合成鞣剂化学和应用
合集下载
- 1、下载文档前请自行甄别文档内容的完整性，平台不提供额外的编辑、内容补充、找答案等附加服务。
- 2、"仅部分预览"的文档,不可在线预览部分如存在完整性等问题,可反馈申请退款(可完整预览的文档不适用该条件!)。
- 3、如文档侵犯您的权益，请联系客服反馈,我们会尽快为您处理(人工客服工作时间：9:00-18:30)。
合并
– Unified approach
统一
Innovation 创新 – High input on R&D
研发的高投入
Services 服务 – Local manufacturing to ensure speedy service
Public Song Ma BU Leather Wet End 08.04.2005
生产本土化确保快速供应
– Large well trained local services team
庞大、训练有素的本土服务团队
Main type of Clariant syntans
科莱恩合成鞣剂的品牌
Tanicor Tergotan Sandotan Syncotan Coralon
Public Song Ma BU Leather Wet End 08.04.2005
润滑皮纤维得到强度和物性
Dyeing染色 – Give leather the desired surface colour
赋予皮革需要的表观颜色
Public Song Ma BU Leather Wet End 08.04.2005
– Cross-section colouring
颜色透心
Function of syntans
S O 3 N a S O 3H
N
Phenolic Syntans
酚类合成鞣剂
Replacement - General Purpose
替代型-通用
– Tanicor PW – Tanicor PSA – Tanicor PG – Sandotan VX (firm leather紧实皮革)
Public Song Ma BU Leather Wet End 08.04.2005
Phenolic Syntans
酚类合成鞣剂
Soft – Filling
软-填充
– Tanicor KW – Sandotan SG – Tanicor CRF (New generation low free formaldehyde) (新一代低游离甲醛产品)
Public Song Ma BU Leather Wet End 08.04.2005
以上所列为主要部分
More information – contact your local Clariant personnel 请与科莱恩当地人员索要更多信息
Public Song Ma BU Leather Wet End 08.04.2005
The challenge for syntan suppliers
Phenolic Syntans
酚类合成鞣剂
White Bleaching
漂白
– Tanicor PWB – Tanicor KWO – Tanicor PWC – Tanicor DRF (New low free formaldehyde) (新一代低游离甲醛产品)
Public Song Ma BU Leather Wet End 08.04.2005
Naphthalene Syntans
萘类合成鞣剂
Auxiliary / Dispersing – Coralon OT Powder Neutralising中和 – Tanicor AS6 Powder – Sandotan NE Pretanning预鞣 – Tanicor VTN Powder
Sulphone Syntans
砜类合成鞣剂
O H O H
H SO 2 4
S O 3H
PHENO L
O HO S O O H
O H
O S O
Public Song Ma BU Leather Wet End 08.04.2005
S O 3H
HO
Sulphone Syntans
砜类合成鞣剂
Shrunken Grain 缩纹 – Tanicor SXL Liquid Speciality for Water Resistance 特别用于防水的 – Tanicor WRS Powder Speciality for wet white 特别用于白湿皮的 – Sandotan SCU liq
Public Song Ma BU Leather Wet End 08.04.2005
SYNTAN TYPES
合成鞣剂的分类
Naphthalene Phenolic Sulphone Amino Resin Polymers Liquids Powders Blends
Public Song Ma BU Leather Wet End 08.04.2005
合成鞣剂的挑战
Environmental, health and safety 环境，健康和安全 – Environmental impact during manufacturing, use and recycle
生产，使用和从新利用对环境的影响
– Health and safety
健康和安全
Supplying 供应 – On time 时间 – At price 价格 Speed of change 变化速度
Public Song Ma BU Leather Wet End 08.04.2005
– Fashion 流行 – Seasons 季节
Strength of Clariant leather WETEND
科莱恩皮革化工水场产品优势
Combination of four famous names 四个品牌结合优选 – Merged operation
合成鞣剂的作用
Improve properties of leather
改善皮革的性能
– Filling the loose part
填充松散部位
– Tighten the grain
紧实粒面
– Set desired handle
得到期望的手感
Assisting dyeing and fatliquoring
Public Song Ma BU Leather Wet End 08.04.2005
Amino Resin Syntans
氨基树脂鞣剂
O HN 2 C N H 2 + C O H 2
O
O
HN 2
C
N H
C H 2
N H
C
N H
HN 2
N
NH 2 N HN 2
C N N C N H 2 N O C N C OSO N H a 2 3
Public Song Ma BU Leather Wet End 08.04.2005
N 2 H
Amino Resin Syntans
氨基树脂鞣剂
Dicyandiamide Resin双氰胺树脂 – Tergotan RSN/RSF Powder Melamine Resin三聚氰胺树脂 – Tergotan RD/RDC Powder, Tergotan RFC – Tergotan RD01-016 (new low free formaldehyde) Urea Resin尿醛树脂 – Tergotan RA Powder
Public Song Ma BU Leather Wet End 08.04.2005
Polymer Syntans
聚合物鞣剂鞣剂
H CH2 C CO O H ACRY L I C ACI D
H C H H CH CH3 C
H C CO O H PO L YMER
CO O H
M E T HACRY L I C ACID
固定
– Correct colour
改正颜色
Types of retanning materials
复鞣材料分类
Metal salt Natural products – Veg tannin – Polysaccharides – Protein Synthetic tannins (Syntans) Specialities – Surfactants – (Poly)Phosphates 金属盐 天然产品 植物鞣剂 多聚糖 蛋白质 合成鞣剂 特殊产品 表面活性剂 (聚)磷酸盐
Public Song Ma BU Leather Wet End 08.04.2005
Some points about our product range
几点说明
Wide range of products cover full spectrum of application（产 品广，适宜所有加工过程） Local products for local needs This is not a exhaust list 地方产品
Syntans Chemistry and application
Public Song Ma BU Leather Wet End 08.04.2005
合成鞣剂化学和应用
Clariant international Range of retanning products.
科莱恩国际系列复鞣产品
The leather making process
Public Song Ma BU Leather Wet End 08.04.2005
助剂/分散剂
Phenolic Syntans
酚类合成鞣剂
O H O H H 2S O 4
S O 3H C H 2O
O H
O H
S O 3H
S O 3H
O H
O H
N H 2 C O
O H
Public Song Ma BU Leather Wet End 08.04.2005
萘类 酚类 砜类 氨基树脂 聚合物 液体 粉状 混合
Naphthalene Syntans
萘类合成鞣剂
H SO 2 4 S O 3H CH O 2
S O 3H NaO H
SO H 3
Public Song Ma BU Leather Wet End 08.04.2005
S O 3 Na
S O 3 Na
辅助染色和加脂
– Change charge characteristics
改变电荷性质
– Set the substrate for dye/fat penetration
固定纤维以利染色/油脂渗透
Public Song Ma BU Leather Wet End 08.04.2005
– Fixation
CH2 C O O
CH
2 C O
M AL E IC ANHY DRI DE
Public Song Ma BU Leather Wet End 08.04.2005
O T HE R M O NO M E RS
O IL S
P RO T E I NS
E tc
Polymer Syntans
聚合物鞣剂鞣剂
Acrylic Based丙烯酸类 – Tergotan PR Liquid, Tergotan H2 Liquid – Tergotan MC liq Acrylic / Polymer丙烯酸 / 聚合物 – Tergotan PMB - improved tightening & filling Styrene Maleic Based苯乙烯马来酸类 – Tergotan S Conc. Liquid
Retanning复鞣 – Set-out the base for handle/feel
赋予皮身的手感
– Improve the uniformity of a hide
改善皮身的均匀性
Fatliquoring加脂 – Give the softness of leather
赋予皮革柔软性
– Lubricating fibre for the strength and performance
皮革生产过程
Raw hide
生皮
Tanning
鞣制
Wet blue
蓝湿皮 Retan/Dyeing
复鞣/染色
Finished
成品
Public Song Ma BU Leather Wet End 08.04.2005
Finishing
涂饰
Crust
皮坯
From wet blue to crust
从蓝湿皮到皮坯
– Unified approach
统一
Innovation 创新 – High input on R&D
研发的高投入
Services 服务 – Local manufacturing to ensure speedy service
Public Song Ma BU Leather Wet End 08.04.2005
生产本土化确保快速供应
– Large well trained local services team
庞大、训练有素的本土服务团队
Main type of Clariant syntans
科莱恩合成鞣剂的品牌
Tanicor Tergotan Sandotan Syncotan Coralon
Public Song Ma BU Leather Wet End 08.04.2005
润滑皮纤维得到强度和物性
Dyeing染色 – Give leather the desired surface colour
赋予皮革需要的表观颜色
Public Song Ma BU Leather Wet End 08.04.2005
– Cross-section colouring
颜色透心
Function of syntans
S O 3 N a S O 3H
N
Phenolic Syntans
酚类合成鞣剂
Replacement - General Purpose
替代型-通用
– Tanicor PW – Tanicor PSA – Tanicor PG – Sandotan VX (firm leather紧实皮革)
Public Song Ma BU Leather Wet End 08.04.2005
Phenolic Syntans
酚类合成鞣剂
Soft – Filling
软-填充
– Tanicor KW – Sandotan SG – Tanicor CRF (New generation low free formaldehyde) (新一代低游离甲醛产品)
Public Song Ma BU Leather Wet End 08.04.2005
以上所列为主要部分
More information – contact your local Clariant personnel 请与科莱恩当地人员索要更多信息
Public Song Ma BU Leather Wet End 08.04.2005
The challenge for syntan suppliers
Phenolic Syntans
酚类合成鞣剂
White Bleaching
漂白
– Tanicor PWB – Tanicor KWO – Tanicor PWC – Tanicor DRF (New low free formaldehyde) (新一代低游离甲醛产品)
Public Song Ma BU Leather Wet End 08.04.2005
Naphthalene Syntans
萘类合成鞣剂
Auxiliary / Dispersing – Coralon OT Powder Neutralising中和 – Tanicor AS6 Powder – Sandotan NE Pretanning预鞣 – Tanicor VTN Powder
Sulphone Syntans
砜类合成鞣剂
O H O H
H SO 2 4
S O 3H
PHENO L
O HO S O O H
O H
O S O
Public Song Ma BU Leather Wet End 08.04.2005
S O 3H
HO
Sulphone Syntans
砜类合成鞣剂
Shrunken Grain 缩纹 – Tanicor SXL Liquid Speciality for Water Resistance 特别用于防水的 – Tanicor WRS Powder Speciality for wet white 特别用于白湿皮的 – Sandotan SCU liq
Public Song Ma BU Leather Wet End 08.04.2005
SYNTAN TYPES
合成鞣剂的分类
Naphthalene Phenolic Sulphone Amino Resin Polymers Liquids Powders Blends
Public Song Ma BU Leather Wet End 08.04.2005
合成鞣剂的挑战
Environmental, health and safety 环境，健康和安全 – Environmental impact during manufacturing, use and recycle
生产，使用和从新利用对环境的影响
– Health and safety
健康和安全
Supplying 供应 – On time 时间 – At price 价格 Speed of change 变化速度
Public Song Ma BU Leather Wet End 08.04.2005
– Fashion 流行 – Seasons 季节
Strength of Clariant leather WETEND
科莱恩皮革化工水场产品优势
Combination of four famous names 四个品牌结合优选 – Merged operation
合成鞣剂的作用
Improve properties of leather
改善皮革的性能
– Filling the loose part
填充松散部位
– Tighten the grain
紧实粒面
– Set desired handle
得到期望的手感
Assisting dyeing and fatliquoring
Public Song Ma BU Leather Wet End 08.04.2005
Amino Resin Syntans
氨基树脂鞣剂
O HN 2 C N H 2 + C O H 2
O
O
HN 2
C
N H
C H 2
N H
C
N H
HN 2
N
NH 2 N HN 2
C N N C N H 2 N O C N C OSO N H a 2 3
Public Song Ma BU Leather Wet End 08.04.2005
N 2 H
Amino Resin Syntans
氨基树脂鞣剂
Dicyandiamide Resin双氰胺树脂 – Tergotan RSN/RSF Powder Melamine Resin三聚氰胺树脂 – Tergotan RD/RDC Powder, Tergotan RFC – Tergotan RD01-016 (new low free formaldehyde) Urea Resin尿醛树脂 – Tergotan RA Powder
Public Song Ma BU Leather Wet End 08.04.2005
Polymer Syntans
聚合物鞣剂鞣剂
H CH2 C CO O H ACRY L I C ACI D
H C H H CH CH3 C
H C CO O H PO L YMER
CO O H
M E T HACRY L I C ACID
固定
– Correct colour
改正颜色
Types of retanning materials
复鞣材料分类
Metal salt Natural products – Veg tannin – Polysaccharides – Protein Synthetic tannins (Syntans) Specialities – Surfactants – (Poly)Phosphates 金属盐 天然产品 植物鞣剂 多聚糖 蛋白质 合成鞣剂 特殊产品 表面活性剂 (聚)磷酸盐
Public Song Ma BU Leather Wet End 08.04.2005
Some points about our product range
几点说明
Wide range of products cover full spectrum of application（产 品广，适宜所有加工过程） Local products for local needs This is not a exhaust list 地方产品
Syntans Chemistry and application
Public Song Ma BU Leather Wet End 08.04.2005
合成鞣剂化学和应用
Clariant international Range of retanning products.
科莱恩国际系列复鞣产品
The leather making process
Public Song Ma BU Leather Wet End 08.04.2005
助剂/分散剂
Phenolic Syntans
酚类合成鞣剂
O H O H H 2S O 4
S O 3H C H 2O
O H
O H
S O 3H
S O 3H
O H
O H
N H 2 C O
O H
Public Song Ma BU Leather Wet End 08.04.2005
萘类 酚类 砜类 氨基树脂 聚合物 液体 粉状 混合
Naphthalene Syntans
萘类合成鞣剂
H SO 2 4 S O 3H CH O 2
S O 3H NaO H
SO H 3
Public Song Ma BU Leather Wet End 08.04.2005
S O 3 Na
S O 3 Na
辅助染色和加脂
– Change charge characteristics
改变电荷性质
– Set the substrate for dye/fat penetration
固定纤维以利染色/油脂渗透
Public Song Ma BU Leather Wet End 08.04.2005
– Fixation
CH2 C O O
CH
2 C O
M AL E IC ANHY DRI DE
Public Song Ma BU Leather Wet End 08.04.2005
O T HE R M O NO M E RS
O IL S
P RO T E I NS
E tc
Polymer Syntans
聚合物鞣剂鞣剂
Acrylic Based丙烯酸类 – Tergotan PR Liquid, Tergotan H2 Liquid – Tergotan MC liq Acrylic / Polymer丙烯酸 / 聚合物 – Tergotan PMB - improved tightening & filling Styrene Maleic Based苯乙烯马来酸类 – Tergotan S Conc. Liquid
Retanning复鞣 – Set-out the base for handle/feel
赋予皮身的手感
– Improve the uniformity of a hide
改善皮身的均匀性
Fatliquoring加脂 – Give the softness of leather
赋予皮革柔软性
– Lubricating fibre for the strength and performance
皮革生产过程
Raw hide
生皮
Tanning
鞣制
Wet blue
蓝湿皮 Retan/Dyeing
复鞣/染色
Finished
成品
Public Song Ma BU Leather Wet End 08.04.2005
Finishing
涂饰
Crust
皮坯
From wet blue to crust
从蓝湿皮到皮坯