配合物稳定常数

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金属-无机配位体配合物的稳定常数(25℃)Stability Constants of Metal Ion-Inorganic Coordination Compounds

序号(No.)

配位体

(Ligand)

金属离子

(Metal

ion)

配位体数目n

(Number of

ligand)

lgβn

1 NH3Ag+ 1,

2 3.24,7.05

Au3+ 4 10.3

Cd2+1,2,3,4,5,6 2.65,4.75,6.19,7.12,6.80,5.14

Co2+1,2,3,4,5,6 2.11,3.74,4.79,5.55,5.73,5.11

Co3+1,2,3,4,5,6 6.7,14.0,20.1,25.7,30.8,35.2

Cu+1,2 5.93,10.86

Cu2+ 1,2,3,4,5 4.31,7.98,11.02,13.32,12.86

Fe2+1,2 1.4,2.2

Hg2+1,2,3,4 8.8,17.5,18.5,19.28

Mn2+1,2 0.8,1.3

Ni2+1,2,3,4,5,6 2.80,5.04,6.77,7.96,8.71,8.74

Pd2+1,2,3,4 9.6,18.5,26.0,32.8

Pt2+ 6 35.3

Zn2+1,2,3,4 2.37,4.81,7.31,9.46

2 Br-Ag+1,2,3,4 4.38,7.33,8.00,8.73

Bi3+1,2,3,4,5,6 2.37,4.20,5.90,7.30,8.20,8.30

Cd2+1,2,3,4 1.75,2.34,3.32,3.70,

Ce3+ 1 0.42

Cu+ 2 5.89

Cu2+ 1 0.30

Hg2+1,2,3,4 9.05,17.32,19.74,21.00

In3+1,2 1.30,1.88

Pb2+1,2,3,4 1.77,2.60,3.00,2.30

Pd2+1,2,3,4 5.17,9.42,12.70,14.90

Rh3+2,3,4,5,6 14.3,16.3,17.6,18.4,17.2

Sc3+1,2 2.08,3.08

Sn2+1,2,3 1.11,1.81,1.46

Tl3+1,2,3,4,5,6 9.7,16.6,21.2,23.9,29.2,31.6

U4+ 1 0.18

Y3+ 1 1.32

3 Cl-Ag+1,2,

4 3.04,5.04,5.30

Bi3+1,2,3,4 2.44,4.7,5.0,5.6

Cd2+1,2,3,4 1.95,2.50,2.60,2.80

Co3+ 1 1.42

Cu+2,3 5.5,5.7

Cu2+1,2 0.1, -0.6

Fe2+ 1 1.17

Fe3+ 2 9.8

Hg2+1,2,3,4 6.74,13.22,14.07,15.07

In3+1,2,3,4 1.62,2.44,1.70,1.60

Pb2+1,2,3 1.42,2.23,3.23

Pd2+1,2,3,4 6.1,10.7,13.1,15.7

Pt2+2,3,4 11.5,14.5,16.0

Sb3+1,2,3,4 2.26,3.49,4.18,4.72

Sn2+1,2,3,4 1.51,2.24,2.03,1.48

Tl3+1,2,3,4 8.14,13.60,15.78,18.00

Th4+1,2 1.38,0.38

Zn2+1,2,3,4 0.43,0.61,0.53,0.20

Zr4+1,2,3,4 0.9,1.3,1.5,1.2

4 CN-Ag+2,3,4 21.1,21.7,20.6

Au+ 2 38.3

Cd2+1,2,3,4 5.48,10.60,15.23,18.78

Cu+2,3,4 24.0,28.59,30.30

Fe2+ 6 35.0

Fe3+ 6 42.0

Hg2+ 4 41.4

Ni2+ 4 31.3

Zn2+1,2,3,4 5.3,11.70,16.70,21.60

5 F-Al3+1,2,3,4,5,

6 6.11,11.12,15.00,18.00,19.40,19.80

Be2+1,2,3,4 4.99,8.80,11.60,13.10

Bi3+ 1 1.42

Co2+ 1 0.4

Cr3+1,2,3 4.36,8.70,11.20

Cu2+ 1 0.9

Fe2+ 1 0.8

Fe3+1,2,3,5 5.28,9.30,12.06,15.77

Ga3+1,2,3 4.49,8.00,10.50

Hf4+1,2,3,4,5,6 9.0,16.5,23.1,28.8,34.0,38.0

Hg2+ 1 1.03

In3+1,2,3,4 3.70,6.40,8.60,9.80

Mg2+ 1 1.30

Mn2+ 1 5.48

Ni2+ 1 0.50

Pb2+1,2 1.44,2.54

Sb3+1,2,3,4 3.0,5.7,8.3,10.9

Sn2+1,2,3 4.08,6.68,9.50

Th4+1,2,3,4 8.44,15.08,19.80,23.20

TiO2+1,2,3,4 5.4,9.8,13.7,18.0

Zn2+ 1 0.78

Zr4+1,2,3,4,5,6 9.4,17.2,23.7,29.5,33.5,38.3 6 I-Ag+1,2,3 6.58,11.74,13.68

Bi3+1,4,5,6 3.63,14.95,16.80,18.80

Cd2+1,2,3,4 2.10,3.43,4.49,5.41

Cu+ 2 8.85

Fe3+ 1 1.88

Hg2+1,2,3,4 12.87,23.82,27.60,29.83

Pb2+1,2,3,4 2.00,3.15,3.92,4.47

Pd2+ 4 24.5

Tl+1,2,3 0.72,0.90,1.08

Tl3+1,2,3,4 11.41,20.88,27.60,31.82 7 OH-Ag+1,2 2.0,3.99

Al3+1,4 9.27,33.03

As3+1,2,3,4 14.33,18.73,20.60,21.20

Be2+1,2,3 9.7,14.0,15.2

Bi3+1,2,4 12.7,15.8,35.2

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