F scales.The fermion F =φ†χis com-posed of the fundamental fermion (χ)and scalar (φ)fields and is unconfined.This raises the hope that a nonperturbatively renormalizable theory with dynamical fermion mass generation might be obtained [1].Motivated by this interesting possibility we have started an investigation of the scaling be-havior of various observables in the vicinity of the point E.We find that apart from am F also the mass am S of a composite scalar boson S = 3i =1φ†x ,t U ( x ,t ),i φ x + i,t scales in the vicinity of E.This,as well as some other properties [2]make the point distinctly different from the (nonrenormal-izable [3])Nambu–Jona-Lasinio model found in the strong coupling limit of the χUφ4model [4].This,as well as the experience that tricritical points give rise to the scaling behavior different from that associated with the adjacent critical points [5],contributes to the hope that the point2x 4µ=1ηµxχx χx ,(2)S U =βP[1−Re U P ],(3)S φ=−κx 4 µ=1φ†xU x,µφx +µ+h .c ..(4)Here U P is the plaquette product of link variablesU x,µand ηµx =(−1)x 1+···+x µ−1.The gauge field link variables U x,µare elements of the compact gauge group U(1).The complex scalar field φof charge one satisfies the constraint |φ|=1.The hopping parameter κvanishes (is infinite)when the squared bare scalar mass is positive (negative)infinite.The staggered fermion field χof charge one leads to the global U(1)chiral symmetry of the2Figure1.Schematic phase diagram of theχUφ4model with U(1)gauge symmetry.Three critical lines, NE,EE∞and EE−∞meet at the tricrititical point E.The NE line is a part of the boundary of the Nambu phase(shadowed region)at m0=0,which is actually a sheet of1st order phase transitions,across which3 Figure2.Chiral condensateχχ .An onsetof the genuine chiral phase transition isindicated with decreasing am0.The fermion massam F(fig.3)behaves similarly.The transitionappears to be smooth,i.e.of2nd order,close toκ≃0.305.Infig.4we show the scalar boson mass am S.The position of the minimum for each am0corre-sponds roughly to the crossection of a continua-tion to smallerβof the nearly horizontal“wing”Figure3.Fermion mass am F.Figure4.Scalar boson mass am S.4Figure 5.Masses of mesons(χχ(meson)masses.For comparison we showalso data for2am F.The Goldstone boson massamπis small around the transition as expected.The fact that theρ-andσ-masses cross the2am Fline in the vicinity of the phase transition in-dicates that in the Nambu phase these mesonscan be interpreted as bound states and that theirmasses scale similarly to am F and thus may existalso in the continuum limit.This is a hint thatthe spectrum of the underlying continuum theorymight be quite complex.Our present results suggest that it is worth-while to continue the investigation of the tricriti-cal point E.For this purpose the full scaling the-ory of tricritical points[5]and afinite size scalingtheory in their vicinity will have to be applied.Some analytic insight into the properties of themodel in the relevant coupling region is highlydesirable.REFERENCES1. C.Frick and J.Jers´a k,Phys.Rev.D52(1995)340.2.W.Franzki,C.Frick,J.Jers´a k and X.Q.Luo,Chiral phase transition in a lattice fermion–gauge–scalar model with U(1)gauge symme-try,preprint HLRZ23/95(to be published inNucl.Phys.B).3. A.Ali Khan,M.G¨o ckeler,R.Horsley,P.E.L.Rakow,G.Schierholz and H.St¨u ben,Phys.Rev.D51(1995)3751.4.I.-H.Lee and R.E.Shrock,Phys.Rev.Lett.59(1987)14.wrie and S.Sarbach,in C.Domb andJ.L.Lebowitz,eds.,Phase transitions andcritical phenomena,vol.9,p.1(Acad.Press,New York,1984).6.W.Franzki,J.Jers´a k and R.Welters,Gaugeinvariant generalization of the2D chiralGross-Neveu model,these Proceedings.。
链条的强度取决于它的薄弱环节英语作文
The Strength of a Chain Lies in Its WeakestLinkIn the realm of mechanical engineering, a common adage goes, "The strength of a chain lies in its weakest link." This proverb, while originally referring to the integrity of physical chains, can be aptly applied to various aspects of life, from the smallest personal endeavors to thelargest societal undertakings. The crux of the matter is that the weakest element, regardless of its size or significance, has the potential to determine the overall strength and durability of the entire system.In the context of personal development, one's weakest link could be a lack of self-discipline, a fear of failure, or a limiting belief about one's capabilities. These weak points, often hidden in the shadows of our subconscious minds, can hold us back from achieving our full potential. It is crucial to identify and address these weaknesses if we want to move forward in our personal growth and development.In the workplace, the weakest link could be a poor communication system, a lack of team cohesion, or a failureto adapt to changing market conditions. If these weaknesses are not addressed, they can lead to breakdowns in productivity, decreased morale, and ultimately, failure to meet organizational goals.On a societal level, the weakest link could be afailure to provide equal educational opportunities, a lack of infrastructure development, or a failure to address social injustices. These issues, if left unresolved, can lead to societal breakdowns, increased social tension, and a lack of progress towards collective goals.The importance of addressing the weakest link isfurther emphasized in the realm of technology. In computer systems, for example, a single faulty component can cause the entire system to crash. Similarly, in engineering projects, a minor flaw in the design or construction of a single component can lead to catastrophic failure of the entire structure.In conclusion, the strength of a chain lies in its weakest link. Whether we are considering personal growth, organizational success, or societal progress, it is imperative that we identify and address the weak pointsthat threaten the integrity of the system. By doing so, we can ensure that we are building stronger, more resilient chains that are capable of withstanding the tests of time and adversity.**链条的强度取决于它的薄弱环节**在机械工程领域,有一句谚语说道:“链条的强度取决于它的薄弱环节。
5_Asymmetric_Alkylation
C6H5 O HO CH3 CH2CH3 78% ee 3-6 N HCl 84%
Meyers, A. I.; Knaus, G.; Kamata, K.; Ford, M. E. J. Am. Chem. Soc. 1976, 98, 567-576.
TDSO CH3 CH3
SO2Ph
HO CH3 CH3
*1999 Aldrich Prices, can be dramatically lower from bulk suppliers.
• Less reactive (non-allylic/benzylic) electrophiles require the use of sodium enolates or triflate as leaving group: O O N CH3 O CH3 NaN(TMS)2, THF –78 °C; EtI 53% 94 : 6 Evans, D. A.; Ennis, M. D.; Mathre, D. J. J. Am. Chem. Soc. 1982, 104, 1737-1739. O O N Et CH3 O CH3
O CH3
TiCl4, (i-Pr)2NEt; (CH3O)3CH
O O N
O CH(OCH3)2 CH3 99 : 1 O
O N
O
Bn
95%
Bn
90%
Evans, D. A.; Urpi, F.; Somers, T. C.; Clark, J. S.; Bilodeau, M. T. J. Am. Chem. Soc. 1990, 112, 8215-8216.
• Asymmetric azidation provides an important route to amino acid derivatives: O t-Bu KHMDS, TrisylN3, –78 °C; HOAc, –78 0 °C O N N3 >99 : 1 O t-Bu
核电英语词汇表
英文absorberA/D converterabilityabnormalabnormal condition abnormal operation abnormal operation transient abnormal temperature rise abovegroundaboveground cableabrading particlesabrasiveabrasive blastingabrasive flap wheelabrasive particlesabrasive wearabrasive wheelabsence of hang-upabsolute densityabsolute encoderabsolute errorabsolute filterabsolute filter bankabsolute filter package absolute fluxabsolute pressureabsolute specific gravity absolute temperature absorbed doseabsorbed dose equivalent rate absorbed dose rate absorbent capacityabsorber rodabsorptionA-weighted sound power level absorption analysisabsorption build-up factor absorption coefficient absorption controlabsorption cross section absorption efficiency absorption factorabsorption lengthabsorption lineabsorption peakabsorption ratioabsorption spectrum abundanceabundance ratio (isotopes)AC generatorAC motoraccelerationacceleration period(motor) accelerometeracceptable quality level acceptable results acceptanceacceptance criteria acceptance report acceptance testacceptance tested(filler metals) access areaaccess authorization for…access hatchaccess panelaccess plugaccess portaccess rampaccessibilityaccessibleaccessible-neutral accessories(filters,scoops,etc.) accident conditionaccident operating conditions accidental exposureaccidental releaseaccoustic emission detector accreditationaccreditedaccumulated doseaccumulated pressure accumulationaccumulatoraccumulator injectionaccumulator tankaccuracyachievement of qualityacid coveringacid etchingacid-proofacid-proof coating acknowledgement(signal,alarm,etc.) acoustic pressureacoustic strain gauge(containment instrumentation)acoustic velocityacoustic waveacoustical adj.acquisition rateactionaction planactivated carbonactivated charcoalactivated charcoal filteractivated charcoal filter bank activated charcoal filter package activated nucleusactivated wateractivationactivation analysisactivation energyactivation productsactiveactive carbon filteractive componentactive core heightactie energyactive failureactive fuel lengthactive height(fuel)active loopactive poweractive power meteractive surface agentactive volumeactivityactivity affecting qualityactivity concentrationactivity curveactivity levelactivity meteractivity supervisoractual capacity(compressor)actuate v.actuating variableactuationactuatoractuator armactuator manufactureracute exposureadaptoradaptor lugadaptor plate(fuel assembly to nozzle) adderaddition or deletion of variables(welding procedure qualification)additional HP governing valve additional lightingadditional loadadditional power source additional workadditiveaddressadhesionadhesive adj.adhesiveadhesive tapeadjoint fluxadjoint of the neutron flux density adjust v.adjustableadjustable blade propeller adjustable pliersadjustable wrenchadjustingadjusting bolt bearingadjusting ring set screw adjusting screwadjustment deviceadjustment moduleadjustment pellet administration building administrative lockout administrative manager admission pressureadvanced fuel assembly advantage factoraerialaerial cableaerial viewaerosolaerosol monitorAFI test (filters)after-heatafter-powerafterglowafterset insertAG 5aluminum-zinc alloyage v.age hardeningage peaking factoraged uranium agglomerated agglomerated flux agglomerated (powder) aggregateaggregate recoilaggressiveaggressive atmosphere aggressive medium aggressive wateragingagitatorair adj.air bindingair blast breakerair bleed valveair breakerair carbon arc gougingair change rateair conditioningair conduitair contaminationair contamination meterair contamination monitorair coolerair cooler duct (electric motor) air coolingair curtainair cylinderair dryerair ductair eductorair entrainmentair equivalentair equivalent materialair exhaustair filterair gapair gaugeair heaterair hoseair inletair intakeair lockair magnetic breakerair operated disk cutterair operated jawsair outletair pocketair pressure amplifierair radiation monitor(gas or air-particulate monitors)air recirculation fanair regulatorair removalair renewalair renewal rateair samplerair sampling deviceair setair set pressure test(for relief valves)air specific gravityair speedair supplyair supply fanair supply supportair supply terminalair to push downair to push upair transportair valveair velocityair ventair washerair-break circuit breakerair-bubbler type level measurement air-bubbler type specific gravity measurementair-cooled condenserair-cooled transformerair-entraining agent(concrete)air-entraining vortexair-line assemblyair-operated adj.air-operated valveair-to-air coolerair-to-close valveair-to-open on-off valveair-to-open valveair-to-water coolerair/bead mixtureairborne particulate control airborne particulatesaircraft crashaircraft warning lightsairing circuitairtightairtight doorairtightnessalarmalarm annunciatoralarm boxalarm lampalarm processingalarm signalalarm windowalarmedalignmentalignment holealignment pinalkaline batteryalkaline cleaningall volatile treatmentall-weld-metal tension(or tensile)test all-welded frameAllen screwalligatoringallowableallowable loadallowable stressallowanceallowance for fabrication tolerances alloy steelalloyed steelalmen intensityalmen stripalpha decayalpha emissionalpha emitteralpha radioactivityalpha ratioalpha raysalpha-phase producing(metallurgy) alphanumeric codealterationalternate energy sourcesalternate systemalternating currentalternating current motoralternating slidingalternating stressalternative energy sources alternatoraluminous cementambient conditionsambient does rateambient lightingambient temperatureAmerican standard pipe thread plug ammeterammonium diuranateampacityamphoteric metalamplification channelamplifieramplfier relayanaloganalog channelanalog controlleranalog diagramanalog digital converteranalog feedback controlanalog inputanalog instrumentationanalog measurementanalog relayanalog signalanalog variableanalyseranalysis(of data)analysis lineanalyzeranchoranchor baranchor boltanchor channelanchor coneanchor drillinganchor plateanchor pointanchor ring(reactor vessel)anchor rodanchoringanchoring pointangleangleangle beam examinationangle beam probeangle beam ultrasonic examination angle check valveangle control valveangle gear driveangle ironangle jointangle of frictionangle of the electron gun(electron beam welding)angle patternangle poleangle styleangle towerangle valveangular adjustmentangular displacement transducer angular momentumanion bedanion bed demineralizeranion bed ion exchangeranion exchange resinanion exchangeranion resinanion vacanciesanisotropy factorannealedannealingannealing passannealing temperatureannular lightingannulus(containment)annunciatedannunciatorannunciator boardannunciator lightannunciator panelanomalyanti-backlash(gears)anti-condensation heater(reactor coolant pump)anti-foaming agentanti-frieezing agent(concrete)anti-oil whip(pump)anti-popout tubeanti-reverseanti-reverse deviceanti-reverse systemanti-rotation deviceanti-rust paintanti-seismic plateanti-simmeranti-vibration baranti-vibration spacer baranti-whip deviceantibirdantichatteranticipatedanticlockwiseanticoincidenceantidustantifreezeantifriction bearingantirotation deviceantirotation lugantirotation toolantisimmer(valve)antisimmer pressure relief valve antivibrationantivibration bar attachmentanvilaperture cardapparatusapparent powerappendageappendage sensorapplicabilityapplicationapplication of new lead sealapproach(cooling tower,condenser) approach to criticalityapprovalapproved packingaquiferarc blowarc chutearc energyarc initiationarc strike(welding)arc trajectory(missile)archarch damarchitectural drawingarchitectural line weightsarcing contactareaarea containing removable ceiling or wall panelsarea drainarea monitorarea radiation monitorarea radiation monitoring system area supervisorarea under the notch(impact test) area-weighted averagingargon hosearithmetic meanarmarm rotationarmaturearmorarmored cablearmoring wirearmouraround-the-clockarrangementarrangement drawing arrangement of runsarrayarrisarticulated armarticulated camera mount artificial radioactivityartificail radionuclideas builtas isas-built(drawings)as-built dimensionas-built drawingas-castas-coated roughnessas-deposited claddingas-weldedas-welded surfaceasbestos cementasbestos cement sleeve asbestos paperaseismicaseismic bearing pad aseismic plateaskarel-filled transformer aspect ratioasperity junctionsasphaltasphalt roofingasphalt-based solifification assemblyassemblyassembly drawingassembly fixture(control rods) assessmentassigneeassignmentassignment check assignment drawingassistant shift supervisor assumedassumptionasymmetricasynchronous motor atmospheric pressure atmospheric relief valve atmospheric steam dump atmospheric steam dump valve atomic chargeatomic energyatomic mass unitatomic numberatomic ratioatomic weightatomize v.attachingattachmentattachment modeattachment pointattack(corrosion)attenuationattenuation coefficientattenuation factorattributeaudible alarmaudible signalsaudible warning deviceaudio radiation indicatorauditaudit follow-upaudit planaudit recordaudit reportauditoraustenitic steelaustenitizingauthorityauthotizationauthorization decree(plant)authorization to proceedauthorization to proceed with fabrication authorizationauthorized for testingauto-manual control stationautoclaveautogenous weldingautomatedautomatic chemical monitoring and control deviceautomatic controlautomatic control assemblyautomatic control relayautomatic control systemautomatic controllerautomatic level(surveying)automatic remote-controlled plugging automatic remote-controlled plugging systemautomatic roll-type filterautomatic rotating-type filter automatic sample changer automatic spiral ratchet screwdriver automatic surface examination automatic switchautomatic synchronization unit automatic weldingautomatic welding machine autonomousautotransformerauxiliary actuating deviceauxiliary alternatorauxiliary boilerauxiliary bridge(fuel handling) auxiliary buildingauxiliary building sump pump auxiliary contactorauxiliary exciterauxiliary feedwaterauxiliary feedwater pump(motor and turbine-driven)auxiliary feedwater storage tank auxiliary feedwater supply(steam generators)auxiliary gengeratorauxiliary hoist(fuel handling) auxiliary loading airauxiliary loading forceauxiliary motor-pump assembly auxiliary oil lift pumpauxiliary oil pumpauxiliary operatorauxiliary power systemauxiliary relayauxiliary rod holdout coil(CRDM) auxiliary rod holdout device(control rod drive mechanism)auxiliary spray lineauxiliary spray valveauxiliary steamauxiliary switchboardauxiliary switchyardauxiliary systemauxiliary trailerauxiliary transformerauxiliary valvesavailabilityavailability(NI)availability factor(NRC)availability improvementavailable headaverageaverage adj.average v.average energy expended per ion pair formedaverage lifeaverage logarithmic energy decrement average outgoing quality(AOQ) averaging amplifierAvogadro's numberaxial blanketaxial bucklingaxial clearanceaxial diffusion coefficientaxial expansionaxial flowaxial flow fanaxial flow impelleraxial flow propelleraxial grid spacing coefficientaxial meanaxial motionaxial offset(flux)axial offset factoraxial peaking hot spot factoraxial segementaxial stiffnessaxial stressaxial thrustaxial-scan closed circuit TV camera axially-splitaxially-split casingaxially-split casing pumpaxisaxis of rotationaxis of symmetryaxlebabbit metalback echoback filter(radiography)back gougingback grindingback lighted rotary pushbutton switch back off v.back out v.back seat bushingback shieldingback vanesback viewback wearing ringback welded branch pipeback weldingback-extractionback-to-backback-to-back impellersback-to-back switchboardback-to-wallback-to-wall switchboardbackdraft damperbacked-up power supplybackfacebackface(mates with backseat on valve body)backfillbackfillingbackfittingbackgroundbackground informationbackground irradiationbackground noisebackground radiationbackingbacking barbacking gasbacking layerbacking platebacking ringbacking runbacking stripbacklashbacklightedbacklighted buttonbacklighted pushbuttonbacklighted rotary switchbacklighted switchbacklightingbacklitbacklit sign(eg.<Exit>,<Fire Escape>) backpressurebackpressure fittingbackpressureregular(incorrectly<backpressure control valve>)backpressure turbinebackscatterbackscatter factorbackscatteringbackseatbackstep method(welding)backupbackup manual operatorbackup ring(CRDM)backwallbackward-curved vanebackwashingbad weatherbafflebaffle assembly(reactor vessel)baffle boltingbaffle jettingbaffle plate(reactor vessel)bailbainiticbakelitebaking(electrodes or fluxes before use) balance stabilizer shaftbalanced check valvebalanced sealbalanced-plug control valve balancingbalancing bellowsbalancing chamberbalancing devicebalancing diskbalancing drumbalancing drum headbalancing of rotating machinery balancing pistonballball bearingball burnishingball control valveball flow indicatorball hardness testing ball isolation valveball lift check valveball millball peen hammerball pressure relief valve ball ringball screwball thrust bearingball valveball-float trapballastballracebanana boundary zone banana regionband spectrum bandsawbank(capacitors,etc) bank slopingbarbar chartbar manipulatorbar stockbarbbarebare busbare cablebare rod bundlesbare shaftbare solid cablebare wirebaring(wire)barrelbarrel casingbarrel casing pumpbarrel pumpbarrelingbarrierbarrier terminal blockbarring gearbarstock adj.barstockbarstock bodybarytes concretebasebase insertbase loadbase load operationbase matbase material test couponbase metalbase metal crackingbase packagebase platebase rockbase slabbase-load compressorbase-load plantbaseboardbaseline databasematbasementbaseplatebasic allowable stress intensity(RCC-M) basic coveringbasin designbasic flow diagrambasic function unitbasic gridbasic grid strapbasicity indexbasin(geographical)basis control modulebasketbasket gripbasketweave armorbastard filebatchbatch distillationbatch numberbatch processingbatch treatmentbatchingbatching tankbatter(of wall or embankment) batterybattery bankbattery chargerbattery packbattery pliersbattery roombaybay windowbayonet connector(quick disconnect) bayonet couplingbeadbead blastingbead collecting system(shot peening) bead collectorbead generatorbeadsbeambeam attenuationbeam clampbeam compassbeam index(ultrasonics)beam powerbearingbearing capacity(soils,etc) bearing cartridge bearing coverbearing end cover bearing framebearing framebearing housingbearing pedestalbearing platebearing pointbearing shaft sleeve bearing shellbearing shell half bearing shoebearing sleevebearing spanbearing stressbearing supportbearing surface bearingsbedbed v.beddingbedding mortarbedding tapebedplatebedrockbeginning of cycle(BOC) beginning of life(BOL) behaviorbellbell end (pipe)bell mouth (pipe)bell-mouth defectbell-shaped end (pipe) Belleville spring belleville washerbellows sealbellows seal valvebellows-type manometerbeltbelt conveyorbelt drivebelvederebench grinderbench markbench testbenchmarkbendbend radiusbend testbendingbending brakebending critical speedbending forcebending induced by thermal contraction bending machinebending momentbending pressbending radiusbending schedulebending strengthbending stressbending tablebending tensile strengthbending testbentonitebermbest efficiency pointbest estimate flowbeta decaybeta quenchbeta radioactivitybeta raysbeta valuebevelbevel anglebevel protractorbevel washerbevelingbeveling machinebiasingbibbibbbichromate-treatedbidbifilarbill of materialsbill of quantitiesbilletbimetalbimetal thermometerbinbinary cyclebinary signalbindbinderbindingbinding energybinding fatiguebinding postbinding screwbinding wirebinocularsbiological concentration biological concentration factor biological effect of radiation biological half-lifebiological holebiological protection biological shieldbiological shieldingbiological equivalent single dose bird cage(shipping cask)bird screenbirdproofbistablebitbite(control rods)bitumenbitumen feltbitumen solidification bituminous paintblack anodizedblack bodyblack plateblack sheetblackenedblackoutbladeblankblank panelblank contractblanking plateblanking-offblast cleaningblast furnace cementbled steambleedbleed v.bleed off v.bleed valvebleed-offbleedingbleeding point(turbine)bleedoffblendblend v.blend back additionblend batchblendback additionblending radiusblind flangeblind holeblind nutblind rivetblind scalerblindingblinding concreteblink v.blisterblisteringblockblock v.(circuit electronique)block and tackleblock diagramblock valveblock valveblockingblocking medium(radiography)blocking valveblockoutblood tissueblow down v.blow off v.blow-off circuitblowdownblowdown control ring(may be the upper or lower adjusting ring)blowdown coolerblowdown line(steam generator) blowdown nozzle(SG)blowdown pipeblowdown pressure(difference between set pressure and reseating pressure)blowdown pumpblowdown tankblowdown tap(SG)blowdown valveblowerblowout diaphragmblunt-nosed stampBNC terminalBNI (Balance of Nuclear Island) boardboard cardboard extenderboard swapping(fault clearing) bodybody burdenbody contaminationbody decontaminationbody endbody gasket;body-to-bonnet joint body radiocartographybody wave(earthquakes)body/bonnet nutboiler feedpumpboilermakerboilermakingboiling crisisboiling pointboltbolt and nutbolt cross-sectionbolt cutterbolt-onbolted bonnetbolted glandbolted linkbolted-pressure connector boltingbolting(bolts,screws,nuts,studs,washers,etc .)bondbond strengthbondedbonded areabonded flux;agglomerated fluxbonded warehousebondingbonding jumperbonding wirebone tissuebone-seekingbonnet(valve)bonnet bearingbonnet plugbonnet stop(prevents bonnet from jamming in body)boom(crane)booster fanbooster pumpbooster relaybooster rodboosting(pump)bootbooth(NDE)BOP(Balance of Plant)borate v.borated glassborated waterboreboreholeborescopeborescope built into the syringe borescope inspectionboric acid(12%)boric acid(12% w/o solution)boric acid batching tankboric acid concentrationboric acid evaporatorboric acid makeupboric acid pumpboric acid removalboric acid surge tankboric acid tankboric oxideboringboring barboring benchboring millboron concentrationboron concentration monitoring boron contentboron criticality searchboron dilutionboron equivalentboron injection tankboron makeupboron meterboron precipitationboron recycleboron recyclingboron releaseboron removalboron steelboron-coated proportional counter boron-lined ion chamberboron-lined ionization chamber boron-lined proportional counter borosilicate glassborosilicate glass tube borosilicate tubebossbottombottom end plug(fuel rod or thimble plug) bottom entrybottom fitting(fuel assembly)bottom frictionbottom grid assembly(fuel assembly) bottom guide tube flangebottom guide tube flange holebottom headbottom head instrument penetration bottom nozzle(fuel assembly)bottom suctionbottom surfacebottom viewbottoming tapbottoms(evaporator)boundaryboundary conditionsboundary markerboundary wallbourndon tubebow(assembly)bow springbowed rodbowingbowlbowl and shaft assemblysupport(multistage pumps)boxbox end socket wrenchbox girderbox gutterbox sectionbox socket wrenchbox wrenchbox wrench(12-point)box-outbracebracketbrackish waterbraidbraided packingbraided shieldingbrakebrake horsepowerbrakingbranchbranch connectionbranch pipe jointbranch pipe weldbranch raceway branching(disintegration) branching crackbrassbraze weldingbrazed jointbrazerbrazingbrazing pastebrazing powderbreachbreakbreak a vacuum v.break contactbreak in electrical continuity break vesselbreak-before-make contact break-in periodbreak-make transfer switch breakawaybreakaway force breakaway starting current breakaway torque breakdownbreaker modulebreaker with ultrashort breaking time breaker-fuse combinationbreaking around an obstruction breaking capacitybreaking strengthbreaking stressbreakoutbreastwallbreather pipebreeches pipebreechlockbreechlock bonnetbreechlock sealbremsstrahlungbrickbridgebridge girderBriggs pipe thread plugbright annealingbright-dim lampbrinebrine heaterbrittlebrittle fracturebroachbroachingbrokenbroken tapbronzebrought outbrought out to terminal blockbrown oxidebrushbrush v.(to remove excess slag) brush surface analyzerbrushing machine brushing unitbubble collapsebubble suitbubbler level sensor bubbling(welding defect) bucklebucklingbuckling lengthbuckling loadbuckling strength buckling testbufferbuffer tankbuffetingbug holes(concrete)build-up factorbuilderbuildingbuilding ground conductor building structure building-type switchboard buildupbuildup sequencebuilt-in reactivitybuilt-up backpressure built-up seat(hard facing) built-up weld deposite builtup roofingbuiltup sectionbulbbulgebulge jointbulkbulk boilingbulk densitybulk materialsbulk storage tankbulkhead(of an air lock)bulkhead connectorbulkingbullet-nose welded end plug(thimble tube) bullet-shaped end plug(thimble tube) bullet-shaped welded ene plug(thimble tube)bumperbumpless transfer systembundlebundle wrapper(steam generator) bundledbundlingbunkerburial depthburial in concrete(using encased duct) buriedburied cableburied grid electrodeburied pipeburied piping and cablesburied-cableburn-off rateburn-up life(neutron detector)burnable posionburnable posion assembly storage adapter burnable posion rodburnable posion rod assembly burnishingburnout(fuel)burnout heat fluxburnout pointburnout ratioburnup fractionburnup sharingburnup sharing fractionburr(concrete)burringburring machine(soyage) burstburst pressureburst testbusbus compartmentbus ductbus sectionbus voltage metering section busbarbush hammeringbushingbushing shellbuswaybusworkbutt jointbutt strapbutt weldbutt weldingbutterflybutterfly control valve butterfly valvebutteringbuttering on dissimilar metal buttress(retaining wall) buttress v.buttress dambuttress threadbuttweld endbuttweld end connection buzzerbypass v.(electronic circuit)bypass breakerbypass damperbypass flow ratebypass linebypass valvecab(lifting equipment)cabinetcablecable anchorcable bookcable boxcable bridgecable capcable chasecanle clampcable clipcable cuttercable deckcable depthcable destinationcable endcable end bushing(protects cable at entry to enclosure)cable end capcable entrancecable entrycable exitcable fillcable fittingscable floorcable gallerycable glandcable gland with seismic-resistant cable clampcable in conduitcable jointcable laddercable laid in trays cable layercable layingcable marking tool cable penetration cable pullercanle puller/tensioner cable pullingcable pulling eye cable rackingcable roomcable routing schedule cable runningcable schedulecable sleevecable spreading area cable spreading room cable storage yard cable strapcable support system cable tagcable termination cable tiecable tie applicator tool cable traycable tunnelcable tyingcable unreelercable vaultcabledcablemancablescablewaycableyardcablingcabling diagramcabling roomcadmium cut-offcadmium ratiocadmium-platedcadweld rebar splicecagecage control valvecage nutcage valve trimcage-guided valve trimcage-type plug disk globe valve caged laddercageless plug disk globe valve caisson(foundations)calaminecalcinationcalcinercalciningcalcining furnacecalciothermycalculationcalculation meshcalculation methodcalculation pointcalculation sheetcalculation timecalculational methodcalculatorcalibrate v.(instrumentation channel) calibrationcalibration benchcalibration blockcalibration coefficientcalibration holecalibration slopecalked joint。
不对称自由基反应英文
不对称自由基反应英文Asymmetric Radical Reactions: An Insight into Their Mechanism and Applications.Introduction.Asymmetric radical reactions have emerged as a powerful tool in organic synthesis, enabling the synthesis of chiral compounds with high enantiomeric purity. These reactions differ significantly from their symmetric counterparts, as they involve the generation and utilization of chiral radicals. These chiral radicals can undergo a range of reactions, including substitution, addition, and cyclization, leading to the formation of enantiomerically enriched products.Mechanism of Asymmetric Radical Reactions.The mechanism of asymmetric radical reactions typically involves three key steps: radical generation, chiralitytransfer, and radical termination.Radical Generation.The first step involves the generation of a radical species. This can be achieved through various methods, such as photolysis, thermal decomposition, or redox reactions. The generated radical can be chiral or achiral, depending on the starting materials and the conditions used.Chirality Transfer.The second step involves the transfer of chirality from a chiral auxiliary or catalyst to the radical species. This chirality transfer can occur through covalent or non-covalent interactions between the catalyst/auxiliary and the radical. The nature of these interactions determines the stereoselectivity of the reaction.Radical Termination.The final step involves the termination of the radicalspecies, leading to the formation of the desired product. This termination can occur through various mechanisms, such as coupling with another radical species, hydrogen atom abstraction, or disproportionation.Applications of Asymmetric Radical Reactions.Asymmetric radical reactions have found widespread applications in various fields of organic synthesis, including the synthesis of natural products, pharmaceuticals, and functional materials.Synthesis of Natural Products.Natural products often possess complex chiral structures, making their synthesis challenging. Asymmetric radical reactions have proven to be effective tools for the synthesis of such chiral natural products. For example, the use of chiral radicals generated from appropriate precursors has enabled the enantioselective synthesis of alkaloids, terpenes, and amino acids.Pharmaceutical Applications.The enantiomers of chiral drugs often differ significantly in their biological activities, making it crucial to control their enantiomeric purity. Asymmetric radical reactions can be used to synthesize enantiomerically enriched chiral drugs with high selectivity. This approach has been successfully applied to the synthesis of various drugs, including anti-inflammatory agents, anticancer agents, and antiviral agents.Functional Materials.Chiral materials possess unique physical and chemical properties that make them useful in various applications, such as displays, sensors, and catalysts. Asymmetricradical reactions can be used to synthesize chiral building blocks for the preparation of such materials. For instance, chiral polymers can be synthesized by utilizing asymmetric radical polymerization reactions, leading to the formation of materials with controlled chirality and tailored properties.Conclusion.Asymmetric radical reactions have emerged as powerful tools for the synthesis of enantiomerically enriched chiral compounds. Their unique mechanism, involving chirality transfer from a chiral catalyst/auxiliary to the radical species, enables high selectivity and enantiopurity in the product. The widespread applications of asymmetric radical reactions in organic synthesis, particularly in the synthesis of natural products, pharmaceuticals, and functional materials, highlight their importance in modern chemistry.Future Perspectives.Despite the significant progress made in the field of asymmetric radical reactions, there are still numerous challenges and opportunities for further exploration.Improving Selectivity and Efficiency.One of the key challenges in asymmetric radical reactions is achieving high selectivity and efficiency. While significant progress has been made in this area, there is still room for improvement. Future research could focus on developing new chiral catalysts/auxiliaries that can promote asymmetric radical reactions with higher selectivity and efficiency.Expanding the Scope of Reactions.Currently, the scope of asymmetric radical reactions is limited by the availability of suitable precursors and the reactivity of the generated radicals. Future research could aim to expand the scope of these reactions by developing new methods for generating radicals with desired functionalities and reactivities.Applications in Sustainable Chemistry.In the context of sustainable chemistry, asymmetric radical reactions offer an attractive alternative to traditional synthetic methods. By utilizing renewableresources and mild reaction conditions, asymmetric radical reactions could contribute to the development of more sustainable synthetic routes for the preparation of chiral compounds.Integration with Other Techniques.The integration of asymmetric radical reactions with other techniques, such as photocatalysis, electrochemistry, and microfluidics, could lead to the development of new and innovative synthetic methods. By combining the advantages of these techniques, it may be possible to achieve even higher selectivity, efficiency, and scalability in asymmetric radical reactions.In conclusion, asymmetric radical reactions have emerged as powerful tools for the synthesis of enantiomerically enriched chiral compounds. While significant progress has been made in this area, there are still numerous opportunities for further exploration and development. Future research in this field could lead tothe discovery of new and innovative synthetic methods with improved selectivity, efficiency, and sustainability.。
晶体结构被破坏英语作文
晶体结构被破坏英语作文1. Oh no! The crystal structure has been completely destroyed! It's a total mess now. I can't believe this happened. Everything was so perfectly arranged before, and now it's all chaotic and disordered.2. It's like a beautiful symphony that has suddenly turned into a cacophony of noise. The once elegant and organized lattice has been shattered into countless fragments. It's heartbreaking to see something so delicate and intricate reduced to such a state of disarray.3. The destruction of the crystal structure is a stark reminder of the fragility of order in our world. It's a harsh reality check that even the most stable and structured systems can be easily disrupted. It's a testament to the unpredictable nature of life and the constant need for adaptation and resilience.4. The loss of the crystal structure also signifies theloss of its inherent properties and functionality. The carefully arranged atoms that gave the crystal its unique characteristics are now scattered and disconnected. It's like a puzzle with missing pieces, rendering it incomplete and ineffective.5. The destruction of the crystal structure also has implications beyond its physical appearance. It symbolizes the breakdown of a larger system or organization. It's a metaphor for the collapse of order and harmony in society, where chaos and disorder prevail.6. However, amidst the destruction, there may be an opportunity for something new to emerge. Just as a forest fire clears the way for new growth, the destruction of the crystal structure may pave the way for a fresh start. It's a chance to rebuild and reimagine, to create something even more beautiful and resilient.7. The destruction of the crystal structure serves as a reminder that nothing lasts forever. Change is inevitable, and sometimes it comes in the form of destruction. It's acall to appreciate and cherish the beauty and order that exist in our lives, as they can be easily shattered and lost.8. In the end, the destruction of the crystal structure is a powerful reminder of the impermanence of everything.It's a wake-up call to embrace the present moment and find beauty in the midst of chaos. Life is unpredictable, andit's up to us to navigate through the broken pieces andfind meaning in the ruins.。
链条的强度取决于它的薄弱环节英语作文
The Strength of a Chain Lies in Its WeakestLinkIn the realm of mechanical engineering, a chain's strength is often judged not by its sturdiest links, but by its weakest ones. This adage applies not just to physical chains but also to the intangible ones that shape our lives, such as habits, beliefs, and systems. In essence, the strength of any entity is contingent upon the weakest part, which, if compromised, can lead to its overall failure.The concept of the weakest link is particularlyrelevant in the context of teamwork. A team, regardless of how talented or skilled its members are, can only achieveits full potential if each member fulfills their role effectively. It is the member who lags behind, the one whois not as proficient or engaged, that can limit the team's overall performance. Similarly, in a chain, it is the weakest link that determines how much weight the chain can bear before breaking.This principle also applies to personal development. We often focus on building our strengths and talents, ignoring the areas where we are weakest. However, it is theseweaknesses that can hold us back from achieving our full potential. It is essential to identify and work on our weaknesses to ensure that they do not become the Achilles' heel that prevents us from reaching our goals.Moreover, the weakest link principle highlights the importance of continuous improvement. In a chain, regular maintenance and replacement of weak links can ensure its durability and longevity. Similarly, in our lives, we must continually strive to improve ourselves, addressing our weaknesses and turning them into strengths.In conclusion, the strength of a chain lies in its weakest link. This principle reminds us that it is our weaknesses, not our strengths, that determine our limits.It urges us to identify and address our weaknesses, to work towards continuous improvement, and to recognize that the smallest link in the chain can have the biggest impact on our overall strength and success.**链条的强度取决于它的薄弱环节**在机械工程领域,链条的强度往往不是由它最坚固的环节决定,而是由最薄弱的环节决定。
HPLC-Q-TOF-MS分析乙酰吉他霉素中的组分和杂质
文章编号:1001-8689(2021)05-0416-07分析质控与制剂HPLC-Q-TOF-MS分析乙酰吉他霉素中的组分和杂质钱建钦陈悦洪利娅*(浙江省食品药品检验研究院国家药品监督管理局仿制药评价关键技术重点实验室,杭州 310052)摘要:目的采用高效液相色谱-四级杆-飞行时间质谱(HPLC-Q-TOF-MS)技术对乙酰吉他霉素中的主要组分和杂质进行鉴色谱柱,以0.1mol/L乙酸铵溶液(乙酸调pH值至6.0)-乙腈(40:60)为流动相。
在正离子定和分析。
方法采用Supelco Discovery C18模式下获取高分辨质谱数据,结合已有的大环内酯类抗生素质谱裂解规律,解析组分和杂质的结构。
根据提取离子质谱图(EIC)峰面积计算乙酰吉他霉素中已知组分和杂质的相对百分含量。
结果分析了乙酰吉他霉素中5个主要组分,并鉴定解析了4大类共16个杂质,分别为2'位去乙酰化物、4位去乙酰化物、3''位乙酰化物、4''位去乙酰化物。
结论 HPLC-Q-TOF-MS技术可快速、灵敏、准确地鉴定乙酰吉他霉素中的组分和杂质。
不同厂家样品中组分和杂质的相对含量差异较大,提示产品质量与生产工艺密切相关。
关键词:乙酰吉他霉素;杂质鉴定;四级杆-飞行时间质谱中图分类号:R978.1 文献标志码:AIdentification of the components and impurities of acetylkitasamycinby HPLC-Q-TOF-MSQian Jian-qin, Chen Yue, and Hong Li-ya(Zhejiang Institute for Food and Drug Control, Key Laboratory of Core Technology for Generic Drug Evaluation, National MedicalProducts Administration, Hangzhou 310052)Abstract Objective To identify the components and impurities of acetylkitasamycin by high performance liquid chromatography quadrupole time-of-flight tandem mass spectrometry (HPLC-Q-TOF-MS). Methods The separation was performed on a Supelco Discovery Ccolumn using isocratic mobile phase of 0.1mol/L ammonium18acetate solution (adjust to pH 6.0 with acetic acid)–acetonitrile (60:40). Full scan and MS2 experiment were performed under the positive ion mode to acquire high-resolution MS data. The chemical structures of the components and impurities were characterized based on the systematic investigation of macrolide fragmentation pathways. The relative percentage of the known components and impurities was calculated considering the peak areas of extracted ion chromatography (EIC) by the area normalization method. Results The high-resolution MS and MS2 data were used for structural elucidation. Five components in acetylkitasamycin were analyzed. In addition, four kinds of impurities (16 impurities in total) were characterized, namely, 2'-deacetyl-acetylkitasamycin, 4-deacetyl-acetylkitasamycin, 3''-acetyl-acetylkitasamycin, and 4''-deacetyl-acetylkitasamycin. To the best of our knowledge, 4-deacetyl-acetylkitasamycin, 3''-acetyl-acetylkitasamycin, 4''-deacetyl-acetylkitasamycin have not been reported before. Conclusion HPLC-Q-TOF-MS is a rapid, sensitive, accurate method for identification of the components and impurities of acetylkitasamyin. The relative percentage of the components and impurities in different samples varied significantly, indicating the收稿日期:2020-04-26作者简介:钱建钦,男,生于1986年,博士,主管药师,研究方向:药物分析,E-mail:********************.cn*通讯作者,E-mail:*****************.cn吉他霉素(kitasamycin ,leucomycin)是由北里链霉菌(S. kitasatoensis )产生的多组分十六元大环内酯类抗生素,主要有效组分为吉他霉素A 组分,包括A 1、A 3、A 4、A 5、A 6、A 7、A 8、A 9和A 13(表1)[1-2]。
压力限制肿瘤增长翻译 中英
最后译文:压力限制肿瘤生长法国物理学家发现了简单的力压在医学上可应用于降低肿瘤的生长速度并限制其生长大小。
通过使用老鼠细胞来完成这项工作的研究者说这个结果可以引生出更好的癌症诊断工具并很可能最终实现用药物治疗癌症。
众所周知当生长细胞中的DNA发生突变时就会形成肿瘤并发展为癌症, .但是这种发展是如何受到肿瘤周围环境的影响仍是一个需要讨论的课题。
由巴黎居里学院的让.弗朗斯科乔尼和其他一些院校进行了一项新的调查,研究肿瘤的生长是如何受到它所经受的压力的限制的,如同按压周围的健康组织一样。
很难把基因学、生物化学和力学在生物机体内的肿瘤中所扮演的角色分离出来。
为了解释这一问题,乔尼的团队用老鼠细胞中的一个直径十余毫米的类似肿瘤的球在实验台上进行了这项工作,工作者们把这个模拟肿瘤放入一个由半渗透聚合物制成的几毫米长的袋子中,这之后就进入到一个滋生细胞的包含营养物的研究方案中。
肿瘤在这种自由的状态下会继续生长两周或者三周, 直到达到细胞的死亡和分裂刚好平衡的稳态。
糖分的严厉打击为了找出在这个生长过程中是什么影响到了压力, 小组在此方案中加入了很多糖分这些糖分由于颗粒太大而无法穿过袋子的微小孔洞所以仍在袋子外面,造成了一种浓度的不平衡,而使其迫切的要解决掉袋子外的溶液以努力恢复其浓度的平衡,袋子外较大浓度的溶液随即对袋子产生了力度的压迫,并且这种压迫被里面的肿瘤所感应到。
这种方法被重复用于同样的肿瘤上,每个不同袋子中的肿瘤被不同浓度的糖分溶液所浸透,因此揭示出每个肿瘤都受到了不同的压力。
该小组发现压力越大,肿瘤生长越慢并且最终尺寸越小。
比如施加500帕的压力,仅仅百分之两点五的气压),便可将肿瘤的增长率和稳态量减半。
为了精准地确立压力是如何减弱增长的,乔恩和他的同事将肿瘤冰冻起来,将其切成非常薄的薄片,.并在薄片上覆盖两种抗体,这个方法显示出了在每个肿瘤上已死亡而被分离的细胞----这两种细胞发出的荧光波长不同-。
高温胁迫下喷施外源一氧化氮对恢复生长期菜豆幼苗相关生理特性的影响
引文格式:陈瑶瑶, 严良文, 刘智成, 等. 高温胁迫下喷施外源一氧化氮对恢复生长期菜豆幼苗相关生理特性的影响[J]. 云南农业大学学报(自然科学), 2023, 38(2): 290−297. DOI: 10.12101/j.issn.1004-390X(n).202207019高温胁迫下喷施外源一氧化氮对恢复生长期菜豆幼苗相关生理特性的影响*陈瑶瑶1, 严良文1 **, 刘智成1, 余 洁2, 蒋春艳1, 蔡建荣1(1. 龙岩市农业科学研究所,福建 龙岩 364000;2. 龙岩市新罗区农业局,福建 龙岩 364000)摘要: 【目的】缓解高温胁迫对菜豆幼苗的伤害。
【方法】以闽西地方菜豆品种黄种豆幼苗为试材,在高温胁迫下喷施不同浓度的外源一氧化氮供体硝普钠(sodium nitroprusside ,SNP),观察测定幼苗生长的变化,并测定其相关生理指标的变化,探讨SNP 对恢复生长期幼苗生理特性的影响。
【结果】高温胁迫明显抑制菜豆幼苗生长,导致叶片灼伤、萎蔫卷曲,其株高、茎粗、鲜质量和干质量显著低于常温对照,适宜浓度的SNP (0.5~1.0 mmol/L)处理可以有效改善胁迫条件下幼苗表型及株高和茎粗,其中以0.7 mmol/L SNP 处理效果最佳。
恢复生长试验结果表明:与常温对照相比,结束高温胁迫0 h 时幼苗叶片叶绿素、可溶性糖、可溶性蛋白、脯氨酸和内源NO 含量以及SOD 和CAT 活性均显著降低,MDA 含量和POD 活性显著升高;高温胁迫下喷施SNP 可提高恢复期幼苗叶片的叶绿素、渗透调节物质和内源 NO 含量,促进抗氧化酶活性,降低MDA 含量,各指标均以0.7 mmol/L SNP 处理最优,且在恢复生长48~72 h 时最接近常温生长幼苗。
【结论】高温胁迫下喷施一定浓度的SNP 可有效保护菜豆幼苗生长并促进生长恢复。
关键词: 外源一氧化氮;高温胁迫;菜豆幼苗;恢复生长;生理特性中图分类号: S643.101 文献标志码: A 文章编号: 1004–390X (2023) 02−0290−08Effects of Spraying Exogenous Nitric Oxide under High Temperat-ure Stress on Physiological Characteristics of Phaseolus vulgaris L. in Recovery Growth PeriodCHEN Yaoyao 1,YAN Liangwen 1,LIU Zhicheng 1,YU Jie 2,JIANG Chunyan 1,CAI Jianrong 1(1. Longyan Institute of Agricultural Sciences, Longyan 364000, China;2. Agriculture Bureau of Xinluo District, Longyan 364000, China)Abstract: [Purpose ]To mitigate the damage of high temperature stress to Phaseolus vulgaris L.[Methods ]Different concentrations of exogenous nitric oxide donor sodium nitroprusside (SNP)were sprayed to the test material ‘Yellow Seed Bean’ seedlings, a local kidney bean variety in west Fujian, under high temperature stress. The growth changes of the seedlings were observed and de-termined, and the changes of the relevant physiological indicators were determined to study the ef-fects of SNP on the physiological characteristics of the seedlings in the recovery growth period.云南农业大学学报(自然科学),2023,38(2):290−297Journal of Yunnan Agricultural University (Natural Science)E-mail: ********************收稿日期:2022-07-11 修回日期:2023-02-28 网络首发日期:2023-04-23*基金项目:福建省2021年团队科技特派员项目(2021T3508039);福建省2021年个人科技特派员项目(202135080180)。
三引物鉴定法英文
三引物鉴定法英文The three-primer identification method is a sophisticated technique used in molecular biology to identify specific DNA sequences. It involves the use of three distinct primers, each designed to bind to a unique region of the DNA strand.This method is particularly useful in genetic testing, where it can help pinpoint mutations or variations in the genetic code. By employing a set of primers, researchers can amplify and analyze specific segments of DNA, providing a more targeted approach to genetic analysis.The process begins with the denaturation of the DNA, separating the two strands to expose the binding sites for the primers. Following this, the primers anneal to their respective sites, initiating the polymerase chain reaction (PCR), which amplifies the target DNA sequence.The amplified products are then subjected to gel electrophoresis, a method that separates DNA fragments based on their size. This allows for the identification and comparison of the DNA sequences, providing insights into the genetic variations present.In forensic science, the three-primer identification method is invaluable for solving crimes. It can help differentiate between samples, ensuring that the correct individual is identified and implicated in a case.Moreover, this method has applications in medical research, where it can be used to study genetic diseases and develop targeted therapies. By understanding the genetic makeup of an individual, researchers can tailor treatments to better suit the patient's needs.In summary, the three-primer identification method is a versatile tool in the field of molecular biology, offering precision and specificity in DNA analysis, with wide-ranging applications from genetic testing to forensic science and medical research.。
定语从句的翻译省名师优质课赛课获奖课件市赛课一等奖课件
The control unit is an important part of the computer, which can cause the machine to operate according to man’s wishes.
控制器是计算机旳主要部分,它能使计算机按人 们旳意愿进行操作。
施加旳压力作用在一种膜片上,于是该膜片 就移动阳极管脚。
Theory is based on practice and in turn serves practice.
理论旳基础是实践, 反过来理论又为实践服务。
当关系代词which引导非限定性定语从句,阐 明整个主句,对主句旳内容作补充阐明、 总结、概括或承上启下旳作用时,可译成 指示代词“这”。
The additional ozone may absorb more than the usual amount of the sun's heat, which in turn may effect our weather.
增长旳臭氧吸收比正常量更多旳太阳旳热量,从 而影响到我们旳天气。
成人教育热继而又增进了整个国家文化水平旳提 升。
There is no place on earth where the days are longer in winter than in summer.
地球上任何地方冬天旳白昼都比夏天长。
金属旳强度、硬度和可塑性这些性能使它们 在工业上得到广泛应用。(红色译为定语 从句)
Strength, hardness and plasticity of metals are the properties that make them so useful for industry.
超难治性癫痫持续状态并昏迷患者的救治体会
•238•中国中西医结合急救杂志2019年3月第26卷第2期Chin JTCMWM Crit Care.March2019,Vol.26,No.2•临床经验•超难治性癫痫持续状态并昏迷患者的救治体会谢文杰王璐黄科生田建国武汉大学人民医院重症医学科,湖北武汉430060通信作者:田建国,Email:410669243@【摘要】目的探讨咪达輕仑联合阿曲库鞍治疗超难治性癫痫持续状态(SRSE)并昏迷的有效性及临床预后。
方法武汉大学人民医院重症医学科2018年5月收治1例SRSE患者,对其症状、体征、实验室检查及治疗过程进行总结,结合文献复习分析治疗过程及预后。
结果24岁男性患者发热4d后出现抽搐,入院时检查血常规、血生化、凝血功能及感染指标基本正常,脑脊液未见明显异常,血中病原微生物检查提示有病毒感染的可能。
脑电图(EEC)提示病变累及右侧额极-额区-颖区。
头颅核磁影像(MRI)提示鼻窦炎及脑膜、海马感染可能。
采用多种抗癫痫药物治疗后抽搐仍不能控制,联合咪达醴仑及阿曲库镀治疗后抽搐才得以控制,并给予抗病毒、糖皮质激素、免疫球蛋白及预防并发症等治疗。
43d后患者意识恢复,肌力逐渐改善。
结论咪达睦仑联合阿曲库钱控制SRSE并昏迷患者是有效的,并可减轻后遗症。
【关键词】超难治性癫痫持续状态;昏迷;咪达輕仑;阿曲库镀;意识恢复基金项目:湖北省自然科学基金(2018CFB216)DOI:10.3969/j.issn.1008-9691.2019.02.026Experience in rescue and treatment of patients with super-refractory status epilepticus and coma Xie Wenjie,Wang Lu,Huang Kesheng,Tian JianguoDepartment of Critical Care Medicine,Renmin Hospital of Wuhan University,Wuhan430060,Hubei,ChinaCorresponding author:Tian Jianguo,Email:410669243@【Abstract]Objective To investigate the efficacy and prognosis of using midazolam combined with atracuriumfor treatment of a patient with super-refractory status epilepticus(SRSE)and coma.Methods A case of SRSE andcoma admitted to the Department of Critical Care Medicine of Renmin Hospital of Wuhan University in May2018wasenrolled.The symptoms,signs,laboratory examinations and treatment process were summarized,and combined withthe literature review,the therapeutic course and prognosis were analyzed.Results A male patient,24years old,had convulsions after4—day fever,blood routine,blood biochemistry,coagulation function and infection indexes werebasically normal on admission.There was no obvious abnormality in cerebrospinal fluid examination;blood pathogenic microorganism examination suggested that viral infection possibly occur.Electroencephalogram(EEG)showed that thelesions involved the right frontal pole-frontal area-temporal area;cranial magnetic resonance imaging(MRI)suggestedthat sinusitis and meningeal and hippocampal infections might be present.Although several antiepileptic drugs hadbeen used,the convulsions could not be controlled,after combined with the application of midazolam and atracurium,the convulsions were controlled,in the mean time,antiviral drug,glucocorticoid and immunoglobulin and therapiesfor prevention of complications were applied.Forty—three days later,the patient's consciousness was recovered andmuscle strength was gradually improved.Conclusion The combination of midazolam and atracurium is effective forcontrolling epileptic activities and alleviating sequelae in patients with SRSE and coma.[Key words】Super-refractory status epilepticus;Coma;Midazolam;Atracurium;Consciousness recoveryFund program:Huhei Science and Technology Plan Project(2018CFB216)DOI:10.3969/j.issn.1008-9691.2019.02.026癫痫持续状态是指癫痫临床发作或脑电图提示痫样放电持续5min及以上或癫痫反复发作持续5min以上,在两次癫痫发作期间意识未恢复至基线水平又频繁再发癫痫⑴,其发病率和病死率均较高,约30%-40%的患者会发展成为难治性癫痫持续状态(RSE),且病死率约为19%~67%⑵。
材料化学专业英语中长难句翻译技巧及解析
材料化学专业英语中长难句翻译技巧及解析本文从网络收集而来,上传到平台为了帮到更多的人,如果您需要使用本文档,请点击下载按钮下载本文档(有偿下载),另外祝您生活愉快,工作顺利,万事如意!材料化学专业英语长句多,翻译困难。
本文举例解析长难句的句型结构,并结合专业知识进行句子翻译技巧的归纳总结,旨在为材料化学专业英语的教和学提供帮助。
材料化学主要介绍金属、陶瓷、高分子及复合材料的结构、性能、加工、设计及用途,其专业英语与日常英语截然不同[1],句子以长难句为主,这对学生阅读专业文献造成很大困扰。
本文举例解析长难句的句型结构,并结合材料化学专业知识进行句子翻译技巧的归纳总结,为材料化学专业英语的教和学提供帮助。
1.翻译技巧为了专业问题表述的严密性和准确性,材料化学专业英语中的句子多为带有修饰成分的长句,即句中多有定语、状语、补语等从句;再者,为了专业问题表述的客观性和专业性,句子多用被动语态,又有若干特定句型,这些就导致专业英语句子翻译困难[2-4]。
专业英语的翻译要求“信、达、雅”:信—准确,即译文要不偏离、不遗漏、不随意增减意思,符合学科的发展规律;达—通顺明白,指句子符合汉语的表达习惯,不拘泥于原文形式;雅—专业得体,指译文选词要专业得体,简明优雅。
实际翻译科技英语句子时,首先要断句准确,即找到句子的主干(主、谓、宾)和枝叶(定、状、补),再根据句型(如It-that句型、被动句型、省略句型等)和特定词汇,结合上下文和专业知识才能准确翻译句子。
因此,专业英语的翻译是对语法、特殊句型、特定词汇和专业知识的综合运用。
2.长难句解析带有特征词汇的句子周丽云[4,5]归纳了表达无机、有机化学经典反应的句子中常带有的一些特征词汇,通过这些词汇可以辨识反应类型并准确翻译句义。
表明特定反应类型的词有:decompose或decomposition (分解),disproportionate或disproportionation (歧化),neutralize 或neutralization (中和),oxidize或oxidation (氧化),reduce或reduction (还原),ionize或dissociate (电离),hydrolyze或hydrolysis (水解),electrolyze或electrolysis (电解),substitution或substitute或replacement或displacement (取代),addition (加成),elimination (消除),polymerize或polymerization (聚合),catalysis (催化)等反应,未表明反应类型的词有:react (反应),form (形成)。
临界反应 英语
临界反应英语Critical ReactionIn chemistry, a critical reaction is a term used to describe a reaction that occurs only under specific conditions. These conditions may include temperature, pressure, concentrations of reactants, or the presence of catalysts. The critical reaction is the point at which the reaction rate changes significantly due to a change in one of these critical factors. Understanding critical reactions is essential for predicting and controlling chemical processes.One common example of a critical reaction is the decomposition of hydrogen peroxide. This reaction occurs slowly at room temperature, but when a catalyst, such as manganese dioxide, is added, the reaction speeds up dramatically. The critical factor in this reaction is the presence of the catalyst, which lowers the activation energy required for the reaction to occur. Without the catalyst, the reaction may not occur at all or may proceed at an extremely slow rate.Another example of a critical reaction is the oxidation of iron. Under normal conditions, iron does not react with oxygen in the air. However, if the iron is heated to high temperatures, a criticalreaction occurs, leading to the formation of iron oxide, also known as rust. The critical factor in this reaction is the temperature, as it determines the energy required for the reaction to take place.Understanding critical reactions is crucial in various industries, such as pharmaceuticals, petrochemicals, and materials science. By controlling the critical factors in a reaction, chemists can optimize reaction conditions to maximize the efficiency of a process, reduce waste, and improve product quality. Additionally, studying critical reactions can lead to the development of new catalysts and processes that can revolutionize the way chemicals are produced and used in various applications.In conclusion, critical reactions play a vital role in chemistry by determining the conditions under which a reaction occurs. By understanding and controlling critical factors, chemists can manipulate reactions to achieve desired outcomes and improve the efficiency of chemical processes. As technology advances, the study of critical reactions will continue to be essential in developing new materials, drugs, and technologies that shape our world.。
- 1、下载文档前请自行甄别文档内容的完整性,平台不提供额外的编辑、内容补充、找答案等附加服务。
- 2、"仅部分预览"的文档,不可在线预览部分如存在完整性等问题,可反馈申请退款(可完整预览的文档不适用该条件!)。
- 3、如文档侵犯您的权益,请联系客服反馈,我们会尽快为您处理(人工客服工作时间:9:00-18:30)。
Alkan Kabak¸ cıo˘ glu1,2and A. Nihat Berker1,2,3
1
arXiv:cond-mat/9811235v2 [cond-mat.dis-nn] 17 Nov 1998
randomness. We have studied the Blume-Emery-Griffiths (i.e., spin1 Ising) model under quenched field randomness. The Hamiltonian is − βH =
<ij> † + Hij (si + sj ) + Hij (si − sj ) , 2 2 2 Jsi sj + Ks2 i sj − ∆ si + sj
<ij> † † 2 2 2 + Lij s2 i sj + si sj + Lij si sj − si sj + Hij (si + sj ) + Hij (si − sj ) † 2 2 2 2 2 Jij si sj + Kij s2 i sj − ∆ij (si + sj ) − ∆ij (si − sj )
பைடு நூலகம்(1)
where si = ±1, 0 at each site i of a simple cubic (d = 3) lattice and < ij > indicates summation over all nearestneighbor pairs of sites. The quenched random fields † Hij , Hij are taken from a distribution P (H, H † ) = 1 δ (H + σH ) δ H † + σH 4 . (2)
<ij>
,
(4)
− → † † where K ij ≡ (Jij , Kij , ∆ij , ∆† ij , Lij , Lij , Hij , Hij ) are the interactions at locality < ij >, the primes refer to the renormalized system, the product is over all unrenormal− → ized localities < ij > whose interactions { K ij } influence ′ − → − → − → the renormalized interaction K i′ j ′ , and R ({ K ij }) is a local recursion relation that embodies the latter dependence. Simply said, Eq.(4) sums over the joint probabilities of the values of neighboring unrenormalized interactions that conspire to yield a given value of the renormalized interaction. The phenomena characteristic to quenched randomness should derive from the probability convolution shown in Eq.(4), rather than the precise form − → of the recursion R that should be a smooth local function. In this work, we use the Migdal-Kadanoff recursion 2
+ δ (H + σH )δ H † − σH + δ (H − σH )δ H † + σH + δ (H − σH ) δ H † − σH All other interactions in the initial Hamiltonian (1) are non-random. Under renormalization-group transformations, the Hamiltonian (1) maps onto a random-field random-bond Hamiltonian, − βH =
,
(3)
where all interactions are quenched random, with a distri† † bution function P Jij , Kij , ∆ij , ∆† ij , Lij , Lij , Hij , Hij determined by the renormalization-group transformation. Specifically, the first four arguments here reflect the rescaling-induced bond randomness of the randomfield system. The renormalization-group transformation is contained in the mapping between the quenched probability distributions of the starting and rescaled systems, ′ ′ <i j > ′ − → − → − →′ − → − → − → d K ij P K ij δ K i′ j ′ − R K ij P ′ K i′ j ′ =
In view of the recently seen dramatic effect of quenched random bonds on tricritical systems, we have conducted a renormalization-group study on the effect of quenched random fields on the tricritical phase diagram of the spin-1 Ising model in d = 3. We find that random fields convert first-order phase transitions into second-order, in fact more effectively than random bonds. The coexistence region is extremely flat, attesting to an unusually small tricritical exponent βu ; moreover, an extreme asymmetry of the phase diagram is very striking. To accomodate this asymmetry, the second-order boundary exhibits reentrance.
Department of Physics, Massachusetts Institute of Technology Cambridge, Massachusetts 02139, U.S.A. 2 Feza G¨ ursey Research Center for Basic Sciences C ¸ engelk¨ oy, Istanbul 81220, TURKEY 3 Department of Physics, Istanbul Technical University Maslak, Istanbul 80626, TURKEY
Tricritical phase diagrams of three-dimensional (d = 3) systems are strongly affected by quenched bond randomness: The first-order phase transitions are replaced, gradually as randomness is increased, by second-order phase transitions. The intervening random-bond tricritical point moves towards, and eventually reaches, zerotemperature, as the amount of randomness is increased. This behavior is an illustration of the general prediction that first-order phase transitions are converted to secondorder by bond randomness [1–7], in a thresholded manner in d = 3. The randomness threshold increases from zero at the non-random tricritical point. The randombond tricritical point maps, under renormalization-group transformations, onto a doubly unstable fixed distribution at strong coupling. Random-bond tricritical points exhibit a remarkably small value for the tricritical exponent βu = 0.02, reflected in the near-flat top of the coexistence region. In the conversion of the first-order phase transition to second-order, traced by the randombond tricritical point, a strong violation of the empirical universality principle occurs, via a renormalization-group fixed-point mechanism. Thus, detailed information now exists on the effect of quenched bond randomness on tricritical points, revealing several qualitatively distinctive features. [5,8] No such information has existed on the effect of quenched field randomness on tricritical points. This topic is of interest also because renormalization-group studies have shown that quenched field randomness induces, under scale change, quenched bond randomness, as the presence of quenched field randomness continues. [9] Accordingly, we have conducted a global renormalization-group study of a tricritical system in d = 3 under quenched random fields. The results, presented below, show that these systems have their own distinctive behavior which is qualitatively different from that of non-random or random-bond tricritical systems. The latter distinction yields a microscopic physical intuition on the different effects of the two types of quenched 1