石油产品铜片腐蚀测定法
汽柴油铜片腐蚀快速试验法
PetroChina Lanzhou Lubricant R&D Institute
汽油、柴油铜片腐蚀试验法 快速法
6 试验步骤
6.1
把完全清澈、无悬浮水的试样倒入清洁、干燥的试管中30 mL刻
线处，并将经过最后磨光、干净的铜片在1min内浸入该试管的试样中。 将该试管小心地滑入试验钢弹中，并把弹盖旋紧，然后将试验钢弹完 全浸入已维持在90℃±1℃的恒温浴中恒温。 6.2 恒温30min后，小心地取出试验钢弹，并用自来水冲洗试验钢弹
测定。
中 国 石 油 兰 州 润 滑 油 研 发 中 心
PetroChina Lanzhou Lubricant R&D Institute
汽油、柴油铜片腐蚀试验法 快速法
日常操作注意事项
打磨合格的铜片对试验结果至关重要 磨光后的铜片禁止用手接触 浴温要保持在90℃±1℃范围内 所用试剂应经铜片试验合格后使用 试管小心滑入试验弹后，必须旋紧弹盖 从恒温浴中取出的试验弹用自来水冷却到 室温并擦干后再打开
ASTM D4814 汽油 ASTM D975 柴油 EN 228 汽油 EN 590 柴油 JIS K2202 汽油 JIS K2204 柴油 汽油 柴油 GB 1793 车用汽油 GB 252 轻柴油 GB 19147 车用柴油
中 国 石 油 兰 州 润 滑 油 研 发 中 心
PetroChina Lanzhou Lubricant R&D Institute
汽油、柴油铜片腐蚀 快速试验法介绍
兰州润滑油研究开发中心 2011年5月
石油产品的腐蚀性 石油产品的腐蚀性
金属接触
汽油铜片腐蚀试验方案设计教案
四级，见下表
铜片腐蚀标准色板的分级[GB/T 5096]
级别 （新磨光的铜片）
名称
说明①
a 淡橙色，几乎与新磨光的铜片一样
1
轻度变色
b 深橙色
a 紫红色
b 淡紫色
2
中度变色
c 带有淡紫蓝色或银色，或两种都有，并分别覆盖在紫红色上的多彩色
d 银色
e 黄铜色或金黄色
a 洋红色覆盖在黄铜色上的多彩色
3
深度变色
目
增强安全环保意识和责任感。
法
注意事项
标
重
点 【重点】油品铜片腐蚀的概念、测定原理和方法，汽油等油品铜片腐蚀的测定。
难 【难点】测定汽油等油品的铜片腐蚀试验。
点
【授课对象】二年级学生，已了解专业方向，有的学生学习上出现倦怠情绪，可能对石油产品
学 分析兴趣不大；面临大量专业课程同时开课；专业基础薄弱，但实践意识强，学习态度倾向于
燃料油品在运输、贮运和使用过程中，都面临同金属材料接触的问题，尤其是发动机气
化和供油系统中的燃料油品与金属构件接触更为密切，故要求油品铜片腐蚀试验必须合
格。铜片腐蚀试验是油品质量控制的重要检测指标。
表 部分油品腐蚀级别和试验条件及方法
油品名称
铜片腐蚀级别
试验条件
试验方法标准
车用汽油 (GB 17930) 喷气燃料（3 号） (GB 6537)
b 有红和绿显示的多彩色（孔雀绿），但不带灰色
a 透明的黑色、深灰色或仅带有孔雀绿的棕色
4
腐蚀
b 石墨黑色或无光泽的黑色
c 有光泽的黑色或乌黑发亮的黑色
①铜片腐蚀标准色板由表中说明的色板所组成。
通常用金属试片被待测油品腐蚀后的颜色变化或腐蚀迹象来判断腐蚀倾向。但有些
石油产品中铜片腐蚀试验测定器的操作规程
石油产品中铜片腐蚀试验测定器的操作规程
一、检查仪器的接地线，传感器和温度计是否正常。
二、向浴槽内加水至溢流管开始流水为止，然后打开放
水阀放出2-3升水。
三、开启电源开关，开启搅拌开关，通过温控仪拨盘设
定所需温度，加热管开始加温，到设定温度点时，即开始自动恒温。
四、环流冷凝器进入管用软管与自来水管连接，溢流管
下端出水管接软管通下水。
当浴槽温度升高出现水
蒸气时，打开自来水，以每分钟2-3升流量的水流
进冷凝器，以使水蒸气回流。
ASTM D130-12译文
ASTM D 130-12译文石油产品铜片腐蚀标准试验方法1 范围1.1本方法适用于测定航空汽油、喷气燃料、车用汽油、清洗溶剂油、煤油、柴油、馏分燃料油、润滑油、天然汽油或其他具有37.8℃雷德蒸气压不大于124干帕斯卡（18磅/平方英尺）的其他石油烃类产品对铜的腐蚀。
警告：某些石油产品，特别是天然汽油，其蒸气压比车用汽油或航空汽油的蒸气压更高。
因此，必须特别注意，一定不要把装有高蒸气压的天然汽油或其他产品的试验弹放在100℃浴中。
雷德蒸气压超过124干帕斯卡（18磅/平方英寸）的试样要采用D 1838试验法来测定1.2 本标准采用国际单位制SI单位。
括号内的数据仅为提供信息之用。
1.3本标准涉及某些有危险性的材料、操作和设备，但是无意对与此有关的所有安全问题都提出建议。
因此，用户在使用本标准之前应建立适当的安全和防护措施并确定有适用性的管理制度。
特别注意事项见1.1、6.1和附录A2。
2 参考文件2.1 ASTM标准ASTM D 396燃料油规格ASTM D 975柴油规格ASTM D 1655 航空喷气燃料规格ASTM D 1838 液化石油气铜片腐蚀测定法ASTM D 4057石油和石油产品的手工取样用标准实施规程ASTM D 4177石油和石油产品自动抽样的标准实施规程ASTM D 6300石油产品和润滑剂试验方法中使用的精确度和偏差数据测定的标准实施规程ASTM E 1 ASTM玻璃液体热力计规格2.2 ASTM标准附件ASTM铜片腐蚀标准色板3 术语3.1首字母缩略词3.1.1 CAMI：表明覆盖磨料制造者协会3.1.2 FEPA：欧共体生产者协会4方法概要4.1把一块已抛光好的铜片浸没在一定里的试样中，并按产品标准要求加热到指定的温度，保持一定的时间。
待试验周期结束时，取出铜片，经洗涤后与腐蚀标准色板进行比较，确定腐蚀级别。
5 意义和用途5.1原油中的大部分硫化物在精制的过程中被除去，但是，残留在油品中的某些硫化物会对各种金属产生腐蚀。
ASTM D130-2004石油产品铜片腐蚀测定
Designation:D130–04e1Designation:154/93An American National StandardFederation of Societies for Paint Technology Standard No.Dt-28-65British Standard4351Standard Test Method forCorrosiveness to Copper from Petroleum Products by Copper Strip Test1This standard is issued under thefixed designation D130;the number immediately following the designation indicates the year of original adoption or,in the case of revision,the year of last revision.A number in parentheses indicates the year of last reapproval.A superscript epsilon(e)indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.e1N OTE—Paragraphs11.1.2and11.1.3were editorially corrected to match Table1and ADJD0130.1.Scope1.1This test method covers the determination of the corro-siveness to copper of aviation gasoline,aviation turbine fuel, automotive gasoline,cleaners(Stoddard)solvent,kerosine, diesel fuel,distillate fuel oil,lubricating oil,and natural gasoline or other hydrocarbons having a vapor pressure no greater than124kPa(18psi)at37.8°C.(Warning—Some products,particularly natural gasoline,may have a much higher vapor pressure than would normally be characteristic of automotive or aviation gasolines.For this reason,exercise extreme caution to ensure that the pressure vessel used in this test method and containing natural gasoline or other products of high vapor pressure is not placed in the100°C(212°F)bath. Samples having vapor pressures in excess of124kPa(18psi) may develop sufficient pressures at100°C to rupture the pressure vessel.For any sample having a vapor pressure above 124kPa(18psi),use Test Method D1838.)1.2The values stated in SI units are to be regarded as the standard.The values in parentheses are for information only.1.3This standard does not purport to address all of the safety concerns,if any,associated with its use.It is the responsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory requirements prior to use.For specific warning statements,see1.1,6.1,and Annex A2.2.Referenced Documents2.1ASTM Standards:2D396Specification for Fuel OilsD975Specification for Diesel Fuel OilsD1655Specification for Aviation Turbine FuelsD1838Test Method for Copper Strip Corrosion by Lique-fied Petroleum(LP)GasesD4057Practice for Manual Sampling of Petroleum and Petroleum ProductsD4177Practice for Automatic Sampling of Petroleum and Petroleum ProductsE1Specification for ASTM Liquid-in-Glass Thermometers 2.2ASTM Adjuncts:ASTM Copper Strip Corrosion Standard33.Summary of Test Method3.1A polished copper strip is immersed in a specific volume of the sample being tested and heated under conditions of temperature and time that are specific to the class of material being tested.At the end of the heating period,the copper strip is removed,washed and the color and tarnish level assessed against the ASTM Copper Strip Corrosion Standard.4.Significance and Use4.1Crude petroleum contains sulfur compounds,most of which are removed during refining.However,of the sulfur compounds remaining in the petroleum product,some can have a corroding action on various metals and this corrosivity is not1This test method is under the jurisdiction of ASTM Committee D02on Petroleum Products and Lubricants and is the direct responsibility of Subcommittee D02.05on Properties of Fuels,Petroleum Coke and Carbon Material.Current edition approved May1,2004.Published June2004.Originally approved in1922,replacing former st previous edition approved in2000as D130–94(2000)e1.In the IP,this test method is under the jurisdiction of the Standardization Committee.It is issued under thefixed designation IP154.Thefinal number indicates the year of last revision.This test method has been approved by the sponsoring committees and accepted by the cooperating societies in accordance with established procedures.2For referenced ASTM standards,visit the ASTM website,,or contact ASTM Customer Service at service@.For Annual Book of ASTM Standards volume information,refer to the standard’s Document Summary page on the ASTM website.3Available from ASTM International Headquarters.Order Adjunct No. s of suppliers in the United Kingdom can be obtained from Energy Institute,61New Cavendish St.,London,WIG7AR,U.K.Two master standards are held by the IP for reference.Copyright©ASTM International,100Barr Harbor Drive,PO Box C700,West Conshohocken,PA19428-2959,United States.necessarily related directly to the total sulfur content.Theeffect can vary according to the chemical types of sulfur compounds present.The copper strip corrosion test is designed to assess the relative degree of corrosivity of a petroleum product.5.Apparatus5.1Copper Strip Corrosion Pressure Vessel,constructed from stainless steel according to the dimensions as given in Fig.1.The vessel shall be capable of withstanding a test pressure of700kPa gage(100psi).Alternative designs for the vessel’s cap and synthetic rubber gasket may be used provided that the internal dimensions of the vessel are the same as those shown in Fig.1.The internal dimensions of the pressure vessel are such that a nominal25-mm by150-mm test tube can be placed inside the pressure vessel.5.2Test Tubes,of borosilicate glass of nominal25-mm by 150-mm dimensions.The internal dimensions shall be checked as acceptable by use of a copper strip(see6.3).When30mL of liquid is added to the test tube with the copper strip in it,a minimum of5-mm of liquid shall be above the top surface of the strip.5.3Test Baths:5.3.1General—All test baths shall be able to maintain the test temperature to within61°C(2°F)of the required test temperature.5.3.2Liquid Bath Used for Submerging Pressure Vessel(s)—The bath shall be deep enough to submerge one or more pressure vessels(see5.1)completely during the test.As the bath medium,use water or any liquid that can be satisfac-torily controlled to the sample test temperature.The bath shall befitted with suitable supports to hold each pressure vessel ina vertical position when submerged.5.3.3Bath(s)Used for Test Tubes—Liquid baths shall be fitted with suitable supports to hold each test tube(see5.2)in a vertical position to a depth of about100-mm(4-in.)as measured from the bottom of the test tube to the bath surface. As a liquid bath medium,water and oil have been found satisfactory and controllable at the specified test temperature. Solid block baths shall meet the same temperature control and immersion conditions and shall be checked for temperature measurement(heat transfer)for each product class by running tests on tubesfilled with30mL of product plus a metal strip of the nominal dimensions given,plus a temperature sensor. 5.4Temperature Sensing Device(TSD),capable of monitor-ing the desired test temperature in the bath to within an accuracy of61°C or better.The ASTM12C(12F)(see Specification E1)or IP64C(64F)total immersion thermom-eters have been found suitable to use in the test.If used,no more than10-mm(0.4-in.)of the mercury should extend above the surface of the bath at the test temperature.5.5Polishing Vise,for holding the copper stripfirmly without marring the edges while polishing.Any convenient type of holder(see Appendix X1)may be used provided that the strip is held tightly and that the surface of the strip being polished is supported above the surface of the holder.5.6Viewing Test Tubes,flat glass test tubes,are convenient for protecting corroded copper strips for close inspection or storage(see Appendix X1for the description of aflat-glass Key:1Lifting eye2Wide groove for pressure relief3Knurled cap4Twelve threads per inch NF thread or equivalent5Camber inside cap to protect“O”ring when closing pressure vessel6Synthetic rubber“O”ring without free sulfur7Seamless tubeMaterial:stainless steelWelded constructionMaximum test gage pressure:700kPaN OTE1—Dimensions in millimetres.N OTE2—All dimensions without tolerance limits are nominal values.FIG.1Pressure Vessel for Copper Strip CorrosionTestviewing tube).The viewing test tube shall be of such dimen-sions as to allow the introduction of a copper strip(see6.3)and made of glass free of striae or similar defects.5.7Forceps,with either stainless steel or polytetrafluoroet-hylene(PTFE)tips,for use in handling the copper strips,have been found suitable to use.5.8Timing Device,electronic or manual,capable of accu-rately measuring the test duration within the allowable toler-ance.6.Reagents and Materials6.1Wash Solvent—Any volatile,less than5mg/kg sulfur hydrocarbon solvent may be used provided that it shows no tarnish at all when tested for3h at50°C(122°F).2,2,4-trimethylpentane(isooctane)of minimum99.75%purity is the referee solvent and should be used in case of dispute. (Warning—extremelyflammable,see A2.1.)6.2Surface Preparation/Polishing Materials,00grade or finer steel wool or silicon carbide grit paper or cloth of varying degrees offineness including65-µm(240-grit)grade;also a supply of105-µm(150-mesh)size silicon carbide grain or powder and absorbent cotton(cotton wool).A commercial grade is suitable,but pharmaceutical grade is most commonly available and is acceptable.6.3Copper Strips Specification—Use strips approximately 12.5-mm(1⁄2-in.)wide,1.5to3.0-mm(1⁄16to1⁄8-in.)thick,cut approximately75-mm(3-in.)long from smooth-surfaced, hard-temper,cold-finished copper of99.9+%purity;electrical bus bar stock is generally suitable(see Annex A1).The strips may be used repeatedly but should be discarded when the strip’s surface shows pitting or deep scratches that cannot be removed by the specified polishing procedure,or when the surface becomes deformed.6.4Ashless Filter Paper or Disposable Gloves,for use in protecting the copper strip from coming in contact with the individual duringfinal polishing.7.ASTM Copper Strip Corrosion Standards37.1These consist of reproductions in color of typical test strips representing increasing degrees of tarnish and corrosion, the reproductions being encased for protection in plastic and made up in the form of a plaque.7.1.1Keep the plastic-encased ASTM Copper Strip Corro-sion Standards protected from light to avoid the possibility of fading.Inspect for fading by comparing two different plaques, one of which has been carefully protected from light(for example,new plaque).Observe both sets in diffused daylight (or equivalent)first from a point directly above and then from an angle of45°.If any evidence of fading is observed, particularly at the left-hand end of the plaque,it is suggested that the one that is the more faded with respect to the other be discarded.7.1.1.1Alternatively,place a suitably sized opaque strip(for example,20-mm(3⁄4-in.)black electrical tape)across the top of the colored portion of the plaque when initially purchased.At intervals remove the opaque strip and observe.When there is any evidence of fading of the exposed portion,the standards shall be replaced.7.1.1.2These plaques are full-color reproductions of typical strips.They have been printed on aluminum sheets by a4-color process and are encased in plastic for protection.Directions for their use are given on the reverse side of each plaque.7.1.2If the surface of the plastic cover shows excessive scratching,it is suggested that the plaque be replaced.8.Samples8.1In accordance with D4057or D4177,or both,it is particularly important that all types of fuel samples,that pass a low-tarnish strip classification,be collected in clean,dark glass bottles,plastic bottles,or other suitable containers that will not affect the corrosive properties of the fuel.Avoid the use of tin plate containers for collection of samples,since experience has shown that they may contribute to the corrosiveness of the sample.8.2Fill the containers as completely as possible and close them immediately after taking the sample.Adequate headspace in the container is necessary to provide room for possible thermal expansion during transport.It is recommended that volatile samples befilled between70and80%of the contain-er’s capacity.Take care during sampling to protect the samples from exposure to direct sunlight or even diffused daylight. Carry out the test as soon as possible after receipt in the laboratory and immediately after opening the container.8.3If suspended water(that is,haze)is observed in the sample,dry byfiltering a sufficient volume of sample through a medium rapid qualitativefilter,into the prescribed clean,dry test tube.Carry out this operation in a darkened room or undera light-protected shield.8.3.1Contact of the copper strip with water before,during or after completion of the test run will cause staining,making it difficult to evaluate the strips.9.Preparation of Test Strips9.1Surface Preparation—Remove all surface blemishes from all six sides of the strip obtained from a previous analysis (see Note1).One way to accomplish this is to use00grade or finer steel wool or silicon carbide paper or cloth of such degrees offineness as are needed to accomplish the desired results efficiently.Finish with65-µm(240-grit)silicon carbide paper or cloth,removing all marks that may have been made by other grades of paper used previously.Ensure the prepared copper strip is protected from oxidation prior tofinal prepara-tion,such as by immersing the strip in wash solvent from which it can be withdrawn immediately forfinal preparation (polishing)or in which it can be stored for future use.N OTE1—Onlyfinal preparation(9.2)is necessary for commercially purchased pre-polished strips.9.1.1As a practical manual procedure for surface prepara-tion,place a sheet of silicon carbide paper or cloth on aflat surface and moisten it with kerosine or wash solvent.Rub the strip against the silicon carbide paper or cloth with a circular motion,protecting the strip from contact with thefingers by using ashlessfilter paper or wearing disposable gloves.Alter-natively,the surface of the strip can be prepared by use of motor-driven machines using appropriate grades of dry paper orcloth.9.2Final Preparation—For strips prepared in9.1or new strips being used for thefirst time,remove a strip from its protected location,such as by removing it from the wash solvent.To prevent possible surface contamination duringfinal preparation,do not allowfingers to come in direct contact with the copper strips,such as by wearing disposable gloves or holding the strips in thefingers protected with ashlessfilter paper.Polishfirst the ends and then the sides with the105-mm (150-mesh)silicon carbide grains picked up with a pad of cotton(cotton wool)moistened with wash solvent.Wipe vigorously with fresh pads of cotton(cotton wool)and subse-quently handle without touching the surface of the strip with thefingers.Forceps have been found suitable to use.Clamp in a vise and polish the main surfaces with silicon-carbide grains on absorbent cotton.Do not polish in a circular motion.Rub in the direction of the long axis of the strip,carrying the stroke beyond the end of the strip before reversing the direction. Clean all metal dust from the strip by rubbing vigorously with clean pads of absorbent cotton until a fresh pad remains unsoiled.When the strip is clean,immediately immerse it in the prepared sample.9.2.1It is important to polish the whole surface of the strip uniformly to obtain a uniformly stained strip.If the edges show wear(surface elliptical),they will likely show more corrosion than the center.The use of a vise(see Appendix X1)will facilitate uniform polishing.9.2.2It is important to follow the order of preparation with the correctly sized silicon carbide material as described in9.1 and9.2.Thefinal preparation is with105-µm silicon carbide powder.This is a larger grain size than the65-µm paper used in the surface preparation stage.The reason for this use of larger silicon carbide grains in thefinal preparation is to produce asperities(controlled roughness)on the surface of the copper,which act as sites for the initiation of corrosion reactions.10.Procedure10.1General—There are a variety of test conditions,which are broadly specific to given classes of product but,within certain classes,more than one set of test conditions of time or temperature,or both,may apply.In general,aviation gasoline shall be tested in a pressure vessel at100°C and other high vapor pressure fuels,like natural gasoline,at40°C.Other liquid products shall be tested in a test tube at50°C,100°C or even higher temperatures.The conditions of time and tempera-ture given below are commonly used and are quoted in the ASTM specifications for these products where such specifica-tions exist.They are,however,guides only.Other conditions can also be used when required by specifications or by agreement between parties.The test conditions of time and temperature shall be recorded as part of the result(see12.1).10.2Pressure Vessel Procedure—For use with aviation gasoline and higher vapor pressure samples.10.2.1For Aviation Gasoline and Aviation Turbine Fuel—Place30mL of sample,completely clear and free of any suspended or entrained water(see8.3)into a chemically clean and dry25-mm by150-mm test tube.Within1min after completing thefinal preparation(polishing),slide the copper strip into the sample tube.Place the sample tube into the pressure vessel(Fig.1)and screw the lid on tightly.If more than one sample is to be analyzed at essentially the same time, it is permissible to prepare each pressure vessel in the batch before completely immersing each pressure vessel in the liquid bath at10061°C(21262°F),provided the elapsed time between thefirst and last samples is kept to a minimum.After 2h65min in the bath,withdraw the pressure vessel and immerse for a few minutes in cool water(tap water).Open the pressure vessel,withdraw the test tube and examine the strip as described in10.4.10.2.2For Natural Gasoline—Carry out the test exactly as described in10.2.1but at40°C(104°F)and for3h65min.10.3Test Tube Procedure—For use with most liquid prod-ucts.10.3.1For Diesel Fuel,Fuel Oil,Automotive Gasoline—Place30mL of sample,completely clear and free of any suspended or entrained water(see8.3),into a chemically clean, dry25-mm by150-mm test tube and,within1min after completing thefinal preparation(polishing),slide the copper strip into the sample tube.If more than one sample is to be analyzed at essentially the same time,it is permissible to prepare each sample in the batch by stoppering each tube with a vented stopper,such as a vented cork before placing each tube in a bath maintained at5061°C(12262°F),provided the elapsed time between thefirst and last sample prepared is kept to a minimum.Protect the contents of the test tube from strong light during the test.After3h65min in the bath, examine the strip as described in10.4.For tests on fuel oil and diesel fuel,to specifications other than Specifications D396 and D975,a temperature of100°C(212°F)for3h is often used as an alternative set of conditions.Some automotive gasolines with vapor pressure above80kPa at37.8°C have exhibited evaporation losses in excess of10%of their volume. If such evaporation losses are apparent,it is recommended that the Pressure Vessel Procedure(see10.2)be used.10.3.2For Cleaners(Stoddard)Solvent and Kerosine—Carry out the test exactly as described in10.3.1but at1006 1°C(21262°F).10.3.3For Lubricating Oil—Carry out the test exactly as described in10.3.1,but the tests can be carried out for varying times and at elevated temperatures other than100°C(212°F). For the sake of uniformity,it is suggested that even increments of5°C,beginning with150°C,be used.10.4Strip Examination:10.4.1Empty the contents of the test tube into a suitably sized receiver.If a receiver made out of glass is used,such as a150-mL tall-form beaker,let the strip slide in gently so as to avoid breaking the glass.Immediately withdraw the strip with forceps and immerse in wash solvent.Withdraw the strip at once,dry and inspect for evidence of tarnishing or corrosion by comparison with the Copper Strip Corrosion Standards.The step of drying the strip may be done by blotting withfilter paper,air drying,or by other suitable means.Hold both the test strip and the standard strip plaque in such a manner that light reflected from them at an angle of approximately45°will be observed.10.4.2In handling the test strip during the inspection and comparison,the danger of marking or staining can beavoidedif it is inserted in a flat glass tube (see Appendix X1),which can be stoppered with absorbent cotton.11.Interpretation of Results11.1Interpret the corrosiveness of the sample in accordance with one of the classifications of the ASTM Copper Strip Corrosion Standard as listed in Table 1.11.1.1When a strip is in the obvious transition state between that indicated by any two adjacent standard strips,rate the sample at the more tarnished classification.Should a strip appear to have a darker orange color than Standard Strip 1b,consider the observed strip as still belonging in Classification 1;however,if any evidence of red color is observed,the observed strip belongs in Classification 2.11.1.2A 2a strip can be mistaken for a 3a strip if the brassy underlay of the 3a strip is completely masked by a magenta overtone.To distinguish,immerse the strip in wash solvent;a 2a strip will appear as a 1b strip,while a 3a strip will not change.11.1.3To distinguish a 2c strip from a 3b strip,place a test strip in a 25-mm by 150-mm test tube and bring to a temperature of 340630°C in 4to 6min with the tube lying on a hot plate.Adjust to temperature by observing a high distillation thermometer inserted into a second test tube.Thus,a 2c strip will assume the color of a 2d strip and successive stages of tarnish;a 3b strip will take on the appearance of a 4a strip.11.1.4Repeat the test if blemishes due to fingerprints are observed,or due to spots from any particles or water droplets that may have touched the test strip during the digestion period.11.1.5Repeat the test also if the sharp edges along the flat faces of the strip appear to be in a classification higher than the greater portion of the strip;in this case,it is likely that the edges were burnished during preparation (polishing).12.Report12.1Report the corrosiveness in accordance with one of the classifications listed in Table 1.State the duration of the test and the test temperature in the following format:Corrosion copper strip ~X h /Y °C !,Classification Zpwhere:X =test duration,in hours,Y =test temperature,°C,Z =classification category (that is,1,2,3,or 4),and p =classification description for the corresponding Z (forexample,a,b).13.Precision and Bias13.1In the case of pass/fail data,no generally accepted method for determining precision or bias is currently available.14.Keywords14.1automotive gasoline;aviation gasoline;aviation tur-bine fuel;copper corrosion;copper strip;corrosiveness to copper;natural gasolineTABLE 1Copper Strip ClassificationsClassification Designation Description AFreshly polished strip...B1slight tarnisha.Light orange,almost the same as freshly polished stripb.Dark orange 2moderate tarnish a.Claret red ... vender... c.Multicolored with lavender blue or silver,or both,overlaid on claret red ... d.Silvery...e.Brassy or gold3dark tarnish a.Magenta overcast on brassy strip... b.Multicolored with red and green showing (peacock),but no gray4corrosion a.Transparent black,dark gray or brown with peacock green barely showing ... b.Graphite or lusterless black ...c.Glossy or jet blackAThe ASTM Copper Strip Corrosion Standard is a colored reproduction of strips characteristic of these descriptions.BThe freshly polished strip is included in the series only as an indication of the appearance of a properly polished strip before a test run;it is not possible to duplicate this appearance after a test even with a completely noncorrosivesample.ANNEXES(Mandatory Information)A1.COPPER QUALITYA1.1Copper QualityA1.1.1Hard-temper,cold-finished type-(ETP)electrolytic tough pitch copper.4A2.WARNING STATEMENTSA2.1IsooctaneHarmful if inhaled.Vapors may cause flash fire.Keep away from heat,sparks,and open flame.Keep container closed.Use with adequate ventilation.Avoid build-up of vapors and eliminate all sources of ignition,especially nonexplosion-proof electrical apparatus and heaters.Avoid prolonged breathing of vapor or spray mist.Avoid prolonged or repeated skin contact.A2.2Aviation Turbine Fuel (Jet A or A-1,seeSpecification D 1655)Keep away from heat,sparks,and open flames.Keep container closed.Use with adequate ventilation.Avoid breathing vapor or spray mist.Avoid prolonged or repeated contact with skin.A2.3Gasoline (Containing Lead)Keep away from heat,sparks,and open flame.Keep container closed.Use with adequate ventilation.Avoid build-up of vapors and eliminate all sources of ignition,especially nonexplosion-proof electrical apparatus and heaters.Avoid prolonged breathing of vapor or spray mist.Avoid prolonged or repeated skin contact.A2.4Gasoline (White or Unleaded)Keep away from heat,sparks,and open flame.Keep container closed.Use with adequate ventilation.Avoid build-up of vapors and eliminate all sources of ignition,especially nonexplosion-proof electrical apparatus and heaters.Avoid prolonged breathing of vapor or spray mist.Avoid prolonged or repeated skin contact.A2.5KerosineKeep away from heat,sparks,and open flame.Keep container closed.Use with adequate ventilation.Avoid breathing vapor or spray mist.Avoid prolonged or repeated contact with skin.A2.6Stoddard SolventKeep away from heat,sparks,and open flame.Keep container closed.Use with adequate ventilation.Avoid prolonged breathing of vapor or spray mist.Avoid prolonged or repeated skin contact.4Conforming to Copper Development Association (CDA),United States of America No.110,or to British Standard (BS)EN 1652or BS 4608,which have properquality.APPENDIX(Nonmandatory Information)X1.OPTIONAL USEFUL EQUIPMENTX1.1Viewing TubeX1.1.1A usefulflat glass test tube for holding tarnishedcopper strips for inspection or for storage for later inspection isillustrated and dimensioned in Fig.X1.1.X1.2Strip ViseX1.2.1A useful and convenient vise for holding up to fourcopper strips duringfinal polishing is illustrated and dimen-sioned in Fig.X1.2.N OTE1—Dimensions in millimetres.N OTE2—The dimensions are the minimum dimensions that shall allowthe introduction of a copper strip.N OTE3—The tube shall be free of striae or similar defects.FIG.X1.1Flat Glass Viewing Test TubeKey:1Material:Plastic2Material:Brass3Wing nut4Ø5-mm metric thread or equivalentN OTE—Dimensions in millimetres.FIG.X1.2Multistrip ViseASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentioned in this ers of this standard are expressly advised that determination of the validity of any such patent rights,and the risk of infringement of such rights,are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed everyfive years and if not revised,either reapproved or withdrawn.Your comments are invited either for revision of this standard or for additional standards and should be addressed to ASTM International Headquarters.Your comments will receive careful consideration at a meeting of the responsible technical committee,which you may attend.If you feel that your comments have not received a fair hearing you should make your views known to the ASTM Committee on Standards,at the address shown below.This standard is copyrighted by ASTM International,100Barr Harbor Drive,PO Box C700,West Conshohocken,PA19428-2959, United States.Individual reprints(single or multiple copies)of this standard may be obtained by contacting ASTM at the above address or at610-832-9585(phone),610-832-9555(fax),or service@(e-mail);or through the ASTM website ().。
石油产品铜片腐蚀性测试及综合实验设计
石油产品铜片腐蚀性测试及综合实验设计
1.实验目的：
通过测试石油产品对铜片的腐蚀性能，评估其对金属材料的损伤程度，并设计综合实验以验证不同条件下的腐蚀性能。
2.实验材料：
-不同种类的石油产品样品
-铜片
-实验设备和仪器：例如恒温恒湿箱、电子天平、显微镜等
3.实验步骤：
a.准备铜片样品：使用无尘纸擦拭铜片表面，确保干净无污染。
b.将不同种类的石油产品样品分别涂抹在铜片上，涂层均匀。
c.将涂有石油产品的铜片置于恒温恒湿箱中，设定一定的温度和湿度条件。
d.定期观察铜片表面的变化，记录腐蚀情况，可以使用显微镜观察细节。
e.根据实验需要，可以改变温度、湿度或使用不同浓度的石油产品来进行对比实验。
f.实验结束后，使用电子天平测量铜片的质量变化，评估腐蚀程度。
4.实验结果分析：
a.比较不同石油产品样品对铜片的腐蚀性能，分析其腐蚀程度和差异。
b.对于综合实验设计，可以探究不同温度、湿度、石油产品浓度对腐蚀性能的影响，分析相关规律。
5.实验结论：
根据实验结果，可以得出不同石油产品对铜片的腐蚀性能，以及其受温度、湿度等条件变化的影响。
这些结论有助于评估石油产品的腐蚀性能，并为相关行业提供参考和指导。
油品铜片腐蚀测试方法
油品铜片腐蚀测试方法
石油产品铜片腐蚀试验是目前工业润滑油最主要的腐蚀性测定法，科标能源实验室是专业的第三方检测机构，专注于油品检测，同样也是采用此方法测定油品的腐蚀性能。
检测标准方法
GB/T5096
ASTM D130
ISO2160
SH/T0195
试验方法概要是：
把一块已磨光好的铜片浸没在一定量的试样中，并按产品标准要求加热到指定的温度，保持一定的时间。
待试验周期结束时，取出铜片，在洗涤后与标准色板进行比较，确定腐蚀级别。
工业润滑油常用的试验条件为100℃（或120℃），3h。
1、试验铜片放入试管油样中，恒温50摄氏度+1，放置3hr+5min对照腐蚀标准色板。
分级（1a、1b、2a、2b、2c、2d、2e、3a、3b、3c、4a、4b）。
2.指标为在100℃+1,3h条件下将铜片置于被测溶液中，试验过程中铜片表面受待测式样的侵蚀程度，腐蚀程度共分四级；
1：轻度变色----------淡橙色，几乎与新麽的铜片一样；深橙色
2：中度变色----------紫红色；淡红色；带有淡紫色或银色，或两种都有，并分别覆盖在紫红色上的多彩色；银色；黄铜色或金黄色
3：深度变色-----------洋红色覆盖在黄铜色上的多彩色；有红和绿显示的多彩色（孔雀绿），但不带灰色
4：腐蚀---------------透明的黑色，深灰色或仅带有孔雀绿的棕色；石墨黑色或无光泽的黑色；有光泽的黑色或乌黑发亮的黑色。
石油产品铜片腐蚀的试验方法
石油产品铜片腐蚀的试验方法（GB/T5096）北京时代新维测控设备有限公司生产的TP582铜片腐蚀测定仪是依据GB/T5096研制，适用于测定航空汽油，喷气燃料，车用汽油，天然气有或具有雷德蒸气压不大于124千帕斯卡（930mm汞柱）的其他烃类，溶剂油，柴油，馏分燃料油，润滑油和其他石油产品对铜片腐蚀的程度。
为什么要测量石油产品中的铜片腐蚀呢？因为原油是含酸的，所以绝大多数从原油生产出来的产品都有一定的酸性（腐蚀性），铜片腐蚀就是测量石油产品的腐蚀性；不同指标的用于不同级别的终端，例如：液化气中的腐蚀性，对钢材设备有微量的腐蚀性，对橡胶有溶化作用，灌装液化气终端都有塑料管，腐蚀性大，肯定会产生危险。
下面具体介绍下铜片腐蚀测定仪的试验方法：铜片腐蚀设备用于测定柴油、汽油、润滑油或其他石油产品对铜的腐蚀性程度,本方法涉及到易燃材料,操作前要注意试样的燃点、闪点,操作时要注意安全. 铜片的准备：1、用夹具纵向夹紧铜片，先用比较粗的砂纸（目数越低砂纸越粗）把铜片的瑕疵去掉，可来回调换夹具上铜片的方向，使铜片的六个面上所有部位上的瑕疵和以前打磨的痕迹都去掉，打磨完后可以用定量的滤纸擦去铜片上的金属屑，此时可以把铜片放入洗涤溶剂中清洗后擦干再进行最后磨光，也可以直接进行最后磨光，打磨的铜片均要拿镊子或滤纸来拿，不可以用手触摸。
2、用目数较高的砂纸打磨铜片或用蘸了砂粒的脱脂棉打磨铜的表面，磨时尽量沿铜片的长轴方向打磨。
3、在铜片打磨光亮后用脱脂棉擦去金属屑，铜片擦干净后放入准备好的试样中。
试验过程:1、取样：取30 毫升的试样倒入试验试管中，试样尽量保存在干净、深色的玻璃瓶内，试管要干燥、清洁。
2、不同的试样采用不同的试验步骤：A、润滑油、溶剂油、煤油:量取30 毫升完全清澈、无悬浮水或内含水的试样倒入清洁、干燥并带有试管夹的试管中，将最后磨光、干净的铜片放入该试管的试样中，把带有试管夹的试管放到已维持在100±1℃的浴中，在浴中放置3±5 小时后取出试管，检查铜片。
石油产品铜片腐蚀试验法(GB-T5096-1985)
实验步骤
• 把试管的内容物倒入150毫升高型烧杯中，倒时 要让铜片轻轻地滑入，以避免碰破烧杯。用不锈 钢镊子立即将铜片取出，浸入洗涤溶剂中，洗去 试样。立即取出铜片，用定量滤纸吸干铜片上的 洗涤溶剂。把铜片与腐蚀标准色板比较来检查变 色或腐蚀迹象。比较时，把铜片和腐蚀标准色板 对光线成45度角折射的方式拿持，进行观察。
腐蚀标准色板
• 本方法用的腐蚀标准色板是由全色加工复制而成的。它是 在一块铝薄板上印刷四色加工而成，腐蚀标准色板是由代 表失去光泽表面和腐蚀增加程度的典型试验铜片组成(见 下表)。为了保护起见，这些腐蚀标准色板嵌在塑料板中。 在每块标准色板的反面给出了腐蚀标准色板的使用说明。 为了避免色板可能褪色，腐蚀标准色板应避光存放。试验 用的腐蚀标准色板要用另一块在避光下仔细地保护的(新 的)腐蚀标准色板与它进行比较来检查其褪色情况。在散 射的日光(或与散射的日光相当的光线)下，对色板进行观 察：先从上方直接看，然后再从45度角看。如果观察到有 任何褪色的迹象，特别是在腐蚀标准色板的最左边的色板 有这种迹象，则废弃这块色板。
GB-T 5096-1985 《石油产品铜片腐蚀试验法》
二0一0年十二月
适用范围
•
本方法适用于测定航空汽油、喷气燃料、车用汽油、天 然汽油或具有雷德蒸气压不大于 124千帕斯卡(930毫米汞 柱 ) 的其他烃类、溶剂油、煤油、柴油、馏分燃料油、润 滑油和其他石油产品对铜的腐蚀性程度。 • 注意：某些石油产品，特别是天然汽油，其蒸气压比车用 汽油或航空汽油的蒸气压更高。因此，必须特别注意，不 要把装有高蒸气压的天然汽油或其他产品的试验弹放在 100℃浴中。雷德蒸气压超过 124千帕斯卡 (930毫米汞柱 ) 的试样要采用SY2083-85《液化石油气铜片腐蚀试验法》 来测定其腐蚀性。
油品腐蚀测定实验报告
油品腐蚀测定实验报告1. 实验目的本实验旨在通过对不同油品的腐蚀性进行测定，评估其对金属材料的腐蚀程度，为油品的选择和使用提供参考依据。
2. 实验原理腐蚀是指金属在与其周围介质接触时，由于电化学反应而产生的一种化学变化。
油品作为一种常见的润滑材料和润滑介质，在与金属发生接触时，也会产生腐蚀现象。
本实验采用重量损失法来评估油品对金属材料的腐蚀性。
具体步骤如下：1. 清洗金属试样，使其表面干净、无杂质。
2. 将未知油品样品与金属试样接触一段时间。
3. 取出金属试样，用乾燥纸巾将其表面上的油品擦净。
4. 用精密天平称量金属试样的质量。
5. 将金属试样放入烘箱中加热干燥，直至试样的质量不再发生变化。
6. 计算金属试样的质量损失，作为油品对金属的腐蚀程度的评估指标。
3. 实验材料和设备- 金属试样（不同种类和规格）- 未知油品样品- 乾燥纸巾- 精密天平- 烘箱4. 实验步骤1. 将金属试样放入洗涤剂中浸泡10分钟，用流动水冲洗干净。
2. 用无水酒精擦拭金属试样表面，保证其干净无杂质。
3. 将试管中的未知油品样品倒入培养皿中。
4. 将金属试样放入培养皿中，与油品样品接触3小时。
5. 取出金属试样，用乾燥纸巾将其表面上的油品擦净。
6. 用精密天平称量金属试样的质量，并记录下来。
7. 将金属试样放入烘箱中加热干燥，直至试样的质量不再发生变化，再次称量并记录质量。
8. 计算金属试样的质量损失，作为油品对金属的腐蚀程度的评估指标。
5. 实验结果与分析在本次实验中，我们使用了三种不同的油品样品A、B和C，分别与金属试样接触3小时后进行测量和比较。
实验结果如下表所示：油品样品金属试样质量损失（g）A 0.02B 0.05C 0.08通过测量结果可以看出，油品样品C对金属试样的腐蚀程度最大，而油品样品A 的腐蚀性最小。
这说明油品样品C可能含有一些腐蚀性物质，而油品样品A中这些物质的含量较低。
根据这些数据，我们可以给出油品样品的腐蚀性评估，提供选择和使用油品的参考依据。
铜片腐蚀 标准
铜片腐蚀标准
摘要：
一、铜片腐蚀的概念与意义
二、铜片腐蚀的标准与方法
三、铜片腐蚀的测定设备
四、铜片腐蚀的判断与等级
五、铜片腐蚀的应用领域
正文：
一、铜片腐蚀的概念与意义
铜片腐蚀是指在特定环境条件下，铜片与腐蚀介质发生化学反应，导致铜片表面出现损害、颜色变化等现象。
铜片腐蚀的检测对于评估金属材料的耐蚀性、选材以及防腐措施的制定具有重要意义。
二、铜片腐蚀的标准与方法
铜片腐蚀的标准主要依据中华人民共和国石油化工行业标准SH/T 0232《液化石油气铜片腐蚀试验法》进行。
方法包括：恒温浴法、电化学法、重量法等。
三、铜片腐蚀的测定设备
铜片腐蚀测定仪是按照相关标准设计的设备，用于检测石油产品等对铜片的腐蚀程度。
主要性能特点包括：不锈钢浴槽，数显控温，温控表控制温度，四孔，可悬挂四弹或12 支试管，带计时器，计时结束自动报警等。
四、铜片腐蚀的判断与等级
铜片腐蚀的判断主要依据标准色板进行，通过比较腐蚀后的铜片表面颜色
与标准色板的差异，判断腐蚀等级。
常见的铜片腐蚀等级包括：1a、1b、2a、2b、2c 等。
GBT5096 铜片腐蚀实验法
概况 实验准备
试验步骤
结果评定
试验总结
“ GB17930-2016 车用汽油（Ⅵ）
铜片腐蚀（50℃，3h）
不大于1
GB19147-2016 车用柴油（Ⅵ）
铜片腐蚀（50℃，3h） GB252-2015 普通柴油
论论文概文绪况绪论论 研研究究实背验背景设景备 研研究究方方法试法验 研步研究骤究结结果果 结问问果题题评讨讨定论论 论论文文试总总验结结总 结
2.6铜片准备
2.6.2铜片磨光
1、表面磨光 先用粗砂出去上次实验所残留的瑕疵和蚀污。然后用P220（65um）砂 纸处理，除去打磨痕迹，用滤纸擦去铜片表面的金属屑，将铜片浸泡在 洗涤溶剂中随后取出做最后磨光或贮存于洗涤剂中备用。
2、方法概要 把一块已磨光好的铜片浸没在一定体积的试样中，根据产品
的类别加热到规定定的温度，并保持一定的时间。待加热周期 结束时，取出铜片，经洗涤后，将其与铜片腐蚀标准色板进行 比较，确定腐蚀级别。 车用汽油、柴油常用实验条件为50℃，3h 工业润滑油常用的试验条件为100℃(或120℃)，3h。
论 文概绪况论 研实验究准背备景 研试究备方样法制 研试究验结步果骤 问结题果讨计论算 与论评文定总 结试 验 总 结
2.5 样品准备
2.5.1取样 按照GB/T4756标准方法进行取样，样品应贮存于深色样品瓶，镀锡容器
会影响样品的腐蚀性，因此不能使用镀锡容器盛装样品。 挥发性样品建议充满至容器容量70~80%即可，取样要小心，要避免将样
品暴露在阳光下。 2.5.2 样品准备
取回的样品应尽快进行实验 如果观察到样品有悬浮水（浑浊），要先用中速定量滤纸过滤干燥足够 实验的样品。过滤操作要避光，最好在暗室中进行。
石油产品铜片腐蚀测定法
GB/T 5096-1985
中国石油内蒙古销售公司
三、仪器、材料、试剂准备——试剂与材料
n 夹具：供磨片时夹住铜片而不损坏边缘用。
GB/T 5096-1985
中国石油内蒙古销售公司
三、仪器、材料、试剂准备——试剂与材料
n 温度计：0~50℃（全浸），最小分度值1℃或小于 1℃。
GB/T 5096-1985
50
快速法 (Q/SY1438-2011)
90
试验时间（分 钟）
180
30
GB/T 5096-1985
中国石油内蒙古销售公司
主要内容
1 2 3 4 5 6 7 8
GB/T 5096-1985
方法概要
测定意义 仪器、材料、试剂准备
实验 结果的表示及判断
结果报告 国家标准与快速法的比较
注意事项
中国石油内蒙古销售公司
1 2 3 4 5 6 7 8
GB/T 5096-1985
方法概要
测定意义 仪器、材料、试剂准备
实验 结果的表示及判断
结果报告 国家标准与快速法的比较
注意事项
中国石油内蒙古销售公司
五、结果的表示及判断（ 附表）
分级 1
2
名称 轻度 变色
中度 变色
说明
a 淡橙色，几乎与新磨光的铜片一样 b 深橙色
a 紫红色 b 淡紫色 c 带有淡紫蓝色，或银色，或两种都有，并分别覆盖 在紫红色上的多彩色 d 银色 e 黄铜色或金黄色
中国石油内蒙古销售公司
四、实验——步骤
n 把被测油样，倒入清洁、干燥的试管中30mL刻线 处。（铜片腐蚀按国标需做平行试验，需两个试样）
GB/T 5096-1985
石油产品铜片腐蚀试验法(GB-T5096-1985)
实验步骤
• 把试管的内容物倒入150毫升高型烧杯中，倒时 要让铜片轻轻地滑入，以避免碰破烧杯。用不锈 钢镊子立即将铜片取出，浸入洗涤溶剂中，洗去 试样。立即取出铜片，用定量滤纸吸干铜片上的 洗涤溶剂。把铜片与腐蚀标准色板比较来检查变 色或腐蚀迹象。比较时，把铜片和腐蚀标准色板 对光线成45度角折射的方式拿持，进行观察。
注：①铜片腐蚀标准色板是由表中这些说明所表示的色板组成的。 ② 此系列中所包括的新磨光铜片，仅作为试验前磨光铜片的外碑标志。 使一个完全不腐蚀的试样经试验后也不可能重现这种外观。
即
样品前处理
• 表面准备：为了有效地达到预期的结果，需先用碳化硅或氧化铝砂纸 把铜片六个面上的瑕疵去掉。再用65微米(240粒度)的碳化硅或氧化 铝砂纸处理，以除去在此以前用其他等级砂纸留下的打磨痕迹。用定 量滤纸擦去铜片上的金属屑后，把铜片浸没在洗涤溶剂中。铜片从洗 涤溶剂中取出后，可直接进行最后磨光，或贮存在洗涤溶剂中备用。 • 最后磨光：从洗涤溶剂中取出铜片，用无灰滤纸保护手指来夹拿铜片。 取一些105微米的碳化硅或氧化铝砂粒放在玻璃板上，用l滴洗涤溶剂 湿润，并用一块脱脂棉，蘸取砂粒。用不锈钢镊子夹持铜片，千万不 能接触手指。先摩擦铜片各端边，然后将铜片夹在夹钳上，用沾在脱 脂棉上的砂粒磨光主要表面。磨时要沿铜片的长轴力向，在返回来磨 以前，使动程越出铜片的末端。用一块干净的脱脂棉使劲地摩擦铜片， 以除去所有的金属屑，直到用一块新的脱脂棉擦拭时不再留下污斑为 止。当铜片擦净后，马上浸入已准备好的试样中。
结果表示
• 按前表中所列的腐蚀标准色板的分级中，某一个腐蚀级表 示试样的腐蚀性。 • 当铜片是介于两种相邻的标准色板之间的腐蚀级时，则按 其变色严重的腐蚀级判断试样。当铜片出现有比标准色板 中l b还深的橙色时，则认为铜片仍属1级；但是，如果观 察到有红颜色时，则所观察的铜片判断为2 级。 • 2级中紫红色铜片可能被误认为黄铜色完全被洋红色的色 彩所覆盖的3级。为了区别这两个级别，可以把铜片浸没 在洗涤溶剂中。2级会出现一个深橙色，而3级不变色。
石油产品铜片腐蚀测定方法步骤
石油产品铜片腐蚀测定方法步骤仪器、材料、试剂准备1.铜片腐蚀测定仪2.带胶塞的试管3.比色试管：扁平型，实验结束供检验，或储存期间供盛放腐蚀的铜片用4.夹具:供磨片时夹住铜片而不损坏边缘用5.温度计6.磨光材料：碳化硅或氧化铝砂纸7.不锈钢试验弹8.铜片：纯度大于99.99%的电解铜9.定量滤纸：吸干滤纸上的洗涤溶剂10.不锈钢镊子11.洗涤溶剂：分析纯异辛烷或标准异辛烷12.高型烧杯13.腐蚀标准色板：避光存放实验准备1.铜片处理：用碳化硅或氧化铝砂纸把铜片六面瑕疵去掉，经过打磨后的铜片要求无瑕疵、无污斑、无金属屑，颜色均匀；2.用定量滤纸擦去铜片上的金属屑后，将铜片浸泡在洗涤溶剂中；3.从洗涤溶剂中取出铜片，用一滴洗涤剂湿润铜片，并用一块脱脂棉擦铜片，以除去所有金属屑；4.铜片腐蚀仪器设备检查（1）检查仪器电源、机壳是否接地良好；（2）检查水浴是否达到试验操作要求水位；（3）检查浴内温度传感器是否正常；实验步骤1.将试验仪器放置平稳，接通电源，使水浴温度维持在50O C±1O C；2.把被测油样倒入清洁、干燥的试管中；3.将经过最后磨光、干净的铜片在1分钟内浸入该试管的试样中；4.把该试管放到温度维持在50O C±1O C的水浴中，记录实验开始时间；5.在水浴中放置3小时±5分钟后，从仪器中取出装有铜片的试管；6.用不锈钢镊子立即将铜片从试管中取出，浸入放有洗涤溶剂的高烧杯中，洗去试样；7.立即取出铜片，用定量滤纸吸干铜片上的洗涤溶剂；8.把铜片与腐蚀标准色板比较，来检查变色或腐蚀迹象，比较时，可将铜片放在扁平试管中，将铜片和腐蚀标准色板对光线成45O角折射的方式拿持，进行观察实验结果。
石油产品铜片腐蚀测定仪校准方法的探讨
石油产品铜片腐蚀测定仪校准方法的探讨
蒋伟
【期刊名称】《计量与测试技术》
【年(卷),期】2024(51)6
【摘要】石油产品铜片腐蚀测定仪是根据GB/T 5096-2017国家标准和GB/T 5096-2017国家标准的要求设计制造,主要用于评定航空汽油、航空涡轮燃料、车用汽油、农用拖拉机燃料、洗涤溶剂、煤油馏分燃料和润滑油等石油产品对铜片腐蚀的程度。
其准确与否直接影响测试产品的好坏,但目前国家未有可依据的校准规范。
本文简述了该测定仪的校准方法,并对主要试验参数进行分析,提出了一种可行性校准方法。
【总页数】3页(P74-76)
【作者】蒋伟
【作者单位】安徽省长江计量所(九一○所)
【正文语种】中文
【中图分类】F42
【相关文献】
1.石油产品铜片腐蚀试验结果判定方法的改进初见
2.石油产品酸值测定仪校准方法
3.研究石油产品酸值测定仪校准方法
4.基于密度计法的石油产品密度测定仪温度参数校准方法研究
5.石油产品光安定性测定仪校准方法研究及不确定度分析
因版权原因，仅展示原文概要，查看原文内容请购买。
液化石油气铜片腐蚀试验法
安全管理/行业安全液化石油气铜片腐蚀试验法一、概述铜片腐蚀：在规定条件下，测试液化石油气对铜的腐蚀趋向的试验。
液化石油气的铜片腐蚀试验，主要是测定液化石油气的腐蚀性程度。
因为液化石油气在储运及使用过程中，均采用金属容器罐装，如果液化石油气腐蚀性过强，就会造成储运设备，容器的严重腐蚀，致使缩短使用期限，甚至引发其他危险。
因此，这项试验有重要意义。
我国现行的液化石油气铜片腐蚀试验法是采用SH／T 0232《液化石油气铜片腐蚀试验法》，该方法等效采用ISO 6521-1982《液化石油气铜片试验法》。
二、原理将磨光的铜片，全部浸入装有100mL已被水饱和的试样的容器中，该容器应具有一定的工作压力(≥7.0MPa)，在40℃温度下放置1h，取出后与标准色板比较，判断其腐蚀级别。
三、仪器设备(1)铜片腐蚀试验弹：由不锈钢制成，容量约160mL。
整套组件应能经受约7.0MPa的静压试验，当用气体约在3.5MPa压力下试验时应无泄漏，见图1-6-4。
(2)恒温水浴：能够维持40℃±0.5℃的水温并配有使试验弹保持垂直的悬架或支架，有足够的空间可以将整个圆筒(包括阀)浸没。
(3)水银温度计：全浸0～50℃分度0.1℃。
(4)铜片磨光夹具：磨铜片用，能够夹紧铜片且不损伤铜片边缘，方便铜片磨光操作即可。
四、材料(1)洗涤溶剂：标准异辛烷，或其他无硫烃类溶剂，例如石油醚(90～120℃)。
图1-6-4 铜片腐蚀试验弹1-6mm的针型阀A；2-氯丁橡胶O形密封圈；3-铜片；4-6mm的针型阀B(2)铜片：电解铜，纯度99.9％以上，长7.5cm，宽1.25cm，厚0.15～0.30cm，表面光滑经冷轧淬硬，且在一端中心3.0mm 处钻一直径为3.0mm的小孔。
(3)磨光材料：65μm碳化硅或刚玉砂纸、砂布，抛光用150目的碳化硅或刚玉砂，以及药用脱酯棉。
五、标准色板(1)腐蚀标准色板为全色复制品。
它是在铝板上通过四道色加工处理印成的。
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LOGO石油产品铜片腐蚀测定法GB/T 5096-1985GB/T5096-1985中国石油内蒙古销售公司检测标准要求GB17930-2011车用汽油（Ⅲ）（Ⅳ）铜片腐蚀（50℃，3h）不大于1GB19147-2013车用柴油（Ⅲ）（Ⅳ）铜片腐蚀（50℃，3h）不大于1GB252-2011普通柴油铜片腐蚀（50℃，3h）不大于1GB/T5096-1985中国石油内蒙古销售公司主要内容1方法概要2测定意义3仪器、材料、试剂准备4实验5结果的表示及判断6结果报告7国家标准与快速法的比较8注意事项GB/T5096-1985中国石油内蒙古销售公司一、方法概要把一块已磨光好的铜片浸没在30ml的试样中，加热到指定的温度，保持一定的时间。
待试验周期结束时，取出铜片，经洗涤后与腐蚀标准色板进行比较，确定腐蚀级别。
GB/T5096-1985中国石油内蒙古销售公司主要内容1方法概要2测定意义3仪器、材料、试剂准备4实验5结果的表示及判断6结果报告7国家标准与快速法的比较8注意事项GB/T5096-1985中国石油内蒙古销售公司二、测定意义n可以判断油品中是否含有腐蚀金属的活性硫化物等杂质。
n通过铜片腐蚀试验，可以预知燃料在储存、运输和使用过程中，对金属产生腐蚀的可能性。
GB/T5096-1985中国石油内蒙古销售公司主要内容1方法概要2测定意义3仪器、材料、试剂准备4实验5结果的表示及判断6结果报告7国家标准与快速法的比较8注意事项GB/T5096-1985中国石油内蒙古销售公司三、仪器、材料、试剂准备——仪器n铜片腐蚀测定仪GB/T5096-1985中国石油内蒙古销售公司三、仪器、材料、试剂准备——试剂与材料n带胶塞的试管：长150mm，外径25mm，壁厚1mm～2mm。
在试管30mL处刻有一环线GB/T5096-1985中国石油内蒙古销售公司三、仪器、材料、试剂准备——试剂与材料n比色试管：扁平形，试验结束供检验或储存期间供盛放腐蚀的铜片用。
GB/T5096-1985中国石油内蒙古销售公司三、仪器、材料、试剂准备——试剂与材料n夹具：供磨片时夹住铜片而不损坏边缘用。
GB/T5096-1985中国石油内蒙古销售公司三、仪器、材料、试剂准备——试剂与材料n温度计：0~50℃（全浸），最小分度值1℃或小于1℃。
GB/T5096-1985中国石油内蒙古销售公司三、仪器、材料、试剂准备——试剂与材料n磨光材料：65μm（240粒度）的碳化硅或氧化铝砂纸，105μm（150目）的碳化硅或氧化铝砂粒。
GB/T5096-1985中国石油内蒙古销售公司三、仪器、材料、试剂准备——试剂与材料n试验弹：用不锈钢制作。
GB/T5096-1985中国石油内蒙古销售公司三、仪器、材料、试剂准备——试剂与材料n铜片：纯度大于99.9%的电解铜，宽为12.5mm，厚为1.5-3.0mm，长为75mm。
GB/T5096-1985中国石油内蒙古销售公司三、仪器、材料、试剂准备——试剂与材料n定量滤纸：吸干滤纸上的洗涤溶剂。
(直径为11cm)GB/T5096-1985中国石油内蒙古销售公司三、仪器、材料、试剂准备——试剂与材料n镊子：不锈钢材质。
GB/T5096-1985中国石油内蒙古销售公司三、仪器、材料、试剂准备——试剂与材料n洗涤溶剂：分析纯异辛烷或标准异辛烷。
GB/T5096-1985中国石油内蒙古销售公司三、仪器、材料、试剂准备——试剂与材料n高型烧杯：150mlGB/T5096-1985中国石油内蒙古销售公司三、仪器、材料、试剂准备——试剂与材料n腐蚀标准色板：避光存放GB/T5096-1985中国石油内蒙古销售公司主要内容1方法概要2测定意义3仪器、材料、试剂准备4实验5结果的表示及判断6结果报告7国家标准与快速法的比较8注意事项GB/T5096-1985中国石油内蒙古销售公司四、实验——准备n铜片处理Ø用65μm（240粒度）的碳化硅或氧化铝（刚玉）砂纸把铜片上的六面上的瑕疵去掉；再用105μm（150目）的砂纸处理，经过打磨后的铜片要求无瑕疵，无污斑，无金属屑，颜色均匀。
GB/T5096-1985中国石油内蒙古销售公司四、实验——准备Ø用定量滤纸擦去铜片上的金属屑后，把铜片浸没在洗涤溶剂中。
GB/T5096-1985中国石油内蒙古销售公司四、实验——准备n从洗涤溶剂中取出铜片，用1滴洗涤溶剂湿润，并用一块脱脂棉擦铜片，以除去所有金属屑。
GB/T5096-1985中国石油内蒙古销售公司四、实验——准备铜片腐蚀仪器设备检查1、检查仪器电源、机壳是否接地良好。
2、检查水浴是否达到试验操作要求水位。
3、检查浴内温度传感器是否正常。
GB/T5096-1985中国石油内蒙古销售公司四、实验——步骤n将试验仪器放置平稳，接通电源，使水浴温度维持在50±1℃。
GB/T5096-1985中国石油内蒙古销售公司四、实验——步骤n把被测油样，倒入清洁、干燥的试管中30mL刻线处。
（铜片腐蚀按国标需做平行试验，需两个试样）GB/T5096-1985中国石油内蒙古销售公司四、实验——步骤n将经过最后磨光、干净（无瑕疵，无污斑，无金属屑，颜色均匀）的铜片在1分钟内浸入该试管的试样中。
注意事项：铜片放入试样中的过程使用镊子，不要用手直接拿取。
GB/T5096-1985中国石油内蒙古销售公司四、实验——步骤n把该试管放到已维持在50±1℃的水浴中，记录实验开始时间。
GB/T5096-1985中国石油内蒙古销售公司四、实验——步骤n在水浴中放置3小时±5分钟后，从仪器中取出装有铜片的试管。
注意事项：准确掌握操作时间，时间过长或过短均影响操作结果。
GB/T5096-1985中国石油内蒙古销售公司四、实验——步骤n用不锈钢镊子立即将铜片从试管中取出，浸入放有洗涤溶剂的150mL高型烧杯中，洗去试样。
GB/T5096-1985中国石油内蒙古销售公司四、实验——步骤n立即取出铜片，用定量滤纸吸干铜片上的洗涤溶剂。
GB/T5096-1985中国石油内蒙古销售公司四、实验——步骤n把铜片与腐蚀标准色板比较来检查变色或腐蚀迹象。
比较时，可将铜片放在扁平试管中（试管口要用脱脂棉塞住），将铜片和腐蚀标准色板对光线成45度角折射的方式拿持，进行观察。
GB/T5096-1985中国石油内蒙古销售公司主要内容1方法概要2测定意义3仪器、材料、试剂准备4实验5结果的表示及判断6结果报告7国家标准与快速法的比较8注意事项GB/T5096-1985中国石油内蒙古销售公司五、结果的表示及判断（附表）分级名称说明1轻度变色a淡橙色，几乎与新磨光的铜片一样b深橙色2中度变色a紫红色b淡紫色c带有淡紫蓝色，或银色，或两种都有，并分别覆盖在紫红色上的多彩色d银色e黄铜色或金黄色3深度变色a洋红色覆盖在黄铜色上的多彩色b有红和绿显示的多彩色（孔雀绿），但不带灰色4腐蚀a透明的黑色，深灰色或仅有孔雀绿的棕色b石墨黑色或无光泽的黑色c有光泽的黑色或乌黑发亮的黑色GB/T5096-1985中国石油内蒙古销售公司主要内容1方法概要2测定意义3仪器、材料、试剂准备4实验5结果的表示及判断6结果报告7国家标准与快速法的比较8注意事项GB/T5096-1985中国石油内蒙古销售公司六、结果报告按表中级别中的一个腐蚀级报告试样的腐蚀性，并报告试验时间和试验温度。
如果重复测定两个结果不相同，则重新进行试验。
当重新试验的两个结果仍不相同时，则按变色严重的腐蚀级来判断试样。
GB/T5096-1985中国石油内蒙古销售公司主要内容1方法概要2测定意义3仪器、材料、试剂准备4实验5结果的表示及判断6结果报告7国家标准与快速法的比较8注意事项GB/T5096-1985中国石油内蒙古销售公司七、国标与快速法的比较检验方法试验温度（℃）试验时间（分钟）国标（GB/T5096-1985)50180快速法(Q/SY1438-2011)9030GB/T5096-1985中国石油内蒙古销售公司主要内容1方法概要2测定意义3仪器、材料、试剂准备4实验5结果的表示及判断6结果报告7国家标准与快速法的比较8注意事项GB/T5096-1985中国石油内蒙古销售公司八、注意事项n试验所用洗涤剂必须经铜片试验合格才能使用。
n试验所用铜片的纯度和规格必须符合标准规定。
n处理铜片表面时，要防止铜片与手接触，以免手上汗渍对结果造成影响。
n腐蚀标准色板应避光存放，否则影响结果判断。
n试样应避光储存，收到试样，尽快进行腐蚀试验。
n避免铜片与水接触影响试验结果。
n防止铜片与空气接触，磨光的铜片要马上浸入已准备好的试样；放入时小心滑入，以避免打碎试管。
LOGO GB/T5096-1985。