A Potential Reduction Method for a Class of Smooth Convex Programming

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应用化学专业英语及答案

应用化学专业英语及答案

黄冈师范学院2009—2010学年度第一学期期末试卷考试课程:专业英语考核类型:考试A卷考试形式:闭卷出卷教师:杨一思考试专业:化学考试班级:应用化学200601 一、Translate the following into English(20 points)1.过滤2.浓缩3.结晶化4.吸附5. 蒸馏6.超临界的7.二氯甲烷8.热力学平衡9.亲电性10.表面张力11.共轭的12.酮13.平衡常数14.丙基15.丁基16.亚甲基18.环己酮19.同位素20.标准熵二、Translate the following into Chinese(20 points)1. methyl propanoate2. rate constant3. ethyl methyl ketone4. free energy5. radical intermediate6. isobutyl methyl ether7. 3-chloropropene8. primary radical9. n-propyl bromide10. bond energy 11. circulating electrons12. local magnetic fields13. tetramethylsilane14. mass to charge ratios15 phenylamine16 amide17. amine18. nucleophile19. perchlorate20. carbocation三、Translation the following into chinese (40 points)A卷【第1页共 3 页】1. We can see why benzene is stable: according to resonance theory, the more resonance forms a substance has, the more stable it is. Benzene, with two resonance forms of equal energy, is therefore more stable and less reactive than a typical alkene.2. Membranes can be defined essentially as barrier, which separates two phases and restricts transport of various chemicals in a selective manner. A membrane can be homogenous or heterogeneous, symmetric or asymmetric in structure, solid or liquid, can carry a positive or negative charge or be neutral or bipolar. Transport through a membrane can be effected by convection or by diffusion of individual molecules, induced by an electric field or concentration, pressure or temperature gradient. The membrane thickness may vary from as small as 100 micron to several mms.3. The most common industrial adsorbents are activated carbon, silica gel, and alumina, because they present enormous surface areas per unit weight.A surface already heavily contaminated by adsorbates is not likely to have much capacity for additional binding, but further heating will drive off these compounds to produce a surface with high adsorptive capacity.Temperature effects on adsorption are profound, and measurements are usually at a constant temperature. Graphs of the data are called isotherms. Most steps using adsorbents have little variation in temperature.A卷【第2页共 3 页】4. In the absence of peroxides, hydrogen bromide adds to peopene via the Markovnikov pathway to yield isopropyl bromide. In the presence of peroxides, however, the order of addition is reversed, and the product is n-propyl bromide; the addition in this case is said to be anti-Markovnikov. This is interpreted in terms of initiation of the addition reaction by bromine atom, rather than by a proton, as is the case for electrophilic addition.四、Translate the following paragraphs into Chinese(20 points)1.Benzene and its derivatives can be nitrated using a mixture of concentrated nitric and sulphuric acid. The temperature must be controlled to prevent more than one nitro-group going in.2. Benzene can be made to react with halogen derivatives using aluminium chloride as a catalyst. This is called a Friedel-Crafts reaction.can be sulphonated by reacting it with fuming sulphuric acid(oleum). The benzene reacts with sulphur trioxide in the oleum.benzene is converted into ethylbenzene by reacting it with ethene. The ethylbenzene (also called styrene) is used to make polystyrene.黄冈师范学院2009—2010学年度第一学期期末试卷参考答案及评分标准考试课程:专业英语考核类型:考试A卷考试形式:闭卷出卷教师:杨一思考试专业:化学考试班级:应用化学200601 一、Translate the following into English(20 points)2. concentrate 4. adsorption chlorideequilibriumtensionconstant14. propylmagneticresonanceentropy二、Translate the following into Chinese(20 points)1. 丙酸甲酯2. 速率常数3. 甲乙酮4. 自有能5. 自由基中间体6. 异丁基甲醚7. 3-氯丙烯8. 伯自由基9. 正丙基溴化10. 键能11.循环电子12. 局部电磁场13. 四甲基硅烷14. 质荷比15.苯胺16.氨基化合物17.胺18亲核试剂19.高氯酸盐20.碳正离子三、Translation the following into chinese (50 points)1.依据共振理论,物质具有的共振式越多就越稳定。

基础化学(人卫第8版)课后习题参考答案

基础化学(人卫第8版)课后习题参考答案


13g 9.0g L1
1.4L
12、 nI2
m(I2 ) M (I2)

0.508g 254g mol 1

2.00 103 mol
nKI KMnO4 2n(I 2 ) 2 2.00 103 mol 4.00 103 mol
Exercises 2. 29.837 29.24 0.018618 0.19
1.89mol
8、 n(ZnCl2 )

m(ZnCl2 ) M (ZnCl2 )

350 g 136.3g mol 1

2.57mol
此溶液的物质的量浓度为:
c(ZnCl 2 )

n(ZnCl 2 ) V

2.57mol 739.5mL

3.48mol

L1
此溶液的质量摩尔浓度为:
b(ZnCl 2 )

n(ZnCl 2 ) m(H 2O)

2.57mol 650g

3.95mol
kg 1
m(K )
20mg
9、 c K n(K ) M (K ) 39.0g mol 1 5.1mmol L1
V
V
100mL
m(Cl )
366mg
c Cl n(Cl ) M (Cl ) 35.5g mol 1 103mmol L1
V
V
100mL
10、 m(C6 H12O6 ) 50.0g L1 500mL 25.0g
m(C6 H12O6
H 2O)

25.0g
M (C6 H12O6 H 2O) M (C6 H12O6 )

应用化学专业英语课后练习题含答案

应用化学专业英语课后练习题含答案
Answer: True.
5.A heterogeneous mixture is one in which the components are evenly distributed throughout.
Answer: False.
Short answer
4.What is the difference between an acid and a base?
Answer: An enzyme is a protein that acts as a catalyst in a biological reaction, lowering the activation energy required for the reaction to occur.
6.What is a heterogeneous mixture?
4.What is the definition of a chemical reaction?
Answer: A chemical reaction is a process in which one or more substances are transformed into different substances through the breaking and forming of chemical bonds.
Chapter 2
True or False
3.The pH scale is a measure of the concentration of hydrogen ions in a solution.
Answer: True.
4.A catalyst is a substance that changes the rate of a chemical reaction without being consumed in the reaction itself.

化学化工英语试题及答案

化学化工英语试题及答案

化学化工英语试题及答案一、选择题(每题2分,共20分)1. Which of the following is a chemical element?A. WaterB. OxygenC. HydrogenD. Carbon答案:B, C, D2. The chemical formula for table salt is:A. NaOHB. NaClC. HClD. NaHCO3答案:B3. What is the process called when a substance changes from a solid to a liquid?A. SublimationB. VaporizationC. MeltingD. Condensation答案:C4. In the periodic table, which group contains alkali metals?A. Group 1B. Group 2C. Group 17D. Group 18答案:A5. What is the name of the process where a substance decomposes into two or more substances due to heat?A. CombustionB. OxidationC. ReductionD. Decomposition答案:D6. Which of the following is a physical property of a substance?A. ColorB. TasteC. SolubilityD. Reactivity答案:A7. What is the term for a compound that releases hydrogen ions (H+) when dissolved in water?A. BaseB. AcidC. SaltD. Neutral答案:B8. The law of conservation of mass states that in a chemical reaction:A. Mass is lostB. Mass is gainedC. Mass remains constantD. Mass can be converted into energy答案:C9. Which of the following is a type of chemical bond?A. Ionic bondB. Covalent bondC. Hydrogen bondD. All of the above答案:D10. What is the name of the process where a substance absorbs energy and changes from a liquid to a gas?A. MeltingB. VaporizationC. SublimationD. Condensation答案:B二、填空题(每题2分,共20分)1. The symbol for the element iron is ________.答案:Fe2. The pH scale ranges from ________ to ________.答案:0 to 143. A compound that produces a basic solution when dissolvedin water is called a ________.答案:base4. The smallest particle of an element that retains its chemical properties is called a ________.答案:atom5. The process of separating a mixture into its individual components is known as ________.答案:separation6. The study of the composition, structure, and properties of matter is called ________.答案:chemistry7. The process of a substance changing from a gas to a liquid is called ________.答案:condensation8. A(n) ________ reaction is a type of chemical reactionwhere two or more substances combine to form a single product. 答案:synthesis9. The volume of a gas at constant temperature and pressureis directly proportional to the number of ________.答案:moles10. The process of converting a solid directly into a gas without passing through the liquid phase is known as ________. 答案:sublimation三、简答题(每题10分,共30分)1. Explain what is meant by the term "stoichiometry" in chemistry.答案:Stoichiometry is the calculation of the relative quantities of reactants and products in a chemical reaction.It is based on the law of conservation of mass and involvesthe use of balanced chemical equations and the molar massesof substances to determine the amounts of reactants needed to produce a certain amount of product or the amounts ofproducts formed from a given amount of reactant.2. Describe the difference between a physical change and a chemical change.答案:A physical change is a change in the state or form of a substance without altering its chemical composition. Examples include melting, freezing, and boiling. A chemical change, on the other hand, involves a change in the chemical composition of a substance, resulting in the formation of new substances. Examples include combustion and rusting.3. What are the three main types of chemical bonds, and givean example of each.答案:The three main types of chemical bonds are ionic bonds, covalent bonds, and metallic bonds. An ionic bond is formed when electrons are transferred from one atom to another, resulting in the formation of oppositely charged ions. An example is the bond between sodium (Na) and chloride (Cl) in table salt (NaCl). A covalent bond is formed when two atoms share electrons, as seen in water (H2O) where hydrogen atoms share electrons with oxygen. Metallic bonds occur in metals, where a "sea" of delocalized electrons is shared among positively charged metal ions, as in sodium metal。

应用化学专业英语第二版万有志主编版(课后答案和课文翻译)

应用化学专业英语第二版万有志主编版(课后答案和课文翻译)

Unit 1 The Roots of ChemistryI. Comprehension.1.C2. B3. D4. C5. BII. Make a sentence out of each item by rearranging the words in brackets.1. The purification of an organic compound is usually a matter of considerable difficulty, and it is necessary to employ various methods for this purpose.2. Science is an ever-increasing body of accumulated and systematized knowledge and is also an activity by which knowledge is generated.3. Life, after all, is only chemistry, in fact, a small example of chemistry observed on a single mundane planet.4. People are made of molecules; some of the molecules in people are rather simple whereas others are highly complex.5. Chemistry is ever present in our lives from birth to death because without chemistry there is neither life nor death.6. Mathematics appears to be almost as humankind and also permeates all aspects of human life, although many of us are not fully aware of this.III. Translation.1. (a) chemical process (b) natural science (c) the technique of distillation2. It is the atoms that make up iron, water, oxygen and the like/and so on/andso forth/and otherwise.3. Chemistry has a very long history, in fact, human activity in chemistry goesback to prerecorded times/predating recorded times.4. According to/From the evaporation of water, people know/realized thatliquids can turn/be/change into gases under certain conditions/circumstance/environment.5. You must know the properties of the material before you use it.IV . Translation化学是三种基础自然科学之一,另外两种是物理和生物。

Supercapacitor

Supercapacitor

SupercapacitorSupercapacitors (SC),[1]comprise a family of electrochemical capacitors. Supercapacitors, sometimes called ultracapacitors or electric double-layer capacitor (EDLC), don't have a conventional solid dielectric. The capacitance value of an electrochemical capacitor is determined by the combination of two storage effects:[2][3][4]∙Double-layer capacitance–electrostatic storage of the electrical energyachieved by separation of charge in a Helmholtz double layer at the interfacebetween the surface of a conductive electrode and a electrolyte. The separation of charge distance in a SC is on the order of a few Angstroms (0.3–0.8 nm) and is static.[5]∙Pseudocapacitance–Electrochemical storage of the electrical energy, achieved by redox reactions with specifically adsorbed ions from the electrolyte, intercalation of atoms in the layer lattice or electro-sorption, underpotential deposition of hydrogen or metal adatoms in surface lattice sites which result in a reversible faradaic charge-transfer.[5]The ratio of the storage resulting from each principle can vary greatly, depending on electrode design and electrolyte composition. Pseudo-capacitance can increase the capacitance value by as much as an order of magnitude over that of the double-layer by itself.[1]Supercapacitors are divided into three families, based on the design of the electrodes: ∙Double-layer capacitors –with carbon electrodes or derivates with muchhigher static double-layer capacitance than the faradaic pseudocapacitance ∙Pseudocapacitors –with electrodes out of metal oxides or conducting polymers with a high amount of faradaic pseudocapacitance∙Hybrid capacitors – capacitors with special electrodes that exhibit significant capacitance from both principlesHierarchical classification of supercapacitors and related typesSupercapacitors occupy the gap between traditional capacitors and rechargeable batteries. They have higher capacitance values per unit volume and greater energy density than other capacitors. They support up to 12 Farads/1.2 Volt, with capacitance values up to 10 times that of electrolytic capacitors.[1] While existing supercapacitors have energy densities that are approximately 10% of a conventional battery, their power density is generally 10 to 100 times greater. Power density is defined as the product of energy density, multiplied by the speed at which the energy is delivered to the load. The greater power density results in much shorter charge/discharge cycles than a battery is capable, and a greater tolerance for numerous charge/discharge cycles.Within electrochemical capacitors, the electrolyte is the conductive connection between the two electrodes, distinguishing them from electrolytic capacitors, in which the electrolyte is the cathode and second electrode.Supercapacitors are polarized and must operate with correct polarity. Polarity is controlled by design with asymmetric electrodes, or, for symmetric electrodes, by a potential applied during the manufacturing process.Supercapacitors support a broad spectrum of applications for power and energy requirements, including:[6]∙Long duration, low current, for memory backup in (SRAMs)∙Power electronics that require very short, high current, as in the KERSsystem in Formula 1 cars∙Recovery of braking energy for vehiclesHistoryDevelopment of electrochemical capacitorsIn the early 1950s, General Electric engineers began experimenting with devices using porous carbon electrodes for fuel cells and rechargeable batteries. Activated charcoal is an electrical conductor that is extremely porous carbon with a high specific surface area, providing a useful electrode material. In 1957 H. Becker developed a "Low voltage electrolytic capacitor with porous carbon electrodes".[7][8][9] He believed that the energy was stored as a charge in the carbon pores as in the etched foils of electrolytic capacitors. Because the double layer mechanism was not known at the time, he wrote in the patent: "It is not known exactly what is taking place in the component if it is used for energy storage, but it leads to an extremely high capacity." General Electric did not immediately pursue this work.In 1966 researchers at Standard Oil of Ohio (SOHIO) developed another version of the devices as ―Electrical energy storage apparatus‖, while working on experimental fuel cell designs.[10][11]The nature of electrochemical energy storage was not described in this patent. Even in 1970, the electrochemical capacitor patented by Donald L. Boos was registered as an electrolytic capacitor with activated carbon electrodes.[12]Principle construction of a supercapacitor; 1. power source, 2. collector, 3.polarized electrode, 4. Helmholtz double layer, 5. electrolyte having positive and negative ions, 6. Separator. By applying a voltage to the capacitor at both electrodes a respective Helmholtz double layer is formed, which has a positive or negative layer of ions from the electrolyte deposited in a mirror image on the respective opposite electrode.These early electrochemical capacitors used a cell design of two aluminum foils covered with activated carbon - the electrodes - which were soaked in an electrolyte and separated by a thin porous insulator. This design gave a capacitor with a capacitance value in the one "farad" area, which was significantly higher than for electrolytic capacitors of the same dimensions. This basic mechanical design remains the basis of most electrochemical capacitors.SOHIO did not commercialize their invention, licensing the technology to NEC, who finally marketed the results as ―supercapacitors‖ in 1971, to provide backup power for computer memory.[11] Other manufacturers followed from the end of the 1970s. Around 1978 Panasonic marketed its "Goldcaps‖ brand.[13]This product became a successful back-up energy source for memory backup applications.[11]The competition started some years later. In 1987 ELNA"Dynacap"s entered the market.[14] This generation had relatively high internal resistance, which limited the discharge current. They were used for low current applications like powering SRAM chips or for data backup.At the end of the 1980s improved electrode materials led to higher capacitance values and in lower resistance electrolytes that lowered the ESR in order to increase the charge/discharge currents. This led to rapidly improving performance and a rapid reduction in cost.The first supercapacitor with low internal resistance was developed in 1982 for military applications through the Pinnacle Research Institute(PRI), and were marketed under the brand name "PRI Ultracapacitor". In 1992, Maxwell Laboratories, later Maxwell Technologies took over this development. Maxwell adopted the term Ultracapacitor from PRI and called them "Boost Caps"[5]to underline their use for power applications.Since the energy content of a capacitor increases with the square of the voltage, researchers were looking for a way to increase the breakdown voltage. Using an anode of a 200V high voltage tantalum electrolytic capacitor in 1994 David A. Evans developed an "Electrolytic-Hybrid Electrochemical Capacitor".[15][16]These capacitors combine features of electrolytic and electrochemical capacitors. They combine the high dielectric strength of an anode from an electrolytic capacitor, and the high capacitance with a pseudocapacitive metal oxide (ruthenium (IV) oxide) cathode from an electrochemical capacitor, yielding a hybrid. Evans' Capattery[17] had an energy content about a factor of 5 higher than a comparable tantalum electrolytic capacitor of the same size.[18]Their high costs limited them to specific military applications.Recent developments in lithium-ion capacitors are also hybrids. They were pioneered by FDK in 2007.[19]They combine an electrostatic double-layer electrode with a doped lithium-ion electrochemical battery electrode to generate high pseudocapacitance additional to high double-layer capacitance.Development of the double layer and pseudocapacitance model HelmholtzWhen a metal (or an electronic conductor) is brought in contact with a solid or liquid ionic-conductor (electrolyte), a common boundary (interface) among the two different phases emerges. Helmholtz[20]was the first to realize that charged electrodes immersed in electrolytic solutions repel the coions of the charge while attracting counterions to their surfaces. With the two layers of opposite polarity formed at the interface between electrode and electrolyte in 1853 he showed that an electrical double layer (DL) that is essentially a moleculear dielectric achieved electrostatic charge storage.[21] Below the electrolyte's decomposition voltage the stored charge is linearly dependent on the voltage applied.This early Helmholtz model predicted a constant differential capacitance independent from the charge density depending on the dielectric constant of the solvent and the thickness of the double-layer.[5][22][23] But this model, while a good foundation, does not consider important factors including diffusion/mixing of ions in solution, the possibility of adsorption onto the surface and the interaction between solvent dipole moments and the electrode.Simplyfied illustration of the potential development in the area and in the further course of a Helmholtz double layer.Gouy\Chapman [edit]Louis Georges Gouy in 1910 and David Leonard Chapman in 1913 both observed that capacitance was not a constant and that it depended on the applied potential and the ionic concentration. The ―Gouy-Chapman model‖ made significant improvements by introducing a diffuse model of the DL. In this model the charge distribution of ions as a function of distance from the metal surface allows Maxwell–Boltzmann statistics to be applied. Thus the electric potential decreases exponentially away from the surface of the fluid bulk.[5][24]Stern [edit]Gouy-Chapman fails for highly charged DLs. In order to resolve this problem Otto Stern in 1924 suggested the combination of the Helmholtz and Gouy-Chapman models. In Stern's model, some of the ions adhere to the electrode as suggested by Helmholtz, giving an internal Stern layer and some form a Gouy-Chapman diffuse layer.[25]The Stern layer accounted for ions' finite size and consequently ions have a closest approach to the electrode on the order of the ionic radius. The Stern model too had limitations, effectively modeling ions as point charges, assuming all significant interactions in the diffuse layer are Coulombic, assuming dielectric permittivity to beconstant throughout the double layer, and that fluid viscosity is constant above the slipping plane.[26]Grahame [edit]Thus, D. C. Grahame modified Stern in 1947.[27]He proposed that some ionic or uncharged species can penetrate the Stern layer, although the closest approach to the electrode is normally occupied by solvent molecules. This could occur if ions lost their solvation shell when the ion approached the electrode. Ions in direct contact with the electrode were called ―specifically adsorbed ions‖. This model proposed the existence of three regions. The inner Helmholtz plane (IHP) plane passing through the centres of the specifically adsorbed ions. The outer Helmholtz plane (OHP) passes through the centres of solvated ions at their distance of closest approach to the electrode. Finally the diffuse layer is the region beyond the OHP.Schematic representation of a double layer on an electrode (BMD) model. 1. Inner Helmholtz plane, (IHP), 2. Outer Helmholtz plane (OHP), 3. Diffuse layer, 4. Solvated ions (cations) 5. Specifically adsorbed ions (redox ion, which contributes to the pseudocapacitance), 6. Molecules of the electrolyte solventBockris/Devanthan/Müller [edit]In 1963 J. O'M. Bockris, M. A. V Devanthan, and K. Alex Müller[28]proposed a model (BDM model) of the double-layer that included the action of the solvent in the interface. They suggested that the attached molecules of the solvent, such as water, would have a fixed alignment to the electrode surface. This first layer of solvent molecules display a strong orientation to the electric field depending on the charge. This orientation has great influence on the permittivity of the solvent which varies with the field strength. The inner Helmholtz plane (IHP) passes through the centers of these molecules. Specifically adsorbed, partially solvated ions appear in this layer. The solvated ions of the electrolyte are outside the IHP. Through the centers of theseions pass a second plane, the outer Helmholtz plane (OHP). The region beyond the OHP is called the diffuse layer. The BDM model now is most commonly used. Trasatti/Buzzanca [edit]Further research with double layers on ruthenium dioxide films in 1971 by Sergio Trasatti and Giovanni Buzzanca demonstrated that the electrochemical behavior of these electrodes at low voltages with specific adsorbed ions was like that of capacitors. The specific adsorption of the ions in this region of potential could also involve a partial charge transfer between the ion and the electrode. It was the first step towards pseudo-capacitors.[22]Ph.D., Brian Evans Conway within the John Bockris Group At Imperical College, London 1947Conway [edit]Between 1975 and 1980 Brian Evans Conway conducted extensive fundamental and development work on the ruthenium oxide type of electrochemical capacitor. In 1991 he described the transition from ‗Supercapacitor‘ to ‗Battery‘ behavior in electrochemical energy storage and in 1999 he coined the term supercapacitor as explanation for increased capacitance by surface redox reactions with faradaic charge transfer between electrodes and ions.[1][29][30]His "supercapacitor" stored electrical charge partially in the Helmholtz double-layer and partially was the result of faradaic reactions with ―pseudocapacitance‖ charge transfer of electron and protons between electrode and electrolyte. The working mechanisms of pseudocapacitors are electrosorption, redox reactions and intercalation.Marcus[edit source | edit]The physical and mathematical basics of electron charge transfer without making chemical bonds leading to pseudocapacitance was developed by Rudolph A. Marcus. Marcus Theory is a theory to explain the rates of electron transfer reactions – the rateat which an electron can move or jump from one chemical species to another. It was originally formulated to address outer sphere electron transfer reactions, in which the two chemical species only change in their charge with an electron jumping. For redox reactions without making or breaking bonds Marcus theory takes the place of Henry Eyring's transition state theory which has been derived for reactions with structural changes. R.A. Marcus received the Nobel Prize in Chemistry in 1992 for this theory Storage principlesElectrostatic vs electrochemical energy storageCharge storage principles of different capacitor types and their inherent voltage progressionThe voltage behavior of supercapacitors and batteries during charging/discharging differs clearlyIn conventional capacitors such as ceramic capacitors and film capacitors the electric energy is stored in a static electric field permeates the dielectric between two metallic conducting plates, the electrodes. The electric field originates by the separation ofcharge carriers. This charge separation creates a potential between the two electrodes, which can be tapped via an external circuit. The total energy stored in this arrangement increases with the amount of stored charge and the potential between the plates. The amount of charge stored per unit voltage is essentially a function of the size, the reciprocal value of the distance, and the material properties of the dielectric, while the potential between the plates is limited by the dielectric's breakdown field strength. The dielectric controls the capacitor's voltage.Conventional capacitors are also called electrostatic capacitors. The potential of a charged capacitor decreases linearly between the electrodes. This static storage also applies for electrolytic capacitors in which most of the potential decreases over the thin oxide layer of the anode. The electrolyte as cathode may be a little bit resistive so that for ―wet‖ electrolytic capacitors a small amount of the potential decreases over the electrolyte. For electrolytic capacitors with high conductive solid polymer electrolyte this voltage drop is negligible.Electrochemical capacitors do not have a conventional solid dielectric that separates the charge. The capacitance value of an electrochemical capacitor is determined by electrostatic and electrochemical principles:Electrostatic storage of the electrical energy is achieved by charge separation in a Helmholtz double layer at the interface between the surface of a conductor electrode and an electrolytic solution electrolyte. This capacitance is called double-layer capacitance.Electrochemical storage of the electrical energy is achieved by redox reactions with: specifically adsorbed ions from the electrolyte; intercalation of atoms in the layer lattice(晶格层); or underpotential deposition of hydrogen or metal adatoms in surface lattice sites that results in a reversible faradaic charge-transfer on the electrode. This capacitance is called pseudocapacitance and is faradaic in origin.[5]Double-layer capacitance and pseudocapacitance combine to provide a supercapacitor's capacitance value.[2][3]Because each supercapacitor has two electrodes, the potential of the capacitor decreases symmetrically over both Helmholtz layers, whereby a little voltage drop across the ESR of the electrolyte achieved.Both the electrostatic and the electrochemical storage are linear with respect to the total charge. This linear behavior implies that the voltage across the capacitor is linear with respect to the amount of stored energy. This linear voltage gradient differs from electrochemical batteries, in which the voltage across the terminals remains independent of the charged energy, providing a constant voltage.Electrostatic double-layer capacitanceSimplified view of a double-layer of negative ions in the electrode and solvated positive ions in the liquid electrolyte, detached from each other through a layer of polarized molecules of the solvent.An electrical double layer is generated by applying a voltage to an arrangement of an electrode and an electrolyte. According to the voltage polarity, the dissolved and solvated ions in the electrolyte move to the electrodes. Two layers of ions are generated. One is in the surface of the electrode. The other, with opposite polarity, is the dissolved ions in the adjacent liquid electrolyte. These layers of opposite ions are separated by a monolayer of isolating molecules of the solvent, such as water. The layers of isolating molecule, the inner Helmholtz plane (IHP), adhere by physical adsorption on the surface of the electrode and separate the opposite ions from each other, building a molecular dielectric(电介质). The amount of charge in the electrode is matched by the same magnitude of counter-charges in the outer Helmholtz plane (OHP). These phenomena can be used to store electrical charges. The stored charge in the IHP forms an electric field that corresponds to the strength of the applied voltage. It is only effective in the molecular layer of the solvent molecules and is static in origin.The "thickness" of a charged layer in the metallic electrode, i.e., the average extension perpendicular to the surface, is about 0.1 nm. It mainly depends on the electron density because the atoms in solid electrodes are stationary. In the electrolyte, the thickness depends on the size of the molecules of the solvent and of the movement and concentration of ions in the solvent. It ranges from 0.1 to 10 nm, and is described by the Debye length. The sum of the thicknesses is the total thickness of a double layer.Field strength [edit]The small thickness of the inner Helmholtz plane creates a strong electric field E. At a potential difference of, for example, U = 2V and a molecular thickness of d = 0.4 nm, the electric field strength will beThe voltage proof of aluminum oxide, the dielectric layer of aluminum electrolytic capacitors is approximately 1.4 nm/V. For a 6.3 V capacitor therefore the layer is 8.8 nm. The electric field is 6.3 V/8.8 nm = 716 kV/mm.The double-layer's field strength of about 5000 kV/mm is unrealizable in conventional capacitors with conventional dielectrics. No dielectric material could prevent charge carrier breakthrough. In a double-layer capacitor the chemical stability of the molecular bonds of the solvent molecules prevents breakthrough.[31]The forces that cause the adhesion are physical, not chemical, forces. Chemical bonds exist within the adsorbed molecules, but they are polarized. The magnitude of the electrical charge that can accumulate in the layers corresponds to the concentration of the adsorbed ions. Up to the electrolyte's decomposition voltage, this arrangement behaves like a capacitor in which the stored electrical charge is linearly dependent on the voltage applied.Structure and function of an ideal double-layer capacitor. Applying a voltage to the capacitor at both electrodes a Helmholtz double-layer will be formed separating the adhered ions in the electrolyte in a mirror charge distribution of opposite polarity. The double-layer is like the dielectric layer in a conventional capacitor, but with the thickness of a single molecule. The early Helmholtz model predicts a constant differential capacitance Cd independent from the charge density, depending on the dielectric constant ε and the charge layer separation δ.If the solvent of the electrolyte is water then with the influence of the high field strength, the permittivity ε is 6 (instead of 80 in normal conditions) and the layerseparation δ ca. 0.3 nm the value of differential capacitance predicted by the Helmholtz model is about 18 F/cm2.[22]This value can be used to calculate capacitance using the standard formula for conventional plate capacitors if only the surface of the electrodes is known. This capacitance can be calculated with:.The capacitance C is therefore greatest in devices made from materials with a high permit tivity ε, large electrode plate surface areas A and a small distance d between plates. The activated carbon electrodes have a surface area in the range of 10 to 40 µF/cm2. The double-layer distance is on the order of a few Angstroms (0.3-0.8 nm). This gives supercapacitors the highest capacitance values among the capacitors.[2][5]Because an electrochemical capacitor is composed of two electrodes the charge distribution in the Helmholtz layer at one electrode can be found in opposite polarity in the Helmholtz layer at the second electrode. The total capacitance value of is that of two capacitors connected in series. Because both capacitances have approximately the same value, the total capacitance is roughly half the capacitance of one electrode.Electrochemical pseudocapacitanceSimplified view of a double-layer with specifically adsorbed ions which have submitted their charge to the electrode to explain the faradaic charge-transfer of the pseudocapacitance.In a Helmholtz double-layer not only a static double-layer capacitance originates. Specifically adsorbed ions with redox reactions, electrosorption and intercalation results in faradaic charge-transfer between electrolyte and surface of an electrodecalled pseudocapacitance. Double-layer capacitance and pseudocapacitance both contribute to the total capacitance value of a electrochemical capacitor.[2][3]The distribution of the amounts of both capacitances depends on the surface area, material and structure the of the electrodes.Redox reactions in batteries with faradaic charge-transfer between an electrolyte and a surface of an electrode are well known since decades. But these chemical processes are associated with chemical reactions of the electrode materials usually with attendant phase changes. Although these chemical processes are relatively reversible, the charge and discharge of batteries often results in irreversibility reaction products of the chemical electrode-reagents. Accordingly, the cycle-life of rechargeable batteries is usually limited, and varies with the battery type. Additional the chemical processes are relatively slow extending the charge and discharge time of the batteries.An essential fundamental difference from redox reactions in batteries arises in supercapacitors, were a fast sequence of reversible redox processes with a linear function of degree of faradaic charge transfers take place. This behavior is the basic function of a new class of capacitance, the pseudocapacitance. Pseudocapacitance comprise fast and reversible faradaic processes with charge transfer between electrolyte and the electrode and is accomplished through reduction-oxidation reactions (redox reactions), electrosorption and intercalation processes in combination with the nonfaradaic formation of an electric double-layer. Capacitors with a high amount of pseudocapacitance are called pseudocapacitors.Applying a voltage at the capacitor terminals the polarized ions or charged atoms in the electrolyte are moving to the opposite polarized electrode forms a double-layer. Depending on the structure or the surface material of the electrode a pseudocapacitance can originate when specifically adsorbed cations pervades(遍及) the double-layer proceeding in several one-electron stages an excess of electrons. The electrons involved in the faradaic processes are transferred to or from valence-electron states (orbitals) of the redox electrode reagent. The electrons enter the negative electrode and flow through the external circuit to the positive electrode were a second double-layer with an equal number of anions has formed. But these anions will not take the electrons back. They are present on the surface of the electrode in the charged state, and the electrons remain in the quite strongly ionized and "electron hungry" transition-metal ions of the electrode. This kind of pseudocapacitance has a linear function within narrow limits and is determined by the potential-dependent degree of coverage of surface with the adsorbed anions from the electrolyte. The storage capacity of the pseudocapacitance with an electrochemical charge transfer takes place to an extent limited by a finite quantity of reagent or of available surface.Discharging the pseudocapacitance the reaction of charge transfer is reversed and the ions or atoms leave the double-layer and move into the electrolyte distributing randomly in the space between both electrodes.Unlike in batteries in pseudocapacitors the redox reactions or intercalation processes with faradaic charge-transfer do not result in slow chemical processes with chemical reactions or phase changes of the electrode materials between charge and discharge. The atoms or ions contribute to the pseudocapacitance simply cling[32]to the atomic structure of the electrode and charges are distributed on surfaces by physical adsorption processes that do not involve the making or breaking of chemical bonds. These faradaic charge transfer processes for charge storing or discharging employed in pseudocapacitors are very fast, much faster than the chemical processes in batteries.Confinement of solvated ions in pores, such as those present in carbide-derived carbon (CDC). As the pore size approaches the size of the solvation shell, the solvent molecules are removed, resulting in larger ionic packing density and increased charge storage capability.The ability of electrodes, to accomplish pseudocapacitance effects like redox reactions of electroactive species, electrosorption of H or metal ad-atoms or intercalation, which leads to a pseudocapacitance, strongly depend on the chemical affinity of electrode materials to the ions sorbed on the electrode surface as well as on the structure and dimension of the electrode pores. Materials exhibiting redox behavior for use as electrodes in pseudocapacitors are transition-metal oxides inserted by doping in the conductive electrode material like active carbon as well as conducting polymers such as polyaniline or derivatives of polythiophene covering the surface of conductive electrode material.Pseudocapacitance may also originates by the structure and especially by the pore size of the electrodes. The use of carbide-derived carbons(CDCs) or carbon nanotubes /CNTs for electrodes provides a network of very small pores formed by nanotube entanglement. These carbon nanoporous with diameters in the range of <2 nm can be referred to as intercalated pores. Solvated ions in the electrolyte can‘t enter these small pores but de-solvated ions which have reduced their ion dimensions are able to enter resulting in larger ionic packing density and increase charge storage capability. The tailored sizes of pores in nano-structured carbon electrodes can maximize ion confinement, increasing specific capacitance by faradaic H2adsorption treatment(?). Occupation of these pores by de-solvated ions from the electrolyte。

青岛“PEP”2024年小学五年级上册第4次英语第二单元期中试卷

青岛“PEP”2024年小学五年级上册第4次英语第二单元期中试卷

青岛“PEP”2024年小学五年级上册英语第二单元期中试卷考试时间:100分钟(总分:140)A卷考试人:_________题号一二三四五总分得分一、综合题(共计100题)1、What is the opposite of right?A. WrongB. CorrectC. TrueD. Accurate答案:A2、听力题:The reaction of acids with metals is often used to produce ______.3、听力题:The chemical formula for ammonium phosphate is _______.4、填空题:A wolf's howl can be heard over long ________________ (距离).5、听力题:The _______ needs sunlight to grow tall.6、What is the name of the bear species that lives in the Arctic?A. Grizzly BearB. Polar BearC. Black BearD. Brown Bear答案:B. Polar Bear7、听力题:Leaves capture _______ from the sun.8、What is the name of the event where you celebrate a new beginning?A. GraduationB. WeddingC. BirthdayD. New Year答案: D9、填空题:We have ______ (许多) animals in the zoo.10、What is the main function of the roots of a plant?A. To produce flowersB. To absorb nutrients and waterC. To support the plantD. To attract pollinators答案: B11、填空题:I like to _______ (参加) science fairs.12、填空题:A _____ (章鱼) can change its shape to fit through tight spaces.13、填空题:I saw a _______ (蜘蛛) spinning a web.14、听力题:She has long ______ (hair).15、听力题:I have a new ___. (computer)16、听力题:The ________ (mountaineer) climbs high peaks.17、填空题:He is a _____ (作家) who writes poetry.18、填空题:The first people to settle in Australia were the __________ (土著).19、听力题:A mountain is a large landform that rises ______ above the surrounding land.20、填空题:I enjoy ______ (学习) about different subjects.21、听力题:Some plants can grow in _______ water.22、听力题:My mom likes to _____ new recipes. (try)23、填空题:My ________ (玩具) helps me learn about colors.24、What is the capital city of Slovenia?A. LjubljanaB. MariborC. CeljeD. Kranj25、填空题:The __________ (历史的思维模式) inspires innovation.26、填空题:She has a beautiful _______ (声音).27、What is the capital of Puerto Rico?a. San Juanb. Poncec. Bayamónd. Mayagüez答案:a28、选择题:What is the name of our planet?A. MarsB. EarthC. VenusD. Jupiter29、What is the name of the famous English playwright?A. Charles DickensB. J.K. RowlingC. William ShakespeareD. Mark Twain答案:C30、选择题:What do you call the person who teaches you in school?A. DoctorB. TeacherC. EngineerD. Chef31、填空题:The __________ (历史的研究领域) continues to grow.32、填空题:My pet likes to play with my _________ (绒毛玩具).33、填空题:A wolverine is a strong ______ (动物).34、听力题:They ride their _____ (bikes) to school.35、填空题:I have a toy ________ that can walk.36、填空题:A goldfish can live in a ______ (鱼缸).37、What is the name of the famous bed and breakfast in "The Shining"?A. Overlook HotelB. Bates MotelC. The Stanley HotelD. The Grand Budapest Hotel答案: A38、听力题:The chemical formula for hydrochloric acid is _______.39、What do we call the top layer of soil?A. BedrockB. SubsoilC. TopsoilD. Humus答案: C40、听力题:The Earth's layers interact in various ______ ways.41、听力题:A compound that can donate protons is called an ______.42、填空题:________ (植物资源开发) benefits communities.The ________ (生态影响监测) keeps track of changes.44、What is the symbol for the element oxygen?A. OB. OxC. O2D. O3答案:A45、填空题:I like to __________ (动词) my __________ (玩具名) before bedtime.46、填空题:The _____ (花蕾) opens to reveal blossoms.47、填空题:My friend is __________ (具有创造力).48、What is the opposite of "fast"?A. QuickB. SlowC. RapidD. Swift答案: B49、填空题:A _______ (螃蟹) walks sideways.50、填空题:在中国历史中,________ (philosophers) 的思想对社会发展产生了深远的影响。

检验专业英语试题及答案

检验专业英语试题及答案

检验专业英语试题及答案一、选择题(每题2分,共20分)1. Which of the following is not a routine test in clinical laboratory?A. Blood countB. Urine analysisC. Liver function testD. DNA sequencing2. The term "hemoglobin" refers to:A. A type of proteinB. A type of enzymeC. A type of hormoneD. A type of lipid3. What is the primary function of the enzyme amylase?A. To break down proteinsB. To break down carbohydratesC. To break down fatsD. To break down nucleic acids4. The process of identifying the presence of a specific microorganism in a sample is known as:A. CulturingB. IsolationC. IdentificationD. Quantification5. Which of the following is a common method for measuring the concentration of glucose in blood?A. SpectrophotometryB. ChromatographyC. ElectrophoresisD. Enzymatic assay6. The term "ELISA" stands for:A. Enzyme-Linked Immunosorbent AssayB. Electrophoresis-Linked Immunosorbent AssayC. Enzyme-Linked Immunofluorescence AssayD. Electrophoresis-Linked Immunofluorescence Assay7. In medical diagnostics, what does "PCR" refer to?A. Polymerase Chain ReactionB. Protein Chain ReactionC. Particle Count ReactionD. Pathogen Characterization Reaction8. The process of measuring the amount of a specific substance in a sample is known as:A. TitrationB. CalibrationC. QuantificationD. Qualification9. Which of the following is a common type of clinical specimen?A. BloodB. SoilC. HairD. Water10. The term "antibodies" refers to:A. Proteins that recognize and bind to specific antigensB. Substances that neutralize toxinsC. Hormones that regulate immune responseD. Cells that produce immune responses二、填空题(每空1分,共10分)1. The process of separating molecules based on their size is known as __________.2. In clinical chemistry, the term "assay" refers to a__________ method.3. The unit of measurement for pH is __________.4. A common method for detecting the presence of antibodies in a sample is the __________ test.5. The process of identifying the type of bacteria in a sample is known as __________.6. The process of separating DNA fragments based on their size is known as __________.7. The term "ELISA" is used in __________ to detect the presence of specific antibodies or antigens.8. The process of identifying the genetic makeup of an organism is known as __________.9. The process of measuring the amount of a substance in a sample using a specific wavelength of light is called__________.10. The process of identifying the presence of specific microorganisms in a sample is known as __________.三、简答题(每题5分,共20分)1. Describe the principle of the Enzyme-Linked Immunosorbent Assay (ELISA).2. Explain the importance of maintaining aseptic technique ina clinical laboratory.3. What are the steps involved in performing a blood count?4. Discuss the role of antibodies in the immune response.四、论述题(每题15分,共30分)1. Compare and contrast the methods of Chromatography and Electrophoresis in terms of their applications in clinical diagnostics.2. Discuss the ethical considerations in the use of genetic testing for medical purposes.五、翻译题(每题5分,共10分)1. 将以下句子从中文翻译成英文:在临床实验室中,酶联免疫吸附测定法是一种常用的检测特定抗体或抗原的方法。

宁波2024年统编版小学第六次英语第二单元测验卷(有答案)

宁波2024年统编版小学第六次英语第二单元测验卷(有答案)

宁波2024年统编版小学英语第二单元测验卷(有答案)考试时间:100分钟(总分:110)B卷考试人:_________题号一二三四五总分得分一、综合题(共计100题)1、填空题:An ant is very ______ (勤劳) and works hard.2、What do we call the study of viruses and bacteria?A. VirologyB. MicrobiologyC. PathologyD. Immunology3、填空题:My family loves to go on ________ (短途旅行).4、填空题:I want to learn how to ________ (做健身操).5、听力题:Chemical reactions often require a change in ________ to occur.6、What do you call a young otter?A. PupB. KitC. CalfD. Cub7、填空题:The cardinal is a bright red ________________ (鸟).8、听力题:A __________ can affect human development.9、What do we call an animal that can live both on land and in water?A. ReptileB. MammalC. AmphibianD. Fish10、What do you call the study of the Earth's physical features?A. GeographyB. AstronomyC. BiologyD. Ecology答案:A11、听力题:A ______ is a way to present scientific information clearly.12、听力题:The chemical formula for caffeine is ________.13、听力题:I see a __ in the house. (cat)14、填空题:A butterfly flutters softly in the _______ enjoying the sunshine.15、选择题:Which planet is closest to the sun?A. MercuryB. VenusC. EarthD. Mars16、填空题:The parrot can _________ words. (模仿)17、What do we call a person who repairs shoes?A. CobblerB. TailorC. BlacksmithD. Mechanic18、听力题:The Sun is at the center of our ______.19、What do you put on a salad?A. SyrupB. DressingC. ButterD. Jam答案:B20、填空题:古代的________ (rituals) 在宗教活动中非常重要。

化学专英试题及答案

化学专英试题及答案

化学专英试题及答案一、选择题(每题2分,共10分)1. The term "stoichiometry" refers to the:A. Study of chemical reactionsB. Calculation of amounts of reactants and products in chemical reactionsC. History of chemistryD. Physical properties of substances2. Which of the following is not a state of matter?A. SolidB. LiquidC. GasD. Energy3. The SI unit for the amount of substance is the:A. CoulombB. JouleC. MoleD. Newton4. In the periodic table, elements are arranged in order of increasing:A. Atomic massB. Atomic numberC. ElectronegativityD. Ionization energy5. The process of converting a solid to a liquid is called:A. SublimationB. VaporizationC. MeltingD. Decomposition二、填空题(每空1分,共10分)1. The chemical symbol for the element oxygen is ________.2. The law that states that the volume of a gas is directly proportional to the number of molecules is known as________'s law.3. The process of a substance changing from a liquid to a solid is called ________.4. The pH scale ranges from ________ to ________, with 7 being neutral.5. A compound that releases hydrogen ions when dissolved in water is known as an ________.三、简答题(每题5分,共20分)1. Explain what is meant by the term "valency" in chemistry.2. Describe the difference between a physical change and a chemical change.3. What is the significance of the Avogadro's number in chemistry?4. Discuss the role of catalysts in chemical reactions.四、计算题(每题10分,共20分)1. If 5 moles of a gas occupy 22.4 liters at standard temperature and pressure (STP), calculate the volume occupied by 10 moles of the same gas at STP.2. A 1.5 M solution of hydrochloric acid (HCl) is mixed witha 3.0 M solution of sodium hydroxide (NaOH) in a 1:1 volume ratio. Calculate the molarity of the resulting solution.五、实验题(每题15分,共30分)1. Describe a laboratory procedure to test for the presence of chloride ions in a solution.2. Outline the steps to prepare a standard solution of potassium permanganate (KMnO4) for titration.答案:一、选择题1. B2. D3. C4. B5. C二、填空题1. O2. Boyle3. Solidification4. 0, 145. Acid三、简答题1. Valency refers to the combining power of an element, which is the number of hydrogen atoms it can combine with or replace in a chemical reaction.2. A physical change is a change in the state or form of a substance without altering its chemical composition, while a chemical change involves a transformation that results in theformation of new substances.3. Avogadro's number (6.022 x 10^23) is significant becauseit represents the number of particles (atoms, molecules, ions, etc.) in one mole of a substance.4. Catalysts are substances that increase the rate of a chemical reaction without being consumed in the process, thus facilitating the reaction without altering the overall chemical equilibrium.四、计算题1. 44.8 liters2. 0.75 M五、实验题1. To test for chloride ions, add a small amount of silver nitrate solution to the test solution. If a white precipitate forms, it indicates the presence of chloride ions.2. To prepare a standard solution of KMnO4, dissolve a known mass of the compound in a minimal amount of distilled water, then dilute it to a known volume in a volumetric flask. The concentration can be calculated using the mass and volume of the solution.。

分子生物学基因工程生物化学复习题

分子生物学基因工程生物化学复习题

1、蛋白质分子(多肽链)的方向性(即:N末端和C末端)是如何确定的?答:由肽键决定即通过氨基酸NH2和氨基酸COOH的脱水缩合,形成了N末端在左,C末端在右2、什么是多肽链的肽平面?什么是二面角?答:肽平面:肽键具有一定程度的双键性质,参与肽键的六个原子C、H、O、N、C1、C2不能自由转动,位于同一平面。

二面角:一个碳原子相连的两个肽平面,由于N1—C1和C1—C2(羧基碳)两个键为单键。

肽平面可以分别围绕这两个键旋转,从而构成不同的构象。

3、维持蛋白质分子的三级结构有哪几种力?次级键包括哪几种?答:二硫键、(氢键疏水性相互作用力、离子键、范德法力。

)第二小题4、如何将蛋白质变性?如何复性?答:加热、加乙醇等有机溶剂、强酸、强碱、重金属离子及生物碱试剂等;去除上述因素,若变性程度较轻即可复性。

5、伴侣分子有哪两种类型?其功能如何?答:分子伴侣和伴侣蛋白;辅助新生肽链折叠的,催化对形成功能所必需的共价键盘变化6、人热休克蛋白在新生蛋白质折叠过程的作用是什么?答:辅助新生肽链正确折叠7、膜蛋白分为哪两种类型?它们各通过何种化学键与膜相结合?答;外周膜蛋白和内在膜蛋白。

1)共价键2)疏水性相互作用力8、疯牛病得病因是什么?蛋白质构象发生改变而凝集使其由可溶性变成不可溶性。

9、蛋白质翻译后需要进行哪些形式的加工才能具有活性?肽键N末端甲硫氨酸残基的切除,蛋白质前体的酶切修饰以及氨基残基侧链基团的化学修饰。

10、胃和胰腺分泌的消化蛋白酶的酶原如何加工才能具有活性?酶切加工11、什么是蛋白质的可逆磷酸化?蛋白质的磷酸化和去磷酸化分别由蛋白激酶和蛋白磷酸酶催化完成。

12、什么是蛋白质的靶向输送?靶向输送的蛋白质的N端通常有何序列?定向动送送执行功能的目的地的过程;信号肽13、何谓‘信号肽’?其结构特点是什么?信号肽:分泌蛋白新生肽段N端的一段能被细胞转动系统识别的特征性的序列。

特点:该序列约为16~30个氨基酸残基分为N端碱性区、疏水核心区及加工区三个区段,紧接其后的是被信号肽酶裂解的点。

国际葡萄与葡萄酒组织(OIV)的全套酿酒法规以及检验标准_2008-Vol1

国际葡萄与葡萄酒组织(OIV)的全套酿酒法规以及检验标准_2008-Vol1
ORGANISATION INTERNATIONALE DE LA VIGNE ET DU VIN
COMPENDIUM OF INTERNATIONAL MÉTHODS OF WINE AND MUST ANALYSIS
EDITION 2008
VOLUME 1
INCLUDED : Resolutions adopted in Budapest (Hungary) 5th A.G. – 15 June 2007
MA-E-INT-00-TABMAT 2008
1
COMPENDIUM OF INTERNATIONAL METHODS OF ANALYSIS-OIV Table of contents
Table of contents........................................................MA-E-INT-00-TABMAT VOLUME 1 Foreword ..................................................................MA-E-INT-01-AVPROP Layout and wording of OIV method of analysis ...............MA-E-INT-04-REDMET ANNEX A – METHODS OF ANALYSIS OF WINES AND MUSTS SECTION 1 – DEFINITIONS AND GENERAL PRINCIPLES General remarks ........................................................MA-E-AS1-02-REMGEN Classification of analytical methods (oeno 9/2000) .........MA-E-AS1-03-CLASMA Matrix effect for metals content analysis (oeno 5/2000) ............................................................MA-E-AS1-04-EFFMAT SECTION 2 – PHYSICAL ANALYSIS Density and Specific Gravity at 20oC (A 1).....................MA-E-AS2-01-MASVOL Evaluation by refractometry of the sugar concentration in grape musts, concentrated grape musts and rectified concentrated grape musts................MA-E-AS2-02-SUCREF Total dry matter (A 3)..................................................MA-E-AS2-03-EXTSEC Ash (A 6)...................................................................MA-E-AS2-04-CENDRE Alkalinity of Ash (A 7)..................................................MA-E-AS2-05-ALCCEN Oxidation-reduction potential (oeno 3/2000)...................MA-E-AS2-06-POTOXY Wine turbidity (oeno 4/2000)........................................MA-E-AS2-08-TURBID Method for isotopic ratio 18O/16O (Oeno 2/96)...............MA-E-AS2-09-MOUO18 Folin-Ciocalteu Index ..................................................MA-E-AS2-10-INDFOL Chromatic Characteristics (Oeno 1/2006) ......................MA-E-AS2-11-CARCHR SECTION 3 – CHIMICAL ANALYSIS SECTION 3.1 – ORGANIC COMPOUNDS SECTION 3.1.1 – SUGARS Reducing sugars (A 4) ................................................MA-E-AS311-01-SUCRED Glucose and fructose (enzymatic method) .....................MA-E-AS311-02-GLUFRU Dosage of sugars by HPLC (Oeno 23/2003) ..................MA-E-AS311-03-SUCRES Stabilisation of musts to detect Addition of sucrose (A 5) .............................................MA-E-AS311-04-STAMOU Detecting enrichment of musts, concentrat ed grape musts, rectified concentrated grape musts and wine by ²H-RMN.........................................MA-E-AS311-05-ENRRMN Polyols derived from sugars (Oeno 9/2006) ...................MA-F-AS311-06-POLYOL Glucose and fructose (pHmetry ) (Oeno 10/2006)............MA-F-AS311-07-GLCFR2 Glucose, fructose and saccharose (pHmetry ) (Oeno 11/2006)..........................................................MA-F-AS311-08-SACCHA

化学专业英语-马永祥-兰州大学

化学专业英语-马永祥-兰州大学

ContentsTHE ELEMENTS AND THE PERIODIC TABLE01. ......................................................- 3 -THE NONMETAL ELEMENTS02. ..................................................................................- 5 -GROUPS IB AND IIB ELEMENTS03. ............................................................................- 7 -GROUPS IIIB—VIIIB ELEMENTS04. ............................................................................- 9 -INTERHALOGEN AND NOBLE GAS COMPOUNDS05. ...........................................- 11 -06. ....................................- 13 -THE CLASSIFICATION OF INORGANIC COMPOUNDSTHE NOMENCLATURE OF INORGANIC COMPOUNDS07. ....................................- 15 -BRONSTED'S AND LEWIS' ACID-BASE CONCEPTS08. ..........................................- 19 -09. ..........................................................................- 22 -THE COORDINATION COMPLEXALKANES10. ..................................................................................................................- 25 -11. .............................................................................- 28 -UNSATURATED COMPOUNDSTHE NOMENCLATURE OF CYCLIC HYDROCARBONS12. ...................................- 30 -SUBSTITUTIVE NOMENCLATURE13. .......................................................................- 33 -14. .......................................................- 37 -THE COMPOUNDS CONTAINING OXYGENPREPARATION OF A CARBOXYLiC ACID BY THE GRIGNARD METHOD15. ..- 39 -THE STRUCTURES OF COVALENT COMPOUNDS16. ............................................- 41 -OXIDATION AND REDUCTION IN ORGANIC CHEMISTRY17. ............................- 44 -SYNTHESIS OF ALCOHOLS AND DESIGN OF ORGANIC SYNTHESIS18. ..........- 47 -ORGANOMETALLICS—METAL π COMPLEXES19. ................................................- 49 -THE ROLE OF PROTECTIVE GROUPS IN ORGANIC SYNTHESIS20. ...................- 52 -ELECTROPHILIC REACTIONS OF AROMATIC COMPOUNDS21. ........................- 54 -POLYMERS22. ................................................................................................................- 57 -ANALYTICAL CHEMISTRY AND PROBLEMS IN SOCIETY23. ............................- 61 -VOLUMETRIC ANALYSIS24. ......................................................................................- 63 -QUALITATIVE ORGANIC ANALYSIS25. ..................................................................- 65 -VAPOR-PHASE CHROMATOGRAPHY26. .................................................................- 67 -INFRARED SPECTROSCOPY27. ..................................................................................- 70 -NUCLEAR MAGNETIC RESONANCE (I)28. ..............................................................- 72 -NUCLEAR MAGNETIC RESONANCE(II)29. ..............................................................- 75 -A MAP OF PHYSICAL CHEMISTRY30. ......................................................................- 77 -THE CHEMICAL THERMODYNAMICS31. ................................................................- 79 -CHEMICAL EQUILIBRIUM AND KINETICS32. ........................................................- 82 -THE RATES OF CHEMICAL REACTIONS33. ............................................................- 85 -NATURE OF THE COLLOIDAL STATE34. .................................................................- 88 -ELECTROCHEMICAL CELLS35. .................................................................................- 90 -BOILING POINTS AND DISTILLATION36. ...............................................................- 93 -EXTRACTIVE AND AZEOTROPIC DISTILLATION37. ............................................- 96 -CRYSTALLIZATION38. ................................................................................................- 98 -39. ...................................................................................- 100 -MATERIAL ACCOUNTINGTHE LITERATURE MATRIX OF CHEMISTRY40. ...................................................- 102 -01. THE ELEMENTS AND THE PERIODIC TABLEThe number of protons in the nucleus of an atom is referred to as the atomic number, or proton number, Z. The number of electrons in an electrically neutral atom is also equal to the atomic number, Z. The total mass of an atom is determined very nearly by the total number of protons and neutrons in its nucleus. This total is called the mass number, A. The number of neutrons in an atom, the neutron number, is given by the quantity A-Z.The term element refers to, a pure substance with atoms all of a single kind. To the chemist the "kind" of atom is specified by its atomic number, since this is the property that determines its chemical behavior. At present all the atoms from Z = 1 to Z = 107 are known; there are 107 chemical elements. Each chemical element has been given a name and a distinctive symbol. For most elements the symbol is simply the abbreviated form of the English name consisting of one or two letters, for example:oxygen==O nitrogen ==N neon==Ne magnesium ==MgSome elements,which have been known for a long time,have symbols based on their Latin names, for example: iron==Fe(ferrum) copper==Cu(cuprum) lead==Pb(plumbum)A complete listing of the elements may be found in Table 1.Beginning in the late seventeenth century with the work of Robert Boyle, who proposed the presently accepted concept of an element, numerous investigations produced a considerable knowledge of the properties of elements and their compounds1. In 1869, D.Mendeleev and L. Meyer, working independently, proposed the periodic law. In modern form, the law states that the properties of the elements are periodic functions of their atomic numbers. In other words, when the elements are listed in order of increasing atomic number, elements having closely similar properties will fall at definite intervals along the list. Thus it is possible to arrange the list of elements in tabular form with elements having similar properties placed in vertical columns2. Such an arrangement is called a periodic Each horizontal row of elements constitutes a period. It should be noted that the lengths of the periods vary. There is a very short period containing only 2 elements, followed by two short periods of 8 elements each, and then two long periods of 18 elements each. The next period includes 32 elements, and the last period is apparently incomplete. With this arrangement, elements in the same vertical column have similar characteristics. These columns constitute the chemical families or groups. The groups headed by the members of the two 8-element periods are designated as main group elements, and the members of the other groups are called transition or inner transition elements.In the periodic table, a heavy stepped line divides the elements into metals and nonmetals. Elements to the left of this line (with the exception of hydrogen) are metals, while those to the right are nonmetals. This division is for convenience only; elements bordering the line—the metalloids-have properties characteristic of - both metals and nonmetals. It may be seen that most of the elements, including all the transition and inner transition elements, are metals.Except for hydrogen, a gas, the elements of group IA make up the alkali metal family. They are very reactive metals, and they are never found in the elemental state in nature. However, their compounds are widespread. All the members of the alkali metal family, form ions having a charge of 1+ only. In contrast, the elements of group IB —copper, silver, and gold—are comparatively inert. They are similar to the alkali metals in that they exist as 1+ ions in many of their compounds. However, as is characteristic of most transition elements, they form ions having other charges as well.The elements of group IIA are known as the alkaline earth metals. Their characteristic ionic charge is 2+. These metals, particularly the last two members of the group, are almost as reactive as the alkali metals. The group IIB elements—zinc, cadmium, and mercury are less reactive than are those of group II A5, but are more reactive than the neighboring elements of group IB. The characteristic charge on their ions is also 2+.With the exception of boron, group IIIA elements are also fairly reactive metals. Aluminum appears to be inert toward reaction with air, but this behavior stems from the fact that the metal forms a thin, invisible film of aluminum oxide on the surface, which protects the bulk of the metal from further oxidation. The metals of group IIIA form ions of 3+ charge. Group IIIB consists of the metals scandium, yttrium, lanthanum, and actinium.Group IVA consists of a nonmetal, carbon, two metalloids, silicon and germanium, and two metals, tin and lead. Each of these elements forms some compounds with formulas which indicate that four other atoms are present per group IVA atom, as, for example, carbon tetrachloride, GCl4. The group IVB metals —titanium, zirconium, and hafnium —also forms compounds in which each group IVB atom is combined with four other atoms; these compounds are nonelectrolytes when pure.The elements of group V A include three nonmetals — nitrogen, phosphorus, and arsenic—and two metals — antimony and bismuth. Although compounds with the formulas N2O5, PCl5, and AsCl5 exist, none of them is ionic. These elements do form compounds-nitrides, phosphides, and arsenides — in which ions having charges of minus three occur. The elements of group VB are all metals. These elements form such a variety of different compounds that their characteristics are not easily generalized.With the exception of polonium, the elements of group VIA are typical nonmetals. They are sometimes known, as the, chalcogens, from the Greek word meaning "ash formers". In their binary compounds with metals they exist as ions having a charge of 2-. The elements of group ⅦA are all nonmetals and are known as the halogens. from the Greek term meaning "salt formers.” They are the most reactive nonmetals and are capable of reacting with practically all the metals and with most nonmetals, including each other.The elements of groups ⅥB, ⅦB, and VIIIB are all metals. They form such a wide Variety of compounds that it is not practical at this point to present any examples as being typical of the behavior of the respective groups.The periodicity of chemical behavior is illustrated by the fact that. excluding the first period, each period begins with a very reactive metal. Successive element along the period show decreasing metallic character, eventually becoming nonmetals, and finally, in group ⅦA, a very reactive nonmetal is found. Each period ends with a member of the noble gas family.02. THE NONMETAL ELEMENTSWe noted earlier. that -nonmetals exhibit properties that are greatly different from those of the metals. As a rule, the nonmetals are poor conductors of electricity (graphitic carbon is an exception) and heat; they are brittle, are often intensely colored, and show an unusually wide range of melting and boiling points. Their molecular structures, usually involving ordinary covalent bonds, vary from the simple diatomic molecules of H2, Cl2, I2, and N2 to the giant molecules of diamond, silicon and boron.The nonmetals that are gases at room temperature are the low-molecular weight diatomic molecules and the noble gases that exert very small intermolecular forces. As the molecular weight increases, we encounter a liquid (Br2) and a solid (I2) whose vapor pressures also indicate small intermolecular forces. Certain properties of a few nonmetals are listed in Table 2.Table 2- Molecular Weights and Melting Points of Certain NonmetalsDiatomic Molecules MolecularWeightMelting Point°CColorH22-239.1'NoneN228-210NoneF238-223Pale yellowO232-218Pale blueCl271-102Yellow — greenBr2160-7.3Red — brownI2254113Gray—blackSimple diatomic molecules are not formed by the heavier members of Groups V and VI at ordinary conditions. This is in direct contrast to the first members of these groups, N2 and O2. The difference arises because of the lower stability of πbonds formed from p orbitals of the third and higher main energy levels as opposed to the second main energy level2. The larger atomic radii and more dense electron clouds of elements of the third period and higher do not allow good parallel overlap of p orbitals necessary for a strong πbond. This is a general phenomenon — strong π bonds are formed only between elements of the second period. Thus, elemental nitrogen and oxygen form stable molecules with both σand π bonds, but other members of their groups form more stable structures based on σbonds only at ordinary conditions. Note3 that Group VII elements form diatomic molecules, but πbonds are not required for saturation of valence.Sulfur exhibits allotropic forms. Solid sulfur exists in two crystalline forms and in an amorphous form. Rhombic sulfur is obtained by crystallization from a suitable solution, such as CS2, and it melts at 112°C. Monoclinic sulfur is formed by cooling melted sulfur and it melts at 119°C. Both forms of crystalline sulfur melt into S-gamma, which is composed of S8 molecules. The S8 molecules are puckered rings and survive heating to about 160°C. Above 160°C, the S8 rings break open, and some of these fragments combine with each other to form a highly viscous mixture of irregularly shaped coils. At a range of higher temperatures the liquid sulfur becomes so viscous that it will not pourfrom its container. The color also changes from straw yellow at sulfur's melting point to a deep reddish-brown as it becomes more viscous.As4 the boiling point of 444 °C is approached, the large-coiled molecules of sulfur are partially degraded and the liquid sulfur decreases in viscosity. If the hot liquid sulfur is quenched by pouring it into cold water, the amorphous form of sulfur is produced. The structure of amorphous sulfur consists of large-coiled helices with eight sulfur atoms to each turn of the helix; the overall nature of amorphous sulfur is described as3 rubbery because it stretches much like ordinary rubber. In a few hours the amorphous sulfur reverts to small rhombic crystals and its rubbery property disappears.Sulfur, an important raw material in industrial chemistry, occurs as the free element, as SO2 in volcanic regions, asH2S in mineral waters, and in a variety of sulfide ores such as iron pyrite FeS2, zinc blende ZnS, galena PbS and such, and in common formations of gypsum CaSO4 • 2H2O, anhydrite CaSO4, and barytes BaSO4 • 2H2O. Sulfur, in one form or another, is used in large quantities for making sulfuric acid, fertilizers, insecticides, and paper.Sulfur in the form of SO2 obtained in the roasting of sulfide ores is recovered and converted to sulfuric acid, although in previous years much of this SO2 was discarded through exceptionally tall smokestacks. Fortunately, it is now economically favorable to recover these gases, thus greatly reducing this type of atmospheric pollution. A typical roasting reaction involves the change:2 ZnS +3 O2—2 ZnO + 2 SO2Phosphorus, below 800℃ consists of tetratomic molecules, P4. Its molecular structure provides for a covalence of three, as may be expected from the three unpaired p electrons in its atomic structure, and each atom is attached to three others6. Instead of a strictly orthogonal orientation, with the three bonds 90° to each other, the bond angles are only 60°. This supposedly strained structure is stabilized by the mutual interaction of the four atoms (each atom is bonded to the other three), but it is chemically the most active form of phosphorus. This form of phosphorus, the white modification, is spontaneously combustible in air. When heated to 260°C it changes to red phosphorus, whose structure is obscure. Red phosphorus is stable in air but, like all forms of phosphorus, it should be handled carefully because of its tendency to migrate to the bones when ingested, resulting in serious physiological damage.Elemental carbon exists in one of two crystalline structures — diamond and graphite. The diamond structure, based on tetrahedral bonding of hybridized sp3orbitals, is encountered among Group IV elements. We may expect that as the bond length increases, the hardness of the diamond-type crystal decreases. Although the tetrahedral structure persists among the elements in this group — carbon, silicon, germanium, and gray tin — the interatomic distances increase from 1.54 A for carbon to 2.80 A for gray tin. Consequently .the bond strengths among the four elements range from very strong to quite weak. In fact, gray tin is so soft that it exists in the form of microcrystals or merely as a powder. Typical of the Group IV diamond-type crystalline elements, it is a nonconductor and shows other nonmetallic properties7.03. GROUPS IB AND IIB ELEMENTSPhysical properties of Group IB and IIBThese elements have a greater bulk use as metals than in compounds, and their physical properties vary widely.Gold is the most malleable and ductile of the metals. It can be hammered into sheets of 0.00001 inch in thickness; one gram of the metal can be drawn into a wire 1.8 mi in length1. Copper and silver are also metals that are mechanically easy to work. Zinc is a little brittle at ordinary temperatures, but may be rolled into sheets at between 120° to 150℃; it becomes brittle again about 200℃-The low-melting temperatures of zinc contribute to the preparation of zinc-coated iron .galvanized iron; clean iron sheet may be dipped into vats of liquid zinc in its preparation. A different procedure is to sprinkle or air blast zinc dust onto hot iron sheeting for a zinc melt and then coating.Cadmium has specific uses because of its low-melting temperature in a number of alloys. Cadmium rods are used in nuclear reactors because the metal is a good neutron absorber.Mercury vapor and its salts are poisonous, though the free metal may be taken internally under certain conditions. Because of its relatively low boiling point and hence volatile nature, free mercury should never be allowed to stand in an open container in the laboratory. Evidence shows that inhalation of its vapors is injurious.The metal alloys readily with most of the metals (except iron and platinum) to form amalgams, the name given to any alloy of mercury.Copper sulfate, or blue vitriol (CuSO4 • 5H2O) is the most important and widely used salt of copper. On heating, the salt slowly loses water to form first the trihydrate (CuSO4 • 3H z O), then the monohydrate (CuSO4 • H2O), and finally the white anhydrous salt. The anhydrous salt is often used to test for the presence of water in organic liquids. For example, some of the anhydrous copper salt added to alcohol (which contains water) will turn blue because of the hydration of the salt.Copper sulfate is used in electroplating. Fishermen dip their nets in copper sulfate solution to inhibit the growth of organisms that would rot the fabric. Paints specifically formulated for use on the bottoms of marine craft contain copper compounds to inhibit the growth of barnacles and other organisms.When dilute ammonium hydroxide is added" to a solution of copper (I) ions, a greenish precipitate of Cu(OH)2 or a basic copper(I) salt is formed. This dissolves as more ammonium hydroxide is added. The excess ammonia forms an ammoniated complex with the copper (I) ion of the composition, Cu(NH3)42+. This ion is only slightly dissociated; hence in an ammoniacal solution very few copper (I) ions are present. Insoluble copper compounds, execpt copper sulfide, are dissolved by ammonium hydroxids. The formation of the copper (I) ammonia ion is often used as a test for Cu2+ because of its deep, intense blue color.Copper (I) ferrocyanide [Cu2Fe(CN)6] is obtained as a reddish-brown precipitate on the addition of a soluble ferrocyanide to a solution of copper ( I )ions. The formation of this salt is also used as a test for the presence of copper (I) ions.Compounds of Silver and GoldSilver nitrate, sometimes called lunar caustic, is the most important salt of silver. It melts readily and may be cast into sticks for use in cauterizing wounds. The salt is prepared by dissolving silver in nitric acid and evaporating the solution.3Ag + 4HNO3—3AgNO3 + NO + 2H2OThe salt is the starting material for most of the compounds of silver, including the halides used in photography. It is readily reduced by organic reducing agents, with the formation of a black deposit of finely divided silver; this action is responsible for black spots left on the fingers from the handling of the salt. Indelible marking inks and pencils take advantage of this property of silver nitrate.The halides of silver, except the fluoride, are very insoluble compounds and may be precipitated by the addition of a solution of silver salt to a solution containing chloride, bromide, or iodide ions.The addition of a strong base to a solution of a silver salt precipitates brown silver oxide (Ag2G). One might expect the hydroxide of silver to precipitate, but it seems likely that silver hydroxide is very unstable and breaks down into the oxide and water — if, indeed, it is ever formed at all3. However, since a solution of silver oxide js definitely basic, there must be hydroxide ions present in solution.Ag2O + H2O = 2Ag+ + 2OH-Because of its inactivity, gold forms relatively few compounds. Two series of compounds are known — monovalent and trivalent. Monovalent (aurous) compounds resemble silver compounds (aurous chloride is water insoluble and light sensitive), while the higher valence (auric) compounds tend to form complexes. Gold is resistant to the action of most chemicals —air, oxygen, and water have no effect. The common acids do not attack the metal, but a mixture of hydrochloric and nitric acids (aqua regia) dissolves it to form gold( I ) chloride or chloroauric acid. The action is probably due to free chlorine present in the aqua regia.3HCl + HNO3----→ NOCl+Cl2 + 2H2O2Au + 3Cl2 ----→ 2AuCl3AuCl3+HCl----→ HAuCl4chloroauric acid (HAuCl4-H2O crystallizes from solution).Compounds of ZincZinc is fairly high in the activity series. It reacts readily with acids to produce hydrogen and displaces less active metals from their salts. 1 he action of acids on impure zinc is much more rapid than on pure zinc, since bubbles of hydrogen gas collect on the surface of pure zinc and slow down the action. If another metal is present as an impurity, the hydrogen is liberated from the surface of the contaminating metal rather than from the zinc. An electric couple to facilitate the action is probably Set up between the two metals.Zn + 2H+----→ Zn2+ + H2Zinc oxide (ZnO), the most widely used zinc compound, is a white powder at ordinary temperatures, but changes to yellow on heating. When cooled, it again becomes white. Zinc oxide is obtained by burning zinc in air, by heating the basic carbonate, or by roasting the sulfide. The principal use of ZnO is as a filler in rubber manufacture, particularly in automobile tires. As a body for paints it has the advantage over white lead of not darkening on exposure to an atmosphere containing hydrogen sulfide. Its covering power, however, is inferior to that of white lead.04. GROUPS IIIB—VIIIB ELEMENTSGroup I-B includes the elements scandium, yttrium, lanthanum, and actinium1, and the two rare-earth series of fourteen elements each2 —the lanthanide and actinide series. The principal source of these elements is the high gravity river and beach sands built up by a water-sorting process during long periods of geologic time. Monazite sand, which contains a mixture of rare earth phosphates, and an yttrium silicate in a heavy sand are now commercial sources of a number of these scarce elements.Separation of the elements is a difficult chemical operation. The solubilities of their compounds are so nearly alike that a separation by fractional crystallization is laborious and time-consuming. In recent years, ion exchange resins in high columns have proved effective. When certain acids are allowed to flow down slowly through a column containing a resin to which ions of Group III B metals are adsorbed, ions are successively released from the resin3. The resulting solution is removed from the bottom of the column or tower in bands or sections. Successive sections will contain specific ions in the order of release by the resin. For example .lanthanum ion (La3+) is most tightly held to the resin and is the last to be extracted, lutetium ion (Lu3+) is less tightly held and appears in one of the first sections removed. If the solutions are recycled and the acid concentrations carefully controlled, very effective separations can be accomplished. Quantities of all the lanthanide series (except promethium, Pm, which does not exist in nature as a stable isotope) are produced for the chemical market.The predominant group oxidation number of the lanthanide series is +3, but some of the elements exhibit variable oxidation states. Cerium forms cerium( III )and cerium ( IV ) sulfates, Ce2 (SO4 )3 and Ce(SO4 )2, which are employed in certain oxidation-reduction titrations. Many rare earth compounds are colored and are paramagnetic, presumably as a result of unpaired electrons in the 4f orbitals.All actinide elements have unstable nuclei and exhibit radioactivity. Those with higher atomic numbers have been obtained only in trace amounts. Actinium (89 Ac), like lanthanum, is a regular Group IIIB element.Group IVB ElementsIn chemical properties these elements resemble silicon, but they become increasingly more metallic from titanium to hafnium. The predominant oxidation state is +4 and, as with silica (SiO2), the oxides of these elements occur naturally in small amounts. The formulas and mineral names of the oxides are TiO2, rutile; ZrO2, zirconia; HfO2, hafnia. Titanium is more abundant than is usually realized. It comprises about 0.44%of the earth's crust. It is over 5.0%in average composition of first analyzed moon rock. Zirconium and titanium oxides occur in small percentages in beach sands.Titanium and zirconium metals are prepared by heating their chlorides with magnesium metal. Both are particularly resistant to corrosion and have high melting points.Pure TiO2 is a very white substance which is taking the place of white lead in many paints. Three-fourths of the TiO2 is used in white paints, varnishes, and lacquers. It has the highest index of refraction (2.76) and the greatest hiding power of all the common white paint materials. TiO2 also is used in the paper, rubber, linoleum, leather, and textile industries.Group VB Elements: Vanadium, Niobium, and TantalumThese are transition elements of Group VB, with a predominant oxidation number of + 5. Their occurrence iscomparatively rare.These metals combine directly with oxygen, chlorine, and nitrogen to form oxides, chlorides, and nitrides, respectively. A small percentage of vanadium alloyed with steel gives a high tensile strength product which is very tough and resistant to shock and vibration. For this reason vanadium alloy steels are used in the manufacture ofhigh-speed tools and heavy machinery. Vanadium oxide is employed as a catalyst in the contact process of manufacturing sulfuric acid. Niobium is a very rare element, with limited use as an alloying element in stainless steel. Tantalum has a very high melting point (2850 C) and is resistant to corrosion by most acids and alkalies.Groups VIB and VIIB ElementsChromium, molybdenum, and tungsten are Group VIB elements. Manganese is the only chemically important element of Group VIIB. All these elements exhibit several oxidation states, acting as metallic elements in lower oxidation states and as nonmetallic elements in higher oxidation states. Both chromium and manganese are widely used in alloys, particularly in alloy steels.Group VIIIB MetalsGroup VIIIB contains the three triads of elements. These triads appear at the middle of long periods of elements in the periodic table, and are members of the transition series. The elements of any given horizontal triad have many similar properties, but there are marked differences between the properties of the triads, particularly between the first triad and the other two. Iron, cobalt, and nickel are much more active than members of the other two triads, and are also much more abundant in the earth's crust. Metals of the second and third triads, with many common properties, are usually grouped together and called the platinum metals.These elements all exhibit variable oxidation states and form numerous coordination compounds.CorrosionIron exposed to the action of moist air rusts rapidly, with the formation of a loose, crumbly deposit of the oxide. The oxide does not adhere to the surface of the metal, as does aluminum oxide and certain other metal oxides, but peelsoff .exposing a fresh surface of iron to the action of the air. As a result, a piece of iron will rust away completely in a relatively short time unless steps are taken to prevent the corrosion. The chemical steps in rusting are rather obscure, but it has been established that the rust is a hydrated oxide of iron, formed by the action of both oxygen and moisture, and is markedly speeded up by the presence of minute amounts of carbon dioxide5.Corrosion of iron is inhibited by coating it with numerous substances, such as paint, an aluminum powder gilt, tin, or organic tarry substances or by galvanizing iron with zinc. Alloying iron with metals such as nickel or chromium yields a less corrosive steel. "Cathodic protection" of iron for lessened corrosion is also practiced. For some pipelines and standpipes zinc or magnesium rods in the ground with a wire connecting them to an iron object have the following effect: with soil moisture acting as an electrolyte for a Fe — Zn couple the Fe is lessened in its tendency to become Fe2+. It acts as a cathode rather than an anode.。

mitotracker染色操作流程曹海燕

mitotracker染色操作流程曹海燕

Mitotracker染色实验操作流程1. 将细胞种植在confocal 专用DISH里,密度为2×104;37℃培养,24-36h等细胞完全贴壁后染色。

2. 准备好无血清培养基、移液器、枪头、避光盒等需要仪器;3. 将mitotracker染色试剂用无血清培养基按1:5000的比例稀释,DAPI试剂(罗氏公司)用无血清培养基按1:1000比例稀释,然后放37℃孵箱里预热10min。

4. 移去DISH里的培养基,加少量无血清培养基冲洗三次,去除残余含血清的培养基;5. 每个DISH钟加入500ul预热的染色液,放37℃孵箱里孵育20-25min(避光操作)。

6. 加入DAPI染色液,500ul/dish,室温避光孵育10min。

7. 移去染色液,加入少量无血清培养基冲洗三次,最后加入500-1000ul无血清培养基孵育细胞,准备用激光共聚焦显微镜拍照。

注:整个染色过程都要注意避光,避免荧光淬灭,影响染色效果。

Mito-Tracker Green ( 线粒体绿色荧光探针)产品简介Mito-Tracker Green 是一种线粒体(mitochondria)绿色荧光探针,可以用于活细胞线粒体特异性荧光染色。

Mito-Tracker Green为采用MolecularProbes公司的carbocyanine进行了荧光标记的一种Mito-Tracker,分子量为671.88,可以用作线粒体特异性的荧光探针。

和rhodamine123或JC-1相比,Mito-Tracker Green对于线粒体的染色不依赖于线粒体膜电位。

Mito-Tracker Green可以用于对活细胞的染色,但染色后如果固定会导致染色消退。

Mito-Tracker Green呈绿色荧光,检测时的最大激发波长为490nm,最大发射波长为516nm。

按最终工作浓度为20-200nM计算,可以配制约370-3700ml Mito-Tracker Green工作液。

黄河中游土壤侵蚀时空变化及驱动因素

黄河中游土壤侵蚀时空变化及驱动因素

第30卷第5期2023年10月水土保持研究R e s e a r c ho f S o i l a n d W a t e rC o n s e r v a t i o nV o l .30,N o .5O c t .,2023收稿日期:2022-06-23 修回日期:2022-07-17资助项目:国家自然科学基金面上项目(41971033);中央高校基本科研业务费专项资金资助(300102291507) 第一作者:张艳(1978 ),女,河北沧州人,博士,副教授,主要研究方向为土地信息系统与土地利用规划㊂E -m a i l :z y z h a n g ya n @c h d .e d u .c n h t t p :ʊs tbc y j .p a p e r o n c e .o r gD O I :10.13869/j.c n k i .r s w c .2023.05.003.张艳,史飞航,张悦,等.黄河中游土壤侵蚀时空变化及驱动因素[J ].水土保持研究,2023,30(5):1-12.Z H A N G Y a n ,S H IF e i h a n g ,Z HA N G Y u e ,e t a l .T e m p o r a l a n dS p a t i a l C h a n g e s a n dD r i v i n g F a c t o r s o f S o i l E r o s i o n i n t h eM i d d l eR e a c h e s o f t h e Y e l l o w R i v e r [J ].R e s e a r c ho f S o i l a n d W a t e rC o n s e r v a t i o n ,2023,30(5):1-12.黄河中游土壤侵蚀时空变化及驱动因素张艳1,2,史飞航1,张悦1,李敏1,崔国屹1,刘正则1(1.长安大学土地工程学院,西安710054;2.陕西省土地整治重点实验室,西安710054)摘 要:[目的]揭示流域生态工程措施和自然因素对土壤侵蚀演变的影响效应,量化工程因子和水文因子对水土流失的抑制程度,为黄土高原区流域土壤侵蚀综合防治和生态环境质量改善研究提供参考㊂[方法]基于黄河中游地区77个气象站点降雨数据以及流域内四期土地利用类型㊁植被覆盖度㊁数字高程模型㊁土壤质地等资料,通过提取流域降水㊁地形㊁气候㊁土壤和土地利用等因子,采用R U S E L 模型和地理探测器方法,开展了土壤侵蚀时空变化及驱动因素研究㊂[结果]黄河中游地区2000 2010年侵蚀减幅最显著,在生态工程影响下,海拔1000~1500m ,8ʎ~15ʎ,半阳坡和半阴坡的土壤流失量减少最剧烈;水土流失治理成效表现为林地>草地>耕地,且植被覆盖度30%~50%区间内侵蚀面积变化最剧烈,为退耕还林工程重点恢复重建区㊂黄河中游多年间降雨呈西北向东南逐渐增加,在地形影响下空间垂直差异会发生变化,年际间呈不显著波动上升趋势,具有加剧土壤侵蚀的潜在条件㊂植被覆盖度呈线性波动上升的趋势,增量从西北到东南呈递增趋势,植被覆盖度是影响土壤侵蚀的主控因素;黄河中游植被覆盖度与坡度的交互作用影响力最强,且植被覆盖度㊁坡度与其他因子协同作用可以显著性增强对土壤侵蚀格局演变的作用力㊂[结论]黄河中游以微度侵蚀为主,多出现在植被发育良好的低海拔地带,中度以上侵蚀出现在黄土高原腹地的粗沙多沙区;黄河中游长期呈农牧为主体的土地利用格局,多年间坡度较陡的耕地不断流向对地形适应性和弹性较高的林草地,反映了国家退耕工程核心一部分是将坡耕地变为林㊁草地;黄河中游以植被覆盖变化为主要特征的生态工程主导了土壤侵蚀量下降的过程和程度,且任意两种因子交互作用的驱动力均大于单个因子㊂关键词:土壤侵蚀;R U S E L 模型;地理探测器;时空变化;黄河中游中图分类号:S 157 文献标识码:A 文章编号:1005-3409(2023)05-0001-12T e m p o r a l a n dS p a t i a l C h a n g e s a n dD r i v i n g Fa c t o r s o f S o i l E r o s i o n i n t h e M i d d l eR e a c h e s o f t h eY e l l o wR i v e rZ H A N G Y a n 1,2,S H IF e i h a n g 1,Z H A N G Y u e 1,L IM i n 1,C U IG u o y i 1,L I UZ h e n gz e 1(1.S c h o o l o f L a n dE n g i n e e r i n g ,C h a n g 'a nU n i v e r s i t y ,X i 'a n 710054,C h i n a ;2.S h a a n x iK e y L a b o r a t o r y o f L a n dR e c l a m a t i o nE n g i n e e r i n g ,X i 'a n 710054,C h i n a )A b s t r a c t :[O b j e c t i v e ]I no r d e r t o p r o v i d e a r e f e r e n c e f o r t h e t h o r o u ghc o n t r o l o fw a t e r s h e ds o i l e r o s i o na n d t h e i m p r o v e m e n to fe c o l o g i c a le n v i r o n m e n t q u a l i t y i nt h eL o e s sP l a t e a ur e g i o n ,t h ee f f e c t so fe c o l o g i c a l e n g i n e e r i n g m e a s u r e s a n dn a t u r a l f a c t o r s o ns o i l e r o s i o ne v o l u t i o nw e r e r e v e a l e d ,a n d t h e i n h i b i t i o nd e g r e e s o f e n g i n e e r i n g f a c t o r sa n dh y d r o l o g i c a l f a c t o r so ns o i le r o s i o n w e r e q u a n t i f i e d .[M e t h o d s ]B a s e do nt h e r a i n f a l l d a t ao f 77m e t e o r o l o g i c a l s t a t i o n s i nt h em i d d l e r e a c h e so f t h eY e l l o w R i v e r ,l a n du s e t y p e s ,v e ge t a t i o n c o v e r a g e ,d i g i t a l e l e v a t i o nm o d e l ,s o i l t e x t u r e a n d o t h e r d a t a of f o u r p e r i o d s i n t h e b a s i n ,t h eR U S E L m o d e l a n dg e o g r a phi cd e t e c t o r m e t h o d w e r eu s e dt os t u d y t h es p a t i o t e m p o r a l c h a n g e sa n dd r i v i n g f a c t o r so f s o i l e r o s i o nb y e x t r a c t i n gp r e c i p i t a t i o n ,t o p o g r a p h y,c l i m a t e ,s o i la n dl a n du s ei nt h eb a s i n .[R e s u l t s ]T h e l a r ge s t r e d u c t i o ni ns e d i m e n te r o s i o ni nt h e Y e l l o w R i v e r 's m i d d l es e c t i o n sb e t w e e n2000a n d2010w a s Copyright ©博看网. All Rights Reserved.o b s e r v e d.S o i l l o s s s i g n i f i c a n t l y r e d u c e d d u e t o e c o l o g i c a l e n g i n e e r i n g a t a l t i t u d e s b e t w e e n1000a n d1500m, a t s l o p e g r a d i e n t sb e t w e e n8ʎa n d15ʎ,a n do nh i l l s i d e st h a tw e r eb o t hs e m i-s h a d e da n ds e m i-s u n n y.T h e c a p a c i t y o f s o i l a n dw a t e r l o s s c o n t r o l d e c r e a s e d i n t h e o r d e r:f o r e s t l a n d>g r a s s l a n d>c u l t i v a t e d l a n d,a n d t h e e r o s i o na r e a c h a n g e dm o s t d r a m a t i c a l l y i n t h e r a n g eo f30%~50%v e g e t a t i o nc o v e r a g e,w h i c hw a s t h ek e y r e s t o r a t i o na n dr e c o n s t r u c t i o na r e ao f t h e p r o j e c t o f c o n v e r t i n g f a r m l a n d t o f o r e s t.I n t h em i d d l e r e a c h e so f t h eY e l l o w R i v e r,r a i n f a l l i n c r e a s e d g r a d u a l l y f r o m n o r t h w e s t t os o u t h e a s to v e r t h e y e a r s,a n dt h es p a t i a l v e r t i c a ld i f f e r e n c ec h a n g e su n d e rt h ei n f l u e n c eo ft o p o g r a p h y,a n dt h ei n t e r a n n u a lf l u c t u a t i o ni n c r e a s e d i n s i g n i f i c a n t l y,w h i c hh a d t h e p o t e n t i a l t o a g g r a v a t e s o i l e r o s i o n.V e g e t a t i o n c o v e r a g e i n c r e a s e d l i n e a r l y,a n d i t s i n c r e m e n t i n c r e a s e df r o m n o r t h w e s t t os o u t h e a s t.V e g e t a t i o nc o v e r a g ew a st h e m a i nc o n t r o l l i n g f a c t o r a f f e c t i n g s o i l e r o s i o n.I n t h em i d d l eY e l l o w R i v e r,t h e i n t e r a c t i o nb e t w e e nv e g e t a t i o n c o v e r a g e a n d t h e s l o p e w a st h e s t r o n g e s t,a n d t h e s y n e r g i s t i c e f f e c t s o f v e g e t a t i o n c o v e r a g e,s l o p e a n d o t h e rf a c t o r s c o u l d s i g n i f i c a n t l y e n h a n c e t h e f o r c eo ns o i l e r o s i o n p a t t e r ne v o l u t i o n.[C o n c l u s i o n]I nt h em i d d l e r e a c h e so f t h e Y e l l o w R i v e r,t h e l a n du s e p a t t e r nw a s d o m i n a t e db y a g r i c u l t u r e a n d a n i m a l h u s b a n d r y f o r a l o n g t i m e,a n d t h e c u l t i v a t e d l a n dw i t hs t e e p s l o p e s f l o w e dc o n t i n u o u s l y t o t h e f o r e s t a n d g r a s s l a n dw i t hh i g ht o p o g r a p h i c a d a p t a b i l i t y a n de l a s t i c i t y o v e r t h e y e a r s,r e f l e c t i n g t h a t t h ec o r e p a r to f t h en a t i o n a l f a r m l a n dc o n v e r s i o n p r o j e c t i s t o c o n v e r t s l o p i n g l a n d i n t o f o r e s t a n d g r a s s l a n d.T h e e c o l o g i c a l e n g i n e e r i n g m a i n l y c h a r a c t e r i z e d b y v e g e t a t i o n c o v e rc h a n g ed o m i n a t e dt h e p r o c e s sa n dd e g r e eo fs o i le r o s i o nr e d u c t i o ni nt h e m i d d l e Y e l l o w R i v e r,a n d t h e d r i v i n g f o r c e o f t h e i n t e r a c t i o no f a n y t w o f a c t o r sw a s g r e a t e r t h a n t h a t o f a s i n g l e f a c t o r. K e y w o r d s:s o i l e r o s i o n;R U S E L m o d e l;g e o g r a p h i cd e t e c t o r;t e m p o r a l a n ds p a t i a l v a r i a t i o n;m i d d l e r e a c h e s o f t h eY e l l o w R i v e r20世纪以来水土流失问题一直都是全球学者研究土地变化的重要课题之一㊂土壤侵蚀是人类活动和自然因素两者共同作用下的一种土地退化现象,严重的水土流失不仅造成土地生产力降低,时刻威胁着流域农业生产,且流失所汇聚的泥沙和污染物对生态系统和社会经济发展也带来严重影响,同时会导致中下游湖库阻塞㊁旱涝灾害加剧等问题[1-2]㊂在此背景下,防治土壤侵蚀㊁修复河道沙土淤积,改善林草退化㊁构建优质生态环境,实现人与自然和谐相处等,早已成为全球各国政府亟需解决的艰巨任务㊂黄河流经黄土高原,特殊的土质和气候水文等使其流域成为我国土壤侵蚀最为严重和密集的地区,尤其是黄河中游近乎都属于黄土高原区,其自然因素影响和人为活动的不合理干扰,使流域范围内土壤侵蚀状况异常剧烈[3-4]㊂我国在黄河中游已开展了一系列生态保护工程,使其经历了气候水文变化和土地利用/覆盖格局变化等为主要特征的自然因素和人为因素的协同效应,从而引起地区水土流失产沙过程和程度发生改变,土壤侵蚀不断下降,生态系统服务显著提升,中下游泥沙淤积情况稳定改善等[5]㊂修正通用土壤流失方程(R e v i s e dU n i v e r s a l S o i l L o s sE q u a t i o n)可以高精度模拟黄土高原水土流失情况[6]㊂众多学者将R U S E L模型实际应用到黄河流域境内的众多小区域㊁次降雨尺度模型土壤侵蚀研究[7-10],但较少学者将模型用到大尺度㊁长序列的水土流失模拟预测㊂基于此以黄河中游为研究区,利用降雨㊁D E M㊁土壤和土地利用/覆被等数据集,采用G I S㊁水文统计㊁R U S L E模型㊁地理探测器等方法,综合探究黄河中游退耕前后降雨㊁土地利用等时空变化,阐明不同年份土壤侵蚀时空变化及驱动因素,量化生态退耕工程和降雨变化等因子对水土流失的抑制程度,为黄土高原水土流失防治研究和生态环境质量改善提供参考㊂1研究区概况黄河中游地区为内蒙古自治区河口镇至河南省三门峡流域片,属于大陆性季风气候区,冬季寒冷,夏季炎热,西部以西北风为主,南部秦岭北侧为南风,年均温介于8~14ħ,年最高温可达42.8ħ,年最低温可达-28.1ħ,年均降水量约为520.45mm㊂境内众多地区被黄土厚厚覆盖,其土壤相对疏松且多孔,具有良好的渗透性,极易发生水土流失[11]㊂境内主要河流有渭河㊁北洛河㊁汾河及支流㊂地貌类型复杂,以黄土塬㊁梁㊁峁为主沟壑纵横,地形多变[12]㊂2数据与方法2.1数据来源与数据预处理(1)土地利用数据㊂1990年㊁2000年㊁2010年㊁2水土保持研究第30卷Copyright©博看网. All Rights Reserved.2020年四期空间分辨率为30m的土地利用数据下载于中国科学院资源环境科学数据中心㊂(2)数字高程模型为地理空间数据云平台下载的分辨率30m的A S T E R G D E M数据,用于获取黄河中游地形(坡度㊁坡向㊁高程)特征数据㊂(3)气象水文数据下载于中国气象科学数据共享服务网的 中国地面气候资料日值数据集 ㊂黄河中游及周边地区1981 2020年共77个气象观测站点及日值降雨量数据,空间分布特征如图1所示㊂(4)土壤质地数据利用寒区旱区科学数据中心的中国1ʒ100万土壤数据库㊂(5)遥感数据下载于美国国家航天航空局E O S/ MO D I S卫星的MO D13Q1v006数据产品(h t t p s:ʊl p d a a c.u s g s.g o v/)㊂图1黄河中游地区示意图2.2研究方法2.2.1 R U S L E模型为确保数据准确性,需全部转换为相同坐标系进行空间运算㊂采用R U S L E模型[6,10]对黄河中游土壤侵蚀模拟分析,表达式为:A=R㊃K㊃L S㊃C㊃P式中:A为单位面积土壤侵蚀模数 t/(h m2㊃a) ;R为降雨侵蚀力因子 M J㊃mm/(h m2㊃h㊃a) ;K为土壤可蚀性因子 t㊃h m2㊃h/(h m2㊃M J㊃mm) ;L S为坡长坡度因子;C为地表植被覆盖与管理因子;P为水土保持措施因子㊂(1)降雨侵蚀力因子(R)㊂关于计算降雨的侵蚀性,众多学者提出了不同背景下的降雨侵蚀力算法模型[13]㊂本文选取谢云降雨侵蚀力模型[14]研究黄河中游降雨侵蚀力情况,公式如下:R i=αðki=1(P d )1.7265式中:R i为一年中第i个半月的降雨侵蚀力;i=1, 2, ,k是半个月内侵蚀降雨的天数;P d为ȡ100 mm的日降雨量㊂在谢云模型中考虑到两天内发生的单个降雨事件可能记录为两个日降雨量,我们将降雨的阈值定义为10mm[13-14],避免了对降雨侵蚀力的低估㊂同时对于该模型各气象站的参数α经过不断实际验证,分别在温暖季节(5月至9月)设置为0.3937,在寒冷季节(10月至4月)设置为0.3101㊂(2)土壤可蚀性因子(K)㊂土壤可蚀性为标准小区内单位降雨侵蚀力引起土壤流失率㊂以土壤质地数据为基础采用E P I C模型进行计算土壤可蚀性[15]㊂公式如下:K=0.13170.2+0.3e x p-0.0256S A N1-S I L100æèçöø÷{}ˑS I LC L A+S L Aæèçöø÷0.3ˑ1-0.25CC+e x p3.72-2.95C()ˑ1-0.7S NS N+e x p22.95N-5.51()式中:S A N,S I L,C L A和C为砂粒㊁粉粒㊁黏粒和有机碳含量,其中S N=1-S A N/100㊂(3)地形因子(L S)㊂在土壤流失方程中,地形是诱导土壤侵蚀发生的重要因素,采用刘宝元在C S L E模型中提出的地形因子算法,带入符素华教授团队开发的土壤侵蚀模型地形因子计算工具(2.0版本)进行地形因子的计算[16]:L S=LˑSL=λ22.13æèçöø÷mm=B B+1B=s i nθ3s i nθ0.8+0.563第5期张艳等:黄河中游土壤侵蚀时空变化及驱动因素Copyright©博看网. All Rights Reserved.S =10.8ˑs i n θ+0.036 θ<6ʎ16.8ˑs i n θ-0.5 6ʎɤθ<15ʎ21.9ˑs i n θ-0.96 θȡ15ʎìîíïïïï式中:λ为坡长(m );m ,B 为变换常量;θ为坡度百分比值(%)㊂(4)植被覆盖因子(C )㊂植被覆盖与管理因子可以反映植被情况对水土流失的具体效应,介于0~1,当C =0时,表示没发生土壤侵蚀,当C =1时,对侵蚀没有起到抑制作用,参考蔡崇法等提出的C 因子计算[17]:C =1 F V C =00.6508-0.3436l g(F V C ) 0<F V C <78.3%0 F V C ȡ78.3%ìîíïïïïF V C =N D V I -N D V I s o i lN D V I m a x -N D V s o i l式中:F V C 为植被覆盖度;N D V I s o i l 为纯裸土像元的N D V I 值;N D V I m a x 纯植被像元的ND V I 值㊂(5)水土保持措施因子(P )㊂水土保持措施因子为一系列工程实施后与顺坡种植时的土壤流失量的比值㊂本文水土保持措施因子的取值结合黄河中游实际情况并参照前人研究[18-21]对不同土地利用进行赋值见表1㊂表1 不同土地利用类型下水土保持措施因子土地利用类型坡度P林地1草地1水域0建设用地0未利用地10ʎ~5ʎ0.1005ʎ~10ʎ0.221耕地10ʎ~15ʎ0.30515ʎ~20ʎ0.57520ʎ~25ʎ0.705>25ʎ0.8002.2.2 土壤侵蚀演变影响因素研究方法(1)降雨因素研究㊂基于黄河中游各站点降雨等数据集,利用地统计分析结合相关参数分别对反距离加权,径向基函数和克里金模型进行优化,并对每个模型的最佳预测结果进行交叉比较,根据地统计精度分析结果,前两者模拟预测结果的均方误差均大于克里金插值结果,同时克里金模型预测结果的绝对误差更小,且误差和的平均值更接近于零,整体比较克里金模型模拟效果以及各项误差指标均优于反距离加权和径向基函数,因此本文选择克里金模型插值作为降雨空间插值的主要方法㊂M a n n -K e n d a l l 秩相关检验方法被广泛应用于水文和气象学的研究[22]㊂通过使用数据序列的顺序而不是实际值来判断两个变量之间的相关程度,可以避免最大或最小值的干扰,同时还可以客观地实现长期数据序列的变化趋势,计算如下:S =ðn -1k =1ðnj =k +1s g n (x j -x i k )s g n (x j -x i k )=1 x j -x i k >00 x j -x i k =01 x j -x i k <0ìîíïïïï式中:n 为时间序列的长度;x j 和x i k 为时间序列中的时间变量值;s g n 是一个符号函数,在确定时间序列数据变化的趋势显著性时,M -K 检验的主要参数有趋势的显著性水平(Z )和趋势的斜率(S );Z 表示变量的趋势是否明显;S 表示趋势的方向和程度㊂当S 的平均值等于零,且方差接近正态分布时,零假设是不可接受的㊂方差计算如下:v a r (S )=118n (n -1)(2n +5)-ðqp =1t p (t p -1)(2t p +5)式中:q 表示具有相同时间序列变量值的集合数;t p 表示集中的p t h 数据数㊂统计量Z 可按如下式计算:Z =S -1v a r (S ) S >00 S =0S +1va r (S ) S <0ìîíïïïïïï如果Z 为正,则时间序列呈单调上升趋势,为负值,则时间序列呈单调下降趋势㊂显著性水平为0.01,0.05,0.10的Z 的绝对临界值分别为2.576,1.960,1.645,表示置信度90%,95%和99%的显著性检验㊂(2)土地利用/覆被因素研究㊂土地利用转移矩阵描述不同土地利用的结构和数量在不同时相下空间位置的改变[23]㊂计算如下: M i j =M 11M 12 M 1n M 21M 22M 2n ︙︙︙︙M n 1M n 2M n n式中:M 代表类型面积;n 为转移前㊁后的类型的总数;i ,j 为转移前㊁后的类型情况㊂土地利用地形位优势度分析㊂地形位指数用来衡量研究区的地形梯度,能更加精细地分析土地利用空间格局与地形梯度的变化关系[24]㊂ T =l g (H H ʎ+1)ˑ(SS ʎ+1)式中:T 代表地形位指数;H ,H ʎ为流域范围内空间上任一位置的海拔值和该位置所在区域内的平均高4 水土保持研究 第30卷Copyright ©博看网. All Rights Reserved.程值;S ,S ʎ为流域范围内空间上任一位置的坡度值和该位置所在区域内的平均坡度值㊂海拔越低㊁坡度越小的位置,相应T 越小;反之越大㊂(3)主导因子贡献率研究方法㊂依据R U S L E模型,将退耕还林工程变化和降雨变化作为土壤侵蚀的影响项分析两者的贡献率[25]㊂ U 1=βR 1ˑβG 1ˑβK L S U 2=βR 2ˑβG 2ˑβK L SΔU T =U 2-U 1式中:U 1,U 2为退耕还林工程前㊁后年均土壤侵蚀量;ΔU T 为工程前㊁后土壤侵蚀变化量;βR 1,βR 2为工程前㊁后降雨侵蚀力因子影响项;βG 1,βG 2为工程前㊁后植被管理因子和水土保持措施因子影响项;βK L S 表征为其他因素影响项㊂U '2=βR 2ˑβG 1ˑβK L SΔU G =U 2-U '2C G =(ΔU G /ΔU T )ˑ100%C R =1-C G式中:U '2为假设工程后植被管理因子和水土保持措施因子影响程度和工程实施前相同情况下的土壤侵蚀量;ΔU G 为工程实施引起的土壤侵蚀变化量;C G ,C R 为工程的实施和降雨变化对土壤侵蚀的贡献率㊂(4)地理探测器模型原理与应用㊂地理探测器用于检验土壤侵蚀空间分异性及揭示土壤侵蚀动态变化的驱动因素贡献情况,其由风险因子探测㊁交互作用探测㊁生态探测㊁风险区探测4个部分组成㊂风险因子探测用来探测因变量的空间分异性以及自变量对特定因变量的解释力,一般用q 衡量其大小;交互作用可以探测两变量间的交互作用,通过对比单变量及双变量的解释力大小可判断双因子间交互作用的方向及方式;生态探测可比较影响因子对土壤侵蚀空间分布的影响是否有显著差异;风险探测器可判断影响因子的层间土壤侵蚀量是否有显著差别,并识别土壤侵蚀高风险区域[26]㊂ q =1-ðLh =1N σ2N σ2=1-S S WS S T式中:h =1,2, ,L ,L 为因变量或自变量的分区;N h 和N 分别为层h 和全区的数据单元数;σh 2和σ2分别是层h 和全区因变量的方差;S S W 为层内方差之和;S S T 为全区总方差㊂探测器驱动因子的解释力q 值越大,则因变量的空间分异性越显著㊂采用地理探测器探索土壤侵蚀空间分异性的驱动因素㊂鉴于因变量土壤侵蚀(Y )和自变量因素(X )在空间统计尺度上存在显著差异,基于王劲峰[25]提出的数据离散化方法,将土地利用(X 1)㊁植被覆盖度(X 2)㊁坡度(X 3)㊁降雨量(X 4)㊁海拔(X 5)㊁土壤类型(X 6)和土壤侵蚀强度(Y )分别离散化,其中土地利用和土壤类型基于其数据类别离散化分级㊁植被覆盖度依据F V Cɤ30%,30%~40%,40%~50%,50%~60%,60%~70%,70%~80%,80%~90%,90%~100%离散化为8级,坡度依据ɤ5ʎ,5ʎ~10ʎ,10ʎ~15ʎ,15ʎ~20ʎ,20ʎ~25ʎ,25ʎ~30ʎ,30ʎ~35ʎ,ȡ35ʎ离散化为8级,降雨量和海拔采用G I S 中自然断点离散化为9级㊂3 结果与分析3.1 土壤侵蚀时空变化鉴于降雨因素具有较大偶然性,将研究期年降雨侵蚀力每10a 间隔计算平均降雨侵蚀力,带入R U -S E L 模型模拟预测土壤侵蚀情况,并依据土壤侵蚀强度分类标准对模拟的土壤侵蚀模数分级㊂依据国家水利部门土壤侵蚀分类分级标准S L 190-2007(表2),对研究区模拟的土壤侵蚀模数进行强度等级划分㊂表2 土壤侵蚀强度分级强度等级土壤侵蚀模数/(t ㊃k m -2㊃a-1)微度<1000轻度1000~2500中度2500~5000强烈5000~8000极强烈8000~15000剧烈>150003.1.1 土壤侵蚀强度时空演变特征 1990年㊁2000年㊁2010年㊁2020年黄河中游平均土壤侵蚀模数为4760.27,6735.52,3006.65,1390.71t /(k m 2㊃a ),呈先升高后急剧下降,整体土壤侵蚀强度为中度㊁强烈㊁中度和轻度侵蚀㊂1990年㊁2010年㊁2020年微度侵蚀占比均大于50%㊂2000年为研究期内侵蚀较严重的年份,剧烈和极强烈侵蚀占比为16.19%和11.08%,经过20a 退耕还林等生态工程建设,剧烈和极强烈侵蚀占比降低到1.42%和3.56%㊂黄河中游以微度侵蚀为主,分布在植被发育良好的低海拔地带,中度以上的侵蚀情况主要发生在黄土高原腹地的粗沙多沙区(表3)㊂基于多年间土壤侵蚀变化情况,黄河中游侵蚀强度不变㊁减轻和加剧面积占比为57.02%,42.00%和0.98%㊂侵蚀状况减轻主要由轻度㊁中度㊁强烈㊁极强烈和剧烈转为微度㊁中度转为轻度㊁极强烈转为中度和剧烈转为极强烈等转移类型引起的㊂侵蚀强度不变大部分源于微度侵蚀的稳定保持,侵蚀加剧出现5第5期 张艳等:黄河中游土壤侵蚀时空变化及驱动因素Copyright ©博看网. All Rights Reserved.在轻度转为中度㊂侵蚀减轻主要集中在延安㊁榆林北㊁庆阳㊁固原㊁天水㊁定西㊁忻州等中游西部黄河干流沿线等地区,侵蚀不变集中在中游东南部植被覆盖度较高的地区,而侵蚀加剧体现在榆林东南部的黄河干线地区,这与榆林为陕西第二大粮仓,需更多耕地资源密切相关㊂侵蚀强度演变情况显著验证了黄土高原多年来大规模实施一系列生态工程取得的巨大成效(图2)㊂表31990-2020年土壤侵蚀强度分级统计侵蚀级别Ⅰ1990面积/k m2比例/%Ⅱ2000面积/k m2比例/%Ⅲ2010面积/k m2比例/%Ⅳ2020面积/k m2比例/%10年动态度/%1990 20002000 20102010 20201990 2020微度156955.8151.97135743.2644.95181218.5860.01231944.1376.80-13.5133.5027.9947.78轻度33345.5811.0434520.8611.4333056.3910.9524940.838.263.52-4.24-24.55-25.21中度26811.088.8828473.279.4327444.409.0918524.406.136.20-3.61-32.50-30.91强烈21149.207.0020910.336.9220897.516.9111555.543.83-1.13-0.06-44.70-45.36极强烈31692.1710.4933455.7711.0824953.408.2610757.893.565.56-25.41-56.89-66.06剧烈32046.1610.6148896.5116.1914429.724.784277.211.4252.58-70.49-70.36-86.65图2黄河中游土壤侵蚀强度空间分布及转移3.1.2不同地形下土壤侵蚀分布格局变化规律黄河中游不同地貌下微度侵蚀面积占比均最高,1000~ 1500m阶段是微度侵蚀面积占比增加了14.16%,其是水土流失防治中的重点区域;黄河中游多年间半阳坡和半阴坡土壤侵蚀变化情况最剧烈;不同坡度下黄河中游土壤侵蚀情况各异,8ʎ~15ʎ土壤侵蚀以微㊁轻和中度侵蚀为主,15ʎ~25ʎ剧烈和极强烈侵蚀为主,25ʎ以上剧烈侵蚀占比最大㊂2000 2010年随着国家生态工程实施,在土壤侵蚀大规模锐减的趋势下,微度侵蚀在8ʎ~15ʎ坡度带内增加最为显著;2010 2020年不同坡度下的土壤侵蚀变化整体态势良好,8ʎ~25ʎ坡度带内侵蚀锐减最明显,相较于工程实施前,极强烈和剧烈侵蚀治理情况成效最大,反映了该区实施的生态修复工程的精准防治,也为黄土高原生态进一步建设奠定良好基础㊂3.1.3不同土地利用下土壤侵蚀分布特征基于黄河中游主要地类影响下的土壤侵蚀模拟情况,耕㊁林和草地平均土壤侵蚀模数差异较大,土壤侵蚀模数表现为草地>耕地>林地,草地略大于耕地,主要与草地分布基数广,低覆盖度草地面积占比高,草地分布坡度高,缺少人工措施保护密切相关㊂黄河中游1990 2020年耕地土壤侵蚀模数减小率高达72.10%,侵蚀强度由中度转为轻度;林地侵蚀强度由轻度转为微度,土壤侵蚀模数减小率为70.52%,封山育林政策是防治水土流失中关键措施;草地侵蚀强度由强烈转为轻度,平均土壤侵蚀模数减小率为70.52%,其作为面积分布最广的地类,是最可能受人为影响的水土流失加剧因素,侵蚀变化对水土流失治理至关重要,分析发现草地整体上土壤侵蚀模数减少最多,因此继续退耕还草工程的实施对土壤侵蚀的治理最为关键的㊂黄河中游植被覆盖度30%~50%范围内土壤侵6水土保持研究第30卷Copyright©博看网. All Rights Reserved.蚀变化最剧烈,其是生态工程重点恢复重建的植被覆盖带㊂在国家推行植被育林造草等生态工程后,植被处于高速生长期,侵蚀强度降低集中在极强烈和剧烈侵蚀级别上,70%~100%的植被覆盖度区间的面积实现了翻倍增加,在高植被覆盖度下,林草地结构良好,且群落层次丰富,其多层结构保持水土的效益得到显著体现,工程实施后优良植被显著增加㊂综上黄河中游耕㊁林和草地等主要地类的水土流失治理成效表现为林地>草地>耕地,充分证明了国家在近几十年来在黄土高原大力推行的退耕还林还草㊁封山育林及山水林田湖草等生态建设工程取得了显著成效㊂3.2土壤侵蚀时空变化影响因素研究在影响土壤侵蚀变化的众多因素中,地形和土壤相对稳定,而降雨㊁土地利用和植被覆盖度是控制侵蚀变化的主导因素㊂3.2.1降雨因素影响土壤侵蚀演变分析降雨到达一定程度将会造成水土流失,我们一般将侵蚀性降雨特征即降雨侵蚀力作为量化计算降雨对土壤侵蚀作用力的重要函数[26],因此分析降雨变化对于研究土壤侵蚀演变具有重要意义㊂黄河中游年均降雨量为520.45mm,最大年降雨量为699.90mm(2003年),最小年降雨量为349.90 mm(1997年),多年间降雨量呈多峰状波动上升的变化特征,年际间波动较大,基于M-K检验多年间降雨没有明显的降雨突变现象,且总体趋势性特征不显著㊂空间上年降雨量空间差异显著,呈自南到北递减趋势,以佛坪㊁留坝㊁商南和太白等为代表的秦岭北部盆地山区的降雨量最大,表明这些地区存在降雨侵蚀威胁的解释力较强;中游北部黄土高原丘陵区的降雨量较少,降雨侵蚀的威胁较小,而中游南部盆地东西两侧的降雨侵蚀威胁也存在显著差异(图3)㊂多年间降雨量的增加代表着降雨侵蚀力的增加,这也就意味着潜在的土壤侵蚀风险增加,在黄河中游降雨侵蚀性增加的地区,应采取适当措施,减少土壤侵蚀的潜在风险,对维护流域内生态安全具有重要意义㊂图3黄河中游年均降水量空间分布格局3.2.2土地利用/植被覆盖因素影响土壤侵蚀演变分析黄河中游1990 2020年维持了长期农牧为主体的土地利用格局,1990年耕㊁草地占比为39.97%和37.00%,林草覆盖率为53.84%,2020年耕㊁草地占比为36.93%和37.87%,林草植被覆盖率增加到55.38%㊂各地类变化特征为耕地㊁未利用地和水域缩减,林地㊁草地和建设用地增加,证明了多年间土壤侵蚀锐减源自退耕还林(草)植被重建工程的实施成果(图4)㊂黄河中游1990 2000年土地利用转移基本相对稳定,空间上耕㊁林地无显著变化特征,西北农牧交错带区草地转移剧烈,侵蚀略微加剧;2000 2010年呈耕地流向林㊁草地和建设用地,草地流向林地的特征,林地空间格局变化显著,集中在黄土高原西北部退耕还林重点区域,这也是侵蚀减轻最为显著的地区;2010 2020年占比70.04%的耕地流出到林地,呈现耕地减少林地增加,但空间分布特征比较零碎,草地维持了相对稳定,侵蚀状况继续减轻㊂黄河中游林㊁草地多年间在西北部退耕还林生态工程实施区域内变化最为剧烈,生态工程对土壤侵蚀抑制效果极显著(表4)㊂注:其他部分指建设用地㊁未利用地和水域之间的转移情况㊂图41990-2020年耕㊁林㊁草地空间流转变化7第5期张艳等:黄河中游土壤侵蚀时空变化及驱动因素Copyright©博看网. All Rights Reserved.表4 1990-2020年土地利用结构格局演变参数地类1990年面积/万k m 2比例/%2000年面积/万k m 2比例/%2010年面积/万k m 2比例/%2020年面积/万k m 2比例/%10年变化率/%1990 20002000 20102010 20201990 2020耕地12.0739.9712.0940.0211.3837.6811.1536.930.13-5.86-1.99-7.61林地5.0916.855.0816.815.3117.575.2917.51-0.184.49-0.343.94草地11.1736.1011.2337.1711.4637.9511.4437.870.482.08-0.212.35水域0.311.020.300.990.280.910.280.92-2.31-8.260.44-9.99建设用地0.622.070.692.291.0083.321.284.2210.9244.8727.22104.43未利用地0.943.100.872.700.782.580.772.56-12.86-4.74-0.78-17.64土地利用分布局限于地形特征,根据水土流失调查中高程㊁坡度和坡向等地形要素分级标准,可知耕㊁林和草地集中在1000~1500m 高程带;耕地集中在斜坡(8ʎ~15ʎ),林草地集中在陡坡(15ʎ~25ʎ);30a 间耕地在海拔1500m ㊁斜坡和陡坡下退耕量最多,2000 2010年退耕量最多,源自该阶段处于国家在黄土高原区大规模实施退耕还林还草等生态工程的黄金期密切相关,同时根据多年间各地类的地形位置优势度分析,我们可发现坡度较陡的耕地不断转移为对地形适应性和弹性最高的林草地,侧面反映了国家退耕工程核心一部分是将坡耕地变为林㊁草地,从而增强对水土流失的防治作用㊂黄河中游多年平均植被覆盖度表现为线性波动上升的特征,2000年前整体上升不明显,之后呈快速增加,表明退耕工程后黄河中游植被重建情况总体良好㊂植被覆盖度增加量呈西北到东南递增,且黄河中游占比78.08%的地区覆盖度出现增加,而减少区仅占比3.59%㊂空间上植被覆盖度呈全域大范围增加,发生在流域的西北地区,这也更好地起到对水土流失的遏制作用㊂对于秦岭两侧及延安等部分区县长期保持良好特征,而关中平原城市群地带(西安㊁宝鸡㊁渭南㊁咸阳)和山西境内的运城㊁太原㊁晋中等城市植被覆盖度下降严重,这与近几十年来西北第一城西安和太原中心城市的高速发展密不可分(图5)㊂图5 黄河中游平均植被覆盖度变化情况3.2.3 土壤侵蚀演变的主导因子贡献率分析 在影响土壤侵蚀的众多因素中,与地形因素和土壤因素不同,降雨和植被在时空上均有较大的变化,是引起特定地区土壤侵蚀的主要因素㊂综合前面影响因素分析,为判断退耕还林工程措施对土壤侵蚀变化的贡献率,将2000年作为实施工程前后的划分标准,来探究主导因子在工程实施前后对土壤侵蚀的影响过程和程度㊂鉴于降雨和植被作为影响土壤侵蚀最为关键的因素,对两因素与侵蚀模数在工程后10a 和20a 探究分析发现㊂表5中5种不同组合类型为面积占比较大的土壤侵蚀变化情况㊂实施工程10a 黄河中游占比61.58%的地区出现植被覆盖度和降雨侵蚀力双增加,而侵蚀模数下降的情况,集中在退耕还林重点区自南向北的流域中心地带;黄河中游占比14.20%的地区呈覆盖度增加,降雨侵蚀力减小,表现在鄂尔多斯㊁榆林北㊁忻州和朔州等北部地区;黄河中游占比15.51%的地区出现降雨侵蚀力和覆盖度双增加,而侵蚀保持较稳定㊂虽降雨侵蚀力增加较多,对水土流失外营力增强,但覆盖度提高对地表的保护作用增强,近地面生长的林草植被具备更好抑制侵蚀的效果(图6)㊂经过20a 生态工程恢复重建,覆盖度和降雨侵蚀力双增加,侵蚀模数减小区占比增加到75.78%,更多耕地转化为林草地,使高覆盖度植被对土壤保护作用增强;侵蚀稳定区占比为16.28%,虽降雨侵蚀力增加较大,但覆盖度提升缓冲了对土壤的破坏,集中在秦岭两侧和覆盖度较稳定的地区;侵蚀增加区占比2.75%,分布在西北部的农牧交错带,这与林草地转为农耕地有关,覆盖度减小,降雨侵蚀力增加引起的侵蚀加剧发生在城市化扩展严重的关中城市群等地㊂基于贡献率计算,工程10a 和20a 后假设降雨侵蚀力无变化的情况下,下垫面变化引起平均侵蚀8 水土保持研究 第30卷Copyright ©博看网. All Rights Reserved.。

桂林2024年03版小学五年级上册G卷英语第3单元期末试卷

桂林2024年03版小学五年级上册G卷英语第3单元期末试卷
19. 填空题: My favorite snack is ______ (薯片).
20. 填空题: I can ______ (跑步) very fast.
21. 填空题: We visit the ______ (艺术中心) to see exhibits.
22. 填空题: I love to create stories with my _________ (玩具车) and _________ (人物).
12. 填空题: We can _______ (一起) plant flowers.
13. 填空题: I believe that everyone should try to _______ (动词) their best in school. It is very _______ (形容词).
25. 填空题: I enjoy cooking new recipes with my _______ (家人). It’s a fun way to bond and try _______ (新事物).
26. 听力题: A hydronium ion is formed when an acid donates a ______.
43. 选择题: How do you say "thank you" in English? A. Sorry B. Please C. Thank you D. Hello 答案:C
44. 听力题: The stars are _______ (shining) brightly.
45. 听力题: The dog is barking ___. (loudly)
37. 听力题: The capital of Portugal is __________.

化学化工专业英语部分练习参考答案

化学化工专业英语部分练习参考答案

化学化工专业英语部分练习参考答案P8.练习答案:(4)I-steel 工字钢;I-shaped I型材;n-region n区p-region p区;T-beam 丁字梁,T型梁P-N-junction P-N结;T-connecting 丁字接头,T形接法A.C.:alternating current 交流电D.C.:direct current 直流电P13.练习答案:一、注意名词单复数的译法1、这台设备已经用了许多年了。

2、空气是各种气体的混合物。

3、许多植物能利用二氧化碳中的氧。

4、带负电荷的机体所含电子数多于质子数。

5、其它蒸发材料(物质)和蒸发过程将简要地加以讨论。

6、这样的一些操作要求物质由气流传递到液体中去。

7、如果不饱和性归因于三键的存在,那么这些化合物都会被称为炔烃。

8、尚未试图在蒸发过程中将蒸汽分馏成各种馏分。

9、许多盐、酸和碱等化合物将被广泛应用于家庭、工业和医药实践中。

10、苯的同系物是那些苯环上含有单烷基(取代一个氢)或多烷基(取代多个氢)的物质。

11、当然,一旦酸失去质子,碱必然接受质子。

因此,酸和碱的反应就是一种质子转移的反应。

这种反应就是我们通常所知的中和反应。

12、这篇文章着重讨论一些原料和成品生产技术上最近的发展。

二、注意词义引申的译法1、叔醇非常难以氧化。

2、含1个到4个碳原子的正烷烃是气体。

3、通常,所有的金属都是良导体,其中银的传导性最好,其次是铜。

4.从两种或任意多种溶液中分离溶质都需要蒸馏的分馏技术。

三、注意词的增译及省译1、橡胶能阻止电流通过。

2、过去每到他轮班时就会给车床上油。

3、从这个意义上讲,结构分析普遍应用于大多数的有机研究。

4、过去在电子尚未被发现以前,人们就假定了不可见电流是从正极流向负极。

5、有人看见这些工人在修理发电机。

6、这些植物提取物的功效已经为早期人类所发现。

7、树木之所以幸存是因为其进化已经使它们成为了高度分隔的有机体。

EPA3060A

EPA3060A

CD-ROM 3060A-1Revision 1December 1996METHOD 3060A ALKALINE DIGESTION FOR HEXAVALENT CHROMIUM1.0SCOPE AND APPLICATION1.1Any reference in this method to “Method 3060" refers to this version of that method,and does not refer to previously published versions (e.g., in the Second Edition of this manual).When published as a new method to SW-846, a method’s number does not include a letter suffix.Each time a method is revised and made a part of SW-846 update, it receives a suffix. However,a method reference found within the text of SW-846 methods always refers to the latest version of that method published in SW-846, even if the method number at that location does not include the appropriate letter suffix.1.2Method 3060 is an alkaline digestion procedure for extracting hexavalent chromium[Cr(VI)] from soluble, adsorbed, and precipitated forms of chromium compounds in soils, sludges,sediments, and similar waste materials. To quantify total Cr(VI) in a solid matrix, three criteria must be satisfied: (1) the extracting solution must solubilize all forms of Cr(VI), (2) the conditions of the extraction must not induce reduction of native Cr(VI) to Cr(III), and (3) the method must not cause oxidation of native Cr(III) contained in the sample to Cr(VI). Method 3060 meets these criteria for a wide spectrum of solid matrices. Under the alkaline conditions of the extraction, minimal reduction of Cr(VI) or oxidation of native Cr(III) occurs. The addition of Mg in a phosphate buffer to the 2+alkaline solution has been shown to suppress oxidation, if observed. The accuracy of the extraction procedure is assessed using spike recovery data for soluble and insoluble forms of Cr(VI) (e.g.,K Cr O and PbCrO ), coupled with measurement of ancillary soil properties, indicative of the 227 4potential for the soil to maintain a Cr(VI) spike during digestion, such as oxidation reduction potential (ORP), pH, organic matter content, ferrous iron, and sulfides. Recovery of an insoluble Cr(VI) spike can be used to assess the first two criteria, and method-induced oxidation is usually not observed except in soils high in Mn and amended with soluble Cr(III) salts or freshly precipitated Cr(OH).31.3The quantification of Cr(VI) in Method 3060 digests should be performed using a suitable technique with appropriate accuracy and precision, for example Method 7196(colorimetrically by UV-VIS spectrophotometry) or Method 7199 (colorimetrically by ion chromatography (IC)). Analytical techniques such as IC with inductively coupled plasma - mass spectrometric (ICP-MS) detection, high performance liquid chromatography (HPLC) with ICP-MS detection, capillary electrophoresis (CE) with ICP-MS detection, etc. may be utilized once performance effectiveness has been validated.2.0SUMMARY OF METHOD2.1This method uses an alkaline digestion to solubilize both water-insoluble (with the exception of partial solubility of barium chromate in some soil matrices, see Reference 10.9) and water soluble Cr(VI) compounds in solid waste samples. The pH of the digestate must be carefully adjusted during the digestion procedure. Failure to meet the pH specifications will necessitate redigestion of the samples.2.2The sample is digested using 0.28M Na CO /0.5M NaOH solution and heating at 90-2395E C for 60 minutes to dissolve the Cr(VI) and stabilize it against reduction to Cr(III).CD-ROM3060A-2Revision 1December 19962.3The Cr(VI) reaction with diphenylcarbazide is the most common and reliable method for analysis of Cr(VI) solubilized in the alkaline digestate. The use of diphenylcarbazide has been well established in the colorimetric procedure (Method 7196), in rapid-test field kits, and in the ion chromatographic method for Cr(VI) (Method 7199). It is highly selective for Cr(VI) and few interferences are encountered when it is used on alkaline digestates.2.4For additional information on health and safety issues relating to chromium, refer to References 10.7 and 10.10.3.0INTERFERENCES3.1When analyzing a sample digest for total Cr(VI), it is appropriate to determine the reducing/oxidizing tendency of each sample matrix. This can be accomplished by characterization of each sample for additional analytical parameters, such as pH (Method 9045), ferrous iron (ASTM Method D3872-86), sulfides (Method 9030), and Oxidation Reduction Potential (ORP) (ASTM MethodD 1498-93 - aqueous samples). Method 9045 (Section 7.2 of Method 9045) is referenced as the preparatory method for soil samples. The ORP and temperature probes are inserted directly into the soil slurry. The displayed ORP value is allowed to equilibrate and the resulting measurement is recorded. Other indirect indicators of reducing/oxidizing tendency include Total Organic Carbon (TOC), Chemical Oxygen Demand (COD), and Biological Oxygen Demand (BOD). Analysis of these additional parameters establishes the tendency of Cr(VI) to exist or not exist in the unspiked sample(s) and assists in the interpretation of QC data for matrix spike recoveries outside conventionally accepted criteria for total metals.3.2Certain substances, not typically found in the alkaline digests of soils, may interfere in the analytical methods for Cr(VI) following alkaline extraction if the concentrations of these interfering substances are high and the Cr(VI) concentration is low. Refer to Methods 7196 and 7199 for a discussion of the specific agents that may interfere with Cr(VI) quantification. Analytical techniques that reduce bias caused by co-extracted matrix components may be applicable in correcting these biases after validation of their performance effectiveness.3.3For waste materials or soils containing soluble Cr(III) concentrations greater than four times the laboratory Cr(VI) reporting limit, Cr(VI) results obtained using this method may be biased high due to method-induced oxidation. The addition of Mg in a phosphate buffer to the alkaline 2+extraction solution has been shown to suppress this oxidation. If an analytical method for Cr(VI) is used that can correct for possible method induced oxidation/reduction, then the Mg addition is 2+optional. The presence of soluble Cr(III) can be approximated by extracting the sample with deionized water (ASTM methods D4646-87, D5233-92, or D3987-85) and analyzing the resultant leachate for both Cr(VI) and total Cr. The difference between the two values approximates soluble Cr(III).4.0APPARATUS AND MATERIALS4.1Digestion vessel: borosilicate glass or quartz with a volume of 250 mL.4.2Graduated Cylinder: 100-mL or equivalent.4.3Volumetric Flasks: Class A glassware, 1000-mL and 100-mL, with stoppers orequivalent.CD-ROM 3060A-3Revision 1December 19964.4Vacuum Filtration Apparatus.4.5Filter membranes (0.45 µm). Preferably cellulosic or polycarbonate membranes.When vacuum filtration is performed, operation should be performed with recognitionof the filter membrane breakthrough pressure.4.6Heating Device - capable of maintaining the digestion solution at 90-95E C withcontinuous auto stirring capability or equivalent.4.7Volumetric pipettes: Class A glassware, assorted sizes, as necessary.4.8Calibrated pH meter.4.9Calibrated balance.4.10Temperature measurement device (with NIST traceable calibration) capable ofmeasuring up to 100E C (e.g. thermometer, thermistor, IR sensor, etc.).4.11An automated continuous stirring device (e.g. magnetic stirrer, motorized stirring rod,etc.), one for each digestion being performed.5.0REAGENTS5.1Nitric acid: 5.0 M HNO , analytical reagent grade or spectrograde quality. Store at 320-25E C in the dark. Do not use concentrated HNO to make up 5.0 M solution if it has a yellow 3tinge; this is indicative of photoreduction of NO to NO , a reducing agent for Cr(VI).3 2-5.2Sodium carbonate: Na CO , anhydrous, analytical reagent grade. Store at 20-25E C 23in a tightly sealed container.5.3Sodium hydroxide: NaOH, analytical reagent grade. Store at 20-25E C in a tightly sealed container.5.4Magnesium Chloride: MgCl (anhydrous), analytical reagent grade. A mass of 4002mg MgCl is approximately equivalent to 100 mg Mg . Store at 20-25E C in a tightly sealed 22+container.5.5Phosphate Buffer:5.5.1K HPO : analytical reagent grade.245.5.2KH PO : analytical reagent grade.245.5.30.5M K HPO /0.5M KH PO buffer at pH 7: Dissolve 87.09 K HPO and 68.0424 24 24g KH PO into 700 mL of reagent water. Transfer to a 1L volumetric flask and dilute to 24volume.CD-ROM 3060A-4Revision 1December 19965.6Lead Chromate: PbCrO , analytical reagent grade. The insoluble matrix spike is 4prepared by adding 10-20 mg of PbCrO to a separate sample aliquot. Store under dry conditions 4at 20-25E C in a tightly sealed container.5.7Digestion solution: Dissolve 20.0 ± 0.05 g NaOH and 30.0 ± 0.05 g Na CO in 23reagent water in a one-liter volumetric flask and dilute to the mark. Store the solution in a tightly capped polyethylene bottle at 20-25E C and prepare fresh monthly. The pH of the digestion solution must be checked before using. The pH must be 11.5 or greater, if not, discard.5.8Potassium dichromate, K Cr O , spiking solution (1000 mg/L Cr(VI)): Dissolve 2.829227g of dried (105E C) K Cr O in reagent water in a one-liter volumetric flask and dilute to the mark.227Alternatively, a 1000 mg/L Cr(VI) certified primary standard solution can be used (Fisher AAS standard or equivalent). Store at 20-25E C in a tightly sealed container for use up to six months.5.8.1Matrix spiking solution (100 mg/L Cr(VI)): Add 10.0 mL of the 1000 mgCr(VI)/L made from K Cr O spiking solution (Section 5.8) to a 100 mL volumetric flask and 227dilute to volume with reagent water. Mix well.5.9Reagent Water - Reagent water will be free of interferences. Refer to Chapter One for a definition of reagent water.6.0.SAMPLE COLLECTION, PRESERVATION, AND HANDLING6.1Samples must have been collected using a sampling plan that addresses the considerations discussed in Chapter Nine of this manual.6.2Samples should be collected using devices and placed in containers that do not contain stainless steel (e.g., plastic or glass).6.3Samples should be stored field-moist at 4 ± 2E C until analysis.6.4Hexavalent chromium has been shown to be quantitatively stable in field-moist soil samples for 30 days from sample collection. In addition, Cr(VI) has also been shown to be stable in the alkaline digestate for up to 168 hours after extraction from soil.6.5Hexavalent chromium solutions or waste material that are generated should be disposed of properly. One approach is to treat all Cr(VI) waste materials with ascorbic acid or other reducing agent to reduce the Cr(VI) to Cr(III). For additional information on health and safety issues relating to chromium, the user is referred to References 10.7 and 10.10.7.0PROCEDURE7.1Adjust the temperature setting of each heating device used in the alkaline digestion by preparing and monitoring a temperature blank [a 250 mL vessel filled with 50 mLs digestion solution (Section 5.7)]. Maintain a digestion solution temperature of 90-95E C as measured with a NIST-traceable thermometer or equivalent.7.2Place 2.5 ± 0.10 g of the field-moist sample into a clean and labeled 250 mL digestion vessel. The sample should have been mixed thoroughly before the aliquot is removed.CD-ROM 3060A-5Revision 1December 1996For the specific sample aliquot that is being spiked (Section 8.5), the spike material should be added directly to the sample aliquot at this point. (Percent solids determination, U.S. EPA CLP SOW for Organic Analysis, OLM03.1, 8/94 Rev.) should be performed on a separate aliquot in order to calculate the final result on a dry-weight basis).7.3Add 50 mL ± 1 mL of digestion solution (Section 5.7) to each sample using a graduated cylinder, and also add approximately 400 mg of MgCl (Section 5.4) and 0.5 mL of 1.0M 2phosphate buffer (Section 5.5.3). For analytical techniques that can correct for oxidation/reduction of Cr, the addition of Mg is optional. Cover all samples with watch glasses.2+7.4Stir the samples continuously (unheated) for at least five minutes using an appropriate stirring device.7.5 Heat the samples to 90-95E C, then maintain the samples at 90-95E C for at least 60minutes with continuous stirring.7.6Gradually cool, with continued agitation, each solution to room temperature. Transfer the contents quantitatively to the filtration apparatus; rinsing the digestion vessel with 3 successive portions of reagent water. Transfer the rinsates to the filtration apparatus. Filter through a 0.45µm membrane filter. Rinse the inside of the filter flask and filter pad with reagent water and transfer the filtrate and the rinses to a clean 250-mL vessel.NOTE: The remaining solids and filter paper resulting from filtration of the matrix spike in Section 7.6 should be saved for possible use in assessing low Cr(VI) matrix spike recoveries.See Section 8.5.2. for additional details. Store the filtered solid at 4 ± 2E C.7.7Place an appropriate stirring device into the sample digest beaker, place the vessel on a stirrer, and, with constant stirring, slowly add 5.0 M nitric acid solution to the beaker dropwise.Adjust the pH of the solution to 7.5 ± 0.5 if the sample is to be analyzed using Method 7196 (adjust the pH accordingly if an alternate analytical method is to be used; i.e. 9.0 ± 0.5 if Method 7199 is to be used) and monitor the pH with a pH meter. If the pH of the digest should deviate from the desired range, discard the solution and redigest. If overshooting the desired pH range occurs repeatedly,prepare diluted nitric acid solution and repeat digestion procedure. If a flocculent precipitate should form, the sample should be filtered through a 0.45 µm membrane filter. If the filter becomes clogged using the 0.45 µm filter paper, a larger size filter paper (Whatman GFB or GFF) may be used to prefilter the samples.CAUTION: CO will be evolved. This step should be performed in a fume hood.27.8Remove the stirring device and rinse, collecting the rinsate in the beaker. Transfer quantitatively the contents of the vessel to a 100 mL volumetric flask and adjust the sample volume to 100 mL (to the mark for the volumetric flask) with reagent water. Mix well.7.9The sample digestates are now ready to be analyzed. Determine the Cr(VI)concentration in mg/kg by a suitable technique with appropriate accuracy and precision, for example Method 7196 (colorimetrically by UV-VIS spectrophotometry) or Method 7199 (colorimetrically by ion chromatography (IC)). Another analytical technique such as IC with inductively coupled plasma -mass spectrometric (ICP-MS) detection, high performance liquid chromatography (HPLC) with ICP-MS detection, capillary electrophoresis (CE) with ICP-MS detection, etc. may be utilized once performance effectiveness has been validated.7.10 CALCULATIONS7.10.1Sample ConcentrationA x D x EConcentration = ------------B x Cwhere:A=Concentration observed in the digest (µg/mL)B=Initial moist sample weight (g)C=% Solids/100D=Dilution FactorE=Final digest volume (mL)7.10.2Relative Percent Difference(S - D)RPD =-------------[(S + D)/2]where:S=Initial sample resultD=Duplicate sample result7.10.3Spike RecoveryPercent Recovery(SSR - SR)x 100=SAwhere:SSR=Spike sample resultSR=Sample (unspiked) resultSA=Spike added8.0QUALITY CONTROL8.1The following Quality Control (QC) analyses must be performed per digestion batch as discussed in Chapter One.8.2 A preparation blank must be prepared and analyzed with each digestion batch, as discussed in Chapter One and detected Cr(VI) concentrations must be less than the method detection limit or one-tenth the regulatory limit or action level, whichever is greater or the entire batch must be redigested.8.3Laboratory Control Sample (LCS): As an additional determination of method performance, utilize the matrix spike solution prepared in Section 5.8.1 or the solid matrix spiking agent PbCrO (Section 5.6) to spike into 50 mL of digestion solution (Section 5.7). Alternatively, the 4use of a certified solid reference material (if available) is recommended. Recovery must be within the certified acceptance range or a recovery range of 80% to 120% or the sample batch must be reanalyzed.8.4 A separately prepared duplicate soil sample must be analyzed at a frequency of one per batch as discussed in Chapter One. Duplicate samples must have a Relative Percent Difference (RPD) of < 20%, if both the original and the duplicate are > four times the laboratory reporting limit.A control limit of ± the laboratory reporting limit is used when either the original or the duplicate sample is < four times the laboratory reporting limit.8.5Both soluble and insoluble pre-digestion matrix spikes must be analyzed at a frequency of one each per batch of < 20 field samples. The soluble matrix spike sample is spiked with 1.0 mL of the spiking solution prepared in Section 5.8.1 (equivalent to 40 mg Cr(VI)/Kg)) or at twice the sample concentration, whichever is greater. The insoluble matrix spike is prepared byadding 10-20 mg of PbCrO (Section 5.6) to a separate sample aliquot. It is used to evaluate the4dissolution during the digestion process. Both matrix spikes are then carried through the digestion process described in Section 7.0. More frequent matrix spikes must be analyzed if the soil characteristics within the analytical batch appear to have significant variability based on visual observation. An acceptance range for matrix spike recoveries is 75-125%. If the matrix spike recoveries are not within these recovery limits, the entire batch must be rehomogenized/redigested/reanalyzed. If upon reanalysis, the matrix spike is not within the recovery limits, but the LCS is within criteria specified in Section 8.3, information such as that specified on Figures 1 and 2 and in Section 3.1 should be carefully evaluated . The Cr(VI) data may be valid for use despite the perceived "QC failure." The information shown on Figure 1 and discussed below is provided to interpret ancillary parameter data in conjunction with data on spike recoveries.8.5.1 First measure the pH (Method 9045) and Oxidation Reduction Potential (ORP)(ASTM Method D 1498-93 - aqueous samples, Method 9045 preparatory for soil samples), in the field if possible. If not possible, the measurements are to be made in the laboratory prior to the determination of the spike recovery data. When and where the measurements are taken must be noted by the analyst. Adjust the ORP measurement based on reference electrode correction factor to yield Eh values. The pH and Eh values should be plotted on Figure 2 in order to give an initial indication of the sample’s reducing/oxidizing nature. Upon completion of the analysis of the analytical batch, the LCS should be evaluated. If the LCS is not within 80 - 120% recovery or the certified acceptance range, then the entire analytical batch (plus the QC samples) should be redigested and reanalyzed. If the LCS was within acceptance criteria and the pre-digestion matrix spike recoveries for Cr(VI) were less than the acceptance range minimum (75%), this indicates that the soil samples reduced Cr(VI)(e.g., anoxic sediments), and no measurable native Cr(VI) existed in the unspiked sample(assuming the criteria in Section 8.3 are met). Such a result indicates that the combined and2+ interacting influences of ORP, pH and reducing agents (e.g., organic acids, Fe and sulfides) caused reduction of Cr(VI) spikes. Characterize each matrix spike sample for additional analytical parameters, such as ferrous iron (ASTM Method D3872-86), and sulfides (Method 9030). Laboratory measurements of pH and ORP should also be performed to confirm the field measurements. Other indirect indicators of reducing/oxidizing tendency include Total Organic Carbon (TOC), Chemical Oxygen Demand (COD), and Biological Oxygen Demand (BOD). Analysis of these additional parameters assists in evaluating the tendency of Cr(VI)to exist or not exist in the unspiked sample(s) and assists in the interpretation of QC data for matrix spike recoveries outside conventionally accepted criteria for total metals.A value of Eh-pH below the bold diagonal line on Fig. 2 indicates a reducing soil forCr(VI). The downward slope to the right indicates that the Eh value, at which Cr(VI) is expected to be reduced, decreases with increasing pH. The solubility and quantity of organic constituents influence reduction of Cr(VI). The presence of H S or other strong odors2indicates a reducing environment for Cr(VI). In general, acidic conditions accelerate reduction of Cr(VI) in soils, and alkaline conditions tend to stabilize Cr(VI) against reduction.If pre-digestion matrix spike recovery is not within the recovery limits, the reductive nature of the sample must be documented. This is done by plotting the Eh and pH data on the Eh-pH diagram (Fig. 2) to see if spike recovery is or is not expected in the soil. If the data point falls below the Cr(VI)-Cr(III) line on the diagram, then the data is not qualified or rejected.The sample is reducing for Cr(VI). If the data point falls above the line, then the sample is capable of supporting Cr(VI). In this case, technical error may be responsible for the poor spike recovery, and the extraction should be repeated, along with the Eh and pH measurements. If re-extraction results in a poor spike recovery again, then the data is qualified. At this point, review of other soil characteristics, such as levels of pH, Eh, TOC, sulfides, Fe(II), is appropriate to understand why poor spike recovery occurred. This extra review of these soil properties is only necessary if the unspiked sample contains detectable Cr(VI).8.5.2 If a low or zero percent pre-digestion matrix spike recovery is obtained, analternate approach can be used to determine the potential contribution of the sample matrix to Cr(VI) reduction. This approach consists of performing a mass balance, whereby total chromium is analyzed (Method 3052) for two samples: (1) a separate unspiked aliquot of the sample previously used for spiking, and (2) the digested solids remaining after the alkaline digestion and filtration of the matrix spike (i.e., the filtered solids from the matrix spike in Section 7.6).The difference between the total chromium measurements should be approximately equal to the amount of the spike added to the matrix spike. If the LCS (Section 8.3) met the acceptance criteria and the Cr(VI) spike is accounted for in the filtered solids as total chromium, it is likely that the reduction of the Cr(VI) to insoluble Cr(III) resulted from the reducing matrix of the original sample subjected to Cr(VI) spiking.8.6 A post-digestion Cr(VI) matrix spike must be analyzed per batch as discussed in Chapter One. The post-digestion matrix spike concentration should be equivalent to 40 mg/kg or twice the sample concentration observed in the unspiked aliquot of the test sample, whichever is greater.8.6.1 Dilute the sample aliquot to a minimum extent, if necessary, so that theabsorbance reading for both the unspiked sample aliquot and spiked aliquot are within the initial calibration curve.8.6.2 A guideline for the post-digestion matrix spike recovery is 85-115%. If notachieved, consider the corrective actions/guidance on data use specified in Section 8.5 or the Method of Standard Additions (MSA) as specified in Section 8.0 of Method 7000. If the MSA technique is applied post digestion and no spike is observed from the MSA, these results indicate that the matrix is incompatible with Cr(VI) and no further effort on the part ofthe laboratory is required. These digestates may contain soluble reducing agents for Cr(VI), such as fulvic acids.9.0METHOD PERFORMANCE9.1 A commercial laboratory analyzed soil/sediment samples containing Cr(VI) with theresults found in Table 1.10.0REFERENCES10.1United States Environmental Protection Agency, 1982. Test Methods for Evaluating Solid Wastes, Physical/Chemical Methods. SW-846, Second Edition. Office of Solid Waste and Emergency Response, Washington, D.C.10.2New Jersey Department of Environmental Protection and Energy (NJDEPE). NJDEPE Modified Methods 3060/7196. 1992.10.3Vitale, R., G. Mussoline, J. Petura, B. James, 1993. A Method Evaluation Study of an Alkaline Digestion (Modified Method 3060) Followed by Colorimetric Determination (Method 7196) for the Analysis for Hexavalent Chromium in Solid Matrices. Environmental Standards, Inc. Valley Forge, PA 19482.10.4Zatka, V.J., 1985. Speciation of Hexavalent Chromium in Welding Fumes Interference by Air Oxidation of Chromium. J. Ray Gordon Research Laboratory, INCO Limited, Sheridan Park, Mississauga, Ontario L5K 1Z9, Am. Ind. Hyg. Assoc. J., 46(6) : 327-331.10.5ASTM (American Society for Testing and Materials), 1981. Standard Practice for Oxidation Reduction Potential of Water. ASTM Designation:D1498-93.10.6Vitale, R.J., Mussoline, G.R., Petura, J.C. and James, B.R. 1994. Hexavalent Chromium Extraction from Soils: Evaluation of an Alkaline Digestion Method. J. Environ. Qual. 23:1249-1256.10.7U.S. Department of Health and Human Services - Agency for Toxic Substances and Disease Registry. Toxicological Profile for Chromium. April, 1993.10.8Vitale, R.J., Mussoline, G.R., Petura, J.C. and James, B.R. 1995. Hexavalent Chromium Quantification in Soils: An Effective and Reliable Procedure. Am. Env. Lab., April Ed.10.9James, B.R., Petura, J.C., Vitale, R.J., and Mussoline, G.R. 1995. Hexavalent Chromium Extraction form Soils: A Comparison of Five Methods. Environ. Sci. Technol. 29:2377-2381.10.10U.S. Environmental Protection Agency. 1993. IRIS: A continuously updated electronic database maintained by the U.S. Environmental Protection Agency. National Library of Medicine, Bethesda, MD.10.11ASTM (American Society for Testing and Materials), 1981. Standard Test Method for Ferrous Iron in Iron Oxides. ASTM Designation:D3872-86.10.12ASTM (American Society for Testing and Materials), 1981. Standard Test Method for 24-h Batch-Type Measurement of Contaminant Sorption by Soil and Sediments. ASTM Designation:D4646-87.10.13ASTM (American Society for Testing and Materials), 1981. Standard Test Method for Single Batch Extraction Method for Waters. ASTM Designation:D5233-92.10.14ASTM (American Society for Testing and Materials), 1981. Standard Test Method for Shake Extraction of Solid Waste with Water. ASTM Designation:D3987-85.10.15U.S. EPA Contract Laboratory Program, Statement of Work for Organic Analysis, Multimedia Multiconcentration Document, OLM03.1, 8/94 Rev.TABLE 1SINGLE LABORATORY METHOD EVALUATION DATA(ppm)(mg/kg)(mg/kg)Range,%Eh S Cr(VI) Conc.Spike Conc.Recovery bd2-Sample Type(mV)pH c Mean Native Mean Cr(VI)Matrix Spike COPR /Soil 5507.4<10.0 4.142.089.8-116a Blends Loam 620 6.4<10.0ND 62.565.0-70.3Clay 840 3.0<10.0ND 63.137.8-71.1COPR 4607.4<10.075981385.5-94.8a Anoxic -1897.225.0ND 3810Sediment Quartz Sand7105.3<10.0ND9.875.5-86.3Source: Reference 10.3Notes:ND -Not detecteda -COPR - chromite ore processing residueb -Corrected for the reference electrode, laboratory field moist measurementc -Field measurementd-Laboratory field moist measurementQUALITY CONTROL FLOW CHARTQUALITY CONTROL FLOW CHART (Continued)Eh/pH PHASE DIAGRAMMETHOD 3060AALKALINE DIGESTION FOR HEXAVALENT CHROMIUM。

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DELFT UNIVERSITY OF TECHNOLOGY
REPORT 90{01 A POTENTIAL REDUCTION METHOD FOR A CLASS OF SMOOTH CONVEX PROGRAMMING PROBLEMS D. den Hertog, C. Roos and T. Terlaky
ISSN 0922{5641 Reports of the Faculty of Technical Mathematics and Informatics no. 90{01 Delft, 1990
1
Address of the authors:
Faculty of Technical Mathematics and Computer Science Delft University of Technology Mekelweg 4 2628 CD Delft Netherlands. This work is completed under the support of a research grant of SHELL. The third author is on leave from the Eotvos University, Budapest, and partially supported by OTKA no. 2116.
ISSN 0922-5641 Copyright c 1990 by the Faculty of Technical Mathematics and Informatics, Delft, The Netherlands. No part of this Journal may be reproduced in any form, by print, photoprint, microfilm, or any other means without permission from the Faculty of Technical Mathematics and Informatics, Delft University of Technology, The Netherlands. Copies of these reports may be obtained from the bureau of the Faculty of Technical Mathematics and Informatics, Julianalaan 132, 2628 BL Delft, phone +3115784568. A selection of these reports is available in PostScript form at the Faculty’s anonymous ftp-site. They are located in the directory /pub/publications/tech-reports at ftp.twi.tudelft.nl2 2Βιβλιοθήκη 1 Introduction
Since Karmarkar 6] presented his projective method for the solution of the linear programming problem in 1984, many other variants have been developed by researchers. Among them are the potential reduction methods, such as proposed by Ye 13], Freund 2], Roos and Vial 10], Gonzaga 3], 4] and Den Hertog, Roos and Terlaky 1]. The advantages of these methods are that they don't use projective transformations as the projective methods do, and that they don't need to follow the socalled central path closely, contrary to the path{following methods. In Jarre 5] and Mehrota and Sun 9] path{following algorithms are proposed for smooth convex programming problems. Again, the great disadvantage of these methods is that they are based on very small stepsizes to remain in the vicinity of the central trajectory. This characteristic of these methods make them unattractable for practice. In this paper we propose a potential reduction method for smooth convex programming problems, which ful l the socalled Relative Lipschitz Condition. Jarre 5] also uses this condition. Our method is a generalization of our potential reduction method for linear programming in 1] and is also based on Jarre's paper. In our potential reduction method we do a linesearch along the Newton direction with respect to a certain strictly convex potential function. If we are close to the current analytic center we update the lower bound somehow, whereafter we do linesearches aiming at getting close to the analytic center associated with the new lower bound. We proof that after a linesearch the potential value reduces at least with a certain constant. Using this result, we proof that the number of iterations required by the algorithm to converge to an {optimal solution is polynomial in , the dimension of the problem and the Lipschitz constant. We note that Liu and Goldfarb 8] already proposed a potential reduction algorithm for convex quadratic programming and Kojima, Mizuno and Yoshise 7] for linear complementarity problems. To our knowledge our algorithm is the rst potential reduction algorithm for (a class of) smooth convex programming. To extend the method to all smooth convex programs (without the Relative Lipschitz Condition) is currently under research. This paper is organized as follows. In Section 2 we will do some preliminary work. In Section 3 we describe our algorithm. Then, in Section 4 we prove some lemmas, needed for the convergence analysis in Section 5. Notation. Throughout the paper we use the following notation. If s denotes a vector, then the corresponding capital letter S will denote the diagonal matrix with the components of s on the diagonal. The vector e will always denote an all one vector of appropriate length. The identity matrix will be denoted by I . Superscripts will be used to denote di erent iterates, e.g. y and y .
Copyright c 1990 by Faculty of Technical Mathematics and Informatics, Delft, The Netherlands. No part of this Journal may be reproduced in any form, by print, photoprint, micro lm or any other means without written permission from Faculty of Technical Mathematics and Informatics, Delft University of Technology, The Netherlands.
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