An efficient joint source-channel coding for a D-dimensional array
央财金融硕士考研—金融学院
中央财经大学——金融学院“考金融,选凯程”!凯程2014中财金融硕士保录班录取8人,专业课考点全部命中,凯程在金融硕士方面具有独到优势,全日制封闭式高三集训,并且在金融硕士方面有独家讲义\独家课程\独家师资\独家复试资源,确保学生录取.其中8人中有4人是二本学生,1人是三本学生,3人是一本学生,金融硕士只要进行远程+集训,一定可以取得成功.摘要现任中央财经大学金融学院教授、院长、院学术委员会主任、国际金融研究中心主任。
毕业于中国人民大学经济学院,获经济学博士。
享受国务院政府特殊津贴,入选“新世纪百千万人才工程(国家级)”、教育部“新世纪优秀人才支持计划”、财政部“跨世纪学科带头人”。
曾在荷兰蒂尔堡大学、世界银行学院、美国国际经济研究所、哥伦比亚大学地球研究院、澳大利亚国立大学做高级访问学者。
兼任中国世界经济学会副会长、中国国际金融学会常务理事及副秘书长、中国国际经济关系学会常务理事、中国金融学会理事、中国财经教育分会金融专业协作组主任委员、亚太经济与金融论坛主席、亚洲经济专家会议(Asian Economic Panel,New York/Tokyo/Seoul)成员、中国证监会第12届发审会委员、中国人民银行货币政策委员会专家咨询组成员、X 鸿儒金融教育基金会学术委员、中国人民银行研究生部学位委员。
研究领域为国际金融和宏观经济。
曾主持国家自然科学基金项目、国家社会科学基金项目、教育部人文社科项目等课题,研究内容涉及新兴市场经济体的资本账户开放、金融自由化、全球经济失衡、国际货币体系改革、经济全球化、汇率制度和货币国际化等。
在《经济研究》、《世界经济》、《金融研究》和《国际金融研究》等学术刊物发表论文80余篇,出版学术著作10余本(包括主编和合著)。
近年来,作为亚洲经济专家会议(AEP)成员、亚欧经济论坛(AEEF)成员、德国开发研究院(GDI)中国地区协调人等,曾赴美国、英国、德国、意大利、挪威、日本、韩国、泰国、越南、印度尼西亚、马来西亚、新加坡、澳大利亚、巴西、XX和XX等国家和地区参加国际学术会议或进行公开演讲。
均相合成多重选择性的新型两亲性C22高效液相色谱固定相
第42 卷第 12 期2023 年12 月Vol.42 No.121580~1587分析测试学报FENXI CESHI XUEBAO(Journal of Instrumental Analysis)均相合成多重选择性的新型两亲性C22高效液相色谱固定相范二乐1,蒋星宇1,张加栋1*,张明亮2,韩海峰1,2,张大兵1,2,陈义1,3(1.淮阴工学院矿盐资源深度利用技术国家地方联合工程研究中心,高端矿盐功能材料智能制备国际合作联合实验室,江苏淮安223003;2.江苏汉邦科技股份有限公司,江苏淮安223000;3.中国科学院化学研究所活体分析化学科学院重点实验室,北京100190)摘要:为解决高效液相色谱(HPLC)固定相非均相合成中产物多变和重现性差等问题,该文采用均相合成新方法,制备了既含有二十二碳烷基(C22)、又嵌入脲(U)和/或酰胺(A)强极性基团的两种新型两亲性色谱固定相C22-A和C22-A/U。
通过元素分析、核磁等手段,证实制备的两种新型固定相含有碳、氮元素,且碳氮元素比例符合理论值,表明酰胺和脲基极性基团成功键合到硅胶上。
通过对多种样品进行色谱分离分析,对两种新型固定相的载体残余硅羟基屏蔽作用、疏水选择性、形状选择性和亲水性等多种性质进行了考察,证实两种新型固定相不但具备作为反相液相色谱(RPLC)的性能,同时也具备亲水相互作用色谱(HILIC)的性能。
相较于C18固定相,C22-A和C22-A/U具有更好的形状选择性,双重嵌入的极性基团极大地降低了固定相硅羟基活性。
将C22-A和C22-A/U两种固定相应用于几种碱性化合物、雌醇(酮)类化合物的分离,C22固定相在一定程度上解决了传统C18固定相上碱性化合物分离拖尾严重或保留不足的问题,成功实现了对雌醇(酮)类化合物的分离。
关键词:色谱固定相;两亲性;均相合成;药物分析;液相色谱中图分类号:O657.7;R914.1文献标识码:A 文章编号:1004-4957(2023)12-1580-08 Homogeneous Synthesis of Novel Amphiphilic C22 StationaryPhases with Multiple SelectivityFAN Er-le1,JIANG Xing-yu1,ZHANG Jia-dong1*,ZHANG Ming-liang2,HAN Hai-feng1,2,ZHANG Da-bing1,2,CHEN Yi1,3(1.International Cooperation Joint Laboratory for Intelligent Preparation of High-end Functional Mineral SaltMaterials,National & Local Joint Engineering Research Center for Mineral Salt Deep Utilization,Huaiyin Instituteof Technology,Huai’an 223003,China;2.Jiangsu Hanbon Science & Technology Co.Ltd.,Huai’an 223000,China;3.CAS Key Laboratory of Analytical Chemistry for Living Biosystems,Instituteof Chemistry,Chinese Academy of Sciences,Beijing 100190,China)Abstract:In order to solve the variable and irreproducible issues of heterogeneously synthesized chromatographic stationary phases,a new method of homogeneous synthesis was established and used to prepare two newly designed amphiphilic stationary phases,C22-A and C22-A/U,where C22 denotes a long docosyl terminal while U and A denote the strong polar insertions of urea and am⁃ide groups at the initial end,respectively. By the means of elemental analysis and nuclear magnetic spectrum,the two new stationary phases contain nitrogen elements,and the ratio of carbon and nitro⁃gen elements accords with the theoretical value,indicating that the amide and urea-based polar groups are successfully bonded to silica gel. Through the chromatographic separation and analysis of the standard sample and the real sample,the shielding effect on upported silicon hydroxyl,hydro⁃phobic selectivity,shape selectivity and hydrophilicity of the two new stationary phases were investi⁃gated.It is confirmed that the two new stationary phases have amphiphilic properties as reversed-phase liquid chromatography(RPLC)and hydrophilic interaction chromatography(HILIC).Com⁃pared with C18 stationary phases,C22-A and C22-A/U own better shape selectivity,and the dou⁃doi:10.19969/j.fxcsxb.23072402收稿日期:2023-07-24;修回日期:2023-09-15基金项目:国家自然科学基金重点项目(22134007)∗通讯作者:张加栋,博士,副教授,研究方向:化学与生物传感、色谱分离分析等,E-mail:jiadongzhang@1581第 12 期范二乐等:均相合成多重选择性的新型两亲性C22高效液相色谱固定相ble embedded polar groups greatly reduce the silica hydroxyl activity of the stationary phase. C22-A and C22-A/U were used for the separation of several alkaline compounds and estrone(ketone) com⁃pounds. The C22 stationary phase solved the problem of serious tailing or insufficient retention of al⁃kaline compounds in the traditional C18 alkyl stationary phase,and successfully realized the separa⁃tion of estrone(ketone) compounds.Key words:chromatographic stationary phase;amphiphilicity;homogeneous synthesis;drug analysis;liquid chromatography色谱固定相的性质决定了保留机理、分离效率以及适合的分离对象[1-2]。
the hydrogen bond in the solid state
1.IntroductionThe hydrogen bond was discovered almost 100years ago,[1]but still is a topic of vital scientific research.The reason forthis long-lasting interest lies in the eminent importance ofhydrogen bonds for the structure,function,and dynamics of avast number of chemical systems,which range from inorganicto biological chemistry.The scientific branches involved arevery diverse,and one may include mineralogy,materialscience,general inorganic and organic chemistry,supramo-lecular chemistry,biochemistry,molecular medicine,andpharmacy.The ongoing developments in all these fields keepresearch into hydrogen bonds developing in parallel.In recentyears in particular,hydrogen-bond research has stronglyexpanded in depth as well as in breadth,new concepts havebeen established,and the complexity of the phenomenaconsidered has increased dramatically.This review is intendedto give a coherent survey of the state of the art,with a focus onthe structure in the solid state,and with weight put mainly on the fundamental aspects.Numerous books [2±9]and reviews on the subject have appeared earlier,so a historical outline is not necessary.Much of the published numerical material is somewhat outdated and,therefore,this review contains some numerical data that have been newly retrieved from the most relevant structural database,the Cambridge Structural Data-base (CSD).[10]It is pertinent to recall here the earlier ™classical∫view on hydrogen bonding.One may consider the directional inter-action between water molecules as the prototype of all hydrogen bonds (Scheme 1,definitions of geometric parameters are also in-cluded).The large difference in electro-negativity between the H and O atoms makes the O ÀH bonds of a water molecule inherently polar,with partial atomic charges of around 0.4on each H atom and À0.8on the O atom.Neighboring water molecules orient in such a way that local dipoles O d ÀÀH d point at negative partial charges O d À,that is,at the electron lone pairs of the filled p orbitals.In the resulting The Hydrogen Bond in the Solid StateThomas Steiner*In memory of JanKroon[*]Dr.T.SteinerInstitut f¸r Chemie–KristallographieFreie Universit‰t BerlinTakustrasse 6,14195Berlin (Germany)Fax:( 49)30-838-56702E-mail:steiner@chemie.fu-berlin.deREVIEWSREVIEWS T.SteinerOÀH¥¥¥j O interaction,the intermolecular distance is short-ened by around1äcompared to the sum of the van der Waals radii for the H and O atoms[11](1ä 100pm),which indicates there is substantial overlap of electron orbitals to form a three-center four-electron bond.Despite significant charge transfer in the hydrogen bond,the total interaction is dominantly electrostatic,which leads to pronounced flexibil-ity in the bond length and angle.The dissociation energy is around3±5kcal molÀ1.This brief outline of the hydrogen bond between water molecules can be extended,with only minor modifications,to analogous interactions XÀH¥¥¥A formed by strongly polar groups X dÀÀH d on one side,and atoms A dÀon the other (X O,N,halogen;A O,N,S,halide,etc.).Many aspects of hydrogen bonds in structural chemistry and structural biology can be readily explained at this level,and it is certainly the relative success of these views that made them dominate the perception of the hydrogen bond for decades.This dominance has been so strong in some periods that research on hydrogen bonds differing too much from the one between water molecules was effectively impeded.[8]Today,it is known that the hydrogen bond is a much broader phenomenon than sketched above.What can be called the™classical hydrogen bond∫is just one among many–a very abundant and important one,though.We know of hydrogen bonds that are so strong that they resemble covalent bonds in most of their properties,and we know of others that are so weak that they can hardly be distinguished from van der Waals interactions.In fact,the phenomenon has continuous transition regions to such different effects as the covalent bond,the purely ionic,the cation±p,and the van der Waals interaction.The electrostatic dominance of the hydrogen bond is true only for some of the occurring configurations,whereas for others it is not.The H¥¥¥A distance is not in all hydrogen bonds shorter than the sum of the van der Waals radii.For an XÀH group to be able to form hydrogen bonds,X does not need to be™very electroneg-ative∫,it is only necessary that XÀH is at least slightly polar. This requirement includes groups such as CÀH,PÀH,and some metal hydrides.XÀH groups of reverse polarity, X d ÀH dÀ,can form directional interactions that parallel hydrogen bonds(but one can argue that they should not be called so).Also,the counterpart A does not need to be a particularly electronegative atom or an anion,but only has to supply a sterically accessible concentration of negative charge. The energy range for dissociation of hydrogen bonds covers more than two factors of ten,about0.2to40kcal molÀ1,and the possible functions of a particular type of hydrogen bond depend on its location on this scale.These issues shall all be discussed in the following sections.For space reasons,it will not be possible to cover all aspects of hydrogen bonding equally well.Therefore,some important fields,for which recent guiding reviews are available,will not be discussed in great length.One example is the role of hydrogen bonds in molecular recognition patters(™supra-molecular synthons∫),[12]and the use of suitably robust motifs for the construction of crystalline archtitectures with desired properties(™crystal engineering∫).[13,14]This area includes the interplay of hydrogen bonds with other intermolecular forces, with whole arrays of such forces,and hierarchies within such an interplay.The reader interested in this complexfield is referred to the articles of Desiraju,[12,13]Leiserowitz et al.,[15] and others.[16]A further topic which could not be covered here is the symbolic description of hydrogen bond networks using tools of graph theory,[17]in particular the™graph set analy-sis∫.[18]An excellent guiding review is also available in this case.[19]For hydrogen bonding in biological structures,the interested reader is referred to the book of Jeffrey and Saenger,[5]and for theoretical aspects to the book of Scheiner[7]as well as other recent reviews.[20]Results obtained with experimental methods other than diffraction will be touched upon only briefly,and will possibly leave some readers dissatisfied.The role of hydrogen bonding in special systems will not be discussed at all,simply because there are too many of them.2.Fundamentals2.1.Definition of the Hydrogen BondBefore discussing the hydrogen bond itself,the matter of hydrogen bond definitions must be addressed.This is an important point,because definitions of terms often limit entire fields.It is,also,a problematic point because very different hydrogen bond definitions have been made,and partREVIEWS Solid-State Hydrogen Bondsof the literature relies quite uncritically on the validity(or thevalue)of the particular definition that is adhered to.Time has shown that only very general and flexibledefinitions of the term™hydrogen bond∫can do justice tothe complexity and chemical variability of the observedphenomena,and include the strongest as well as the weakestspecies of the family,and inter-as well as intramolecularinteractions.A far-sighted early definition is that of Pimenteland McClellan,who essentially wrote that™...a hydrogenbond exists if1)there is evidence of a bond,and2)there isevidence that this bond sterically involves a hydrogen atomalready bonded to another atom∫.[2]This definition leaves thechemical nature of the participants,including their polaritiesand net charges,unspecified.No restriction is made on theinteraction geometry except that the hydrogen atom must besomehow™involved∫.The crucial requirement is the existenceof a™bond∫,which is itself not easy to define.The methods totest experimentally if requirements1and2are fulfilled arelimited.For crystalline compounds,it is easy to see withdiffraction experiments whether an H atom is involved,but itis difficult to guarantee that a given contact is actually™bonding∫.A drawback of the Pimentel and McClellan definition isthat in the strict sense it includes pure van der Waals contacts(which can be clearly™bonding∫,with energies of severaltenths of a kcal molÀ1),and it also includes three-center two-electron interactions where electrons of an XÀH bond are donated sideways to an electron-deficient center(™agosticinteraction∫).From a modern viewpoint,it seems advisable tomodify point2,such as by requiring that XÀH acts as a proton (not electron)donor.Therefore,the following definition is proposed:An XÀH¥¥¥A interaction is called a™hydrogen bond∫,if 1.it constitutes a local bond,and2.XÀH acts as proton donor to A.The second requirement is related to the acid/base proper-ties of XÀH and A,and has the chemical implication that a hydrogen bond can at least in principle be understood as an incipient proton-transfer reaction from XÀH to A.It excludes, for example,pure van der Waals contacts,agostic interactions, so-called™inverse hydrogen bonds∫(see Section8),and B-H-B bridges.As a matter of fact,point2should be interpreted liberally enough to include symmetric hydrogen bonds XÀHÀX,where donor and acceptor cannot be distin-guished.The direction of formal or real electron transfer in a hydrogen bond is reverse to the direction of proton donation.Apart from general chemical definitions,there are manyspecialized definitions of hydrogen bonds that are based oncertain sets of properties that can be studied with a particulartechnique.For example,hydrogen bonds have been definedon the basis of interaction geometries in crystal structures(short distances,fairly™linear angles∫q),certain effects in IRabsorption spectra(red-shift and intensification of n XH,etc.),or certain properties of experimental electron density distri-butions(existence of a™bond critical point∫between H andA,with numerical parameters within certain ranges).All suchdefinitions are closely tied to a specific technique,and may be quite useful in the regime accessible to it.Nevertheless,theyare more or less useless outside that regime,and many amisunderstanding in the hydrogen bond literature has beencaused by applying such definitions outside their region ofapplicability.The practical scientist often requires a technical definition,and automated data treatment procedures for identifyinghydrogen bonds cannot be done without.It is not within thescope of this article to discuss any set of threshold values thata™hydrogen bond∫must pass in any particular type oftechnical definition.It is only mentioned that the™van derWaals cutoff∫definition[21]for identifying hydrogen bonds ona structural basis(requiring that the H¥¥¥A distance issubstantially shorter than the sum of the van der Waals radiiof H and A)is far too restrictive and should no longer beapplied.[5,6,8]If distance cutoff limits must be used,XÀH¥¥¥A interactions with H¥¥¥A distances up to3.0or even3.2äshould be considered as potentially hydrogen bonding.[6]Anangular cutoff can be set at>908or,somewhat moreconservatively,at>1108.A necessary geometric criterionfor hydrogen bonding is a positive directionality preference,that is,linear XÀH¥¥¥A angles must be statistically favored over bent ones(this is a consequence of point2of the above definition).[22]2.2.Further TerminologyA large part of the terminology concerning hydrogen bonds is not uniformly used in the literature,and still today, terminological discrepancies lead to misunderstanding be-tween different authors.Therefore,some of the technical terms used in this review need to be explicitly defined.In a hydrogen bond XÀH¥¥¥A,the group XÀH is called the donor and A is called the acceptor(short for™proton donor∫and™proton acceptor∫,respectively).Some authors prefer the reverse nomenclature(XÀH electron acceptor,Y electron donor),which is equally justified.In a simple hydrogen bond,thedonor interacts with one acceptor(Scheme2a).Since the hydro-gen bond has a long range,adonor can interact with two andthree acceptors simultaneously(Scheme2b,c).Hydrogen bondswith more than three acceptorsare possible in principle,but areonly rarely found in practice be-cause they require very highspatial densities of acceptors.The terms™bifurcated∫and™tri-furcated∫are commonly used todescribe the arrangements inScheme2b and c,respectively.The term™two-centered∫hydro-gen bond is an alternative descrip-tor for XÀH¥¥¥A(Scheme2a)where the H-atom is bonded totwo other atoms,and is itself notX H AX HAX H AAAAb)c)a)dd1d2d1d2d3Scheme2.Different typesof hydrogen bridges.a)Nor-mal hydrogen bond with oneacceptor.b)Bifurcated hy-drogen bond;if the twoH¥¥¥A separations are dis-tinctly different,the shorterinteraction is called majorcomponent,and the longerone the minor component ofthe bifurcated bond.c)Tri-furcated hydrogen bond.REVIEWST.Steiner counted as a center.Consequently,the arrangements in Scheme 2b and 2c may be called ™three-∫and ™four-centered∫hydrogen bonds,respectively.[5,6]This terminology is logical,but leads to confusion from the point of view of regarding hydrogen bonds O ÀH ¥¥¥O as ™three-center four-electron∫interactions,where the H-atom is counted as a center.A bifurcated hydrogen bond (Scheme 2b)is then termed ™three-centered∫,but also represents a ™four-center six-electron∫interaction.To avoid such ambiguities,the older term ™bifurcated∫is used here.There is particular confusion concerning the terms attrac-tive and repulsive .Some authors use these terms to character-ize forces,and others to characterize energies.In the latter case,an ™attractive interaction∫is taken as a synonym for ™bonding interaction∫,that is,one that requires the input of energy to be broken.Following well-founded recommenda-tions,[23]the terms ™attractive∫and ™repulsive∫are used here exclusively to describe forces.Negative and positive bond energies are indicated by the terms ™stabilizing∫(or ™bond-ing∫)and ™destabilizing∫,respectively.The schematic hydro-gen bond potential in Figure 1shows that a stabilizing interaction (that is,with E <0)is associated with a repulsive force if it is shorter than the equilibrium distance (see figure legend for further details).[8]Figure 1.Schematic representation of a typical hydrogen bond potential.[8]A hydrogen bond length differing from d 0implies a force towards a geometry of lower energy,that is,by attraction if d >d 0and repulsion if d <d 0.Note that the interaction can at the same time be ™stabilizing∫(or ™bonding∫)and ™repulsive∫!The distortions from d 0occurring in practice are limited by the energy penalties that have to be paid,and in crystals,only a few hydrogen bonds have energies differing by more than 1kcal mol À1from optimum.Hydrogen bonds are sometimes called ™nonbonded inter-actions∫.At least to this author,this appears a contradiction in terms which should be avoided.2.3.Constituent InteractionsThe hydrogen bond is a complexinteraction composed of several constituents that are different in their natures.[6,7]Most popular are partitioning modes that essentially follow those used by Morokuma.[24]The total energy of a hydrogen bond (E tot )is split into contributions from electrostatics (E el ),polarization (E pol ),charge transfer (E ct ),dispersion (E disp ),and exchange repulsion (E er ),somewhat different,but still related,partitioning schemes are also in use.The distance and angular characteristics of these constituents are very different.The electrostatic term is directional and of long range (diminishing only slowly as Àr À3for dipole ±dipole and as Àr À2for dipole ±monopole interactions).Polarization de-creases faster (Àr À4)and the charge-transfer term decreases even faster,approximately following e Àr .According to natural bond orbital analysis,[25]charge transfer occurs from an electron lone pair of A to an antibonding orbital of X ÀH,that is n A 3s *XH .The dispersion term is isotropic with a distance dependence of Àr À6.The exchange repulsion term increases sharply with reducing distance (as r À12).The dispersion and exchange repulsion terms are often combined into an isotropic ™van der Waals∫contribution that is approx-imately described by the well-known Lennard ±Jones poten-tial (E vdW $A r À12ÀB r À6).Depending on the particular chem-ical donor ±acceptor combination,and the details of the contact geometry,all these terms contribute with different weights.It cannot be globally stated that the hydrogen bond as such is dominated by this or that term in any case.Some general conclusions can be drawn from the overall distance characteristics.In particular,it is important that of all the constituents,the electrostatic contribution reduces slowest with increasing distance.The hydrogen bond potential for any particular donor ±acceptor combination (Figure 1)is,there-fore,dominated by electrostatics at long distances,even if charge transfer plays an important role at optimal geometry.Elongation of a hydrogen bond from optimal geometry always makes it more electrostatic in nature.In ™normal∫hydrogen bonds E el is the largest term,but a certain charge-transfer contribution is also present.The van der Waals terms too are always present,and for the weakest kinds of hydrogen bonds dispersion may contribute as much as electrostatics to the total bond energy.Purely ™electrostatic plus van der Waals∫models can be quite successful despite their simplicity for hydrogen bonds of weak to intermediate strengths.[26]Such simple models fail for the strongest types of hydrogen bonds,for which their quasi-covalent nature has to be fully considered (see Section 7).2.4.Energies The energy of hydrogen bonds in the solid state cannot be directly measured,and this circumstance leaves open ques-tions in many structural putational chemistry,on the other hand,produces results on hydrogen bond energies at an inflationary rate,[7,20]many obtained at high levels of theory and even more in rather routine calculations using black-box methods.Theoretical studies are not the topic of the present review,but an idea of typical results can be gained from the collection of calculated values listed in Table 1.[27]It appears that hydrogen bond energies cover more than two orders of magnitude,about À0.2to À40kcal mol À1.On a logarithmic scale,the bond energy of the water dimer is roughly in the middle.REVIEWS Solid-State Hydrogen BondsThe values in Table1are computed for dimers in optimal geometry undisturbed by their surroundings.In the solid state, hydrogen bonds are practically never in optimal geometry, and are always influenced by their environment.There are numerous effects from the close and also from the remote surrounding that may considerably increase or lower hydro-gen bond energies(™crystal-field effects∫).Hydrogen bonds do not normally occur as isolated entities but form networks. Within these networks,hydrogen bond energies are not additive(see Section4).In such cases,it is not reasonable to split up the network into individual hydrogen bonds and to calculate energies for each one.In this sense,calculated hydrogen bond energies should always be taken with caution.2.5.Transition to Other Interaction TypesAs outlined previously,the hydrogen bond is composed of several constituent interactions which are variant in their contributing weights.Chemical variation of donor and/or acceptor,and possibly also of the environment,can gradually change a hydrogen bond to another interaction type.This shall be detailed here for the most important cases.The transition to pure van der Waals interaction is very common.The polarity of XÀH or A(or both)in the array X dÀÀH d ¥¥¥A dÀcan be reduced by suitable variation of X or A.This reduces the electrostatic part of the interaction, whereas the van der Waals component is much less affected. In consequence,the van der Waals component gains relative weight,and the angular characteristics gradually change from directional to isotropic.Since the polarities of X dÀÀH d or A dÀcan be reduced to zero continuously,the resulting transition of the interaction from hydrogen bond to van der Waals type is continuous too.Such a behavior was actually demonstrated for the directionality of CÀH¥¥¥O C interactions,which gradually disappears when the donor is varied from C CÀH to C CH2to CÀCH3(see Figure8,Section3.2).[22]At the acceptor side of a hydrogen bond,sulfur is typical of an atom that allows continuous variation of the partial charge from S dÀto S d .Therefore,one can create a continuum of chemical situations between the S atom acting as a fairly strong hydrogen bond acceptor,and being inert to hydrogen bonding (the extreme cases are ionic species such as XÀSÀand X S ÀY).At the other end of the energy scale,there is a continuous transition to covalent bonding.[28]In the so-called symmetric hydrogen bonds XÀHÀX,where an H atom is equally shared between two chemically identical atoms X,no distinction can be made between a donor and an acceptor,or a™covalent∫XÀH and™noncovalent∫H¥¥¥X bond(found experimentally for X F,O,and possibly N).In fact,this situation can be conveniently described as a hydrogen atom forming two covalent bonds with bond orders s 1³2.In crystals(and also in solution),all intermediate cases exist between the extremes XÀH¥¥¥¥¥¥IX and XÀHÀX.Strongly covalent hydrogen bonds will be discussed in greater detail in Section7,and the bond orders(™valences∫)of H¥¥¥O over the whole distance range will be given in Section9(Table7).There is also a gradual transition from hydrogen bonding to purely ionic interactions.If in an interaction X dÀÀH d ¥¥¥Y dÀÀH d the net charges on XÀH and YÀH are zero,the electrostatics are of the dipole±dipole type.In general, however,the net charges are not zero.Alcoholic OÀH groups have a partial negative charge in addition to their dipole moment,ammonium groups have a positive net charge,and so on.This situation leads to ionic interactions between the charge centers with the energy having a rÀ1distance depend-ence.If the charges are large,the ionic behavior may become dominant.For fully charged hydrogen bond partners,ener-getics are typically dominated by the Coulombic interaction between the charge centers,but the total interaction still remains directional,with XÀH not oriented at random but pointing at A.An important example are the so-called salt-bridges between primary ammonium and carboxylate groups in biological structures,[5]N ÀH¥¥¥OÀ.If weakly polar XÀH groups are attached to a charged atom,such as the methyl groups in the N Me4ion,they are often involved in short contacts to an approaching counterion,N ÀXÀH¥¥¥AÀ.[8] Although these interactions are directional and may still be classified as a kind of hydrogen bond,their dominant part is certainly the ionic bond N ¥¥¥AÀ.Finally,there is a transition region between the hydrogen bond and the cation±p interaction.In the pure cation±p interaction a spherical cation such as K contacts the negative charge concentration of a p-bonded moiety such as a phenyl ring.This can be considered an electrostatic monopole±quadrupole interaction.The bond energy isÀ19.2kcal molÀ1 for the example of K ¥¥¥benzene.[29]A pure p-type hydrogen bond X dÀÀH d ¥¥¥Ph is formally a dipole±quadrupole inter-action with much lower energies of only a few kcal molÀ1 (Table1).If charged hydrogen bond donors such as NH4 interact with p-electron clouds,local dipoles are oriented atTable1.Calculated hydrogen bond energies(kcal molÀ1)in some gas-phase dimers.[a]Dimer Energy Ref.[FÀHÀF]À39[27a] [H2OÀHÀOH2] 33[27b] [H3NÀHÀNH3] 24[27b] [HOÀHÀOH]À23[27a]NH4 ¥¥¥OH219[27c]NH4 ¥¥¥Bz17[27d] HOH¥¥¥ClÀ13.5[27c]O CÀOH¥¥¥O CÀOH7.4[27e] HOH¥¥¥OH2 4.7;5.0[27f,g]N CÀH¥¥¥OH2 3.8[27h] HOH¥¥¥Bz 3.2[27i]F3CÀH¥¥¥OH2 3.1[27j]MeÀOH¥¥¥Bz 2.8[27k]F2HCÀH¥¥¥OH2 2.1;2.5[27f,j] NH3¥¥¥Bz 2.2[27i]HC CH¥¥¥OH2 2.2[27h]CH4¥¥¥Bz 1.4[27i]FH2CÀH¥¥¥OH2 1.3[27f,j] HC CH¥¥¥C CHÀ 1.2[27l] HSH¥¥¥SH2 1.1[27m]H2C CH2¥¥¥OH2 1.0[27l]CH4¥¥¥OH20.3;0.5;0.6;0.8[27f,n±p] C CH2¥¥¥C C0.5[27l]CH4¥¥¥FÀCH30.2[27q] [a]For computational details,see the original literature.Bz benzyl.REVIEWS T.Steinerthe p face,[30]but the energetics are dominated by the charge±quadrupole interaction[27d](NH4 ¥¥¥Bz experimentally:À19.3kcal molÀ1).[29]If the XÀH groups of the cation are only weakly polar,they may also orient at the p face and cause some modulation of the dominant cation±p interaction,but this modulation fades to zero with decreasing XÀH polarity.2.6.Incipient Proton Transfer ReactionA very important way of looking at hydrogen bonds is to regard them as incipient proton-transfer reactions. From this viewpoint,a stable hydrogen bond XÀH¥¥¥Y is a ™frozen∫stage of the reaction XÀH¥¥¥Y>XÀ¥¥¥HÀÀ Y(orX ÀH¥¥¥Y>X¥¥¥HÀÀ Y,etc.).This means that a partial bond H¥¥¥Y is already established and the XÀH bond is concomitantly weakened.[31]In the case of strong hydrogen bonds,the stage of proton transfer can be quite advanced.In some hydrogen bonds the proton position is not stable at X or Y,but proton transfer actually takes place with high rates.In other cases these rates are small or negligible.The interpretation of hydrogen bonds as an incipient chemical reaction is complementary to electrostatic views on hydrogen bonding.It brings into play acid±base consid-erations,proton affinities,the partially covalent nature of the H¥¥¥Y bond,and turns out to be a very powerful concept for understanding the stronger types of hydrogen bonds in particular.For example,the partial H¥¥¥Y bond can only become strong if its orientation roughly coincides with the orientation of the full HÀY bond that would be formed upon proton transfer.Approach in different orientations may still be favorable in electrostatic terms,but results only in moderately strong hydrogen bonds.This view also helps in deciding whether a particular type of XÀH¥¥¥A interaction may be classified as a hydrogen bond or not(compare the definition in Section2.1).Only if it may be thought of as a frozen proton-transfer reaction,may it be called a hydrogen bond.2.7.Location of the H AtomAn atom is constituted of a nucleus and its electron shell. Normally,the centers of gravity of the nucleus and electron shell coincide well,and this common center is called the ™location∫of the atom.For H atoms,however,this is generally not the case.In a covalent bond with a more electronegative atom,the average position of the single electron of the H atom is displaced towards that other atom. The centers of gravity of the nucleus and electron no longer coincide,and this leads to a conceptual problem:what should be taken as the™location∫of the atom?It is not chemically reasonable to consider one of the two centers of gravity as the ™right∫location of the atom,and the other as™wrong∫,but one must accept that a point-atom model is simplistic in this situation.[32,33]In practice,this leads to unpleasant complica-tions.X-ray diffraction experiments determine electron-density distributions and locate the electron-density maxima of the atoms.Neutron diffraction,on the other hand,locates the nuclei.The results of the two techniques for H atoms often differ by more than0.1ä.[34]Neither of the two results is more true than the other,but they are complementary and both represent useful pieces of information.Nevertheless,neutron diffraction results are much more precise and reliable,and allow the proton positions to be located as accurately as other nuclei.It has become a practice in the analysis of X-ray diffraction results to™normalize∫the XÀH bonds by shifting the position found for the H atom(that is,the position of the electron center of gravity)along the XÀH vector to the average neutron-determined internuclear distance,namely,to the approximate position of the proton.[35]This theoretical position is then used for the calculation of hydrogen bond parameters.The currently used standard bond lengths are: OÀH 0.983,NÀH 1.009,CÀH 1.083,BÀH 1.19,and SÀH 1.34ä;a more complete list can be found in ref.[8]. The normalization procedure is generally reasonable,well suited to smooth out the large experimental uncertainty of X-ray diffraction data,and is particularly useful in statistical database analysis.Nevertheless,one must be aware that it is not a correction in the strict sense,instead it replaces a certain structural feature(the location of the electron center of gravity)by a chemically different one(the proton position). Furthermore,the internuclear XÀH bond length is fairly constant only in weak and moderate hydrogen bonds,whereas it is significantly elongated in strong ones.In the latter situation,the elongation should at least in principle be taken into account in the normalization.This requires,however, knowledge of the relationship between the relevant XÀH and H¥¥¥A distances(see Section3.6).[36]2.8.Charge Density PropertiesThe precise mapping of the distribution of charge density in hydrogen-bonded systems is a classical topic in structural chemistry,[37]with a large number of individual studies reported.[38]Currently,Baders quantum theory of atoms in molecules(AIM)is the most frequently used formalism in theoretical analyses of charge density.[39]Each point in space is characterized by a charge density1(r),and further quantities such as the gradient of1(r),the Laplacian function of1(r), and the matrixof the second derivatives of1(r)(Hessian matrix).The relevant definitions and the topology of1(r)in a molecule or molecular complexcan be best understood with the help of an illustration(Figure2;see figure legend for details).[40]The thin lines represent lines of steepest ascent through1(r)(trajectories).If there is a chemical bond between two atoms(such as a hydrogen bond),they are directly connected by a trajectory called the™bond path∫.The point with the minimal1value along the bond path is called the™bond critical point∫(BCP).It represents a saddle point of 1(r)(strictly speaking,trajectories terminate at the BCP,so that the bond path represents a pair of trajectories each of which connects a nucleus with the BCP).Different kinds of chemical bonds have different numerical properties at the BCP,such as different electron density1BCP and different。
MBA英语考试复习
(2) Industry policy The national government identifies key domestic industries critical to the country’s future economic growth, and then formulates programs that promote their competitiveness.
(3) Maintenance of existing jobs Well-established firms and their workers, particularly in high-wage countries, are often threatened by imports from low-wage countries.
Barriers to international trade (1) Tariffs ad valorem fixed tariff
(2) Non-tariff barriers characteristic: A. Flexibility B. Validity C. Discriminately
Contract Manufacturing - advantages
Low financial risks Minimise resources devoted to manufacturing Focus firm’s resources on other elements of the value chain Avoid tariffs, barriers to trade, restrictions on foreign investment
FDI - Disadvantages
consistency regularization 出处 -回复
consistency regularization 出处-回复Consistency Regularization: An Overview and ApplicationsIntroductionConsistency regularization has emerged as a powerful technique in machine learning, specifically in the field of deep learning. It aims to improve the generalization and robustness of models by encouraging consistency in their predictions. This regularization technique has found applications in various domains, including image classification, natural language processing, and speech recognition. In this article, we will provide an overview of consistency regularization, discuss its theoretical foundations, and explore its applications in different areas.Theoretical FoundationsConsistency regularization is rooted in the principle of encouraging smoothness and stability in model predictions. The underlying assumption is that small changes in the input should not significantly alter the output of a well-trained model. This principle is particularly relevant in scenarios where the training data maycontain noisy or ambiguous samples.One of the commonly used methods for achieving consistency regularization is known as consistency training. In this approach, two different input transformations are applied to the same sample, creating two augmented versions. The model is then trained to produce consistent predictions for the transformed samples. Intuitively, this process encourages the model to focus on the underlying patterns in the data rather than being influenced by specific input variations.Consistency regularization can be formulated using several loss functions. One popular choice is the mean squared error (MSE) loss, which measures the discrepancy between predictions of the original input and transformed versions. Other approaches include cross-entropy loss and Kullback-Leibler divergence.Applications in Image ClassificationConsistency regularization has yielded promising results in image classification tasks. One notable application is semi-supervised learning, where the goal is to leverage a small amount of labeleddata with a larger set of unlabeled data. By applying consistent predictions to both labeled and unlabeled data, models can effectively learn from the unlabeled data and improve their performance on the labeled data. This approach has been shown to outperform traditional supervised learning methods in scenarios with limited labeled samples.Additionally, consistency regularization has been explored in the context of adversarial attacks. Adversarial attacks attempt to fool a model by introducing subtle perturbations to the input data. By training models with consistent predictions for both original and perturbed inputs, their robustness against such attacks can be significantly improved.Applications in Natural Language ProcessingConsistency regularization has also demonstrated promising results in natural language processing (NLP) tasks. In NLP, models often face the challenge of understanding and generating coherent sentences. By applying consistency regularization, models can be trained to produce consistent predictions for different representations of the same text. This encourages the model tofocus on the meaning and semantics of the text rather than being influenced by superficial variations, such as different word order or sentence structure.Furthermore, consistency regularization can be used in machine translation tasks, where the goal is to translate text from one language to another. By enforcing consistency between translations of the same source text, models can generate more accurate and consistent translations.Applications in Speech RecognitionSpeech recognition is another domain where consistency regularization has found applications. One of the key challenges in speech recognition is handling variations in pronunciation and speaking styles. By training models with consistent predictions for different acoustic representations of the same speech utterance, models can better capture the underlying patterns and improve their accuracy in recognizing speech in different conditions. This can lead to more robust and reliable speech recognition systems in real-world scenarios.ConclusionConsistency regularization has emerged as an effective technique for improving the generalization and robustness of models in various machine learning tasks. By encouraging consistency in predictions, models can better learn the underlying patterns in the data and generalize well to unseen examples. This regularization technique has been successfully applied in image classification, natural language processing, and speech recognition tasks, among others. As research in consistency regularization continues to advance, we can expect further developments and applications in the future.。
宣传物流的短视频脚本模板
宣传物流的短视频脚本模板Title: Unlocking the Power of Logistics[Opening scene: A catchy and energetic background score plays as vibrant visuals of transportation modes like ships, trains, trucks, and planes are shown]Narrator: Whether it's delivering a package to your doorstep or ensuring goods reach international markets, logistics plays a vital role in connecting businesses and people across the globe.[Scene transition: A small business owner struggling to manage his inventory]Narrator: Meet Mike, a small business owner who is facing difficulties managing his inventory and delivering products to his customers on time.[Scene transition: A solution brought in]Narrator: But little does he know, there's a solution that can solve all his logistics worries.[Scene: Introduction of a logistics professional]Narrator: Introducing Lucy, a highly experienced logistics professional. Let's see how she helps Mike revolutionize his business with the power of logistics.[Scene: Lucy discussing with Mike about his current challenges]Lucy: Hey Mike! I see you're facing challenges with inventory management and timely deliveries. Don't worry, I'm here to help you by unlocking the power of logistics.[Scene: Visual representation of logistics process]Narrator: But wait, what exactly is logistics?[Scene transition: Graphics illustrating the three key stages of logistics - procurement, production, and distribution]Narrator: Logistics encompasses the seamless coordination of procurement, production, and distribution to ensure goods flow smoothly from suppliers to consumers.[Scene: Lucy explaining the benefits of logistics]Lucy: By implementing effective logistics practices, you can streamline your operations, save costs, and improve customer satisfaction.[Scene transition: Lucy and Mike brainstorming]Lucy: Let's dive into how we can optimize your inventory management by using smart technology and data analysis to forecast demand accurately.[Scene: Introduction of technology solutions]Narrator: With advancements in technology, logistics has become more efficient than ever before.[Scene: Visual representation of technology solutions like inventory management software, tracking systems, etc.]Narrator: Mike learns how the latest inventory management software and tracking systems can enhance his business operations.[Scene transition: Lucy explaining international logistics]Lucy: Mike, expanding your business to international markets can be challenging. But with our international logistics expertise, your products can reach customers worldwide faster and more efficiently.[Scene: Visual representation of international transportation modes and customs clearance process]Narrator: From customs clearance to choosing the right transportation modes, Lucy guides Mike through the complexities of international logistics.[Scene transition: Showcasing the benefits of logistics]Narrator: By leveraging the power of logistics, Mike witnesses a transformation in his business.[Scene: Mike's business thriving]Narrator: His inventory is well-managed, deliveries are on time, and customer satisfaction is at an all-time high.[Scene transition: Highlighting customer testimonials] Narrator: But don't just take our word for it. Here's what Mike's delighted customers have to say.[Scene: Happy customers expressing satisfaction]Customer 1: The products always arrive on time, and the packaging is impeccable!Customer 2: I've never had a smoother online shopping experience. The company's logistics game is on point![Scene: Conclusion]Narrator: The power of logistics has transformed Mike's business, and it can do the same for you too.[Scene: Lucy and Mike shaking hands]Lucy: Are you ready to unlock the power of logistics and take your business to new heights?Mike: Absolutely! Thank you, Lucy, for showing me the way. [Closing scene: High-energy background music playing as visuals of Mike's thriving business are shown]Narrator: Unlock the power of logistics and witness the transformation in your business.[Closing shot: A strong call to action with the company's contact information displayed on the screen]Narrator: Contact us now to unleash the true potential of your business with logistics.[Background music fades out as the video ends]。
超声骨刀英文版护理课件
02
Preoperational care
Patient assessment
Physical condition
Assess the patient's general physical condition, including vital signs, weight, height, and body mass index
within normal limits
Monitor respiration
03
Monitor respiration regularly to ensure that it remains
within normal limits
Prevention of applications
Prevent infection
Prevent thromboembolism
Thromboembolism is a serious complication that can occur during surgery, so the number should ensure that all necessary measures are taken to
Assist the surgeon in sterilizing the surgical field
The nurse should assist the surgeon in sterilizing the surgical field and ensuring that all surgical instruments and equipment are sterile before the
Training and education
低频活动漂浮潜水船声探测系统(LFATS)说明书
LOW-FREQUENCY ACTIVE TOWED SONAR (LFATS)LFATS is a full-feature, long-range,low-frequency variable depth sonarDeveloped for active sonar operation against modern dieselelectric submarines, LFATS has demonstrated consistent detection performance in shallow and deep water. LFATS also provides a passive mode and includes a full set of passive tools and features.COMPACT SIZELFATS is a small, lightweight, air-transportable, ruggedized system designed specifically for easy installation on small vessels. CONFIGURABLELFATS can operate in a stand-alone configuration or be easily integrated into the ship’s combat system.TACTICAL BISTATIC AND MULTISTATIC CAPABILITYA robust infrastructure permits interoperability with the HELRAS helicopter dipping sonar and all key sonobuoys.HIGHLY MANEUVERABLEOwn-ship noise reduction processing algorithms, coupled with compact twin line receivers, enable short-scope towing for efficient maneuvering, fast deployment and unencumbered operation in shallow water.COMPACT WINCH AND HANDLING SYSTEMAn ultrastable structure assures safe, reliable operation in heavy seas and permits manual or console-controlled deployment, retrieval and depth-keeping. FULL 360° COVERAGEA dual parallel array configuration and advanced signal processing achieve instantaneous, unambiguous left/right target discrimination.SPACE-SAVING TRANSMITTERTOW-BODY CONFIGURATIONInnovative technology achievesomnidirectional, large aperture acousticperformance in a compact, sleek tow-body assembly.REVERBERATION SUPRESSIONThe unique transmitter design enablesforward, aft, port and starboarddirectional transmission. This capabilitydiverts energy concentration away fromshorelines and landmasses, minimizingreverb and optimizing target detection.SONAR PERFORMANCE PREDICTIONA key ingredient to mission planning,LFATS computes and displays systemdetection capability based on modeled ormeasured environmental data.Key Features>Wide-area search>Target detection, localization andclassification>T racking and attack>Embedded trainingSonar Processing>Active processing: State-of-the-art signal processing offers acomprehensive range of single- andmulti-pulse, FM and CW processingfor detection and tracking. Targetdetection, localization andclassification>P assive processing: LFATS featuresfull 100-to-2,000 Hz continuouswideband coverage. Broadband,DEMON and narrowband analyzers,torpedo alert and extendedtracking functions constitute asuite of passive tools to track andanalyze targets.>Playback mode: Playback isseamlessly integrated intopassive and active operation,enabling postanalysis of pre-recorded mission data and is a keycomponent to operator training.>Built-in test: Power-up, continuousbackground and operator-initiatedtest modes combine to boostsystem availability and accelerateoperational readiness.UNIQUE EXTENSION/RETRACTIONMECHANISM TRANSFORMS COMPACTTOW-BODY CONFIGURATION TO ALARGE-APERTURE MULTIDIRECTIONALTRANSMITTERDISPLAYS AND OPERATOR INTERFACES>State-of-the-art workstation-based operator machineinterface: Trackball, point-and-click control, pull-down menu function and parameter selection allows easy access to key information. >Displays: A strategic balance of multifunction displays,built on a modern OpenGL framework, offer flexible search, classification and geographic formats. Ground-stabilized, high-resolution color monitors capture details in the real-time processed sonar data. > B uilt-in operator aids: To simplify operation, LFATS provides recommended mode/parameter settings, automated range-of-day estimation and data history recall. >COTS hardware: LFATS incorporates a modular, expandable open architecture to accommodate future technology.L3Harrissellsht_LFATS© 2022 L3Harris Technologies, Inc. | 09/2022NON-EXPORT CONTROLLED - These item(s)/data have been reviewed in accordance with the InternationalTraffic in Arms Regulations (ITAR), 22 CFR part 120.33, and the Export Administration Regulations (EAR), 15 CFR 734(3)(b)(3), and may be released without export restrictions.L3Harris Technologies is an agile global aerospace and defense technology innovator, delivering end-to-endsolutions that meet customers’ mission-critical needs. The company provides advanced defense and commercial technologies across air, land, sea, space and cyber domains.t 818 367 0111 | f 818 364 2491 *******************WINCH AND HANDLINGSYSTEMSHIP ELECTRONICSTOWED SUBSYSTEMSONAR OPERATORCONSOLETRANSMIT POWERAMPLIFIER 1025 W. NASA Boulevard Melbourne, FL 32919SPECIFICATIONSOperating Modes Active, passive, test, playback, multi-staticSource Level 219 dB Omnidirectional, 222 dB Sector Steered Projector Elements 16 in 4 stavesTransmission Omnidirectional or by sector Operating Depth 15-to-300 m Survival Speed 30 knotsSize Winch & Handling Subsystem:180 in. x 138 in. x 84 in.(4.5 m x 3.5 m x 2.2 m)Sonar Operator Console:60 in. x 26 in. x 68 in.(1.52 m x 0.66 m x 1.73 m)Transmit Power Amplifier:42 in. x 28 in. x 68 in.(1.07 m x 0.71 m x 1.73 m)Weight Winch & Handling: 3,954 kg (8,717 lb.)Towed Subsystem: 678 kg (1,495 lb.)Ship Electronics: 928 kg (2,045 lb.)Platforms Frigates, corvettes, small patrol boats Receive ArrayConfiguration: Twin-lineNumber of channels: 48 per lineLength: 26.5 m (86.9 ft.)Array directivity: >18 dB @ 1,380 HzLFATS PROCESSINGActiveActive Band 1,200-to-1,00 HzProcessing CW, FM, wavetrain, multi-pulse matched filtering Pulse Lengths Range-dependent, .039 to 10 sec. max.FM Bandwidth 50, 100 and 300 HzTracking 20 auto and operator-initiated Displays PPI, bearing range, Doppler range, FM A-scan, geographic overlayRange Scale5, 10, 20, 40, and 80 kyd PassivePassive Band Continuous 100-to-2,000 HzProcessing Broadband, narrowband, ALI, DEMON and tracking Displays BTR, BFI, NALI, DEMON and LOFAR Tracking 20 auto and operator-initiatedCommonOwn-ship noise reduction, doppler nullification, directional audio。
协同机制英语
协同机制英语Collaborative Mechanisms in EnglishCollaboration has become an increasingly important aspect of modern life, as individuals and organizations recognize the value of working together to achieve common goals. In the realm of the English language, collaborative mechanisms play a crucial role in facilitating effective communication, learning, and the dissemination of knowledge. This essay will explore the various collaborative mechanisms that exist within the English language ecosystem, highlighting their significance and the ways in which they contribute to the growth and development of the language.One of the primary collaborative mechanisms in the English language is the community of speakers. English is a global language, spoken by millions of people around the world, each bringing their own cultural and linguistic backgrounds. This diversity of speakers creates a rich tapestry of linguistic exchange, where individuals can learn from one another, share ideas, and collectively shape the evolution of the language. Through online forums, social media platforms, and face-to-face interactions, English speakers engage in collaborative discussions, share resources, and offer feedback to oneanother, fostering a sense of community and contributing to the ongoing development of the language.Another important collaborative mechanism in the English language is the education system. Educational institutions, from primary schools to universities, play a pivotal role in teaching and promoting the use of English. Teachers, professors, and language experts collaborate to develop curricula, design teaching materials, and implement innovative pedagogical approaches to ensure that students acquire proficiency in the language. This collaborative effort not only helps students to learn English but also contributes to the standardization and refinement of the language, as educational institutions work to maintain and uphold linguistic norms and conventions.The publishing industry also serves as a collaborative mechanism within the English language ecosystem. Writers, editors, publishers, and language experts work together to produce a vast array of written materials, from books and articles to websites and digital content. This collaborative process involves the exchange of ideas, the review and revision of written work, and the collective effort to ensure that the content produced is of high quality and adheres to linguistic standards. The publishing industry's collaborative efforts help to shape the evolution of the English language, as new words, phrases, and styles are introduced and incorporated into thelanguage.Additionally, the development of linguistic technologies, such as machine translation, natural language processing, and language-learning applications, relies heavily on collaboration. Teams of linguists, computer scientists, and language experts work together to develop and refine these technologies, which in turn facilitate the learning, translation, and dissemination of the English language. These collaborative efforts contribute to the accessibility and usability of the English language, enabling more people to engage with and use the language effectively.Furthermore, the translation industry, which plays a crucial role in bridging linguistic divides, is inherently collaborative. Translators, interpreters, and language specialists work together to ensure accurate and efficient translation of materials from one language to another, including the translation of English content into other languages and vice versa. This collaborative effort not only facilitates cross-cultural communication but also helps to preserve the integrity and nuances of the English language in the translation process.Finally, the academic and research community within the field of linguistics also engages in collaborative mechanisms to further the understanding and study of the English language. Linguists, researchers, and scholars collaborate on research projects, sharefindings, and engage in peer review processes to advance the collective knowledge about the structure, evolution, and usage of the English language. These collaborative efforts contribute to the ongoing scholarly discourse and the development of new theories and insights that can inform the teaching, learning, and application of the English language.In conclusion, collaborative mechanisms are essential to the growth and development of the English language. From the community of speakers to the education system, the publishing industry, linguistic technologies, the translation industry, and the academic and research community, these collaborative efforts work together to shape, refine, and disseminate the English language across the globe. By embracing and fostering these collaborative mechanisms, we can continue to enhance the accessibility, versatility, and richness of the English language, ensuring its continued relevance and impact in an increasingly interconnected world.。
国家科研论文和科技信息高端交流平台的战略定位与核心特征
国家科研论文和科技信息高端交流平台的战略定位与核心特征*李广建,罗立群*本文系国家社会科学基金重大项目“大数据时代知识融合的体系架构、实现模式及实证研究”(项目编号:15ZDB129)研究成果。
摘要建设高端交流平台是对国家科技信息和科技情报体系的顶层设计,也是新时期科技情报研究和工作的指导思想,为科技情报的未来指明了发展方向。
在国家“十四五”规划中,高端交流平台的构建上升到了国家战略高度,是加强我国科学战略力量的重要任务之一,相较于一般意义的平台具有更丰富的内涵和更高的定位。
文章站在全球科技格局和创新生态的高度,从国家科技安全、国家重大需求、科技创新范式等三个维度系统思考高端交流平台的战略定位。
基于对高端交流平台的三个定位、中国国家科技战略发展的根本需要以及对全球科技创新态势的正确认知,结合中国国情,从三个维度阐释高端交流平台构建的核心特征:一是开放,从单向被动不对等开放走向双向主动对等开放交流;二是融合,从成果发布走向知识融合;三是计算,从辅助科学发现的工具走向自主科学发现的主体。
关键词高端交流平台知识融合情报计算科学发现开放科学引用本文格式李广建,罗立群.国家科研论文和科技信息高端交流平台的战略定位与核心特征[J].图书馆论坛,2022,42(1):13-20.On the Positioning and Core Features of the National High-end Exchange Platform for Scientific and Technological Papers and InformationLI Guangjian &LUO LiqunAbstract The construction of the national high-end exchange platform for scientific and technological papers and information is among the top-level designs of the national scientific and technological information and intelligence system ,and it is vital for the strengthening of China ’s scientific strategic forces.With a view of global scientific andtechnological pattern and innovation ecology ,this paper discusses the positioning of such a national high-end exchange platform ,focusing on national scientific and technological security ,major national needs ,and scientific and technological innovation paradigms.It then makes an analysis of its three core features ,i.e.,openness ,fusion ,and computing.As for openness ,it should transfer from the one-way passive non-equivalent openness to the two-way active reciprocal open communication.As for fusion ,it should transfer from the singlerelease of scientific and technological findings to the fusion of such findings.As for computing ,it should not onlyact as a tool to assist scientific discovery ,but also become a main body of autonomous independent scientific discoveries.Keywords high-end exchange platform ;knowledge fusion ;intelligence computing ;scientific discovery ;open science0引言国家科研论文和科技信息高端交流平台(以下简称“高端交流平台”)已经被正式列入《中华人民共和国国民经济和社会发展第十四个五年规划和2035年远景目标纲要》,这是党和国家在“百年未有之大变局”时代对我国国家科技创新体系的高瞻远瞩,是对国家科技信息和科技情报体系的顶层设计,也是新时期科技情报研究和工作的指导思想,为科技情报的未来指明了发展方向。
毛家网官方产品介绍:AWK-1131A系列入门级工业IEEE802.11a b g n无线AP 客户
AWK-1131A SeriesEntry-level industrial IEEE802.11a/b/g/n wireless AP/clientFeatures and Benefits•IEEE802.11a/b/g/n AP/client support•Millisecond-level Client-based Turbo Roaming1•Integrated antenna and power isolation•5GHz DFS channel supportCertificationsIntroductionThe AWK-1131A industrial wireless AP/client meets the growing need for faster data transmission speeds by supporting IEEE802.11n technology with a net data rate of up to300Mbps.The AWK-1131A is compliant with industrial standards and approvals covering operating temperature, power input voltage,surge,ESD,and vibration.The two redundant DC power inputs increase the reliability of the power supply.The AWK-1131A can operate on either the2.4or5GHz bands and is backwards-compatible with existing802.11a/b/g deployments to future-proof your wireless investments.Improved Higher Data Rate and Channel Capacity•High-speed wireless connectivity with up to300Mbps data rate•MIMO technology to improve the capability of transmitting and receiving multiple data streams•Increased channel width with channel bonding technology•Supports flexible channel selection to build up wireless communication system with DFSSpecifications for Industrial-Grade Applications•Redundant DC power inputs•Integrated isolation design with enhanced protection against environmental interference•Compact aluminum housing,IP30-ratedSpecificationsWLAN InterfaceWLAN Standards802.11a/b/g/n802.11i Wireless SecurityModulation Type DSSSMIMO-OFDMOFDMFrequency Band for US(20MHz operating channels) 2.412to2.462GHz(11channels)5.180to5.240GHz(4channels)5.260to5.320GHz(4channels)25.500to5.700GHz(11channels)25.745to5.825GHz(5channels)Frequency Band for EU(20MHz operating channels) 2.412to2.472GHz(13channels)5.180to5.240GHz(4channels)1.The Turbo Roaming recovery time indicated herein is an average of test results documented,in optimized conditions,across APs configured with interference-free20-MHz RF channels,WPA2-PSK security,and default Turbo Roaming parameters.The clients are configured with3-channel roaming at100Kbps traffic load.Other conditions may also impact roaming performance.For more information about Turbo Roaming parameter settings,refer to the product manual.5.260to5.320GHz(4channels)35.500to5.700GHz(11channels)3Frequency Band for JP(20MHz operating channels) 2.412to2.484GHz(14channels)5.180to5.240GHz(4channels)5.260to5.320GHz(4channels)35.500to5.700GHz(11channels)3Wireless Security WEP encryption(64-bit and128-bit)WPA/WPA2-Enterprise(IEEE802.1X/RADIUS,TKIP,AES)WPA/WPA2-PersonalTransmission Rate802.11b:1to11Mbps802.11a/g:6to54Mbps802.11n:6.5to300MbpsTransmitter Power for802.11a23±1.5dBm@6to24Mbps21±1.5dBm@36Mbps20±1.5dBm@48Mbps18±1.5dBm@54MbpsTransmitter Power for802.11b26±1.5dBm@1Mbps26±1.5dBm@2Mbps26±1.5dBm@5.5Mbps25±1.5dBm@11MbpsTransmitter Power for802.11g23±1.5dBm@6to24Mbps21±1.5dBm@36Mbps19±1.5dBm@48Mbps18±1.5dBm@54MbpsTransmitter Power for802.11n(2.4GHz)23±1.5dBm@MCS0/820MHz18±1.5dBm@MCS7/1520MHz23±1.5dBm@MCS0/840MHz17±1.5dBm@MCS7/1540MHzTransmitter Power for802.11n(5GHz)23±1.5dBm@MCS0/820MHz18±1.5dBm@MCS7/1520MHz23±1.5dBm@MCS0/840MHz17±1.5dBm@MCS7/1540MHzTransmitter Power2.4GHz26dBm18dBm18dBm5GHz(UNII-1)23dBm21dBm21dBm5GHz(UNII-2)23dBm21dBm21dBm5GHz(UNII-2e)23dBm23dBm23dBm5GHz(UNII-3)23dBm––Note:Based on regional regulations,the maximum transmission power allowed onthe UNII bands is restricted in the firmware,as indicated above.Receiver Sensitivity for802.11a-90dBm@6Mbps-88dBm@9Mbps-88dBm@12Mbps-85dBm@18Mbps-81dBm@24Mbps-78dBm@36Mbps-74dBm@48Mbps-72dBm@54MbpsReceiver Sensitivity for802.11b-93dBm@1Mbps-93dBm@2Mbps-93dBm@5.5Mbps-88dBm@11MbpsReceiver Sensitivity for802.11g-88dBm@6Mbps-86dBm@9Mbps-85dBm@12Mbps-85dBm@18Mbps-85dBm@24Mbps-82dBm@36Mbps-78dBm@48Mbps-74dBm@54MbpsReceiver Sensitivity for802.11n(2.4GHz)-70dBm@MCS720MHz-69dBm@MCS1520MHz-67dBm@MCS740MHz-67dBm@MCS1540MHzReceiver Sensitivity for802.11n(5GHz)-69dBm@MCS720MHz-71dBm@MCS1520MHz-63dBm@MCS740MHz-68dBm@MCS1540MHzWLAN Operation Mode Access point,Client,SnifferAntenna External,2/2dBi,Omni-directionalAntenna Connectors2RP-SMA femaleEthernet Interface10/100/1000BaseT(X)Ports(RJ45connector)1Standards IEEE802.1X for authenticationIEEE802.3for10BaseTIEEE802.3ab for1000BaseT(X)IEEE802.3u for100BaseT(X)Ethernet Software FeaturesManagement DHCP Server/Client,DNS,HTTP,IPv4,LLDP,Proxy ARP,SMTP,SNMPv1/v2c/v3,Syslog,TCP/IP,Telnet,UDP,Wireless Search Utility,VLAN,MXview,MXconfig Security HTTPS/SSL,RADIUS,SSHTime Management SNTP ClientFirewallFilter ICMP,MAC address,IP protocol,Port-basedSerial InterfaceConsole Port RS-232,8-pin RJ45LED InterfaceLED Indicators PWR,FAULT,STATE,SIGNAL,WLAN,LANInput/Output InterfaceButtons Reset buttonPhysical CharacteristicsHousing MetalIP Rating IP30Dimensions58x115x70mm(2.29x4.53x2.76in)Weight307g(0.68lb)Installation DIN-rail mounting,Wall mounting(with optional kit)Power ParametersInput Current0.56A@12VDC,0.14A@48VDCInput Voltage12to48VDCPower Connector1removable4-contact terminal block(s)Power Consumption 6.96W(max.)Reverse Polarity Protection SupportedEnvironmental LimitsOperating Temperature Standard Models:0to60°C(32to140°F)Wide Temp.Models:-40to75°C(-40to167°F)Storage Temperature(package included)-40to85°C(-40to185°F)Ambient Relative Humidity5to95%(non-condensing)Standards and CertificationsEMC EN55032/24EMI CISPR32,FCC Part15B Class BEMS IEC61000-4-2ESD:Contact:4kV;Air:8kVIEC61000-4-3RS:80MHz to1GHz:10V/mIEC61000-4-4EFT:Power:2kV;Signal:1kVIEC61000-4-5Surge:Power:2kV;Signal:1kVIEC61000-4-6CS:3VIEC61000-4-8PFMFRadio ANATEL,EN300328,EN301489-1/17,EN301893,FCC ID SLE-WAPN008,MIC,NCC,RCM,SRRC,WPC,KC,RCMSafety EN60950-1,UL60950-1Vibration IEC60068-2-6MTBFTime749,476hrsStandards Telcordia SR332WarrantyWarranty Period5yearsDetails See /warrantyPackage ContentsDevice1x AWK-1131Series wireless AP/clientInstallation Kit1x cap,plastic,for RJ45port1x DIN-rail kitAntenna2x2.4/5GHz antennaDocumentation1x quick installation guide1x warranty cardDimensionsOrdering InformationModel Name Band Standards Operating Temp. AWK-1131A-EU EU802.11a/b/g/n0to60°C AWK-1131A-EU-T EU802.11a/b/g/n-40to75°C AWK-1131A-JP JP802.11a/b/g/n0to60°C AWK-1131A-JP-T JP802.11a/b/g/n-40to75°C AWK-1131A-US US802.11a/b/g/n0to60°C AWK-1131A-US-T US802.11a/b/g/n-40to75°C Accessories(sold separately)AntennasANT-WDB-ANF-0407 2.4/5GHz,omni-directional antenna,4/7dBi,N-type(male)ANT-WDB-ANF-0609 2.4/5GHz,omni-directional antenna,6/9dBi,N-type(female)ANT-WDB-ANM-0306 2.4/5GHz,omni-directional antenna,3/6dBi,N-type(male)ANT-WDB-ANM-0407Dual-band omni-directional antennas,4dBi at2.4GHz or7dBi at5GHzANT-WDB-ANM-0502 2.4/5GHz,omni-directional antenna,5/2dBi,N-type(male)ANT-WDB-ANM-0609 2.4/5GHz,omni-directional antenna,6/9dBi,N-type(male)ANT-WDB-ARM-02 2.4/5GHz,omni-directional rubber duck antenna,2dBi,RP-SMA(male)ANT-WDB-ARM-0202 2.4/5GHz,panel antenna,1.8/1.8dBi,RP-SMA(male)ANT-WDB-PNF-1518 2.4/5GHz,panel antenna,15/18dBi,N-type(female)MAT-WDB-CA-RM-2-0205 2.4/5GHz,ceiling antenna,2/5dBi,MIMO2x2,RP-SMA-type(male)MAT-WDB-DA-RM-2-0203-1m 2.4/5GHz,desktop antenna,2/3dBi,MIMO2x2,RP-SMA-type(male),1m cableMAT-WDB-PA-NF-2-0708 2.4/5GHz,panel antenna,7/8dBi,MIMO2x2,N-type(female)ANT-WSB5-ANF-125GHz,omni-directional antenna,12dBi,N-type(female)ANT-WSB5-PNF-185GHz,directional panel antenna,18dBi,N-type(female)ANT-WSB-ANF-09 2.4GHz,omni-directional antenna,9dBi,N-type(female)ANT-WSB-PNF-12 2.4GHz,directional panel antenna,12dBi,N-type(female)ANT-WSB-PNF-18 2.4GHz,directional panel antenna,18dBi,N-type(female)ANT-WSB-AHRM-05-1.5m 2.4GHz,omni-directional/dipole antenna,5dBi,RP-SMA(male),1.5m cableWireless AdaptorsA-ADP-RJ458P-DB9F-ABC01DB9female to RJ45connector for the ABC-01Wireless Antenna CableA-CRF-RFRM-R4-150RF magnetic stand,RP-SMA(male)to RP-SMA(female),RG-174/U cable,1.5mA-CRF-RFRM-S2-60SS402cable,RP-SMA(male)to RP-SMA(female)A-CRF-RMNM-L1-300N-type(male)to RP SMA(male),LMR-195Lite cable,3mA-CRF-RMNM-L1-600N-type(male)to RP SMA(male),LMR-195Lite cable,6mA-CRF-RMNM-L1-900N-type(male)to RP SMA(male),LMR-195Lite cable,9mSurge ArrestorA-SA-NFNF-01Surge arrestor,N-type(female)to N-type(female)A-SA-NMNF-01Surge arrester,N-type(female)to N-type(male)Wireless Terminating ResistorA-TRM-50-RM Termination resistor,50ohms,N-type maleWireless Antenna CableCRF-N0117SA-3M N-type(male)to RP SMA(male),CFD200cable,3mWall-Mounting KitsWK-51-01Wall-mounting kit,2plates,6screws,51.6x67x2mm©Moxa Inc.All rights reserved.Updated Apr30,2019.This document and any portion thereof may not be reproduced or used in any manner whatsoever without the express written permission of Moxa Inc.Product specifications subject to change without notice.Visit our website for the most up-to-date product information.。
SCI写作句型汇总
S C I论文写作中一些常用的句型总结(一)很多文献已经讨论过了一、在Introduction里面经常会使用到的一个句子:很多文献已经讨论过了。
它的可能的说法有很多很多,这里列举几种我很久以前搜集的:A.??Solar energy conversion by photoelectrochemical cells?has been intensively investigated.?(Nature 1991, 353, 737 - 740?)B.?This was demonstrated in a number of studies that?showed that composite plasmonic-metal/semiconductor photocatalysts achieved significantly higher rates in various photocatalytic reactions compared with their pure semiconductor counterparts.C.?Several excellent reviews describing?these applications are available, and we do not discuss these topicsD.?Much work so far has focused on?wide band gap semiconductors for water splitting for the sake of chemical stability.(DOI:10.1038/NMAT3151)E.?Recent developments of?Lewis acids and water-soluble organometalliccatalysts?have attracted much attention.(Chem. Rev. 2002, 102, 3641?3666)F.?An interesting approach?in the use of zeolite as a water-tolerant solid acid?was described by?Ogawa et al(Chem.Rev. 2002, 102, 3641?3666)G.?Considerable research efforts have been devoted to?the direct transition metal-catalyzed conversion of aryl halides toaryl nitriles. (J. Org. Chem. 2000, 65, 7984-7989) H.?There are many excellent reviews in the literature dealing with the basic concepts of?the photocatalytic processand the reader is referred in particular to those by Hoffmann and coworkers,Mills and coworkers, and Kamat.(Metal oxide catalysis,19,P755)I. Nishimiya and Tsutsumi?have reported on(proposed)the influence of the Si/Al ratio of various zeolites on the acid strength, which were estimated by calorimetry using ammonia. (Chem.Rev. 2002, 102, 3641?3666)二、在results and discussion中经常会用到的:如图所示A. GIXRD patterns in?Figure 1A show?the bulk structural information on as-deposited films.?B.?As shown in Figure 7B,?the steady-state current density decreases after cycling between 0.35 and 0.7 V, which is probably due to the dissolution of FeOx.?C.?As can be seen from?parts a and b of Figure 7, the reaction cycles start with the thermodynamically most favorable VOx structures(J. Phys. Chem. C 2014, 118, 24950?24958)这与XX能够相互印证:A.?This is supported by?the appearance in the Ni-doped compounds of an ultraviolet–visible absorption band at 420–520nm (see Fig. 3 inset), corresponding to an energy range of about 2.9 to 2.3 eV.B. ?This?is consistent with the observation from?SEM–EDS. (Z.Zou et al. / Chemical Physics Letters 332 (2000) 271–277)C.?This indicates a good agreement between?the observed and calculated intensities in monoclinic with space groupP2/c when the O atoms are included in the model.D. The results?are in good consistent with?the observed photocatalytic activity...E. Identical conclusions were obtained in studies?where the SPR intensity and wavelength were modulated by manipulating the composition, shape,or size of plasmonic nanostructures.?F.??It was also found that areas of persistent divergent surfaceflow?coincide?with?regions where convection appears to be consistently suppressed even when SSTs are above 27.5°C.(二)1. 值得注意的是...A.?It must also be mentioned that?the recycling of aqueous organic solvent is less desirable than that of pure organic liquid.B.?Another interesting finding is that?zeolites with 10-membered ring pores showed high selectivities (>99%) to cyclohexanol, whereas those with 12-membered ring pores, such as mordenite, produced large amounts of dicyclohexyl ether. (Chem. Rev. 2002, 102,3641?3666)C.?It should be pointed out that?the nanometer-scale distribution of electrocatalyst centers on the electrode surface is also a predominant factor for high ORR electrocatalytic activity.D.?Notably,?the Ru II and Rh I complexes possessing the same BINAP chirality form antipodal amino acids as the predominant products.?(Angew. Chem. Int. Ed., 2002, 41: 2008–2022)E. Given the multitude of various transformations published,?it is noteworthy that?only very few distinct?activation?methods have been identified.?(Chem. Soc. Rev., 2009,?38, 2178-2189)F.?It is important to highlight that?these two directing effects will lead to different enantiomers of the products even if both the “H-bond-catalyst” and the?catalyst?acting by steric shielding have the same absolute stereochemistry. (Chem. Soc. Rev.,?2009,?38, 2178-2189)G.?It is worthwhile mentioning that?these PPNDs can be very stable for several months without the observations of any floating or precipitated dots, which is attributed to the electrostatic repulsions between the positively charge PPNDs resulting in electrosteric stabilization.(Adv. Mater., 2012, 24: 2037–2041)2.?...仍然是个挑战A.?There is thereby an urgent need but it is still a significant challenge to?rationally design and delicately tail or the electroactive MTMOs for advanced LIBs, ECs, MOBs, and FCs.?(Angew. Chem. Int. Ed.2 014, 53, 1488 – 1504)B.?However, systems that are?sufficiently stable and efficient for practical use?have not yet been realized.C.??It?remains?challenging?to?develop highly active HER catalysts based on materials that are more abundant at lower costs. (J. Am. Chem.Soc.,?2011,?133, ?7296–7299)D.?One of the?great?challenges?in the twenty-first century?is?unquestionably energy storage. (Nature Materials?2005, 4, 366 - 377?)众所周知A.?It is well established (accepted) / It is known to all / It is commonlyknown?that?many characteristics of functional materials, such as composition, crystalline phase, structural and morphological features, and the sur-/interface properties between the electrode and electrolyte, would greatly influence the performance of these unique MTMOs in electrochemical energy storage/conversion applications.(Angew. Chem. Int. Ed.2014,53, 1488 – 1504)B.?It is generally accepted (believed) that?for a-Fe2O3-based sensors the change in resistance is mainly caused by the adsorption and desorption of gases on the surface of the sensor structure. (Adv. Mater. 2005, 17, 582)C.?As we all know,?soybean abounds with carbon,?nitrogen?and oxygen elements owing to the existence of sugar,?proteins?and?lipids. (Chem. Commun., 2012,?48, 9367-9369)D.?There is no denying that?their presence may mediate spin moments to align parallel without acting alone to show d0-FM. (Nanoscale, 2013,?5, 3918-3930)(三)1. 正如下文将提到的...A.?As will be described below(也可以是As we shall see below),?as the Si/Al ratio increases, the surface of the zeolite becomes more hydrophobic and possesses stronger affinity for ethyl acetate and the number of acid sites decreases.(Chem. Rev. 2002, 102, 3641?3666)B. This behavior is to be expected and?will?be?further?discussed?below. (J. Am. Chem. Soc.,?1955,?77, 3701–3707)C.?There are also some small deviations with respect to the flow direction,?whichwe?will?discuss?below.(Science, 2001, 291, 630-633)D.?Below,?we?will?see?what this implies.E.?Complete details of this case?will?be provided at a?later?time.E.?很多论文中,也经常直接用see below来表示,比如:The observation of nanocluster spheres at the ends of the nanowires is suggestive of a VLS growth process (see?below). (Science, 1998, ?279, 208-211)2. 这与XX能够相互印证...A.?This is supported by?the appearance in the Ni-doped compounds of an ultraviolet–visible absorption band at 420–520 nm (see Fig. 3 inset), corresponding to an energy range of about 2.9 to 2.3 eVB.This is consistent with the observation from?SEM–EDS. (Chem. Phys. Lett. 2000, 332, 271–277)C.?Identical conclusions were obtained?in studies where the SPR intensity and wavelength were modulated by manipulating the composition, shape, or size of plasmonic nanostructures.?(Nat. Mater. 2011, DOI: 10.1038/NMAT3151)D. In addition, the shape of the titration curve versus the PPi/1 ratio,?coinciding withthat?obtained by fluorescent titration studies, suggested that both 2:1 and 1:1 host-to-guest complexes are formed. (J. Am. Chem. Soc. 1999, 121, 9463-9464)E.?This unusual luminescence behavior is?in accord with?a recent theoretical prediction; MoS2, an indirect bandgap material in its bulk form, becomes a direct bandgapsemiconductor when thinned to a monolayer.?(Nano Lett.,?2010,?10, 1271–1275)3.?我们的研究可能在哪些方面得到应用A.?Our ?ndings suggest that?the use of solar energy for photocatalytic watersplitting?might provide a viable source for?‘clean’ hydrogen fuel, once the catalyticef?ciency of the semiconductor system has been improved by increasing its surface area and suitable modi?cations of the surface sites.B. Along with this green and cost-effective protocol of synthesis,?we expect that?these novel carbon nanodots?have potential applications in?bioimaging andelectrocatalysis.(Chem. Commun., 2012,?48, 9367-9369)C.?This system could potentially be applied as?the gain medium of solid-state organic-based lasers or as a component of high value photovoltaic (PV) materials, where destructive high energy UV radiation would be converted to useful low energy NIR radiation. (Chem. Soc. Rev., 2013,?42, 29-43)D.?Since the use of?graphene?may enhance the photocatalytic properties of TiO2?under UV and visible-light irradiation,?graphene–TiO2?composites?may potentially be usedto?enhance the bactericidal activity.?(Chem. Soc. Rev., 2012,?41, 782-796)E.??It is the first report that CQDs are both amino-functionalized and highly fluorescent,?which suggests their promising applications in?chemical sensing.(Carbon, 2012,?50,?2810–2815)(四)1. 什么东西还尚未发现/系统研究A. However,systems that are sufficiently stable and efficient for practical use?have not yet been realized.B. Nevertheless,for conventional nanostructured MTMOs as mentioned above,?some problematic disadvantages cannot be overlooked.(Angew. Chem. Int. Ed.2014,53, 1488 – 1504)C.?There are relatively few studies devoted to?determination of cmc values for block copolymer micelles. (Macromolecules 1991, 24, 1033-1040)D. This might be the reason why, despite of the great influence of the preparation on the catalytic activity of gold catalysts,?no systematic study concerning?the synthesis conditions?has been published yet.?(Applied Catalysis A: General2002, 226, ?1–13)E.?These possibilities remain to be?explored.F.??Further effort is required to?understand and better control the parameters dominating the particle surface passivation and resulting properties for carbon dots of brighter photoluminescence. (J. Am. Chem. Soc.,?2006,?128?, 7756–7757)2.?由于/因为...A.?Liquid ammonia?is particularly attractive as?an alternative to water?due to?its stability in the presence of strong reducing agents such as alkali metals that are used to access lower oxidation states.B.?The unique nature of?the cyanide ligand?results from?its ability to act both as a σdonor and a π acceptor combined with its negativecharge and ambidentate nature.C.?Qdots are also excellent probes for two-photon confocalmicroscopy?because?they are characterized by a very large absorption cross section?(Science ?2005,?307, 538-544).D.?As a result of?the reductive strategy we used and of the strong bonding between the surface and the aryl groups, low residual currents (similar to those observed at a bare electrode) were obtained over a large window of potentials, the same as for the unmodified parent GC electrode. (J. Am. Chem. Soc. 1992, 114, 5883-5884)E.?The small Tafel slope of the defect-rich MoS2 ultrathin nanosheets is advantageous for practical?applications,?since?it will lead to a faster increment of HER rate with increasing overpotential.(Adv. Mater., 2013, 25: 5807–5813)F. Fluorescent carbon-based materials have drawn increasing attention in recent years?owing to?exceptional advantages such as high optical absorptivity, chemical stability, biocompatibility, and low toxicity.(Angew. Chem. Int. Ed., 2013, 52: 3953–3957)G.??On the basis of?measurements of the heat of immersion of water on zeolites, Tsutsumi etal. claimed that the surface consists of siloxane bondings and is hydrophobicin the region of low Al content. (Chem. Rev. 2002, 102, 3641?3666)H.?Nanoparticle spatial distributions might have a large significance for catalyst stability,?given that?metal particle growth is a relevant deactivation mechanism for commercial catalysts.?3. ...很重要A.?The inhibition of additional nucleation during growth, in other words, the complete separation?of nucleation and growth,?is?critical(essential, important)?for?the successful synthesis of monodisperse nanocrystals. (Nature Materials?3, 891 - 895 (2004))B.??In the current study,?Cys,?homocysteine?(Hcy) and?glutathione?(GSH) were chosen as model?thiol?compounds since they?play important (significant, vital, critical) roles?in many biological processes and monitoring of these?thiol?compounds?is of great importance for?diagnosis of diseases.(Chem. Commun., 2012,?48, 1147-1149)C.?This is because according to nucleation theory,?what really matters?in addition to the change in temperature ΔT?(or supersaturation) is the cooling rate.(Chem. Soc. Rev., 2014,?43, 2013-2026)(五)1. 相反/不同于A.?On the contrary,?mononuclear complexes, called single-ion magnets (SIM), have shown hysteresis loops of butterfly/phonon bottleneck type, with negligiblecoercivity, and therefore with much shorter relaxation times of magnetization. (Angew. Chem. Int. Ed., 2014, 53: 4413–4417)B.?In contrast,?the Dy compound has significantly larger value of the transversal magnetic moment already in the ground state (ca. 10?1?μB), therefore allowing a fast QTM. (Angew. Chem. Int. Ed., 2014, 53: 4413–4417)C.?In contrast to?the structural similarity of these complexes, their magnetic behavior exhibits strong divergence.?(Angew. Chem. Int. Ed., 2014, 53: 4413–4417)D.?Contrary to?other conducting polymer semiconductors, carbon nitride ischemically and thermally stable and does not rely on complicated device manufacturing. (Nature materials, 2009, 8(1): 76-80.)E.?Unlike?the spherical particles they are derived from that Rayleigh light-scatter in the blue, these nanoprisms exhibit scattering in the red, which could be useful in developing multicolor diagnostic labels on the basis not only of nanoparticle composition and size but also of shape. (Science 2001,? 294, 1901-1903)2. 发现,阐明,报道,证实可供选择的词包括:verify, confirm, elucidate, identify, define, characterize, clarify, establish, ascertain, explain, observe, illuminate, illustrate,demonstrate, show, indicate, exhibit, presented, reveal, display, manifest,suggest, propose, estimate, prove, imply, disclose,report, describe,facilitate the identification of?举例:A. These stacks appear as nanorods in the two-dimensional TEM images, but tilting experiments?confirm that they are nanoprisms.?(Science 2001,? 294, 1901-1903)B. Note that TEM?shows?that about 20% of the nanoprisms are truncated.?(Science 2001,? 294, 1901-1903)C. Therefore, these calculations not only allow us to?identify?the important features in the spectrum of the nanoprisms but also the subtle relation between particle shape and the frequency of the bands that make up their spectra.?(Science 2001,? 294, 1901-1903)D. We?observed?a decrease in intensity of the characteristic surface plasmon band in the ultraviolet-visible (UV-Vis) spectroscopy for the spherical particles at λmax?= 400 nm with a concomitant growth of three new bands of λmax?= 335 (weak), 470 (medium), and 670 nm (strong), respectively. (Science 2001,? 294, 1901-1903)E. In this article, we present data?demonstrating?that opiate and nonopiate analgesia systems can be selectively activated by different environmental manipulationsand?describe?the neural circuitry involved. (Science 1982, 216, 1185-1192)F. This?suggests?that the cobalt in CoP has a partial positive charge (δ+), while the phosphorus has a partial negative charge (δ?),?implying?a transfer of electron density from Co to P.?(Angew. Chem., 2014, 126: 6828–6832)3. 如何指出当前研究的不足A. Although these inorganic substructures can exhibit a high density of functional groups, such as bridging OH groups, and the substructures contribute significantly to the adsorption properties of the material,surprisingly little attention has been devoted to?the post-synthetic functionalization of the inorganic units within MOFs. (Chem. Eur. J., 2013, 19: 5533–5536.)B.?Little is known,?however, about the microstructure of this material. (Nature Materials 2013,12, 554–561)C.?So far, very little information is available, and only in?the absorber film, not in the whole operational devices. (Nano Lett.,?2014,?14?(2), pp 888–893)D.?In fact it should be noted that very little optimisation work has been carried out on?these devices. (Chem. Commun., 2013,?49, 7893-7895)E. By far the most architectures have been prepared using a solution processed perovskite material,?yet a few examples have been reported that?have used an evaporated perovskite layer. (Adv. Mater., 2014, 27: 1837–1841.)F. Water balance issues have been effectively addressed in PEMFC technology through a large body of work encompassing imaging, detailed water content and water balance measurements, materials optimization and modeling,?but very few of these activities have been undertaken for?anion exchange membrane fuel cells,? primarily due to limited materials availability and device lifetime. (J. Polym. Sci. Part B: Polym. Phys., 2013, 51: 1727–1735)G. However,?none of these studies?tested for Th17 memory, a recently identified T cell that specializes in controlling extracellular bacterial infections at mucosal surfaces. (PNAS, 2013,?111, 787–792)H. However,?uncertainty still remains as to?the mechanism by which Li salt addition results in an extension of the cathodic reduction limit. (Energy Environ. Sci., 2014,?7, 232-250)I.?There have been a number of high profile cases where failure to?identify the most stable crystal form of a drug has led to severe formulation problems in manufacture. (Chem. Soc. Rev., 2014,?43, 2080-2088)J. However,?these measurements systematically underestimate?the amount of ordered material. ( Nature Materials 2013, 12, 1038–1044)(六)1.?取决于a.?This is an important distinction, as the overall activity of a catalyst will?depend on?the material properties, synthesis method, and other possible species that can be formed during activation.?(Nat. Mater.?2017,16,225–229)b.?This quantitative partitioning?was determined by?growing crystals of the 1:1 host–guest complex between?ExBox4+?and corannulene. (Nat. Chem.?2014,?6177–178)c.?They suggested that the Au particle size may?be the decisive factor for?achieving highly active Au catalysts.(Acc. Chem. Res.,?2014,?47, 740–749)d.?Low-valent late transition-metal catalysis has?become indispensable to?chemical synthesis, but homogeneous high-valent transition-metal catalysis is underdeveloped, mainly owing to the reactivity of high-valent transition-metal complexes and the challenges associated with synthesizing them.?(Nature2015,?517,449–454)e.?The polar effect?is a remarkable property that enables?considerably endergonic C–H abstractions?that would not be possible otherwise.?(Nature?2015, 525, 87–90)f.?Advances in heterogeneous catalysis?must rely on?the rational design of new catalysts. (Nat. Nanotechnol.?2017, 12, 100–101)g.?Likely, the origin of the chemoselectivity may?be also closely related to?the H?bonding with the N or O?atom of the nitroso moiety, a similar H-bonding effect is known in enamine-based nitroso chemistry. (Angew. Chem. Int. Ed.?2014, 53: 4149–4153)2.?有很大潜力a.?The quest for new methodologies to assemble complex organic molecules?continues to be a great impetus to?research efforts to discover or to optimize new catalytic transformations. (Nat. Chem.?2015,?7, 477–482)b.?Nanosized faujasite (FAU) crystals?have great potential as?catalysts or adsorbents to more efficiently process present and forthcoming synthetic and renewablefeedstocks in oil refining, petrochemistry and fine chemistry. (Nat. Mater.?2015, 14, 447–451)c.?For this purpose, vibrational spectroscopy?has proved promising?and very useful.?(Acc Chem Res. 2015, 48, 407–413.)d.?While a detailed mechanism remains to be elucidated and?there is room for improvement?in the yields and selectivities, it should be remarked that chirality transfer upon trifluoromethylation of enantioenriched allylsilanes was shown. (Top Catal.?2014,?57: 967.?)e.?The future looks bright for?the use of PGMs as catalysts, both on laboratory and industrial scales, because the preparation of most kinds of single-atom metal catalyst is likely to be straightforward, and because characterization of such catalysts has become easier with the advent of techniques that readily discriminate single atoms from small clusters and nanoparticles. (Nature?2015, 525, 325–326)f.?The unique mesostructure of the 3D-dendritic MSNSs with mesopore channels of short length and large diameter?is supposed to be the key role in?immobilization of active and robust heterogeneous catalysts, and?it would have more hopeful prospects in?catalytic applications. (ACS Appl. Mater. Interfaces,?2015,?7, 17450–17459)g.?Visible-light photoredox catalysis?offers exciting opportunities to?achieve challenging carbon–carbon bond formations under mild and ecologically benign conditions. (Acc. Chem. Res.,?2016, 49, 1990–1996)3. 因此同义词:Therefore, thus, consequently, hence, accordingly, so, as a result这一条比较简单,这里主要讲一下这些词的副词词性和灵活运用。
Firm resources and sustained competitive advantage
The resource-based model of the firm examines the implications of these two assumptions for the analysis of sources of sustained competitive advantage
Resource-based v.s. Industry-based models
Research background
Although both internal analyses of organizational strengths and weaknesses and external analyses of opportunities and threats have received some attention in the literature, recent work has tended to focus primarily on analyzing a firm’s opportunities and threats in its competitive environment (Lamb, 1984) To help focus the analysis of the impact of a firm’s environment on its competitive position, much of this type of strategic research has placed little emphasis on the impact of idiosyncratic firm attributes on a firm’s competitive position
核能与核安全(英文版)
the fuel cladding
the second layer of defense is the primary circuit pressure boundary
The human development and utilization of nuclear energy is mainly developed nuclear power, relative to other forms of energy, nuclear energy has distinct advantages.
Байду номын сангаас
1kg U
=
2700 tons of coal
Meanwhile, nuclear power is clean energy and to protect the environment. Nuclear power generation unlike fossil fuel power plants that emit huge amounts of pollutants into the atmosphere.
The world nuclear power distribution
In the 30 countries that now have nuclear power, the proportion of nuclear power changes greatly. Up to 80 percent from France, Belgium 52, South Korea 39, Switzerland 37, Japan 29, United States 20, South Africa 4 and China 2.
Deep Connection
Deep ConnectionIn the vast expanse of human existence, connections are the threads that weave together the tapestry of our lives. A deep connection, a profound and meaningful bond, is the essence of human connection that enriches our experiences and fosters growth. As the ancient Chinese philosopher Confucius once observed, "The strength of a nation derives from the integrity of the home." A deep connection is the integrity of the home, the foundation that supports our relationships and nourishes our souls.A deep connection is not the superficial interaction that is fleeting and transient; it is the enduring bond that provides strength and support, enduring through the trials of time. It is the deep connection depicted in George Eliot's "Middlemarch," where the character Dorothea Brooke's unwavering loyalty to her husband and principles ultimately leads to her happiness. This connection is subtle, yet it is the very essence of true connection.The logic of a deep connection is rooted in the understanding that our shared humanity connects us all. The philosopher Immanuel Kant, in his moral philosophy, argued for the categorical imperative, which commands us to act in such a way that our actions could be universalized. A deep connection embodies this imperative, as it compels us to act in ways that promote the well-being of others as if it were our own.The language used to describe a deep connection should be as nuanced and profound as the emotion itself. Poets like John Keats have captured its essence in lines like, "A thing of beauty is a joy forever." These words suggest a connection that is not fleeting but enduring, a joy that is subtle yet profound.The structure of this essay mirrors the gentle yet firm nature of a deep connection. Each paragraph is carefully crafted to reflect the theme, moving from the initial exploration of a deep connection's nature to its logical underpinnings, and finally to its literary expressions. The essay maintains a clear and coherent structure, with each section building upon the last to create a comprehensive understanding of the topic.Content-wise, the essay is filled with examples that highlight the profound impact of a deep connection. The deep connection of a parent to their child, the unwavering commitment that endures through thick and thin, or the connection of a friend to their companion, the enduring bond that withstands the test of time, are all powerful manifestations of this concept.In conclusion, a deep connection is the gentle force that binds us together, the tender touch that fills our hearts with joy. It is the subtle yet profound expression of affection that touches our souls and guides us through life's journey. As we navigate the complexities of human relationships, let us cherish and cultivate deep connections. Forit is through this gentle and tender connection that we find meaning, joy, and the deepest expressions of love.。
协同油脂super n参数
协同油脂super n参数英文回答:The Synergistic Oil and Fat Super N is a revolutionary product that combines the benefits of various oils and fats to enhance its overall performance. It is formulated using a unique blend of high-quality oils, such as olive oil, coconut oil, and avocado oil, along with essential fatty acids and antioxidants.One of the key parameters of the Synergistic Oil and Fat Super N is its smoke point. The smoke point refers to the temperature at which the oil or fat starts to break down and produce smoke. This parameter is important because it determines the suitability of the oil or fat for different cooking methods.The Synergistic Oil and Fat Super N has a high smoke point, making it ideal for high-temperature cooking methods like frying and sautéing. It can withstand heat withoutbreaking down or producing smoke, ensuring that your food cooks evenly and retains its natural flavors.Another important parameter of the Synergistic Oil and Fat Super N is its fatty acid composition. This product contains a balanced ratio of saturated, monounsaturated, and polyunsaturated fats, which is essential for maintaining a healthy diet. These fats provide energy, support cell growth, and help absorb fat-soluble vitamins.The Synergistic Oil and Fat Super N also contains antioxidants, which are compounds that help protect the body against damage from harmful free radicals. These antioxidants can help reduce inflammation, support heart health, and boost the immune system.In addition to its nutritional benefits, the Synergistic Oil and Fat Super N is also versatile in its culinary applications. It can be used for various cooking methods, such as baking, roasting, and grilling. Its neutral flavor profile allows it to enhance the taste of different dishes without overpowering them.To illustrate the versatility of the Synergistic Oil and Fat Super N, let's consider an example. Imagine you are making a stir-fry dish with vegetables and chicken. By using the Synergistic Oil and Fat Super N, you can achieve a delicious and healthy meal. The high smoke point of the oil ensures that the chicken and vegetables are cooked evenly and retain their natural textures. The balancedfatty acid composition provides the necessary nutrients for a balanced diet. And the antioxidants help protect your body against oxidative stress.中文回答:协同油脂Super N是一种革命性的产品,它结合了各种油脂的优点,以提高其整体性能。
永宁油田河川区水平井泡沫驱开发研究
1241 区域概述志丹油田河川油区位于鄂尔多斯盆地陕北斜坡的中东部,构造模式为西倾单斜,局部发育鼻状构造,微型构造的发育为油气的高效运移提供了动力。
本区块长6油藏埋深中等,油层中部埋深1550~1800m;油层温度平均为57.38℃,地温梯度平均为3.25℃/100m,原始压力系数为0.69MPa/100m,为常温低压系统;原油整体表现为低比重、低粘度、低含硫特点的轻质油,原油物性较好[1];地层原油密度为0.7963g/cm 3,地层原油体积系数1.1066,气油比26.26m 3/t,PH值为6.5,平均Cl -含量为49734.58mg/L,平均总矿化度为82136.04mg/L,地层水属封闭的原生水,油藏保存条件较好[1]。
本区块2012年起进行长6水平井开发,2015年开始大规模开发水平井,2018年已初步形成107口水平井、周边856口常规井的开发井网。
目前本区长6水平井开发面临最大的问题是注水开发更容易暴性水淹,水淹后无有效的控水增油治理措施,且本区块目前采用采出水回注的方式进行补充能量,进一步加强了油层暴性水淹[2];针对以上问题,本次探索并研究最佳、成本最低的空气泡沫驱技术高效补充致密砂岩油藏地层能量,利用泡沫调驱剂增加高渗透渗流通道渗流阻力,扩大气驱波及体积,为此类油藏的高效开发探索一条可持续发展之路[2]。
2 泡沫驱配方优化及研究2.1 矿化度对发泡剂性能的影响(1)发泡剂溶液配制用蒸馏水将矿化度为112857mg/L、二价阳离子为9367mg/L的永232-3地层水按比例稀释成不同矿化度系列溶液,搅拌均匀即可。
本次实验的矿化度分别为32527,65054,85580mg/L,钙镁离子依次为2044,4744,6447mg/L,发泡剂浓度均为0.20%,见表1。
(2)矿化度对发泡剂性能影响研究本次共完成4种发泡剂在3个矿化度和钙镁离子下的发泡实验,通过方案试验和比选可以发现CAAS随着矿化度的增加,发泡容量增加,发泡速率降低,泡沫的半衰期增加,综合指数增大,消泡速率降低;HSAS随着矿化度的增加,发泡容量和发泡速率降低,泡沫的半衰期增加,综合指数先增大后降低,消泡速率降低;CHAG-2随着矿化度的增加,发泡容量先增加后降低,发泡速率变化较小,泡沫的半衰期先增加后降低,综合指数先增大后降低,消泡速率变化不大,总之泡沫的综合性能出现最大值;CAAG-2随着矿化度的增加,发泡容量先增加后降低,发泡速率降低,泡沫的半衰期增加,综合指数先增大后降低,消泡速率降低,泡沫的综合性能出现最大值。
重建最佳关联的翻译
重建最佳关联的翻译王雪丽;贾薇;董丽敏【摘要】Sperber和Wilson提出的关联理论从认知心理的角度指导人们的交际活动;而翻译属交际活动的下义范畴,因此关联理论对翻译具有同样的指导意义.关联理论认为,人类认知倾向于同最大关联相吻合,但在交际中人们只期待一个最佳关联.而翻译的核心就是努力做到使原文作者的意图与译文读者的期盼相吻合,即重建"最佳关联性".不同民族所具有的独特文化导致翻译工作困难重重,如何使不同的文化意象在翻译中达成统一,关联理论中的最佳关联原则给了翻译工作者很大的启发与指导.【期刊名称】《东北大学学报(社会科学版)》【年(卷),期】2009(011)002【总页数】5页(P174-177,183)【关键词】关联理论;翻译;跨文化交际;最佳关联【作者】王雪丽;贾薇;董丽敏【作者单位】东北大学外国语学院,辽宁沈阳,110004;东北大学外国语学院,辽宁沈阳,110004;东北大学外国语学院,辽宁沈阳,110004【正文语种】中文【中图分类】H059从法国学者Dan Sperber和英国学者Deirdre Wilson共同提出关联理论至今只有二十多年的时间,但该理论对语用学界所带来的影响却不容小觑。
许多学者对它进行了研究并将其应用于各种语言现象的解释,如会话含义、文本分析、幽默、礼貌以及跨文化交际等等。
Sperber和Wilson的学生Ernst-August Gutt又在1991年发表了题为《翻译与关联----认知与语境》的著作,提出了关联翻译理论,为翻译研究开辟了新的途径,对翻译工作具有重要的指导意义。
一、关联理论关联理论以格莱斯(Grice)会话含义理论为基础发展起来,并对其作出了修正与完善。
关联理论从认知心理的角度阐述了人们在交流过程中选择语言与理解语言的机制,即Sperber和Wilson提出的“明示—推理”(ostensive-inferential)模式。
effective communication课后答案
effective communication课后答案大海是地球上面积最大的,它也是人类最宝贵的资源。
蔚蓝的大海、微微的海风,让我们陶醉在这美丽的梦乡。
大海的水让我陶醉。
凉凉的海水,轻轻地拍在自己的脸上,使人精神一振,心情顿时也会变得非常愉快。
从小跟着父母在海边玩耍、嬉戏。
刚开始知道海时,只知道是水,我也不知海水为什么不能喝?只知道水很咸。
当自己幼年时不经意地喝了一小口,马上就吐了出来,“真是咸的,真是咸的。
”我大叫着。
我母亲忍不住嘲笑我愚蠢的外表。
现在我已明白海水不能喝的原因,但它带给我们的财富是数不清的。
我还喜欢在海水中游泳,在水中我感到舒服和放松。
大海的风让我陶醉。
海风是让人捉摸不透的,有时它是温柔的,凉爽的,而有时他又是勇猛的,冷酷的,尖叫着好像要毁掉一切。
夏天,闷热的天气,人们最理想的地方就是在海边,享受海风带来的凉爽,享受海浪带给我们的刺激,轻轻的海风吹拂着,面朝大海享受那无比的轻松。
就连夏天的暑气也消失在那海风中。
心情沉闷的时候,我喜欢一个人在海边慢慢地走着,向大海诉说我的心事,我们用心在彼此的沟通,它会用它那温柔的手抚摸我,安慰我,而那只手就是风。
大海海底让我陶醉。
在海底,有许多奇怪的鱼和五颜六色的珊瑚。
那些奇丽的颜色使我眼花缭乱。
在那海底就像一个宝库,那些奇形怪状鱼儿和珊瑚,构成了一幅多么美丽的画卷啊!让我们领略大海的气息。
鱼儿在水中悠闲地游着,海带在水中摇摆着它那柔软的身躯,在那就是一个“鱼间天堂”。
我喜欢大海,因为大海的水、大海的风、海底使我陶醉,让我心旷神怡。
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a r X i v :c o n d -m a t /0308308v 1 [c o n d -m a t .s t a t -m e c h ] 15 A u g 2003An efficient joint source-channel coding for a D-dimensional arrayIdo Kanter,Haggai Kfir and Shahar KerenMinerva Center and the Department of Physics,Bar-Ilan University,Ramat-Gan 52900,Israel(July 2003)An efficient joint source-channel (S/C)decoder based on the side information of the source andon the MN-Gallager Code over Galois fields,q ,is presented.The dynamical posterior probabilitiesare derived either from the statistical mechanical approach for calculation of the entropy for thecorrelated sequences,or by the Markovian joint S/C algorithm.The Markovian joint S/C decoderhas many advantages over the statistical mechanical approach,among them:(a)there is no need forthe construction and the diagonalization of a q ×q matrix and for a solution to saddle point equationsin q dimensions;(b)a generalization to a joint S/C coding of an array of two-dimensional bits (orhigher dimensions)is achievable;(c)using parametric estimation,an efficient joint S/C decoderwith the lack of side information is discussed.Besides the variant joint S/C decoders presented,wealso show that the available sets of autocorrelations consist of a convex volume,and its structurecan be found using the Simplex algorithm.I.INTRODUCTION Source coding is a process for removing redundant information from the source information symbol stream.Suppose we have a bitmapped image,then converting the bitmap image to GIF,JPEG or any of the familiar image formats used on the web is a source coding process.Not only can images be coded,but also sound,video frames,etc.,and compressing the stream of information is source coding.Channel coding is a procedure for adding redundancy as protection into the information stream which is to be transmitted;in other words,channel coding can be regarded as adding protection to the transmission process.For example,a wireless communication channel is affected by many factors such as distance,speed at which either party is moving,weather,buildings,other users’unintentional interference,etc.,so errors cannot be avoided.During the last decade engineers and also physicists have designed efficient error correction techniques such as Low-Density-Parity-Check-Codes (LDPC)[1–4]or Turbo [5]codes that nearly saturate Shannon’s limit.In a typical scenario of a communication channel there are two major resources which are highly limited.The first is power,which includes both transmitter power and receiver power.The second is bandwidth (channel capacity)indicating the speed at which the channel can transmit information,or more exactly,how many bps (bits per second).Both of these determine the capability of a channel.For example,by increasing the power we can reduce the error,but the power is limited.On the other hand,if the channel capacity is unlimited,we can just go ahead and add a large amount of protection (low rate),but again we cannot afford that since channel capacity is a commodity which in many scenarios is even more precious than power.The main tradeoffin communication is the following:given a fixed capacity channel and a fixed amount of power,how should we allocate them between the source and the channel to get the best result,i.e,the smallest distortion?We know that a certain amount of channel capacity is allocated to the source and the rest is used for protection,but what is the ratio between them?Shannon separation theorem states that source coding (compression)and channel coding (error protection)can be performed separately and sequentially,while maintaining optimality [6–9].However,this is true only in the case of asymptotically long block lengths of data and point-to-point transmission.In many practical applications,the conditions of the Shannon’s separation theorem neither holds,nor can it be used as a good approximation.Thus,considerable interest has developed in various schemes of joint source-channel (S/C)coding,where compression and error correction are combined into one mechanism (see,for instance,the following selected publications [10–15]).The paper is organized as follows.In Section II Statistical Mechanical (SM)joint S/C coding is introduced,whereasin Section III the threshold of the code is calculated using scaling behavior for the required number of messages passing for the convergence of the algorithm [4,16,17].In Section IV the efficiency of the SM joint S/C coding is compared to various separation schemes.A degradation in the performance of the SM joint S/C coding is examined in Section V as a function of the spectrum of the eigenvalues of the transfer matrix.In Section VI the Simplex algorithm is used to calculate the available space of a possible set of autocorrelations.The drawbacks of the SM joint S/C coding are discussed in Section VII,and advanced S/C coding is presented in Section VIII.The Markovian joint S/C coding and its efficiency are discussed in Section IX.Based on the parametric estimation methods the Markovian joint S/Cdecoder with the lack of side information is discussed in Section X.Its extension to higher dimensions is discussed in Section XI.The paper closes with some concluding remarks.II.JOINT S/C CODING-STATISTICAL MECHANICAL APPROACHIn our recent papers[18,17]a particular scheme based on a SM approach for the implementation of the joint S/C coding was presented and the main steps are briefly summarized below.The original boolean source isfirst mapped to a binary source[19,20]{x i±1}i=1,...,L,and is characterized by afinite set of autocorrelations bounded by the length k0C k1,...,k m=1ln2[1H2({C k1,...,k m})−H2(P b)(6)where f is the channel bit error rate and p b is a bit error rate.The saddle point solutions derived from eq.4indicate that the equilibrium properties of the one-dimensional Ising spin system(x i=±1)with up to order k0multi-spin interactions[24]H=− i k0 k=1y k1,...,k mq j=1γj n(10)where l/r/c denotes the state of the left/right/center(n−1/n+1/n)block respectively and q l L/q r R are their posterior probabilities.S I(c)=e−βH I stands for the Gibbs factor of the inner energy of a block,k0successive binary variables spins,characterized by an energy H I at a state c,see eq.7.Similarly S L(l,c)(S R(c,r))stands for the Gibbs factor of consecutive Left/Center(Center/Right)blocks at a state l,c(c,r)[17,18].The complexity of the calculation of the block prior probabilities is O(Lq2/log q)where L/log q is the number of blocks.The decoder complexity per iteration of the MN codes over afinitefield q can be reduced to order O(Lqu)[2,29],where u stands for the average number of checks per block.Hence the total complexity of the DBP decoder is of the order of O(Lqu+Lq2/log q). Another way to represent the dynamical behavior of the SM joint S/C decoder is in the framework of message passing on a graph.Typically,the graph is bipartite and consists of variable nodes and check nodes.A message from variables to checks is a horizontal pass,and a message from checks to variables is a vertical pass.In the SM joint S/C decoder there are three layers,as presented in Fig.1.Thefirst layer represents the checks and the second layer represents the variables,where each variable and check stands for a block of k0bits.The size of the third layer,denoted as dynamical block posterior probabilities derived from the Transfer Matrix(TM)method,is equal to the size of the source in blocks,L0=L/k0.Each element in the third layer receives two arrows,representing the posterior probabilities of the neighboring blocks,and sends one output arrow to the center block,representing the current updated dynamical posterior probabilities which are then used for the vertical pass.FIG.1.A message passing in the SM joint S/C decoder is represented by a graph with the following three layers.The check blocks are represented by full squares,the full/open circles denote source/noise block variables and the open diamonds denote the calculators for the dynamical block posterior probabilities for the source block variables.Each one of these calculators receives an input message from its two neighbors (module L 0)and sends its output message to its block.For simplification of the discussion below,in almost all of the simulation results we concentrate on rate 1/3and the construction of the matrices A and B follow reference [4]which is sketched in Fig. 2.The advantage of this construction is that the matrices A and B are very sparse,but the threshold of the code for large blocks is only 1−3%from the channel capacity [4,16].Furthermore,since B has a systematic structure,the complexity of the encoder scales linearly with L although B −1is dense [30,31].Of course,codes with higher thresholds exist (for instance in references [1,2]),hence the performance of the joint S/C algorithm reported below should be interpreted as a lower bound.(Results for a limited example with rate greater than one,R >1,are briefly discussed in reference [35])We conclude this section with the comment that the extension of the SM joint S/C algorithm in the framework of the MN-Gallager decoder to the Gallager decoder [32]is in question.In the Gallager decoder we first solve L 0(1/R −1)equations for the noise variables,and only in the final step is the message recovered.Since the noise is not spatially correlated,we do not see a simple way to incorporate in the Gallager case the side information about the spatial correlations among the message variables.The equivalence between these two (MN-Gallager and Gallager)similar decoders is in question.B -1B A M 1.75 NM ...........N ..N N N 1 bit per row/column 3 bits per row/column M 3 bits per row/column FIG.2.The structure of the matrices A and B for the MN decoder taken from reference citeKS,for rate 1/3.The black dots (area)denote the non-zero elements of the matrices A,B,B −1For illustration,in Fig.3we present results for rate R =1/3,L =10,000,q =4and 8where the decoding is based on the dynamical block posterior probabilities,eq.10,and with the following parameters.For q =4(open circles)C 1=0.55,C 2=0.5,C 12=0.4(y 1=0.275,y 2=0.291,y 12=0.422)and H 2=0.683.Shannon’s lower bound,eq.6,is denoted by the double dotted line,where for p b =0the channel noise level is f c =0.227.For q =8(open diamonds)C 1=0.77,C 2=0.69,C 3=0.56,C 123=0.7(y 1=0.349,y 2=0.36,y 3=0.211,y 123=0.443)and H 2=0.453.Shannon’s lower bound is denoted by the dashed line,where for p b =0the channel noise level is f c =0.275.Each point was averaged over at least 1,000messages.These results for both q =4and 8indicate that the threshold of the presented decoder with L =10,000is ∼15%−20%below the channel capacity for infinite sourcemessages.FIG.3.Simulation results for ratecircles)C1=0.55,C2=0.5,C12=eq.6,is denoted by the double dotted line.For q=8(open diamonds)C1=0.77,C2=0.69,C3=0.56,C123=0.7 (y1=0.349,y2=0.36,y3=0.211,y123=0.443)and H2=0.453.Shannon’s lower bound is denoted by the dashed line.Each point was averaged over at least1,000source messages with the desired set of autocorrelations.III.THE THRESHOLD OF THE CODEAn interesting question is to measure the efficiency of the decoder,eq.10,as a function of the maximal correlation length taken k0,the strength of the correlations,the size of thefinitefields q and to compare the efficiency with the separation schemes.A direct answer to the questions raised is to implement exhaustive simulations on increasing source length,variousfinitefields q,and sets of autocorrelations,which result in the bit error probability versus the flip rate f.Besides the enormous computational time required,the conclusions would be controversial since it is unclear how to compare,for instance,the performance as a function of q;with the same number of transmitted blocks or with the same number of transmitted bits.In order to overcome these difficulties,for a given MN-Gallager code and with DBP decoding over GF(q)and a set of autocorrelations,the threshold f c for L→∞is estimated from the scaling argument of the convergence time, which was previously observed for q=2[4,16].The median number of message passing steps,t med,necessary for the convergence of the MN-DBP algorithm is assumed to diverge as the level of noise approaches f c from below.More precisely,we found that the scaling for the divergence of t med is independent of q and is consistent withAt med=FIG.4.Theflip rate f as a The lines are a result of a linear regressionfit.The c of N. All simulation results presented below are derived for rate1/3and the construction of the matrices A and B of the MN code are taken from[4].In all examined sets of autocorrelations,103≤L≤5×104and4≤q≤64,the scaling for the median convergence time was indeed recovered.For illustration,in Fig.5,we present the scaling behavior for the amount of message passing for the two examined cased presented in Fig.3.(Note that this decoder can be extended to rate R>1and results for a limited example are presented in reference[35])FIG.5.Theflip rate f as a for q=4,8 is0.223,0.265,which are aboutFor a given set of autocorrelations,{C k1,...,k m}where k m≤k0,the MN decoder,eq.10,can be implementedwith anyfield q≥2k0.In order to optimize the complexity of the decoder it is clear that one has to work with the minimal allowedfield,q=2k0.However,when the goal is to optimize the threshold of the code,the selection of the optimalfield,q,is in question.To answer this question we present in Fig.6results for k0=2(C1=C2=0.86)and q=4,16,64.It is clear that the threshold,f c,increases as a function of q as was previously found for the case of i.i.d sources.[26,27]More precisely,the estimated thresholds for q=4,16,64are∼0.293,0.3,0.309,respectively, and the corresponding Ratios(≡f c/f Sh)are0.913,0.934,0.962,where Shannon’s lower bound f Sh=0.321.Note that the extrapolation of f c for large q appears asymptotically to be consistent with f c(q)∼0.316−0.18/q.FIG.6.The scaling behavior,f are a re-sult of a linear regressionfit.TheRatio≡f c/f Sh=0.913,0.934,0.962,where f Sh=0.321.PARISON BETWEEN JOINT AND SEPARATION SCHEMESResults of simulations for q=4,8,16and32and selected sets of autocorrelations are summarized in Table I(Fig.7)and the definition of the symbols is:{C k}denotes the imposed values of two-point autocorrelations as defined in eqs.1and2;{y k}are the interaction strengths,eq.7;H represents the entropy of sequences with the given set of autocorrelations,eq.5;f c is the estimated threshold of the MN decoder with the DBP derived from the scaling behavior of t med,eq.11;f Sh is Shannon’s lower bound,eq.6;Ratio is the efficiency of our code,f c/f Sh;Z R indicates the gzip compression rate averaged overfiles of the sizes105−106bits with the desired set of autocorrelations. We assume that the compression rate with L=106achieves its asymptotic ratio,as was indeed confirmed in the compression offiles with different L;1/R⋆indicates the ideal(minimal)ratio between the transmitted message and the source signal after implementing the following two steps:compression of thefile using gzip and then using an ideal optimal encoder/decoder,for a given BSC with f c.A number greater than(less than)3in this column indicates that the MN joint S/C decoder is more efficient(less efficient)in comparison to the channel separation method using the standard gzip compression.The last four columns of Table I(Fig.7)are devoted to the comparison of the presented joint S/C decoder with advanced compression methods.P P M R and AC R represent the compression rate offiles of the size105−106bits with the desired autocorrelations using the Prediction by Partial Match[36]and for the Arithmetic Coder[37],respectively.Similarly to the gzip case,1/R P P M and1/R AC denote the optimal(minimal) rate required for the separation process(first a compression and then an ideal optimal encoder/decoder)assuming a BSC with f c.FIG.7.Results for q=4,8,16,32and selected sets of two-point autocorrelations{C k}Table I indicates the following main results:(a)For q=4(the upper part of Table I)a degradation in the performance is observed as the correlations are enhanced,and as a result the entropy decreases.The degradation appears to be significant as the entropy is below∼0.3(or for the test case R=1/3,f c≥0.3).[38]A similar degradation was also observed for larger values of q as the entropy decreases.(b)The efficiency of our joint S/C coding technique is superior to the alternative standard gzip compression in the S/C separation technique.For high entropy the gain of the MN decoder is about5−10%.This gain disappears as the entropy and the performance of thepresented decoder,eq.10,are decreased.(c)In comparison to the standard gzip,the compression rate is improved by 2−5%using the AC method.A further improvement of a few percent is achieved by the PPM compression.This latter improvement appears to be significant in the event of low entropy.(d)With respect to the performance,the presented joint S/C decoder,eq.10,appears to be comparable with the presented separation methods,but for low entropy it appears that the PPM compression is superior.However,one should bear in mind a better threshold for the MN code can be found by optimizing the code[1].(e)With respect to the computational time of the S/C coding,our limited experience indicates that the joint S/C decoder is faster than the AC separation method and the PPM separation method is substantially slower.Finally,we note that using the side information,the set of autocorrelations,one can design a special compression procedure which may overcome the disadvantages of the abovementioned compression methods[42].V.THE ROLE OF THE SPECTRUM OF EIGENV ALUESFor a given q,there are many sets of autocorrelations,{C k1,...,k m},in q dimensions obeying the same entropy(seethe discussion in section VI below).An interesting question is whether the performance of the presented MN decoder measured by the Ratio(≡f c/f Sh)is a function of the entropy only.Our numerical simulations indicate that the entropy is not the only parameter which controls the performance of the algorithm.For the same entropy and q the Ratio canfluctuate widely among different sets of correlations.For illustration,in Table II(Fig.8)results for two sets of autocorrelations with the same entropy are summarized for each q=4,8,16and32.It is clear that as the Ratio(≡f c/f Sh)is much degradated the gzip performance is superior(the second example with q=8and32in Table II(Fig.8)where the Ratio is0.8and0.72,respectively).The crucial question is tofind the criterion to classify the performance of the algorithm among all sets of autocorrelations obeying the same entropy.Our generic criterion is the decay of the correlation function over distances beyond two successive blocks.However,before examination of this criterion,we return to some aspects of statistical physics.The entropy of sequences with a given set of autocorrelations bounded by a distance k0=log2(q)is determined via the effective Hamiltonian consisting of q interactions,eq.7.As a result the entropy of these sequences is thesame as the entropy of the effective Hamiltonian,H{y k1,...,k m},at the inverse temperatureβ=1,eq.5.As for theusual scenario of the transfer matrix method,the leading order of quantities such as free energy and entropy are a function of the largest eigenvalue of the transfer matrix only.On the other hand the decay of the correlation function is a function of the whole spectrum of the q=2k0eigenvalues(and eigenvectors)[23].Asymptotically,the decay of the correlation function is determined from the ratio between the second largest eigenvalue,λ2,and the largest eigenvalue,λ2/λmax.From the statistical mechanical point of view,one may wonder why thefirst q correlations can be determined using the information ofλmax only.The answer is that once the transfer matrix is defined as afunction of{y k1,...,k m},eqs.3-7,all eigenvalues are determined as well asλmax.There is no way to determineλmaxindependently of all other eigenvalues.In Table II(Fig.8)results of the MN decoder,eq.10,for q=4,8,16,32are presented.For each q,two different sets of autocorrelations characterized by the same entropy and threshold f Sh are examined.The practical method we used to generate different sets of autocorrelations with the same entropy was a simple Monte Carlo over the space of{C k1,...,k m}[39].The additional column in Table II(in comparison with Table I)is the ratio betweenλ2/λmax,whichcharacterizes the decay of the correlation function over large distances.It is clear that for a given entropy asλ2/λmax increases/decreases,the performance of the joint S/C decoder measured by the Ratio f c/f Sh is degradated/enhanced, independent of q.The new criterion to classify the performance of the decoder among all sets of autocorrelations obeying the same entropy is the decay of the correlation function.This criterion is consistent with the tendency that as thefirst k0two-points autocorrelations are increased/decreased a degradation/enhancement in the performance is observed(see Table I).The physical intuition is that as the correlation length increases,the relaxation time to the equilibrium macroscopic state increases,andflips on larger scales than nearest neighbor blocks are required.Finally, we note that in the general scenario,thefirst two largest eigenvalues are not sufficient to approximate the correlation function on short length scales and the comparison of the efficiency of the decoder should take into account the entire spectrum of eigenvalues and the eigenvectors[23].FIG.8.Results for q=4,8,16,32and different sets of two-point autocorrelations.For each q,two different sets of two-point autocorrelations characterized by the same entropy and threshold f Sh are examined.Asλ2/λmax increases/decreases, the performance of the joint S/C decoder measured by the Ratio f c/f Sh is degradated/enhanced.Note that the decay of the correlation function in the intermediate region of a small number of blocks is a function of all the2k0eigenvalues.Hence,in order to enhance the effect of the fast decay of the correlation function in the case of smallλ2/λmax,we also try to enforce in our Monte Carlo search that all other2k0−2eigenvalues be less than Aλmax with the minimal possible constant A.This additional constraint was easily fulfilled for q=4with A=0.1, but for q=32the minimal A was around0.5.VI.POSSIBLE SETS OF AUTOCORRELATIONS AND THE SIMPLEX ALGORITHMThe entropy of correlated sequences can be calculated from eq.5.For the simplest case of sequences obeying only C1and C2the numerical solution of the saddle point equations indicate that the entropy is non-zero only in the regime−(1+C2)/2≤C1≤(1+C2)/2(12) where out of this regime the entropy is zero.The boundaries,C1=|(1+C2)/2|,are characterized by the following phenomena:(a)the entropy falls abruptly to zero at the boundary,and(b)y1and−y2diverge at the boundary(the one-dimensional Hamiltonian,eq.7consists of frustrated loops).These limited results obtained from the numerical solutions of the saddle point equations suffer from the followinglimitations:(a)finding the boundaries of the regime in the spaces of{C k1,...,k m}with afinite entropy is very sensitiveto the numerical precision since on the boundary{|y i|}diverge;(b)it is unclear whether the available space consists of a connected regime;(c)the question of whether out of the space with afinite entropy,there are afinite or infinite number of sequences(for instance e√For a given C1and C2,these15equations and inequalities can be solved for the minimum and the maximum available C3using the Simplex method.The Simplex solution indicates:(a)the available solution in the three-dimensional box (−1:1,−1:1,−1:1)for(C1,C2,C3)is a connected region bounded by a few plans whose detailed equations will be given elsewhere[40];(b)the fraction of the volume of the box with a positive number of sequences obeying the three constants is∼0.222.Preliminary results indicate that for4(C i,i=1,2,3,4)and5(C i,i=1,2,3,4,5)constraints the available volume is∼0.085,0.034,respectively.The fraction of possible sets of autocorrelations appears to decrease as the number of constraints increases.However, the question of whether the fraction of available autocorrelations drops exponentially with the number of constraints as well as its detailed spatial shape is the subject of our current research[40].We conclude the discussion in this section with the following general result[42].The available volume for thegeneral case of q constraints{C k1,...,k m}k m<log2(q)is convex.The main idea is that one can verify that the set ofequalities can be written in a matrix representation in the following formM P=C(13)where M is a matrix with elements±1;P represents the marginal probabilities P(±,±,....)and C represents the desired correlations or a normalization constant(for instance C1/2,C2/2and1/2,for the case of eq.15).The inequalities force the probabilities into the range[0:1].Clearly if P1(±,±,...)and P2(±,±,...)are two sets of probabilities obeying eq.13thenλP1+(1−λ)P2(14)is also a solution of the set of the equalities(0≤λ≤1).Hence,the available volume is convex.P(−,−,+)+P(−,−,−)−P(+,−,+)−P(+,−,−)=C1/2P(+,−,−)+P(−,−,−)−P(+,−,+)−P(−,−,+)=C1/2P(−,−,+)+P(−,−,−)+P(+,−,+)+P(+,−,−)=1/2P(+,−,+)+P(−,−,−)−P(+,−,−)+P(−,−,+)=C2/20≤P(±,−,±)≤1(15)P(+,+,−,+)+P(+,+,−,−)+P(−,−,−,+)+P(−,−,−,−)−P(+,−,−,+)−P(+,−,−,−)−P(−,+,−,+)−P(−,+,−,−)=C1/2P(+,−,−,+)+P(+,−,−,−)+P(−,−,−,+)+P(−,−,−,−)−P(+,+,−,+)−P(+,+,−,−)−P(−,+,−,+)−P(−,+,−,−)=C1/2P(+,+,−,−)+P(+,−,−,−)+P(−,+,−,−)+P(−,−,−,−)−P(+,+,−,+)−P(+,−,−,+)−P(−,+,−,+)−P(−,−,−,+)=C1/2P(−,+,−,+)+P(−,+,−,−)+P(−,−,−,+)+P(−,−,−,−)−P(+,+,−,+)−P(+,+,−,−)−P(+,−,−,+)−P(+,−,−,−)=C2/2P(+,+,−,+)+P(+,−,−,−)+P(−,+,−,+)+P(−,−,−,−)−P(+,+,−,−)−P(+,−,−,+)−P(−,+,−,−)−P(−,−,−,+)=C2/2P(+,+,−,+)+P(+,−,−,+)+P(−,+,−,−)+P(−,−,−,−)−P(+,+,−,−)−P(+,−,−,−)−P(−,+,−,+)−P(−,−,−,+)=C3/2P(+,+,−,+)+P(+,−,−,−)+P(−,+,−,+)+P(−,−,−,−)+P(+,+,−,−)+P(+,−,−,+)+P(−,+,−,−)+P(−,−,−,+)=1/20≤P(±,±,−,±)≤1(16)VII.DRA WBACKS OF THE SM APPROACHThe presented joint S/C decoder based on the SM approach suffers from the following drawbacks:(a)For each transmitted block one must calculate a q×q matrix,where each element of this matrix is a function of all q autocorre-lations,{C k1,...,k m}.Hence,the naive complexity of the construction of the transfer matrix is O(q4).Furthermore,foreach transmitted block the complexity of the calculation of the leading eigenvalue of the transfer matrix is of O(q3).(b)The required memory is of the order O(q2),where,for instance,for K0=20it results in a1Mega Bytes.(c) The solution of the saddle point equations,eqs.4-5,requires the calculation many times and with high precision of the leading eigenvalue of q×q matrix.From our experience,the calculation with high precision of the saddle pointequations in q=2k0dimensions,{y k1,...,k m}is a heavy numerical task for k0≥4.(d)The extension of the decoderbased on the SM approach to include an array of bits in two or a higher number of dimensions is impossible,since the trace in eq.2can be done only for very limited two-dimensional cases[23].VIII.JOINT S/C DECODER WITH ADV ANCED THRESHOLDIn order to overcome some of the abovementioned difficulties we present in this section a decoder with an advanced threshold,where the decoder gains fromfluctuations among differentfinite source messages.For a given sequence of L bits,{x1,x2,...,x L},and k m≤k0,there are L0=L/k0blocks,denoted by{A1,A2,...,A L}.For a given finitefield q=2k0we denote the number of possible different blocks by B m m=1,2,...,q.In thefirst step of the algorithm,the probability of occurrence of all three possible successive blocks is calculatedˆP(Bi ,B j,B k)≡1q b=1ˆP(B i,b,B j)q i m−1q j m+1(18)ˆP B mn=γB mn。