中甸红山矽卡岩铜矿稳定同位素特征及其对成矿过程的指示
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中甸红山矽卡岩铜矿稳定同位素特征及其 对成矿过程的指示
王守旭!" #张兴春! #冷成彪!" #秦朝建! #王外全$ #赵茂春% ! " &' ( )*+, -. -!" / 0 ' ( ). 1 23 4 +-2! 5 6 ( )4 +7 23 8 1 9 , : ; (4 +9 , < 1 9 2! &' ( )&9 1 : -9 2$ 9 2= / 0 ' >?9 , 4 +-2%
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` ^ 8W *? > & W !$ !F 4 9 K -7, Oa "Y %\ !Y EZ 9 2= J +7 > 9 K -7, O !DY $\ ""Y %Z Q 9 M TK 7N 9 H M 7 U L M V H J 9 K K 1 R 7 =O M , QJ +7, L 7 9 21 LL 9 M T, 29 J 7 @G +7 ` ^ 8W *? > & W O , M J +7L 9 K L 1 J 7 W 7 1 2O , M Q 7 =1 2J +7 K 9 J 7 , M 7 U H J 9 3 7 1 2=1 L 9 J 7 J +9 J J +7 L 9 M T, 29 2= , [ V 3 7 2, O L 9 K L 1 J 7 W 7 1 29 M 7 Q 9 1 2K V H , -M L 7 =O M , QJ +7 Q 9 M TK 7 @ ; 23 7 27 M 9 K 1 J 1 H H -3 3 7 H J 7 = J +9 J J +70 , 23 H +9 2 H S9 M 2 L , -K = T7O , M Q 7 = 1 2 J +7K 1 J +, K , 3 1 L 9 K J M 9 2H 1 J 1 , 2 R , 27T7 J N 7 7 2 J +7L K 9 H J 1 LM , L SH9 2= K 7 9 > U M 1 L +H 7 L , 2=9 M VQ 9 3 Q 9N +1 L +N 9 H O , M Q 7 =J +M , -3 +J +79 H H 1 Q 1 K 9 J 1 , 2, O L 9 M T, 29 J 7N 1 J +J +7L M V H J 9 K K 1 R 9 J 1 , 2, O 9*1 > " ' "> $ b "> $ 4 L 9 M T, 29 J 7TVJ +7-2=7 M 27 9 J + I, M I+V M VQ 9 3 Q 9 @; J 1 H 9 K H ,T7 K 1 7 W 7 =J +9 J J +7, M 7 U O , M Q 1 23Q 9 J 7 M 1 9 K H 9 2= J +7, M 7 U O , M Q 1 23O K -1 =, O J +7H S9 M 2 Q 1 27 M 9 K 1 R 9 J 1 , 21 2J +70 , 23 H +9 2 =7 I, H 1 J 9 M 7L , 23 7 27 J 1 LJ ,J +, H 7, O J +7I, M I+V M VL , II7 M Q 1 7 2M 9 K 1 R 9 J 1 , 2 -2=7 M 27 9 J +@ G + HI 1A 0 : ##*J 9 TK 71 H , J , I7 0 , 23 H +9 2H S9 M 2L , II7 M =7 I, H 1 J / +, 23 =1 9 2
!@中国科学院 地球化学研究所 矿床地球化学国家重点实验室 贵阳#AABBB" "@中国科学院 研究生院 北京#!BBB$C $@云南省地质调查院矿产调查所 大理#DE!BBB %@云南省地质勘查院大理矿产所 大理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收稿 "BBF F B$ F B$ 改回!
中甸红山矽卡岩铜矿稳定同位素特征及其 对成矿过程的指示
王守旭!" #张兴春! #冷成彪!" #秦朝建! #王外全$ #赵茂春% ! " &' ( )*+, -. -!" / 0 ' ( ). 1 23 4 +-2! 5 6 ( )4 +7 23 8 1 9 , : ; (4 +9 , < 1 9 2! &' ( )&9 1 : -9 2$ 9 2= / 0 ' >?9 , 4 +-2%
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` ^ 8W *? > & W !$ !F 4 9 K -7, Oa "Y %\ !Y EZ 9 2= J +7 > 9 K -7, O !DY $\ ""Y %Z Q 9 M TK 7N 9 H M 7 U L M V H J 9 K K 1 R 7 =O M , QJ +7, L 7 9 21 LL 9 M T, 29 J 7 @G +7 ` ^ 8W *? > & W O , M J +7L 9 K L 1 J 7 W 7 1 2O , M Q 7 =1 2J +7 K 9 J 7 , M 7 U H J 9 3 7 1 2=1 L 9 J 7 J +9 J J +7 L 9 M T, 29 2= , [ V 3 7 2, O L 9 K L 1 J 7 W 7 1 29 M 7 Q 9 1 2K V H , -M L 7 =O M , QJ +7 Q 9 M TK 7 @ ; 23 7 27 M 9 K 1 J 1 H H -3 3 7 H J 7 = J +9 J J +70 , 23 H +9 2 H S9 M 2 L , -K = T7O , M Q 7 = 1 2 J +7K 1 J +, K , 3 1 L 9 K J M 9 2H 1 J 1 , 2 R , 27T7 J N 7 7 2 J +7L K 9 H J 1 LM , L SH9 2= K 7 9 > U M 1 L +H 7 L , 2=9 M VQ 9 3 Q 9N +1 L +N 9 H O , M Q 7 =J +M , -3 +J +79 H H 1 Q 1 K 9 J 1 , 2, O L 9 M T, 29 J 7N 1 J +J +7L M V H J 9 K K 1 R 9 J 1 , 2, O 9*1 > " ' "> $ b "> $ 4 L 9 M T, 29 J 7TVJ +7-2=7 M 27 9 J + I, M I+V M VQ 9 3 Q 9 @; J 1 H 9 K H ,T7 K 1 7 W 7 =J +9 J J +7, M 7 U O , M Q 1 23Q 9 J 7 M 1 9 K H 9 2= J +7, M 7 U O , M Q 1 23O K -1 =, O J +7H S9 M 2 Q 1 27 M 9 K 1 R 9 J 1 , 21 2J +70 , 23 H +9 2 =7 I, H 1 J 9 M 7L , 23 7 27 J 1 LJ ,J +, H 7, O J +7I, M I+V M VL , II7 M Q 1 7 2M 9 K 1 R 9 J 1 , 2 -2=7 M 27 9 J +@ G + HI 1A 0 : ##*J 9 TK 71 H , J , I7 0 , 23 H +9 2H S9 M 2L , II7 M =7 I, H 1 J / +, 23 =1 9 2
!@中国科学院 地球化学研究所 矿床地球化学国家重点实验室 贵阳#AABBB" "@中国科学院 研究生院 北京#!BBB$C $@云南省地质调查院矿产调查所 大理#DE!BBB %@云南省地质勘查院大理矿产所 大理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收稿 "BBF F B$ F B$ 改回!