水性汽车涂料用颜料
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颜料要在体系的基础上发挥性能 A pigment can only be as good as the system allows 一个不恰当的配方 不恰当的配方可以毁掉一个好颜料 不恰当的配方 a poor formulation can ruin an excellent pigment, 一个不适合的颜料选择 不适合的颜料选择可以毁掉一个高性能配方 不适合的颜料选择 a poor choice of pigment can ruin a high performance coating
Hansa
有限的耐溶剂性，应用于非烘烤体系 Pigments with limited solvent fastness for non-baking systems
室内装饰涂料 Interior Decorative
Lisa Zhang, BU Pigments, Coatings Business (Copyright Clariant. All rights reserved.)
较好性能颜料，但在某些性质上有缺陷， 如抗渗色性或者是耐 热性 Pigments with good performance, but deficits in some properties, such as bleeding or heat resistance
工业， 室内装饰涂料 Industrial, Interior Decorative
P.Y.150 Hostaperm Yellow HN4G
P.R.179 Hostaperm Red P2GL-WD
P.R.254 Hostaperm Red D3G 70
P.V.23 Hostaperm Violet RL special P.Y. 139 Novoperm Yellow M2R 70
Removal of “mother solution” Washing Removal of impurities Creation of aggregates and agglomerates
Removal of moisture Creation of clusters 去除水分 生成颜料群
Breaking up very big clusters 打破颜料群
Isoindoline/ Isoindolinone
H N
R N H3C N N O O H N O N H
O
O
N H
P.Y.74 Hansa Brilliant Yellow 2GX 70
P.Y. 154 Hostaperm Yellow H3G
P.R.122 Hostaperm Pink E P.B. 15:1 Hostaperm Blue A4R
范围 Range Hostaperm 定义 Definition 高性能颜料，抗渗色，耐候性在标准色深1/3时高于Hostaperm Red E5B 02 High performance pigments, bleeding resistance and weather fastness in SD 1/3 is equal to or better than Hostaperm Red E5B 02 Novoperm 在深色中有出色性能的高性能颜料，抗渗色，耐候性在标准色深 1/3时高于Novoperm Red F5RK High performance pigments with good performance in deep shades, bleeding resistance and weather fastness in SD1/3 is equal to or better than Novoperm Red F5RK Permanent 汽车， 工业 Automotive, Industrial 典型应用领域Typical Applications 所有应用领域 All
– Chemical configuration – Color strength – Compatibility – Bleeding
Test method for waterborne Automotive coating Pigments suitable for waterborne Automotive coating
Lisa Zhang, BU Pigments, Coatings Business (Copyright Clariant. All rights reserved.)
General knowledge of Pigments – Pigment – Pigment properties Trend of waterborne Automotive coating
3/13/2013
着色剂介绍 General knowledge of pigments
Public Lisa Zhang BU Pigments Technical Marketing BS Coating 16.08.2012
颜料制造工艺 Pigment production process
3/13/2013
Lisa Zhang, BU Pigments, Coatings Business (Copyright Clariant. All rights reserved.)
科莱恩颜料范围 Clariant pigment ranges
商品名和颜料应用范围定义 Trade names and definitions of ranges
合成 Synthesis 后处理 Finishing 过滤 Filtration 干燥 Drying 研磨 Milling
Chemistry of the pigment Making primary particles 颜料的化学结 构 制造初级粒子
Crystal growth Purification Surface treatment 晶体成长 提纯 “愈合”晶体 缺陷 表面处理
Lisa Zhang, BU Pigments, Coatings Business (Copyright Clariant. All rights reserved.)
PY 151
R=-COOH Hostaperm Yellow H4G
提高了分子间力和改善了耐溶剂性和耐久 性 Carbonic acid amide goups increase intermolecular forces and improve solvent fastness and durability
Organic Pigments Azo Pigments Polycyclic Pigments
Mono-Azo
Bis-Azo
Special Azo
Metal Complex
Quinacridone
Perylene
Di-ketopyrrolo-pyrrol
Carbazole
Phthalocyanine
水性汽车涂料有利于环保
Waterborne Automotive coating is good for the environment
去除“母液” 水洗 去除杂质 生成凝聚体和团聚体
Lisa Zhang, BU Pigments, Coatings Business (Copyright Clariant. All rights reserved.) 3/13/2013
重要有机颜料的结构 （部分） Important classes of organic pigments (part)
单偶氮颜料 Azo Pigments 苯并咪唑酮颜料 苯并咪唑酮颜料
Benzimidazolone Azo pigments
R N H3C O O N N H N O N H
P.Y.74 Hansa Brilliant Yellow 2GX 70 分子量和分子间键力太低无法提供汽车原厂漆所 需的耐候性和抗迁移性 Molecular weight and inter-molecular bonding are too weak to provide sufficient weather fastness and bleeding resistance for Automotive OEM
颜色 Color 透明性或者遮盖力Transparency or opacity 耐酸耐碱性 Alkaline and Acid Fastness 耐迁移 Fastness to bleeding 耐发花 Fastness to blooming 光泽 Gloss 雾影 Haze 指研 Rub-out 耐光性和耐候性 Light- and weather fastness 耐热性 Heat stability
水性汽车涂料用颜料 Pigments for waterborne Automotive coating
Public Lisa Zhang BU Pigments Technical Marketing BS Coating 16.08.2012
内Leabharlann Baidu Content
着色剂介绍 – 颜料 – 颜料的性能 水性汽车涂料发展趋势 Pigment-related problems in water based 颜料在水性里遇到的问题 – 化学结构 – 着色力 – 相容性 – 迁移 水性汽车涂料用颜料测试方法 适用于水性汽车涂料的颜料
3/13/2013
科莱恩命名补充 Nomenclature of suffices
70 例如E.g. Hostaperm Red D3G 70 – 表明颜料具有优化的遮盖性 Indicates a pigment optimized for opacity -EDS – 例如 E.g. Hosatperm Pink E-EDS – 表明此类颜料在溶剂体系的“易分散性”Indicates that a pigment is “easy to disperse” in solvent system -WD – 例如 E.g. Hostaperm Red P2GL-WD – 表明颜料被优化适用于水性涂料体系 Indicates that this pigment is optimized for use in water based paint systems -NF – 例如 E.g. Novoperm Orange HL 70-NF – 表明颜料表面经过处理具有较好的抗絮凝稳定性 Indicates a pigment with surface treatment to prevent flocculation 其他 Others – 高透明性和特殊应用 Transparent, special
–
Lisa Zhang, BU Pigments, Coatings Business (Copyright Clariant. All rights reserved.) 3/13/2013
水性汽车涂料发展趋势 Trend of waterborne Automotive coating
Public Lisa Zhang BU Pigments Technical Marketing BS Coating 16.08.2012
3/13/2013
颜料的性能 Pigment properties
在涂料中 In paint 在涂层中 In coating
絮凝 Flocculation 流变性 Rheology 分散性 Dispersibility 重结晶 Recrystallisation 沉降 Sedimentation
重点 Important to remember:
3/13/2013
P.Y.83 Novoperm Yellow HR 70
Lisa Zhang, BU Pigments, Coatings Business (Copyright Clariant. All rights reserved.)
颜料的化学结构 Chemical structure of pigment
Hansa
有限的耐溶剂性，应用于非烘烤体系 Pigments with limited solvent fastness for non-baking systems
室内装饰涂料 Interior Decorative
Lisa Zhang, BU Pigments, Coatings Business (Copyright Clariant. All rights reserved.)
较好性能颜料，但在某些性质上有缺陷， 如抗渗色性或者是耐 热性 Pigments with good performance, but deficits in some properties, such as bleeding or heat resistance
工业， 室内装饰涂料 Industrial, Interior Decorative
P.Y.150 Hostaperm Yellow HN4G
P.R.179 Hostaperm Red P2GL-WD
P.R.254 Hostaperm Red D3G 70
P.V.23 Hostaperm Violet RL special P.Y. 139 Novoperm Yellow M2R 70
Removal of “mother solution” Washing Removal of impurities Creation of aggregates and agglomerates
Removal of moisture Creation of clusters 去除水分 生成颜料群
Breaking up very big clusters 打破颜料群
Isoindoline/ Isoindolinone
H N
R N H3C N N O O H N O N H
O
O
N H
P.Y.74 Hansa Brilliant Yellow 2GX 70
P.Y. 154 Hostaperm Yellow H3G
P.R.122 Hostaperm Pink E P.B. 15:1 Hostaperm Blue A4R
范围 Range Hostaperm 定义 Definition 高性能颜料，抗渗色，耐候性在标准色深1/3时高于Hostaperm Red E5B 02 High performance pigments, bleeding resistance and weather fastness in SD 1/3 is equal to or better than Hostaperm Red E5B 02 Novoperm 在深色中有出色性能的高性能颜料，抗渗色，耐候性在标准色深 1/3时高于Novoperm Red F5RK High performance pigments with good performance in deep shades, bleeding resistance and weather fastness in SD1/3 is equal to or better than Novoperm Red F5RK Permanent 汽车， 工业 Automotive, Industrial 典型应用领域Typical Applications 所有应用领域 All
– Chemical configuration – Color strength – Compatibility – Bleeding
Test method for waterborne Automotive coating Pigments suitable for waterborne Automotive coating
Lisa Zhang, BU Pigments, Coatings Business (Copyright Clariant. All rights reserved.)
General knowledge of Pigments – Pigment – Pigment properties Trend of waterborne Automotive coating
3/13/2013
着色剂介绍 General knowledge of pigments
Public Lisa Zhang BU Pigments Technical Marketing BS Coating 16.08.2012
颜料制造工艺 Pigment production process
3/13/2013
Lisa Zhang, BU Pigments, Coatings Business (Copyright Clariant. All rights reserved.)
科莱恩颜料范围 Clariant pigment ranges
商品名和颜料应用范围定义 Trade names and definitions of ranges
合成 Synthesis 后处理 Finishing 过滤 Filtration 干燥 Drying 研磨 Milling
Chemistry of the pigment Making primary particles 颜料的化学结 构 制造初级粒子
Crystal growth Purification Surface treatment 晶体成长 提纯 “愈合”晶体 缺陷 表面处理
Lisa Zhang, BU Pigments, Coatings Business (Copyright Clariant. All rights reserved.)
PY 151
R=-COOH Hostaperm Yellow H4G
提高了分子间力和改善了耐溶剂性和耐久 性 Carbonic acid amide goups increase intermolecular forces and improve solvent fastness and durability
Organic Pigments Azo Pigments Polycyclic Pigments
Mono-Azo
Bis-Azo
Special Azo
Metal Complex
Quinacridone
Perylene
Di-ketopyrrolo-pyrrol
Carbazole
Phthalocyanine
水性汽车涂料有利于环保
Waterborne Automotive coating is good for the environment
去除“母液” 水洗 去除杂质 生成凝聚体和团聚体
Lisa Zhang, BU Pigments, Coatings Business (Copyright Clariant. All rights reserved.) 3/13/2013
重要有机颜料的结构 （部分） Important classes of organic pigments (part)
单偶氮颜料 Azo Pigments 苯并咪唑酮颜料 苯并咪唑酮颜料
Benzimidazolone Azo pigments
R N H3C O O N N H N O N H
P.Y.74 Hansa Brilliant Yellow 2GX 70 分子量和分子间键力太低无法提供汽车原厂漆所 需的耐候性和抗迁移性 Molecular weight and inter-molecular bonding are too weak to provide sufficient weather fastness and bleeding resistance for Automotive OEM
颜色 Color 透明性或者遮盖力Transparency or opacity 耐酸耐碱性 Alkaline and Acid Fastness 耐迁移 Fastness to bleeding 耐发花 Fastness to blooming 光泽 Gloss 雾影 Haze 指研 Rub-out 耐光性和耐候性 Light- and weather fastness 耐热性 Heat stability
水性汽车涂料用颜料 Pigments for waterborne Automotive coating
Public Lisa Zhang BU Pigments Technical Marketing BS Coating 16.08.2012
内Leabharlann Baidu Content
着色剂介绍 – 颜料 – 颜料的性能 水性汽车涂料发展趋势 Pigment-related problems in water based 颜料在水性里遇到的问题 – 化学结构 – 着色力 – 相容性 – 迁移 水性汽车涂料用颜料测试方法 适用于水性汽车涂料的颜料
3/13/2013
科莱恩命名补充 Nomenclature of suffices
70 例如E.g. Hostaperm Red D3G 70 – 表明颜料具有优化的遮盖性 Indicates a pigment optimized for opacity -EDS – 例如 E.g. Hosatperm Pink E-EDS – 表明此类颜料在溶剂体系的“易分散性”Indicates that a pigment is “easy to disperse” in solvent system -WD – 例如 E.g. Hostaperm Red P2GL-WD – 表明颜料被优化适用于水性涂料体系 Indicates that this pigment is optimized for use in water based paint systems -NF – 例如 E.g. Novoperm Orange HL 70-NF – 表明颜料表面经过处理具有较好的抗絮凝稳定性 Indicates a pigment with surface treatment to prevent flocculation 其他 Others – 高透明性和特殊应用 Transparent, special
–
Lisa Zhang, BU Pigments, Coatings Business (Copyright Clariant. All rights reserved.) 3/13/2013
水性汽车涂料发展趋势 Trend of waterborne Automotive coating
Public Lisa Zhang BU Pigments Technical Marketing BS Coating 16.08.2012
3/13/2013
颜料的性能 Pigment properties
在涂料中 In paint 在涂层中 In coating
絮凝 Flocculation 流变性 Rheology 分散性 Dispersibility 重结晶 Recrystallisation 沉降 Sedimentation
重点 Important to remember:
3/13/2013
P.Y.83 Novoperm Yellow HR 70
Lisa Zhang, BU Pigments, Coatings Business (Copyright Clariant. All rights reserved.)
颜料的化学结构 Chemical structure of pigment