美利肯透明聚丙烯-谢春平

总结
Conclusion
2
Millad® NX8000 的产品定位
position in the market 十多年来，Millad® 3988一直是透明聚丙烯市场的百尺竿头
Millad® 3988,the Industry Benchmark for Clear Polypropylene
Millad® NX8000 更进一步
…Millad® NX8000 is for the Ultimate in Clear Polypropylene
Millad® NX8000 是透明聚丙烯领域的重大突破。其所能达到的透 明度增加了许多商机。
Millad® NX8000 gives a new clarity standard for cPP, a breakthrough in PP transparency, permitting attractive opportunities in market value growth through the development of new clear resins
缩短成型周期
Improved cycle time
7
透明聚丙烯在注塑产品的应用
Markets for Injection Molded Clear PP
8
新一代聚丙烯透明剂有何不同？
Millad® NX8000将 Millad® 3988i 的雾度降低几乎一半
Millad® NX8000 gives half the haze as Millad® 3988i at any thickness.
Decreasing loading
Millad® NX8000 使 挤出注塑瓶的外形大 为改观从而加宽了透 明聚丙烯在挤出注塑 领域的应用
Millad® NX8000 yields new PP aesthetics in EBM bottles permitting a broader application of cPP in EBM applications.
Millad® NX8000 的价值何在？
What is the Value?
提高挤出吹塑产品的透明度
EBM - Improved clarity
拓宽挤出吹塑的加工窗口
EBM - Improved processing window
16
透明聚丙烯在挤出注塑产品的应用
Markets for Extrusion Blow Molded Clear PP
LSLHL HSHHL LTHHL HTLHL LSHHH HSLHH HTHHH LTLHH
HTHLL
LTLLL
LSHLL LTHLH
HTLLH HSHLH HSLLL LSLLH
Processing Conditions
Note: DOEs conducted in 12 MFI RCP; Millad NX8000 at 4000 ppm
13
Millad® NX8000 的价值何在？
What is the Value?
提高透明度 增宽加工窗口
Improved clarity Broad processing window
缩短成型周期
Improved cycle time
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Millad® NX8000结晶温度更高，成型周期更短,产能提高 5-10%
最新一代聚丙烯透明剂
谢春平博士，美利肯化工
内容简介

Outline
Millad® 3988i, Millad® NX8000产品概述
Product Summary

Millad ® NX8000介绍
What is Millad NX8000?

Millad ® NX8000个例经济分析
Millad® NX8000 Commercial Case Study
提高透明度 增宽加工窗口
Improved clarity Broad processing window
缩短成型周期
Improved cycle time
6
Millad® NX8000 的价值何在？
What is the Value?
提高透明度 增宽加工窗口
Improved clarity Broad processing window
A broad processing window giving excellent haze under all processing conditions.
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Parameter
18 16 14
% Haze (50mil)
Low Low Intensity (L) Single Screw (S) ~190°C (L) 190°C (L) 2.4cc/s (L)
Tc Data
600
119
T1/2 Data
118
500
117
400
116
T1/2 (sec)
Tc (C)
115
300
114 113
200
100
112
111 Tc
0 130C 135C
Millad NX8000
Millad 3988i
Millad NX8000
Millad 3988i
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Note: Expts conducted in 12 MFI RCP; Millad 3988i at 2000 ppm; Millad NX8000 at 4000 ppm
Haze, %
20
Clarified (3G) PP (HOMO) 15-20
Clarified (3G) mPP (HOMO) 13-16
10
Clarified (NX8000) PP (RACO & HOMO) 3.5-7.0
Clarified (3G) PP (RACO) 10-15
Clarified (3G) mPP (RACO) 9-11
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Millad® NX8000显著提高挤出注塑产品的外观
Millad® NX8000 consistently gives improved aesthetics in EBM
雾度
30 25
Haze
要点

Points to note
Haze (%)
20 15 10 5 0 190C 205C Millad NX8000 Millad 3988 220C
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Millad® NX8000 的价值何在？
What is the Value?
Leabharlann Baidu
提高透明度 增宽加工窗口
Improved clarity Broad processing window
缩短成型周期
Improved cycle time
12
新一代聚丙烯透明剂有何不同？ What is Next Generation Millad? Millad® NX8000在各种条件下都能得到好的雾度
雾度
45 40 35 30
Haze (%)
Haze
要点

Points to note
Millad® NX8000 把不同 厚度产品的雾度都几乎 降低了一半
Millad® NX8000 delivers significantly improved haze at all thickness in IM (~50%) under commercial conditions
Haze Continuum for Selected Plastic Materials
80
Unclarified PP (HOMO) 50-70 Unclarified PP (RACO) 40-50 Unclarified HDPE 80+
60
40
Clarified PP (1G) RACO 20-30
Millad® NX8000使得透明聚丙烯看 起来近似聚苯乙烯和聚碳酸酯因而使 材料取代成为可能

Millad® NX8000 allows polypropylene to approach the look and clarity of high clarity plastics like polystyrene and polycarbonate creating material substitution opportunities
通过取代别的透明塑料来加速聚丙烯的增长
Accelerating PP growth through material replacement of clear polymers
在已存在的应用通过提高顾客对更为透明产品的兴趣来增长
Reinvigorating and growing polypropylene in existing applications through improved consumer interest and acceptance
High High Intensity (H) Twin Screw (T) ~230°C (H) 230°C (H) 30cc/s (H)
Mixing Extrusion Extrusion Temp. IM Barrel Temp. IM Injection Rate
12 10 8 6 4 2 0
25 20 15 10 5 0 0.8 mm 1.3 mm Millad NX8000 2.0 mm Millad 3988i 2.9 mm

Millad® NX8000 显著地 增宽了加工区间从而使 得雾度在各种操作条件 下都接近一致
Millad® NX8000 has a significantly broadened processing window - allowing for consistently superior clarity across all polypropylene melt flows and processing conditions
内部光泽度
Inside Gloss
110 105
Inside Gloss (%)
100 95 90 85 80 190C Millad NX8000 205C Millad 3988i 220C

Millad® NX8000 在 雾度和光泽度都有显 著提高
Millad® NX8000 gives superior performance in haze and gloss at high 18 loadings.
3
What is Millad NX8000?
Millad® NX8000是一全新分子结构的透明剂
Millad® NX8000 is a new-to-the-world clarifier based on a new type chemistry that significantly expands the performance of PP clarification
Millad® NX8000 has a higher Tc and shorter T1/2. When coupled with the broader processing window, productivity enhancements (generally 5 – 10%) are possible without reducing other quality requirements.
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Note: DOEs conducted in 12 MFI RCP; Millad 3988i at 2000 ppm; Millad NX8000 at 4000 ppm
…For the Ultimate in Clear Polypropylene
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…For the Ultimate in Clear Polypropylene
5
3
PET PC
1 0
Glass PMMA PS
5
Note: 1.25 mm plaques
“Water White” Clarity (1–3)
Evolutionary Improvements in Polypropylene Clarity
Millad® NX8000 的价值何在？
What is the Value?

商业级树脂在全球各地都有开发
Commercial grades are in development in each region of the world
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Millad® NX8000 使聚丙烯更接近透明工程塑料
Millad® NX8000 allows PP to close the haze gap on “water white” polymers