Coupling Rydberg atoms to superconducting qubits via nanomechanical resonator

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专业英语

专业英语

Definition of polymers A simple understanding of polymers can be gained by imaging them to be like a chain or, perhaps, a string of pearls, where the individual pearl represent small molecules that are chemically bonded together. Therefore, a polymer is a molecule made up of smaller molecules that are joined together by chemical bonds. The word polymer means „many parts or units.‟ The parts or units are the small molecules that combine. The result of the combination is, of course, a chainlike molecule (polymer). Usually the polymer chains are long, often consisting of hundreds of units, but polymers consisting of only a few units linked together are also known and can be commercially valuable.
Figure 1.1 Diagram illustrating the definition of plastics.
As Figure 1.1 shows, all materials can be classified as gases, simple liquids, or solids, with the understanding that most materials can be converted from one state to another through heating or cooling. If only materials that are structural solids at normal temperatures are examined, three major types of materials are encountered: metals, polymers, and ceramics. The polymer materials can be further divided into synthetic polymers and natural polymers. Most synthetic polymers are those that do not occur naturally and are represented by materials such as nylon, polyethylene, and polyester. Some synthetic polymers could be manufactured copies of naturally occurring materials (such as

全超导磁体托卡马克装置 英语

全超导磁体托卡马克装置 英语

全超导磁体托卡马克装置英语作文Title:Fully Superconducting Tokamak (FST)A Fully Superconducting Tokamak (FST) is a pioneering design in the realm of nuclear fusion research, aiming to harness the power of the stars for sustainable energy production. This essay will provide an overview of FST technology, its operational principles, and its significance in the quest for clean energy.The FST is based on the Tokamak configuration, a doughnut-shaped (toroidal) device that uses magnetic fields to confine plasma, the hot, ionized gas necessary for nuclear fusion reactions. Unlike traditional tokamaks that use copper coils for magnetic confinement, FSTs employ superconducting coils. These coils, operating at extremely low temperatures, can maintain strong magnetic fields with minimal electrical resistance, significantly enhancing the device's efficiency and operational time.The heart of an FST lies in its superconducting coils, which are cooled to cryogenic temperatures, typically near absolute zero, using liquid helium. At these temperatures, the coils become superconductors, meaning they can conductelectricity with zero resistance. This property allows for the creation of powerful, stable magnetic fields that can confine the plasma in the toroidal chamber for extended periods.The plasma, consisting of hydrogen isotopes such as deuterium and tritium, is heated to temperatures exceeding 100 million degrees Celsius, the conditions necessary for nuclear fusion to occur. The magnetic fields generated by the superconducting coils prevent the plasma from touching the chamber walls, which would cool the plasma and disrupt the fusion process.FST technology offers several advantages over conventional tokamaks. Firstly, the use of superconducting coils allows for a more compact design, reducing the overall size and cost of the device. Secondly, FSTs can operate continuously for extended periods, potentially leading to a steady-state fusion reactor that can provide a constant source of electricity. This is in contrast to traditional tokamaks, which can only operate in short bursts due to the limitations of their copper coils.The development of FSTs represents a significant step forward in the pursuit of clean, sustainable energy. Nuclear fusion, if successfully harnessed, could provide a virtuallylimitless supply of energy without the greenhouse gas emissions associated with fossil fuels or the radioactive waste produced by nuclear fission. FSTs, with their improved efficiency and operational stability, bring the dream of fusion power closer to reality.In conclusion, the Fully Superconducting Tokamak (FST) is a cutting-edge technology that promises to revolutionize the field of nuclear fusion. By employing superconducting coils to confine plasma, FSTs offer a more efficient and stable approach to fusion energy production. As research in this area continues, FSTs could pave the way for a future where clean, sustainable energy is a global reality.。

英文版原子物理课件

英文版原子物理课件
Shanxi University Atomic Physics
1.1 Introduction
The origins of atomic physics :quantum mechanics Bohr model of the H This introductory chapter surveys some of the early ideas: Spectrum of atomic H and Bohr Theory Einstein's treatment of interaction of atom with light the Zeeman effect Rutherford scattering And so on
Shanxi University Atomic Physics
1.2 Spectrum of atomic hydrogen_3
Wavenumbers may seem rather old-fashioned but they are very useful in atomic physics
the characteristic spectrum for atoms is composed of discrete lines that are the ‘fingerprint' of the element.
In 1888, the Swedish professor J. Rydberg found that the spectral lines in hydrogen obey the following mathematical formula:
Shanxi University Atomic Physics
Lyman series: n’ = 2; 3; 4; … n = 1. Balmer (n = 2), Paschen series: (n = 3), Brackett (n = 4) and Pfund (n = 5)

多晶硅技术英语词汇

多晶硅技术英语词汇

Anhydrous 无水的(Anhydrous HCl 无水氯化氢) Bulk metals 体内金属 “dry” Azeotropic 共沸 Bulk 批量的、大批的 By-product 副产品 Batch Hydrolyzer 水解槽 Buffer tank 缓冲罐 By-pass 旁路 Bag house 布袋除尘器 C: Canned pump 屏蔽泵 Chlorine 氯气 Liquid chlorine 液氯 Chloride 氯化物 D: Dopant 掺杂物,掺杂剂 Distillation 精馏,蒸馏 Discomposition 分解 Doping (半导体)掺杂(质), 加添加剂[填料]
Impurity 杂质(heavy impurity Stream 高沸物, light impurity Stream 低沸物) Infrared 红外线 Incinerator n. 焚化装置, 焚化炉, 焚尸炉 Incineration 焚烧 IFD issue for design 提交给设计的文件 ISBL means process area: Ignition system 点火系统 K: L: Layout 工厂布局图或 plot plan LTFTIR 低温傅立叶转换红外光谱学 Long lead 长周期 Loading curve 负荷曲线 M: N:
溢出涌流充满symbol符号syntheticzeolite合成沸石用于分子筛tet四氯化硅tfctotalfixedcapital总固定资产thruput单位时间产量kghrtoptail头尾料tbddetermined待定tokuyama德山曹达日本多晶硅生产企业之一toxic有毒的热氧化thermaloxidizationtankfarmtailtowerthermalreboiler热虹吸worstcase最恶劣工况soosequenceoperation操作步序spillcontainment溢出物的围堵singlepass一次通过的slab厚平板混凝土路面settler沉淀物移民者scrubbersettler淋洗沉降槽schematic示意性的switchyard变电站skidmountpackage撬装集装整装unitprice单价utility设施ultrahighpurity超高纯vldvaporliquiddeposition熔融析出法日开发的工艺viscositycp粘度粘性workforce人力wwworldwide全球范围wiresawzonemelting区熔单晶

蓄电池技术手册中英文版

蓄电池技术手册中英文版

● Portable TV, pickup camera, radio and tape recorder.●电动工具、割草机、吸尘器。

●Electric tool, field mower. Vacuum cleaner.●照相机、新闻摄影设备。

●Camera, news photography equipment.●便携式个人计算机、语言处理器、终端。

●Portable personal computer, language processor, terminal.●野外测试设备、医疗仪器设备。

●Outdoor testing equipment, medical instrument equipment.●移动电话机、对讲机。

●Mobile phone, walkie-talkie.●矿灯、割胶灯、应急灯、铁路信号灯。

●Lamp, tapping lamp, emergency light, railway signal light.●电动玩具、电动轮椅。

●Electric toy, electric wheel chair.3 电池结构Structure of the battery图1.蓄电池结构(12V系列) Fig.1 structrue of the storage battery (12V series)图2.蓄电池结构(2V系列) Fig.2 structrue of the storage battery (2V series)表1 SUPER FM GFM 系列蓄电池构件与功能Table.1 SUPER FM GFM series storage battery component and its function部件结构材料功能battery to be 13.5V. While float charge saturation state reaches, float charge current shall be generally 2-4mA for each AH, whose charging feature shown as Fig.5.浮充电压应根据温度变化进行调整,其校正系数K为-3mV/℃即Float charge voltage must be regulated in accordance with variation of temperature, herein ,calibrating coefficient K is -3mv/℃Vt=V25+K(t-25)具体选择可按图6进行。

里德堡原子微波电场测量

里德堡原子微波电场测量

doi:10.11823/j.issn.1674-5795.2021.01.01里德堡原子微波电场测量白金海,胡栋,贡昊,王宇(航空工业北京长城计量测试技术研究所,北京100095)摘要:里德堡原子是处于高激发态的原子,其主量子数大、寿命高,具有极化率高、电偶极矩大等特点,对外电场十分敏感。

基于热蒸气室中里德堡原子的量子干涉原理(电磁感应透明和Autler-Towns分裂效应)的微波电场精密测量不仅具有远高于传统偶极天线的灵敏度,且具有自校准、对外电场干扰少、测量频率范围大等优点,是下一代电场测量标准。

本文综述了里德堡原子的微波电场测量研究,详细介绍了其基本原理和当前研究进展,并讨论了未来发展方向。

关键词:量子精密测量;里德堡原子;微波电场;电磁感应透明中图分类号:TB97文献标识码:A文章编号:1674-5795(2021)01-0001-09Rydberg Atoms Based Microwave Electric Field SensingBAIJinhai,HU Dong,GONG Hao$WANG Yu(Changcheng Institute of Metrology&Measurement,Beijing100095,China)Abstract:Rydberg atoms are the atoms in highly excited states with lar-e principaO quantum numbers n,and long lifetimes.The lar-e Ryd-ber-atom polarizabilitu and strong dipole transitions between enereetically nearby states are highly sensitive to electris fielOs.The new developed scheme for microwave electric field precision measurement is based on quantum interference effects(electromaaneticclly induced transparency and Autler-Townes splitting)in Rydbere atoms contained in a dielectric vapoe cell.The mininium measured strengths of microwave electric fieies of the new scheme are far below the standard values obtained by traditional antenna methods.And it has several advantages,such as self-calibra­tion,non-perturbation to the measured field,a broadband measurement frequency range,etc,is the next-generation electric field standard.In this review,we describe work on the new method for measuring microwave electric field based on Rydberg atoms.We introducc the basic theory and experimental techniques of the new method,and discuss the future development direction.Key words:quantum precision measurement;Rydberg atoms;microwave electric fielO;electromagnetically induced transparency0引言原子是一种典型的量子体系,具有可复现、性能稳定、能级精确等优点。

晶格的热平衡的英文

晶格的热平衡的英文

晶格的热平衡的英文Lattice Thermal Equilibrium。

In solid-state physics, the concept of lattice thermal equilibrium plays a crucial role in understanding the behavior of materials at the atomic level. It refers to the state in which the lattice vibrations, or phonons, within a crystal are in a state of balance, resulting in a uniform distribution of energy throughout the material. This phenomenon has significant implications for various properties of solids, including thermal conductivity, specific heat capacity, and even the stability of crystal structures.At the heart of lattice thermal equilibrium lies the principle of energy conservation. In a crystal lattice, energy can be transferred between neighboring atoms through phonons, which are quantized vibrations of the lattice. These phonons carry both energy and momentum, allowing the lattice to exchange thermal energy. However, for the lattice to be in thermal equilibrium, the rate of energy transfer between neighboring atoms must be equal in all directions.To understand this concept further, let us consider a simplified model of a one-dimensional crystal lattice. Imagine a row of identical atoms, each connected to its nearest neighbors by springs. When a phonon is created at one end of the lattice, it propagates through the lattice by transferring energy to the neighboring atoms. As the phonons travel, they undergo scattering events, where they can be absorbed or emitted by the atoms. These scattering events are essential for maintaining thermal equilibrium.In a system at thermal equilibrium, the rate of energy transfer due to phonon absorption must equal the rate of energy transfer due to phonon emission. This balance ensures that the lattice remains in a steady state, with no net flow of energy. If there were a significant imbalance in energy transfer, the lattice would either heat up or cool down, leading to a departure from thermal equilibrium.The concept of lattice thermal equilibrium becomes particularly relevant when considering the thermal conductivity of materials. Thermal conductivity measures amaterial's ability to conduct heat, and it is directly influenced by the efficiency of phonon transport. In materials with strong phonon-phonon scattering, such as amorphous solids, the lattice thermal conductivity is significantly lower compared to crystalline materials. This is because the random arrangement of atoms in amorphous solids disrupts the regular phonon propagation paths, leading to increased scattering events.Furthermore, lattice thermal equilibrium also affects the specific heat capacity of materials. Specific heat capacity measures the amount of heat required to raise the temperature of a given mass of material by a certain amount. In a system at thermal equilibrium, the specific heat capacity is constant and independent of temperature. This is because the energy supplied to the lattice is evenly distributed among the phonons, resulting in a uniform increase in temperature throughout the material.In summary, lattice thermal equilibrium is a fundamental concept in solid-state physics that governs the behavior of materials at the atomic level. It ensures a uniform distribution of energy within a crystal lattice, influencing properties such as thermal conductivity and specific heat capacity. Understanding and controlling lattice thermal equilibrium is crucial for designing materials with desired thermal properties, and it continues to be an active area of research in the field of materials science.。

超导合金英文作文

超导合金英文作文

超导合金英文作文英文:Superconducting alloys are materials that exhibit zero electrical resistance and perfect diamagnetism at low temperatures. They have various applications in fields such as power transmission, magnetic levitation, and superconducting magnets. One example of a superconducting alloy is Nb3Sn, which is composed of niobium and tin. This alloy has a critical temperature of around 18 K, which means it can superconduct at temperatures below this value.Superconducting alloys have several advantages over conventional conductors. Firstly, they can carry much higher currents without any energy loss due to resistance. This means they are much more efficient and can save a lot of energy. Secondly, they can produce much stronger magnetic fields, which is useful in applications such as MRI machines and particle accelerators. Finally, they can be used to create levitation systems, which can be used totransport objects without any friction.However, superconducting alloys also have some disadvantages. Firstly, they are expensive to produce and require specialized equipment and techniques. Secondly,they are very brittle and can easily break under mechanical stress. Finally, they require very low temperatures to operate, which can be difficult to achieve and maintain.Despite these challenges, superconducting alloys have many potential applications and are an active area of research. For example, researchers are working ondeveloping superconducting wires that can be used in power transmission, which could greatly improve the efficiency of the electrical grid. They are also working on developing superconducting magnets that can be used in fusion reactors, which could provide a clean and sustainable source of energy.中文:超导合金是一种在低温下表现出零电阻和完美的抗磁性的材料。

半导体器件机理 英文

半导体器件机理 英文

半导体器件机理英文Semiconductor Device Mechanisms.Semiconductors are materials that have electrical conductivity between that of a conductor and an insulator. This unique property makes them essential for a wide range of electronic devices, including transistors, diodes, and solar cells.The electrical properties of semiconductors are determined by their electronic band structure. In a semiconductor, the valence band is the highest energy band that is occupied by electrons, while the conduction band is the lowest energy band that is unoccupied. The band gap is the energy difference between the valence band and the conduction band.At room temperature, most semiconductors have a relatively large band gap, which means that there are very few electrons in the conduction band. This makessemiconductors poor conductors of electricity. However, the electrical conductivity of a semiconductor can be increased by doping it with impurities.Donor impurities are atoms that have one more valence electron than the semiconductor atoms they replace. When a donor impurity is added to a semiconductor, the extra electron is donated to the conduction band, increasing the number of charge carriers and the electrical conductivityof the semiconductor.Acceptor impurities are atoms that have one lessvalence electron than the semiconductor atoms they replace. When an acceptor impurity is added to a semiconductor, the missing electron creates a hole in the valence band. Holes are positively charged, and they can move through the semiconductor by accepting electrons from neighboring atoms. This also increases the electrical conductivity of the semiconductor.The type of impurity that is added to a semiconductor determines whether it becomes an n-type semiconductor (witha majority of electrons as charge carriers) or a p-type semiconductor (with a majority of holes as charge carriers).The combination of n-type and p-type semiconductors is used to create a wide range of electronic devices,including transistors, diodes, and solar cells.Transistors.Transistors are three-terminal devices that can be used to amplify or switch electronic signals. The threeterminals are the emitter, the base, and the collector.In a bipolar junction transistor (BJT), the emitter is an n-type semiconductor, the base is a p-type semiconductor, and the collector is another n-type semiconductor. When a small current is applied to the base, it causes a large current to flow between the emitter and the collector. This makes BJTs ideal for use as amplifiers.In a field-effect transistor (FET), the gate is a metal electrode that is insulated from the channel. When avoltage is applied to the gate, it creates an electricfield that attracts or repels electrons in the channel. This changes the conductivity of the channel, which in turn controls the flow of current between the source and the drain. FETs are ideal for use as switches.Diodes.Diodes are two-terminal devices that allow current to flow in only one direction. The two terminals are the anode and the cathode.In a p-n diode, the anode is a p-type semiconductor and the cathode is an n-type semiconductor. When a voltage is applied to the diode, it causes electrons to flow from the n-type semiconductor to the p-type semiconductor, but not vice versa. This makes diodes ideal for use as rectifiers, which convert alternating current (AC) to direct current (DC).Solar Cells.Solar cells are devices that convert light energy into electrical energy. They are made of a semiconductor material, such as silicon, that has a p-n junction.When light strikes the solar cell, it creates electron-hole pairs in the semiconductor. The electrons areattracted to the n-type semiconductor, while the holes are attracted to the p-type semiconductor. This creates a voltage difference between the two semiconductors, which causes current to flow.Solar cells are used to power a wide range of devices, including calculators, watches, and satellites. They are also used to generate electricity for homes and businesses.Conclusion.Semiconductors are essential for a wide range of electronic devices. Their unique electrical properties make them ideal for use in transistors, diodes, and solar cells. As semiconductor technology continues to develop, we canexpect to see even more innovative and efficient electronic devices in the future.。

关于拓扑超导的英文演讲

关于拓扑超导的英文演讲

关于拓扑超导的英文演讲Topological superconductivity is a fascinating topic in the field of condensed matter physics that has garnered significant attention in recent years. In this speech, I will provide an overview of the concept, its potential applications, and the ongoing research in this exciting field.Firstly, let's understand what topological superconductivity is. Superconductivity is a quantum phenomenon that occurs at very low temperatures, where certain materials can conduct electricity without any resistance. This property is due to the formation of Cooper pairs, which are pairs of electrons with opposite spins. Topological superconductivity refers to a special class of superconductors where the Cooper pairs exhibit an additional quantum property known as non-Abelian statistics.Non-Abelian statistics means that the quantum wavefunction of the system is not invariant under the exchange of particles. This unique characteristic holds the potential for storing and manipulating quantum information, making topological superconductors a promising platform for developing quantum computers. Unlike conventional superconductors, which are described by Abelian statistics, the non-Abelian nature of topological superconductivity provides protection against certain types of local perturbations and disturbances, making them more stable against noise.The study of topological superconductivity is closely connected to the field of topological insulators. Topological insulators are materials that have a unique electronic band structure that results in conducting surface states while remaining insulating in the bulk. This distinct behavior arises due to the nontrivial topology of the electron wavefunctions. By introducing superconductivity into topological insulators, researchers have been able to realize topological superconductivity.One of the most exciting prospects of topological superconductivity is its potential for hosting Majorana fermions. Majorana fermions are hypothesized particles that are their own antiparticles, meaning they can annihilate and reappear as their own particle. Majorana fermions have distinct properties that make them attractive for quantumcomputing, as they are expected to have a higher resistance to decoherence. Decoherence is a phenomenon that can disrupt quantum states and is a major challenge in quantum computing.Numerous experimental efforts have been dedicated to the search for evidence of Majorana fermions in topological superconductors. One of the most notable experiments is the creation of a hybrid structure called a topological superconductor nanowire. This nanowire, made of materials with strong spin-orbit coupling and proximity-induced superconductivity, exhibits the predicted signatures of Majorana fermions. These experimental advancements have sparked great excitement and sparked further research in the field of topological superconductivity.Apart from quantum computing, topological superconductivity also has potential applications in other areas, such as topological quantum computation and fault-tolerant quantum memories. Researchers are actively exploring the possibilities of using the unique properties of topological superconductors to create new technologies that can revolutionize various fields.In conclusion, topological superconductivity is a captivating area of research with great potential for quantum technologies. Its non-Abelian nature and the possible existence of Majorana fermions make it a promising platform for quantum computing and other applications. Continued experimental efforts and theoretical investigations are crucial in unraveling the mysteries and realizing the full potential of topological superconductivity. The future of this field holds exciting possibilities that could shape the future of quantum technology.。

法布里珀罗基模共振英文

法布里珀罗基模共振英文

法布里珀罗基模共振英文The Fabryperot ResonanceOptics, the study of light and its properties, has been a subject of fascination for scientists and researchers for centuries. One of the fundamental phenomena in optics is the Fabry-Perot resonance, named after the French physicists Charles Fabry and Alfred Perot, who first described it in the late 19th century. This resonance effect has numerous applications in various fields, ranging from telecommunications to quantum physics, and its understanding is crucial in the development of advanced optical technologies.The Fabry-Perot resonance occurs when light is reflected multiple times between two parallel, partially reflective surfaces, known as mirrors. This creates a standing wave pattern within the cavity formed by the mirrors, where the light waves interfere constructively and destructively to produce a series of sharp peaks and valleys in the transmitted and reflected light intensity. The specific wavelengths at which the constructive interference occurs are known as the resonant wavelengths of the Fabry-Perot cavity.The resonant wavelengths of a Fabry-Perot cavity are determined bythe distance between the mirrors, the refractive index of the material within the cavity, and the wavelength of the incident light. When the optical path length, which is the product of the refractive index and the physical distance between the mirrors, is an integer multiple of the wavelength of the incident light, the light waves interfere constructively, resulting in a high-intensity transmission through the cavity. Conversely, when the optical path length is not an integer multiple of the wavelength, the light waves interfere destructively, leading to a low-intensity transmission.The sharpness of the resonant peaks in a Fabry-Perot cavity is determined by the reflectivity of the mirrors. Highly reflective mirrors result in a higher finesse, which is a measure of the ratio of the spacing between the resonant peaks to their width. This high finesse allows for the creation of narrow-linewidth, high-resolution optical filters and laser cavities, which are essential components in various optical systems.One of the key applications of the Fabry-Perot resonance is in the field of optical telecommunications. Fiber-optic communication systems often utilize Fabry-Perot filters to select specific wavelength channels for data transmission, enabling the efficient use of the available bandwidth in fiber-optic networks. These filters can be tuned by adjusting the mirror separation or the refractive index of the cavity, allowing for dynamic wavelength selection andreconfiguration of the communication system.Another important application of the Fabry-Perot resonance is in the field of laser technology. Fabry-Perot cavities are commonly used as the optical resonator in various types of lasers, providing the necessary feedback to sustain the lasing process. The high finesse of the Fabry-Perot cavity allows for the generation of highly monochromatic and coherent light, which is crucial for applications such as spectroscopy, interferometry, and precision metrology.In the realm of quantum physics, the Fabry-Perot resonance plays a crucial role in the study of cavity quantum electrodynamics (cQED). In cQED, atoms or other quantum systems are placed inside a Fabry-Perot cavity, where the strong interaction between the atoms and the confined electromagnetic field can lead to the observation of fascinating quantum phenomena, such as the Purcell effect, vacuum Rabi oscillations, and the generation of nonclassical states of light.Furthermore, the Fabry-Perot resonance has found applications in the field of optical sensing, where it is used to detect small changes in physical parameters, such as displacement, pressure, or temperature. The high sensitivity and stability of Fabry-Perot interferometers make them valuable tools in various sensing and measurement applications, ranging from seismic monitoring to the detection of gravitational waves.The Fabry-Perot resonance is a fundamental concept in optics that has enabled the development of numerous advanced optical technologies. Its versatility and importance in various fields of science and engineering have made it a subject of continuous research and innovation. As the field of optics continues to advance, the Fabry-Perot resonance will undoubtedly play an increasingly crucial role in shaping the future of optical systems and applications.。

超冷rydberg分子;双色光缔合;绝热势能曲线

超冷rydberg分子;双色光缔合;绝热势能曲线

超冷rydberg分子随着科学技术的不断进步,人类对物质微观世界的认识也日益深入。

在这一过程中,超冷rydberg分子作为一种新奇而又神秘的物质形态,引起了科学界的广泛关注。

本文将重点探讨超冷rydberg分子的形成机制、性质及其在双色光缔合和绝热势能曲线研究中的应用。

一、超冷rydberg分子的形成机制1. 电子云激发:超冷rydberg分子的形成主要依赖于外层电子云的激发。

当一种原子或分子受到外界激发能量的影响时,其外层电子云将被激发至高能级状态,形成rydberg态。

2. 量子干涉效应:在低温条件下,由于量子效应的作用,原子或分子之间的相互作用将呈现出更加复杂的干涉效应。

这种量子干涉效应会导致一些原本不稳定的态被锁定,形成超冷rydberg分子。

二、超冷rydberg分子的性质1. 特殊低温:超冷rydberg分子一般形成于极低温条件下,其温度通常低于微开尔文。

这种特殊低温条件下所形成的rydberg态,使得超冷rydberg分子具有独特的动力学和能谱性质。

2. 长寿命:由于电子云的激发和量子干涉效应的影响,超冷rydberg分子的寿命可达数百毫秒以上,远远超过一般分子和原子的寿命。

三、超冷rydberg分子在双色光缔合中的应用1. 双色光激发:通过双色光激发,可以将两种不同波长的激光混合在一起,通过调节其频率和强度,可以有效操控超冷rydberg分子的形成和解离。

这一技术被广泛应用于原子和分子的操控、量子信息存储等领域。

2. 光谱分析:利用双色光缔合技术,可以对超冷rydberg分子的能级结构和振动转动态进行精确的测量和分析,为超冷rydberg分子的研究提供了有力的工具和手段。

四、超冷rydberg分子在绝热势能曲线研究中的应用1. 分子间相互作用:超冷rydberg分子在特殊低温条件下的形成和性质,使得其可以很好地用于研究分子间的相互作用和绝热势能曲线。

这为分子结构和反应动力学的表征提供了新的视角和方法。

超导合金英文作文

超导合金英文作文

超导合金英文作文Superconducting alloys, also known as superalloys, area group of materials that exhibit the unique property of superconductivity at low temperatures. This means that they can conduct electricity with zero resistance, making them extremely useful in various applications such as in MRI machines, particle accelerators, and magnetic levitation trains.The discovery of superconducting alloys has revolutionized many industries, particularly in the fieldof medical imaging. MRI machines, for example, rely on superconducting magnets to produce high-quality images of the human body. Without the use of superconducting alloys, these machines would not be able to generate the strong magnetic fields necessary for the imaging process.In addition to their applications in medical technology, superconducting alloys are also used in the development of particle accelerators. These devices require powerfulmagnets to steer and focus particle beams, and superconducting alloys provide the necessary magneticfields without the energy losses associated withtraditional materials.One of the most exciting potential applications of superconducting alloys is in the development of magnetic levitation trains. These trains, also known as maglev trains, use superconducting magnets to levitate above the tracks, allowing for frictionless movement and high speeds. This technology has the potential to revolutionize the transportation industry by providing faster, more efficient, and environmentally friendly travel options.Despite their many advantages, superconducting alloys also present some challenges. One of the main obstacles is the need to maintain low temperatures in order to achieve superconductivity. This requires the use of cryogenic systems, which can be costly and complex to operate. Researchers are constantly working to develop new superconducting materials that can operate at higher temperatures, which would make them more practical andcost-effective for a wider range of applications.In conclusion, superconducting alloys have had a profound impact on various industries, from healthcare to transportation. Their unique ability to conduct electricity without resistance has opened up new possibilities for technological advancement, and ongoing research in this field holds great promise for the future.。

Cavity quantum electrodynamics for superconducting electrical circuits an architecture for

Cavity quantum electrodynamics for superconducting electrical circuits an architecture for
PACS numbers: 03.67.Lx, 73.23.Hk, 74.50.+r, 32.80.-t
I.
INTRODUCTION
Cavity quantum electrodynamics (cQED) studies the properties of atoms coupled to discrete photon modes in high Q cavities. Such systems are of great interest in the study of the fundamental quantum mechanics of open systems, the engineering of quantum states and the study of measurement-induced decoherence [1, 2, 3], and have also been proposed as possible candidates for use in quantum information processing and transmission [1, 2, 3]. Ideas for novel cQED analogs using nanomechanical resonators have recently been suggested by Schwab and collaborators [4, 5]. We present here a realistic proposal for cQED via Cooper pair boxes coupled to a one-dimensional (1D) transmission line resonator, within a simple circuit that can be fabricated on a single microelectronic chip. As we discuss, 1D cavities offer a number of practical advantages in reaching the strong coupling limit of cQED over previous proposals using discrete LC circuits [6, 7], large Josephson junctions [8, 9, 10], or 3D cavities [11, 12, 13]. Besides the potential for entangling qubits to realize two-qubit gates addressed in those works, in the present work we show that the cQED approach also gives strong and controllable isolation of the qubits from the electromagnetic environment, permits high fidelity quantum non-demolition (QND) readout of multiple qubits, and can produce states of microwave photon fields suitable for quantum communication. The proposed circuits therefore provide a simple and efficient architecture for solid-state quantum computation, in addition to opening up a new avenue for the study of entanglement and quantum measurement physics with macroscopic objects. We will frame our discussion in a way that makes contact between the language of atomic physics and that of electrical engineering. We begin in Sec. II with a brief general overview of

库仑能隙conduction

库仑能隙conduction

库仑能隙conduction库仑能隙是指在固体材料中,电子在能带之间跃迁所需的最小能量差。

能带是指电子能级的能量分布图,与电子的允许能量范围有关。

库仑能隙直接影响到材料的电导性能,对于半导体材料而言,库仑能隙对于其导电行为具有决定性的影响。

在半导体材料中,当固体中的价带满带(价带是指具有最高电子密度的能级),而导带(导带是指比价带高一个库伦能级的能级)为空带时,该材料被称为本征半导体。

在这种情况下,电子无法在价带和导带之间自由跃迁,因为需要克服库仑能隙的能量差。

半导体材料的库仑能隙可以通过经验公式如布飞勒公式计算得到。

布飞勒公式给出了库仑能隙与半导体材料的禁带宽度之间的关系:Eg = 2.82 + 0.1246 * (hc/λ)其中,Eg是半导体的库仑能隙,而λ是光波的波长,hc是普朗克常量与光速的乘积。

库仑能隙不仅与材料的禁带宽度有关,还与材料的晶格结构和化学成分有关。

当材料的晶格结构产生偏离时,库仑能隙也会发生变化。

此外,添加掺杂物可以有效地调节材料的库仑能隙,从而改变其导电性能。

对于半导体材料来说,库仑能隙的大小对于其导电性能具有重要的影响。

当材料的库仑能隙较大时,半导体可以被认为是绝缘体,因为电子不能轻易跃迁到导带。

相反,当库仑能隙较小时,半导体可以具有良好的导电性能,因为电子可以容易地从价带跃迁到导带。

此外,库仑能隙还与材料的温度有关。

根据金属的波尔兹曼公式,材料的电导率与温度呈指数关系,其指数与材料的库仑能隙相关。

因此,随着温度的升高,材料的库仑能隙减小,从而导致电导率的增加。

总之,库仑能隙是半导体材料电导率的重要参数,直接影响着材料的导电性能。

通过调节材料的禁带宽度、晶格结构和添加掺杂物等方法,可以有效地改变材料的库仑能隙,从而实现对材料导电性能的调控。

高分子专业英语翻译[最新]

高分子专业英语翻译[最新]

高分子专业英语翻译[最新]第五课乳液聚合大部分的乳液聚合都是由自由基引发的并且表现出其他自由基体系的很多特点,最主要的反应机理的不同源自小体积元中自由基增长的场所不同。

乳液聚合不仅允许在高反应速率下获得较高分子量,这在本体聚合中是无法实现或效率低下的,,同时还有其他重要的实用优点。

水吸收了大部分聚合热且有利于反应控制,产物在低粘度体系中获得,容易处理,可直接使用或是在凝聚,水洗,干燥之后很快转化成固体聚合物。

在共聚中,尽管共聚原理适用于乳液体系,单体在水相中溶解能力的不同也可能导致其与本体聚合行为不同,从而有重要的实际意义。

乳液聚合的变化很大,从包含单一单体,乳化剂,水和单一引发剂的简单体系到这些包含有2,3个单体,一次或分批添加,,混合乳化剂和助稳定剂以及包括链转移剂的复合引发体系。

单体和水相的比例允许变化范围很大,但是在技术做法上通常限制在30/70到60/40。

单体和水相比更高时则达到了直接聚合允许的极限,只有通过分批添加单体方法来排除聚合产生的大量的热。

更复杂的是随着胶体数的增加粘度也大大增加,尤其是当水溶性的单体和聚合物易容时,反应结束胶乳浓度降低。

这一阶段常常伴随着通过聚集作用或是在热力学不稳定时凝结作用而使胶粒尺寸增大。

第十课高分子的构型和构象本课中我们将使用根据经典有机化学术语而来的构型和构象这两个词。

构型异构是由于分子中存在一个或多个不对称中心,以最简单的C原子为例,每一碳原子的绝对构型为R型和S型,当存在双键时会有顺式和反式几何异构。

以合成聚合物为例,构型异构的典型问题和R.S型不对称碳原子在主链上的排布有关。

这些不对称碳原子要么来自不对称单体,如环氧丙烷,要么来自对称单体,如乙烯单体,,这些物质的聚合,在每个单体单元中形成至少一个不对称碳原子。

大分子中的构型异构源于侧链上存在不对称的碳原子,例如不对称乙烯单体的聚合,也是可能的,现今已经被广泛研究。

和经典有机化学术语一致,构象,旋转体,旋转异构体,构象异构体,指的是由于分子单键的内旋转而形成的空间排布的不同。

高分子英语课文翻译

高分子英语课文翻译

unit1all polymers are built up from bonding together a single kind of repeating unit. At the other extreme ,protein molecules are polyamides in which n amino acide repeat units are bonded together. Although we might still call n the degree of polymerization in this case, it is less usefull,since an amino acid unit might be any one of some 20-odd molecules that are found in proteins. In this case the molecular weight itself,rather than the degree of the polymerization ,is generally used to describe the molecule. When the actual content of individual amino acids is known,it is their sequence that is of special interest to biochemists and molecular biologists.并不是所有的聚合物都是由一个重复单元链接在一起而形成的;在另一个极端的情形中,蛋白质分子是由n个氨基酸重复单元链接在一起形成的聚酰胺;尽管在这个例子中,我们也许仍然把n称为聚合度,但是没有意义,因为一个氨基酸单元也许是在蛋白质中找到的20多个分子中的任意一个;在这种情况下,一般是分子量本身而不是聚合度被用来描述这个分子;当知道了特定的氨基酸分子的实际含量,它们的序列正是生物化学家和分子生物学家特别感兴趣的地方;1,题目:Another striking ...答案:.that quantity low saturation bottom much absorb 2. 乙烯分子带有一个双键,为一种烯烃,它可以通过连锁聚合大量地制造聚乙烯,目前,聚乙烯已经广泛应用于许多技术领域和人们的日常生活中,成为一种不可缺少的材料;Ethylene molecule with a double bond, as a kind of olefins, it can make chain polymerization polyethylene, at present, polyethylene has been widely used in many fields of technology and People's Daily life, become a kind of indispensable materials.Unit31 The polymerization rate may be experimentally followed by measuring the changes in any of several properties of the system such as density,refractive index,viscosity, or light absorption. Density measurements are among the most accurate and sensitive of the techniques. The density increases by 20-25 percent on polymerization for many monomers. In actual practice the volume of the polymerizing system is measured by carrying out the reaction in a dilatometer. This is specially constructed vessel with a capillary tube which allows a highly accurate measurement of small volume changes. It is not uncommon to be able to detect a few hundredths of a percent polymerization by the dilatometer technique. 聚合速率在实验上可以通过测定体系的任一性质的变化而确定,如密度、折射率、黏度、或者吸光性能;密度的测量是这些技术中最准确最敏感的;对许多单体的聚合来说,密度增加了20%-25%;在实际操作中,聚合体系的体积是通过在膨胀计中进行反应测定的;它被专门设计构造了毛细导管,在里面可以对微小体积变化进行高精确度测量;通过膨胀计技术探测聚合过程中万分之几的变化是很常见的;Unti42 合成聚合物在各个领域中起着与日俱增的重要作用,聚合物通常是由单体通过加成聚合与缩合聚合制成的;就世界上的消耗量而论,聚烯烃和乙烯基聚合物居领先地位,聚乙烯、聚丙烯等属聚烯烃,而聚氯乙烯、聚苯乙烯等则为乙烯基聚合物;聚合物可广泛地用作塑料、橡胶、纤维、涂料、粘合剂等The synthetic polymers play an increasingly important role on a range of domains, which are synthesized by monomers through addition polymerization or condensation polymerization. Polyolefin and vinyl polymer have taken the lead in terms of the world consumption. PE, PP, etc. belong to the polyolefin, while PS, PVC etc. belong to the vinyl polymer. Polymers can be widely applied in plastics, rubbers, fibers, coatings, glues and so on.Unit7Ring-opening polymerizations proceed only by ionic mechanisms, the polymerization of cyclic ethers mainly by cationic mechanisms, and the polymerization of lactones andlactones by either a cationic or anionic mechanism. Important initiators for cyclic ethers and lactone polymerization are those derived from aluminum alkyl and zinc alkyl/water systems. It should be pointed out that substitution near the reactive group of the monomer is essential for the individual mechanism that operates effectively in specific cases; for example, epoxides polymerize readily with cationic and anionic initiators, while fluorocarbon epoxides polymerize exclusively by anionic mechanisms.开环聚合反应只能通过离子机理进行,环醚的开环聚合主要通过阳离子机理,而内酯和内酰胺的聚合物是通过阳离子或阴离子机理;对于环醚和内酯型聚合物很重要的引发剂是那些来自于烷基铝和烷基锌/水的体系;应该指出的是对于在活性基团附近有取代的单体,只能由单一机理,这一机理是在特定条件下的有效;1 Polymers can be classified into two main groups, addition polymers and ___condensation__ polymers. This classification is based on whether or not the repeating unit of the polymer contains the same atoms __as____ the monomer. The repeating unit of an addition polymer is identical _with/to____ the monomer, while condensation polymers contain __different/less___ because of formation of __compound/byproduct___ during the polymerization process. The corresponding polymerization processed would then be called addition polymerization and condensation polymerization. As was mentioned earlier, this classification can result ___in__ confusion, since it has been shown in later years that many important types of polymers can be _prepared by both addition and condensation processes. For example, polyesters, polyamides and polyurethanes are usually considered to be _condensation____ polymers, but they can be prepared by addition as well as by condensation reaction. Similarly, polyethylene normally considered an _addition_ polymer, can also be prepared by _condensation_ reaction.2. Answer the following questions in English1 What is chain polymerization Manyolefinicandvinylunsaturatedcompoundsareabletoformchain-likemacromoleculesthrougheliminationofdoublebond.2 Which kinds of monomers can carry out step-growth polymerization processThere are two kinds of monomers could carry out step-growth polymerization process. One ispolyfunctionalmonomers and the other isasinglemonomercontainingbothtypesoffunctional groups.3 What properties of polymers can be based on for measuring the molecular weightThe molecular weight of polymer could be measured based on colligativeproperties, lightscattering, viscosity, ultracentrifugation sedimentation.3. Please write out at least 10 kinds of polymers both in English and in Chinesethe corresponging chemical structure5 In general,head-to-tail addition is considered to be the predominant mode of propagation in all polymerizations;However,when the substitutes on the monomer are small and do not offer appreciable steric hindrance to the approaching radical or do not have a large resonance stabilizing effect,as in the case of fluorine atoms,sizable amounts of head-to-head propagation may occur. The effect of increasing polymerization temperature is to increase the amount of head-to-head placement;Increased temperature leads to less selective more random propagation but the effect is not large. Thus,the head-to-head content in poly vinyl acetate only increases from to percent when the polymerization temperature in increased from 30 to 90 ℃.通常在所有聚合物的链增长中,头-尾加成是主要方式;然而,当单体中的取代基很小对接近的自由基没有空间阻碍或没有较大的共振稳定作用,如氟原子,则有相当量的头头增长发生;提高聚合温度的影响是提高头-头排列的量;温度的提高导致较少的选择更多的无规增长,但影响不大;因而,在聚乙酸乙烯酯中,当聚合温度由30C提高到90C,头-头含量仅由%提高到%;2.Write out an abstract in English for the text in this unitPolymers with different structures present various properties. Usually, polymers are divided into three categories, . plastic, elastomer, fiber with different initial modulus range respectively. Polymers show quite different behaviors due to the different interchain forces in elastomer and fiber. However, with the advent of new techniques and mechanisms to improve the structure of polymers, polymers may be classified and named according to the mechanism, and their properties will largely depend on the structure. 3.Put the following words into Chineseentanglement 纠缠 irregularity 无规 sodium isopropylate异丙醇钠 permeability渗透性crystallite 微晶stoichiomertric balance 当量平衡fractionation分馏法light scattering光散射 matrix 基体 diffraction衍射4.Put the following words into English形态 morphology 酯化 esterification 异氰酸酯isocyanate杂质impurity 二元胺 diamine 转化率change ratio 多分散性polydispersity 力学性能mechanical property 构象conformation 红外光谱法infrared spectroscopy常见聚合物命名1常见杂链和元素有机聚合物类型Polyamide ----聚酰胺. Polyester----聚酯 Poly‘urethane ------聚氨酯 Polysiloxane -------聚硅氧烷Phenol-formaldehyde----酚醛.Urea-formaldehyde-----脲醛Polyureas------聚脲 Polysulfide -----聚硫Polyacetal-------聚缩醛 Polysulfone polysulphone------聚砜 Polyether---------聚醚第五单元Traditional methods of living polymerization are based on ionic, coordination or group transfer mechanisms.活性聚合的传统方法是基于离子,配位或基团转移机理;Ideally, the mechanism of living polymerization involves only initiation and propagation steps.理论上活性聚合的机理只包括引发和增长反应步骤;All chains are initiated at the commencement of polymerization and propagation continues until all monomer is consumed.在聚合反应初期所有的链都被引发,然后增长反应继续下去直到所有的单体都被消耗殆尽;A type of novel techniques for living polymerization, known as living possibly use “controlled” or “mediated” radical polymerization, is developed recently. 最近开发了一种叫做活性自由基聚合的活性聚合新技术;The first demonstration of living radical polymerization and the current definition of the processes can be attributed to Szwarc.第一个活性自由基聚合的证实及目前对这一过程的解释或定义,应该归功于Szwarc;Up to now, several living radical polymerization processes, including atom transfer radical polymerization ATRP, reversible addition-fragmentation chain transfer polymerization RAFT, nitroxide-mediated polymerization NMP, etc., have been reported one after another.到目前为止,一些活性自由基聚合过程,包括原子转移自由基聚合,可逆加成-断裂链转移聚合,硝基氧介导聚合等聚合过程一个接一个被报道;The mechanism of living radical polymerization is quite different not only from that of common radical polymerization but also from that of traditional living polymerization. 活性自由基聚合的机理不仅完全不同于普通自由基聚合机理,也不同于传统的活性聚合机理;It relies on the introduction of a reagent that undergoes reversible termination with the propagating radicals thereby converting them to a following dormant form:活性自由基聚合依赖于向体系中引入一种可以和增长自由基进行可逆终止的试剂,形成休眠种:The specificity in the reversible initiation-termination step is of critical importance in achieving living characteristics.这种特殊的可逆引发-终止反应对于获得分子链活性来说具有决定性的重要意义;This enables the active species concentration to be controlled and thus allows such a condition to be chosen that all chains are able to grow at a similar rate if not simultaneously throughout the polymrization.可逆引发终止使活性中心的浓度能够得以控制;这样就可以来选择适宜的反应条件,使得在整个聚合反应过程中只要没有平行反应所有的分子链都能够以相同的速度增长;This has, in turn, enabled the synthesis of polymers with controlled composition, architecture and molecular weight distribution.这样就可以合成具有可控组成,结构和分子量分布的聚合物;They also provide routes to narrow dispersity end-functional polymers, to high purity block copolymers, and to stars and other more complex architecture.这些还可以提供获得狭窄分布末端功能化聚合物,高纯嵌段共聚物,星型及更复杂结构高分子的合成方法;The first step towards living radical polymerization was taken by Ostu and his colleagues in 1982.活性自由基聚合是Ostu和他的同事于1982年率先开展的;In 1985, this was taken one step further with the development by Solomon et al. of nitroxide-mediated polymerization NMP.1985年,Solomon等对氮氧化物稳定自由基聚合的研究使活性自由基聚合进一步发展;This work was first reported in the patent literature and in conference papers but was not widely recognized until 1993 when Georges et al. applied the method in the synthesis of narrow polydispersity polystyrene.这种方法首先在专利文献和会议论文中报道,但是直到1993年Georges等把这种方法应用在窄分子量分布聚苯乙烯之后,才得以广泛认知;The scope of NMP has been greatly expended and new, more versatile, methods have appeared. NMP的领域已经得到很大的延展,出现了新的更多样化的方法;The most notable methods are atom transfer radical polymerization ATRP and polymerization with reversible addition fragmentation RAFT.最引人注目的方法是原子转移自由基聚合和可逆加成断裂聚合;到2000年,这个领域的论文已经占所有自由基聚合领域论文的三分之一;如图所示;Naturally, the rapid growth of the number of the papers in the field since 1995 ought to be almost totally attributable to development in this area. 、自然地,纸的数量的迅速增长在领域,因为1995在这个区域应该是几乎完全可归属的到发展;UNIT9 Structure and Properties of Polymers 聚合物的结构和性质Most conveniently, polymers are generally subdivided in three categories, namelyviz., plastics, rubbers and fibers. 很方便地,聚合物一般细分为三种类型,就是塑料,橡胶和纤维; In terms of initial elastic modules, rubbers ranging generally between 106 to 107dynes/cm2, represent the lower end of the scale, while fibers with high initial modjulai, of 1010 to 1011dynes/cm2 are situated on the upper end of the scale; plastics, having generally an initial elastic modulus of 108 to 109dynes/cm2, lie in-between. 就初始弹性模量而言,橡胶一般在 6到107达因平方厘米,在尺度的低端, 10到1011达因平方厘米,尺度的高端,而纤维具有高的初始模量, 达到10到1011达因平方厘米,尺度的高端,塑料的弹性模量一般在 8到109达因平方厘米,在尺度的中间As is found in all phases of polymer chemistry, there are many exceptions to this categorization. 正如高分子化学的各个部分都可以看到的那样,在高分子化学的所有阶段,我们都可以发现,这种分类方法有许多例外的情况;An elastomer or rubber results from a polymer having relatively weak interchain forces and high molecular weights. 弹性体是具有相对弱的链之间作用力和高分子量的聚合物; When the molecular chains are “straightened out” or stretched by a process of extension, they do not have sufficient attraction for each other to maintain the oriented state and will retract once the force is released. This is the basis of elastic behavior. 当通过一个拉伸过程将分子链拉直的时候,分子链彼此之间没有足够的相互吸引力来保持其取向状态,作用力一旦解除,将发生收缩;这是弹性行为的基础;However, if the interchain forces are very great, a polymer will make a good fiber. 然而,如果分子链之间的力非常大,聚合物可以用做纤维;Therefore, when the polymer is highly stretched, the oriented chain will come under the influence of the powerful attractive forces and will “crystallize” permanently in a more or less oriented matrix. 因此,当聚合物被高度拉直的时候,取向分子链在不同程度取向的母体中将受强引力的影响而“永久地结晶;These crystallization forces will then act virtually as crosslinks, resulting in a material of high tensile strength and high initial modulus, ., a fiber. 而后,这些结晶力实际上以交联方式作用,产生高拉伸强度和高初始模量的材料,如纤维;Therefore, a potential fiber polymer will not become a fiber unless subjected to a “drawing” process, ., a process resulting in a high degree of intermolecular orientation. 因此,一个可能的潜在的纤维高分子不会变成纤维,除非经历一个拉伸过程, 即, 这导致分子间高度取向的拉伸过程;Crosslinked species are found in all three categories and the process of crosslinking may change the cited characteristics of the categories. 交联的种类在所有三种类型塑料,橡胶,纤维中找到,而交联过程可以改变分类的引用特征;Thus, plastics are known to possesspzes a marked range of deformability in the order of 100 to 200%; they do not exhibit this property when crosslinked, however. 因此,我们熟知塑料具有的形变能力大约在100-200%范围内,然而当交联发生时塑料不能展示这个性能; Rubber, on vulcanization, changes its properties from low modulus, low tensile strength, low hardness, and high elongation to high modulus, high tensile strength, high hardness, and low elongation. 对橡胶而言,硫化可以改变其性质,从低模量,低拉伸强度,低硬度及高拉伸率到高模量,高拉伸强度,高硬度及低拉伸率;Thus, polymers may be classified as noncrosslinked and crosslinked, and this definition agrees generally with the subclassification in thermoplastic and thermoset polymers. 这样,聚合物可以分为非交联和交联的,这个定义与把聚合物细分为热塑性和热固性聚合物相一致; From the mechanistic point of view, however, polymers are properly divided into addition polymers and condensation polymers. Both of these species are found in rubbers, plastics, and fibers. 然而,从反应机理的观点看,聚合物可以分成加聚物和缩聚物;这些种类聚合物在塑料,橡胶和纤维中都可以找得到;In many cases polymers are considered from the mechanistic point of view. Also, the polymer will be named according to its source whenever it is derived from a specific hypothetical monomer, or when it is derived from two or more components which are built randomly into the polymer. 在许多情况下,聚合物可以从反应机理的角度考虑分类; 每当聚合物来自于一个假象单体,或来自于两个或两个以上组成物无规则构建聚合物时,也可以根据聚合物的来源来命名; This classification agrees well with the presently used general practice. 这种分类方法与目前实际情况相符合;When the repeating unit is composed of several monomeric components following each other in a regular fashion, the polymer is commonly named according to its structure. 当重复单元由几个单体组成物规则排布,聚合物通常根据它的结构来命名;It must be borne in mind that, with the advent of Ziegler-Natta mechanisms and new techniques to improve and extend crystallinity, and the closeness of packing of chains, many older data given should be critically considered in relation to the stereoregular and crystalline structure. 必须记住,随着Ziegler-Natta机理,以及提高结晶度和链堆砌紧密度新技术的出现,对许多过去已经得到的关于空间结构和晶体结构旧的资料,应当批判地接受;The properties of polymers are largely dependent on the type and extent of both stereoregularity and crystallinity. As an example, the densities and melting points of atactic and isotactic species are presented in Table . 聚合物的性质主要依靠立体规整性和结晶度的类型和程度;如,无规立构和全同立构物质的密度和熔点展示在表中 ;UNIT11 Functional PolymersFunctional polymers are macromolecules to which chemically functional groups are attached; they have the potential advantages of small molecules with the same functional groups. 功能聚合物是具有化学功能基团的大分子,这些聚合物与具有功能聚合物是具有化学功能基团的大分子, 相同功能基团的小分子一样具有潜在的优点;Their usefulness is related both to the functional groups and to the nature of the polymers whose characteristic properties depend mainly on the extraordinarily large size of the molecules.它们的实用性不仅与功能基团有关,而且与巨大分子尺寸带来的聚合物特性有关;The attachment of functional groups to a polymer is frequently the first step towards the preparation of a functional polymer for a specific use. 把功能基团连接到聚合物上常常是制备特殊用途功能高分子的第一步;However, the proper choice of the polymer is an important factor for successful application. 然而,对成功应用而言,选择适当的聚合物是的一个重要因素;In addition to the synthetic aliphatic and aromatic polymers, a wide range of natural polymers have also been functionalized and used as reactive materials. 除了合成的脂肪组和芳香组聚合物之外,许多天然高分子也被功能化,被用做反应性材料;Inorganic polymers have also been modified with reactive functional groups and used in processes requiring severesi’vi service conditions. 无机聚合物也已经用反应功能基团改性,被用于要求耐用条件的场合;In principle, the active groups may be part of the polymer backbone or linked to a side chain as a pendant group either directly or viavai a space rs’peis group. 理论上讲,活性基团可以是聚合物主链上的一部分,或者直接连接到侧链或通过一个中间基团的侧基;A required active functional group can be introduced onto a polymeric support chain 1 by incorporation during the synthesis of the support itself through polymerization or copolymerization of monomers containing the desired functional groups, 2 by chemical modification of a nonfunctionalized performed support matrix and 3 by a combination of 1 and 2. 所需的活性功能基团可以通过几种方法引入到聚合物主链上, 1在主链的合成过程中,通过聚合或共聚合含有理想功能基团的单体来获得,2通过对已有的非功能化主链进行化学改性的方法,3通过结合1和2来获得;Each of the two approaches has its own advantages and disadvantages, and one approach may be preferred for the preparation of a particular functional polymer when the other would be totally impractical.两种途径中的每一种都有自身的优点和缺点,对特殊功能聚合物的制备而言,当其他方法都无法实现时,所选的方法或许是更合适的;The choice between the two ways to the synthesis of functionalized polymers depends mainly on the required chemical and physical properties of the support for a specific application. 功能聚合物合成的两种方法中,如何选择主要取决于特殊应用要求的主链聚合物的化学和物理性质;Usually the requirements of the individual system must be thoroughly examined in order to take full advantage of each of the preparative techniques. 为了充分利用每种制备方法,必须全面地考察独立体系的要求;Rapid progress in the utilization of functionalized polymeric materials has been noted in the recent past. 近年来,功能化聚合物材料的使用方面有了飞速的发展;Interest in the field is being enhanced due to the possibility of creating systems that combine the unique properties of conventional active moieties and those of high molecular weight polymers. 由于能够制造出来兼有活性官能团特性和高分子量聚合物性能的功能聚合物,所以,人们对功能聚合物这个领域的兴趣与日俱增;The successful utilization of these polymers are based on the physical form, solution behavior, porosity, chemical reactivity and stability of the polymers. 这些聚合物的成功利用,基于功能聚合物的物理形态,溶液行为,空隙率,化学活性及稳定性;The various types of functionalized polymers cover a broad range of chemical applications, including the polymeric reactants, catalysts, carriers, surfactants, stabilizers,ionexchange resins, etc.各种功能化聚合物类型覆盖化学应用的宽广领域,包括聚合物试剂,催化剂, 载体,表面活性剂,稳定剂,离子交换树脂等;In a variety of biological and biomedical fields, such as the pharmaceutical, agriculture, food industry and the like, they have become indispensable materials, especially in controlled release formulation of drugs and agrochemicals. 在生物学及生物医学领域中,如药物,农业,食品工业等, 在生物学及生物医学领域中,如药物,农业,食品工业等,功能聚合物是不可缺少的材料,尤其在药物和农药的控制释放配方上;Besides, these polymers are extensively used as the antioxidants, flame retardants, corrosion inhibitors, flocculating agents, antistatic agents and the other technological applications. 此外,这些聚合物被广泛地用做抗氧化剂,阻燃剂,缓蚀剂, 絮凝剂,抗静电剂及其他技术应用;In addition, the functional polymers possessp’zes broad application prospects in the high technology area as conductive materials, photosensitizers, nuclear track detectors, liquid crystals, the working substances for storage and conversion of solar energy, etc. 另外,功能化聚合物在高科技领域具有广阔的应用前景; 如导电材料,光敏剂,核径迹探测器,液晶,用于太阳能等的转化与储存的工作物质;第十二单元实验室制备氨基树脂氨基树脂是由氨基衍生物和醛在酸性或碱性条件下反应生产得到的其中最重要最具代表性的物质是脲醛树脂和蜜胺树脂; 药品:尿素,福尔马林37%,乙醇,2N NaOH, NaOH溶液,1N标准NaOH溶液,1N标准HCl溶液,冰醋酸,糠醇,三乙醇胺,木粉,磷酸钙,氯化铵, H2SO4溶液,Na 2SO3,1%乙醇百里酚酞指示剂溶液,三聚氰胺,甘油和单羟甲基脲; 装置:烧瓶和烧杯,500ml的三口烧瓶,加热套,机械搅拌器,冷凝器,迪安—斯达克塔分水器,烘箱,广泛试纸,试管,250mL的容量烧瓶,冰浴,10ml 的移液管,滴管,油浴和广口瓶; 酸性条件下制备脲醛树脂:为了证明尿素和甲醛在酸性条件下的迅速反应,将5 g尿素和6 mL福尔马林在试管中混合,振荡试管直到尿素全部溶解;滴加4滴 N H2SO4以调节溶液pH到4,观察析出沉淀所需要的时间,取出部分沉淀并比较此沉淀以及单羟甲基脲样品在水中的溶解性;制备脲醛树脂粘合剂:将600g1mole尿素和137g福尔马林放入500ml三口烧瓶中,并安装好机械搅拌器和回流冷凝器,通过用广泛试纸测定用2NNaOH溶液把混合物PH值调至7~~8,然后将混合物回流2小时;1每隔半小时用下面的方法测定一次混合物中的自由甲醛含量,直到水完全脱除为止;2 当混合物回流2小时后,将迪安—斯达克塔分水器安装在烧瓶和回流冷凝器之间 ;大约有40ml水被蒸馏,用5滴冰醋酸将溶液酸化;将44g糠醇和的三乙醇胺加入到反应混合液中,加热此溶液到90℃并恒温15分钟;将混合物冷却到室温;取出15g的树脂样品和由1g木粉,磷酸钙和氯化铵组成的硬化剂混合 ;将混合物进行室温固化;3将剩下的没有加工硬化剂的树脂放入广口瓶中并提交给实验导师;自由甲醛含量的测定:自由甲醛含量的测定:准备250mL 1N Na2SO3溶液,并中和该溶液,从而使其产生淡蓝色的百里酚酞指示剂溶液;在250ml锥形瓶中加入重为2到3克的树脂样品到100mL的水中,摇晃锥形瓶使锥形瓶内的溶液充分溶解;如果树脂不能溶解,加入乙醇可以帮助溶解;在冰浴中使溶液的温度下降到4℃,加25mL的1M Na2SO3溶液在100mL的烧瓶中,用移液管移取10ml标准的1N HCl溶液到烧瓶中,降温至4℃;加10-15滴百里酚酞指示剂溶剂到样品烧瓶中,调整溶液的颜色至淡蓝色;用冷水冷却以后迅速地转移酸式亚硫酸盐溶液到样品烧瓶中;4滴定溶液到百里酚酞的终点标准1N NaOH 溶液;CH2O+Na2SO3+H2O →CH2OHSO3-Na++NaOH通过中和树脂溶液的HCl溶液的量来测定自由甲醛的百分含量;三聚氰胺甲醛树脂的制备:在一个500ml的配置有机械搅拌器和一个冷凝器的反应器中加入63g 的三聚氰胺和122g的福尔马林37%;混合物回流40分钟;%自由甲醛需要每隔十分钟测定一次;自由甲醛的测定步骤如上所述;样品经过20分钟加热后,在烧瓶和冷凝器间插入一个迪安—斯达克分水器,从而有10mL的水被蒸馏掉;把未固化的样品放入螺丝帽的坛子中,连同固化的树脂一起交给实验指导老师;15单元到目前为止大多数的PVC生产通过悬浮聚合;在这个过程中,氯乙烯单体悬浮液体滴,在连续水相剧烈的搅拌和保护胶体的悬浮剂;使用单体溶自由基引发剂polymeri等自下而上发生在悬浮液滴内,通过一个机制,已被证明相当于本体聚合;商业植物是基于批量反应堆,这增加了支持的大小,多年来;原来的工厂建于1940年代通常由IOOO 加仑反应堆;在1960年代和1950年代这t0 3000一5000加仑和增加随后,在1970年代初,29000加仑反应堆系统开发的胫完全②,t0 44000加仑200立方米的德国公司Huls;目前一些新的工厂正在建造的反应堆由不到isooo加仑容量,有一个批处理大小约25吨单体;小型反应堆通常衬玻璃给光洁度,抵制存款的搁置在墙上;~大反应堆通常的抛光不锈钢;氯乙烯的聚合反应是一个放热反应的能力,移走热量通常试图减少反应时间的限制因素;随着规模的反应堆已经增加了表面积体积比,因此加重这一问题;内部冷却线圈通常不用作吸引存款和很难清洁,从而对产品性能有不利影响;问题通常是克服使用冷冻水或回流冷凝器的装置,通过氯乙烯单体的连续回流;利用其潜热冷却的目的;一个简单的悬浮聚合配方可能包含以下成分:冷水通常是首先向反应堆虽然有时预热;然后添加pH值调节剂紧随其后的是分散剂的形式解决方案;发起者年代立即撒到水相的表面密封反应堆然后撤离前去除氧,因为这可以增加聚合时间,影响产品性能;当引发反应完成乙烯氯化物被指控和加热反应堆的内容开始;反应但真正的,产品分子量的主要控制因素;通常是在50——70 'c导致反应堆压力范围100 - 165 psi;趋势是朝着大的操作只打开关闭反应堆维护或可能偶尔打扫道;”:在这种情况下所有的原料都是负责解决方案或分散体,一般不需要疏散的一步;当达到所需的转换了,通常75%一95%,反应可以如果需要化学short-stopped和剩余的大部分单体恢复;他产品泥浆然后剥下来非常低的残留氯乙烯治疗-水平表示“状态”姆温度升高,在反应堆或类似容器,或接触蒸汽在逆流多平台汽提塔;然后脱水离心法和由此产生的泥浆湿饼乾,多级闪蒸干燥机一般,虽然各种不同的干燥类型使用不同的生产;干燥后,产品是通过某种剥皮屏幕去除无关的大颗粒装袋之前或装载散装油轮;—T 16 Styrene-Butadiene Copolymer第十六单元丁二烯-苯乙烯共聚物合成橡胶工业,以自由基乳液过程为基础,在第二次世界大战期间几乎很快地形成;那时,丁苯橡胶制造的轮胎性能相当优越,使天然橡胶在市场黯然失色;丁苯橡胶的标准制法是组分重量分数组分重量分数丁二烯72 过硫酸钾苯乙烯25 肥皂片十二烷基硫醇水180 混合物在搅拌下50℃加热,每小时转化5%~6%,在转化率达70%~75%时通过加入“终止剂”聚合反应终止,例如对苯二酚大约的重量百分含量,抑制自由基并避免过量支化和微凝胶形成;未反应的丁二烯通过闪蒸去除,苯乙烯在萃取塔中通过蒸汽萃取剥离;在加入抗氧剂后,例如N-甲基-β-萘胺的重量百分含量,加入盐水,其次加入稀释的硫酸或硫酸铝后乳液凝胶;凝胶碎片被洗涤、干燥。

(节选)新能源材料外文翻译--存储锂离子的层状硅中锂的吸收和扩散

(节选)新能源材料外文翻译--存储锂离子的层状硅中锂的吸收和扩散
ABSTRACT:The energy density of Li-ion batteries depends critically on the specific charge capacity of the constituent electrodes. Silicene, the silicon analogue to graphene, being of atomic thickness could serve as high-capacity host of Li in Li-ion secondary batteries. In this work, we employfirst-principles calculations to investigate the interaction of Li with Si in model electrodes of free-standing single-layer and double-layer silicene. More specifically, we identify strong binding sites for Li, calculate the energy barriers accompanying Li diffusion, and present ourfindings in the context of previous theoretical work related to Li-ionstorage in other structural forms of silicon: the bulk and nanowires. The binding energy of Li is∼2.2 eV per Li atom and shows small variation with respect to Li content and silicene thickness (one or two layers) while the barriers for Li diffusion are relatively low, typically less than 0.6 eV. We use our theoreticalfindings to assess the suitability of two-dimensional silicon in the form of silicene layers for Li-ion storage.
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II. ATOM-RESONATOR COUPLING
*
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As shown in Fig. 1, the proposed system includes three parts: a disk nanomechanical resonator of radius R and thickness b and an atom trapped at a distance L above the nanomechanical resonator, which is capacitively coupled to a SCQ. The resonator consists of a piezoelectric film sandwiched between two metal electrodes. It has a fundamental dilatational resonance frequency ωm /2π of a few gigahertz [17] and can be cooled to its quantum ground state with conventional cryogenic ˆ †a ˆ (¯ h = 1) with refrigeration [1]. The Hamiltonian is ωm a ˆ † (a ˆ ), and mechanical the creation (annihilation) operator a oscillation generates, through the piezoelectric effect, a charge ˆ +a ˆ † ) on the electrodes, where σ0 is the magnitude σ ˆ = σ0 (a ˆ with of the charge. The charge creates an electric field E the magnitude E outside the resonator. The atom is trapped above the center of the upper disk where the electric field is perpendicular to the disk (along the z axis), so the atom-resonator coupling via the electric field is given by ˆz,a , where d ˆ a −m = E ˆ zd ˆz,a is the z component of the atomic H dipole moment operator. When the atom is in its ground state, the interaction between the electric field and the atom can be neglected due to the negligibly small dipole moments. Therefore, the atom can be excited to the Rydberg states to
dipole moments and choosing appropriate parameters of the resonator, we can make the atom-resonator coupling large enough. Recent experiments have shown that the SCQ can be coupled to a piezoelectric nanomechanical resonator [17]. Thus, a quantized mechanical resonator can be coupled to both the SCQs and the atoms. This hybrid system can be used to obtain an effective interaction between the SCQ and the atom via adiabatically eliminating the dynamics of the resonator and then allowing reversible quantum-state transfer between two systems. The idea of hybrid quantum systems has been proposed in recent years [18,19]. However, our study can combine scalable SCQ systems [20] with quantum memory realized by the neutral atoms. In contrast to the cavity-mediated schemes [21], the system here is a mechanical analog and has significantly smaller dimensions, which may provide a truly scalable approach.
PHYSICAL REVIEW A 83, 022309 (2011)
Coupling Rydberg atoms to superconducting qubits via nanomechanical resonator
Ming Gao,1,2 Yu-xi Liu,3 and Xiang-Bin Wang1,*
The Key Laboratory of Atomic and Molecular Nanosciences, Ministry of Education, Tsinghua University, Beijing, 100084, China 2 Department of Physics, National University of Defense Technology, Changsha, 410073, China 3 Institute of Microelectronics, Tsinghua University, Beijing 100084, China (Received 19 October 2010; published 11 February 2011) We propose a hybrid system to realize long information storage and fast quantum operation via Rydberg atoms and superconducting qubits (SCQs). The internal states of a Rydberg atom are coupled to a nanomechanical resonator. The atom-resonator coupling is achieved via an electric field generated by the quantized motions of the resonator and temporarily exciting the atom to Rydberg states. The coupling can be made large enough to allow quantum manipulation and measurement of the resonator via the atom. The resonator can also be coupled to a SCQ, and therefore the tripartite system can provide a quantum interface between the SCQ and the atom via the nanomechanical resonator. DOI: 10.1103/PhysRevA.83.022309 PACS number(s): 03.67.Lx, 03.67.Mn, 42.50.Ex, 85.85.+j
1
I. INTRODUCTION
ቤተ መጻሕፍቲ ባይዱ
Recently there has been great experimental progress in cooling micromechanical and nanomechanical resonators to their quantum ground states [1–3]. Coupling a quantized resonator to other quantum systems enables us to explore quantum mechanics at the mesoscopic scale. This can also be used for quantum-limited measurements and quantuminformation processing. Several hybrid systems have been studied, for example, the coupling of the nanomechanical resonator to photons via radiation pressure [4], to an atomic vapor via magnetic field [5], to a Bose-Einstein condensate via surface potentials [6], and to a superconducting qubit (SCQ) via electrical signals [1,7]. A few proposals also have been put forward to couple the nanomechanical resonators to the motions of ions [8] or molecules [9], to spins in solid-state systems [10], and to the displacements of a single atom in the cavity [11]. Experimental studies have shown that neutral atoms and SCQs are very good candidates for quantum-information processing. Neural atoms can be trapped with high precision at a distance of a few micrometers from the resonator by magnetic microtraps [12]. Atomic internal states can be easily manipulated and have long coherence time. Atomic Rydberg states are used to realize controlled interaction between the atoms [13,14]. The Rabi oscillations between the atomic ground state and the Rydberg state have been demonstrated [15]. On the other hand, the SCQ is one of the well-developed solid-state quantum devices; it can be easily controlled and has fast quantum operation time. However, its coherence time is relatively short [16]. Here we first study a method that enables a strong and switchable coupling between individual atomic internal states and a piezoelectric nanomechanical resonator. This atomresonator coupling can be switched off when the atom is in its ground state since the dipole moment of the ground state is small and the coupling can be neglected. Through temporarily exciting the atom into a Rydberg state with large transition
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